4-Methylbenzoic acid (p-Toluic acid) by Asch

Reaxys

PubChem

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Reactions (774)

Yield

LabNetwork

Substances (1)

Citations (976)

Conditions

References

298

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Rx-ID: 8540831 Find similar reactions

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Stage #1: methyllithium With B-OMe-9-borabicyclo[3.3.1]nonane in tetrahydrofuran

T=-78 - 20°C; Methylation; 1 h; Stage #2: para-iodobenzoic acid With barium dihydroxide; triphenyl-arsane; bis(benzonitrile)palladium(II) dichloride in tetrahydrofuran; N,N-dimethyl-formamide

T=20°C; Suzuki reaction; 12 h;

299

Braun, Matthew P.; Dean, Dennis C.; Melillo, David G.

Journal of Labelled Compounds and Radiopharmaceuticals, 1999 , vol. 42, # 5 p. 469 - 476 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 16473395 Find similar reactions

Multi-step reaction with 2 steps 1: 99 percent / H2O2, methyltrioxorhenium, NaBr / acetic acid / 10 h / Ambient temperature 2: H2O2, methyltrioxorhenium, NaBr, AcOH / 10 h / Ambient temperature View Scheme

Espenson; Zhu; Zauche

Journal of Organic Chemistry, 1999 , vol. 64, # 4 p. 1191 - 1196 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 99 percent / H2O2, methyltrioxorhenium, NaBr / acetic acid / 10 h / Ambient temperature 2: H2O2, methyltrioxorhenium, NaBr, AcOH / methanol / 10 h / Ambient temperature View Scheme

Espenson; Zhu; Zauche

Journal of Organic Chemistry, 1999 , vol. 64, # 4 p. 1191 - 1196 Title/Abstract Full Text View citing articles Show Details

300

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Rx-ID: 22844748 Find similar reactions

E.I. DU PONT DE NEMOURS AND COMPANY Patent: EP642491 B1, 1999 ;

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Title/Abstract Full Text Show Details

Our prior EP-A-498591 discloses a process for the production of terephthalic acid by the liquid phase oxidation of para-xylene in which mother liquor (comprising mainly water) obtained following conventional crystallisation of purified terephthalic acid in the purification stage is treated to recover further terephthalic acid (and co-precipitated p-toluic acid). A

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301

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B: 24%

With acetic acid in para-xylene

Hide Experimental Procedure

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Daicel Chemical Industries, Ltd.

Patent: US5958821 A1, 1999 ; Title/Abstract Full Text Show Details

E.3:Example E3 Example E3 A mixture of 1.06 grams (10 millimoles) of p-xylene, 0.32 gram (2 millimoles) of N-hydroxyphthalimide, 0.018 gram (0.05 millimole) of acetylacetonatocobalt(III) Co(AA)3 and 25 milliliters of acetic acid was stirred in an oxygen atmosphere at a temperature of 100° C. for 12 hours. As a result, p-xylene was transformed into terephthalic acid (yield 71percent) and p-methylbenzoic acid (yield 24percent) with a transformation rate of 99percent.

302

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Rx-ID: 2000576 Find similar reactions

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75%

With bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide

T=90°C; electrolytic reduction;

Jutand, Anny; Negri, Serge; Mosleh, Adil

Journal of the Chemical Society, Chemical Communications, 1992 , # 23 p. 1729 - 1730 Title/Abstract Full Text View citing articles Show Details

75%

With tetra-n-butylammonium tetrafluoroborate; bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide

T=90°C; electrochemical reaction;

Jutand, Anny; Negri, Serge

European Journal of Organic Chemistry, 1998 , # 9 p. 1811 - 1821 Title/Abstract Full Text View citing articles Show Details

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303

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A: 20% C: 32%

With magnesium chlorite; 9,10-anthracenedicarbonitrile; oxygen in acetonitrile

1 h; IrradiationDCA-sensitized photooxygenation of polyphenylene compounds; rate constants for fluorescence quenching of DCA; DCA-sensitized photoizomerization of 1,2-bis(4methoxyphenyl)cyclopropanes; generation of radical cations; cosensitization; chain mechanism; Product distribution;

Tamai, Toshiyuki; Ichinose, Nobuyuki; Tanaka, Tomoko; Sasuga, Tsuneo; Hashida, Isao; Mizuno, Kazuhiko

Journal of Organic Chemistry, 1998 , vol. 63, # 10 p. 3204 - 3212 Title/Abstract Full Text View citing articles Show Details

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304

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With lithium diisopropyl amide

1.) THF, hexane, -70 deg C, 10 min, 2.) THF, hexane, -70 deg C -> room temperature; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

Wang, Anlai; Maguire, John A.; Biehl, Ed

Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2451 - 2455 Title/Abstract Full Text View citing articles Show Details

With lithium diisopropyl amide

1.) THF, hexane, -70 deg C, 10 min, 2.) THF, hexane, -70 deg C -> room temperature; Yield given. Multistep reaction. Yields of byproduct given;

Wang, Anlai; Maguire, John A.; Biehl, Ed

Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2451 - 2455 Title/Abstract Full Text View citing articles Show Details

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305

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With 2-(2-methoxyphenyl)acetonitrile; lithium diisopropyl amide

1.) THF, hexane, -70 deg C, 10 min; other reagents: LDA/phenylacetonitrile, LDA/4-methoxyphenylacetonitrile, 2.) THF, hexane, -70 deg C -> room temperature; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

Wang, Anlai; Maguire, John A.; Biehl, Ed

Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2451 - 2455 Title/Abstract Full Text View citing articles Show Details

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306

Synthesize Find similar Rx-ID: 4940804 Find similar reactions

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With lithium diisopropyl amide

1.) THF, hexane, -70 deg C, 10 min, 2.) THF, hexane, -70 deg C -> room temperature; Yield given. Multistep reaction. Yields of byproduct given;

307

Wang, Anlai; Maguire, John A.; Biehl, Ed

Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2451 - 2455 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 4946814 Find similar reactions

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With lithium diisopropyl amide

1.) THF, hexane, -70 deg C, 10 min, 2.) THF, hexane, -70 deg C -> room temperature; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

Wang, Anlai; Maguire, John A.; Biehl, Ed

Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2451 - 2455 Title/Abstract Full Text View citing articles Show Details

With lithium diisopropyl amide

1.) THF, hexane, -70 deg C, 10 min, 2.) THF, hexane, -70 deg C -> room temperature; Yield given. Multistep reaction. Yields of byproduct given;

Wang, Anlai; Maguire, John A.; Biehl, Ed

Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2451 - 2455 Title/Abstract Full Text View citing articles Show Details

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308

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Rx-ID: 5007563 Find similar reactions

With tetramethylpiperidine; diisopropylamine

1.) THF, hexane, -70 deg C, 30 min, 2.) THF, -70 deg C, 30 min, then rt. overnight; Yield given. Multistep reaction. Yields of byproduct given;

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Wang, Anlai; Zhang, Hongming; Biehl, Ed

Heterocycles, 1998 , vol. 48, # 2 p. 303 - 310 Title/Abstract Full Text View citing articles Show Details

309

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With sulfuric acid in acetonitrile-D3; water-d2

T=34.85°C; bimolecular rate constant and Arrhenius data (ln A, ΔS<*>, Ea); acid-independent rate constants at 298-338 K; Rate constantThermodynamic data; A

Glover, Stephen A.; Hammond, Gerard P.; Bonin, Antonio M.

