Prop-1-en-1-ylbenzene (cis- and trans- mixture) by Asch

Reaxys

PubChem

eMolecules

Reactions (350)

Yield

LabNetwork

Substances (2)

Citations (320)

Conditions

References A

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199

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Rx-ID: 3738205 Find similar reactions

A: 12 % Chromat. B: 5 % Chromat. C: 22 % Chromat. D: 34 % Chromat.

With tris(p-bromophenylammoniumyl) hexachloroantimonate

Ambient temperature; Further byproducts given;

Ishiguro, Katsuya; Sawaki, Yasuhiko; Iwamura, Hiizu

Chemistry Letters, 1987 , p. 1853 - 1856 Title/Abstract Full Text Show Details

200

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Rx-ID: 2680767 Find similar reactions

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With naphthalenyllithium

1.) THF, -78 deg C; Yield given. Multistep reaction;

Ager, David J.

Tetrahedron Letters, 1981 , vol. 22, # 30 p. 2923 - 2926 Title/Abstract Full Text View citing articles Show Details

With naphthalenyllithium

1.) THF, -78 deg C, 0.5 h, 2.) THF, -78 deg C -> room temperature; Yield given. Multistep reaction;

Ager, David J.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 183 - 194 Title/Abstract Full Text View citing articles Show Details

201

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Rx-ID: 2681903 Find similar reactions

47%

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With potassium carbonate in benzene

T=80°C;

Dehmlow, Eckehard V.; Barahona-Naranjo, Simon

Journal of Chemical Research, Miniprint, 1981 , # 5 p. 1748 - 1762 Title/Abstract Full Text Show Details

With n-butyllithium in hexane; benzene

6 h; Ambient temperature; Yield given;

Marples, Brian A.; Saint, Christopher G.; Traynor, John R.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 567 - 574 Title/Abstract Full Text View citing articles Show Details

With potassium carbonate in benzene

T=80°C; further reagents, further solvents, further temperatures; Product distribution;

Dehmlow, Eckehard V.; Barahona-Naranjo, Simon

Journal of Chemical Research, Miniprint, 1981 , # 5 p. 1748 - 1762 Title/Abstract Full Text Show Details

202

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Synthesize Find similar Rx-ID: 3379463 Find similar reactions

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With hydrogen; PtGe in ethanol

T=59.9°C; Further byproducts given;

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Galvagno, S.; Poltarzewski, Z.; Donato, A.; Neri, G.; Pietropaolo, R.

Journal of the Chemical Society, Chemical Communications, 1986 , # 23 p. 1729 - 1731 Title/Abstract Full Text View citing articles Show Details

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203

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With amalgamated zinc in ethanol

T=20°C;

Burdon, James; Price, Robin C.

Journal of the Chemical Society, Chemical Communications, 1986 , # 12 p. 893 - 894 Title/Abstract Full Text View citing articles Show Details

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204

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Rx-ID: 2008924 Find similar reactions

B: 9%

With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

3 h; Heating;

Miyaura, Norio; Yamada, Kinji; Suginome, Hiroshi; Suzuki, Akira

Journal of the American Chemical Society, 1985 , vol. 107, # 4 p. 972 - 980 Title/Abstract Full Text View citing articles Show Details

205

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82.5%

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Rx-ID: 2059339 Find similar reactions

With n-butyllithium in diethyl ether

T=-30 - -25°C;

Villieras, J.; Rambaud, M.; Kirschleger, B.; Tarhouni, R.

Bulletin de la Societe Chimique de France, 1985 , # 5 p. 837 - 843 Title/Abstract Full Text Show Details

206

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76.5%

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Rx-ID: 2140820 Find similar reactions

With n-butyllithium in diethyl ether

T=-30°C;

Villieras, J.; Rambaud, M.; Kirschleger, B.; Tarhouni, R.

Bulletin de la Societe Chimique de France, 1985 , # 5 p. 837 - 843 Title/Abstract Full Text Show Details

207

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Rx-ID: 2181588 Find similar reactions

With sodium hydride in DME

Heating;

Urabe, Kazuo; Tanaka, Yoshiyuki; Izumi, Yusuke

Chemistry Letters, 1985 , p. 1595 - 1596 Title/Abstract Full Text Show Details

208

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Rx-ID: 2313333 Find similar reactions

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B: 55% C: 4%

With magnesium

1.) THF, 60 deg C, 40 min; 2.) ether, -78 to 5 deg C, overnight; Yield given. Multistep reaction. Yields of byproduct given;

Padwa, Albert; Rieker, William F.; Rosenthal, Robert J.

Journal of the American Chemical Society, 1985 , vol. 107, # 6 p. 1710 - 1717 Title/Abstract Full Text View citing articles Show Details

C: 4% D: 6%

With magnesium

1.) THF, 60 deg C, 40 min; 2.) ether, -78 to 5 deg C, overnight; Yield given. Multistep reaction. Yields of byproduct given;

Padwa, Albert; Rieker, William F.; Rosenthal, Robert J.

