Weidlich / Grajcar, editors
URBAN ENERGY FLOWS Course Research Papers 2017 Urban Energy Flows - Course Research Papers 2017
XQ4 www.blauer-engel.de/uz195
Weidlich / Grajcar, editors Research Efficiency in Architecture and Planning HafenCity Universität Hamburg - Universität für Baukunst und Metropolentwicklung Überseeallee 16 - 20457 Hamburg
Impressum First published 2018 © HafenCity Universität Hamburg Professur REAP Revised by: Maria Grajcar, Ingo Weidlich Design and layout: Pia Schnellberger Print: oeding print GmbH Editors: Univ.-Prof. Dr.-Ing. Ingo Weidlich Dipl.-Ing. Mgr. Maria Grajcar, MA Tel.: +49 (0)40 42827 - 5700 E-Mail:ingo.weidlich@hcu-hamburg.de ISBN: 978-3-941722-64-4
Diese Veröffentlichung ist urheberrechtlich geschützt. Sie darf ohne vorherige Genehmigung der Autoren/ Herausgeber nicht vervielfältigt werden. Alle Angaben dieser Broschüre sind nach bestem Gewissen unter Anwendung aller gebotenen Sorgfalt erstellt worden Trotzdem kann von den Autoren und den Herausgebern keine Haftung für etwaige Fehler übernommen werden. DANKSAGUNG: Die Autoren und Herausgeber danken dem Energieforschungsverbund Hamburg für die Förderung dieser Publikation.
PREFACE
3
HYDROGEN AND SYNTHETIC METHANE IN THE FUTURE ENERGY SYSTEM
5
SUSTAINABILITY OF CHP FUEL CELLS
19
THE SHALE GAS INDUSTRY IN EUROPE: BARRIERS AND OPPORTUNITIES
35
COMPRESSION CHILLERS: OPERATION CHALLENGES RECOMMENDATIONS TO OPTIMIZE OPERATION
AND
50
ELECTRIC BUS ANALYSIS FOR BOGOTÁ PUBLIC TRANSPORTATION SYSTEM
64
ENERGY FROM NORTH TO SOUTH: NEW ELECTRICITY GRIDS FOR GERMANY
79
REFERENCES
93
3—
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— Ingo Weidlich, Maria Grajcar This is a collection of the six best research papers that were elaborated by REAP students of the 8th generation in the course Urban Energy Flows (UEF) in 2017. This collection shall give best practice to further generations of REAP students, who will participate in the UEF course and give appreciation to the excellence of the students’ work. When we dived into the lectures of Urban Energy Flows in summer term 2017 we were very curious and motivated but we did not know exactly what to expect. We wanted to transfer as much of our knowledge and professional experience from the energy sector as possible to the students. Time was short and the number of lectures was very limited because we decided to change from collective grades in groups to individual presentations and research papers. This was our concept to increase motivation for
the semester work. Students could choose from a broad range of topics representing the whole Urban Energy Flow – technologies and themes or come up with their own ideas. More than 30 presentations were given and the same amount of research papers was written. Maria Grajcar introduced a new methodology how the students could present their topics. Two options were offered to choose from “conference mode” and “university mode”. “Conference mode” meant something unusual could happen after the first five minutes of the presentation or within five minutes of Discussion section that could disturb the presenter (like in a real conference), while in “university mode” nothing unexpected was foreseen. Most students chose the training option “conference mode” and they learned to deal with impertinent questions, dinner offers, audience looking out of the window,
angry boss, foto shootings, tiny voices, badly translated comments, reckless noise, conversations …. Of course the presenting student did not know in advance what will happen. It was fun! More than 760 pages of research paper had to be reviewed and the results were more than satisfying. We chose the six most excellent ones from our perspective. Without doubt there are more impressive papers written by this generation, so these five only represent the great work of: Feras Abu Diab, Saad Afridi, Ahmed Ahmed, Amir Mohammad Alinaghian, Sindre Andresen, Anastasiya Andrukovich, Animesh Behera, Anda Bufi, Adrian Burduh, Maximilian Busch, Alessandro Caraccini, Elena Chikulaeva, Patricia Dreifus Zaluski, Jonas Falck, Nasimeh Fallahranjbar, Juliane Fritz Benachio, Laura Garcia Rios, Xhelona
Haveriku, Rihab Hlel, Malek Ismail, Delaram Jenab, Noriko Kakue, Nurnida Kemala Ayu, Abdullah Khisraw, Yesim Köroglu, Rodolfo Mesquita Macedo, Comfort Mosha, Mahmoud Moursy Hussein, Gabriel Nießen, Gustavo Pagliari Valerio Dos Santos, Pakdad Pourbozorgi Langroudi, Pragnya Rayaprolu, Kristina Rumiantceva, Pia Schnellberger, Jessica Sellin, Oluwaseun Shittu, Muhammad Shoaib, Tobias Teferra, Mariya Todorova, and Sepideh Yari. Thank you and we want more in the future! Univ.-Prof. Dr.-Ing Ingo Weidlich Dipl.-Ing. Mgr. Maria Grajcar, MA
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—6
INTRODUCTION
— Anastasiya Andrukovich
Anastasiya Andrukovich is an architect and urban planner from Belarus, co-founder of the NGO Minsk urban platform. The main professional focus is a city as a complex organism. Currently, she is a REAP master student at HafenCity University in Hamburg.
KEYWORDS Hydrogen economy, energy carrier, fuel cell, decarbonization, electrolysis, methanation, gasification, green gas, synthetic methane, torrefaction, syngas.
ABSTRACT Climate change driving by constantly increasing energy demand is happening. Certainly, the necessity in transformation of global energy system towards decarbonized economy is recognized. Hydrogen is considered as a possible solution, capable of assisting in issues of environmental emissions, sustainability and energy security. Hydrogen is a green energy carrier which has the potential to ensure energy demand without an impact on the environment, both locally and globally. However, the transition from a carbon-based system to a hydrogen economy requires a significant technological breakthroughs and socio-economic
changes. In this case, synthesis of methane can be an intermediate step capable to solve storage and distribution problems connected with current hydrogen industry. Development of a cross-sectoral system solution power-to-gas solves the problem of fluctuations electricity generation from renewable sources converting electric energy to chemical one and, as a result, obtaining hydrogen and methane. The synergetic technology unifies renewable energy production, mobility, industry, heat supply and power generation.
LIST OF ABBREVIATIONS CHP – combined heat and power GHG – greenhouse gas SNG – substitute natural gas EU – European Union PtG – Power-to-gas
The problem of anthropogenically driven climate change caused by constantly rising energy demand is the main challenge facing humankind. Additionally, in the condition of impending exhaustion of fossil fuel resources the society cannot rely anymore on the current oil orientated economy. Thus, the establishment of carbon-neutral and environmentally friendly energy system is the key task in order to save the world for the next generations. The transformation of economy from fossil fuel-based to renewable sources has three main questions: — Efficient conversion of renewable energy into electricity; — Electricity storage; — Efficient production of a synthetic fuel. Addressing the aforesaid, hydrogen is conceded as one of the most promising energy carriers in the future energy sector. Unlike oil, gas or coal, hydrogen is not a primary source. It does not exist freely in nature and has to be produced from hydrogen-containing sources using energy and then transported for future use where its latent chemical energy can be fully realized (Edwards et al., 2007). On the one hand, accomplishments in fuel cell technology have substantially increased the role of hydrogen in the energy system over the last decade. Combining hydrogen and oxygen, a fuel cell converts chemical potential energy into electrical energy. On the other hand, the development of power-to-gas system offers to convert the electricity from
renewable energy sources into hydrogen or methane and feeding it into the gas infrastructure, or using it directly (German Energy Agency, 2015). Despite that hydrogen can be obtained from diverse sources, both renewable and nonrenewable, there is a wide range of challenges connected with high cost of «green» production, safety, storage and transportation. Moreover, speaking about hydrogen injection directly to the gas grid, maximum hydrogen content in the natural gas infrastructure must be in the range from 0.1 to 10% in EU depending on the grid requirements, and up to 2 % in Germany (German Energy Agency, 2015). Recognizing the growing sector of renewable energy production, the efficient energy storage and delivery are the preconditions for the further hydrogen development. Taking into consideration limitations connected with current hydrogen industry, methanation can be the second step in the PtG system where SNG produced in the reaction of hydrogen and carbon dioxide can be fed in the gas grid without significant restrictions. Thus, development and wide introduction of methanation technologies is transition stage towards hydrogen economy where hydrogen is a major carrier in the energy supply cycle. However, any transitions from a carbonbased to hydrogen-based economy require scientific researches and face technological, socio-economic obstacles. To sum up, hydrogen economy is the alternative direction in order to replace fossil fuel-based economy. PtG technology is central to the hydrogen economy. It is a cross-sectoral
7—
system which creates synergy between renewable energy production, industry, mobility, heat supply and power generation. This paper is dedicated to analysis of the hydrogen and synthetic methane potential for the transition to the decarbonized economy.
—8
Germany in particular are used as a ground for the evaluation of hydrogen and synthetic methane potential in the future energy system.
HYDROGEN IN THE ENERGY SYSTEM
The paper provides the vision of hydrogen
Hydrogen is considered as a clean, flexible energy carrier. Hydrogen utilization is a free of toxic gas formation and GHG emission, can easily be applied in fuel cells for electricity
and synthetic methane role in the future energy system, prospects and challenges in order to achieve decarbonized economy. Hydrogen and synthetic methane production, storage, delivery, safety issues and challenges are analyzed and presented in the chapters 3 and 4. Holistic cross-sectoral system solution
generation. However, there is a significant challenge for the current energy industry. Being the simplest and most abundant element in the Universe, up to 75 % [Periodic Table, 2017], molecular hydrogen (H2) does not occur naturally in the high concentration. Hydrogen is normally bound up with other
unifying renewable energy production, mobility, industry, heat supply and power generation is discussed in the chapter 5. The resent researches and implemented projects from the USA, EU in general and
elements in chemical compounds, for example, water and hydrocarbons are the most common. Therefore, hydrogen can be obtained from hydrogen-containing sources using the diverse technologies.
MATERIALS AND METHODS
Production Hydrogen is produced from wide range sources using different methods: -- From hydrocarbons (natural gas, oil);
coal,
-- From water by electrolysis, photolytic or thermal splitting;
2H2O + energy −> 2H2↑ + O2↑
-- From biomass and municipal waste by fermentation, gasification and pyrolysis.
The reverse of the reaction is employed for electricity generation in the fuel cell:
Such a variety of sources assures the energy security for hydrogen-based economy. The manufacture of hydrogen from fossil fuels using reformation and gasification processes is always accompanied by carbon dioxide emission. Currently, up to 95 % of the produced hydrogen is from coal, oil or natural gas (Hosseini and Wahid, 2015). This fact is explained by more mature mechanisms of hydrogen production from hydrocarbons and high cost of technologies based on renewable sources. However, to achieve the benefits of a truly sustainable hydrogen energy economy, we must clearly move to a situation where hydrogen is produced from non-fossil resources, principal among these being water (J.A. Turner, 2004). Electrolysis of Water
Figure 1: Hydrogen production sources.
a synergy of the renewable energy sector and hydrogen production makes hydrogen a buffer mechanism to cap fluctuations in electricity generation. The process of electrolysis is described by following formula:
Hydrogen can be obtained via electrolysis of water using any electrical source. The water splitting into hydrogen and oxygen using renewable sources of energy is a promising solution for hydrogen production. The process is not only environmentally friendly but also solves the problem of electricity storage from renewable sources transforming PtG. Thus,
2H2 + O2 −> 2H2O + energy The price for hydrogen yield from electrolysis depends on the electricity cost and materials used for electrodes‘ coating, for instance, platinum. Currently, the green production is not cost-competitive with the production from fossil hydrocarbons. Hydrogen from biomass The diverse range of biomass sources is applied for hydrogen production, for instance, wood, agricultural crops, municipal solid waste, waste from food processing. Biomass can easily be converted into a number of liquid fuels, including methanol, ethanol, biodiesel, and pyrolysis oil, which could be transported and used to generate hydrogen on site (Turner, 2004). Methods of hydrogen production from biomass: -- Biological -- Anaerobic digestion -- Fermentation -- Metabolic processing -- Thermo-chemical
9—
— 10
Process
sector and another for stationary applications.
following options:
Cost of Hydrogen (US Dollar per kg), 2015
Cost of Hydrogen (Euro per kg), 2015*
Natural gas reforming
1.03
0.93
restrictions of hydrogen storage are less critical
Natural gas reforming + CO2 capture
1.22
1.1
than those for vehicles; stationary hydrogen
Coal gasification
0.96
0.87
storage systems can occupy a large area,
-- Hydrogen carriers such as solid metal
Coal gasification + CO2 capture
1.03
0.93
operate at high temperatures and pressures
hydride, liquid organic hydrogen carriers
Electrolysis (wind power)
6.64
6.03
and have extra capacity to compensate for
or hydrogen carriers in the form of fuels
Biomass gasification
4.63
4.2
slow kinetics (Edwards et al., 2007).
such as ammonia;
Biomass pyrolysis
3.8
3.45
Currently, there are several probable methods
Nuclear thermal splitting of water
1.63
1.45
for the hydrogen storage (Züttel, 2003):
Gasoline (for reference)
0.93 0.84 * exchange rate US Dollar - Euro is 1.1 (December, 2015)
Table 1: The cost comparison of hydrogen based on various production processes.
-- Gasification -- High pressure aqueous -- Pyrolysis The cost comparison of hydrogen based on various production processes is provided in the table 1 ( Hosseini and Wahid, 2015). Thus, hydrogen production from carbon-free sources with the low price is the long term aim
Secondly, hydrogen is the lightest element and has a very low energy density per unit volume. But even when hydrogen is stored at high pressures, it still does not provide sufficient energy density. Significant high-pressure decentralized storage is required for transport applications due to space constraints (Staffell and Dodds, 2017). At normal conditions, 4 kg
For stationary applications, weight and volume
-- High-pressure gas cylinders (up to 800 bar); -- Liquid hydrogen in cryogenic tanks (-253°C);
-- Tube trailers for compressed gas; -- Tanker trucks for liquefied hydrogen;
-- Natural gas grid injection; -- Hydrogen high-pressure pipeline The current storage and transportation system for conventional fuels cannot be easily transformed for the hydrogen use. Obviously,
-- Absorbed on interstitial sites in a host metal
that infrastructure requires major technological
(at ambient pressure and temperature);
breakthrough in order to impact on the
-- Through oxidation of reactive metals, for example, lithium, sodium, magnesium, aluminum, zinc with water; -- Geological storage.
transition to the hydrogen economy.
SAFETY Safety concerns are the biggest barriers for the widest introduction of hydrogen technologies. Thus, designing facilities and infrastructure
of hydrogen – sufficient amount to drive a fuel cell car up to 500 km – occupies a volume of
Geological storage is one of the most
for its production, storage and delivery a
48 m³ (Edwards et al., 2007).
diverse range of factors have to be taking into
Storage and delivery
promising technologies for large-scale storage
Thirdly, it has to be compressed to liquid
at low cost (Sørensen, 2006). The first option is
consideration.
Hydrogen can be stored as a compressed
state in order to decrease the volume of
deposit in cavities created in salt domes. The
First of all, there is a risk of gas leaks. Hydrogen
gas, cryogenic storage as liquid hydrogen,
storage facilities. Today, liquid hydrogen,
next variation is aquifers in the water carrying
is lighter than air and has a rapid diffusivity, 3.8
metal or chemical hydrides. However, storage
which is the most common form of storage,
layers capped with impermeable layers
times faster than natural gas (Schüth, 2009).
availability and feasibility are crucial and
is hard and expensive to handle because
above into which hydrogen can be pumped
Despite hydrogen is the lightest element in the
the most technically challenging obstacles
hydrogen becomes a liquid only at the ultra-
replacing water. Underground storage is also
universe, it can become a fire hazard being
towards the wide use of hydrogen as an
frigid temperature of -253°C at atmospheric
applicable for compressed gas or liquid
confined in structure containing raising gas.
effective energy carrier.
pressure (Koeneman, 2016).
hydrogen tanks for smaller volume and depth
Hence, the proper design of facilities with
First of all, hydrogen is prone to leakage due
Finally, safety aspects have to be taken into
in order to safe ground space.
ventilation helps hydrogen to escape in case
to small molecules size. Besides, hydrogen
consideration due to hydrogen volatility and
The unique chemical properties that make
of an unexpected release is the precondition
tends to permeate metal. Therefore, storage
flammability.
hydrogen challenging to store, also make it
for infrastructure.
facilities and infrastructure have to be safe,
The hydrogen economy requires two types of
challenging to transport (Koeneman, 2016.).
Secondly, hydrogen is odorless, colorless
durable and fulfilled from reliable materials.
hydrogen storage systems, one for transport
Hydrogen delivery system is presented by
and tasteless. Therefore, human senses
for hydrogen economy establishing.
11 —
— 12
SYNTHETIC METHANE IN THE ENERGY SYSTEM
cannot detect the leaks. Thus, industries have
with several physical parameters including
to install sensors in order to distinguish that
temperature and pressure [Rivkin et al., 2015].
problem. At the same time, natural gas also
This characteristic determines limitations in
has no odor, color or taste, but industry adds a
terms of hydrogen concentration in the gas
sulfur-containing odorant to make it detectable
grids. Thus, in Europe the maximum hydrogen
by people. Unfortunately, the same approach
content allowed by national standards for
has obstacles in hydrogen sector because
biomethane injection into the grids generally
odorants contaminate fuel cells.
varies from 0.1 to 10 % in volume depending
Thirdly, hydrogen has high flammability and
on the country (ENEA Consulting, 2016).
might combust in the presence of oxygen.
Finally, the widespread use of hydrogen could,
However, mixtures of hydrogen gas and air do
of course, have unknown environmental effects
not react unless ignited with a flame or spark,
due to increased anthropogenic emissions
Taking into account current immaturity of hydrogen technologies, methanation as a means of producing synthetic natural gas is the next step of wind or solar energy transformation to gas. Methanation is the conversion of carbon oxides to methane through hydrogenation – a chemical reaction between molecular hydrogen and another compound or element, usually in the presence of a catalyst.
resulting in a fire or explosion. Hydrogen can
of molecular hydrogen to the atmosphere
Production
be explosive at concentrations of 18.3 - 59%
(Tromp et al., 2003).
Obtained hydrogen from the electrolysis can be converted to synthetic or substitute natural gas (SNG) using carbon dioxide or carbon
but oxygen must be present in a concentration of at least 10% pure oxygen or 41% air (Schüth, 2009). It is important to emphasize that an
Challenges The current challenges are connected with the
explosion cannot occur in a tank or any
development of hydrogen production, storage,
storage facility that contains only hydrogen.
distribution and utilization technologies. Due
Moreover, there is very little probability that
to the low energy density and volatility, the
hydrogen will combust or explode in open air
design and development of infrastructure
due to its rapid diffusivity and tendency to rise
represents a unique task.
rapidly.
Moreover, economic feasibility is the main
Fourthly, hydrogen can damage storage,
barrier for the wide introduction of hydrogen
piping, and appurtenances materials through
technologies. Firstly, the enormous expenses
processes that are partially a function of the
are
relatively small size of the hydrogen molecule
processes
(Rivkin et al., 2015). Basically, hydrogen
pressure storage and distribution, liquefaction
„attacks“ certain material and this ability is
of hydrogen. Secondly, catalysts, materials
referred to hydrogen embrittlement. Hydrogen
for storage and transportation are significantly
embrittlement is a type of deterioration which
influence the final cost.
can be linked to corrosion processes. As
In addition, safety is not only a technological
a result, metals such as steel become
issue, but also the major psychological and
brittle and fracture due to the introduction
sociological issue facing the adoption of the
and subsequent diffusion of hydrogen into
hydrogen economy [Edwards et al., 2007].
the metal. The mechanisms of hydrogen
In order to integrate hydrogen into energy
embrittlement can be complex and vary
system, it has to be conceded safe by society.
connected such
with as
energy-intensive electrolysis,
high-
Figure 2: PtG, methanation.
monoxide in a methanation process. This methane synthesize can be either a biological or chemically catalyzed reaction: CO2+4H2 −> CH4 + 2H2O CO+3H2 −> CH4 + H2O Catalytic methanation reactors are typically operated at temperatures between 200 °C and 550 °C and at pressures ranging from 1 to 100 bar (Gotz et al., 2015). The methanation is highly exothermic reaction. 165.1 or 206.3 kJ is produced during the catalytic methanation of 1 mol of carbon dioxide or carbon monoxide, respectively (Gotz et al., 2015). Nickel is considered as the optimum catalysts option for the reaction in comparison with other possible metals such as ruthenium, rhodium, and cobalt due to its relatively high
13 —
— 14
activity, methane selectivity up to 100%, and
is more robust against impurities than
To sum up, there are not only economic
catalytic methanation. For instance, relatively
low raw material price (Müller et al., 2013). For
catalytic
that
advantages but also time saving benefits
cheap nickel based catalysts require a high
example, the cost of ruthenium is 1750 euro
catalytic methanation requires high purity
with regard to permission of authorities,
purity of the feed gas. There is a dilemma
per kg and Nickel is 9.75 euro per kg, August
of the feed gas and, as a result, there are
public accepters, design and implementation
between technology, materials and feedstock
2017 (Consensus economist, 2017).
additional expenses connected with refining.
processes.
The required carbon oxides can be obtained
preferences in order to achieve economic
Furthermore, final cost of catalytic methanation
from exhaust and process gases of industries
efficiency.
is influenced by catalysts price. On the other
CHALLENGES
or fossil power plants, biogas plants, or from
On the one hand, methanation solves the
Nevertheless, taking into account obstacles
hand, the efficiency of catalytic methanation is
the atmosphere and sea water but using
higher and the reactors size is much smaller
problem of hydrogen storage and delivery.
connected with the current hydrogen storage
certainly more energy-demandable methods.
for the same volume of supplied gas.
On the other hand, there are a range of
and delivery, synthetic methane production
challenges connected with technological
considered as a bridge technology towards
Storage and delivery
processes and economic feasibility.
hydrogen economy.
The biological methanation is the next option
SNG produced via methanation is nearly
First of all, methanation is the second step
for PtG process chain where microorganisms
identical to fossil natural gas. However, the
work as biocatalysts. The first step is the
remaining sulphur components still have to
hydrolysis of biomass to simple monomers
be removed prior to gas grid injection (Gotz
in a biogas plant. As a result, methane and
et al., 2015). Therefore, SNG can be fed into
carbon dioxide are produced. Then, carbon
natural gas grid without significant limitation
dioxide is converted to methane by feeding
and already existing delivery and storage
hydrogen into the reactor in the presence
gas infrastructure can be applied for the
of microorganisms. Biological methanation
transfer of renewable electricity in the form
proceeds under anaerobic conditions at
of SNG. Thus, investments in construction of
temperatures between 20 and 70 °C and
the new infrastructure for transport, storage
mostly at ambient pressure (Gotz et al., 2015).
and utilization of synthetic methane are not
On the one hand, biological methanation
required.
The methanation waste heat can be applied for further use in a steam power cycle.
methanation.
It
means
in the PtG process; consequently, additional chemical conversion causes energy losses (Gotz et al., 2015). The efficiency has to be
Future energy system Apparently, the dominating fossil fuel-based energy system can be gradually replaced
improved at the level of electrolysis and then
by the renewable sources-based one. Wide
heat from the methanation reactor has to be
introduction of hydrogen as an energy carrier
utilized.
is considered as a promising vision for the
Secondly,
a
range
of
challenges
are
connected with tolerance of impurities in Path
future synergetic energy system. Current technologies
Efficiency (%)
connected
Boundary conditions
Electricity to Gas Electricity −> Hydrogen
54 -72
Including compression to 200 bar
Electricity −> Methane (SNG)
49 - 64
(underground storage working pressure)
Electricity −> Hydrogen
57 - 73
Including compression to 80 bar
Electricity −> Methane (SNG)
50 - 64
(feed in gas grid for transportation)
Electricity −> Hydrogen
64 - 77
Electricity −> Methane (SNG)
51- 65
Without compression
Electricity to Gas to Electricity Gasoline (for reference)
0.93
0.84
Electricity −> Hydrogen −> Electricity
34 - 44
Conversion to electricity:
Electricity −> Methane −> Electricity
30 - 38
60%, compression to 80 bar
Electricity to gas to combined heat and power
Figure 2: Energy losses caused by chemical conversion.
with
Electricity −> Hydrogen −> CHP
48 - 62
40 % electricity and 45% heat,
Electricity −> Methane −> CHP
43 - 54
compression to 80 bar
Table 2: Efficiencies for different Power-to-Gas process chains.
synthetic
15 —
— 16
methane production are the transition stage
and reasonable. Secondly, the synergetic
synergy between the renewable energy
methanation, synthetic methane is nearly
towards carbon-free economy.
approach does not allow any waste providing
production and transformation it into chemical
identical to natural one and can be integrated
The future energy system has to be based on
second value for it and integrating into cycle.
energy, mobility, industry, heat and power
in the gas infrastructure without any further
the principle of valorization. It is the productive
Thirdly, all the by-products of the processes
supply.
restrictions.
and efficient use of resources avoiding losses.
have to be applied in the system.
POWER-TO-GAS TECHNOLOGY
However, transition processes within the
First of all, energy consumption has to be smart
PtG technology implements an idea of the
Power-to-gas is a cross-sectoral system solution
unifying
renewable
energy
production, mobility, industry, heat supply and power generation. PtG can be conceded as a storage method which converts electricity from renewable energy sources to hydrogen or methane solving the problem of fluctuations electricity generation from renewable sources. Thus, the over produced electricity is applied for water electrolysis to obtain hydrogen. In the result of electrolysis, water is split into hydrogen and oxygen. The generated oxygen can be released to the atmosphere or applied
Figure 3: Research and pilot PtG projects in Germany.
Power-to-Gas chain are associated with energy losses. The conversion efficiencies can be improved by either technical progress in the single conversion steps, namely water electrolysis and methanation or by synergies with industrial processes which are coupled with the PtG plants (Tichler et al., 2014). The German Energy Agency (DENA) initiated the Strategy Platform to support the use and development of the PtG system solution. Over 20 research and pilot projects in Germany demonstrate technical feasibility of PtG system (German Energy Agency, 2015).
for industrial needs depending on the existing
SYNERGY
demand and synergy level between different
Fluctuating
sectors. At the same time, hydrogen can be
generation in the renewable energy sector
fed either in an own hydrogen distribution grid
poses a huge challenge how to store the
or injected in the natural gas grid, transported
electricity. Transformation of electricity into
by truck and train or stored. This way, electricity
chemistry, PtG technology, might be a solution.
can be stored, distributed and made available
Water is a basic to a PtG installation. Thus,
for various energy usage scenarios (German
hydrogen and oxygen are generated from
Energy Agency, 2015).
water via electrolysis obtaining electricity from
The second possible step in the chain is
renewable sources. Received hydrogen can
methanation. It is a chemically or biologically
be used in the full cell, transport sector, fed
catalyzed reaction of hydrogen and carbon
into the gas greed or applied to the chemical
dioxide resulting to synthetic methane or other
industry as a widely used feedstock. Heat as
words substitute natural gas obtaining. The
a by-product of electrolysis can be fed into the
necessary carbon dioxide can be derived
district or local heating network. In turn, oxygen
from biogenic carbon, for example, biogas,
is the important element in the next value chain,
sewage gas, biomass gasification, breweries,
gasification of biomass. At the base of this
and bioethanol industry or from conventional
process, organic woodstock is transformed
power plants and industrial processes. Via
into biocoal thought torrefaction. Torrefaction is
character
of
the
electricity
17 —
— 18
CHALLENGES
role in a regenerative, environmentally sound
The idealistic approach unifying renewable
and sustainable energy system. The growing
energy production, mobility, industry, heat supply and power generation have numerous
contributes to technology enhancement.
barriers in the real implementation.
