Prop-1-en-1-ylbenzene (cis- and trans- mixture) by Asch

Reaxys

PubChem

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Reactions (350)

Yield

LabNetwork

Substances (2)

Citations (320)

Conditions

References A

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With (pivalate)(o-isopropoxyphenylmethylene)(1,3-di(2,4,6-trimethylphenyl)imidazolidin-2-yl-H)ruthenium in benzene

T=23°C; 2 h; GloveboxInert atmosphere; Catalytic behavior; Reagent/catalystTime;

Endo, Koji; Herbert, Myles B.; Grubbs, Robert H.

Organometallics, 2013 , vol. 32, # 18 p. 5128 - 5135 Title/Abstract Full Text View citing articles Show Details

With C35H47N3O4Ru in tetrahydrofuran

T=35°C; 12 h; Catalytic behavior; Reagent/catalystTime; diastereoselective reaction;

Bronner, Sarah M.; Herbert, Myles B.; Patel, Paresma R.; Marx, Vanessa M.; Grubbs, Robert H.

Chemical Science, 2014 , vol. 5, # 10 p. 4091 - 4098 Title/Abstract Full Text View citing articles Show Details

With C56H55N3O2RuS*CH2Cl2 in acetic acid methyl ester

T=40°C; 4 h; Schlenk technique; SolventTime; Hide Experimental Procedure

Bergen Teknologioverføring AS; Jensen, Vidar Remi; Occhipinti, Giovanni

Patent: EP2826783 A1, 2015 ; Location in patent: Paragraph 0098; 0099 ; Title/Abstract Full Text Show Details

9:Example 9: Homocoupling of allylbenzene using 4a in presence of air (in solution).

General procedure: In the fume hood, a 50 mL Schlenk flask equipped with a Young’s tap and a magnetic stirring bar was chargedwith the catalyst (0.005 mmol), and with 2 mmol of substrate (stored under air). The solvent (stored under air) was addedto the flask to obtain 0.5 mL of a 4 M solution. The Schlenk flask was closed and the reaction mixture was stirred andheated in an oil bath at 40°C.

With C63H66ClN3RuS2

T=22°C; 0.0833333 h; Glovebox; Hide Experimental Procedure

BERGEN TEKNOLOGIOVERFØRING AS; JENSEN, Vidar Remi; OCCHIPINTI, Giovanni

Patent: WO2017/9232 A1, 2017 ; Location in patent: Page/Page column 39; 40 ; Title/Abstract Full Text Show Details

12:Example 12 Homocoupling of neat allylbenzene

General procedure: In a glove box, a 4 mL vial equipped with a magnetic stirring bar was charged with 59 mg (0.50 mmol) of allylbenzene and the catalyst (0.005 mmol, 1 mol percent). The reaction mixture was stirred at room temperature (22°C) for five minutes (open atmosphere). The reaction was quenched by filtration through silica gel using hexane as eluent. Determination of conversions, yields, and Z-selectivities were done according to literature procedures. (20, 28) A

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Stage #1: With bis(cyclopentadienyl)titanium dichloride; magnesium in diethyl ether

14 h; Schlenk techniqueInert atmosphere; Stage #2: With dihydrogen peroxide

T=0°C; Inert atmosphereAlkaline conditionsSchlenk technique;

Khusainova, Liliya I.; Khafizova, Leila O.; Tyumkina, Tatyana V.; Ryazanov, Kirill S.; Dzhemilev, Usein M.

Journal of Organometallic Chemistry, 2017 , vol. 832, p. 12 - 17 Title/Abstract Full Text View citing articles Show Details

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With bis(cyclopentadienyl)titanium dichloride; magnesium in diethyl ether

T=0 - 25°C; 14 h; Schlenk techniqueInert atmosphere; Overall yield = 40 percent; Hide Experimental Procedure

Khusainova, Liliya I.; Khafizova, Leila O.; Tyumkina, Tatyana V.; Ryazanov, Kirill S.; Dzhemilev, Usein M.

Journal of Organometallic Chemistry, 2017 , vol. 832, p. 12 - 17 Title/Abstract Full Text View citing articles Show Details

4.1.1. General procedure

General procedure: A glass reactor (50 mL), under a dry argon atmosphere at 0 ,was charged under stirring with Cp2TiCl2 (2 mmol, 0.498 g), magnesium(powder) (20 mmol, 0.486 g), Et2O (30 mL), the correspondinga-olefin (10 mmol) and PhBCl2 (12 mmol, 1.91 g). Thetemperature was raised to 25 °C and the mixture was stirred foradditional 14 h. Then the reaction mixture was centrifuged, theexcess of magnesium was filtered off, the diethyl ether was evaporated,and 12 mmol of pyridine was added. The mixture wasstirred for 30 min and placed in a sublimation chamber. Pyridinewas removed; the residue was subjected to vacuum sublimation inan argon atmosphere.

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80%

Zhu, Nengbo; Zhao, Jianguo; Bao, Hongli

Chemical Science, 2017 , vol. 8, # 3 p. 2081 - 2085 Title/Abstract Full Text Show Details

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A: 7 %Spectr. B: 7 %Spectr.

Abrams, Dylan J.; West, Julian G.; Sorensen, Erik J.

Chemical Science, 2017 , vol. 8, # 3 p. 1954 - 1959 Title/Abstract Full Text Show Details

With chloropyridinecobaloxime(III); tetrakis(tetrabutylammonium)decatungstate(VI) in [D3]acetonitrile

T=31°C; 96 h; Inert atmosphereUV-irradiationMolecular sieve; Overall yield = 14 percentSpectr.;

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Rx-ID: 44747822 Find similar reactions

With iron(III) trifluoromethanesulfonate

T=80°C; Heck Reaction; 12 h;

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With indium(III) chloride; chloro(1,5-cyclooctadiene)rhodium(I) dimer; bis[2-(diphenylphosphino)phenyl] ether in toluene

T=120°C; 18 h; Schlenk technique; regioselective reaction;

Kim, Ju Hyun; Song, Taemoon; Chung, Young Keun

Organic Letters, 2017 , vol. 19, # 5 p. 1248 - 1251 Title/Abstract Full Text Show Details

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C: 22%

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Wakeham, Russell J.; Baillie, Rhett A.; Patrick, Brian O.; Legzdins, Peter; Rosenfeld, Devon C.

Organometallics, 2017 , vol. 36, # 1 p. 39 - 52 Title/Abstract Full Text Show Details

T=55°C; 72 h; Sealed tubeGloveboxInert atmosphere;

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With aluminum (III) chloride; triphenylphosphine in nitromethane

T=80°C; 2 h; Reagent/catalyst; Hide Experimental Procedure

Rx-ID: 280272 Find similar reactions

Liu, Changhui; Pan, Bin; Gu, Yanlong

Chinese Journal of Catalysis, 2016 , vol. 37, # 6 p. 979 - 986 Title/Abstract Full Text Show Details

2.2. A typical alcohol dehydration procedure

General procedure: In a typical reaction, alcohol (0.4 mmol) was mixed with AlCl3 (0.02 mmol, 5 molpercent) and triphenylphosphine (PPh3, 0.02 mmol, 5 molpercent) in nitromethane (1.0 mL). Thereafter the mixture was stirred at 80 °C for 2 h. After the reaction, the mixture was cooled to room temperature, and the product was isolated using preparative thin layer chromatography (TLC, eluting solution: petroleum ether/ethyl acetate, 5/1 (v/v)). Tests for substrate scope were all performed with an analogous procedure. With phosphorus pentachloride

Wagner

Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1884 , vol. 16, p. 324 Chemische Berichte, 17 Ref. <1884>, 317 Full Text View citing articles Show Details

With hydrogenchloride

Wagner

Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1884 , vol. 16, p. 324 Chemische Berichte, 17 Ref. <1884>, 317 Full Text View citing articles Show Details

With hydrogenchloride

Behandeln mit Pyridin;

Klages

Chemische Berichte, 1902 , vol. 35, p. 2263 Chemische Berichte, 1905 , vol. 38, p. 913 Full Text Show Details

With pyridine; hydrogenchloride

T=125°C; im geschlossenen Rohr;

Klages

Chemische Berichte, 1903 , vol. 36, p. 621 Full Text View citing articles Show Details

durch Destillation;

Hell; Bauer

Chemische Berichte, 1903 , vol. 36, p. 207 Full Text View citing articles Show Details

With acetic anhydride; trichlorophosphate

Spaeth; Koller

Chemische Berichte, 1925 , vol. 58, p. 1269 Full Text View citing articles Show Details

Klages

Chemische Berichte, 1903 , vol. 36, p. 621 Full Text View citing articles Show Details

Zincke; Zahn

Chemische Berichte, 1910 , vol. 43, p. 855 Full Text View citing articles Show Details

108 % Turnov.

With methyltrioxorhenium(VII)

72 h;

Zhu, Zuolin; Espenson, James H.

Journal of Organic Chemistry, 1996 , vol. 61, # 1 p. 324 - 328 Title/Abstract Full Text View citing articles Show Details

85 %Chromat.

With LiCl-acidic alumina T=80°C; 0.05 h; Microwave irradiation;

Bagheri Marandi; Pourjavadi; Hosseinzadeh

Oriental Journal of Chemistry, 2012 , vol. 28, # 3 p. 1141 - 1145 Title/Abstract Full Text View citing articles Show Details

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With diethyl ether; iron(III) chloride

substance of uncertain configuration;

Kharasch; Fuchs

Journal of Organic Chemistry, 1945 , vol. 10, p. 292,294 Full Text View citing articles Show Details

With diethyl ether

substance of uncertain configuration;

Kharasch; Fuchs

Journal of Organic Chemistry, 1945 , vol. 10, p. 292,294 Full Text View citing articles Show Details

80 %Chromat.

With iron(III)-acetylacetonate in tetrahydrofuran

T=20°C; 0.25 h; Time;

Muñoz, Salvador B.; Daifuku, Stephanie L.; Brennessel, William W.; Neidig, Michael L.