Journal of Organic Chemistry, 1998 , vol. 63, # 26 p. 9684 - 9689 Title/Abstract Full Text View citing articles Show Details

310

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Rx-ID: 24664475 Find similar reactions

Mitsubishi Chemical Corporation

Patent: US5760288 A1, 1998 ;

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Title/Abstract Full Text Show Details

25:Example 25

Example 25 The reaction was conducted in the same manner as in Example 14 except that 0.593 g of Ru(acac)3 and 4.06 g of a tri-deficient heteropoly-acid (Na10 SiW9 O34!) were used (ruthenium concentration 1,000 ppm) as a catalyst starting material. Consequently, the conversion of p-xylene was 94percent, and the selectivity for terephthalic acid relative to p-xylene reacted was 55percent. As the other products, carbon dioxide, 4-carboxybenzaldehyde and p-toluic acid were formed in the selectivities of 18percent, 0.93percent and 13.2percent respectively. A

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311

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A: 41% B: 23%

With silica gel

48 h; Irradiation;

Hasegawa, Tadashi; Imada, Manabu; Imase, Yoshihiro; Yamazaki, Yuko; Yoshioka, Michikazu

Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 9 p. 1271 - 1273 Title/Abstract Full Text View citing articles Show Details

A: 41% B: 23%

With silica gel

48 h; Irradiation;

Hasegawa, Tadashi; Imada, Manabu; Imase, Yoshihiro; Yamazaki, Yuko; Yoshioka, Michikazu

Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 9 p. 1271 - 1273 Title/Abstract Full Text View citing articles Show Details

312

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Rx-ID: 4739461 Find similar reactions

A: 3 % Chromat. B: 16% C: 31%

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With ammonium cerium(IV) nitrate

T=70°C; 1 h;

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Giurg; Mlochowski

Polish Journal of Chemistry, 1997 , vol. 71, # 8 p. 1093 - 1101 Title/Abstract Full Text View citing articles Show Details

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313

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Rx-ID: 4832224 Find similar reactions

A: 18% B: 62% C: 18%

Blum, Jochanan; Gelman, Dmitri; Baidossi, Wael; Shakh, Eduard; Rosenfeld, Ayelet; Aizenshtat, Zeev; Wassermann, Birgit C.; Frick, Michael; Heymer, Bernd; Schutte, Stefan; Wernik, Sonja; Schumann, Herbert

Journal of Organic Chemistry, 1997 , vol. 62, # 25 p. 8681 - 8686 Title/Abstract Full Text View citing articles Show Details

With Pd(PPh3)4Cl2 in benzene

T=85°C; 8 h;

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314

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A: 18% B: 95% C: 18%

315

With Pd(PPh3)4Cl2 in benzene

T=85°C; 3 h;

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Journal of Organic Chemistry, 1997 , vol. 62, # 25 p. 8681 - 8686 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 5267668 Find similar reactions

With hydrogenchloride; trimethylhexadecylammonium chloride in 1,4-dioxane; water

T=55°C; Hydrolysis; Kinetics; Further Variations:Reaction partnersReagents;

Ghosh, Kallol K.; Roy, Supriya

Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1997 , vol. 36, # 4 p. 324 - 328 Title/Abstract Full Text View citing articles Show Details

316

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Rx-ID: 3961217 Find similar reactions

With borane; dihydrogen peroxide; cyclohexene

1.) THF; Yield given. Multistep reaction;

Larson, Gerald L.; Ortiz, Margarita; Roca, Marisol Rodriguez de

Synthetic Communications, 1981 , vol. 11, # 7 p. 583 - 590 Title/Abstract Full Text Show Details

With water

0.5 h; Yield given;

Yamamoto, Yasushi; Shimizu, Hideaki; Hamada, Yoshitaka

Journal of Organometallic Chemistry, 1996 , vol. 509, # 2 p. 119 - 122 Title/Abstract Full Text View citing articles Show Details

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317

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Rx-ID: 4423631 Find similar reactions

A: 40% B: 13 % Chromat. C: 19% D: 15 %

With sodium hydroxide; pentacarbonyliron(0); tetrabutylammomium bromide in water; benzene

T=70°C; 52 h; Further byproducts given;

Brunet, Jean-Jacques

Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 1 p. 75 - 82 Title/Abstract Full Text View citing articles Show Details

Chromat.

A: 40% B: 13 % Chromat. C: 19% D: 15 % Chromat.

With sodium hydroxide; pentacarbonyliron(0); tetrabutylammomium bromide in water; benzene

T=70°C; 52 h; Further byproducts given;

Brunet, Jean-Jacques

Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 1 p. 75 - 82 Title/Abstract Full Text View citing articles Show Details

A: 40 % Chromat. B: 13 % Chromat. C: 19% D: 15 % Chromat.

With sodium hydroxide; pentacarbonyliron(0); tetrabutylammomium bromide in water; benzene

T=70°C; 52 h; Further byproducts given;

Brunet, Jean-Jacques

Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 1 p. 75 - 82 Title/Abstract Full Text View citing articles Show Details

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318

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Benedetti, Fabio; Berti, Federico; Colombatti, Alfonso; Ebert, Cynthia; Linda, Paolo; Tonizzo, Federico

Chemical Communications, 1996 , # 12 p. 1417 - 1418 Title/Abstract Full Text View citing articles Show Details

With water in 1,4-dioxane

T=25°C; antibody 312D6, TRIS buffer, aq. NaCl, pH: 8.0; Rate constant;

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319

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Benedetti, Fabio; Berti, Federico; Colombatti, Alfonso; Ebert, Cynthia; Linda, Paolo; Tonizzo, Federico

Chemical Communications, 1996 , # 12 p. 1417 - 1418 Title/Abstract Full Text View citing articles Show Details

With water in 1,4-dioxane

T=25°C; antibody 312D6, TRIS buffer, aq. NaCl, pH: 8.0; Rate constant;

320

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A: 25% B: 26% C: 19%

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With silica gel in dichloromethane

0.0833333 h; Irradiation;

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Hasegawa, Tadashi; Imase, Yoshihiro; Imada, Manabu; Kumakura, Kazushige; Yoshioka, Michikazu

Journal of Physical Organic Chemistry, 1996 , vol. 9, # 10 p. 677 - 682 Title/Abstract Full Text View citing articles Show Details

321

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92%

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Rx-ID: 4633242 Find similar reactions

With sodium periodate; dibenzo-18-crown-6; N-benzyl-N,N,N-triethylammonium chloride in ethanol

5 h; Heating;

Kore; Salunkhe

Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1996 , vol. 35, # 2 p. 151 - 153 Title/Abstract Full Text View citing articles Show Details

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322

Synthesize Find similar Rx-ID: 4789329 Find similar reactions

With hydrogenchloride in 1,4-dioxane

T=55°C; Rate constant;

Ghosh, Kallol K.; Rajput, Surendra K.; Ghosh, Sharmistha

Journal of the Indian Chemical Society, 1996 , vol. 73, # 10 p. 540 - 541 Title/Abstract Full Text View citing articles Show Details

323

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Rx-ID: 17795244 Find similar reactions

Multi-step reaction with 2 steps 1: 79 percent Chromat. / methyl iodide / toluene / 100 h / 100 - 115 °C 2: H2O / 0.5 h View Scheme

Yamamoto, Yasushi; Shimizu, Hideaki; Hamada, Yoshitaka

Journal of Organometallic Chemistry, 1996 , vol. 509, # 2 p. 119 - 122 Title/Abstract Full Text View citing articles Show Details

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324

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With water; 1H-imidazole in acetonitrile

T=25°C; variation of temperature; ΔH(excit.), ΔS(excit.), ΔG(excit.); KineticsThermodynamic data;

Menegheli, Paulo; Farah, Joao P. S.; Seoud, Omar A. El

Berichte der Bunsen-Gesellschaft, 1991 , vol. 95, # 12 p. 1610 - 1615 Title/Abstract Full Text Show Details

With 2-iodosylbenzoic acid; water in acetonitrile

T=18 - 45°C; ΔH(excit.), ΔS(excit.), ΔG(excit.); determination of catalytic effect of o-iodosobenzoic acid; KineticsMechanismThermodynamic data;

Seoud, Omar A. El; Martins, Monica F.