DISCUSSION
Firstly, the possibility to integrate the full value
Broad implementation of hydrogen and
chain between various stakeholders depends on the physical location. For example, oxygen after electrolysis can be used in biogas plant. Taking into consideration that oxygen is usually transported in the liquid condition the distance for supply this by-product to the next
Figure 4: The synergetic model of the energy system.
fraction of renewable energy generation
synthetic methane into energy system is the way towards decarbonized society. Thus, PtG is the promising system solution for the future energy sector. However, the process chain contains the numerous quantities of stages. Thus, the further development has to avoid
value stage has to be minimized or it has to be
unnecessary conversion steps whenever
utilized at the site of electrolysis otherwise the
possible in order to reduce losses and
solution is not technically and economically
increase efficiency. Therefore, economic and
relevant.
technological feasibility will assure benefits of
Secondly, current transformation chain from
the green system in comparison with fossil fuel-
electric energy to chemical and back to
based one. The wide introduction of hydrogen
electric one contains too many steps which
and synthetic methane contributes to the
reduce the efficiency and, consequently, not-
energy security due to multiple sources and
competitive on the market. Thus, the efficiency
production methods. In addition, synergetic
can be increased through technological
model offers numerous options for business
breakthroughs
losses
development due to its technical flexibility and
minimization.Thirdly, the profitable business
the wide range of applications of hydrogen,
a thermal process used to produce high-grade
methane, carbon dioxide, carbon monoxide
solid biofuels from various streams of woody
and it is the source of various gas applications.
biomass or agro residues heating the biomass
Firstly, syngas is a green feedstock for many
to temperatures 250-300°C in a low-oxygen
processes in chemical industry. For example,
condition (Blackwood technology, 2017). The
syngas is applied as an intermediate in
end product is a stable, homogeneous, high
the industrial synthesis of ammonia and
quality solid biofuel with far greater energy
methanol.
models have to be developed in order to
density and calorific value than the original
converted to hydrogen. Thirdly, upgraded to
methane, and sub-products of technology.
establish economy of scale. Optimized
feedstock. The energy value is doubled with
a green gas, synthetic methane, it provides
Moreover, there are also opportunities to create
business models are based on an integrated
innovative new businesses in green industry.
this treatment. In addition, oxygen can be
energy for households, mobility, and industry.
value chain approach for a most beneficial
The transformation process involves not only
used in other industrial production processes,
The gasification process is accompanied with
combination of input and output parameters
technical development but also adjustment of
like the chemical or the metallurgical industry.
the carbon dioxide release. Combining it with
(Breyer et al., 2015).However, in the long-
legal frameworks and formulation of strategies
However, the utilization of oxygen depends
hydrogen, we get synthetic methane again.
term perspective PtG indeed can play a key
at local and international level. —
strongly on the local conditions, particularly
Moreover, carbon dioxide can be captured
the distance to the potential consumers and
from the conventional coal power plants or
the consumer demand (Tichler et al., 2014).
other industries for example cement or steel
The next step is the production of syngas
production. This integration allows reducing
feeding the biocoal into gasification process.
carbon dioxide emissions in the transition
Syngas is the rich mixture of hydrogen,
phase towards hydrogen economy.
Secondly,
syngas
can
be
towards
transition
19 —
— 20
— Noriko Kakue
Noriko Kakue graduated from San Francisco State University with B.A. Environmental Studies concentrating on the Urban Environment. After working in both governmental and nongovernmental planning and developing sectors in the U.S. and Bangladesh, she entered M.Sc. REAP program with an interest in sustainable infrastructure systems.
KEYWORDS
INTRODUCTION
CHP, Fuel Cell, Heating, Electricity, CO2, Life
Combined Heat and Power (CHP) fuel cell is
Cycle Assessment, Japan, Natural Gas
a power generation system for commercial,
ABSTRACT
industrial and residential buildings, and its
Concerns over climate change shifted the world towards the low-carbon society in the last few decades and energy is one of the most influenced sectors in this challenge. The technology of CHP fuel cell utilizes hydrogen as its primary source that produces no CO2 emission, and also has a high efficiency
hydrogen extraction from natural gas, CHP fuel cells generate no significant emission during electricity or heat generations. There are a few studies conducted to evaluate the overall environmental impact of this emerging technology, despite the fact the mass production of micro-CHP fuel cell for residential home and commercial CHP fuel cells is taking place currently. This paper discusses on the overall sustainability of the CHP fuel cells from its environmental impacts measured from its life cycle assessment and hazardous gas emissions.
METHODOLOGY The argument on this paper is constructed through literature reviews. The data used for this paper is collected from various sources including official reports from government and research institutions. The section, CHP Fuel Cells in Japan, mostly compares the before and after of Fukushima Daiichi nuclear disaster in that these used data are especially time sensitive. All currency such as U.S. Dollar and Japanese Yen are converted in Euro with the average exchange rate of August 2017.
usage is expanding around the world. There are several factors brought CHP fuel cells under the spotlight at the current energy market – for example, the shift in primary energy source due to climate change, price reduction in micro-CHP fuel cells due to technology improvement, and the anti-nuclear movement
by reusing waste heat as a thermal energy
which drove the public more focused on safer
source that it has been under the spotlight as
and reliable power generation.
a stable low-carbon energy solution. While most studies on CHP fuel cells concentrate
CHP fuel cells reuse the waste heat from
on the environment impact at its usage stage,
electricity generation to heating of the building
lifetime impact of the system though life cycle
or water that the total efficiency of the system
assessment has been neglected. Through
is higher than that from other power generation
literature reviews on various international
systems such as combustion, hydroelectric,
researches, this paper concludes that the
and from renewable sources. Although
sustainability of CHP fuel cell is questionable.
CO2 are produced during the process of
Figure.1: (a) Electrolysis of water where electric current separates water into hydrogen and oxygen. (b) Reverse electrolysis where hydrogen and oxygen recombined and an electric current is produced.
21 —
— 22
BASIC TECHNOLOGY OF FUEL CELLS AND CHP FUEL CELLS
Even the most efficient combustion power
There are four types of CHP fuel cells available
plant in the recent years can reach about 60%
in the current market: Low-Temperature (LT)
The technology of CHP fuel cells are applied
of electric efficiency and the rest is discharged
and High-Temperature (HT) Proton Exchange
to commercial, industrial and residential
as waste heat (Ikegami, 2016). Electric
Membrane/Polymer
buildings to provide both electricity and
efficiency can be calculated as the equation
Phosphoric Acid (PAFC), Molten Carbonate
heat. There are various sizes of CHP fuel
below:
(MCFC) and Solid Oxide (SOFC). The
cells systems available depending on the
Electric Efficiency =
difference is based on the material used for its
electricity demand of the building or the
(Eff FPS * H2 Utilization * EffStack * EffPC)* * HHV LHV
complex – typically 200 to 2800kW of capacity is considered for commercial and industrial use and 3 to 10kW for residential and small commercial use (U.S. Environmental Protection
Agency,
2015).
The
basic
principle of the fuel cell system was invented by Sir William Grove in late 1839, where he demonstrated a hydrogen fuel cell (Figure 1). In his demonstration, water (liquid) is being electrolyzed into hydrogen (gas) and oxygen (gas) by passage of an electric current as
Where: Figure 2: Basic structure of fuel cell and its chemical reactions.
when drawing a useful current. In order to produce useful voltage, multiple cells must be connected in series. The connection of such fuel cells is known as a stack (Laeminie and Dicks, 2003). As illustrated in the figure, this chemical reaction discharges only H2O
Eff FPS
= Fuel Processing Subsystem
Efficiency, LLV (LHV of H2 Generated/LHV of
Membrane
(PEMFC),
catalyst electrolyte, and each type has unique strengths and characteristics (Figure 3). All CHP fuel cell systems utilizes hydrogen from hydrocarbon fuels as its primary fuel as shown in the figure above, therefore can be also operated by variety of alternative gaseous fuels including:
Fuel Consumed)
-- Natural gas: methane from the pipeline.
H2 Utilization = % of H2 actually consumed in
-- Liquefied petroleum gas (LPG): propane
the stack EffStack
= (Operating Voltage/Energy
Potential ~1.23 volts)
and butane mixtures. -- Sour gas: unprocessed natural gas as it comes directly from the gas well.
(water) and heat in the end of the process.
EffPC
By using the same structure with different
generated) (auxiliary loads are assumed dc
stack and electrolytes, fuel cell can produce
loads here)
different levels of power and thermal energy
HHV = Higher Heating Value
that currently the technology is utilized to power
LHV = Lower Heating Value
military and space equipment, transportation,
(U.S. Environmental Protection Agency, 2015)
special vehicles, and also as a backup power,
The
portable power and distributed generation
generation is utilized in CHP system for
2H2 + O2 −> 2H2O + e
system (U.S. Department of Energy, 2011).
-- Manufactured gases: typically low- and
heating of the building or the facility, and as a
medium-Btu gas produced as products
Fuel cells function based on this principle. In
CHP fuel cell is based on the same technology
result, the total CHP efficiency can reach 70-
of gasification or pyrolysis processes
order to increase the efficiency of the system,
aside from the fact that the thermal energy
90%. CHP efficiency can be calculated as the
(U.S. Environmental Protection Agency,
thinly layered electrodes and electrolyte are
produced during the reverse electrolysis is
equation below:
2015).
used to maximize the contact area between the
utilized as a heating source. When fossil fuel
CHP Efficiency =
gas, the electrode and the electrolyte, and to
was used for combustion to rotate turbine
minimize the distance between the electrodes
to generate electricity, the chemical energy
(Laeminie and Dicks, 2003) (Figure 2).
cannot be converted 100% electric energy
Energy Used (Natural Gas)
The voltage of a fuel cell is small, about 0.7V
due to the second law of thermodynamics.
(U.S. Environmental Protection Agency, 2015)
shown in the chemical equation below. 2H2O + e− −> 2H2 + O2 When the power supply has been replaced with an ammeter, and a small current flows while recombining hydrogen and oxygen. This reverse electrolysis is where the electricity is produced. −
=
= AC power delivered/(dc power
heat
-- Biogas: any of combustible gases produced from biological degradation or organic wastes.
produced
during
-- Industrial waste gases: flare gases
electricity
Energy Generated (Electricity + Heat)
and process off-gases from refineries, chemical plants and steel mill.
However, the operations with alternative gaseous fuels require appropriate system design and might cause inefficiency and affect durability of the stack. Therefore, most systems ended up utilizing natural gas, which
23 —
— 24
Type
LT-PEMFC
HT-PEMFC
PAFC
Operating Temperature 60-80°C
110-180°C
160-220°C
Typical Stack Size
< 1kW–
< 1kW–
400 kW
100kW
100kW
100 kW module
Electric Efficiency
MCFC 600-700°C
SOFC 800-1000°C
300 kW-3MW 1 kW–2 MW
Electrical Efficiency (%)
300 kW
Fuel Input (MMBtu/hr)
module
CHP Efficiency (%)
40-60%
50-60%
36-45%
55-65%
55-65%
Power to Heat Ratio Net Heat Rate (Btu/kWh)
87-90%
85-90%
85-90%
85%
90%
Common Electrolyte
Perfluoro
Perfluoro
Phosphoric
Solution
Yttria
sulfonic acid
sulfonic acid
acid soaked
of lithium,
stabilized
in a matrix
sodium, and/ zirconia or potassium soaked in a matrix
Mobile Ion
H+
H+
H+
Fuel Source
Natural gas
Natural gas
Natural gas
CO32-
Natural gas,
O2-
Natural gas
biogas, H2,
H2,
H2,
H2, CH4
H2, CH4, CO
methanol/
methanol/
(external
(external
(internal
ethanol
ethanol
reformer)
reformer)
reformer)
(external
(external
reformer)
reformer)
Residential,
Residential,
Commercial
Utilities, large
Commercial
small
small
buildings-
universities,
buildings-
commercial
commercial
baseload
industrial-
baseload
baseload Quick start-
Quick start-
Higher
Variety of
up,
up,
tolerance
catalysts can catalysts can
Sensitive to
Sensitive to
to fuel
be used,
fuel impurities fuel impurities impurities,
Variety of
Long start-up Long start-up
Figure 3: Characteristics of different CHP fuel cells.
System 3
System 4
System 5
PEMFC
SOFC
MCFC
PAFC
MCFC
0.7
1.5
300
400
1,400
35.5
54.4
47
34.3
42.5
0.0068
0.0094
2.2
4
11.2
86
74
82
81
82
0.7
2.78
1.34
0.73
1.08
9,666
6,272
7,260
9,948
8,028
Advantages
Disadvantages
Portable and can be placed both
-
High initial cost
indoor/outdoor
-
Low durability of stack (requires stack
-
replacement in 3-5 years)
Wide range of size of electric generation
and heat generation capacities
-
No availability during power outage
-
Low service and maintenance effort
-
Noise (low-frequency sound)
-
Less pollution and greenhouse gases
-
Inefficient operation due to the lack of
user education
-
High CHP efficiency
-
High part load efficiency
-
Quiet operation due to no moving parts
-
High availability
-
Longer operating time than batteries
-
Fuel flexibility
Figure 5: Advantages and disadvantages of CHP fuel cells. CHP Technology
Typical Capacity
Installed Cost (EUR/kW)
CHP Efficiency (%)
Gas Turbine
500kW-300MW
1,011-2,782 (540MW)
66-71
Steam Turbine
50kW < 1000MW
565-927
80
Microturbine
30kW-250kW
2,108-3,625
63-70
Internal-Combustion
1kW-10MW
1,265-2,445
75-80
5kW-2MW
4,215-5,480
55-80%
be used,
Fuel flexibility, Fuel flexibility, time
System 2
during operation
others
Characteristics
System 1
Figure 4: Typical performance parameters of CHP fuel cells available in the U.S. in 2014 (created by author based on data from U.S. Environmental Protection Agency, 2015).
-
carbonates,
Typical Application
Fuel Cell Type Nominal Electricity Capacity (kW)
CHP Efficiency
Fuel Compatibility
Performance Characteristics
time
Engine Fuel Cell
Figure 6: CHP capital, engineering cost and efficiency depending on the technology.
25 —
— 26
is the most stable and less contaminated
below shows the comparison between 5
well that every CHP technology has more than
Availability during power outage
fuel among above. The electricity and heat
different CHP fuel cell systems available in
60% efficiency, which is the highest electric
Since the operation of CHP fuel cells is based
demands depend on the use of building.
2014, and the power to heat ratio of CHP fuel
efficiency conventional power plant can
on reverse electrolysis, the system requires
Commonly hotels and hospitals have higher
cell differs greatly to each other depending on
reach (Figure 6). When compared with other
small amount of electricity to start its operation.
heat demand than electricity, and office
the user’s preference while the CHP efficiency
CHP technologies, the efficiency of fuel cells
Commonly available micro-CHP fuel cells are
is similar (Figure 4).
is not considerable. However, these efficiency
programed to shutoff the operation once a
rates are usually at their peak efficiency, in
day in order to keep high efficiency in power
other words, measured at 100% load. CHP
and heat generation. This makes it difficult to
fuel cell systems maintain higher efficient
operate during the long-term power outage.
performance at part loads, below 100% load,
The latest model from Panasonic and Tokyo
than combustion engines in terms of electric
Gas has improved features that enable to
efficiency (Figure 7).
operate CHP fuel cell during the sudden
buildings have higher electricity demand than heat. The demand priority changes
also depending on geographical locations, CHARACTERISTICS seasons and the time of the day. It is difficult
The common characteristics for all types of
to equalize the electricity and heat generation
CHP fuel cells are verified as follows (Figure
ratio and its demand ratio, therefore, there are
5). Among those listed above, this paper
two systems in order to adjust the need of the
focuses on the recent studies conducted on
users: thermal output control and electrical
three aspects (efficiency, cost and availability
output control. Thermal output control operates the CHP unit based on the heat demand and substitute the insufficient electricity by grid or
during power outage) and discusses in depth. Efficiency
Cost
power outage. New stack technology allows 192 hours of continuous power generation
The high cost of CHP fuel cell has been a
performance, which is about twice as long as
barrier for its expansion in both commercial
the previous model. In addition, the system
and residential sectors. In 2011, residential
does not require specialized autonomous
the like, and electrical output control operates
As described in the earlier chapter, CHP fuel
the CHP unit based on the electricity demand
cell utilize both electric and thermal energy from
micro-CHP with the capacity of 0.7 to 1kW was
and substitute insufficient heat by hot water
one system that has a high CHP efficiency. This
startup system, and can be started using
priced between 22,000 to 27,000 Euro (Staffell
boiler or the like (Ikegami, 2016). The figure
commonly available batteries and generators
method applies to other CHP technologies as
and Green, 2011). 6 years later in 2017, the
when the power outage occurs while the
latest model to be released by Panasonic
system is in off mode (ITmedia, 2017). This
and Tokyo Gas reached the price of 12,000
technology could increase the reliability
Euro, the lowest price ever made in Japan,
of CHP fuel cell as an emergency energy
which is 44 to 55% price reduction since 2011.
generation supply, and would be suitable to
The reduction of the price was done by
regions where often experience power outage
simplification of the system components and
due to natural disasters and system failures of
achieving 20% of components reduction
energy suppliers.
compared to the ones currently available on the
CHP FUEL CELLS IN JAPAN
market by the same manufacturers (ITmedia,
The United States, Canada, the United
2017). Also, Tokyo Gas aims for further cost
Figure 7: Comparison of Part Load Efficiency between PAFC fuel cell and natural gas combustion plant.
Kingdom,
Germany,
Spain,
Denmark,
reduction and is currently researching the
and Japan have been the front runners
system design to reach the price under
in the commercial and residential CHP
7,600 Euro per system (Tokyo Gas, 2014).
fuel cell installations and development.
Reduction of price, especially in micro-CHP
Recently influential legislative and technical
fuel cell, could accelerate the popularization of
development are also taking place in South
the system in single family homes and multi-
Africa, Australia, and South Korea (OECD,
family apartment complexes.
2011; Ellamla, et. al., 2015).
27 —
— 28
Japan is considered at the forefront in CHP
117 bcm, where 69.8% was consumed by
homes, Japan aims to install 5.3 million
dropped from 19.4% to 6.2%, ranked 33 out
installation and commercialization among
power generation sector (IEA, 2016). Natural
CHP fuel cells to single family homes and
of 34 OECD countries (Shimizu and Nakano,
above. CHP research development and
gas accounts for 22.7% of the total energy
apartments by 2030 (Tokyo Gas, 2014). Ene-
2017). This is considerably low compared to
demonstration in Japan started in the 1990’s
imports, mostly imported from countries such
Farms is the most common type of micro-
other non-resource-producing nations such
by the government with the development
as Australia, Malaysia, Qatar, United Arab
CHP fuel cell and also its market is rapidly
as Spain (26.7%), Italy (20.1%) and South
of 1 kW PEMFC CHP system for residential
Emirates, and Oman (IEA, 2016; Shimizu
growing in Japan since 2011. Supported by
Korea (17.5%) (METI, 2015). This sudden
homes, and the commercialization began
and Nakano, 2017). Along with the dramatic
the Japanese government’s subsidies, the
drop in of self-sufficiency rate is caused by
in 2009 (Ellamla, et al.., 2015). Before
increase in natural gas availability, the
total number of installation is expected to reach
the exponential increase in natural gas import
installation of CHP fuel cells in commercial,
0.6 million by 2030 (Advanced Cogeneration
as explained earlier. Not all the natural gas is
Japan’s sources for electric energy consisted
industry and residential uses increased.
and Energy Utilization Center, 2017; Tokyo
consumed by CHP fuel cell systems, however,
of 27% coal, 27% nuclear, and 26% natural
METI (2012) reports that 65% of installed CHP
Gas, 2014) (Figure 8). Japanese government
as the number of installation increase, the
gas. Since the incident, Japan has shifted its
systems in Japan are natural gas-base, and
revised the Long-Term Energy Supply and
need for natural gas could become greater
energy dependency on natural gas and its
produce 48% of total electric generation in
ratio rose 24% compared to 2010 (Shimizu
CHP category. 27 TWh of electric power was
and Nakano, 2017). Japan has very limited
produced from CHP in 2016, and Japan aims
natural gas resources that only 2% of the
to increase CHP capacity to 150 TWh in 2030
natural gas demand is met by the domestic
that the increase in installation of CHP fuel
supply in 2015. Compared to 2005, there was
cells in residential, industrial and commercial
44.6% increase in the import of natural gas in
sectors is inevitable (METI, 2011; METI, 2017).
2015, and the volume of import has reached
In terms of micro-CHP fuel cells for residential
Fukushima Daiichi nuclear disaster in 2011,
Figure 8: Annual and total installations of Ene-Farm.
Demand Outlook in 2015. The outlook aims to address mainly four challenges that Japan faces in order to maintain the stable supply
than the current situation.
SUSTAINABILITY
and demand balance: safety, energy security,
CHP fuel cells are considered to have lower
economic efficiency and environment (METI,
direct CO2 emissions and fuel consumption
2015). Among those four challenges, what is
than traditional electricity generation systems.
most intricate for Japan is the energy security.
However, as we see in nuclear technology, the
Improving energy self-sufficiency rate has been
whole life cycle including the manufacturing
Japan’s biggest challenge for over decades.
and disposal of CHP fuel call system must
Due to the country-wide shutdown of nuclear
be considered in order to verify its long-term
power plants after Fukushima Daiichi nuclear
sustainability (Figure 9). As displayed in the
disaster, Japan’s self-sufficiency rate has
previous chapters, CO2 emission at the usage
Figure 9: Life cycle of CHP fuel cells (created by author based on data from Staffell, 2012)
29 —
stage is already proven to be significantly low. Therefore, this chapter focuses on hazardous emissions and material life cycle assessment at the stages of manufacture and disposal. In order to verify the environmental impact at manufacture stage, it is important to verify what
— 30
pipework, electronic control systems, etc.)
Fuel Cell Type
-- An auxiliary boiler to supply peak heat
Nominal Electricity Capacity (kW)
-- A fuel processing system (converts natural gas (or other hydrocarbons) to hydrogen + CO2); -- A grid-tie inverter (to convert low-voltage DC to AC with export ability);
System 5
PEMFC
SOFC
MCFC
PAFC
MCFC
0.7
1.5
300
400
1,400
Negligible
0.005
0.005
0.005
SOx (kg/MWh)
Negligible
Negligible
0.00005
Negligible
0.00005
CO (kg/MWh)
Negligible
Negligible
Negligible
0.01
Negligible
VOCs (kg/MWh)
Negligible
Negligible
Negligible
0.01
Negligible
CO2 (kg/MWh)
513
333
445
476
445
CO2 with heat recovery (kg/MWh)
188
252
236-308
225
236
of the building’s heat demand); -- Control, interaction and feedback: -- Touch-screen LCD interface;
Figure 11: Estimated fuel cell emission characteristics without additional control .
-- Remote control system;
As stated in the previous chapter, CHP fuel
-- Smart-meter for measuring consumption and production; -- Internet-based remote monitoring and control (Staffell and Green, 2013).
-- Heat exchangers (to transfer waste heat
-- The figure below (Figure 10) illustrates
from the exhaust and coolant loops to an
the example of the major inventories of
external system);
producing a SOFC CHP furl cell.
-- Balance of plant (pumps, valves, sensors,
System 4
Negligible
capacity fuel cell can supply the majority
heat, electricity and water);
System 3
NOx (kg/MWh)
this stage. A complete package of a CHP fuel
-- A fuel cell stack (converts hydrogen to
System 2
cell system); -- A high-efficiency heat store (so that a low-
-- The main fuel cell system:
System 1
demands (usually integrated into the fuel
components and processes are included at cell consists of:
Performance Characteristics
-- Additional thermal management:
Emission (usage stage)
cells emit very few pollutants and greenhouse gases that considered as one of the clean energy
solutions.
U.S.
Environmental
Protection Agency conducted a research on the hazardous emission from commonly available CHP fuel cells during its lifetime operation (usage stage) and the result shows that the environmental impact from CHP fuel cell emissions is lower than fossil fuel based power plants such as with coal, which emits 720 to 910 kg/MW (Schlömer, et al.., 2014)
In addition to the pollutants listed above, the primary energy of natural gas CH4, which is 25 times more powerful greenhouse gases than CO2, can also be emitted as a consequences of incomplete combustion or leaks and losses during transportation (Ellamla, et al.., 2015). There are already some CHP fuel cell models utilize alternative gaseous fuels as listed in the previous chapter, and the technology
(Figure 11). Although CHP fuel cells produce
improvement in this field could reduce
no significant amount of hazardous emissions
substantial amount of emissions.
during the operation, the process of reforming
Emission (manufacture stage)
natural gas into usable hydrogen produce about 318 to 408 kg/MWh of CO2 (U.S. Environmental Protection Agency, 2015). A study in 2006 shows that the total life cycle emissions from a 200kW CHP fuel cell used for 85,000 hours are:
Figure 10: Example of an inventory of producing a SOFC CHP fuel cell system. Dashed lines indicate that additional inputs can be considered for every stage.
-- CO2: 9.537 tonnes (Rooijen, 2006).
--
NOx: 123 kg
--
CO: 177 kg
In CHP fuel cells, the production of catalyst metals such as nickel and platinum are exceedingly energy intensive. Life cycle emission rate can be calculated when these emissions from manufacturing is included to the lifetime energy output and averaged over. Compared to other electricity supply technologies, the life cycle CO2 emission of CHP fuel cell is even lower than most low
31 —
— 32
Type
Life Cycle CO2 emission (kg/MWh)
Life Cycle CO2 emission -median (kg/MWh)
Residential PEMFC/SOFC
10-20
-
Wind Onshore
7-56
11
Wind Offshore
8-35
Nuclear Fusion
Stack Type
PAFC
Stack materials
Assumed lifetime
Units required to operate for 10 years
Major energy consuming stages
Platinum
40-60,000 h
0.67-1
Forming or
Graphite
machining
12
Silicon Carbide
graphite
3.7-110
12
Phosphoric Acid
Ocean (tidal and wave)
5.6-28
17
Hydropower
1-2200
24
Concentrated Solar Power
8.8-63
27
Geothermal
6-79
38
Solar Photovoltaic (rooftop)
26-60
41
Solar Photovoltaic (utility scale)
18-180
48
Biomass (from dedicated crops)
130-420
230
Gas (combined cycle)
410-650
490
Strontium
Biomass (cofiring with coal)
620-890
740
Gallium
Coal (pulverized coal)
720-910
820
Yttrium
PTFE Carbon PEMFC
Platinum
20-40,000 h
1-2
Forming or
Ruthenium
machining
Graphite
graphite
PFSA PTFE Carbon SOFC
Nickel Oxide
Negligible
0.005
10-15
0.67-1
0.005
Lanthanum
Zirconium Stainless Steel
Figure 12: Comparison of life cycle CO2 emission in electricity generation technologies.
carbon (renewable) technologies (Figure 12).
