Hydrogen cyanide (Hydrocyanic acid; HCN)

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Reactions (1913)

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Substances (4)

Citations (2399)

Conditions

References A

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Sacks, Gavin L.; Brenna, J. Thomas

Analytical Chemistry, 2003 , vol. 75, # 20 p. 5495 - 5503 Title/Abstract Full Text View citing articles Show Details

T=780°C; Product distribution; Further Variations:Temperatures;

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Sacks, Gavin L.; Brenna, J. Thomas

Analytical Chemistry, 2003 , vol. 75, # 20 p. 5495 - 5503 Title/Abstract Full Text View citing articles Show Details

T=880°C; Product distribution; Further Variations:Temperatures;

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A: 6.1% B: 79.6% C: 1.5%

With ammonia; oxygen; BiFeMoOx in water

T=440°C; P=1277.21 Torr; Product distribution / selectivity; Hide Experimental Procedure

Seely, Michael J.; Godbole, Sanjay P.; Paparizos, Christos

Patent: US2003/219372 A1, 2003 ; Location in patent: Page/Page column 3-4 ; Title/Abstract Full Text Show Details

Ammoxidation reactions of propylene using air and ammonia were conducted with and without the addition of a carboxylic acid. The catalyst utilized in all of the examples was a promoted BiFeMoOx known for its suitability in the ammoxidation of propylene to acrylonitrile. Crude acetic acid in the amount of 2.5, 5 and 10percent of the ammonia feed on a molar basis was added to an ammoxidation reactor along with propylene and air to give the results set forth below in Table I. The crude acetic acid mixture was brought to pH 5 by the addition of ammonium hydroxide solution and the resulting acid diluted to 67percent water before being fed to the reactor. In each of the following examples, the reactor temperature was 440° C., the pressure was 10.0 psig and the molar feed ratio of propylene/ammonia/air/acid was 1/1.17/10.0/X (X=0.029, 0.059, 0.12). The wwh was 0.08 (grams of hydrocarbon/grams of catalyst, hour). [TABLE-US-00001] TABLE I Acetic Acid percent percent Example as Mole percent Acrylonitrile Acetonitrile percent HCN No. of Ammonia Feed Yield Yield Yield 1(comp.) 0 79.6 1.5 6.1 2 2.5 80.1 2.2 5.9 3 5 78.7 2.8 5.8 4 10 77.3 3.9 6.0 A

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A: 5.8% B: 77.3% C: 2.2%

With ammonia; oxygen; BiFeMoOx in water

T=440°C; P=1277.21 Torr; pH=5; Product distribution / selectivity; Hide Experimental Procedure

Seely, Michael J.; Godbole, Sanjay P.; Paparizos, Christos

Patent: US2003/219372 A1, 2003 ; Location in patent: Page/Page column 3-4 ; Title/Abstract Full Text Show Details

Ammoxidation reactions of propylene using air and ammonia were conducted with and without the addition of a carboxylic acid. The catalyst utilized in all of the examples was a promoted BiFeMoOx known for its suitability in the ammoxidation of propylene to acrylonitrile. Crude acetic acid in the amount of 2.5, 5 and 10percent of the ammonia feed on a molar basis was added to an ammoxidation reactor along with propylene and air to give the results set forth below in Table I. The crude acetic acid mixture was brought to pH 5 by the addition of ammonium hydroxide solution and the resulting acid diluted to 67percent water before being fed to the reactor. In each of the following examples, the reactor temperature was 440° C., the pressure was 10.0 psig and the molar feed ratio of propylene/ammonia/air/acid was 1/1.17/10.0/X (X=0.029, 0.059, 0.12). The wwh was 0.08 (grams of hydrocarbon/grams of catalyst, hour). [TABLE-US-00001] TABLE I Acetic Acid percent percent Example as Mole percent Acrylonitrile Acetonitrile percent HCN No. of Ammonia Feed Yield Yield Yield 1(comp.) 0 79.6 1.5 6.1 2 2.5 80.1 2.2 5.9 3 5 78.7 2.8 5.8 4 10 77.3 3.9 6.0 A

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With catalyst: Ag/Al2O3; O2; ethanol in neat (no solvent, gas phase) byproducts: NCO, C2H4, CH3CHO; selective catalytic reduction at different temperatures; monitored by FTIR and mass spectrometry;

Bion, Nicolas; Saussey, Jacques; Haneda, Masaaki; Daturi, Marco

Journal of Catalysis, 2003 , vol. 217, # 1 p. 47 - 58 Title/Abstract Full Text View citing articles Show Details

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Carl, Shaun A.; Nguyen, Hue Minh Thi; Nguyen, Minh Tho; Peeters, Jozef

Journal of Chemical Physics, 2003 , vol. 118, # 24 p. 10996 - 11008 Title/Abstract Full Text View citing articles Show Details

in gas Kinetics; Irradiation (UV/VIS); C2H2, NO2 and N2 (as a buffer) gas mixed in reaction chamber; C2H radicals obtained by pulsed laser photolysis at 193 nm; gas mixt. heated from 288 to 800 K at pressure 5 Torr (N2);

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A: 4.8% B: 15.4% C: 8.9% D: 51.6%

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Tsuji, Hideto; Koyasu, Yukio

Journal of the American Chemical Society, 2002 , vol. 124, # 20 p. 5608 - 5609 Title/Abstract Full Text View citing articles Show Details

With air; ammonia; Mo1V0.3Nb0.12Te0.17Ox

T=428°C; P=760.051 Torr; Product distribution; Further Variations:TemperaturesCatalysts;

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Nanba; Obuchi; Sugiura; Kouno; Uchisawa; Kushiyama

Journal of Catalysis, 2002 , vol. 211, # 1 p. 53 - 63 Title/Abstract Full Text View citing articles Show Details

in sodium hydroxide

0.1 M NaOH soln. cntg. 1.4percent KCN introduced into 1 M H2SO4 at 0 °C;

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Nanba; Obuchi; Sugiura; Kouno; Uchisawa; Kushiyama

Journal of Catalysis, 2002 , vol. 211, # 1 p. 53 - 63 Title/Abstract Full Text View citing articles Show Details

in gas Kinetics; byproducts: nitroethylene; further products; over H-FER-17 ferrierite; investigated in the range 200-500 °C;

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Temps; Eshchenko; Koecher; Kerst

Chemical Physics Letters, 2002 , vol. 356, # 1-2 p. 181 - 187 Title/Abstract Full Text View citing articles Show Details

in gas Irradiation (UV/VIS); photolysis at 193 nm, large excess of NO, 296 K (298 K), 3.5 mbar, he bath gas, tubular flow reactor;

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in sulfur dioxide

SO2 was condensed at -196 °C into Me4NCN, mixt. was warmed up to -60 °C, soln. was concd. at -70 °C up to its 1/4 vol., some H2O was condensed at -196 °C, mixt. was warmed up to -70 °C, 1 bar O2 was introduced; storage for a week; under N2 or absence of water there is no reaction;

Kornath, Andreas; Doz, Priv-; Blecher, Oliver

Zeitschrift fur Anorganische und Allgemeine Chemie, 2002 , vol. 628, # 3 p. 625 - 631 Title/Abstract Full Text View citing articles Show Details

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With acrolein or acetaldehyde; catalyst=SnO2/γAlO3 in gas byproducts: HC(O)H; further reagents: catalysts γ-Al2O3; at 475°C; acrolein or acetaldehyde 160-170 ppm; further byproduct HCHO;

Lee; Yezerets; Kung

Chemical Communications, 2001 , # 15 p. 1404 - 1405 Title/Abstract Full Text View citing articles Show Details


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B: 0%

Pasinszki, Tibor; Karpati, Tamas; Westwood, Nicholas P. C.

Journal of Physical Chemistry A, 2001 , vol. 105, # 25 p. 6258 - 6265 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent, gas phase) thermolysis at 800-900°C;

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Decker, Brian K.; Macdonald, R. Glen

Journal of Physical Chemistry A, 2001 , vol. 105, # 28 p. 6817 - 6825 Title/Abstract Full Text View citing articles Show Details

in gas Kinetics; reaction carried out in a transverse flow reactor consisted of a stainless steel vacuum-tight vessel containing Teflon box; detected by infrared transient absorption spectroscopy;

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in gas Kinetics; reaction carried out in a transverse flow reactor consisted of a stainless steel vacuum-tight vessel containing Teflon box; detected by infrared transient absorption spectroscopy;

Decker, Brian K.; Macdonald, R. Glen

Journal of Physical Chemistry A, 2001 , vol. 105, # 28 p. 6817 - 6825 Title/Abstract Full Text View citing articles Show Details


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Guo; Carrington; Filseth

Journal of Chemical Physics, 2001 , vol. 115, # 18 p. 8411 - 8417 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent) byproducts: C2H, C2H2, C2H3; Irradiation (UV/VIS); 157.6 nm photolysis; other products may be:HCCN, HCHCCN, H2CCCN, HCCCN, H2CN;

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Sevy, Eric T.; Muyskens, Mark A.; Rubin, Seth M.; Flynn, George W.; Muckerman, James T.

