Home Care Hard Surface Cleaning
Multipurpose Solutions for Surface Clean
Juraci Marques da Silva, Technical Consultant August, 2016
1 | Driving Forces to Innovation and Claims to choose
2 | Conclusions
8/24/2016
2
Multipurpose Solutions for Surface Clean! Claims to choose Convenient Cleaning
Spotless Drying
High-Performance Cleaning
Easy-toclean-again Effect
Convenience: Ease of Use, Emotional Purchase
Primary Cleaning Boost
Glossy & Streak-Free
Performance
Sustainable Cleaning Gentle Cleaning
Skin Care
Renewable Base and Biodegradable
Surface Care
Safeness: Hygiene, Material Protection…
Sustainable Solutions: Environmentally friendly product, water and energy efficiency, 3 packaging/refill
Multipurpose Solutions for Surface Clean! Claims to choose – Convenient Cleaning
Convenient Cleaning
Spotless Drying
Easy-to-cleanagain Effect
4
Multipurpose Solutions for Surface Clean! The Polyquart® Types Polyquart® 149 Aqueous solution of acrylic copolymer Yellowish clear liquid 21.5 – 22.5 % active Stable at pH ranges from 3 – 10 Dosage 0.2% - 1.0% as is
Polyquart® Ecoclean Aerobic and anaerobic biodegradability
Starch acrylic copolymer Yellowish clear liquid 21.5 – 22.5 % active Stable at pH ranges from 3 – 10 Dosage 0.5% - 1.5% as is
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Surface Modification Polyquart® 149 Uniform and quick drying
Uniform wetting
120
More hydrophilic
Untreated Surface
Contact Angle [°]
100
80
Polyquart 149
More hydrophobic
60
40
20
0 Ceramic 8/24/2016
Glass
Stainless Steel
Car Panel
PVC
PP 6
Surface Modification PolyquartÂŽ Ecoclean Excellent wetting & uniform drying
Unchanged surface
90 Untreated Surface
80 Polyquart Ecoclean
Contact Angle [°]
70 60
More hydrophilic
50 40 30 20 10 0 Ceramic
Glass
Stainless Steel
Plastics*
* PVC 8/24/2016
7
Multipurpose Solutions for Surface Clean! Test Method Water Drainage / Sheeting 1. Pretreatment with test solution Test solution ( e.g. 0.5% active surfactant and 0.1% active polymer or a cleaner formulation) is dropped on a ceramic tile 15x15cm by 25 drops, 5x5 drops in square. These drops are wiped via Kim Wipe in twice, 10 wiping cycles in both directions to get a homogenous film
2. Air drying Drying at roomtemperature for 24 hours
3. Rinse with water stream Pretreated plate is placed vertical and a water stream is placed on the upper end from the right to the left corner in order to rinse the ceramic. After stopping the water stream, you can evaluate the sheeting effect)
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Multipurpose Solutions for Surface Clean! Water Drainage / Sheeting Effect
Water sheeting effect
No effect
Water drainage effect
caused by hydrophilization of the surface
on a non treated surface
caused by hydrophobization of the surface
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Multipurpose Solutions for Surface Clean! Water Drainage / Sheeting 0.5% active surfactant
1% active surfactant
2% active surfactant without polymer
hydrophilization
hydrophobization
Water drainage
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no effect - rip
1
1
1
Water sheeting
Lutensol®
1
-0.5
-0.5
Lutensol®/ Glucopon® 425 (1:3) 10
Multipurpose Solutions for Surface Clean! Water Drainage by Polyquart® 149 0.5% active surfactant
0.5% active surfactant + 0.1% active Polyquart® 149
6 Water drainage
hydrophilization
hydrophobization
4
8/24/2016
1
1
Water sheeting
Lutensol®
Lutensol®/ Glucopon® 425 (1:3) 11
Multipurpose Solutions for Surface Clean! Water Sheeting by Polyquart® Ecoclean 0.5% active
0.5% active + 0.1% active Polyquart® Ecoclean
hydrophilization
hydrophobization
Water drainage
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1
1
Water sheeting
-1 Lutensol®
-1 Lutensol®/ Glucopon® 425 (1:3) 12
Multipurpose Solutions for Surface Clean! Water Drainage / Sheeting Effect on water sheeting / drainage by Polyquart® types for a spotless drying:
Polyquart® 149
Polyquart® Ecoclean spotless drying & anti-rain
quick & spotless drying
Strength of water sheeting / drainage effect 8/24/2016
13
Multipurpose Solutions for Surface Clean! Effect to choose – Convenient Cleaning
Convenient Cleaning
Spotless Drying
Easy-to-cleanagain Effect
14
Multipurpose Solutions for Surface Clean! Test Method Easy-to-clean-again 1. Pretreatment with test solution e.g. 1% active surfactant and 0.1% active polymer is dropped on a ceramic tile. 25 drops, 5x5 drops in square for 15x15cm tile. These drops are wiped via Kim Wipe in twice 10 wiping cycles in both directions to get a homogenous film.