Journal of Physical Organic Chemistry, 1995 , vol. 8, # 10 p. 637 - 646 Title/Abstract Full Text Show Details

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325

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With sulfuric acid in 1,4-dioxane; water

Ghosh, Kallol K.; Ghosh, Sharmistha

T=55°C; ΔH(excit.), ΔS(excit.), ΔG(excit.), kinetic solvent isotope kH/kD effect in the hydrolysis, substituent and temperature effect; Thermodynamic dataRate constantKinetics;

Journal of Organic Chemistry, 1994 , vol. 59, # 6 p. 1369 - 1374 Title/Abstract Full Text View citing articles Show Details

With hydrogenchloride in 1,4-dioxane

T=55°C; Rate constant;

Ghosh, Kallol K.; Krishnani, Kishor K.

Journal of Chemical Research, Miniprint, 1993 , # 12 p. 3143 - 3154 Title/Abstract Full Text Show Details

With hydrogenchloride; N-hexadecyl-N,N,N-trimethylammonium bromide in 1,4-dioxane; water

T=65°C; ΔH(excit.), ΔS(excit.), ΔG(excit.); Rate constantThermodynamic data;

Ghosh, Kallol K.; Sar, Santosh K.

Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1994 , vol. 33, # 1 p. 51 - 54 Title/Abstract Full Text Show Details

Hide Details

With sodium hydroxide; trimethylhexadecylammonium chloride in 1,4-dioxane

T=65°C; with or without var. sufactants; Rate constant;

Ghosh, Kallol K.; Sar, Santosh K.

Journal of the Indian Chemical Society, 1995 , vol. 72, # 9 p. 597 - 602 Title/Abstract Full Text Show Details

With sodium hydroxide in 1,4-dioxane

T=65°C; Rate constant;

Ghosh, Kallol K.; Ghosh, Sharmistha

Journal of the Indian Chemical Society, 1995 , vol. 72, # 9 p. 603 - 608 Title/Abstract Full Text Show Details

326

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Rx-ID: 4158972 Find similar reactions

82%

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With potassium hydroxide; palladium dichloride

T=90°C; 3 h;

Rai, Roopa; Aubrecht, Katherine B.; Collum, David B.

Tetrahedron Letters, 1995 , vol. 36, # 18 p. 3111 - 3114 Title/Abstract Full Text View citing articles Show Details

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327

Synthesize Find similar Rx-ID: 4161247 Find similar reactions

With Oxonereg;; sulfuric acid in water; acetonitrile

T=25°C; var. temp. and solvents; ΔH(excit.), ΔS(excit.); Rate constantKineticsThermodynamic data;

Bunton, Clifford A.; Foroudian, Houshang J.; Kumar, Anurag

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1995 , # 1 p. 33 - 40 Title/Abstract Full Text Show Details

328

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25%

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Rx-ID: 4164112 Find similar reactions

With sulfuryl dichloride

0.166667 h; Ambient temperature;

Lowe; Braden

Archiv der Pharmazie, 1995 , vol. 328, # 3 p. 283 - 285 Title/Abstract Full Text View citing articles Show Details

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329

Synthesize Find similar Rx-ID: 4276873 Find similar reactions

With hydrogenchloride in 1,4-dioxane

T=55°C; var. conc. HCl; ΔH(excit.), ΔS(excit.), ΔG(excit.); Rate constantThermodynamic dataMechanism;

Ghosh, Kallol K.; Ghosh, Sharmistha

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1995 , vol. 34, # 4 p. 315 - 319 Title/Abstract Full Text Show Details

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330

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Rx-ID: 4335550 Find similar reactions

A: 76% B: 13.5%

With tert-Amyl alcohol; sodium hydride; cobalt(II) acetate in tetrahydrofuran

T=40°C; P=760 Torr; 14 h; Irradiation;

Marchal, Joel; Bodiguel, Jacques; Fort, Yves; Caubere, Paul

Journal of Organic Chemistry, 1995 , vol. 60, # 26 p. 8336 - 8340 Title/Abstract Full Text View citing articles Show Details

331

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Rx-ID: 4343316 Find similar reactions

A: 76% B: 13.5%

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With methanol; tert-Amyl alcohol; sodium hydride; cobalt(II) acetate in tetrahydrofuran

T=40°C; P=760 Torr; 14 h; Irradiation;

Marchal, Joel; Bodiguel, Jacques; Fort, Yves; Caubere, Paul

Journal of Organic Chemistry, 1995 , vol. 60, # 26 p. 8336 - 8340 Title/Abstract Full Text View citing articles Show Details

332

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Rx-ID: 4476198 Find similar reactions

Ray, Paresh Chandra; Das, Puspendu Kumar

Journal of Physical Chemistry, 1995 , vol. 99, # 51 p. 17891 - 17895 Title/Abstract Full Text View citing articles Show Details

in methanol

equilibrium constant for dissociation; also in ethylene glycol; Equilibrium constant;

333

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Rx-ID: 1918511 Find similar reactions

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Jenner, G.; Taleb, A. Ben

Journal of Organometallic Chemistry, 1994 , vol. 470, # 1.2 p. 257 - 262 Title/Abstract Full Text View citing articles Show Details

With potassium hydroxide; [(P{(C6H11)3})2Pd(Cl)2]; tri-ruthenium(0)dodecacarbonyl; N-hexadecyl-N,N,N-trimethylammonium bromide

T=160°C; 10 h; A

334

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Rx-ID: 2391767 Find similar reactions

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With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; β-cyclodextrin

T=50°C; 8 h; other aromatic aldehydes, other reagents, var. amount of TEBA and β-cyclododextrin; Product distribution;

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Zhou; Yuan; Xie

Synthetic Communications, 1994 , vol. 24, # 1 p. 43 - 46 Title/Abstract Full Text View citing articles Show Details

335

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Rx-ID: 3950973 Find similar reactions

With 1H-imidazole; potassium chloride in water; acetonitrile

T=25 - 50°C; ΔH(excit.), ΔS(excit.), ΔG(excit.); KineticsThermodynamic data;

Seoud, Omar A. El; Menegheli, Paulo; Pires, Paulo A. R.; Kiyan, Nilo Z.

Journal of Physical Organic Chemistry, 1994 , vol. 7, # 8 p. 431 - 436 Title/Abstract Full Text Show Details

336

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Rx-ID: 3961160 Find similar reactions

With acetate buffer; iodine; α-cyclodextrin

T=25°C; pH 4.8, var. conc. of cyclodextrin; Rate constant;

Davies, D. Martin; Garner, G. Alun; Savage, James R.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1994 , # 7 p. 1531 - 1538 Title/Abstract Full Text View citing articles Show Details

With methyloxirane

Mitsubishi Gas Chemical Company, Inc.