Staffell (2012) also states that 55% of
Ellamla (2015) states that manufacturing of a
overall CO2 emission is produced from the
1 kW residential CHP fuel cell emits around
manufacturing is from the stack construction
Fuel processer, inverter & other balance of plant
years
Figure 13: Assumed lifetimes of typical fuel cell stacking technology and other CHP system components. Bolded text indicates that the material is considered as a precious metal.
of information on collection and recycling of
the recycling rate for electric devices is very
Considering most CHP fuel cell types require
CHP fuel cells at the end of their lifetime.
low. Most electronic devices consist precious
system emits 25 to 100 tonnes. On the other
more than one stack in 10 year lifetime of the
hand, a study by Staffell (2012) shows that
Materials
total system, the environmental impact of the
0.5 to 1.0 tonnes of CO2 into the atmosphere,
especially
while manufacturing of a 100 kW commercial
410 to 530 kg of CO2 would be emitted only by construction of typical 1 kW SOFC stack, and combined with inventories for the production
from
the
sintering
process.
stack construction is significant for the CHP fuel cell’s sustainability.
of fuel processor and other balance of plant EMISSION (DISPOSAL STAGE)
Recycling and disposal of CHP fuel cell
metals such as platinum and silver, and common metals such as steel, aluminum, nickel, and copper that could be recycled
systems is another essential stage to verify its
and reused. Statistically, 50% of consumer
long-term sustainability. Although legislations
goods materials are recycled, and the
such as the WEEE Directive in EU raised
remaining 40% are sent to landfill and 10%
components, the complete micro-CHP fuel
There is no study conducted to verify the
awareness and availability of recycling
to incinerator in Europe (Staffell and Ingram,
cell system would emit 1.8 to 2.9 tonnes.
emission from disposal stage due to the lack
options for general public and industries,
2010). There is no specific research being
33 —
conducted to quantify the total amount of CHP fuel cell systems and fuel cell stacks being collected and recycled, however, considering the circumstances stated above, the collection and recycling rates of CHP fuel cell components are assumed to be low as well. The figure below shows the materials composing each type of fuel cell stack (Figure 13). In each CHP fuel cell, there are the average of 1.32g of platinum, 1.2kg of nickel, 6kg of copper and 33kg of steel. If these fuel cell stacks are collected, dismantled and separated properly, the recovering yield for precious metals could reach up to 98%, and 90% for common metals (Staffell and Ingram, 2010). Nevertheless, the collection and recycling of the CHP fuel cell and its parts are not mandated by the manufacturers, and the value of recovered materials do not always meet the cost of the collection and recycling process. Considering the production and installation of CHP fuel cells are increasing exponentially as we see in Japan case, soon the problem of waste from CHP fuel cell could be a major environmental issue when microCHP fuel cells and commercial CHP fuel cells are installed in every building around the world as smart phones and personal computers to our society nowadays.
RECENT RESEARCH In order to improve the sustainability of CHP fuel cell, prolonging the stack lifetime close to the lifetime of the total CHP fuel cell system, reducing the cases if inefficiency due to the lack of user education, and improving the collection and recycling rate would be necessary. The investment in research and development to
— 34
engineer new CHP fuel cell system would be one of the solutions. Recently, there are some researches on alkaline based micro-CHP fuel cell to be commercialized. Alkaline based fuel cells (AFC) are commonly used for power generation in larger facilities such as military base and spacecraft due to its high electrical efficiency (60 to 70%) and wide range in operating temperature (below zero to 230°C ) (U.S. Department of Energy, 2011; Wilberforce etc., 2016). Due to this operating temperature, one study shows also the possibility of using the waste thermal energy to cooling (Zhao, 2015). The advantage of using AFC for CHP system is its lower CO2 emissions in overall life cycle than other CHP fuel cells even though the lifetime of stack is much shorter than other fuel cells that requires 5 to 8 replacements for a 10 years duration of the total CHP system (Staffell and Ingram, 2010). In addition, the low cost on components compared to other CHP fuel cell system is another advantage.
CONCLUSION As many researchers and government officials concluded, the application of CHP fuel cell technology is expanding in various sectors as the technology improves and price becomes affordable. With the primary energy shift from high CO2 emitting sources such as oil and coal, and controversial nuclear, the rise of natural gas usage thus CHP fuel cell technology is inevitable. The World Economic Forum (2015) also recognizes the possibility in further development and expansion of hydrogen technology such as CHP fuel cells, however, concluded that the technology “will not
contribute seriously to decarbonization unless hydrogen taken from carbon-free sources.” As discussed above, the overall sustainability of CHP fuel cell is still unknown. Nevertheless, taking into account that the current system requires finite natural resource, natural gas, as primary energy source, it is questionable to consider current CHP fuel cell system as a sustainable solution. The waste from CHP fuel cell could also accelerate the generation
of e-waste, which is a complicated global issue in the world is facing at the same time with climate change. CHP fuel cell could be a short-term solution for climate change to bridge over the energy transition from fossil fuel base to renewable sources, however, there must be new innovation and technology improvement added to the current system in order to call CHP fuel cell technology sustainable in a long term. —
35 —
— 36
might mark the next step to a carbon neutral
fracturing has been widely practiced in the
future.
United States within the past 15 years. The
INTRODUCTION
USA is the world pioneer in the industry and
Shale gas production refers to the extraction
— Mariya Todorova
and
production
of
natural
gas
from
sedimentary rocks through the unconventional
Mariya Todorova has graduated in Sociology from the Sofia University “St. Kliment Ohridski, Bulgaria. She has participated into the social impact assessment of the Bulgarian part of the Nabucco Gas Pipeline project. She is currently a student in the Masters Program Resource Efficiency in Architecture and Planning and her area of interest is sustainable urbanism.
method of hydraulic fracturing (fracking or fracturing). Natural gas is geological hydrocarbon formation that occurs after the decomposition of marine sediments and their exposure to specific conditions such as depth, temperature and exposure time. The emerging hydrocarbon formations escape from the source rock and migrate, generally upwards, into porous and permeable strata.
has since set the example for other countries in
both
technological
application
and
scientific research. A study by the U.S. Energy Information
Administration,
suggests
the
potential technical recovery of 203,910 Bcm of shale gas on a global scale (EIA, 2013). Nevertheless, there are only four other countries that produce shale gas on a commercial scale – Canada, China, Argentine and Australia. Following these examples, several countries in Europe have, since 2010, undertaken their first efforts into industry development through legislation establishment and licensing shale
ABSTRACT
prospects and barriers. The topic is explored
Layers of impermeable rock aid as a seal
Speculations about the future of shale gas in
through literature review based on reports
and allow the hydrocarbon accumulation into
issued by the European institutions, peer-
an easily accessible reservoir a few kilometres
reviewed academic articles and online news
below the earth’s surface. Some hydrocarbon
articles. The subject is approached through
accumulations migrate and reach reservoir
a discussion on the management of the
rocks with lower porosity and permeability and
environmental implications of the method of
some stay trapped within the fractures of fine
What brings excitement to the situation is that
production, as well as on a discussion on the
grained shale rocks, called respectively tight
European member states are to explore their
role of natural gas consumption, import and
and shale gas. The terms “conventional” and
natural resources freely, as long as they
production in Europe.
“unconventional” gas extraction do not have
follow the established strict environmental
The paper concludes that the shale gas
a sharp and clear distinction but relate to the
regulations. Controversy in the public and
industry is at an early stage and faces many
overall nature of the reservoir and the method
academic debate is fuelled by, on one hand,
obstacles of economic and legislative matter.
of extraction. “Conventional” gas extraction
the many benefits observed in the USA,
Additionally, further continuous research that
refers to the extraction of natural gas from
such as energy diversification, independent
addresses the many environmental risks
the relatively shallow basins, usually through
development of local resources, political
and concerns in an open public debate is of
vertical drilling, whereas “unconventional”
freedom, a leap from the coal industry into a
led public debates, introduced regulations or
an utter must to the future of the sector. The
implies lower permeability of the source rock
cleaner industry and satisfaction of a market
moratoriums, granted licenses to shale gas
dynamic nature of the innovation field and
and the use of more sophisticated methods
of growing demand, to, on the other hand,
exploration companies or initiated first tests.
the development of new technologies that
such as hydraulic fracturing. Within the group
adverse environmental impacts. Examples
The
the
optimise the wells performance are a source of
of “unconventional” fall the above mentioned
for such are groundwater and surface water
development of the industry in Europe,
optimism. Should technologies such as CCS
tight gas and shale gas extraction (European
contamination, ambient water pollution, land
its current state and the associated future
be massively applied, shale gas production
Parliament, 2011). The method of hydraulic
take, risk to biodiversity, increased seismicity.
Europe are primarily based on the experience collected in the United States. Throughout the past eight years, the US shale gas industry has transformed the hydrocarbon production sector, marking the so called “shale gas revolution”. Several countries have since, taken first steps into commercial production with the promise of the benefits achieved in the USA – energy security, lower energy prices and reduction in the CO2 intensity of the energy production sector. In pursuit of the same goals 11 European Union member states with identified shale gas resources have
following
paper
deals
with
gas exploration projects. The public response triggered varied widely from supportive (Spain, Lithuania), to protests and demonstrations, resulting in moratoriums issued by the corresponding government (France, Bulgaria).
37 â&#x20AC;&#x201D;
â&#x20AC;&#x201D; 38
RESULTS
Several examples of negative effects on the
of shale gas resources globally and in
research attempts about the impacts of
human health are also recorded from the US
Europe (Section 3.1), the paper argues that
hydraulic fracturing are impaired by the lack
experience (European Commission, 2011).
the resource estimates pose as a serious
of systematic baseline monitoring data, lack
All those factors, along with the commitment
argument in favour of considering further shale
of incident rates, as well as lack of data on
to a carbon free economy defined by the
gas exploration. Section 3.2 comments on the
the concentration, behaviour and effects
European Union in the Energy 2020 package
process of shale gas production. It introduces
of the chemicals that are used in the shale
and the Energy 2050 Roadmap shape the
the stages of the development of a shale gas
gas production process. Furthermore, risk
an optimistic future of the sector. With the
contentious debate on the future of shale gas
production site, aiming to situate the topical
assessment needs to take into consideration
progressive depletion of readily accessible
production in Europe (European Commission,
in the European context exploration phase
the difference between the impact of an
gas reserves and the parallel development of
2016). Such debate should, therefore, include
within the life cycle of the basin exploitation.
individual installation and the cumulating
mining technologies, the shale gas industry
both a discussion on the management of the
An overview of the technological process in
effects of multiple installations at different stage
in the USA is on an up rise. The US Energy
environmental implications of the method of
reference to conventional gas production
of the project life. Risk analysis is also to a
Information Administration (EIA) projects that
production, as well as a discussion on the
outlines several barriers to the industry
great extent site specific (Policy Department
the natural gas production from shales will
role of natural gas consumption, import and
development. Those are complemented in
C - Citizens' Rights and Constitutional Affairs,
grow from 21 billion cubic meters (Bcm) per
production in Europe.
3.3 Main adverse environmental impacts
2012). Furthermore, when it comes to the
year as recorded in 2005 (4.1% of all gas
associate with shale gas production and the
research on the state of the industry within
produced in the US) to 561 Bcm per year in
method of hydraulic fracturing, as described
national contexts, European Union data was
2040 (53% of all gas produced). From 2004 to
by the European Commission (European
outdated.
The information in English was
2015, approximately 14,000 unconventional
Commission, 2011) .Section 3.4 explores the
limited which constrained the research to
wells were drilled in the Appalachian Basin,
main conclusions drawn in the Europe 2050
few online news articles with relatively lower
including Pennsylvania, Ohio, and West
Energy Strategy and the trends projected
objectivity.
Virginia. Nearly 9,600 of those were drilled in
Methodology The subject of the following paper is the development of the shale gas industry in Europe. The paper aims to determine what is the current state and future prospects of the shale gas industry in Europe and what are the main barriers that it faces. The focus is on the member states of the European Union that have shale gas resources as estimated by the U.S. Energy Information Administration (EIA, 2013). What makes Europe an even more exciting focus point is the freedom that the individual countries share to explore their own natural resources while taking into account the strict environmental regulations imposed by the European Union. The topic is explored through literature review based on reports issued by the European Parliament and European Commission and peer-reviewed academic articles. Where data was outdated,
Shale gas resources availability globally and in Europe A first look into the shale gas production history of the pioneer in the industry, USA, shows
in the EU Reference Scenario 2016 about the role played by both conventional and unconventional natural gas in the gross inland energy consumption in Europe (European Commission, 2016). It explores the prospects of the shale gas industry in the context of carbon free Europe and the current state of the industry in member states with identified shale gas resources.
Chapter 4. summarises the
main findings of the paper. The final chapter, 5. Outlook, opens a discussion on some future prospects for the industry that could strengthen its role on a European and global scale.
it was complemented with information from
Limitations
online news articles.Analysing the availability
An overview of the available literature suggests
Figure 1: Map of the top ten countries with technically recoverable shale gas resources.
39 —
— 40
Pennsylvania alone (Whitton et al., 2017;
Mexico Australia, South Africa, Russia and
caution. The development of a potential site is
Because of the lower scale of the intervention,
EPRS, 2014). Among the benefits attributed to
Brazil. The consolidated figure for Europe is
usually a long, continuous process in which
this procedure has fewer risks and potential
the robust growth of the industry is the fall in gas
actually even higher than the one for USA,
starting with initial research is followed by an
environmental impacts. Should a EU Member
prices observed on the US market, reduction in
respectively 16,934 Bcm and 16,056 Bcm,
exploration phase and, only if the feasibility
State decide to develop its unconventional
the carbon intensity through substituting coal-
which is an argument in favour of potential
of the basin is proved, production phase
gas resources, the multiplication of all activities
fired with gas-fired power generation, and the
investments in the industry development in
can commence. Even if the exploitation of
increases both the likelihood and magnitude
improvement in the energy independence
Europe. Worldwide, however, as of the end
a site is at a particular point in time not yet
of adverse environmental impacts. Therefore,
and security around the globe through the
of 2015, commercial shale gas production
economically feasible or technically possible,
the understanding and addressing of any
exploitation of new technically recoverable
was observed only in the USA, Argentina,
such should not be entirely ruled out because
risks from this stage is of major importance.
reserves (Middleton et al., 2017).
Canada and China. Taking a closer look into
of the dynamic nature of the sector and the
After the completion of the exploration phase
Preliminary geological assessments suggest
Europe’s resources, 12 out of 28 countries
prospects for technological advancement.
and the both the company and the member
the abundant global distribution of shale gas
stand out with promising shale gas reserves
Therefore,
reveals
state decide to pursue with production, the
around the globe (Figure 1). As per a study
(Figure 2). Among the leaders are Poland,
favourable prospects for the development of
second stage can commence. In this phase
by EIA conducted in 2013, the unproven wet
France and Ukraine with unproved wet shale
shale gas industry in Europe.
the full corresponding infrastructure for the
shale gas technically recoverable resources
gas TTR between approximately 3,600 and
(TTR) worldwide amount to 203,910 Bcm
4,200 Bcm. For a quick reference, Poland’s
(EIA, 2013). The ten countries with largest
2015 natural gas consumption is estimated
technically recoverable shale gas resources are USA, China, Argentina, Algeria, Canada,
resource
availability
The process of shale gas production
production process is constructed and installed. This involves the clearing of the site, the well construction of roads, manoeuvring
to 14.79 Bcm. Naturally, unproved resources
Overview of the stages of an unconventional gas production site development
should, however, be treated with extreme
As already outlined, there is a long path towards
transport of fracking fluid and the construction
social, economic and environmental benefits
of flow-back fluid treatment pits or tanks.
from unconventional natural resources. Before
Depending on the scale of the production
setting into commercial production, a member
site, a natural gas production plant could be
state and/or a licensed company should
present. The drilling equipment is transported
successfully complete the exploration phase
and assembled and the hydraulic fracturing
of a site. The stages that follow it are: moving
process commenced. The third phase,
into production; production and abandonment
production, consists of the maintenance and
of the site. The exploration stage, currently
further development of wells on the site. The
topical in Europe, is a pilot phase aiming to
initial production is expected to decline within
determine the site requirements, presence
the first few months and retain lower levels until
of gas and the sour gas probability, the
the end of the exploitation period (Wynn G.,
characteristics of the geologic structure,
Grant A., 2015). Upon well abandonment,
seismicity of the region and the economic
the equipment is decommissioned and
viability of the undertaking. It consists of the
transported, the well is capped with a surface
construction of 2 or 3 wells and the minimum
plug and the site is restored as far as possible.
needed corresponding infrastructure to service
In the context of that timeline, Europe has a
the well pad - access roads and storage
long way to go before realising the potential of
facilities (The Climate Principles, 2013).
its shale gas resources. Furthermore, because
Figure 2: Unproved wet shale gas technically recoverable resources (TTR), Europe, in billion cubic meters.
sites, storage facilities and the well pad, the
41 â&#x20AC;&#x201D;
â&#x20AC;&#x201D; 42
of the controversy of the method of hydraulic
USA are permitted to retain the composition of
well drilling on a particular site, unconventional
negative impacts, as a thorough review
fracturing, a foul course in the exploration
the chemicals in the fracturing fluid under the
drilling is more area extensive in terms of
would be the subject of a different, focused
phase due to poor practices has the capacity
pretext it is a commercial confidentiality, which
land use. At last but not least, the described
research. The main sources of the overview
to trigger negative public reaction and impair
challenges the assessment of the impact
operation relies extensively on heavy freight
are 2 research papers by the European
any further prospects for the development of
of those chemicals on the environment.
vehicle transport, which is connected with
Commission (2011) and the Policy Department
the sector. Moreover, failure to monitor and
Such is not the case however in the UK,
additional resources and is in short-term not
C - Citizens' Rights and Constitutional Affairs
ensure up-to-standard procedures, poses
where companies are obliged to disclose
contributing to the positive environmental
(2012). Based on the US experience, adverse
immense risks to the environment and human
the chemical composition under the Water
impacts are caused mainly because of
health.
footprint of the operation (AEA 2012).
Resource Act 1991 (Whitton et al., 2017).
Overview of the technology of hydraulic fracturing
Apart from the initial chemical and proppant
Whereas conventional gas production relies mainly on vertical drilling and some internal pressure of the gas within the reservoir, the drilling in unconventional gas production is executed in two stages - vertical drilling in order for the bore to reach the shale layer, and directional drilling, penetrating the shale horizontally. In both situations steel casing pipes are installed into the borehole and
composition, the flow back fluid contains substances
naturally
present
in
the
reservoir, such as salt, radioactive materials, hydrocarbon, metals (European Parliament, 2011). It is transported into pits or tanks and could be reused or pre-treated and transported to an industrial treatment facility. The well clean-up and testing involves the flaring and monitoring of the well throughout the process.
cemented to the rock formation afterwards.
Depending on the capacity of the site,
After the casing is done, the drilling rig
a centralised compression facility could
is removed. Small explosions along the
be installed for the purpose of the gas
horizontal are created to perforate the casing.
production.
The hydraulic fracturing commences by
between conventional and unconventional
pumping fracturing fluid under high pressure
gas production operations could be drawn.
into the well. This pressure creates fractures
Due to the drilling depth with fracking (up
along the horizontal of the shale rocks
to several kilometres depending on the
(Tagliaferri, Lettieri and Chapman, 2015).
geological structure of the site), the amount
Upon pressure reduction, the wastewater
of water needed for the pumping could be
flows up, mixed with heavy or radioactive
up to 10 times more than in conventional
metals. The proppant in the fracking fluid
production. This is a serious factor in regions
serves as spline and keep the cracks open
under water stress. Another serious challenge
allowing the further gas extraction. The
is the treatment of the waste water, which,
chemicals aid to achieve homogeneous
if done could be energy extensive, and if
distribution of the proppant, reduce friction
skipped poses number of environmental and
and prevent corrosion. Companies in the
health risks. Because of the practice of dense
Several
main
differentiations
Main adverse environmental impacts associated with shale gas production and the method of hydraulic fracturing Unconventional
gas
production
is,
by
definition, largely dependent on the specific
malpractices and legislation breaches as well as equipment failure and inadequate handling of the operations. The accident rate calculated by the NY State is between 1 and 2% and the Marcellus shale in Pennsylvania registered 1,600 violations on a total of 2,300
geological structure of the site. Therefore, a
wells (European Parliament, 2011).
risk analysis should always combine general
Among the highest risk for groundwater and soil
issues with site-specific aspects. An analysis
is the contamination from naturally occurring
on the general risk ratings on the individual
radioactive elements through existing or
environmental
moderate
artificially created through the process of
to high risk for individual installations and
fracturing pathways in the area of active
predominantly high, cumulative risk for multiple
or abandoned wells. Such contamination
installations (Table 1). The following section
could occur from failed cementing too.
aims to provide an overview on potential
With migration, NORMS can contaminate
aspects
shows
Environmental Aspect
Project Assessment
Cumulative Assessment
Groundwater contamination
High
High
Surface water contamination
High
High
Water resources
Moderate
High
Release to air
Moderate
High
Land take
Moderate
High
Risk to biodiversity
Moderate
High
Noise impact
Moderate to High
High
Visual impact
Low to Moderate
Moderate
Seismicity
Low
Low
Traffic
Moderate
High
Groundwater, surface water contamination and water resources Table 1: Overview of preliminary risk assessment of hydraulic fracturing across all project phases.
43 —
— 44
groundwater and in result drinking water
times more water than conventional drilling
Air pollutant emissions such as noise,
within this area could reach up to 6 wells/km2.
supplies. Permeation in the underground is
which is a serious issue in areas already
particulates, SO2, NOx, NMVOC and CO,
Such density increases the occurrence of one
a slow process and hard to observe which
experiencing water stress. Additionally, large
could originate from activities connected to
or more risks (European Commission 2011).
could lead to long-term adverse effects. Prior
portion of the fracking fluid remains in the
the operation of heavy freight vehicles, drilling,
Additionally, that might be agricultural land (as
activity, local geology needs to be analysed
formation – not more than 20% of it flows
natural gas processing and transportation,
in considered during 2011 potential sites in
and monitoring and control should allow zero
back. It is not a common practice that the
waste water ponds evaporation, spills and
Bulgaria and France) and the disruption of the
tolerance for compromises.
water is reused because of the change in
blow outs. US experience recorded many
landscape could pose a threat to biodiversity.
Another source of contamination could be
the chemical composition. Full treatment of
complaints of human illness and several
the chemicals used in the hydraulic fracking
the water is possible but not regarded as
complaints of animal death (Dish, Texas). An
process. Spills of fracking fluid during
economically feasible. Usually, after pre-
independently conducted study registered
treatment wastewater is injected back to the
“the presence in high concentrations of
geological formations, posing a risk of soil
carcinogenic and neurotoxin compounds
salinisation and contamination, as well as
in ambient air and/or residential properties”
increased seismicity (Policy Department C
(European
- Citizens' Rights and Constitutional Affairs,
methane emissions from drilling, flow back,
2012; European Commission, 2011).
fracturing fluids evaporation, valve and
pumping, transportation or due to overflow of the wastewater fluid container are the most commonly occurring accidents. Within the risk mitigation measures is the further research improved mixtures with lower toxicity as well as monitoring and report that prevents accidental spills. Fracturing requires approximately 10
Release to air, noise and traffic
Commission,
2011).
Fugitive
compressor leakage, have huge impact on the greenhouse gas balance. Serious accidents that occurred in the U.S. are the well blow-out resulting in a 16-hour long spewing off 133 cubic meters of wastewater and natural gas into the air (Pennsylvania, 2010), explosion of a well and injuries of several workers (West Virginia, 2010), fire of a waste water storage tank and open pit (Atlas well pad, 2010), (European Commission 2011). Mitigation measures to be undertaken to prevent such scenarios are strict health and
Figure 3: Potential flows of air pollutant emissions, harmful substances into water and soil and naturally occurring radioactive materials (NORM).
Need of further research Although the list of potential negative impacts and risks and the activities during which they might occur, is long, and the registered high accident rate – high, several encouraging arguments with high validity are expressed in the public debate. The main one is that proven accidents and violation are due to poor practices by the servicing companies. State-of-the-art technology along with trained personal, regulations, monitoring and control could effectively prevent large share of those accidents. Furthermore, often reports do not come up with a solid proof of the causality of hydraulic fracturing and the resulting adverse impacts. Hence, future data collection and research could address some of the concerns and lower the remaining risks and negative impacts, allowing shale gas exploration a future in Europe.
safety regulations, monitoring and control. Land take and biodiversity
The role of conventional and unconventional natural gas in the EU
The shale gas production operation is area
Investment and advancement of the industry is
extensive as it requires additional area for
connected with the economic climate and the
storage of technical equipment, trucks with
active legislation within the EU and its member
compressors, chemicals, proppant, water
states. The following section examines the
containers for waste water and others. A
projected role of both conventionally and
typical multi-well site in Pennsylvania is about
unconventionally produced natural gas in
(16,200-20,250 m2). The concentration of wells
Europe.
45 —
— 46
Natural gas consumption projections in the European Union
energy consumption. Because of that, the
decline in conventional production.
described scenarios are also marked with
As illustrated in both graphics, according to the
Within the goals of the Europe 2050 Energy
the close collaboration between decentralised
reference scenario, natural gas is attributed
Strategy is the transition of the European
and centralised power systems and heat
a role limited to a “flexible back-up and
energy system into a carbon neutral one
generation systems. Furthermore, carbon
balancing capacity where renewable energy
(with 80-95% reduction of greenhouse gases
capture and storage (CCS) is expected to
supplies are variable”. A crucial condition for
based on 1990 levels), along with ensuring
play a “pivotal role” in the transformation of
the classification of natural gas as low carbon
competitiveness and security of supply. This
the system. Should CCS be commercialised,
technology is the large-scale application of
is to be achieved following the established
it is to contribute with mitigating up to 32%
CCS technologies (European Commission,
by the European Commission (2011) Energy
of the CO2 emissions in power generation
2011). Successful domestic shale gas
Roadmap. The scenarios in this roadmap
(European Commission, 2011).
production, could compensate for the decline
project a decarbonised system in which
The projections drawn from the EU Reference
in the domestic conventional natural gas
capital expenditures are relatively higher
Scenario 2016 (REF2016) show a drop in
production and minimise the need of import.
and fuel costs, lower. Electricity is expected
the gross inland energy consumption in the
That should however, not compromise the
to play an increasing role, with an almost
EU (Figure 4). Two trends are observed in the
doubled share in final energy demand of up
period from 2005 to 2050 – the decline in the
to 36-39% in 2050, stressing the importance
solid fuels and the oil consumed, and the rise
of a sustainable electricity production. The
of the renewable energy used. The amount
share of renewables is also expected to
of nuclear energy and natural gas used are
rise, reaching at least 55% of the gross final
expected to remain with a stable share.
Figure 4a: Gross inland energy consumption in Europe (EU28) from 2005 to 2050, in ktoe. 2
The projection takes into account the global and EU market trends, along with the already adopted by the EU and its member states energy and climate policies.
Figure 4b: Gross inland energy consumption in Europe (EU28) from 2005 to 2050, in ktoe.
environmental integrity within the member states or pose any risks to human health. It should, additionally prove the long-term GHG
When we take a closer look into the natural
neutrality of unconventional gas production.
gas production, imports and consumption consumption during the period from 2005 to
Positions of the member states with shale gas development prospects towards the method of hydraulic fracturing
2015, followed by projections for a modest
In spite of the shared goals in the Europe 2050
increase in demand during the period from
Energy Strategy, the choice of energy source
2017 to 2021. This is to be explained with
to be developed by the European Member
the expected retirements of several coal and
States remains in their own competence.
nuclear power plants. Additionally, domestic
Although there is no specific EU policy on the
EU gas production is experiencing a gradual
development of shale gas, there is a non-
decline (41% over the past 10 years), leading
binding Recommendation 2014/70/EU on the
to an increase in imports demand. Russia is
use of fracking for the exploration or production
the main gas importer in Europe with 44% of
of shale gas. It addresses the environmental
the EU imports in 2015. Alternatives in gas
aspects of the sector that could produce
supply are recognised in the liquefied natural
cross-border
gas import and the unconventional gas
advocates
production (European Commission, 2016).
whole process and especially the use of
Nevertheless, unconventional gas production
chemicals. Member States that decide to
is predicted to remain below 20 Bcm by 2035
proceed with shale gas explorations are
and will therefore not compensate for the
additionally invited to report their environmental
(Figure 5), we see a drop in the gross inland
impacts. transparency
The
Regulation
concerning
the
47 —
— 48
causing exploration companies to give up
speed of a process supposed to address as
fracking in Spain. Exploratory drilling was also
many of the concerns as possible, might end
approved in Poland , Romania and Lithuania.
up to obstruct the success of the endeavour.
