Hydrogen iodide & Hydriodic acid [HI] by Asch

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14843 reactions 2016-03-14 20h:45m:43s (EST) in Reaxys

Search as: As drawn 5442 reactions in Reaxys

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(1. Query) AND itemno in (1)

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310 reactions in 2016-03-14 22h:11m:20s (EST) Reaxys

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Rx-ID: 26082971 View in Reaxys 1/310 Yield

Conditions & References With hydroselenic acid, reduction; Rolla, L.; Repetto, A.; Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti; vol. 21; nb. II; (1912); p. 463 - 463 View in Reaxys vol. I: MVol.1; 51, page 175 - 177 ; (from Gmelin) View in Reaxys With (COO)2(2-), byproducts: CO2; with oxalic acid; at high I(1-) concentration; Berthoud; Helvetica Chimica Acta; vol. 16; (1933); p. 393 View in Reaxys vol. I: MVol.2; 155, page 590 - 592 ; (from Gmelin) View in Reaxys With (COO)2(2-), byproducts: CO2; with oxalic acid; mechanism discussed; Abel, E.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 154; (1931); p. 170 - 170 View in Reaxys Berthoud, A.; Helvetica Chimica Acta; vol. 16; (1933); p. 397 - 397 View in Reaxys vol. I: MVol.2; 155, page 590 - 592 ; (from Gmelin) View in Reaxys With oxalic acid, byproducts: CO2; with oxalic acid; at low I(1-)-concentration; mechanism discussed; Berthoud; Helvetica Chimica Acta; vol. 16; (1933); p. 393 View in Reaxys vol. I: MVol.2; 155, page 590 - 592 ; (from Gmelin) View in Reaxys With oxalic acid in further solvent(s), byproducts: CO2; Irradiation (UV/VIS); with oxalic acid; effect of light to temperature coefficient discussed; Dhar; Bhattacharya; Mukerji; Nature (London, United Kingdom); vol. 131; (1933); p. 840 View in Reaxys Allmand, A. J.; Young, K. W.; Transactions of the Faraday Society; vol. 27; (1931); p. 519 - 519 View in Reaxys vol. I: MVol.2; 156, page 592 - 594 ; (from Gmelin) View in Reaxys With oxalic acid in further solvent(s), byproducts: CO2; Irradiation (UV/VIS); with oxalic acid; mechanism discussed; Griffith; McKeown; Winn; Transactions of the Faraday Society; vol. 29; (1933); p. 368,386 View in Reaxys Abel, E.; Schmid, H.; Retter, K.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 163; (1933); p. 62 - 62 View in Reaxys Abel, E.; Schmid, H.; Retter, K.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 163; (1933); p. 66 - 66 View in Reaxys Allmand, A. J.; Young, K. W.; Transactions of the Faraday Society; vol. 27; (1931); p. 522 - 522 View in Reaxys Berthoud, A.; Helvetica Chimica Acta; vol. 16; (1933); p. 397 - 397 View in Reaxys Griffith, R. O.; Keown, A. Mc; Winn, A. G.; Transactions of the Faraday Society; vol. 29; (1933); p. 369 - 369 View in Reaxys Griffith, R. O.; Keown, A. Mc; Winn, A. G.; Transactions of the Faraday Society; vol. 29; (1933); p. 395 - 395 View in Reaxys Schpolski, E. W.; Zhurnal Fizicheskoi Khimii; vol. 2; (1931); p. 468 - 468

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View in Reaxys vol. I: MVol.2; 156, page 592 - 594 ; (from Gmelin) View in Reaxys With oxalic acid in further solvent(s), Kinetics, byproducts: CO2; Irradiation (UV/VIS); with oxalic acid; effect of light discussed; Abel, E.; Schmid, H.; Retter, K.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 163; (1933); p. 59 - 59 View in Reaxys Abel, E.; Schmid, H.; Retter, K.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 163; (1933); p. 66 - 66 View in Reaxys vol. I: MVol.2; 156, page 592 - 594 ; (from Gmelin) View in Reaxys With oxalic acid in further solvent(s), Kinetics, byproducts: CO2; Irradiation (UV/VIS); with oxalic acid; effect of unfiltered Hg light or light with 3660 - 4050.ANG: discussed; Abel, E.; Schmid, H.; Retter, K.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 163; (1933); p. 65 - 65 View in Reaxys vol. I: MVol.2; 156, page 592 - 594 ; (from Gmelin) View in Reaxys With oxalic acid, Kinetics, byproducts: CO2; with oxalic acid; no influence of I3(1-); Abel, E.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 154; (1931); p. 173 - 173 View in Reaxys vol. I: MVol.2; 155, page 590 - 592 ; (from Gmelin) View in Reaxys With oxalic acid, Kinetics, byproducts: CO2; with oxalic acid; temperature coefficient discussed; Dhar; Bhattacharya; Mukerji; Nature (London, United Kingdom); vol. 131; (1933); p. 840 View in Reaxys Allmand; Young; Transactions of the Faraday Society; vol. 27; (1931); p. 518 View in Reaxys Berthoud, A.; Helvetica Chimica Acta; vol. 16; (1933); p. 396 - 396 View in Reaxys Griffith, R. O.; Keown, A. Mc; Transactions of the Faraday Society; vol. 28; (1932); p. 756 - 756 View in Reaxys vol. I: MVol.2; 155, page 590 - 592 ; (from Gmelin) View in Reaxys With oxalic acid, Kinetics, byproducts: CO2; with oxalic acid; Abel, E.; Schmid, H.; Retter, K.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 163; (1933); p. 53 - 53 View in Reaxys Abel, E.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 154; (1931); p. 172 - 172 View in Reaxys vol. I: MVol.2; 155, page 590 - 592 ; (from Gmelin) View in Reaxys With hydrogen sulfide in not given Mohr, F.; N. Repert. Pharm. Buchner; vol. 10; (1861); p. 152 View in Reaxys Mohr, F.; Z. Ch.; vol. 4; (1861); p. 543 View in Reaxys vol. K: MVol.3; 2.1.1.1, page 586 - 588 ; (from Gmelin) View in Reaxys

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With anhydrous sulfurous acid in water, byproducts: H2SO4; dild. aq. H2SO3 conc. of SO2 < 0.5percent anonymous; Min. J. (London); vol. 217; (1942); p. 272 View in Reaxys vol. Cu: MVol.A1; 5.1.2, page 490 - 493 ; (from Gmelin) View in Reaxys With sulfur dioxide, water in water, byproducts: H2SO4 Meyer, E. v.; J. Prakt. Chem. (2); vol. 36; (1887); p. 292 - 294 View in Reaxys vol. C: MVol.D3; 6.2.6.6.7.4, page 260 - 261 ; (from Gmelin) View in Reaxys With colophonium in neat (no solvent), byproducts: tar; iodine mixed with equal amounts of colophonium and sand; slowly heated;; tar condensed in receiver; iodine retained by red phosphorus in U-tube; HI passed over P2O5; dry, pure gas; Kastle, J. H.; Bullock, J. H.; American Chemical Journal; vol. 18; (1896); p. 109 - 109 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys >99

With copaivaoil (terpene) Bruylants, G.; Bulletin de la Classe des Sciences, Academie Royale de Belgique; vol. 47; (1879); p. 767 - 767 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys With hydrogen, Kinetics Balint, Imre; Ban, Miklos I.; Acta Chimica Hungarica; vol. 128; nb. 3; (1991); p. 431 - 438 ; (from Gmelin) View in Reaxys With kerosene in not given, shaking of a I2 soln. with kerosene; Panteleimonow, B.; Zh. Khim. Prom - sti.; vol. 5; (1928); p. 1220 - 1220 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys With starch in not given, shaking of a I2 soln. with starch; Panteleimonow, B.; Zh. Khim. Prom - sti.; vol. 5; (1928); p. 1220 - 1220 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys in 1,2,3,4-tetrahydro-naphthalene, addn. of I2 solution to the boiling solvent Yamamoto, Kimihisa; Oyaizu, Kenichi; Tsuchida, Eishun; Journal of the American Chemical Society; vol. 118; nb. 50; (1996); p. 12665 - 12672 ; (from Gmelin) View in Reaxys Bruylants, G.; Ber.; vol. 12; (1879); p. 2059 - 2059 ; (from Gmelin) View in Reaxys

H S

Rx-ID: 26083394 View in Reaxys 2/310 Yield

Conditions & References in neat (no solvent), Kinetics, byproducts: S; react. of solid I2 with gaseous H2S; Pollitzer, F.; Z. Anorg. Chem.; vol. 64; (1909); p. 121 - 121 View in Reaxys

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vol. I: MVol.2; 5, page 256 - 257 View in Reaxys Pollitzer, F.; Dissert. Berlin 1909 ; (from Gmelin) View in Reaxys With water in diethyl ether, byproducts: H2SO3 Parsons, L. B.; Journal of the American Chemical Society; vol. 47; (1925); p. 1820 - 1830 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys in gas, byproducts: S; dry H2S, gas reaction; equilibrium; Pollitzer, F.; Z. Anorg. Chem.; vol. 64; (1909); p. 121 - 121 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 View in Reaxys Pollitzer, F.; Dissert. Berlin 1909 ; (from Gmelin) View in Reaxys in tetrachloromethane, favorable effect of addn. of H2O; Rao, M. R. A.; Rao, B. S.; Journal of the Chemical Society; (1933); p. 836 - 839 ; (from Gmelin) View in Reaxys in water, byproducts: S; equilibrium; Pollitzer, F.; Z. Anorg. Chem.; vol. 64; (1909); p. 121 - 121 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 View in Reaxys Pollitzer, F.; Dissert. Berlin 1909 ; (from Gmelin) View in Reaxys in water, byproducts: S; no formation of sulfuric acid at room temp.; Rammelsberg, C.; Annalen der Physik (Weinheim, Germany); vol. 55; (1842); p. 253 - 253 View in Reaxys Rose, H.; Annalen der Physik (Weinheim, Germany); vol. 47; (1839); p. 163 - 163 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys in water, byproducts: S; on heating only a small amount of sulfuric acid forms as a by-product; Rammelsberg, C.; Annalen der Physik (Weinheim, Germany); vol. 55; (1842); p. 253 - 253 View in Reaxys Rose, H.; Annalen der Physik (Weinheim, Germany); vol. 47; (1839); p. 163 - 163 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys in water, byproducts: sulfur; impured with I2 or S (depending on excess of educt); Moles, E.; Miravalles, R.; Anales de la Real Sociedad Espanola de Fisica y Quimica; vol. 24; (1926); p. 364 - 364 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys in water, byproducts: sulfur; removing colloidal sulfur by 48 hour dialysis through collodion membrane, distn.;; pure HIsoln.; Whitehead, T. H.; Journal of Chemical Education; vol. 8; (1931); p. 541 - 541 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin)

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View in Reaxys in neat (no solvent), byproducts: sulfur; pptd. sulfur removed by filtration through glass wool and distillation; Husa, W. J.; Shattuck, P. St.; Journal of the American Pharmaceutical Association (1912-1977); vol. 21; (1932); p. 115 - 115 View in Reaxys Moles, E.; Miravalles, R.; Anales de la Real Sociedad Espanola de Fisica y Quimica; vol. 24; (1926); p. 364 - 364 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys >99

in diethyl ether, byproducts: S; absolute dry ether; Parsons, L. B.; Journal of the American Chemical Society; vol. 47; (1925); p. 1820 - 1830 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys in diethyl ether, byproducts: S; equilibrium reaction in ether soln.; vol. I: MVol.1; 55, page 182 - 183 View in Reaxys Parsons, L. B.; Journal of the American Chemical Society; vol. 47; (1925); p. 1820 - 1830 ; (from Gmelin) View in Reaxys in diethyl ether, favorable effect of addition of H2O; Rao, M. R. A.; Rao, B. S.; Journal of the Chemical Society; (1933); p. 836 - 839 ; (from Gmelin) View in Reaxys in carbon disulfide, byproducts: sulfur; introduction of H2S in a soln. of I2 in CS2 covered with H2O;; sulfur dissolves in CS2; separation of aq. HI-soln. and distn. gives pure HI-soln.; Rieckher; N. Jb. Pharm.; vol. 17; (1862); p. 328 - 328 View in Reaxys Winkler, Cl.; Journal fuer Praktische Chemie (Leipzig); vol. 102; (1867); p. 33 - 33 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys in neat (no solvent), easy react. of dry H2S with I2 at ambient temp.;; very small amounts of HI obtained; Pollitzer, F.; Z. Anorg. Chem.; vol. 64; (1909); p. 121 - 148 View in Reaxys vol. S: MVol.B1; 27, page 60 - 62 ; (from Gmelin) View in Reaxys in tetrachloromethane, favorable effect of addn. of H2O; vol. S: MVol.B1; 51, page 111 - 113 ; (from Gmelin) View in Reaxys in diethyl ether, favorable effect of addition of H2O; vol. S: MVol.B1; 51, page 111 - 113 ; (from Gmelin) View in Reaxys

H O

Rx-ID: 26082984 View in Reaxys 3/310 Yield 98 %

Conditions & References in gas, byproducts: O2; presence of coal, reactn.temp.: 800 °C; Daniltschenko, P.; Rawitsch, M.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 127 - 127; C. II; (1929); p. 708 ; (from Gmelin)

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View in Reaxys 98 %

in neat (no solvent, gas phase), byproducts: O2; presence of coal, reactn.temp.: 800 °C; vol. I: MVol.1; 50, page 173 - 175 ; (from Gmelin) View in Reaxys With phosphorus in neat (no solvent), according to J. R. Partington, General and Inorganic Chemistry (Macmillan, London, 1946); low temp. distn. Pettersson, Mika; Nieminen, Janne; Khriachtchev, Leonid; Raesaenen, Markku; Journal of Chemical Physics; vol. 107; nb. 20; (1997); p. 8423 - 8431 ; (from Gmelin) View in Reaxys

>99

in presence of organ. reducing agents, for instance tannine or peptones; Casanova, C.; Carcano, L.; Bollettino Chimico Farmaceutico; vol. 51; (1912); p. 292 - 292 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys With phosphorus in water, according to J. R. Partington, General and Inorganic Chemistry, Macmillan, London, 1946; low temp. distillation Pettersson, Mika; Nieminen, Janne; Chemical Physics Letters; vol. 283; nb. 1-2; (1998); p. 1 - 6 ; (from Gmelin) View in Reaxys

With carbon, potassium iodide in water, addition of KI inhibits formation of HI; Daniltschenko, P. T.; Rawitsch, M. J.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 123 - 123; C. II; (1929); p. 708 View in Reaxys vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Daniltschenko, P. T.; Rawitsch, M. J.; RU7791; (1928) ; (from Gmelin) View in Reaxys With carbon in water, after addition of HI and 15 hour heating stable equilibrium reached;; soln. contains neither IOH nor HIO3; Daniltschenko, P. T.; Rawitsch, M. J.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 123 - 123; C. II; (1929); p. 708 View in Reaxys vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Daniltschenko, P. T.; Rawitsch, M. J.; RU7791; (1928) ; (from Gmelin) View in Reaxys With carbon in water, at 86-92°C equilibrium reached after ca. 15 hours; Daniltschenko, P. T.; Rawitsch, M. J.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 123 - 123; C. II; (1929); p. 708 View in Reaxys vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Daniltschenko, P. T.; Rawitsch, M. J.; RU7791; (1928) ; (from Gmelin) View in Reaxys With carbon in water, at common temp. equilibrium reached after one year; hydrolysis; Daniltschenko, P. T.; Rawitsch, M. J.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 123 - 123; C. II; (1929); p. 708 View in Reaxys vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Daniltschenko, P. T.; Rawitsch, M. J.; RU7791; (1928) ; (from Gmelin)

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View in Reaxys With carbon in neat (no solvent), byproducts: CO2, H2, CO; at 800°C; with activated coal the temp. is reduced; formation of water gas;; HI collected in a cooled receiver; Daniltschenko, P. T.; Rawitsch, M. J.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 123 - 123; C. II; (1929); p. 708 View in Reaxys vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Daniltschenko, P. T.; Rawitsch, M. J.; RU7791; (1928) ; (from Gmelin) View in Reaxys With carbon, byproducts: O2; at higher temp.; Daniltschenko, P. T.; Rawitsch, M. J.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 123 - 123; C. II; (1929); p. 708 View in Reaxys vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Daniltschenko, P. T.; Rawitsch, M. J.; RU7791; (1928) ; (from Gmelin) View in Reaxys With dimethyl sulfoxide in water, dimethyl sulfoxide, byproducts: Me2SO2; I2 added to DMSO-H2O; monitored by UVvis spectra, conductometric and pH-metric study, argentometric titration and gas chromy. Markaryan; Grigoryan; Sarkisyan; Asatryan; Adamyan; Russian Journal of General Chemistry; vol. 76; nb. 11; (2006); p. 1801 - 1803 ; (from Gmelin) View in Reaxys 10-20

in gas, byproducts: O2; presence of coal, reactn.temp.: 400 up to 500 °C; Daniltschenko, P.; Rawitsch, M.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 127 - 127; C. II; (1929); p. 708 ; (from Gmelin) View in Reaxys in ethanol, hydrolysis; Carter, R. M.; Industrial and Engineering Chemistry; vol. 18; (1926); p. 827 - 827 View in Reaxys Oestling, G. J.; Dansk Tidsskrift for Farmaci; vol. 1; (1926); p. 139 - 139; C. I; (1927); p. 138 View in Reaxys Scherk; Apoth. Ztg.; vol. 41; (1926); p. 583 - 583 ; (from Gmelin) View in Reaxys in water, hydrolysis; small amounts of HI formed;; not isolated; Lockspeiser, B.; Transactions of the Faraday Society; vol. 26; (1930); p. 592 - 592 ; (from Gmelin) View in Reaxys in water, hydrolysis; small amounts of HI formed;; not isolated; vol. I: MVol.1; 28, page 130 - 132 ; (from Gmelin) View in Reaxys in ethanol, hydrolysis; vol. I: MVol.1; 37, page 149 - 151 ; (from Gmelin) View in Reaxys

10-20

in neat (no solvent, gas phase), byproducts: O2; presence of coal, reactn.temp.: 400 up to 500 °C; vol. I: MVol.1; 50, page 173 - 175 ; (from Gmelin) View in Reaxys

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Rx-ID: 26083426 View in Reaxys 4/310 Yield 90 %

Conditions & References With platinum, equilibrium; at about 175°C; Hautefeuille, P.; Bulletin de la Societe Chimique de France; vol. 7; (1867); p. 205 - 205 View in Reaxys Hautefeuille, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 64; (1867); p. 609 - 609 ; (from Gmelin) View in Reaxys

90 %

equilibrium; pure dry hydrogen containing pure dry iodine vapour; in a Siemens tube; strength of electric current: 0.191amp./m2; 19.6°C; Warburg, E.; Zeitschrift fuer Physik; vol. 21; (1924); p. 378 - 378 ; (from Gmelin) View in Reaxys

90 %

With platinum, equilibrium; at about 175°C; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys

90 %

equilibrium; pure dry hydrogen containing pure dry iodine vapour; in a Siemens tube; strength of electric current: 0.191amp./m2; 19.6°C; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys

78 %

With platinum, equilibrium; at about 700°C; Hautefeuille, P.; Bulletin de la Societe Chimique de France; vol. 7; (1867); p. 205 - 205 View in Reaxys Hautefeuille, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 64; (1867); p. 609 - 609 ; (from Gmelin) View in Reaxys

78 %

With platinum, equilibrium; at about 700°C; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys

7.6 %

Kinetics, Irradiation (UV/VIS); in quartz vessel, wavelength above 2200Å, ambient temp.; Coehn, A.; Stuckardt, K.; Abh. Ges. Wiss. Goettingen, Math. - Phys. Kl.; (1916); p. 105 - 105 View in Reaxys Coehn, A.; Stuckardt, K.; Z. phys. Ch.; vol. 91; (1916); p. 725 - 725 View in Reaxys vol. I: MVol.2; 3, page 250 - 253 ; (from Gmelin) View in Reaxys in acetic acid, at 150-200°C and 420-490atm; vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Weston, P. E.; Roessler & Hasslacher Chemical Co.; AU1890874; (1930); C. I; (1933); p. 1494 ; (from Gmelin) View in Reaxys With platinum, catalyst: platinum sponge; Blundell; Annalen der Physik (Weinheim, Germany); vol. 2; (1824); p. 216 - 216 View in Reaxys Corenwinder, B.; Ann. Chim. Phys.; vol. 34; (1852); p. 79 - 79 View in Reaxys Corenwinder, B.; Journal fuer Praktische Chemie (Leipzig); vol. 55; (1852); p. 300 - 300 View in Reaxys

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Corenwinder, B.; Liebigs Annalen der Chemie; vol. 84; (1852); p. 255 - 255 View in Reaxys Hautefeuille, P.; Bulletin de la Societe Chimique de France; vol. 7; (1867); p. 205 - 205 View in Reaxys Hautefeuille, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 64; (1867); p. 609 - 609 ; (from Gmelin) View in Reaxys With platinum in neat (no solvent), High Pressure; reactor filled with H2 and I2 (in ratio 6:1) pressure 1.7 bar in presence of Pt sponge; reaction at 673 K for 4 h; trapped at 77 K; I2/HI mixt. distilled at 243 K; trapped at 77 K; solid reheated to ambient temp.; distilled again Goulay; Rebrion-Rowe; Carles; Le Garrec; Rowe; Journal of Chemical Physics; vol. 121; nb. 3; (2004); p. 1303 1308 ; (from Gmelin) View in Reaxys Irradiation (UV/VIS); at 270°C and waves lower than 3400 Å; or irradiation of shorter waves (1830 Å); vol. I: MVol.2; 3, page 250 - 253 View in Reaxys Sasaki, N.; Nakamura, K.; On the photochemical reaction of iodine with hydrogen in: Anniversary volume dedicated to Masumi Chikashige, Inst. Chem. Depart. Sci. Univ. Kyoto 1930 299. ; (from Gmelin) View in Reaxys Irradiation (UV/VIS); by pressure; Coehn, A.; Stuckardt, K.; Abh. Ges. Wiss. Goettingen, Math. - Phys. Kl.; (1916); p. 105 - 105 View in Reaxys Coehn, A.; Stuckardt, K.; Z. phys. Ch.; vol. 91; (1916); p. 725 - 725 View in Reaxys vol. I: MVol.2; 3, page 250 - 253 ; (from Gmelin) View in Reaxys 0%