Patent: US3981909 A1, 1976 ;

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Title/Abstract Full Text Show Details

6:EXAMPLE 6

Therefore, the selectivity to propylene oxide, based on the per-p-toluic acid, is 90.8percent by mole, and the reacted per-p-toluic acid is almost all converted to p-toluic acid.

Mitsubishi Gas Chemical Company, Inc.

Patent: US3981909 A1, 1976 ;

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Title/Abstract Full Text Show Details

9:EXAMPLE 9

EXAMPLE 9 200 g of the same per-p-toluic acid product solution containing 31.6percent by weight of per-p-toluic acid as used in Example 8 and 48.2 g (0.830 mole) of allyl alcohol, which corresponds to twice the moles of per-p-toluic acid, are charged into an autoclave, and subjected to reaction at a temperature of 60° to 62°C for 1.5 hours. After the completion of the reaction, the autoclave is cooled, and the contents are withdrawn from the autoclave. The entire amount of the contents is 243.6 g. Deposited crystals are filtered off from the contents, and dried, whereby 52.0 g (0.382 moles) of p-toluic acid is obtained. A

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337

Synthesize Find similar Rx-ID: 3964473 Find similar reactions

With sulfuric acid; dihydrogen peroxide; acetic anhydride; acetic acid

1.) r.t., 4 h; Yield given. Multistep reaction;

Conte, L.; Napoli, M.; Gambaretto, J. P.; Guerrato, A.; Carlini, F. M.

Journal of Fluorine Chemistry, 1994 , vol. 67, # 1 p. 41 - 46 Title/Abstract Full Text View citing articles Show Details

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338

Synthesize Find similar Rx-ID: 4067196 Find similar reactions

A: 14% B: 46%

With oxygen; bismuth mandelate in dimethyl sulfoxide

T=80°C; P=760 Torr; 2.3 h; Rate constant;

Boisselier, Veronique Le; Dunach, Elisabet; Postel, Michele

Journal of Organometallic Chemistry, 1994 , vol. 482, # 1-2 p. 119 - 124 Title/Abstract Full Text View citing articles Show Details

A: 14% B: 46%

With oxygen; bismuth mandelate in dimethyl sulfoxide

T=80°C; P=760 Torr; 2.3 h;

Boisselier, Veronique Le; Dunach, Elisabet; Postel, Michele

Journal of Organometallic Chemistry, 1994 , vol. 482, # 1-2 p. 119 - 124 Title/Abstract Full Text View citing articles Show Details

A: 14% B: 46%

With oxygen; bismuth mandelate in dimethyl sulfoxide

T=80°C; P=760 Torr; 2.3 h;

Boisselier, Veronique Le; Dunach, Elisabet; Postel, Michele

Journal of Organometallic Chemistry, 1994 , vol. 482, # 1-2 p. 119 - 124 Title/Abstract Full Text View citing articles Show Details

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339

Synthesize Find similar Rx-ID: 4153606 Find similar reactions

C: 24%

With dihydrogen peroxide in acetonitrile

72 h; Ambient temperature; Yields of byproduct given;

Tsuno, Takashi; Sugiyama, Kunio; Ago, Hideo

Heterocycles, 1994 , vol. 38, # 12 p. 2631 - 2654 Title/Abstract Full Text View citing articles Show Details

340

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Rx-ID: 1986296 Find similar reactions

65%

With nickel copper; carbon in ethylene glycol dimethyl ether

T=85°C; 20 h;

Marceau, P.; Beguin, F.; Guillaumet, G.

Journal of Organometallic Chemistry, 1988 , vol. 342, p. 137 - 142 Title/Abstract Full Text View citing articles Show Details

24%

With diethylzinc; tetrakis(triphenylphosphine) palladium(0) in hexane; N,N-dimethyl-formamide

T=25°C; 1 h;

Agrios, Konstantinos A.; Srebnik, Morris

Journal of Organic Chemistry, 1993 , vol. 58, # 24 p. 6908 - 6910 Title/Abstract Full Text View citing articles Show Details

341

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With water in 1,4-dioxane

T=25°C; also in the presence of strong mineral acids; Rate constant;

Rx-ID: 1995759 Find similar reactions

Satchell, Derek P. N.; Wassef, Wasfy N.; Bhatti, Zaheer A.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 12 p. 2373 - 2380

Title/Abstract Full Text View citing articles Show Details

342

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Rx-ID: 2124845 Find similar reactions

With water

T=25°C; Rate constant;

Song, Byeong Doo; Jencks, William P.

Journal of the American Chemical Society, 1989 , vol. 111, # 22 p. 8470 - 8479 Title/Abstract Full Text View citing articles Show Details

With perchloric acid; water in 1,4-dioxane

T=25°C; other acyl fluorides; other reagent var. temperature; Mechanism;

Motie, Richard E..; Satchell, Derek P. N.; Wassef, Wasfy N.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 6 p. 1087 - 1090 Title/Abstract Full Text View citing articles Show Details

With perchloric acid; water in 1,4-dioxane

T=25°C; other acyl fluorides; other reagent var. temperature; Rate constant;

Motie, Richard E..; Satchell, Derek P. N.; Wassef, Wasfy N.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 6 p. 1087 - 1090 Title/Abstract Full Text View citing articles Show Details

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343

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Rx-ID: 2138155 Find similar reactions

B: 55%

With sodium tetrachloropalladium (II); sodium carbonate in water

T=50°C; 10 h; Yields of byproduct given;

Grushin, Vladimir V.; Alper, Hovard

Journal of Organic Chemistry, 1993 , vol. 58, # 18 p. 4794 - 4795 Title/Abstract Full Text View citing articles Show Details

344

Synthesize Find similar Rx-ID: 3237708 Find similar reactions

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With pyrene

Irradiation;

Sakurai; Okamoto; Inoue

Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 12 p. 3707 - 3711 Title/Abstract Full Text View citing articles Show Details

With pyrene

Irradiationvar. solvents; MechanismQuantum yield;

Sakurai; Okamoto; Inoue

Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 12 p. 3707 - 3711 Title/Abstract Full Text View citing articles Show Details

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345

Synthesize Find similar Rx-ID: 3390484 Find similar reactions

With sulfuric acid; mercury(II) diacetate; bromic acid in water; acetic acid

T=39.9°C; ΔH(excit.), ΔS(excit), ΔG(excit.); Rate constantKineticsThermodynamic data;

Murthy, N. Krishna; Reddy, Ch. Sanjeeva; Sundaram, E. V.

Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1993 , vol. 32, # 10 p. 899 - 902 Title/Abstract Full Text Show Details

346

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Rx-ID: 18936527 Find similar reactions

Multi-step reaction with 2 steps 1: NaOCl / acetic acid 2: 55 percent / Na2<PdCl4>, Na2CO3 / H2O / 10 h / 50 °C View Scheme

Grushin, Vladimir V.; Alper, Hovard

Journal of Organic Chemistry, 1993 , vol. 58, # 18 p. 4794 - 4795 Title/Abstract Full Text View citing articles Show Details

347

Synthesize Find similar Rx-ID: 1842141 Find similar reactions

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With hydrogenchloride in ethylene glycol dimethyl ether

T=72°C; Rate constantMechanism;

Bennet; Slebocka-Tilk; Brown

Journal of the American Chemical Society, 1992 , vol. 114, # 8 p. 3088 - 3092 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide

T=25°C; Rate constant;

Brown; Bennet; Slebocka-Tilk; Jodhan

Journal of the American Chemical Society, 1992 , vol. 114, # 8 p. 3092 - 3098 Title/Abstract Full Text View citing articles Show Details

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348

Synthesize Find similar

Rx-ID: 1877252 Find similar reactions

With water; lithium perchlorate

T=20°C; var. temp., and conc. LiClO4, also in absence of H2O; ΔH(excit.), ΔS(excit.); Rate constantThermodynamic data;

Karavan, V. S.; Eliseeva, E. E.; Antipova, E. A.

Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 6.2 p. 958 - 963 Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 6 p. 1224 - 1231 Title/Abstract Full Text Show Details

349

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With 2,3,5,6-tetramethylhydroquinone in acetonitrile

T=25°C; Yield given;

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Rx-ID: 1996703 Find similar reactions

Adam, Waldemar; Schoenberger, Andre

Chemische Berichte, 1992 , vol. 125, # 9 p. 2149 - 2154

Title/Abstract Full Text Show Details

With 1,4-dihydroxy naphthalene in acetonitrile

T=25°C; other hydroquinones; Rate constant;

Adam, Waldemar; Schoenberger, Andre

Chemische Berichte, 1992 , vol. 125, # 9 p. 2149 - 2154 Title/Abstract Full Text Show Details

350

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Rx-ID: 2002261 Find similar reactions

11600 % Turnov.

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With potassium hydroxide; [(P{(C6H11)3})2Pd(Cl)2] in water

72 h; Heating;

Grushin, Vladimir V.; Alper, Howard

Journal of the Chemical Society, Chemical Communications, 1992 , # 8 p. 611 - 612 Title/Abstract Full Text View citing articles Show Details

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351

Synthesize Find similar Rx-ID: 2090050 Find similar reactions

With potassium permanganate; perchloric acid; sodium perchlorate; NAF; acetic acid in water

T=29.9°C; var. temperatures; ΔH(excit.), ΔS(excit.); Rate constantKineticsThermodynamic data;

Sikkandar, G.; Ahamed, K. A. Basheer; Kannan, S.

Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1992 , vol. 31, # 11 p. 845 - 848 Title/Abstract Full Text Show Details

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352

Synthesize Find similar

Rx-ID: 2731012 Find similar reactions

A: 13% B: 6% C: 41%

With potassium hydroxide; samarium diiodide in tetrahydrofuran; water

0.00805556 h; Ambient temperature;

Kamochi, Yasuko; Kudo, Tadahiro

Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 11 p. 3049 - 3054 Title/Abstract Full Text Show Details

A: 13% B: 6% C: 41%

With potassium hydroxide; samarium diiodide in tetrahydrofuran; water

0.00805556 h; Ambient temperature;

Kamochi, Yasuko; Kudo, Tadahiro

Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 11 p. 3049 - 3054 Title/Abstract Full Text Show Details

A: 13% B: 6% C: 41%

With potassium hydroxide; samarium diiodide in tetrahydrofuran; water

0.00805556 h; Ambient temperature;

Kamochi, Yasuko; Kudo, Tadahiro

Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 11 p. 3049 - 3054 Title/Abstract Full Text Show Details

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353

Synthesize Find similar Rx-ID: 2756675 Find similar reactions

With oxygen; rose bengal in water; benzene

Irradiationoxidative fragmentation; Quantum yield;

Haugen, Christian M.; Bergmark, William R.; Whitten, David G.

Journal of the American Chemical Society, 1992 , vol. 114, # 26 p. 10293 - 10297 Title/Abstract Full Text View citing articles Show Details

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354

Synthesize Find similar Rx-ID: 3154050 Find similar reactions

With 4,4'-bis-(N,N-dimethylamino)-benzophenone in 1,2-dichloro-ethane

T=25°C; Irradiationother sensitizers; Quantum yield;

Sakurai, Tadamitsu; Utsumi, Kazuo; Ohkita, Akira; Nakamura, Makoto; Inoue, Hiroyasu

Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 7 p. 1950 - 1956 Title/Abstract Full Text Show Details

355

Synthesize Find similar Rx-ID: 3234793 Find similar reactions

A: 60 mg B: 79%

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With sodium hydroxide; water in ethanol; ethyl acetate

T=75 - 85°C; 16 h;

Cho, Jaeeock; Kim, Kyongtae

Journal of Heterocyclic Chemistry, 1992 , vol. 29, # 6 p. 1433 - 1439 Title/Abstract Full Text Show Details

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356

Synthesize Find similar Rx-ID: 3237709 Find similar reactions

With benzophenone in dichloromethane

Irradiationother benzophenone derivatives, var. solvents; Mechanism;

Sakurai, Tadamitsu; Nakamura, Makoto; Hakii, Tsuyoshi; Inoue, Hiroyasu

Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 10 p. 2789 - 2793 Title/Abstract Full Text Show Details

357

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Rx-ID: 19671341 Find similar reactions

Multi-step reaction with 2 steps 1: 2 percent / tetrasulfur tetranitride (S4N4) / 10 h / 115 °C 2: 60 mg / NaOH, water / ethanol; ethyl acetate / 16 h / 75 - 85 °C View Scheme

Cho, Jaeeock; Kim, Kyongtae

Journal of Heterocyclic Chemistry, 1992 , vol. 29, # 6 p. 1433 - 1439 Title/Abstract Full Text Show Details

Multi-step reaction with 2 steps

Cho, Jaeeock; Kim, Kyongtae

1: 39 percent / tetrasulfur tetranitride (S4N4) / chlorobenzene / 48 h / Heating 2: 60 mg / NaOH, water / ethanol; ethyl acetate / 16 h / 75 - 85 °C View Scheme

Journal of Heterocyclic Chemistry, 1992 , vol. 29, # 6 p. 1433 - 1439 Title/Abstract Full Text Show Details

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358

Synthesize Find similar Rx-ID: 1626839 Find similar reactions

A: 64.1% B: 10%

With sulfur in diphenylether

T=280°C; P=5171.5 Torr; 8.33333 h; dependence from conc., reaction temp. and time, pressure, solvent; Product distribution;

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Sickle, Dale E. Van

Journal of Organic Chemistry, 1991 , vol. 56, # 10 p. 3263 - 3267 Title/Abstract Full Text View citing articles Show Details

359

Synthesize Find similar Rx-ID: 2098007 Find similar reactions

With water; 1H-imidazole in acetonitrile

T=15°C; variation of temperature; ΔH(excit.), ΔS(excit.), ΔG(excit.); KineticsThermodynamic data;

Menegheli, Paulo; Farah, Joao P. S.; Seoud, Omar A. El

Berichte der Bunsen-Gesellschaft, 1991 , vol. 95, # 12 p. 1610 - 1615 Title/Abstract Full Text Show Details

360

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88%

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With triethyl borane; trifluorormethanesulfonic acid in 1,2,2-trifluoro-trichloroethane

a) -30 deg C, 30 min, b) room temperature, 6 h;

Rx-ID: 2163839 Find similar reactions

Olah; Wu

Synthesis, 1991 , # 5 p. 407 - 408

Title/Abstract Full Text View citing articles Show Details

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361

Synthesize Find similar Rx-ID: 2393068 Find similar reactions

A: 72.5% B: 2.2%

With ammonium hydroxide; dipotassium peroxodisulfate; copper(II) nitrate

T=25°C; 15 h;

Arora, Pramod K.; Sayre, Lawrence M.