Journal of the American Chemical Society, 2016 , vol. 138, # 24 p. 7492 - 7495 Title/Abstract Full Text View citing articles Show Details

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96%

With hydrogen in toluene

T=20°C; P=22801.5 Torr; 18 h; Autoclave; Catalytic behavior; Reagent/catalyst;

Mitsudome, Takato; Yamamoto, Masaaki; Maeno, Zen; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Journal of the American Chemical Society, 2015 , vol. 137, # 42 p. 13452 - 13455 Title/Abstract Full Text View citing articles Show Details

94%

With hydrogen; G2 Py-C6 Pd4-Pt in dichloromethane

T=20°C; P=760 Torr; 0.7 h;

Murata, Makoto; Tanaka, Yuko; Mizugaki, Tomoo; Ebitani, Kohki; Kaneda, Kiyotomi

Chemistry Letters, 2005 , vol. 34, # 2 p. 272 - 273 Title/Abstract Full Text View citing articles Show Details

With hydrogen; RhCl(PPh3)3 in ethanol; benzene

T=30°C; P=760 Torr; 6 h; hydrogenation in presence of var. additives, (Li-salts); Product distribution;

Urabe, Kazuo; Tanaka, Yoshiyuki; Izumi, Yusuke

Chemistry Letters, 1985 , p. 1595 - 1596 Title/Abstract Full Text Show Details

With hydrogen; RhCl(PPh3)3; 4Li(1+)*O40SiW12(4-); (20 mmol); (4 mmol) in ethanol; benzene T=30°C; P=760 Torr; 1.1 h; Yield given;

Urabe, Kazuo; Tanaka, Yoshiyuki; Izumi, Yusuke

Chemistry Letters, 1985 , p. 1595 - 1596 Title/Abstract Full Text Show Details

With hydrogen; palladium in diethyl ether

T=25°C;

Fowley, Lissa A.; Michos, Demetrius; Luo, Xiao-Liang; Crabtree, Robert H.

Tetrahedron Letters, 1993 , vol. 34, # 19 p. 3075 - 3078 Title/Abstract Full Text View citing articles Show Details

With hydrogen; [Rh(COD)(bis(diphenylphosphino)ethane)]BF4 in methanol; d(4)-methanol P=2250.23 Torr;

Aguilar, Juan A.; Elliott, Paul I. P.; Lopez-Serrano, Joaquin; Adams, Ralph W.; Duckett, Simon B.

Chemical Communications, 2007 , # 11 p. 1183 - 1185 Title/Abstract Full Text View citing articles Show Details

With quinoline; hydrogen; Lindlar's catalyst in diethyl ether

Zhao, Yu; Mitra, Aurpon W.; Hoveyda, Amir H.; Snapper, Marc L.

Angewandte Chemie - International Edition, 2007 , vol. 46, # 44 p. 8471 - 8474 Title/Abstract Full Text View citing articles Show Details

With Pd0005Pb0995; hydrogen in ethanol

T=25°C; P=760.051 Torr;

Niu, Wenxin; Gao, Yongjun; Zhang, Weiqing; Yan, Ning; Lu, Xianmao

Angewandte Chemie - International Edition, 2015 , vol. 54, # 28 p. 8271 - 8274 Angew. Chem., 2015 , vol. 127, p. 8389 - 8392,4 Title/Abstract Full Text View citing articles Show Details

With carbon monoxide; hydrogen in tetrahydrofuran

T=70°C; P=7757.43 Torr; 6 h; Autoclave; Hide Experimental Procedure

Jagtap, Samadhan A.; Sasaki, Takehiko; Bhanage, Bhalchandra M.

Journal of Molecular Catalysis A: Chemical, 2016 , vol. 414, p. 78 - 86 Title/Abstract Full Text View citing articles Show Details

99 % Chromat.

2.3. General experimental procedure for synthesis of alkenes viasemi-hydrogenation of alkynes

General procedure: To a 100 mL high-pressure reactor, phenylacetylene (1 mmol),Pd (0.96 molpercent) in a 10 mL THF were transferred under an inertatmosphere. The reactor was flushed three times with nitrogen then pressurized with desired 150 psi of syngas, then heated at70C with constant stirring (400 rpm) for 6 h. After the comple-tion of reaction, the reactor cooled down to room temperature andthe remaining syngas was carefully depressurized. The resultantreaction mixture filtered off by simple filtration. The filtrate was then collected in sample vial and the product was extracted for further analysis such as GC, GC–MS,1H &13C NMR and matched with those of authentic data. Selective experiments were performed in triplicate and it was observed that results showed variation of ±2percent. A

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With (bis(tricyclohexyl)phosphine)palladium(II) dichloride; hydrogen; triethylamine in benzene

T=155°C; P=53200 Torr; 6 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Ishii; Miyashita; Kamita; Hidai

Journal of the American Chemical Society, 1997 , vol. 119, # 27 p. 6448 - 6449 Title/Abstract Full Text View citing articles Show Details

A: 10 % Chromat.

With (bis(tricyclohexyl)phosphine)palladium(II) dichloride; hydrogen; triethylamine in benzene

T=155°C; P=53200 Torr; 6 h; Yields of byproduct given. Title compound not separated from byproducts;

Ishii; Miyashita; Kamita; Hidai

Journal of the American Chemical Society, 1997 , vol. 119, # 27 p. 6448 - 6449 Title/Abstract Full Text View citing articles Show Details

A: 9.8 %Chromat.

With BTPP; [Rh(acac)2(CO)2]; hydrogen in toluene

T=100°C; P=7500.75 Torr; 24 h; Autoclave; Catalytic behavior; regioselective reaction;

Zhang, Zongpeng; Wang, Qian; Chen, Caiyou; Han, Zhengyu; Dong, Xiu-Qin; Zhang, Xumu

Organic Letters, 2016 , vol. 18, # 13 p. 3290 - 3293 Title/Abstract Full Text View citing articles Show Details

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With (.eta.2,.eta.2-norbornadiene)(.eta.2-maleic anhydride)palladium(0); 1,3-bis-(2,6-diethylphenyl)imidazolium chloride; hydrogen; potassium tert-butylate in tetrahydrofuran

T=20°C; P=750.06 Torr; 2.75 h;

Sprengers, Jeroen W.; Wassenaar, Jeroen; Clement, Nicolas D.; Cavell, Kingsley J.; Elsevier, Cornells J.

Angewandte Chemie - International Edition, 2005 , vol. 44, # 13 p. 2026 - 2029 Title/Abstract Full Text View citing articles Show Details

With (.eta.2,.eta.2-norbornadiene)(.eta.2-maleic anhydride)palladium(0); hydrogen in tetrahydrofuran

T=20°C; P=750.06 Torr; 2 h;

Sprengers, Jeroen W.; Wassenaar, Jeroen; Clement, Nicolas D.; Cavell, Kingsley J.; Elsevier, Cornells J.

Angewandte Chemie - International Edition, 2005 , vol. 44, # 13 p. 2026 - 2029 Title/Abstract Full Text View citing articles Show Details

With hydrogen in hexane

T=25°C; P=7500.75 Torr; Catalytic behaviorKineticsMechanism; Reagent/catalyst; chemoselective reaction;

Markov; Bragina; Baeva; Mashkovskii; Rassolov; Yakushev; Vargaftik; Stakheev, A. Yu.

Kinetics and Catalysis, 2016 , vol. 57, # 5 p. 625 - 631 Kinet. Katal., 2016 , vol. 57, # 5 p. 629 - 635,7 Title/Abstract Full Text View citing articles Show Details

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59%

With palladium diacetate in cyclohexane

T=140°C; 24 h; Molecular sieveair;

Modak, Atanu; Deb, Arghya; Patra, Tuhin; Rana, Sujoy; Maity, Soham; Maiti, Debabrata

Chemical Communications, 2012 , vol. 48, # 35 p. 4253 - 4255 Title/Abstract Full Text View citing articles Show Details

90 %Chromat.

With palladium nanoparticles supported on fibrous silica in cyclohexane

T=130°C; 22 h; Molecular sieve;

Kundu, Pintu K.; Dhiman, Mahak; Modak, Atanu; Chowdhury, Arindam; Polshettiwar, Vivek; Maiti, Debabrata

ChemPlusChem, 2016 , vol. 81, # 11 p. 1142 - 1146 Title/Abstract Full Text View citing articles Show Details

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69%

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Stage #1: With bis(1,5-cyclooctadiene)diiridium(I) dichloride; benzyl Ether; IPNBSH in acetonitrile

18 h; Sealed tubeInert atmosphereGlovebox; Stage #2: With acetic acid in tetrahydrofuran; 2,2,2-trifluoroethanol; water

2 h; Sealed tubeInert atmosphereGlovebox; regioselective reaction;

Lundgren, Rylan J.; Thomas, Bryce N.

Chemical Communications, 2016 , vol. 52, # 5 p. 958 - 961 Title/Abstract Full Text View citing articles Show Details

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With silver tetrafluoroborate in dichloromethane

T=40°C; 3 h;

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Shibata, Yu; Kudo, Eiji; Sugiyama, Haruki; Uekusa, Hidehiro; Tanaka, Ken

Organometallics, 2016 , vol. 35, # 10 p. 1547 - 1552 Title/Abstract Full Text View citing articles Show Details

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99 %Chromat.

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Muñoz, Salvador B.; Daifuku, Stephanie L.; Brennessel, William W.; Neidig, Michael L.

Journal of the American Chemical Society, 2016 , vol. 138, # 24 p. 7492 - 7495 Title/Abstract Full Text View citing articles Show Details

in tetrahydrofuran

T=20°C; 0.0111111 h; Time;

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6 %Chromat.

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Muñoz, Salvador B.; Daifuku, Stephanie L.; Brennessel, William W.; Neidig, Michael L.

Journal of the American Chemical Society, 2016 , vol. 138, # 24 p. 7492 - 7495 Title/Abstract Full Text View citing articles Show Details

in tetrahydrofuran

T=20°C; 0.0333333 h; Time;

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With lithium chloride; palladium dichloride

3 h; Inert atmosphereSealed tubeHeating; Hide Experimental Procedure

4.4:Representative Procedure for Decarbonylation Reactions.

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Tolman, William Baker; Hillmyer, Marc A.; John, Alex; Hogan, Levi Thomas

Patent: US2016/194276 A1, 2016 ; Location in patent: Paragraph 0071-0072; 0074 ; Title/Abstract Full Text Show Details

General procedure: Inside a N2 filled glove box, a Schlenk tube was charged with the p-nitrophenylhydrocinnamate (0.075 g, 0.276 mmol, 1 equiv.), PdCl2 (0.004 g, 0.026 mmol, 10 mol percent or 0.002 g, 0.013 mmol, 5 mol percent). LiCl (0.010 g, 0.236 mmol, 100 mol percent) and DMPU (ca. 0.5 mL) was injected in followed by a Teflon-coated stir bar to yield a light yellow mixture. The Schlenk tube was sealed, brought outside the glove box and set in an oil bath pre-heated to 155-160° C. The reaction mixture was allowed to stir at this temperature for the stipulated period of time during which it darkened to a final red-brown color. At the end of the reaction, the Schlenk tube was removed from the oil bath and allowed to cool to room temperature. (a) For GC-MS analysis: The reaction mixture was transferred to a separatory funnel diluted with EtOAc (ca. 5 mL) and washed with 1M HCl (ca. 5 mL×2) and brine (ca. 5 mL). The organic layer was collected, dried over MgSO4, and analyzed by GC-MS using 1,3,5-trimethoxybenzene as an internal standard. (b) For olefin isolation (reaction carried out at 1 mmol scale): The reaction mixture was transferred to a separatory funnel, diluted with 1M HCl (ca. 10 mL). This mixture was extracted with pentane (ca. 5 ml×3). The combined organic layers were washed with 1M HCl (ca. 5 mL) and then separated. The pentane extracts were dried with MgSO4, and then concentrated under vacuum to remove the pentane. Analysis of the residue by 1H NMR spectroscopy showed the olefin product in >90percent purity.