Irradiation (UV/VIS); in uviol glass with wavelength above 2540Å, or in Jenaer glass; Coehn, A.; Stuckardt, K.; Abh. Ges. Wiss. Goettingen, Math. - Phys. Kl.; (1916); p. 105 - 105 View in Reaxys Coehn, A.; Stuckardt, K.; Z. phys. Ch.; vol. 91; (1916); p. 725 - 725 View in Reaxys vol. I: MVol.2; 3, page 250 - 253 ; (from Gmelin) View in Reaxys Irradiation (UV/VIS) Smits, A.; Aten, A. H. W.; Zeitschrift fuer Elektrochemie; vol. 16; (1910); p. 264 View in Reaxys vol. I: MVol.2; 3, page 250 - 253 ; (from Gmelin) View in Reaxys

absolute dry gases; Lewis, B.; Rideal, E. K.; Journal of the American Chemical Society; vol. 48; (1926); p. 2553 - 2553 ; (from Gmelin) View in Reaxys electric method; mechanism described; Warburg, E.; Zeitschrift fuer Physik; vol. 21; (1924); p. 372 - 380 ; (from Gmelin) View in Reaxys electric spark; Riche, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 46; (1858); p. 352 ; (from Gmelin) View in Reaxys

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equilibrium; pure dry hydrogen containing pure dry iodine vapour; in a Siemens tube; different strength of electric current; Warburg, E.; Zeitschrift fuer Physik; vol. 21; (1924); p. 378 - 378 ; (from Gmelin) View in Reaxys equilibrium; pure dry hydrogen, pure dry iodine vapour; in a Siemens tube; Warburg, E.; Zeitschrift fuer Physik; vol. 21; (1924); p. 372 - 380 ; (from Gmelin) View in Reaxys equilibrium; Bodenstein, M.; Z. phys. Ch.; vol. 29; (1899); p. 295 - 295 View in Reaxys Chatelier, Le H.; Ann. Mines; vol. 13; (1888); p. 261 - 261 View in Reaxys Lemoime, G.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 80; (1875); p. 792 792 View in Reaxys Lemoime, G.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 85; (1877); p. 34 - 34 View in Reaxys Lemoine, G.; Ann. Chim. Phys.; vol. 12; (1877); p. 145 - 145 View in Reaxys vol. I: MVol.2; 2, page 247 - 250 ; (from Gmelin) View in Reaxys mechanism described; Trautz, M.; Z. Anorg. Chem.; vol. 104; (1918); p. 169 - 169 ; (from Gmelin) View in Reaxys other Radiation; α-radiation, at 100°C, in darkness; Vandamme, J.; Bulletin des Societes Chimiques Belges; vol. 41; (1932); p. 605 - 605 ; (from Gmelin) View in Reaxys other Radiation; α-radiation; Lind, S. C.; Journal of Physical Chemistry; vol. 16; (1912); p. 564 - 580 View in Reaxys Lind, S. C.; Radium (Paris); vol. 10; (1913); p. 174 - 174 View in Reaxys Lind, S. C.; Radium (Paris); vol. 9; (1912); p. 426 - 426 View in Reaxys Lind, S. C.; Journal of Physical Chemistry; vol. 16; (1912); p. 612 - 612 View in Reaxys Vandamme, J.; Bulletin des Societes Chimiques Belges; vol. 41; (1932); p. 604 - 604 ; (from Gmelin) View in Reaxys other Radiation; at 100°C, α-radiation; Lind, S. C.; Trans. Am. elektrochem. Soc.; vol. 21; (1912); p. 177 - 177 View in Reaxys Vandamme, J.; Bulletin des Societes Chimiques Belges; vol. 41; (1932); p. 603 - 603 ; (from Gmelin) View in Reaxys silent discharge; Smits, A.; Aten, A. H. W.; Zeitschrift fuer Elektrochemie; vol. 16; (1910); p. 264 ; (from Gmelin) View in Reaxys Courtois, B.; Clement; Desormes; Annales de Chimie (Cachan, France); vol. 88; (1813); p. 304 - 304 View in Reaxys Courtois, B.; Clement; Desormes; Annalen der Physik (Weinheim, Germany); vol. 48; (1814); p. 367 - 367 View in Reaxys

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Gay-Lussac, J. L.; Annales de Chimie (Cachan, France); vol. 91; (1814); p. 22 - 22 View in Reaxys Gay-Lussac, J. L.; Annales de Chimie (Cachan, France); vol. 91; (1814); p. 9 - 9 View in Reaxys Gay-Lussac, J. L.; Schw. J.; vol. 13; (1815); p. 384 - 384 View in Reaxys Berzelius, J. J.; Lehrbuch der Chemie, deutsche Uebersetzung, 5. Aufl., Leipzig 1856, Bd. 1, S. 257 View in Reaxys Dumas, J.-B.; Traite de chimie appliquee aux arts, Paris 1828, S. 99 View in Reaxys Vogel v. Falkenstein, K.; Z. phys. Ch.; vol. 72; (1910); p. 115 - 115 View in Reaxys vol. I: MVol.2; 2, page 247 - 250 ; (from Gmelin) View in Reaxys in gas, Kinetics, Electric Arc; plasma reactor, temperature range from 300 to 800 K; absorption spectroscopy Miethke, Frank; Journal of Physical Chemistry A; vol. 103; nb. 13; (1999); p. 2024 - 2030 ; (from Gmelin) View in Reaxys in gaseous matrix, Kinetics, Electric Arc; (He); plasma reactor, temperature range from 300 to 800 K; absorption spectroscopy Miethke, Frank; Journal of Physical Chemistry A; vol. 103; nb. 13; (1999); p. 2024 - 2030 ; (from Gmelin) View in Reaxys in tetrachloromethane, at 150-200°C and 420-490atm; vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Weston, P. E.; Roessler & Hasslacher Chemical Co.; AU1890874; (1930); C. I; (1933); p. 1494 ; (from Gmelin) View in Reaxys in water, at 150-200°C and 420-490atm; vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Weston, P. E.; Roessler & Hasslacher Chemical Co.; AU1890874; (1930); C. I; (1933); p. 1494 ; (from Gmelin) View in Reaxys in water, reduction of an aq. soln. of I2 with H2 in presence of platinum black; Cooke, St.; Chem. News J. Ind. Sci.; vol. 58; (1888); p. 105 - 105 View in Reaxys Gall, H.; Manchot, W.; Ber.; vol. 58; (1925); p. 485 - 485 ; (from Gmelin) View in Reaxys in toluene, at 150-200°C and 420-490atm; vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Weston, P. E.; Roessler & Hasslacher Chemical Co.; AU1890874; (1930); C. I; (1933); p. 1494 ; (from Gmelin) View in Reaxys in neat (no solvent), catalytic reaction on platinized asbestos Nakamura, K.; Masaki, N.; Okamoto, M.; Sato, S.; Shimokoshi, K.; Journal of Chemical Physics; vol. 86; nb. 9; (1987); p. 4949 - 4951 ; (from Gmelin) View in Reaxys 0%

in neat (no solvent), combustion of H2 in I2-atmosphere; Bussy, A.; Journal de Pharmacie et de Chimie; vol. 17; (1850); p. 20 - 20

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View in Reaxys Bussy, A.; Journal fuer Praktische Chemie (Leipzig); vol. 50; (1850); p. 62 - 62 ; (from Gmelin) View in Reaxys in neat (no solvent), hydrogen purified from O by Ni-catalyst; pure iodine; H-stream saturated with I at 100°C runs over electrically heated, 600°C Pt-spiral on quartz;; condensation of excess iodine by ice-sodium chloride freezing mixture; condensation of HI with liquid air (H evaporates), then fractionation; traces of I removed with Hg; dried by long standing with P2O5; purified by melting and fractionation; Giauque, W. F.; Wiebe, R.; Journal of the American Chemical Society; vol. 51; (1929); p. 1441 - 1449 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys in further solvent(s), at 150-200°C and 420-490atm; SnCl4 as solvent; vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Weston, P. E.; Roessler & Hasslacher Chemical Co.; AU1890874; (1930); C. I; (1933); p. 1494 ; (from Gmelin) View in Reaxys in not given, synthesized from H2 and I2 in presence of platinized asbestos; repeated trap-to-trap distns. Umemoto, Hironobu; Uchida, Teruo; Tsunashima, Shigeru; Sato, Shin; Bulletin of the Chemical Society of Japan; vol. 60; (1987); p. 1641 - 1644 ; (from Gmelin) View in Reaxys 0%

Kinetics, Irradiation (UV/VIS); glass vessel, sunlight; Berthelot, M.; Ann. Chim. Phys.; vol. 15; (1898); p. 345 - 345 View in Reaxys Lemoine, G.; Ann. Chim. Phys.; vol. 12; (1877); p. 232 - 232 View in Reaxys Lemoine, G.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 85; (1877); p. 144 144 View in Reaxys vol. I: MVol.2; 3, page 250 - 253 ; (from Gmelin) View in Reaxys Kinetics, equilibrium; Bodenstein, M.; Ber.; vol. 26; (1893); p. 2610 - 2610 View in Reaxys Bodenstein, M.; Z. phys. Ch.; vol. 13; (1894); p. 110 - 110 View in Reaxys Bodenstein, M.; Z. phys. Ch.; vol. 13; (1894); p. 56 - 56 View in Reaxys Bodenstein, M.; Z. phys. Ch.; vol. 13; (1894); p. 88 - 88 View in Reaxys Bodenstein, M.; Z. phys. Ch.; vol. 13; (1894); p. 93 - 93 View in Reaxys Bodenstein, M.; Z. phys. Ch.; vol. 29; (1899); p. 295 - 295 View in Reaxys Nernst, W.; Zeitschrift fuer Elektrochemie; vol. 15; (1909); p. 691 - 691 View in Reaxys vol. I: MVol.2; 2, page 247 - 250 View in Reaxys Bodenstein, M.; Gasreaktionen in der chemischen Kinetik, Habilitationsschrift Heidelberg 1899, S. 25 ; (from Gmelin) View in Reaxys

>99

Kinetics, formation in flowing gases, hydrogen concentration sufficiently high forquantitative reaction of I2; Bodenstein, M.; Wolgast, K.; Z. phys. Ch.; vol. 61; (1908); p. 422 - 422 ; (from Gmelin) View in Reaxys

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Kinetics, mechanism described; Eckstein, H.; Polanyi, M.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 15; (1932); p. 334 - 334 View in Reaxys Eyring, H.; Journal of the American Chemical Society; vol. 53; (1931); p. 2546 - 2546 ; (from Gmelin) View in Reaxys Kinetics Bodenstein, M.; Z. phys. Ch.; vol. 29; (1899); p. 312 - 312 View in Reaxys Eyring, H.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 7; (1930); p. 244 - 244 View in Reaxys Kassel, L. S.; Physical Review; vol. 35; (1930); p. 261 - 261 View in Reaxys Lewis, W. C. McC.; Journal of the Chemical Society; vol. 113; (1918); p. 471 - 471 View in Reaxys Lewis, W. C. McC.; Journal of the Chemical Society; vol. 113; (1918); p. 475 - 475 View in Reaxys Bodenstein, M.; Gasreaktionen in der chemischen Kinetik, Habilitationsschrift Heidelberg 1899, S. 31 ; (from Gmelin) View in Reaxys vol. I: MVol.1; 52, page 177 - 179 ; (from Gmelin) View in Reaxys 0%

in neat (no solvent), combustion of H2 in I2-atmosphere; vol. I: MVol.1; 52, page 177 - 179 ; (from Gmelin) View in Reaxys in water, reduction of an aq. soln. of I2 with H2 in presence of platinum black; vol. I: MVol.1; 52, page 177 - 179 ; (from Gmelin) View in Reaxys equilibrium; pure dry hydrogen containing pure dry iodine vapour; in a Siemens tube; different strength of electric current; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys With platinum, catalyst: platinum sponge; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys

absolute dry gases; vol. I: MVol.2; 1, page 245 - 247 ; (from Gmelin) View in Reaxys electric method; mechanism described; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys electric spark; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys equilibrium; pure dry hydrogen, pure dry iodine vapour; in a Siemens tube; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys

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equilibrium; Bodenstein, M.; Jost, W.; Journal of the American Chemical Society; vol. 49; (1927); p. 1416 - 1416 ; (from Gmelin) View in Reaxys mechanism described; vol. I: MVol.2; 1, page 245 - 247 ; (from Gmelin) View in Reaxys other Radiation; α-radiation, at 100°C, in darkness; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys other Radiation; α-radiation; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys other Radiation; at 100°C, α-radiation; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys silent discharge; vol. I: MVol.2; 4, page 253 - 256 ; (from Gmelin) View in Reaxys Kinetics, equilibrium; vol. I: MVol.2; 1, page 245 - 247 ; (from Gmelin) View in Reaxys >99

Kinetics, formation in flowing gases, hydrogen concentration sufficiently high forquantitative reaction of I2; vol. I: MVol.2; 1, page 245 - 247 ; (from Gmelin) View in Reaxys Kinetics, mechanism described; vol. I: MVol.2; 1, page 245 - 247 ; (from Gmelin) View in Reaxys Kinetics vol. I: MVol.2; 1, page 245 - 247 ; (from Gmelin) View in Reaxys Bodenstein, M.; Z. phys. Ch.; vol. 22; (1897); p. 1 - 1 View in Reaxys Vogel v. Falkenstein, K.; Z. phys. Ch.; vol. 68; (1910); p. 280 - 280 ; (from Gmelin) View in Reaxys

OH O

P H

O I

H O

P OH OH

Rx-ID: 26481719 View in Reaxys 5/310 Yield

Conditions & References With n-propanol or AgCl in not given, Kinetics, oxidation of H3PO2 with HIO3; further react. of HI inhibited by n-propanol or AgCl; Hayward, P.; Yost, D. M.; Journal of the American Chemical Society; vol. 71; (1949); p. 915 - 919 View in Reaxys Mitchell, A. D.; Journal of the Chemical Society; vol. 117; (1920); p. 1322 - 1335 View in Reaxys

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vol. P: MVol.C; 53, page 112 - 113 ; (from Gmelin) View in Reaxys With propan-1-ol in not given, oxidation of H3PO2 with HIO3; further react. of HI inhibited by n-propanol; Hayward, P.; Yost, D. M.; Journal of the American Chemical Society; vol. 71; (1949); p. 915 - 919 View in Reaxys vol. P: MVol.C; 53, page 112 - 113 ; (from Gmelin) View in Reaxys

O–

3 –O

Ti3+

S OO

O–

O– Ti4+

Rx-ID: 26352636 View in Reaxys 6/310 Yield

Conditions & References With sulfuric acid in water, byproducts: H2O; mechanism discussed; Hendrixson, W. S.; Journal of the American Chemical Society; vol. 45; (1923); p. 2013 - 2017 View in Reaxys vol. I: MVol.2; 118, page 499 - 501 ; (from Gmelin) View in Reaxys H N

NH +4

NH 2

I–

NH 2

Rx-ID: 26341723 View in Reaxys 7/310 Yield

Conditions & References

>99, >99, >99, >99

With water in water, Kinetics vol. C: MVol.D1; 48.4.2.4, page 464 - 465 ; (from Gmelin) View in Reaxys

>99, >99, >99, >99

With H2O in water, Kinetics Bartlett; Journal of the American Chemical Society; vol. 54; (1932); p. 2853 ; (from Gmelin) View in Reaxys

H H

P+ HH

I–

Rx-ID: 26393017 View in Reaxys 8/310 Yield

Conditions & References With potassium hydroxide, water in diethyl ether, decomposition with aq. ether; Messinger, J.; Engels, C.; Ber.; vol. 21; (1888); p. 326 - 336 View in Reaxys Schut, W.; Jansen, J. D.; Recueil des Travaux Chimiques des Pays-Bas; vol. 51; (1932); p. 321 - 341 View in Reaxys Melville, H. W.; Bolland, J. L.; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 160; (1937); p. 384 - 406 ; (from Gmelin) View in Reaxys With water in water, decomposition with H2O or aq. liquids; Billardiere, H. de la; An.. Chim. Phys. (2); vol. 6; (1817); p. 304 - 307 View in Reaxys Billardiere, H. de la; Annalen der Physik (Weinheim, Germany); vol. 68; (1821); p. 253 - 259 View in Reaxys Ponndorf, A. L.; Jenaische Z. Naturwiss. (2. Suppl.-H.); vol. 10; (1876); p. 45 - 62 View in Reaxys Rose, H.; Ann. Phys. Chem. (2); vol. 24; (1832); p. 109 - 165 View in Reaxys Work, J. B.; Fernelius, W. C., Inorganic Syntheses, Bd. 2, New York - London 1946, S. 141/4 ; (from Gmelin)

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View in Reaxys With potassium hydroxide, water in water, decomposition with aq. KOH; Messinger, J.; Engels, C.; Ber.; vol. 21; (1888); p. 326 - 336 View in Reaxys Schut, W.; Jansen, J. D.; Recueil des Travaux Chimiques des Pays-Bas; vol. 51; (1932); p. 321 - 341 View in Reaxys Melville, H. W.; Bolland, J. L.; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 160; (1937); p. 384 - 406 ; (from Gmelin) View in Reaxys With H2O in water, decomposition with H2O or aq. liquids; vol. P: MVol.C; 229, page 525 - 527 ; (from Gmelin) View in Reaxys With KOH, H2O in water, decomposition with aq. KOH; vol. P: MVol.C; 229, page 525 - 527 ; (from Gmelin) View in Reaxys With KOH, H2O in diethyl ether, decomposition with aq. ether; vol. P: MVol.C; 229, page 525 - 527 ; (from Gmelin) View in Reaxys With potassium hydroxide, water in water, decomposition with aq. KOH; Rammelsberg, C; Ber.; vol. 6; (1873); p. 88 - 88 ; (from Gmelin) View in Reaxys With potassium hydroxide, water in diethyl ether, decomposition with aq. ether; Rammelsberg, C; Ber.; vol. 6; (1873); p. 88 - 88 ; (from Gmelin) View in Reaxys O I

Rx-ID: 26483368 View in Reaxys 9/310 Yield >99

Conditions & References With P in water, byproducts: H3PO3; quantitative formation of HI also in very dild. HIO3 soln.; excess HIO3 results in formation of I2; Ditte, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 70; (1870); p. 623 - 623 ; (from Gmelin) View in Reaxys With P in water, byproducts: H3PO3; from HIO3 soln. with red P; Ditte, A.; Ann. Chim. Phys.; vol. 21; (1870); p. 23 - 23 View in Reaxys Ditte, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 70; (1870); p. 623 - 623 View in Reaxys Ditte, A.; Liebigs Annalen der Chemie; vol. 156; (1870); p. 339 - 339 View in Reaxys Ditte, A.; Z. Ch. (2); vol. 6; (1870); p. 305 - 305 View in Reaxys Pollacci, E.; Chem. News J. Ind. Sci.; vol. 28; (1873); p. 264 - 264 View in Reaxys Pollacci, E.; Gazzetta Chimica Italiana; vol. 3; (1873); p. 476 - 476 View in Reaxys Sonstadt, E.; Chem. News J. Ind. Sci.; vol. 28; (1873); p. 288 - 288 ; (from Gmelin) View in Reaxys

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With P in water, byproducts: H3PO3; from HIO3 soln. with red P; Ditte, A.; Bulletin de la Societe Chimique de France; vol. 13; (1870); p. 320 - 320 View in Reaxys vol. I: MVol.2; 114, page 492 - 494 ; (from Gmelin) View in Reaxys >99

With P in water, byproducts: H3PO3; quantitative formation of HI also in very dild. HIO3 soln.; excess HIO3 results in formation of I2; Ditte, A.; Ann. Chim. Phys.; vol. 21; (1870); p. 22 - 22 View in Reaxys Ditte, A.; Bulletin de la Societe Chimique de France; vol. 13; (1870); p. 320 - 320 View in Reaxys Ditte, A.; Liebigs Annalen der Chemie; vol. 156; (1870); p. 338 - 338 View in Reaxys Ditte, A.; Z. Ch. (2); vol. 6; (1870); p. 304 - 304 View in Reaxys vol. I: MVol.2; 114, page 492 - 494 ; (from Gmelin) View in Reaxys

Rx-ID: 26083228 View in Reaxys 10/310 Yield

Conditions & References With water in water, with H laden Pd is reducing iodine water in dild. soln. to HI; Graham, Th.; Journal of the Chemical Society; vol. 20; (1867); p. 275 - 275 View in Reaxys Graham, T.; Justus Liebigs Annalen der Chemie; vol. 5; (1867); p. 57 - 57 ; (from Gmelin) View in Reaxys With H2O in water, with H laden Pd is reducing iodine water in dild. soln. to HI; Graham, Th.; Annalen der Physik (Weinheim, Germany); vol. 129; (1866); p. 598 - 598 View in Reaxys Graham, Th.; Philosophical Transactions of the Royal Society of London; vol. 156; (1866); p. 428 - 428 View in Reaxys Graham, T.; Ann. Chim. Phys.; vol. 12; (1867); p. 506 - 506 View in Reaxys Graham, T.; Philosophical Magazine (1798-1977); vol. 32; (1866); p. 518 - 518 View in Reaxys vol. Pd: MVol.2; 55, page 252 - 255 ; (from Gmelin) View in Reaxys

FeI2

Rx-ID: 26451807 View in Reaxys 11/310 Yield

Conditions & References With air in water, fast oxydation of aq. FeI2 solutions on air by changing color to yellow-red, brown or red-brown; at the same time evolution of I and HI, turbidity of solution and sedimentation of a yellow-brown precipitate; Kop; Pharmaceutical Journal; vol. 5; (1845); p. 133 - 133 View in Reaxys Dupasquier, A.; J. Pharm.; vol. 27; (1840); p. 128 - 128 View in Reaxys Menil, du; Archiv der Pharmazie (Weinheim, Germany); vol. 57; (1836); p. 56 - 56 View in Reaxys Schoor, O. van; Handel. 15. Vlaamsch natuur-geneesk. Congr. Ostende 1911, S. 77 ; (from Gmelin) View in Reaxys With air in water, fast oxydation of aq. FeI2 solutions on air by changing color to yellow-red, brown or red-brown; at the same time evolution of I and HI, turbidity of solution and sedimentation of a yellow-brown precipitate;