Journal of the American Chemical Society, 1985 , vol. 107, # 6 p. 1710 - 1717 Title/Abstract Full Text View citing articles Show Details

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209

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Rx-ID: 2313337 Find similar reactions

With magnesium

1.) THF, 60 deg C, 40 min; 2.) ether, -78 to 5 deg C, overnight; Yield given. Multistep reaction. Yields of byproduct given;

Padwa, Albert; Rieker, William F.; Rosenthal, Robert J.

Journal of the American Chemical Society, 1985 , vol. 107, # 6 p. 1710 - 1717 Title/Abstract Full Text View citing articles Show Details

210

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Rx-ID: 2689105 Find similar reactions

Yield given. Multistep reaction;

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Bottaro, Jeffrey C.

Synthetic Communications, 1985 , vol. 15, # 3 p. 195 - 200 Title/Abstract Full Text Show Details

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211

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Rx-ID: 2706370 Find similar reactions

B: 46 % Chromat.

Mitsudo, Take-aki; Kadokura, Mamoru; Watanabe, Yoshihisa

Tetrahedron Letters, 1985 , vol. 26, # 42 p. 5143 - 5144 Title/Abstract Full Text View citing articles Show Details

With triethylamine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

T=120°C; 5 h;

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212

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Rx-ID: 2723233 Find similar reactions

B: 60%

Mitsudo, Take-aki; Kadokura, Mamoru; Watanabe, Yoshihisa

Tetrahedron Letters, 1985 , vol. 26, # 42 p. 5143 - 5144 Title/Abstract Full Text View citing articles Show Details

With triethylamine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

T=120°C; 5 h;

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213

Synthesize Find similar Rx-ID: 2728014 Find similar reactions

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B: 30%

Mitsudo, Take-aki; Kadokura, Mamoru; Watanabe, Yoshihisa

Tetrahedron Letters, 1985 , vol. 26, # 42 p. 5143 - 5144 Title/Abstract Full Text View citing articles Show Details

With triethylamine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

T=120°C; 5 h;

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214

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Rx-ID: 2733884 Find similar reactions

B: 74%

With triethylamine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

T=120°C; 5 h; Var. aroyl chlorides; Product distribution;

Mitsudo, Take-aki; Kadokura, Mamoru; Watanabe, Yoshihisa

Tetrahedron Letters, 1985 , vol. 26, # 42 p. 5143 - 5144 Title/Abstract Full Text View citing articles Show Details

B: 74%

With triethylamine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

T=120°C; 5 h;

Mitsudo, Take-aki; Kadokura, Mamoru; Watanabe, Yoshihisa

Tetrahedron Letters, 1985 , vol. 26, # 42 p. 5143 - 5144 Title/Abstract Full Text View citing articles Show Details

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215

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Rx-ID: 2742716 Find similar reactions

B: 32%

216

Mitsudo, Take-aki; Kadokura, Mamoru; Watanabe, Yoshihisa

Tetrahedron Letters, 1985 , vol. 26, # 42 p. 5143 - 5144 Title/Abstract Full Text View citing articles Show Details

With triethylamine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

T=120°C; 5 h;

Synthesize Find similar Rx-ID: 3381925 Find similar reactions

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With n-butyllithium; B-n-butyl-9-borabicyclolt;3.3.1gt;nonane

1.) hexane, RT, 1 h; 2.) hexane, 20 deg C, 18 h; Yield given. Multistep reaction. Yields of byproduct given;

Toi, Hiroo; Yamamoto, Yoshinori; Sonoda, Akio; Murahashi, Shun-Ichi

Tetrahedron, 1981 , vol. 37, p. 2261 - 2268 Title/Abstract Full Text View citing articles Show Details

A: 35 % Chromat. B: 60 % Chromat.

With sodium cyanoborohydride; tin(ll) chloride in diethyl ether

1 h; Ambient temperature;

Kim, Sunggak; Ko, Jae Suk

Synthetic Communications, 1985 , vol. 15, # 7 p. 603 - 606 Title/Abstract Full Text Show Details

A: 35 % Chromat. B: 60 % Chromat.

With sodium cyanoborohydride; tin(ll) chloride in diethyl ether

1 h; Ambient temperature;

Kim, Sunggak; Ko, Jae Suk

Synthetic Communications, 1985 , vol. 15, # 7 p. 603 - 606 Title/Abstract Full Text Show Details

217

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Rx-ID: 19231250 Find similar reactions

Multi-step reaction with 2 steps 1: 87 percent / potassium hydrogen sulfate, phosphorus pentoxide, 4-tert-butylcatechol / 230 °C 2: 1.) Mg / 1.) THF, 60 deg C, 40 min; 2.) ether, -78 to 5 deg C, overnight View Scheme

Padwa, Albert; Rieker, William F.; Rosenthal, Robert J.

Journal of the American Chemical Society, 1985 , vol. 107, # 6 p. 1710 - 1717 Title/Abstract Full Text View citing articles Show Details

218

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Multi-step reaction with 3 steps 1: 1.) Mg / 1.) ether, reflux, 2 h; 2.) ether, 12 h, room temp. 2: 87 percent / potassium hydrogen sulfate, phosphorus pentoxide, 4-tert-butylcatechol / 230 °C 3: 1.) Mg / 1.) THF, 60 deg C, 40 min; 2.) ether, -78 to 5 deg C, overnight View Scheme

Rx-ID: 19263732 Find similar reactions

Padwa, Albert; Rieker, William F.; Rosenthal, Robert J.