2. Air drying Drying at roomtemperature for 24 hours.
3. Soiling tile with Ca-Stearate by air brush 3 ml soil is sprayed homgenous on the hole area of tile. (Soil: 5% Ca-Stearate, 10% Water, 85% Ethanol the soil should be stirred by Ultra Turrax and Ultra Sonic Bath and stored under usual stiring for 1 day)
4. Heating at for melting the Stearate layer (30 Minutes at 180°C)
5. Wiping with sponge under rinsing tap water Wiping with constant low pressure under water stream for 10 cycles.
6. Evaluation 8/24/2016
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Multipurpose Solutions for Surface Clean! Easy-to-clean-again Effect ď Ž Evaluation: left side of tile untreated
right side of tile pretreated
Grading examples (0 to 3):
0 8/24/2016
1
2
3 16
Multipurpose Solutions for Surface Clean! Easy-to-clean-again: Polyquart® 149 0.5% active surfactant + 0.1% active Polyquart® 149 2% active surfactant + 0.1% active Polyquart® 149
3
2
No effect with 0.5% active surfactant, slight effect on Lutensol® and Glucopon® mixtures with 2.0% active surfactant and 0.1% Polyquart® 149.
1
1
0
0
0 Lutensol® 8/24/2016
0 Lutensol®/ Glucopon® 425 (1:3) 17
Multipurpose Solutions for Surface Clean! Easy-to-clean-again: Polyquart® 149 0.5% active surfactant + 0.2% active Polyquart® 149 2% active surfactant + 0.2% active Polyquart® 149
3
2
1
Slight effect with 0.5% / 2.0% active surfactant and 0.2% Polyquart®149.
1
1
0
0 Lutensol® 8/24/2016
1
Lutensol®/ Glucopon® 425 (1:3) 18
Multipurpose Solutions for Surface Clean! Easy-to-clean-again: Polyquart® Ecoclean 0.5% active surfactant + 0.1% active Polyquart® Ecoclean 2% active + 0.1% active Polyquart® Ecoclean
3
3
Slight effect with 0.5% active surfactant, excellent effect on Lutensol® but not on Glucopon® mixtures with 2.0% active surfactant and 0.1% Polyquart® Ecoclean. 2
1
1
1
1
0 Lutensol® 8/24/2016
Lutensol®/ Glucopon® 425 (1:3) 19
Multipurpose Solutions for Surface Clean! Easy-to-clean-again: Polyquart® Ecoclean 0.5% active surfactant + 0.2% active Polyquart® Ecoclean 2% active + 0.2% active Polyquart® Ecoclean
3
Slight effect with 0.5% active surfactant, significant effect on Lutensol® and Glucopon® mixtures with 2.0% active surfactant and 0.2% Polyquart® Ecoclean.