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With lithium chloride; palladium dichloride

3 h; Inert atmosphereSealed tubeHeating; Hide Experimental Procedure

Tolman, William Baker; Hillmyer, Marc A.; John, Alex; Hogan, Levi Thomas

Patent: US2016/194276 A1, 2016 ; Location in patent: Paragraph 0071-0072; 0074 ; Title/Abstract Full Text Show Details

4.3:Representative Procedure for Decarbonylation Reactions.

Inside a N2 filled glove box, a Schlenk tube was charged with the p-nitrophenylhydrocinnamate (0.075 g, 0.276 mmol, 1 equiv.), PdCl2 (0.004 g, 0.026 mmol, 10 mol percent or 0.002 g, 0.013 mmol, 5 mol percent). LiCl (0.010 g, 0.236 mmol, 100 mol percent) and DMPU (ca. 0.5 mL) was injected in followed by a Teflon-coated stir bar to yield a light yellow mixture. The Schlenk tube was sealed, brought outside the glove box and set in an oil bath pre-heated to 155-160° C. The reaction mixture was allowed to stir at this temperature for the stipulated period of time during which it darkened to a final red-brown color. At the end of the reaction, the Schlenk tube was removed from the oil bath and allowed to cool to room temperature. (a) For GC-MS analysis: The reaction mixture was transferred to a separatory funnel diluted with EtOAc (ca. 5 mL) and washed with 1M HCl (ca. 5 mL×2) and brine (ca. 5 mL). The organic layer was collected, dried over MgSO4, and analyzed by GC-MS using 1,3,5-trimethoxybenzene as an internal standard. (b) For olefin isolation (reaction carried out at 1 mmol scale): The reaction mixture was transferred to a separatory funnel, diluted with 1M HCl (ca. 10 mL). This mixture was extracted with pentane (ca. 5 ml×3). The combined organic layers were washed with 1M HCl (ca. 5 mL) and then separated. The pentane extracts were dried with MgSO4, and then concentrated under vacuum to remove the pentane. Analysis of the residue by 1H NMR spectroscopy showed the olefin product in >90percent purity. A

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A: 30 %Chromat. B: 56 %Chromat.

With bis(acetylacetonate)nickel(II); N,N,N,N,-tetramethylethylenediamine in toluene

T=20°C; 12 h; Inert atmosphere;

Wu, Qiang; Wang, Lanlan; Jin, Rizhe; Kang, Chuanqing; Bian, Zheng; Du, Zhijun; Ma, Xiaoye; Guo, Haiquan; Gao, Lianxun

European Journal of Organic Chemistry, 2016 , vol. 2016, # 32 p. 5415 - 5422 Title/Abstract Full Text View citing articles Show Details

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A: 36% B: 60%

With anhydrous iron chloride; hydrogen; ethyl magnesium chloride in tetrahydrofuran

T=18°C; P=750.075 Torr; 20 h; Inert atmosphereSealed tube; Catalytic behavior; Reagent/catalystSolventTemperaturePressure;

Gieshoff, Tim N.; Villa, Matteo; Welther, Alice; Plois, Markus; Chakraborty, Uttam; Wolf, Robert; Jacobi Von Wangelin, Axel

Green Chemistry, 2015 , vol. 17, # 3 p. 1408 - 1413 Title/Abstract Full Text View citing articles Show Details

A: 56% B: 42%

With anhydrous iron chloride; hydrogen; ethyl magnesium chloride in tetrahydrofuran

T=18°C; P=3000.3 Torr; 1 h; Inert atmosphereSealed tube;

Gieshoff, Tim N.; Villa, Matteo; Welther, Alice; Plois, Markus; Chakraborty, Uttam; Wolf, Robert; Jacobi Von Wangelin, Axel

Green Chemistry, 2015 , vol. 17, # 3 p. 1408 - 1413 Title/Abstract Full Text View citing articles Show Details

With hydrogen; palladium in hexane

other solvents; other catalysts; KineticsMechanismRate constant;

Cerveny, Libor; Paseka, Ivo; Fialova, Eva; Ruzicka, Vlastimil

Collection of Czechoslovak Chemical Communications, 1987 , vol. 52, # 4 p. 1015 - 1020 Title/Abstract Full Text Show Details

With FeCl3-poly-1,2-butadiene-P(OC6H11)2; hydrogen; diisobutylaluminium hydride in benzene

T=25°C; further iron complexes on supports containing phosphorus-based coordinating groups; further solvents (heptane); Product distribution;

Sukhobok, L. N.; Potapov, G. P.; Luksha, V. G.; Krutii, V. N.; Polkovnikov, B. D.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 10 p. 2033 - 2035 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 10 p. 2310 - 2312 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 2690600 Find similar reactions

100 % Chromat.

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in tetrahydrofuran

T=0°C; 1 h;

Bandmann, Heinz; Bartik, Tamas; Bauckloh, Sylvia; Behler, Ansgar; Brille, Frank; et al.

Zeitschrift fuer Chemie (Stuttgart, Germany), 1990 , vol. 30, # 6 p. 193 - 204 Title/Abstract Full Text Show Details

T=20°C; Wittig Olefination; 10 h;

Liu, Wenbo; Li, Lu; Chen, Zhengwang; Li, Chao-Jun

Organic and Biomolecular Chemistry, 2015 , vol. 13, # 22 p. 6170 - 6174 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 40026964 Find similar reactions

C: 22 %Chromat.

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With trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); potassium carbonate; tris-(o-tolyl)phosphine in methanol; N,N-dimethyl acetamide

T=90°C; 24 h; Schlenk technique; Hide Experimental Procedure

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ETH ZURICH; SARRIA TORO, Juan Manuel; CHEN, Peter; DEN HARTOG, Tim

Patent: WO2015/67696 A1, 2015 ; Location in patent: Page/Page column 4; 5; 7 ; Title/Abstract Full Text Show Details

General procedure: In the glove box, a 5 ml . Young Schlenk (approximately 10 mL total volume) was equipped with a glass coated st ir bar. In the glove box, base (1.5 equiv ), methylenat ion reagent ( 1 .5 equiv), olefin (1 equiv). and catalyst (5 molpercent) were transferred to the vial. A degassed solvent mixture of a polar solvent (16 mL/mmol. substrate) and a ROH solvent (2 mL/mmol substrate) were added and the Schlenk was closed. After transferring the Schlenk outside the glove box, the reaction mixture was heated to 90 °C in an oil bath and st irred for 16 h. Then the reaction mixture was ra idly cooled to 0 °C in an ice bath. Consecutively undecane (0.4 equiv) as internal standard, EbO (45 ml . mmol substrate) and water (45 ml. /mmol substrate) were then added. The phases were separated and the aqueous phase was extracted with EbO (45 mL/mmol substrate). The combined organic phases were washed w ith brine (45 mL/mmol substrate), dried over MgS04 and analyzed by GC-MS. A

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A: 13% B: 68%

With tert.-butylhydroperoxide; palladium diacetate; toluene-4-sulfonic acid in water; acetonitrile

T=20°C; Wacker Oxidation; 3 h; chemoselective reaction;

Zhao, Jinwu; Liu, Li; Xiang, Shijian; Liu, Qiang; Chen, Huoji

Organic and Biomolecular Chemistry, 2015 , vol. 13, # 20 p. 5613 - 5616 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 41596784 Find similar reactions

A: 60 %Spectr. B: 40 %Spectr.

With bis(cyclopentadienyl)titanium dichloride; magnesium in tetrahydrofuran

T=0°C; Inert atmosphere; Hide Experimental Procedure

Khusainova; Khafizova; Tyumkina; Dzhemilev

Russian Journal of Organic Chemistry, 2015 , vol. 51, # 11 p. 1517 - 1523 Zh. Org. Khim., 2015 , vol. 51, # 11 p. 1551 - 1557,7 Title/Abstract Full Text View citing articles Show Details

Reactions of α-olefins with BCl3·SMe2 in the presence of catalyst Cp2TiCl2. General procedure.

General procedure: Into a glass reactor (50 mL) in an atmosphere of dry argon at stirring with a magnetic stirrer was charged in succession while cooling to 0 °C 5 mL of THF, 4 mg at of Mg powder, 1 mmol of α-olefin, 0.2 mmol of catalyst Cp2TiCl2, and 2 mmol of BCl3·SMe2. The excess of magnesium was filtered off, the solvent was evaporated, and 1-chloro-2-R-borirane was analyzed by NMR.

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Rx-ID: 63782 Find similar reactions

100%

With potassium hydroxide in ethylene glycol dimethyl ether

T=40°C; 0.5 h;

D'Incan, E.; Viout, P.

