4-Methylbenzoic acid (p-Toluic acid) by Asch

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Reactions (774)

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References

Synthesize Find similar 100%

With oxygen; potassium hydoxide in methanol; water

T=50°C; P=760.051 Torr; 4 h;

Synthesize Find similar

Rx-ID: 267471 Find similar reactions

WISCONSIN ALUMNI RESEARCH FOUNDATION; Stahl, Shannon S.; Powell, Adam B.; Root, Thatcher W.; Mannel, David S.; Ahmed, Maaz S.

Patent: US9593064 B2, 2017 ; Location in patent: Sheet 7; 20 ; Title/Abstract Full Text Show Details

99%

With oxygen; potassium hydoxide in toluene

T=100°C; P=760.051 Torr; 12 h;

Yang, Huimin; Cui, Xinjiang; Deng, Youquan; Shi, Feng

RSC Advances, 2014 , vol. 4, # 104 p. 59754 - 59758 Title/Abstract Full Text View citing articles Show Details

98%

With periodic acid; pyridinium chlorochromate in acetonitrile

Hunsen, Mo

Synthesis, 2005 , # 15 art. no. M00905SS, p. 2487 - 2490 Title/Abstract Full Text View citing articles Show Details

98%

With periodic acid; PFC in acetonitrile

Hunsen, Mo

T=0°C; 3 h;

Journal of Fluorine Chemistry, 2005 , vol. 126, # 9-10 p. 1356 - 1360 Title/Abstract Full Text View citing articles Show Details

96%

With sodium periodate; MnTEPyP in water

T=60°C; 4 h;

Ren, Qing-Gang; Chen, Shao-Yun; Zhou, Xian-Tai; Ji, Hong-Bing

Bioorganic and Medicinal Chemistry, 2010 , vol. 18, # 23 p. 8144 - 8149 Title/Abstract Full Text View citing articles Show Details

96%

With dihydrogen peroxide in water; toluene

T=20 - 85°C; 4 h;

Hu, Yu Lin; Ma, Xiao Yun; Ge, Qiang; Lu, Ming

Acta Chimica Slovenica, 2010 , vol. 57, # 4 p. 927 - 930 Title/Abstract Full Text View citing articles Show Details

95.6%

With silica-supported Jones reagent in dichloromethane

0.035 h;

Wiles, Charlotte; Watts, Paul; Haswell, Stephen J.

Tetrahedron Letters, 2006 , vol. 47, # 30 p. 5261 - 5264 Title/Abstract Full Text View citing articles Show Details

95%

With lithium hydroxide monohydrate; oxygen in water

T=25°C; 12 h;

Tang, Lin; Guo, Xuefeng; Li, Yunfeng; Zhang, Shuai; Zha, Zhenggen; Wang, Zhiyong

Chemical Communications, 2013 , vol. 49, # 45 p. 5213 - 5215 Title/Abstract Full Text View citing articles Show Details

94%

Stage #1: With Oxonereg;; sodium 2-iodobenzenesulfonate in acetonitrile

T=70°C; 1 h; Stage #2: With water in acetonitrile

3 h;

Uyanik, Muhammet; Akakura, Matsujiro; Ishihara, Kazuaki

Journal of the American Chemical Society, 2009 , vol. 131, p. 251 - 262 Title/Abstract Full Text View citing articles Show Details

94%

With [MnIV,IV2(μ-O)3(N,N',N''-trimethyl-1,4,7-triazacyclononane)2] (PF6)2*H2O; dihydrogen peroxide; salicylic acid in water; acetonitrile

T=20°C;

Saisaha, Pattama; Buettner, Lea; Van Der Meer, Margarethe; Hage, Ronald; Feringa, Ben L.; Browne, Wesley R.; De Boer, Johannes W.

Advanced Synthesis and Catalysis, 2013 , vol. 355, # 13 p. 2591 - 2603 Title/Abstract Full Text View citing articles Show Details

94%

With Oxonereg;; pre-IBS; water in acetonitrile

T=70°C; 4 h; chemoselective reaction;

Uyanik, Muhammet; Kazuaki, Kazuaki

Organic Syntheses, 2012 , vol. 89, p. 105 - 114 Title/Abstract Full Text View citing articles Show Details

93%

With potassium pyrosulfate; potassium aquapentachlororuthenate(III); potassium hydoxide

T=20°C; 0.5 h; Sonication; Catalytic behavior; Hide Experimental Procedure

Shoair, Abdel Ghany F.

Journal of Molecular Liquids, 2015 , vol. 206, p. 68 - 74 Title/Abstract Full Text View citing articles Show Details

2.2.3. Ultrasonic-assisted catalytic dehydrogenation of primary amines to nitriles by trans-[RuO3(OH)2]2−/S2O8 2− To 50 cm3 of trans-[RuO3(OH)2]2-/S2O8 2- reagent, primary amine (2mmol) was added, the reaction mixture turned dark green. The reaction mixture was further irradiated for half an hour, after which time, the reaction is completed since the original orange color of ruthenate reappears. The mixture was then extracted with diethyl ether(3 × 25 cm3). The ether extracts were dried over anhydrous MgSO4then filtered and evaporated to give the product. Similarly, nitriles were hydrated to their respective amides at 100 °C. Also, primary alcohols were oxidized to their respective carboxylicacids. The alkaline aqueous layer was acidified with 2 M H2SO4 to pH 2 and extracted with diethyl ether. The extract was dried over anhydrous MgSO4 then filtered and evaporated to give the product.

93%

With oxygen; Azobenzene; sodium hydroxide in 1,4-dioxane

T=80°C; 24 h;

Liu, Chengkou; Fang, Zheng; Yang, Zhao; Li, Qingwen; Guo, Shiyu; Guo, Kai

RSC Advances, 2015 , vol. 5, # 97 p. 79699 - 79702 Title/Abstract Full Text View citing articles Show Details

92%

With sodium bromate; CeEPS10 in acetonitrile

24 h; Heating;

Al-Haq, Nazli; Sullivan, Alice C.; Wilson, John R. H.

Tetrahedron Letters, 2003 , vol. 44, # 4 p. 769 - 771 Title/Abstract Full Text View citing articles Show Details

92%

With oxygen; sodium t-butanolate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride in dichloromethane

T=20°C; 30 h; Molecular sieve; Reagent/catalyst; Hide Experimental Procedure

Yu, Dong-Fang; Xing, Ping; Jiang, Biao

Tetrahedron, 2015 , vol. 71, # 25 p. 4269 - 4273 Title/Abstract Full Text View citing articles Show Details

4.1. General procedure for the oxidation of aryl alcohol 1a-1o, or 6a-6h

General procedure: Under Oxygen atmosphere, aryl alcohol (2.00 mmol), precatalyst(SIMesHCl or SIPrHCl, 0.06 mmol), NaOtBu (960.5 mg,10.00 mmol), and 1 g 3 A molecular sieve were added todichloromethane (20 mL). This solutionwas allowed to stir for 30 h.After filtrating through a pad of Celite, the cake was added tohydrochloric acid (2N, 50 mL) and extracted with ethyl acetate(50 mL3). The organic layer was dried over Na2SO4 and concentratedunder reduced pressure. The products did not need furtherpurification. 91%

With potassium hydroxide; air in water

T=26.84°C; 4 h;

Tsunoyama, Hironori; Tsukuda, Tatsuya; Sakurai, Hidehiro

Chemistry Letters, 2007 , vol. 36, # 2 p. 212 - 213 Title/Abstract Full Text View citing articles Show Details

91%

With sodium tetrahydroborate; 1 Pd/C; water; potassium hydoxide in methanol

T=20°C; 12 h; In air;

An, Gwangil; Ahn, Hyunseok; De Castro, Kathlia A.; Rhee, Hakjune

Synthesis, 2010 , # 3 art. no. F19009SS, p. 477 - 485 Title/Abstract Full Text View citing articles Show Details

90%

With methyl 3,5-bis((1H-1,2,4-triazol-1-yl)methyl)benzoate; oxygen; sodium acetate; nickel dibromide

T=120°C; P=760.051 Torr; 72 h;

Urgoitia; Sanmartin; Herrero; Domínguez

Chemical Communications, 2015 , vol. 51, # 23 p. 4799 - 4802 Title/Abstract Full Text View citing articles Show Details

90%

With tert.-butylhydroperoxide in water

T=60°C; 4 h; Inert atmosphereGreen chemistry;

Azizi, Kobra; Esfandiary, Naghmeh; Karimi, Meghdad; Yazdani, Elahe; Heydari, Akbar

RSC Advances, 2016 , vol. 6, # 92 p. 89313 - 89321 Title/Abstract Full Text View citing articles Show Details

88%

Stage #1: With [RuCl2(p-cymene)(iPr2-imy)]; tricyclohexylphosphine tetrafluoroborate; potassium hydoxide in toluene

6 h; Schlenk techniqueInert atmosphereReflux; Stage #2: With hydrogenchloride in water

pH=1;

Santilli, Carola; Makarov, Ilya S.; Fristrup, Peter; Madsen, Robert

Journal of Organic Chemistry, 2016 , vol. 81, # 20 p. 9931 - 9938 Title/Abstract Full Text View citing articles Show Details

87%

With 1,4-diaza-bicyclo[2.2.2]octane; oxygen; copper(II) 2-ethylhexanoate; vanadyl acetylacetonate

T=95°C; P=760.051 Torr; 24 h;

Jiang, Nan; Ragauskas, Arthur J.

Journal of Organic Chemistry, 2007 , vol. 72, # 18 p. 7030 - 7033 Title/Abstract Full Text View citing articles Show Details

87%

With O40PW12(3-)*3C17H38NO3S(1+); dihydrogen peroxide T=70°C; 4 h; Green chemistry; Hide Experimental Procedure

Li, Xinzhong; Cao, Rong; Lin, Qi

Catalysis Communications, 2015 , vol. 69, p. 5 - 10 Title/Abstract Full Text View citing articles Show Details

2.3. General procedure for oxidation of alcohols

General procedure: A mixture of S4SiIL or S3PIL (0.05mmol) and alcohol (30mmol) in a 25 mL flask fitted with a reflux condenser was heated to the reactiontemperature, then the required amount of aqueous H2O2 was addeddropwise under stirring. The progress of the reaction was monitored by TLC (GF254 silica gel coloration in phosphomolybdic acid/ethanol for aromatic alcohol, in KMnO4 solution for aliphatic alcohol). After the completion, the reaction mixture was extracted with diethyl ether(3 × 20 mL), solvent was evaporated in a vacuum. The residual was analyzedby gas chromatography (HP 6890) equippedwith a flame ionizationdetector and an SE-54 column. The aqueous phase was subjected torotary evaporation, and then was dried at 85 °C under a vacuum for 8 hto give regenerated ionic liquids. Pure oxidation products were obtainedby column chromatography (petroleum ether-ethyl acetate 9:1 (V/V))and identified by the comparison of their IR and 1H NMR spectra withthose of authentic samples. 87%

With C32H25Cl2N6O2Rh2(1+)*Cl(1-); sodium hydroxide in water T=100°C; 12 h; Sealed tubeGreen chemistry;

Wang, Xuewei; Wang, Chao; Liu, Yuxuan; Xiao, Jianliang

Green Chemistry, 2016 , vol. 18, # 17 p. 4605 - 4610 Title/Abstract Full Text View citing articles Show Details

86%

With Styrene oxide; [(C6H5)3P]3Ru(CO)(Cl)H in toluene

T=90°C; 12 h; Inert atmosphere;

Barati, Behjat; Moghadam, Majid; Rahmati, Abbas; Tangestaninejad, Shahram; Mirkhani, Valiollah; Mohammadpoor-Baltork, Iraj

Synlett, 2013 , vol. 24, # 1 p. 90 - 96 Title/Abstract Full Text View citing articles Show Details

85%

With sodium hydroxide; osmium(VIII) oxide; sulfuric acid; potassium hexacyanoferrate(III) in water

3 h; Ambient temperature;

Bailey, Alan J.; Bhowon, Minu G.; Griffith, William P.; Shoair, Abdel G. F.; White, Andrew J. P.; Williams, David J.