Journal of Chemical Physics, 2000 , vol. 112, # 13 p. 5829 - 5843 Title/Abstract Full Text View citing articles Show Details

in various solvent(s) Decomposition; UV-irradiation; KineticsQuantum yield;

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With ammonia; oxygen

T=976.85°C; Andrussow reaction; P=750.06 Torr; Product distribution; Further Variations:oxygen content;

Trusov; Grin'; Prezhdo

Russian Journal of Applied Chemistry, 2000 , vol. 73, # 9 p. 1517 - 1521 Title/Abstract Full Text View citing articles Show Details


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in neat (no solvent)

Intosh, Mc; Archibald

Proceedings of the Royal Society of London, 1904 , vol. 73, p. 454 - 454 Full Text Show Details

Intosh, Mc; Archibald

Z. phys. Ch., 1906 , vol. 55, p. 151 - 151 Full Text Show Details

in water

equal volumes of 2-methyl-tetrahydrofuran and aq. soln. of potassium cyanide put in a vial, forming an organic layer on top of an aq. layer, dropwise addition of concentrated HCl; HCN partitioned into the organic layer, not isolated, detected by IR;

Andrews, Steven S.; Boxer, Steven G.

Journal of Physical Chemistry A, 2000 , vol. 104, # 51 p. 11853 - 11863 Title/Abstract Full Text View citing articles Show Details

Gmelin Handbook: Cl: MVol., 45, page 134 - 136 Full Text Show Details

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in gaseous matrix Irradiation (UV/VIS); H atoms (by photolyzing CH3SH) reacted with (CN)2 at low pressures under bulk conditions; not isolated; HNC rovibrational populations probed by time- and frequency-resolved IR absorption spectroscopy with sub-Doppler frequency resoln.; A

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Macdonald, R. Glen

Journal of Physical Chemistry A, 2000 , vol. 104, # 45 p. 10202 - 10211 Title/Abstract Full Text View citing articles Show Details


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Figlar; Stanbury

Inorganic Chemistry, 2000 , vol. 39, # 22 p. 5089 - 5094 Title/Abstract Full Text View citing articles Show Details

in water

Kinetics; 25°C;

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With argon; nitrogen(II) oxide; nitrogen(IV) oxide

P=427.534 Torr; Ambient temperatureIrradiation; Rate constant;

Eickhoff; Temps

Physical Chemistry Chemical Physics, 1999 , vol. 1, # 2 p. 243 - 251 Title/Abstract Full Text View citing articles Show Details

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4.08%

With argon

High Pressure; pressure: 7400 kp/cm2;

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Markevich, A. M.; Tamm, I. I.; Ryabinin, Yu. N.

Doklady Akademii Nauk SSSR, 1957 , vol. 113, p. 856 - 859 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details


3.04%

High Pressure; pressure: 9200 kp/cm2;

Markevich, A. M.; Tamm, I. I.; Ryabinin, Yu. N.

Doklady Akademii Nauk SSSR, 1957 , vol. 113, p. 856 - 859 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With argon

Kinetics; at 1400-6000 K; reaction time: 1-1.5 ms; with shock wave;

Rao, V. V.; Mackay, D.; Trass, O.

Can. J. Chem. Eng., 1967 , vol. 45, p. 61 - 66 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Hide Details

at incandescent filament;

Gmelin Handbook: N: MVol.1, 1.4.2.34, page 248 - 248 Full Text Show Details

Alexejew, D.

Zersetzung von Acetylen druch Explosion <russ.>, Moskau 1915, S. 89; C. 1925 II 1589 Full Text Show Details

by heating to 200°C, molar ratio of educts = 1:1;

Francesconi, L.; Ciurlo, A.

Gazzetta Chimica Italiana, 1924 , vol. 54, p. 687 - 697 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

in corona discharge;

Montemartini, C.

Gazzetta Chimica Italiana, 1922 , vol. 52 II, p. 96 - 97 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

in flame discharge;

Berthelot, M.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1907 , vol. 144, p. 354 - 357 Full Text Show Details

Berthelot, M.

Liebigs Annalen der Chemie, 1869 , vol. 150, p. 60 - 66 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

with explosion of mixture;

Garner; Matsumo

Journal of the Chemical Society, 1922 , vol. 121, p. 1729 Full Text View citing articles Show Details

Garner; Matsuno

Journal of the Chemical Society, 1921 , vol. 119, p. 1903 Full Text View citing articles Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With inert gas other Radiation; with α-rays; at 25°C;

Lind, S. C.; Bardwel, D. C.

Journal of the American Chemical Society, 1926 , vol. 48, p. 1575 - 1584 Full Text View citing articles Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

in gaseous matrix byproducts: NH2, H2CNH, N2H4; continuous-flow microwave plasma discharge, pressure 20 Torr; depending on concn.; Li(+) ion attachment mass spectrometry;

Fujii, Toshihiro

Chemical Physics Letters, 1999 , vol. 313, # 5-6 p. 733 - 740 Title/Abstract Full Text View citing articles Show Details

in water

High Pressure; pressure: 100 kp/cm2; at 300-500°C; inert solvent: water vapour;

Sortland, L. D.; Prausnitz, J. M.

Chem. Eng. Sci., 1965 , vol. 20, p. 847 - 850 Full Text View citing articles Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Kinetics; other Radiation; with electron;

Dzantiev, B. G.; Trubnikov, V. P.


Vestsi Akad. Navuk Belarusk. SSR Ser. Fiz. Tekhn. Navuk, 1966 , # 3 p. 13 - 15 C.A., 1966 , vol. 65, p. 17954 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

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With C3H8 in gaseous matrix Kinetics; Irradiation (UV/VIS); components in Ar carrier gas flowing continuously through transverse flow reactor, photolysis by 193 nm laser (5 Hz, 10-20 mJ/cm**2) at 293 K; monitoring using IR time.resolved and frequency-scanned absorption spectroscopy; A

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He; Seth, Michael; Tokue; Macdonald, R. Glen

Journal of Chemical Physics, 1999 , vol. 110, # 16 p. 7821 - 7831 Title/Abstract Full Text View citing articles Show Details

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Rim, Kwang Taeg; Hershberger, John F.

Journal of Physical Chemistry A, 1999 , vol. 103, # 19 p. 3721 - 3725 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent) Kinetics; Irradiation (UV/VIS); not isolated, infrared spectrosc. monitored;

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Mueller, Jens; Sternkicker, Henning

Journal of the Chemical Society - Dalton Transactions, 1999 , # 23 p. 4149 - 4153 Title/Abstract Full Text View citing articles Show Details

byproducts: CH4, C2H4, propene; high-vacuum thermolysis (55-65°C, E-6 to E-7 mbar); further org. species detected; not isolated (matrix isolation techniques combined with IR monitoring);

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Mueller, Jens; Sternkicker, Henning

Journal of the Chemical Society - Dalton Transactions, 1999 , # 23 p. 4149 - 4153 Title/Abstract Full Text View citing articles Show Details

byproducts: CH4, C2H4, propene; high-vacuum thermolysis (80-90°C, E-6 to E-7 mbar); further org. species detected; not isolated (matrix isolation techniques combined with IR monitoring);

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With sulphur(VI) hexafluoride

laser pyrolysis (IR LPHP method, 1100-1150 K); 2-, 3-, 4-bromopyridine investigated (at ca. 1000 K); Product distributionMechanism;

Hore, Nathan R.; Russell, Douglas K.

Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 2 p. 269 - 275 Title/Abstract Full Text View citing articles Show Details

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With sulphur(VI) hexafluoride

laser pyrolysis (IR LPHP method, 1100-1150 K); 5-bromopyrimidine and pyrazine investigated; Product distributionMechanism;

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Hore, Nathan R.; Russell, Douglas K.

Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 2 p. 269 - 275 Title/Abstract Full Text View citing articles Show Details

129

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With sulphur(VI) hexafluoride

laser pyrolysis (IR LPHP method, 1100-1150 K); Product distribution;

Hore, Nathan R.; Russell, Douglas K.

Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 2 p. 269 - 275 Title/Abstract Full Text View citing articles Show Details

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Blank, David A.; Suits, Arthur G.; Lee, Yuan T.; North, Simon W.; Hall, Gregory E.