Tetrahedron, 1984 , vol. 40, # 18 p. 3421 - 3424 Title/Abstract Full Text View citing articles Show Details

100%

With potassium hydroxide in butan-1-ol

3 h; Heating;

Ogibin, Yu. N.; Sokolov, A. B.; Ilovaiskii, A. I.; Elison, M. N.; Nikishin, G. I.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 3.2 p. 561 - 566 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 3 p. 644 - 649 Title/Abstract Full Text View citing articles Show Details

99%

With [Ni0(1,5-cyclooctadiene)2]; 1,3-bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene in toluene T=130°C; 1 h; Reagent/catalystTemperatureTime;

Lee, Wei-Chih; Wang, Chun-Han; Lin, Yung-Huei; Shih, Wei-Chun; Ong, Tiow-Gan

Organic Letters, 2013 , vol. 15, # 20 p. 5358 - 5361 Title/Abstract Full Text View citing articles Show Details

Ramart-Lucas; Amagat

Bulletin de la Societe Chimique de France, 1932 , vol. <4> 51, p. 108,117 Full Text View citing articles Show Details

With sodium hydroxide; tetrabutylammomium bromide in water; toluene

T=75°C; var.: stirring rate, catalyst structure, catalyst concentration, temperature, counterion, aqueous hydroxide; Rate constantKineticsMechanism;

Halpern, Marc; Sasson, Yoel; Rabinovitz, Mordecai

Journal of Organic Chemistry, 1983 , vol. 48, # 7 p. 1022 - 1025 Title/Abstract Full Text View citing articles Show Details

With nBu4NPF6; hydridophosphonitecobalt(I) in acetonitrile T=30°C; 5 h; Irradiationvarious catalysts; with or without irradiation; Product distribution;

Onishi, Masayoshi; Hiraki, Katsuma; Ishida, Yasuhiro; Dakeshita, Kengo

Chemistry Letters, 1986 , p. 333 - 336 Title/Abstract Full Text Show Details

With cat.: DowexR 1 anion exchanger resin supported RhCl3 in ethanol; water Heatingvar. solv.: BuOH, THF, C2D5OD, add of var. quant. H2O, D2O; Product distribution;

Setty-Fichman, Merav; Blum, Jochanan; Sasson, Yoel; Eisen, Moris

Tetrahedron Letters, 1994 , vol. 35, # 5 p. 781 - 784 Title/Abstract Full Text View citing articles Show Details

With potassium hydroxide; butan-1-ol

substance of uncertain configuration;

Campbell; Young

Journal of the American Chemical Society, 1947 , vol. 69, p. 688 Full Text View citing articles Show Details

With potassium hydroxide; ethylene glycol

T=160°C; substance of uncertain configuration;

Koch

Journal of the Chemical Society, 1948 , p. 1123,1128 Full Text View citing articles Show Details

With sodium ethanolate

substance of uncertain configuration;

Stuurman

Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen, Series B: Physical Sciences, 1935 , vol. 38, p. 451 Chem. Zentralbl., 1935 , vol. 106, # II p. 991 Full Text View citing articles Show Details

T=300°C; Leiten ueber Palladium; substance of uncertain configuration;

Lewina; Zurikow

Zhurnal Obshchei Khimii, 1934 , vol. 4, p. 1250,1256 Chem. Zentralbl., 1936 , vol. 107, # I p. 4289 Full Text View citing articles Show Details

Lewina

Zhurnal Obshchei Khimii, 1939 , vol. 9, p. 2287,2288, 2289 Chem. Zentralbl., 1940 , vol. 111, # I p. 2455 Full Text View citing articles Show Details

Leiten ueber Aluminiumoxyd; substance of uncertain configuration;

Lewina; Derendjajewa; Fainsilberg

Zhurnal Obshchei Khimii, 1946 , vol. 16, p. 817,818 Chem.Abstr., 1947 , p. 1625 Full Text View citing articles Show Details

Lewina

Zhurnal Obshchei Khimii, 1939 , vol. 9, p. 2287,2288, 2289 Chem. Zentralbl., 1940 , vol. 111, # I p. 2455 Full Text View citing articles Show Details

Lewina

Zhurnal Obshchei Khimii, 1937 , vol. 7, p. 1587,1588 Chem. Zentralbl., 1937 , vol. 108, # II p. 3596 Full Text View citing articles Show Details

Leiten ueber Chrom(III)-oxyd; substance of uncertain configuration;

Lewina; Derendjajewa; Fainsilberg

Zhurnal Obshchei Khimii, 1946 , vol. 16, p. 817,818 Chem.Abstr., 1947 , p. 1625 Full Text View citing articles Show Details

Lewina

Zhurnal Obshchei Khimii, 1939 , vol. 9, p. 2287,2288, 2289 Chem. Zentralbl., 1940 , vol. 111, # I p. 2455 Full Text View citing articles Show Details

Lewina

Zhurnal Obshchei Khimii, 1937 , vol. 7, p. 1587,1588 Chem. Zentralbl., 1937 , vol. 108, # II p. 3596 Full Text View citing articles Show Details

With potassium hydroxide

Tiffeneau

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1904 , vol. 139, p. 482 Full Text View citing articles Show Details

With infusorial earht

T=500°C;

Ramart; Amagat

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1929 , vol. 188, p. 638 Full Text View citing articles Show Details

With chlorohydridotris(triphenylphosphine)ruthenium in toluene

Heating;

Stille, J. K.; Becker Y.

Journal of Organic Chemistry, 1980 , vol. 45, # 11 p. 2139 - 2145 Title/Abstract Full Text View citing articles Show Details

With cyclopalladated N-(p-tolyl)p-nitrobenzaldimine tetrafluoroborate

T=100°C; 19 h;

Wu, Guangzhong; Geib, Steven J.; Rheingold, Arnold L.; Heck, Richard F.

Journal of Organic Chemistry, 1988 , vol. 53, # 14 p. 3238 - 3241 Title/Abstract Full Text View citing articles Show Details

With nBu4NPF6; hydridophosphonitecobalt(I) in acetonitrile

T=30°C; 5 h; Irradiation; Yield given;

Onishi, Masayoshi; Hiraki, Katsuma; Ishida, Yasuhiro; Dakeshita, Kengo

Chemistry Letters, 1986 , p. 333 - 336 Title/Abstract Full Text Show Details

With DowexR 1 anion exchanger resin supported RhCl3 in ethanol; water

Heating; Yield given;

Setty-Fichman, Merav; Blum, Jochanan; Sasson, Yoel; Eisen, Moris

Tetrahedron Letters, 1994 , vol. 35, # 5 p. 781 - 784 Title/Abstract Full Text View citing articles Show Details

With Mg-AIR T=249.85°C; Product distribution; Further Variations:Catalysts;

Marinas; Aramendia; Borau; Jimenez; Urbano

Journal of Catalysis, 2002 , vol. 211, # 2 p. 556 - 559 Title/Abstract Full Text View citing articles Show Details

With Au/Ni immobilized on γ-alumina

T=170°C;

Smirnov; Lanin; Vasil'kov; Nikolaev; Murav'eva; Tyurina; Vlasenko

Russian Chemical Bulletin, 2005 , vol. 54, # 10 p. 2286 - 2289 Title/Abstract Full Text View citing articles Show Details

With Au-Ni/SiO2

T=170°C; in glas ampoules;

Vasil'kov, Alexander Yu.; Nikolaev, Sergey A.; Smirnov, Vladimir V.; Naumkin, Alexander V.; Volkov, Ilija O.; Podshibikhin, Vladislav L.

Mendeleev Communications, 2007 , vol. 17, # 5 p. 268 - 270 Title/Abstract Full Text View citing articles Show Details

With [Pt(1,4-bis(diphenylphosphanyl)butane)(H2O)2][OTf]2; hydrogen in chloroform

T=50°C; P=750.075 Torr;

Gottardo, Marina; Scarso, Alessandro; Paganelli, Stefano; Strukul, Giorgio

Advanced Synthesis and Catalysis, 2010 , vol. 352, # 13 p. 2251 - 2262 Title/Abstract Full Text View citing articles Show Details

With C54H48N2O4P2Ru in Sec-butyl alcohol

T=80°C; Inert atmosphere;

Ding, Fu; Doorslaer, Sabine Van; Cool, Peggie; Verpoort, Francis

Applied Organometallic Chemistry, 2011 , vol. 25, # 8 p. 601 - 607 Title/Abstract Full Text View citing articles Show Details

With C47H43IrN4; sodium t-butanolate in deuterated toluene

T=100°C; Inert atmosphereGlovebox; Kinetics; Concentration;

Knapp, Spring Melody M.; Shaner, Sarah E.; Kim, Daniel; Shopov, Dimitar Y.; Tendler, Jennifer A.; Pudalov, David M.; Chianese, Anthony R.

Organometallics, 2014 , vol. 33, # 2 p. 473 - 484 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 10021712 Find similar reactions

With hydrogen; 6-DPPon; [rhodium(I)(carbonyl)2(acetylacetonate)] in tetrahydrofuran

T=22°C; P=760 Torr; 20 h; Title compound not separated from byproducts;

Seiche, Wolfgang; Schuschkowski, Alexander; Breit, Bernhard

Advanced Synthesis and Catalysis, 2005 , vol. 347, # 11-13 p. 1488 - 1494 Title/Abstract Full Text View citing articles Show Details

With [rhodium(I)(carbonyl)2(acetylacetonate)]; phosphoric acid; hydrogen; 3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetra-oxa-3,9-diphosphaspiro[5.5]-undecane; methoxybenzene in dichloromethane

T=110°C; P=15514.9 Torr; 2 h; Autoclave;

Alhaffar, Mouheddin; Suleiman, Rami; Ali, Bassam El

Catalysis Communications, 2010 , vol. 11, # 8 p. 778 - 782 Title/Abstract Full Text View citing articles Show Details

With [RhCl(η2:η2-cycloocta-1,5-diene)]2; hydrogen; triphenylphosphine in toluene

T=50°C; P=37503.8 Torr; 17 h; Reagent/catalyst; regioselective reaction;

Madalska, Martyna; Loennecke, Peter; Hey-Hawkins, Evamarie

Journal of Molecular Catalysis A: Chemical, 2014 , vol. 383-384, p. 137 - 142 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 22083480 Find similar reactions

54%

With 1,10-phenanthroline; Cu(OH)2 in 1-methyl-pyrrolidin-2-one

T=180°C; 5 h; Inert atmosphereGreen chemistry;

Cadot, Stephane; Rameau, Nelly; Mangematin, Stephane; Pinel, Catherine; Djakovitch, Laurent

Green Chemistry, 2014 , vol. 16, # 6 p. 3089 - 3097 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps

Simonsen

1: glacial acetic acid; hydrogen bromide / 100 °C / im Rohr 2: natrium carbonate View Scheme

Journal of the Chemical Society, 1920 , vol. 117, p. 569 Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 32601107 Find similar reactions

With C29H36N3O4Ru in tetrahydrofuran

T=35°C; 3 h; Inert atmosphere;

Keitz, Benjamin K.; Endo, Koji; Patel, Paresma R.; Herbert, Myles B.; Grubbs, Robert H.

Journal of the American Chemical Society, 2012 , vol. 134, # 1 p. 693 - 699 Title/Abstract Full Text View citing articles Show Details

With C31H39ClN3O4Ru in tetrahydrofuran

T=35°C; 3 h; Inert atmosphere;

Keitz, Benjamin K.; Endo, Koji; Patel, Paresma R.; Herbert, Myles B.; Grubbs, Robert H.

Journal of the American Chemical Society, 2012 , vol. 134, # 1 p. 693 - 699 Title/Abstract Full Text View citing articles Show Details

With C35H47N3O4Ru in tetrahydrofuran

T=23°C; 6.5 h; Inert atmosphere; Catalytic behavior; Reagent/catalystTimeTemperature; Overall yield = 91 percent;

Rosebrugh, Lauren E.; Herbert, Myles B.; Marx, Vanessa M.; Keitz, Benjamin K.; Grubbs, Robert H.

