Allylbenzene by Asch

Reaxys

PubChem

eMolecules

Reactions (440)

Yield

LabNetwork

Substances (2)

Citations (416)

Conditions

References A

Synthesize Find similar

100

Synthesize Find similar

Rx-ID: 28886877 Find similar reactions

With di[(cyclooctadiene)(.mu.-hydroxido)iridium(I)]; tri-n-octyl phosphine in toluene

T=100°C; 15 h; Inert atmosphere;

101

Obora, Yasushi; Hatanaka, Shintaro; Ishii, Yasutaka

Organic Letters, 2009 , vol. 11, # 15 p. 3510 - 3513 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 28886878 Find similar reactions

Synthesize Find similar

With di[(cyclooctadiene)(.mu.-hydroxido)iridium(I)]; tri-n-octyl phosphine in toluene

T=100°C; 15 h; Inert atmosphere;

Obora, Yasushi; Hatanaka, Shintaro; Ishii, Yasutaka

Organic Letters, 2009 , vol. 11, # 15 p. 3510 - 3513 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

102

Synthesize Find similar

Rx-ID: 28886879 Find similar reactions

With di[(cyclooctadiene)(.mu.-hydroxido)iridium(I)]; tri-n-octyl phosphine in toluene

T=100°C; 15 h; Inert atmosphere;

Obora, Yasushi; Hatanaka, Shintaro; Ishii, Yasutaka

Organic Letters, 2009 , vol. 11, # 15 p. 3510 - 3513 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

103

Synthesize Find similar

Rx-ID: 28886880 Find similar reactions

B: 65%

104

With di[(cyclooctadiene)(.mu.-hydroxido)iridium(I)]; tri-n-octyl phosphine in toluene

T=100°C; 15 h; Inert atmosphere;

Obora, Yasushi; Hatanaka, Shintaro; Ishii, Yasutaka

Organic Letters, 2009 , vol. 11, # 15 p. 3510 - 3513 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 29030809 Find similar reactions

40%

Synthesize Find similar

Stage #1: allylboronic acid pinacol ester With sec.-butyllithium in tetrahydrofuran; hexane

T=-78 - 20°C; Suzuki-Miyaura coupling; Inert atmosphere; Stage #2: iodobenzene With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate in tetrahydrofuran; hexane

Suzuki-Miyaura coupling; Inert atmosphereReflux;

Gerbino, Dario C.; Mandolesi, Sandra D.; Schmalz, Hans-Guenther; Podesta, Julio C.

European Journal of Organic Chemistry, 2009 , # 23 p. 3964 - 3972 Title/Abstract Full Text View citing articles Show Details

105

Synthesize Find similar

Rx-ID: 29030838 Find similar reactions

96 %Chromat.

Synthesize Find similar

Gerbino, Dario C.; Mandolesi, Sandra D.; Schmalz, Hans-Guenther; Podesta, Julio C.

European Journal of Organic Chemistry, 2009 , # 23 p. 3964 - 3972 Title/Abstract Full Text View citing articles Show Details

With palladium diacetate in 1,4-dioxane

T=100°C; Suzuki-Miyaura coupling; 6 h;

106

Synthesize Find similar

Rx-ID: 30097285 Find similar reactions

78%

107

With Fe(acetylacetonate)3 in tetrahydrofuran

T=25°C; 3 h; Inert atmosphere;

Synthesize Find similar

Volla, Chandra M. R.; Markovic, Dean; Dubbaka, Srinivas Reddy; Vogel, Pierre

European Journal of Organic Chemistry, 2009 , # 36 p. 6281 - 6288 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 9599241 Find similar reactions

Synthesize Find similar

70%

Stage #1: dimethyl sulfoxide With lithium diisopropyl amide in tetrahydrofuran

T=-70°C; Stage #2: With copper(I) bromide in tetrahydrofuran

T=-40 - 20°C; Stage #3: 1,1-diiodo-2-phenylethane With Di-n-butylzinc; lithium bromide in tetrahydrofuran

T=20°C; 1 h;

Abramovitch, Adi; Varghese, Jos P.; Marek, Ilan

Organic Letters, 2004 , vol. 6, # 4 p. 621 - 623 Title/Abstract Full Text View citing articles Show Details

70%

Stage #1: dimethyl sulfoxide With lithium diisopropyl amide in tetrahydrofuran

T=-70 - 0°C; Stage #2: With copper(I) bromide in tetrahydrofuran

T=-40 - 0°C; Stage #3: 1,1-diiodo-2-phenylethane With Di-n-butylzinc in tetrahydrofuran

T=20°C; 1 h;

Abramovitch, Adi; Marek, Ilan

European Journal of Organic Chemistry, 2008 , # 29 p. 4924 - 4931 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

108

Synthesize Find similar

Rx-ID: 26059909 Find similar reactions

A: 50% B: 5%

Kawatsura, Motoi; Ata, Fumio; Hirakawa, Takuya; Hayase, Shuichi; Itoh, Toshiyuki

Tetrahedron Letters, 2008 , vol. 49, # 33 p. 4873 - 4875 Title/Abstract Full Text View citing articles Show Details

With tri-ruthenium(0)dodecacarbonyl; 2-(diphenylphosphino)benzoic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene in 1,4-dioxane

T=100°C; 12 h;

Synthesize Find similar

109

Synthesize Find similar Rx-ID: 26059915 Find similar reactions

A: 50% B: 5%

Synthesize Find similar

With tri-ruthenium(0)dodecacarbonyl; 2-(diphenylphosphino)benzoic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene in 1,4-dioxane

T=100°C; 12 h;

Kawatsura, Motoi; Ata, Fumio; Hirakawa, Takuya; Hayase, Shuichi; Itoh, Toshiyuki

Tetrahedron Letters, 2008 , vol. 49, # 33 p. 4873 - 4875 Title/Abstract Full Text View citing articles Show Details

110

Synthesize Find similar

Rx-ID: 28170798 Find similar reactions

72%

Synthesize Find similar

With tetrabutyl ammonium fluoride; tetrabutylammomium bromide; palladium dichloride in tetrahydrofuran

10 h; Reflux; stereoselective reaction;

Dey, Raju; Chattopadhyay, Kalicharan; Ranu, Brindaban C.

Journal of Organic Chemistry, 2008 , vol. 73, # 23 p. 9461 - 9464 Title/Abstract Full Text View citing articles Show Details

111

Synthesize Find similar

Rx-ID: 28397213 Find similar reactions

72%

Synthesize Find similar

With potassium hydroxide; C16H16Cl2N2O4Pd2; tetrabutylammomium bromide in water; acetone

T=25°C; 4 h; DarknessInert atmosphere;

Alacid, Emilio; Najera, Carmen

Organic Letters, 2008 , vol. 10, # 21 p. 5011 - 5014 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

112

Synthesize Find similar

Rx-ID: 11068247 Find similar reactions

A: 3 % Chromat. B: 92 % Chromat.

With bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran

T=25°C; 1 h; Product distribution; Further Variations:Reagents;

Synthesize Find similar

Naitoh, Yoshitaka; Bando, Fumiaki; Terao, Jun; Otsuki, Kazutaka; Kuniyasu, Hitoshi; Kambe, Nobuaki

Chemistry Letters, 2007 , vol. 36, # 2 p. 236 - 237 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

113

Synthesize Find similar Rx-ID: 11095438 Find similar reactions

A: 5% B: 10% C: 63%

With tri-n-butyl-tin hydride; triethylamine; palladium diacetate in dichloromethane

18 h; Heating;

In, Su Kim; Guang, Ri Dong; Young, Hoon Jung

Journal of Organic Chemistry, 2007 , vol. 72, # 14 p. 5424 - 5426 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

114

Synthesize Find similar Rx-ID: 11175460 Find similar reactions

With formic acid; tributyl-amine; [Pd(PPh3)2(OAc)2] in N,N-dimethyl-formamide

T=35°C; 0.5 h; Title compound not separated from byproducts.;

Pandey, Sushil K.; Greene, Andrew E.; Poisson, Jean-Francois

Journal of Organic Chemistry, 2007 , vol. 72, # 20 p. 7769 - 7770 Title/Abstract Full Text View citing articles Show Details

115

Synthesize Find similar

Multi-step reaction with 2 steps 1: 2,6-di-tert-butyl-4-methylpyridine / 1,2-dichloro-ethane / 1 h / 70 °C 2: formic acid; tributylamine / Pd(OAc)2(PPh3)2 / dimethylformamide / 0.5 h / 35 °C View Scheme

Rx-ID: 11300794 Find similar reactions

Pandey, Sushil K.; Greene, Andrew E.; Poisson, Jean-Francois

Journal of Organic Chemistry, 2007 , vol. 72, # 20 p. 7769 - 7770 Title/Abstract Full Text View citing articles Show Details

116

Synthesize Find similar

Rx-ID: 694241 Find similar reactions

Synthesize Find similar

With diethyl ether

Tiffeneau

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1904 , vol. 139, p. 482 Full Text View citing articles Show Details

Hershberg

Helvetica Chimica Acta, 1934 , vol. 17, p. 351,354 Full Text View citing articles Show Details

With vanadium(III) chloride

1.) dichloromethane, -78 grad C, 20 min, 2.) dichloromethane, -78 grad C, 1.5 h, room temp. 2.5 h; Yield given. Multistep reaction;

Hirao, Toshikazu; Misu, Daisuke; Yao, Koichi; Agawa, Toshio

Tetrahedron Letters, 1986 , vol. 27, # 8 p. 929 - 932 Title/Abstract Full Text View citing articles Show Details

in diethyl ether

2 h; Heating;

Tanaka, Jiro; Nojima, Masatomo; Kusabayashi, Shigekazu; Nagase, Shigeru

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 673 - 678 Title/Abstract Full Text View citing articles Show Details

Hide Details

Tiffeneau

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1904 , vol. 139, p. 482 Full Text View citing articles Show Details

Ignatowska, Jolanta; Dmowski, Wojciech

Journal of Fluorine Chemistry, 2006 , vol. 127, # 6 p. 720 - 729 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

117

Synthesize Find similar Rx-ID: 11043946 Find similar reactions

With oxygen in acetonitrile

P=760.051 Torr; 5 h; Irradiation; Product distribution; Further Variations:Reagents;

Shiraishi, Yasuhiro; Saito, Naoya; Hirai, Takayuki

Chemical Communications, 2006 , # 7 p. 773 - 775 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

118

Synthesize Find similar

Rx-ID: 11076066 Find similar reactions

With oxygen

T=110°C;

Rostovshchikova; Kiseleva; Smirnov; Maksimov; Suzdalev; Prusakov; Tsodikov; Ikorskii

Russian Chemical Bulletin, 2006 , vol. 55, # 10 p. 1768 - 1774 Title/Abstract Full Text View citing articles Show Details

119

Synthesize Find similar

Rx-ID: 944815 Find similar reactions

Synthesize Find similar

Heating;

Grignon,J. et al.

Journal of Organometallic Chemistry, 1975 , vol. 96, p. 225 - 235 Full Text View citing articles Show Details

With cesium fluoride; palladium diacetate in 1,4-dioxane

T=100°C; Stille cross-coupling; 6 h;

Gajare, Anil S.; Jensen, Rader S.; Toyota, Kozo; Yoshifuji, Masaaki; Ozawa, Fumiyuki

Synlett, 2005 , # 1 art. no. U25204ST, p. 144 - 148 Title/Abstract Full Text View citing articles Show Details

120

Synthesize Find similar

Rx-ID: 9816634 Find similar reactions

47%

With xanthone powder in acetonitrile

Synthesize Find similar

Milanesi, Silvia; Fagnoni, Maurizio; Albini, Angeld

T=20°C; Photolysis;

Journal of Organic Chemistry, 2005 , vol. 70, # 2 p. 603 - 610 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

121

Synthesize Find similar

Rx-ID: 9867384 Find similar reactions

A: 2% C: 62 % Spectr. D: 25%

With potassium carbonate; 1-n-butyl-3-methylimidazolium tetrafluoroborate in acetonitrile

T=115°C; 45 h; Further byproducts given;

Jorapur, Yogesh R.; Lee, Chang-Hee; Chi, Dae Yoon

Organic Letters, 2005 , vol. 7, # 7 p. 1231 - 1234 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

122

Synthesize Find similar Rx-ID: 9990303 Find similar reactions

B: 78%

With 1,1-dimethylethylmagnesium chloride; Cl2Ni(1,2-bis(diphenylphosphino)ethane) in tetrahydrofuran; toluene

T=20°C; 0.0833333 h;

Kamijo, Shin; Huo, Zhibao; Jin, Tienan; Kanazawa, Chikashi; Yamamoto, Yoshinori

Journal of Organic Chemistry, 2005 , vol. 70, # 16 p. 6389 - 6397 Title/Abstract Full Text View citing articles Show Details

123

Synthesize Find similar

Rx-ID: 9234188 Find similar reactions

Synthesize Find similar

63 % Chromat.

With potassium hydroxide; phenone oxime-derived palladacycle; tetrabutylammomium bromide in water; acetone

T=20°C; Suzuki coupling; 7 h;

Botella, Luis; Najera, Carmen

Journal of Organometallic Chemistry, 2002 , vol. 663, # 1-2 p. 46 - 57 Title/Abstract Full Text View citing articles Show Details

82 % Chromat.