Journal of Chemical Physics, 1998 , vol. 108, # 14 p. 5784 - 5794 Title/Abstract Full Text View citing articles Show Details

in gas Irradiation; Mechanism;

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Martin; Ascanio; Rodriguez

International Journal of Chemical Kinetics, 1998 , vol. 30, # 6 p. 451 - 456 Title/Abstract Full Text View citing articles Show Details

T=510 - 550°C; P=7 - 11 Torr; 0.000194444 h; gas-phase thermolysis; toluene - carrier gas; Product distributionThermodynamic dataRate constant;

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Martin; Ascanio; Rodriguez

International Journal of Chemical Kinetics, 1998 , vol. 30, # 6 p. 451 - 456 Title/Abstract Full Text View citing articles Show Details

T=510 - 560°C; P=7 - 11 Torr; 0.000194444 h; gas-phase thermolysis; toluene - carrier gas; Product distributionThermodynamic dataRate constant;

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Martin; Ascanio; Rodriguez

International Journal of Chemical Kinetics, 1998 , vol. 30, # 6 p. 451 - 456 Title/Abstract Full Text View citing articles Show Details

T=641°C; P=7 - 11 Torr; 0.000194444 h; gas-phase thermolysis; toluene - carrier gas; Product distributionThermodynamic dataRate constant;

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Maier, Guenther; Endres, Joerg

European Journal of Organic Chemistry, 1998 , # 8 p. 1517 - 1520 Title/Abstract Full Text View citing articles Show Details

in gaseous matrix T=-263.2°C; Irradiationphotofragmentation; Product distribution;

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in gas Irradiation (UV/VIS); photodissociation at 266 nm;

Park, Jeunghee

Chemical Physics Letters, 1998 , vol. 293, # 5-6 p. 383 - 390 Title/Abstract Full Text View citing articles Show Details

in gaseous matrix Irradiation (UV/VIS); photolysis of triazine (193 nm, 0.025 - 0.5 Torr in 5 Torr Ar); not isolated; fluorescence spectroscopy;

Goates, S. R.; Chu, J. O.; Flynn, G. W.

Journal of Chemical Physics, 1984 , vol. 81, # 10 p. 4521 - 4525 Title/Abstract Full Text View citing articles Show Details

depolymerization above 600°C;

Grundmann, C.

Angewandte Chemie, 1963 , vol. 75, p. 393 - 407 Full Text Show Details

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With aluminium trichloride

100°C;

Hinkel, L. E.; Ayling, E. E.; Beynon, J. H.

Journal of the Chemical Society, 1935 , p. 674 - 679 Full Text View citing articles Show Details

other Radiation; with (60)Co-γ-radiation;

Hummel, D.; Janssen, O.

Zeitschrift fuer Physikalische Chemie (Muenchen), 1962 , vol. 31, p. 111 - 139 Full Text Show Details

136

Gmelin Handbook: C: MVol.D1, 18.1, page 248 - 250 Full Text Show Details

With AlCl3

Gmelin Handbook: C: MVol.D1, 18.1, page 248 - 250 Full Text Show Details


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in gaseous matrix Irradiation (UV/VIS); transverze flow reactor (Ar, 293-324 K, excimer 193 nm); time-resolved IR spectroscopy;

Bethardy; Northrup; He; Tokue; MacDonald, R. Glen

Journal of Chemical Physics, 1998 , vol. 109, # 11 p. 4224 - 4236 Title/Abstract Full Text View citing articles Show Details

by elektric discharge;

Boillot

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1873 , vol. 76, p. 1132 Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1873 , p. 293 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

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He; Tokue; Macdonald, R. Glen

Journal of Physical Chemistry A, 1998 , vol. 102, # 24 p. 4585 - 4591 Title/Abstract Full Text View citing articles Show Details

in gas Kinetics; (Ar or He); 293-380 K;

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A: 84.2% B: 2.4% C: 14.7%

With nitrogen(II) oxide in gaseous matrix P=480.04 Torr; 2 h; Ambient temperatureIrradiation; Product distributionKinetics;

Grussdorf; Temps; Gg Wagner

Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1997 , vol. 101, # 1 p. 134 - 138 Title/Abstract Full Text View citing articles Show Details

A

B

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139

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Adamson; DeSain; Curl; Glass

Journal of Physical Chemistry A, 1997 , vol. 101, # 5 p. 864 - 870 Title/Abstract Full Text View citing articles Show Details

With nitrogen(II) oxide

P=6 Torr; Irradiationvarious pressures; also with O2; Rate constant;

140

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Rx-ID: 6931880 Find similar reactions

90%

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at 800-980°C; over granulated Al2O3 with 0.2-2 mol percent ThO2 or Ti, Zr, Hf, Si, Ce or Ca oxide;

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Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Kotake, M.

Patent: DE1008719 , 1957 ; Full Text Show Details

Kotake, M.

Patent: GB761166 , 1956 ; C.A., 1957 , p. 8392 Full Text Show Details

87.5%

With air

catalyst: Pt(90percent)-Rh(10percent); molar ratio of CH4/NH3 = 1.55 and air/(CH4+NH3) = 3.25; at 1117°C;

Pan, B. Y. K.; Roth, R. G.

Ind. Eng. Chem. Process Design Develop., 1968 , vol. 7, # 1 p. 53 - 61 Full Text View citing articles Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

70%

With catalyst: Al2O3-SiO2

1050°C; raising of yield with presence of CS2 or H2S; catalyst: Al2O3-SiO2 (1-20 molpercent SiO2);

Kotake, M.; Nakagawa, M.; Ohara, T.; Harada, K.; Ninomiya, M.

Kogyo Kagaku Zasshi, 1956 , vol. 59, p. 121 - 124 C.A., 1956 , p. 16049 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details


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36.15%

With air

catalyst on SiO2; at 600°C; reaction time: 5.6 s;

Giovannini, E.

Chimica e l'Industria (Milan, Italy), 1951 , vol. 33, p. 480 - 483 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

36.15%

With air

catalyst on SiO2; at 600°C; reaction time: 5.6 s;

Giovannini, E.

Chimica e l'Industria (Milan, Italy), 1951 , vol. 33, p. 480 - 483 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

E. Asendorf; W. Klempt in F. Ullmann

Encyklopaedie der technischen Chemie, 3. Aufl. Bd V <Muenchen-Berlin 1954> S. 635 Full Text Show Details

With air; platinum

reaction time: 1/10000 s; at 1000-1200°C; on Pt gauze;

Andrussow, L.

Angewandte Chemie, 1935 , vol. 48, p. 593 - 595 Full Text Show Details

Andrussow, L.

Bulletin de la Societe Chimique de France, 1951 , p. 45 - 50 Full Text Show Details

Andrussow, L.

Chemie Ingenieur Technik, 1955 , vol. 27, p. 469 - 472 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With Pt(90),Rh(10) (X)

600-750°C, 0.10 Torr total pressure;

Bockholt; Harding; Nix

Journal of the Chemical Society - Faraday Transactions, 1997 , vol. 93, # 21 p. 3869 - 3878 Title/Abstract Full Text View citing articles Show Details

With platinum

600-750°C, 0.10 Torr total pressure;

Bockholt; Harding; Nix

Journal of the Chemical Society - Faraday Transactions, 1997 , vol. 93, # 21 p. 3869 - 3878 Title/Abstract Full Text View citing articles Show Details

With platinum

Pt is on Al2O3 or SiO2; at 1000°C;

Maffezoni, U.

Chimica e l'Industria (Milan, Italy), 1952 , vol. 34, p. 460 - 465 Full Text Show Details

Maffezoni, U.

Chimie et Industrie (Paris), 1953 , vol. 69, p. 842 - 847 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With platinum in gas Kinetics; byproducts: hydrogen; react. at atmospheric pressure, various NH3/CH4 ratios, 1200-1500 K;

Suarez, M. Patricia; Loeffler, Daniel G.

Journal of Catalysis, 1986 , vol. 97, p. 240 - 242 Full Text View citing articles Show Details

With platinum

Kinetics;

Pfeil, E.; Hoffmann, P.

Berichte der Bunsen-Gesellschaft fuer Physikalische Chemie, 1963 , vol. 67, p. 229 - 235 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

50-60

Electric Arc; reaction time: 0.01-0.002 s, at reduce pressure; at 1100-1300°C; absence of O2;

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Societe Anon. des Manufactures des Glaces et Produits Chimiques

Patent: AT201076 , 1958 ; C.A., 1959 , p. 14789 Full Text Show Details

Societe Anon. des Manufactures des Glaces et Produits Chimiques

Patent: US2899275 , 1959 ; Full Text Show Details


above 1450°C;

Mihail, R.; Herscovici, J.

Kinetika i Kataliz, 1962 , vol. 3, p. 727 - 734 Kinetika i Kataliz, 1962 , vol. 3, p. 836 - 845 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

at high temp.;

Adadurov, I. E.

Ukrains'kii Khemichnii Zhurnal, 1936 , vol. 11, p. 237 - 249 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

at lower temp.;

Andrussow, L.

Chemie Ingenieur Technik, 1955 , vol. 27, p. 469 - 472 Full Text Show Details

Andrussow, L.

Genie Chim., 1961 , vol. 86, # 2 p. 39 - 44 Full Text Show Details

Wendlandt, R.

Zeitschrift fuer Elektrochemie, 1949 , vol. 53, p. 307 - 319 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Andrussow, L.

Actes 2e Intern. Congr. Catalyse, Paris 1960 (1961), S. 2659/68, Diskussion S. 2668/70 Full Text Show Details

byproducts: H2; with graphite electrode; at 1400-1600°C; in natural gas or light petrol;

Anonymous

Chemical and Engineering News, 1960 , vol. 38, # 47 p. 55 - 56 Full Text Show Details

Banciu, A. S.