Tetrahedron Letters, 1991 , vol. 32, # 8 p. 1007 - 1010 Title/Abstract Full Text View citing articles Show Details

A: 65% B: 20%

With nickel sulphate; ammonium hydroxide; sodium hydroxide; dipotassium peroxodisulfate in water

3 h; Ambient temperature;

Yamazaki, Shigakazu; Yamazaki, Yasuyuki

Chemistry Letters, 1990 , # 4 p. 571 - 574 Title/Abstract Full Text Show Details

A: 65% B: 20%

With nickel sulphate; ammonium hydroxide; sodium hydroxide; dipotassium peroxodisulfate in water

3 h; Ambient temperature;

Yamazaki, Shigakazu; Yamazaki, Yasuyuki

Chemistry Letters, 1990 , # 4 p. 571 - 574 Title/Abstract Full Text Show Details

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362

Synthesize Find similar Rx-ID: 2482644 Find similar reactions

363

Slebocka-Tilk; Bennet; Hogg, Heather J.; Brown

Journal of the American Chemical Society, 1991 , vol. 113, # 4 p. 1288 - 1294 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide in ethylene glycol dimethyl ether

T=100°C; activation parameters: ΔH(excit.), ΔS(excit.), ΔG(excit.)100 deg C; deuterated reagent; Rate constantMechanismThermodynamic data;

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Rx-ID: 1458816 Find similar reactions

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Jackson, Lorraine B.; Waring, Anthony J.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1990 , # 6 p. 907 - 913 Title/Abstract Full Text View citing articles Show Details

T=25°C; MechanismKinetics;

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364

Synthesize Find similar Rx-ID: 1717523 Find similar reactions

Slebocka-Tilk; Bennet; Keillor; Brown; Guthrie, J. Peter; Jodhan

Journal of the American Chemical Society, 1990 , vol. 112, # 23 p. 8507 - 8514 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide; potassium chloride; water

T=100°C; hydrolysis and oxygen exchange rate constants; solvent kinetic isotope effect with D2O; Rate constant;

365

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90%

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Rx-ID: 1743391 Find similar reactions

With potassium permanganate; N-benzyl-N,N,N-triethylammonium chloride; acetic acid in chloroform; water

4 h; Ambient temperature;

Nai-ju, Huang; Liang-heng, Xu

Synthetic Communications, 1990 , vol. 20, # 10 p. 1563 - 1567 Title/Abstract Full Text Show Details

366

Synthesize Find similar Rx-ID: 1746533 Find similar reactions

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A: 6 % Chromat. B: 58 % Chromat. C: 6 % Chromat.

With air; 2-hydroxyethanethiol; lt;lt;Fe(salen)gt;2Ogt; in acetonitrile

T=20°C; 2 h;

Murata, Satoru; Suzuki, Kaoru; Miura, Masahiro; Nomura, Masakatsu

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 2 p. 361 - 365 Title/Abstract Full Text View citing articles Show Details

A: 6 % Chromat. B: 58 % Chromat. C: 6 % Chromat.

With air; 2-hydroxyethanethiol; lt;lt;Fe(salen)gt;2Ogt; in acetonitrile

T=20°C; 2 h; pyridine, water; diphenyl sulphide;

Murata, Satoru; Suzuki, Kaoru; Miura, Masahiro; Nomura, Masakatsu

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 2 p. 361 - 365 Title/Abstract Full Text View citing articles Show Details

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367

Synthesize Find similar Rx-ID: 1746534 Find similar reactions

A: 5 % Chromat. B: 43 % Chromat. C: 25 % Chromat.

With sodium sulfide; air; lt;lt;Fe(salen)gt;2Ogt; in pyridine; water

T=20°C; 2 h; acetonitrile; 2-mercaptoethanol;

Murata, Satoru; Suzuki, Kaoru; Miura, Masahiro; Nomura, Masakatsu

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 2 p. 361 - 365 Title/Abstract Full Text View citing articles Show Details

A: 5 % Chromat. B: 43 % Chromat. C: 25 % Chromat.

With sodium sulfide; air; lt;lt;Fe(salen)gt;2Ogt; in pyridine; water

T=20°C; 2 h;

Murata, Satoru; Suzuki, Kaoru; Miura, Masahiro; Nomura, Masakatsu

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 2 p. 361 - 365 Title/Abstract Full Text View citing articles Show Details

368

Synthesize Find similar Rx-ID: 1988314 Find similar reactions

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A: 39% B: 46%

With dinitrogen tetraoxide in acetonitrile

T=-20°C; 2 h;

Kim, Yong Hae; Kim, Kweon; Park, Young Jun

Tetrahedron Letters, 1990 , vol. 31, # 27 p. 3893 - 3894 Title/Abstract Full Text View citing articles Show Details

A: 39% B: 46%

With dinitrogen tetraoxide in acetonitrile

T=-20°C; 2 h;

Kim, Yong Hae; Kim, Kweon; Park, Young Jun

Tetrahedron Letters, 1990 , vol. 31, # 27 p. 3893 - 3894 Title/Abstract Full Text View citing articles Show Details

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369

Synthesize Find similar

Rx-ID: 2000347 Find similar reactions

With n-butyllithium; N,N,N',N,-tetramethylethylenediamine; nickel

Multistep reaction;

Cabiddu, Salvatore; Fattuoni, Claudia; Floris, Costantino; Gelli, Gioanna; Melis, Stefana; Sotgiu, Francesca

Tetrahedron, 1990 , vol. 46, # 3 p. 861 - 884 Title/Abstract Full Text View citing articles Show Details

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370

Synthesize Find similar Rx-ID: 2000416 Find similar reactions

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With n-butyllithium; nickel

Multistep reaction;

Cabiddu, Salvatore; Fattuoni, Claudia; Floris, Costantino; Gelli, Gioanna; Melis, Stefana; Sotgiu, Francesca

Tetrahedron, 1990 , vol. 46, # 3 p. 861 - 884 Title/Abstract Full Text View citing articles Show Details

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371

Synthesize Find similar

Rx-ID: 2002270 Find similar reactions

A: 57% B: 6% C: 20% D: 8 % Chromat.

Brunet, Jean-Jacques; Taillefer, Marc

Journal of Organometallic Chemistry, 1990 , vol. 384, p. 193 - 197 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide; tetrabutylammomium bromide; dicobalt octacarbonyl; pentacarbonyliron(0) in water; benzene

T=65°C; 48 h; Further byproducts given;

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372

Synthesize Find similar Rx-ID: 2005654 Find similar reactions

With water; copper; trifluoroacetic acid in acetone

1 h; Rate constant;

Shul'pin, G. B.; Kitaigorodskii, A. N.

J. Gen. Chem. USSR (Engl. Transl.), 1990 , vol. 60, # 5 p. 1042 - 1045,920 - 921 Title/Abstract Full Text Show Details

With water; copper; trifluoroacetic acid in pyridine

1 h; Rate constant;

Shul'pin, G. B.; Kitaigorodskii, A. N.

J. Gen. Chem. USSR (Engl. Transl.), 1990 , vol. 60, # 5 p. 1042 - 1045,920 - 921 Title/Abstract Full Text Show Details

With water; iron; trifluoroacetic acid in acetone

1 h; Rate constant;

Shul'pin, G. B.; Kitaigorodskii, A. N.