With tetrabutylammomium bromide; potassium carbonate; [1-cyclohexyl-3-(di-pyridin-2-yl-methyl)-urea][PdCl2] in water

T=100°C; Suzuki-Miyaura coupling; 8 h;

Najera, Carmen; Gil-Molto, Juan; Karlstroem, Sofia

Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1798 - 1811 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

124

Synthesize Find similar

Rx-ID: 9301182 Find similar reactions

A: 35% B: 15% C: 50%

A: 35% B: 35% C: 50%

With acetic acid; zinc dibromide; zinc; cobalt(II) dibromide in acetonitrile

T=20°C; 3 h;

Gomes, Paulo; Gosmini, Corinne; Perichon, Jacques

Organic Letters, 2003 , vol. 5, # 7 p. 1043 - 1045 Title/Abstract Full Text View citing articles Show Details

Perichon, Jacques; Gosmini, Corinne; Bastienne, Mylene; Gomes, Paulo

Patent: US2004/186328 A1, 2004 ; Location in patent: Page 12-13 ;

Title/Abstract Full Text Show Details

Synthesize Find similar

125

Synthesize Find similar

Rx-ID: 9334418 Find similar reactions

A: 14% B: 38% C: 48%

With manganese; cobalt(II) dibromide; FeBr2 in pyridine; acetonitrile

T=50°C; Hide Experimental Procedure

Perichon, Jacques; Gosmini, Corinne; Bastienne, Mylene; Gomes, Paulo

Patent: US2004/186328 A1, 2004 ; Location in patent: Page 13-14 ; Title/Abstract Full Text Show Details

3:Example 3;Allylation of Aryl Chloride

[0266] Allyl acetate (10 mmol) and aryl chloride (5 mmol) are introduced into a pyridine acetonitrile solution (AN=20 ml/Py=2 ml) that contains manganese dust (50 mmol), cobalt bromide dust (2 mmol), and ferrous bromide dust (5 mmol). The reaction mixture is brought to 50 C. and is stirred until aryl chloride completely disappears (not detectable in gas chromatography).

A: 14 % Chromat. B: 38 %

With pyridine; manganese; FeBr2; cobalt(II) dibromide in acetonitrile

T=50°C; 24 h;

Gomes, Paulo; Gosmini, Corinne; Perichon, Jacques

Organic Letters, 2003 , vol. 5, # 7 p. 1043 - 1045 Title/Abstract Full Text View citing articles Show Details

Chromat. C: 48 % Chromat.

Synthesize Find similar

126

Synthesize Find similar Rx-ID: 9725720 Find similar reactions

A: 34% B: 13%

With vinyl-magnesium chloride; nickel dichloride in tetrahydrofuran

T=25°C; 3 h;

Terao, Jun; Watabe, Hiroyasu; Watanabe, Hiroyuki; Kambe, Nobuaki

Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1674 - 1678 Title/Abstract Full Text View citing articles Show Details

127

Synthesize Find similar

Rx-ID: 9802353 Find similar reactions

90 % Chromat.

Synthesize Find similar

Kayaki, Yoshihito; Koda, Takashi; Ikariya, Takao

European Journal of Organic Chemistry, 2004 , # 24 p. 4989 - 4993 Title/Abstract Full Text View citing articles Show Details

With triphenyl phosphite; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in 1,4-dioxane

T=80°C; Suzuki-Miyaura coupling; 6 h;

128

Synthesize Find similar

Rx-ID: 9802369 Find similar reactions

91 %

Synthesize Find similar

With triphenyl phosphite; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in 1,4-dioxane

Synthesize Find similar

Kayaki, Yoshihito; Koda, Takashi; Ikariya, Takao

Chromat.

European Journal of Organic Chemistry, 2004 , # 24 p. 4989 - 4993 Title/Abstract Full Text View citing articles Show Details

T=80°C; Suzuki-Miyaura coupling; 6 h;

129

Synthesize Find similar

Rx-ID: 9802392 Find similar reactions

58 % Chromat.

Synthesize Find similar

Kayaki, Yoshihito; Koda, Takashi; Ikariya, Takao

European Journal of Organic Chemistry, 2004 , # 24 p. 4989 - 4993 Title/Abstract Full Text View citing articles Show Details

With triphenyl phosphite; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in 1,4-dioxane

T=80°C; Suzuki-Miyaura coupling; 6 h;

130

Synthesize Find similar

Rx-ID: 9802417 Find similar reactions

88 % Chromat.

Synthesize Find similar

Kayaki, Yoshihito; Koda, Takashi; Ikariya, Takao

European Journal of Organic Chemistry, 2004 , # 24 p. 4989 - 4993 Title/Abstract Full Text View citing articles Show Details

With triphenyl phosphite; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in 1,4-dioxane

T=80°C; Suzuki-Miyaura coupling; 6 h;

131

Synthesize Find similar

Rx-ID: 9819999 Find similar reactions

51 % Chromat.

Synthesize Find similar

With tetrabutylammomium bromide; potassium carbonate; [1-cyclohexyl-3-(di-pyridin-2-yl-methyl)-urea][PdCl2] in water

T=100°C; Suzuki-Miyaura coupling; 2 h;

Najera, Carmen; Gil-Molto, Juan; Karlstroem, Sofia

Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1798 - 1811 Title/Abstract Full Text View citing articles Show Details

132

Synthesize Find similar

Rx-ID: 9845520 Find similar reactions

With air

T=850°C; 0.0277778 h; Formation of xenobiotics;

Font, Rafael; Aracil, Ignacio; Fullana, Andres; Conesa, Juan A.

Chemosphere, 2004 , vol. 57, # 7 p. 615 - 627 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

133

Synthesize Find similar Rx-ID: 10016616 Find similar reactions

Koverzanova; Usachev; Shilkina; Lomakin; Gumargalieva; Zaikov

Russian Journal of Applied Chemistry, 2004 , vol. 77, # 3 p. 445 - 448 Title/Abstract Full Text View citing articles Show Details

T=700°C; Product distribution; Further Variations:Temperatures;

Synthesize Find similar

134

Synthesize Find similar Rx-ID: 9209401 Find similar reactions

A: 5% B: 81%

Irradiation;

Synthesize Find similar

Milanesi, Silvia; Fagnoni, Maurizio; Albini, Angelo

Chemical Communications, 2003 , # 2 p. 216 - 217 Title/Abstract Full Text View citing articles Show Details

A: 47% B: 5%

With xanthone powder

Irradiation;

Milanesi, Silvia; Fagnoni, Maurizio; Albini, Angelo

Chemical Communications, 2003 , # 2 p. 216 - 217 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

135

Synthesize Find similar

Rx-ID: 9303667 Find similar reactions

Stage #1: iodobenzene With chloro-trimethyl-silane; zinc in diethylene glycol dimethyl ether

T=130°C; 24 h; Stage #2: Allyl acetate With bis(dibenzylideneacetone)-palladium(0) in diethylene glycol dimethyl ether

T=20°C; 6 h;

Ikegami, Ryo; Koresawa, Akiko; Shibata, Takanori; Takagi, Kentaro

Journal of Organic Chemistry, 2003 , vol. 68, # 6 p. 2195 - 2199 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

136

Synthesize Find similar Rx-ID: 9313384 Find similar reactions

A: 27 % Chromat. B: 1 % Chromat. C: 5 % Chromat. D: 49 % Chromat.

137

With nickel-salen complex; water; [Me4N][BF4] in N,N-dimethyl-formamide

UV-irradiation; Title compound not separated from byproducts;

Vanalabhpatana, Parichatr; Peters, Dennis G.