Journal of the Chemical Society - Dalton Transactions, 1997 , # 18 p. 3245 - 3250 Title/Abstract Full Text View citing articles Show Details

83%

With C14H14N6O2; oxygen; sodium acetate; palladium diacetate

T=120°C; P=760.051 Torr; 72 h;

Urgoitia, Garazi; Maiztegi, Ainhoa; Sanmartin, Raul; Herrero, María Teresa; Domínguez, Esther

RSC Advances, 2015 , vol. 5, # 125 p. 103210 - 103217 Title/Abstract Full Text View citing articles Show Details

81%

With oxygen; sodium carbonate in water

T=100°C; P=52505.3 Torr; 0.533333 h; Flow reactorGreen chemistry;

Osako, Takao; Torii, Kaoru; Uozumi, Yasuhiro

RSC Advances, 2015 , vol. 5, # 4 p. 2647 - 2654 Title/Abstract Full Text View citing articles Show Details

80%

With sodium tungstate; dihydrogen peroxide; [Me(n-C8H17)3N]HSO4

T=90°C; 12 h;

Sato, Kazuhiko; Takagi, Junko; Aoki, Masao; Noyori, Ryoji

Tetrahedron Letters, 1998 , vol. 39, # 41 p. 7549 - 7552 Title/Abstract Full Text View citing articles Show Details

80%

With dihydrogen peroxide; [Me(n-C8H17)3N]HSO4; sodium tungstate in water

T=90°C; Oxidation; 12 h;

Sato, Kazuhiko; Aoki, Masao; Takagi, Junko; Zimmermann, Klaus; Noyori, Ryoji

Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 10 p. 2287 - 2306 Title/Abstract Full Text View citing articles Show Details

78.3%

With tert.-butylhydroperoxide

T=60°C; 15 h;

Zhang, Yuecheng; Chu, Ruosi; Zhang, Hongyu; Zhao, Jiquan

Transition Metal Chemistry, 2017 , vol. 42, # 2 p. 105 - 116

Hide Experimental Procedure

Title/Abstract Full Text View citing articles Show Details

Catalytic oxidation of alcohols

General procedure: In a typical process, into a 5-ml two-necked round-bottomflask equipped with a magnetic stirrer were addedRu(pbbp)(pydic) (0.002 mmol) and alcohol (2 mmol)successively at room temperature. The mixture washeated to 60 C under stirring, and then TBHP (70percentaqueous solution) was slowly dropped in 0.5 h. Thereaction was monitored by GC equipped with a SE 54column (30 m 9 0.5 lm). After reaction, the product waspurified by column chromatography over silica gel (eluent:n-hexane/ethyl acetate) and characterized by 1HNMR. 74%

With tert.-butylhydroperoxide; vanadia in water

T=100°C; 9 h; Hide Experimental Procedure

Alagiri, Kaliyamoorthy; Prabhu, Kandikere Ramaiah

Tetrahedron, 2011 , vol. 67, # 44 p. 8544 - 8551 Title/Abstract Full Text View citing articles Show Details

4.3. Typical experimental procedure for oxidation of alcohols

General procedure: To a well-stirred suspension of alcohol (1 mmol) and V2O5 (0.05 mmol) in water (1 mL) was added aq TBHP (70percent, 4 mmol). The reaction mixture was heated at reflux until the completion of the reaction (monitored by TLC). The reaction mixture was extracted with ethyl acetate (3.x.15 mL). The combined organic layer was dried over Na2SO4 and evaporated under vacuum to furnish the crude product, which was purified on a silica gel column using EtOAc and hexane as the solvent mixture. In case of problem in isolating the acid, the solvent was evaporated under vacuum and the crude residue was purified by column chromatography on silica gel (EtOAc/hexane). 69%

With dihydrogen peroxide; benzenesulfonic acid; potassium bromide in dichloromethane; water

T=20°C; 24 h; Irradiation; Reagent/catalystSolvent;

Moriyama, Katsuhiko; Takemura, Misato; Togo, Hideo

Journal of Organic Chemistry, 2014 , vol. 79, # 13 p. 6094 - 6104 Title/Abstract Full Text View citing articles Show Details

60%

With carbon tetrabromide; oxygen; triphenylphosphine

fluorescent irradiation;

Sugai, Taichi; Itoh, Akichika

Tetrahedron Letters, 2007 , vol. 48, # 52 p. 9096 - 9099 Title/Abstract Full Text View citing articles Show Details

With sulfur

T=190 - 200°C;

Szperl

Roczniki Chemii, vol. 6, p. 736 Chem. Zentralbl., 1927 , vol. 98, # I p. 2985 Full Text View citing articles Show Details

With N-methylpyrrolidine-2-one hydrotribromide; dihydrogen peroxide in acetonitrile

Heating;

Joseph, Jomy K.; Jain, Suman L.; Sain, Bir

European Journal of Organic Chemistry, 2006 , # 3 p. 590 - 594 Title/Abstract Full Text View citing articles Show Details

100 %Chromat.

With oxygen; sodium hydroxide in tetrahydrofuran; water

T=25°C; 12 h;

Soule, Jean-Francois; Miyamura, Hiroyuki; Kobayashi, Shu

Journal of the American Chemical Society, 2011 , vol. 133, # 46 p. 18550 - 18553 Title/Abstract Full Text View citing articles Show Details

92 %Spectr.

With oxygen; sodium carbonate in water

T=100°C; P=760.051 Torr; 24 h; Green chemistry;

Osako, Takao; Uozumi, Yasuhiro

Chemistry Letters, 2009 , vol. 38, # 9 p. 902 - 903 Title/Abstract Full Text View citing articles Show Details

89 %Chromat.

With [(C6H5)3P]3Ru(CO)(Cl)H; diphenyl sulphoxide in tetrahydrofuran

T=70°C; 2.5 h; Inert atmosphereSealed tubeGreen chemistry; Hide Experimental Procedure

Barati, Behjat; Moghadam, Majid; Rahmati, Abbas; Mirkhani, Valiollah; Tangestaninejad, Shahram; Mohammadpoor-Baltork, Iraj

Inorganic Chemistry Communications, 2013 , vol. 29, p. 114 - 117 Title/Abstract Full Text View citing articles Show Details

Typical procedure for the ruthenium hydride-catalyzed direct oxidation of alcohols to carboxylic acids with diphenyl sulfoxide

General procedure: Benzyl alcohol 1a (108.1 mg, 1 mmol), diphenyl sulfoxide 2 (202.3 mg, 1 mmol), [RuHCl(CO)(PPh3)3] (39.1 mg, 0.04 mmol) and THF (2 mL) were placed in a screw capped test tube. The test tube was purged with argon and sealed. The mixture was stirred at 70 °C for 2.5 h. After the reaction was completed, the solvent was removed under reduce pressure. The residue was purified by silica gel chromatography (petroleum ether/ethyl acetate = 6/1) and recrystallized from H2O–methanol to give the compound 3a as a white crystal. #10;#10;

With E. coli xanthine dehydrogenase; F. graminearum galactose oxidase variant M35; oxygen; catalase in aq. phosphate buffer; acetonitrile

T=37°C; pH=7.6; Enzymatic reaction;

Bechi, Beatrice; Herter, Susanne; McKenna, Shane; Riley, Christopher; Leimkühler, Silke; Turner, Nicholas J.; Carnell, Andrew J.

Green Chemistry, 2014 , vol. 16, # 10 p. 4524 - 4529 Title/Abstract Full Text View citing articles Show Details

> 99 %Chromat.

With oxygen; potassium carbonate in water

T=80°C; P=759.826 Torr; 22 h; Green chemistry;

Karimi, Babak; Naderi, Zahra; Khorasani, Mojtaba; Mirzaei, Hamid M.; Vali, Hojatollah

ChemCatChem, 2016 , vol. 8, # 5 p. 906 - 910 Title/Abstract Full Text View citing articles Show Details

78 %Chromat.

With [2,2]bipyridinyl; Iron(III) nitrate nonahydrate; 2,2,6,6-Tetramethyl-1piperidinyloxy free radical; oxygen; acetic acid

T=80°C; P=760.051 Torr; 3 h;

Lagerblom, Kalle; Wrigstedt, Pauli; Keskiväli, Juha; Parviainen, Arno; Repo, Timo

ChemPlusChem, 2016 , vol. 81, # 11 p. 1160 - 1165 Title/Abstract Full Text View citing articles Show Details

98 %Chromat.

With water; potassium carbonate

T=80°C; Catalytic behavior;

Vessally, Esmail; Ghasemisarabbadeih, Mostafa; Ekhteyari, Zeynab; Hosseinzadeh-Khanmiri, Rahim; Ghorbani-Kalhor, Ebrahim; Ejlali, Ladan

RSC Advances, 2016 , vol. 6, # 108 p. 106769 - 106777 Title/Abstract Full Text View citing articles Show Details

67 %Chromat.

With C56H44Cl3CuN2OP2S; dihydrogen peroxide; 3-butyl-1-methyl-1H-imidazol-3ium hexafluorophosphate

T=70°C; 48 h; Hide Experimental Procedure

2.5 Procedure for catalytic oxidation

General procedure: To a mixture of alcohol (5mmol) and complex 1 (7mg, 0.007mmol) in [bmim][PF6] (0.1mL), hydrogen peroxide (6mmol, 0.678mL) was added. The reaction mixture was stirred for 48h at 70°C. After the appropriate time, the resulting mixture was extracted with n-hexane and then the extract was analyzed by GC. To identify the reaction products and determine their percentage yields, the retention times and corresponding peak areas were compared with authentic commercial samples under identical experimental conditions. To calculate the percentage yields of the formed products the area normalization method was used. To determine the isolated yields of acetophenone and benzoic acid, their crude mixture was purified by columnchromatography. To investigate the recyclability of the IL and the catalyst, [bmim][PF6] with complex 1 was recovered by overnight drying in vacuo. For the five consecutive cycles, the recovered complex 1 in [bmim][PF6] was used by adding fresh 1-phenylethanol (5mmol) and hydrogen peroxide (6mmol) under the same experimental conditions.

Rx-ID: 277164 Find similar reactions

Synthesize Find similar

Gunasekaran; Bhuvanesh; Karvembu

Polyhedron, 2017 , vol. 122, p. 39 - 45 Title/Abstract Full Text View citing articles Show Details

A: 2% B: 85%

With N -hydroxyphthalimide; oxygen; cobalt(II) acetate in acetic acid

T=25°C; P=760 Torr; 20 h;

Yoshino, Yasushi; Hayashi, Yoshiaki; Iwahama, Takahiro; Sakaguchi, Satoshi; Ishii, Yasutaka

Journal of Organic Chemistry, 1997 , vol. 62, # 20 p. 6810 - 6813 Title/Abstract Full Text View citing articles Show Details

A: 5.4% B: 73.3%

With N -hydroxyphthalimide; oxygen in acetic acid

T=90°C; 2.5 h; Hide Experimental Procedure

Zhou, Yulu; Lin, Shasha; Bian, Yinghui; Xia, Daohong; Xiang, Yuzhi

Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2016 , vol. 55B, # 5 p. 624 - 628 Title/Abstract Full Text View citing articles Show Details

Experimental Section

General procedure: In a general procedure, into a three-neck flask, 3 mmol of aromatics, 5 mL of acetic acid, 5 mol percent of NHPI, and 0.83 mol percent of CoSPc were added. Thereafter, 02 was bubbled at 2.5 mL/s into the flask. The oxidation was carried out at 90°C under stirring. Oxidation process was monitored by TLC. After the original substrate was exhausted, the reaction solution was concentrated under reduced pressure and the reside was separated on silica gel. The products were confirmed by 'H NMR, and the assignments and yields determination of the volatile products, such as benzyl aldehyde, were estimated according to the retention times and peak areas by GC.

A: 70% B: 21%

With Marshall's acid; copper(II) sulfate in water; acetonitrile

T=75 - 80°C; 1 h;

Perumal, P. Thirumalai; Bhatt, M. Vivekananda

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1981 , vol. 20, # 2 p. 153 - 155 Title/Abstract Full Text Show Details

Hide Details

A: 70% B: 20%

With potassium bromate; ammonium cerium(IV) nitrate in 1,4dioxane; water; toluene

T=95°C; 24 h;

Ganin; Amer

Synthetic Communications, 1995 , vol. 25, # 20 p. 3149 - 3154 Title/Abstract Full Text View citing articles Show Details

A: 70% B: 20%

With potassium bromate; ammonium cerium(IV) nitrate in 1,4dioxane; water; toluene

T=95°C; 24 h;

Ganin; Amer

Synthetic Communications, 1995 , vol. 25, # 20 p. 3149 - 3154 Title/Abstract Full Text View citing articles Show Details

A: 21.7% B: 5.2%

With [FeCl2{κ3-HC(pyrazol-1-yl)3}]; dihydrogen peroxide; nitric acid in water; acetonitrile

T=35°C; 12 h; Green chemistry; Catalytic behavior; Overall yield = 31.7 percent; Hide Experimental Procedure

Mendes, Marta; Ribeiro, Ana Paula C.; Alegria, Elisabete C.B.A.; Martins, Luísa M.D.R.S.; Pombeiro, Armando J.L.

Polyhedron, 2017 , vol. 125, p. 151 - 155 Title/Abstract Full Text View citing articles Show Details

General procedure: The xylenes oxidations were carried out in air in round bottomflasks with vigorous stirring and using CH3CN as solvent (up to3 mL total volume). Typically, [FeCl2{j3-HC(pz)3}] (10 lmol) wasadded to the solvent as a solid or in the form of a stock solution.After the addition of xylene (o-, m- or p-; 5 mmol) the reactionstarted when hydrogen peroxide (50percent aq. sol., 10 mmol) was addedin one portion. In the experiments with HNO3 (65percent, 0.1–0.5 mmol)this acid was added immediately before the addition of the substrate.The reactions were stopped by cooling the reactional solution.Extraction was performed with 10 mL of diethyl ether and90 μL of cyclopentanone were inserted in the extracted mixture.All products formed were identified by GC.

With benzeneseleninic anhydride

T=120°C; 119 h; Yield given. Yields of byproduct given;

Barton, Derek H. R.; Hui, Raymond A. H. F.; Ley, Steven V.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 9 p. 2179 - 2186 Title/Abstract Full Text Show Details

With iron(III) oxide; water; oxygen

T=235°C; P=44130.5 Torr;

I.G. Farbenind.