Journal of the American Chemical Society, 2013 , vol. 135, # 4 p. 1276 - 1279 Title/Abstract Full Text View citing articles Show Details

With C37H49N3O4Ru in tetrahydrofuran

T=35°C; 7 h; Catalytic behavior; Reagent/catalystTime; diastereoselective reaction;

Bronner, Sarah M.; Herbert, Myles B.; Patel, Paresma R.; Marx, Vanessa M.; Grubbs, Robert H.

Chemical Science, 2014 , vol. 5, # 10 p. 4091 - 4098 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 37318171 Find similar reactions

A: 58 %Chromat. B: 8 %Chromat. C: 7 %Chromat.

With [(P(OEt)3)2Ni(1,3-cyclooctadiene)]

T=160°C; P=4137.29 Torr; 72 h; Schlenk techniqueInert atmosphere;

Reyes-Sanchez, Adan; Garcia-Ventura, Ilnett; Garcia, Juventino J.

Dalton Transactions, 2014 , vol. 43, # 4 p. 1762 - 1768 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 37318172 Find similar reactions

A: 14% B: 51%

Reyes-Sanchez, Adan; Garcia-Ventura, Ilnett; Garcia, Juventino J.

Dalton Transactions, 2014 , vol. 43, # 4 p. 1762 - 1768 Title/Abstract Full Text View citing articles Show Details

With bis(1,5-cyclooctadiene)nickel (0)

T=180°C; 72 h; Schlenk techniqueInert atmosphere;

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Rx-ID: 37318173 Find similar reactions

A: 12% B: 29%

With [(1,2-bis(diisopropylphosphino)ethane)NiCl2]

T=180°C; 72 h; Schlenk techniqueInert atmosphere;

Reyes-Sanchez, Adan; Garcia-Ventura, Ilnett; Garcia, Juventino J.

Dalton Transactions, 2014 , vol. 43, # 4 p. 1762 - 1768 Title/Abstract Full Text View citing articles Show Details

A: 75 %Chromat. B: 12 %Chromat.

With [(dippf)Ni(1,3-cyclooctadiene)]

T=160°C; P=4137.29 Torr; 72 h; Schlenk techniqueInert atmosphere; Reagent/catalyst;

Reyes-Sanchez, Adan; Garcia-Ventura, Ilnett; Garcia, Juventino J.

Dalton Transactions, 2014 , vol. 43, # 4 p. 1762 - 1768 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 37318174 Find similar reactions

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A: 16 %Chromat. B: 51 %Chromat. C: 5 %Chromat.

Reyes-Sanchez, Adan; Garcia-Ventura, Ilnett; Garcia, Juventino J.

Dalton Transactions, 2014 , vol. 43, # 4 p. 1762 - 1768 Title/Abstract Full Text View citing articles Show Details

With Ni(PEt3)2Cl2

T=160°C; P=4137.29 Torr; 72 h; Schlenk techniqueInert atmosphere; Reagent/catalystTemperature;

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Synthesize Find similar Rx-ID: 37335037 Find similar reactions

Multi-step reaction with 3 steps 1: 1,2,3-Benzotriazole; thionyl chloride / dichloromethane / 2.5 h / 25 °C / |Inert atmosphere; |Schlenk technique 2: bis(1,5-cyclooctadiene)nickel (0); diphenylcyclohexyl phosphine; triethylamine; triethylsilyl trifluoromethanesulphonate / toluene / 2 h / 25 °C / 760.05 Torr 3: C40H37ClIrN5; sodium t-butanolate / benzene-d6 / 80 °C / |Inert atmosphere; |Glovebox View Scheme

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Knapp, Spring Melody M.; Shaner, Sarah E.; Kim, Daniel; Shopov, Dimitar Y.; Tendler, Jennifer A.; Pudalov, David M.; Chianese, Anthony R.

Organometallics, 2014 , vol. 33, # 2 p. 473 - 484 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 37335045 Find similar reactions

Multi-step reaction with 2 steps 1: bis(1,5-cyclooctadiene)nickel (0); diphenylcyclohexyl phosphine; triethylamine; triethylsilyl trifluoromethanesulphonate / toluene / 2 h / 25 °C / 760.05 Torr 2: C40H37ClIrN5; sodium t-butanolate / benzene-d6 / 80 °C / |Inert atmosphere; |Glovebox View Scheme

Knapp, Spring Melody M.; Shaner, Sarah E.; Kim, Daniel; Shopov, Dimitar Y.; Tendler, Jennifer A.; Pudalov, David M.; Chianese, Anthony R.

Organometallics, 2014 , vol. 33, # 2 p. 473 - 484 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 37335050 Find similar reactions

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Multi-step reaction with 4 steps 1: lithium aluminium deuteride / tetrahydrofuran / 16 h / 0 - 25 °C / |Inert atmosphere; |Schlenk technique 2: 1,2,3-Benzotriazole; thionyl chloride / dichloromethane / 2.5 h / 25 °C / |Inert atmosphere; |Schlenk technique 3: bis(1,5-cyclooctadiene)nickel (0); diphenylcyclohexyl phosphine; triethylamine; triethylsilyl trifluoromethanesulphonate / toluene / 2 h / 25 °C / 760.05 Torr 4: C40H37ClIrN5; sodium t-butanolate / benzene-d6 / 80 °C / |Inert atmosphere; |Glovebox View Scheme

Knapp, Spring Melody M.; Shaner, Sarah E.; Kim, Daniel; Shopov, Dimitar Y.; Tendler, Jennifer A.; Pudalov, David M.; Chianese, Anthony R.

Organometallics, 2014 , vol. 33, # 2 p. 473 - 484 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 37335061 Find similar reactions

With C40H37ClIrN5; sodium t-butanolate in benzene-d6

T=80°C; Inert atmosphereGlovebox;

Knapp, Spring Melody M.; Shaner, Sarah E.; Kim, Daniel; Shopov, Dimitar Y.; Tendler, Jennifer A.; Pudalov, David M.; Chianese, Anthony R.

Organometallics, 2014 , vol. 33, # 2 p. 473 - 484 Title/Abstract Full Text View citing articles Show Details

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43%

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Rx-ID: 37499704 Find similar reactions

With styrene; 1,1'-bis-(diphenylphosphino)ferrocene; tetrakis(triphenylphosphine) palladium(0); 1-trans-IODO-4-CYCLOHEXYL; α,α,α-trifluorotoluene; N,N-dicyclohexylmethylamine

T=110°C; Heck Reaction; 5 h; Inert atmosphereGlovebox; Mechanism;

Zou, Yinjun; Zhou, Jianrong

Chemical Communications, 2014 , vol. 50, # 28 p. 3725 - 3728 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 37499705 Find similar reactions

A: 41% B: 13%

Zou, Yinjun; Zhou, Jianrong

Chemical Communications, 2014 , vol. 50, # 28 p. 3725 - 3728 Title/Abstract Full Text View citing articles Show Details

With 1,1'-bis-(diphenylphosphino)ferrocene; tetrakis(triphenylphosphine) palladium(0); α,α,α-trifluorotoluene; N,N-dicyclohexylmethylamine

T=110°C; Heck Reaction; 12 h; Inert atmosphereGlovebox; Mechanism;

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85 %Chromat.

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Rx-ID: 37570652 Find similar reactions

With silver-deposited TiO2 in isopropyl alcohol

T=24.84°C; 3 h; Inert atmosphereIrradiation;

Kominami, Hiroshi; Yamamoto, Satoshi; Imamura, Kazuya; Tanaka, Atsuhiro; Hashimoto, Keiji

Chemical Communications, 2014 , vol. 50, # 35 p. 4558 - 4560 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 38012534 Find similar reactions

With hydrogenchloride; toluene

T=420°C; P=46 Torr; 7 h; Kinetics; TimeTemperaturePressure;

Julio, Libia L.; Lezama, Jesus; Maldonado, Alexis; Mora, Jose R.; Chuchani, Gabriel

Journal of Physical Organic Chemistry, 2014 , vol. 27, # 5 p. 450 - 455 Title/Abstract Full Text View citing articles Show Details

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With ZSM-5 zeolite T=550°C; Temperature;

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Li, Xiangyu; Li, Jian; Zhou, Guoqiang; Feng, Yu; Wang, Yujue; Yu, Gang; Deng, Shubo; Huang, Jun; Wang, Bin

Applied Catalysis A: General, 2014 , vol. 481, p. 173 - 182 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 39957562 Find similar reactions

Parfenova, Lyudmila V.; Berestova, Tatyana V.; Kovyazin, Pavel V.; Yakupov, Aydar R.; Mesheryakova, Ekaterina S.; Khalilov, Leonard M.; Dzhemilev, Usein M.

Journal of Organometallic Chemistry, 2014 , vol. 772, p. 292 - 298 Title/Abstract Full Text View citing articles Show Details

With [Zr(η5-C5H5)Cl3]; magnesium in tetrahydrofuran

T=0 - 22°C; 72 h; Inert atmosphereSchlenk technique; diastereoselective reaction; Hide Experimental Procedure

Reaction of allylbenzenes (1a–c) with EtAlCl2 (Et2AlCl) and Mg in the presence of complexes 2a–j

General procedure: A 10ml flask equipped with a magnetic stirrer and filled with argon was loaded with 0.2mmol of complexes (2a–j), 4mmol of Mg (powder), 3ml of a solvent (THF or Et2O) and 4mmol of allylbenzene (1a–c). The mixture was cooled to 0°C and 5mmol of EtAlCl2 or Et2AlCl was added dropwise. The reaction mixture was stirred for 72h at 20–30°C. Further, the mixture was decomposed with 10percent HCl or DCl at 0°C. The products were extracted with Et2O; the organic layer was dried over Na2SO4 and analyzed by GC and GC–MS. The products 8,9a–c were isolated by column chromatography on silica gel (hexane/Et2O 5:1). NMR characteristics and mass-spectral data of 8a, 9a were identical to the literature data [2d]. The oxidation of the reaction mixture with tBuOOH for 24h, subsequent hydrolysis with 10percent HCl and extraction with Et2O gave alcohol 16a, which was isolated by column chromatography on silica gel (hexane/ethyl acetate 97:3). A

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Synthesize Find similar Rx-ID: 39957563 Find similar reactions

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With Cp(1-neomenthylindenyl)ZrCl2; magnesium in tetrahydrofuran

T=0 - 22°C; 72 h; Inert atmosphereSchlenk technique; stereoselective reaction; Hide Experimental Procedure

Parfenova, Lyudmila V.; Berestova, Tatyana V.; Kovyazin, Pavel V.; Yakupov, Aydar R.; Mesheryakova, Ekaterina S.; Khalilov, Leonard M.; Dzhemilev, Usein M.