Journal of the American Chemical Society, 1985 , vol. 107, # 6 p. 1710 - 1717 Title/Abstract Full Text View citing articles Show Details

219

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Rx-ID: 20754768 Find similar reactions

Multi-step reaction with 2 steps 1: 88 percent / HMPA / tetrahydrofuran; diethyl ether; H2O / -100 - -60 °C 2: 76.5 percent / nBuLi / diethyl ether / -30 °C View Scheme

Villieras, J.; Rambaud, M.; Kirschleger, B.; Tarhouni, R.

Bulletin de la Societe Chimique de France, 1985 , # 5 p. 837 - 843 Title/Abstract Full Text Show Details

220

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Rx-ID: 20755195 Find similar reactions

Multi-step reaction with 2 steps 1: 84 percent / HMPA / tetrahydrofuran; diethyl ether; H2O / -100 - -60 °C 2: 82.5 percent / nBuLi / diethyl ether / -30 - -25 °C View Scheme

Villieras, J.; Rambaud, M.; Kirschleger, B.; Tarhouni, R.

Bulletin de la Societe Chimique de France, 1985 , # 5 p. 837 - 843 Title/Abstract Full Text Show Details

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221

Synthesize Find similar Rx-ID: 1549817 Find similar reactions

With formic acid; triethylamine; monoaluminum phosphate; silica gel; palladium

8 h; Heatingfurther catalysts; Product distributionMechanism;

Aramendia, Maria Angeles; Borau, Victoriano; Jimenez, Cesar; Marinas, Jose Maria

Gazzetta Chimica Italiana, 1984 , vol. 114, # 9/10 p. 451 - 456 Title/Abstract Full Text Show Details

222

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Rx-ID: 1587629 Find similar reactions

A: 4 % Chromat. B: 5 % Chromat. C: 30 % Chromat. D: 35 % Chromat.

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Sawaki, Yasuhiko; Ishiguro, Katsuya

Tetrahedron Letters, 1984 , vol. 25, # 14 p. 1487 - 1490 Title/Abstract Full Text View citing articles Show Details

T=0°C; 0.25 h; IrradiationRose Bengal;

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223

Synthesize Find similar Rx-ID: 1989158 Find similar reactions

A: 10 % Spectr. B: 3 % Spectr.

With sodium tetrahydroborate; nickel dichloride in N,N-dimethyl-formamide

T=-10°C; 0.5 h; Product distribution;

Ipaktschi, Junes

Chemische Berichte, 1984 , vol. 117, # 11 p. 3320 - 3324 Title/Abstract Full Text Show Details

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224

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A: 46 % Chromat. B: 3.3 % Chromat. C: 41 % Chromat.

With oxygen in benzene

T=20°C; 6 h; Irradiation;

Sawaki, Yasuhiko; Ishiguro, Katsuya

Tetrahedron Letters, 1984 , vol. 25, # 14 p. 1487 - 1490 Title/Abstract Full Text View citing articles Show Details

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225

Synthesize Find similar Rx-ID: 2817776 Find similar reactions

A: 27% B: 15 % Chromat. C: 19 % Chromat.

Hickson, Clare L.; McNab, Hamish

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1569 - 1572 Title/Abstract Full Text View citing articles Show Details

T=650°C; P=0.005 - 0.03 Torr; 0.416667 h;

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226

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Rx-ID: 3382234 Find similar reactions

With di(cyclopentadienyl)titanocarbene

competitive experiment;

Clawson, Leigh; Buchwald, Stephen L.; Grubbs, Robert H.

Tetrahedron Letters, 1984 , vol. 25, # 50 p. 5733 - 5736 Title/Abstract Full Text View citing articles Show Details

227

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With formic acid; triethylamine; monoaluminum phosphate; silica gel; palladium

8 h; Heatingfurther catalysts; Product distribution;

Aramendia, Maria Angeles; Borau, Victoriano; Jimenez, Cesar; Marinas, Jose Maria

Gazzetta Chimica Italiana, 1984 , vol. 114, # 9/10 p. 451 - 456 Title/Abstract Full Text Show Details

228

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Rx-ID: 20606180 Find similar reactions

Multi-step reaction with 2 steps 1: 89 percent / potassium hydroxide / ethanol / 0.25 h / Heating 2: 15 percent Chromat. / 0.42 h / 650 °C / 0.01 - 0.03 Torr View Scheme

Hickson, Clare L.; McNab, Hamish

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1569 - 1572 Title/Abstract Full Text View citing articles Show Details

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229

Synthesize Find similar Rx-ID: 1548713 Find similar reactions

230

Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918 Title/Abstract Full Text View citing articles Show Details

With [2,2']bipyridinyl; hydrogen; pentacyanocobaltate(II)(3-) in methanol; water

T=45°C; P=760 Torr; 5 h; <PhCCMe>/<Co> : 1; Yield given. Yields of byproduct given;

