Bromine [Br2] by Asch

Query Query 1. Query

Results

Date

751 reactions in Reaxys

2017-08-09 05h:00m:50s (EST)

751 reactions in Reaxys

2017-08-09 05h:01m:49s (EST)

Search as: As drawn, No salts, No mixtures, No isotopes, No charges, No radicals 2. Query

(1. Query) AND itemno in (1)

1/201

2017-08-09 05:21:10

Br( 1-)

Rx-ID: 26109272 View in Reaxys 1/751 Yield 95 %

Conditions & References With water, chlorine, modified Kubiersky`s method; less H2O vapor consumption Michels, W.; Przibylla, C.; Die Kalirohsalze, ihre Gewinnung und Verarbeitung in: Fischer, F., Chemische Technologie in Einzeldarstellungen, Spamer, O., Leipzig 1916, S. 226 ; (from Gmelin) View in Reaxys

>90 %

With nitric acid, cetyltrimethylammonim bromide in chloroform, water, Kinetics, byproducts: NO2(1-), NO3(1-), H2O; reaction in the reverse micelle; at 40°C; for 2 h Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys

86 %

With Cl2, H2O, modified Kubiersky`s method Walter, J.; Horst, C.; Bull. Soc. Ind. Mulhouse; vol. 97; (1931); p. 41 ; (from Gmelin) View in Reaxys

73-85 %

With nitrosonium tetrafluoroborate in acetonitrile, Kinetics, byproducts: NO(1-); at 25°C Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys

50 %

With nitric acid, cetyltrimethylammonim bromide in chloroform, water, Kinetics, byproducts: NO2(1-), NO3(1-), H2O; reaction in the reverse micelle; at 25°C; for 11h Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys

50 %

With nitric acid, cetyltrimethylammonim bromide in chloroform, water, Kinetics, byproducts: NO2(1-), NO3(1-), H2O; reaction in the reverse micelle; at 30°C; for 7h Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys

50 %

With nitric acid, cetyltrimethylammonim bromide in chloroform, water, Kinetics, byproducts: NO2(1-), NO3(1-), H2O; reaction in the reverse micelle; at 35°C; for 3h Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys

50 %

With nitric acid, cetyltrimethylammonim bromide in chloroform, water, Kinetics, byproducts: NO2(1-), NO3(1-), H2O; reaction in the reverse micelle; at 40°C; for 1h Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys

1-73 %

With 1-hexene, nitric acid, cetyltrimethylammonim bromide in chloroform, water, reaction in the reverse micelle; at 25°C

2/201

2017-08-09 05:21:10

Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys 1-77 %

With nitric acid, cetyltrimethylammonim bromide, 2-Methyl-1-butene in chloroform, water, reaction in the reverse micelle; at 25°C Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys

1-75 %

With nitric acid, cetyltrimethylammonim bromide in chloroform, water, reaction in the reverse micelle; at 25°C Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys

1-89 %

With 3,3-dimethyl-1-butene, nitric acid, cetyltrimethylammonim bromide in chloroform, water, reaction in the reverse micelle; at 25°C Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys With water, chlorine, Kubiersky`s tower method; combined tower/chamber technique in closed apparatus Krebs, O.; Chem. Appar.; vol. 17; (1930); p. 218 View in Reaxys Krebs, O.; Chem. Appar.; vol. 17; (1930); p. 254 View in Reaxys Kubierschky, K.; Chem. Appar.; vol. 1; (1914); p. 2 View in Reaxys Patent; Kubierschky, K.; DE194567; (1906) View in Reaxys Patent; Kubierschky, K.; 269995; (1913) View in Reaxys Kubierschky, K.; Brom, Bromverbindungen in: Ullmann, F., 2. Aufl., Urban & Schwarzenberg, Berlin-Wien 1928, Bd. 2, S. 673 View in Reaxys Mitreiter, M.; Die Gewinnung des Broms in der Kaliindustrie in: Wohlgemuth, L. M., Monographien ueber chemischtechnische Fabrikationsmethoden, Knapp, W., Halle a. S. 1910, Bd. 20, S. 11 ; (from Gmelin) View in Reaxys Dow`s method: by blowing in air; from brines containing bromide in low concn.; after oxidn. absorbing in form of different bromide salts or as a mixt. of bromides and bromates vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Dow, H. H.; DE6054; (1891) View in Reaxys Patent; Dow, H. H.; The Midland Chemical Company of Midland Michigan; AU1232; (1892) View in Reaxys Patent; Dow, H. H.; The Midland Chemical Company of Midland Michigan; AU714160; (1900) ; (from Gmelin) View in Reaxys Electrolysis; Kossuth`s method, combined synthesis of KOH and Br2 Patent; Kossuth, H.; DE211068; (1908) ; (from Gmelin) View in Reaxys Electrolysis; Kossuth`s method; without diaphragm; simple; high working safety; carbon electrodes

3/201

2017-08-09 05:21:10

Hof, H.; Chemiker-Zeitung; vol. 32; (1908); p. 993 View in Reaxys Patent; Kossuth, H.; DE103644; (1897) View in Reaxys Kubierschky, K.; Brom, Bromverbindungen in: Ullmann, F., 1. Aufl., Urban & Schwarzenberg, Berlin-Wien 1928, Bd. 2, S. 100; 2. Aufl., Bd. 2, S. 671 View in Reaxys Michels, W.; Przibylla, C.; Die Kalirohsalze, ihre Gewinnung und Verarbeitung in: Fischer, F., Chemische Technologie in Einzeldarstellungen, Spamer, O., Leipzig 1916, S. 228 View in Reaxys Mitreiter, M.; Die Gewinnung des Broms in der Kaliindustrie in: Wohlgemuth, L. M., Monographien ueber chemischtechnische Fabrikationsmethoden, Knapp, W., Halle a. S. 1910, Bd. 20, S. 24 View in Reaxys Schloetter, M.; Ueber die elektrolytische Gewinnung von Brom und Jod in: Engelhardt, V., Monographien ueber angewandte Elektrochemie, Knapp, W., Halle a. S. 1907, Bd. 27, S. 4, 21 ; (from Gmelin) View in Reaxys Electrolysis; combined electrolysis/column technique Mitreiter, M.; Die Gewinnung des Broms in der Kaliindustrie in: Wohlgemuth, L. M., Monographien ueber chemischtechnische Fabrikationsmethoden, Knapp, W., Halle a. S. 1910, Bd. 20, S. 21 View in Reaxys Schloetter, M.; Ueber die elektrolytische Gewinnung von Brom und Jod in: Engelhardt, V., Monographien ueber angewandte Elektrochemie, Knapp, W., Halle a. S. 1907, Bd. 27, S. 4, 14 View in Reaxys Schloetter, M.; Ueber die elektrolytische Gewinnung von Brom und Jod in: Engelhardt, V., Monographien ueber angewandte Elektrochemie, Knapp, W., Halle a. S. 1907, Bd. 27, S. 4, 24 View in Reaxys Schloetter, M.; Ueber die elektrolytische Gewinnung von Brom und Jod in: Engelhardt, V., Monographien ueber angewandte Elektrochemie, Knapp, W., Halle a. S. 1907, Bd. 27, S. 4, 29 ; (from Gmelin) View in Reaxys Electrolysis; current yield with or without diaphragm; effect of Mg(OH)2 Michels, W.; Przibylla, C.; Die Kalirohsalze, ihre Gewinnung und Verarbeitung in: Fischer, F., Chemische Technologie in Einzeldarstellungen, Spamer, O., Leipzig 1916, S. 227 View in Reaxys Mitreiter, M.; Die Gewinnung des Broms in der Kaliindustrie in: Wohlgemuth, L. M., Monographien ueber chemischtechnische Fabrikationsmethoden, Knapp, W., Halle a. S. 1910, Bd. 20, S. 14 ; (from Gmelin) View in Reaxys Electrolysis; from sea water; extn. with organic solvents Dyson, G. M.; Chem. Age (London); vol. 15; (1926); p. 392 View in Reaxys vol. Br: MVol.; 1.3, page 44 - 48 ; (from Gmelin) View in Reaxys Electrolysis; with carbon eletrodes; from final liquors containing Mg; using diaphragm at high alkali chloride/bromide concn. Schloetter, M.; Ueber die elektrolytische Gewinnung von Brom und Jod in: Engelhardt, V., Monographien ueber angewandte Elektrochemie, Knapp, W., Halle a. S. 1907, Bd. 27, S. 10 ; (from Gmelin) View in Reaxys Electrolysis vol. Br: MVol.; 1.3, page 44 - 48 View in Reaxys Patent; Tobler, H.; American Bromine Company, of Maywood, New Jersey; AU38852; (1918) View in Reaxys Patent; Tobler, H.; American Bromine Company, of Maywood, New Jersey; AU38853; (1920) ; (from Gmelin) View in Reaxys modified Dow`s method

4/201

2017-08-09 05:21:10

vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Dow, H. H.; AU741637; (1903) View in Reaxys Patent; Dow, H. H.; AU752331; (1903) View in Reaxys Patent; Dow, H. H.; AU752332; (1903) ; (from Gmelin) View in Reaxys oxidn.; extn. with an oil (e.g. satd. hydrocarbons with low density), distribution coeff. > 6:1; removing Cl2 residue from oil with aq. KBr soln.; obtaining Br2 with aq. alkali hydroxide or carbonate or hydrocarbonate soln. vol. Br: MVol.; 1.3, page 44 - 48 View in Reaxys Patent; Tobler, H.; AU38851; (1918) View in Reaxys Patent; Tobler, H.; American Bromine Company, of Maywood, New Jersey; AU51642; (1920) ; (from Gmelin) View in Reaxys vol. Br: MVol.; 1.3, page 44 - 48 View in Reaxys Patent; Societe Anonyme; Aloformia; FR58583; (1924) View in Reaxys Patent; Velardi, G.; A. P. I. C. E. Soc. An. Prodotti Italiani Chimici Estrattivi; EP25134; (1925) ; (from Gmelin) View in Reaxys With water, chlorine, Frank`s 2. method: continuous oxidation (countercurrent technique); brine (60-80 °C) introducing at the top, Cl2 and H2O vapor at the plate; sepn. of crude Br2 Kubierschky, K.; Brom, Bromverbindungen in: Ullmann, F., 2. Aufl., Urban & Schwarzenberg, Berlin-Wien 1928, Bd. 2, S. 670 ; (from Gmelin) View in Reaxys With water, chlorine, Frank`s 2. method: continuous oxidation (countercurrent technique); brine (60-80 °C) introducing at the top, Cl2 and H2O vapor at the plate Huettner, W.; z. ang. Ch.; vol. 35; (1922); p. 432 View in Reaxys Kubierschky, K.; Brom, Bromverbindungen in: Ullmann, F., 2. Aufl., Urban & Schwarzenberg, Berlin-Wien 1928, Bd. 2, S. 670 View in Reaxys Michels, W.; Przibylla, C.; Die Kalirohsalze, ihre Gewinnung und Verarbeitung in: Fischer, F., Chemische Technologie in Einzeldarstellungen, Spamer, O., Leipzig 1916, S. 224 ; (from Gmelin) View in Reaxys With water, chlorine, Frank`s 2. method: continuous oxidation (countercurrent technique); different processes in one Glover tower (filled with coke, stone, etc.) Patent; Mueller, R.; Boeckel, H.; DE7743; (1878) View in Reaxys anonym; Dinglers Polytech. J.; vol. 235; (1880); p. 53 View in Reaxys Patent; Frank, A.; DE2251; (1877) View in Reaxys Patent; Vereinigte Chemische Fabriken A. G.; DE9353; (1878) View in Reaxys Michels, W.; Przibylla, C.; Die Kalirohsalze, ihre Gewinnung und Verarbeitung in: Fischer, F., Chemische Technologie in Einzeldarstellungen, Spamer, O., Leipzig 1916, S. 223 View in Reaxys Schloetter, M.; Ueber die elektrolytische Gewinnung von Brom und Jod in: Engelhardt, V., Monographien ueber angewandte Elektrochemie, Knapp, W., Halle a. S. 1907, Bd. 27, S. 8 ; (from Gmelin) View in Reaxys With water, chlorine, Frank`s 2. method: continuous oxidation in column (countercurrent technique)

5/201

2017-08-09 05:21:10

Patent; Frank, A.; DE2251; (1877) ; (from Gmelin) View in Reaxys With water, chlorine, continuous technique; crude Br2 by condensing in a cooled column Patent; Sauerbrey, R.; Wuensche, A.; DE158715; (1903) View in Reaxys Patent; Sauerbrey, R.; Wuensche, A.; DE196111; (1903) ; (from Gmelin) View in Reaxys With water, chlorine, modified Kubiersky`s method Kaltenbach, M.; Chim. Ind.; vol. 25; (1931); p. 543 View in Reaxys Kaltenbach, M.; Chim. Ind.; vol. 25; (1931); p. 552 View in Reaxys Walter, J.; Horst, C.; Bull. Soc. Ind. Mulhouse; vol. 97; (1931); p. 32 View in Reaxys Patent; Kubierschky, K.; DE41107; (1924) ; (from Gmelin) View in Reaxys With water, chlorine, modified method to avoid forming of bromine chloride Patent; Salzbergwerk Neu-Stassfurt; DE10822; (1898) ; (from Gmelin) View in Reaxys With chlorine in water, Balard`s method; isolation by distn.; better quality and yield by extn. with ether Balard, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 342 ; (from Gmelin) View in Reaxys With chlorine in water, Electrolysis; from very dil. soln. (e.g. sea water); oxidn. with Cl2; adding Ag; dissolving AgBr in 5-25 percent KBr soln. (40-65 °C); obtain by electrolysis at anode Br2 and at cathode Ag vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Wilson, R. E.; Standard Oil of Whiting, Indiana; AU55108; (1924) ; (from Gmelin) View in Reaxys With chlorine in water, Electrolysis; from very dil. soln. (e.g. sea water); oxidn. with Cl2; adding Ag; dissolving AgBr in 5-25 percent Na2S2O3 soln. (40-65 °C); obtain by electrolysis at anode Br2 and at cathode Ag vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Wilson, R. E.; Standard Oil of Whiting, Indiana; AU55108; (1924) ; (from Gmelin) View in Reaxys With chlorine in water, Electrolysis; from very dil. soln. (e.g. sea water); oxidn. with Cl2; adding Cu-amalgam; dissolving metal bromide in 5-25 percent KBr soln. (40-65 °C); Br2 was obtained by electrolysis at anode and Hg at cathode vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Wilson, R. E.; Standard Oil of Whiting, Indiana; AU55108; (1924) ; (from Gmelin) View in Reaxys With chlorine in water, Electrolysis; from very dil. soln. (e.g. sea water); oxidn. with Cl2; adding Cu-amalgam; dissolving metal bromide in 5-25 percent Na2S2O3 soln. (40-65 °C); Br2 was obtained by electrolysis at anode and Hg at cathode vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Wilson, R. E.; Standard Oil of Whiting, Indiana; AU55108; (1924) ; (from Gmelin) View in Reaxys

6/201

2017-08-09 05:21:10

With chlorine in water, Electrolysis; from very dil. soln. (e.g. sea water); oxidn. with Cl2; adding Hg; dissolving Hg bromide in 5-25 percent KBr soln. (40-65 °C); Br2 was obtained by electrolysis at anode and Hg at cathode vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Wilson, R. E.; Standard Oil of Whiting, Indiana; AU55108; (1924) ; (from Gmelin) View in Reaxys With chlorine in water, Electrolysis; from very dil. soln. (e.g. sea water); oxidn. with Cl2; adding Hg; dissolving Hg bromide in 5-25 percent Na2S2O3 soln. (40-65 °C); Br2 was obtained by electrolysis at anode and Hg at cathode vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Wilson, R. E.; Standard Oil of Whiting, Indiana; AU55108; (1924) ; (from Gmelin) View in Reaxys With chlorine in water, modified Dow`s method; absorbing Br2 with 4 percent NaOH soln. Chamagne, G.; Ind. chim.; vol. 13; (1926); p. 495 View in Reaxys vol. Br: MVol.; 1.2, page 40 - 44 ; (from Gmelin) View in Reaxys With chlorine in water, modified Dow`s method; absorbing Br2 with wet Fe turnings Chamagne, G.; Ind. chim.; vol. 13; (1926); p. 495 View in Reaxys vol. Br: MVol.; 1.2, page 40 - 44 ; (from Gmelin) View in Reaxys With chlorine in water Balarad, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 351 - 355 View in Reaxys Balarad, A. J.; Annalen der Physik (Weinheim, Germany); vol. 8; (1826); p. 323 ; (from Gmelin) View in Reaxys With chloric acid in not given, very slow oxydation even at addn. of V(V)-salts; vol. Cl: MVol.; 122, page 324 - 326 View in Reaxys Rutter; Dissert. Leipzig 1906, S. 60 ; (from Gmelin) View in Reaxys 0%