J. Gen. Chem. USSR (Engl. Transl.), 1990 , vol. 60, # 5 p. 1042 - 1045,920 - 921 Title/Abstract Full Text Show Details

Hide Details

With water; iron; trifluoroacetic acid in pyridine

1 h; Rate constant;

Shul'pin, G. B.; Kitaigorodskii, A. N.

J. Gen. Chem. USSR (Engl. Transl.), 1990 , vol. 60, # 5 p. 1042 - 1045,920 - 921 Title/Abstract Full Text Show Details

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373

Synthesize Find similar Rx-ID: 2036628 Find similar reactions

With sodium hydroxide; potassium chloride; water

T=100°C; hydrolysis and oxygen exchange rate constants; Rate constant;

Slebocka-Tilk; Bennet; Keillor; Brown; Guthrie, J. Peter; Jodhan

Journal of the American Chemical Society, 1990 , vol. 112, # 23 p. 8507 - 8514 Title/Abstract Full Text View citing articles Show Details

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374

Synthesize Find similar Rx-ID: 2085657 Find similar reactions

With sodium hydroxide; potassium chloride; water

T=100°C; other primary, secondary, and tertiary toluamides; hydrolysis and oxygen exchange rate constants; Product distributionRate constantMechanism;

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Slebocka-Tilk; Bennet; Keillor; Brown; Guthrie, J. Peter; Jodhan

Journal of the American Chemical Society, 1990 , vol. 112, # 23 p. 8507 - 8514 Title/Abstract Full Text View citing articles Show Details

375

Synthesize Find similar Rx-ID: 2117057 Find similar reactions

With sodium hydroxide; potassium chloride; water

T=100°C; hydrolysis and oxygen exchange rate constants; Rate constant;

Slebocka-Tilk; Bennet; Keillor; Brown; Guthrie, J. Peter; Jodhan

Journal of the American Chemical Society, 1990 , vol. 112, # 23 p. 8507 - 8514 Title/Abstract Full Text View citing articles Show Details

376

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90%

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Rx-ID: 2117680 Find similar reactions

With sodium tetrahydroborate; sodium hydrogen telluride in ethanol

1) 5 deg C, 0.5h, 2) RT, 1h; also with Se as cat.;

Huang, Zhi-Zhen; Zhou, Xun-Jun

Synthesis, 1990 , # 7 p. 633 - 634 Title/Abstract Full Text Show Details

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377

Synthesize Find similar Rx-ID: 2141882 Find similar reactions

A: 28% B: 64%

With dinitrogen tetraoxide in acetonitrile

T=-20°C; 2 h;

Kim, Yong Hae; Kim, Kweon; Park, Young Jun

Tetrahedron Letters, 1990 , vol. 31, # 27 p. 3893 - 3894 Title/Abstract Full Text View citing articles Show Details

A: 28% B: 64%

With dinitrogen tetraoxide in acetonitrile

T=-20°C; 2 h;

Kim, Yong Hae; Kim, Kweon; Park, Young Jun

Tetrahedron Letters, 1990 , vol. 31, # 27 p. 3893 - 3894 Title/Abstract Full Text View citing articles Show Details

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378

Synthesize Find similar Rx-ID: 2221056 Find similar reactions

With water; sulfuric acid

T=25°C; Rate constantMechanism;

Challis, Brian C.; Rosa, Eduarda; Iley, Jim; Norberto, Fatima

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1990 , # 1 p. 179 - 183

Title/Abstract Full Text View citing articles Show Details

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379

Synthesize Find similar Rx-ID: 2421924 Find similar reactions

Slebocka-Tilk; Bennet; Keillor; Brown; Guthrie, J. Peter; Jodhan

Journal of the American Chemical Society, 1990 , vol. 112, # 23 p. 8507 - 8514 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide; potassium chloride; water

T=100°C; hydrolysis and oxygen exchange rate constants; solvent kinetic isotope effect with D2O; Δ(excit); Rate constantThermodynamic data;

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380

Synthesize Find similar

Rx-ID: 3303188 Find similar reactions

Jackson, Lorraine B.; Waring, Anthony J.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1990 , # 6 p. 907 - 913 Title/Abstract Full Text View citing articles Show Details

T=25°C; MechanismKinetics;

381

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79%

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With carbon monoxide; water; sodium acetate; (dipp)2Pd(O) in N,N-dimethyl-formamide

T=150°C; P=3620.04 Torr; 20 h;

Rx-ID: 278162 Find similar reactions

Ben-David, Yehoshua; Portnoy, Moshe; Milstein, David

Journal of the American Chemical Society, 1989 , vol. 111, # 23 p. 8742 - 8744 Title/Abstract Full Text View citing articles Show Details

With sodium; benzene

Behandeln des Reaktionsgemisches mit Kohlendioxid;

Winthrop Chem. Co.

Patent: US2012372 , 1932 ;

With cyclohexane; sodium

Behandeln des Reaktionsgemisches mit Kohlendioxid;

Winthrop Chem. Co.

Patent: US2012372 , 1932 ;

Full Text Show Details

Gilman; Pacevitz; Baine

Journal of the American Chemical Society, 1940 , vol. 62, p. 1514,1519 Full Text View citing articles Show Details

I.G. Farbenind.

Patent: DE644486 , 1931 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 279 Full Text Show Details

Full Text Show Details

Gilman; Pacevitz; Baine

Journal of the American Chemical Society, 1940 , vol. 62, p. 1514,1519 Full Text View citing articles Show Details

I.G. Farbenind.

Patent: DE644486 , 1931 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 279 Full Text Show Details

Hide Details

With sodium; Petroleum ether

Behandeln des Reaktionsgemisches mit Kohlendioxid;

Winthrop Chem. Co.

Patent: US2012372 , 1932 ;

With carbon dioxide; sodium; benzene

Morton; Le Fevre; Hechenbleikner

Journal of the American Chemical Society, 1936 , vol. 58, p. 754 Full Text View citing articles Show Details

Morton; Stevens

Journal of the American Chemical Society, 1931 , vol. 53, p. 4028,4031 Full Text View citing articles Show Details

382

Full Text Show Details

Gilman; Pacevitz; Baine

Journal of the American Chemical Society, 1940 , vol. 62, p. 1514,1519 Full Text View citing articles Show Details

I.G. Farbenind.

Patent: DE644486 , 1931 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 279 Full Text Show Details

beim Leiten ueber auf Bimsstein aufgebrachte erhitzte Metall-Katalysatoren;

Dieterle; Eschenbach

Archiv der Pharmazie (Weinheim, Germany), 1927 , p. 193 Full Text View citing articles Show Details

With sodium; toluene

Behandeln des Reaktionsgemisches mit Kohlendioxid;

Winthrop Chem. Co.

Patent: US2012372 , 1932 ; Full Text Show Details

Gilman; Pacevitz; Baine

Journal of the American Chemical Society, 1940 , vol. 62, p. 1514,1519 Full Text View citing articles Show Details

I.G. Farbenind.

Patent: DE644486 , 1931 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 279 Full Text Show Details

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Rx-ID: 2062952 Find similar reactions

With sulfuric acid; mercury(II) diacetate; bromate anion in water; acetic acid

Mechanism;

Reddy, Ch. Sanjeeva; Sundaram, E. V.