Synthesize Find similar Rx-ID: 1548714 Find similar reactions

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Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918 Title/Abstract Full Text View citing articles Show Details

With pentacyanocobaltate(II)(3-); hydrogen in water

P=760 Torr; 24 h; different reaction time, other solvent, different reagent ratio (effect of 2,2'-bipyridyl on product distribution); Product distribution;

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231

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Rx-ID: 1710289 Find similar reactions

With lithium perchlorate; triethylamine; triphenylphosphine in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide

electrolysis;

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Rollin, Yolande; Meyer, Gilbert; Troupel, Michel; Fauvarque, Jean-Francois; Perichon, Jacques

Journal of the Chemical Society, Chemical Communications, 1983 , # 15 p. 793 - 794 Title/Abstract Full Text View citing articles Show Details

232

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A: 15%

233

T=600°C; P=0.1 Torr;

Govindan, C. K.; Taylor, Grant

Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5348 - 5354 Title/Abstract Full Text View citing articles Show Details

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96 % Chromat.

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Rx-ID: 2061341 Find similar reactions

With potassium hydroxide; PEG-grafted to cross-linked polystyrene in hexane

T=70°C; 1 h; or without catalyst, three-phase cond., var. solvents, var. times, var. temp., var. yields;

Kimura, Yoshikazu; Regen, Steven L.

Journal of Organic Chemistry, 1983 , vol. 48, # 2 p. 195 - 198 Title/Abstract Full Text View citing articles Show Details

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234

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Rx-ID: 2395027 Find similar reactions

B: 40%

With hydrogenchloride; potassium fluoride; 18-crown-6 or silica-supported tetrabutylammonium fluoride in tetrahydrofuran

T=20°C; 12 h; Yields of byproduct given;

Ricci, Alfredo; Degl'Innocenti, Alessandro; Fiorenza, Mariella; Taddei, Maurizio; Spartera, Maria A.; Walton, David R.M.

Tetrahedron Letters, 1982 , vol. 23, # 5 p. 577 - 578 Title/Abstract Full Text View citing articles Show Details

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235

Synthesize Find similar Rx-ID: 2681043 Find similar reactions

B: 50%

236

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With hydrogenchloride; potassium fluoride; 18-crown-6 or silica-supported tetrabutylammonium fluoride in tetrahydrofuran

T=20°C; 12 h; Yields of byproduct given;

Ricci, Alfredo; Degl'Innocenti, Alessandro; Fiorenza, Mariella; Taddei, Maurizio; Spartera, Maria A.; Walton, David R.M.

Tetrahedron Letters, 1982 , vol. 23, # 5 p. 577 - 578 Title/Abstract Full Text View citing articles Show Details

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10%

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Rx-ID: 7085421 Find similar reactions

With N,N,N',N',N'',N''-hexamethylphosphoric triamide; ethylmagnesium bromide; lithium chloride; palladium dichloride in tetrahydrofuran

1.) -45 deg C, 2 h, 2.) RT, 15 h;

Broquet, C.; Riviere, H.

Journal of Organometallic Chemistry, 1982 , vol. 226, # 1 p. 1 - 10 Title/Abstract Full Text View citing articles Show Details

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237

Synthesize Find similar Rx-ID: 2010098 Find similar reactions

A: 9% B: 53%

Yamamoto, Takakazu; Ishizu, Junichi; Yamamoto, Akio

Journal of the American Chemical Society, 1981 , vol. 103, # 23 p. 6863 - 6869 Title/Abstract Full Text View citing articles Show Details

With bis(1,5-cyclooctadiene)nickel (0); triphenylphosphine in tetrahydrofuran

T=30°C; 48 h; Product distribution;

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238

Synthesize Find similar Rx-ID: 2015380 Find similar reactions

With dimethyl sulfoxide

T=175°C; 2.5 h; Yield given;

Molnar, Arpad; Bartok, Mihaly

Helvetica Chimica Acta, 1981 , vol. 64, # 2 p. 389 - 398 Title/Abstract Full Text Show Details

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239

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Rx-ID: 2093841 Find similar reactions

C: 1.4% D: 8.4%

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Abramovitch, Rudolph A.; Holcomb, William D.; Wake, Shigeo

Journal of the American Chemical Society, 1981 , vol. 103, # 6 p. 1525 - 1533 Title/Abstract Full Text View citing articles Show Details

T=650°C; 0.26 h; other temperature; Product distribution;

240

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Rx-ID: 2627328 Find similar reactions

97 % Chromat.

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With lithium chloride in N,N,N,N,N,N-hexamethylphosphoric triamide

T=70°C; 24 h;

Larock, R. C.; Hershberger, S. S.

Tetrahedron Letters, 1981 , vol. 22, # 26 p. 2443 - 2446 Title/Abstract Full Text View citing articles Show Details

241

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Rx-ID: 2868813 Find similar reactions

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With naphthalenyllithium

1.) THF, -78 deg C; Yield given. Multistep reaction;

Ager, David J.