With perchloric acid in not given Centnerszwer, M.; Zablocki, W.; Z. phys. Ch.; vol. 122; (1926); p. 473 ; (from Gmelin) View in Reaxys With periodate in water, reaction of bromides with acidic IO4(1-) soln.; Rose, H.; Finkener, R.; Handbuch der analytischen Chemie, 6. Aufl., Leipzig 1867, Bd. 1, S. 748 View in Reaxys Rose, H.; Traite complet de chimie analytique, Paris 1858, Bd. 1, S. 624 ; (from Gmelin) View in Reaxys With manganese(IV) oxide, sulfuric acid in water, Frank`s first method; from stassfurtic salt with 60 °Be H2SO4; distn. at 60-75 °C Pfeiffer, E.; Handbuch der Kaliindustrie in: Bolley, P. A., Birnbaum, K., Handbuch der chemischen Technologie, F. Vieweg & Sohn, Braunschweig 1887, Bd. 2, Gruppe 1, Abt. 2, S. 322 ; (from Gmelin) View in Reaxys With nitronium tetrafluoborate in acetonitrile, Kinetics, byproducts: NO2(1-); at 25°C

7/201

2017-08-09 05:21:10

With 2,3-Dimethyl-2-butene, nitric acid, cetyltrimethylammonim bromide in chloroform, water, reaction in the reverse micelle; at 25°C Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys

0-69 %

With 2-methyl-but-2-ene, nitric acid, cetyltrimethylammonim bromide in chloroform, water, reaction in the reverse micelle; at 25°C Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys With perchloric acid, nitric acid, cetyltrimethylammonim bromide in chloroform, water, Kinetics, byproducts: NO2(1-), H2O; reaction in the reverse micelle Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys With perchloric acid, cetyltrimethylammonim bromide in chloroform, water, Kinetics, reaction in the reverse micelle Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys With perchloric acid, cetyltrimethylammonim bromide, sodium nitrite in chloroform, water, Kinetics, reaction in the reverse micelle Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys With sodium nitrate, perchloric acid, cetyltrimethylammonim bromide in chloroform, water, Kinetics, reaction in the reverse micelle Hojo, Masashi; Ueda, Tadaharu; Daike, Chihiro; Takezaki, Fumiko; Furuya, Yumi; Miyamoto, Kiyomi; Narutaki, Akio; Kato, Ryosuke; Bulletin of the Chemical Society of Japan; vol. 79; nb. 8; (2006); p. 1215 - 1222 ; (from Gmelin) View in Reaxys With hydrogenchloride, dichromate anion in water Leisler, L.; Dinglers Polytech. J.; vol. 179; (1866); p. 386 View in Reaxys Leisler, L.; Mechanics'Mag. {2}; vol. 14; (1865); p. 380 ; (from Gmelin) View in Reaxys With TiO2/Ru(C36H18N6O12)(4-), HClO4 in water, Irradiation (UV/VIS); photoelectrochemical oxidn. of Br(1-) on irradiation with visible light in presence of sensitizers consisting of TiO2 or Ru(C36H18N6O12)(4-) coated on TiO2 Vlachopoulos, Nick; Liska, Paul; Augustynski, Jan; Graetzel, Michael; Journal of the American Chemical Society; vol. 110; nb. 4; (1988); p. 1216 - 1220 ; (from Gmelin) View in Reaxys

8/201

2017-08-09 05:21:10

With Cl2 in water, Balard`s method; isolation by distn.; better quality and yield by extn. with ether Balard, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 338 ; (from Gmelin) View in Reaxys With Cl2 in water vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys 0%

With HClO4 in not given vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With IO4 (1-) in water, reaction of bromides with acidic IO4(1-) soln.; vol. I: MVol.2; 131, page 530 - 533 ; (from Gmelin) View in Reaxys vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys With Cl2, H2O vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys With Cl2 in water vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys With H2SO4, MnO2 in water vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys With HCl, dichromate in water vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys With [Ru(2,2′-bipyridine)2(4,4′-(CO2CH2CH3)2-2,2′-bipyridine)](PF6)2, 4-bromo-benzenediazonium ion in acetonitrile, Kinetics, Catalytic behavior, Reagent/catalyst, Concentration Tsai, Kelvin Yun-Da; Chang, I-Jy; Inorganic Chemistry; vol. 56; nb. 14; (2017); p. 8497 - 8503 View in Reaxys

BrK

Rx-ID: 26097266 View in Reaxys 2/751 Yield

Conditions & References With ozone in neat (no solvent) Schoenbein, C. F.; Annalen der Physik (Weinheim, Germany); vol. 65; (1845); p. 69 - 80 View in Reaxys vol. O: MVol.4; 87, page 1174 - 1176 View in Reaxys Schoenbein, C. F.; Ueber die Erzeugung des Ozons auf chemischem Wege, Basel 1844, S. 115 ; (from Gmelin) View in Reaxys decompn. during melting Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1913); p. 739 ; (from Gmelin) View in Reaxys

9/201

2017-08-09 05:21:10

Slevin; Macpherson; Unwin; Journal of Physical Chemistry B; vol. 101; nb. 50; (1997); p. 10851 - 10859 ; (from Gmelin) View in Reaxys With water in water, Kinetics, byproducts: H2O2; Sonication; investigation of sonolysis of aq. soln. of KBr (pH 3.0 adjusted by HClO4) under argon-oxygen-atmospheres of various compositions;; not isolated, determination by spectrophotometry at 350 nm; Gutierrez, Maritza; Henglein, Arnim; Ibanez, Fernando; Journal of Physical Chemistry; vol. 95; nb. 15; (1991); p. 6044 - 6047 ; (from Gmelin) View in Reaxys With sulfuric acid, byproducts: SO2, HBr; concd. H2SO4 Diesel, E.; Archiv der Pharmazie (Weinheim, Germany); vol. 99; (1847); p. 274 ; (from Gmelin) View in Reaxys With sulfuric acid in not given, dild. H2SO4 Addyman, F. T.; Journal of the Chemical Society; vol. 61; (1892); p. 97 ; (from Gmelin) View in Reaxys With hydrogenchloride in hydrogenchloride Bose, E.; Zeitschrift fuer Elektrochemie; vol. 5; (1898); p. 159 ; (from Gmelin) View in Reaxys With potassium dichromate, sulfuric acid, adding concd. H2SO4 to a mixt. of KBr and K2Cr2O7; distn. vol. Br: MVol.; 1.4, page 48 - 53 View in Reaxys Frerichs, G.; Arends, G.; Zoernig, H.; Hagers Handbuch der pharmazeutischen Praxis, Berlin 1925, Bd. 1, S. 694 ; (from Gmelin) View in Reaxys With potassium dichromate, sulfuric acid in water, melting KBr with K2Cr2O7; cooling; adding aq. H2SO4 soln.; removing iodate with K metabisulphite, Cl2 by distn. and treating with aq. KBr soln., decompn. of organics with KMnO4 Bolas, Th.; Groves, Ch. E.; Liebigs Annalen der Chemie; vol. 160; (1871); p. 176 View in Reaxys Scott, A.; Journal of the Chemical Society; vol. 103; (1913); p. 848 View in Reaxys vol. Br: MVol.; 1.4, page 48 - 53 ; (from Gmelin) View in Reaxys With potassium bromate, sulfuric acid in water, adding dild. H2SO4 to a mixt. of pure KBr and KBrO3; distn.; removing H2O with concd. H2SO4; storage in desiccator over concd. H2SO4 Trautz, M.; Henglein, F. A.; Z. Anorg. Chem.; vol. 110; (1920); p. 271 View in Reaxys vol. Br: MVol.; 1.4, page 48 - 53 ; (from Gmelin) View in Reaxys With Nitrogen dioxide, anhydrous, liq. NO2 Frankland, P. F.; Farmer, R. C.; Journal of the Chemical Society; vol. 79; (1901); p. 1361 ; (from Gmelin) View in Reaxys With oxygen, titanium(IV) oxide in water, Irradiation (UV/VIS); within 40 h of irradn. of O2-satd. aq. halide soln. contg. TiO2 catalyst at pH 5.5 Reichman, Benjamin; Byvik, Charles E.; Journal of Physical Chemistry; vol. 85; nb. 15; (1981); p. 2255 - 2258 ; (from Gmelin) View in Reaxys With oxygen in water, Irradiation (UV/VIS); irradn. of O2-satd. aq. halide soln. contg. Pt-TiO2 catalyst at severalpH

10/201

2017-08-09 05:21:10

Reichman, Benjamin; Byvik, Charles E.; Journal of Physical Chemistry; vol. 85; nb. 15; (1981); p. 2255 - 2258 ; (from Gmelin) View in Reaxys With sulfuric acid in water, Electrochem. Process; chronoamperometric oxidn. of sample soln. (aq. H2SO4 as background electrolyte, Pt working ultramicroelectrode, potential steeping from 0.7 to 1.20 V vs. Ag as quasi-reference electrode) Slevin; Macpherson; Unwin; Journal of Physical Chemistry B; vol. 101; nb. 50; (1997); p. 10851 - 10859 ; (from Gmelin) View in Reaxys With kaolin, in dried air-stream Gorgeu, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 102; (1886); p. 1165 View in Reaxys Gorgeu, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 102; (1886); p. 1166 ; (from Gmelin) View in Reaxys With stannic acid, warming Schoenbein, C. F.; Annalen der Physik (Weinheim, Germany); vol. 78; (1849); p. 519 ; (from Gmelin) View in Reaxys in H2SO4, Electrochem. Process; ultramicroelectrodes, CO(ads) at the Pt, KBr in 0.5 M H2SO4, 0.75-1.156 V vs Ag/ AgCl; scanning electrochemical microscopy Wang, Qian; Rodriguez-Lopez, Joaquin; Bard, Allen J.; Journal of the American Chemical Society; vol. 131; nb. 47; (2009); p. 17046 - 17047 ; (from Gmelin) View in Reaxys With O3 in neat (no solvent) vol. O: MVol.4; 82, page 1163 - 1165 ; (from Gmelin) View in Reaxys With H2SO4 in not given, dild. H2SO4 vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With HCl in hydrogenchloride vol. Br: MVol.; 7.4, page 226 - 233 ; (from Gmelin) View in Reaxys With IF7 in neat (no solvent), with gaseous IF7 on warming;; pptn.; Ruff, O.; Keim, R.; Z. Anorg. Chem.; vol. 193; (1930); p. 176 - 176 View in Reaxys vol. I: MVol.2; 160, page 602 - 604 ; (from Gmelin) View in Reaxys in dimethyl sulfoxide, Electrolysis; DMSO soln. of KBr oxidized on nanopaper electrode at 0.8-0.9 V; monitored by NMR Krivenko; Komarova; Ryabenko; Naumkin; Stenina; Sviridova; Sulyanov; Russian Chemical Bulletin; vol. 60; nb. 6; (2011); p. 1071 - 1077 ; (from Gmelin) View in Reaxys vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys With H2SO4 vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin)

11/201

2017-08-09 05:21:10

View in Reaxys With NO2 vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys With kaolin vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys With stannic acid vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys With nitric acid, titanium(IV) oxide, ozone in water, Time= 5h, T= 40 °C , UV-irradiation Parrino, Francesco; Camera Roda, Giovanni; Loddo, Vittorio; Palmisano, Leonardo; Angewandte Chemie - International Edition; vol. 55; nb. 35; (2016); p. 10391 - 10395; Angew. Chem.; vol. 128; nb. 35; (2016); p. 10547 10551,5 View in Reaxys

BrNa

ClNa

Rx-ID: 42075044 View in Reaxys 3/751 Yield

Conditions & References 4 : Electrolytic Chlorine and Bromine Generation. The process describe in Example 2 was further employed to generate an additional biocide. Again, the effluent streams (elemental chlorine and sodium hydroxide) were not combined. Acti-Brom (42.8percent sodium bromide solution) was added to the elemental chlorine stream at a rate of 4.28 mL/min. The sodium bromide reacted with chlorine to produce bromine at a production rate of 4.51 lb/day, according to the following reaction: 2NaBr +Cl2→Br2+2NaCl (0103) A further depiction of the chlorine and bromine production is illustrated in FIG. 8. Beneficially, the methods of the invention allow the use of chlorine to generate the second biocide bromine within a single system. in water Patent; Ecolab USA Inc.; DiMascio, Felice; O'Brien, Donald; (18 pag.); US2016/29639; (2016); (A1) English View in Reaxys

Rx-ID: 26179628 View in Reaxys 4/751 Yield 7%

Conditions & References With oxygen in water, byproducts: H2O; Irradiation (UV/VIS); 600 W high-pressure Hg lamp; O2-swept HBr soln., 2 wk Fuchs, Benzion; Mayer, Wilfried J. W.; Abramson, Sarah; Journal of the Chemical Society, Chemical Communications; (1985); p. 1711 - 1713 ; (from Gmelin) View in Reaxys With chlorine, Kinetics, byproducts: HCl Jost, W.; Z. phys. Ch.; vol. B 14; (1931); p. 419 ; (from Gmelin) View in Reaxys by oxydn.; Scheidt, K.; Zh. Khim. Prom - sti.; vol. 3; (1926); p. 1200 View in Reaxys vol. Br: MVol.; 1.2, page 40 - 44 ; (from Gmelin) View in Reaxys

byproducts: H2; Irradiation (UV/VIS); sunlight, 50 d

12/201

2017-08-09 05:21:10

Berthelot, M.; Ann. Chim. Phys.; vol. 21; (1900); p. 206 View in Reaxys vol. Br: MVol.; 5.3, page 180 - 184 ; (from Gmelin) View in Reaxys 0%

byproducts: H2; Irradiation (UV/VIS) Berthelot, D.; Gaudechon, H.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 156; (1913); p. 890 View in Reaxys vol. Br: MVol.; 5.3, page 180 - 184 ; (from Gmelin) View in Reaxys byproducts: H2; electric discharge, at room temp. Smits, A.; Aten, A. H. W.; Zeitschrift fuer Elektrochemie; vol. 16; (1910); p. 264 View in Reaxys vol. Br: MVol.; 5.3, page 180 - 184 ; (from Gmelin) View in Reaxys

byproducts: H2; heating at 228-238 °C Bodenstein, M.; Z. phys. Cim.; vol. 49; (1904); p. 67 View in Reaxys vol. Br: MVol.; 5.2, page 168 - 180 ; (from Gmelin) View in Reaxys

byproducts: H2; heating at 444 °C Bodenstein, M.; Lind, S. C.; Z. phys. Ch.; vol. 57; (1907); p. 175 View in Reaxys vol. Br: MVol.; 5.2, page 168 - 180 ; (from Gmelin) View in Reaxys

byproducts: H2; heating at 700 °C Bodenstein, M.; Lind, S. C.; Z. phys. Ch.; vol. 57; (1907); p. 175 View in Reaxys vol. Br: MVol.; 5.2, page 168 - 180 ; (from Gmelin) View in Reaxys byproducts: H2; heating at 700 °C Bodenstein, M.; Z. phys. Cim.; vol. 49; (1904); p. 67 View in Reaxys vol. Br: MVol.; 5.2, page 168 - 180 ; (from Gmelin) View in Reaxys byproducts: H2; in discharge tube partial decompn. Ludlam, E. B.; West, W.; Proc. R. Soc. Edinburgh; vol. 44; (1923); p. 196 View in Reaxys Weizel, W.; Wolf, H. W.; Binkele, E.; Z. phys. Ch.; vol. B 10; (1930); p. 462 View in Reaxys vol. Br: MVol.; 5.3, page 180 - 184 ; (from Gmelin) View in Reaxys byproducts: H2; other Radiation; anhydrous liq. HBr, 10 mg Ra (α radiation) Lind, S. C.; Radium (Paris); vol. 8; (1911); p. 291 View in Reaxys vol. Br: MVol.; 5.3, page 180 - 184 ; (from Gmelin) View in Reaxys byproducts: H2; other Radiation; by radium emanation fast decompn. (15 min) Gillerot, R.; Bulletin des Societes Chimiques Belges; vol. 39; (1930); p. 515