Especially high were the expectations of
While the availability of resources and the
Poland and Romania in replicating the US
industry proficiency are of great importance,
success. Poor results from first tests due to
it is governance that has the potential of being
unfavourable geology in Poland, along with
a deciding factor for the industry’s future.
legislative complications such as the time-
Experience shows that the lack of multi-level
restriction in concessions, led to the drop in
inclusive governance causes high likelihood
concessions and companies pulling out.
of triggering negative public reaction. Both
Announcing their exit from the Romanian,
favouring local economic interests and
where the ban was shortly beforehand lifted,
undermining them while not adequately
the US based shale gas company Chevron
addressing the potential risks the stakeholders
explained that the Black sea state does not
endure, could bring larger environmental and
Figure 5: Indigenous natural gas production, net imports and consumption in EU28 from 2005 to 2050, in ktoe.
compete favourably with other investment
social impacts once the industry advances.
opportunities in the company’s portfolio .
What global experience so far shows is that in
impact measures on an annual basis. Since
(EPRS, 2014). After years of discussion and
Chevron had already departed Lithuania in
lack of scientific knowledge base is among
research, Germany and Netherlands also
2014, citing the inhospitable fiscal regime as
the barriers to the development of the sector,
banned the method of hydraulic fracturing (in
one of the reasons for leaving the country.
the European Commission has established a
2017 and 2015 respectively).
Soon after, in 2015, the government drafted a
High hopes and first fracking attempts in Europe
rate, renewing the interest of the partially owned
European Science and Technology Network on Unconventional Hydrocarbon Extraction (EPRS, 2014). Active debate was led in several
new law with improved base gas extraction tax by Chevron LL Investicijos . Shale gas is also
all the countries, except USA, the growth rate and volumetric magnitudes of the shale gas production were insufficiently low to lead to any positive energy or economic effects (Fukui et al., 2017). Thus, a transparent, inclusive and realistic strategy needs to be developed. The above described examples illustrate that pioneer companies are on the other hand
Spain is among the EU member states
explored in Sweden and Denmark , but the
that regarded high hopes on replicating
limited availability of the resource makes those
the success observed in the US shale gas
shales not that attractive of an investment.
industry. As per a report by the Spanish
Highest hopes are currently regarded on UK’s
Bulgaria was in the process of negotiation
Association of Research, Exploration and
shale gas exploration’s projects, although the
with the US giant Chevron for the exploration
Production, the resources of shale gas in the
industry is still a long way to go . After brief
of site in the Dobrudzha area, a territory
Iberain Peninsula could provide gas supply
seismic activities in initial vertical drilling in
CONCLUSION
with high agricultural significance. After loud
potential equal to 70 years of consumption,
2011, UK had voted moratorium which they
The topic of shale gas exploration in Europe
negative reactions in 2012, the government
thus lowering the import dependence of the
later lifted. First fracking tests are scheduled
stays controversial and the public opinion –
imposed moratorium and revoked licenses
country. Although the National Congress
for 2017 and it is argued that this will be the
divided. Out of the 11 reviewed countries, four
for exploration. Due to the large significance
adopted
2013
most closely observed shale gas exploration
have an active ban on hydraulic fracturing
of the agricultural sector, France also banned
greenlighting shale gas exploration and
project so far, aiming to prove the potential for
(Germany, Netherlands, Bulgaria and France),
fracking, cancelled exploration licenses and
granting
regional
safe hydraulic fracturing. Legal challenges
four have had high hopes but have recently
upheld the ban in their constitutional court
assemblies formed an opposition, eventually
from environmental groups and the slow
lost their initial enthusiasm (Poland, Spain,
European Member States in the last decade. Active ban on hydraulic fracturing. An active ban on hydraulic fracturing is currently present in four European member states.
legislative five
changes
licenses,
several
in
often discouraged into pursuing long-term investments due to unstable political positions and current low gas prices compromising the economic feasibility of the endeavours at the current state of the available technology.
49 —
— 50
Lithuania, Romania), two have exploration in
(Middleton et al., 2017), concludes that a
place but with limited return projected (Sweden
likely enhancement of well productivity lies in
and Denmark) and one (UK) has upcoming
identifying better performing mechanisms and
exploration activities and optimistic prospects
applying them. Modelling production data
for the industry. The individual stories of the
recognises differences of factor of ten between
member states show that the industry is still
the wells with best and worst performance.
too young and expectations are blinded
Therefore, long-term production should be
by unreasonably optimistic hopes and
considered as a subject of further research and
fierce ideological criticism. Within the main
has a potential to “massively increase shale
barriers that the paper identified are the early
gas extraction and re-revolutionise hydraulic
stage of the industry, the low success rate of
fracturing”. Furthermore, the study argues
exploration activities and the questionable
that refracturing is not negatively impacted
economic feasibility at the current global gas
by
prices and European regulation. Additionally,
advancement shows a potential for re-
negative public opinion poses a serious
stimulating existing wells, which could be
threat. The data on the risks and impacts
more cost effective and pose a smaller
is still underdeveloped and shows high accident rates and insufficient measures for risk mitigation. This has the potential to fuel the public debate on the long run and obstruct the future of European shale gas production in the long run. However, the promising dynamics of the sector and the continuous role of natural gas provided that carbon capture and storage technology is developed reveals some prospects for the sector in Europe. Success will need to be based on multi-level governance, transparency and a sufficient
previous
production.
— Abdullah Khisraw
Abdullah Khisraw is doing his M.Sc. in REAP with a fully funded scholarship by the prestigious German Academic Exchange program (DAAD). He is graduated with a B.Sc degree from Civil Engineering Faculty of Kabul University. He is the author of two mathematic books in his native language, and worked for more than three years in national and international organizations.
Technological
environmental footprint than developing new shale formations. These findings, if proved and developed have potential to significantly improve the prospects of the shale gas industry in Europe. Furthermore, should CCS technologies become available and applied at a large scale, this could classify shale gas as a low-carbon technology (European Commission, 2011). A recently researched
INTRODUCTION Compression
chillers
in functioning of compression chillers, some are
mechanical
machines used for cooling purposes in
to operation of compression chillers are
commercial areas, industrial areas and
discussed at the end of this paper.
residential units. This paper discusses the
PRINCIPLES
principles upon which compression chillers work, starting from the very basic physics knowledge to understand them, and later gives an insight to the mechanical parts and
approach to reducing the anthropogenic CO2
clarifies how do all parts of the compression
gas recovery (EGR) operations in depleted
cooling. In addition some of the operation
emissions is through coupling of enhanced
of the general recommendations in regards
chillers work together to give a final effect of
To understand the mechanics of how a compression chiller works, it is necessary to understand some of the fundamental thermodynamics principles upon which the system is designed. Here some of the very essential of these principles are discussed in detail:
shale gas reservoirs with long-term CO2
challenges are discussed, mainly challenges and problems associated with compressor
Phase change and latent heat
Along with further research and cost-based
part of the compression chillers, compressor,
The refrigerant we use in compression chillers
economic analysis, CO2-EOR might turn out
being one of the key drivers in compression
experiences phase changes, in order to
chillers is more vulnerable and requires
understand how the process works in this part
The research community is still learning a lot
that could serve the final stages of depleted
proper functioning of all other parts of the
of the paper the latent heat is explained:
about the aspects of shale gas production.
shale gas reservoirs, address some of the
compression chiller to function correctly and
“Latent heat is the quantity of heat which must
Contrary to the established opinion so far, a
concerns of the industry and take the next step
efficiently. Despite all these challenges there
be communicated to a body in a given state
recent research on the 20 years of exploitation
to carbon neutral future. —
are recommendations to minimize faulty
in order to convert it into another state without
operations and to maintain higher efficiency
changing its temperature” (Maxwell, 1970).
set of measures addressing the concerns in ensuring the environmental integrity in the EU Member States.
OUTLOOK
of over 20,000 wells in the Barnett formation
storage operations (Schaef et al., 2014).
to be one of the many revolutionary findings
51 —
— 52
Freezing temperature
0 degree Celsius
it is cold down to 100 °C. Important result of
Refrigerant
Boiling temperature
100 degree Celsius
this analysis is the very high amount of energy
The liquid used inside a compression chiller
Latent heat of fusion
334 J / g
required to evaporate the water compared to
to transfer heat is called refrigerant, usually the
Latent heat of vaporization
2.230 J /g
amount required to melt it. It is vivid the same
refrigerant has a lower boiling point depending
Specific heat capacity of water (cwater)
4.187 J / (kg °C) or 1 cal / (g °C)
amount of energy would be extracted during
on its application different refrigerants are used
Hydropower
2.220 J / (kg °C) or 0.53 cal / (g °C)
condensation. If a gas can be used to cool
for commercial, industrial or residential areas.
Concentrated Solar Power
1.890 J / (kg °C) or 0.45 cal / (g °C)
down another medium, it can absorb more
Depending on requirement of the compression
energy to condense compared to a liquid. In
chiller
compression chillers the similar procedure is
pressure and temperature a proper refrigerant
applied, R-134a as the refrigerant will absorb
is used in compression chillers. Some of the
Table 1: Water properties at 1 atm pressure.
and
mechanical
constraints
like
Every matter has two sorts of internal energy,
to raise its temperature from 0 °C to 100 °C, Q4
a lot of energy by condensation from the
very common refrigerants are listed in table 3.
one which is sensible in terms of temperature
= 446,000 J to evaporate the 200 g of water
places of higher temperature, transfer it to
It is important to note that refrigerants use are
without raising the temperature, and at the end
places of lower temperature and loses the
bindings between the building blocks of the
Q5 = 3780 J to raise its temperature from 100
energy there. Table 2 summarized some of
matter, this energy is latent and not sensible. In
°C to 110 °C. Figure 1 shows the process of
the R-134a properties (at 1 atm atmospheric
order to undergo a phase change this energy
heat application on this 200 g of ice, and in
pressure).
shall either be taken away from the matter
order to convert the 110 °C steam back to -10
or shall be transferred into it. This amount of
°C ice the same amount of energy should
energy for different matters differ whether it
be extracted. (For step by step calculations
changes from which phase to which. For
please inspect Appendices section at the
example latent heat of vaporization of R134a
end of this paper). From this analysis it is
is 173.1 J/g (Kondou, et al., 2014) while that of
vivid that the biggest amount of energy in
water is 2230 J/g (Halliday, et al., 2011).
phase change is Q4=446000J where water
Heat can act in two different ways on a
evaporates, the same amount of energy
Gay Lussac’s law
substance either it will change the temperature
would be extracted from water steam when
As shown by the French chemist Joseph Louis
and second is the energy affiliated to the
legally challenged depending on their Ozone depletion potential (ODP) and global warming potential (GWP). -- Ozone Depletion Potential (ODP) of a chemical is the relative value that
Freezing temperature
- 96.67 °C
indicates the potential of a substance to
Boiling temperature
- 26.07 °C
destroy ozone gas as compared with the
Table 2: R-134a properties.
potential of chlorofluorocarbon-11 (CFC11) which has a reference value of 1 (Luthra, 2017). -- Global Warming Potential (GWP) is another measure of consideration when a refrigerant use is restricted, it show the
of the substance or it may change state of the
Gay-Lussac (1778–1850) in his experiments,
substance. To further clarify this, water would
the pressure and absolute temperature of a
be considered as an example and will be
fixed volume of a gas are directly proportional
analyzed as it changes from ice to water vapor
to each other.
by applying heat and from vapor back to ice
Based on this law, in compression chillers
by extracting heat under 1atm atmospheric
thermal expansion valve decreases the
pressure. Table 1 shows the properties of
pressure thus decreasing the temperature of
water in 1 atm atmospheric pressure.
the gas, on the other hand the compressor
Assuming 200 g of ice in -10 °C, Q1 = 4440 J
increases the pressure thus increasing
COMPRESSION CHILLERS
of heat is applied to raise the temperature from
the temperature of the gas, which makes
Compression chillers are machines to collect
-10 °C to 0 °C, Q2 = 66,800 J to melt the ice
it possible for the refrigerant to absorb and
heat from places where it is not needed
release the energy.
and dissipate it to places of no objection.
without raising the temperature, Q3 = 83,740 J
Figure 1: Heat graph.
potential of gas that can absorb energy compared to similar mass of CO2, for example if GWP of a gas is 1700 it means the gas is 1700 times stronger than CO2 in terms of energy absorption. It is important to notice that GWP is controversial (EPA, 2017).
53 â&#x20AC;&#x201D;
â&#x20AC;&#x201D; 54
Refrigerant
Ozone Depletion Potential Global Warming Potential
also possible to transfer heat from places of lower temperature to higher temperature only
R-11 Trichlorofluoromethane
1.0
4000
R-12 Dichlorodifluoromethane
1.0
2400
R-13 B1 Bromotrifluoromethane
10
0
0.05
1700
0
650
R-113 Trichlorotrifluoroethane
0.8
4800
R-114 Dichlorotetrafluoroethane
1.0
3.9
R-123 Dichlorotrifluoroethane
0.02
0.02
R-124 Chlorotetrafluoroethane
0.02
620
Compression chillers component
R-125 Pentafluoroethane
0
3400
Compression chillers mainly composed of
R-134a Tetrafluoroethane
0
1300
4 major components, the compressor, the
R-143a Trifluoroethane
0
4300
evaporator, the condenser, and the thermal
R-152a Difluoroethane
0
120
expansion valve. Here the functionality of
R-245a Pentafluoropropane
0
0
R-401A (53% R-22, 34% R-124, 13% R-152a)
0.37
1100
R-401B (61% R-22, 28% R-124, 11% R-152a)
0.04
1200
R-402A (38% R-22, 60% R-125, 2% R-290)
0.02
2600
R-404A (44% R-125, 52% R-143a, R-134a)
0
3300
R-407A (20% R-32, 40% R-125, 40% R-134a)
0
2000
R-407C (23% R-32, 25% R-125, 52% R-134a)
0
1600
0.283
4.1
R-507 (45% R-125, 55% R-143)
0
3300
R-717 Ammonia - NH3
0
0
R-718 Water - H2O
0
0
R-729 Air
0
0
R-744 Carbon Dioxide - CO2
0
1
R-22 Chlorodifluoromethane R-32 Difluoromethane
R-502 (48.8% R-22, 51.2% R-115)
Table 3: Refrigerants.
if external work is involved. In compression chillers external work in terms of mechanical work by compression chillers are constantly doing work on the system to make sure that the heat will flow from lower temperature to higher temperature, the basic principle upon which compression chillers are working.
each component is briefly discussed.
Figure 2: Reciprocating Compressor Schematic.
compressors (Figure 2.) refrigerant is sucked by the piston and then pumped back through the discharge chamber by support of series
The compressor
of suction and discharge reeds. It is important
In a compression chiller compressor is the
to mention that reciprocating compressors
main heart of the system driving the machine, it
are easy to build and cost less than rotary
increases the pressure of the vapor refrigerant
compressors, but the issue with reciprocating
circulating the compression chiller, and drives
compressors is its high noise level and high
the refrigerant through different compartments;
vibrations. They can reach up to very high
compressor is responsible for most of the
capacities and despite all above mentioned
energy consumption of the system. The
challenges for applications of more than 1
mechanical work by the compressor increases
Megawatt reciprocating compressors are the
the pressure of the gas thus increasing its
only solution. (Carel, 2017)
temperature as well, based on Gay Lussacs Law. The refrigerant entering the compressor
Rotary Vane Compressors
should be in gaseous state, or else liquids are
The compressor consists of a cylindrical
incompressible. There are different types of
casing with two openings, one for suction of
Compression chillers function based on
cycle is widely used in natural gas plants,
compressors using rotating or reciprocating
the refrigerant and other one for discharging
vapor-compression refrigeration (VCR) cycle
petroleum refineries, food and beverage
systems. Reciprocating compressors feature
the refrigerant. A rotor is positioned in center
through which refrigerant undergoes a phase
processing industries. (Araner, 2017)
reciprocating motion similar to that of a piston
of the cylinder and driven by motor to apply
change. VCR refrigeration is considered to be
A very simple definition of Second law of
to compress the refrigerant while rotary
pressure on the refrigerant, in this chamber
harmful to environment but it is still applicable
thermodynamics states that heat can only
compressors like rotary vane, scroll, screw and
the refrigerant is compressed (Pneumofore,
and the time to switch to an environmentally
spontaneously flow from higher temperature
centrifugal compressors feature a rotational
2017). One of the advantages of rotary vane
friendly solution is not very close. The VCR
to lower temperature (Ben-Naim, 2010). It is
movement. (Carel, 2017). In a reciprocating
compressor is its low cost and compacted
55 â&#x20AC;&#x201D;
â&#x20AC;&#x201D; 56
to 120 kW, scroll compressors are limited
The condenser:
in terms of applications or are at least not
After compressor the refrigerant enters condenser, here the refrigerant releases its energy and condenses back to liquid and partially vapor, the function of a condenser is to make sure that refrigerant releases its energy into condenserâ&#x20AC;&#x2122;s medium either water or air. There are generally two types of mediums for condensers air medium or water medium. For compression chillers mostly water is used (Miller, 2017). If the condenser uses air, it resembles the functionality of a radiator that cools down engine in a car. Radiators use an air blower to force air through wide surface of refrigerant lines, the condenser is designed in way to ensure maximum surface touch between refrigerant and air. Air cooled condensers require outside temperature of 35 degree Celsius or below to operate effectively (Miller, 2017). Water cooled condenser perform similar function as air cooled condensers, and the only difference is that water cooled condensers work in two stages, first in condensing chamber the refrigerant releases its heat and water absorbs the heat (there is no direct contact between refrigerant and water, the heat exchange occurs through the surface of refrigerant pipes inside the condenser), in second step hot water is pumped to cooling tower where again the water is blew by air and excess heat is released to atmosphere, after water is cooled down it is directed back to condenser chamber where it starts back capturing excess energy from refrigerant and repeats the same cycle again.
preferred compared to its competitors, piston and rotary compressors which are preferred for small capacity applications and screw and centrifugal compressors which are preferred for higher capacities. (Carel, 2017) Advantages of scroll compressors are their Figure 3: Rotary van compressor (NPTEL, 2017)
small size and lower weight than medium size reciprocating compressors, albeit higher than
dimension, due to this fact vane compressors
rotary compressors. They also have excellent
are suitable for small commercial uses like
efficiency at a predefined compression ratio.
fridges, freezers, air-conditioners and etc.
They also have lower noise level and reduced
(Carel, 2017). A more advanced version of
vibrations. (Carel, 2017)
rotary vane compressor has double revolving
Screw compressors:
rotors in opposing directions, which in return generates less noise and less vibration. Rotary vane compressors are preferred than scroll compressors which are more expensive and also bulky. Double rotors compressors have also increased energy efficiency and has the same cost as regular ones. They are suitable for applications of up to 50 kW. These compressors can reach up to 7800 rpm while scroll compressor typically achieve 5400 to
Screw compressors are made of two driving screws attached to each other, these screws are joined in a way that the space between them gradually decreases as the screws are rotated and refrigerant is driven toward the outlet of the compressor, due to decrease of space between screws, pressure increases inside the compressor chamber thus compressing the refrigerant. Screw compressors require lubrication and come with built in oil and
6600 rpm (Carel, 2017).
lubrication cooler. (Air compressor guide,
Scroll compressors:
2017)
These compressors use two scrolls, one of
Centrifugal compressors:
them fixed to the body of compressor while
Main part of these compressor is the impeller;
the other one is rotated by the motor, these two
the compressors sucks the refrigerant and
scrolls are designed and positioned in a way
directs it to impeller where it is rotated in high
that rotating scroll pushes the refrigerant thus
speed and gains kinetic energy, later the gas
compressing the refrigerant and discharging.
escapes the impeller and the kinetic energy
(TestEquity LLC, 2017) They are used in
is converted to compression. Centrifugal
homes, commercial air-conditioning systems,
compressors are limited to high cooling
Thermostatic Expansion valve (TXV):
and heat pumps. Capacity ranges from 3
capacities usually large chillers. (Carel, 2017)
Thermostatic expansion valve is the key
Figure 4: Thermal Expansion Valve.
element of refrigeration cycle. It controls the flow of refrigerant and decreases the pressure of refrigerant. Thermal expansion valve uses temperature sensing bulb filled with the similar refrigerant as main refrigeration cycle. The valve has an orifice with a closing cap which is regulated by a moving pin, the pin is connected to a diaphragm and it moves according to pressure increase or decrease of the refrigerant in evaporator and sensing bulb. As the temperature in evaporator increases, it indicates that more refrigerant flow into evaporator is needed. The high temperature at outlet of the evaporator heats up the sensor bulb thus increasing the pressure of bulb, the refrigerant expands and pushes the diaphragm inside the expansion valve, the diaphragm then moves the connected pin and opens the closing cap and allows more refrigerant flow, as more refrigerant flows the temperature at the outlet of evaporator decreases, and the gas inside the sensing bulb cools down. As a
57 â&#x20AC;&#x201D;
â&#x20AC;&#x201D; 58
result the pressure in sensing bulb decreases
like rigidity and safety for the tubes, they
inside cylinder and water inside the tube,
malfunctioning of the system and decrease in
and pulls back the diaphragm and closing
are easy to clean, and helps capture of
it is a flooded type of chillers. (Khemani &
efficiency of the evaporator.
back the refrigerant flow. Inside thermostatic
heat by refrigerant, further they are easy to
Stonecypher, 2010)
expansion valve there is a spring constantly
manufacture and cost less. They can be
pushing the diaphragm and keeping the cap
formed easily into the required shapes, for
close to stop the refrigerant flow, the spring
example box shapes to form closed spaces.
pressure is adjustable which makes it easy to
Plate type evaporators can easily be seen
optimize the function of valve (Whitman, et al.,
in some fridges and freezers. Due to these
2005).
advantages and flexibility they are used
The evaporators
extensively. (ref-wiki.com, 2017)
Evaporator in a chiller is responsible for absorbing heat from warm water and to produce chilled water using the refrigerants capacity to absorb heat from water and evaporate. There are different types of evaporators for various refrigeration applications. They can be classified according to their construction, method of feeding the refrigerant, and etc. There are three types of evaporators based on their construction: bare tube evaporators, plate type evaporators, finned Evaporators, shell and tube evaporators. (Khemani & Stonecypher, 2010) Bare Tube Evaporators: as the name suggests these are evaporators made up of either bare copper tubes or steel pipes. Steel pipes are used for ammonia as refrigerant while copper tubes are used with other refrigerants. The bare tube evaporators are usually used for liquid chilling. They are used in very few applications, but the bare evaporators attached with finned mesh plates are common, called as finned evaporators. (Khemani & Stonecypher, 2010)
Plate type evaporators: In this type of evaporators the tubes are constructed inside the plates, the plates provides advantages
Finned Evaporators: They are the bare tube type evaporators covered with fins. With the bare tube type evaporators, due to few surface contact area less heat is absorbed from the cooling medium either water or air, on the other hand when covered with fins more surface for refrigerant tube is created thus facilitating the absorption of heat. The fined evaporators are more efficient compare to bare tube evaporators. (Khemani & Stonecypher, 2010) Shell and tube evaporators: Almost all of the chillers uses this kind of evaporator. These types of evaporators are composed of single large steel cylinder. Inside this cylinder the warm water tubes which has already collected excessive heat run through it and cools down by dissipating heat to refrigerant. There is no direct connection between the refrigerant and the water tubes the heat exchange occurs through the surface wall of the chilled water tubes. Depending on the direction of flow of refrigerant there are two types of evaporators: Dry expansion type and flooded type chillers. The only difference between both is direction of refrigerant flow, if refrigerant flows alongside the tubes and water alongside the cylinder it is a dry expansion type, if refrigerant flows
Refrigerant loop
Compression chillers operation loops
The refrigeration cycle is the fundamental
Compression chillers have generally three
process
cycle, first the chilled water cycle where it
compression chillers. The refrigeration cycle
collects heat and brings it to evaporator,
consists of following components
second the refrigerant cycle which transfers the heat to condenser, and third is the condenser loop which collects heat from refrigerant and
behind
cooling
effect
of
the
-- Compressor -- Evaporator
transfers it to place of no objection.
-- Condenser
Chilled water loop
-- Expansion valve
In this cycle chilled water (typically between 4
Just
to 7 degree Celsius, (Brain, et al., 2017)) leaves
refrigerant is liquid, with high pressure and
the evaporator and travels into residential units
high temperature as it passes through the
or offices to collect heat via radiators, next step
expansion valve, due to throttling effect of
it simply brings heat to evaporator where later
expansion valve the pressure decreases and
the water loses the absorbed heat back to
so temperature as well.
refrigerant and it is cooled down, in evaporator
Now after passing the TXV the refrigerant with
chamber there is no direct contact between
low pressure and low temperature enters the
refrigerant and the chilled water, rather the
evaporator in a saturated mixture liquid and
heat is exchanged through skin of meshed
gas refrigerant, the liquid refrigerant boils inside
lines of refrigerant. It is important to keep
the evaporator and absorbs heat from the chill
refrigerant isolated from chilled water to avoid
water cycle, totally evaporating and to be sure
Figure 5: Refrigerant cycle.
before
the
expansion
valve,
the
59 â&#x20AC;&#x201D;
â&#x20AC;&#x201D; 60
that only refrigerant in gas state is entering the
gas by evaporation and in condenser the
compressor, the refrigerant should ideally be
refrigerant phase changes from gas to
superheated (a vapor heated to more than
liquid by condensing. Figure 7 shows the
its boiling temperature) this is regulated and
expansion valve and compressorâ&#x20AC;&#x2122;s function. The TXV changes pressure from high to low and decreases refrigerant temperature on the other hand compressor increases refrigerant pressure from low to high thus increasing the temperature. Condenser loop Water in condenser loop absorbs energy from refrigerant in condenser and condenses the refrigerant, the captured heat is later transferred
Figure 6: Condenser and Evaporator phase change.
to cooling tower, where the transferred heat is
Figure 7: Expansion valve and compressor pressure change.
compressors, if liquid refrigerant enters in
compressing equipment either rotors, screws
large amounts it causes hydraulic shock
or scrolls all are vulnerable to liquids, simply
leading to compressor failures, even in small
because liquids are hardly compressible, so
amounts can simply dilute the oil and destroy
excessive compression by compressing units
compressor bearings. (achrnews, 2005)
in compressors leads to their destruction.