Tetrahedron Letters, 1981 , vol. 22, # 30 p. 2923 - 2926 Title/Abstract Full Text View citing articles Show Details

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242

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Rx-ID: 3745448 Find similar reactions

With n-butyllithium; B-n-butyl-9-borabicyclolt;3.3.1gt;nonane

1.) hexane, RT, 1 h; 2.) hexane, 25 deg C, 18 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

Toi, Hiroo; Yamamoto, Yoshinori; Sonoda, Akio; Murahashi, Shun-Ichi

Tetrahedron, 1981 , vol. 37, p. 2261 - 2268 Title/Abstract Full Text View citing articles Show Details

243

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Rx-ID: 21517840 Find similar reactions

Multi-step reaction with 2 steps 1: 1.)lithium naphthalenide / 1.) THF, -78 deg C, 0.25 h 2: 1.)lithium naphthalenide / 1.) THF, -78 deg C View Scheme

Ager, David J.

Tetrahedron Letters, 1981 , vol. 22, # 30 p. 2923 - 2926 Title/Abstract Full Text View citing articles Show Details

244

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Rx-ID: 27083926 Find similar reactions

68%

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With p-toluenesulfonic acid in tetrahydrofuran

Ni complex transferred to NMR tube and capped with a rubber septum, added alkyne via syringe at room temp. then added TsOH; yields calcd. by GC;

Huggins, John M.; Bergman, Robert G.

Journal of the American Chemical Society, 1981 , vol. 103, # 11 p. 3002 - 3011 Title/Abstract Full Text View citing articles Show Details

245

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68%

With p-toluenesulfonic acid

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Rx-ID: 27087893 Find similar reactions

Huggins, John M.; Bergman, Robert G.

under air-free condition;

Journal of the American Chemical Society, 1981 , vol. 103, # 11 p. 3002 - 3011 Title/Abstract Full Text View citing articles Show Details

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246

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Rx-ID: 27116699 Find similar reactions

A: 9% B: 53% C: 30% D: 51% E: <1

With triphenylphosphine in tetrahydrofuran

under N2 or argon or under vac., soln. of org. compd. (3.8 mol) added to mixt. of Ni(cod)2 and PPh3 (1.0/2.2 mol ratio), stirred at 30°Cfor 2 d; detn. by IR and NMR;

Yamamoto, Takakazu; Ishizu, Junichi; Yamamoto, Akio

Journal of the American Chemical Society, 1981 , vol. 103, # 23 p. 6863 - 6869 Title/Abstract Full Text View citing articles Show Details

247

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Rx-ID: 31799760 Find similar reactions

Multi-step reaction with 2 steps 1: tetrahydrofuran 2: p-toluenesulfonic acid View Scheme

Huggins, John M.; Bergman, Robert G.

Journal of the American Chemical Society, 1981 , vol. 103, # 11 p. 3002 - 3011 Title/Abstract Full Text View citing articles Show Details

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248

Synthesize Find similar Rx-ID: 1802014 Find similar reactions

T=650°C; P=0.01 - 0.5 Torr; other temperatures (550 and 600 deg C); reaction stereospecificity; Product distributionMechanism;

Cameron, Tim B.; Pinnick, Harold W.

Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 744 - 747 Title/Abstract Full Text View citing articles Show Details

T=650°C; P=0.01 - 0.5 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Cameron, Tim B.; Pinnick, Harold W.

Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 744 - 747 Title/Abstract Full Text View citing articles Show Details

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249

Synthesize Find similar Rx-ID: 1988738 Find similar reactions

A: 10% B: 85%

With bromine; mercury(II) oxide in tribromo methane

T=8°C; 0.25 h;

Sychkova, L. D.; Shabarov, Yu. S.

Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 10 p. 1775 - 1779 Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 10 p. 2086 - 2091 Title/Abstract Full Text Show Details

A: 10% B: 85%

With bromine; mercury(II) oxide in tribromo methane

T=8°C; 0.25 h;

Sychkova, L. D.; Shabarov, Yu. S.

Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 10 p. 1775 - 1779 Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 10 p. 2086 - 2091 Title/Abstract Full Text Show Details

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250

Synthesize Find similar Rx-ID: 2011550 Find similar reactions

C: 76%

With hydrogen; palladium in ethanol

T=20°C; P=760 Torr;

Cerveny, Libor; Sabata, Stanislav; Ruzicka, Vlastimil

Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 12 p. 3525 - 3531 Title/Abstract Full Text Show Details

With hydrogen; palladium in methanol

T=20°C; P=760 Torr; effects of solvent and catalyst; Rate constantProduct distribution;

Cerveny, Libor; Sabata, Stanislav; Ruzicka, Vlastimil

Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 12 p. 3525 - 3531 Title/Abstract Full Text Show Details

251

Synthesize Find similar Rx-ID: 2068101 Find similar reactions

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Hutchins, Robert O.; Learn, Keith; Fulton, Robert P.