Patent: US1815985 , 1929 ;

B: 6 mg

With benzeneseleninic anhydride

T=120°C; 119 h; Yields of byproduct given;

Barton, Derek H. R.; Hui, Raymond A. H. F.; Ley, Steven V.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 9 p. 2179 - 2186 Title/Abstract Full Text Show Details

With potassium bromate; ammonium cerium(IV) nitrate in 1,4-dioxane; toluene

T=95°C; 24 h; other alkyl benzenes; Product distributionMechanism;

Ganin; Amer

Synthetic Communications, 1995 , vol. 25, # 20 p. 3149 - 3154 Title/Abstract Full Text View citing articles Show Details

With Coprinus sp. peroxidase; tartaric acid buffer; dihydrogen peroxide in water; acetone

T=20°C; pH=5;

Russ, Rainer; Zelinski, Thomas; Anke, Timm

Tetrahedron Letters, 2002 , vol. 43, # 5 p. 791 - 793 Title/Abstract Full Text View citing articles Show Details

With N -hydroxyphthalimide; xanthone; oxygen; tetramethlyammonium chloride in acetonitrile

T=60°C; P=3750.38 Torr; 3 h; Autoclave;

Du, Zhongtian; Sun, Zhiqiang; Zhang, Wei; Miao, Hong; Ma, Hong; Xu, Jie

Tetrahedron Letters, 2009 , vol. 50, # 15 p. 1677 - 1680 Title/Abstract Full Text View citing articles Show Details

With ([MnIII(5,10,15,20-tetra(4-chlorophenyl)porphyrin)]chloride); cobalt(II) diacetate tetrahydrate

T=170°C; P=9000.9 Torr; 5 h; Neat (no solvent)Autoclave;

Xiao, Yang; Zhang, Xiaoyan; Wang, Qin Bo; Tan, Ze; Guo, Can Cheng; Deng, Wei; Liu, Zhi Gang; Zhang, He Fei

Chinese Chemical Letters, 2011 , vol. 22, # 2 p. 135 - 138 Title/Abstract Full Text View citing articles Show Details

With dmap; oxygen; benzyl bromide in acetonitrile

T=140°C; P=7500.75 Torr; 3 h; Autoclave;

Zhang, Zhan; Gao, Jin; Wang, Feng; Xu, Jie

Molecules, 2012 , vol. 17, # 4 p. 3957 - 3968 Title/Abstract Full Text View citing articles Show Details

With C36H36ClMnN6O8

T=120°C; P=760.051 Torr; 9.5 h;

Li, Jian-Zhang; He, Xi-Yang; Zeng, Jun; Xiao, Zheng-Hua; Qin, Sheng-Ying

Transition Metal Chemistry, 2012 , vol. 37, # 1 p. 31 - 35 Title/Abstract Full Text View citing articles Show Details

With N -hydroxyphthalimide; oxygen; cobalt(II) acetate

T=80°C; P=760.051 Torr; Ionic liquid;

Lu, Tingting; Lu, Ming; Yu, Wang; Liu, Zhongjie

Croatica Chemica Acta, 2012 , vol. 85, # 3 p. 277 - 282 Title/Abstract Full Text View citing articles Show Details

With dihydrogen peroxide; acetic acid

T=30°C; 20 h; Reagent/catalystTemperatureTimeConcentration; Hide Experimental Procedure

Rohitha; Kulkarni; Narender

Synthetic Communications, 2013 , vol. 43, # 21 p. 2853 - 2866 Title/Abstract Full Text View citing articles Show Details

Full Text Show Details

General Procedure for Oxidation of p-Xylene

The liquid-phase oxidation of p-xylene was carried out over metallomacrocycle encapsulated in MCM-41. In a typical reaction, 0.1 g of dried catalyst was added to the stirred solution of p-xylene (2 mmol) in acetic acid (6 ml), followed by 8 mmol of 30percent H2O2 (dropwise). Then reaction mixture was allowed to stir in the temperaturerange of 30-100°C. The reaction was monitored by thin-layer chromatography (TLC). After completion of the reaction, the catalyst was filtered and washed with ethyl acetate. The combined filtrates were washed with saturated sodium bicarbonate solution. The organic extract was dried over anhydrous sodium sulfate and solvent was evaporated under reduced pressure. The products were quantified by gas chromatography, verified by GC-MS and purified by column chromatography over silica gel (finer than 200 mesh). All the products are characterized by 1HNMR, 13C NMR,and mass spectroscopy.

With oxygen in acetonitrile

T=24.84°C; P=760.051 Torr; IrradiationGreen chemistry; Reagent/catalyst;

Tsukamoto, Daijiro; Shiraishi, Yasuhiro; Hirai, Takayuki

Catalysis Science and Technology, 2013 , vol. 3, # 9 p. 2270 - 2277 Title/Abstract Full Text View citing articles Show Details

With N -hydroxyphthalimide; oxygen; cobalt(II) diacetate tetrahydrate; acetic acid

T=20°C; 3 h; Kinetics;

Gaster, Eden; Kozuch, Sebastian; Pappo, Doron

Angewandte Chemie - International Edition, 2017 , vol. 56, # 21 p. 5912 - 5915 Angew. Chem., 2017 , vol. 129, p. 6006 - 6009,4 Title/Abstract Full Text Show Details

Synthesize Find similar

Rx-ID: 572916 Find similar reactions

100%

With phosphate-buffered silica gel supported KMnO4 in cyclohexane

T=65°C;

Takemoto; Yasuda; Ley

Synlett, 2001 , # 10 p. 1555 - 1556 Title/Abstract Full Text View citing articles Show Details

100%

With periodic acid; PFC in acetonitrile

T=0°C; 1.5 h;

Hunsen, Mo

Journal of Fluorine Chemistry, 2005 , vol. 126, # 9-10 p. 1356 - 1360 Title/Abstract Full Text View citing articles Show Details

100%

With [Cu2C6H4(CHNCH2CH2N(CH2C5H4N)2)2](2+)*2ClO4(1)=C H Cu N (ClO )2; oxygen in acetone

36 38 2 8 4

Garcia-Bosch, Isaac; Company, Anna; Cardellach, Mar; Costas, Miquel; Frisch, Jonathan R.; Que Jr., Lawrence; Torrent-Sucarrat, Miquel; Gamba, Ilaria; Casella, Luigi; Gueell, Mireia; Luis, Josep M.

Angewandte Chemie, International Edition, 2010 , vol. 49, # 13 p. 2406 - 2409 Angewandte Chemie, 2010 , vol. 122, # 13 p. 2456 - 2459 Title/Abstract Full Text View citing articles Show Details

T=-90.16°C;

Hide Details

99%

With periodic acid; pyridinium chlorochromate in acetonitrile

1.5 h;

Hunsen, Mo

Synthesis, 2005 , # 15 art. no. M00905SS, p. 2487 - 2490 Title/Abstract Full Text View citing articles Show Details

99%

With tert.-butylhydroperoxide; di-tert-butyl peroxide; silica-supported selenamide in water; tert-butyl alcohol

T=75°C; 7 h;

Giurg; Brzaszcz; Mlochowski

Polish Journal of Chemistry, 2006 , vol. 80, # 3 p. 417 - 428 Title/Abstract Full Text View citing articles Show Details

99%

With 2-mesityl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine in acetonitrile

T=20°C;

Zhao, Junfeng; Mueck-Lichtenfeld, Christian; Studer, Armido

Advanced Synthesis and Catalysis, 2013 , vol. 355, # 6 p. 1098 - 1106 Title/Abstract Full Text View citing articles Show Details

99%

With tert.-butylhydroperoxide; iron oxide; ethyl acetoacetate in decane

T=75 - 80°C; 24 h; Green chemistry; Reagent/catalyst; Hide Experimental Procedure

Villano, Rosaria; Acocella, Maria Rosaria; Scettri, Arrigo

Tetrahedron Letters, 2014 , vol. 55, # 15 p. 2442 - 2445 Title/Abstract Full Text View citing articles Show Details

Typical procedure for the oxidation of aldehydes to carboxylic acids

General procedure: To a vial with the catalyst (20 mol percent) under air, aldehyde (0.0625 mmol) and ethyl acetoacetate (1 equiv) were added. The mixture was heated at 75–80 °C for 24 h. After cooling at rt, ethyl acetate (1.0 ml) was added and the catalyst was separated by simple magnetic decantation. Then, the combined solvent was removed in vacuo and the mixture was purified via trituration or flash column. Spectroscopic data of products 2 were consistent with those reported in the literature (2a,14 2b,15 2c,16 2d,14 2e,17 2f,14 2h,18 2i,19 2j20 and 2k21). 4-Methylbenzoic acid (2d): 6.0 mg, 71percent yield. 1H NMR (400 MHz, CDCl3) δ 7.99 (d, 2H, J = 8.0 Hz), 7.27 (d, 2H, J = 8.0 Hz), 2.43 (s, 3H). 13C NMR (100 MHz, CDCl3) δ 172.3, 144.7, 130.3, 129.2, 126.5, 21.8. 99%

With C4H11FeMo6NO24(3-)*3C16H36N(1+); water; oxygen; sodium carbonate

T=50°C; P=760.051 Torr; 8 h; Green chemistry;

Yu, Han; Ru, Shi; Dai, Guoyong; Zhai, Yongyan; Lin, Hualin; Han, Sheng; Wei, Yongge

Angewandte Chemie - International Edition, 2017 , vol. 56, # 14 p. 3867 - 3871 Angew. Chem., 2017 , vol. 129, # 14 p. 3925 - 3929,5 Title/Abstract Full Text Show Details

97%

With Oxonereg; in N,N-dimethyl-formamide

T=20°C; 3 h;

Travis, Benjamin R.; Sivakumar, Meenakshi; Hollist, G. Olatunji; Borhan, Babak

Organic Letters, 2003 , vol. 5, # 7 p. 1031 - 1034 Title/Abstract Full Text View citing articles Show Details

97%

With sodium hydroxide in water

T=20 - 75°C; 18 h; Catalytic behavior; Hide Experimental Procedure

Saadati, Fariba; Khani, Neda; Rahmani, Mohammad; Piri, Farideh

Catalysis Communications, 2016 , vol. 79, p. 26 - 30 Title/Abstract Full Text View citing articles Show Details

2.4. Oxidation of aldehydes catalyzed by CuO(at)HPS

General procedure: In a two-necked round bottom flask equipped with a condenser, the aldehyde (1 mmol), was dropped into the mixture of catalyst (4 molpercent) and NaOH (1.5 mmol) in deionized water (3 mL). The resulting mixture was stirred at room temperature under air atmosphere for 15 min and then the temperature reached 75 °C. The progress of the reaction was monitored by TLC. After completion of the reaction, the reaction mixture was filtered off and the catalyst rinsed with deionized water and ethanol. The filtrate was treated with H2SO4 (30 wt.percent). The precipitated carboxylic acid was filtered, washed with water and dried in vacuum. (For liquid products after addition of H2SO4, the product was extracted using diethyl ether (4 × 5 mL). 96%

With aluminum oxide; oxone; water

0.15 h; microwave irradiation;

Alavi Nikje, Mir M.; Bigdeli, Mohammad A.

Phosphorus, Sulfur and Silicon and the Related Elements, 2004 , vol. 179, # 7 p. 1445 - 1448 Title/Abstract Full Text View citing articles Show Details

95%

With tert.-butylhydroperoxide; potassium tert-butylate in water

T=60°C; 5 h; Hide Experimental Procedure

Shaikh, Tanveer Mahammadali; Hong, Fung-E

Tetrahedron, 2013 , vol. 69, # 42 p. 8929 - 8935 Title/Abstract Full Text View citing articles Show Details

4.1.1 Typical experimental procedure for oxidation of aldehydes to carboxylic acids (2a–q)

General procedure: In a 25mL round-bottom flask, t-BuOK (0.5mmol) was dissolved in water (1mL), and an aldehyde (0.5mmol) was added. Subsequently, aq 70percent TBHP (1mmol) was slowly added to this flask. The resulting slurry was stirred at 60°C or (optional) 25°C for 5h or 40h. After completion of reaction this slurry was cooled to room temperature. The slurry was then acidified with 2M hydrochloric acid until the aqueous layer was strongly acidic by pH paper. This on simple filtration resulted in pure carboxylic acids. 92%

With sodium perborate in acetic acid

T=45 - 50°C;

McKillop, Alexander; Kemp, Duncan

Tetrahedron, 1989 , vol. 45, # 11 p. 3299 - 3306 Title/Abstract Full Text View citing articles Show Details

92%

With potassium permanganate in ethanol; water

T=80°C; 4 h;

Shojaei, Abdollah Fallah; Rezvani, Mohamad Ali; Heravi, Majid

Journal of the Serbian Chemical Society, 2011 , vol. 76, # 11 p. 1513 - 1522 Title/Abstract Full Text View citing articles Show Details

91%

With potassium hydroxide; sodium tetrahydroborate; air; palladium on activated charcoal in methanol

T=20°C; 1.5 h;

Lim, Minkyung; Yoon, Cheol Min; An, Gwangil; Rhee, Hakjune

Tetrahedron Letters, 2007 , vol. 48, # 22 p. 3835 - 3839 Title/Abstract Full Text View citing articles Show Details

91%

Stage #1: With tin(II) oxide; dihydrogen peroxide in water; acetonitrile

T=60°C; 0.833333 h; Stage #2: With hydrogenchloride in water

pH=2.0;

Dehbashi, Mohsen; Aliahmad, Mousa; Shafiee, Mohammad Reza Mohammad; Ghashang, Majid

Phosphorus, Sulfur and Silicon and the Related Elements, 2013 , vol. 188, # 7 p. 864 - 872 Title/Abstract Full Text View citing articles Show Details

90%

With (bipyH2)-CrOCl5 in dichloromethane

T=28 - 30°C; 3 h; oxidation with further chromium reagents;

Chakraborty, T.K.; Chandrasekaran, S.