In reciprocating compressors, check valves
98% of the times that a compressor fails is due
COMPRESSION CHILLERS OPERATION too, and the refrigerant is still in gaseous state. CHALLENGES
that control refrigerant inflow and outflow
to a problem in the system that causes the
is a vulnerable part of the system. When
Next step the high pressure, high temperature
compressor to fail. Some of the very common
As mentioned before, compressor acts
operating the compressor, a broken check
gaseous refrigerant travels to condenser,
causes are also listed below (Park, 2009):
as heart of the compression chillers and
valve in suction line allows the compressed
where it meets cooled water coming from
it is the main driver of the system, making it
gas back to suction line, thus increasing the
cooling tower, due to the temperature
also the most vulnerable part of the system.
pressure in suction channel and stopping
difference between the refrigerant and cooled
Compressors operation required continuous
proper flow of refrigerant into compressor,
water, the heat is lost from refrigerant to cooled
inspection and maintenance of not only the
similarly when the diffusion line check valve is
water, as a result the refrigerant is cooled down
compressor but other parts like evaporator,
broken the compressed gas can back flow
and forms saturated mixture of liquid and
condenser, TXV, pumps, radiators, cooling
into the compression chamber and may not
gaseous refrigerant, and leave the condenser
tower, piping, valves, and etc.
only decrease the efficiency of the system but
with same pressure as before heading toward
The oil level in compressors easily lowers and
can cause complete breakdown of the entire
the thermal expansion valve and repeating
decreases the efficiency of the compressor,
system too.
the same cycle again and again. For more
in different compressor designs oil is part of
A challenge in operating compression chillers
clarification see figure 6 and 7.
the requirement for fully functionality of the
is to ensure that compressor receives only
Figure 6 simplifies how evaporator actually
compressors.
refrigerant gas. Liquid refrigerant inside
changes refrigerant phase from liquid to
Liquid refrigerant is another problem for the
compressor could cause destruction of
dissipated into atmosphere either by blowing air or by natural air flow if outside temperature
ensured by the bulb sensor of the TXVs.
is appropriate. The water is cooled in cooling
After absorbing heat, the refrigerants enters the
tower and then driven back to condenser in
compressor, here the compressor increases
order to collect back the heat from refrigerant.
its pressure, thus increasing the temperature
-- Dirty evaporators or condensers -- Improper refrigerant charge -- Miss adjustment of Expansion valves -- Clogged
pipes
and
tubes
inside
condenser -- Pressure loss or malfunctioning of sensor bulb in TXV Refrigerant leakage is one of the worst issues of operating chillers, a leakage not only cause loss of refrigerant but also have significant
environmental
impact
as
all
61 —
refrigerants are classified according to their impact degree on global warming and ozone depletion potential, some can cause serious environmental impacts. It also requires very careful inspection to first find out a leakage in its early stages, later locating the leakage itself is a challenging job especially if it is inside condenser or evaporator. Important issue with chillers’ evaporators and condensers is the erosion of refrigerant and water channels not only due to corrosive property of refrigerant but also due to a long term significant temperature fluctuation which in presence of the extra corrosive dissolved minerals in water simply forms limescales and masses attached to the pipes and tubes and can even block lines in condensers. Similarly in water cooled systems, the water used in cooling tower is continuously warmed up and cooled down, if not proper precautions are taken, water can form limescale inside condenser units or cooling tower, not only might significantly decrease cooling tower’s efficiency, but might completely block it. In thermal expansion valves the pressure formed by the sensor at very end of evaporator might not always be accurate to control refrigerant flow, to make sure that least liquid refrigerant is allowed into compressor. Maintaining and controlling the correct pressure at both side of the controlling membrane which regulates valve opening is a challenging job. Space requirement for compression chillers is another issue, especially with water cooled systems, which requires additional cooling tower, while air cooled systems requires less
— 62
area and are easier to install too. Similarly, there are a lot of other issues with other mechanical parts of the compression chillers like minor problems with chilled water radiators inside homes, offices or industrial compartments to be cooled, with plumbing of both chilled water loop and condenser loop, with water pumps used to circulate the water in these loops, and etc. These problems are easy to discover and solve compared to problems in refrigeration loop.
RECOMMENDATIONS Compressor as the main mechanical unit of the compression chillers consumes most of the energy required by the entire unit. Operators must ensure that this part of the system is performing efficiently. Continuous monitoring of the compressor could be one of the measure to take for checking any deficiency in performance. It is also important to notice that most compressors do not support easy routine inspections, simply there is no way to inspect them, as discussed in previous sections some are even not able to open. So one way is to consider design modifications to support routine inspection (achrnews, 2005). As discussed previously oil in compressors lower easily and can cause inefficient operation of it. To detect any potential fault in oiling system of the compressor, the oil level should continuously be monitored and checked daily, further the additional routine oil supply of the compressor should be noted every time the compressor oil compartment is refilled, the refilled amount should be cross checked with manufacturer’s guide and design specification to detect any potential
fault in the system. Condenser medium of cooling has its own design requirements as well as operation restrictions, making it hard to generally recommend one. There are always pros and cons with each alternative, a logical trade off can be done considering the restriction and concerns of installation and operating a unit. If life cycle cost of refrigeration and operation costs are matter of concern, the proper option would be to use water cooled system, because in long run water cooled condensers consume less energy than air cooled system due to the fact that water cooled system do not need continuous air blower run by electricity. However, water cooled systems require more initial investment because of numerous pipe installations and the water tower itself. On the other hand if water cost is a major concern, then using an air cooled system is the proper option, because of water losses in water tower due to evaporation or leakages. Initial cost of air cooled system installation is many times less than that of water cooled, because it requires fewer supporting units and plumbing, also its installation is faster and easier. In air cooled chillers, it is also possible to separate the condenser section entirely and put it outdoors, away from the chiller to increase efficiency and performance of condenser. (Miller, 2017) As it is vivid the general procedure by which a compression chiller functions is the proper absorption of heat by evaporator and releasing by compressor. In most compression chillers where both these units are manufactured very close to each other it is a must to
insulate them properly, one might argue that may only insulation of evaporator is needed because this unit absorbs energy from water coming to be chilled and it is necessary to insulate the evaporator to avoid unwanted heat absorption from surroundings of the evaporator, but indeed it is also important to insulate the condenser too, due to the fact that condenser actually hosts high temperature refrigerant and can simply dissipate heat to surroundings easily and in some cases it can directly affect the evaporator and may cause evaporator to capture the dissipated heat this is specifically true when evaporator and condenser are manufactured in single unit close to each other. Generally talking, it is necessary to insulate properly both the condenser and evaporator. On the other hand if the condenser is sufficiently outside that its dissipated heat does not significantly warm up surroundings of evaporator, it would be beneficial to remove the insulation of the condenser to make it easier for the system to get rid of unwanted heat in refrigerant. It is important to mention that all manufacturers currently are aware of this issue and to a very high extent this concern has already been addressed. The water used either in condenser loop or chilled water loop should be initially tested for presence of unwanted corrosive hard minerals which can simply form around the pipes and cause clogging. This can simply be achieved by sampling the water and testing it, if high concentrations of these minerals are detected the water should be replaced and pure water should be charged back into the system.
63 —
— 64
Even without presence of these minerals, it is
loop, and condenser loop. The four main
important to regularly replace chiller waters,
part of the compression chiller are principally
because no matter how precisely a chiller
working in refrigerant loop, while condenser
system is maintained it is always possible
and evaporator shares it with condenser and
for water to corrode the steel pipes due to
chilled water loop respectively too.
dissolved oxygen and mix the fine corrosion
Compressors
particles with itself, consequently decreasing
compression chillers, they are also highly
the efficiency of the relevant loop, and the
responsible for most of the power consumption
entire chiller system too.
of the system, thus making them most
CONCLUSION
vulnerable part of the system too.
are
main
drivers
— Laura Garcia Rios of
the
Laura Garcia Rios is currently making a master focus on Sustainability and Resource Efficiency (M.Sc. REAP) and working as a tutor and research assistant in HafenCity University, Hamburg. She is graduated from Los Andes University from Colombia with B.A. Economics. Her main professional focus is business development and economic consultant of environmental and social projects.
compression
Despite all operation challenges there are
chillers principally uses the high capacity of
specific measures to take in order to optimize
refrigerant’s latent heat of vaporization and
the chiller’s operations which are discussed
phase change to extract heat from one location
as recommendations in last part of this paper.
to another one, leading to a cooling effect.
Generally, best recommendation for proper
Main components of compression chillers are
operation of compression chillers is to make
ABSTRACT
electric bus for Bogotá even thought is a big
compressor, condenser, thermal expansion
sure that compressor is working well, and 98%
This report studies the benefits of switching
challenge; the electric bus could contribute
valve, and evaporator, while there are other
of the times compressor fails because of other
from diesel buses to electric buses for the
parts as well like cooling tower, chilled water
parts of the system not functioning properly,
Bogotá public transportation system. The
circuit water pumps and several other.
so concluding to the fact that best operation
report provides a descriptive analysis of the
There are three main cycles in compression
can be ensured by proper servicing of all
electric buses in the public transport system
chillers, the chilled water loop, refrigerant
other parts of the system too. —
As
mentioned
previously
and how the technology of electric buses has been developed in the different markets during the last decade. In continuance
APPENDIX
with the study, the benefits that bring by the replacement of the current vehicle fleet with electric buses in the public transportation system in the city of Bogotá are evaluated, in environmental, economic and social terms. Finally, taking into account the descriptive analysis results and the results from the specific case of implementing electric buses in Bogotá, the report finalizes with a discussion
significantly in the Bogota’s inhabitant life quality, especially with improvements such as emission reduction and lower noise level. According to Eurostat European Environment Agency calculations, all sectors have reduced their emissions except the transportation sector; countries such as Germany have reduced their emissions in all sectors by 27 % between 1990 and 2015; however, in the transport sector the reduction has been only 9.8 % (EEA, 2017). The transportation sector is the second largest source of CO2 emissions
from energy use. In 2012, transportation emitted around 10 Gt CO2e and consumed
half the world‘s oil consumption (ICCT, 2012). CO2 emissions from the transportation sector have increased faster than emissions from
and conclusion about the city for future
other sources over the past two decades.
assessments. The main conclusions drawn
Greenhouse gas (GHG) emissions from
by the proposed evaluation process is that the
buses for the year 2015 are forecast to be
65 —
around 700Mt of CO2, with a 50% growth rate expected by 2030 (ICCT, 2012). Using electric buses could further reduce GHG emissions. Nevertheless, the actual data shows that the number of buses, especially in developing countries, is growing rapidly (Frost & Sullivan Report, 2013). It is expected that more than 80% of the buses in 2020 will be acquired in developing countries (Frost & Sullivan Report, 2013), and Colombia is not an exception, where from 2013 to 2016, the buses fleet increased with diesel buses by 53% (Bogotá Mobility Observatory, 2017). Bogotá, the capital of Colombia, is the largest regional economy in Colombia, generates more than 26% of the national GDP and is the third most populous city in Latin America. According to the UN-HABITAT 2012 report, in Latin America, there are 8 mega-cities and Bogota is one of them with almost 8 million inhabitants. In order to process economic dynamics and to attend the needs of its inhabitants, a mega-city has to meet high demands of environmental goods and services, which leads to large amounts of waste and emissions, high financial costs and high impact for human health, undoubtedly generating negative impacts on the environmental, social and economic level. Currently 5,000,000 people, or almost 70% of the city‘s commuters, travel each day by diesel bus. It has been estimated that mobile sources are the main cause of air pollution in major Latin American cities, particularly those located at a high elevation like Bogota, with an annual CO2 of 15.9 million tons, of which 44% is due to transport. SO2, NOx, TSP, CO,
— 66
HC, O3 are some of the prominent elements of its air composition, with a 75% presence of particulate matter, especially PM10 and PM2.5. Similar to other cities, Bogotá can improve its current situation by deploying electric buses in the public transportation system. According to the Automotive District Institute, of the 90,000 mobilized vehicles located in the city of Bogota, approximately 24,000 are public transport buses. The main objective of this research is to analyze the social, economic and environmental impacts and benefits of replacing the current buses with 24,000 public transportation electric buses, considering assumptions that facilitate the study and with the goal to answer the following two research questions; the first one collect information about the main technologies and the global market of electric buses and the second one considers Bogotá as a case study.
RESEARCH QUESTIONS — What are the main electric bus technologies used in the last 10 years in the public transportation sector and how efficient are the electric buses technologies compared to other technologies available in the market? — In Bogotá case, how is the current situation of the city bus fleet, and what are the main benefits in sustainable terms if electric buses are implemented in the public transportation system?
public transport are described. This section summarized information about what the main electric bus technologies used in the last 10 years in public transportation system are, how efficient the electric buses technologies are, the global market for these technologies, and challenges for the future. The second section is the Case Study Evaluation Process, where the benefits of implementation of electric buses in the public transportation system for Bogotá in sustainable terms are estimated. It continues with the evaluation process: a social, environmental and economic level is considered in this section to evaluate the main challenges and benefits at those levels. At the environmental level, CO2, VOC, NOx, PM10 measures from the local environmental observatory are the primary reference. In the economic level comparison of profitability between different technologies including the initial costs, the energy consumption of the electric buses vs. diesel are studied based on the actual prices of the same bus brand. The difference in the national taxes and local fees of a new electric bus fleet vs. a diesel bus fleet and local fuel prices are also taken into account as an assumption for this process.
METHODOLOGY In order to answer the this study is divided into section is the Analytical market and the electric
research question, 3 sections. The first Process, where the bus technology in
Figure 1: Alternative Bus Technology..
The Prescriptive Process, in which critical results, recommendations and challenges are given based on the analytical and evaluation process results. The analytical and evaluation process of this study collect and analyze data based on available information from reliable research projects. The first process is based on numerous documents, however this information is provided by the main bus producers, the main international technical reports and researchers, such as Fraunhofer or ZeUs (Zero emissions Urban bus System) who evaluate the economic, environmental, societal feasibility of electric urban bus systems through operational scenarios across the world. The market research analyses and technology analyses are based on the Frost&Sullivan Research‘s Reports. For the second process, the evaluation is based on prior studies published by the main Colombian Research Institutes and the university leading mobility research. This is due to the fact that since the eighties, the organization of urban transport is a municipal responsibility; the data collection for second process is made through the database of
67 —
the IDU (Urban Development Institute of Bogotá), Secretary of Mobility of Bogotá, Environmental observatory of Bogotá. Furthermore, publications provided for the environmental department from los Andes University focus on mobility emissions and the study “Low carbon technologies can transform Latin America” from Inter-American Develop Bank (IDB) guide for the sustainable evaluation process. This chapter covers technical details related to buses specifically the aspects of charging, energy storage and propulsion system as shown in the figure 1. According to the last ZeUS report, the electric bus can come in different forms, depending on the type of technology used to produce the bus. In contrast with the hybrid or the diesel buses, the electric bus refers to a motor road vehicle emission free at the point of operation, because the battery driven that the buses use to have a lower environmental impact than an internal combustion engine system (2017,
Figure 2: Battery Technology Roadmap.
— 68
ZeUS Report). As is shown in the Figure 1, the electric bus is composed of 3 important technologies: the charging infrastructure, the energy storage system and the propulsion system.
THE CHARGING INFRASTRUCTURE The charging infrastructure can be categorized as one of three types. A plug-in, which refers to the relates to the direct charging, inductive charging, where the bus is charged wirelessly by creating a magnetic field between two inductive plates and overhead charging, that uses the same method that has been applied by trolleybuses since the „Electro motor”, which was the world‘s first trolleybus in Berlin, Germany, 1882. Surprisingly, nowadays the overhead charging is the most expensive system due to costly investment in the city infrastructure.
ENERGY STORAGE SYSTEM The energy storage system can be categorized
Function
Electric Bus
Diesel Bus
Energy source
Battery
Diesel tank
Replenishing energy source
Charger
Diesel pump
Mechanical energy generator
Traction motor
Diesel engine
Speed and acceleration control
Electronic controller
Mechanical carburetor
Power supply accessories
Electronic power converters
Alternator
Regenerative braking
Motor/Generator
CO2 with heat recovery
188
252
(kg/MWh)
Table 1. Equipment comparison between electric buses and diesel buses.
under 3 types of mature technologies. First, ultra-capacitors, which work by mechanically separating the negative and the positive charges on two parallel plates, and connects them electrically via an electrolyte (Fraunhofer, 2014). Compared to batteries, Ultracapacitors have a longer life cycle (Urban Foresight et al. 2014), have a higher power density can be charged and discharged within a shorter period, however these systems are only able to store 10% of the energy that the best battery technology can. Batteries are the most common storage system used, and can currently be found in types of such as Pb, NiCd and NiMH, which are considered mature technology in the following battery technology road-map, figure 2. Other types such as lithium-ion (Lis and Li air) are the most innovative batteries but are currently still in development (Meisenzahl, S., P.-P. Sittig, and M. Höck. 2014). In conclusion, batteries have a broader market and due to the difference in cost, energy density, weight, lifetime, power density, selfdischarge and recycling, it cannot be said that one is better than the others because it
depends on the usage and market maturity, as shown in the figure 2. The third type of energy storage system is fuel cells, which in comparison to batteries need a continuous source of fuel and oxygen to sustain a chemical reaction. Hydrogen has the highest energy density available, but hydrocarbons or alcohols are also suitable as fuels. This type of energy storage system has a low energy density and as a consequence, requires large fuel tanks and has a longer response time. Fuel cells have a high conversion efficiency of fuel to electrical energy, a low noise emission, and almost no greenhouse-gas (GHG) emissions. However, fuel cells are more expensive due to the high price of the main raw material: platinum and palladium. (Fraunhofer, 2014). Fuel cell-powered buses continue to be demonstrated in public transport services around the world. In the last 10 years, demonstration projects have been launched in various stages of implementation. Many have been finished, and some of them are still on process. (Zlatomir Živanović and Zoran Nikolić, 2012).
69 —
— 70
PROPULSION
propulsion system with the electric propulsion
Electric and electric buses. This is followed by
(Albright, Edie, and Al-Hallaj 2012). On the
A Propulsion system refers to the technology
system. Hybrid buses are further classified
the advantages and disadvantages of each
other hand, diesel, CNG, and hybrid buses
into the following segments according to their
segment using data from different research
have higher maintenance requirements and
drive system configuration: the hybrid series,
studies. Although much evidence can be found
costs (Noel and McCormack 2014). Diesel
where the internal combustion engine is solely
to support the benefits in terms of sustainability
maintenance includes frequent oil changes,
connected to the power converter in order to
of electric buses and it is well-established in
filter replacements, periodic tune-ups, exhaust
charge the battery and to propel the electric
the literature that the use of electric buses
system repairs, water pump, fuel pump and
engine, the hybrid parallel which connects
will bring down the overall Greenhouse Gas
alternator replacements, among others.
both engines to the power transmission and is
(GHG) emissions (IEA 2012), the diesel buses
Even though prices can vary within the same
called parallel because the bus can work with
continue as the leaders of the market. This is
segment, as is shown in the comparison
one or both at the same time, and the hybrid
attributed to a mature technology with a well-
table 2. electric bus prices are, on average,
combined, where both other types of hybrid
established supply chain and competitive
5.2 time higher than CNG and diesel buses,
drives are combined connecting the internal
pricing which makes the electric buses not
and electric buses on average can cost 20%
combustion engine to the transmission,
attractive for the consumers. Electric bus
less than a hybrid bus because hybrid buses
helping to recharge the battery, and making
prices are the highest when compared to the
combine 2 types of power source (Electricity
this technology more complex compared to
other four segments, mainly due to battery
& Fuel). Nevertheless, diesel, CNG and hybrid
the hybrids systems (Shen, C., P. Shan, and
costs, the complex design of power train
buses prices as well as electric buses prices
T. Gao. 2011.)
systems and nascent technology. (Delucchi
have been reduced since 2012. On the
2001) (Noel and McCormack 2014).
other hand, the operating costs of the electric
Related to maintenance, electric buses are
buses are less when compared with internal
the segment that has fewest moving parts,
combustion system buses (CNG, Diesel,
making their design the least complicated
Hybrid) due to lower maintenance, cheaper
amongst the four buses segments. Electric
power, and higher fuel efficiency. However,
buses have controllers and chargers, which
the high initial capital costs of the electric bus
are in charge of managing power and stored
and its charging infrastructure make them
energy levels in the battery. Apart from that,
expensive (Global Green Growth Institute
there are no other electronic devices with
2014). Van Hool completed data collection
moving parts and almost no maintenance.
and analysis on nitrogen oxides (NOx)
The batteries used by the electric buses
emissions and Particular matter (PM) of 3
require minimal maintenance and in some
different fleets of buses for 50.000 km per year
cases is better to replace the whole piece
with an average speed 20 km/h, and is shown
that produces thrust to push an object forward. It can come as a motor, hybrid or pure electric type. The motor is the most common and mature technology used around the world. The first commercially successful internal combustion engine was created by Étienne Lenoir around 1859 (Encyclopedia Britannica, 2013). As is showed in the table 1, the equipment between electric buses and diesel buses vary depending on its function, in electric buses the equipment motor/generator take over the function of regenerative breaking, a highly efficient process. While the energy from this process in diesel buses is essentially wasted, in electric buses it saves an energy consumption of approximately 30%. Furthermore, some of the difference in function
BUSES TECHNOLOGY COMPARISON
of the equipment represents the difference in
This section showcases a comparison
efficiency, maintenance, costs, noise, etc. as
matrix among four segments and collects
explained in the comparison section. Hybrids
information from different technology analyses
combine the internal combustion engine
illustrated in the table 2: Diesel, CNG, Hybrid
Parameters
Electric Bus
Hybrid Bus
CNG Bus
Diesel Bus
Power Source
Electricity
Electriicity + Fuel
CNG
Diesel
Power Generator
Battery
Internal
Internal
Internal
Combustion
Combustion
Combustion
Engine + Battery
Engine
Engine
Enery Losses
1.02k Wh/km
-
-
3.640kWh/km
Investment Costs
5.2 x
6.4 x
1x
1x
Fuel Efficiency
10.2 km / l
1.9 km / l
1.4 km / l
1.6 km / l
Fuel Cost
0.13 € / km
Emissions
zero
low
low
Noise
minimum
low
Maintenance
low
high
Bus Technology
NOx (per year)
PM (per year)
high (baseline)
100 Diesel Euro III buses
65.5 tons
1.25 tons
high
high (baseline)
100 CNG buses
25 tons
0.25 tons
high
high
100 Hybrid fuel cell buses
zero
zero
0.17 - 0.22 € / km 0.17 - 0.27 € / km
Table 2. Comparison of different parameters and Bus Technology
0.2 - 0.31 € / km
Table 3. Main parameters matrix among the segments comparison..
71 —
— 72
in the table the results presented; while hybrid
98.3% of the world market. This development
electric buses in 2016-2017, half of them to
Latin-American is expected to have the 21% of
fuel cell buses have zero nitrogen oxides and
is attributed to a strong Chinese government
be fully operational on the day of the COP22
the share of the global urban buses. Europe
zero particular matter, the CNG buses emit 25
policy, with an official program for ‘new energy
climate change conference in November
and North America are only expected to be
tons of NOx and 0,25 tons of PM per year and
buses’ that is looking to produce 1.67 million
2016. In Latin America, it is the same case
part of the market at 8%, with growth rates
the same bus fleet of Diesel segment gives
electric buses and expected to create 1.2
as African development and research: taking
smaller than other regions. Hybrid and electric
approximately 3 times NOx and PM of CNG
million jobs annually for the period 2010-2020.
slow steps and the biggest development has
buses producers like Yutong, Wuzhoulong,
buses emissions.
(ZeEUS eBus Report, 2016).On the other
been done in only a few cities, where there are
Foton, Kinglong and BYD Volvo, ADL and
hand, although the European market is one of
some ongoing pilot projects, like Campinas
Daimler are currently leading the global
the leading regions for electric bus research
(Brazil), Montevideo (Uruguay) and Bogota
market, producers that are primarily from
and development, the Asia-pacific region
(Colombia). (Global Green Growth Institute,
China. (Global Green Growth Institute, 2015)
is the biggest producers of both buses and
2015). On average, the additional cost for
According to Frost &Sullivan data, this market
batteries. Additionally, the infrastructure for
a hybrid bus is in the range of $ 100,000 to
has not been explored completely at a global
charging electric buses is currently weak
$ 150,000 and for an electric bus is from $
level. More than 250 BRT are currently under
in many countries, restricting the growth
250,000 to $ 300,000. According to the ZeEUs
planning, which proves the potential of the
of the electric bus market. (ZeEUS eBus
report, in 2010 about 16 million buses is the
new technology buses. Hybrid and electric
Report,2016). In Africa, even though it is the
number of operating buses, and this number
buses are projected to fill the market with
smallest share in bus production, Marrakech
is expected to grow to 18 million buses in
27,000 units, or a 20% annual rate. In 2012
ELECTRIC BUSES WORLDWIDE The operating costs and the capital cost per bus vary greatly between regions; an electric bus purchased in China is in the price range of a conventional diesel bus in North America or Europe. Additional costs as a percentage of hybrid and electric buses are much higher in low-priced markets such as China, India and Russia, and much lower in high-priced markets such as Europe or North America.
is developing a market with the Morocco’s
The worldwide electric bus fleet is estimated
2020, and to 20 million buses in 2030. In
this percentage was just 6% or 8,000 units
Energy Investment Company (SIE,) where
to have reached approximately 173,000 units
2010, China, South Korea, United States,
sold (Frost &Sullivan, 2014).
launch electric buses were produced in 2017
in 2015 where China is leading this global
Russia, and India were the countries with the
for local and international markets. Marrakech
ELECTRIC BUSES FOR BOGOTÁ
new market, with about 170,000 buses, or
largest operating bus fleets, with 17%, 12%,
has also announced the distribution of 30
6%, 6% and 4% respectively. For 2030, China,
Bogotá Background
India and Korea are expected to be the three
Bogotá is the capital of Colombia and is
leading countries with the largest bus fleets.
located in the geographical center of the
In 2020, 300,000 buses are expected to be
country, in the natural region known as the
sold, and the following figure shows the main
Savannah of Bogota, on the plateau of the
regions of buses consumers. (ZeEUS, 2016).
eastern Andes mountain range. The city has
Asia and Oceania currently have 71% of the
a temperate climate, slightly humid, constant
worldwide bus production and just China is
almost the whole year. Temperatures regularly
expected to have 26% of the global market
range between 5°C and 20°C, with an annual
with 70,000 buses units in 2020. It is proof how
average of 14°C. The city has a height of 2600
China is not only the leader in production, but
meters above sea level. It was founded on
will be also be the leader in implementing
August 6, 1539, in times of conquest. In terms
buses for its local public transportation system.
of economic divisions, in Bogotá there are
The Americas have only 13% of the global
more than a thousand neighborhoods with six
production, inside the region the biggest bus
different strata. The highest strata are located
production is in North-America. However,
in the north and northeast, in residences and
Figure 3. Worldwide bus production by region (2011-2013).
Figure 4. Forecast Global Urban Buses Market 2020.