Journal of Organometallic Chemistry, 2014 , vol. 772, p. 292 - 298 Title/Abstract Full Text View citing articles Show Details

Reaction of allylbenzenes (1a–c) with EtAlCl2 (Et2AlCl) and Mg in the presence of complexes 2a–j

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Rx-ID: 39957574 Find similar reactions

With zirconocene dichloride; magnesium in tetrahydrofuran

T=0 - 22°C; 72 h; Inert atmosphereSchlenk technique; diastereoselective reaction; Hide Experimental Procedure

Parfenova, Lyudmila V.; Berestova, Tatyana V.; Kovyazin, Pavel V.; Yakupov, Aydar R.; Mesheryakova, Ekaterina S.; Khalilov, Leonard M.; Dzhemilev, Usein M.

Journal of Organometallic Chemistry, 2014 , vol. 772, p. 292 - 298 Title/Abstract Full Text View citing articles Show Details

Reaction of allylbenzenes (1a–c) with EtAlCl2 (Et2AlCl) and Mg in the presence of complexes 2a–j

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Synthesize Find similar Rx-ID: 39957580 Find similar reactions

A: 29 %Chromat. B: 16 %Chromat. C: 10 %Chromat. D: 9 %Chromat. E: 21 %Chromat.

Parfenova, Lyudmila V.; Berestova, Tatyana V.; Kovyazin, Pavel V.; Yakupov, Aydar R.; Mesheryakova, Ekaterina S.; Khalilov, Leonard M.; Dzhemilev, Usein M.

Journal of Organometallic Chemistry, 2014 , vol. 772, p. 292 - 298 Title/Abstract Full Text View citing articles Show Details

Stage #1: With [Zr(η5-C5H5)Cl3]; ethylaluminum dichloride; magnesium in tetrahydrofuran

T=0 - 22°C; 72 h; Inert atmosphereSchlenk technique; Stage #2: With DCl in tetrahydrofuran; water-d2

Inert atmosphereSchlenk technique; Hide Experimental Procedure

Reaction of allylbenzenes (1a–c) with EtAlCl2 (Et2AlCl) and Mg in the presence of complexes 2a–j

chromatography on silica gel (hexane/Et2O 5:1). NMR characteristics and mass-spectral data of 8a, 9a were identical to the literature data [2d]. The oxidation of the reaction mixture with BuOOH for 24h, subsequent hydrolysis with 10percent HCl and extraction with Et2O gave alcohol 16a, which was isolated by column chromatography on silica gel (hexane/ethyl acetate 97:3). A

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Synthesize Find similar Rx-ID: 39957582 Find similar reactions

A: 10 %Chromat. B: 9 %Chromat. C: 14 %Chromat. D: 29 %Chromat.

Stage #1: With zirconocene dichloride; diethylaluminium chloride; magnesium in tetrahydrofuran

T=0 - 22°C; 72 h; Inert atmosphereSchlenk technique; Stage #2: With hydrogen chloride in tetrahydrofuran; water-d2

Inert atmosphereSchlenk technique; Hide Experimental Procedure

Parfenova, Lyudmila V.; Berestova, Tatyana V.; Kovyazin, Pavel V.; Yakupov, Aydar R.; Mesheryakova, Ekaterina S.; Khalilov, Leonard M.; Dzhemilev, Usein M.

Journal of Organometallic Chemistry, 2014 , vol. 772, p. 292 - 298 Title/Abstract Full Text View citing articles Show Details

Reaction of allylbenzenes (1a–c) with EtAlCl2 (Et2AlCl) and Mg in the presence of complexes 2a–j

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Synthesize Find similar Rx-ID: 39957583 Find similar reactions

A: 24 %Chromat. B: 14 %Chromat. C: 7 %Chromat. F: 18 %Chromat.

Stage #1: With Cp(1-neomenthylindenyl)ZrCl2; ethylaluminum dichloride; magnesium in tetrahydrofuran

T=0 - 22°C; 72 h; Inert atmosphereSchlenk technique; Stage #2: With DCl in tetrahydrofuran; water-d2

Inert atmosphereSchlenk technique; Hide Experimental Procedure

Parfenova, Lyudmila V.; Berestova, Tatyana V.; Kovyazin, Pavel V.; Yakupov, Aydar R.; Mesheryakova, Ekaterina S.; Khalilov, Leonard M.; Dzhemilev, Usein M.

Journal of Organometallic Chemistry, 2014 , vol. 772, p. 292 - 298 Title/Abstract Full Text View citing articles Show Details

Reaction of allylbenzenes (1a–c) with EtAlCl2 (Et2AlCl) and Mg in the presence of complexes 2a–j

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Rx-ID: 34654574 Find similar reactions

A: 6 %Spectr. B: 84 %Spectr.

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Larsson, Johanna M.; Szabó, Kálmán J.

Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 443 - 455 Title/Abstract Full Text View citing articles Show Details

With tetrakis(acetonitrile)palladium(II) tetrafluoroborate in dimethylsulfoxide-d6; d(4)-methanol

T=50°C; 15 h;

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Rx-ID: 34654578 Find similar reactions

Larsson, Johanna M.; Szabó, Kálmán J.

Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 443 - 455 Title/Abstract Full Text View citing articles Show Details

in dimethylsulfoxide-d6; d(4)-methanol

T=50°C;

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Synthesize Find similar Rx-ID: 34654580 Find similar reactions

A: 23 %Spectr. B: 69 %Spectr.

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Stage #1: 1-Phenyl-2-propen-1-ol With tetrakis(acetonitrile)palladium(II) tetrafluoroborate in dimethylsulfoxide-d6; d(4)-methanol

T=50°C; 15 h; Stage #2: 1,1,1,2,2,2-hexamethyldisilane With tetrakis(acetonitrile)palladium(II) tetrafluoroborate in dimethylsulfoxide-d6; d(4)-methanol

T=50°C; 15 h;

Larsson, Johanna M.; Szabó, Kálmán J.

Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 443 - 455 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 34654586 Find similar reactions

Multi-step reaction with 2 steps 1: silver tetrafluoroborate / 0.17 h / |Inert atmosphere; |Darkness 2: dimethylsulfoxide-d6; d(4)-methanol / 50 °C View Scheme

Larsson, Johanna M.; Szabó, Kálmán J.

Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 443 - 455 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 34654592 Find similar reactions

Multi-step reaction with 2 steps 1: tetrakis(acetonitrile)palladium(II) tetrafluoroborate / dimethyl sulfoxide / 15 h / 50 °C 2: tetrakis(acetonitrile)palladium(II) tetrafluoroborate / dimethylsulfoxide-d6; d(4)-methanol / 15 h / 50 °C View Scheme

Larsson, Johanna M.; Szabó, Kálmán J.

Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 443 - 455 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1.1: boron trifluoride diethyl etherate / dimethyl sulfoxide / 0.17 h / 20 °C / |Inert atmosphere 1.2: 0.17 h / 20 °C / |Inert atmosphere 2.1: silver tetrafluoroborate / 0.17 h / |Inert atmosphere; |Darkness 3.1: dimethylsulfoxide-d6; d(4)-methanol / 50 °C View Scheme

Larsson, Johanna M.; Szabó, Kálmán J.

Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 443 - 455 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 35188198 Find similar reactions

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Frazier, Brenda A.; Williams, Valerie A.; Wolczanski, Peter T.; Bart, Suzanne C.; Meyer, Karsten; Cundari, Thomas R.; Lobkovsky, Emil B.

Inorganic Chemistry, 2013 , vol. 52, # 6 p. 3295 - 3312 Title/Abstract Full Text View citing articles Show Details

in benzene-d6

T=23°C; 156 h; Inert atmosphereSealed tube;

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Synthesize Find similar Rx-ID: 35668427 Find similar reactions

A: 6 %Chromat. B: 16 %Chromat. C: 18 %Chromat. D: 47 %Chromat.

With water

T=120°C; 2 h; Sealed tube;

Simion, Alina-Marieta; Arimura, Takashi; Simion, Cristian

Comptes Rendus Chimie, 2013 , vol. 16, # 5 p. 476 - 481 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 35668432 Find similar reactions

Multi-step reaction with 2 steps 1: water / 3 h / |Reflux; |Sealed tube 2: water; rhodium contaminated with carbon / 2 h / 120 °C / |Sealed tube View Scheme

Simion, Alina-Marieta; Arimura, Takashi; Simion, Cristian

Comptes Rendus Chimie, 2013 , vol. 16, # 5 p. 476 - 481 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 35668435 Find similar reactions

A: 15 %Chromat. B: 18 %Chromat. C: 7 %Chromat.

With rhodium contaminated with carbon; water

T=120°C; 2 h; Sealed tube;

Simion, Alina-Marieta; Arimura, Takashi; Simion, Cristian

Comptes Rendus Chimie, 2013 , vol. 16, # 5 p. 476 - 481 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 35668436 Find similar reactions

A: 16 %Chromat. B: 9 %Chromat.

With rhodium contaminated with carbon; water

T=120°C; 2 h; Sealed tube;

Simion, Alina-Marieta; Arimura, Takashi; Simion, Cristian

Comptes Rendus Chimie, 2013 , vol. 16, # 5 p. 476 - 481 Title/Abstract Full Text View citing articles Show Details

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Find similar Rx-ID: 35668438 Find similar reactions

A: 5.6 %Chromat. B: 94 %Chromat.

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With water

1 h; Reflux; Time;

Simion, Alina-Marieta; Arimura, Takashi; Simion, Cristian

Comptes Rendus Chimie, 2013 , vol. 16, # 5 p. 476 - 481 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 35668439 Find similar reactions

A: 6 %Chromat. B: 9 %Chromat. C: 84.5 %Chromat.

With water

1 h; Reflux; Time;

Simion, Alina-Marieta; Arimura, Takashi; Simion, Cristian

Comptes Rendus Chimie, 2013 , vol. 16, # 5 p. 476 - 481 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 36381194 Find similar reactions

With samarium diiodide; tert-butyl alcohol in tetrahydrofuran

T=-78 - 20°C; Inert atmosphere; Hide Experimental Procedure

Schaefer, Sara L.; Roberts, Connor L.; Volz, Erasmus O.; Grasso, Monika R.; O'Neil, Gregory W.