Synthetic Communications, 1980 , vol. 10, # 12 p. 951 - 956 Title/Abstract Full Text Show Details

90%

With dihydrogen peroxide; benzeneseleninic acid in tetrahydrofuran

20 h; Heating;

Choi, Joong-Kwon; Chang, Young-Kil; Hong, Sung Yeap

Tetrahedron Letters, 1988 , vol. 29, # 16 p. 1967 - 1970 Title/Abstract Full Text View citing articles Show Details

89%

With polysterene-bound phenylseleninic acid; dihydrogen peroxide in tetrahydrofuran

24 h; Heating;

Qian, Hao; Shao, Li-Xiong; Huang, Xian

Journal of Chemical Research - Part S, 2002 , # 10 p. 514 - 515 Title/Abstract Full Text View citing articles Show Details

88%

With aluminium trichloride; silver bromate in acetonitrile

0.5 h; Heating;

Firouzabadi, Habib; Mohammadpoor-Baltork, Iraj

Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 8 p. 2319 - 2326 Title/Abstract Full Text Show Details

88%

With selenium(IV) oxide; dihydrogen peroxide in tetrahydrofuran

7 h; Heating;

Brzaszcz; Kloc; Maposah; Mlochowski

Synthetic Communications, 2000 , vol. 30, # 24 p. 4425 - 4434 Title/Abstract Full Text View citing articles Show Details

88%

With tert.-butylhydroperoxide in water

T=97°C; 2 h;

Choudhary, Vasant R.; Dumbre, Deepa K.; Narkhede, Vijay S.

Journal of Chemical Sciences, 2012 , vol. 124, # 4 p. 835 - 839 Title/Abstract Full Text View citing articles Show Details

86%

With [Ni(cdacacen)]; dihydrogen peroxide in water; acetonitrile

T=60°C; 2 h;

Esfandiari, Hadi; Jameh-Bozorghi, Saeed; Esmaielzadeh, Sheida; Shafiee, Mohammad Reza Mohammad; Ghashang, Majid

Research on Chemical Intermediates, 2013 , vol. 39, # 7 p. 3319 - 3325 Title/Abstract Full Text View citing articles Show Details

85%

With urea-hydrogen peroxide in formic acid

T=20°C; 2.5 h;

Balicki

Synthetic Communications, 2001 , vol. 31, # 14 p. 2195 - 2198 Title/Abstract Full Text View citing articles Show Details

85%

With dihydrogen peroxide; toluene-4-sulfonic acid; captisol® in water

T=50°C; 15 h; Hide Experimental Procedure

Jeong, Se Young; Kim, Nagyeong; Lee, Jong Chan

Bulletin of the Korean Chemical Society, 2014 , vol. 35, # 11 p. 3366 - 3368 Title/Abstract Full Text View citing articles Show Details

General Procedure.

General procedure: To a solution of 30percent hydrogen peroxide(5.0 mmol) was added aldehyde (1.0 mmol), PTSA(1.0 mmol) and β-cyclodextrin (0.1 mmol). The reactionmixture was stirred for 15 h at 50 oC. After cooling to roomtemperature, the reaction mixture was dissolved in the solutionof 10percent aqueous sodium bicarbonate, extracted intodiethyl ether (2 × 25 mL), and washed with water. The aqueouslayer was acidified to pH 3 with 2 M hydrochloric acid.The product was extracted with dichloromethane (2 × 25mL) and dried over magnesium sulfate. Evaporation of organiclayer under reduced pressure gave the desired carboxylicacid. 85%

With diphenyl diselenide; dihydrogen peroxide in water

T=20°C; 6 h; Green chemistry; Hide Experimental Procedure

Sancineto, Luca; Tidei, Caterina; Bagnoli, Luana; Marini, Francesca; Lenardo, Eder J.; Santi, Claudio

Molecules, 2015 , vol. 20, # 6 p. 10496 - 10510 Title/Abstract Full Text View citing articles Show Details

3.2. General Procedure for the Synthesis of Carboxylic Acids 2

General procedure: Diphenyl diselenide (3, 0.006 g; 0.02 mmol) was treated with H2O2 (30percent·w/w, 0.1 mL, 1 mmol) andwater (0.2 mL) and stirred at room temperature at 800 rpm until the discoloration of the reaction mixture;then, the aldehyde 1 (1 mmol) was added. After 6 h, the aqueous mixture was extracted three times withEtOAc (3 × 20 mL). The collected organic layers were dried over Na2SO4 and the solvent evaporatedunder reduced pressure. 82%

With sodium chlorite in dichloromethane; acetic acid

Bayle, J. P.; Perez, F.; Courtieu, J.

Bulletin de la Societe Chimique de France, 1990 , # 4 p. 565 - 567 Title/Abstract Full Text Show Details

82%

With oxygen; sodium hydride; 1-butyl-3-methylimidazolium chloride in tetrahydrofuran; mineral oil

T=20°C; P=760.051 Torr; 8 h;

Kim, Sun Min; Kim, Young Sug; Yang, Jung Woon

Bulletin of the Korean Chemical Society, 2011 , vol. 32, # 8 p. 2529 - 2530 Title/Abstract Full Text View citing articles Show Details

82%

With oxygen

T=120°C; 5 h; Neat (no solvent);

Choudhary, Vasant R.; Dumbre, Deepa K.

Catalysis Communications, 2011 , vol. 13, # 1 p. 82 - 86 Title/Abstract Full Text View citing articles Show Details

80%

With sodium bromate; sodium hydrogen sulfate in acetonitrile

15 h; Heating;

Shirini, Farhad; Ali Zolfigol, Mohammad; Torabi, Shayesteh

Synthetic Communications, 2006 , vol. 36, # 19 p. 2833 - 2840 Title/Abstract Full Text View citing articles Show Details

80%

With 1,4-diaza-bicyclo[2.2.2]octane; oxygen; copper(II) 2-ethylhexanoate; vanadyl acetylacetonate

T=95°C; P=760.051 Torr; 12 h;

Jiang, Nan; Ragauskas, Arthur J.

Journal of Organic Chemistry, 2007 , vol. 72, # 18 p. 7030 - 7033 Title/Abstract Full Text View citing articles Show Details

77%

With dihydrogen peroxide; 7-(trifluoromethyl)-1,10-ethyleneisoalloxazinium chloride in water; acetonitrile

T=85°C; 18 h;

Murray, Alexander T.; Matton, Pascal; Fairhurst, Nathan W. G.; John, Matthew P.; Carbery, David R.

Organic Letters, 2012 , vol. 14, # 14 p. 3656 - 3659 Title/Abstract Full Text View citing articles Show Details

76%

With tetraethylammonium bromide in N,N-dimethyl-formamide

T=20°C; Oxidation;

Singh, Sundaram; Singh, Krishna Nand

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1997 , vol. 36, # 9 p. 805 - 807 Title/Abstract Full Text View citing articles Show Details

75%

With oxygen; acetic anhydride; butyraldehyde; cobalt(II) chloride in acetonitrile

Ambient temperature;

Punniyamurthy; Kalra, Swinder Jeet Singh; Iqbal, Javed

Tetrahedron Letters, 1994 , vol. 35, # 18 p. 2959 - 2960 Title/Abstract Full Text View citing articles Show Details

75%

With N-hydroxy-o-benzenedisulphonimide in acetic acid; acetonitrile

T=60°C; 4.5 h;

Barbero, Margherita; Degani, Lacopo; Fochi, Rita; Perracino, Paolo

Journal of Organic Chemistry, 1996 , vol. 61, # 25 p. 8762 - 8764 Title/Abstract Full Text View citing articles Show Details

74%

With oxygen

Oxidation; 0.133333 h; microwave irradiation;

Sahadeva Reddy; Pratap Reddy; Reddy

Synthetic Communications, 1999 , vol. 29, # 17 p. 2949 - 2951 Title/Abstract Full Text View citing articles Show Details

74%

With air; octadecafluorodecahydronaphthalene

Liu, Chao; Shen, Dong-Mei; Chen, Qing-Yun

(cis+trans); isobutyraldehyde; [Co{TPP(C8F17)4}] in acetonitrile

P=760 Torr; 10 h;

European Journal of Organic Chemistry, 2006 , # 12 p. 2703 - 2706 Title/Abstract Full Text View citing articles Show Details

68%

With dihydrogen peroxide in acetonitrile

T=20 - 90°C; 10 h; Green chemistry; Reagent/catalystSolvent;

Kashyap, Rajarshi; Talukdar, Dhruba Joyti; Pratihar, Sanjay

New Journal of Chemistry, 2015 , vol. 39, # 2 p. 1430 - 1437 Title/Abstract Full Text View citing articles Show Details

63%

With oxygen; nickel(II) acetylacetonate in various solvent(s) T=60°C; Oxidation; 12 h;

Howarth

Tetrahedron Letters, 2000 , vol. 41, # 34 p. 6627 - 6629 Title/Abstract Full Text View citing articles Show Details

62%

With oxygen; acetic anhydride; CoCl2 in 1,2-dichloro-ethane

T=25°C;

Bhatia, Beena; Iqbal, Javed

Tetrahedron Letters, 1992 , vol. 33, # 51 p. 7961 - 7964 Title/Abstract Full Text View citing articles Show Details

62%

With oxygen; acetic anhydride; cobalt(II) chloride in 1,2-dichloro-ethane

T=25°C; 20 h;

Bhatia, Beena; Punniyamurthy, T.; Iqbal, Javed

Journal of Organic Chemistry, 1993 , vol. 58, # 20 p. 5518 - 5523 Title/Abstract Full Text View citing articles Show Details

62%

With carbon dioxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,3-bis(2,4,6trimethylphenyl)-4,5-dihydroimidazolium chloride in tetrahydrofuran

T=20°C; 0.25 h;

Nair, Vijay; Varghese, Vimal; Paul, Rony Rajan; Jose, Anu; Sinu; Menon, Rajeev S.

Organic Letters, 2010 , vol. 12, # 11 p. 2653 - 2655 Title/Abstract Full Text View citing articles Show Details

58%

With dihydrogen peroxide in acetic acid

T=90°C; 7 h;

Yang, Xiaomei; Tang, Si; Lu, Tianliang; Chen, Chen; Zhou, Lipeng; Su, Yunlai; Xu, Jie

Synthetic Communications, 2013 , vol. 43, # 7 p. 979 - 985 Title/Abstract Full Text View citing articles Show Details

57%

With dihydrogen peroxide; methyltrioctylammonium tetrakis(oxodiperoxotungsto)phosphate

T=90°C; 1.5 h;

Venturello, Carlo; Gambaro, Mario

Journal of Organic Chemistry, 1991 , vol. 56, # 20 p. 5924 - 5931 Title/Abstract Full Text View citing articles Show Details

43%

With barium manganate in dichloromethane

13 h; Ambient temperature;

Srivastava, R.G.; Venkataramani, P.S.

Synthetic Communications, 1988 , vol. 18, # l6-17 p. 2193 - 2200 Title/Abstract Full Text Show Details

41%

With dihydrogen peroxide; [Me(n-C8H17)3N]HSO4 in water

T=90°C; Oxidation; 3 h;

Sato, Kazuhiko; Hyodo, Mamoru; Takagi, Junko; Aoki, Masao; Noyori, Ryoji

Tetrahedron Letters, 2000 , vol. 41, # 9 p. 1439 - 1442 Title/Abstract Full Text View citing articles Show Details

41.3%

With 1,3-dinitrobenzene; sodium hydroxide in water

T=100°C; 2.5 h; Sealed tube;

Bjorsvik, Hans-Rene; Liguori, Lucia; Minisci, Francesco

Organic Process Research and Development, 2001 , vol. 5, # 2 p. 136 - 140 Title/Abstract Full Text View citing articles Show Details

39 % Turnov.

With ammonium cerium(IV) nitrate; sodium dodecyl-sulfate in cyclohexane; water

Skrzewski; Cichacz

Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 1 p. 271 - 274 Title/Abstract Full Text View citing articles Show Details

T=25°C; 1 h; var. catalyst conc.; Product distribution;

With perchloric acid; pyridinium chlorochromate in acetic acid

T=29.9 - 59.9°C; E(a), ΔH(excit.), ΔS(excit.), ΔG(excit.); Thermodynamic data;

Pillay, M Krishna; Jameel, A Abdul

Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1992 , vol. 31, # 1.2 p. 46 - 48 Title/Abstract Full Text Show Details

With perchloric acid; N-bromobenzamide; water in acetic acid

T=19.9°C; ΔH*, ΔS*, other temp.; Thermodynamic dataKineticsRate constant;

Banerji, Kalyan K.

Journal of Organic Chemistry, 1986 , vol. 51, # 25 p. 4764 - 4767 Title/Abstract Full Text View citing articles Show Details

With potassium sulfate; potassium hydrogensulfate; disodium hydrogenphosphate; sodium dihydrogenphosphate; oxone in water; acetonitrile

T=29.9°C; pH = 6; Rate constantMechanism;

Naseeruddin, Ahmad; Swamy, A. S. R.; Jagannadham, V.

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1987 , vol. 26, # 5 p. 427 - 429 Title/Abstract Full Text Show Details

With perchloric acid; mercury(II) diacetate; N-bromoacetamide in acetic acid

Gupta, Anita; Mathur, Sandhya; Banerji, Kalyan K.

T=24.9°C; other temperatures, ΔG(excit.), ΔH(excit.), ΔS(excit.); KineticsMechanismThermodynamic data;

Journal of Chemical Research, Miniprint, 1988 , # 1 p. 201 - 223 Title/Abstract Full Text Show Details

With perchloric acid; PFC in water; acetic acid

T=34.9°C; Rate constant;

Ramakrishnan, P. S.; Chockalingam, P.

Journal of the Indian Chemical Society, 1993 , vol. 70, # 6 p. 581 - 582 Title/Abstract Full Text Show Details

With potassium hydroxide; potassium metaperiodate; diperiodato cuprate(III) in water; tert-butyl alcohol

T=26.9°C; E(excit.), ΔG(excit.), ΔS(excit.), other temperatures; KineticsMechanismThermodynamic data;

Bal Reddy, K.; Sethuram, B.; Navaneeth Rao, T.