Tetrahedron Letters, 1980 , vol. 21, # 1 p. 27 - 30 Title/Abstract Full Text View citing articles Show Details

With sodium cyanoborohydride; triphenylphosphine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

T=66°C; 16 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

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252

Synthesize Find similar Rx-ID: 2127119 Find similar reactions

Temerk, T. M.; Zhrui, A. Z. Abu

Bulletin des Societes Chimiques Belges, 1980 , vol. 89, # 7 p. 489 - 498 Title/Abstract Full Text Show Details

in ethanol; water

T=25°C; polarography, variation of pH, and conc. of various surfactants; Product distribution;

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253

Synthesize Find similar Rx-ID: 2140088 Find similar reactions

D: 48%

in diethyl ether

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Richey, Herman G.; Bension, Rouvain M.

Journal of Organic Chemistry, 1980 , vol. 45, # 25 p. 5036 - 5042 Title/Abstract Full Text View citing articles Show Details

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254

Synthesize Find similar Rx-ID: 2431624 Find similar reactions

With N,N,N',N,-tetramethylethylenediamine

T=310°C; 3 h; variation of time and temperature; Product distribution;

Imai, Toshiro; Nishida, Shinya

Chemistry Letters, 1980 , p. 41 - 44 Title/Abstract Full Text Show Details

255

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Rx-ID: 2841714 Find similar reactions

With zinc; nickel dichloride in N,N-dimethyl-formamide

T=110°C; 5 h;

Goto, Toshio; Onaka, Makoto; Mukaiyama, Teruaki

Chemistry Letters, 1980 , p. 709 - 712 Title/Abstract Full Text Show Details

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256

Synthesize Find similar Rx-ID: 3034980 Find similar reactions

With N,N,N',N,-tetramethylethylenediamine

T=310°C; 3 h; variation of time and temperature; Product distribution;

Imai, Toshiro; Nishida, Shinya

Chemistry Letters, 1980 , p. 41 - 44 Title/Abstract Full Text Show Details

257

Synthesize Find similar Rx-ID: 3040844 Find similar reactions

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T=650°C; P=0.01 - 0.5 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Cameron, Tim B.; Pinnick, Harold W.

Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 744 - 747 Title/Abstract Full Text View citing articles Show Details

T=650°C; P=0.01 - 0.5 Torr; other temperature (600 deg C); reaction stereospecificity; Product distributionMechanism;

Cameron, Tim B.; Pinnick, Harold W.

Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 744 - 747 Title/Abstract Full Text View citing articles Show Details

258

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Rx-ID: 11713211 Find similar reactions

Multi-step reaction with 3 steps 1: 95 percent / aq. H2O2, NaOH / H2O / 1 h / 80 - 90 °C 2: 78 percent / 10percent aq. HCl / 1 h / 100 °C 3: 10 percent / bromine, red mercuric oxide / CHBr3 / 0.25 h / 8 °C View Scheme

Sychkova, L. D.; Shabarov, Yu. S.

Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 10 p. 1775 - 1779 Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 10 p. 2086 - 2091 Title/Abstract Full Text Show Details

259

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Multi-step reaction with 2 steps 1: 78 percent / 10percent aq. HCl / 1 h / 100 °C 2: 10 percent / bromine, red mercuric oxide / CHBr3 / 0.25 h / 8 °C

Rx-ID: 11713279 Find similar reactions

Sychkova, L. D.; Shabarov, Yu. S.

Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 10 p. 1775 - 1779 Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 10 p. 2086 - 2091

Title/Abstract Full Text Show Details

View Scheme

260

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Multi-step reaction with 4 steps 1: 87 percent / NaOH, benzyltriethylammonium chloride / H2O / 1 h / 75 - 80 °C 2: 95 percent / aq. H2O2, NaOH / H2O / 1 h / 80 - 90 °C 3: 78 percent / 10percent aq. HCl / 1 h / 100 °C 4: 10 percent / bromine, red mercuric oxide / CHBr3 / 0.25 h / 8 °C View Scheme

Rx-ID: 11724677 Find similar reactions

Sychkova, L. D.; Shabarov, Yu. S.

Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 10 p. 1775 - 1779 Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 10 p. 2086 - 2091 Title/Abstract Full Text Show Details

261

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Rx-ID: 6904562 Find similar reactions

Destillation ueber KHSO4; substance of uncertain configuration;

Bodot,H. et al.

Bulletin de la Societe Chimique de France, 1960 , p. 1086 - 1097 Full Text View citing articles Show Details

Gauthier; Gauthier

Bulletin de la Societe Chimique de France, 1933 , vol. <4> 53, p. 323,326 Full Text View citing articles Show Details

Destillation ueber NaHSO4; substance of uncertain configuration;

Bodot,H. et al.