Tetrahedron Letters, 2013 , vol. 54, # 45 p. 6125 - 6128 Title/Abstract Full Text View citing articles Show Details

Alkene 28

General procedure: To a freshly prepared solution of SmI2 (0.1 M, 10.2 mL) at -78 °C was added degassed tBuOH(290 μL, 3.06 mmol) and the mixture was warmed to 0 °C for 10 min. The solution was cooledto -78 °C before adding 26 (0.050 g, 0.14) and the mixture was then warmed to roomtemperature for 1 h. The reaction was quenched with aq. NH4Cl (25 mL) and extracted with ethylacetate (2 x 15 mL). The combined organic extracts were dried over MgSO4 and concentrated in vacuo. Purification by flash column chromatography on silica (20:1 hexanes:ethyl acetate)afforded 28 (21 mg, 66percent). IR (neat) 2955, 2928, 2856, 1737, 1716, 1590, 1562, 1472, 1437 cm-1. 1H NMR (500 MHz, CDCl3): δ 7.37 (d, J = 1.6 Hz, 1H), 7.08 (dd, J = 8.3, 1.6 Hz, 1H), 6.83(d, J = 8.3 Hz, 1H), 5.92 (m, 1H), 5.08 (s, 1H), 5.06 (dd, J = 6.7, 1.2 Hz, 1H), 3.87 (s, 3H), 3.30(d, J = 6.6 Hz, 2H). 13C NMR (126 MHz, CDCl3): δ 154.4, 137.0, 133.4, 130.4, 128.5, 125.9,116.1, 111.8, 56.3, 38.7. A

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Rx-ID: 36381196 Find similar reactions

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With samarium diiodide; tert-butyl alcohol in tetrahydrofuran

T=-78 - 20°C; Inert atmosphere; Hide Experimental Procedure

Schaefer, Sara L.; Roberts, Connor L.; Volz, Erasmus O.; Grasso, Monika R.; O'Neil, Gregory W.

Tetrahedron Letters, 2013 , vol. 54, # 45 p. 6125 - 6128 Title/Abstract Full Text View citing articles Show Details

Alkene 28

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Rx-ID: 36513256 Find similar reactions

With iron(II) chloride in 1-methyl-pyrrolidin-2-one; m-xylene

T=20°C; 6 h;

Gaertner, Dominik; Konnerth, Hannelore; Von Wangelin, Axel Jacobi

Catalysis Science and Technology, 2013 , vol. 3, # 10 p. 2541 - 2545 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 36513257 Find similar reactions

With iron(II) chloride in tetrahydrofuran

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Gaertner, Dominik; Konnerth, Hannelore; Von Wangelin, Axel Jacobi

T=20°C; 6 h;

Catalysis Science and Technology, 2013 , vol. 3, # 10 p. 2541 - 2545 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 36875989 Find similar reactions

With Titanium(IV) oxide in isopropyl alcohol

60 h; IrradiationInert atmosphere;

Li, Yue; Ji, Hongwei; Chen, Chuncheng; Ma, Wanhong; Zhao, Jincai

Angewandte Chemie - International Edition, 2013 , vol. 52, # 48 p. 12636 - 12640 Angew. Chem., 2013 , vol. 125, # 48 p. 12868 - 12872,5 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 3379462 Find similar reactions

With hydrogen; PtGe in ethanol

T=59.9°C; influence of Ge content on the rate constant; Rate constantProduct distribution;

Galvagno, S.; Poltarzewski, Z.; Donato, A.; Neri, G.; Pietropaolo, R.

Journal of the Chemical Society, Chemical Communications, 1986 , # 23 p. 1729 - 1731 Title/Abstract Full Text View citing articles Show Details

With hydrogen in n-heptane

T=89.84°C; P=7500.75 Torr;

MacHado, Bruno F.; Morales-Torres, Sergio; Perez-Cadenas, Agustin F.; Maldonado-Hodar, Francisco J.; Carrasco-Marin, Francisco; Silva, Adrian M.T.; Figueiredo, Jose L.; Faria, Joaquim L.

Applied Catalysis A: General, 2012 , vol. 425-426, p. 161 - 169 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 32600561 Find similar reactions

With iron (+/-)-(N,N'-bis(pyridin-2-ylmethylene)cyclohexane-1,2-diamine)dichloride in tetrahydrofuran

T=-20°C; 0.25 h;

Le Bailly, Bryden A. F.; Greenhalgh, Mark D.; Thomas, Stephen P.

Chemical Communications, 2012 , vol. 48, # 10 p. 1580 - 1582 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 33482870 Find similar reactions

Multi-step reaction with 2 steps 1: pyridine 2: hydrogen / toluene / 16 h / 60 °C View Scheme

Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Chemical Communications, 2012 , vol. 48, # 53 p. 6723 - 6725 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 33482877 Find similar reactions

A: 89% B: 10%

With hydrotalcite-supported Au nanoparticles in toluene

T=80°C; 3 h; Inert atmosphere; chemoselective reaction;

Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Chemical Communications, 2012 , vol. 48, # 53 p. 6723 - 6725 Title/Abstract Full Text View citing articles Show Details

Synthesize

Find similar Rx-ID: 33482878 Find similar reactions

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With hydrogen in toluene

T=80°C; P=760.051 Torr; 12 h; chemoselective reaction;

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Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Chemical Communications, 2012 , vol. 48, # 53 p. 6723 - 6725 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 33482879 Find similar reactions

With hydrogen in toluene

T=80°C; P=760.051 Torr; 12 h; chemoselective reaction;

Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Chemical Communications, 2012 , vol. 48, # 53 p. 6723 - 6725 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 33482888 Find similar reactions

With hydrogen in toluene

T=60°C; 16 h; chemoselective reaction;

Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Chemical Communications, 2012 , vol. 48, # 53 p. 6723 - 6725 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 33482890 Find similar reactions

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Multi-step reaction with 2 steps 1: pyridine 2: hydrotalcite-supported Au nanoparticles / toluene / 3 h / 80 °C / Inert atmosphere View Scheme

Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Chemical Communications, 2012 , vol. 48, # 53 p. 6723 - 6725 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 33482891 Find similar reactions

Multi-step reaction with 2 steps 1: pyridine 2: hydrogen / toluene / 12 h / 80 °C / 760.05 Torr View Scheme

Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Chemical Communications, 2012 , vol. 48, # 53 p. 6723 - 6725 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 33482892 Find similar reactions

Multi-step reaction with 2 steps 1: pyridine 2: hydrogen / toluene / 12 h / 80 °C / 760.05 Torr View Scheme

Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Chemical Communications, 2012 , vol. 48, # 53 p. 6723 - 6725 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 33724082 Find similar reactions

A: 31% B: 64%

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With Rh(acac)(CO)2; 3,3',5,5'-tetra(2,4-difluorophenyl)-2,2',6,6'-tetra((di-1-pyrrolylphosphino)oxy)-1,1'-biphenyl; hydrogen in toluene

T=120°C; P=3800.26 Torr; 2 h; Autoclave; regioselective reaction;

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Cai, Chaoxian; Yu, Shichao; Cao, Bonan; Zhang, Xumu

Chemistry - A European Journal, 2012 , vol. 18, # 32 p. 9992 - 9998 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 34285562 Find similar reactions

A: 34% B: 95%

With 1-n-butyl-3-methylimidazolim bromide

T=90°C; 1 h; Inert atmosphereGreen chemistry; ConcentrationTemperatureTime;

Liu, Yajun; Xu, Yongnan; Jung, Sun Ho; Chae, Junghyun

Synlett, 2012 , vol. 23, # 18 p. 2692 - 2698,7 Title/Abstract Full Text Show Details

Liu, Yajun; Xu, Yongnan; Jung, Sun Ho; Chae, Junghyun

Synlett, 2012 , vol. 23, # 18 p. 2692 - 2698 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 34285579 Find similar reactions

Multi-step reaction with 2 steps 1: pyridine / 20 °C

Liu, Yajun; Xu, Yongnan; Jung, Sun Ho; Chae, Junghyun

Synlett, 2012 , vol. 23, # 18 p. 2692 - 2698,7

2: 1-n-butyl-3-methylimidazolim bromide / 1 h / 90 °C / |Inert atmosphere; |Green chemistry View Scheme

Title/Abstract Full Text Show Details

Liu, Yajun; Xu, Yongnan; Jung, Sun Ho; Chae, Junghyun

Synlett, 2012 , vol. 23, # 18 p. 2692 - 2698 Title/Abstract Full Text View citing articles Show Details

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100%

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Rx-ID: 2068103 Find similar reactions

Keinan, Ehud; Greenspoon, Noam

Tetrahedron Letters, 1982 , vol. 23, # 2 p. 241 - 244 Title/Abstract Full Text View citing articles Show Details

With tetrakis(triphenylphosphine) palladium(0); tri-n-butyl-tin hydride in tetrahydrofuran

77%

With sodium tetrahydroborate; nickel dichloride in methanol

T=20°C; 0.166667 h;

Yin, Biao-Lin; Cai, Cong-Bi; Lai, Jin-Qiang; Zhang, Ze-Ren; Huang, Li; Xu, Li-Wen; Jiang, Huan-Feng

Advanced Synthesis and Catalysis, 2011 , vol. 353, # 18 p. 3319 - 3324 Title/Abstract Full Text View citing articles Show Details

32%

With tetraethylammonium tosylate; benzaldehyde; bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide

electrochemical reduction;

Qiu, Weiming; Wang, Zhiqin

Journal of the Chemical Society, Chemical Communications, 1989 , p. 356 - 357 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 3821289 Find similar reactions

94%

With carbon monoxide in tetrahydrofuran; water

T=110°C; P=6840.46 Torr; 3 h; Autoclave; chemoselective reaction;

Mikami, Yusuke; Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Tetrahedron Letters, 2010 , vol. 51, # 41 p. 5466 - 5468 Title/Abstract Full Text View citing articles Show Details

70%

With sodium tetrahydroborate; bis(tetra-n-butylammonium) tetrakis(benzenethiolato-.mu.3-sulphido-iron) in ethanol; acetonitrile

T=25°C; 3 h;

Itoh, Takashi; Nagano, Tetsuo; Sato, Mitsuo; Hirobe, Masaaki

Tetrahedron Letters, 1989 , vol. 30, # 46 p. 6387 - 6388 Title/Abstract Full Text View citing articles Show Details

98 %Chromat.

With isopropyl alcohol in toluene

T=110°C; 4 h; Inert atmosphere; chemoselective reaction;

Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi

Molecules, 2011 , vol. 16, # 10 p. 8209 - 8227 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 31881032 Find similar reactions

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Palacios, Laura; Miao, Xiaowei; Di Giuseppe, Andrea; Pascal, Simon; Cunchillos, Carmen; Castarlenas, Ricardo; Perez-Torrente, Jesus J.; Lahoz, Fernando J.; Dixneuf, Pierre H.; Oro, Luis A.