Rev. Chim. (Bucarest), 1964 , vol. 15, p. 369 - 376 Full Text Show Details

Boye, E.

Chemiker-Zeitung, 1964 , vol. 88, p. 869 Full Text Show Details

Johnson, H. S.

Can. J. Chem. Eng., 1961 , vol. 39, p. 145 - 147 Full Text Show Details

Kutzleben, S. E. v.

Erdoel Kohle, 1963 , vol. 16, p. 762 - 763 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Shawinigan Chemicals Ltd.,

Patent: CA573348 , 1959 ; C.A., 1959 , p. 16486 Full Text Show Details

Shawinigan Chemicals Ltd.,

Patent: DE1099514 , 1958 ; Full Text Show Details

Shawinigan Chemicals Ltd.,

Patent: CA710717 , 1965 ; C.A., 1965 , vol. 63, p. 9516 Full Text Show Details

Shawinigan Chemicals Ltd.,

Patent: US3097921 , 1963 ; C.A., 1964 , vol. 60, p. 6515 Full Text Show Details

Shawinigan Chemicals Ltd.,

Patent: GB928907 , 1963 ; C.A., 1963 , vol. 59, p. 9516 Full Text Show Details

Montgomery, P. D.

in: Encyclopedia of Chemical Technology, herausgegeben von R.E. Kirk, D.F. Othmer. The Interscience Encyclopedia, Inc., New York. 2. Aufl., Bd. 6, 1965, S. 579 Full Text Show Details

Schwarz, G.

F. Ullmann (foerst), Enzyklopaedie der Technischen Chemie 3. Aufl., Erg.-Bd., 1970, S.486 Full Text Show Details

Sperka, G.; Tennstedt, K.; Weitbrecht, G.

K. J. Mundo in: K. Winnacker, L. Kuechler (3. Aufl., Bd. 1,Tl. I, 1970, S. 698 Full Text Show Details


0%

in electric discharge, in presence of Ar;

Topouzkhanian, A.; d'Incan, J.; Janin, J.

Journal de Chimie Physique et de Physico-Chimie Biologique, 1969 , vol. 66, p. 1424 - 1428 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

in electric discharge, in presence of He;

Topouzkhanian, A.; d'Incan, J.; Janin, J.

Journal de Chimie Physique et de Physico-Chimie Biologique, 1969 , vol. 66, p. 1424 - 1428 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

in electric discharge, in presence of Ne;

Topouzkhanian, A.; d'Incan, J.; Janin, J.

Journal de Chimie Physique et de Physico-Chimie Biologique, 1969 , vol. 66, p. 1424 - 1428 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

in electric discharge; at reduce pressure; yield depends on ratio of CH4:NH3;

Peters, K.; Kuester, H.

Brennstoff-Chemie, 1931 , vol. 12, p. 122 - 127 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

other Radiation; in nuclear reactor with radiation of fission products; cooling with liquid N2; pressure: 3-10 atm; time of irradiation: 10-15 d;

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

other Radiation; in nuclear reactor; yield of HCN depends on irradiation; ratio of NH3-CH4 = 1:1;

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Gudkov, B. S.; Dzantiev, B. G.; Popov, V. N.; Rumyantsev, Yu. M.

C.A., Tr. 2-go Vses. Soveshch. po Radiats. Khim. Akad. Nauk SSSR Otd. Khim. Nauk, Moscow 1960 (1962), S. 733/7 1963 , vol. 58, p. 3073 Full Text Show Details

with high frequency discharge, at about 25 MHz; diln. with He, Ne, Ar or H2;

Topouzkhanian, A.; d'Incan, J.; Janin, J.

Journal de Chimie Physique et de Physico-Chimie Biologique, 1967 , vol. 64, p. 1299 - 1306 Full Text Show Details

Topouzkhanian, A.; d'Incan, J.; Janin, J.

Journal de Chimie Physique et de Physico-Chimie Biologique, 1967 , vol. 64, p. 506 - 513 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

0%

Tsiklis, D. S.; Borodina, M. D.

Doklady Akademii Nauk SSSR, 1962 , vol. 147, p. 1067 - 1069 Doklady Akademii Nauk SSSR, 1962 , vol. 147, p. 860 - 862 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With argon

by adiabatic compression; temp. more thousand °; quick heating and cooling; diln. with Ar; formation of HCN depends on content of Ar in mixture;

Tsiklis, D. S.; Borodina, M. D.

Doklady Akademii Nauk SSSR, 1962 , vol. 147, p. 1067 - 1069 Doklady Akademii Nauk SSSR, 1962 , vol. 147, p. 860 - 862 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With hydrogen

with glowed Cu; at 1100-1400°C; raising of yield with H2;

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Deutsche Gold- und Silberscheideanstalt

Patent: US2927844 , 1960 ; C.A., 1960 , p. 12514 Full Text Show Details

Deutsche Gold- und Silberscheideanstalt

Patent: DE1064933 , 1959 ; Full Text Show Details

0%

With nitrogen

Tsiklis, D. S.; Borodina, M. D.


diln. with N2;

Doklady Akademii Nauk SSSR, 1962 , vol. 147, p. 1067 - 1069 Doklady Akademii Nauk SSSR, 1962 , vol. 147, p. 860 - 862 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With oxygen; Pt(90),Rh(10) (X)

600-750°C, 0.10 Torr total pressure;

Bockholt; Harding; Nix

Journal of the Chemical Society - Faraday Transactions, 1997 , vol. 93, # 21 p. 3869 - 3878 Title/Abstract Full Text View citing articles Show Details

With oxygen; platinum

600-750°C, 0.10 Torr total pressure;

Bockholt; Harding; Nix

Journal of the Chemical Society - Faraday Transactions, 1997 , vol. 93, # 21 p. 3869 - 3878 Title/Abstract Full Text View citing articles Show Details

With oxygen; platinum

600°C, 0.10 Torr total pressure;

Bockholt; Harding; Nix

Journal of the Chemical Society - Faraday Transactions, 1997 , vol. 93, # 21 p. 3869 - 3878 Title/Abstract Full Text View citing articles Show Details

With oxygen in gas Kinetics; byproducts: CO, H2, H2O; Electrochem. Process; at 750-1000°C; oxygen gaseous or electrochemical produced; further byproducts: CO2, N2 and N2O;

Kiratzis, Nikolas; Stoukides, Michael

Journal of Catalysis, 1991 , vol. 132, p. 257 - 262 Full Text View citing articles Show Details

With oxygen in neat (no solvent) byproducts: H2O; oxidn. over Pt/Rh gauze or Pt on ceramic monoliths depending on gas flow and catalyst geometry;

Hickman, D. A.; Schmidt, L. D.

Journal of Catalysis, 1992 , vol. 136, p. 300 - 308 Full Text View citing articles Show Details

With oxygen in gas byproducts: CO, H2; Electrochem. Process; at 960°C;

Kiratzis, Nikolas; Stoukides, Michael

Journal of Catalysis, 1991 , vol. 132, p. 257 - 262 Full Text View citing articles Show Details

0%

With air; nickel

on Ni gauze;

Chretien, A.; Thomas, A.

Bulletin de la Societe Chimique de France, 1948 , p. 354 - 357 Full Text Show Details

Thomas, A.

Ann. Chim. (Paris) (12), 1949 , vol. 4, p. 258 - 285 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With air; nickel

Andrussow, L.

Bulletin de la Societe Chimique de France, 1951 , p. 45 - 50 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

0%

With air; gold

on Au gauze;

Chretien, A.; Thomas, A.

Bulletin de la Societe Chimique de France, 1948 , p. 354 - 357 Full Text Show Details

Thomas, A.

Ann. Chim. (Paris) (12), 1949 , vol. 4, p. 258 - 285 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

0%

With air; copper

on Cu gauze;

Chretien, A.; Thomas, A.

Bulletin de la Societe Chimique de France, 1948 , p. 354 - 357 Full Text Show Details

Thomas, A.

Ann. Chim. (Paris) (12), 1949 , vol. 4, p. 258 - 285 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With air; platinum

at 1000-1100°C; reaction time: 1E-3 s; on Pt gauze; yield of HCN depends on content of mixture of gas;

Chretien, A.; Thomas, A.

Bulletin de la Societe Chimique de France, 1948 , p. 354 - 357 Full Text Show Details

Thomas, A.


Ann. Chim. (Paris) (12), 1949 , vol. 4, p. 258 - 285 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With air; platinum

in turbulence bed with Pt on Al2O3, SiO2 or MgO;

Mihail, R.

Chem. Prumysl, 1957 , vol. 7, p. 360 - 361 C.A., 1958 , p. 13201 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With air; platinum

Andrussow, L.

Bulletin de la Societe Chimique de France, 1951 , p. 45 - 50 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

0%

With air; silver

on Ag gauze;

Chretien, A.; Thomas, A.