73 —
— 74
apartment buildings surrounded by wooded
moment. The consumption per transport went
the general population of the city of Bogota,
constitutes a public health problem (Harris,
areas and numerous parks and playgrounds.
from 5,040 Gwh/year in 2000 up to 8,242 Gwh/
the requirements and necessities of the users
1985), and the levels of pollution in Bogotá
The neighborhoods with smaller strata and
year in 2012. (Municipality Bogota, 2012).
as well as mobility behavior. The success
are alarming, according to a study carried
where the greater part of the population lives
In terms of environmental impact, the transport
of electric mobility products depends on the
out in streets where the largest number buses
are located to the south and the south-east.
sector in is responsible for 15% of total CO2
fulfillment of users’ expectations (Pierre et al.
transit. It affirms that the noise levels found are
The middle sectors usually inhabit the central,
emissions in the country, meaning 26M tons
2011, Sammer et al. 2008). However, other
considered high levels within the framework of
western and northwestern portion of the city
per year and depends entirely on fossil fuels
indirect impacts that are not perceived for
the institutions that have dealt with the world-
(DANE, 2016). As a result of poor urban
(diesel). Bogotá is not the exception, where
the inhabitants must also be considered.
wide issue, such as WHO and EPA. The main
distribution, the population has to constantly
the transportation system depends 100% on
Altering the vehicle fleet from diesel to electric
avenue of Bogotá reaches levels considered
move to long distances to access their
fossil fuels, its emissions are 6M tons of CO2
technology will bring benefits to Bogotá in
a public health problem, with probable
workplace, according to the study prepared
per year, 1,400 tons of particulate matter,
terms of air quality, noise level, and public
hearing damage on the population most
by the Bogotá Mobility Observatory, based
54,000 tons of NO2.
health. The highest impact for the inhabitants
exposed to it and even other physiological
is related to the air quality, people in any city,
and
generally care about air pollution only when
González, 2011).
it affects them. When diseases result from
Environmental Evaluation
on the District Mobility Department. The main reasons for traveling are: To the residence, work and study with 43.9%, 25.1% and 13.7% of the total trips made in the city respectively in 2009 (Municipal Bogotá Mobility Observatory, 2012). The city is in constant growth, as a result not only of its own evolution but also of the migration and the displacement of the population due to internal conflicts within the country. At present, it has more than 9.4 million inhabitants, this growth has been uneven and there is urban disorder and a lack of goods and services. Despite this, the capital is notable for its large number of cultural activities In Colombia, the transportation system consumes 38% of the primary energy, and it is expected that by 2030, the energy demand for the transportation sector will increase by 2.2 times. In Bogotá the energy consumption of transport in the last decade seems to be fluctuating, although increasing. This would be associated with, among other things, population, economics, urban growth
Sustainable Evaluation Sustainability has been commonly defined most
often
as
“Economic
and
social
development that meets the needs of the current generation without undermining the ability of future generations to meet their own needs“ (WCED, 1987). This study focus on the second research question by evaluating the impact of deploying the current bus fleet with electric buses in the public transportation system instead diesel buses, bringing together the three pillars of sustainability; environmental, economic and social development. The following section summarizes prior research in the field of technical tests and studies from the main local institutes and data collectors. For the environmental evaluation, the benefits and impact are estimated based on prior calculations and the economic evaluation is based on financial analysis of the initial investment of the electric bus and the energy consumption.
the pollution on the other hand, as the public health system is funding by national budget, every cost of healthcare associated with these illnesses will in the end affect the inhabitants. This study does not present any information related to number of cases of diseases results from the pollution in Bogotá, due to the lack of data research in this field. However, air pollution is one of the major contributors
psychological
problems
(Ramírez
According to the Bogotá environmental observatory accounts and research made by Los Andes University where the emissions criteria (CO, NOx SOx, PM10, COV) and (CO2,
N2O, CH4) for every vehicle category were estimated, the buses presented the most critical results, and is the category with the biggest contribution to the total emissions in the city. Buses contribute in a high percentage
when it comes to health and life quality in the
of many pollutants: around 30% of the CO
main urban centers around the world. It has
emissions, 40% of NOx emissions, 40% of
been estimated that mobile sources are the
SOx emissions, 50% of PM10 emissions and
main cause of air pollution in major Latin-
20% of CO2 emissions. However, the situation
American cities, particularly those located
is even more critical, considering that buses
at high elevation such as Bogotá (Project,
represent less than 5% of the city‘s vehicle
2017). During the last few years, Bogotá’s air
fleet (Montezuma, R., 2005). According to the
quality has been continuously deteriorating,
same data, in Bogota, the buses contribute
showing noncompliance with air quality
half of the total PM10 emissions, which is
standards. Mobility being one of the top
one of the most harmful pollutants in terms
contributors in it, with its usage of bad quality
of public health (Neuberger et al., 2004). The
and motor vehicle growth, which has varied
Social Evaluation
diesel has resulted in major respiratory and
large share of this category in CO emissions
according to the circumstances of each
The social evaluation considers the benefits of
stress disorders (UNICEF, 2017). Noise also
(30%), is proof of the presence of a significant
75 —
— 76
number of buses that use gasoline as fuel. It is common in many countries, that most vehicles in this category use diesel as the main fuel (Sawyer et al. 2000). In Bogotá, 100% of public transportation buses use diesel as a fuel. (STT Annual Vehicle Report, 2014). It is clear that the quality of the diesel in Bogotá must be improved. According to the latest report of the Bogotá Mobility Observatory 2016, the problem lies in the quality of the fuel used by buses in Bogotá: the fuel contains 1500 ppm sulfur, a higher content compared to other levels in Latin America where cities like Santiago de Chile have only a sulfur level of 50 ppm. This is a serious problem considering that there is a direct relationship between sulfur content in diesel and PM10 emissions. (Durbin, 2003) Actual vehicle Fleet Emission The are models for estimating emissions from different sources, the most used being MOBILE and COPERT, developed by the United States Environmental Protection Agency (USEPA) and the European Environmental Agency (EEA), respectively. The main drawback of these models is that the emissions estimations for different cities, is influenced by conditions and characteristics that each place has in vehicle emission factors. In 2003, the International Vehicle Emissions Model (IVE) was developed, and
since then it has become the most common model used in cities in developing countries. In the case of Bogotá, the inventory of vehicle emissions was carried out with researchers from the University of California and the International Center for Sustainable Systems Research (ISSRC) using the model (IVE).To estimate emissions per day in this study, the results from the ISSRC research were taken into account, and the fleet increased values and the share were used as assumptions, the distance traveled per day was updated with the 2016 size of bus fleet, which is most recent data from the mobility department of Bogota. Taking into account that in Bogota, the buses fleet totals 24,400 and in a year, the buses travel 18.330.000 km (STT,2014), Assuming that the vehicle fleet has increased with the same share, the CO2e emissions have been estimated for the complete buses fleet from Bogotá: 24,400 buses from different categorizes (size, technology, fuel and age). The total emissions for buses for a year are about 866k metric tons of CO2 per day. CO VOC, NOx, PM10 were also estimated.
thermal source for the environment, (CREG,
models, looking at the power supply to
2016). This is a great advantage for a country
massive electric transport systems. The results
whose public transport works with fossil fuels
show that is possible to develop the necessary
and generates unfavorable environmental
infrastructure and reach the energy demand
impacts. Professors such as Mario Rios
for an electric charging system. This is due
from the electric engineering department
primarily to the fact the maximum demand in
in Los Andes University, who focuses his
Bogotá is around 2,500 megawatts (MW) and
research on massive transportation systems,
the power demand of consumption would
affirms that the electric public transportation
be around 20 megawatts in peak hours,
system, is much faster, more comfortable
which indicates that it would not be a very
and safer: „As a citizen you need a mass
high requirement to reach, even if it implies a
transit system to guarantee these three
change in the redistribution of energy since the
conditions to stop using the private vehicle.“
existing substations located on the planned
He also points out that from the point of view
route are with little capacity available, ie at
of electric supply and demand, there is no
full load. Secondly, the company Codensa
impediment to establishing it. Codensa, which
has the capacity to make this redistribution.
ENERGY SOURCE AND FEASIBILITY According to the Energy Generation Commission Regulation (CREG) in Colombia, 70% or 80% of the energy generated is hydraulic, and non-polluting. The rest is produced with natural gas, the least harmful
Total Buses (2016)
km / year
km / day
CO
VOC
NOX
PM10
24.440
1.833.000.000
5.021.918
866
50
75
4
Table 4: Current vehicle fleet emissions estimations.
is a Colombian company, dedicated to the distribution and commercialization of electrical energy, reaches 108 municipalities within Cundinamarca (state of Bogotá) and covers 100% of the capital of the country, “is technically and humanly prepared to implement it, knows what technology is needed and how much
Finally as was previously mentioned in this document, these buses have a technology called regenerative braking, which allows to use the energy generated in braking, saving the energy consumption approximately 30% (Rios, 2016).
electrical power will be demanded. The
Economic Evaluation
only thing that is required is to carry out the
For the economic evaluation comparison of
electrical planning of the distribution network
profitability between different technologies
once the specific points of location of the
including
traction substations are known“. (Rios, 2016)
consumption and the maintenance costs of
In addition, technical analysis have been
the electric buses vs. diesel are studied. The
carried out with distribution planning systems
study is based on the bus model Volvo 7900,
Buses Prices 2016
the
Diesel Bus
initial
costs,
the
Electric Bus
%
€
%
€
Vehicle cost
86.5
96,000
94.1
383,000
National taxes and fees
13.5
15.000
5.9
24.000
Total Cost
100.0
111.000
100.0
407.000
Table 5: Buses technologies prices comparison
energy
77 —
— 78
as it is the same brand and capacity that is
performance of an electric bus in Bogota
development in this field, however cities located
advantages in prices, such as diesel buses.
currently used by the bus fleet of Trasmilenio in
of 12m is 0.88kWh/km while for the case of
in Latin America and Africa are potential clients
For this reason, is indispensable that there
Bogotá (Transmilenio; Public transport system
diesel buses performing the same routes
for those markets. In the second section, this
be the investment of national authorities, in
of Bogotá) (Colombia Transport Ministry
the average performance was 7.3 km/gal.
paper explored the current situation of Bogotá
research and the implementation of legal
2016), Even though the current bus fleet varies
Thus, the electric bus price per km traveled
in order to estimate the impact. Changing
instruments that incentive the implementation
in technology and equipment, in order to
is EUR0.09 while a diesel bus is EUR0.27
diesel buses for electric buses would represent
of clean technologies. On the other hand,
simplify this study, the estimation assumes a
in Colombia. Considering that in Bogotá the
a significant impact, in environmental and
the sales of electric buses is very small
bus fleet of 24400 Volvo 7900 12m vehicles.
current bus fleet (24400 buses) is changed by
social terms, attributed mainly to the high
compared to those of conventional fuel-based
the electric bus model Volvo 7900 and keeping
level of emissions and noise that the public
buses. Despite the fact that we are in an era
transportation system represents. The electric
of globalization, it is difficult to enter a new
bus fleet would benefit not only the users of
country‘s market due to the large requirements
the transport system also the inhabitants of
requested by the national authorities to
CONCLUSIONS
the city, who are currently affected by the
introduce a foreign product to the local market.
compare these two technologies in Bogotá,
The objective of this study is to collect
emissions and noise level, especially in the
Worldwide, there are just a few electric bus
the national taxes were included in the prices.
information about the main technology, the
main avenue where the diesel buses operate.
manufacturers. Only large companies such
In the case of diesel, the national taxes
global market of electric buses, the efficiency
In economic terms, it was found that to offer
as Volvo or Siemens have been able to invest
of those buses technologies compared to
the same service, the city would need to invest
in electric buses developments, and those
diesel buses technology available in the
approximately EUR407,000 including national
market and analyze the social, economic
fees and taxes, meaning 4.2 times the prices
and environmental impact and benefits of
of the current diesel buses.
Investment Price According to the Volvo Price catalog 2016, the Volvo 7900 bus costs approximately EUR383,000. While the same capacity Volvo diesel bus costs EUR96,000. In order to
represent approximately 14% of the total value of the bus, and for electric buses the only 6%. This is due to the national benefit taxation for a clean energy conversion project. Fuel tariff and efficiency. According to the Ministry of Mines and Energy of Colombia, the price of diesel fuel in the capital is approximately EUR2.24/ gal, which is in the average when compared to other cities in Latin America (World Bank
the same distance traveled per day (5 million km per day), this change will represent a savings of more than EUR924,000.
replacing the current public transportation electric buses that are operating in the city. In the first section of this study, the only parameter from the parameter study in that section that has an advantage over the electric bus is the
Data base, 2016).
cost of the available buses in the market and
Fuel Tariff and Efficiency
their mass adoption. The main reason for the
this is the cause of one of the major barriers in
DISCUSSION
companies get the invest capital with the net income from conventional fuel based vehicles sales. Except for BYD, all other electric bus manufacturers have comparatively small production numbers. As a result the demand
Despite the great benefits in sustainable terms
and supply are currently very limited. In the
of implement electric buses in the public
case of Bogota, there have been very little
transportation system, the simplicity of the
research and consultancies that have work
system, the great technological advances
on the field to determine the requirements of
buses and the cities initiatives in new clean
electric buses implementation that have been
alternatives, it is clear that there is still a long
carried out by academic sources. As such, does not achieve a significant interest of the
According to Codensa reports, the main
high costs of electric buses is the battery cost
way to have a complete electric bus fleet
energy distributor company in Bogotá, the
and that the battery industry has not reached
instead of diesel or CNG buses. This is
local authorities. Furthermore, the city budget
price of energy in 2017 is EUR0.2/KWh, ie the
a mature period. Related to the market and
attributed to the obstacles of each market.
is focused on metro implementation, with
price per kilometer traveled is EUR1.22. In the
the main technologies, China is leading in
Currently, the technologies have not yet
the aim to increase the supply of the public
literature review, only two studies of electric
global mass deployment, with more than
reached a maturation period and require large
transport system. However, the metro project
bus performance in Bogotá have been done,
170,000 buses (98.3% of the global total).
investments that only government entities or
does not aim to reduce the environmental
one from the National University and the
This can be attributed to a successful local
great leaders can realize. Creating a new
impact, reduce the number of diesel buses
second one from the Salle University. Both
policy implementation.
European markets,
market, it takes time and even more when
or change the current bus fleet with clean
studies presented similar results, the average
especially Germany, lead the research and
the supplementary product has absolute
alternative technologies. —
79 —
— 80
— Pia Schnellberger
Pia Schnellberger studied Architecture at the Chinese University of Hong Kong and the Universitiy of Applied Science in Stuttgart, where she graduated. With a professional background in the field of sustainable development of natural and built assets, Schnellberger currently studies REAP at HafenCity University Hamburg. Her focus lays on energy production and supply and sustainable urban development, including practical studies in Kazakhstan and Egypt.
RELEVANCE
INTRODUCTION
The integration of renewables is a highly energetic
In a time of resource depletion, energy from wind power plants is highly discussed as an alternative for fossil and nuclear power and as an opportunity for a sustainable energy supply. Wind energy is one of the technical environmental innovation which plays a role in the ecological modernization of economy (Blazejczak et al 1999). Any innovation in any field – be it in chemistry, economy or technology – implies either “a new idea, method, or device” or its introduction (“innovation” in Merriam Webster Dictionary, 2012). The basic idea of generating energy from wind is several centuries old when wind mills were used to perform mechanical work on site. The following idea of using wind force to generate electricity is a development of the working principle of a windmill: As the wind blows, kinetic energy is turned into rotation energy by the sails of a wind mill. In the next and formerly final step, the energy is translated into
topic – not only technically speaking. Political and public discussions about electricity from renewable sources such as off-shore wind parks bear high dynamics as seen in articles like “paradox energy policy” (original title: “Energiepolitik paradox”; Süddeutsche Zeitung, 2014) or „Bavaria electrified” (original title: “Bayern unter Strom”; BR, 2017). Despite the various opinions on renewable energy within Germany, the energy turnaround requires a growing share of these sources within the near future. Especially the high dependence on nuclear power in the south of Germany draws attention on alternative sources of non-atomic and (almost) carbon-free energy. Whilst the federal government strives for the integration of national renewable energy sources, opposing sides suggest the inflow of gas imports. This background led to the consideration of both energy sources, renewables and gas, not as competing but as complementary elements for the development of a reliable electricity grid.
mechanical work by the working shaft inside the mill. Instead of ending the sequence at the point where mechanical work is performed on site for grinding grains or pumping water, rotation energy can be transformed into mechanical energy which finally generates electricity – and thereby opens the boundaries of stationary energy generation towards the generation of transportable electricity. More than one century after the realisation of the first plants to distribute wind energy (Vindmøllenindustrien, 2003), progress of introducing such technical innovations can be traced in Germany. Facing the energy turnaround and its interim and final goals of increasing the share of renewable energy in the German energy mix and decreasing carbon emissions (BMWi, 2016), the implementation of wind energy (and other sustainable sources such as solar energy and biomass) and its distribution as a technical innovation progressed since 2010. One of the core elements to meet the challenges of the energy turnaround is the development of the national electricity grid – the medium for the implementation of technical innovations. Research Question Two research questions underlay the following chapters of this paper: — What are the recent planning and governance influences on the German electricity grid? — Which technological options can be applied to integrate energy from the North into a reliable German electricity grid?
Scope and Delimitation The title „Energy from North to South“ refers to the national transport of energy within Germany only. Its interpretation in a European context, whereas is not further elaborated in the course of this paper. Systems and technologies for the implementation of grid development plans are reviewed from a technical point of view and form the main body of research, thus related market dynamics and influences are not targeted. Time This paper is mainly based on rather recent environmental and electricity related policies and planning from the year 2000 and ongoing. The technical development and statuses are considered from this date and following as well as future development plans for the electricity grids in Germany and the European electricity market. Methodology Within this paper, the focus lays on the evaluation of the current situation of electricity grids and electricity transmission in Germany with a particular emphasis on the transportation of renewable energy from the north to the south. The main data used within this paper is provided by the official statistical data of the German Government and governmental institutions (such as BMWi, Umweltbundesamt, Destatis). General descriptions and technical specifications from governmental sources and operating companies form the basis for the assessment of the current grid conditions and the identification of weaknesses and necessary improvements. In accordance
81 —
to these preceding results, the application of synthetic gas storages is assessed towards a stable electricity grid in compliance with feed in from wind energy farms. The accumulation of results and findings forms the final statement. Keywords Electricity grid; electricity consumption; supply reliability; power to gas; transmission technologies.
ENERGY TRANSFER FROM NORTH TO SOUTH Any kind change and innovation requires an adjustment of the involved technologies. Over the past years, the German electricity grid reached its limits and stands in close relation with the targeted energy turnaround. Amongst targets such as the integration of renewable energy, the maintaining of a high supply reliability and the realisation of a European energy market, a reworked system for electricity transfer - specifically from the north to the south of Germany - is required. These motives are explained as follows: National integration of renewable energies One of the strongest motivation for the integration of renewable energies in Germany is the energy turnaround which aims, amongst other goals, to move away from fossil fuels and nuclear power (BMWi, 2016). This shift of energy sources can be recognized in a share of 31.7 % electricity from renewable sources in the German electricity mix in 2015; in comparison, renewable sources only provided 6.9 % of the gross electric consumption in 2000 (BMWi, 2017). This growth can be traced especially since the
— 82
inception of the Renewable Energy Act (EEG) which introduced the feed-in of regenerative energy sources into the grid. Despite the high share of electricity from renewable sources on a national level, the respective energy mix shows a different constellation of fuel types on a state level. Especially federal states such as Baden-Wuerttemberg or Bavaria in the south of Germany still provide a relatively high share of nuclear energy for electricity consumption of up to 42% in 2015 which is produced within the states’ boundaries (Destatis, 2016). This circumstance can be explained by the topographic and climatic conditions which differ throughout the country: As one example, the so called “Windhöffigkeit” (a measure of wind frequency and speed) assesses the suitability of an area for wind energy generation. The south of Germany shows a relatively low wind speed in different heights which is rated as rather unfavourable for wind power generation (Koch, 2014). In further context with the energy turnaround, the nuclear power plants, which some of the southern Federal States are dependent on, will be shut down by the year 2022 and make it necessary to find alternative sources of supply of energy (Bundesnetzagentur). Lower energy related emissions for electricity generation In relation to the overall energy mix in Germany stands the share of development of CO2-emissions of the German energy mix. The overall energy-related emissions of the German electricity mix decreased by more than 14% since 1990 (Umweltbundesamt, 2017) whilst the share of renewable energy has
decreased in that time period. The generation
stage procedure as a basis for grid
of electricity with a low carbon footprint can
development plans by several researchers.
lead to a further reduction of emissions, hence
On the basis of the Energy Industry act
be beneficiary for the energy turnaround.
(EnWG), the federal government intends the elaboration of grid development plans
Supply Reliability and European Energy Market
(NEP) by the transmission system operators (“Übertragungsnetzbetreiber).
The reliable supply of energy stands in close
These
NEP
resolve in strategies for a needs-oriented
connection to the previous mentioned points.
expansion of the national electricity grid on the
According to data from BMWi, the reliability of
basis of scenario analyses and projections.
supply in Germany is exceptionally high in an international comparison. In the year 2014, the
Projections of Electricity Demand
overall average of electricity disruption was 14
Different factors affect the electricity demand in
minutes, whereas countries as France, Great
Germany: Demographic changes, the overall
Britain or Canada show three to twenty-five
economy, and the industrial sectors are
times this amount (BMWi). To maintain the
fundamental parameters for the projection of
current standard of supply reliability during
the future electricity demand. Furthermore, the
and after the nuclear energy fade-out, the
development and use of recent technology
integration of all types of energy generation into
such as electric mobility, heat pumps or smart
the grid, especially renewables, is targeted by
appliances and the overall energy efficiency
the government (BMWi, 2016). Furthermore,
matter (Übertragungsnetzbetreiber, 2017).
the common European Energy Market plays
The
a role in the steady provision of electricity with
transmission
system
operators
(“Übertragungsnetzbetreiber”) for electricity
the help of grid developments.
are obligated towards the federal government
PARAMETERS FOR ELECTRICITY GRIDS to assess the overall electricity demand as a IN GERMANY basis for the elaboration of grid development Several parameters are revised in a multiNet electricity demand [TWh]
plans (Netzausbau, 2017). The following
2013
A 2030
B 2030
B 2035
C 2030
Net electricity demand incl. grid losses
543
523
510
513
543
Net electricity demand excl. grid losses
523
503
490
493
523
Thereof electric vehicles
0.4
6
16
25
23
Thereof heat pumps
3
19
20
24
22
Thereof further electric appliances
-
-
-
-
21
Reduction of net electricity demand by
-
-42
-66
-76
-63
further influences (e.g. increase in efficiency)
Figure 1 – Net Electricity Demand in Germany. Table based on data from Fraunhofer ISE, 2015.
83 —
table (c.f. Fig. 1) shows the prognosis of total net electricity consumption for immediate future under different scenarios. A scenario is considered an interplay of the mutual influences of the pace of transformation (regarding the energy turnaround) and the degree of innovation (Fraunhofer ISE, 2015): -- Scenario A. The energy turnaround proceeds with moderate pace and only a limited use of new technologies with a rather low degree of innovation. Furthermore, the build-up of wind energy plants and photovoltaic systems is considered moderate within this scenario. -- Scenario B. This scenario reflects the use of various measures and technologies within the development of new plants and a higher use of electric mobility. Scenario B includes a higher convergence between electricity generation and heat generation with technologies such as heat pumps. Simultaneously, a rise in efficiency for existing electric applications and flexibility in load management are expected. -- Scenario C. The accelerated energy turnaround is represented with an intensive use of new technologies and a coupling of the sectors transport, heat and electricity. Scenario C is also characterised by a high energy productivity of PV systems as well as the use of storage options for energy. The use of electric powered vehicles instead of conventional combustion engines is targeted by the Federal Government which indicates a future shift in the consumption sectors regarding
— 84
electricity, projected to increase the electricity demand (Übertragungsnetzbetreiber, 2017). According to data from BMWi (2017), the transport sector represents the biggest consumer of final energy in Germany with 2.619 PJ in 2015. Currently, 94 % of the necessary energy for the transport sector is mineral oil products, which could undergo a change towards the use of more electricity. This assumption considers the governmental plans of introducing one million electric vehicles by the year 2020 (NPE, 2014) and the public discussions about the ban of diesel powered vehicles in 2017. The counterpart to that development can be found in an increasing energy efficiency which is reflected in figure 1. Despite an increasing use of electric appliances such as electric vehicles or heat pumps, an improvement of electric efficiency can reduce the net electricity consumption overall. Another factor that is responsible for a lower electricity consumption is the use of technical devices such as PV panels and batteries at a household level. This share of decentralized energy production and storage can be (in principal) subtracted from the net electricity demand (Fraunhofer ISE, 2015). At this point, especially the projected electricity demand on a state level is emphasised. For further planning actions, regional changes in energy consumption and energy have an influence on the spatial layout of extensions to the electricity grid (Schlemmer, T., Schmidt, U., & Diebels, W., 2017): federal states such as Baden-Württemberg or Bavaria will have difficulties in covering up to 42% of the former share of nuclear energy for electricity
consumption (as of 2015) with their own
Germany (for a technical description c.f.
resources as a consequence of the nuclear
chapter IV) which improves the supply
fadeout. This regional condition mirrors in the
reliability, but possibly mitigates the idea of a
planned expansion of the grid in north south
European energy market. Another possibility
axis (c.f. Fig. 2).
is the use of interconnectors at the interfaces
Primary Energy Emissions
Sources
and
Carbon
On the side of the ÜNB, market relevant factors are considered to assess the feasibility
between neighbouring grids. Instead of a national storage, any energy surplus could be discharged into the European energy grid and vice versa.
of technologies to be applied. The two factors
Public and Political Challenges
primary energy sources and CO2 prices
Besides concerns of technical nature, regional
(related to carbon emissions) are considered
and political challenges add to the complexity
as influencing factors on the final energy prices
of grid expansion in Germany. The national
(Übertragungsnetzbetreiber,
Market
goal for electric mobility or the entry into force
analysis tools aim to model final consumption
of the new Renewable Energies Act are two
prices, including levies and taxes. Besides
examples for legislative influences on the
financial importance, this approach has
parameters for the development of new grids.
an influence on the timing and amount of
Speaking in a federal context, the policies on
renewable energy fed into the grid (thus
a state level need to be mentioned at this point
influences the choice of applied technologies).
as regional, political strategies which have an
The above-mentioned scenarios consider
influence on the development of renewable
2017).
different impacts of the parameter of primary energy sources and carbon emissions
energy generation, thus affect the regional electricity mix. The required protective distances
(Deutscher Bundestag, 2007).
between wind turbines and residential areas
Technical Challenges
example for a regional regulation which has
or protected areas can be considered as one
With an increasing share of electricity from
a direct influence on the ground potential for
renewable sources like wind and sun,
the economical harvesting of wind energy,
challenges such as fluctuations in generation
according to calculations by the Federal
have
respective
Environmental Agency (Umweltbundesamt,
electricity grid. The corresponding factor is
2013). Political obstacles of this kind can
the intermittency of renewable energy sources
lead to delays in the development progress
which stands in close relation with supply
for building new transmission lines or cause
reliability.
an interruption of the whole undertaking
Two systems are applied to ensure the
itself. Further actions on a state level, such
reliability of supply. One option is the storage
as autonomous actions that do not comply
of electricity surplus for later demand in
with the sense of federal decisions, can have
be
absorbed
by
the
85 —
a similar effect. In particular, the example of Russian-Bavarian trade relations is mentioned at this point. In the course of assuring a stable energy supply within its territory, the Bavarian Ministry of Economics agreed in 2012 on a common roadmap with the Russian gas supplier “Gazprom” for future natural gas trade (Bayerischer Landtag, 2014). On first sight, these actions might support the idea of a European Energy Market, but could counteract the federal attempts of improving the German electricity grid: In the early
— 86
stages of the development of a national grid development plan after the nuclear disaster of Fukushima in 2011, such actions might undermine endeavours on a national level in the first place. Besides politic strategies, the public acceptance by the society should be mentioned as a factor that can change the initiated use of technology. Its potential influence on the implementation of grid extension plans is further mentioned in chapter IV regarding the appliance and decision of technical systems. The intended connections of
transmission
(overhead
lines
lines
or
underground cables) are shown in this map based on
BBPlG
These
and
EnLAG
connections
illustrated
are
schematically
which show the direct link between two intended grid nodes, the routing is defined in respective detailed plans (Netzausbau).