Tetrahedron Letters, 2003 , vol. 44, # 16 p. 3245 - 3247 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 9337418 Find similar reactions

Synthesize Find similar

Stage #1: iodobenzene With chloro-trimethyl-silane; zinc in diethylene glycol dimethyl ether

T=130°C; 24 h; Stage #2: 3-chloroprop-1-ene With bis(dibenzylideneacetone)-palladium(0) in diethylene glycol dimethyl ether

T=0°C; 0.0833333 h;

Ikegami, Ryo; Koresawa, Akiko; Shibata, Takanori; Takagi, Kentaro

Journal of Organic Chemistry, 2003 , vol. 68, # 6 p. 2195 - 2199 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

138

Synthesize Find similar Rx-ID: 9350266 Find similar reactions

Timokhin, Vitaliy I.; Gastaldi, Stephane; Bertrand, Michele P.; Chatgilialoglu, Chryssostomos

Journal of Organic Chemistry, 2003 , vol. 68, # 9 p. 3532 - 3537 Title/Abstract Full Text View citing articles Show Details

With C6HMe5

T=19.85°C; Kinetics;

139

Synthesize Find similar

Rx-ID: 9383487 Find similar reactions

93%

Synthesize Find similar

With bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran

T=60°C; 12 h;

140

Synthesize Find similar

Schumann, Herbert; Kaufmann, Jens; Schmalz, Hans-Guenther; Boettcher, Andreas; Gotov, Battsengel

Synlett, 2003 , # 12 p. 1783 - 1788 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 9443988 Find similar reactions

Synthesize Find similar

Reid, Simon J.; Baird, Michael C.

Journal of the Chemical Society. Dalton Transactions, 2003 , # 20 p. 3975 - 3980 Title/Abstract Full Text View citing articles Show Details

in xylene

2 h; Heating;

141

Synthesize Find similar

Rx-ID: 9464184 Find similar reactions

67%

Synthesize Find similar

With [PdBr(N-succinimidyl)(PPh3)2] in toluene

T=60°C; Stille reaction; 24 h;

Crawforth, Catherine M.; Burling, Suzanne; Fairlamb, Ian J. S.; Taylor, Richard J. K.; Whitwood, Adrian C.

Chemical Communications, 2003 , # 17 p. 2194 - 2195 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

142

Synthesize Find similar Rx-ID: 9483205 Find similar reactions

T=400°C; Pyrolysis; Thermodynamic dataKinetics; Further Variations:TemperaturesPressures;

Chuchani, Gabriel; Marquez, Edgar; Herize, Armando; Dominguez, Rosa Maria; Tosta, Maria; Brusco, Doris

Journal of Physical Organic Chemistry, 2003 , vol. 16, # 11 p. 839 - 848 Title/Abstract Full Text View citing articles Show Details

143

Synthesize Find similar

Rx-ID: 1250954 Find similar reactions

With potassium tert-butylate

Kinetics;

Oae,S.; Yano,Y.

Tetrahedron, 1968 , vol. 24, p. 5721 - 5729 Full Text View citing articles Show Details

T=419.4 - 480.6°C; activation energy; gas-phase pyrolysis; KineticsThermodynamic data;

Chuchani, Gabriel; Rotinov, Alexandra; Martin, Ignacio

Journal of Physical Chemistry, 1985 , vol. 89, # 3 p. 551 - 552 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 45 percent Chromat. / Mg / 600 °C / 0.01 - 0.1 Torr 2: 14 percent Chromat. / Mg / 600 °C / 0.01 - 0.1 Torr View Scheme

Aitken, R. Alan; Hodgson, Philip K.G.; Morrison, John J.; Oyewale, Adebayo O.

Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 402 - 415 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

144

Synthesize Find similar Rx-ID: 9003974 Find similar reactions

A: 18 % Chromat. B: 40 % Chromat. C: 19 % Chromat. D: 14 % Chromat.

With magnesium

T=600°C; P=0.01 - 0.1 Torr; Further byproducts. Title compound not separated from byproducts.;

145

Aitken, R. Alan; Hodgson, Philip K.G.; Morrison, John J.; Oyewale, Adebayo O.

Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 402 - 415 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 9005685 Find similar reactions

A: 21 % Chromat. B: 41 % Chromat. C: 15 % Chromat. D: 6 % Chromat.

Synthesize Find similar

With magnesium

T=600°C; P=0.01 - 0.1 Torr; Further byproducts. Title compound not separated from byproducts.;

Synthesize Find similar

Aitken, R. Alan; Hodgson, Philip K.G.; Morrison, John J.; Oyewale, Adebayo O.

Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 402 - 415 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

146

Synthesize Find similar Rx-ID: 9019200 Find similar reactions

A: 26 % Chromat. B: 45 % Chromat. C: 20 % Chromat. D: 2 % Chromat.

With magnesium

T=600°C; P=0.01 - 0.1 Torr; Further byproducts. Title compound not separated from byproducts.;

Aitken, R. Alan; Hodgson, Philip K.G.; Morrison, John J.; Oyewale, Adebayo O.

Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 402 - 415 Title/Abstract Full Text View citing articles Show Details

Synthesize

147

Synthesize Find similar

Rx-ID: 9246220 Find similar reactions

Find similar

Stage #1: With bis(cyclopentadienyl)titanium dichloride; ethylaluminum dichloride; magnesium in tetrahydrofuran

T=0 - 20°C; Stage #2: With hydrogenchloride in tetrahydrofuran

Find similar

Ibragimov; Khafizova; Gil'fanova; Dzhemilev

Russian Chemical Bulletin, 2002 , vol. 51, # 12 p. 2255 - 2260 Title/Abstract Full Text View citing articles Show Details

148

Synthesize Find similar

Rx-ID: 14875608 Find similar reactions

Multi-step reaction with 2 steps 1: 70 percent / PBr3 / 18 h / ice cooling 2: 18 percent Chromat. / Mg / 600 °C / 0.01 - 0.1 Torr View Scheme

Aitken, R. Alan; Hodgson, Philip K.G.; Morrison, John J.; Oyewale, Adebayo O.

Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 402 - 415 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: 70 percent / PBr3 / 18 h / ice cooling 2: 40 percent Chromat. / Mg / 600 °C / 0.01 - 0.1 Torr 3: 14 percent Chromat. / Mg / 600 °C / 0.01 - 0.1 Torr View Scheme

Aitken, R. Alan; Hodgson, Philip K.G.; Morrison, John J.; Oyewale, Adebayo O.

Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 402 - 415 Title/Abstract Full Text View citing articles Show Details

149

Synthesize Find similar

150

Multi-step reaction with 2 steps 1: 40 percent Chromat. / Mg / 600 °C / 0.01 - 0.1 Torr 2: 14 percent Chromat. / Mg / 600 °C / 0.01 - 0.1 Torr View Scheme

Synthesize Find similar

Rx-ID: 14880372 Find similar reactions

Aitken, R. Alan; Hodgson, Philip K.G.; Morrison, John J.; Oyewale, Adebayo O.

Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 402 - 415 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 14886282 Find similar reactions

Multi-step reaction with 2 steps 1: 12 percent Spectr. / Mg / 600 °C / 0.01 - 0.1 Torr 2: 14 percent Chromat. / Mg / 600 °C / 0.01 - 0.1 Torr View Scheme

Aitken, R. Alan; Hodgson, Philip K.G.; Morrison, John J.; Oyewale, Adebayo O.

Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 402 - 415 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

151

Synthesize Find similar Rx-ID: 8766044 Find similar reactions

Chuchani, Gabriel; Nunnez, Oswaldo; Marcano, Norka; Napolitano, Suvighey; Rodriguez, Henry; Dominguez, Marianella; Ascanio, Judany; Rotinov, Alexandra; Dominguez, Rosa M.; Herize, Armando

Journal of Physical Organic Chemistry, 2001 , vol. 14, # 3 p. 146 - 158 Title/Abstract Full Text View citing articles Show Details

T=340.5 - 400.6°C; Kinetics;

152

Synthesize Find similar

Rx-ID: 8877069 Find similar reactions

With triethylamine; 1H-2,3-diketo-5-chloro-7,8-dimethoxypyrido[4,3,2-de]quinoline in tetrahydrofuran

T=20°C; 10 h;

Shao, Huawu; Ding, Qizhu; Lown, J. William

Heterocyclic Communications, 2001 , vol. 7, # 2 p. 107 - 112 Title/Abstract Full Text View citing articles Show Details

153

Synthesize Find similar

Rx-ID: 8883758 Find similar reactions

94%

Synthesize Find similar

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran

1 h; Heating;

Perez; Sestelo; Sarandeses

Journal of the American Chemical Society, 2001 , vol. 123, # 18 p. 4155 - 4160 Title/Abstract Full Text View citing articles Show Details

154

Synthesize Find similar

Rx-ID: 8970508 Find similar reactions

With gallium(III) chloride; 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene

T=17°C; UV-irradiation;

Ericsson, Cecilia; Engman, Lars

Organic Letters, 2001 , vol. 3, # 22 p. 3459 - 3462 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

155

Synthesize Find similar Rx-ID: 8989203 Find similar reactions

Kondo, Hideo; Kageyama, Akira; Yamaguchi, Yoshitaka; Haga, Masa-Aki; Kirchner, Karl; Nagashima, Hideo

Bulletin of the Chemical Society of Japan, 2001 , vol. 74, # 10 p. 1927 - 1937 Title/Abstract Full Text View citing articles Show Details

in tetrahydrofuran; diethyl ether

T=0°C; 1 h; Title compound not separated from byproducts;

156

Synthesize Find similar Rx-ID: 9006135 Find similar reactions

Synthesize Find similar

Cubbage; Guo; McCulla; Jenks

Journal of Organic Chemistry, 2001 , vol. 66, # 26 p. 8722 - 8736 Title/Abstract Full Text View citing articles Show Details

in acetonitrile

T=240°C; Kinetics; Further Variations:Temperatures;

Synthesize Find similar

157

Synthesize Find similar Rx-ID: 9033604 Find similar reactions

Cubbage; Guo; McCulla; Jenks

Journal of Organic Chemistry, 2001 , vol. 66, # 26 p. 8722 - 8736 Title/Abstract Full Text View citing articles Show Details

in acetonitrile

T=225°C; Kinetics; Further Variations:Temperatures;

Synthesize Find similar

158

Synthesize Find similar

Rx-ID: 11012162 Find similar reactions

With [2,2']bipyridinyl in acetic acid

T=80°C; 24 h; Product distribution; Further Variations:ReagentsTemperatures;

Zhang; Lu; Han

Journal of Organic Chemistry, 2001 , vol. 66, # 23 p. 7676 - 7684 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

159

Synthesize Find similar Rx-ID: 8558238 Find similar reactions

Cubbage, Jerry W.; Vos, Brian W.; Jenks, William S.

Journal of the American Chemical Society, 2000 , vol. 122, # 20 p. 4968 - 4971 Title/Abstract Full Text View citing articles Show Details

T=490 - 550°C; Elimination; Activation energyThermodynamic data;

Synthesize Find similar

160

Synthesize Find similar

Rx-ID: 8610883 Find similar reactions

A: 21 % Chromat. B: 6 % Chromat. C: 72 % Chromat.

With [Pt(dba)2]; triphenyl-arsane; triethylamine in toluene

T=50°C; borylation; 16 h; Product distribution; Further Variations:ReagentsSolvents;

Murata, Miki; Watanabe, Shinji; Masuda, Yuzuru

Tetrahedron Letters, 2000 , vol. 41, # 31 p. 5877 - 5880 Title/Abstract Full Text View citing articles Show Details

161

Synthesize Find similar

With triphenylphosphine in benzene

T=5°C; Demetallation; Photolysis;

Rx-ID: 8664234 Find similar reactions

Reid; Freeman; Baird

Chemical Communications, 2000 , # 18 p. 1777 - 1778 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

162

Rx-ID: 8664235 Find similar reactions

With triphenylphosphine in benzene

T=25°C; Demetallation; Photolysis;

Reid; Freeman; Baird

Chemical Communications, 2000 , # 18 p. 1777 - 1778 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

163

Synthesize Find similar Rx-ID: 8664248 Find similar reactions

With triphenylphosphine in benzene

T=60°C; Substitution; Isomerization; Title compound not separated from byproducts.;

Reid; Freeman; Baird

Chemical Communications, 2000 , # 18 p. 1777 - 1778 Title/Abstract Full Text View citing articles Show Details

164

Synthesize Find similar

84%

Synthesize Find similar

Rx-ID: 8713419 Find similar reactions

With sodium tetrahydroborate; (CF3(CF2)5C6H4Se)2 in tetrahydrofuran; ethanol

Elimination; Heating;

Crich, David; Neelamkavil, Santhosh; Sartillo-Piscil, Fernando

Organic Letters, 2000 , vol. 2, # 25 p. 4029 - 4030 Title/Abstract Full Text View citing articles Show Details

165

Synthesize Find similar

Rx-ID: 8734924 Find similar reactions

A: 13 % Chromat. B: 10 % Chromat. C: 28 % Chromat.

Synthesize Find similar

Jeffery

Tetrahedron Letters, 2000 , vol. 41, # 44 p. 8445 - 8449 Title/Abstract Full Text View citing articles Show Details

With tetrabutyl-ammonium chloride; N-ethyl-N,N-diisopropylamine; bis(dibenzylideneacetone)-palladium(0) in acetonitrile

T=20°C; Heck-type reaction; 21 h;

Synthesize Find similar

166

Synthesize Find similar

Rx-ID: 8734925 Find similar reactions

A: 80%

With 4 A molecular sieve; tetrabutylammonium acetate; triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide

T=50°C; Heck-type reaction; 24 h;

Jeffery

Tetrahedron Letters, 2000 , vol. 41, # 44 p. 8445 - 8449 Title/Abstract Full Text View citing articles Show Details

167

Synthesize Find similar

89%

Synthesize Find similar

With hydrogen sulfide; triphenylphosphine; methyltrioxorhenium (VII) in acetonitrile-D3

4 h; Ambient temperature;

Rx-ID: 5139392 Find similar reactions

Jacob, Josemon; Espenson, James H.