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1984 , vol. 23, # 7 p. 593 - 595 Title/Abstract Full Text Show Details

With potassium bromate; perchloric acid; ruthenium(III) in water

T=50°C; ΔEa, ΔH(excit.), ΔS(excit.); further solvent: AcOH:H2O (10-30percent); further temperatures: 60, 70 deg C; Thermodynamic dataKineticsMechanism;

Radhakrishnamurti, P. S.; Sarangi, L. D.

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1980 , vol. 19, # 11 p. 1124 - 1126 Title/Abstract Full Text Show Details

With perchloric acid; trichloroisocyanuric acid in acetic acid

T=35°C; Rate constant;

Pati, Subas C.; Sahu, Ashok Kumar; Sriramulu, Y.

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1987 , vol. 26, # 8 p. 693 - 695 Title/Abstract Full Text Show Details

in water

T=25°C; xanthine oxidase; also in aerosol OT/isooctane and cationic and nonionic micellar systems; Rate constant;

Bommarius, Andreas S.; Hatten, T. Alan; Wang, Daniel I. C.

Journal of the American Chemical Society, 1995 , vol. 117, # 16 p. 4515 - 4523 Title/Abstract Full Text View citing articles Show Details

With perchloric acid; bis(2,2'-bipyridyl) copper(II) permanganate in water; acetic acid

T=14.9°C; other temperatures; ΔH, ΔS, ΔG; kinetics and mechanism of the oxidation of monosubstituted benzaldehydes by bis(2,2'-bipyridyl)copper(II) permanganate (BBCP); formation and decomposition of benzaldehyde-BBCP complexes; Rate constantKineticsThermodynamic data;

Mohnot, Kavita; Sharma, Pradeep K.; Banerji, Kalyan K.

Journal of Organic Chemistry, 1996 , vol. 61, # 4 p. 1310 - 1314 Title/Abstract Full Text View citing articles Show Details

With tert-butylhypochlorite; acetic acid

Ginsburg

Journal of the American Chemical Society, 1951 , vol. 73, p. 702 Full Text View citing articles Show Details

With iodine

Irradiation;

Mascarelli; Russi

Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1910 , vol. <5> 19 II, p. 241 Gazzetta Chimica Italiana, 1912 , vol. 42 I, p. 94 Full Text View citing articles Show Details

With potassium permanganate; Aliquatreg; 336 in water; benzene

0.25 h; Ambient temperature;

Hanumantha Rao; Bhagawanth Rao

Journal of the Indian Chemical Society, 1991 , vol. 68, # 3 p. 132 - 134 Title/Abstract Full Text View citing articles Show Details

With rat hepatic microsomal aldehyde dehydrogenase; NAD in phosphate buffer; N,N-dimethyl-formamide

T=37°C; Dehydrogenation; pH=7.4; Enzyme kinetics;

Martini, Robert; Murray, Michael

Chemical Research in Toxicology, 1996 , vol. 9, # 1 p. 268 - 276 Title/Abstract Full Text View citing articles Show Details

With ((2,2'-(ethane-1,2diylbis[(nitrilo-.kappa.N)methylidyne])bis(phenolato-.kappa.O))(2))oxomanganese(1+) hexafluorophosphate in acetonitrile

T=14.85°C; Oxidation; Kinetics; Further Variations:CatalystsTemperatures;

Bansal, Varsha; Sharma, Pradeep K.; Banerji, Kalyan K.

Journal of Chemical Research, Miniprint, 1999 , # 8 p. 2052 - 2074 Title/Abstract Full Text Show Details

With acetic acid; QCC in water

T=29.85°C; Oxidation; Kinetics; Further Variations:Temperatures;

Jameel, A. Abdul

Journal of the Indian Chemical Society, 1998 , vol. 75, # 8 p. 439 - 442 Title/Abstract Full Text View citing articles Show Details

With HABR in water; acetic acid

T=14.85 - 44.85°C; Oxidation; pH=2.04; Kinetics;

Gangwani; Sharma; Banerji

International Journal of Chemical Kinetics, 2000 , vol. 32, # 10 p. 615 - 622 Title/Abstract Full Text View citing articles Show Details

With pyridinium hydrobromide perbromide in water; acetic acid

T=44.85°C; Activation energyKineticsThermodynamic data; Further Variations:Temperatures;

Aneja, Meenakshi; Kothari, Seema; Banerji, Kalyan K.

Journal of Physical Organic Chemistry, 2001 , vol. 14, # 9 p. 650 - 656 Title/Abstract Full Text View citing articles Show Details

With benzyltrimethylammonium tribromide; potassium bromide in water; acetic acid

T=44.85°C; 10 h; Kinetics; Further Variations:Temperatures;

Mehla, Satish K.; Kothari, Seema; Banerji, Kalyan K.

Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2002 , vol. 41, # 4 p. 832 - 838 Title/Abstract Full Text View citing articles Show Details

With perchloric acid; nicotinium dichromate in water; acetic acid

T=26.85°C; 24 h; Kinetics; Further Variations:Temperatures;

Sekar

Journal of Chemical Research - Part S, 2002 , # 12 p. 626 - 627 Title/Abstract Full Text View citing articles Show Details

With sodium chlorite; 2-methyl-but-2-ene; acetic acid in DME; water

T=20°C; 16 h;

Deady, Leslie W.; Devine, Shane M.; Rogers, Michael L.

Organic Preparations and Procedures International, 2003 , vol. 35, # 6 p. 627 - 630 Title/Abstract Full Text View citing articles Show Details

With sulfuric acid; quinolinium dichromate(VI) in acetic acid

T=29.85°C; KineticsThermodynamic data; Further Variations:Temperatures;

Medien, Hesham A. A.

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2003 , vol. 58, # 12 p. 1201 - 1205 Title/Abstract Full Text View citing articles Show Details

With NaBO3; acetic acid in water

T=49.85°C; Kinetics; Further Variations:Temperatures;

Medien

Polish Journal of Chemistry, 2004 , vol. 78, # 3 p. 437 - 445 Title/Abstract Full Text View citing articles Show Details

With N-chloro-succinimide; perchloric acid; acetic acid; sodium chloride

T=34.85°C; 36 h; Kinetics; Further Variations:Temperatures;

Mathiyalagan; Sridharan

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2005 , vol. 44, # 10 p. 2044 - 2047 Title/Abstract Full Text View citing articles Show Details

With potassium hydroxide; dihydrogen peroxide in methanol; water

Heating;

Cong, Zhi-Qi; Wang, Chun-Ian; Chen, Tie; Yin, Bing-Zhu

Synthetic Communications, 2006 , vol. 36, # 5 p. 679 - 683 Title/Abstract Full Text View citing articles Show Details

With benzyltrimethylammonium chlorobromate in water; acetic acid

T=24.84°C; Oxidation; pH=2.04; KineticsThermodynamic data; Further Variations:Temperatures;

Raju, V. Sitarama; Sharma, Pradeep K.; Banerji, Kalyan K.

Journal of Organic Chemistry, 2000 , vol. 65, # 11 p. 3322 - 3325 Title/Abstract Full Text View citing articles Show Details

42 %Chromat.

With dihydrogen peroxide; Nafion NR50 in water

T=90°C; 2 h; Hide Experimental Procedure

Sato, Kazuhiko; Usui, Yoko

Patent: US2006/167311 A1, 2006 ; Location in patent: Page/Page column 4 ; Title/Abstract Full Text Show Details

Example 8; Nafion NR50 (500 mg), 30percent aqueous hydrogen peroxide solution (1.3 mL, 11 mmol), and p-tolualdehyde (1.6 mL, 10 mmol) were mixed and stirred at 90° C. for 2 hours. After the reaction solution was cooled to room temperature, the yield of p-toluic acid by measurement of GLC was 42percent. 100 % Turnov.

With tert.-butylhydroperoxide in tert-butyl alcohol

T=80°C; 72 h;

Wojtowicz, Halina; Soroko, Grazyna; Mlochowski, Jacek

Synthetic Communications, 2008 , vol. 38, # 12 p. 2000 - 2010 Title/Abstract Full Text View citing articles Show Details

With tetra-N-butylammonium tribromide; acetic acid

T=14.84°C; Kinetics; Further Variations:Temperatures;

Chouhan; Sharma, Monica; Sharma, Vinita

Journal of the Indian Chemical Society, 2007 , vol. 84, # 6 p. 582 - 587 Title/Abstract Full Text View citing articles Show Details

With BPCC in dimethyl sulfoxide

T=24.84°C; Kinetics; Temperature;

Sharma, Pradeep K.

Journal of the Indian Chemical Society, 2008 , vol. 85, # 12 p. 1281 - 1288 Title/Abstract Full Text View citing articles Show Details

With MCC in dimethyl sulfoxide

T=44.84°C; Kinetics; Temperature;

Choudhary, Anurag; Malani; Agarwal; Sharma; Sharma, Vinita

Journal of the Indian Chemical Society, 2009 , vol. 86, # 9 p. 927 - 935 Title/Abstract Full Text View citing articles Show Details

With O2CrClO(1-)*NEt4(1+) in dimethyl sulfoxide

T=24.84°C; Kinetics; Temperature;

Gehlot; Prasadrao; Sharma

Asian Journal of Chemistry, 2011 , vol. 23, # 3 p. 1173 - 1178 Title/Abstract Full Text View citing articles Show Details

With methanol; dihydrogen peroxide in water

T=20°C;

Shokrolahi, Arash; Zali, Abbas; Keshavarz, Mohammad Hossein

Chinese Journal of Catalysis, 2010 , vol. 31, # 11-12 p. 1427 - 1432 Title/Abstract Full Text Show Details

With bis(tetrabutylammonium) hexatungstate; dihydrogen peroxide in neat (no solvent) 0.0666667 - 0.0833333 h; Microwave irradiationGreen chemistry;

Bamoharram, Fatemeh F.; Heravi, Majid M.; Omidinia, Raheleh; Tavakoli-Hoseini, Niloofar

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2013 , vol. 43, # 2 p. 125 - 130 Title/Abstract Full Text View citing articles Show Details

With bis(tetrabutylammonium) hexatungstate; dihydrogen peroxide in water; acetonitrile

6 h; RefluxGreen chemistry; TemperatureTimeConcentration;

Bamoharram, Fatemeh F.; Heravi, Majid M.; Omidinia, Raheleh; Tavakoli-Hoseini, Niloofar

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2013 , vol. 43, # 2 p. 125 - 130 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1.1: aluminium; potassium hydoxide / methanol / 1 h / 0 °C / |Inert atmosphere 2.1: sodium t-butanolate; oxygen / tetrahydrofuran / 5 h / 20 °C / 760.05 Torr 2.2: pH 1 View Scheme

Kim, Sun Min; Kim, Dong Wan; Yang, Jung Woon

Organic Letters, 2014 , vol. 16, # 11 p. 2876 - 2879 Title/Abstract Full Text View citing articles Show Details

With potassium permanganate in water; acetonitrile

Pratihar, Sanjay

Organic and Biomolecular Chemistry, 2014 , vol. 12, # 30 p. 5781 - 5788 Title/Abstract Full Text View citing articles Show Details

Stage #1: With [Ag(py)2MnO4]; acetic acid in water

T=24.84°C; 10 h; Darkness; Stage #2: With hydrogenchloride

Kinetics; Temperature;

Purohit, Trupti; Banerji, Jayshree; Kotai, Laszlo; Sajo; Banerji; Sharma, Pradeep K.

Journal of the Indian Chemical Society, 2012 , vol. 89, # 8 p. 1045 - 1052 Title/Abstract Full Text View citing articles Show Details

95 %Chromat.

With water; copper dichloride

T=250°C; P=30003 Torr; 6 h; Sealed tubeGreen chemistry;

Yang, Ziming; Hartnett, Hilairy E.; Shock, Everett L.; Gould, Ian R.

Journal of Organic Chemistry, 2015 , vol. 80, # 24 p. 12159 - 12165 Title/Abstract Full Text View citing articles Show Details

With oxygen

T=100°C; P=26252.6 Torr; 6 h; Autoclave;

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

70 %Spectr.

With C59H45BFeN6O3; oxygen in benzene

T=20°C; 0.333333 h;

Bhattacharya, Shrabanti; Rahaman, Rubina; Chatterjee, Sayanti; Paine, Tapan K.

Chemistry - A European Journal, 2017 , vol. 23, # 16 p. 3815 - 3818 Title/Abstract Full Text Show Details

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97%

With copper(II) nitrate trihydrate; oxygen in acetonitrile

T=120°C; P=4500.45 Torr; 10 h; Autoclave; Hide Experimental Procedure

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Rx-ID: 719041 Find similar reactions

Liu, Huifang; Wang, Min; Li, Hongji; Luo, Nengchao; Xu, Shutao; Wang, Feng

Journal of Catalysis, 2017 , vol. 346, p. 170 - 179 Title/Abstract Full Text View citing articles Show Details

2.2.1. The oxidation of acetophenone and substituted aryl ketones

General procedure: The catalytic reactions were performed in a 15-mL autoclavereactor with an internal Teflon insert. Typically, 0.5 mmol ofketone, 0.1 mmol of copper salt and 2 mL of solvent were addedinto the reactor. Then, the reactor was charged with 0.6 MPa O2and heated to 120 °C under magnetic stirring. After cooling to theroom temperature, the reaction mixture was diluted with 4 mLmethanol before analysis. The products were identified and quantifiedusing gas chromatography-mass spectrometry (GC–MS) andan Agilent 7890A/5975C instrument equipped with an HP-5 MScolumn (30 m in length, 0.25 mm in diameter). p-Xylene was usedas the internal standard.