Bulletin de la Societe Chimique de France, 1948 , p. 354 - 357 Full Text Show Details

Thomas, A.

Ann. Chim. (Paris) (12), 1949 , vol. 4, p. 258 - 285 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With air

on platinum sponge or platinum black on asbestos or on pumice stone; HCN formed in trace;

Chretien, A.; Thomas, A.

Bulletin de la Societe Chimique de France, 1948 , p. 354 - 357 Full Text Show Details

Thomas, A.

Ann. Chim. (Paris) (12), 1949 , vol. 4, p. 258 - 285 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

60-80

With catalyst: Al2O3-ThO2

1050°C; raising of yield with presence of CS2 or H2S; catalyst:Al2O3-ThO2 (1-5 molpercent ThO2);

Kotake, M.; Nakagawa, M.; Ohara, T.; Harada, K.; Ninomiya, M.

Kogyo Kagaku Zasshi, 1956 , vol. 59, p. 121 - 124 C.A., 1956 , p. 16049 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With catalyst: Pt on yttria stabilized zirconia in gas Kinetics; byproducts: H2; Electrochem. Process; at 750-1000°C;

Kiratzis, Nikolas; Stoukides, Michael

Journal of Catalysis, 1991 , vol. 132, p. 257 - 262 Full Text View citing articles Show Details

With catalyst: Pt, Ru, Al with anhyd. NH3 and CH4; at 1200-1300°C; quick cooling down to 300°C; catalyst: 60percentPt, 8percentRu, 32percentAl; washing with dild. H2SO4, cold water; rectification;

Endter, F.

Chemie Ingenieur Technik, 1958 , vol. 30, p. 305 - 310 Full Text Show Details

Endter, F.

Chemie Ingenieur Technik, 1961 , vol. 33, p. 512 - 513 Full Text Show Details

Endter, F.

Dechema Monograph., 1959 , vol. 33, p. 28 - 46 Full Text Show Details

Endter, F.

Hydrocarbon Process. Petrol. Refiner, 1967 , vol. 46, # 11 p. 189 Full Text Show Details

Sherwood, P. W.

Petrol. Engr., 1959 , vol. 31, p. C 51 - C 54 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Schwarz, G.

F. Ullmann (foerst), Enzyklopaedie der Technischen Chemie 3. Aufl., Erg.-Bd., 1970, S.486 Full Text Show Details

Sperka, G.; Tennstedt, K.; Weitbrecht, G.

laut K. J. Mundo in: K. Winnacker, L. Kuechler (3. Aufl., Bd. 1, Tl. I, 1970, S. 697 Full Text Show Details

With catalyst: Pt-Rh

Maffezoni, U.


at 1000°C, for more h; catalyst: Pt-Rh (5percent);

Chimica e l'Industria (Milan, Italy), 1952 , vol. 34, p. 460 - 465 Full Text Show Details

Maffezoni, U.

Chimie et Industrie (Paris), 1953 , vol. 69, p. 842 - 847 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With catalyst: Pt-Ru

Wendlandt, R.

Zeitschrift fuer Elektrochemie, 1949 , vol. 53, p. 307 - 319 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

With catalyst: Pt-asbestos 750-900°C;

Mihail, R.; Herscovici, J.

Kinetika i Kataliz, 1962 , vol. 3, p. 727 - 734 Kinetika i Kataliz, 1962 , vol. 3, p. 836 - 845 Full Text Show Details

Mihail, R.; Herscovici, J.

Revista de Chimie (Bucharest, Romania), 1958 , vol. 9, p. 412 - 415 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Mihail, R.; Herscovici, J.

Proc. 2nd U.N. Intern. Conf. Peaceful Uses At. Energy, Geneva 1958 (1959), Bd.29, S.317/21 Full Text Show Details

With catalyst: Pt-asbestos other Radiation; with (60)Co-γ radiation; at 650°C;

Mihail, R.; Herscovici, J.

Kinetika i Kataliz, 1962 , vol. 3, p. 727 - 734 Kinetika i Kataliz, 1962 , vol. 3, p. 836 - 845 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Mihail, R.; Herscovici, J.

Proc. 2nd U.N. Intern. Conf. Peaceful Uses At. Energy, Geneva 1958 (1959), Bd.29, S.317/21 Full Text Show Details

With catalyst: alum earch 800-1000°C;

Bredig, G.; Eloed, E.; Demme, E.

Zeitschrift fuer Elektrochemie, 1930 , vol. 36, p. 991 - 1003 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

in not given in presence of catalysts, higher temp.;

Bredig, G.; Eloed, E.; Demme, E.

Zeitschrift fuer Elektrochemie, 1930 , vol. 36, p. 1001 Full Text Show Details

Kinetics; other Radiation; with electron irradiation; in nuclear raector;

Dzantiev, B. G.; Trubnikov, V. B.; Popov, V. N.

Vestsi Akad. Navuk Belarusk. SSR Ser. Fiz. Tekhn. Navuk, 1966 , # 3 p. 5 - 7 C.A., 1966 , vol. 65, p. 17956 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

Kinetics; with high frequency discharge, at 40 MHz;

Miyazaki, S.; Takahashi, S.

Nippon Kagaku Zasshi, 1958 , vol. 79, p. 135 - 138 C.A., 1958 , p. 16046 Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

in not given in presence of catalysts, higher temp.;

Gmelin Handbook: N: MVol.2, 5.2.2, page 490 - 493 Full Text Show Details

other Radiation; in nuclear reactor with radiation of fission products; cooling with liquid N2; pressure: 3-10 atm; time of irradiation: 10-15 d;

Dzantiev, B. G.; Trubnikov, V. P.; Popov, V. N.

Vestsi Akad. Navuk Belarusk. SSR Ser. Fiz. Tekhn. Navuk, 1966 , # 3 p. 8 - 12 C.A., 1966 , vol. 65, p. 17955 Full Text Show Details


A

B

C

D

E

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141

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Rx-ID: 26165857 Find similar reactions

A: 84% B: 15%

byproducts: H2CO; Irradiation (UV/VIS); photolysis of CH2CO/NO/Ar mixt. with 200 W high pressure Hg lamp (photolysis of CH2CO generates CH2 radicals) in Duran glass tube (20 cm long, 4cm i.d.) at room temp. and ambient pressure;

A

B

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Grussdorf; Temps; Gg Wagner

Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1997 , vol. 101, # 1 p. 134 - 138 Title/Abstract Full Text View citing articles Show Details

142

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in gaseous matrix Kinetics; reaction of CN radicals (generated by pulsed laser photolysis of NCNO at 532 nm) with NH3; 30 Torr , T between 294 and 761K , Ar carrier gas; products not isolated; decay of concentration of CN radicals monitored by laser induced fluorescence;;

Sims, Ian R.; Smith, Ian W. M.

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1988 , vol. 84, p. 527 - 539 Full Text View citing articles Show Details

in gaseous matrix Kinetics; reaction of CN (produced on photodissociation of NCNO, 582 nm) with NH3 (25 - 295 K, inert carrier gas, CRESU apparatus); not isolated;

Sims, I. R.; Queffelec, J.-L.; Defrance, A.; Rebrion-Rowe, C.; Travers, D.; et al.

Journal of Chemical Physics, 1994 , vol. 100, # 6 p. 4229 - 4241 Title/Abstract Full Text View citing articles Show Details

Kinetics; monitoring by infrared diode laser spectoscopy;

Lindholm, Ned; Hershberger, John F.

Journal of Physical Chemistry A, 1997 , vol. 101, # 27 p. 4991 - 4995 Title/Abstract Full Text View citing articles Show Details

A

143

B


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Rx-ID: 27142580 Find similar reactions

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Entley, William R.; Treadway, Christopher R.; Wilson, Scott R.; Girolami, Gregory S.

Journal of the American Chemical Society, 1997 , vol. 119, # 27 p. 6251 - 6258 Title/Abstract Full Text View citing articles Show Details

A

B

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144

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Rx-ID: 4467198 Find similar reactions

McEwan; Fairley; Scott; Anicich

Journal of Physical Chemistry, 1996 , vol. 100, # 10 p. 4032 - 4037 Title/Abstract Full Text View citing articles Show Details

T=24.9°C; P=0.0005 Torr; Rate constant;

A

B

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145

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146

Irradiation; MechanismThermodynamic data;

Gejo; Harrison; Huber, J. Robert

Journal of Physical Chemistry, 1996 , vol. 100, # 33 p. 13941 - 13949 Title/Abstract Full Text View citing articles Show Details


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Rx-ID: 7076949 Find similar reactions

With nitrogen in gas T=24.9°C; P=620 Torr; Irradiationtemperature and pressure dependence; Rate constantKineticsThermodynamic data;

Becker; Geiger; Wiesen

International Journal of Chemical Kinetics, 1996 , vol. 28, # 2 p. 115 - 123 Title/Abstract Full Text View citing articles Show Details

147

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Rx-ID: 26154950 Find similar reactions

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With P2O5 in neat (no solvent) action of phosphoric acid (with excess P2O5 added) on solid KCN in vac.;

Goodwin, Elizabeth J.; Legon, A. C.