Chemical Communications, 1999 , # 11 p. 1003 - 1004 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

168

Synthesize Find similar Rx-ID: 5142969 Find similar reactions

in gas T=450.1 - 490.6°C; P=65 - 198 Torr; pyrolysis in static system; Ea, log A, ΔH(act.), ΔS(act.); kinetic and mechanism of gas phase elimination of primary, secondary and tertiary 2-hydroxyalkylbenzenes; stoichiometry; effect of inhibitor toluene; Rate constantThermodynamic dataProduct distribution; A

Synthesize Find similar

Chuchani, Gabriel; Rotinov, Alexandra; Dominguez, Rosa M.

International Journal of Chemical Kinetics, 1999 , vol. 31, # 6 p. 401 - 407 Title/Abstract Full Text View citing articles Show Details

169

Synthesize Find similar

Rx-ID: 5264475 Find similar reactions

A: 26% B: 61%

With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in dichloromethane

T=50°C; Alkylation; 8 h;

Synthesize Find similar

Komatsu, Yuzo; Sakamoto, Toru; Kitazume, Tomoya

Journal of Organic Chemistry, 1999 , vol. 64, # 22 p. 8369 - 8374 Title/Abstract Full Text View citing articles Show Details

170

Synthesize Find similar Rx-ID: 1989156 Find similar reactions

A: 0.6 % Chromat. B: 87.3%

With N-propyl-1,4-dihydronicotinamide; lithium perchlorate; RhCl(PPh3)3 in acetonitrile

T=70°C; 17 h; var. cat. solv. and addendum;

Nakamura, Kaoru; Ohno, Atsuyoshi; Oka, Shinzaburo

Tetrahedron Letters, 1983 , vol. 24, # 32 p. 3335 - 3336 Title/Abstract Full Text View citing articles Show Details

A: 30.8 % Chromat. B: 15.4 % Chromat.

With N-propyl-1,4-dihydronicotinamide; lithium perchlorate; tetrakis(triphenylphosphine) palladium(0) in acetonitrile

T=70°C; 17 h; var. cat., solv. and addendum;

Nakamura, Kaoru; Ohno, Atsuyoshi; Oka, Shinzaburo

Tetrahedron Letters, 1983 , vol. 24, # 32 p. 3335 - 3336 Title/Abstract Full Text View citing articles Show Details

With samarium diiodide; isopropyl alcohol; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

1 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Tabuchi, Takanori; Inanaga, Junji; Yamaguchi, Masaru

Tetrahedron Letters, 1986 , vol. 27, # 5 p. 601 - 602 Title/Abstract Full Text View citing articles Show Details

Hide Details

A: 25 % Chromat. B: 50 % Chromat.

With polymethylhydrosiloxane; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

24 h; Ambient temperature;

Keinan, Ehud; Greenspoon, Noam

Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3545 - 3548 Title/Abstract Full Text View citing articles Show Details

A: 25 % Chromat. B: 50 % Chromat.

With polymethylhydrosiloxane; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

24 h; Ambient temperature;

Keinan, Ehud; Greenspoon, Noam

Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3545 - 3548 Title/Abstract Full Text View citing articles Show Details

With samarium diiodide; isopropyl alcohol; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

1 h; Ambient temperaturevarious allylic acetates, other catalysts; Product distribution;

Tabuchi, Takanori; Inanaga, Junji; Yamaguchi, Masaru

Tetrahedron Letters, 1986 , vol. 27, # 5 p. 601 - 602 Title/Abstract Full Text View citing articles Show Details

A: 25 % Chromat. B: 50 % Chromat.

With polymethylhydrosiloxane; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

24 h; Ambient temperaturepresence of cinnamaldehyde; influence of cinnamoyl chloride; Product distribution;

Keinan, Ehud; Greenspoon, Noam

Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3545 - 3548 Title/Abstract Full Text View citing articles Show Details

With tetrakis(triphenylphosphine) palladium(0); 1,1,3,3-tetramethyldisiloxane in benzene-d6

0.4 h; other palladium complexes; other Lewis acids; other solvents; unsaturated carbohydrates; Product distribution;

Greenspoon, Noam; Keinan, Ehud

Journal of Organic Chemistry, 1988 , vol. 53, # 16 p. 3723 - 3731 Title/Abstract Full Text View citing articles Show Details

With samarium diiodide; water; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

2 h; Ambient temperatureother reag.; Product distribution;

Yoshida, Akihiro; Hanamoto, Takeshi; Inanaga, Junji; Mikami, Koichi

Tetrahedron Letters, 1998 , vol. 39, # 13 p. 1777 - 1780 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

171

Synthesize Find similar Rx-ID: 4683251 Find similar reactions

With Ru(CO)12 in xylene

T=139°C; 24 h; var. cat.: Pd(dbc)3CHCl3*4PPh3; Product distribution;

Shimizu, Isao; Sakamoto, Toshiaki; Kawaragi, Saeko; Maruyama, Yooichiro; Yamamoto, Akio

Chemistry Letters, 1997 , # 2 p. 137 - 138 Title/Abstract Full Text View citing articles Show Details

With samarium diiodide; water; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

1 h; Ambient temperatureother reag.; Product distribution;

Yoshida, Akihiro; Hanamoto, Takeshi; Inanaga, Junji; Mikami, Koichi

Tetrahedron Letters, 1998 , vol. 39, # 13 p. 1777 - 1780 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

172

Synthesize Find similar Rx-ID: 4897136 Find similar reactions

A: 5 % Chromat. C: 9 % Chromat. E: 6 % Chromat. F: 7 % Chromat.

Aitken, R. Alan; Mesher, Shaun T. E.

Journal of Chemical Research, Miniprint, 1998 , # 2 p. 564 - 579 Title/Abstract Full Text Show Details

T=600°C; P=0.001 Torr; var. chiral thiazolidine 1,1-dioxides, other temp.; Product distributionMechanism;

Synthesize Find similar

173

Synthesize Find similar Rx-ID: 4942484 Find similar reactions

Yoshida, Akihiro; Hanamoto, Takeshi; Inanaga, Junji; Mikami, Koichi

Tetrahedron Letters, 1998 , vol. 39, # 13 p. 1777 - 1780 Title/Abstract Full Text View citing articles Show Details

With samarium diiodide; water; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

2 h; Ambient temperatureother reag., other reaction time; Product distribution;

Synthesize Find similar

174

Synthesize Find similar Rx-ID: 4979335

Find similar reactions

B: 89%

With chloro-trimethyl-silane; 3 A molecular sieve; sodium cyanoborohydride in acetonitrile

24 h; Ambient temperature;

Box, Vernon G.S.; Meleties, Panayiotis C.