Bulletin de la Societe Chimique de France, 1960 , p. 1086 - 1097 Full Text View citing articles Show Details

Gauthier; Gauthier

Bulletin de la Societe Chimique de France, 1933 , vol. <4> 53, p. 323,326 Full Text View citing articles Show Details

With sulfuric acid

T=150°C; substance of uncertain configuration;

Bruylants

Bulletin des Societes Chimiques Belges, 1950 , vol. 59, p. 421,425 Full Text View citing articles Show Details

Niederl; Riley

Journal of the American Chemical Society, 1934 , vol. 56, p. 2412 Full Text View citing articles Show Details

With phosphoric acid

substance of uncertain configuration;

Woronkow; Broun; Karpenko

Zhurnal Obshchei Khimii, 1949 , vol. 19, p. 1927,1939 Chem.Abstr., 1950 , p. 1955

Full Text View citing articles Show Details

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262

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Rx-ID: 8209846 Find similar reactions

Leonard; Gelfand

Journal of the American Chemical Society, 1955 , vol. 77, p. 3272,3274,3276 Full Text View citing articles Show Details

T=200°C;

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263

Synthesize Find similar Rx-ID: 472960 Find similar reactions

Berti

Journal of the American Chemical Society, 1954 , vol. 76, p. 1213,1214 Full Text View citing articles Show Details

T=350°C;

264

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With sodium hydroxide; hydrazine hydrate; 2,2'-[1,2-ethanediylbis(oxy)]bisethanol

T=200°C; substance of uncertain configuration;

Rx-ID: 714599 Find similar reactions

Huang-Minlon

Journal of the American Chemical Society, 1949 , vol. 71, p. 3301 Full Text View citing articles Show Details

With ethanol; hydrazine hydrate

anschliessendes Erhitzen mit Natrium-aethylat auf 210grad; substance of uncertain configuration;

Lardelli; Jeger

Helvetica Chimica Acta, 1949 , vol. 32, p. 1817,1832 Full Text View citing articles Show Details

With sodium hydroxide; hydrazine hydrate; diethylene glycol

T=200°C; substance of uncertain configuration;

Huang-Minlon

Journal of the American Chemical Society, 1949 , vol. 71, p. 3301 Full Text View citing articles Show Details

265

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Rx-ID: 6671966 Find similar reactions

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Lardelli; Jeger

Helvetica Chimica Acta, 1949 , vol. 32, p. 1817,1832 Full Text View citing articles Show Details

anschliessend Erhitzen mit Natriumaethylat auf 210grad;

266

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Rx-ID: 6671968 Find similar reactions

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Huang-Minlon

Journal of the American Chemical Society, 1949 , vol. 71, p. 3301 Full Text View citing articles Show Details

T=200°C;

267

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Find similar Rx-ID: 6671969 Find similar reactions

Find similar

Huang-Minlon

Journal of the American Chemical Society, 1949 , vol. 71, p. 3301 Full Text View citing articles Show Details

T=200°C;

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268

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Rx-ID: 8286380 Find similar reactions

Buu-Hoi; Hoan

Journal of Organic Chemistry, 1949 , vol. 14, p. 1023,1030 Full Text View citing articles Show Details

269

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Rx-ID: 6671967 Find similar reactions

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Campbell; Young

Journal of the American Chemical Society, 1947 , vol. 69, p. 688 Full Text View citing articles Show Details

Behandlung der erhaltenen Loesung des Natriumsalzes mit NH4Cl;

270

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Rx-ID: 663729 Find similar reactions

With diethyl ether

substance of uncertain configuration;

Kharasch; Lambert; Urry

Journal of Organic Chemistry, 1945 , vol. 10, p. 298,302 Full Text View citing articles Show Details

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271

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Rx-ID: 663732 Find similar reactions

Kharasch; Lambert; Urry

Journal of Organic Chemistry, 1945 , vol. 10, p. 298,302 Full Text View citing articles Show Details

272

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Rx-ID: 663742 Find similar reactions

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With diethyl ether

substance of uncertain configuration;

Kharasch; Lambert; Urry

Journal of Organic Chemistry, 1945 , vol. 10, p. 298,302 Full Text View citing articles Show Details

273

Rx-ID: 7155661

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Find similar reactions

Kharasch; Fuchs

Journal of Organic Chemistry, 1945 , vol. 10, p. 292,294 Full Text View citing articles Show Details

<2-bromo-vinyl>-benzene;

274

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Rx-ID: 7155664 Find similar reactions

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Kharasch; Fuchs

Journal of Organic Chemistry, 1945 , vol. 10, p. 292,294 Full Text View citing articles Show Details

<2-bromo-vinyl>-benzene;

275

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Rx-ID: 195741 Find similar reactions

276

With diethyl ether

substance of uncertain configuration;

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E. Lilly and Co.

Patent: US2404235 , 1944 ; Full Text Show Details

Kharasch; Fuchs

Journal of the American Chemical Society, 1943 , vol. 65, p. 504 Journal of Organic Chemistry, 1945 , vol. 10, p. 292,294 Full Text View citing articles Show Details

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Rx-ID: 664602 Find similar reactions

Destillation ueber Kupfer-Pulver und K2CO3; substance of uncertain configuration;

Wittig; Harborth

Chemische Berichte, 1944 , vol. 77, p. 320 Anm. 8 Full Text View citing articles Show Details

With sodium ethanolate

substance of uncertain configuration;

Meisenheimer; Link

Justus Liebigs Annalen der Chemie, 1930 , vol. 479, p. 211,248 Full Text Show Details