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Jackson, C. L.; Derby, I. H.; American Chemical Journal; vol. 24; (1900); p. 23 - 23 View in Reaxys vol. Fe: MVol.B2; 13, page 338 - 341 ; (from Gmelin) View in Reaxys

I2Mg

MgO

Rx-ID: 26540806 View in Reaxys 12/310 Yield

Conditions & References

100 %, 100 in water, byproducts: water; 400 - 500 °C; part of a Mg-S-I water splitting cycle % Kumagai, Toshiya; Mizuta, Susumu; Chemistry Letters; (1983); p. 679 - 682 ; (from Gmelin) View in Reaxys

Rx-ID: 26083410 View in Reaxys 13/310 Yield

Conditions & References in 1,2,3,4-tetrahydro-naphthalene, 207°C; Hoffman, C. J. , Inorg. Synth., 1963, 7, 180; HI vapor was passed through a tetralin trap before condensing in a N2 trap, low-temp. distillation in vac. Fushitani, Mizuho; Shida, Tadamasa; Momose, Takamasa; Raesaenen, Markku; Journal of Physical Chemistry A; vol. 104; nb. 16; (2000); p. 3635 - 3641 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction of I2 with boiling org. compd.; according to C. J. Hoffman, Inorg. Synth. 7 (1963) 180; distillation Hewett, Kevin B.; Setser; Chemical Physics Letters; vol. 297; nb. 3-4; (1998); p. 335 - 342 ; (from Gmelin) View in Reaxys in further solvent(s), iodine plates dropped into boiling tetrahydronaphthalene;; pure dry HI; vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Boedler, J.; DE405376; (1922) ; (from Gmelin) View in Reaxys in 1,2,3,4-tetrahydro-naphthalene, prepn. according to Handbuch der Praeparativen Anorganischen Chemie, Ed.by G. Brauer (Ferdinand Enke, Berlin; Mir, Moscow, 1985) from soln. of I2 in tetralin and boiling tetralin; dried over phosphorus pentoxide Drozdova; Malinina; Polyakova; Razgonyaeva; Zhizhin; Kuznetsov; Russian Journal of Inorganic Chemistry; vol. 52; nb. 1; (2007); p. 52 - 57 ; (from Gmelin) View in Reaxys in not given, prepn. from iodine and tetralin according to Handbuch der praeparativen anorganischen Chemie, Ed. by G. Brauer (Ferdinand Enke, Stuttgart, 1975-1981; Mir, Moscow, 1985) Drozdova; Zhizhin; Malinina; Polyakova; Kuznetsov; Russian Journal of Inorganic Chemistry; vol. 52; nb. 7; (2007); p. 996 - 1001 ; (from Gmelin) View in Reaxys

I (v5)I

Nb I

Rx-ID: 26386109 View in Reaxys 14/310 Yield

Conditions & References With water in neat (no solvent), in moist air; Alexander, K. M.; Fairbrother, F.; Journal of the Chemical Society; (1949); p. 2472 - 2476 ; (from Gmelin) View in Reaxys

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With H2O in neat (no solvent), in moist air; Littke, W.; Brauer, G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 325; (1963); p. 122 - 129 View in Reaxys vol. Nb: MVol.B1; 117, page 252 - 254 ; (from Gmelin) View in Reaxys O O O

Rx-ID: 26488327 View in Reaxys 15/310 Yield

Conditions & References With hydrogen sulfide in not given, byproducts: S, H2O; violent reaction at room temp.; Ditte; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 70; (1870); p. 621 View in Reaxys Ditte, A.; Ann. Chim. Phys.; vol. 21; (1870); p. 12 - 12 View in Reaxys Ditte, A.; Bulletin de la Societe Chimique de France; vol. 13; (1870); p. 318 - 318 View in Reaxys Ditte, A.; Liebigs Annalen der Chemie; vol. 156; (1870); p. 336 - 336 View in Reaxys Nicloux, M.; Ann. Chim. Phys.; vol. 14; (1898); p. 565 - 565 View in Reaxys Nicloux, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 126; (1898); p. 746 746 View in Reaxys vol. I: MVol.2; 87, page 438 - 439 ; (from Gmelin) View in Reaxys With H2S in not given, byproducts: S, H2O; violent reaction at room temp.; Ditte, A.; Z. Ch. (2); vol. 6; (1870); p. 304 - 304 ; (from Gmelin) View in Reaxys

Ni + (v1)

Rx-ID: 26638593 View in Reaxys 16/310 Yield

Conditions & References in gas, byproducts: Ni(C5H5)(C6H4)(1+); The react. is performed on an ion cyclotron resonance (ICR) mass spectrometer. The nickel ion and the aromatic compd. are admitted to the ICR cell in approx. 1:1 ratio, to a total pressure of 6E-6 Torr.; MS Stepnowski, Richard; Allison, John; Journal of the American Chemical Society; vol. 111; nb. 2; (1989); p. 449 - 457 ; (from Gmelin) View in Reaxys O–

2 Na + O O

O S

O O–

–O

S HO

Na +

Rx-ID: 26366581 View in Reaxys 17/310 Yield

Conditions & References With water in hydrogenchloride, Kinetics, reaction of a hydrochloric soln. in the heat; Mueller, M. J. A.; Bulletin de la Societe Chimique de France; vol. 5; (1909); p. 1119 - 1119 View in Reaxys Mueller, M. J. A.; Bulletin de la Societe Chimique de France; vol. 9; (1911); p. 183 - 183 ; (from Gmelin) View in Reaxys

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With water in sulfuric acid, Kinetics, reaction of a sulfuric soln. in the heat; Mueller, M. J. A.; Bulletin de la Societe Chimique de France; vol. 5; (1909); p. 1119 - 1119 View in Reaxys Mueller, M. J. A.; Bulletin de la Societe Chimique de France; vol. 9; (1911); p. 183 - 183 ; (from Gmelin) View in Reaxys With H2O in hydrogenchloride, Kinetics, reaction of a hydrochloric soln. in the heat; vol. Na: MVol.; 218, page 625 - 626 ; (from Gmelin) View in Reaxys With H2O in sulfuric acid, Kinetics, aq. H2SO4; reaction of a sulfuric soln. in the heat; vol. Na: MVol.; 218, page 625 - 626 ; (from Gmelin) View in Reaxys O–

OH HO

I(1-)

S OO

O S

H O

Rx-ID: 26414717 View in Reaxys 18/310 Yield

Conditions & References in gaseous matrix, Kinetics, flow tube, 0.8 Torr helium, temp. 368 +/- 5 K Viggiano; Henchman; Dale; Deakyne; Paulson; Journal of the American Chemical Society; vol. 114; nb. 11; (1992); p. 4299 - 4306 ; (from Gmelin) View in Reaxys -1 OH

I(1-)

S F

(v1)

O O

S F

O O

Rx-ID: 26414727 View in Reaxys 19/310 Yield

O O

Rx-ID: 26484561 View in Reaxys 20/310 Yield

Conditions & References With anhydrous sulfurous acid in water, byproducts: H2SO4; excess of SO3(2-); Selmons, F.; Ber.; vol. 21; (1888); p. 230 - 230 View in Reaxys Selmons, F.; Dissert. Berlin 1887 ; (from Gmelin) View in Reaxys With H2SO3 in water, byproducts: H2SO4; excess of SO3(2-); vol. I: MVol.2; 131, page 530 - 533 ; (from Gmelin) View in Reaxys

OH B

B HO

Rx-ID: 26486188 View in Reaxys 21/310 Yield

Conditions & References With water in water

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Besson; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 112; (1891); p. 1002 View in Reaxys Sabatier; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 112; (1891); p. 864 ; (from Gmelin) View in Reaxys With H2O in water Moissan; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 112; (1891); p. 718 View in Reaxys vol. B: MVol.; 11, page 128 - 129 ; (from Gmelin) View in Reaxys –O

O I

OH K+ HO

S OO

Rx-ID: 26532356 View in Reaxys 22/310 Yield

Conditions & References With sulfur dioxide in water, with excess SO2 Gay-Lussac, L. J.; Annales de Chimie (Cachan, France); vol. 91; (1814); p. 5 - 160 View in Reaxys Davy, H.; Philosophical Transactions of the Royal Society of London; (1814); p. 211 - 266 View in Reaxys Gay-Lussac, L. J.; Annalen der Physik (Weinheim, Germany); vol. 49; (1915); p. 211 - 266 View in Reaxys vol. S: MVol.B2; 1.6.2.5, page 520 - 522 ; (from Gmelin) View in Reaxys H

NH +4

I–

H N

Rx-ID: 26091570 View in Reaxys 23/310 Yield >99, >99

Conditions & References in gas, thermical dissoziation in gas phase; Purcell, R. H.; Lange, W. de; Journal of the Chemical Society; (1929); p. 279 - 279 ; (from Gmelin) View in Reaxys at 440 and 860°C Sainte-Claire Deville, H.; Troost, L.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 56; (1863); p. 895 ; (from Gmelin) View in Reaxys total dissociation even below 400 °C Purcell, R. H.; Lange, de W.; Journal of the Chemical Society; (1929); p. 275 View in Reaxys vol. NH4: MVol.1; 2.10.1, page 222 - 230 ; (from Gmelin) View in Reaxys <400°C Purcell, R. H.; Lange, de W.; Journal of the Chemical Society; (1929); p. 275 View in Reaxys vol. NH4: MVol.1; 2.10.1, page 222 - 230 ; (from Gmelin) View in Reaxys at 440 and 860°C vol. NH4: MVol.1; 2.10.1, page 222 - 230 ; (from Gmelin) View in Reaxys

>99, >99

in neat (no solvent, gas phase), thermical dissoziation in gas phase;

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vol. I: MVol.2; 56, page 370 - 371 ; (from Gmelin) View in Reaxys

CuI

Rx-ID: 26101605 View in Reaxys 24/310 Yield

Conditions & References With water in water, trituration with Sb or Bi, boiling with H2O; Berthemot; J. Pharm.; vol. 14; (1828); p. 610 - 619 View in Reaxys Berthemot; Trommsdorff; vol. 18; nb. II; (1829); p. 113 - 126 View in Reaxys vol. Cu: MVol.B1; 183, page 404 - 406 ; (from Gmelin) View in Reaxys

CdI 2

Rx-ID: 26149466 View in Reaxys 25/310 Yield

Conditions & References

With hydrogen in neat (no solvent), passing H2 over CdI2 at 700°C during 2h; Jellinek, K.; Uloth, R.; Z. Anorg. Chem.; vol. 151; (1926); p. 160 - 160 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. I: MVol.2; 67, page 394 - 396 ; (from Gmelin) View in Reaxys

I2Pb

Rx-ID: 26172338 View in Reaxys 26/310 Yield

Conditions & References With hydrogen in neat (no solvent), passing H2 over at 500°C; Carli, F. de; Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti; vol. 33; nb. II; (1924); p. 96 - 96 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. I: MVol.2; 67, page 394 - 396 ; (from Gmelin) View in Reaxys

Hg 3I2Se2

Rx-ID: 26372449 View in Reaxys 27/310 Yield

Conditions & References With manganese(IV) oxide in sulfuric acid, boiling aq. H2SO4 Fonzes-Diacon, H.; These Paris 1901, pp.1-117, 97 ; (from Gmelin) View in Reaxys With MnO2 in sulfuric acid, aq. H2SO4; boiling aq. H2SO4 vol. Hg: MVol.B3; 2.6.5, page 1107 - 1109 ; (from Gmelin) View in Reaxys

H O H

Na + O – OS O

–O

S HO

Na +

Rx-ID: 26446874 View in Reaxys 28/310 Yield

Conditions & References With water in not given, oxidation in NaHCO3 soln. with iodine;

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Raschig; Schwefel- und Stickstoffstudien, Leipzig-Berlin 1924, S. 154 ; (from Gmelin) View in Reaxys With water in acetic acid, oxidation of a soln. in aq. acetic acid with iodine; Raschig; Schwefel- und Stickstoffstudien, Leipzig-Berlin 1924, S. 154 ; (from Gmelin) View in Reaxys With I, H2O in acetic acid, aq. acetic acid; oxidation of a soln. in aq. acetic acid with iodine; vol. Na: MVol.; 222, page 631 - 633 ; (from Gmelin) View in Reaxys With I, H2O in not given, oxidation in NaHCO3 soln. with iodine; vol. Na: MVol.; 222, page 631 - 633 ; (from Gmelin) View in Reaxys CoI 2

.alpha.

Rx-ID: 26455079 View in Reaxys 29/310 Yield

Conditions & References With hydrogen in neat (no solvent), equilibrium investigated; Jellinek, K.; Uloth, R.; Z. Anorg. Chem.; vol. 151; (1926); p. 160 - 160 View in Reaxys Jellinek, K.; Uloth, R.; Z. Anorg. Chem.; vol. 151; (1926); p. 165 - 165 ; (from Gmelin) View in Reaxys With H2 in neat (no solvent), equilibrium investigated; vol. Co: MVol.A2; 35, page 312 - 313 ; (from Gmelin) View in Reaxys

OH HO

S OO

Rx-ID: 26483372 View in Reaxys 30/310 Yield

Conditions & References With sulfur dioxide, water in water, excess SO2 Eggert, J.; Helvetica Chimica Acta; vol. 32; (1949); p. 692 - 702 View in Reaxys Morgan, K. J.; Quarterly Reviews, Chemical Society; vol. 8; (1954); p. 123 - 146 View in Reaxys vol. S: MVol.B2; 1.6.2.5, page 520 - 522 ; (from Gmelin) View in Reaxys

O P

P OH OH

Rx-ID: 26486156 View in Reaxys 31/310 Yield

Conditions & References With water in neat (no solvent), reaction with H2O with formation of HI, H3PO3 and orange red flakes; Corenwinder, B.; Ann. Chim. Phys.; vol. 30; (1850); p. 242 - 251 View in Reaxys Corenwinder, B.; Liebigs Annalen der Chemie; vol. 78; (1851); p. 76 - 84 ; (from Gmelin) View in Reaxys With H2O in neat (no solvent), reaction with H2O with formation of HI, H3PO3 and orange red flakes; vol. P: MVol.C; 228, page 522 - 524 ; (from Gmelin)

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View in Reaxys I I

Sn I I

Rx-ID: 26488837 View in Reaxys 32/310 Yield

Conditions & References With hydrogen in neat (no solvent), passing H2 over at 600°C; Carli, F. de; Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti; vol. 33; nb. II; (1924); p. 96 - 96 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. I: MVol.2; 67, page 394 - 396 ; (from Gmelin) View in Reaxys

I2Mo

Rx-ID: 26501456 View in Reaxys 33/310 Yield

Conditions & References With H2O in water, boiling of an aq. soln. of MoI2; Guichard, M.; Ann. Chim. Phys.; vol. 23; (1901); p. 566 - 566 View in Reaxys Guichard, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 123; (1896); p. 821 - 821 View in Reaxys vol. Mo: MVol.; 64, page 179 - 181 ; (from Gmelin) View in Reaxys

Cu 2I2

Rx-ID: 26506287 View in Reaxys 34/310 Yield

Conditions & References With hydrogen in neat (no solvent), passing H2 over at 300°C; Carli, F. de; Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti; vol. 33; nb. II; (1924); p. 96 - 96 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. I: MVol.2; 67, page 394 - 396 ; (from Gmelin) View in Reaxys

Rx-ID: 26542102 View in Reaxys 35/310 Yield

Conditions & References With hydrogen in neat (no solvent) Bodenstein, M.; Sitzungsber. Preuss. Akad. Wiss., Phys. - Math. Kl.; (1926); p. 108 - 108 View in Reaxys Mueller, W.; Z. phys. Ch.; vol. 123; (1926); p. 22 - 22 ; (from Gmelin) View in Reaxys With H2 in neat (no solvent) vol. I: MVol.2; 176, page 634 - 636 ; (from Gmelin) View in Reaxys

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I Bi

Rx-ID: 26588567 View in Reaxys 36/310 Yield

Conditions & References With air in neat (no solvent), loss of HI in dry air; Arppe; Annalen der Physik (Weinheim, Germany); vol. 64; (1845); p. 250 - 250 View in Reaxys vol. Bi: MVol.; 60, page 158 - 159 ; (from Gmelin) View in Reaxys O

H O

H+

O–

Rx-ID: 26082976 View in Reaxys 37/310 Yield

Conditions & References in water, heating an aq. I2 soln.; Schoenbein, Ch. F.; Journal fuer Praktische Chemie (Leipzig); vol. 84; (1861); p. 402 - 402 ; (from Gmelin) View in Reaxys in water, Irradiation (UV/VIS); influence of sun light, formation of HI and HIO3 (and changing colour of soln. to colorless); Gay-Lussac, L. J.; Annales de Chimie (Cachan, France); vol. 91; (1814); p. 155 - 155 View in Reaxys Gay-Lussac, L. J.; Schw. J.; vol. 13; (1815); p. 384 - 384 View in Reaxys Inglis, J.; Journal fuer Praktische Chemie (Leipzig); vol. 7; (1836); p. 394 - 394 View in Reaxys Inglis, J.; Philosophical Magazine (1798-1977); vol. 7; (1835); p. 441 - 441 View in Reaxys Schoenbein, Ch. F.; Journal fuer Praktische Chemie (Leipzig); vol. 84; (1861); p. 402 - 402 View in Reaxys Berzelius, J. J.; Lehrbuch der Chemie, deutsche Uebersetzung, 5. Aufl., Leipzig 1856, Bd. 1, S. 255 View in Reaxys Grotthusz, Th. v.; Abhandlungen ueber Licht und Elektrizitaet in: Ostwald, Wi., Klassiker der exakten Wissenschaften Nr. 152, Leipzig 1906, S. 103 View in Reaxys Grotthusz, Th. v.; Abhandlungen ueber Licht und Elektrizitaet in: Ostwald, Wi., Klassiker der exakten Wissenschaften Nr. 152, Leipzig 1906, S. 119 ; (from Gmelin) View in Reaxys

in water, Irradiation (UV/VIS); no decomposition of the H2O/I2-soln. on influence of sun light; Berthelot, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 127; (1898); p. 796 - 796 ; (from Gmelin) View in Reaxys in water, Irradiation (UV/VIS); influence of sun light, formation of HI and HIO3 (and changing colour of soln. to colorless); Dossios, L.; Weith, W.; Z. Ch. (2); vol. 5; (1869); p. 379 - 379 View in Reaxys vol. I: MVol.1; 50, page 173 - 175 View in Reaxys Dossios, L.; Weith, W.; Ber. naturw. Ges. Zuerich; (1868); p. 258 - 258 ; (from Gmelin) View in Reaxys

in water, Irradiation (UV/VIS); no decomposition of the H2O/I2-soln. on influence of sun light; vol. I: MVol.1; 50, page 173 - 175 ; (from Gmelin) View in Reaxys

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in water, heating an aq. I2 soln.; vol. I: MVol.1; 50, page 173 - 175 ; (from Gmelin) View in Reaxys O

Rx-ID: 26083107 View in Reaxys 38/310 Yield

Conditions & References in water Berg, A.; Bulletin de la Societe Chimique de France; vol. 27; (1902); p. 1077 - 1083 View in Reaxys Cupr, V.; Rec. Trav. chim.; vol. 47; (1928); p. 55 - 72 View in Reaxys Henville, D.; Analyst (Cambridge, United Kingdom); vol. 54; (1929); p. 228 - 231 View in Reaxys Lindner, J.; Monatshefte fuer Chemie; vol. 33; (1912); p. 613 - 672 View in Reaxys Macauley, R. M.; Journal of the Chemical Society; vol. 121; (1922); p. 552 - 556 View in Reaxys Raschig, F.; Z. Anorg. Chem.; vol. 17; (1904); p. 577 - 585 View in Reaxys vol. S: MVol.B2; 1.5.3, page 498 - 514 ; (from Gmelin) View in Reaxys H

Rx-ID: 26083454 View in Reaxys 39/310 Yield

Conditions & References With ozone in ethanol, byproducts: CH3CHO, CH3COOH; Irradiation (UV/VIS); presence of ozone reduces formation of HI3 in favor of ethanol'soxidation; Batley, A.; Transactions of the Faraday Society; vol. 24; (1928); p. 438 - 438 ; (from Gmelin) View in Reaxys in ethanol, Irradiation (UV/VIS) Batley, A.; Transactions of the Faraday Society; vol. 24; (1928); p. 438 - 438 ; (from Gmelin) View in Reaxys With ozone in ethanol, byproducts: CH3CHO, CH3COOH; Irradiation (UV/VIS); presence of ozone reduces formation of HI3 in favor of ethanol'soxidation; vol. I: MVol.1; 37, page 149 - 151 ; (from Gmelin) View in Reaxys in ethanol, Irradiation (UV/VIS) vol. I: MVol.1; 37, page 149 - 151 ; (from Gmelin) View in Reaxys

I P

I2P4S3

Rx-ID: 26343466 View in Reaxys 40/310 Yield

Conditions & References With hydrogen sulfide in neat (no solvent), slow reaction with dry H2S at 110 to 120°C; Ouvrard, L.; Ann. Chim. Phys.; vol. 2; (1894); p. 212 - 251 ; (from Gmelin) View in Reaxys With H2S in neat (no solvent), slow reaction with dry H2S at 110 to 120°C;

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vol. P: MVol.C; 227, page 520 - 522 ; (from Gmelin) View in Reaxys H+ H 2N

Rx-ID: 26366788 View in Reaxys 41/310 Yield

Conditions & References in not given, byproducts: water; the react. sensitive to ZnO and sunlight Bhattacharya, A. K.; Dhar, N. R.; Q. J. Indian Chem. Soc.; vol. 4; (1927); p. 300 ; (from Gmelin) View in Reaxys in not given, byproducts: water Lobry de Bruyn, C. A.; Rec. Trav. chim.; vol. 10; (1891); p. 111 View in Reaxys Meyeringh, W.; Ber.; vol. 10; (1877); p. 1940 ; (from Gmelin) View in Reaxys in not given, Kinetics, byproducts: water; effect of HCl and light was investigated Bhattacharya, A. K.; Dhar, N. R.; Z. Anorg. Chem.; vol. 192; (1930); p. 211 ; (from Gmelin) View in Reaxys in not given, Kinetics, byproducts: water; effect of HCl and light was investigated vol. NH4: MVol.2; 14, page 569 - 586 ; (from Gmelin) View in Reaxys in not given, byproducts: water; the react. sensitive to ZnO and sunlight vol. NH4: MVol.2; 14, page 569 - 586 ; (from Gmelin) View in Reaxys in not given, byproducts: water vol. NH4: MVol.2; 14, page 569 - 586 ; (from Gmelin) View in Reaxys