2
2
1
1
2
1
0 Lutensol® 8/24/2016
Lutensol®/ Glucopon® 425 (1:3) 20
Multipurpose Solutions for Surface Clean! Easy-to-clean-again Easy-to-clean-again effect by Polyquart® types:
Polyquart® 149
Polyquart® Ecoclean
Strength of easy-to-clean-again effect* *using Ca-stearate based soil 8/24/2016
21
Home Care Claims to choose – High-Performance
High-Performance Cleaning
Primary Cleaning Boost
Glossy & Streak-Free
22
Multipurpose Solutions for Surface Clean! Test Method Primary Cleaning
Modified Gardner test method by automatic test equipment
0.5% / 1% / 2 % active surfactant in distilled water
25 °C
Using oil soil (IPP 83/21) on polyvinylchloride (PVC) strips
Evaluation of cleaned PVC strips after 10 wipes
Oily Soil (IPP 83/21) % Content 17.0 Myritol 318 (caprylic / capric triglyceride) 40.0 Nytex 801 (Nynas; processing oil, naphthenic) 36.0 Benzine (80/110) 7.0 Special Carbon Black (Orion Engineered Carbons, D-60528 Francfort, Germany)
(1) Soiling by brush
(3) Applying test solution
(2) Analysis of soiled surface
(4) Wiping with sponge
(5) Rinsing with water (6) Analysis of cleaned surface 8/24/2016
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Multipurpose Solutions for Surface Clean! Primary Cleaning Performance Test in distilled water at 25 °C, using the modified Gardner test on PVC with oil soil
0.5% active surfactant
1% active surfactant
2% active surfactant
70
62 Soil Removal [%]
60 50
58 51
50
55
52
40 30 20 10 0 Lutensol®
Lutensol®/ Glucopon® 425 (1:3)
Multipurpose Solutions for Surface Clean! Primary Cleaning – Polyquart® 149 Test in distilled water at 25 °C, using modified Gardner test on PVC with oil soil
1% active surfactant 0.5% active surfactant 0.5% active surfactant + 0.1% active Polyquart® 149
Soil Removal [%]
80
71 70
63
62
60 50
50
55
51
40 30
Excellent primary cleaning boost of Lutensol® / Glucopon® combination (3:1) by 0.1% active Polyquart® 149.
20 10 0 Lutensol®
Lutensol®/ Glucopon® 425 (1:3)
Multipurpose Solutions for Surface Clean! Primary Cleaning – Polyquart® Ecoclean Test in distilled water at 25 °C, using modified Gardner test on PVC with oil soil
1% active surfactant 0.5% active surfactant 0.5% active surfactant + 0.1% active Polyquart® Ecoclean
Soil Removal [%]
70
62
58
60 50
50
55
51
54
40 30 20
Excellent primary cleaning boost of Lutensol® / Glucopon® combination (3:1) by 0.1% active Polyquart® Ecoclean.
10 0 Lutensol®
Lutensol®/ Glucopon® 425 (1:3)
Multipurpose Solutions for Surface Clean! Primary Cleaning Boost effect on primary cleaning by Polyquart® types:
Polyquart® 149
Polyquart® Ecoclean
Strength of primary cleaning boost effect
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Home Care Claims to choose – High-Performance
High-Performance Cleaning
Primary Cleaning Boost
Glossy & StreakFree 28
Multipurpose Solutions for Surface Clean! Test Method Gloss Retention 1.
Measure reflection of clean ceramic tile
2.
Pretreatment with test solution (1% active surfactant is dropped on a ceramic tile. 25 drops, 5x5 drops in square for 15x15cm tile. These drops are wiped via Kim Wipe in twice 10 wiping cycles in both directions to get a homogenous film)
3.
Air drying at room temperature
4.
Measure reflection of treated ceramic tile
5.
Calculate gloss retention out of 1. and 4.
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N 20° 60° 85°
29
Multipurpose Solutions for Surface Clean! Gloss Retention – Polyquart® 149 Test in distilled water at 20 °C on black ceramic tiles
0.5% active surfactant 0.5% active surfactant + 0.1% Polyquart® 149
Gloss Retention [%]
2.0% active surfactant 2.0% active surfactant + 0.1% Polyquart® 149
100 90 80 70 60 50 40 30 20 10 0
96.6 95.3
91.8 78.2
79.7 80.4
85.2 88.2
Gloss retention boost by Polyquart® 149 only on Lutensol® types – mixtures with Glucopon® show already excellent gloss retention; better results with 0.5% active surfactant.