In addition to the ÜNB, agencies such as the Federal Network Agency (BNetzA), the Federal Ministry of Economic Affairs and Energy (BMWi) and the platform for sustainable energy grids are substantially involved in the revision and implementation of grid development strategies (“Netzentwicklungsplan”). The elaborated parameters in the previous chapter, amongst others, have a substantial impact on the composition of the electric transmission system. These were analysed by the ÜNB and are revised in the form of implementation drafts by the above-mentioned federal agencies to form (c.f. Figure 2). In the final step, expansion requirement plans are developed in consensus with all involved parties. The basic transmission and storage technologies which are considered in scenario planning as well as in the final action plans are reviewed in the following chapter.
TECHNOLOGIES DEVELOPMENT
FOR
GRID
Technical Electricity Transmission The above-mentioned acts for a specified grid development plan (BBPlG) and the accelerated expansion of electricity transmission technologies (EnLAG) intend the usage of different transmission technologies for its implementation. In general, electricity can be transferred via overhead lines or underground cables in the form of direct or alternating current. Both types of current have specific features when implemented into the transmission system of electricity which translate on the specifications of used cables, such as quality and dimension.
Figure 2 - Transmission Systems in Germany.
Besides different types of current, the voltages of the distributing grid play an important role for the decision on the deployed technology. The German electricity grid contains four levels of voltage between the electricity generators in the beginning and the households at the end of the supply chain. Extra high voltage in a rage from 220 to 380 kV is used to cover longer distances. At this stage, especially nuclear power plants or coal fire power plants currently feed their generated electricity into the grid. Renewable sources whereas tend to connect with high voltage of 110 kV or medium voltage of one to 50 V to the grid. Finally, households can receive electricity after the last transformation to 400 V or the usual 230 V (DIHK, 2015). Not only is the used voltage of consumers responsible for the different voltage levels of transmission but also the transportability of electricity. Over longer distances, energy losses can be minimized with higher voltage levels: Pv = R · I²; from P = V · I and V = I · R with Pv: transmission losses Pv
=
R · I²
=
R·P
V·I P V² This formula shows the relation of voltage, intensity and resistance in context with transmission losses. By logic, the denominator (voltage) needs to be as high as possible to minimise transmission losses. Applied on the German electricity grid, this principle leads to the current distribution pattern of higher voltages for higher distances between producer and consumer of electricity (Bundesnetzagentur, 2016 b).
Figure 3: Transmission Technology Analysis.
+ minimal landscape distruption after installation + shielding of electric fields by earth masses + lower transmission losses - no direct access for maintenance and damage assessment - higher costs for transformation from DC to AC (if used)
X 400 V – 230 V
+ low costs and fast construction + easy access for maintenance; direct visibility of damages + flexibility and option of retrofitting - adverse effect on environment by infrastructure intrusions (habitat loss, optical interference) - electric field (no shielding of electric fields) - vulnerable to atmospheric influences Assessment
X 1 – 50 kV
X X
Voltage
110 kV
X X 220 - 380 kV
No change of phases result in an absence of reactive power loads. Preferably used for the transmission of electricity over long distances for lower transmission losses (see previous page). Currently, most of the DC lines are in use as see cables. In comparison to AC masts, DC masts consists of two systems for both negative and positive charge. The electric circuits in the transmission line conductors of AC masts show three phases, whereas DC masts only have one (thus have no reactive power). Type of current DC
Underground cables with alternating current are suitable for low and medium voltages. Higher voltages increase the reactive power (Q) loads and require more compensation measures by phase shifting (φ) of the current. Q = V · I · sinφ Conventional overground lines use alternating current for all voltages. This system does not require a current transformation, thus transmitted electricity can be used directly. The structure of existing masts can be further developed to carry both AC and DC lines (hybrid lines). AC
Masts of up to 80 meters carry the cables for the transmission of electricity. Overground lines are the most common used transmission technology. The resulting heat which is caused by the current flow are cooled by the surrounding air.
Fluctuating electricity loads is one of the challenges that need to be considered for the development of transmission grids (c.f. chapter III). One approach to compensate the variability of solar radiation or wind intensity is to store the surplus as soon as it is available. This can be realized with centralized or decentralized storage units. All development scenarios (c.f. chapter III) assume the further operation of existing centralized storages which are represented by pumped-storage power plants in most cases. A joint study by the grid operators rates these storages as a factor towards more system stability, however new storage technologies are scarcely considered within thei initial assessment by the ÜNB (Übertragungsnetzbetreiber, 2017). On a household-level, decentralized storages such as batteries for small PV systems are increasingly used. This trend has an influence on the load profiles for the electricity grids and was considered for the projection of net
Specfication
Centralized and Decentralised Storage
Overground Lines
Underground Cables
new overground masts or earth cables (Bundesnetzagentur, 2016 b). With respect to the transmission of energy from the north towards the south, the use of buried highvoltage direct current cables seems to carry a high potential. Recent political and public discussions about landscape disruption and loss of natural habitat, especially in the south of Germany, draw attention on the mentioned system combination: Not only is the absence of reactive power loads a striking argument for direct current, a lower visibility can furthermore be convincing for the successful development of connecting lines through Germany.
Transmission Technology
The extra high voltage grid in combination with direct current can be used as a very effective way to transmit electricity over long distances with relatively lower transmission losses. In the range of medium to low voltage, alternating current has the advantage that it can be directly consumed without transformation processes from direct current to alternating current (DIHK, 2015). Especially for the scenario of transporting electricity from the north to the south, direct current lines are foreseen in the grid development plan to overcome these greater distances with as low losses as possible. As a result of public and political discussions (c.f. chapter III), buried DC cables are expected to be promising solutions for electricity transmission that is accepted by the general public. With a voltage of 320 kV, the commonly used cables in Germany show a transmission capacity of 2000 MW. In comparison, the alternating current overhead lines on a basis of 400 kV has a higher transmission capacity. For that reason, a development in the used technology could help overcome this obstacle by introducing another voltage level of 525 kV. An overview over applied transmission technologies in combination with alternating and direct current are illustrated in the following table. The combinations of transmission technologies and type of current can be considered as rather synergetic technologies than competing approaches. The presence of overground masts with alternating current is a factor that induces further thoughts on an additional equipping of existing lines than constructing
— 88
Underground cables are usually buried under 1.5 meters and require specific preparation of trenches. The resulting heat of current transmission is emitted to the surrounding soil, thus natural cooling is not possible.
87 —
89 —
— 90
electricity demand by the network operators
a household-level. The combination
The
in chapter III. Especially developments such
of photovoltaic and battery storage in
have different roles in the development of a
as smart mobility and smart houses promote
particular is rated as a promising solution
stable electricity grid. While batteries, as one
this technology. Additional to the classification
with an impact on the energy market
example, are mostly used for electric mobility
of centralized and decentralized systems, a
(REN21, 2017).
or on a household-level, medium to long-
necessary factor for the integration into the electricity grid is the possible storage time of the different systems. Figure 3 illustrates the storage capacity of applied storage technologies which is further explained as follows using the most commonly used systems in Germany as an example. -- Short-term storage: Batteries represent the most commonly used short-term storage which last up to several weeks. Mobile and stationary applications are possible such as batteries in electric vehicles or storages for produced solar energy on
-- Medium
to
long-time
storage.
Pumped storages are primarily used to store energy up to several months and are widely used as a medium to longtime storage option. Thereby, energy is stored by pumping water to a higher
above-mentioned
storage
options
time storage options are responsible for the compensation of fluctuations on the electricity market. Besides the relation of given values of discharge time and energy, this illustration of storage capacity of different energy storage systems indirectly implies information about
elevation point (thus making use of
the respective system performances.
potential energy) where it can generate energy again by driving turbines in times
FURTHER ASSESSMENT OF POWER TO GAS TECHNOLOGIES
of demand. Considering losses during
Concerning the overarching title “Energy
that process, this technology recaptures
from North to South”, the compatibility of wind
up to 85% of the initial amount of energy
energy and gas storage is further assessed
(REN21, 2017).
in this chapter as an option for an integrative national electricity supply. It is expected that wind energy provides the highest share of the national energy mix in the future (Übertragungsnetzbetreiber, 2017).
Figure 3 - Storage Capacity of Different Energy Storage Systems.
Figure 4 – Maturity of Energy Storage Systems.
With reference to the goals for the energy turnaround, the federal government projects a share of forty percent electricity from renewable sources (BMWi, 2016), thus a higher share of electricity is affected by intermittency. According to a study by REN21 (2017), this share of renewables in the electricity mix consequentially requires the use of storage technologies to guarantee supply reliability. Researchers from the Fraunhofer Institute for Wind Energy and Energy Systems Technology (IWES), amongst others, have introduced an innovative system for medium to long-time storage. The “power to gas” technology transforms energy surplus from renewable energy – in this case wind energy – to hydrogen by the electrolysis of water. In the next step, the extracted hydrogen reacts with carbon and thus creates methane. This product can finally be stored and distributed any time through the existing gas network (Fraunhofer IWES, 2014). By the combination with regional heat networks, methane cannot
91 —
— 92
only be used for energy supply, but also to
generated surplus electricity and of using it
a different legal landscape could potentially
of carbon which can derive from industry or
provide heat. Another potential of this system
on demand, electricity can be bought on the
lead to more developments.
transport and lead towards a circular energy
lays in the provision of pure carbon for the
common European energy market when the
Environmental innovations generally aim
economy. For the transmission of energy from
creation of methane which is a critical point to
prices are low.
to reduce the strain on the environment as
the north to the south, power to gas storages
well as to avoid additional environmental
can represent an essential stability factor for
tackle at the same time (REN21). With the use of exhaust carbon from industry or transport for the methanation, the power to gas system could be a promising technology for the development of a circular electricity economy. Currently, pilot projects of 1 – 2 MW are installed in Germany, however lacking political or governmental support might be the reason for an insufficient commercialisation (c.f. fig. 4) of this option (REN21, 2017). With regards to political influences, this technology could also be one technical argument in discussions such as to import gas instead of agreeing on the constructions for the implementation of grid development plans in the south of Germany (Süddeutsche Zeitung, 2014). As a final conclusion, a grid system with the option of power to gas bears a high potential
CONCLUSION The shift from fossil to renewable energy sources for the German electricity mix is carried on transmission lines, metaphorically speaking. The proceeding energy turnaround involves high demands on the future use of energy and its distribution: existing conventional supply patterns change with the withdrawal from nuclear energy by 2022 and the aim for a dominating share of renewable energy in the long term. Electricity grids play a significant role in this development, regarding the integration of renewable energy on a national and international level. From a technical point of view, this progress requires evaluation
the of
application parameters.
of
preliminary Consumption
patterns play an important role on the
to meet the challenges of a reliable supply
projection
system under the aspects of the energy
and allow conclusions on the forthcoming
turnaround. The transportation of energy
implementation of electric mobility or energy
sources with a low carbon foot print such as
storage options. The overall approach of
electricity from wind or sun with the option of
electricity supply grid operators shows that
compensating load fluctuations is a basis
market and pricing is a limiting influence on the
for a reliable grid. In addition to electricity
presumed development speed and feasibility.
transmission, the system of power to gas
The modelled pricing has an impact on the
can also undertake the function as a carbon
amount and speed of renewable energy fed
sink, when provided that exhaust emissions
into the electricity grid, thus is assumed to slow
from industry, transport or biogenic sources
down possible progressive developments.
are used. The integration of such a storage
The assessment of changes in parameters or
option furthermore provides the opportunity for
stronger incentives by the government could
the development of an integrated electricity
consequently be beneficial. Regarding the
market. Besides the option of storing national
development of environmental innovations,
of
future
electricity
demand
damage in a society and growing economy. By definition, an innovation does not solely refer to a new technical system, it also refers to the progress of implementation of innovative ideas (c.f. chapter I). Power to gas is considered as one of them and was further assessed in this context. It shows, that this storage system lacks political interest which can be assumed to be a reason for its lower
the grid and for the realisation of development plans. Finally, it is given the impression that the federal generation of electricity involves greater effort than the option of importing energy such as gas from countries like Russia. In its nature, a factor of uncertainty is attached to politics and diplomacy. Thus, the advantage of the
degree of maturity. Within the elaborated
implementation of a future-proof electricity grid
scenarios by the electricity grid operators,
from north to south combined with the use
synthetic methane as a storage option is only
of national renewable energy sources is the
considered for the year 2040 or not at all. In
provision for energetic independency and the
its core, the technology allows the storage
higher foreseeability of circumstances. —
93 —
— 94
Cover + background image Cover picture and background image based on: Cb22h, 2013. [image]. Karte der Gewässer in Hamburg. [Accessed 16 January 2018]. Hydrogen and Synthetic Methane in
the
Future
Energy
System,
Anastasiya Andrukovich. Figure 1: Hydrogen production sources. Source: Anrukovich, 2017. Figure 2: PtG, methanation. Source: Andrukovich, 2017. Figure 3: Energy losses caused by chemical conversion. Own Illustration. Data: Gotz et al., 2015. Figure 4: Research and pilot PtG projects in Germany. Own Illustration. Data: German Energy Agency, 2015. Figure 5: The synergetic model of the energy system. Source: Andrukovich, 2017. Table 1: The cost comparison of hydrogen based on various production processes. Data: Hosseini and Wahid, 2015). Literature Bennaceur, K., Clark, B., Orr, F., Ramakrishman, T., S., Roulet, C., Stout, E., 2001. Hydrogen: a future energy carrier? Oilfield Review, Volume 17, Issue 1, pp 30-41. Available at: <http://www.slb.com/resources/ publications/industry_articles/oilfield_review/2005/or2005spr03_hydrogen.aspx> [Accessed 16 June
2017]. Breyer, C., Tsupati, E., Tikka, V., Vainikka, P., 2015. Power-to-Gas as an Emerging Profitable Business Through Creating an Integrated Value Chain. Energy Procedia, Volume 73, pp 182-189. Available at: <http:// www.sciencedirect.com/science/ article/pii/S1876610215014368#!> [Accessed 16 June 2017]. Edwards, P.P., Kuznetsov, V.L., David, W.I.F., 2007. Hydrogen energy. Philosophical Transactions of the Royal Society, Volume 365, pp 1043–1056. The Royal Society publishing. Available at: <http://rsta. royalsocietypublishing.org/content/ roypta/365/1853/1043.full.pdf> [Accessed 20 June 2017]. Gotz, M., Lefebvre, J., Mors, F., Koch, A., Graf, F., Bajohr, S., Reimert, R., Kolb, T., 2015. Renewable Power-to-Gas: A technological and economic review. Renewable Energy, Volume, pp 1371-1390. Available at: <http://www.dvgw-ebi. de/download/Review_Artikel_PtG_ Renewable_Energy_2015.pdf> [Accessed 16 June 2017]. Hosseini, S.E., Wahid, M.A., 2015. Hydrogen Production from Renewable and Sustainable Energy Resources: Promising Green Energy Carrier for Clean Development. Renewable and Sustainable Energy Reviews, Issue 57. Available at: <https://www.researchgate.net/ publication/287209182_Hydrogen_Production_from_Renewable_ and_Sustainable_Energy_Resour-
ces_Promising_Green_Energy_ Carrier_for_Clean_Development> [Accessed 20 June 2017]. Müller, K., Stadter, M., Rachow, F., Hoffmannbeck, D., Schmeißer, D., 2013. Sabatier-based CO2-methanation by catalytic conversion, Environ. Earth Sci., pp 1-8, Available at: <https://link.springer.com/article/10.1007/s12665-013-2609-3> [Accessed 15 August 2017]. Schüth, F., 2009. Challenges in hydrogen storage. The European Physical Journal, Issue 176, pp. 155-166. Available at: <https://link.springer.com/content/pdf/10.1140%2Fepjst%2Fe2009-01155-x.pdf> [Accessed 20 June 2017]. Tichler, R., Lehner, M., Steinmüller, H., Koppe, M., 2014. Power-to-Gas: Technology and Business Models. Springer Briefs in Energy. Renewable Energy, Volume 85, pp 13711390. Available at: <http://www. sciencedirect.com/science/article/ pii/S0960148115301610> [Accessed 20 June 2017]. Tromp, T. K., Shia, R.-L., Allen, M., Eiler, J. M. & Yung, Y. L. 2003 Potential environmental impact of a hydrogen economy on the stratosphere. Science, Issue 30, 1740–1742. J.A. Turner, 2004. Sustainable hydrogen production. Science, Issue 305, pp 972-974. Available at: <https://www.researchgate.net/publication/8400212_Sustainable_Hydrogen_Production> [Accessed 20
August 2017]. Züttel, A, 2003. Materials for hydrogen storage. Physics Department, University of Fribourg, Pérolles, Switzerland. Materialstoday, Volume 6, Issue 9,pp 24-33. Available at:<https://ac.els-cdn. com/S1369702103009222/1-s2.0S1369702103009222-main. pdf?_tid=44b97ea8-c4d7-11e78eeb-00000aab0f26&acdn a t = 1 5 1 0 1 8 1 6 3 1 _ e b a b 8 6 c d799a1b9f382c86236c2e16bf> [Accessed 15 August 2017]. ENEA Consulting, 2016. The potential of power-to-gas. Available at: <http://www.enea-consulting. com/wp-content/uploads/2016/01/ ENEA-Consulting-The-potential-ofpower-to-gas.pdf> [Accessed 20 June 2017]. German Energy Agency, 2015. Power to Gas system solution: Opportunities, challenges and parameters on the way to marketability. Power to Gas Strategy Platform, German Energy Agency. Available at: <http://www.powertogas. info/fileadmin/content/Downloads/ Brosch%C3%BCren/dena_PowertoGas_2015_engl.pdf > [Accessed 20 June 2017]. Lipman, T., 2011. An Overview of Hydrogen Production and Storage Systems with Renewable Hydrogen Case Studies, Montpellier: Office of Energy Efficiency and Renewable Energy Fuel Cell Technologies Program. Report. Available at: <https:// cesa.org/assets/2011-Files/Hydrogen-and-Fuel-Cells/CESA-Lipman-H2-prod-storage-050311.pdf> [Accessed 20 June 2017]. Purr, K., Osiek,D., Lange, M., Adlunger, K., 2016. Integration of Power to Gas/Power to Liquids into the ongoing transformation process. German
Environment Agency Section, Dessau-Rosslau, Germany. Available at: <https://www.umweltbundesamt. de/sites/default/files/medien/377/ publikationen/uba_position_powertoliquid_engl.pdf> [Accessed 20 August 2017]. Rivkin C., Burgess R., and Buttner W., 2015. Hydrogen Technologies Safety Guide. National Renewable Energy Laboratory. Technical Report January 2015. Available at < https://www.nrel.gov/ docs/fy15osti/60948.pdf > [Accessed 29 August 2017]. Staffell, I. and Dodds P.E. (Eds.), 2017. The role of hydrogen and fuel cells in future energy systems. H2FC SUPERGEN, London, UK. Available at: <http://www.h2fcsupergen.com/ w p-con ten t/u ploads /2 0 1 5 /0 8 / J5212_H2FC_Supergen_Energy_ Systems_WEB.pdf> [Accessed 20 June 2017]. Sterner M., Jentsch M., Holzhammer U., 2011. Energiewirtschaftliche und ökologische Bewertung eines Windgas-Angebotes. Fraunhofer IWES, Kassel, p 18. Available at: <https://www.greenpeace-energy.de/fileadmin/docs/sonstiges/ Greenpeace_Energy_Gutachten_ Windgas_Fraunhofer_Sterner.pdf> [Accessed 29 August 2017]. Sørensen, B. 2006. Underground hydrogen storage in geological formations, and comparison with other storage solutions. Roskilde University Department of Environmental, Social and Spatial Change Energy, Environment and Climate Group, Roskilde, Denmark. Available at: <http://energy.ruc.dk/HstoreMerida07.pdf [Accessed 20 August 2017]. BBC, 2014. Energy transfers – fuel
cells. Available at: <http://www.bbc. co.uk/schools/gcsebitesize/science/triple_ocr_gateway/chemistry_out_there/energy_transfers/revision/1/> [Accessed 20 June 2017]. Hydrogenious technologies, 2016. Successful completion of the network «modular hydrogen plant and energy storage». Available at: <http:// www.hydrogenious.net/en/2016/04/ successful-completion-network-modular-hydrogen-plant-energy-storage/> [Accessed 20 June 2017]. Office of Energy Efficiency & Renewable Energy, 2017. Hydrogen: A Clean, Flexible Energy Carrier. Available at: <https://energy.gov/ eere/articles/hydrogen-clean-flexible-energy-carrier> [Accessed 20 June 2017]. Koeneman, R., 2016. The Challenges of Hydrogen: Light Element, Heavy Burden. Joiscientific. Available at <https://www.joiscientific.com/ hydrogen-light-element-heavy-burden/> [Accessed 15 August 2017]. Sustainability of CHP Fuel Cells, Noriko Kakue. Figure 1(a): Electrolysis of water where electric current separates water into hydrogen and oxygen. (b) Reverse electrolysis where hydrogen and oxygen recombined and an electric current is produced. Own Illustration. Data: Laeminie and Dicks, 2003. Figure 2: Basic structure of fuel cell and its chemical reactions. Source: Laeminie and Dicks, 2003. Figure 3: Characteristics of different CHP fuel cells. Own Illustration. Data: Ellamla, et.al., 2015; Laeminie and Dicks, 2003; U.S. Department of Energy, 2011; Wilberforce etc., 2016. Figure 4: Typical performance pa-
95 — rameters of CHP fuel cells available in the U.S. in 2014. Own Illustration. Data: U.S. Environmental Protection Agency, 2015. Figure 6: CHP capital, engineering cost and efficiency depending on the technology. Own Illustration. Data: Mundada, et. al., 2016. Figure 7: Comparison of Part Load Efficiency between PAFC fuel cell and natural gas combustion plant Source: U.S. Environmental Protection Agency, 2015. Figure 8: Annual and total installations of Ene-Farm. Own Illustration. Data: Advanced Cogeneration and Energy Utilization Center, 2017; The Japan Gas Association, 2017. Figure 9: Life cycle of CHP fuel cells. Own Illustration. Data: Staffell, 2012. Figure 10: Example of an inventory of producing a SOFC CHP fuel cell system. Dashed lines indicate that additional inputs can be considered for every stage. Own Illustration. Data: Staffell, 2012. Figure 11: Estimated fuel cell emission characteristics without additional control (created by author based on Data: U.S. Environmental Protection Agency, 2015. Figure 12: Comparison of life cycle CO2 emission in electricity generation technologies: Own Illustration. Data: Schömer, et.al., 2014; Ellamla, et.al., 2015. Figure 13: Assumed lifetimes of typical fuel cell stacking technology and other CHP system components. Bolded text indicates that the material is considered as a precious metal. Own Illustration. Data: Staffell and Ingram, 2010. Literature Advanced Cogeneration and Energy Utilization Center. (2017). [online]. Available from: http://www.ace.or.jp/
— 96 fc/works_0010.html [Accessed 31 August 2017]. Boehnke, J. (2007). Business Models formicro-CHP in Residential Buildings. PhD Thesis. University of St. Gallen. Ellamla, R. H., Staffell, I., Bujlo, P., Pollet, G. B. and Pasupathi, S. (2015). Current status of fuel cell based combined heat and power systems for residential sector. Journal of Power Sources. Vol. 293, pg. 315-328. Fernandez Pales, A. (2013). The IEA CHP and DHC Collaborative - CHP/ DHC Country Scorecard: Japan. OECD/IEA: Paris. Hosono, T. Nikkei BP net. [online]. Available from: http://www.nikkeibp. co.jp/article/sj/20130311/343363/ [Accessed 2 September 2017]. IEA (International Energy Agency). (2016). Energy Policies of IEA Countries – Japan 2016 Review. OECD/ IEA: Paris. Ikegami, T. (2016). 用語解説 第 62 回テーマ: . IEEJ Transactions on Power and Energy. Vol. 136, no.5, pg. 5-6. The Institute of Electrical Engineers: Tokyo ITmedia. (2017). “つながる“新型 エネファーム、機能アップで価格 は初の150万円未満に. [online]. Available from: http://www.itmedia. co.jp/smartjapan/articles/1702/15/ news048.html [Accessed 14 June 2017]. Kurzweil, P. (2016). Brennstoffzellentechnik. Springer: Wiesbaden. Available from: Spinger Vieweg. [Accessed 14 June 2017]. Laeminie, J. and Dicks, A. (2003). Fuel Cell Systems Explained – Second Edition. John Wiley & Sons Ltd.: West Sussex. METI (Ministry of Economy, Trade and Industry). (2012). [pdf]. Availa-