Chemical Physics, 1984 , vol. 87, p. 81 - 92 Full Text View citing articles Show Details

in neat (no solvent) action of phosphoric acid on potassium cyanide in vac.;

Legon, A. C.; Willoughby, L. C.

Chemical Physics, 1984 , vol. 85, p. 443 - 450 Full Text View citing articles Show Details

in water

dripping aq. soln. HCN into concentrated H3PO4, collecting resulting gasin liq. N2 cooled vessel;

Pfeiffer, Joann M.; Metz, Ricardo B.; Thoemke, John D.; Woods III, Ephraim; Crim, F. Fleming

Journal of Chemical Physics, 1996 , vol. 104, # 12 p. 4490 - 4501 Title/Abstract Full Text View citing articles Show Details

148

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With sulfuric acid; water; iron(II) sulfate

With sulfuric acid; water

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Rx-ID: 533671 Find similar reactions

Brauer,G.

Handbuch der Praeparativen Anorganischen Chemie, 2. Aufl., Bd. 1 <Stuttgart 1960> S. 584 Full Text Show Details

Pauer

Monatshefte fuer Chemie, 1931 , vol. 58, p. 1,9 Full Text View citing articles Show Details

Giauque; Ruehrwein

Journal of the American Chemical Society, 1939 , vol. 61, p. 2626 Full Text View citing articles Show Details

Kurtz

Houben-Weyl, 1952 , vol. 8, p. 255 Full Text Show Details

Slotta

Chemische Berichte, 1934 , vol. 67, p. 1030


Full Text Show Details

With steam; sulfur dioxide

California Cyanide Co

Chem. Zentralbl., 1929 , vol. 100, # I p. 1397 Full Text Show Details

California Cyanide Co.

Patent: US1761433 , 1927 ;

Full Text Show Details

California Cyanide Co.

Patent: GB299019 ; Full Text Show Details

Hide Details

With carbon dioxide; steam

California Cyanide Co

Chem. Zentralbl., 1929 , vol. 100, # I p. 1397 Full Text Show Details

California Cyanide Co.

Patent: US1761433 , 1927 ;

Full Text Show Details

California Cyanide Co.

Patent: GB299019 ; Full Text Show Details

With sulfuric acid; water; sodium hydrogensulfite

Carlisle

Industrial and Engineering Chemistry, 1933 , vol. 25, p. 960 Full Text Show Details

Du Pont de Nemours and Co

Chem. Zentralbl., 1934 , vol. 105, # I p. 1885 Full Text Show Details

Du Pont de Nemours and Co.

Patent: US1950899 , 1931 ;

Full Text Show Details

Du Pont de Nemours and Co.

Patent: GB401351 ; Full Text Show Details

With sulfuric acid

Ziegler

Chemische Berichte, 1921 , vol. 54, p. 110 Full Text Show Details

Ziegler

Org. Synth. Coll. Vol., 1932 , vol. I, p. 307; deutsche Ausgabe S. 310 Full Text Show Details

With phosphoric acid in neat (no solvent) dry phosphoric acid addn. (vacuum);

Hinds, K.; Legon, A. C.

Chemical Physics Letters, 1995 , vol. 240, p. 467 - 473 Title/Abstract Full Text View citing articles Show Details

A

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149

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A: 19 % Spectr. B: 9 % Spectr. C: 30 % Spectr.

Fujiwara, Hideo; Egawa, Toru; Konaka, Shigehiro

Journal of Molecular Structure, 1995 , vol. 344, p. 217 - 226 Title/Abstract Full Text View citing articles Show Details

T=535°C; 0.0116667 h; in quartz tube, var. temp.; Product distribution;

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150

Synthesize Find similar Rx-ID: 4241008 Find similar reactions

Chin, Wee S.; Mok, Chup Y.; Huang, Hsing H.; Rzepa, Henry S.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1995 , # 3 p. 427 - 430 Title/Abstract Full Text View citing articles Show Details

T=950°C; also 2-pyrrolidinethione; var. temp.; Mechanism;

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151

Synthesize Find similar Rx-ID: 4249645 Find similar reactions

Sakaizumi, Takeshi; Nishikawa, Motoi; Ohashi, Asamu

Journal of Molecular Spectroscopy, 1995 , vol. 171, # 2 p. 518 - 524 Title/Abstract Full Text View citing articles Show Details

T=550°C; Mechanism;

A

152

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Synthesize Find similar Rx-ID: 4362704 Find similar reactions

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Yokotsuji, Dana Lyn S.; Dailey, William P.; Kende, Andrew S.; Birzan, Liviu; Liu, Kun

Journal of Physical Chemistry, 1995 , vol. 99, # 43 p. 15870 - 15873 Title/Abstract Full Text View citing articles Show Details

in solid matrix T=-261.2°C; Irradiation; Product distribution;

A

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153

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Rx-ID: 4433313 Find similar reactions

Olmstead, William N.; Brauman, John I.

Journal of Mass Spectrometry, 1995 , vol. 30, # 12 p. 1653 - 1662 Title/Abstract Full Text Show Details

in gas P=1E-06 - 5E-05 Torr; Rate constant;

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D

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F

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154

Synthesize Find similar Rx-ID: 5727335 Find similar reactions

With methanol in gas T=778.9°C; studies in a single-pulse shock tube; other temp.; other reag.; with/without reag.; Product distributionKinetics;

A

155

Lifshitz, Assa; Wohlfeiler, Dror; Tamburu, Carmen

Journal of Physical Chemistry, 1995 , vol. 99, # 29 p. 11436 - 11446 Title/Abstract Full Text View citing articles Show Details

B

C

D

E


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Waschewsky, G. C. G.; Kitchen, D. C.; Browning, P. W.; Butler, L. J.

Journal of Physical Chemistry, 1995 , vol. 99, # 9 p. 2635 - 2645 Title/Abstract Full Text Show Details

in gas Irradiationa time-of-flight study of photodissociation;

A

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D

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156

Synthesize Find similar Rx-ID: 6217020 Find similar reactions

With ammonia

T=800°C; other halobenzenes, other temperatures; Product distribution;

Kashin, A. N.; Maiorov, O. V.; Ivanova, G. G.

Russian Journal of Organic Chemistry, 1995 , vol. 31, # 5 p. 672 - 676 Zhurnal Organicheskoi Khimii, 1995 , vol. 31, # 5 p. 726 - 731 Title/Abstract Full Text Show Details

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157

Synthesize Find similar Rx-ID: 7082131 Find similar reactions

Waschewsky, G. C. G.; Kitchen, D. C.; Browning, P. W.; Butler, L. J.

Journal of Physical Chemistry, 1995 , vol. 99, # 9 p. 2635 - 2645 Title/Abstract Full Text Show Details

in gas Irradiationa time-of-flight study of photodissociation;

A

158

B


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Rx-ID: 26341022 Find similar reactions

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in gaseous matrix byproducts: formaldehyde, CH4; at 473-873 K; not isolated, FTIR;

Radtke, Frank; Koeppel, Rene A.; Baiker, Alfons

Journal of the Chemical Society, Chemical Communications, 1995 , # 4 p. 427 - 428 Title/Abstract Full Text View citing articles Show Details

A: 0%

With water in gaseous matrix byproducts: formaldehyde, CH4; at 473-873 K; not isolated, FTIR;

Radtke, Frank; Koeppel, Rene A.; Baiker, Alfons

Journal of the Chemical Society, Chemical Communications, 1995 , # 4 p. 427 - 428 Title/Abstract Full Text View citing articles Show Details

A

B

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159

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Rx-ID: 26341116 Find similar reactions

A: 0%

With water in gaseous matrix byproducts: formaldehyde, CH4; at 473-873 K; not isolated, FTIR;

Radtke, Frank; Koeppel, Rene A.; Baiker, Alfons

Journal of the Chemical Society, Chemical Communications, 1995 , # 4 p. 427 - 428 Title/Abstract Full Text View citing articles Show Details

in gaseous matrix byproducts: formaldehyde; at 473-873 K; not isolated, FTIR;

Radtke, Frank; Koeppel, Rene A.; Baiker, Alfons

Journal of the Chemical Society, Chemical Communications, 1995 , # 4 p. 427 - 428 Title/Abstract Full Text View citing articles Show Details

A

160

B

C

D

E


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With water in water

byproducts: [Fe(III)(CN)6-x(H2O)x]((3-x)-), [Fe(II)(CN)6-x(H2O)x]((4-x)-); Irradiation (UV/VIS); unfiltered UV/VIS light or filters (λ>230 or 415 or 430 nm), 298K, then standing in dark; not isolated, detd. by UV/VIS, IR and mass spectroscopy; product ratio depending on wavelength; A

B

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Oliveira, Marcelo G. de; Langley, G. John; Rest, Antony J.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1995 , # 12 p. 2013 - 2020 Title/Abstract Full Text View citing articles Show Details