Lutensol®
Lutensol®/ Glucopon® 425 (1:3)
Multipurpose Solutions for Surface Clean! Gloss Retention – Polyquart® Ecoclean Test in distilled water at 20 °C on black ceramic tiles
0.5% active surfactant 0.5% active surfactant + 0.1% Polyquart® Ecoclean
Gloss Retention [%]
2.0% active surfactant 2.0% active surfactant + 0.1% Polyquart® Ecoclean
100 90 80 70 60 50 40 30 20 10 0
92.2 78.2
88 79.7
96.6 98.2
85.2 87.5
Gloss retention boost by Polyquart® Ecoclean only on Lutensol® types; better results at 0.5% active surfactant.
Lutensol®
Lutensol®/ Glucopon® 425 (1:3)
Multipurpose Solutions for Surface Clean! Gloss Retention / Streak-Free Effect Effect on gloss retention / streak-free boost with Polyquart® types:
Polyquart®
149
Only with alkoxylated surfactants like Lutensol® types; no boost of mixtures with Glucopon® types!
Polyquart® Ecoclean
Strength of gloss retention / streak-free effect
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Home Care Claims to choose – Gentle Cleaning
Gentle Cleaning
Skin Care
Surface Care
33
Multipurpose Solutions for Surface Clean! Skin Care – Glucopon® Glucopon® surfactants are significantly less skin irritating than comparable to nonionic and anionic (LAS) surfactants. Glucopon® surfactants can even reduce the skin irritation factor of other surfactants when being used in combination. Perfect mildness to skin.
Multipurpose Solutions for Surface Clean! Skin Care - Glucopon® Test Method: Modified Duhring - Chamber Test Tested Surfactants:
Alkyl Polyglucoside - APG® Linear Alkylbenzene Sulphonate - LAS Fatty Alcohol Ether Sulfate - FAES Sodium Alkene Sulfate - SAS Fatty Alcohol Sulfate – FAS Mixtures of other surfactants with APG®
Test Conditions: 20 subjects (male and female) Mode of application: once, occlusive, for 24 hours Concentration of the test solution: 1% active substance
Multipurpose Solutions for Surface Clean! Skin Care - Glucopon® Test Method: Modified
APG®
Duhring - Chamber Test LAS
Test Conditions:
FAES
20 subjects (male and female). Mode of Application: once, occlusive, for 24 hours The concentration of the test solution was 1% active substance.
SAS FAS C12/14 LAS / APG® (1:1) FAES / APG® (1:1) SAS / APG® (1:1) FAS / APG® (1:1)
0
100
200
300
Relative irritation score (%)
400
Home Care Claims to choose – Gentle Cleaning
Gentle Cleaning
Skin Care
Surface Care
37
Multipurpose Solutions for Surface Clean! Test Method Plastic Compatibility ISO 22088-4 test method (spline / corrosion test) A test method to determine the plastic compatibility of hard surface cleaner ingredients like surfactants, solvents, acids, alkaline and further components.
unchanged
Methodology: The plastic test strip, containing a stainless steal pin in a hole (tension), is dipped shortly into the test solution (1% active). The test strip is checked visually after
4 hours
3 days
7 days and
14 days test period
fissures
throughcracks
fraction 8/24/2016
38
Multipurpose Solutions for Surface Clean! Plastic Compatibility (PMMA) Test solution: 1% active surfactant – Lutensol® :Glucopon® 425 (1:3) – w/wo 0.2% Polyquart® type Substrate: Plexiglass 8N80 (PMMA - Polymethylmethacrylat)
unchanged
Superior plastic compatibility with high content of Glucopon® types; no influence by Polyquart® types. fissures
14 days 7 days 3 days Lutensol®
Lutensol® / Glucopon® 425
throughcracks
4 hours Lutensol® / Glucopon® 425 / Polyquart® 149
Lutensol® / Glucopon® 425 / Polyquart® Ecoclean
fraction
Multipurpose Solutions for Surface Clean! Plastic Compatibility (PC) Test solution: 1% active surfactant – Lutensol® :Glucopon® 425 (1:3) – w/wo 0.2% Polyquart® type Substrate: Makrolon 3103 (PC - Polycarbonate)
Superior plastic compatibility with high content of Glucopon® types; no influence by Polyquart® types.