(v1) + Ni

(v5)

Ni +

Ni( 1+)

(v2)

(v5)

Rx-ID: 26418689 View in Reaxys 42/310 Yield

Conditions & References in gas, The react. is performed on an ion cyclotron resonance (ICR) mass spectrometer. The nickel ion and the aromatic compd. are admitted to the ICR cell in approx. 1:1 ratio, to a total pressure of 6E-6 Torr.; MS Stepnowski, Richard; Allison, John; Journal of the American Chemical Society; vol. 111; nb. 2; (1989); p. 449 - 457 ; (from Gmelin) View in Reaxys

I I

(v4)

I I

Rx-ID: 26433154 View in Reaxys 43/310 Yield

Conditions & References With hydrogen in neat (no solvent), on heating in H, loss of I, forming of HI; Guichard, M.; Bulletin de la Societe Chimique de France; vol. 3; (1908); p. 13 - 13 View in Reaxys Guichard, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 145; (1907); p. 921 - 921 View in Reaxys

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vol. U: MVol.; 46, page 139 - 141 ; (from Gmelin) View in Reaxys O

HO O– Na +

Na +

–

Rx-ID: 26471926 View in Reaxys 44/310 Yield

Conditions & References With iodine in water, byproducts: H2O; oxidation of aq. NaHSO3 with I2; Spring, W.; Bourgeois, E.; Bulletin de la Societe Chimique de France; vol. 46; (1886); p. 151 View in Reaxys Spring; Bourgeois; Bulletin de la Societe Chimique de France; vol. 6; (1891); p. 920 - 920 View in Reaxys vol. Na: MVol.; 175, page 532 - 535 ; (from Gmelin) View in Reaxys

O I

Rx-ID: 26483380 View in Reaxys 45/310 Yield

Conditions & References With H2S4O6 in water, byproducts: H2SO4, H2S; side reaction of iodate reaction with thiosulfate; Casolari, A.; Gazzetta Chimica Italiana; vol. 37; (1907); p. 615 - 615 View in Reaxys vol. I: MVol.2; 144, page 567 - 569 ; (from Gmelin) View in Reaxys

O O

S OO

Rx-ID: 26484558 View in Reaxys 46/310 Yield

Conditions & References With sulfur dioxide, water in water, Kinetics Selmons, F.; Ber.; vol. 21; (1888); p. 230 - 234 View in Reaxys vol. S: MVol.B2; 1.6.2.6, page 522 - 524 View in Reaxys Selmons, F.; Diss. Berlin 1887. ; (from Gmelin) View in Reaxys

I(x)O(x)P(x)

P OH OH

P OH O

O I

O P OH

OH OH

Rx-ID: 26586701 View in Reaxys 47/310 Yield

Conditions & References With water in water, byproducts: H4P2O5, PH3; easy hydrolysis; Baudler, M.; Fricke, G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 319; (1963); p. 211 - 229 View in Reaxys Baudler, M.; Ang. Chem.; vol. 73; (1961); p. 761 - 761 View in Reaxys Baudler, M.; Ang. Chem.; vol. 74; (1962); p. 493 - 493 View in Reaxys vol. P: MVol.C; 230, page 527 - 529 ; (from Gmelin) View in Reaxys

(Ag,Cu)I

Rx-ID: 26636505 View in Reaxys 48/310

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Yield

Conditions & References With H2 in not given, heating in H2 atmosphere; Rodwell, G. F.; Philosophical Transactions of the Royal Society of London; vol. 173; (1882); p. 1125 - 1168 View in Reaxys Rodwell, G. F.; Proc. Roy. Soc. (London); vol. 33; (1881); p. 143 - 145 View in Reaxys vol. Ag: MVol.B4; 50.4.7.2, page 450 - 454 ; (from Gmelin) View in Reaxys -2

(v1)

2 Na +

S O

(v1)

O O

–O

S HO

Na +

Rx-ID: 26089996 View in Reaxys 49/310 Yield

Conditions & References With water in not given, with HCl acidified KIO4 soln., at 19.2°C, 31°C and 40°C Carriere, E.; Delpla, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 205; (1937); p. 1157 - 1158 ; (from Gmelin) View in Reaxys With H2O in not given, with HCl acidified KIO4 soln., at 19.2°C, 31°C and 40°C vol. S: MVol.B2; 7.5.3, page 910 - 913 ; (from Gmelin) View in Reaxys

CuI

CuS

Rx-ID: 26101589 View in Reaxys 50/310 Yield

Conditions & References

>99

With hydrogen sulfide in water, on introduction of H2S; Ponomarev, V. D.; Gubel'bank, S. M.; Zhurnal obshchei Khim. (russ.); vol. 9; (1939); p. 1365 - 1368; C. A.; (1940); p. 1265 View in Reaxys vol. Cu: MVol.B1; 183, page 404 - 406 ; (from Gmelin) View in Reaxys

Rx-ID: 26102492 View in Reaxys 51/310 Yield

Conditions & References With SiF4 in ethanol, byproducts: ethyl iodide, I2 Knop, W.; Journal fuer Praktische Chemie (Leipzig); vol. 74; (1858); p. 41 - 62 View in Reaxys vol. Si: MVol.B; 231, page 631 - 633 ; (from Gmelin) View in Reaxys

Cu 2I2

H S

Rx-ID: 26170763 View in Reaxys 52/310 Yield

Conditions & References in acetonitrile, byproducts: Cu2S; reaction of a Cu2I2 soln. in acetonitrile with gaseous H2S; formation of a Cu2S soln. and escaping of HI; equilibrium; Naumann, A.; Schier, A.; Ber.; vol. 47; (1914); p. 253 - 253 View in Reaxys Naumann, A.; Schier, A.; Ber.; vol. 47; (1914); p. 255 - 255 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin)

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View in Reaxys in acetonitrile Naumann, A.; Schier, A.; Ber.; vol. 47; (1914); p. 248 - 248 View in Reaxys Naumann, A.; Schier, A.; Ber.; vol. 47; (1914); p. 253 - 253 View in Reaxys Naumann, A.; Schier, A.; Ber.; vol. 47; (1914); p. 255 - 255 ; (from Gmelin) View in Reaxys in acetonitrile vol. I: MVol.2; 51, page 360 - 362 ; (from Gmelin) View in Reaxys

Cl 3IP

H H

P OH OH

Rx-ID: 26173570 View in Reaxys 53/310 Yield

Conditions & References With water in water, decompn. with water forming H3PO3, HCl, HI and a small amount of a yellow-red compound; Moot, C. G.; Ber.; vol. 13; (1880); p. 2029 - 2031 ; (from Gmelin) View in Reaxys With H2O in water, decompn. with water forming H3PO3, HCl, HI and a small amount of a yellow-red compound; vol. P: MVol.C; 231, page 529 - 530 ; (from Gmelin) View in Reaxys

I P

P OH OH

P OH O

Rx-ID: 26343462 View in Reaxys 54/310 Yield

Conditions & References With water in water, byproducts: H3PO2, P12H6 Kolitowska, J. H.; Roczniki Chemii; vol. 15; (1935); p. 29 - 36 View in Reaxys Kolitowska, J. H.; Roczniki Chemii; vol. 17; (1937); p. 616 - 619 ; (from Gmelin) View in Reaxys With H2O in water, byproducts: H3PO2, P12H6 vol. P: MVol.C; 227, page 520 - 522 ; (from Gmelin) View in Reaxys

BI2P

P2S3

B2S3

Rx-ID: 26362091 View in Reaxys 55/310 Yield

Conditions & References With hydrogen sulfide in not given, heating with H2S; Moissan, H.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 113; (1891); p. 624 627 ; (from Gmelin) View in Reaxys With H2S in not given, heating with H2S; vol. P: MVol.C; 269, page 618 - 620 ; (from Gmelin) View in Reaxys

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H 2 Cl H 2N

NH 2

Rx-ID: 26366214 View in Reaxys 56/310 Yield

Conditions & References With chloride or bromide or nitrate, Kinetics, reaction inhibited by chloride, bromide, or nitrate ions Berthoud, A.; Porret, D.; Helvetica Chimica Acta; vol. 17; (1934); p. 32 ; (from Gmelin) View in Reaxys With ZnO or Al2O3 or erythrosine, the reaction is sensitized by ZnO or Al2O3 or erythrosine Bhattacharya, A. K.; Dhar, N. R.; Q. J. Indian Chem. Soc.; vol. 4; (1927); p. 300 View in Reaxys Bhattacharya, A. K.; Dhar, N. R.; Q. J. Indian Chem. Soc.; vol. 4; (1927); p. 301 ; (from Gmelin) View in Reaxys Kinetics, in the dark Berthoud, A.; Porret, D.; Helvetica Chimica Acta; vol. 17; (1934); p. 32 ; (from Gmelin) View in Reaxys With ZnO or Al2O3 or erythrosine, the reaction is sensitized by ZnO or Al2O3 or erythrosine vol. NH4: MVol.2; 12, page 532 - 552 ; (from Gmelin) View in Reaxys With chloride or bromide or nitrate, Kinetics, reaction inhibited by chloride, bromide, or nitrate ions vol. NH4: MVol.2; 12, page 532 - 552 ; (from Gmelin) View in Reaxys Kinetics, in the dark vol. NH4: MVol.2; 12, page 532 - 552 ; (from Gmelin) View in Reaxys I

GeH

Rx-ID: 26366249 View in Reaxys 57/310 Yield

Conditions & References Dennis, L. M.; Skow, N. A.; Journal of the American Chemical Society; vol. 52; (1930); p. 2371 - 2371 ; (from Gmelin) View in Reaxys vol. Ge: MVol.; 6, page 27 - 29 ; (from Gmelin) View in Reaxys

Rx-ID: 26382255 View in Reaxys 58/310 Yield

Conditions & References With hydrogen sulfide in water, byproducts: S; longer reaction of H2S;; pptn. of S; HI - HCl soln.; McIvor, R. W. E.; Chem. News J. Ind. Sci.; vol. 86; (1902); p. 6 - 6 View in Reaxys vol. I: MVol.2; 173, page 628 - 629 ; (from Gmelin) View in Reaxys

BrHgI

HgS

Rx-ID: 26384677 View in Reaxys 59/310 Yield >99

Conditions & References With hydrogen sulfide in water, soln. containing KI;; precipitation; Oppenheim, A.; Ber. Dtsch. Chem. Ges.; vol. 2; (1869); p. 571 - 573 ; (from Gmelin)

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View in Reaxys With H2S in water vol. Hg: MVol.B2; 260, page 949 - 951 ; (from Gmelin) View in Reaxys Cl I

Rx-ID: 26483528 View in Reaxys 60/310 Yield

Conditions & References With hydrogen in neat (no solvent), H2 highly heated before passing over ICl3; violent reaction; Christomanos, A. C.; Ber.; vol. 10; (1877); p. 440 - 440 ; (from Gmelin) View in Reaxys With H2 in neat (no solvent), H2 highly heated before passing over ICl3; violent reaction; vol. I: MVol.2; 169, page 621 - 623 ; (from Gmelin) View in Reaxys

I I

Rx-ID: 26487448 View in Reaxys 61/310 Yield

Conditions & References With hydrogen in neat (no solvent), at 100°C formation of HI and CHI3; Lantenois, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 156; (1913); p. 1629 - 1631 View in Reaxys vol. C: MVol.D2; 4.1.4.6, page 281 - 283 ; (from Gmelin) View in Reaxys

K+

O3Sb2

Sb– I I I

BrK

Rx-ID: 26604557 View in Reaxys 62/310 Yield

Conditions & References With water in not given Vournazos, A. C.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 175; (1922); p. 164 ; (from Gmelin) View in Reaxys With H2O in not given vol. K: MVol.5; 5.4.4, page 1049 - 1049 ; (from Gmelin) View in Reaxys

( 137)Cs(

131)I

Rx-ID: 27179784 View in Reaxys 63/310 Yield

Conditions & References With H2O, O2, NH3 in neat (no solvent, gas phase), byproducts: CsOH, H2O, N2; Pt boat with (air) H2O and NH3 heated to 1070-1170 K; heated to 1270-1470 K (sublimation); further reagent NH4Cl; vapor condensed in different parts of chamber; aerosols partially transferred with gas flow onto paper filter; aerosol breakthrough the filter monitored with 2 bubblers filled with Na2S3O3; elem.anal.; electron microscopy Kulyukhin, S. A.; Mikheev, N. B.; Kamenskaya, A. N.; Melikhov, I. V.; Rumer, I. A.; Novichenko, V. L.; Radiochemistry (Moscow); vol. 43; (2001); p. 580 - 585; Radiokhimiya; vol. 43; (2001); p. 510 - 514 ; (from Gmelin) View in Reaxys

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Rx-ID: 27394144 View in Reaxys 64/310 Yield

Conditions & References in solid matrix, Irradiation (UV/VIS); irradiated (254 nm) in Ar at 10 K; not isolated, detected by IR, UV Bettinger, Holger F.; Chemical Communications; nb. 21; (2005); p. 2756 - 2757 ; (from Gmelin) View in Reaxys

(CH3)2C:CH2

Rx-ID: 6211266 View in Reaxys 65/310 Yield

Conditions & References T= 134 - 190 °C , Gleichgewicht Jones; Ogg; Journal of the American Chemical Society; vol. 59; (1937); p. 1944 View in Reaxys T= 345 - 430 °C , Gleichgewicht, Kinetics Polanyi; Nature (London, United Kingdom); vol. 151; (1943); p. 97; ; (1943); p. 2642 View in Reaxys Butler; Mandel; Polanyi; Transactions of the Faraday Society; vol. 41; (1945); p. 304,305; ; (1945); p. 5160 View in Reaxys Butler; Polanyi; Transactions of the Faraday Society; vol. 39; (1943); p. 19,23, 25 View in Reaxys

H 2N

Rx-ID: 26083430 View in Reaxys 66/310 Yield

Conditions & References dry hydroxylamine; Bruyn, L. De; Rec. Trav. chim.; vol. 11; (1892); p. 30 - 30 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys in neat (no solvent), dry hydroxylamine; vol. I: MVol.2; 184, page 652 - 655 ; (from Gmelin) View in Reaxys in neat (no solvent) Bruyn, L. de; Rec. Trav. chim.; vol. 11; (1892); p. 30 - 30 ; (from Gmelin) View in Reaxys

I Cl

Rx-ID: 26088559 View in Reaxys 67/310 Yield

Conditions & References With hydrogenchloride, Irradiation (UV/VIS); photochemical reaction; Williams, R. R.; Ogg, R. A.; Journal of Chemical Physics; vol. 15; (1947); p. 696 - 702 ; (from Gmelin) View in Reaxys With HCl, Irradiation (UV/VIS); photochemical reaction; vol. Cl: SVol.B1; 81, page 213 - 215 ; (from Gmelin) View in Reaxys

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O BI2P

P OH OH

B HO

Rx-ID: 26362094 View in Reaxys 68/310 Yield

Conditions & References With water in water, hydrolysis; formation of HI, H3BO3, H3PO3 and evolution of a small amount of PH3; Moissan, H.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 113; (1891); p. 624 627 ; (from Gmelin) View in Reaxys With H2O in water, hydrolysis; formation of HI, H3BO3, H3PO3 and evolution of a small amount of PH3; vol. P: MVol.C; 269, page 618 - 620 ; (from Gmelin) View in Reaxys

–O

O–

S OS

S – OO

O S

H O

Rx-ID: 26366289 View in Reaxys 69/310 Yield

Conditions & References With water in not given, in neutral or acidic soln. Muller, J. A.; Bulletin de la Societe Chimique de France; vol. 5; (1909); p. 1119 - 1121 ; (from Gmelin) View in Reaxys With H2O in not given, in neutral or acidic soln. vol. S: MVol.B2; 10, page 979 - 992 ; (from Gmelin) View in Reaxys

H 2N

Rx-ID: 26366787 View in Reaxys 70/310 Yield

Conditions & References in water, byproducts: water Lobry de Bruyn, C. A.; Rec. Trav. chim.; vol. 10; (1891); p. 111 View in Reaxys Meyeringh, W.; Ber.; vol. 10; (1877); p. 1940 ; (from Gmelin) View in Reaxys in not given, byproducts: water; the react sensitive to ZnO and sunlight Bhattacharya, A. K.; Dhar, N. R.; Q. J. Indian Chem. Soc.; vol. 4; (1927); p. 300 ; (from Gmelin) View in Reaxys in water, byproducts: water vol. NH4: MVol.2; 14, page 569 - 586 ; (from Gmelin) View in Reaxys in not given, byproducts: water; the react sensitive to ZnO and sunlight vol. NH4: MVol.2; 14, page 569 - 586 ; (from Gmelin) View in Reaxys H

(v1)

Rx-ID: 26433521 View in Reaxys 71/310 Yield

Conditions & References in gas, Kinetics Mayer; Schieler; Johnston, Harold S.; The Journal of Chemical Physics; vol. 45; nb. 1; (1966); p. 385 - 391 View in Reaxys

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Mayer, S. W.; Szabo, J. B.; Schieler, L.; WSCI-65-24 (1965), S. 1 - 19; C. A.; vol. 64; (1966); p. 4315 ; (from Gmelin) View in Reaxys in neat (no solvent, gas phase), Kinetics vol. B: B-Verb.14; 1, page 1 - 8 ; (from Gmelin) View in Reaxys

Rx-ID: 26436537 View in Reaxys 72/310 Yield

Conditions & References

With sulfur dioxide, excess of SO2; Alsterberg, G.; Biochemische Zeitschrift; vol. 172; (1926); p. 223 - 232 View in Reaxys Chattaway, F. D.; Wadmore, J. D.; Journal of the Chemical Society; vol. 81; (1902); p. 191 - 203 View in Reaxys Meinecke, C.; Z. Anorg. Chem.; vol. 2; (1892); p. 157 - 164 View in Reaxys Meyer, E. v.; Journal fuer Praktische Chemie (Leipzig); vol. 36; (1887); p. 292 - 299 ; (from Gmelin) View in Reaxys

With SO2, excess of SO2; vol. S: MVol.B2; 1.6.4, page 543 - 552 ; (from Gmelin) View in Reaxys

CaF 2

CaI 2

Rx-ID: 26439317 View in Reaxys 73/310 Yield

Conditions & References Fredenhagen, K.; Cadenbach, G.; Klatt, W.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 164; (1933); p. 176 - 200 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction of CaI2 with waterfree liquid HF under formation of HI and CaF2; Fredenhagen, K.; Cadenbach, G.; Klatt, W.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 164; (1933); p. 176 - 200 ; (from Gmelin) View in Reaxys Fredenhagen, K.; Cadenbach, G.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 146; (1930); p. 245 - 280 View in Reaxys vol. Ca: MVol.B2; 82, page 452 - 454 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction of CaI2 with waterfree liquid HF under formation of HI and CaF2; Fredenhagen, K.; Cadenbach, G.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 146; (1930); p. 245 - 280 View in Reaxys vol. Ca: MVol.B2; 153, page 614 - 616 ; (from Gmelin) View in Reaxys I

OH P

As 2O3 I

As HO

P OH O

Rx-ID: 26486171 View in Reaxys 74/310 Yield

Conditions & References With water in water, addn. of PI3 to aq. As2O3; pptn. of colloidal As; Sen, N. N.; J. Proc. Asiatic Soc. Bengal (2); vol. 15; (1919); p. 263 - 265; C. A.; (1920); p. 3377 ; (from Gmelin)

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View in Reaxys With H2O in water, addn. of PI3 to aq. As2O3; pptn. of colloidal As; vol. P: MVol.C; 159, page 363 - 366 ; (from Gmelin) View in Reaxys F F F F PB-7 I F F

F2H 2

Rx-ID: 26493814 View in Reaxys 75/310 Yield

Conditions & References With H2 in neat (no solvent), on heating; explosion; Ruff, O.; Keim, R.; Z. Anorg. Chem.; vol. 193; (1930); p. 176 - 176 View in Reaxys vol. I: MVol.2; 160, page 602 - 604 ; (from Gmelin) View in Reaxys

I Te I

Rx-ID: 26535752 View in Reaxys 76/310 Yield

Conditions & References in water, hydrolysis; Berzelius, J. J.; Ann. Chim. Phys.; vol. 58; (1835); p. 273 - 273 View in Reaxys Berzelius, J. J.; Annalen der Physik (Weinheim, Germany); vol. 32; (1834); p. 620 - 620 ; (from Gmelin) View in Reaxys in water, hydrolysis; vol. Te: MVol.; 107, page 346 - 349 ; (from Gmelin) View in Reaxys

I I

Rx-ID: 5817720 View in Reaxys 77/310 Yield

Conditions & References mit UV-Licht; Produkt5: Wasserstoff.Irradiation Emschwiller; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 192; (1931); p. 800,800 Anm.; Annales de Chimie (Cachan, France); vol. <10>17; (1932); p. 425 View in Reaxys T= 25 °C , mit Licht (lambda: 253.7 mmy); weitere Produkte: Methan und Wasserstoff.Irradiation West; Schlessinger; Journal of the American Chemical Society; vol. 60; (1938); p. 962 View in Reaxys Jones; Bates; Journal of the American Chemical Society; vol. 56; (1934); p. 2286 View in Reaxys T= 25 °C , mit Licht (lambda: 202.6 mmy); weitere Produkte: Methan und Wasserstoff.Irradiation West; Schlessinger; Journal of the American Chemical Society; vol. 60; (1938); p. 962 View in Reaxys Jones; Bates; Journal of the American Chemical Society; vol. 56; (1934); p. 2286 View in Reaxys Photolysis Bunbury et al.; Journal of the American Chemical Society; vol. 78; (1956); p. 6228