Tetrahedron, 1989 , vol. 45, # 7 p. 2109 - 2126 Title/Abstract Full Text View citing articles Show Details

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383

Synthesize Find similar Rx-ID: 2070805 Find similar reactions

With mercury(II) diacetate; bromate anion; ruthenium trichloride in sulfuric acid; acetic acid

T=35.9°C; E(activ.), ΔG(excit.), ΔH(excit.), ΔS(excit.), other temperatures; various substrate and reagent concentrations, various solvent composition; KineticsMechanismThermodynamic data;

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Narasimha Char, P.; Sondu, S.; Sethuram, B.; Navaneeth Rao, T.

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1989 , vol. 28, # 1 p. 36 - 39 Title/Abstract Full Text Show Details

384

Synthesize Find similar Rx-ID: 2125353 Find similar reactions

With lithium hydroxide

Multistep reaction;

Morozov, A. A.

J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 1.2 p. 215 - 222,186 - 192 Title/Abstract Full Text Show Details

With lithium hydroxide in water

enthalpy of stepwise dissociation, entropy changes; Equilibrium constantThermodynamic data;

Morozov, A. A.

J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 1.2 p. 215 - 222,186 - 192

Title/Abstract Full Text Show Details

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385

Synthesize Find similar Rx-ID: 2131639 Find similar reactions

A: 18% B: 67%

With amalgamated magnesium; titanium tetrachloride in tetrahydrofuran

0 deg C -> room temperature, 2 h;

Satyanarayana, K.; Chidambaram, N.; Chandrasekaran, S.

Synthetic Communications, 1989 , vol. 19, # 11-12 p. 2159 - 2166 Title/Abstract Full Text Show Details

A: 18% B: 67%

With amalgamated magnesium; titanium tetrachloride in tetrahydrofuran

0 deg C -> room temperature, 2 h;

Satyanarayana, K.; Chidambaram, N.; Chandrasekaran, S.

Synthetic Communications, 1989 , vol. 19, # 11-12 p. 2159 - 2166 Title/Abstract Full Text Show Details

386

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Rx-ID: 2392129 Find similar reactions

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Baumstark, A. L.; Beeson, M.; Vasquez, P. C.

Tetrahedron Letters, 1989 , vol. 30, # 41 p. 5567 - 5570 Title/Abstract Full Text View citing articles Show Details

in acetone

18 h; Ambient temperatureopen to the atmosphere and under inert gas; MechanismProduct distribution;

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387

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Rx-ID: 2548069 Find similar reactions

A: 6% B: 9% C: 2% D: 20%

With oxygen in isopropyl alcohol

4 h; Irradiation;

Yoshioka, Michikazu; Funayama, Kazuhiko; Hasegawa, Tadashi

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 1411 - 1414 Title/Abstract Full Text Show Details

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388

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A: 22% B: 9% C: 15%

With oxygen in benzene

4 h; IrradiationMeCN, pentane, iPrOH;

Yoshioka, Michikazu; Funayama, Kazuhiko; Hasegawa, Tadashi

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 1411 - 1414 Title/Abstract Full Text Show Details

A: 22% B: 9% C: 15%

With oxygen in benzene

4 h; Irradiationpentane, iPrOH;

Yoshioka, Michikazu; Funayama, Kazuhiko; Hasegawa, Tadashi

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 1411 - 1414 Title/Abstract Full Text Show Details

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389

Synthesize Find similar Rx-ID: 2563102 Find similar reactions

B: 8% C: 30%

With lead(IV) acetate in dichloromethane

T=0°C; Yield given;

Theocharis; Maroulis; Hadjiantoniou-Maroulis; Alexandrou

Journal of the Chemical Society, Perkin Transactions 1, 1989 , # 3 p. 619 - 621 Title/Abstract Full Text View citing articles Show Details

B: 8% C: 30%

With lead(IV) acetate in dichloromethane

T=0°C;

Theocharis; Maroulis; Hadjiantoniou-Maroulis; Alexandrou

Journal of the Chemical Society, Perkin Transactions 1, 1989 , # 3 p. 619 - 621 Title/Abstract Full Text View citing articles Show Details

390

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Rx-ID: 2723125 Find similar reactions

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Bentley, T. William; Koo, In Sun

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 1385 - 1392 Title/Abstract Full Text View citing articles Show Details

in water

T=25°C; Rate constant;

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391

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Rx-ID: 2723181 Find similar reactions

Bentley, T. William; Koo, In Sun

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 1385 - 1392 Title/Abstract Full Text View citing articles Show Details

in water

T=25°C; Rate constant;

392

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93%

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Rx-ID: 3250919 Find similar reactions

With disodium telluride in N,N-dimethyl-formamide

12 h; Ambient temperature;

Suzuki, Hitomi; Padmanabhan, Seetharamaiyer; Ogawa, Takuji

Chemistry Letters, 1989 , p. 1017 - 1020 Title/Abstract Full Text Show Details

393

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Rx-ID: 3958762 Find similar reactions

A: 4 % Chromat. B: 78 % Chromat.

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Kamigata, Nobumasa; Satoh, Akira; Yoshida, Masato; Kameyama, Masayuki

Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 605 - 607 Title/Abstract Full Text Show Details

With tetrakis(triphenylphosphine) palladium(0) in acetic acid; benzene

T=80°C; 2 h;

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394

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Rx-ID: 4027379 Find similar reactions

A: 6 % Chromat. B: 37 % Chromat. C: 35 % Chromat.

With tetrakis(triphenylphosphine) palladium(0) in acetic acid; benzene

T=80°C; 2 h;

Kamigata, Nobumasa; Satoh, Akira; Yoshida, Masato; Kameyama, Masayuki

Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 605 - 607 Title/Abstract Full Text Show Details

A: 6 % Chromat. B: 37 % Chromat. C: 35 % Chromat.

With tetrakis(triphenylphosphine) palladium(0) in acetic acid; benzene

T=80°C; 2 h;

Kamigata, Nobumasa; Satoh, Akira; Yoshida, Masato; Kameyama, Masayuki

Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 605 - 607 Title/Abstract Full Text Show Details

395

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Rx-ID: 4027380 Find similar reactions

A: 6 % Chromat. B: 1 % Chromat. C: 37 % Chromat. D: 35 % Chromat.

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Kamigata, Nobumasa; Satoh, Akira; Yoshida, Masato; Kameyama, Masayuki

Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 605 - 607 Title/Abstract Full Text Show Details

With tetrakis(triphenylphosphine) palladium(0) in acetic acid; benzene

T=80°C; 2 h; various arylazo aryl sulfones investigated; Product distribution;

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396

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Rx-ID: 4030989 Find similar reactions

A: 3 % Chromat. B: 34 % Chromat. C: 42 % Chromat.

With tetrakis(triphenylphosphine) palladium(0) in acetic acid; benzene

T=80°C; 2 h;

Kamigata, Nobumasa; Satoh, Akira; Yoshida, Masato; Kameyama, Masayuki

Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 605 - 607 Title/Abstract Full Text Show Details

A: 3 % Chromat. B: 34 % Chromat. C: 42 % Chromat.

With tetrakis(triphenylphosphine) palladium(0) in acetic acid; benzene

T=80°C; 2 h;

Kamigata, Nobumasa; Satoh, Akira; Yoshida, Masato; Kameyama, Masayuki

Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 605 - 607 Title/Abstract Full Text Show Details