96%

With sodium hydroxide; sodium bromite; sodium bromide in water

6 h; Ambient temperature;

Kajigaeshi, Shoji; Nakagawa, Takashi; Nagasaki, Noritaka; Fujisaki, Shizuo

Synthesis, 1985 , # 6/7 p. 674 - 675 Title/Abstract Full Text Show Details

93%

With copper(l) iodide; hydroxylamine hydrochloride; oxygen in dimethyl sulfoxide

T=100°C; 8 h;

Sathyanarayana, Pochampalli; Ravi, Owk; Muktapuram, Prathap Reddy; Bathula, Surendar Reddy

Organic and Biomolecular Chemistry, 2015 , vol. 13, # 37 p. 9681 - 9685 Title/Abstract Full Text View citing articles Show Details

Hide Details

93%

With phen; oxygen; copper diacetate; potassium hydoxide in dimethyl sulfoxide

T=130°C; P=3000.3 Torr; 12 h; Autoclave; Hide Experimental Procedure

Wang, Min; Lu, Jianmin; Li, Lihua; Li, Hongji; Liu, Huifang; Wang, Feng

Journal of Catalysis, 2017 , vol. 348, p. 160 - 167 Title/Abstract Full Text Show Details

2.2. Catalytic tests

General procedure: The catalytic reactions were performed in a 10-mL autoclave reactor with an internal Teflon insert. Typically, 0.5 mmol of secondary alcohols, 0.04 mmol of Cu(OAc)2 and 0.04 mmol of ligand, 1 mmol of base, and 2 mL of solvent were added to the reactor.Then, the reactor was charged with 0.4 MPa O2 and heated to the desired temperature under magnetic stirring. When the reaction reached completion, the reaction mixture was diluted with 4 mL of methanol, and the catalyst was separated via centrifugation.The acid product was esterified with addition of 40 μl of BF3OEt2 at 100 °C for 6 h in Ar atmosphere. In reaction condition optimization experiment, the products were identified and quantified using gas chromatography-mass spectrometry (GC–MS) and an Agilent7890A/5975C instrument equipped with an HP-5 MS column (30 m in length, 0.25 mm in diameter). p-Xylene was used as the internal standard. In the substrate scope experiment, the product was isolated and identified by NMR. The procedure for the isolation of the product is as follows: after the reaction completed, the reactor was cooled to room temperature in water and vented the gas.The reaction mixture was acidified with HCl 1.0 M (pH 1–2,15 mL) and then extracted with Et2O (3 x 20 mL). Next, the combined organic layers were washed with HCl 1.0 M (pH 1–2,3 10 mL), dried over anhydrous Na2SO4, and filtered and the Et2O was rotary evaporated. Solid products obtained were vacuum dried for 10 h at 60 °C. 83%

Stage #1: With tert.-butylhydroperoxide; sodium hydroxide; tungsten(VI) oxide in water

T=80°C; 8 h; Stage #2: With hydrogenchloride in water

Shaikh, Tanveer Mahammad Ali; Sudalai, Arumugam

European Journal of Organic Chemistry, 2008 , # 29 p. 4877 - 4880 Title/Abstract Full Text View citing articles Show Details

82%

With oxygen; manganese (II) acetate tetrahydrate in acetic acid

T=100°C; P=760.051 Torr; 15 h;

Nakamura, Ryota; Obora, Yasushi; Ishii, Yasutaka

Advanced Synthesis and Catalysis, 2009 , vol. 351, # 10 p. 1677 - 1684 Title/Abstract Full Text View citing articles Show Details

61%

With potassium hydroxide in N,N-dimethyl-formamide

T=65 - 68°C; alkaline cleavage; 12 h;

Zabjek, Alenka; Petric, Andrej

Tetrahedron Letters, 1999 , vol. 40, # 33 p. 6077 - 6078 Title/Abstract Full Text View citing articles Show Details

60%

With tert.-butylhydroperoxide; rhenium(VII) oxide; acetic acid

T=100°C; 4 h;

Gurunath; Sudalai

Synlett, 1999 , # 5 p. 559 - 560 Title/Abstract Full Text View citing articles Show Details

55%

With hydroxylamine hydrochloride; iodine in dimethyl sulfoxide

T=100°C; 10 h;

Sathyanarayana, Pochampalli; Upare, Atul; Ravi, Owk; Muktapuram, Prathap Reddy; Bathula, Surendar Reddy

RSC Advances, 2016 , vol. 6, # 27 p. 22749 - 22753 Title/Abstract Full Text View citing articles Show Details

15%

With Ambelyst 15 in toluene

30 h; Reflux;

Kumar, Amit; Dixit, Manish; Singh, Salil P.; Raghunandan, Resmi; Maulik, Prakas R.; Goel, Atul

Tetrahedron Letters, 2009 , vol. 50, # 30 p. 4335 - 4339 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide; chlorine

Van Arendonk; Cupery

Journal of the American Chemical Society, 1931 , vol. 53, p. 3184 Full Text View citing articles Show Details

With sodium hypobromide

Coulson

Journal of the Chemical Society, 1934 , p. 1406,1410 Full Text View citing articles Show Details

Buu-Hoi et al.

Journal of Organic Chemistry, 1952 , vol. 17, p. 1463 Full Text View citing articles Show Details

With alkaline potassium ferricyanide

Buchka; Irish

Chemische Berichte, 1887 , vol. 20, p. 1763 Full Text View citing articles Show Details

With air

T=150 - 200°C; unter Lichtausschluss;

Maruyama; Goto

Wood Res. KyotoChem.Abstr., 1956 , # 16 p. 16,20; engl. Ref. S. 24 Wood Res. KyotoChem.Abstr., 1957 , p. 4313 Full Text Show Details

With 18-crown-6 ether; acetophenone in benzene

T=25°C; 24 h; relative reactivity; further oxidative agents; Mechanism;

Lissel, Manfred

Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1987 , vol. 42, # 1 p. 12 - 14 Title/Abstract Full Text Show Details

With manganese(II) nitrate; oxygen; cobalt(II) nitrate in acetic acid

T=100°C; 6 h;

Minisci, Francesco; Recupero, Francesco; Fontana, Francesca; Bjorsvik, Hans-Rene; Liguori, Lucia

Synlett, 2002 , # 4 p. 610 - 612 Title/Abstract Full Text View citing articles Show Details

85 % Chromat.

With dihydrogen peroxide; oxygen; Ce(NTf2)x in acetic acid

Baeyer-Villiger oxidation; 6 h; Heating;

Baudry, Denise Barbier; Dormond, Alain; Duris, Fanny; Bernard, Jean Marie; Desmurs, Jean Roger

Journal of Fluorine Chemistry, 2003 , vol. 121, # 2 p. 233 - 238 Title/Abstract Full Text View citing articles Show Details

With dihydrogen peroxide in water

T=22 - 25°C; 11688 h;

Terent'ev, Alexander O.; Pastukhova, Zhanna Yu.; Yaremenko, Ivan A.; Bruk, Lev G.; Nikishin, Gennady I.

Mendeleev Communications, 2016 , vol. 26, # 4 p. 329 - 331 Title/Abstract Full Text View citing articles Show Details

With oxygen

T=140°C; P=15001.5 Torr; 6 h; Autoclave;

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

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A: 7% B: 21.1% C: 5.8%

With [FeCl2{κ3-HC(pyrazol-1-yl)3}]; dihydrogen peroxide; nitric acid in water; acetonitrile

T=35°C; 9 h; Green chemistry; Catalytic behavior; Time; Overall yield = 33.9 percent; Hide Experimental Procedure

Mendes, Marta; Ribeiro, Ana Paula C.; Alegria, Elisabete C.B.A.; Martins, Luísa M.D.R.S.; Pombeiro, Armando J.L.

Polyhedron, 2017 , vol. 125, p. 151 - 155 Title/Abstract Full Text View citing articles Show Details

A: 19 % Chromat. B: 11 % Chromat. C: 27 % Chromat.

With (NH4)6H2lt;Ce(IV)Mo12O42*10H2O; tetrabutylammonium acetate in water; acetic acid

T=50°C; 2 h; without protection from air; Product distribution;

Eberson, Lennart; Joensson, Lennart

Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1986 , vol. 40, # 2 p. 79 - 91 Title/Abstract Full Text Show Details

A: 10 % Chromat. B: 60 % Chromat. C: 10 % Chromat.

With air; Ptlt;NPhNC(S)SCH3gt;2 in acetonitrile

Ambient temperatureIrradiationrelative rate; Product distribution;

Monaci, Anna

Gazzetta Chimica Italiana, 1986 , vol. 116, # 6 p. 339 - 340 Title/Abstract Full Text Show Details

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A: 2.7 % Turnov. B: 67.4 % Turnov. C: 29.9 % Turnov.

With N -hydroxyphthalimide; tetrabutyl-ammonium chloride; oxygen in acetonitrile T=75°C; 20 h; atmospheric pressure;

Figiel; Sobczak

Polish Journal of Chemistry, 2001 , vol. 75, # 6 p. 869 - 873 Title/Abstract Full Text View citing articles Show Details

With oxygen; pyridine; manganese acetate (II); hydrogen bromide; cobalt(II) acetate

T=170°C; P=10501.1 Torr; 5 h; Product distribution / selectivity;

Toray Industries, Inc.

Patent: JP2005/213181 A, 2005 ; Location in patent: Page/Page column 7; 9 ;

With oxygen; pyridine; manganese acetate (II); hydrogen bromide; cobalt(II) acetate; copper (I) acetate

T=170°C; P=10501.1 Torr; 5 h; Product distribution / selectivity;

Toray Industries, Inc.

Patent: JP2005/213181 A, 2005 ; Location in patent: Page/Page column 7-9 ;

With oxygen; pyridine; manganese acetate (II); hydrogen bromide; cobalt(II) acetate; cerium(III) acetate

T=170°C; P=10501.1 Torr; 5 h; Product distribution / selectivity;

Toray Industries, Inc.

Patent: JP2005/213181 A, 2005 ; Location in patent: Page/Page column 8-9 ;

With oxygen; pyridine; hydrogen bromide; cobalt(II) acetate; copper (I) acetate

T=170°C; P=10501.1 Torr; 5 h; Product distribution / selectivity;

Toray Industries, Inc.

Patent: JP2005/213181 A, 2005 ; Location in patent: Page/Page column 7; 9 ;

Title/Abstract Full Text Show Details

With oxygen; pyridine; hydrogen bromide; cobalt(II) acetate

T=170°C; P=10501.1 Torr; 5 h; Product distribution / selectivity;

Toray Industries, Inc.

Patent: JP2005/213181 A, 2005 ; Location in patent: Page/Page column 8-9 ; Title/Abstract Full Text Show Details

With oxygen

T=100°C; P=760.051 Torr; 24 h;

Hu, Lei; Shi, Linyan; Hong, Haiyan; Li, Min; Bao, Qinye; Tang, Jianxin; Ge, Jianfeng; Lu, Jianmei; Cao, Xueqin; Gu, Hongwei

Chemical Communications, 2010 , vol. 46, # 45 p. 8591 - 8593 Title/Abstract Full Text View citing articles Show Details

With oxygen in acetonitrile

T=150°C; P=7500.75 Torr; 22 h; Autoclave; chemoselective reaction;

Li, Xin-Hao; Chen, Jie-Sheng; Wang, Xinchen; Sun, Jianhua; Antonietti, Markus

Journal of the American Chemical Society, 2011 , vol. 133, # 21 p. 8074 - 8077 Title/Abstract Full Text View citing articles Show Details

With ([MnIII(5,10,15,20-tetra(4-chlorophenyl)porphyrin)]chloride)

T=190°C; P=9000.9 Torr; 5 h; Neat (no solvent)Autoclave;

Xiao, Yang; Zhang, Xiaoyan; Wang, Qin Bo; Tan, Ze; Guo, Can Cheng; Deng, Wei; Liu, Zhi Gang; Zhang, He Fei

Chinese Chemical Letters, 2011 , vol. 22, # 2 p. 135 - 138 Title/Abstract Full Text View citing articles Show Details

B: 221 μmol

With oxygen

T=20°C; P=750.075 Torr; 4 h; Irradiation; Kinetics; Reagent/catalystTimeSolvent;

Yuan, Rusheng; Fan, Shaolong; Zhou, Huaxi; Ding, Zhengxin; Lin, Sen; Li, Zhaohui; Zhang, Zizhong; Xu, Chao; Wu, Ling; Wang, Xuxu; Fu, Xianzhi

Angewandte Chemie - International Edition, 2013 , vol. 52, # 3 p. 1035 - 1039 Angew. Chem., 2013 , vol. 125, # 3 p. 1069 - 1073 Title/Abstract Full Text View citing articles Show Details

With cobalt naphthenate; 5,10,15,20-tetrakis(4methylphenyl)porphyrinatocopper(II); C40H32MnN8

T=130°C; P=3750.38 - 7500.75 Torr; 5 h; Reagent/catalystPressureTemperature;

Quzhou Qunying Chemical Technology Co. Ltd; Wang, Qinbo; Xiong, Zhenhua; Chen, Chuxiong

Patent: CN105237343 A, 2016 ; Location in patent: Paragraph 0060; 0061 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

550 g of p-xylene was added to a 1 L batch-type oxidation reactor, and 800 ppm (concentration in p-xylene) of cobalt naphthenate, metal phthalocyanine of the general formula (IV) (R1= CH3CH2, R2= H, M = Mn), metalloporphyrins having the structure of general formula (I)1= R2= H, R3= CH3, M = Cu) as a catalyst, and 99.0 g of a mixture of p-carboxybenzyl alcohol, p-methylbenzaldehyde and p-methylbenzyl alcohol as a co-oxidizing agent, 1.0 MPa of air was continuously introduced, The reactor was kept at a pressure of 0.5 MPa while the temperature of the reactor was kept at 130 . After 5 hours, the reaction was stopped and the reaction mixture was rapidly cooled and sampled and analyzed.The analytical results of the liquid chromatography showed that the conversion of p-xylene was 11.9percent, the total selectivity of the alcoholic acid in the final oxidation product was 98.0percent, and the total selectivity of the aldol was 83.9percent. The selectivity to pmethylbenzyl alcohol was 37.7percent The selectivity to p-methylbenzaldehyde was 46.2percent The selectivity to p-toluic acid was 14. 1percent.