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View in Reaxys

I HO

S OO

Rx-ID: 26082986 View in Reaxys 78/310 Yield

Conditions & References

100 %, 100 0 - 25 °C; part of a Mg-S-I water splitting cycle % Kumagai, Toshiya; Mizuta, Susumu; Chemistry Letters; (1983); p. 679 - 682 ; (from Gmelin) View in Reaxys

Ba2+

–O

O–

Rx-ID: 26082987 View in Reaxys 79/310 Yield

Conditions & References in water, byproducts: BaSO4, O2; BaO2, I2 and water mixed; equal amount of iodine added and SO2 passed until decoloration of soln.;; HI distilled, SO2-containing first running rejected; HI-soln. contains sulfur compounds; vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys in water, byproducts: BaSO4, O2; BaO2, I2 and water mixed; equal amount of iodine added and SO2 passed until decoloration of soln.;; HI distilled, SO2-containing first running rejected; Bodroux, F.; Bulletin de la Societe Chimique de France; vol. 35; (1906); p. 493 - 493 View in Reaxys Bodroux, F.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 142; (1906); p. 279 279 View in Reaxys Bodroux, F.; Chemiker-Zeitung; vol. 30; (1906); p. 156 - 156 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys in water, byproducts: BaSO4, O2; BaO2, I2 and water mixed; equal amount of iodine added and SO2 passed until decoloration of soln.;; HI distilled, SO2-containing first running rejected; HI-soln. contains sulfur compounds; Kassner, G.; Apoth. Ztg.; vol. 24; (1909); p. 562 - 562 ; (from Gmelin) View in Reaxys -2

-2 (v1)

2 Na +

S O

(v1)

–O

O O

S HO

O– Na +

–O

S OO

(v1)

O S

S O

Rx-ID: 26083004 View in Reaxys 80/310 Yield

Conditions & References With water in not given, neutral soln. Pickering, S. U.; Journal of the Chemical Society; vol. 37; (1880); p. 128 - 140 ; (from Gmelin) View in Reaxys With H2O in not given, neutral soln. vol. S: MVol.B2; 7.4, page 894 - 903 ; (from Gmelin) View in Reaxys

S3Sb2

HgI 2

I2O5Sb4

Hg 3I2S2

Rx-ID: 26149902 View in Reaxys 81/310 Yield

Conditions & References With water in water, reaction time 2 days; 10 °C; Montignie, E.; Bulletin de la Societe Chimique de France; vol. 8; (1941); p. 201 - 201

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View in Reaxys vol. Sb: MVol.B3; 11, page 522 - 524 ; (from Gmelin) View in Reaxys

OH HO

S OO

Rx-ID: 26157760 View in Reaxys 82/310 Yield

Conditions & References With alkaline earth iodides, byproducts: alkaline earth sulfates; reaction of alkaline earth iodides with H2SO4; no formation of iodine; Glover, R. M.; L'Institut; vol. 8; nb. I; (1840); p. 387 - 387 View in Reaxys Glover, R. M.; Philosophical Magazine (1798-1977); vol. 19; (1841); p. 92 - 92 View in Reaxys Glover, R. M.; Rep. 10 Brit. Assoc. Notices; (1840); p. 75 - 75 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys

H O

Rx-ID: 26183167 View in Reaxys 83/310 Yield

Conditions & References in ethanol, Irradiation (UV/VIS); 254 nm photolysis; not isolated, monitored by UV and Raman Mendoza, Edgar A.; Gafney, Harry D.; Inorganic Chemistry; vol. 29; (1990); p. 4853 - 4854 ; (from Gmelin) View in Reaxys

BaI2

Rx-ID: 26452000 View in Reaxys 84/310 Yield

Conditions & References With sulfuric acid, immediate decompn. under influence of alcoholic and ethereal H2SO4; Hantzsch, A.; Carlson, H.; Z. Anorg. Chem.; vol. 160; (1927); p. 11 View in Reaxys Hantzsch, A.; Carlson, H.; Z. Anorg. Chem.; vol. 160; (1927); p. 12 ; (from Gmelin) View in Reaxys With H2SO4, immediate decompn. under influence of alcoholic and ethereal H2SO4; vol. Ba: MVol.; 9.1, page 238 - 245 ; (from Gmelin) View in Reaxys

I N

N I

Rx-ID: 26595001 View in Reaxys 85/310 Yield

Conditions & References in water, with concentrated acids; dry NI3*NH3; Chattaway, F. D.; Stevens, H. P.; Chem. News J. Ind. Sci.; vol. 79; (1899); p. 91 - 91 View in Reaxys Chattaway, F. D.; Stevens, H. P.; American Chemical Journal; vol. 24; (1900); p. 331 - 331 View in Reaxys Raschig, F.; Schwefel- und Stickstoffstudien, Leipzig-Berlin 1924, S. 35 ; (from Gmelin) View in Reaxys in water, with concentrated acids; dry NI3*NH3; vol. I: MVol.2; 158, page 597 - 599 ; (from Gmelin)

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View in Reaxys

Rx-ID: 7057719 View in Reaxys 86/310 Yield

Conditions & References Lobry de Bruyn; Chemische Berichte; vol. 26; (1893); p. 269; Recueil des Travaux Chimiques des Pays-Bas; vol. 13; (1894); p. 127 View in Reaxys With air in ethanol, byproducts: CH3CHO, CH3COOH, CH3COOC2H5; Irradiation (UV/VIS); longer storage in light and air; oxidation favored by impurities (partially inhibited by addn. of KI, NaI or KBr); Bohrisch, P.; Apoth. Ztg.; vol. 43; (1928); p. 436 - 436 View in Reaxys Gualdini, G. C.; Bollettino Chimico Farmaceutico; vol. 69; (1930); p. 6 - 6 View in Reaxys Knoll, W.; Apoth. Ztg.; vol. 43; (1928); p. 1324 - 1324 View in Reaxys Panopoulos, G.; Megaloikonomos, J.; Praktika tes Akademias Athenon; vol. 2; (1927); p. 15 - 15 View in Reaxys Schwarzl; Pharm. Presse; vol. 30; (1925); p. 60 - 60 ; (from Gmelin) View in Reaxys

byproducts: aldehyde Lawall, Ch. H.; Tice, L. F.; Journal of the American Pharmaceutical Association (1912-1977); vol. 21; (1932); p. 122 - 122 ; (from Gmelin) View in Reaxys With air in ethanol, byproducts: CH3CHO, CH3COOH, CH3COOC2H5; Irradiation (UV/VIS); longer storage in light and air; oxidation favored by impurities (partial inhibition by addn. of KI, NaI or KBr); Budde, Th.; Veroeffentl. Gebiete Militaer-Sanitaetswesens; nb. 52; (1912); p. 93 - 93; C. I; (1912); p. 1856 View in Reaxys Copley, D. M.; Journal of the American Pharmaceutical Association (1912-1977); vol. 13; (1924); p. 806 - 806 View in Reaxys Courtot, C.; Journal de Pharmacie et de Chimie; vol. 1; (1910); p. 297 - 297 View in Reaxys Courtot, C.; Journal de Pharmacie et de Chimie; vol. 1; (1910); p. 354 - 354 View in Reaxys Courtot, C.; Journal de Pharmacie et de Chimie; vol. 2; (1910); p. 344 - 344 View in Reaxys Courtot, C.; Journal de Pharmacie et de Chimie; vol. 9; (1914); p. 69 - 69 View in Reaxys Droste; Pharmazeutische Zentralhalle fuer Deutschland; vol. 55; (1914); p. 503 - 503 View in Reaxys Droste; Pharmazeutische Zentralhalle fuer Deutschland; vol. 55; (1914); p. 525 - 525 View in Reaxys Droste; Pharmazeutische Zentralhalle fuer Deutschland; vol. 63; (1922); p. 372 - 372 View in Reaxys Hergenholtz, C.; Pharmazeutische Zeitung; vol. 52; (1907); p. 222 - 222 View in Reaxys Kebler, L. F.; American Journal of Pharmacy and the Sciences Supporting Public Health (1937-1978); vol. 85; (1913); p. 153 - 153 View in Reaxys Papst; Apoth. Ztg.; vol. 32; (1917); p. 626 - 626 View in Reaxys Roques, F.; Journal de Pharmacie et de Chimie; vol. 9; (1914); p. 277 - 277 View in Reaxys Rupp, E.; Wegner, W.; Maisz, P.; Archiv der Pharmazie (Weinheim, Germany); vol. 262; (1924); p. 5 - 5 View in Reaxys Ruszkowski, M.; Sprawozd. Prac Instyt. farm.; vol. 7; nb. 2; (1924); p. 1 - 1; C. I; (1930); p. 1329

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View in Reaxys Thurston, A.; J. Ind. Eng. Chem.; vol. 1; (1909); p. 789 - 789 View in Reaxys Thurston, A.; Pharmazeutische Zeitung; vol. 35; (1910); p. 108 - 108 View in Reaxys Wiebelitz; Pharmazeutische Zeitung; vol. 57; (1912); p. 73 - 73 ; (from Gmelin) View in Reaxys in ethanol, soln. of iodine in ethanol decomposes in darkness; Panopoulos, G.; Megaloikonomos, J.; Praktika tes Akademias Athenon; vol. 2; (1927); p. 15 - 15 ; (from Gmelin) View in Reaxys With air in ethanol, byproducts: CH3CHO, CH3COOH, CH3COOC2H5; Irradiation (UV/VIS); longer storage in light and air; oxidation favored by impurities (partial inhibition by addn. of KI, NaI or KBr); vol. I: MVol.1; 37, page 149 - 151 ; (from Gmelin) View in Reaxys With air in ethanol, byproducts: CH3CHO, CH3COOH, CH3COOC2H5; Irradiation (UV/VIS); longer storage in light and air; oxidation favored by impurities (partially inhibited by addn. of KI, NaI or KBr); vol. I: MVol.1; 37, page 149 - 151 ; (from Gmelin) View in Reaxys in ethanol, soln. of iodine in ethanol decomposes in darkness; vol. I: MVol.1; 37, page 149 - 151 ; (from Gmelin) View in Reaxys 0%

byproducts: aldehyde vol. I: MVol.2; 183, page 649 - 652 ; (from Gmelin) View in Reaxys O

HO H

H O

O– Na +

–O

S HO

Na +

Rx-ID: 23827624 View in Reaxys 87/310 Yield

Conditions & References 16 :16. Reaction of a non-metallic reducing agent in phosphonium-based ionic liquid; [00070] To trihexyl(tetradecyl) phosphonium decanoate (5 mL), iodine (ca.0.2g) was added. A dark red brown solution was obtained and to it sodium bisulphite was added with a few drops of water to increase solubitly of sodium bisulphate (excess). Decolorization from dark brown to pale yellow occurs without decomposition of the ionic liquid as confirmed by gas chromatography mass spectrometry. in [TDTHP][Deca], Reactivity Patent; SIMON FRASER UNIVERSITY; WO2006/7703; (2006); (A1) English View in Reaxys

red

Rx-ID: 26184772 View in Reaxys 88/310 Yield

Conditions & References With iodine, excess of I2 Richardson, A.; Journal of the Chemical Society; vol. 51; (1887); p. 801 - 806 ; (from Gmelin) View in Reaxys With I2, excess of I2 vol. P: MVol.B; 3.4.1.7, page 285 - 288 ; (from Gmelin) View in Reaxys

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I (v4)

Os I I I

Rx-ID: 26344336 View in Reaxys 89/310 Yield

Conditions & References in ethanol, on heating HI and a black ppt. is formed; Moraht, H.; Wischin, C.; Z. Anorg. Chem.; vol. 3; (1893); p. 171 - 175 View in Reaxys vol. Os: MVol.; 30, page 57 - 58 ; (from Gmelin) View in Reaxys in water, on heating HI and a black ppt. is formed; Moraht, H.; Wischin, C.; Z. Anorg. Chem.; vol. 3; (1893); p. 171 - 175 View in Reaxys vol. Os: MVol.; 30, page 57 - 58 ; (from Gmelin) View in Reaxys 2

O K+

(v6)

K+

(v6) – O

Cr – O OI

(v6)

O–

Rx-ID: 26390707 View in Reaxys 90/310 Yield

Conditions & References in water, hydrolysis; Guyot, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 73; (1871); p. 46 - 47 View in Reaxys Guyot, P.; Journal fuer Praktische Chemie (Leipzig); vol. 4; (1871); p. 33 - 34 ; (from Gmelin) View in Reaxys in water, hydrolysis; vol. Cr: MVol.B; 271, page 600 - 602 ; (from Gmelin) View in Reaxys

I 2

I3K3

Rx-ID: 26454622 View in Reaxys 91/310 Yield

Conditions & References With sulfuric acid, decomposition of double salt upon treatment with concd. H2SO4; Schneider, R.; Schaeffer, J.; Annalen der Physik (Weinheim, Germany); vol. 109; (1860); p. 615 - 615 ; (from Gmelin) View in Reaxys With H2SO4, decomposition of double salt upon treatment with concd. H2SO4; vol. Sb: MVol.B3; 1, page 497 - 499 ; (from Gmelin) View in Reaxys

I Sb I

I4K4

Rx-ID: 26455605 View in Reaxys 92/310 Yield

Conditions & References With sulfuric acid, decomposition of double salt upon treatment with concd. H2SO4;

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Schneider, R.; Schaeffer, J.; Annalen der Physik (Weinheim, Germany); vol. 109; (1860); p. 611 - 611 ; (from Gmelin) View in Reaxys With H2SO4, decomposition of double salt upon treatment with concd. H2SO4; vol. Sb: MVol.B3; 1, page 497 - 499 ; (from Gmelin) View in Reaxys

I 4

I3K3

Rx-ID: 26456483 View in Reaxys 93/310 Yield

BeI2

Rx-ID: 26511369 View in Reaxys 94/310 Yield

Conditions & References With water Lebeau, P.; Ann. Chim. Phys.; vol. 16; (1899); p. 493 View in Reaxys Lebeau, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 126; (1898); p. 1272 View in Reaxys vol. Be: MVol.; 3.7, page 125 - 127 ; (from Gmelin) View in Reaxys

I Sb

I4Tl4

Rx-ID: 26583719 View in Reaxys 95/310 Yield

I Sb I

I4Rb 4

Rx-ID: 26583740 View in Reaxys 96/310 Yield

Conditions & References With sulfuric acid, decomposition of double salt upon treatment with concd. H2SO4;

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Schneider, R.; Schaeffer, J.; Annalen der Physik (Weinheim, Germany); vol. 109; (1860); p. 615 - 615 ; (from Gmelin) View in Reaxys With H2SO4, decomposition of double salt upon treatment with concd. H2SO4; vol. Sb: MVol.B3; 1, page 497 - 499 ; (from Gmelin) View in Reaxys 3

3 H I 2

I–

N+ HH Sb

Rx-ID: 26583975 View in Reaxys 97/310 Yield

Conditions & References With sulfuric acid, decomposition of ammonium salt upon treatment with concd. H2SO4; Schneider, R.; Schaeffer, J.; Annalen der Physik (Weinheim, Germany); vol. 109; (1860); p. 615 - 615 ; (from Gmelin) View in Reaxys With H2SO4, decomposition of ammonium salt upon treatment with concd. H2SO4; vol. Sb: MVol.B3; 1, page 497 - 499 ; (from Gmelin) View in Reaxys 4

I–

H I

N HH Sb

Rx-ID: 26584158 View in Reaxys 98/310 Yield

I 2

I3Rb 3

Rx-ID: 26585503 View in Reaxys 99/310 Yield

I 2

Sb I

I3Tl3

Rx-ID: 26585506 View in Reaxys 100/310

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Yield

I Sb

I2Rb 2

Rx-ID: 26585753 View in Reaxys 101/310 Yield

I Sb

I2Tl2

Rx-ID: 26585807 View in Reaxys 102/310 Yield

3 H I 4

N+ HH Sb

I–

Rx-ID: 26586250 View in Reaxys 103/310 Yield

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2 H I

I–

N+ HH Sb

Rx-ID: 26586678 View in Reaxys 104/310 Yield

I Sb

ITl

Rx-ID: 26588013 View in Reaxys 105/310 Yield

I Sb

IRb

Rx-ID: 26588072 View in Reaxys 106/310 Yield

H H I

N+

Rx-ID: 26588294 View in Reaxys 107/310 Yield

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vol. Sb: MVol.B3; 1, page 497 - 499 ; (from Gmelin) View in Reaxys

I Sb

I2K2

Rx-ID: 26588694 View in Reaxys 108/310 Yield

I Sb

Rx-ID: 26588901 View in Reaxys 109/310 Yield

I 4

I3Rb 3

Rx-ID: 26588906 View in Reaxys 110/310 Yield

I 4

Sb I

I3Tl3

Rx-ID: 26588944 View in Reaxys 111/310 Yield

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View in Reaxys With H2SO4, decomposition of double salt upon treatment with concd. H2SO4; vol. Sb: MVol.B3; 1, page 497 - 499 ; (from Gmelin) View in Reaxys O

Rx-ID: 26061866 View in Reaxys 112/310 Yield

Conditions & References in formic acid, heating, reflux cooler;; pure, free of P; Kropatschek, W.; Monatshefte fuer Chemie; vol. 25; (1904); p. 591 - 591 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys

I HO

S OO

Rx-ID: 26082964 View in Reaxys 113/310 Yield

Conditions & References With water, sulfur, excess of I2, at 70 °C Muller, J. A.; Bulletin de la Societe Chimique de France; vol. 5; (1909); p. 1119 - 1121 ; (from Gmelin) View in Reaxys With S, H2O, excess of I2, at 70 °C vol. S: MVol.B2; 10, page 979 - 992 ; (from Gmelin) View in Reaxys

H HO

S OO

ClK

Rx-ID: 26083070 View in Reaxys 114/310 Yield

Conditions & References With water in tetrachloromethane, water, addn. of SOCl2 (in CCl4) to aq. KI/I2; shaking; product ratio depends on I2 concn.; Evans, A. G.; Meadows, G. W.; Transactions of the Faraday Society; vol. 43; (1947); p. 667 - 674 ; (from Gmelin) View in Reaxys With H2O in tetrachloromethane, water, addn. of SOCl2 (in CCl4) to aq. KI/I2; shaking; product ratio depends on I2 concn.; vol. S: MVol.B3; 124, page 1796 - 1798 ; (from Gmelin) View in Reaxys I

I H

I P

Rx-ID: 26083389 View in Reaxys 115/310 Yield

Conditions & References in neat (no solvent), heating I2 with dry PH3 in excess; formation of P2I4 and HI; Hofman, A. W.; Liebigs Annalen der Chemie; vol. 103; (1857); p. 355 - 356 View in Reaxys Holt, A.; Myers, J. E.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 82; (1913); p. 278 - 282 View in Reaxys vol. P: MVol.C; 20, page 39 - 40 ; (from Gmelin)

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View in Reaxys H

O O

Rx-ID: 26083436 View in Reaxys 116/310 Yield

Conditions & References in not given, byproducts: O2; neutral soln.; vol. I: MVol.1; 54, page 180 - 182 View in Reaxys Gyr, K.; Dissert. Zuerich 1902, S. 27 View in Reaxys Michaelis, A.; Anorganische Chemie in: Graham-Otto, Lehrbuch der Chemie, 5. Aufl., Braunschweig 1873, Bd. 2, Tl. 1, S. 253 ; (from Gmelin) View in Reaxys

H N

Rx-ID: 26083460 View in Reaxys 117/310 Yield

Conditions & References in ammonia, partial ammonolysis in liq. NH3;; not isolated; Fernelius, W. C.; Johnson, W. C.; Journal of Chemical Education; vol. 7; (1930); p. 1297 - 1297 ; (from Gmelin) View in Reaxys in ammonia, NH3 (liquid); partial ammonolysis in liq. NH3;; not isolated; vol. I: MVol.1; 33, page 140 - 142 ; (from Gmelin) View in Reaxys

AgI

Rx-ID: 26096113 View in Reaxys 118/310 Yield

Conditions & References With sulfuric acid, decompn.in sealed tube at 180°C Ladenburg, A.; Liebigs Annalen der Chemie; vol. 135; (1865); p. 1 - 24 View in Reaxys vol. Ag: MVol.B2; 8.2.8.7.5, page 297 - 297 ; (from Gmelin) View in Reaxys

I(1-)

Rx-ID: 26109516 View in Reaxys 119/310 Yield

Conditions & References in neat (no solvent), byproducts: H(1-); supersonich beam experiment; collision between H2 molecules and fast I(1-) ions; reaction cross section and angular distribution of HI investigated;; not isolated; Durup-Ferguson, M.; Brenot, J. C.; Fayeton, J. A.; Provost, K.; Barat, M.; Chemical Physics; vol. 114; (1987); p. 389 - 398 ; (from Gmelin) View in Reaxys

I 3

H O

CdI 2

Rx-ID: 26179765 View in Reaxys 120/310 Yield

Conditions & References With air, decomposition in presence of air; Dobroserdow; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 32; (1900); p. 297 - 297; C. II; (1900); p. 526 ; (from Gmelin)

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View in Reaxys With air, decomposition in presence of air; vol. Cd: MVol.; 44, page 112 - 114 ; (from Gmelin) View in Reaxys 2H

Rx-ID: 26370534 View in Reaxys 121/310 Yield

Conditions & References in gas, Kinetics, byproducts: (2)H Linert, Wolfgang; Chemical Physics; vol. 114; (1987); p. 449 - 456 ; (from Gmelin) View in Reaxys H

I2Mo

Rx-ID: 26377946 View in Reaxys 122/310 Yield

Conditions & References in neat (no solvent), byproducts: H2; react. of MoI2 with overheated H2O vapor; Guichard, M.; Ann. Chim. Phys.; vol. 23; (1901); p. 566 - 566 View in Reaxys Guichard, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 123; (1896); p. 821 - 821 View in Reaxys vol. Mo: MVol.; 64, page 179 - 181 ; (from Gmelin) View in Reaxys

S OO

Rx-ID: 26436542 View in Reaxys 123/310 Yield

Conditions & References With sulfur dioxide Serullas, G. S.; Ann. Chim. Phys.; vol. 27; (1824); p. 184 - 195 View in Reaxys Serullas, G. S.; Schw. J.; vol. 43; (1825); p. 42 - 53 ; (from Gmelin) View in Reaxys With SO2 vol. S: MVol.B2; 1.6.4, page 543 - 552 ; (from Gmelin) View in Reaxys