13/201

2017-08-09 05:21:10

View in Reaxys vol. Br: MVol.; 5.3, page 180 - 184 View in Reaxys Lind, S. C.; Ogg, E. F.; Z. phys. Ch. Bodenstein-Festband 1931, S. 805 ; (from Gmelin) View in Reaxys 0%

byproducts: H2; other Radiation; by radium emanation Lind, S. C.; Radium (Paris); vol. 8; (1911); p. 290 View in Reaxys vol. Br: MVol.; 5.3, page 180 - 184 ; (from Gmelin) View in Reaxys

byproducts: H2; other Radiation; under 2/3 atm, at room temp., 37 d, 0.2 g RaCl2 Lind, S. C.; Radium (Paris); vol. 8; (1911); p. 290 View in Reaxys vol. Br: MVol.; 5.3, page 180 - 184 ; (from Gmelin) View in Reaxys

byproducts: H2; pass through a tube at red heat vol. Br: MVol.; 5.2, page 168 - 180 ; (from Gmelin) View in Reaxys With chlorine, byproducts: HCl Trautz, M.; Henglein, F. A.; Z. Anorg. Chem.; vol. 110; (1920); p. 285 ; (from Gmelin) View in Reaxys With chlorine in water Balarad, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 351 - 355 View in Reaxys Balarad, A. J.; Annalen der Physik (Weinheim, Germany); vol. 8; (1826); p. 323 ; (from Gmelin) View in Reaxys With anhydrous cobalt diacetate, cobalt acetate tetrahydrate in water, acetic acid, Kinetics, HBr as 48percent aq. soln.; oxidation at 40°C with Co(III) species in the presence of Co(II) in glacial AcOH; monitored by UV-visible methods; spectrophotometry Jiao; Metelski; Espenson; Inorganic Chemistry; vol. 40; nb. 13; (2001); p. 3228 - 3233 ; (from Gmelin) View in Reaxys With anhydrous cobalt diacetate, cobalt acetate tetrahydrate in acetic acid, Kinetics, HBr as 48percent aq. soln.; oxidation at 40°C with Co(III) species in the presence of Co(II) in 0.1percent aq. AcOH; monitored by UV-visible methods; spectrophotometry Jiao; Metelski; Espenson; Inorganic Chemistry; vol. 40; nb. 13; (2001); p. 3228 - 3233 ; (from Gmelin) View in Reaxys With cobalt acetate tetrahydrate in acetic acid, Kinetics, HBr as 48percent aq. soln.; oxidation at 35°C; monitored by UV-visible methods; spectrophotometry Jiao; Metelski; Espenson; Inorganic Chemistry; vol. 40; nb. 13; (2001); p. 3228 - 3233 ; (from Gmelin) View in Reaxys With dihydrogen peroxide in water, byproducts: H2O; mixt. of H2O2 (35percent) and HBR (40percent) cooled with ice-cold water; equilibrium reaction; content of H2O2 = 22.6 vol-percent Stratiichuk; Tomashik; Feichuk; Russian Journal of Inorganic Chemistry; vol. 49; nb. 12; (2004); p. 1941 - 1945 ; (from Gmelin) View in Reaxys With dihydrogen peroxide in water Maass, O.; Hutcher, W. H.; Journal of the American Chemical Society; vol. 44; (1922); p. 2476 ; (from Gmelin)

14/201

2017-08-09 05:21:10

View in Reaxys With sulfuric acid in not given, byproducts: SO2; 60 percent H2SO4 soln., 169 °C Proskouriakoff, K.; Journal of Physical Chemistry; vol. 33; (1929); p. 718 ; (from Gmelin) View in Reaxys With sulfuric acid in not given, byproducts: SO2; 70 percent H2SO4 soln., 100 °C Proskouriakoff, K.; Journal of Physical Chemistry; vol. 33; (1929); p. 718 ; (from Gmelin) View in Reaxys With sulfuric acid in not given, byproducts: SO2; 80 percent H2SO4 soln., 46 °C Proskouriakoff, K.; Journal of Physical Chemistry; vol. 33; (1929); p. 718 ; (from Gmelin) View in Reaxys With sulfuric acid in not given, byproducts: SO2; 90 percent H2SO4 soln., 35 °C Proskouriakoff, K.; Journal of Physical Chemistry; vol. 33; (1929); p. 718 ; (from Gmelin) View in Reaxys With sulfuric acid in not given, byproducts: SO2 Balard, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 352 View in Reaxys Ditz, H.; Margosches, B. M.; Angewandte Chemie; vol. 14; (1901); p. 1090 ; (from Gmelin) View in Reaxys With chlorosulfonic acid, byproducts: H2SO4, SO2, HCl; 50 °C Besson, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 124; (1897); p. 402 ; (from Gmelin) View in Reaxys With anhydrous cobalt diacetate, manganese triacetate in water, acetic acid, Kinetics, HBr as 48percent aq. soln.; oxidation at 20°C with Mn(III) species in the presence of Co(II) in glacial AcOH; monitored by UV-visible methods; spectrophotometry Jiao; Metelski; Espenson; Inorganic Chemistry; vol. 40; nb. 13; (2001); p. 3228 - 3233 ; (from Gmelin) View in Reaxys With Manganese (II) acetate, manganese triacetate in water, acetic acid, Kinetics, HBr as 48percent aq. soln.; oxidation at 20°C with Mn(III) species in the presence of Mn(II) in glacial AcOH; monitored by UV-visible methods; spectrophotometry Jiao; Metelski; Espenson; Inorganic Chemistry; vol. 40; nb. 13; (2001); p. 3228 - 3233 ; (from Gmelin) View in Reaxys With sulfuryl dichloride, byproducts: SO2, HCl Schulze, H.; Journal fuer Praktische Chemie (Leipzig); vol. 24; (1881); p. 183 ; (from Gmelin) View in Reaxys With vanadium(5+) in sulfuric acid, byproducts: V(4+); oxidation with V(5+) (NaVO3) in presence of chloride or sulfate at 10, 20 or 30°C in aq. H2SO4 (not above 12 mol H2O per mol H2SO4);; removing Br2 with a stream of CO2; Bobtelsky, M.; Czosnek, S.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 205; (1932); p. 401 - 413 View in Reaxys vol. V: MVol.A2; 109, page 572 - 574 ; (from Gmelin) View in Reaxys With vanadium(5+) in hydrogenchloride, byproducts: V(4+); oxidation with V(5+) in aq. HCl; Bobtelsky, M.; Czosnek, S.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 205; (1932); p. 401 - 413 View in Reaxys vol. V: MVol.A2; 109, page 572 - 574 ; (from Gmelin)

15/201

2017-08-09 05:21:10

View in Reaxys With chlorine, Kinetics, byproducts: hydrochloric acid Balint, Imre; Ban, Miklos I.; Acta Chimica Hungarica; vol. 128; nb. 3; (1991); p. 431 - 438 ; (from Gmelin) View in Reaxys With fluorine, Kinetics, byproducts: hydrofluoric acid Balint, Imre; Ban, Miklos I.; Acta Chimica Hungarica; vol. 128; nb. 3; (1991); p. 431 - 438 ; (from Gmelin) View in Reaxys With iodine, Kinetics, byproducts: hydroiodic acid Balint, Imre; Ban, Miklos I.; Acta Chimica Hungarica; vol. 128; nb. 3; (1991); p. 431 - 438 ; (from Gmelin) View in Reaxys With metavanadic acid in not given Ditte, A.; Ann. Chim. Phys.; vol. 13; (1888); p. 190 - 271 View in Reaxys vol. V: MVol.A2; 109, page 572 - 574 View in Reaxys Ditte, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 102; (1886); p. 1310 1312 ; (from Gmelin) View in Reaxys in water, Electrolysis; aq. soln. of HBr electrolyzed in electrolyzer with anode and cathode spaces sepd. by NAFFION-403 membrane; bromine extd. with chloroform Kaabak; Stepnova; Khudenko; Tomilov; Russian Journal of Applied Chemistry; vol. 76; nb. 8; (2003); p. 1315 1318 ; (from Gmelin) View in Reaxys in water, byproducts: H2; other Radiation; 10 mg Ra (α radiation); fast decompn. Lind, S. C.; Radium (Paris); vol. 8; (1911); p. 291 View in Reaxys vol. Br: MVol.; 5.3, page 180 - 184 ; (from Gmelin) View in Reaxys 11 :EXAMPLE 11In this example, 1 g SeO2 was loaded into two bubbler containers. A 3.06 ml, 62 wt. percent aqueous HBr solution was added to the first one (2.915.6 g HBr, 4.7 g soln.), and 3.67 ml of the same solution to the second one (3.645 g HBr, 5.88 g soln.) at room temperature. The samples were submerged in a preheated oil bath at 100 0C. A 3 ml/min. oxygen stream was passed over . . the containers with the gas leaving the containers passed through 15 ml 4 M NaOH solution that captured all bromine vapors. The NaOH traps were changed every hour and the bromine content was determined by iodometric titration with standard 0.1000 M Na2S2O3. The results are shown in Table 6 below. With selenium(IV) oxide, oxygen in water, T= 100 °C , Product distribution / selectivity Patent; GAS REACTION TECHNOLOGIES, INC.; GADEWARD, Sagar; ZHANG, Aihua; JULKA, Vivek; MCFARLAND, Eric, W.; GROSSO, Philip; JANMANCHI, Krishna; SARDAR, Saydul, Amin; STOIMENOV, Peter; KOMON, Zachary, J.A.; LIN, Hongfei; CUTLER, Charles, Ian; CHENG, Jihong; WHEELER, Jean; SUN, Shouli; AUERBACH, Daniel, J.; WYRSTA, Michael, D.; CORONELLA, Charles, J.; HUFF, Shawn; WO2010/9376; (2010); (A1) English View in Reaxys 1 :EXAMPLE 1Referring to Figure 1, the flow rate in methane feed line 1 to the bromination reactor 100 is 100 kg/hr, the flow rate in methane recycle line 2 is 73 kg/hr and the flow rate in the bromine feed line 3 is 1164 kg/hr. Reactor 100 is operated at 5100C and300OkPa. The conversion of methane is 50percent and the selectivity to monobromomethane is 67percent.Reproportionation reactor 120 is also operated at 5100C and 300OkPa. The conversion is 43percent and the selectivity to monobromomethane is 100percent. Coupling reactor 140 is operated at 425°C and 250OkPa. The conversion of the monobromomethane is 100percent and the selectivity to BTX is 32percent.Bromine generation reactor 110 is operated at 375°C and 20OkPa and the flow rate of air through feed line 36 is 554 kg/hr. The conversion and selectivity are both 100percent. The flow rate in water stream 39 is 131 kg/hr. Steam cracker

16/201

2017-08-09 05:21:10

270 is operated at 8400C and 10OkPa. The conversion of the monobromomethane is 84percent and the selectivity to lower olefins is 60percent.14 kg/hr of benzene and 23 kg/hr of p-xylene are produced. 25 kg/hr of ethylene and 12 kg/hr of propylene are produced. With oxygen, copper oxide, T= 375 °C , p= 1500.15Torr , Industry scale Patent; SHELL OIL COMPANY; SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.; FONG, Howard Lam Ho; SWAIN, Richard Dale; WO2010/42440; (2010); (A1) English View in Reaxys 1 :EXAMPLE 1; Referring to FIG. 1, the flow rate in methane feed line 1 to the bromination reactor 100 is 100 kg/hr. Reactor 100 is operated at 510° C. and 3000 kPag. The conversion of methane is 50percent and the selectivity to methyl bromide is 67percent.Reproportionation reactor 120 is also operated at 510° C. and 3000 kPag. The conversion is 43percent and the selectivity to methyl bromide is 100percent.BTX coupling reactor 140 is operated at 425° C. and 2500 kPag. The conversion of methyl bromide is 100percent and the selectivity to BTX is 32percent.LO coupling reactor 210 is operated at 400° C. and 2500 kPag. The conversion of methyl bromide is 100percent with a selectivity to light olefins (ethane and propylene) of 55percent.Bromine generation reactor 110 is operated at 375° C. and 200 kPag and the flow rate of air through feed line 36 is 554 kg/hr. The conversion and selectivity are both 100percent. The flow rate in water stream 42 is 111 kg/hr.The process produces 4 kg/hr of ethane, 7 kg/hr of LPG, 9 kg/hr of benzene, 14 kg/hr of p-xylene, 17 kg/hr of ethylene and 29 kg/hr of propylene. With oxygen, copper(II) oxide, T= 375 °C Patent; FONG, Howard Lam Ho; Swain, Richard Dale; US2010/234637; (2010); (A1) English View in Reaxys 3 :Example 3; The packing of the quartz tube of Examples 1 and 2 is modified by filling the entire first heated zone of the tube with ceramic Berl saddles having the same characteristics as Examples 1 and 2. The first 5 inches (127 mm) of the second heated zone of the tube is packed with 50 cm3 of catalyst and the remaining 7 inches (178 mm) of the second heated zone are filled with the ceramic Berl saddles. As such, the quartz tube simulates the function of the catalytic reactor 458 as shown in FIGS. 2 and 3.A series of catalytic test runs, C-1 through C-4, are performed in the apparatus using the same analytical methods as above to determine the effect that catalysts, operating within a lower range of temperatures, have on hydrogen bromide oxidation. The operating parameters and results of the catalytic test runs are set forth below in Table 3. With oxygen, copper oxides/alumina, T= 350 °C , Product distribution / selectivity Patent; Marathon GTF Technology, Ltd.; US2011/15458; (2011); (A1) English View in Reaxys 0%

byproducts: H2; pass through a tube at red heat Balard, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 349 ; (from Gmelin) View in Reaxys byproducts: H2; in discharge tube partial decompn. Stead, G.; Proceedings of the Royal Society of London; vol. A 85; (1911); p. 397 ; (from Gmelin) View in Reaxys With Cl2 in water vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With Cl2, byproducts: HCl vol. Br: MVol.; 6.3, page 208 - 213 ; (from Gmelin) View in Reaxys With Cl2, Kinetics, byproducts: HCl vol. Br: MVol.; 6.3, page 208 - 213 ; (from Gmelin) View in Reaxys With H2O2 in water

17/201

2017-08-09 05:21:10

vol. Br: MVol.; 6.3, page 208 - 213 ; (from Gmelin) View in Reaxys With H2SO4 in not given, byproducts: SO2; 60 percent H2SO4 soln., 169 °C vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With H2SO4 in not given, byproducts: SO2; 70 percent H2SO4 soln., 100 °C vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With H2SO4 in not given, byproducts: SO2; 80 percent H2SO4 soln., 46 °C vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With H2SO4 in not given, byproducts: SO2; 90 percent H2SO4 soln., 35 °C vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With H2SO4 in not given, byproducts: SO2 vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With HSO3Cl, byproducts: H2SO4, SO2, HCl; 50 °C vol. Br: MVol.; 6.3, page 208 - 213 ; (from Gmelin) View in Reaxys With SO2Cl2, byproducts: SO2, HCl vol. Br: MVol.; 6.3, page 208 - 213 ; (from Gmelin) View in Reaxys With Ru((NC5H4)2)3Cl2/Co(NH3)5Cl3 in sulfuric acid, aq. H2SO4; Electrochem. Process; HBr was oxidized in a photoelectochemicel cell illuminated with a tungsten-halogen lamp (0-250 W) Neumann-Spallart, Michael; Kalyanasundaram, K.; Berichte der Bunsen-Gesellschaft; vol. 85; nb. 7; (1981); p. 704 - 709 ; (from Gmelin) View in Reaxys With Ru((NC5H4)2)3Cl2/K2S2O8 in sulfuric acid, aq. H2SO4; Electrochem. Process; HBr was oxidized in a photoelectochemicel cell illuminated with a tungsten-halogen lamp (0-250 W) Neumann-Spallart, Michael; Kalyanasundaram, K.; Berichte der Bunsen-Gesellschaft; vol. 85; nb. 7; (1981); p. 704 - 709 ; (from Gmelin) View in Reaxys With Ru((NC5H4)2)3Cl2/Tl(ClO4)3 in sulfuric acid, aq. H2SO4; Electrochem. Process; HBr was oxidized in a photoelectochemicel cell illuminated with a tungsten-halogen lamp (0-250 W) Neumann-Spallart, Michael; Kalyanasundaram, K.; Berichte der Bunsen-Gesellschaft; vol. 85; nb. 7; (1981); p. 704 - 709 ; (from Gmelin) View in Reaxys With oxygen, T= 156.84 °C , p= 760.051Torr , Catalytic behavior, Reagent/catalyst, Temperature Moser, Maximilian; Rodriguez-Garcia, Laura; Amrute, Amol P.; Perez-Ramirez, Javier; ChemCatChem; vol. 5; nb. 12; (2013); p. 3520 - 3523 View in Reaxys With oxygen, Titanium(IV) oxide, Time= 5h, T= 349.84 °C , Gas phase, Flow reactor, Inert atmosphere, Reagent/ catalyst, Temperature