With hafnium(IV) oxide; N-hydroxy-o-sulphonyl benzamide; C44H28N4O8Ru; C32H12F4FeN8; oxygen in water

T=168 - 179°C; P=4500.45 - 5250.53 Torr; 2.9 h; Flow reactor; PressureReagent/catalystTemperature; Hide Experimental Procedure

Quzhou Qunying Chemical Technology Co. Ltd.,; Wang, Qinbo; Xiong, Zhenhua; Chen, Chuxiong

Patent: CN105237344 A, 2016 ; Location in patent: Paragraph 0065-0066 ; Title/Abstract Full Text Show Details

The catalyst dissolved in the fresh paraxylene of the system is Hf02, N-hydroxy-o-sulphonylbenzamide, metal phthalocyanine with structure of formula (IV) = H, R2 = F, M = Fe) And metalloporphyrins d having the general formula (1) = R3 = 0H, R2 = H, and M = Ru) in a total concentration of 600 ppm. The steady-state operation of the apparatus, the fresh paraxylene in the primary oxidation reactor was fed at a flow rate of 15. 7 mL / h and the recycle of the octa-rich oxygen-containing compound and para-xylene The flow rate is 125. OmL / h, and the total flow rate is 140.7mL / h in the primary oxidation reactor. The average residence time of the primary oxidation reactor in the liquid phase was 1.6 h, and the pressurized pure oxygen was continuously fed into the primary oxidation reactor. The reaction temperature was 179 ° C and the reaction pressure was 0.6 MPa . The volume of water added into the secondary oxidation reactor was 46.3 mL / h, and the volume of water added into the secondary oxidation reactor was 0.33: 1, and the pressurized pure oxygen was continuously fed into the reactor. The reaction temperature in the secondary oxidation reactor was maintained at 175 ° C and the reaction pressure was 0.7 MPa. The residence time of the liquid phase in the secondary oxidation reactor was 1.3 h.The outlet of the secondary oxidation reactor was continuously introduced into the liquid-liquid delaminator. The temperature of the delaminator was 168 ° C, The pressure was 0.6 MPa. The oil phase rich in octa-carbon oxygen-containing compounds and paraxylene at the upper portion of the liquid-liquid delaminator is recirculated back to primary oxygen The lower layer contains p-methylbenzoic acid, p-methylbenzyl alcohol / aldehyde and a small amount of impurities in the aqueous phase of terephthalic acid into the subsequent units. The conversion of p-xylene in the system was 99.5percent, and the conversion of pmethylbenzene The total selectivity of formic acid and p-methylbenzyl alcohol / aldehyde was 98.74percent. The selectivity of p-methylbenzoic acid was 93. 9percent.

With dihydrogen peroxide in 1,4-dioxane

T=55°C; 4 h;

Domínguez, María Isabel; Cojocaru, Bogdan; Tudorache, Madalina; Odriozola, José Antonio; Centeno, Miguel Angel; Parvulescu, Vasile I.

Comptes Rendus Chimie, 2016 , vol. 19, # 10 p. 1156 - 1165 Title/Abstract Full Text View citing articles Show Details

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90%

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With phen; oxygen; copper diacetate; potassium hydoxide in dimethyl sulfoxide

T=130°C; P=3000.3 Torr; 12 h; Autoclave; Hide Experimental Procedure

Rx-ID: 40158574 Find similar reactions

Wang, Min; Lu, Jianmin; Li, Lihua; Li, Hongji; Liu, Huifang; Wang, Feng

Journal of Catalysis, 2017 , vol. 348, p. 160 - 167 Title/Abstract Full Text Show Details

2.2. Catalytic tests

88%

With oxygen; 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride; sodium t-butanolate in dichloromethane

T=20°C; 30 h; Molecular sieve; Reagent/catalyst; Hide Experimental Procedure

Yu, Dong-Fang; Xing, Ping; Jiang, Biao

Tetrahedron, 2015 , vol. 71, # 25 p. 4269 - 4273 Title/Abstract Full Text View citing articles Show Details

4.1. General procedure for the oxidation of aryl alcohol 1a-1o, or 6a-6h

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85%

With tert.-butylhydroperoxide; copper diacetate in neat (no solvent) T=80°C; 5 h; Green chemistry;

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With water in acetonitrile

1.5 h; Photolysis; Quantum yield; Wavelength;

Hashemi; Saberi; Poorsadeghi; Niknam

RSC Advances, 2017 , vol. 7, # 13 p. 7619 - 7622 Title/Abstract Full Text View citing articles Show Details

Rx-ID: 45035013 Find similar reactions

Chaudhuri, Amrita; Venkatesh, Yarra; Behara, Krishna Kalyani; Singh, N. D. Pradeep

Organic Letters, 2017 , vol. 19, # 7 p. 1598 - 1601 Title/Abstract Full Text Show Details

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Rx-ID: 44747965 Find similar reactions

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84%

With iodine; dimethyl sulfoxide

T=120°C; 28 h; Sealed tubeGreen chemistry;

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Rx-ID: 45050952 Find similar reactions

Kalmode, Hanuman P.; Vadagaonkar, Kamlesh S.; Shinde, Suresh L.; Chaskar, Atul C.

Journal of Organic Chemistry, 2017 , vol. 82, # 7 p. 3781 - 3786 Title/Abstract Full Text Show Details

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Rx-ID: 277170 Find similar reactions

88%

With MoO(O2)(8-quinolinolate)2; dihydrogen peroxide in acetonitrile

Oxidation; 6 h; Heating;

Bandyopadhyay, Ratna; Biswas, Sudeb; Guha, Subhadra; Mukherjee, Alok K.; Bhattacharyya, Ramgopal

Chemical Communications, 1999 , # 17 p. 1627 - 1628 Title/Abstract Full Text View citing articles Show Details

86%

T=165°C; P=2432.16 Torr; Hide Experimental Procedure

Yuanjiang Hualong Catalyst Technology Co., Ltd.; Guo, Cancheng; Guo, Xin

Patent: CN105218344 A, 2016 ; Location in patent: Paragraph 0049; 0050 ; Title/Abstract Full Text Show Details

2:Example 2

The p-methylbenzoic acid product was prepared by air oxidation of p-xylene using the reaction separation synchronous reactor shown in Fig. 1;ContainingP-xylene raw materialsCopper tetraphenylporphyrin (concentration: 30 ppm)And cobalt oxide (concentration up to 120 ppm)As the composite catalyst,The mixed solution is fed from the reaction material inlet in the top of the constant temperature settling tower into the thermostatic settling tower and the bubbling gravity reaction tower connected with the thermostatic settling tower until it is filled with the reaction zone of the constant temperature settling tower and the bubble gravity reaction tower, Of the gas feed inlet into the air, the bubble gravity reactor temperature is adjusted to 165 , the pressure inside the tower to maintain 3.2atm oxidation reaction, open the loop of the valve, open the circulating pump, the reaction of p-methyl benzoic acid products along The rapid settlement of the gravity settling plate, into the thermostat settling tower, p-methylbenzoic acid product retained in the porous plate. When the p-methylphenyl formic acid is required to be withdrawn, the circulation pump is stopped, the reaction liquid is recovered from the bottom of the thermostat settling column, the thermostat settling column is taken out and the p-methylphenyl formic acid in the constant temperature settling column is collected. After simple drying of the collected p-methylbenzoic acid product, the product was detected, the p-xylene conversion was 92.0percentThe yield of p-toluic acid was 86.0percent.The reaction continued and no pipe plugging occurred.

83%

With 2-chloroanthracene-9,10-dione; water; oxygen; trifluoroacetic acid in ethyl acetate

24 h; Irradiation;

Tada, Norihiro; Hattori, Kasumi; Nobuta, Tomoya; Miura, Tsuyoshi; Itoh, Akichika

Green Chemistry, 2011 , vol. 13, # 7 p. 1669 - 1671 Title/Abstract Full Text View citing articles Show Details

Hide Details

80.2%

With 2H(1+)*Co(2+)*C16H24N4O10(4-)

T=110°C; 5 h; Catalytic behavior; Reagent/catalyst; Hide Experimental Procedure

Wei, Xing-Yue; Wang, Xing-Min; Li, Ning; Qin, Sheng-Ying

Chinese Chemical Letters, 2015 , vol. 26, # 1 p. 100 - 102 Title/Abstract Full Text View citing articles Show Details

2 Experimental

The oxidation of p-xylene to p-toluic acid (PTA) catalyzed by CoL1–CoL4 were conducted in a normal gas–liquid apparatus. Air was bubbled into the mixture of p-xylene (40 mL) and CoL (1×10−3molL−1) with a 2.0 Lmin−1 flow rate at 110°C. The reaction mixture (0.1 mL) was sampled by pipette periodically before the precipitates appeared (in 5 h), and diluted to 15 mL with ethanol. The accumulative concentration of PTA was determined by the standard acid–base titration. The selective oxidation for PTA was determined by HPLC. The catalytic oxidation performances of CoL1–CoL4 were shown in Table 2. 78%

Stage #1: With tert.-butylhydroperoxide; sodium hydroxide; tungsten(VI) oxide in water

T=80°C; 10 h; Stage #2: With hydrogenchloride in water

Shaikh, Tanveer Mahammad Ali; Sudalai, Arumugam

European Journal of Organic Chemistry, 2008 , # 29 p. 4877 - 4880 Title/Abstract Full Text View citing articles Show Details

77%

With zinc(II) oxide in N,N-dimethyl-formamide

0.1 h; microwave irradiation;

Gupta, Monika; Paul, Satya; Gupta, Rajive; Loupy, Andre

Tetrahedron Letters, 2005 , vol. 46, # 30 p. 4957 - 4960 Title/Abstract Full Text View citing articles Show Details

72%

With sodium bromate; 1-n-butyl-3-methylimidazolim bromide

T=70°C; 12 h;

Shaabani, Ahmad; Farhangi, Elham; Rahmati, Abbas

Monatshefte fur Chemie, 2008 , vol. 139, # 8 p. 905 - 908 Title/Abstract Full Text View citing articles Show Details

70%

With sodium periodate; sulfuric acid; lithium bromide in water

T=95°C; 18 h;

Shaikh, Tanveer Mahammad Ali; Emmanuvel, Lourdusamy; Sudalai, Arumugam

Journal of Organic Chemistry, 2006 , vol. 71, # 13 p. 5043 - 5046 Title/Abstract Full Text View citing articles Show Details

51%

With 2,2'-azobis(isobutyronitrile); oxygen; sodium bromide; cobalt(II)

Yang, Fan; Sun, Jing; Zheng, Rui; Qiu, Wenwei; Tang, Jie; He, Mingyuan

acetate; acetic acid in various solvent(s) T=110°C; P=760.051 Torr; 2 h;

Tetrahedron, 2004 , vol. 60, # 5 p. 1225 - 1228 Title/Abstract Full Text View citing articles Show Details

35%

With (CH3)3NO SbCl5; oxygen

Yamamoto, Jiro; Murakami, Mitushige; Kameoka, Noriaki; Otani, Norio; Umezu, Masahiro; Matsuura, Teruo

Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 1 p. 345 - 346 Title/Abstract Full Text Show Details

30%

With chromium(VI) oxide; acetic acid

T=7°C; 2 h; Irradiation;

Shul'pin, G. B.; Macova, E.; Lederer, P.

J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 11 p. 2604 - 2611,2329 - 2334 Title/Abstract Full Text Show Details

30%

With water; ozone in acetonitrile

15 h; Hide Experimental Procedure

NATIONAL TSING HUA UNIVERSITY; HWANG, Kuo-Chu

Patent: US2016/102038 A1, 2016 ; Location in patent: Paragraph 0049 ; Title/Abstract Full Text Show Details

On the other hand, the present invention may also only use ozone and substrates to carry out the reaction without additional irradiation, but yield thereof is lower (as compared to the photo-irradiated reaction). The mechanism of the dark reaction is also not the same as that of the photo-irradiated reaction. The mechanism of the dark reaction mainly involves that ozone abstracts a hydrogen atom directly from substrates to produce HOOO. and alkyl (R.) free radicals. The alkyl free radical can further react with molecular oxygen to proceed through a peroxidation chain reaction to generate alkyl hydroperoxide (ROOH). Consequently, the Embodiments 19 to 35 in accordance with the present invention are akin to the Embodiments 2 to 18 which are to use the same reactants, co-solvent; and the reaction time is the same, as well. The difference thereof only lies in that the former is the reaction carried out in the presence of ozone in the dark, and the related reaction conditions and yields of the Embodiments 19 to 35 in accordance with the present invention are summarized in the following Tables 4, 5 and 6.

25%

With Co4O4(O2CMe)4(py)4; oxygen

T=130°C; 7 h; neat (no solvent);

Das, Birinchi Kumar; Chakrabarty, Rajesh

Journal of Chemical Sciences, 2011 , vol. 123, # 2 p. 163 - 173 Title/Abstract Full Text View citing articles Show Details

With air; magnesium naphthenate

T=130°C;

Farbenfabr. Bayer

Patent: DE767366 , 1940 ; DRP/DRBP Org.Chem. Full Text Show Details

With cobalt(II) 4-methylbenzoate; oxygen

Hercules Powder Co.