I (v4)

O2W

W I I

Rx-ID: 26436838 View in Reaxys 124/310 Yield

Conditions & References With H2O, slow react. in cold H2O; fast react. in boiling H2O Defacqz, E.; Ann. Chim. Phys.; vol. 22; (1901); p. 260 View in Reaxys Defacqz, E.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 127; (1898); p. 510 View in Reaxys vol. W: MVol.; 2.8, page 183 - 184 ; (from Gmelin) View in Reaxys

I2Sr

Rx-ID: 26439685 View in Reaxys 125/310

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Yield

Conditions & References in neat (no solvent), reaction with waterfree HF; Fredenhagen, H.; Cadenbach, G.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 146; (1930); p. 249 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction with waterfree HF; vol. Sr: MVol.; 63, page 157 - 158 ; (from Gmelin) View in Reaxys

Rx-ID: 26448300 View in Reaxys 126/310 Yield

Conditions & References in further solvent(s), Irradiation (UV/VIS); org. compd. soln. (in squalane) irradiation with nanosecond laser pulsesat 275 nm (laser fluence 0.6 mJ/cm**2 Furlan, Alan; Journal of Physical Chemistry B; vol. 103; nb. 9; (1999); p. 1550 - 1557 ; (from Gmelin) View in Reaxys

–O

I N

O I

NH +4

I–

Rx-ID: 26594999 View in Reaxys 127/310 Yield

Conditions & References in further solvent(s), Irradiation (UV/VIS); decompn. by light and hydrolysis in dild. NH4(1+) soln.; dependence on wave length and mechanism discussed; Chattaway, F. D.; Orton, K. J. P.; American Chemical Journal; vol. 24; (1900); p. 159 - 159 View in Reaxys Chattaway, F. D.; Orton, K. J. P.; American Chemical Journal; vol. 24; (1900); p. 167 - 167 ; (from Gmelin) View in Reaxys in further solvent(s), Irradiation (UV/VIS); decompn. by light and hydrolysis in dild. NH4(1+) soln.; dependence on wave length and mechanism discussed; vol. I: MVol.2; 158, page 597 - 599 ; (from Gmelin) View in Reaxys

H O

(v2) I–

Rx-ID: 26082981 View in Reaxys 128/310 Yield

Conditions & References in water, hydrolysis; with increasing of HI concn. and in presence of a precipitate reactn. to I3(1-); Daniltschenko, P.; Rawitsch, M.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 124 - 124 ; (from Gmelin) View in Reaxys in water, hydrolysis; with increasing of HI concn. and in presence of a precipitate reactn. to I3(1-); vol. I: MVol.1; 50, page 173 - 175 ; (from Gmelin) View in Reaxys

H S

H O

Rx-ID: 26082995 View in Reaxys 129/310 Yield

Conditions & References in further solvent(s), dissolving I2 in liquid H2S in an U-tube; decompn. with H2O;; condensation;

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vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Kemp; Inglis, J. (Phil. Mag. (2) 7 (1835) 444) View in Reaxys Odling, W.; Beschreibendes und theoretisches Handbuch der Chemie, aus dem Englischen uebersetzt von Oppenheim, A., Erlangen 1865, Bd. 1, S. 75 ; (from Gmelin) View in Reaxys O

Rx-ID: 26083105 View in Reaxys 130/310 Yield

Conditions & References

in water, with dild. and cooled soln. Stas, J. S.; Z. Ch. {2}; vol. 2; (1866); p. 522 - 540 View in Reaxys vol. S: MVol.B2; 1.5.3, page 498 - 514 View in Reaxys Stas, J. S.; Untersuchungen ueber die Gesetze der chemischen Proportionen. Ueber die Atomgewichte und ihre gegenseitigen Verhaeltnisse, Leipzig 1867, P. 64 ; (from Gmelin) View in Reaxys H

O 2 Cl

K+ Cl

Sn ClCl

Sn2ClCl

Rx-ID: 26083429 View in Reaxys 131/310 Yield

Conditions & References

>99, >99

in hydrogenchloride, byproducts: KCl, H2O; HCl acidic soln.; Karantassis, T.; Capatos, L.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 194; (1932); p. 1938 - 1938 ; (from Gmelin) View in Reaxys

>99, >99

in hydrogenchloride, byproducts: KCl, H2O; HCl acidic soln.; vol. I: MVol.2; 184, page 652 - 655 ; (from Gmelin) View in Reaxys

Rx-ID: 26083455 View in Reaxys 132/310 Yield

Conditions & References in ethanol, 24 hours standing; Delepine, M.; Arquet, M.; Bulletin des Sciences Pharmacologiques; vol. 35; (1928); p. 625 - 625 View in Reaxys vol. I: MVol.1; 37, page 149 - 151 ; (from Gmelin) View in Reaxys

OH OH

HO OH

Rx-ID: 26102439 View in Reaxys 133/310 Yield

Conditions & References in water, byproducts: potassium tartrate; formation of aq. HI soln.;; pptn. of potassium tartrate; Beyer, G.; Dinglers Polytech. J.; vol. 171; (1864); p. 466 - 466 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin)

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View in Reaxys

Rx-ID: 26138161 View in Reaxys 134/310 Yield

Conditions & References in gaseous matrix, Kinetics, large axcess of CF3I; carrier gas Ar; temp. 295-731 K, pressure 58.5-151.0 mbar; timeresolved resonance fluorescence Yuan, Jessie; Wells, Leah; Marshall, Paul; Chemical Physics Letters; vol. 297; (1998); p. 553 - 557 ; (from Gmelin) View in Reaxys

I 7

H O

AgI

Ag3I3

Rx-ID: 26146765 View in Reaxys 135/310 Yield

Conditions & References With water Berthelot, M.; Ann. Chim. Phys.; vol. 23; (1881); p. 85 - 93 View in Reaxys vol. Ag: MVol.B2; 8.44, page 461 - 461 ; (from Gmelin) View in Reaxys I

H 3Sb

Rx-ID: 26366743 View in Reaxys 136/310 Yield

Conditions & References in not given, at normal temp.; Husson, C.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 67; (1868); p. 56 - 56 View in Reaxys Jacobsen, O.; Ber.; vol. 20; (1887); p. 2000 - 2000 View in Reaxys vol. I: MVol.1; 55, page 182 - 183 ; (from Gmelin) View in Reaxys I

AsH 3

Rx-ID: 26366831 View in Reaxys 137/310 Yield

O –O

P H

K+

I O

O– K+

Rx-ID: 26390468 View in Reaxys 138/310 Yield

Conditions & References in water, byproducts: H2O; mechanism discussed; Vitali, D.; Bollettino Chimico Farmaceutico; vol. 38; (1899); p. 207

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View in Reaxys Hovorka, V.; Collection of Czechoslovak Chemical Communications; vol. 2; (1930); p. 561 - 561 View in Reaxys vol. I: MVol.2; 116, page 496 - 497 ; (from Gmelin) View in Reaxys Cr 4+ -1

O– –O O– – – I O O

2 Cr 3+ O

O–

3 O

K+

O–

Rx-ID: 26404321 View in Reaxys 139/310 Yield

Conditions & References With H2SO3, H2S, byproducts: K2SO4 Berg, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 104; (1887); p. 1514 1517 View in Reaxys vol. Cr: MVol.B; 271, page 600 - 602 ; (from Gmelin) View in Reaxys

BaI2

BaF2

Rx-ID: 26439314 View in Reaxys 140/310 Yield

Conditions & References in hydrogen fluoride, HF (liquid); reaction of BaI2 with liquid waterfree HF forms at normal temperature HI and BaF2; Fredenhagen, K.; Zeitschrift fuer Elektrochemie; vol. 37; (1931); p. 684 - 694 ; (from Gmelin) View in Reaxys in hydrogen fluoride vol. Ba: SVol.; 115, page 394 - 396 ; (from Gmelin) View in Reaxys

Ba2F2I2

Rx-ID: 26606701 View in Reaxys 141/310 Yield

Conditions & References With H2SO4, byproducts: BaSO4 Defacqz, E.; Ann. Chim. Phys.; vol. 1; (1904); p. 357 View in Reaxys Defacqz, E.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 138; (1904); p. 199 View in Reaxys vol. Ba: MVol.; 9.2, page 246 - 249 ; (from Gmelin) View in Reaxys

CuI 3OSb

O3Sb2

CuI

Rx-ID: 26648406 View in Reaxys 142/310 Yield

Conditions & References in water Vournazos, A. C.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 170; (1920); p. 1256 - 1259 ; (from Gmelin) View in Reaxys in water vol. Cu: MVol.B2; 154, page 970 - 971 ; (from Gmelin) View in Reaxys

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Rx-ID: 26651535 View in Reaxys 143/310 Yield

Conditions & References in water Kappeler, H.; Ber.; vol. 44; (1911); p. 3501 - 3501 View in Reaxys vol. I: MVol.2; 100, page 463 - 465 ; (from Gmelin) View in Reaxys

Na +

O–

Rx-ID: 8213676 View in Reaxys 144/310 Yield

Conditions & References T= 70 °C , Geschwindigkeit Simpson; Journal of the American Chemical Society; vol. 40; (1918); p. 680 View in Reaxys O

H+

O–

Rx-ID: 26082974 View in Reaxys 145/310 Yield

Conditions & References

0 %, 0 %

in water, byproducts: O; in presence of coal, sorption of formed O; no formation of HIO and HIO3 Daniltschenko, P.; Rawitsch, M.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 61; (1929); p. 124 - 124 ; (from Gmelin) View in Reaxys

0 %, 0 %

in water, byproducts: O; in presence of coal, sorption of formed O; no formation of HIO and HIO3 vol. I: MVol.1; 50, page 173 - 175 ; (from Gmelin) View in Reaxys

red

H O

Rx-ID: 26082997 View in Reaxys 146/310 Yield

Conditions & References in water, byproducts: PH4I; reaction in the beginning moderated by cooling, heating of vessel at the end of reaction; educts stoichiometry: 4P : 10I2 : 16H2O; lower amounts of iodine leads to formation of phosphorous acid, which after redn. to PH3 reacts with HI to PH4I;; HI passes over moist glass beads and moist red phosphorus to retain traces of iodine; HI absorbed in water gives concd. soln. which is free of iodine, but contains phosphorus compounds; Moles, E.; Miravalles, R.; Anales de la Real Sociedad Espanola de Fisica y Quimica; vol. 24; (1926); p. 362 - 362 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys

Rx-ID: 26083011 View in Reaxys 147/310 Yield

Conditions & References in water, equilibrium; Meyer, E. v.; Journal fuer Praktische Chemie (Leipzig); vol. 36; (1887); p. 294 - 294 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys

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O– O

Ba2+ O

O–

Rx-ID: 26083108 View in Reaxys 148/310 Yield

Conditions & References in water, in presence of BaI2 Bodroux, F.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 142; (1906); p. 279 280 View in Reaxys vol. S: MVol.B2; 1.5.3, page 498 - 514 ; (from Gmelin) View in Reaxys

O H

I–

P OH OH

I H

I P

P+

(v2)

P OH O

Rx-ID: 26083137 View in Reaxys 149/310 Yield

Conditions & References in neat (no solvent), heating an excess of H3PO3 with I2 on a water bath for a few h; Gustavson, G.; Bull. Acad. Imp. Sci. St. - Petersbourg; vol. 11; (1867); p. 299 - 301 View in Reaxys Gustavson, G.; J. prf. Ch.; vol. 101; (1867); p. 123 - 125 ; (from Gmelin) View in Reaxys in neat (no solvent), heating an excess of H3PO3 with I2 on a water bath for a few h; vol. P: MVol.C; 57, page 122 - 124 ; (from Gmelin) View in Reaxys

H O

Si Si HO OH OH OH

Rx-ID: 26084849 View in Reaxys 150/310 Yield

Conditions & References in water, byproducts: Si2(OH)6; decompn. of Si2I6 with water; Friedel, C.; Ladenburg, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 68; (1869); p. 922 - 922 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys

I BaO

BaI2

Rx-ID: 26097132 View in Reaxys 151/310 Yield

Conditions & References in neat (no solvent), BaO reacts with CHI3 under formation of BaI2 after some days; CHI3 decomposites under formation of I2 and HI at influence of light; Montignie, E.; Bulletin de la Societe Chimique de France; vol. 3; (1936); p. 704 - 705 ; (from Gmelin) View in Reaxys vol. Ba: SVol.; 65, page 287 - 289 ; (from Gmelin) View in Reaxys

OH HO

P OH O

Rx-ID: 26102396 View in Reaxys 152/310

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Yield

Conditions & References in further solvent(s), N2 atmosphere; refluxing of KI and H3PO4; sepn. in trap (263 K), freezing in trap (77 K), drying (over P2O5), removalof I2 by treatment with red phosphorus, further purifn. by freeze-thaw cycles between 193 and 77 K Nicholas, John E.; Vaghjiani, Ghanshyam; Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics; vol. 82; (1986); p. 737 - 744 ; (from Gmelin) View in Reaxys OH

B HO

Rx-ID: 26114133 View in Reaxys 153/310 Yield

Conditions & References in neat (no solvent), byproducts: caesium borates, H2O; cesium iodide and boric acid were heated together to temp. in the range 400-1000 °C;; nitrogen-matrix IR of the obtained vapor products; Nicholas; High temperature science; vol. 24; nb. 3; (1987); p. 125 - 171 ; (from Gmelin) View in Reaxys

BaI2

S OO

Rx-ID: 26149108 View in Reaxys 154/310 Yield

Conditions & References Glover, R. M.; Br. Assoc. Adv. Sci., Rep.; (1840); p. 75 - 75 View in Reaxys Glover, R. M.; L'Institut; vol. 8; nb. I; (1840); p. 387 - 387 View in Reaxys Glover, R. M.; Philosophical Magazine (1798-1977); vol. 19; (1841); p. 92 - 92 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys Stevenson, W.; Chem. News J. Ind. Sci.; vol. 36; (1877); p. 201 - 201 ; (from Gmelin) View in Reaxys

Rx-ID: 26366878 View in Reaxys 155/310 Yield

Conditions & References in water, equilibrium, mechanism discussed; Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1930); p. 2750 View in Reaxys vol. I: MVol.2; 156, page 592 - 594 ; (from Gmelin) View in Reaxys

-1

H O

S2Sn

-1 O2Sn

Rx-ID: 26366942 View in Reaxys 156/310 Yield

Conditions & References in water, reaction of iodine with an aq. SnS2 suspension; Joergensen, G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 28; (1901); p. 140 - 153 View in Reaxys vol. Sn: MVol.C2; 9.7.7.6, page 52 - 53 ; (from Gmelin) View in Reaxys

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Rx-ID: 26374147 View in Reaxys 157/310 Yield

Conditions & References in neat (no solvent, gas phase), other Radiation; I atoms obtained by microwave discharge of MeI in a quartz flow tube (pressure: 1E-4 Torr); not isolated, detn. by photoelectron spect. Wang, Dianxun; Li, Ying; Li, Sheng; Zhao, Hengqi; Chemical Physics Letters; vol. 222; (1994); p. 167 - 170 ; (from Gmelin) View in Reaxys

Rx-ID: 26433529 View in Reaxys 158/310 Yield

Conditions & References in gas, Kinetics, measurements between 1755 K - 2605 K Michael; Kumaran; Su; Lim; Chemical Physics Letters; vol. 319; nb. 1-2; (2000); p. 99 - 106 ; (from Gmelin) View in Reaxys

HSe

red

Rx-ID: 26433534 View in Reaxys 159/310 Yield

Conditions & References in not given, reaction in presenc of water; Hautefeuille, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 68; (1869); p. 1557 - 1557 View in Reaxys vol. Se: MVol.B; 8, page 14 - 15 ; (from Gmelin) View in Reaxys

3 H

N+ HH

I 3-I I I Y (v6) I

H N

(v3)

Rx-ID: 26751408 View in Reaxys 160/310 Yield

Conditions & References in neat (no solvent), heating Oppermann, H.; Herrera, S.; Huong, D. Q.; Ehrlich, S.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 621; (1995); p. 1808 - 1812 ; (from Gmelin) View in Reaxys

Rx-ID: 26082983 View in Reaxys 161/310 Yield

Conditions & References in gas, heating Tagawa, Hiroaki; Saijo, Hiroyuki; Kawabe, Katsuya; Endo, Takayuki; Tachibana, Chisato; et al.; Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan); vol. 63; (1988); p. 1253 - 1260 ; (from Gmelin) View in Reaxys

H O

Rx-ID: 26082994 View in Reaxys 162/310 Yield

Conditions & References in further solvent(s), byproducts: Et2SO2, CH2CHS(O)CH2CH3; I2 added to Et2SO-H2O; monitored by UV-vis spectra, conductometric and pH-metric study, argentometric titration and gas chromy.

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Markaryan; Grigoryan; Sarkisyan; Asatryan; Adamyan; Russian Journal of General Chemistry; vol. 76; nb. 11; (2006); p. 1801 - 1803 ; (from Gmelin) View in Reaxys H

I2Zn

OZn

Rx-ID: 26086474 View in Reaxys 163/310 Yield

Conditions & References in neat (no solvent), heating Tagawa, Hiroaki; Saijo, Hiroyuki; Kawabe, Katsuya; Endo, Takayuki; Tachibana, Chisato; et al.; Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan); vol. 63; (1988); p. 1253 - 1260 ; (from Gmelin) View in Reaxys

-1

MgO

-1 I2Mg

Rx-ID: 26187273 View in Reaxys 164/310 Yield

Conditions & References in neat (no solvent), 673 K; TG and DTA monitoring Mizuta, Susumu; Kumagai, Toshiya; Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan); vol. 63; (1988); p. 1241 - 1252 ; (from Gmelin) View in Reaxys

H Sb

I P

Rx-ID: 26343490 View in Reaxys 165/310 Yield

Conditions & References in neat (no solvent) Stock, A.; Guttmann, O.; Ber.; vol. 37; (1904); p. 885 - 900 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. P: MVol.C; 227, page 520 - 522 ; (from Gmelin) View in Reaxys

Br 2

I B

P I

P OH O

P HO

B HO

Rx-ID: 26359871 View in Reaxys 166/310 Yield

Conditions & References With H2O Tarible, J.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 132; (1901); p. 204 207 View in Reaxys vol. P: MVol.C; 269, page 618 - 620 ; (from Gmelin) View in Reaxys

H H

H O

Rx-ID: 26366192 View in Reaxys 167/310 Yield

Conditions & References in water, passing PH3 (prepared from Ca-phosphide and HCl) into an aq. suspension of I2 in a bulb under CO2 or N2 (agitation) until initial brown discoloration has vanished;; removal of H2O and HI by repeated distn. at 40 °C and 40 Torr and addn. of small amounts of water to the residue before 2nd and 3rd distillation;

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vol. P: MVol.C; 46, page 93 - 95 View in Reaxys Paris, R.; Tardy, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 223; (1946); p. 242 - 243 ; (from Gmelin) View in Reaxys

Ge I

Rx-ID: 26366792 View in Reaxys 168/310 Yield

Conditions & References in gas, Kinetics, 420-474 K; spectrophotometric monitoring, mass spectroscopy Dancaster; Walsh; Journal of Physical Chemistry; vol. 83; (1979); p. 578 ; (from Gmelin) View in Reaxys F

I P

BF2H 3O2

B2O6P2

Rx-ID: 26367452 View in Reaxys 169/310 Yield

Conditions & References in neat (no solvent), moderate heating; Long, L. H.; Dollimore, D.; Journal of the Chemical Society; (1951); p. 1608 - 1612 ; (from Gmelin) View in Reaxys in neat (no solvent), moderate heating; vol. P: MVol.C; 228, page 522 - 524 ; (from Gmelin) View in Reaxys

FeI2

FeO

Rx-ID: 26376684 View in Reaxys 170/310 Yield

S3Sb2

HgI 2

I2O5Sb4

Hg 3I2S2

Rx-ID: 26376734 View in Reaxys 171/310 Yield

Conditions & References in water Montignie, E.; Bulletin de la Societe Chimique de France; vol. 8; (1941); p. 202 - 202 ; (from Gmelin) View in Reaxys in water vol. Sb: MVol.B3; 1, page 497 - 499 ; (from Gmelin) View in Reaxys I

Al2O3

Rx-ID: 26377514 View in Reaxys 172/310 Yield

Conditions & References in neat (no solvent), heating

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Tagawa, Hiroaki; Saijo, Hiroyuki; Kawabe, Katsuya; Endo, Takayuki; Tachibana, Chisato; et al.; Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan); vol. 63; (1988); p. 1253 - 1260 ; (from Gmelin) View in Reaxys H

CuI 2

CuO

Rx-ID: 26378114 View in Reaxys 173/310 Yield

F2Ni

NiO

Rx-ID: 26378783 View in Reaxys 174/310 Yield

I2Mg

MgO

Rx-ID: 26378827 View in Reaxys 175/310 Yield

O– 2

K+

S O

K+ –O

O N

O–

–O

Rx-ID: 26436570 View in Reaxys 176/310 Yield

Conditions & References in not given, warming Strecker, A.; Liebigs Annalen der Chemie; vol. 148; (1868); p. 90 - 96 View in Reaxys vol. S: MVol.B2; 1.6.4, page 543 - 552 ; (from Gmelin) View in Reaxys H

H 3IMg2O3

MgO

Rx-ID: 26537594 View in Reaxys 177/310 Yield

Conditions & References in neat (no solvent), >553 K; TG and DTA monitoring, X-ray diffraction Mizuta, Susumu; Kumagai, Toshiya; Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan); vol. 63; (1988); p. 1241 - 1252 ; (from Gmelin) View in Reaxys

H O

I2Mg

HIMgO

Rx-ID: 26539682 View in Reaxys 178/310

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Yield

Conditions & References in neat (no solvent), 433-493 K; TG and DTA monitoring, X-ray diffraction Mizuta, Susumu; Kumagai, Toshiya; Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan); vol. 63; (1988); p. 1241 - 1252 ; (from Gmelin) View in Reaxys