161

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Rx-ID: 26514560 Find similar reactions

A: 0%

With water in gaseous matrix byproducts: formaldehyde, NH3, CH4 and ethene; at 473-873 K; not isolated, FTIR;

Radtke, Frank; Koeppel, Rene A.; Baiker, Alfons

Journal of the Chemical Society, Chemical Communications, 1995 , # 4 p. 427 - 428 Title/Abstract Full Text View citing articles Show Details

in gaseous matrix byproducts: formaldehyde, ethene; at 473-873 K; not isolated, FTIR;

Radtke, Frank; Koeppel, Rene A.; Baiker, Alfons

Journal of the Chemical Society, Chemical Communications, 1995 , # 4 p. 427 - 428 Title/Abstract Full Text View citing articles Show Details

A

B

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162

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Rx-ID: 26537750 Find similar reactions

A: 0%

With water in gaseous matrix byproducts: formaldehyde, ethene and CH4, NH3; at 473-873 K; not isolated, FTIR;

Radtke, Frank; Koeppel, Rene A.; Baiker, Alfons

Journal of the Chemical Society, Chemical Communications, 1995 , # 4 p. 427 - 428 Title/Abstract Full Text View citing articles Show Details

in gaseous matrix byproducts: formaldehyde, ethene; at 473-873 K; not isolated, FTIR;

Radtke, Frank; Koeppel, Rene A.; Baiker, Alfons

Journal of the Chemical Society, Chemical Communications, 1995 , # 4 p. 427 - 428 Title/Abstract Full Text View citing articles Show Details

A

B

C

D


163

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Rx-ID: 3210984 Find similar reactions

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With nitric oxide

T=16.9 - 426.9°C; P=2 Torr; KineticsThermodynamic dataProduct distribution;

Boullart, Werner; Nguyen, Minh Tho; Peeters, Jozef

Journal of Physical Chemistry, 1994 , vol. 98, # 33 p. 8036 - 8043 Title/Abstract Full Text View citing articles Show Details

A

B

C

D

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164

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Rx-ID: 3737593 Find similar reactions

D: 25.2% E: 3.2%

Ruckenstein, Eli; Khan, Ashraf Z.

Journal of Catalysis, 1994 , vol. 145, # 2 p. 390 - 401 Title/Abstract Full Text View citing articles Show Details

With helium; Na+ + 5percent Cs+; CaO

T=750°C; P=760 Torr; effects of alkali metal compounds, reaction temperature, pseudo-contact time, partial pressures of reactants; Product distribution;

165

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Rx-ID: 3954062 Find similar reactions

With nitrogen(II) oxide

T=1042.9°C; P=362.3 Torr; var. temp.; KineticsMechanism;

Hennig; Wagner

Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1994 , vol. 98, # 5 p. 749 - 753 Title/Abstract Full Text View citing articles Show Details

A

B

C


166

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With perchloric acid; NaBiO3; hydrogen fluoride in water

T=35°C; Oxidation; 3 h; Kinetics; Further Variations:Temperatures;

Devra; Jain; Sharma

International Journal of Chemical Kinetics, 1994 , vol. 26, # 5 p. 577 - 586 Title/Abstract Full Text View citing articles Show Details

A

B

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167

Synthesize Find similar Rx-ID: 1844981 Find similar reactions

Lifshitz, Assa; Tamburu, Carmen; Frank, Peter; Just, Thomas

Journal of Physical Chemistry, 1993 , vol. 97, # 16 p. 4085 - 4090 Title/Abstract Full Text View citing articles Show Details

With nitrogen(II) oxide

T=826.9 - 1056.9°C; A, E, ΔH0; MechanismKinetics;

A

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C

D

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168

Synthesize Find similar Rx-ID: 1895052 Find similar reactions

With nitrogen(II) oxide

T=859.9 - 1047.9°C; Product distribution;

Lifshitz, Assa; Tamburu, Carmen; Frank, Peter; Just, Thomas

Journal of Physical Chemistry, 1993 , vol. 97, # 16 p. 4085 - 4090 Title/Abstract Full Text View citing articles Show Details


A

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C

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169

Synthesize Find similar Rx-ID: 2430368 Find similar reactions

With ammonia

T=26.9°C; ΔH; Rate constantProduct distributionThermodynamic data;

Petrie, Simon; Bettens, Ryan P. A.; Freeman, Colin G.; McEwan, Murray J.

Journal of Physical Chemistry, 1993 , vol. 97, # 51 p. 13673 - 13676 Title/Abstract Full Text View citing articles Show Details

170

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Rx-ID: 26147419 Find similar reactions

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Bu, Y.; Ma, L.; Lin, M. C.

Journal of Physical Chemistry, 1993 , vol. 97, # 27 p. 7081 - 7087 Title/Abstract Full Text View citing articles Show Details

in water

in vac.; trap-to-trap distn.;

171

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Rx-ID: 26499925 Find similar reactions

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Frost, Michael J.; Smith, Ian W. M.; Spencer-Smith, Rowland D.

Journal of the Chemical Society, Faraday Transactions, 1993 , vol. 89, # 14 p. 2355 - 2362 Title/Abstract Full Text View citing articles Show Details

Kinetics; byproducts: Cl; Irradiation (UV/VIS); photolysis at room temp.; react. is monitored by infrared fluorescence measurements;

A

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E


172

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Doughty, Alan; Mackie, John C.

Journal of Physical Chemistry, 1992 , vol. 96, # 25 p. 10339 - 10348 Title/Abstract Full Text View citing articles Show Details

in gas T=1350 - 1500°C; P=10640 - 12160 Torr; single-pulse shock tube experiments; MechanismProduct distribution;

A

B

C

D

E

F

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173

Synthesize Find similar Rx-ID: 1615721 Find similar reactions

Doughty, Alan; Mackie, John C.

Journal of Physical Chemistry, 1992 , vol. 96, # 1 p. 272 - 281 Title/Abstract Full Text View citing articles Show Details

T=926.9 - 1226.9°C; P=13680 - 15200 Torr; in argon in a single-pulse shock tube; Product distributionKinetics;

A

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174

Synthesize Find similar Rx-ID: 1922698 Find similar reactions

in gas Rate constant;

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Wladkowski, Brian D.; Brauman, John I.

Journal of the American Chemical Society, 1992 , vol. 114, # 26 p. 10643 - 10644 Title/Abstract Full Text View citing articles Show Details


A

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175

Synthesize Find similar Rx-ID: 3229290 Find similar reactions

Herrmann, Wolfgang A.; Denk, Michael; Behm, Joachim; Scherer, Wolfgang; Klingan, Franz-Robert; et al.

Angewandte Chemie, 1992 , vol. 104, # 11 p. 1489 - 1492 Title/Abstract Full Text Show Details

T=626.9°C;

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176

Synthesize Find similar Rx-ID: 3342081 Find similar reactions

T=926.9 - 1226.9°C; P=13680 - 15200 Torr; in argon in a single-pulse shock tube; Product distributionKinetics;

Doughty, Alan; Mackie, John C.

Journal of Physical Chemistry, 1992 , vol. 96, # 1 p. 272 - 281 Title/Abstract Full Text View citing articles Show Details

177

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Rx-ID: 3539025 Find similar reactions

With perchloric acid; dichloramine-B; sodium perchlorate in water; acetic acid

T=39.9°C; other α-amino acids; var. temp. and conditions; Ea, ΔH(excit.), ΔS(excit.), ΔG(excit.); mechanism; Rate constantKineticsThermodynamic data;

Gowda, B. Thimme; Rao, P. Jagan Mohana

Journal of the Indian Chemical Society, 1992 , vol. 69, # 12 p. 825 - 829 Title/Abstract Full Text Show Details

by pyrolysis at 260-280°C;

Heyns, K.; Pavel, K.

Zeitschrift fuer Naturforschung, 1957 , vol. 12b, p. 97 - 109


Full Text Show Details

Gmelin Handbook: C: MVol.D1, 15.4.2.3, page 127 - 161 Full Text Show Details

A

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178

Synthesize Find similar Rx-ID: 3812467 Find similar reactions

Mosandl, Thomas; Kappe, C. Oliver; Flammang, Robert; Wentrup, Curt

Journal of the Chemical Society, Chemical Communications, 1992 , # 21 p. 1571 - 1573 Title/Abstract Full Text View citing articles Show Details

T=700°C; flash vacuum pyrolysis; also for Maldrum's acid derivatives; Mechanism;

A

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179

Synthesize Find similar Rx-ID: 3877249 Find similar reactions

With silica gel; nickel

T=576.9°C; P=0.008 Torr; Product distribution;

Bock, Hans; Berkner, Bodo

Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1992 , vol. 47, # 11 p. 1551 - 1560 Title/Abstract Full Text Show Details

A

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180

Synthesize Find similar Rx-ID: 3877250 Find similar reactions


Bock, Hans; Berkner, Bodo

Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1992 , vol. 47, # 11 p. 1551 - 1560 Title/Abstract Full Text Show Details

T=896.9°C; P=8E-05 Torr; various temperatures and pressures; Product distribution;

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181

Synthesize Find similar Rx-ID: 5727725 Find similar reactions

Lifshitz, Assa; Wohlfeiler, Dror

Journal of Physical Chemistry, 1992 , vol. 96, # 11 p. 4505 - 4515 Title/Abstract Full Text View citing articles Show Details

T=806.9°C; Arrhenius parameters; variation of temperature (868 - 1080 K); decoposition in reflected shock waves; effect of toluene; mechanism; Product distributionKineticsThermodynamic data;

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182

Synthesize Find similar Rx-ID: 5733854 Find similar reactions

Terentis, Andrew; Doughty, Alan; Mackie, John C.