Patent: US2727921 , 1954 ;

With oxygen; thallium(I) acetate

With nitric acid

Full Text Show Details

Union Oil Co. of California

Patent: US2887511 , 1953 ; Full Text Show Details

Brueckner

Justus Liebigs Annalen der Chemie, 1880 , vol. 205, p. 118 Full Text View citing articles Show Details

Fittig; Ahrens; Mattheides

Justus Liebigs Annalen der Chemie, 1868 , vol. 147, p. 29 Full Text View citing articles Show Details

Dittmar; Kekule

Justus Liebigs Annalen der Chemie, 1872 , vol. 162, p. 339 Full Text View citing articles Show Details

Yssel de Schepper; Beilstein

Justus Liebigs Annalen der Chemie, 1866 , vol. 137, p. 302 Full Text Show Details

With 9,10-phenanthrenequinone

Irradiation;

Eckert

Patent: DE383030 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 14, p. 442 Full Text Show Details

With air; sodium carbonate

T=250°C; P=45600 Torr;

Fischer,F.

Patent: DE364442 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 14, p. 439 Full Text Show Details

With water; oxygen

im Sonnenlicht;

Ciamician; Silber

Chemische Berichte, 1912 , vol. 45, p. 41

Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1911 , vol. <5> 20 II, p. 675 Full Text View citing articles Show Details

With manganese(IV) oxide; sulfuric acid

T=20 - 25°C;

Wegscheider; Suida

Monatshefte fuer Chemie, 1912 , vol. 33, p. 1010 Full Text View citing articles Show Details

With chloropicrin

Irradiation;

Piutti; Badolato

Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1924 , vol. <5> 33 I, p. 478 Full Text View citing articles Show Details

With oxygen; cobalt(II) acetate

Manukowskaja et al.

Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 158; engl. Ausg. S. 162 Full Text View citing articles Show Details

85 % Chromat.

With N -hydroxyphthalimide; oxygen; cobalt(II) acetate in acetic acid

T=25°C; P=760.051 Torr; 20 h;

Tashiro, Yasutaka; Iwahama, Takahiro; Sakaguchi, Satoshi; Ishii, Yasutaka

Advanced Synthesis and Catalysis, 2001 , vol. 343, # 2 p. 220 - 225 Title/Abstract Full Text View citing articles Show Details

With oxygen; acetic acid; palladium diacetate; V(acac)3; C8H12HfO8; antimony(III) acetate in water

T=167°C; P=10501.1 Torr; 1 h; Product distribution / selectivity; Hide Experimental Procedure

BP Corporation North America Inc.

Patent: US2009/69594 A1, 2009 ; Location in patent: Page/Page column 21-22 ; Title/Abstract Full Text Show Details

43-17:

EXAMPLE 43; Following the procedure of Examples 1-4, a series of para-xylene oxidation trials in aqueous acetic acid solvent was conducted using compositions prepared from various combinations of one or more acetic acid soluble salts of palladium, platinum, vanadium, titanium, molybdenum, chromium, tin, antimony and, in some cases, acetic acid-soluble salts of one or more of additional metal or metalloid or standardized solutions thereof in aqueous acetic acid in amounts providing the metals or metalloids in about equal parts by weight corresponding to about 500 ppmw based on weight of acetic acid solvent used in the oxidations. Metal and metalloid combinations, temperatures and oxidation results are reported in TABLE 14; results of Examples 1-4 are also included for reference. 28 %Chromat.

With PEG-1000; carbon dioxide; oxygen; cobalt(II) acetate

T=100°C; P=75007.5 Torr; 12 h; AutoclaveNeat (no solvent);

Wang, Jin-Quan; He, Liang-Nian

New Journal of Chemistry, 2009 , vol. 33, # 8 p. 1637 - 1640 Title/Abstract Full Text View citing articles Show Details

7.8 %Chromat.

With oxygen

T=140°C; 3 h; Neat (no solvent);

Beier, Matthias J.; Schimmoeller, Bjoern; Hansen, Thomas W.; Andersen, Jens E.T.; Pratsinis, Sotiris E.; Grunwaldt, Jan-Dierk

Journal of Molecular Catalysis A: Chemical, 2010 , vol. 331, # 1-2 p. 40 - 49 Title/Abstract Full Text View citing articles Show Details

With sodium nitrate; C35H34Cl2MnN3O6

T=120°C; P=760.051 Torr; 12 h;

Li, Jian-Zhang; Yang, Zhu-Zhu; He, Xi-Yang; Zeng, Jun; Qin, Sheng-Ying

Journal of Chemical Research, 2010 , # 10 p. 581 - 584 Title/Abstract Full Text View citing articles Show Details

With sodium nitrate; C36H37ClMnN3O6

T=120°C; P=760.051 Torr; 12 h;

Li, Jian-Zhang; Yang, Zhu-Zhu; He, Xi-Yang; Zeng, Jun; Qin, Sheng-Ying

Journal of Chemical Research, 2010 , # 10 p. 581 - 584 Title/Abstract Full Text View citing articles Show Details

With sodium nitrate; C25H22Cl2MnN3O3

T=120°C; P=760.051 Torr; 12 h;

Li, Jian-Zhang; Yang, Zhu-Zhu; He, Xi-Yang; Zeng, Jun; Qin, Sheng-Ying

Journal of Chemical Research, 2010 , # 10 p. 581 - 584 Title/Abstract Full Text View citing articles Show Details

With sodium nitrate; C25H22BrClMnN3O3(2+)

T=120°C; P=760.051 Torr; 12 h;

Li, Jian-Zhang; Yang, Zhu-Zhu; He, Xi-Yang; Zeng, Jun; Qin, Sheng-Ying

Journal of Chemical Research, 2010 , # 10 p. 581 - 584 Title/Abstract Full Text View citing articles Show Details

With sodium nitrate; C20H13Cl2MnN2O2

T=120°C; P=760.051 Torr; 12 h;

Li, Jian-Zhang; Yang, Zhu-Zhu; He, Xi-Yang; Zeng, Jun; Qin, Sheng-Ying

Journal of Chemical Research, 2010 , # 10 p. 581 - 584 Title/Abstract Full Text View citing articles Show Details

With C20H13BrClMnN2O2; potassium nitrate

T=120°C; P=760.051 Torr; 12 h;

Li, Jian-Zhang; Yang, Zhu-Zhu; He, Xi-Yang; Zeng, Jun; Qin, Sheng-Ying

Journal of Chemical Research, 2010 , # 10 p. 581 - 584 Title/Abstract Full Text View citing articles Show Details

With sodium nitrate; C35H34BrClMnN3O6

T=120°C; P=760.051 Torr; 12 h;

Li, Jian-Zhang; Yang, Zhu-Zhu; He, Xi-Yang; Zeng, Jun; Qin, Sheng-Ying

Journal of Chemical Research, 2010 , # 10 p. 581 - 584 Title/Abstract Full Text View citing articles Show Details

15.5 %Chromat.

With oxygen; acetic acid

T=80°C; P=104260 Torr; 22 h; Supercritical conditions;

Zuo, Xiaobin; Niu, Fenghui; Snavely, Kirk; Subramaniam, Bala; Busch, Daryle H.

Green Chemistry, 2010 , vol. 12, # 2 p. 260 - 267 Title/Abstract Full Text View citing articles Show Details

29.7 %Chromat.

With oxygen; cobalt(II) acetate; manganese(II) acetate; 1,3,5trihydroxyhexahydro-1,3,5-triazine-2,4,6-trione in water

T=150°C; P=3750.38 Torr; 5 h; Product distribution / selectivity; Hide Experimental Procedure

Shibamoto, Akihiro

Patent: US2011/71313 A1, 2011 ; Location in patent: Page/Page column 11-12 ; Title/Abstract Full Text Show Details

Example 2; The reaction was conducted in the same manner as in Example 1 except that 0.025 g (0.141 mmol) of trihydroxyisocyanuric acid was used instead of N-hydroxysuccinimide. The conversion of the substrate and the amount and yield of the product were determined. As the results, the conversion of p-xylene was 36.4percent, and 113 g of p-toluic acid (yield 29.7percent), 21 g of terephthalic acid (yield 4.52percent), and 0.30 g of benzoic acid as a by-product (yield 0.0878percent) were obtained.

With C56H60Cl3MnN4O10

T=120°C; P=760.051 Torr; 9.5 h;

Li, Jian-Zhang; He, Xi-Yang; Zeng, Jun; Xiao, Zheng-Hua; Qin, Sheng-Ying

Transition Metal Chemistry, 2012 , vol. 37, # 1 p. 31 - 35 Title/Abstract Full Text View citing articles Show Details

With 2-pyridinecarboxylic acid; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; iodobenzene; oxygen

T=120°C; 12 h;

Yan, Yunyun; Chen, Yanyan; Yan, Ming; Li, Xingshu; Zeng, Wei

Catalysis Communications, 2013 , vol. 35, p. 64 - 67 Title/Abstract Full Text View citing articles Show Details

With acetic acid

T=64.84°C; P=760.051 Torr; 3 h; KineticsCatalytic behavior; Concentration;

Plekhov; Kushch; Opeida; Kompanets

Russian Journal of Applied Chemistry, 2014 , vol. 87, # 7 p. 982 - 985 Zh. Prikl. Khim. (S.-Peterburg, Russ. Fed.), 2014 , vol. 87, # 7 p. 986 - 989,4 Title/Abstract Full Text View citing articles Show Details

With C16H26CoN4O10

T=110°C; 5 h; Reagent/catalyst;

Long, Liang-Jun; Wei, Xing-Yue; Wang, Xing-Min; Li, Ning

Journal of the Chemical Society of Pakistan, 2015 , vol. 37, # 6 p. 1099 - 1102 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 277836 Find similar reactions

With manganese(IV) oxide; oxygen

T=140 - 170°C;

Sensemann; Stubbs

Industrial and Engineering Chemistry, 1932 , vol. 24, p. 1184 Full Text View citing articles Show Details

With manganese p-toluate; oxygen

T=140 - 170°C;

Sensemann; Stubbs

Industrial and Engineering Chemistry, 1932 , vol. 24, p. 1184 Full Text View citing articles Show Details

With air; vanadia

T=375°C;

Sensemann; Stubbs

Industrial and Engineering Chemistry, 1931 , vol. 23, p. 1129 Full Text View citing articles Show Details

Hide Details

With air; sodium carbonate

T=210°C; unter Druck;

Schrader

Abh. Kenntnis Kohle, vol. 4, p. 329 Chem. Zentralbl., 1921 , vol. 92, # I p. 537 Full Text Show Details

With chromium(III) oxide; sulfuric acid

T=100°C;

Meyer,H.; Bernhauer

Monatshefte fuer Chemie, 1929 , vol. 53/54, p. 728 Full Text View citing articles Show Details

With nitric acid

Tuley; Marvel

Organic Syntheses, 1947 , vol. 27, p. 86 Full Text Show Details

With sulfuric acid; nitric acid

Halse; Dedichen; Aschan; zit. bei Alfthan

Chemische Berichte, 1920 , vol. 53, p. 83,84 Full Text Show Details

Multi-step reaction with 2 steps 1: oxygen / 1 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: oxygen / 24 h / 100 °C / 15001.5 Torr / |Autoclave 2: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: oxygen / 6 h / 100 °C / 6000.6 Torr / |Autoclave 2: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: oxygen / 6 h / 80 °C / 15001.5 Torr / |Autoclave 2: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: oxygen; manganese(III) oxide / 6 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen / 1 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen / 1 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen / 24 h / 100 °C / 15001.5 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Multi-step reaction with 3 steps 1: oxygen / 24 h / 100 °C / 15001.5 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen / 24 h / 100 °C / 15001.5 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen / 24 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen / 24 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen / 6 h / 100 °C / 6000.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen / 6 h / 100 °C / 6000.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen / 6 h / 80 °C / 15001.5 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen; iron(III) oxide / 6 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen; manganese(III) oxide / 6 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen; iron(III) oxide / 6 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: oxygen; manganese(III) oxide / 6 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1: oxygen / 1 h / 100 °C / 26252.6 Torr 2: oxygen / 6 h / 100 °C / 26252.6 Torr 3: oxygen / 6 h / 100 °C / 26252.6 Torr 4: oxygen / 6 h / 100 °C / 26252.6 Torr View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1: oxygen / 1 h / 100 °C / 26252.6 Torr 2: oxygen / 6 h / 100 °C / 26252.6 Torr 3: oxygen / 6 h / 100 °C / 26252.6 Torr 4: oxygen / 6 h / 140 °C / 15001.5 Torr View Scheme

Multi-step reaction with 4 steps 1: oxygen / 24 h / 100 °C / 15001.5 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 4: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1: oxygen / 24 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 4: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

/ / / /

|Autoclave |Autoclave |Autoclave |Autoclave

/ / / /

|Autoclave |Autoclave |Autoclave |Autoclave

/ / / /

|Autoclave |Autoclave |Autoclave |Autoclave

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1: oxygen / 6 h / 100 °C / 6000.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 4: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1: oxygen / 6 h / 80 °C / 15001.5 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 4: oxygen / 6 h / 140 °C / 15001.5 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1: oxygen; iron(III) oxide / 6 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 4: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme

Neaţu, Florentina; Culică, Geanina; Florea, Mihaela; Parvulescu, Vasile I.; Cavani, Fabrizio

ChemSusChem, 2016 , vol. 9, # 21 p. 3102 - 3112 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1: oxygen; manganese(III) oxide / 6 h / 100 °C / 26252.6 Torr / |Autoclave 2: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 3: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave 4: oxygen / 6 h / 100 °C / 26252.6 Torr / |Autoclave View Scheme