18/201

2017-08-09 05:21:10

Moser, Maximilian; Czekaj, Izabela; Lopez, Nuria; Perez-Ramirez, Javier; Angewandte Chemie - International Edition; vol. 53; nb. 33; (2014); p. 8628 - 8633; Angew. Chem.; vol. 126; nb. 33; (2014); p. 8772 - 8777,6 View in Reaxys 1 : EXAMPLE 1 A laboratory test setup was used to demonstrate the process described herein. This example was used to demonstrate oxidation of hydrogen bromide with a metal oxide. A mixture of simulated process recycle gas is composed of about 54 mol percent methane, about 26 mol percent hydrogen bromide gas, and about 20percent nitrogen to act as an inert tie-element for calculating a mole percent is fed to a tubular reactor containing approximately 20 cm3 of a “solid reactant” composed of iron oxide dispersed on a porous inert support. The solid reactant contains approximately 20 wt percent (as Fe) iron oxide dispersed on 3/16th inch spherical porous beads of gamma-alumina with a specific surface area of approximately 30 m2/g, manufactured by St. Gobain. The externally-insulated reactor tube is maintained at an external wall temperature in the range of approximately 150° C. to 200° C. by electrical resistance heating tape under the insulation to prevent excessive heat loss. Evolution of elemental bromine is observed in the reactor effluent, demonstrating that hydrogen bromide can be oxidized by iron oxide to yield elemental bromine. With iron oxide/γ-alumina, T= 150 - 200 °C Patent; GTC Technology US, LLC; Waycuilis, John J.; US2015/166423; (2015); (A1) English View in Reaxys

Br3Fe

Br2Fe

Rx-ID: 40258540 View in Reaxys 5/751 Yield

Conditions & References 2 : EXAMPLE 2 This example was used to demonstrate regeneration of a metal bromide with an oxygen containing gas mixture. Fifty (50) g of FeBr3 is dissolved in minimal water and imbibed into 75 cm3 of St. Gobain spherical alumina support ( 3/16th spheres). This material is loaded into a reactor tube composed of glass-lined steel pipe that is electrically heat-traced and insulated. N2 gas was flowed at a rate at 15 ml/min though the reactor while ramping up heating of the reactor tube to 150° C. After a period of time bromine evolution is observed in the effluent gas. N2 gas flow is continued until Br2 evolution fell off significantly, then heating is reduced to cool reactor tube to 50° C. under continued N2. Due to the heating under N2 flow FeBr3 is reduced to FeBr2 according to the following reversible reaction: 2FeBr3(s)=2FeBr2(s)+Br2(g) With aluminum oxide, water, oxygen, T= 150 °C , Flow reactor Patent; GTC Technology US, LLC; Waycuilis, John J.; US2015/166423; (2015); (A1) English View in Reaxys

O Br O

K+

BrK

O–

Rx-ID: 26097325 View in Reaxys 6/751 Yield

Conditions & References With fructose powder, oxalic acid in sulfuric acid, byproducts: Ce(3+), CO2, H2O; oscillatory reaction monitored electrocmically Rastogi; Chand, Prem; Chemical Physics Letters; vol. 369; nb. 3-4; (2003); p. 434 - 440 ; (from Gmelin) View in Reaxys Bromate-Bromide solution (10 μgml-1) A stock standard solution of 100 μg ml-1 bromate solution for brominegeneration was prepared by dissolving accurately weighed 0.05 g of potassiumbromate (Sarabhai M. Chemicals, India) and 0.5 g of potassium bromide (S. D. Fine Chem., India) in water and diluted to the mark in a 500 ml calibrated flask.To get 20 μg ml-1 of KBrO3 stock solution, 20 ml of bromate-bromide mixturewas diluted to 100 ml in distilled water. Then, 50 ml of this stock solution wastransferred in to a 100 ml calibrated flask containing 40 ml of 4.25 M H2SO4and diluted to 100 ml with water to get the working concentration of 10 μgml-1 of KBrO3. This bromate solution (10 μg ml-1) was freshly prepared on theday of use. With sulfuric acid in water

19/201

2017-08-09 05:21:10

Deepakumari; Prashanth; Revanasiddappa; Journal of the Chilean Chemical Society; vol. 59; nb. 1; (2014); p. 2382 - 2388 View in Reaxys

(v2)

+ Br Br– H(v1)

Rx-ID: 37486388 View in Reaxys 7/751 Yield

Conditions & References in water, T= 25 °C , Photolysis, Kinetics, Equilibrium constant, pH-value Kalmar, Jozsef; Doka, Eva; Lente, Gabor; Fabian, Istvan; Dalton Transactions; vol. 43; nb. 12; (2014); p. 4862 4870 View in Reaxys Br

(v4)

C–

(v1) (v4) (v6) Br– P Pt4+ P OC-6 – Br (v4) (v1) Br– (v1)

Rx-ID: 35274016 View in Reaxys 8/751 Yield

Conditions & References Photolysis Raphael Karikachery, Alice; Lee, Han Baek; Masjedi, Mehdi; Ross, Andreas; Moody, Morgan A.; Cai, Xiaochen; Chui, Megan; Hoff, Carl D.; Sharp, Paul R.; Inorganic Chemistry; vol. 52; nb. 7; (2013); p. 4113 - 4119 View in Reaxys Br

Rx-ID: 25002580 View in Reaxys 9/751 Yield

Conditions & References 1 : Preparation of the intermediate ethyl 3,3-dimethyl-4,6-dibromo-b,7,7,7-tetrafluoro-heptanoate Elemental analysis: Bromine: calculated, 38.41percent; found: 37.83percent Patent; Montedison S.p.A.; US4258202; (1981); (A1) English View in Reaxys 3 : Preparation of the ethyl 3,3-dimethyl-4,6,6-tribromo-7,7,7-trifluoro heptanoate intermediate Elemental analysis: Bromine: theoretical=50.26percent; found =48.57percent Patent; Montedison S.p.A.; US4258202; (1981); (A1) English View in Reaxys 69 : Preparation of Mg Br2 Solution Example 69 Preparation of Mg Br2 Solution As in Example 67 using 19.0 gm Br2 in 134 ml methanol plus 2.89 gm Mg. Patent; Shell Oil Company; US4806696; (1989); (A1) English View in Reaxys Nishimura, Koichiro; Kinugawa, Masahiko; Organic Process Research and Development; vol. 16; nb. 2; (2012); p. 225 - 231 View in Reaxys

20/201

2017-08-09 05:21:10

F F

O–

N+

N E N

F F

O–

HN N+

N+

Rx-ID: 32617250 View in Reaxys 10/751 Yield

Conditions & References With hydrogen bromide in acetonitrile-D3 Kniep, Florian; Walter, Sebastian M.; Herdtweck, Eberhardt; Huber, Stefan M.; Chemistry - A European Journal; vol. 18; nb. 5; (2012); p. 1306 - 1310 View in Reaxys

Rx-ID: 26179630 View in Reaxys 11/751 Yield

Conditions & References in neat (no solvent), decompn. caused by radium emanation; Lind; Radium (Paris); vol. 8; (1911); p. 289 - 289 View in Reaxys vol. He: Edelgase/MVol.; 65, page 230 - 231 ; (from Gmelin) View in Reaxys With LiBr, KBr, CsBr in melt, Electrolysis; (N2), 1.2 V, 200 mA/cm*2 Park; Chen, Chen; Wieder; Vohs; Gorte; Electrochimica Acta; vol. 56; nb. 3; (2011); p. 1581 - 1584 ; (from Gmelin) View in Reaxys With NaBr in melt, Electrolysis; (N2), 1.2 V, 200 mA/cm*2, 1013 or 1033 K Park; Chen, Chen; Wieder; Vohs; Gorte; Electrochimica Acta; vol. 56; nb. 3; (2011); p. 1581 - 1584 ; (from Gmelin) View in Reaxys Irradiation (UV/VIS); unpolarized excimer radiation (193 and 248 nm, ca 25 mJ/cm**2) of adsorbed (LiF(001)) HBr (ultra-high vac., 85 K); time-of-flight mass spectrometry Cho, C.-C.; Polanyi, J. C.; Stanners, C. D.; Journal of Chemical Physics; vol. 90; (1989); p. 598 - 600 ; (from Gmelin) View in Reaxys

Br( 1-)

H( 1+)

Rx-ID: 26349545 View in Reaxys 12/751 Yield

Conditions & References in water, Kinetics Becker, Robert H.; Bartlett, Wenzel P.; Urbansky, Edward T.; Margerum, Dale W.; Dalton Transactions; nb. 5; (2002); p. 695 - 700 ; (from Gmelin) View in Reaxys in not given Yadav, Narendra; Srivastava; New Journal of Chemistry; vol. 35; nb. 5; (2011); p. 1080 - 1087 ; (from Gmelin) View in Reaxys

BrK

Br -1Br

Rx-ID: 33187411 View in Reaxys 13/751 Yield

Conditions & References in water, Electrochem. Process; aq. soln. of KBr oxidized on nanopaper electrode at 1-1.5 V for 20 and 50 min Krivenko; Komarova; Ryabenko; Naumkin; Stenina; Sviridova; Sulyanov; Russian Chemical Bulletin; vol. 60; nb. 6; (2011); p. 1071 - 1077 ; (from Gmelin) View in Reaxys

21/201

2017-08-09 05:21:10

BrNa

Rx-ID: 25841457 View in Reaxys 14/751 Yield

Conditions & References 7 :Example 7; Sodium chlorite 1.0 gramPotassium monopersulfate 2.0 grams Sodium bromide 0.9 gramsAdd to 300 ml of water. A dark red color was formed immediately that remained for over 2 hours. The characteristic odor of bromine was detected. The solution did not yield any visible or measurable chlorine dioxide. It is believed that the pH was too low, due to the large amount of potassium monopersulfate, thus driving the reaction to form bromine. With Oxonereg;, sodium chlorite, water, Time= 2h, Reactivity Patent; SANDERSON, William, D.; WO2007/78838; (2007); (A2) English View in Reaxys With cobalt acetate tetrahydrate in acetic acid, Kinetics, oxidation at 35°C; monitored by UV-visible methods; spectrophotometry Jiao; Metelski; Espenson; Inorganic Chemistry; vol. 40; nb. 13; (2001); p. 3228 - 3233 ; (from Gmelin) View in Reaxys With anhydrous cobalt diacetate, cobalt acetate tetrahydrate in acetic acid, Kinetics, oxidation at 40°C with Co(III) species in the presence of Co(II) in 0.1percent aq. AcOH; monitored by UV-visible methods; spectrophotometry Jiao; Metelski; Espenson; Inorganic Chemistry; vol. 40; nb. 13; (2001); p. 3228 - 3233 ; (from Gmelin) View in Reaxys With sulfuric acid in not given, dild. H2SO4 Addyman, F. T.; Journal of the Chemical Society; vol. 61; (1892); p. 97 ; (from Gmelin) View in Reaxys With NaCl, NaNO3 in H2O, byproducts: I2, IBr, BrCl; Irradiation (UV/VIS); frozen soln. (248-263 K) contg. NaCl, NaBr and NaNO3 illuminated by 1000W xenon lamp; gas-phase products (Br2, I2, IBr, BrCl) detected by mass spectrometry Abbatt; Oldridge; Symington; Chukalovskiy; McWhinney; Sjostedt; Cox; Journal of Physical Chemistry A; vol. 114; nb. 23; (2010); p. 6527 - 6533 ; (from Gmelin) View in Reaxys With H2SO4 in not given, dild. H2SO4 vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys

OH HO

S OO

Rx-ID: 29197500 View in Reaxys 15/751 Yield

Conditions & References 3 :EXAMPLE 3; Separation of Anhydrous HBrDehydration with H2SO4 was attempted by adding a concentrated solution of H2SO4 to HBr. Qualitative tests were conducted in which different concentration Of H2SO4 were added to HBr for determination of the threshold concentration where oxidation of HBr no longer occurs: _ .2HBr+H2SO4 --> Br2+SO2+2H2OIt was determined that the H2SO4 concentration below which no oxidation is apparent is about 70 wt. percent. 30 ml 70percent H2SO4 was added to 30 ml stock HBr azeotrope (48 wt. percent) and the mixture was heated to boiling. The HBr content was determined quantitatively by AgNO3 precipitation and gravimetric determination of AgBr from a solution aliquot at the moment of mixing, after 15 min and after 30 min boiling. in water, Reflux, Reactivity Patent; GAS REACTION TECHNOLOGIES, INC.; GADEWARD, Sagar; ZHANG, Aihua; JULKA, Vivek; MCFARLAND, Eric, W.; GROSSO, Philip; JANMANCHI, Krishna; SARDAR, Saydul, Amin; STOIMENOV, Peter; KOMON, Zachary, J.A.; LIN, Hongfei; CUTLER, Charles, Ian; CHENG, Jihong; WHEELER, Jean; SUN, Shouli; AUERBACH, Daniel, J.; WYRSTA, Michael, D.; CORONELLA, Charles, J.; HUFF, Shawn; WO2010/9376; (2010); (A1) English

22/201

2017-08-09 05:21:10

View in Reaxys

BrNa

Mn( 4+)

Rx-ID: 30083331 View in Reaxys 16/751 Yield

Conditions & References in acetic acid, Kinetics, aq. acetic acid; NaBr reacted with Mn(4+) in aq. glacial acetic acid at 25-45°C Jee, Joo-Eun; Pestovsky, Oleg; Bakac, Andreja; Dalton Transactions; vol. 39; nb. 48; (2010); p. 11636 - 11642 ; (from Gmelin) View in Reaxys in acetic acid, Kinetics, NaBr reacted with Mn(4+) in glacial acetic acid at 25°C Jee, Joo-Eun; Pestovsky, Oleg; Bakac, Andreja; Dalton Transactions; vol. 39; nb. 48; (2010); p. 11636 - 11642 ; (from Gmelin) View in Reaxys O

O O

2 O O–

O–

Br( 1-)

Br O

O 5

K+

-1

O S OH

Br Br

(v2)

O–

S O–

Rx-ID: 28405747 View in Reaxys 17/751 Yield

Conditions & References With sodium perchlorate in water, Kinetics, soln. of 2KHSO5*KHSO4*K2SO4 in H2O reacted with Br(1-) (excess) at pH 0.8 in presence of NaClO4 at 25°C; not isolated; monitored by UV-vis spectra Lente, Gabor; Kalmar, Jozsef; Baranyai, Zsuzsa; Kun, Aliz; Kek, IIdikoe; Bajusz, David; Takacs, Marcell; Veres, Lilla; Fabian, Istvaen; Inorganic Chemistry; vol. 48; nb. 4; (2009); p. 1763 - 1773 ; (from Gmelin) View in Reaxys

Br -1Br

Br( 1-)