Tetrahedron Letters, 1998 , vol. 39, # 39 p. 7059 - 7062 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

175

Synthesize Find similar Rx-ID: 5008050 Find similar reactions

With titanium(IV) isopropylate; hydrogenchloride; isopropylmagnesium chloride

1.) ether, -50 deg C to -40 deg C; 2.) -78 deg C to 0 deg C; Yield given. Multistep reaction. Yields of byproduct given;

Matsuda, Shin-Ichiro; An, Duk Keun; Okamoto, Sentaro; Sato, Fumie

Tetrahedron Letters, 1998 , vol. 39, # 41 p. 7513 - 7516 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

176

Synthesize Find similar Rx-ID: 5093153 Find similar reactions

A: 19.3 % Chromat. B: 21.7 % Chromat. C: 6.2 % Chromat. D: 34 % Chromat.

With water; RuCl2(C6H6)(PPh2(C6F5))

12 h; Further byproducts given. Title compound not separated from byproducts;

Tokunaga, Makoto; Wakatsuki, Yasuo

Angewandte Chemie - International Edition, 1998 , vol. 37, # 20 p. 2867 - 2869 Title/Abstract Full Text View citing articles Show Details

A: 19.3 % Chromat. B: 21.7 % Chromat. C: 6.2 % Chromat. D: 34 % Chromat.

With water; RuCl2(C6H6)(PPh2(C6F5))

12 h; Further byproducts given. Title compound not separated from byproducts;

Tokunaga, Makoto; Wakatsuki, Yasuo

Angewandte Chemie - International Edition, 1998 , vol. 37, # 20 p. 2867 - 2869 Title/Abstract Full Text View citing articles Show Details

With water; lt;RuCl2(C6H6)gt;lt;PPh2(C6F5)gt;; diphenyl(pentafluorophenyl)phosphine in isopropyl alcohol

T=70°C; 12 h; another catalyst, temperatures, time and solvent; Product distribution;

Tokunaga, Makoto; Wakatsuki, Yasuo

Angewandte Chemie - International Edition, 1998 , vol. 37, # 20 p. 2867 - 2869 Title/Abstract Full Text View citing articles Show Details

177

Synthesize Find similar

Rx-ID: 5105120 Find similar reactions

Synthesize Find similar

With cerium(III) chloride; lithium hydride

1.) THF, 0 deg C, 1 h, 2.) THF, -78 deg C to -20 deg C, 18 h; Yield givenMultistep reaction;

Dalpozzo, Renato; De Nino, Antonio; Tagarelli, Antonio; Bartoli, Giuseppe; Bellucci, M. Cristina; Bosco, Marcella; Sambri, Letizia

Journal of Organic Chemistry, 1998 , vol. 63, # 25 p. 9559 - 9560 Title/Abstract Full Text View citing articles Show Details

178

Synthesize Find similar

Rx-ID: 693582 Find similar reactions

With hydrogen fluoride

With iron(III) chloride

With aluminium trichloride

T=20 - 25°C;

Synthesize Find similar

Simons; Archer

Journal of the American Chemical Society, 1939 , vol. 61, p. 1521 Full Text View citing articles Show Details

Nasarowa; Zukerwanik

Zhurnal Obshchei Khimii, 1944 , vol. 14, p. 77,78 Chem.Abstr., 1945 , p. 916 Full Text View citing articles Show Details

Huston; Sager

Journal of the American Chemical Society, 1926 , vol. 48, p. 1957 Full Text View citing articles Show Details

Hide Details

With boron trifluoride

48 % Chromat.

With scandium tris(trifluoromethanesulfonate)

T=115 - 120°C; 8 h;

McKenna; Sowa

Journal of the American Chemical Society, 1937 , vol. 59, p. 470 Full Text View citing articles Show Details

Tsuchimoto, Teruhisa; Tobita, Kazuo; Hiyama, Tamejiro; Fukuzawa, Shin-Ichi

Journal of Organic Chemistry, 1997 , vol. 62, # 20 p. 6997 - 7005 Title/Abstract Full Text View citing articles Show Details

179

Synthesize Find similar

Rx-ID: 3325534 Find similar reactions

Synthesize Find similar

76%

With sodium hydroxide; palladium dichloride in water

T=100°C; 3 h; other reaction time, temperature; Product distribution;

Bumagin; Bykov

Russian Journal of General Chemistry, 1996 , vol. 66, # 12 p. 1925 - 1938 Title/Abstract Full Text View citing articles Show Details

76%

With sodium carbonate; palladium dichloride in water

T=100°C;

Bumagin, Nikolai A.; Bykov, Victor V.

Tetrahedron, 1997 , vol. 53, # 42 p. 14437 - 14450 Title/Abstract Full Text View citing articles Show Details

31 % Chromat.

With palladium diacetate; sodium acetate in acetic acid

T=25°C; 20 h;

Cho, Chan Sik; Uemura, Sakae

Journal of Organometallic Chemistry, 1994 , vol. 465, # 1-2 p. 85 - 92 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

180

Synthesize Find similar Rx-ID: 4643183 Find similar reactions

Aitken, R. Alan; Armstrong, David P.; Galt, Ronald H. B.; Mesher, Shaun T. E.

Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 6 p. 935 - 943 Title/Abstract Full Text View citing articles Show Details

T=600°C; P=0.004 Torr; Yield given. Yields of byproduct given;

181

Synthesize

Find similar Rx-ID: 4784440 Find similar reactions

94 % Chromat.

Find similar

With Pb3BrF5

T=60°C; 2 h;

Ichihara, Junko

Chemical Communications, 1997 , # 19 p. 1921 - 1922 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

182

Synthesize Find similar Rx-ID: 4788862 Find similar reactions

A: 18% B: 8% C: 15% D: 7% E: 12% F: 5%

Aitken, R. Alan; Armstrong, David P.; Galt, Ronald H. B.; Mesher, Shaun T. E.

Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 14 p. 2139 - 2145 Title/Abstract Full Text View citing articles Show Details

T=650°C; P=0.001 - 0.002 Torr; 2.77778E-06 h; other products of flash vacuum pyrolysis; Product distribution;

Synthesize Find similar

183

Synthesize Find similar Rx-ID: 8493572 Find similar reactions

A: 22 % Chromat. B: 17 % Chromat. C: 6 % Chromat. D: 7 % Chromat. E: 6 % Chromat. F: 51 % Chromat.

in tert-butyl alcohol

Irradiationphotolysis of alkyl aryl sulfoxides; homolytic cleavage; possible reaction pathways; proposed mechanism; thermal degradation (t-BuOH, 80 deg C); comparison of olefinic products from photolysis and thermolysis; regioselectivity of alkene products; Product distributionQuantum yield;

Guo, Yushen; Jenks, William S.

Journal of Organic Chemistry, 1997 , vol. 62, # 4 p. 857 - 864 Title/Abstract Full Text View citing articles Show Details

184

Synthesize Find similar Rx-ID: 8515919 Find similar reactions

A: 12 % Chromat. B: 4 % Chromat. C: 34 % Chromat. D: 18 % Chromat. E: 15 % Chromat. F: 22 % Chromat.

Synthesize Find similar

in tert-butyl alcohol

Irradiationother solvents (MeCN, acetone); photolysis of alkyl aryl sulfoxides; quantum yield for disappearance of starting material; homolytic cleavage; possible reaction pathways; racemization; proposed mechanism; Product distributionQuantum yield;

Synthesize Find similar

Guo, Yushen; Jenks, William S.