ble from: http://www.enecho.meti. go.jp/category/electricity_and_gas/ other/cogeneration/pdf/1-1.pdf [Accessed 30 August 2017]. METI (Ministry of Economy, Trade and Industry). (2015). 長期エネル ギー需給見通し. [pdf]. Available from: http://202.232.86.11/jp/singi/ ondanka/kaisai/dai30/sankou1.pdf [Accessed 30 August 2017]. METI (Ministry of Economy, Trade and Industry). (2017). 5-(3)自家 用発電[xlsx] Available from: http:// www.enecho.meti.go.jp/statistics/ electric_power/ep002/xls/2016/53-H28.xlsx [Accessed 30 August 2017]. Mundada, S.A., Shah, L.K. and Pearce, M.J. (2016). Levelized Cost of Electricity for Solar Photovoltaic, Battery and Cogen Hybrid Systems. Renewable and Sustainable Energy Reviews. Vol. 57, pg. 692-703. OECD. (2011). OECD Studies on Environmental Innovation Better Policies to Support Eco-innovation. OECD Publishing. Ogawa, M.´and Yabuki, M. (2014). Approachs towards Expansion of Residential Fuel Cell Systems. Toshiba Review. Vol. 69, No. 5. pp. 53-57. [Accessed 14 June 2017]. Rooijen, J. (2006). A Life Cycle Assessment of the PureCell Stationary Fuel Cell System: Providing a Guide for Environmental Improvement. [pdf] Available from: http://css.umich.edu/sites/default/files/css_doc/ CSS06-08.pdf [Accessed 31 August 2017]. Schlömer S., T. Bruckner, L. Fulton, E. Hertwich, A. McKinnon, D. Perczyk, J. Roy, R. Schaeffer, R. Sims, P. Smith, and R. Wiser. (2014). Annex III: Technology-specific cost and performance parameters. In: Climate Change 2014: Mitigation of Clima-
te Change. Contribution of Working Group III to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Edenhofer, O., R. Pichs-Madruga, Y. Sokona, E. Farahani, S. Kadner, K. Seyboth, A. Adler, I. Baum, S. Brunner, P. Eickemeier, B. Kriemann, J. Savolainen, S. Schlömer, C. von Stechow, T. Zwickel and J.C. Minx (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA. Shimizu, Y. and Nakano, M. (2017). Change of Japan’s energy security level after 5 years from the Great East Japan Earthquake. People and Environment. Vol.43, No. 1, pg. 2-13. Srinivasan, S. (2006). Fuel cells: from fundamentals to applications. Springer: New York. Staffell, I. (2012). Energy and carbon payback times for solid oxide fuel cell based domestic CHP. International Journal of Hydrogen Energy. Vol. 37, Issue 3, pg. 2509-2523. Staffell, I. and Green, R. (2013). The cost of domestic fuel cell micro-CHP systems. [pdf]. Available from: https://www.researchgate.net/profile/Iain_Staffell/ publication/257174781_The_cost_ of_domestic_fuel_cell_micro-CHP_ systems/links/0046352a39b9cb5854000000.pdf [Accessed 8 June 2017]. Staffell, I. and Ingram, A. (2010). Life cycle assessment of an alkaline fuel cell CHP system. International Journal of Hydrogen Energy. Vol.35, Issue 6, pg. 2491-2505. The Japan Gas Association. (2017). 家庭用燃料電池「エネファーム」 累積 20 万台突破について. [pdf] Available from: http://www.gas.or.jp/ newsrelease/2017ef20.pdf [Acces-
sed 31 August 2017]. Tokyo Gas. (2014). エネファーム の現状と普及拡大に向けた課題. [pdf]. Availabel from: https://www. jimin.jp/policy/policy_topics/pdf/ pdf154_1.pdf [Accessed 8 June 2017]. U.S. Department of Energy. (2011). Comparison of Fuel Cell Technologies. Fuel Cell Technologies Program. [pdf]. Available from: https:// energy.gov/sites/prod/files/2014/03/ f9/fc_comparison_chart_0.pdf [Accessed 8 June 2017]. U.S. Environmental Protection Agency. (2015). Catalog of CHP Technologies: section 6. Technology Characterization – Fuel Cells. [pdf]. Available from: https://www.epa. gov/sites/production/files/2015-07/ documents/catalog_of_chp_technologies_section_6._technology_characterization_-_fuel_cells.pdf [Accessed 8 June 2017]. Wilberforce, T., Alaswad, A., Palumbo, A., Dassisti, M. and Olabi, A.G. (2016). Advances in stationary and portable fuel cell applications. International Journal of Hydrogen Energy. World Economic Forum. (2015). Scaling Technologies to Decarbonize Energy. [pdf] Available from: http://www3.weforum.org/docs/ WEF_GAC_Decarbonizing_Energy_White_Paper.pdf [Accessed 2 September 2017]. Zhao, M., Zhao, H., Wu, M., Zhang, H., Hu, Z. and Zhao, Z.(2015). Thermodynamic Analysis of a Hybrid System Integrating an Alkaline Fuel Cell with an Irreversible Absorption Refrigerator. International Journal of Electrochemical Science. Vol.10, pg. 10045-10060. Compression
Chillers
Operation
Challenges and Recommendations to Optimize Operation, Abdullah Khisraw. Figure 1: Heat graph. Source: Khisraw, 2017. Figure 2: Reciprocating Compressor Schematic. Source: (Khisraw, 2017) Figure 3: Rotary van compressor Source: (NPTEL, 2017). Figure 4: Thermal Expansion Valve . Source: (Neurotronix, 2009). Figure 5: Refrigeration cycle. Source: (North, 2016), Descriptions by Abdullah Khisraw. Figure 6: Condenser and Evaporator phase change. Source: (Khisraw, 2017). Figure 7: Expansion valve and compressor pressure change . Source: (Khisraw, 2017). Figure 8: Compression chiller . Source: (Carrier Corporation , 2017), Descriptions by Abdullah Khisraw. Table 1: Water properties at 1 atm pressure. Source: (Britanica, 2017), (Halliday, et al., 2011), (The Engineering Toolbox, 2017). Table 2: R-134a properties. Source: (Kondou, et al., 2014) (Chiller city corp, 2001). Table 3: Refrigerants. Source: (The Engineering Toolbox, 2017). Literature achrnews, 2005. http://www.achrnews.com. [Online] Available at: http://www.achrnews. com/articles/93523-the-challenges-of-chiller-compressors [Accessed 25 8 2017]. Air compressor guide, 2017. Rotary screw air compressors. [Online] Available at: http://www.air-compressor-guide.com/learn/compressor-types/rotary-screw-compressor [Accessed 28 8 2017]. allseasonshire, 2017. http://www.all-
97 — seasonshire.eu. [Online] Available at: http://www.allseasonshire.eu/chiller-hire/how-chillerswork/ [Accessed 1 9 2017]. Araner, 2017. Araner.com. [Online] Available at: http://www.araner.com/ blog/vapor-compression-refrigeration-cycle/ [Accessed 15 8 2017]. Ben-Naim, A., 2010. Discover Entropy and the Second Law of Thermodynamics. Singapore: World scientific publishing Co. Pte. Ltd.. Brain, M., W.Brayant, C. & Elliott, S., 2017. How Air Conditioners Work. [Online] Available at: http://home.howstuffworks.com/ac4.htm [Accessed 29 8 2017]. Carel, 2017. Carel.com. [Online] Available at: http://www.carel.com/ types-of-compressor [Accessed 15 8 2017]. Carrier Corporation , 2017. Water-Cooled Chillers. [Online] Available at: https://www.carrier. com/commercial/en/us/products/ chillers-components/water-cooled-chillers/19xr/ [Accessed 1 9 2017]. Chiller city corp, 2001. chillercity. com. [Online] Available at: http://chillercity.com/ Refrigerant_Data.php [Accessed 3 9 2017]. EPA, 2017. Environmental Protection Agency. [Online] Available at: https://www.epa.gov/ ghgemissions/understanding-global-warming-potentials [Accessed 22 8 2017]. Halliday, D., Resnick, R. & Walker, J., 2011. Fundementals of Physics. 9th ed. United States of America: John Wiley and Sons Inc.. Khemani, H. & Stonecypher, L.,
— 98 2010. brighthubengineering.com. [Online] Available at: http://www.brighthubengineering.com/hvac/61270-types-of-refrigeration-evaporators/ [Accessed 24 8 2017]. Kondou, C., Mishima, F., Liu, J. & Koyama, S., 2014. Condensation and Evaporation of R134a,. s.l.:Purdue e-Pubs. Luthra, V., 2017. Businessdictionary. [Online] Available at: http://www.businessdictionary.com/definition/ozone-depletion-potential-ODP.html [Accessed 19 8 2017]. Maxwell, J. C., 1970. Theory of Heat. New York: Westport, Conn., Greenwood Press. Mexichem, 2017. mexichemfluor. com. [Online] Available at: http://www.mexichemfluor.com/products/refrigeration/ r134a-refrigerant-klea134a/ [Accessed 3 9 2017]. Miller, T., 2017. Conarigroup.com. [Online] Available at: http://www.conairgroup.com/assets/Knowledge-Center/Whitepapers/ Heat-Transfer/Understanding-Chillers-Which-is-Right-for-Your-Application-0910.pdf [Accessed 15 8 2017]. Neurotronix, 2009. Wikipedia.com. [Online] Available at: https://en.wikipedia. org/wiki/File:Thermostatic_Expansion_Valve_PHT.jpg [Accessed 2 9 2017]. North, K. J., 2016. wikimedia.org. [Online] Available at: https://en.wikipedia. org/wiki/Chiller#/media/File:Water_ Cooled_Chiller_Diagram.png [Accessed 28 8 2017]. NPTEL, 2017. Rotary van compres-
sor. [Online] Available at: http://nptel.ac.in/courses/112103174/module6/lec2/2. html Park, H., 2009. rpctubes.com. [Online] Available at: http://www.rpctubes. com/ [Accessed 28 8 2017]. Pneumofore, 2017. What makes rotary vane machines so great?. [Online] Available at: http://www.pneumofore.com/technology/innovation/ rotary-vane [Accessed 3 9 2017]. ref-wiki.com, 2017. Plate Evaporators. [Online] Available at: http://www.ref-wiki. com/content/view/31539/181/ [Accessed 29 8 2017]. TestEquity LLC, 2017. How a Scroll Compressor Works. [Online] Available at: https://www.testequity. com/static/45/ [Accessed 3 9 2017]. The editors of Encyclopaedia Britannica, 2017. Britanica. [Online] Available at: https://www.britannica. com/science/latent-heat The Engineering Toolbox, 2017. Refrigerants - Environment Properties. [Online] Available at: http://www.webcitation.org/6HtctfLPj?url=http:// www.engineeringtoolbox.com/ Refrigerants-Environment-Properties-d_1220.html [Accessed 27 8 2017]. The Engineering Toolbox, 2017. The Engineering Toolbox. [Online] Available at: http://www.engineeringtoolbox.com/water-vapor-d_979.html [Accessed 20 8 2017]. Whitman, W. C., Johnson, W. M. & Tomczyk, J. A., 2005. Refrigeration
and Air Conditioning Technology. 5th ed. United States of America: Thomson Delmar Learning. Electric bus analysis for Bogotá Public Transportation System. Laura Garcia Rios. Figure 1. Alternatives Bus Technology. Own Illustration. Data: Fraunhofer MOEZ, 2015. Figure 2. Battery Technology Roadmap. Own Illustration. Data: Te Zlatomir Živanović, Zoran Nikolić (2014). Figure 3. Worldwide bus production by region (2011-2013). Own Illustration. Data: Organization International Automobil Construction (OICA). Figure 4. Forecast Global Urban Buses Market 2020. Own Illustration. Data: Frost & Sullivan, Strategic analysis of Global Hybrid and electric Heavy-Duty Transit Bus Market (2013). Table 1. Equipment comparison between electric buses and diesel buses. Own Illustration. Data: (IUT, CSTEP 2014 research). Table 2. Comparison of different parameters and Bus Technology. Own Illustration. Data: Fraunhofer, 2014/ IRENA 2015/IUT, and CSTEP. 2014 / Global Green Growth Institute 2014 / Noel and McCormack 2014. Table 3. Main parameters matrix among the segments comparison. Own Illustration. Data: A uthor Data Source: Global Green Growth Institute, 2015. Table 4. Current vehicle fleet emissions estimations. Source: Laura Garcia Rios. Table 5. Buses technologies prices comparison. Source: Initial Prices in USD Exchange rate : 0.86EUR/USD Based on Volvo 12m Euro V Data; Data from Volvo Colombia and con-
firm by TransMilenio SA; The costs include VAT. Literature Albright, Greg, Jake Edie, and Said Al-Hallaj.(2012). “A Comparison of Lead Acid to Lithium-Ion in Stationary Storage Application.”by AllCell Technologies LLC. International Council on Clean Transportation Europe (2012). „European Vehicle Market Statistics. Poketbook. Delucchi, Mark A. (2001). “An Analysis of the Retail and Lifecycle Cost of Battery-Powered Electric Vehicles.” ELSEVIER, Transportation Research Part D: Transport, and Environment, 6 (6): 371–404. Durbin T. (2003) Effects of diesel particulate filters and a low aromatic, low sulfur siesel fuel on emissaions foe meidum duty diesel buses. Atmospherci enviromental pag 2105 to 2117. Harris,C.M. (1985). “Manual de medidas acústicas y control del ruido” English: acoustic measurements and noise control tookit „.McGrawHill. IEA. (2012). “Energy Technology Perspectives 2012.” Guide book Available: https://www.iea.org/publications/freepublications/publication/ETP2012_free.pdf. International Council on Clean Transportation, (2012). “European Vehicle Market Statistics Pocketbook”, Berlin Germany Neuberger M. (2004) effects of particulate matter on respiratory diseases, symptoms, and functions: epidemiological results of the Austrian Protection on Health Effects of Particulate Matter page 3971 to 3981. Nikolic, Z., Filipovic, Z., & Janjusevic, Lj. (2011). State of development of the electric and hybrid vehicles,
energetic and ecological aspect of applications. Industry, 34(4), 267292. Pierre M, Jemelin C, Louvet N (2011) Driving an electric vehicle. A sociological analysis on pioneer users. Energ Effi 4(4):511–522 Sammer G, Meth D, Gruber CJ (2008) Elektromobilität-Die Sicht der Nutzer. e i Elektrotechnik Informationstechnik 125(11):393–400 Sawyer, R (2000). “Mobile sources critical review”: 1998 NARSTO assessment. Atmospheric environmental page 2161-2181 Urban Foresight, International Energy Agency (2014), “EV City Casebook - 50 Big Ideas Shaping the Future of Electric Mobility.” Electric Vehicle Initiative, and Clean Energy Ministrerial. Zlatomir Živanović, Zoran Nikoli (2012) by licensee InTech.. “New Generation of Electric Vehicles” , Chapter 6 Electric and plug-in hybrid electric vehicles. International The Application of Electric Drive Technologies in City Buses. Available: http://www.intechopen.com/books/ new-generation-of-electricvehicles Fraunhofer, (2014). „Nano-supercapacitors for electric cars“. Research News. Ramírez González, Alberto, Domínguez Calle, Efraín Antonio, & Borrero Marulanda, Isabel. (2011) El ruido vehicular urbano y su relacion con medidades de resticcion de flujo de automoviles. Revista de la Academia Colombiana de Ciencias Exactas, Físicas y Naturales, 35(135), 143-156 Shen, C., P. Shan, and T. Gao. (2011). “A Comprehensive Overview of Hybrid Electric Vehicles.”International Journal of Vehicular Technology 2011(2):1–7.
99 — Global Green Growth Institute (2014). “Green Growth Strategy for Karnataka.” Case Studies. http://gggi.org/ wp-content/uploads/2014/12/Karnataka-GG-Case-Studies_FINAL_ Web-Version.pdf. Global Green Growth Institute and Center for Study of Science, Technology and Policy (2015). “Electric Buses in India: Technology, Policy and Benefits”. GGGI, Seoul, Republic of Korea Herrera Dayana (2007). Modelo de Emisiones vehiculares para la ciudad de Bogotá. Facultad de Ingenieria Master Thesis Los andes University, Bogotá Inter Governmental Panel for Climate Change. (2006). “2006 IPCC Guidelines for National Greenhouse Gas Inventorie: Chapter 3 - Mobile Combustion.” Volume 2: Energy. Judah Aber (2016). Electric Bus Analysis for New York City Transit. Columbia University Meisenzahl, S., P.-P. Sittig, and M. Höck. (2014). “Zukunftstechnologie Lithium-Batterien - Technologie- roadmap für Lithium-Gerätebatterien.” Chemie Ingenieur Technik 86(8):1180–6. Montezuma, R., (2005).”The transformation of Bogotá, 1995-2000: Investing in citizenshio und urban mobility”. Municipality of Bogotá, (2012). Spanish:“Aproximación al consumo energético por uso urbano y actividad económica en Bogotá 1980/2012” English: „Approximation to the energy consumption by u ban use and economic activity in Bogota 1980/2012“, Bogotá: Camilo E Gaitán V, Alcaldía Mayor deBogotá Noel, Lance, and Regina McCormack. (2014). „A Cost-Benefit Ana-
— 100 lysis of a V2G-Capable Electric School Bus Compared to a Traditional Diesel School Bus.“ Applied Energy. Rios Mario (2016),”Energy Strategic Center Research”, Los Andes University Contact Magazine. Bogotá Colombia WCED (1987) Our Common Future. World Commission on Environment and Development Oxford University Press, Oxford Colombia Transport Ministry, (2016). Spanish: “diagnóstico para la formulación del nuevo Plan Nacional 14 de Desarrollo”, English: „Diagnosis for the formulation of the new”. Bogota, Colombia. Energy and Gas Regulation Commision, (2016) “Informe de gestión CREG 2016” English: Management Report 2016. Bogota Colombia Fraunhofer, (2014). “FRAUNHOFER MOEZ TECHVIEW REPORT”, Karl Gürges, Sebastian Borufka Frost & Sullivan, (2013). “Strategic Analysis of Global Hybrid and Electric Heavy-Duty Transit Bus Market.” Inter-American Development Bank, (2013). “Low carbon technologies can transform Latin America’s bus fleets”. IRENA. (2015). “Battery Storage for Renewables.” Battery Storage for Renewables: Market Status and Technology Outlook. International Renewable Energy Agency Available: http:/e/www.irena.org/publications/ Observatorio de Movilidad de Bogotá, (2017). “Reporte Anual de Movilidad 2016”, English: Bogotá Mobility Observatory, 2017, “Anual Mobility Report 2016”, Bogotá Colombia United Nations Human Settlements Programme (UN-HABITAT), (2013).
“States of world’s cities 2012-2013, Prosperity of Cities” New York, United States. Zero Emission Urban Buses, (2016). “An overview of electric buses in Europe, 2016 Report”. UITP, the International Association of Public Transport. DANE, (2016). Departamento Nacional de Planeación Colombia Database. [Online] Available at: https:// geoportal.dane.gov.co EEA, (2017), Greenhouse gas emissions by source sector database, Last update: 08-06-2017 Available at: http://appsso.eurostat.ec.europa.eu/nui/show.do?dataset=env_ air_gge&lang=en International Monetary Fund (IMF) (2013). Government Finance Statistics database, “General Government and Central Government Budgets.” Encyclopædia Britannica (2013) “Etienne Lenoir” Encyclopædia Britannica, inc., Available:https://www. britannica.com/biography/Etienne-Lenoir Project, T., (2017). World air quality. Available at: http://aqicn.org Secretaria de Transito y Transporte de Bogotá (STT), (2014). Available:Anual Vehicle Register. Bogotá, Colombia. The World Bank Group, (2016). Data World Bank Available at: http:// data.worldbank.org UNICEF, (2017). UNICEF. Available at: https://www.unicef.org The Shale Gas Industry in Europe: Barriers and Opportunities. Mariya Todorova. Figure 1: Map of the top ten countries with technically recoverable shale gas resources. Own Illustration. Data: U.S. Energy Information
Administration, 2013). Figure 2: Unproved wet shale gas technically recoverable resources (TTR), Europe, in billion cubic meters. Own Illustration. Data: U.S. Energy Information Administration, 2013, p. 6. Figure 3: Potential flows of air pollutant emissions, harmful substances into water and soil and naturally occurring radioactive materials (NORM). Own Illustration. Data: Policy Department C Citizens‘ Rights and Constitutional Affairs, 2012). Figure 4: Gross inland energy consumption in Europe (EU28) from 2005 to 2050, in ktoe. Own Illustration. Data: European Commission, 2016, p. 140) Figure 5: Indigenous natural gas production, net imports and consumption in EU28 from 2005 to 2050, in ktoe. Own Illustration. Data: European Commission, 2016, p. 140) Table 1: Overview of preliminary risk assessment of hydraulic fracturing across all project phases. Own Illustration. Data: Policy Department C - Citizens‘ Rights and Constitutional Affairs, 2012. Literature AEA, Foster, D., Perks, J. 2012. Climate impact of potential shale gas production in the EU. European Commission DG Clima, Brussels European Commission (2011). Communication from the Commission to the European Parliament, the Council, the European Economic and Social Committee and the Committee of the Regions Energy Roadmap 2050 /* COM/2011/0885 final */. Brussels: European Parliament. European Commission (2011).
Impacts of shale gas and shale oil extraction on the environment and on human health. Policy Department, Economic and scientific policy. Brussels European Commission (2016). EU Reference Scenario 2016. Energy, transport and GHG emissions - Trends to 2050. Main results. Directorate-General for Energy, Directorate-General for Climate Action and Directorate-General for Mobility and Transport. European Parliament. (2011) Impacts of shale gas and shale oil extraction on the environment and on human health. Directorate General for International Policies. Brussels. European Parliament Research Service (EPRS) (2014). Shale gas and EU energy security. European Parliament. Fukui, R., Greenfield, C., Pogue, K. and van der Zwaan, B. (2017). Experience curve for natural gas production by hydraulic fracturing. Middleton, R., Gupta, R., Hyman, J. and Viswanathan, H. (2017). The shale gas revolution: Barriers, sustainability, and emerging opportunities. Applied Energy, 199, pp.88-95. Policy Department C - Citizens‘ Rights and Constitutional Affairs (2012). Impacts of shale gas extraction on the environment and on human health - 2012 update. Brussels: European Parliament. Schaef, H., Davidson, C., Owen, A., Miller, Q., Loring, J., Thompson, C., Bacon, D., Glezakou, V. and McGrail, B. (2014). CO2 Utilization and Storage in Shale Gas Reservoirs: Experimental Results and Economic Impacts. Energy Procedia, 63, pp.7844-7851.
Tagliaferri, C., Lettieri, P. and Chapman, C. (2015). Life Cycle Assessment of Shale Gas in the UK. Energy Procedia, [online] 75, pp.2706-2712. The Climate Principles (2013) Shale gas exploration and production. Key issues and responsible business practices. U.S. Energy Information Administration (2013). Technically Recoverable Shale Oil and Shale Gas Resources. U.S. Energy Information Administration, U.S. Department of Energy. Whitton, J., Brasier, K., CharnleyParry, I., & Cotton, M. (2017). Shale gas governance in the United Kingdom and the United States: Opportunities for public participation and the implications for social justice. Energy Research & Social Science, [online] 26, pp 11-22. Whitton, J., Brasier, K., CharnleyParry, I. and Cotton, M. (2017). Shale gas governance in the United Kingdom and the United States: Opportunities for public participation and the implications for social justice. Energy from North to South: New Electricity Grids for Germany. Pia Schnellberger. Figure 1: Net Electricity Demand in Germany. Table based on data from Fraunhofer ISE, 2015. Figure 2: Transmission Systems in Germany. Image based on data from source: Netzausbau. Figure 3: Transmission Technology Analysis. Source: table based on Fraunhofer ISE (2015) and Bundesnetzagentur, 2016a/2016b. Figure 4: Storage Capacity of Different Energy Storage Systems.
101 — Image based on data from source: REN21, 2017. Figure 5: Maturity of Energy Storage Systems. Image based on data from source: World Energy Council, 2016. Literature Innovation. (2012). In: Merriam Webster‘s Collegiate Dictionary, 11th ed. Springfield: Merriam Webster, p.645. Koch, 2014. Ausbau der Windenergie – Möglichkeiten und Probleme der Umsetzung. UVPreport 28 (5), 220-229. Blazejczak, J., et al, 1999. Umweltpolitik und Innovation: Politikmuster und Innovationswirkungen im internationalen Vergleich. Zeitschrift für Umweltpolitik. 22(1), 1-32. Schlemmer, T., Schmidt, U., & Diebels, W., 2017. Netzausbau und Systemsicherheit in Zeiten der Energiewende. VGB PowerTech. 97, 35-41. BMWi, 2016. Fünfter MonitoringBericht zur Energiewende – Die Energie der Zukunft. [pdf] Available at: https://www.bmwi. de/Redaktion/DE/Publikationen/ E n e r g i e / f u e n f t e r- m o n i t o r i n g b e r i c h t - e n e r g i e - d e r- z u k u n f t . pdf?__blob=publicationFile&v=24 [Accessed 01 September 2017] BMWi, 2017. Energieeffizienz in Zahlen. [pdf] Available at: http://www.bmwi.de/Redaktion/ DE/Publikationen/Energie/ energieeffizienz-in-zahlen.pdf?__ blob=publicationFile&v=10 [Accessed 01 September 2017] Bundesnetzagentur, 2016a. Netzausbau – Erdkabel. [pdf] Available at: https://www. netzausbau.de/SharedDocs/ Downloads/DE/P ublikationen/
— 102 BroschuereErdkabel.pdf?__ blob=publicationFile [Accessed 31 August 2017] Bundesnetzagentur, 2016b. Netzausbau – Freileitungen. [pdf] Available at: https://www. netzausbau.de/SharedDocs/ Downloads/DE/P ublikationen/ BroschuereFreileitungen.pdf?__ blob=publicationFile [Accessed 31 August 2017] Bundestag, 2016. CO2-Bilanzen verschiedener Energieträger im Vergleich. [pdf] Available at: https://www. bundestag.de/blob/406432/70f77c4c170d9048d88dcc3071b7721c/ wd-8-056-07-pdf-data.pdf [Accessed 31 August 2017] DIHK, 2015. Faktenpapier Stromnetze. [pdf] Available at: https://www.ihk-nuernberg.de/de/ Geschaeftsbereiche/InnovationUmwelt/Energie/Energiepolitikund-Energierecht/ausbau-derstromnetze [Accessed 31 August 2017] Fraunhofer ISE, 2015. Wege zur Transformation des Deutschen Energiesystems bis 2050. [pdf] Available at: https://www.ise. fraunhofer.de/content/dam/ise/de/ documents/publications/studies/ Fraunhofer-ISE-Studie-Was-kostetdie-Energiewende.pdf [Accessed 01 September 2017] Fraunhofer IWES, 2014. Potenziale von Power-to-Gas Energiespeichern. [pdf] Available at: https://www.fraunhofer.de/content/ d a m / z v / d e / Fo r s c h u n g s f e l d e r / Energie-Rohstoffe/Potenziale%20 v o n % 2 0 Po w e r- t o - G a s % 2 0 Energiespeichern.pdf [Accessed 01 September 2017[ NPE, 2014. Fortschrittsbericht 2014 – Bilanz der Marktvorbereitung. [pdf] Available at: https://
w w w. b m w i . d e / R e d a k t i o n / D E / Publikationen/Industrie/nationaleplattform-elektromobilitaetfortschrittsbericht-2014.pdf?__ blob=publicationFile&v=6 [Accessed 1 September 2017] Ü b e r t r a g u n g s n e t z b e t r e i b e r, 2017. Szenariorahmen für die Netzentwicklungspläne Strom 2030 (2017). [pdf] Available at: https:// www.netzentwicklungsplan.de/ sites/default/files/paragraphsfiles/170214_Einf%C3%BChrung_ NEP_2030_Barth.pdf [Accessed 01 September 2017] Umweltbundesamt, 2017. Entwicklung der spezifischen Kohlendioxid-Emissionen des deutschen Strommix in den Jahren 1990 – 2016. [pdf] Available at: https://www.umweltbundesamt. de/sites/default/files/medien/1410/ publikationen/2017-05-22_climatechange_15-2017_strommix.pdf [Accessed 31 August 2017] World Energy Council, 2016. World Energy Resources E-storage: Shifting from cost to value Wind and solar applications. [pdf] Available at: http://speicherinitiative.at/ assets/Uploads/01-E-storage.pdf [Accessed 01 September 2017] BMWi. Versorgungssicherheit in Deutschland auf hohem Niveau. [online] Available at: https://www.bmwi.de/Redaktion/ DE/Infografiken/Energie/ versorgungssicherheit-indeutschland.html [Accessed 31 August 2017] BR, 2017. Bayern Unter Strom. [online] Available at: http://www. br.de/br-fernsehen/sendungen/ mehrwert/strom-trassesuedlink-100.html [Accessed 31 August 2017] Bundesnetzagentur. Warum
brauchen wir den Netzausbau? [online] Available at: https://www. netzausbau.de/wissenswertes/ warum/de.html [Accessed 31 August 2017] Netzausbau. Leitungsvorhaben. [online] Available at: https://www. netzausbau.de/leitungsvorhaben/ de.html?cms_map=4 [Accessed 01 September 2017] Sueddeutsche Zeitung, 2014. Seehofers Kurs gegen Stromtrassen – Energiepolitik paradox. [online] Available at: h t t p : / / w w w. s u e d d e u t s c h e . d e /
bayern/seehofers-kurs-gegens t r o m t r a s s e n - e n e r g i e p o l i t i kparadox-1.1886230 [Accessed 31 August 2017] Umweltbundesamt, 2013. Potenziale der Windenergie an Land. [pdf] Available at: https://www. umweltbundesamt.de/sites/default/ files/medien/378/publikationen/ potenzial_der_windenergie.pdf [Accessed 31 August 2017] U m w e l t b u n d e s a m t . Stromerzeugung erneuerbar und konventionell. [online] Available at: https://www.umweltbundesamt.
de/daten/energiebereitstellungverbrauch/stromerzeugungerneuerbar-konventionell [Accessed 31 August 2018] Bayerischer Landtag, 2014. Schriftliche Anfrage der Abgeordneten Christine Kamm Bündnis 90/DIE GRÜNEN vom 19.08.2014 – Gazprom auf dem bayerischen Strommarkt. [online] Available at: https://www.bayern. landtag.de/www/ElanTextAblage_ WP17/Drucksachen/Schriftliche%20 Anfragen/17_0003943.pdf [Accessed 15 November 2017]