Rx-ID: 26369113 View in Reaxys 18/751 Yield

Conditions & References in water, Kinetics, flash photolysis, 288 K; conductometric detection Wagner, I.; Strehlow, H.; Berichte der Bunsen-Gesellschaft; vol. 91; (1987); p. 1317 - 1321 ; (from Gmelin) View in Reaxys in water, Kinetics, other Radiation; pulse radiolysis of soln. Ershov; Janata; Gordeeva; Russian Chemical Bulletin; vol. 57; nb. 9; (2008); p. 1821 - 1826 ; (from Gmelin) View in Reaxys

BrNa

(v1)

Rx-ID: 26068629 View in Reaxys 19/751 Yield

Conditions & References With sodium lauryl sulfate, sodium chloride in water, Kinetics, in rotating wetted-wall tube at 269 K; various product ratios for various conditions (pH, bromide-to-chloride ratio in soln.); not isolated, detected by mass spectrometry Frinak, Elizabeth K.; Abbatt, Jonathan P. D.; Journal of Physical Chemistry A; vol. 110; nb. 35; (2006); p. 10456 10464 ; (from Gmelin) View in Reaxys

Rx-ID: 26131594 View in Reaxys 20/751

23/201

2017-08-09 05:21:10

Yield

Conditions & References catalytic recombination (wall effect) Bodenstein, M.; Zeitschrift fuer Elektrochemie; vol. 35; (1929); p. 535 View in Reaxys Jost, W.; Z. phys. Ch.; vol. B 3; (1929); p. 104 - 110 ; (from Gmelin) View in Reaxys in neat (no solvent), Kinetics, Recombination of Br atoms giving Br2 is monitored by luminescence spectroscopy. Lavrushenko, B. B.; Bakianov, A. V.; Strunin, V. P.; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy; vol. 46; (1990); p. 479 - 482 ; (from Gmelin) View in Reaxys Kinetics, Irradiation (UV/VIS); recombination Kondratjew, V.; Leipunsky, A.; Naturw..; vol. 16; (1928); p. 463 View in Reaxys Kondratjew, V.; Leipunsky, A.; Zeitschrift fuer Physik; vol. 50; (1928); p. 370 View in Reaxys Kondratjew, V.; Leipunsky, A.; Zeitschrift fuer Physik; vol. 56; (1929); p. 353 View in Reaxys Kondratjew, V.; Leipunsky, A.; Z. fiz. Chim.; vol. 1; (1930); p. 327 ; (from Gmelin) View in Reaxys Kinetics, recombination by collision Trautz, M.; Zeitschrift fuer Elektrochemie; vol. 18; (1912); p. 516 - 516 View in Reaxys Bodenstein, M.; Luetkemeyer, H.; Zeitschrift fuer Elektrochemie; vol. 30; (1924); p. 417 View in Reaxys Bodenstein, M.; Luetkemeyer, H.; Z. phys. Ch.; vol. 114; (1924); p. 233 View in Reaxys Bodenstein, M.; Zeitschrift fuer Elektrochemie; vol. 35; (1929); p. 535 View in Reaxys Herzfeld, K. F.; Annalen der Physik (Weinheim, Germany); vol. 59; (1919); p. 650 View in Reaxys Herzfeld, K. F.; Zeitschrift fuer Elektrochemie; vol. 25; (1919); p. 302 View in Reaxys Herzfeld, K. F.; Zeitschrift fuer Physik; vol. 8; (1922); p. 135 View in Reaxys Jost, W.; Jung, G.; Z. phys. Ch.; vol. B 3; (1929); p. 94 View in Reaxys Jost, W.; Z. phys. Ch.; vol. B 3; (1929); p. 121 View in Reaxys Franck, J.; Jordan, P.; Anregung von Quantenspruengen durch Stoesse, Berlin 1926, S. 301 ; (from Gmelin) View in Reaxys Kinetics Bodenstein, M.; Lind, S. C.; Z. phys. Ch.; vol. 57; (1907); p. 1190 View in Reaxys Bodenstein, M.; Lind, S. C.; Z. phys. Ch.; vol. 57; (1907); p. 168 View in Reaxys Bodenstein, M.; Luetkemeyer, H.; Z. phys. Ch.; vol. 114; (1925); p. 208 View in Reaxys Christiansen, J. A.; Matematisk-Fysiske Meddelelser - Kongelige Danske Videnskabernes Selskab; vol. 1; nb. 14; (1919); p. 4 View in Reaxys Herzfeld, K. F.; Annalen der Physik (Weinheim, Germany); vol. 59; (1919); p. 649 View in Reaxys Herzfeld, K. F.; Annalen der Physik (Weinheim, Germany); vol. 59; (1919); p. 654 View in Reaxys Herzfeld, K. F.; Zeitschrift fuer Elektrochemie; vol. 25; (1919); p. 301

24/201

2017-08-09 05:21:10

View in Reaxys Polanyi, M.; Zeitschrift fuer Elektrochemie; vol. 26; (1920); p. 49 View in Reaxys vol. Br: MVol.; 5.2, page 168 - 180 View in Reaxys Jellinek, K.; Physikalische Chemie der homogenen und heterogenen Gasreaktionen, Leipzig 1913, S. 736 ; (from Gmelin) View in Reaxys catalytic recombination (wall effect) vol. Br: MVol.; 2.2, page 65 - 71 ; (from Gmelin) View in Reaxys Kinetics, Irradiation (UV/VIS); recombination vol. Br: MVol.; 2.2, page 65 - 71 ; (from Gmelin) View in Reaxys Kinetics, recombination by collision vol. Br: MVol.; 2.2, page 65 - 71 ; (from Gmelin) View in Reaxys in neat (no solvent, gas phase), Kinetics, kinetic of recombination of Br atoms at temp. 243-293 K in nitrogen or helium buffer gas was studied; pulsed laser induced fluorescence Donohoue, Deanna L.; Bauer, Dieter; Cossairt, Brandi; Hynes, Anthony J.; Journal of Physical Chemistry A; vol. 110; nb. 21; (2006); p. 6623 - 6632 ; (from Gmelin) View in Reaxys O –O

Na +

Rx-ID: 26448189 View in Reaxys 21/751 Yield

Conditions & References With malonic acid, sulfuric acid, [Fe(1,10-phenanthroline)3]2+ in 1,4-dioxane, water, Kinetics, Belousov-Zhabotinskiireaction, excess of dioxane; stirred; 293+/-0.1 K; spectrophotometry Kovalenko, A. S.; Theoretical and Experimental Chemistry; vol. 19; (1983); p. 197 - 201; Teoreticheskaya i Eksperimental'naya Khimiya; vol. 19; (1983); p. 220 - 225 ; (from Gmelin) View in Reaxys With malonic acid, sulfuric acid, cerium(III) sulphate in 1,4-dioxane, water, Kinetics, Belousov-Zhabotinskii-reaction, excess of dioxane; stirred; 293+/-0.1 K; spectrophotometry Kovalenko, A. S.; Theoretical and Experimental Chemistry; vol. 19; (1983); p. 197 - 201; Teoreticheskaya i Eksperimental'naya Khimiya; vol. 19; (1983); p. 220 - 225 ; (from Gmelin) View in Reaxys With 2-hydroxypropionic acid, sulfuric acid, [Cu(5,7,12,14-tetraethyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)](ClO4)2 in water, byproducts: CH3COCOOH, BrCH2COCOOH, Br(1-); Cu compd. added to mixt. of NaBrO3, H2SO4 and lactic acid in water; oscillation observed with Pt and bromide selective electrode Hu, Gang; Zhang, Zude; Chemistry Letters; vol. 35; nb. 10; (2006); p. 1154 - 1155 ; (from Gmelin) View in Reaxys With 4H(1+)*SiMo12O40 (4-)=H4SiMo12O40#dotC in water, Electrochem. Process Wang, Peng; Wang, Xiangping; Zhu, Guoyi; New Journal of Chemistry; vol. 24; nb. 7; (2000); p. 481 - 483 ; (from Gmelin) View in Reaxys

25/201

2017-08-09 05:21:10

Br2Mg

Rx-ID: 23577016 View in Reaxys 22/751 Yield

Conditions & References 5 Electrolysis Patent; CERAMATEC, INC.; US2005/161340; (2005); (A1) English View in Reaxys

BrLi

Rx-ID: 23577864 View in Reaxys 23/751 Yield

Conditions & References 1; 5 :EXAMPLE 1 Cold Bromination with Sulfide or Polysulfide This first example applies to recovery of alkali metal from sodium sulfide, sodium polysulfide, lithium sulfide, or lithium polysulfide. In this example, liquid bromine is reacted with the solid alkali sulfide or polysulfide to form alkali bromide such as sodium bromide or lithium bromide. An advantage of this approach is the low reaction temperatures that allow the usage of longer lasting, lower cost materials in the reaction vessels. Bromine vaporizes at 59 C; sulfur melts at 115C, while the sodium bromide and lithium bromide melt at 755C and 547C respectively. To remove the bromide reaction product and sulfur from the surface of the reactant, milling may be used. For example, an attrition mill or ball mill promotes mixing of the reactants and removal of passivation layers. Such mills may be operated in batch mode or continuous mode, cooling may be required depending on the intensity of the milling to keep the temperature below the boiling point of bromine or alternatively the milling may operate under pressure to suppress boiling of the bromine. After reaction the slurry can be filtered to remove bromine from the solids consisting of sulfur and alkali bromide. Filtered bromine can be reused for further bromination. Next the solids are heated to approximately >150C to liquefy the sulfur to promote separation of the alkali bromide from the sulfur. Additional reaction stages may be introduced either to reduce the amount of sodium content in the sulfur product or to reduce the amount of sulfide in the alkali bromide. After forming the alkali bromide, the bromide may be added directly to an electrolytic cell or pretreated to remove non-alkali metals. The pretreatment consists of mixing the bromide with other salts to form a relatively low temperature melt. Where lithium is the intended alkali metal to be cycled for desulfurization, the melt can be low melting. An example electrolyte is 34percent LiCl, 32.5percent LiBr, and 33.5percent KBr which melts at less than 350 C. The mixture of salts melts lower than any of the salts individually. But LiBr has the lowest decomposition voltage in the melt and is the constituent to preferentially electrolyze later in the cell. After the bromide salts have been added to the salt mixture melt, some lithium metal is added to the melt where it reacts with any non-alkali metal bromides such as vanadium, nickel, or iron bromides to form metallic vanadium, nickel, and iron and lithium bromide. The non-alkali metals being more dense and in a different phase than the melt can be separated by settling, filtering or the like. The treated melt can be transferred to the electrolytic cell, which may be very similar to the commercial Downs-cell. The Downs-cell has a steel cathode and graphite anode with steel mesh there between. The electrolyte melt is in contact with both electrodes and is free to flow through the mesh. As DC current is applied to the cell, bromine gas is evolved from the anode. A hood over the anode is used to collect the gas to chillers and storage where it can be used for subsequent bromination of sulfides. Concurrently, molten lithium is formed on the cathode. Since lithium metal is lighter than the melt it floats to the top where it can be suctioned out of the cell for use in further desulfurization. Lithium bromide must be added at about the same rate as consumed by the electrode reactions in a continuous or semi-continuous fashion to maintain the bath composition. Where sodium is the intended alkali metal to be cycled for desulfurization, all is the same as described for lithium above except that a different electrolyte must be utilized. Here the mixture will be of NaCl, NaBr, KBr and or CaBr2 and BaBr2. Again, the melt has a lower melting temperature than the individual salts and NaBr preferentially electrolyzes. Instead of cycling lithium to the desulfurization and demetallation, sodium is cycled.; EXAMPLE 5 Electrolysis with Down's Cell Operation of the Down's cell to produce sodium from a melt containing NaCl, CaCl2 and BaCl2 is well known and described in the prior art. Such cells have produced on a commercial scale sodium metal and chlorine gas, consuming sodium chloride salt. For the purposes of this invention, this mode of operation is a satisfactory path. Sodium can be used in the desulfurization process described in the prior art and chlorine can be used to chlorinate the sodium sulfide, sodium polysulfide, or sodium hydrosulfide formed as byproduct of those processes. However, the preference is to use the Down's cell to form either lithium and bromine from lithium bromide in a suitable melt as described in Example 1 or sodium and bromine from sodium bromide in a suitable melt again as described in Example 1. An advantage of using bromine in the cycle over chlorine is the decomposition voltage of the bromides are lower than the chlorides, thus the cell is able to maintain the same current and produce the same molar amount of metal using less power and less energy. Another advantage is the bromine is less corrosive than chlorine, and therefore the materials in the vessels and gas ducts may be constructed from less expensive material or be expected to last longer. Another advantage of bromine over chlorine is that the melts

Copyright ÂŠ 2017 Reed Elsevier Properties SA. All rights reserved. Authorized use only. ReaxysÂŽ and the ReaxysÂŽ trademark are owned and protected by Reed Elsevier Properties SA and used under license.

26/201

2017-08-09 05:21:10

have lower melting temperatures; therefore the cells are able to operate at lower temperature. Lower cell temperature extends cell life and decreases cost of operation. , Electrolysis Patent; CERAMATEC, INC.; US2005/161340; (2005); (A1) English View in Reaxys

BrNa

Rx-ID: 23579172 View in Reaxys 24/751 Yield

Conditions & References 1; 5 :EXAMPLE 1 Cold Bromination with Sulfide or Polysulfide This first example applies to recovery of alkali metal from sodium sulfide, sodium polysulfide, lithium sulfide, or lithium polysulfide. In this example, liquid bromine is reacted with the solid alkali sulfide or polysulfide to form alkali bromide such as sodium bromide or lithium bromide. An advantage of this approach is the low reaction temperatures that allow the usage of longer lasting, lower cost materials in the reaction vessels. Bromine vaporizes at 59 C; sulfur melts at 115C, while the sodium bromide and lithium bromide melt at 755C and 547C respectively. To remove the bromide reaction product and sulfur from the surface of the reactant, milling may be used. For example, an attrition mill or ball mill promotes mixing of the reactants and removal of passivation layers. Such mills may be operated in batch mode or continuous mode, cooling may be required depending on the intensity of the milling to keep the temperature below the boiling point of bromine or alternatively the milling may operate under pressure to suppress boiling of the bromine. After reaction the slurry can be filtered to remove bromine from the solids consisting of sulfur and alkali bromide. Filtered bromine can be reused for further bromination. Next the solids are heated to approximately >150C to liquefy the sulfur to promote separation of the alkali bromide from the sulfur. Additional reaction stages may be introduced either to reduce the amount of sodium content in the sulfur product or to reduce the amount of sulfide in the alkali bromide. After forming the alkali bromide, the bromide may be added directly to an electrolytic cell or pretreated to remove non-alkali metals. The pretreatment consists of mixing the bromide with other salts to form a relatively low temperature melt. Where lithium is the intended alkali metal to be cycled for desulfurization, the melt can be low melting. An example electrolyte is 34percent LiCl, 32.5percent LiBr, and 33.5percent KBr which melts at less than 350 C. The mixture of salts melts lower than any of the salts individually. But LiBr has the lowest decomposition voltage in the melt and is the constituent to preferentially electrolyze later in the cell. After the bromide salts have been added to the salt mixture melt, some lithium metal is added to the melt where it reacts with any non-alkali metal bromides such as vanadium, nickel, or iron bromides to form metallic vanadium, nickel, and iron and lithium bromide. The non-alkali metals being more dense and in a different phase than the melt can be separated by settling, filtering or the like. The treated melt can be transferred to the electrolytic cell, which may be very similar to the commercial Downs-cell. The Downs-cell has a steel cathode and graphite anode with steel mesh there between. The electrolyte melt is in contact with both electrodes and is free to flow through the mesh. As DC current is applied to the cell, bromine gas is evolved from the anode. A hood over the anode is used to collect the gas to chillers and storage where it can be used for subsequent bromination of sulfides. Concurrently, molten lithium is formed on the cathode. Since lithium metal is lighter than the melt it floats to the top where it can be suctioned out of the cell for use in further desulfurization. Lithium bromide must be added at about the same rate as consumed by the electrode reactions in a continuous or semi-continuous fashion to maintain the bath composition. Where sodium is the intended alkali metal to be cycled for desulfurization, all is the same as described for lithium above except that a different electrolyte must be utilized. Here the mixture will be of NaCl, NaBr, KBr and or CaBr2 and BaBr2. Again, the melt has a lower melting temperature than the individual salts and NaBr preferentially electrolyzes. Instead of cycling lithium to the desulfurization and demetallation, sodium is cycled. ; EXAMPLE 5 Electrolysis with Down's Cell Operation of the Down's cell to produce sodium from a melt containing NaCl, CaCl2 and BaCl2 is well known and described in the prior art. Such cells have produced on a commercial scale sodium metal and chlorine gas, consuming sodium chloride salt. For the purposes of this invention, this mode of operation is a satisfactory path. Sodium can be used in the desulfurization process described in the prior art and chlorine can be used to chlorinate the sodium sulfide, sodium polysulfide, or sodium hydrosulfide formed as byproduct of those processes. However, the preference is to use the Down's cell to form either lithium and bromine from lithium bromide in a suitable melt as described in Example 1 or sodium and bromine from sodium bromide in a suitable melt again as described in Example 1. An advantage of using bromine in the cycle over chlorine is the decomposition voltage of the bromides are lower than the chlorides, thus the cell is able to maintain the same current and produce the same molar amount of metal using less power and less energy. Another advantage is the bromine is less corrosive than chlorine, and therefore the materials in the vessels and gas ducts may be constructed from less expensive material or be expected to last longer. Another advantage of bromine over chlorine is that the melts have lower melting temperatures; therefore the cells are able to operate at lower temperature. Lower cell temperature extends cell life and decreases cost of operation. , Electrolysis