H O

H 3IMg2O3

HIMgO

Rx-ID: 26539765 View in Reaxys 179/310 Yield

Conditions & References in neat (no solvent), 493-553 K; TG and DTA monitoring, X-ray diffraction Mizuta, Susumu; Kumagai, Toshiya; Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan); vol. 63; (1988); p. 1241 - 1252 ; (from Gmelin) View in Reaxys

(v1) I–

(v1) N+

H N

(v1) –(v5) I–– I Nd 3+ I (v1) – I (v1)

(v3)

Rx-ID: 27349116 View in Reaxys 180/310 Yield

Conditions & References in neat (no solvent), total decompn. at ca. 410°C Hennig; Oppermann; Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences; vol. 55; nb. 1; (2000); p. 65 - 73 ; (from Gmelin) View in Reaxys

(v1) I– (v1) I– – (v1) –I – Nd 3+ I (v1) I N+ (v6) H H (v1) –

3 H

(v1) I–

2 H

(v1)

H N

(v1) –(v5) I–– I Nd 3+ I (v1) I– (v1)

(v1) N+

Rx-ID: 27349120 View in Reaxys 181/310 Yield

Conditions & References in neat (no solvent), decompd. at ca. 440°C Hennig; Oppermann; Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences; vol. 55; nb. 1; (2000); p. 65 - 73 ; (from Gmelin) View in Reaxys

NH 2 H

N I–

H N

N+

Rx-ID: 29666421 View in Reaxys 182/310 Yield

Conditions & References

0 %, 0 %

in neat (no solvent), byproducts: 1-methyl-1,2,3-triazole, CH3I; under N2 or Ar; heated at 290°C; detd. by IR and mass spectra Chowdhury, Arindrajit; Thynell, Stefan T.; Thermochimica Acta; vol. 505; nb. 1-2; (2010); p. 33 - 40 ; (from Gmelin) View in Reaxys

N I–

N N+

H N

NH 2

Rx-ID: 29666422 View in Reaxys 183/310

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Yield

Conditions & References

0 %, 0 %

in neat (no solvent), byproducts: 1-methyl-1,2,4-triazole; under N2 or Ar; heated at 230-300°C; detd. by IR and mass spectra Chowdhury, Arindrajit; Thynell, Stefan T.; Thermochimica Acta; vol. 505; nb. 1-2; (2010); p. 33 - 40 ; (from Gmelin) View in Reaxys

HCl

H 2N

NH 2

Rx-ID: 26366576 View in Reaxys 184/310 Yield

Conditions & References Kinetics Bhattacharya, A. K.; Dhar, N. R.; Z. Anorg. Chem.; vol. 192; (1930); p. 210 ; (from Gmelin) View in Reaxys Kinetics, Irradiation (UV/VIS); 4700-8500 Å Bhattacharya, A. K.; Dhar, N. R.; Z. Anorg. Chem.; vol. 192; (1930); p. 210 ; (from Gmelin) View in Reaxys Kinetics, Irradiation (UV/VIS); 4700-8500 Å vol. NH4: MVol.2; 12, page 532 - 552 ; (from Gmelin) View in Reaxys Kinetics vol. NH4: MVol.2; 12, page 532 - 552 ; (from Gmelin) View in Reaxys

F H

Rx-ID: 26433139 View in Reaxys 185/310 Yield

Conditions & References in neat (no solvent), reaction with atomic H in a stream of He; determination by MS; Leipunskii, I. O.; Morozov, I. I.; Tal'roze, V. L.; Doklady Akademii Nauk SSSR; vol. 198; (1971); p. 547 - 550; Doklady Akademii Nauk SSSR; vol. 198; (1971); p. 1367 - 1370 View in Reaxys vol. C: MVol.D2; 4.2.4.4.5, page 319 - 320 ; (from Gmelin) View in Reaxys

Ca 2+ –O 2

H 2N

Ca 2+

NH 2

O–

O– S

S OH

S OO

Rx-ID: 26447128 View in Reaxys 186/310 Yield

Conditions & References in not given, reaction of Ca(IO3)2 with N2H6SO4-solution; Riegler, E.; Zeitschrift fuer Analytische Chemie; vol. 43; (1904); p. 205 - 214 ; (from Gmelin) View in Reaxys in not given, reaction of Ca(IO3)2 with N2H6SO4-solution; vol. Ca: MVol.B2; 140, page 628 - 630 ; (from Gmelin) View in Reaxys

H P

P+ HH

I–

I F

H 2P

Rx-ID: 26478114 View in Reaxys 187/310

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Yield

Conditions & References in neat (no solvent), reaction at 240°C in a closed tube; vol. C: MVol.D2; 4.2.4.4.7, page 322 - 323 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction at 240°C in a closed tube; Haszeldine, R. N.; West, B. O.; Journal of the Chemical Society; (1956); p. 3631 - 3637 ; (from Gmelin) View in Reaxys

Rx-ID: 26497383 View in Reaxys 188/310 Yield

Conditions & References in neat (no solvent), Kinetics, Irradiation (UV/VIS); flash photolysis of mixtures of H2S and IBr at 296 K in presence of quenchers;; not isolated; detection by atomic resonance spectroscopy; Boriev, I. A.; Gordon, E. B.; Efimenko, A. A.; Chemical Physics Letters; vol. 120; (1985); p. 486 - 490 ; (from Gmelin) View in Reaxys I

4.5

Sn– I

K+

Rx-ID: 26312443 View in Reaxys 189/310 Yield

Conditions & References 140-150°C Personne, J.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 54; (1862); p. 216 220 View in Reaxys vol. Sn: MVol.C3; 22.24, page 67 - 67 ; (from Gmelin) View in Reaxys

NH 2

Rx-ID: 26366295 View in Reaxys 190/310 Yield

Conditions & References Kinetics, byproducts: water Berthoud, A.; Porret, D.; Helvetica Chimica Acta; vol. 17; (1934); p. 32 ; (from Gmelin) View in Reaxys Kinetics, byproducts: water vol. NH4: MVol.2; 14, page 569 - 586 ; (from Gmelin) View in Reaxys

BaI2

Rx-ID: 26439315 View in Reaxys 191/310 Yield

Conditions & References Fredenhagen, H.; Cadenbach, G.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 146; (1930); p. 249 ; (from Gmelin) View in Reaxys vol. Ba: MVol.; 9.1, page 238 - 245 ; (from Gmelin) View in Reaxys

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FeI2

Rx-ID: 26588614 View in Reaxys 192/310 Yield

Conditions & References by heating; Jackson, C. L.; Derby, I. H.; American Chemical Journal; vol. 24; (1900); p. 23 - 23 View in Reaxys vol. Fe: MVol.B2; 13, page 338 - 341 ; (from Gmelin) View in Reaxys

H 2

O+ H

I I 2- I I Os (v6) I I

Rx-ID: 26836168 View in Reaxys 193/310 Yield

Conditions & References on standing slowly loses HI Ferguson, J. E.; Robinson, B. H.; Roper, W. R.; Journal of the Chemical Society; (1962); p. 2113 - 2115 View in Reaxys vol. Os: SVol.1; 3.6.3.1.1, page 161 - 161 ; (from Gmelin) View in Reaxys

H 2N

(v1) I– (v2) (v2) S– Cd 2+S– (v4) I– (v1)

NH +2

NH 2

H N

CdS

NH 2

Rx-ID: 26986703 View in Reaxys 194/310 Yield

Conditions & References in neat (no solvent), Kinetics, byproducts: melam, melem; thermolysis by heating at rate of 10 K/min up to ca. 800 K during TA/TG/DTA/DTG expt.; X-ray diffraction anal. Semenov; Naumov; Russian Journal of General Chemistry; vol. 71; nb. 4; (2001); p. 495 - 499 ; (from Gmelin) View in Reaxys HO

OH HO

S OO

Rx-ID: 26083113 View in Reaxys 195/310 Yield

Conditions & References Soubeiran, E.; J. Pharm.; vol. 13; (1827); p. 421 - 421 View in Reaxys Soubeiran, E.; Trommsdorff (2); vol. 16; nb. II; (1828); p. 132 - 132 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys

C 10H 16

Rx-ID: 26083315 View in Reaxys 196/310 Yield

Conditions & References iodine or iodine soln. dropped into pinene; one half of HI appears immediately, the other half on heating;; condensation, then passed over red phosphorus to remove I2; vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Frankforter, G. B.; AU1380951; (1919) ; (from Gmelin) View in Reaxys

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H 2N

NH 2

Rx-ID: 26083317 View in Reaxys 197/310 Yield

Conditions & References Bhattacharya, A. K.; Dhar, N. R.; Z. Anorg. Chem.; vol. 192; (1930); p. 210 ; (from Gmelin) View in Reaxys vol. NH4: MVol.2; 12, page 532 - 552 ; (from Gmelin) View in Reaxys

CsI

Rx-ID: 26100650 View in Reaxys 198/310 Yield

Conditions & References CsI reacts with liquid HF at 14-18 °C generating HI; Fredenhagen, H.; Cadenbach, G.; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 146; (1930); p. 249 View in Reaxys vol. Cs: MVol.2; 49, page 199 - 200 ; (from Gmelin) View in Reaxys

Rx-ID: 26138783 View in Reaxys 199/310 Yield

Conditions & References byproducts: H; Irradiation (UV/VIS); at ambient temp. only by extreme short waves; Bowen, E. J.; Journal of the Chemical Society; vol. 125; (1924); p. 1233 - 1233 View in Reaxys vol. I: MVol.2; 3, page 250 - 253 ; (from Gmelin) View in Reaxys

CaI 2

Rx-ID: 26149315 View in Reaxys 200/310 Yield

Conditions & References dry HCl passed over dry calcium iodide powder in three glass tubes in sequence; HCl stream should be sufficiently slow to avoid reversal of reaction due to heat of reaction;; HI passed into diluted aq. HI; vol. I: MVol.2; 8, page 262 - 263 View in Reaxys Patent; Guitton, J. A.; FR536274; (1921) ; (from Gmelin) View in Reaxys O–

O–

Rx-ID: 26366303 View in Reaxys 201/310 Yield

Conditions & References Goehring, M.; Stamm, H.; Angewandte Chemie; vol. 60; (1948); p. 147 - 155 View in Reaxys vol. S: MVol.B2; 1.5.3, page 498 - 514 ; (from Gmelin) View in Reaxys

–S

Rx-ID: 26366305 View in Reaxys 202/310 Yield

Conditions & References Goehring, M.; Stamm, H.; Angewandte Chemie; vol. 60; (1948); p. 147 - 155 View in Reaxys vol. S: MVol.B2; 1.5.3, page 498 - 514 ; (from Gmelin)

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View in Reaxys O

CaI 2

Rx-ID: 26452386 View in Reaxys 203/310 Yield

Conditions & References decompn. in presence of CO2; Neugebauer, H.; Brunner, K.; Pharmazeutische Zeitung; vol. 82; (1937); p. 799 - 800 View in Reaxys vol. Ca: MVol.B1; 40, page 100 - 102 ; (from Gmelin) View in Reaxys I

IOSb

Rx-ID: 26607067 View in Reaxys 204/310 Yield

Conditions & References Vournazos, A. C.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 170; (1920); p. 1256 - 1256 ; (from Gmelin) View in Reaxys vol. Sb: MVol.B3; 1, page 497 - 499 ; (from Gmelin) View in Reaxys

I I

air

Rx-ID: 8261648 View in Reaxys 205/310 Yield

Conditions & References Janz; Danyluk; Journal of the American Chemical Society; vol. 81; (1959); p. 3850,3851 View in Reaxys

Rx-ID: 26083227 View in Reaxys 206/310 Yield

Conditions & References Kinetics, Irradiation (UV/VIS); higher I2-concentration; Bonhoeffer, K. F.; Farkas, L.; Z. phys. Ch.; vol. 132; (1928); p. 235 - 235 View in Reaxys vol. I: MVol.2; 3, page 250 - 253 ; (from Gmelin) View in Reaxys

HS( 1-)

I(1-)

S(1-)

–S

Rx-ID: 26109511 View in Reaxys 207/310 Yield

Conditions & References further products; reaction studied by means of a TOF-MS at target gas pressures between 1E-4 and 1E-5 Torr; temp. 296-300 K Rffaey; Journal of Chemical Physics; vol. 65; (1976); p. 2002 View in Reaxys vol. S: SVol.4a/b; 1.3.8.3, page 195 - 200 ; (from Gmelin) View in Reaxys

N O–

2 Na + O–

O H

H O

H+

N+

O– N

(v2)

O–

Rx-ID: 26349501 View in Reaxys 208/310

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Yield

Conditions & References in water, Kinetics, separately equilibrated (35°C) solns. of Na2N2O2 in one flask and acetate buffer and iodine in another are flushed with N2, Na2N2O2 soln. is added to second flask; N2 and NO are collected over water, N2, N2O and NO over water saturated with N2O, N2 over water saturated with FeSO4, N2 and N2O over water saturated with N2O and FeSO4; spectrophotometrical detn. Bhatnagar, Pankaj; Mittal, Rama K.; Gupta, Yugal K.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1990); p. 3669 - 3674 ; (from Gmelin) View in Reaxys

Mg2+

H 2O O–

O–

S O

I2Mg

HIMgO

Rx-ID: 26360683 View in Reaxys 209/310 Yield

Conditions & References byproducts: H2O; heated in N2 atm. at 200°C Mizuta, Susuma; Kumagai, Toshiya; Chemistry Letters; (1982); p. 81 - 82 ; (from Gmelin) View in Reaxys

(v1)

Rx-ID: 26433531 View in Reaxys 210/310 Yield

Conditions & References Kinetics, Irradiation (UV/VIS); React. of iodine atoms with HO2 radicals, produced by modulated-photolysis (UV spectroscopy), at 50 Torr and 283-353 K. Jenkin, M. E.; Cox, R. A.; Mellouki, A.; Bras, G. Le; Poulet, G.; Journal of Physical Chemistry; vol. 94; nb. 7; (1990); p. 2927 - 2934 ; (from Gmelin) View in Reaxys Kinetics, React. (298 K) of iodine atoms with HO2 radicals, both generated (separately) in reactor equipped with double microwave discharge (discharge-flow/EPR technique). Jenkin, M. E.; Cox, R. A.; Mellouki, A.; Bras, G. Le; Poulet, G.; Journal of Physical Chemistry; vol. 94; nb. 7; (1990); p. 2927 - 2934 ; (from Gmelin) View in Reaxys H

Mg2+

H 2O O–

O–

H 3IMg2O3

S O

HIMgO

Rx-ID: 26507114 View in Reaxys 211/310 Yield

Conditions & References byproducts: H2O; heated in N2 atm. at 240°C Mizuta, Susuma; Kumagai, Toshiya; Chemistry Letters; (1982); p. 81 - 82 ; (from Gmelin) View in Reaxys

H O

S– K+

Rx-ID: 26082993 View in Reaxys 212/310 Yield

Conditions & References byproducts: H2SO4, KI Rupp, E.; Schiedt, A.; Ber.; vol. 35; (1902); p. 2192 - 2192 View in Reaxys vol. I: MVol.2; 5, page 256 - 257 ; (from Gmelin) View in Reaxys

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NH +4

I–

O5P2

INa

Rx-ID: 26083845 View in Reaxys 213/310 Yield

Conditions & References

>99

byproducts: NaNH4P2O6; absolute dry NH4I, NaI and P2O5 mixed, vessel evacuated; water previously cooled with alcohol-carbondioxide distills over and initiates reaction without rise of temp.; HI washed with saturated HI-soln. free of iodine, remaining iodine and main amount of water removed in a tube cooled to -40°C, dried by P2O5; gives very pure, condensable gaseous HI; Moles, E.; Miravalles, R.; Anales de la Real Sociedad Espanola de Fisica y Quimica; vol. 24; (1926); p. 367 - 367 View in Reaxys vol. I: MVol.2; 7, page 259 - 261 ; (from Gmelin) View in Reaxys

–O

-2

O–

(v1)

2 Na +

(v1)

S O

Rx-ID: 26090349 View in Reaxys 214/310 Yield

Conditions & References Fialkov, Y. A.; Kagan, F. E.; Ukrainskii Khimicheskii Zhurnal (Russian Edition); vol. 18; (1952); p. 55 - 63 View in Reaxys vol. S: MVol.B2; 1.6.2.6, page 522 - 524 ; (from Gmelin) View in Reaxys

–O

Cl I

2 Na +

-2

O–

(v1)

2 Na +

(v1)

S O

Rx-ID: 26166907 View in Reaxys 215/310 Yield

Mg2+

H 2O O–

(v1)

O– S

H 3IMg2O3

MgO

Mg2+

(v1)

S OO

Rx-ID: 26174116 View in Reaxys 216/310 Yield

Conditions & References byproducts: H2O; heated in N2 atm. at 350°C Mizuta, Susuma; Kumagai, Toshiya; Chemistry Letters; (1982); p. 81 - 82 ; (from Gmelin) View in Reaxys

Hg 2I2

(v2)

Rx-ID: 26390260 View in Reaxys 217/310 Yield

Conditions & References Esteve, E.; Chemiker-Zeitung; vol. 35; (1911); p. 1152 - 1153 View in Reaxys vol. Hg: MVol.B2; 203, page 829 - 831 ; (from Gmelin) View in Reaxys

(v3)

(v2) OH 2(v1) (v1) (v3) I– –I I– 2+ 2 2+ 2+ H 2O MgOH Hg OH 2– (v4) – H 2O (v3) Hg(v4) I (v6) I (v3) I– (v1) OH 2 (v1) (v2)

H O

MgO

HgI 2

(v3)

Rx-ID: 27072753 View in Reaxys 218/310 Yield

Conditions & References decompn. at 103°C

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Brodersen, K.; Pezzei, G.; Thiele, G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 502; (1983); p. 209 - 214 ; (from Gmelin) View in Reaxys

I I

Rx-ID: 5817683 View in Reaxys 219/310 Yield

Conditions & References T= 192 °C , die thermische Dissoziation beginnt Kahan; Journal of the Chemical Society; vol. 93; (1908); p. 140 View in Reaxys Blitz-Photolyse.Photolysis Thrush; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 243; (1957); p. 555,558 View in Reaxys

Rx-ID: 6074554 View in Reaxys 220/310 Yield

Conditions & References T= 0.1 °C , Geschwindigkeit.Hydrolysis Cooper; Hughes; Journal of the Chemical Society; (1937); p. 1186 View in Reaxys T= 25 °C , Geschwindigkeit.Hydrolysis Cooper; Hughes; Ingold; Journal of the Chemical Society; (1937); p. 1281 View in Reaxys Cooper; Hughes; Journal of the Chemical Society; (1937); p. 1186 View in Reaxys T= 5 - 45 °C , Geschwindigkeit.Hydrolysis Shorter; Hinshelwood; Journal of the Chemical Society; (1949); p. 2416 View in Reaxys O

H O

CH3COCH2I Rx-ID: 6211324 View in Reaxys 221/310

Yield

Conditions & References T= 20 °C , Equilibrium constant Bell; Gelles; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 210; (1952); p. 310,318,319 View in Reaxys T= 25 °C , Equilibrium constant Bell; Gelles; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 210; (1952); p. 310,318,319 View in Reaxys T= 30 °C , Equilibrium constant Bell; Gelles; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 210; (1952); p. 310,318,319 View in Reaxys

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H 2 H+ H

N+ HH

H 2N

NH 2

2 NH +O 4

O 3

O–

S OO

H O

Rx-ID: 26404715 View in Reaxys 222/310 Yield

Conditions & References Riegler, E.; Bl. Chimistes Sucrerie, Distillerie; vol. 24; (1906); p. 531 ; (from Gmelin) View in Reaxys vol. NH4: MVol.2; 12, page 532 - 552 ; (from Gmelin) View in Reaxys

I I

Rx-ID: 5817722 View in Reaxys 223/310 Yield

Conditions & References Photolysis Bunbury et al.; Journal of the American Chemical Society; vol. 78; (1956); p. 6228 View in Reaxys -2 (v1)

Fe 2O3

Fe 2+ (v1)

S OO

Rx-ID: 26072279 View in Reaxys 224/310 Yield

Conditions & References Tagawa, Hiroaki; Saijo, Hiroyuki; Kawabe, Katsuya; Endo, Takayuki; Tachibana, Chisato; et al.; Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan); vol. 63; (1988); p. 1253 - 1260 ; (from Gmelin) View in Reaxys

H N

N+

N+ I–

I–

Rx-ID: 38249757 View in Reaxys 225/310 Yield

Conditions & References T= 25 °C , Kinetics, Mechanism, Thermodynamic data Bowler, Jeannette T.; Wong, Freeman M.; Gronert, Scott; Keeffe, James R.; Wu, Weimings; Organic and Biomolecular Chemistry; vol. 12; nb. 32; (2014); p. 6175 - 6180 View in Reaxys

H O

CH3COCHICOCH3 Rx-ID: 6211330 View in Reaxys 226/310

Yield

Conditions & References T= 25 °C , Equilibrium constant Bell; Gelles; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 210; (1952); p. 310,318,319 View in Reaxys

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H O

CH3-CHI-NO2

Rx-ID: 6727008 View in Reaxys 227/310 Yield

Conditions & References T= 25 °C , Rate constant Bell; Gelles; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 210; (1952); p. 310,318,319 View in Reaxys

H 2N

O H

H O

CH3CONHI

Rx-ID: 6727019 View in Reaxys 228/310 Yield

Rx-ID: 7053896 View in Reaxys 229/310 Yield

Conditions & References T= 190 °C Alechin; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 15; (1883); p. 175 View in Reaxys

1-iodo-1-nitro-propane

Rx-ID: 5817685 View in Reaxys 230/310 Yield

I I

Rx-ID: 5817719 View in Reaxys 231/310 Yield

Conditions & References T= -190 °C , 253 nm.Photolysis Jones et al; Journal of Physical Chemistry; vol. 62; (1958); p. 9,14 View in Reaxys

hydrogen

I I

Rx-ID: 7053903 View in Reaxys 232/310 Yield

Conditions & References T= 140 °C Moissan; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 113; (1891); p. 20 View in Reaxys

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N N

HO H

N N

OH N

Rx-ID: 5688231 View in Reaxys 233/310 Yield

Conditions & References T= 125 °C Klason; Journal fuer Praktische Chemie (Leipzig); vol. <2>34; (1886); p. 157 View in Reaxys