Organometallics, 2011 , vol. 30, # 19 p. 5208 - 5213 Title/Abstract Full Text View citing articles Show Details

in toluene

T=20°C; 1.25 h;

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Rx-ID: 33050540 Find similar reactions

A: 6%

With platinum in toluene

T=70°C; 3 h; regioselective reaction;

El Malki, Abdelghani; Hannioui, Abdellah; El Mostapha, Rakib; Knouzi, Nourredine; Vaultier, Michel

Letters in Organic Chemistry, 2011 , vol. 8, # 5 p. 361 - 363 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 29321324 Find similar reactions

B: 6%

in N,N-dimethyl-formamide

T=95°C; 2 h;

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Shi, Xiao-Xin; Shen, Chun-Li; Yao, Jian-Zhong; Nie, Liang-Deng; Quan, Na

Tetrahedron Asymmetry, 2010 , vol. 21, # 3 p. 277 - 284 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 29321325 Find similar reactions

C: 63%

Shi, Xiao-Xin; Shen, Chun-Li; Yao, Jian-Zhong; Nie, Liang-Deng; Quan, Na

Tetrahedron Asymmetry, 2010 , vol. 21, # 3 p. 277 - 284 Title/Abstract Full Text View citing articles Show Details

T=95°C; 3 h; optical yield given as percent ee;

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Rx-ID: 29321326 Find similar reactions

B: 12%

With 18-crown-6 ether in benzene

T=80°C; 32 h;

Shi, Xiao-Xin; Shen, Chun-Li; Yao, Jian-Zhong; Nie, Liang-Deng; Quan, Na

Tetrahedron Asymmetry, 2010 , vol. 21, # 3 p. 277 - 284 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 29321327 Find similar reactions

C: 60%

T=95°C; 3 h; optical yield given as percent ee;

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Shi, Xiao-Xin; Shen, Chun-Li; Yao, Jian-Zhong; Nie, Liang-Deng; Quan, Na

Tetrahedron Asymmetry, 2010 , vol. 21, # 3 p. 277 - 284 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 29321328 Find similar reactions

B: 8%

Shi, Xiao-Xin; Shen, Chun-Li; Yao, Jian-Zhong; Nie, Liang-Deng; Quan, Na

Tetrahedron Asymmetry, 2010 , vol. 21, # 3 p. 277 - 284 Title/Abstract Full Text View citing articles Show Details

in N,N-dimethyl-formamide

T=90°C; 2 h;

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Rx-ID: 29321329 Find similar reactions

C: 62%

Shi, Xiao-Xin; Shen, Chun-Li; Yao, Jian-Zhong; Nie, Liang-Deng; Quan, Na

Tetrahedron Asymmetry, 2010 , vol. 21, # 3 p. 277 - 284 Title/Abstract Full Text View citing articles Show Details

T=95°C; 3 h; optical yield given as percent ee;

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Rx-ID: 29665917 Find similar reactions

Zhang, Yunlong; Kubicki, Jacek; Platz, Matthew S.

Organic Letters, 2010 , vol. 12, # 14 p. 3182 - 3184 Title/Abstract Full Text View citing articles Show Details

in cyclohexane

T=20°C; Flash photolysis;

Synthesize Find similar Rx-ID: 29743583 Find similar reactions

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With n-butyllithium in tetrahydrofuran; hexane

T=-80°C; 0.0833333 h; Inert atmosphere;

Scholz, Roland; Hellmann, Gunther; Rohs, Susanne; Raabe, Gerhard; Runsink, Jan; Oezdemir, Diana; Luche, Olaf; Hess, Thomas; Giesen, Alexander W.; Atodiresei, Juliana; Lindner, Hans J.; Gais, Hans-Joachim

European Journal of Organic Chemistry, 2010 , # 24 p. 4559 - 4587 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 29951089 Find similar reactions

With Mg/Al calcined hydrotalcite T=300°C;

Manivannan; Pandurangan

Kinetics and Catalysis, 2010 , vol. 51, # 1 p. 56 - 62 Title/Abstract Full Text View citing articles Show Details

With Mg/Al-3.0 calcined hydrotalcite T=400°C;

Manivannan; Pandurangan

Kinetics and Catalysis, 2010 , vol. 51, # 1 p. 56 - 62 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 29951090 Find similar reactions

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With Mg/Al-3.0 calcined hydrotalcite T=300°C;

Manivannan; Pandurangan

Kinetics and Catalysis, 2010 , vol. 51, # 1 p. 56 - 62 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 29951091 Find similar reactions

With Mg/Al-7.0 calcined hydrotalcite T=300°C;

Manivannan; Pandurangan

Kinetics and Catalysis, 2010 , vol. 51, # 1 p. 56 - 62 Title/Abstract Full Text View citing articles Show Details

With Mg/Al-10.0 calcined hydrotalcite T=300°C;

Manivannan; Pandurangan

Kinetics and Catalysis, 2010 , vol. 51, # 1 p. 56 - 62 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 6904555 Find similar reactions

Campbell,J.R. et al.

Australian Journal of Chemistry, 1971 , vol. 24, p. 1425 - 1436 Full Text View citing articles Show Details

Klamann,D.; Weyerstahl,P.

Chemische Berichte, 1964 , vol. 97, p. 2534 - 2538 Full Text View citing articles Show Details

Heck,R.F.

Journal of the American Chemical Society, 1971 , vol. 93, p. 6896 - 6901 Full Text View citing articles Show Details

Vedejs,E. et al.

Journal of the American Chemical Society, 1979 , vol. 101, p. 249 - 251 Full Text View citing articles Show Details

Traynelis,V.J. et al.

Journal of Organic Chemistry, 1962 , vol. 27, p. 2377 - 2383 Full Text View citing articles Show Details

Traynelis,V.J. et al.

Journal of Organic Chemistry, 1964 , vol. 29, p. 123 - 129 Full Text View citing articles Show Details

Traynelis,V.J.; Ode,R.H.

Journal of Organic Chemistry, 1970 , vol. 35, # 7 p. 2207 - 2212 Full Text View citing articles Show Details

Tagaki,W. et al.

Tetrahedron Letters, 1974 , # 30 p. 2587 - 2590 Full Text View citing articles Show Details

Levina,R.Ya. et al.

J. Gen. Chem. USSR (Engl. Transl.), 1960 , vol. 30, p. 868 - 875,883 - 889 Full Text View citing articles Show Details

Ando,W.; Sekiguchi,A.

Journal of Organometallic Chemistry, 1977 , vol. 133, p. 219 - 230 Full Text View citing articles Show Details

Eberson; Persson

Journal of Medicinal and Pharmaceutical Chemistry, 1962 , vol. 5, p. 738,746 Full Text Show Details

Hutchins et al.

Journal of the Chemical Society [Section] D: Chemical Communications, 1971 , p. 1097 Full Text View citing articles Show Details

Boden

Synthesis, 1975 , p. 783 Full Text Show Details

Feinstein et al.

Journal of Organic Chemistry, 1970 , vol. 35, p. 303 Full Text View citing articles Show Details

Schlosser; Christmann

Angewandte Chemie, 1964 , vol. 76, p. 683 Full Text Show Details

Schlosser et al.

Chemische Berichte, 1970 , vol. 103, p. 2814,2815, 2819 Full Text Show Details

Heitz; Michels

Justus Liebigs Annalen der Chemie, 1973 , p. 227 Full Text Show Details

Babajan et al.

Zhurnal Organicheskoi Khimii, 1966 , vol. 2, p. 1974,1939 Full Text Show Details

Bayer A.-G.

Patent: NL6504228 , 1964 ; Chem.Abstr., 1966 , vol. 64, # 17477c Full Text Show Details

Seghers; Shechter

Tetrahedron Letters, 1976 , p. 1943,1944, 1945 Full Text View citing articles Show Details

Kolonko; Shapiro

Journal of Organic Chemistry, 1978 , vol. 43, p. 1404,1407 Full Text Show Details

Mori et al.

Bulletin of the Chemical Society of Japan, 1973 , vol. 46, p. 1505,1507 Full Text Show Details

Wayaku et al.

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96 %Chromat.

Gifu University; Riken; Hamamatsu Photonics K.K.

Patent: EP2070897 A1, 2009 ; Location in patent: Page/Page column 10 ;

Title/Abstract Full Text Show Details

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Synthesize Find similar Rx-ID: 28388152 Find similar reactions

A: 15% B: 30% C: 55%

With niobium pentachloride; zinc in tetrahydrofuran; benzene

T=23°C; 3 h; Inert atmosphere;

Oh, Kyungsoo; Knabe, William Eric

Tetrahedron, 2009 , vol. 65, # 15 p. 2966 - 2974 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 28841995 Find similar reactions

C: 21.3 %Chromat.

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With C24H25Cl3N3Pd; lithium bromide in tetrahydrofuran; 10,11-dihydro-5-[3-(methylamino)propyl]-5H-dibenz(b,f)azepin

T=20°C; Negishi coupling reaction; 2 h; Inert atmosphere;

Chass, Gregory A.; O'Brien, Christopher J.; Hadei, Niloufar; Kantchev, Eric Assen B.; Mu, Wei-Hua; Fang, De-Cai; Hopkinson, Alan C.; Csizmadia, Imre G.; Organ, Michael G.

Chemistry - A European Journal, 2009 , vol. 15, # 17 p. 4281 - 4288 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 28876081 Find similar reactions

B: 81% C: 10%

With water

T=20°C;

Kleiner, Christian M.; Horst, Luise; Wuertele, Christian; Wende, Raffael; Schreiner, Peter R.

Organic and Biomolecular Chemistry, 2009 , vol. 7, # 7 p. 1397 - 1403 Title/Abstract Full Text View citing articles Show Details

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With [Ru(tricyclohexylphosphine)Cl2(CHC6H4O(i-Pr))] in chloroform

T=100°C;

Lozano Vila, Ana M.; Monsaert, Stijn; Drozdzak, Renata; Wolowiec, Stanislaw; Verpoort, Francis

Advanced Synthesis and Catalysis, 2009 , vol. 351, # 16 p. 2689 - 2701 Title/Abstract Full Text View citing articles Show Details

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With [Ru(tricyclohexylphosphine)Cl2(CHC6H4O(i-Pr))] in chloroform

T=80°C;

Lozano Vila, Ana M.; Monsaert, Stijn; Drozdzak, Renata; Wolowiec, Stanislaw; Verpoort, Francis

Advanced Synthesis and Catalysis, 2009 , vol. 351, # 16 p. 2689 - 2701 Title/Abstract Full Text View citing articles Show Details