27/201

2017-08-09 05:21:10

Patent; CERAMATEC, INC.; US2005/161340; (2005); (A1) English View in Reaxys

Rx-ID: 23665354 View in Reaxys 25/751 Yield

Conditions & References 9; 10; 11; 16 :Example 9 This example represents a four-fold scale-up of the reactions described in examples 2-8. To a stirred reaction flask containing 48percent hydrogen bromide (111.2 g) was added 50percent H202 (16.96 g) dropwise so that the reaction flask temperature did not exceed 142F. AFTER allowing the reaction flask to cool to around 85°F, solid sulfamic acid (76.8 g) was introduced. The resulting slurry was stirred as 50percent sodium hydroxide solution (91.9 g) was charged to the reaction flask to give a pH of 1.5. The flask was chilled during this process so that the temperature did not exceed 80-90° F. A single charge of granular trichloroisocyanuric acid (TCCA) (36.0 g) was introduced to the reaction flask that was stirred for 20 minutes. Most of the coarse TCCA granules were observed to have reacted within this period, as a fine powdery precipitate developed and the pH of the reaction medium was measured to be 1.5. Deionized water (28 g) was added to the reaction flask to facilitate the complete reaction of the TCCA. The cyanuric acid solid was removed by vacuum filtration and the filter cake was washed with deionized water (12.5 ml) that was not combined with the mother liquors. The wet filter cake was placed in an oven at 130°F for drying overnight. To the filtration mother liquors was added 50percent NAOH (104 g), also with cooling, and at a rate such that the temperature did not exceed 80-90° F. Any additional solid cyanurate salts that developed were removed by vacuum filtration. The solids retained on the filter were washed with deionized water (5.0 g) and then dried in an oven at 130° F. Iodometric titration of the resultant golden yellow solution yielded a percent Br2 content of 23.7percent (or 10.54percent as C12). The theoretical amount OF BR2 (or C12 equivalent) produced as a function of the sum of the hydrogen peroxide and TCCA charges was used to compute a reaction yield of 100percent. The weight of the dried solids removed by filtration indicated that cyanuric acid and cyanurate salts were recovered in close to quantitative yield.; Examples 10-11 A general procedure for preparing the liquid stabilized bromine concentrates listed in Table III is as follows: To a stirred reaction flask containing 48percent HBr, the appropriate amount of 50percent hydrogen peroxide was added drop-wise at a rate such that the temperature did not exceed 142° F. After allowing the reaction flask to cool to around 95° F, solid sulfamic acid was introduced. The resulting slurry was stirred as the appropriate amount of 50percent NAOH solution was charged to the reaction flask that was cooled so the temperature did not exceed 85° F. Thereafter, the correct amount of granular calcium hypochlorite (59.5percent available chlorine) was introduced, also with stirring. Upon filtration of insolubles, sufficient 50percent NAOH and solid NAOH was slowly introduced so that the overall mole ratio of aqueous hydrogen bromide to hydroxide was 1: 3. During the addition, the reaction flask was cooled on ice so that the temperature of the contents did not exceed 80-90° F. Iodometric titration of the resultant golden yellow solutions was used to determine the weight percent Br2 (or Cl2) contents. The theoretical amounts of Br2 (or C12 equivalent) produced as a function of the sum of the hydrogen peroxide and calcium hypochlorite charges were then used to compute the percent yield of each reaction.; Example 16 To a stirred reaction flask containing 48percent HBr (69.5 g) was added 50percent H202 (10.6 g) dropwise so that the reaction flask temperature did not exceed 142° F. After allowing the reaction flask to cool to about 90° F, solid sulfamic acid (48 g) was introduced. The resulting slurry was stirred as solid sodium hydroxide pellets were charged to the reaction flask. The flask was chilled during this process so that the temperature did not exceed 80° F. A single charge of granular trichloroisocyanuric acid (22.0 g) was introduced to the reaction flask that was stirred for about 20 minutes. Not all the coarse TCCA granules were observed to have reacted during this time, and so deionized water (5 ml) was added to the reactor to assist the process. As the reaction proceeded, a fine powdery precipitate developed which was removed by vacuum filtration. Then additional solid NaOH pellets (17 g) were introduced also with cooling and at a rate such that the temperature did not exceed 80° F. Any additional precipitate that developed was immediately removed by vacuum filtration. Iodometric titration of the resulting golden yellow solution was used to determine its Br2 content of 27.2percent (or 12. 1percent as CIS). Within a few minutes, this highly concentrated bromine solution started to turn turbid as crystals began to form. The crystallizing solution was chilled in an ice bath to expedite the development of the crystals. A large crop of yellow crystalline material was separated by vacuum filtration, and the mother liquors were retitrated iodometrically. The new bromine content was found to be 24.3percent (10.8percent as CLZ), indicating that the solution had lost soluble oxidant as the solids crystallized. The yellow crystalline material displayed exceptionally high solubility in water. The dissolution process was rapid and complete. There were no insoluble residues. Iodometric titration of resulting solutions was used to calculate that the crystalline solid contained 29.9percent Br2 (13. 1percent as C12). in water, T= 61.1011 °C , Product distribution / selectivity Patent; ENVIRO TECH CHEMICAL SERVICES INC.; WO2005/9127; (2005); (A1) English View in Reaxys

28/201

2017-08-09 05:21:10

Br Ge

Ge Br

Br2Ge

Rx-ID: 26484355 View in Reaxys 26/751 Yield

Conditions & References in gas, thermodynamics of equilibrium stidued via vapor pressure measurements; not isolated Zelenina; Titov; Chusova; Russian Journal of Physical Chemistry A; vol. 79; nb. 1; (2005); p. 43 - 46 ; (from Gmelin) View in Reaxys

(v3)

(v2)

OH 2

(v4)

3+ 3 H 3N RhNH NH 3 H 3NOC-6(v6)

(v4)

(v3)

OOH –

BrNa

(v4)

OH – (v4) 3+ 3 H 3N RhNH NH 3 (v4) H 3NOC-6(v6) (v4) OH 2

(v3)

Rx-ID: 26281942 View in Reaxys 27/751 Yield

Conditions & References With perchloric acid in water, Kinetics, satd. soln. of bromide in 0.10 M HClO4, 25+/-0.2 degree.C; not sepd., detected by UV-vis spectra Lemma, Kelemu; Bakac, Andreja; Inorganic Chemistry; vol. 43; nb. 14; (2004); p. 4505 - 4510 ; (from Gmelin) View in Reaxys

HO H N

N (v2) O–(v4) (v6) (v4)Rh 3+ (v4) OC-6 N OH(v4) 2 H N (v3)

(v3) (v4) (v4)

N OH 2NH Rh 3+ OC-6 (v6) H N(v4) N (v4)OH (v3)2H

BrNa

Rx-ID: 26281951 View in Reaxys 28/751 Yield

O Br

(v4)

Rx-ID: 26384938 View in Reaxys 29/751 Yield

Conditions & References in dichloromethane Alves, Wagner A.; Cortes, Carlos E. S.; Faria, Roberto B.; Inorganic Chemistry; vol. 43; nb. 14; (2004); p. 4112 4114 ; (from Gmelin) View in Reaxys O

Br( 1-)

H( 1+)

O–

Rx-ID: 26414406 View in Reaxys 30/751 Yield

Conditions & References With acetate in water, Kinetics, 25°C Cortes, Carlos Eduardo S.; Faria, Roberto B.; Inorganic Chemistry; vol. 43; nb. 4; (2004); p. 1395 - 1402 ; (from Gmelin) View in Reaxys in water, Kinetics, 25°C Cortes, Carlos Eduardo S.; Faria, Roberto B.; Inorganic Chemistry; vol. 43; nb. 4; (2004); p. 1395 - 1402 ; (from Gmelin) View in Reaxys

29/201

2017-08-09 05:21:10

(v1)

Xe O

F(v6)

F + FTe F F

F F TeF F F F F F F TeF O FTeF F F F O O Sb– O F O F Te F F FTeF F F F O F F TeF F F F

F F F F Te F F F F F Te O O F – O Sb O F O O F Te F Te F F F F F

C+

F F F F Te F

F F Te F F F F Te F F F F F F

O F O Te F F F

C+

Te F

F F F F Te F F F F F Te O O F – O Sb O F O O F Te F Te F F F F F

F F

F F F

F F F Te F F F F F F

Rx-ID: 27470928 View in Reaxys 31/751 Yield

Conditions & References in ClSO2F (sulfuryl chloride fluoride), inside the drybox; (XeOTeF5)(Sb(OTeF5)6) and CBr4 loaded into vessel at -120°C; removed cold from drybox; placed in a -78°C bath; SO2ClF condensed under static vac.; warmed over period for several hs toabout -50°C; solvent and other volatiles removed under vac. between -78 and 0°C; monitored by NMR spectroscopy and Raman spectroscopy Mercier, Helene P. A.; Moran, Matthew D.; Schrobilgen, Gary J.; Steinberg, Christoph; Suontamo, Reijo J.; Journal of the American Chemical Society; vol. 126; nb. 17; (2004); p. 5533 - 5548 ; (from Gmelin) View in Reaxys

H H HO H N – (v2) N O 3+ (v4) (v6) (v4)Rh (v4) OC-6N H N OH (v3)2 H (v4)

H H

BrNa

H (v3) N OH(v4) 2 (v6) (v4) (v4)Rh 3+ OC-6N H N OH (v3)2 H

(v4)

Rx-ID: 27702438 View in Reaxys 32/751 Yield

O –O Mn2+

Br O

2 O–

O–

K+ –O

O S

–O

MnO 2 .gamma.

OH HO

S OO

Rx-ID: 26376028 View in Reaxys 33/751 Yield

Conditions & References With poly(ethylene glycol) or poly(vinylpyrrolidone) in water, High Pressure; for urchinlike structures soln. of mixt. sealed in autoclave, heated to 110 or 130 °C (1 °C/min), maintained at 130 °C for 16 h; for sisalike structures polymer added, heated in autoclave at 110(PEG) or 90 °C (PVP) for 16 h Wu, Changzheng; Xie, Yi; Wang, Dong; Yang, Jun; Li, Tanwei; Journal of Physical Chemistry B; vol. 107; nb. 49; (2003); p. 13583 - 13587 ; (from Gmelin) View in Reaxys -1

Br Br

(v2)

Rx-ID: 26483819 View in Reaxys 34/751 Yield

Conditions & References With (C2H5)4NClO4 in acetonitrile, Kinetics, Electrochem. Process; at 25°C; Et4NClO4 as supporting electrolyte; not isolated Datta; Bhattacharya; Sinha; Kundu; Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry; vol. 42; nb. 10; (2003); p. 2509 - 2512 ; (from Gmelin)

30/201

2017-08-09 05:21:10

View in Reaxys With (C2H5)4NClO4 in further solvent(s), Kinetics, Electrochem. Process; at 25°C in propylene carbonae; Et4NClO4 as supporting electrolyte; not isolated Datta; Bhattacharya; Sinha; Kundu; Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry; vol. 42; nb. 10; (2003); p. 2509 - 2512 ; (from Gmelin) View in Reaxys With (C2H5)4NClO4 in N,N-dimethyl-formamide, Kinetics, Electrochem. Process; at 25°C; Et4NClO4 as supporting electrolyte; not isolated Datta; Bhattacharya; Sinha; Kundu; Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry; vol. 42; nb. 10; (2003); p. 2509 - 2512 ; (from Gmelin) View in Reaxys 6 Br– Br 2 Br

Pd2+

Pd4+ 4

6 Br–

H H 2N

Pd2+

NH 2 H

4+ HPd H 2N NH 2 H

Rx-ID: 27688688 View in Reaxys 35/751 Yield

Conditions & References in neat (no solvent), ground in mortar by exposing to air Asaji, Tetsuo; Sakurai, Toshio; Ikeda, Ryuichi; Solid State Communications; vol. 125; nb. 3-4; (2003); p. 171 173 ; (from Gmelin) View in Reaxys CuO

Rx-ID: 24006281 View in Reaxys 36/751 Yield 100%

Conditions & References Testing Reaction 3: The solid CuBr2/ZrO2 was transferred from Reactor 2to Reactor 3and treated with O2 at 300° C. to yield Br2 and CuO/ZrO2 at 100percent yield and conversion. This reaction may be run at 1000 h-1. Patent; Zhou, Xiao Ping; Lorkovic, Ivan Marc; Sherman, Jeffrey H.; US2002/198416; (2002); (A1) English View in Reaxys

100%

Reaction 3 Reaction 3 The solid CuBr2/ZrO2 was transferred from Reactor 2 to Reactor 3 and treated with O2 at 300° C. to yield Br2 and CuO/ZrO2 at 100percent yield and conversion. This reaction may be run at 1000 h-1. Patent; GRT, Inc.; The Regents of the University of California; US6465696; (2002); (B1) English View in Reaxys Patent; GRI, Inc.; The Regents of the University of California; US6465699; (2002); (B1) English View in Reaxys Patent; GRT, Inc.; The Regents of the University of California; US6486368; (2002); (B1) English View in Reaxys

BrNa

HNaO

Rx-ID: 26063506 View in Reaxys 37/751 Yield

Conditions & References in neat (no solvent), Kinetics, detected by MS

31/201

2017-08-09 05:21:10

Chu, Liang T.; Diao, Guowang; Chu, Liang; Journal of Physical Chemistry B; vol. 106; nb. 22; (2002); p. 5679 5688 ; (from Gmelin) View in Reaxys O

H –O

Na +

Rx-ID: 26147716 View in Reaxys 38/751 Yield

Conditions & References in hydrogenchloride, Kinetics, mixing of aq. bromate soln. with aq. hydrochloric acid; detected by UV Ensafi, Ali A; Rezaei; Movahedinia; Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy; vol. 58; nb. 12; (2002); p. 2589 - 2594 ; (from Gmelin) View in Reaxys

Br C

Rx-ID: 26156207 View in Reaxys 39/751 Yield

Conditions & References in neat (no solvent), Kinetics, byproducts: BrCO; Irradiation (UV/VIS); photodissociation at 2567 nm; detected by multiphoton ionization and time-of-flight mass spectroscopy Xu, Dadong; Huang, Jianhua; Francisco, Joseph S.; Hansen, Jaron C.; Jackson, William M.; Journal of Chemical Physics; vol. 117; nb. 16; (2002); p. 7483 - 7490 ; (from Gmelin) View in Reaxys

ice doped with HBr

Rx-ID: 26405542 View in Reaxys 40/751 Yield

Conditions & References

8 %, 4 %, 43 %

in neat (no solvent), Kinetics, byproducts: HNO3; orifice reactor; 180-210 K; MS Aguzzi, Arnaud; Rossi, Michel J.; Journal of Physical Chemistry A; vol. 106; nb. 24; (2002); p. 5891 - 5901 ; (from Gmelin) View in Reaxys