Journal of Organic Chemistry, 1997 , vol. 62, # 4 p. 857 - 864 Title/Abstract Full Text View citing articles Show Details

185

Synthesize Find similar

Rx-ID: 17375667 Find similar reactions

Multi-step reaction with 3 steps 1: 86 percent / P2S5 / CH2Cl2 / 40 h / Heating 2: 93 percent / PhCO2H, aq. KMnO4, benzyltriethylammonium chloride / CH2Cl2 / 15 h / Ambient temperature 3: 600 °C / 0 Torr View Scheme

186

Synthesize Find similar

Rx-ID: 17375810 Find similar reactions

Aitken, R. Alan; Armstrong, David P.; Galt, Ronald H. B.; Mesher, Shaun T. E.

Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 6 p. 935 - 943 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Multi-step reaction with 4 steps 1: 83 percent / NEt3 / CH2Cl2 / 20 h / Ambient temperature 2: 86 percent / P2S5 / CH2Cl2 / 40 h / Heating 3: 93 percent / PhCO2H, aq. KMnO4, benzyltriethylammonium chloride / CH2Cl2 / 15 h / Ambient temperature 4: 600 °C / 0 Torr View Scheme

Aitken, R. Alan; Armstrong, David P.; Galt, Ronald H. B.; Mesher, Shaun T. E.

Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 6 p. 935 - 943 Title/Abstract Full Text View citing articles Show Details

187

Synthesize Find similar

Rx-ID: 17387249 Find similar reactions

Multi-step reaction with 2 steps 1: 93 percent / PhCO2H, aq. KMnO4, benzyltriethylammonium chloride / CH2Cl2 / 15 h / Ambient temperature 2: 600 °C / 0 Torr View Scheme

Aitken, R. Alan; Armstrong, David P.; Galt, Ronald H. B.; Mesher, Shaun T. E.

Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 6 p. 935 - 943 Title/Abstract Full Text View citing articles Show Details

188

Synthesize Find similar

Rx-ID: 4529584 Find similar reactions

92%

in various solvent(s) 0.0166667 h; Irradiation;

Matloubi Moghaddam, Firouz; Ghaffarzadeh, Mohammad

Tetrahedron Letters, 1996 , vol. 37, # 11 p. 1855 - 1858 Title/Abstract Full Text View citing articles Show Details

92%

in various solvent(s) 0.0166667 h; Irradiationother sulfoxides, thermal elimination; Product distribution;

Matloubi Moghaddam, Firouz; Ghaffarzadeh, Mohammad

Tetrahedron Letters, 1996 , vol. 37, # 11 p. 1855 - 1858 Title/Abstract Full Text View citing articles Show Details

189

Synthesize

Rx-ID: 4537916

Find similar

90%

Find similar

Find similar reactions

Matloubi Moghaddam, Firouz; Ghaffarzadeh, Mohammad

Tetrahedron Letters, 1996 , vol. 37, # 11 p. 1855 - 1858 Title/Abstract Full Text View citing articles Show Details

in various solvent(s) 0.0166667 h; Irradiation;

Synthesize Find similar

190

Synthesize Find similar Rx-ID: 4540261 Find similar reactions

With formic acid; Pd/Pb/C in ethanol; benzene

0.25 h; Heatingvarious catalysts; Product distribution;

Cristiano, M. Lurdes S.; Johnstone, Robert A. W.; Price, Peter J.

Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 12 p. 1453 - 1459 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

191

Synthesize Find similar

Rx-ID: 4766072 Find similar reactions

A: 42 % Chromat. B: 40 % Chromat.

Fujiwara, Masahiro; Tanaka, Mutsuo; Baba, Akio; Ando, Hisanori; Souma, Yoshie

Journal of Organometallic Chemistry, 1996 , vol. 525, # 1-2 p. 39 - 42 Title/Abstract Full Text View citing articles Show Details

With tetrakis(triphenylphosphine) palladium(0) in acetonitrile

T=80°C; 24 h;

Synthesize

192

Synthesize Find similar

Find similar

Rx-ID: 4767865 Find similar reactions

A: 33 % Chromat. B: 63 % Chromat.

Find similar

Fujiwara, Masahiro; Tanaka, Mutsuo; Baba, Akio; Ando, Hisanori; Souma, Yoshie

Journal of Organometallic Chemistry, 1996 , vol. 525, # 1-2 p. 39 - 42 Title/Abstract Full Text View citing articles Show Details

With tetrakis(triphenylphosphine) palladium(0) in acetonitrile

T=80°C; 24 h;

193

Synthesize Find similar

Rx-ID: 4784319 Find similar reactions

91 % Chromat.

Synthesize Find similar

Fujiwara, Masahiro; Tanaka, Mutsuo; Baba, Akio; Ando, Hisanori; Souma, Yoshie

Journal of Organometallic Chemistry, 1996 , vol. 525, # 1-2 p. 39 - 42 Title/Abstract Full Text View citing articles Show Details

in acetonitrile

T=60°C; 24 h;

Synthesize Find similar

194

Synthesize Find similar

Rx-ID: 4787523 Find similar reactions

A: 85 % Chromat. B: 13%

Fujiwara, Masahiro; Tanaka, Mutsuo; Baba, Akio; Ando, Hisanori; Souma, Yoshie

Journal of Organometallic Chemistry, 1996 , vol. 525, # 1-2 p. 39 - 42 Title/Abstract Full Text View citing articles Show Details

in acetonitrile

T=40°C; 24 h;

195

Synthesize

Find similar Rx-ID: 4834802 Find similar reactions

88%

Find similar

Gai, Yonghua; Julia, Marc; Jean-Noe; Verpeaux

Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 9 p. 805 - 816 Title/Abstract Full Text View citing articles Show Details

With Fe(C6H5COCHCOC6H5)3 in tetrahydrofuran

T=10°C; 20 h;

Synthesize Find similar

196

Synthesize Find similar

Rx-ID: 4834803 Find similar reactions

With bis(acetylacetonate)nickel(II) in tetrahydrofuran

T=10°C; 20 h; Yield given. Yields of byproduct given;

Gai, Yonghua; Julia, Marc; Jean-Noe; Verpeaux

Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 9 p. 805 - 816 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

197

Synthesize Find similar

Rx-ID: 4834809 Find similar reactions

Gai, Yonghua; Julia, Marc; Jean-Noe; Verpeaux

Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 9 p. 805 - 816 Title/Abstract Full Text View citing articles Show Details

With Fe(C6H5COCHCOC6H5)3 in tetrahydrofuran

T=10°C; 20 h; Yield given. Yields of byproduct given;

198

Synthesize

Find similar Rx-ID: 4834810 Find similar reactions

With iron (III) acetylacetonate in tetrahydrofuran

T=10°C; 20 h; Yield given. Yields of byproduct given;

Find similar

Synthesize Find similar

Gai, Yonghua; Julia, Marc; Jean-Noe; Verpeaux

Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 9 p. 805 - 816 Title/Abstract Full Text View citing articles Show Details