unchanged
fissures
14 days 7 days 3 days Lutensol®
Lutensol® / Glucopon® 425
throughcracks
4 hours Lutensol® / Glucopon® 425 / Polyquart® 149
Lutensol® / Glucopon® 425 / Polyquart® Ecoclean
fraction
Multipurpose Solutions for Surface Clean! Plastic Compatibility (ABS) Test solution: 1% active surfactant – Lutensol®: Glucopon® 425 (1:3) – w/wo 0.2% Polyquart® type Substrate: Polylac PA 727 (ABS - Acrylnitril Butadien Styrol)
Superior plastic compatibility with high content of Glucopon® types; no influence by Polyquart® types.
unchanged
fissures
14 days 7 days 3 days Lutensol®
Lutensol® / Glucopon® 425
throughcracks
4 hours Lutensol® / Glucopon® 425 / Polyquart® 149
Lutensol® / Glucopon® 425 / Polyquart® Ecoclean
fraction
Multipurpose Solutions for Surface Clean! Claims to choose – Sustainable Cleaning
Sustainable Cleaning
Renewable Base 42
Multipurpose Solutions for Surface Clean! Renewable Base Renewable Base: Glucopon® types (alkyl polyglucoside) = sugar / fatty alcohol Polyquart® Ecoclean = teric modified starch Existing statement for vegetable origin of Polyquart® Ecoclean Aerobic and anaerobic biodegradability, no labelling for the following products: Glucopon® types, Lutensol® types Polyquart® Ecoclean 8/24/2016
43
Home Care and I&I Glucopon® types Product information Application:
Home Care and I&I Focus Hard Surface Cleaning
Customer industry: Market:
Consumer Goods and I&I
Global
Sustainability performance
Differentiation potential
Gloss improvement, foam stabilization
Customer Performance in modern formulations Health and safety Consumer Health & safety Material protection
Cleaning performance 100% renewable based Meets eco-label requirements – aerobic and anaerobic biodegradable Registered in main chemical inventories
A balanced surfactant combining efficiency with an excellent eco-tox profile
44
Home Care and I&I Polyquart® Ecoclean Product information Application:
Home Care and I&I Focus Hard Surface Cleaners
Customer industry: Market:
Consumer Goods and I&I
Global
Sustainability performance
Differentiation potential
Amphoteric modified starch
Customer
Excellent eco-tox profile Aerobic and anaerobic biodegradable Supports sustainable convenience claims such as easy-to-clean-again, time-saving, easy-to-use
Supported modern claims Consumer Health & safety Convenience Performance
A product that supports modern consumer needs
45
1 | Driving Forces to Innovation and Claims to choose 2 | Conclusions
8/24/2016
46
Multipurpose Solutions for Surface Clean! The Elements Polyquart® types Long-lasting effects High gloss Cleaning boost
Lutensol®
Glucopon® types
types
Skin and surface care Formulability Foam stabilization High gloss
Excellent wetting Emulsification Disperging
renewables
8/24/2016
Multipurpose Solutions!
sustainable
47
Multipurpose Solutions for Surface Clean! Summary Convenient Cleaning
High-Performance Cleaning
Easy-to-clean-again effect
Excellent primary cleaning
Quick and spotless drying
Glossy and streak-free surfaces
Time-saving and effortless cleaning
Foam stability
Gentle Cleaning
Sustainable Cleaning
Material protection
Biodegradable products
Skin protection
Renewable based raw materials 48
Lutensol®, Glucopon® & Polyquart®: Multipurpose Solutions for Surface Clean!
Juraci M. da Silva
juraci.silva@basf.com