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277

Synthesize Find similar Rx-ID: 455988 Find similar reactions

Annales de Chimie (Cachan, France), 1940 , vol. <11> 13, p. 175,233 Full Text View citing articles Show Details

With potassium hydroxide; pentan-1-ol

T=125°C; (+-)-3-phenyl-penten-(2)-ol-(4) of bp 14: 130 degree;

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278

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Rx-ID: 7980228 Find similar reactions

Annales de Chimie (Cachan, France), 1940 , vol. <11> 13, p. 175,233 Full Text View citing articles Show Details

T=125°C;

279

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With diethyl ether; magnesium

anschliessende Hydrolyse; substance of uncertain configuration;

Young; Ballou; Nozaki

Journal of the American Chemical Society, 1939 , vol. 61, p. 11,14 Full Text View citing articles Show Details

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280

Synthesize Find similar Rx-ID: 5806859 Find similar reactions

Paul

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1939 , vol. 208, p. 1320 Bulletin de la Societe Chimique de France, 1941 , vol. <5>8, p. 509 Full Text View citing articles Show Details

T=190°C;

281

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Rx-ID: 7978171 Find similar reactions

Prevost; Ou

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1938 , vol. 206, p. 1661 Full Text View citing articles Show Details

T=340°C;

282

Synthesize Find similar Rx-ID: 5958089 Find similar reactions

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Faworskii <Favorsky>

Zhurnal Obshchei Khimii, 1935 , vol. 5, p. 1728,1733 Bulletin de la Societe Chimique de France, 1936 , vol. <5> 3, p. 239,245 Full Text View citing articles Show Details

T=320 - 330°C;

283

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Rx-ID: 6904564 Find similar reactions

With potassium hydroxide

substance of uncertain configuration;

Sontag

Annales de Chimie (Cachan, France), 1934 , vol. <11> 1, p. 359,404 Full Text View citing articles Show Details

284

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Rx-ID: 7978173 Find similar reactions

Sabetay

Bulletin de la Societe Chimique de France, 1930 , vol. <4> 47, p. 614,617 Full Text View citing articles Show Details

Sontag

Annales de Chimie (Cachan, France), 1934 , vol. <11> 1, p. 359,404 Full Text View citing articles Show Details

285

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Rx-ID: 6676347 Find similar reactions

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Nenitzescu; Isacescu

Chemische Berichte, 1933 , vol. 66, p. 1100,1103 Full Text View citing articles Show Details

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286

Synthesize Find similar Rx-ID: 440553 Find similar reactions

Rona; Chain; Ammon

Biochemische Zeitschrift, 1932 , vol. 247, p. 113,119 Full Text View citing articles Show Details

Aufbewahren;

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287

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Rx-ID: 64567 Find similar reactions

With diethyl ether

anschliessende Hydrolyse; substance of uncertain configuration;

Prevost

Bulletin de la Societe Chimique de France, 1931 , vol. <4> 49, p. 1372,1376 Full Text View citing articles Show Details

288

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Rx-ID: 6904563 Find similar reactions

With sodium amide; xylene

substance of uncertain configuration;

Amagat

Bulletin de la Societe Chimique de France, 1931 , vol. <4> 49, p. 1410,1413 Full Text View citing articles Show Details

289

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Rx-ID: 357421 Find similar reactions

With sodium; toluene

substance of uncertain configuration;

Bert; Raynaud

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1930 , vol. 191, p. 454 Full Text View citing articles Show Details

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290

Synthesize Find similar

Rx-ID: 436387 Find similar reactions

Meisenheimer; Link

Justus Liebigs Annalen der Chemie, 1930 , vol. 479, p. 211,248 Full Text Show Details

291

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Rx-ID: 7022262 Find similar reactions

With ethanol; sodium ethanolate

Meisenheimer; Link

Justus Liebigs Annalen der Chemie, 1930 , vol. 479, p. 211,248 Full Text Show Details

292

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Rx-ID: 7541992 Find similar reactions

Synthesize Find similar

Bert; Raynaud

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1930 , vol. 191, p. 454 Full Text View citing articles Show Details

T=110°C;

293

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Rx-ID: 267744 Find similar reactions

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With infusorial earht

T=400 - 500°C;

Ramart; Amagat

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1929 , vol. 188, p. 639 Full Text View citing articles Show Details

294

Synthesize Find similar Rx-ID: 267753 Find similar reactions

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With thionyl chloride

Ramart-Lucas; Amagat

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1929 , vol. 188, p. 638 Full Text View citing articles Show Details

Ramart; Amagat

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1929 , vol. 188, p. 638 Full Text View citing articles Show Details

295

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Rx-ID: 287425 Find similar reactions

With ethanol; sodium

Bert; Anglade

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1929 , vol. 189, p. 645 Full Text View citing articles Show Details

296

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Rx-ID: 6671970 Find similar reactions

Ramart-Lucas; Amagat

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1929 , vol. 188, p. 638 Full Text View citing articles Show Details

T=500°C;

297

Synthesize Find similar Rx-ID: 6904577 Find similar reactions

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Ramart-Lucas; Amagat

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1929 , vol. 188, p. 638 Full Text View citing articles Show Details