Rx-ID: 6680031 View in Reaxys 234/310 Yield

Conditions & References T= 100 °C Niederist; Justus Liebigs Annalen der Chemie; vol. 196; (1879); p. 356; Justus Liebigs Annalen der Chemie; vol. 186; (1877); p. 393 View in Reaxys I

OH H

Rx-ID: 6683080 View in Reaxys 235/310 Yield

Conditions & References T= 100 °C , im Rohr Niederist; Justus Liebigs Annalen der Chemie; vol. 186; (1877); p. 391 View in Reaxys

O H

H O

Rx-ID: 7053905 View in Reaxys 236/310 Yield

I Cl

H O

chloroethylene oxide

Rx-ID: 7071558 View in Reaxys 237/310 Yield

Conditions & References T= 150 °C Ssabanejew; Justus Liebigs Annalen der Chemie; vol. 216; (1883); p. 267,279; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 17; (1885); p. 175 View in Reaxys

phosphine

I F

H 2P

phosphorus (III)-iodide Rx-ID: 7084807 View in Reaxys 238/310

Yield

Conditions & References T= 240 °C Haszeldine; West; Journal of the Chemical Society; (1956); p. 3631,3636 View in Reaxys

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N N

HO H

N OH

Rx-ID: 5688232 View in Reaxys 239/310 Yield

Conditions & References T= 125 °C Klason; Journal fuer Praktische Chemie (Leipzig); vol. <2>34; (1886); p. 157 View in Reaxys

C O

H2 Rx-ID: 6728568 View in Reaxys 240/310

Yield

Conditions & References 2537, 3130, 3650 Angstroem.Photolysis Gorin; Journal of Chemical Physics; vol. 7; (1939); p. 258 View in Reaxys

Rx-ID: 7057720 View in Reaxys 241/310 Yield

Conditions & References T= 80 °C , im Rohr Traube,J.; Neuberg,O.; Chemische Berichte; vol. 24; (1891); p. 520 View in Reaxys I I

Rx-ID: 6680029 View in Reaxys 242/310 Yield

Conditions & References Blitzphotolyse (150 bis 180 nm).Photolysis Thrush; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 243; (1957); p. 555,558 View in Reaxys

lead oxide

Rx-ID: 7062699 View in Reaxys 243/310 Yield

Conditions & References beim Destillieren Woehlk; Journal fuer Praktische Chemie (Leipzig); vol. <2>61; (1900); p. 206 View in Reaxys Beilstein; Justus Liebigs Annalen der Chemie; vol. 122; (1862); p. 372 View in Reaxys Wislicenus; Justus Liebigs Annalen der Chemie; vol. 166; (1873); p. 15; Justus Liebigs Annalen der Chemie; vol. 174; (1874); p. 286,297 View in Reaxys

H O

Rx-ID: 6680030 View in Reaxys 244/310

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Yield

Conditions & References untersucht wurde der zeitliche Verlauf sowie die Produktausbeute bei Einwirkung von γ-Strahlen Meshitsuka; Burton; Radiation Research; vol. 10; (1959); p. 499 View in Reaxys Cl

alcoholic KOH-solution

Rx-ID: 7053897 View in Reaxys 245/310 Yield

Conditions & References van de Walle; Henne; Bulletin de la Classe des Sciences, Academie Royale de Belgique; vol. <5>11; (1925); p. 366; Chem. Zentralbl.; vol. 97; nb. I; (1926); p. 870,2450 View in Reaxys

alcoholic KOH-solution

Rx-ID: 7053898 View in Reaxys 246/310 Yield

alcoholic KOH-solution

Rx-ID: 7053899 View in Reaxys 247/310 Yield

Conditions & References Reagiert ca. 200 mal rascher als das feste Isomere Chavanne; Vos; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 158; (1914); p. 1582 View in Reaxys

alcoholic KOH

Rx-ID: 7053900 View in Reaxys 248/310 Yield

Conditions & References Monti; Gazzetta Chimica Italiana; vol. 60; (1930); p. 777,778 View in Reaxys

Rx-ID: 7058492 View in Reaxys 249/310 Yield

Conditions & References empfindlich gegen Feuchtigkeit, zerlegt Guthrie; Justus Liebigs Annalen der Chemie; vol. 103; (1857); p. 335 View in Reaxys Thiele; Haakh; Justus Liebigs Annalen der Chemie; vol. 369; (1909); p. 144 View in Reaxys

Ag2O

C2H3Br Rx-ID: 7070494 View in Reaxys 250/310

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Yield

Conditions & References Pfaundler; Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften; (1865); p. 483 View in Reaxys

alcoholic potash

C2H3Br

Rx-ID: 7070495 View in Reaxys 251/310 Yield

Conditions & References Pfaundler; Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften; (1865); p. 483 View in Reaxys

I Cl

alcoholic potash

C2H3Cl

Rx-ID: 7070496 View in Reaxys 252/310 Yield

Conditions & References Simpson; Justus Liebigs Annalen der Chemie; vol. 125; (1863); p. 102 View in Reaxys

alcoholic potash

C 2H 3I

Rx-ID: 7070500 View in Reaxys 253/310 Yield

Conditions & References Gustavson; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 6; (1874); p. 164; Chemische Berichte; vol. 7; (1874); p. 731 View in Reaxys

Cl I

alcoholic potash

CH2:CClCH3

Rx-ID: 7071214 View in Reaxys 254/310 Yield

Conditions & References Sorokin; ; (1871); p. 264 View in Reaxys

alcoholic potash

CH3CI:CH2

Rx-ID: 7071329 View in Reaxys 255/310 Yield

Conditions & References Sorokin; ; (1871); p. 264 View in Reaxys

heptylene Rx-ID: 7077099 View in Reaxys 256/310

Yield

Conditions & References Sieden unter gewoehnlichem Druck Venable; Chemische Berichte; vol. 13; (1880); p. 1651 View in Reaxys

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O OH

S–

(v6)

Na +

Rx-ID: 7916271 View in Reaxys 257/310 Yield

Conditions & References T= 200 °C , im geschlossenen Rohr Otto; Engelhardt; Chemische Berichte; vol. 21; (1888); p. 654 View in Reaxys

OH P+

OH – OH I

Rx-ID: 8213677 View in Reaxys 258/310 Yield

Conditions & References beim Aufbewahren de Girard; Annales de Chimie (Cachan, France); vol. <6>2; (1884); p. 11 View in Reaxys

KOH-solution

Rx-ID: 8213682 View in Reaxys 259/310 Yield

Conditions & References Tiemann; Chemische Berichte; vol. 30; (1897); p. 597 View in Reaxys Behal; Bulletin de la Societe Chimique de France; vol. <3> 13; (1895); p. 836; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 120; (1895); p. 927 View in Reaxys

potash

Rx-ID: 6074556 View in Reaxys 260/310 Yield

Conditions & References Butlerow; Justus Liebigs Annalen der Chemie; vol. 144; (1867); p. 6; ; (1867); p. 362 View in Reaxys

silver oxide

Rx-ID: 6074557 View in Reaxys 261/310 Yield

Conditions & References Butlerow; Justus Liebigs Annalen der Chemie; vol. 144; (1867); p. 6; ; (1867); p. 362 View in Reaxys HO

S OO

Rx-ID: 7053907 View in Reaxys 262/310 Yield

Conditions & References Chattaway; Wadmore; Journal of the Chemical Society; vol. 81; (1902); p. 200 View in Reaxys Strecker; Justus Liebigs Annalen der Chemie; vol. 148; (1868); p. 92 View in Reaxys v.Meyer,E.; Journal fuer Praktische Chemie (Leipzig); vol. <2>36; (1887); p. 298 View in Reaxys

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alcoholic KOH-solution

Rx-ID: 7062698 View in Reaxys 263/310 Yield

Conditions & References v.Schneider; Erlenmeyer; Chemische Berichte; vol. 3; (1870); p. 340 View in Reaxys

KOH-solution

H Cl

Rx-ID: 7065075 View in Reaxys 264/310 Yield

Conditions & References Kling; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 137; (1903); p. 758; Bulletin de la Societe Chimique de France; vol. <3>31; (1904); p. 17 View in Reaxys

hexylene

Rx-ID: 7077385 View in Reaxys 265/310 Yield

Conditions & References Destillation Friedel; Silva; Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften; (1873); p. 340; Chemische Berichte; vol. 6; (1873); p. 146,826 View in Reaxys

sulfur

Rx-ID: 7087330 View in Reaxys 266/310 Yield

Conditions & References Chattaway; Wadmore; Journal of the Chemical Society; vol. 81; (1902); p. 200 View in Reaxys v.Meyer,E.; Journal fuer Praktische Chemie (Leipzig); vol. <2>36; (1887); p. 298 View in Reaxys

N H

H+

H O

-1 I

(v3)

Hg I

Rx-ID: 8213678 View in Reaxys 267/310 Yield

Conditions & References beim Kochen Barnett; Smiles; Journal of the Chemical Society; vol. 97; (1910); p. 984 View in Reaxys

H 2N

Rx-ID: 8213679 View in Reaxys 268/310 Yield

Conditions & References Ingle; Chem. Zentralbl.; vol. 73; nb. I; (1902); p. 1401 View in Reaxys

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Ag2O

Sn O

meta tin oic acid

Rx-ID: 8280126 View in Reaxys 269/310 Yield

Conditions & References Emmert; Eller; Chemische Berichte; vol. 44; (1911); p. 2331 View in Reaxys O

aq. barium hydroxide solution

Sn O

O O

meta tin oic acid

Rx-ID: 8280127 View in Reaxys 270/310 Yield

Conditions & References Emmert; Eller; Chemische Berichte; vol. 44; (1911); p. 2331 View in Reaxys O

KOH-solution

Sn O

O O

meta tin oic acid

Rx-ID: 8280128 View in Reaxys 271/310 Yield

Conditions & References Emmert; Eller; Chemische Berichte; vol. 44; (1911); p. 2331 View in Reaxys O N N

N-methyl-granatenine

Rx-ID: 8282852 View in Reaxys 272/310 Yield

Conditions & References Ciamician; Silber; Gazzetta Chimica Italiana; vol. 24 I; (1894); p. 127,128; Chemische Berichte; vol. 26; (1893); p. 2743,2744 View in Reaxys

H 2N

N N

alkali

I 2H

sulfur

NH 2

Rx-ID: 8288237 View in Reaxys 273/310 Yield

Conditions & References Reissert; Grube; Chemische Berichte; vol. 42; (1909); p. 3712 View in Reaxys

OH O

HO SH

Rx-ID: 5817684 View in Reaxys 274/310 Yield

Conditions & References Hellstroem; View in Reaxys Hellstroem; Arkiv foer Kemi; vol. 13A; nb. 6; (1939); p. 2,6; Chem. Zentralbl.; vol. 110; nb. I; (1939); p. 1742 View in Reaxys

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H P

P+

I–

Rx-ID: 5817811 View in Reaxys 275/310 Yield

Conditions & References Doerken; Chemische Berichte; vol. 21; (1888); p. 1507 View in Reaxys

N H

Rx-ID: 5818280 View in Reaxys 276/310 Yield

Conditions & References Steinkopf; Bessaritsch; Journal fuer Praktische Chemie (Leipzig); vol. <2>109; (1925); p. 259 View in Reaxys

Rx-ID: 5853492 View in Reaxys 277/310 Yield

Conditions & References in saurer wss.Loesung Hellstroem,N.; View in Reaxys Hellstroem; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 157; (1931); p. 249-265,163<1933>33-47 View in Reaxys

SH O

NH 2

S S

Rx-ID: 5853493 View in Reaxys 278/310 Yield

–

Ag+

Rx-ID: 6074555 View in Reaxys 279/310 Yield

Conditions & References Puchot; Annales de Chimie (Cachan, France); vol. <5>38; p. 545 View in Reaxys

H O

zinc

Rx-ID: 6074558 View in Reaxys 280/310 Yield

Conditions & References Butlerow; Justus Liebigs Annalen der Chemie; vol. 144; (1867); p. 6; ; (1867); p. 362 View in Reaxys

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Rx-ID: 6188112 View in Reaxys 281/310 Yield

Conditions & References Dobbin; Journal of the Chemical Society; vol. 37; (1880); p. 246 View in Reaxys

Rx-ID: 7053901 View in Reaxys 282/310 Yield

Conditions & References Palazzo; Gazzetta Chimica Italiana; vol. 78; (1948); p. 652 View in Reaxys

H O

Rx-ID: 7053902 View in Reaxys 283/310 Yield

Conditions & References Bauer,K.; Justus Liebigs Annalen der Chemie; vol. 220; (1883); p. 163 View in Reaxys

Rx-ID: 7061175 View in Reaxys 284/310 Yield

Conditions & References Niederist; Justus Liebigs Annalen der Chemie; vol. 196; (1879); p. 356; Justus Liebigs Annalen der Chemie; vol. 186; (1877); p. 393 View in Reaxys

sodium carbonate

Rx-ID: 7062700 View in Reaxys 285/310 Yield

Conditions & References Woehlk; Journal fuer Praktische Chemie (Leipzig); vol. <2>61; (1900); p. 206 View in Reaxys

alcoholic potash

I Br

Rx-ID: 7065854 View in Reaxys 286/310 Yield

Conditions & References beim Erwaermen Lagermark; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 5; (1873); p. 334 View in Reaxys

HO I

I I

oxygen

Rx-ID: 7084088 View in Reaxys 287/310 Yield

Conditions & References Elektrolyse des Natriumsalzes; weitere Produkte:Kohlenoxyd und Kohlendioxyd.Electrolysis Kaufler; Herzog; Chemische Berichte; vol. 42; (1909); p. 3868 View in Reaxys

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concentrated aqueous silver nitrate

Rx-ID: 7448177 View in Reaxys 288/310 Yield

Conditions & References Tiffeneau; Annales de Chimie (Cachan, France); vol. <8> 10; (1907); p. 188,355 View in Reaxys

yellow mercury oxide

Rx-ID: 7448178 View in Reaxys 289/310 Yield

Conditions & References Tiffeneau; Annales de Chimie (Cachan, France); vol. <8> 10; (1907); p. 188,355 View in Reaxys I

I H

Rx-ID: 8213680 View in Reaxys 290/310 Yield

Conditions & References Dehn; Wilcox; American Chemical Journal; vol. 35; (1906); p. 24 View in Reaxys

I O

natrium carbonate

Rx-ID: 8213681 View in Reaxys 291/310 Yield

Conditions & References Fittig; Binder; Justus Liebigs Annalen der Chemie; vol. 195; (1879); p. 132 View in Reaxys

O H

AsH

(v5)

Rx-ID: 8213683 View in Reaxys 292/310 Yield

Conditions & References La Coste; Justus Liebigs Annalen der Chemie; vol. 208; (1881); p. 16 View in Reaxys

O N+ H

potassium carbonate

I–

O O

Rx-ID: 8213684 View in Reaxys 293/310 Yield

Conditions & References Willstaetter; Chemische Berichte; vol. 30; (1897); p. 711,712; Chem. Zentralbl.; vol. 69; nb. I; (1898); p. 228 View in Reaxys

I O

H O

O HO

Rx-ID: 8255561 View in Reaxys 294/310 Yield

Conditions & References Fittig; Binder; Justus Liebigs Annalen der Chemie; vol. 195; (1879); p. 132 View in Reaxys

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concentrated KOH-solution

I–

N+

Rx-ID: 8261962 View in Reaxys 295/310 Yield

Conditions & References Claus; Rautenberg; Chemische Berichte; vol. 14; (1881); p. 621 View in Reaxys

meta tin oic acid

Rx-ID: 8280124 View in Reaxys 296/310 Yield

Conditions & References Emmert; Eller; Chemische Berichte; vol. 44; (1911); p. 2331 View in Reaxys O

meta tin oic acid

Rx-ID: 8280125 View in Reaxys 297/310 Yield

Conditions & References Emmert; Eller; Chemische Berichte; vol. 44; (1911); p. 2331 View in Reaxys

H 2N

NH4I

sulfur Rx-ID: 6220095 View in Reaxys 298/310

Yield

Conditions & References Ray; Dey; Journal of the Chemical Society; vol. 109; (1916); p. 700 View in Reaxys

I Cl

S OO

Rx-ID: 7053904 View in Reaxys 299/310 Yield

Conditions & References Sorokin; ; (1870); p. 519 View in Reaxys

O S

S S

Rx-ID: 7058100 View in Reaxys 300/310 Yield

Conditions & References Kinetics Holmberg; Journal fuer Praktische Chemie (Leipzig); vol. <2>135; p. 59,83,86 View in Reaxys

O S

S OH

S S

Rx-ID: 7058660 View in Reaxys 301/310 Yield

Conditions & References Kinetics

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Holmberg; Journal fuer Praktische Chemie (Leipzig); vol. <2>135; (1932); p. 60; ; nb. 103; (1930); p. 13; Chem. Zentralbl.; vol. 101; nb. II; (1930); p. 2770 View in Reaxys

I O

H 2N

hydriodide of hydrazine

Rx-ID: 7081871 View in Reaxys 302/310 Yield

Conditions & References Curtius; Pflug; Journal fuer Praktische Chemie (Leipzig); vol. <2> 44; (1891); p. 540 View in Reaxys

H 2N

OH HO

I–

N+

H N

zinc

S OO

Rx-ID: 8258009 View in Reaxys 303/310 Yield

Conditions & References Fischer,E.; Justus Liebigs Annalen der Chemie; vol. 199; (1879); p. 309 View in Reaxys

O N O

I–

P+ O

O P

Rx-ID: 8265183 View in Reaxys 304/310 Yield

Conditions & References Michaelis; Kaehne; Chemische Berichte; vol. 31; (1898); p. 1051 View in Reaxys

Rx-ID: 5817721 View in Reaxys 305/310 Yield

Conditions & References Irradiation Emschwiller; Annales de Chimie (Cachan, France); vol. <10>17; (1932); p. 459,467; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 191; (1930); p. 208 View in Reaxys

Rx-ID: 7053906 View in Reaxys 306/310 Yield

Conditions & References Hellstroem; Arkiv foer Kemi; vol. 13A; nb. 6; (1939); p. 2,6; Chem. Zentralbl.; vol. 110; nb. I; (1939); p. 1742 View in Reaxys

O H

HO SH

S S

Rx-ID: 7058921 View in Reaxys 307/310

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Yield

Conditions & References Kinetics Hellstroem; Arkiv foer Kemi; vol. 13A; nb. 6; (1939); p. 2,6; Chem. Zentralbl.; vol. 110; nb. I; (1939); p. 1742 View in Reaxys

Rx-ID: 24377259 View in Reaxys 308/310 Yield 83.8%

Conditions & References 3 : EXAMPLE 3 EXAMPLE 3 N-3-hydroxypropyl-5'-methoxylaudanosinium iodide (50 g, 72.5percent trans, 26.7percent cis) was dissolved in 337 mL of hot water. The solution was cooled to 25° for 3 hours. The mixture was filtered to yield 15.5 g of cis iodide (83.8percent cis--purified (>99percent cis) by recrystallization from methanol). The filtrate was concentrated to dryness in vacuo to yield the trans iodide (95.6percent trans by HPLC). The crude trans iodide was purified by recrystallization from dry acetonitrile (2.5 mL CH3 CN/g) to yield 99.6percent trans iodide (71percent recovery). In similar experiments 94.5percent trans iodide gave 99.3percent pure trans (67percent recovery) and 97percent trans gave 99.6percent trans (86percent recovery). Trans iodide was also purified by trituration with acetone (3 mL/g): 92.7percent trans gave 97.7percent trans (95percent recovery). Ethanol (95percent, 4 mL/g) could also be used as a recrystallization solvent: 97.7percent trans gave 99.6percent trans (61percent recovery). Patent; Burroughs Wellcome Co.; US4491665; (1985); (A1) English View in Reaxys hydrobromic acid hydroiodic acid iron trichloride zirconium tetrachloride hydrofluoroboric acid Patent; American Cyanamid Company; US5371215; (1994); (A1) English View in Reaxys Patent; American Cyanamid Company; US5189158; (1993); (A1) English View in Reaxys 42.A : N,N'-[[[4-(Aminocarbonyl)phenyl]imino]methylene]bis[benzamide] (A) A mixture of 3.22 g of N-benzoylcarbamimidothioic acid, methyl ester, monohydriodide (Ex. 3), 1.36 g of 4-aminobenzamide and 150 ml of isopropyl alcohol was heated and maintained at reflux for 48 hours. The mixture gradually thickened and the solid that formed was collected by filtration. The solid was washed with 100 ml of hot isopropyl alcohol, then air dried to give 2.05 g of product, as the monohydriodide, mp 249°-250° C. (dec.). Patent; American Cyanamid Company; US4977189; (1990); (A1) English View in Reaxys

I N O

O O

NH 2

Rx-ID: 23859894 View in Reaxys 309/310 Yield

Conditions & References 2.3 : 2.3

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2.3 A solution of 0.11 g of "BC" and 0.13 ml of iodomethane in 10 ml of acetone is refluxed for 2 hours. After the solvent has been removed, the residue is triturated with ether, giving 0.1 g of methyl (2S)-3-[2-(2'-tert-butylsulfamoylbiphenyl-4-ylcarbamoyl)pyrrolidin-1-yl]thiobenzimidate, hydroiodide ("BD"), FAB 551 Patent; Mederski, Werner; Juraszyk, Horst; Dorsch, Dieter; Tsaklakidis, Christos; Gleitz, Johannes; Barnes, Christopher; US2003/176465; (2003); (A1) English View in Reaxys

O O O

O N O

S NH

Rx-ID: 24602506 View in Reaxys 310/310 Yield

Conditions & References 11 : Example 11 Example 11 0.92 g of tert-butyl (2R)-2-[3-(4-thiocarbamoylphenyl)-2-oxo-5-oxazolidinylcarbonylamino]-3-phenylpropionate [obtainable according to Example 10] is dissolved in 15 ml of acetone, and 1.75 ml of methyl iodide are added. The solution is stirred at room temperature for 2 h and given the customary workup. tert-Butyl, (2R)-2-[3-(4-imino(methylthio)methylphenyl)-2-oxo-5-oxazolidinylcarbonylamino]-3-phenylpropionate, hydroiodide, is obtained, m.p. 140°. Patent; Merck Patent Gesellschaft Mit Beschrankter Haftung; US5614535; (1997); (A1) English View in Reaxys

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