O Br

O–

Rx-ID: 26456994 View in Reaxys 41/751 Yield

Conditions & References With fructose powder, sulfuric acid, cerium(IV)(4+) in sulfuric acid, Kinetics, byproducts: Ce(3+), 5-keto glutaric acid; by stirring; monitored spectrophotometrically at 316.9 nm Rastogi; Husain; Chand, Prem; Misra; Das, Mukul; Chemical Physics Letters; vol. 353; nb. 1-2; (2002); p. 40 48 ; (from Gmelin) View in Reaxys With sulfur in water, at 160°C in an evacuated sealed tube Lewis, G. N.; Randall, M.; Bichowsky v, F. R.; Journal of the American Chemical Society; vol. 40; (1918); p. 356 362 View in Reaxys vol. S: MVol.A3; 5.3.4, page 713 - 718 ; (from Gmelin) View in Reaxys With manganese cation, Kinetics, oscillation reaction Alamgir, Mohamed; Orban, Miklos; Epstein, Irving R.; Journal of Physical Chemistry; vol. 87; nb. 19; (1983); p. 3725 - 3728 ; (from Gmelin) View in Reaxys

32/201

2017-08-09 05:21:10

O Br O

K+

O–

Rx-ID: 26111328 View in Reaxys 42/751 Yield >99

Conditions & References With sulfuric acid, cobalt(II) dibromide in water, obtain Br2 from KBr by adding H2SO4 and more KBrO3 vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Jones, C. W.; Schaefer, A. E.; AU03121; (1909) ; (from Gmelin) View in Reaxys

>99

With sulfuric acid, FeBr2 in water, byproducts: Fe2O3; obtain Br2 from KBr by adding H2SO4 and more KBrO3 vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Jones, C. W.; Schaefer, A. E.; AU03121; (1909) ; (from Gmelin) View in Reaxys

>99

With sulfuric acid, niobium bromide in water, obtain Br2 from KBr by adding H2SO4 and more KBrO3 vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Jones, C. W.; Schaefer, A. E.; AU03121; (1909) ; (from Gmelin) View in Reaxys With sulfur dioxide in water Balard, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 337 - 384 View in Reaxys Balard, A. J.; Annalen der Physik (Weinheim, Germany); vol. 8; (1826); p. 461 - 474 View in Reaxys vol. S: MVol.B2; 1.6.2.4, page 519 - 520 ; (from Gmelin) View in Reaxys With cerium (IV) sulfate, malonic acid in sulfuric acid, Kinetics, in closed unstirred system at 0-8°C Masia, Marco; Marchettini, Nadia; Zambrano, Vincenzo; Rustici, Mauro; Chemical Physics Letters; vol. 341; nb. 3-4; (2001); p. 285 - 291 ; (from Gmelin) View in Reaxys With sulfuric acid in water, Kinetics, byproducts: Br(1-); at 20.0 +/- 0.1 °C the mixture of soln. of pyrogallic acid and sulphuric acid was taken in reaction cell, potassium bromate soln. was added, time period of oscillation was observed Ameta, Suresh C.; Khandia, B. L.; Zeitschrift fuer Physikalische Chemie (Leipzig); vol. 263; nb. 2; (1982); p. 410 412 ; (from Gmelin) View in Reaxys With oxonium, thiourea in perchloric acid, Kinetics, byproducts: (NH4)2SO4, CO2; pH < 2, 30+/-0.2°C, 0.2 M NaClO4 (continuously stirred tank reactor); monitored by spectrophotometry and potentiometric measurements Simoyi, Reuben H.; Journal of Physical Chemistry; vol. 90; nb. 13; (1986); p. 2802 - 2804 ; (from Gmelin) View in Reaxys With hydrogen fluoride, anhydrous HF Gore, G.; Journal of the Chemical Society; vol. 22; (1869); p. 394 ; (from Gmelin) View in Reaxys With selenium, reduction; Coleman, W. C.; McCrosky, C. R.; Journal of the American Chemical Society; vol. 59; (1937); p. 1459 - 1459 View in Reaxys Montignie, E.; Bulletin de la Societe Chimique de France; vol. 53; (1933); p. 1392 - 1392 View in Reaxys

33/201

2017-08-09 05:21:10

vol. Se: MVol.A1; 78, page 252 - 254 ; (from Gmelin) View in Reaxys With sulfuric acid in tetrahydrofuran, water, Kinetics, at 303 K in presence of ferroin indicator; reaction studied by calorimetrically and potentiometrically Biswas, Sudeshna; Mukherjee, Kallol; Basu, Samarendra Nath; Mukherjee, Dulal Chandra; Moulik, Satya Priya; Zeitschrift fur Physikalische Chemie; vol. 215; nb. 5; (2001); p. 575 - 592 ; (from Gmelin) View in Reaxys With sulfuric acid in water, N,N-dimethyl-formamide, Kinetics, at 303 K in presence of ferroin indicator; reaction studied by calorimetrically and potentiometrically Biswas, Sudeshna; Mukherjee, Kallol; Basu, Samarendra Nath; Mukherjee, Dulal Chandra; Moulik, Satya Priya; Zeitschrift fur Physikalische Chemie; vol. 215; nb. 5; (2001); p. 575 - 592 ; (from Gmelin) View in Reaxys With sulfuric acid in water, acetonitrile, Kinetics, at 303 K in presence of ferroin indicator; reaction studied by calorimetrically and potentiometrically Biswas, Sudeshna; Mukherjee, Kallol; Basu, Samarendra Nath; Mukherjee, Dulal Chandra; Moulik, Satya Priya; Zeitschrift fur Physikalische Chemie; vol. 215; nb. 5; (2001); p. 575 - 592 ; (from Gmelin) View in Reaxys With sulfuric acid in 1,4-dioxane, water, Kinetics, at 303 K in presence of ferroin indicator; reaction studied by calorimetrically and potentiometrically Biswas, Sudeshna; Mukherjee, Kallol; Basu, Samarendra Nath; Mukherjee, Dulal Chandra; Moulik, Satya Priya; Zeitschrift fur Physikalische Chemie; vol. 215; nb. 5; (2001); p. 575 - 592 ; (from Gmelin) View in Reaxys With sodium parawolframate, decompn. at 280-300 °C Potylizyn, A.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 27; (1895); p. 273 ; (from Gmelin) View in Reaxys With HF vol. K: MVol.3; 1.6.2, page 580 - 581 ; (from Gmelin) View in Reaxys With sodium parawolframate vol. K: MVol.3; 1.6.2, page 580 - 581 ; (from Gmelin) View in Reaxys

(v2)

N O

(v1)

Rx-ID: 26405544 View in Reaxys 43/751 Yield

Conditions & References in gaseous matrix, Kinetics, Irradiation (UV/VIS); flash photolysis, large excess of BrONO2 over Br, 0.5 Torr CO2 added, 224- 352 K, 20-251 Torr, using 248-355 nm radiation Soller; Nicovich; Wine; Journal of Physical Chemistry A; vol. 105; nb. 9; (2001); p. 1416 - 1422 ; (from Gmelin) View in Reaxys

Ce 4+ O 4 O

O– Cl

–O

O Mn2+

BrK

Mn( 2+)

Rx-ID: 26063371 View in Reaxys 44/751 Yield

Conditions & References in acetic acid, Kinetics, stopped-flow technique; oxidn. of KBr by Mn(III); soln. of Mn(III) prepared in situ by rapid oxidn. of Mn(OAc)2 by Ce(ClO4)4 in 10percent aq. acetic acid at 4.5°C; monitored spectrophotometrically

34/201

2017-08-09 05:21:10

Jiao, Xiang-Dong; Espenson, James H.; Inorganic Chemistry; vol. 39; nb. 7; (2000); p. 1549 - 1554 ; (from Gmelin) View in Reaxys Ce 4+ O 4

–

O–

Mn2+

BrLi

Mn( 2+)

Rx-ID: 26063372 View in Reaxys 45/751 Yield

Conditions & References in acetic acid, Kinetics, stopped-flow technique; oxidn. of LiBr by Mn(III); soln. of Mn(III) prepared in situ by rapid oxidn. of Mn(OAc)2 by Ce(ClO4)4 in 10percent aq. aceticacid at 4.5°C; monitored spectrophotometrically Jiao, Xiang-Dong; Espenson, James H.; Inorganic Chemistry; vol. 39; nb. 7; (2000); p. 1549 - 1554 ; (from Gmelin) View in Reaxys

Ce 4+ O 4

–O

O–

Mn2+

BrNa

Mn( 2+)

Rx-ID: 26063373 View in Reaxys 46/751 Yield

Conditions & References in acetic acid, Kinetics, stopped-flow technique; oxidn. of NaBr by Mn(III); soln. of Mn(III) prepared in situ by rapid oxidn. of Mn(OAc)2 by Ce(ClO4)4 in 10percent aq. aceticacid at 4.5°C; monitored spectrophotometrically Jiao, Xiang-Dong; Espenson, James H.; Inorganic Chemistry; vol. 39; nb. 7; (2000); p. 1549 - 1554 ; (from Gmelin) View in Reaxys

Ce 4+ O 4

–O

O–

O Mn2+

Mn( 2+)

Rx-ID: 26063375 View in Reaxys 47/751 Yield

Conditions & References in acetic acid, Kinetics, stopped-flow technique; oxidn. of HBr by Mn(III) (molar ratio (6-17.5):1); soln. of Mn(III) prepared in situ by rapid oxidn. of Mn(OAc)2 by Ce(ClO4)4 in 10percent aq. acetic acid at 4.5°C; monitored spectrophotometrically Jiao, Xiang-Dong; Espenson, James H.; Inorganic Chemistry; vol. 39; nb. 7; (2000); p. 1549 - 1554 ; (from Gmelin) View in Reaxys K+

Br( 1-)

Br O

O–

Rx-ID: 26111330 View in Reaxys 48/751 Yield

Conditions & References With fructose powder, sulfuric acid, 2,3-dihydroxybutanedioic acid, CAS in water, Kinetics, system and order of addn.: H2SO4 (1.5 M) + BrO3(1-) (0.06 M) + Ce(4+) (1.45E-3 M) + fructose (0.01-0.4 M) + tartaric acid (0.005-0.6 M); temp. =26+/-1°C; with and without KBr; not isolated; determination of Br(1-) with ion-sensitive electrode and of Br2 and Ce(4+) spectrophotometrically Rastogi; Husain; Chand; Das; Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry; vol. 39; nb. 7; (2000); p. 679 - 684 ; (from Gmelin) View in Reaxys

Br Br

Rx-ID: 26179658 View in Reaxys 49/751 Yield 65.2-93.8

Conditions & References Cl2/Br(1-) molar ratio 0.82-1.80

35/201

2017-08-09 05:21:10

Vlasov; Bushina; Buravtseva; Mukhametshina; Russian Journal of Applied Chemistry; vol. 73; nb. 4; (2000); p. 726 - 727 ; (from Gmelin) View in Reaxys ice doped with HBr

Rx-ID: 26356026 View in Reaxys 50/751 Yield

Conditions & References Kinetics, HBr deposited on ice at 200 K, this exposed to BrCl flow; products thermally desorbed and monitored by MS Allanic; Oppliger; Van Den Bergh; Rossi; Zeitschrift fur Physikalische Chemie; vol. 214; nb. 11; (2000); p. 1479 1500 ; (from Gmelin) View in Reaxys

(v1)

Rx-ID: 26385132 View in Reaxys 51/751 Yield

Conditions & References in gas, Kinetics, detected by IR Orlando, John J.; Burkholder, James B.; Journal of Physical Chemistry A; vol. 104; nb. 10; (2000); p. 2048 2053 ; (from Gmelin) View in Reaxys

ice doped with HI

Rx-ID: 26405543 View in Reaxys 52/751 Yield

Conditions & References Kinetics, byproducts: HNO3; continous flow experiments for heterogeneous reaction on ice doped withHI at 200 K, at various concentrations of BrONO2; products thermally desorbed and identified by MS Allanic; Oppliger; Van Den Bergh; Rossi; Zeitschrift fur Physikalische Chemie; vol. 214; nb. 11; (2000); p. 1479 1500 ; (from Gmelin) View in Reaxys

ice doped with HBr

Rx-ID: 26413221 View in Reaxys 53/751 Yield

Conditions & References

88.5-92.0, 65.7 %

Kinetics, byproducts: HNO3; continous flow experiments for heterogeneous reaction on ice doped withHBr at 200 K, at various concentrations of ClONO2; products thermally desorbed and monitored by MS Allanic; Oppliger; Van Den Bergh; Rossi; Zeitschrift fur Physikalische Chemie; vol. 214; nb. 11; (2000); p. 1479 1500 ; (from Gmelin) View in Reaxys

94.3-104.7 , 80.7-81.0

Kinetics, byproducts: HNO3; continous flow experiments for heterogeneous reaction on ice doped withHBr at 180 K, at various concentrations of ClONO2; products thermally desorbed and monitored by MS Allanic; Oppliger; Van Den Bergh; Rossi; Zeitschrift fur Physikalische Chemie; vol. 214; nb. 11; (2000); p. 1479 1500 ; (from Gmelin) View in Reaxys

O+Z N Br

O–

Br Br

(v1)

Rx-ID: 27095949 View in Reaxys 54/751

36/201

2017-08-09 05:21:10

Yield

Conditions & References in gas, Kinetics, detected by IR Orlando, John J.; Burkholder, James B.; Journal of Physical Chemistry A; vol. 104; nb. 10; (2000); p. 2048 2053 ; (from Gmelin) View in Reaxys

Rx-ID: 26167290 View in Reaxys 55/751 Yield

Conditions & References With O in gaseous matrix, carrier gas He Bergeat; Calvo; Dorthe; Loison; Chemical Physics Letters; vol. 308; nb. 1-2; (1999); p. 7 - 12 ; (from Gmelin) View in Reaxys

Br2Pb

Rx-ID: 26172299 View in Reaxys 56/751 Yield

Conditions & References by distn. vol. Br: MVol.; 1.3, page 44 - 48 View in Reaxys Pfeiffer, E.; Handbuch der Kaliindustrie in: Bolley, P. A., Birnbaum, K., Handbuch der chemischen Technologie, F. Vieweg & Sohn, Braunschweig 1887, Bd. 2, Gruppe 1, Abt. 2, S. 328 ; (from Gmelin) View in Reaxys in neat (no solvent), Irradiation (UV/VIS); on exposure to light (sunlight for long time) Distanov; Drebushchak; Journal of Thermal Analysis and Calorimetry; vol. 57; nb. 2; (1999); p. 599 - 605 ; (from Gmelin) View in Reaxys in neat (no solvent), other Radiation; cathodic radiation under discoloration; Nagaoka, H.; Michima, T.; Sci. Papers Inst. Phys. Chem. Res. (Tokyo); vol. 28; (1935); p. 77 - 94 View in Reaxys vol. Pb: MVol.C2; 7, page 359 - 361 ; (from Gmelin) View in Reaxys

Br (v4)

Mo Br BrBr

(v3)

Rx-ID: 26518785 View in Reaxys 57/751 Yield

Conditions & References in neat (no solvent), N2 atmosphere; 200°C (1 h) Holmes, Michael; Sendlinger, Shawn C.; Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry; vol. 29; nb. 1; (1999); p. 143 - 153 ; (from Gmelin) View in Reaxys in neat (no solvent), melting of MoBr4; Blomstrand, C. W.; Journal fuer Praktische Chemie (Leipzig); vol. 82; (1861); p. 434 - 434 View in Reaxys vol. Mo: MVol.; 63, page 177 - 179 ; (from Gmelin) View in Reaxys

37/201

2017-08-09 05:21:10

(v4)

Br Si Si

N Si Ce TB-5 N Si

(v5)

Si N

(v5)

Si (v2)

(v4)

Ce TB-5 (v5)

N Si

(v4)

Rx-ID: 27276088 View in Reaxys 58/751 Yield

Conditions & References in not given Morton, Colin; Alcock, Nathaniel W.; Lees, Martin R.; Munslow, Ian J.; Sanders, Christopher J.; Scott, Peter; Journal of the American Chemical Society; vol. 121; nb. 48; (1999); p. 11255 - 11256 ; (from Gmelin) View in Reaxys

Br3MoN

Br2MoN

Rx-ID: 27468483 View in Reaxys 59/751 Yield

Conditions & References in neat (no solvent), heating (above 200°C, vac.) Holmes, Michael; Sendlinger, Shawn C.; Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry; vol. 29; nb. 1; (1999); p. 143 - 153 ; (from Gmelin) View in Reaxys