Journal of Physical Chemistry, 1992 , vol. 96, # 25 p. 10334 - 10339 Title/Abstract Full Text View citing articles Show Details

in gas T=1350 - 1500°C; P=10640 - 12160 Torr; single-pulse shock tube experiments; KineticsProduct distribution;

A

B

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183

Synthesize Find similar Rx-ID: 5738918 Find similar reactions


Wight, Charles A.; Botcher, Tod R.

Journal of the American Chemical Society, 1992 , vol. 114, # 21 p. 8303 - 8304 Title/Abstract Full Text Show Details

Irradiation; Mechanism;

184

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Rx-ID: 5738927 Find similar reactions

Nahon, Laurent; Morin, Paul; Larzilliere, Michel; Nenner, Irene

Journal of Chemical Physics, 1992 , vol. 96, # 5 p. 3628 - 3635 Title/Abstract Full Text View citing articles Show Details

in gas Irradiationlaser induced photodissociation; Mechanism;

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185

Synthesize Find similar Rx-ID: 5742118 Find similar reactions

Behrens, Richard; Bulusu, Suryanarayana

Journal of Physical Chemistry, 1992 , vol. 96, # 22 p. 8877 - 8891 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent) T=195 - 215°C; other temperature; other isotopes; other phase; rates of formation of the gaseous pyrolysis products; Mechanism;

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186

Synthesize Find similar Rx-ID: 5742119 Find similar reactions

T=198°C; other temperature; also with isotopic labelled RDX; deuterium kinetic isotope effects; isotopic crossover experiments; Mechanism;

Behrens, Richard; Bulusu, Suryanarayana


Journal of Physical Chemistry, 1992 , vol. 96, # 22 p. 8891 - 8897 Title/Abstract Full Text View citing articles Show Details

187

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Rx-ID: 26061981 Find similar reactions

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With nickel

react. of CF2Cl2 with NH3 depending on temp. and feed gas composition;

Takita, Yusaku; Imamura, Takeshi; Mizuhara, Yukako; Ishihara, Tatsumi

Journal of Catalysis, 1992 , vol. 136, p. 617 - 620 Full Text View citing articles Show Details

With iron

react. of CF2Cl2 with NH3 depending on temp. and feed gas composition;

Takita, Yusaku; Imamura, Takeshi; Mizuhara, Yukako; Ishihara, Tatsumi

Journal of Catalysis, 1992 , vol. 136, p. 617 - 620 Full Text View citing articles Show Details

With cobalt

react. of CF2Cl2 with NH3 depending on temp. and feed gas composition;

Takita, Yusaku; Imamura, Takeshi; Mizuhara, Yukako; Ishihara, Tatsumi

Journal of Catalysis, 1992 , vol. 136, p. 617 - 620 Full Text View citing articles Show Details

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188

Synthesize Find similar Rx-ID: 26062188 Find similar reactions

189

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With water in water

Kinetics; byproducts: H(1+); react. at pH 3.67-10.6 in acid perchlorate, acetate, phosphate and borate buffer media (30°C, various conditions);

Mishra, Dilip Kumar; Amala Dhas, T. Peter; Bhatnagar, Pankaj; Gupta, Y. K.

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical Chemistry, 1992 , vol. 31, p. 91 - 96 Full Text Show Details


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Rx-ID: 26082547 Find similar reactions

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Copeland, Leon R.; Mohammad, Fida; Zahedi, Mansour; Volman, David H.; Jackson, William M.

Journal of Chemical Physics, 1992 , vol. 96, # 8 p. 5817 - 5826 Title/Abstract Full Text View citing articles Show Details

in gas Kinetics; byproducts: n-C4H9; Irradiation (UV/VIS); (Ar); laser photolysis at 275-455 K; IR emission spectroscopy;

190

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Rx-ID: 26091701 Find similar reactions

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Copeland, Leon R.; Mohammad, Fida; Zahedi, Mansour; Volman, David H.; Jackson, William M.

Journal of Chemical Physics, 1992 , vol. 96, # 8 p. 5817 - 5826 Title/Abstract Full Text View citing articles Show Details

in gas Kinetics; byproducts: i-C4H9; Irradiation (UV/VIS); (Ar); laser photolysis at 275-455 K; IR emission spectroscopy;

191

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Rx-ID: 26091769 Find similar reactions

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With catalyst: 19percent Cr2O3/Al2O3 in melt H2 is passed over molten substrate 10-20 K below its boiling point; monitored by gas chromy.;

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Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details


192

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Rx-ID: 26150193 Find similar reactions

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Copeland, Leon R.; Mohammad, Fida; Zahedi, Mansour; Volman, David H.; Jackson, William M.

Journal of Chemical Physics, 1992 , vol. 96, # 8 p. 5817 - 5826 Title/Abstract Full Text View citing articles Show Details

in gas Kinetics; byproducts: neo-C5H11; Irradiation (UV/VIS); (Ar); laser photolysis at 275-455 K; IR emission spectroscopy;

193

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Rx-ID: 26158008 Find similar reactions

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Copeland, Leon R.; Mohammad, Fida; Zahedi, Mansour; Volman, David H.; Jackson, William M.

Journal of Chemical Physics, 1992 , vol. 96, # 8 p. 5817 - 5826 Title/Abstract Full Text View citing articles Show Details

in gas Kinetics; byproducts: C2H5, HNC; Irradiation (UV/VIS); (Ar); laser photolysis at 275-455 K; IR emission spectroscopy;

194

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Rx-ID: 26165900 Find similar reactions

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in gas Kinetics; byproducts: C3H7; Irradiation (UV/VIS); (Ar); laser photolysis at 275-455 K; IR emission spectroscopy;

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Copeland, Leon R.; Mohammad, Fida; Zahedi, Mansour; Volman, David H.; Jackson, William M.

Journal of Chemical Physics, 1992 , vol. 96, # 8 p. 5817 - 5826 Title/Abstract Full Text View citing articles Show Details


195

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Rx-ID: 26166702 Find similar reactions

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With catalyst: 19percent Cr2O3/Al2O3

react. at 875 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

196

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Rx-ID: 26168133 Find similar reactions

in gaseous matrix Kinetics; byproducts: acetylene, methane, H2; other Radiation; pyrolysis of dilute mixt. of 2-picoline and argon at 1300-1550 K; decompn. pathways proposed; further N-containing org. compds., anal. of reactant mixt. by GC; elem. anal.;;

Terentis, Andrew; Doughty, Alan; Mackie, John C.

Journal of Physical Chemistry, 1992 , vol. 96, # 25 p. 10334 - 10339 Title/Abstract Full Text View citing articles Show Details

197

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Rx-ID: 26168265 Find similar reactions

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With catalyst: 0.5percent Rh/SiO2 or 5percent Ir/SiO2

byproducts: toluene; react. at 825 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

With aluminum oxide

byproducts: benzene; react. at 825 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details


With Catalyst M-Chromium oxide

byproducts: benzene; react. at 925 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

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With magnesium oxide

byproducts: benzene; react. at 925 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

With MnO

byproducts: benzene; react. at 925 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

byproducts: benzene; various conditions (825-925 K, 8-16 h); monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

With catalyst: 0.5percent Pd/Al2O3

byproducts: benzene; react. at 875 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

With catalyst: 0.5percent Rh/Al2O3 or 1percent Pd/Si-Al byproducts: benzene; react. at 825 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

With catalyst: 0.5percent Ru/Al2O3 or 0.5percent Pt/Al2O3

byproducts: benzene; react. at 825 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

With catalyst: 1percent Cr2O3/SiO2 or 10percent Cr2O3/Al2O3

byproducts: benzene; react. at 825 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

With catalyst: 1percent Pd/C or 1percent Pd/MgO or 1percent Pd/SiO2

byproducts: benzene; react. at 825 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

With catalyst: 1percent Pt/SiO2 or 0.4percent Ru/SiO2

byproducts: toluene; react. at 825 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

With catalyst: 1.0percent Pd/ZnO byproducts: benzene; react. at 875 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details

198

Rx-ID: 26168330

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With catalyst: 19percent Cr2O3/Al2O3

react. at 875 K; monitored by gas chromy.;

Weigert; Moguel

Journal of molecular catalysis, 1992 , vol. 75, # 2 p. 209 - 218 Title/Abstract Full Text View citing articles Show Details


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