Rx-ID: 26349513 View in Reaxys 60/751 Yield

Conditions & References in neat (no solvent), on NaNO3(s) Mochida; Akimoto; Van Den Bergh; Rossi; Journal of Physical Chemistry A; vol. 102; nb. 25; (1998); p. 4819 4828 ; (from Gmelin) View in Reaxys

BrK

HKO

Rx-ID: 26349538 View in Reaxys 61/751 Yield

Conditions & References in neat (no solvent), Kinetics Mochida; Akimoto; Van Den Bergh; Rossi; Journal of Physical Chemistry A; vol. 102; nb. 25; (1998); p. 4819 4828 ; (from Gmelin) View in Reaxys

N O

(v1)

Rx-ID: 26385128 View in Reaxys 62/751 Yield

Conditions & References in neat (no solvent), Knudsen reactor, molecular flow; MS-monitored Caloz, Francois; Seisel, Sabine; Fenter, Frederick F.; Rossi, Michel J.; Journal of Physical Chemistry A; vol. 102; nb. 38; (1998); p. 7470 - 7479 ; (from Gmelin) View in Reaxys

38/201

2017-08-09 05:21:10

Br K+

BrK

–O

Rx-ID: 26385129 View in Reaxys 63/751 Yield

(v2)

Rx-ID: 26402872 View in Reaxys 64/751 Yield

Conditions & References in neat (no solvent), Kinetics, IR and UV monitored Broeske; Zabel; Journal of Physical Chemistry A; vol. 102; nb. 44; (1998); p. 8626 - 8631 ; (from Gmelin) View in Reaxys

Br2Pt

Rx-ID: 26068909 View in Reaxys 65/751 Yield

Conditions & References in neat (no solvent), heating over 400°C Pausch; Burggraf; Gruehn; Zeitschrift fur Anorganische und Allgemeine Chemie; vol. 623; nb. 11; (1997); p. 1835 1842 ; (from Gmelin) View in Reaxys H2O#dotNaCl#dotNaBr

Rx-ID: 26349546 View in Reaxys 66/751 Yield <1 %

Conditions & References Kinetics, HOBr/He mixt. passing over doped ice at 240 K sprayed onto flow tube wall; monitoring by TOF MS Kirchner; Benter, Th; Schindler; Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics; vol. 101; nb. 6; (1997); p. 975 - 977 ; (from Gmelin) View in Reaxys

Br Au Br Br

(v3)

Rx-ID: 26436275 View in Reaxys 67/751 Yield

Conditions & References decompn. in N2, between 90 and 140°C Manchot, W.; Lehmann, G.; Ber.; vol. 63; (1930); p. 1221 - 1224 ; (from Gmelin) View in Reaxys decompn. in CO betwwen 40 and 90°C Manchot, W.; Lehmann, G.; Ber.; vol. 63; (1930); p. 1221 - 1224 ; (from Gmelin) View in Reaxys decompn. in N2, between 90 and 140°C vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin) View in Reaxys decompn. in CO betwwen 40 and 90°C vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin)

39/201

2017-08-09 05:21:10

View in Reaxys in neat (no solvent), temperature higher than room temp. Beck; Wagner; Zeitschrift fur Anorganische und Allgemeine Chemie; vol. 623; nb. 11; (1997); p. 1810 - 1814 ; (from Gmelin) View in Reaxys F

F –Br (v2)

F Br– SP-4 (v4) F

N+

Rx-ID: 27710309 View in Reaxys 68/751 Yield

Conditions & References in neat (no solvent), absence of moisture; room temp. Minkwitz, Rolf; Broechler, Raimund; Ludwig, Ralf; Inorganic Chemistry; vol. 36; nb. 19; (1997); p. 4280 - 4283 ; (from Gmelin) View in Reaxys

(v2)

Rx-ID: 26348875 View in Reaxys 69/751 Yield

Conditions & References in gaseous matrix, Kinetics, Irradiation (UV/VIS); in SF6 at 220 K Mauldin, R. L.; Wahner, A.; Ravishankara, A. R.; Journal of Physical Chemistry; vol. 97; nb. 29; (1993); p. 7585 7596 ; (from Gmelin) View in Reaxys in gaseous matrix, Kinetics, Irradiation (UV/VIS); 193-373 K, UV-VIS monitoring Rowley, David M.; Harwood, Matthew H.; Freshwater, Raymond A.; Jones, Roderic L.; Journal of Physical Chemistry; vol. 100; nb. 8; (1996); p. 3020 - 3029 ; (from Gmelin) View in Reaxys in gaseous matrix, Kinetics, Irradiation (UV/VIS); in N2 at 220 K Mauldin, R. L.; Wahner, A.; Ravishankara, A. R.; Journal of Physical Chemistry; vol. 97; nb. 29; (1993); p. 7585 7596 ; (from Gmelin) View in Reaxys in gaseous matrix, Kinetics, Irradiation (UV/VIS); in helium at 298 K or 220 K Mauldin, R. L.; Wahner, A.; Ravishankara, A. R.; Journal of Physical Chemistry; vol. 97; nb. 29; (1993); p. 7585 7596 ; (from Gmelin) View in Reaxys

BrNa

Rx-ID: 26097618 View in Reaxys 70/751 Yield

Conditions & References With methyltrioxorhenium (VII) in water-d2, Kinetics, byproducts: H2O; not isolated, reaction followed by UV/VIS spectroscopy Pestovsky, Oleg; Eldik, Rudi van; Huston, Patrick; Espenson, James H.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); nb. 1; (1995); p. 133 - 138 ; (from Gmelin) View in Reaxys With methyltrioxorhenium (VII) in perchloric acid, Kinetics, byproducts: H2O; 1-45°C, 5-150 MPa, 2 M NaClO4; not isolated, reaction followed by UV/VIS spectroscopy Pestovsky, Oleg; Eldik, Rudi van; Huston, Patrick; Espenson, James H.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); nb. 1; (1995); p. 133 - 138 ; (from Gmelin)

40/201

2017-08-09 05:21:10

View in Reaxys in not given Maass; Hatcher; Journal of the American Chemical Society; vol. 44; (1922); p. 2472 View in Reaxys vol. O: MVol.7; 18, page 2196 - 2198 ; (from Gmelin) View in Reaxys Cl

N H

Br( 1-)

Br Br

Rx-ID: 26349535 View in Reaxys 71/751 Yield

Conditions & References in water, Kinetics, mixing NHCl2 with HBrO, then mixing with Br(1-) (after 3 s, pH = 5.6 - 6.2, phosphate buffer); extn. (Et2O), UV/VIS monitoring of both aq. and Et2O fractions Gazda, Michael; Kumar, Krishan; Margerum, Dale W.; Inorganic Chemistry; vol. 34; (1995); p. 3536 - 3542 ; (from Gmelin) View in Reaxys

N H

Br( 1-)

Rx-ID: 26384361 View in Reaxys 72/751 Yield

Conditions & References in water, Kinetics, pH = 5.6 +/- 0.1 (phosphate buffer); UV/VIS monitoring Gazda, Michael; Kumar, Krishan; Margerum, Dale W.; Inorganic Chemistry; vol. 34; (1995); p. 3536 - 3542 ; (from Gmelin) View in Reaxys

Cl Br( 1-)

Cl( 1-)

Rx-ID: 26414421 View in Reaxys 73/751 Yield

Conditions & References in water, Kinetics, pH = 3.2 - 6.5; UV/VIS monitoring Gazda, Michael; Kumar, Krishan; Margerum, Dale W.; Inorganic Chemistry; vol. 34; (1995); p. 3536 - 3542 ; (from Gmelin) View in Reaxys 1

Br( 1-)

Cl( 1-)

(v4)

N HH

Rx-ID: 26414422 View in Reaxys 74/751 Yield

Conditions & References With hydrogen cation in water, pH = 0 - 3; UV/VIS monitoring Gazda, Michael; Kumar, Krishan; Margerum, Dale W.; Inorganic Chemistry; vol. 34; (1995); p. 3536 - 3542 ; (from Gmelin) View in Reaxys

Cr Br

Br (v3)

(v2)

Br Cr Br

(v4)

Cr BrBr

Br4Cr 2

Rx-ID: 26518264 View in Reaxys 75/751 Yield

Conditions & References in neat (no solvent), evapn. of CrBr3 from silica holder at 500-600°C; deposition in Ar- or N2-matrix; product mixt. not sepd., detd. by IR spectroscopy; product ratio depending on temp., pressure and time of evapn.

41/201

2017-08-09 05:21:10

Gregory, Paul D.; Ogden, J. Steven; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); nb. 9; (1995); p. 1423 - 1426 ; (from Gmelin) View in Reaxys H

Br( 1-)

Rx-ID: 26109313 View in Reaxys 76/751 Yield

Conditions & References With methyltrioxorhenium (VII) in water, Kinetics, monitored by UV-visible spectrophotometry Espenson; Pestovsky; Huston; Staudt; Journal of the American Chemical Society; vol. 116; nb. 7; (1994); p. 2869 - 2877 ; (from Gmelin) View in Reaxys O

Rx-ID: 1646493 View in Reaxys 77/751 Yield

Conditions & References With hydrogen bromide, Equilibrium constant Lind, Johan; Jonsson, Mats; Eriksen, Trygve E.; Merenyi, Gabor; Eberson, Lennart; Journal of Physical Chemistry; vol. 97; nb. 8; (1993); p. 1610 - 1614 View in Reaxys AgBr#dotCdBr2

Rx-ID: 26171672 View in Reaxys 78/751 Yield

Conditions & References in neat (no solvent), Electrochem. Process; production of halogen molecules by applying a voltage to solid-state cell (AgBr#dotCdBr2 / Pt, 6 or 60 μA) Patrin, J. C.; Weaver, J. H.; Physical Review B: Condensed Matter and Materials Physics; vol. 48; (1993); p. 17913 - 17921 ; (from Gmelin) View in Reaxys

-1

Br Bi– Br BrBr

N+

Br Br

(v2)

Rx-ID: 26638836 View in Reaxys 79/751 Yield

Conditions & References in acetonitrile, Irradiation (UV/VIS); photolysis (Ar satd. MeCN soln., Xe/Hg 1000 W lamp, room temp.); not isolated; UV/VIS monitoring Oldenburg, Karin; Vogler, Arnd; Zeitschrift fuer Naturforschung, B: Chemical Sciences; vol. 48; nb. 11; (1993); p. 1519 - 1523 ; (from Gmelin) View in Reaxys

Rx-ID: 26179659 View in Reaxys 80/751 Yield

Conditions & References fast flow reactor; at 200 K; in presence of ice or cold glas; mass spectrometry Hanson, David R.; Ravishankara, A. R.; Journal of Physical Chemistry; vol. 96; nb. 23; (1992); p. 9441 - 9446 ; (from Gmelin) View in Reaxys

42/201

2017-08-09 05:21:10

O S–

H( 1+)

O–

–O

S OO

Rx-ID: 26355431 View in Reaxys 81/751 Yield

Conditions & References in perchloric acid, Kinetics, excess of BrO3(1-); detected by UV Zhang, Yi-Xue; Field, Richard J.; Journal of Physical Chemistry; vol. 96; nb. 3; (1992); p. 1224 - 1228 ; (from Gmelin) View in Reaxys

BrNa

Rx-ID: 26069504 View in Reaxys 82/751 Yield

Conditions & References in neat (no solvent), byproducts: NaCl; flowing a mixture of BrCl/He trough a cell packed with NaBr at 298 K Berko, H. N.; McCaslin, P. C.; Finlayson-Pitts, B. J.; Journal of Physical Chemistry; vol. 95; nb. 18; (1991); p. 6951 - 6958 ; (from Gmelin) View in Reaxys

BrNa

Br Cl

Rx-ID: 26097623 View in Reaxys 83/751 Yield

Conditions & References in neat (no solvent), byproducts: NaCl; flowing a mixture of Cl2/He trough a cell packed with NaBr at 298 K Berko, H. N.; McCaslin, P. C.; Finlayson-Pitts, B. J.; Journal of Physical Chemistry; vol. 95; nb. 18; (1991); p. 6951 - 6958 ; (from Gmelin) View in Reaxys

BrNa

Rx-ID: 26395573 View in Reaxys 84/751 Yield

Conditions & References in neat (no solvent), byproducts: NaNO3, NaCl; flowing a mixture of ClONO2/He trough a cell packed with NaBr at 298 K; monitored by MAS Berko, H. N.; McCaslin, P. C.; Finlayson-Pitts, B. J.; Journal of Physical Chemistry; vol. 95; nb. 18; (1991); p. 6951 - 6958 ; (from Gmelin) View in Reaxys

N+

CTc

Br14Tc 6( 2-)

Rx-ID: 26419316 View in Reaxys 85/751 Yield

Conditions & References thermolysis of starting material at 260-390°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

H O

Br13Tc 8

Rx-ID: 26420936 View in Reaxys 86/751

43/201

2017-08-09 05:21:10

Yield

Conditions & References thermolysis of starting material at 300-600°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys -1

(v4)

Cl SP-4 Br– Cl

BrK

Br Cl

-1 Cl

(v2)

Rx-ID: 26675968 View in Reaxys 87/751 Yield

Conditions & References With sodium chloride in water, mixing solns. of similar concentration; monitored by UV Kazantseva, N. N.; Ozerova, T. I.; Khodzhamamedov, A.; Fedorova, L. V.; Ksenzenko, V. I.; Doklady Chemistry (English Translation); vol. 317; (1991); p. 63 - 65; Doklady Akademii Nauk SSSR; vol. 317; (1991); p. 375 - 378 ; (from Gmelin) View in Reaxys Cl

(v4)

Cl SP-4 Br– Cl

BrK

Rx-ID: 26675969 View in Reaxys 88/751 Yield

Conditions & References in water, mixing solns. of similar concentration; monitored by UV Kazantseva, N. N.; Ozerova, T. I.; Khodzhamamedov, A.; Fedorova, L. V.; Ksenzenko, V. I.; Doklady Chemistry (English Translation); vol. 317; (1991); p. 63 - 65; Doklady Akademii Nauk SSSR; vol. 317; (1991); p. 375 - 378 ; (from Gmelin) View in Reaxys

(v5)

Tc O O(v3) (v3) OO (v3) O(v3) O O Tc O

(v6)

Rx-ID: 26739980 View in Reaxys 89/751 Yield

Conditions & References thermolysis of starting material at 400-460°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

(v3)

H+

O H (v3) H

(v2)

Br14Tc 8( 1-)

Rx-ID: 26740113 View in Reaxys 90/751 Yield

Conditions & References thermolysis of starting material at 620-820°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

44/201

2017-08-09 05:21:10

(v3)

H+

(v2)

H (v3) H

Br13Tc 8( 1-)

Rx-ID: 26740391 View in Reaxys 91/751 Yield

Conditions & References thermolysis of starting material at 400-600°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

N+

CTc

Br11Tc 6( 2-)

Rx-ID: 26741107 View in Reaxys 92/751 Yield

Conditions & References thermolysis of starting material at 250-400°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

N+

CTc

Br14Tc 6( 2-)

Rx-ID: 26741227 View in Reaxys 93/751 Yield

Conditions & References thermolysis of starting material at 270-390°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

Br BrBr Br Tc (v5) Tc 3Br BrBr BrH H

H O

Br (v5)

Br–

NH +4

2Br TcBr Br Br (v6)

NH +4

N+ HH

Rx-ID: 26741311 View in Reaxys 94/751 Yield

Conditions & References thermolysis at 260-430°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

45/201

2017-08-09 05:21:10

Br BrBr Br Tc (v5) Tc 3Br BrBr BrH H

(v5)

Br–

NH +4

NTc

N+ HH

Rx-ID: 26741312 View in Reaxys 95/751 Yield

Conditions & References thermolysis of starting material at 430-470°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

(v2)

H+ H O 2 H O H H H H (v3) H O

(v3) (v2)

(v3)

Br11Tc 6( 2-)

Rx-ID: 26741680 View in Reaxys 96/751 Yield

Conditions & References thermolysis of starting material at 550-800°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

(v2)

H+ H O 2 H O H H H (v3) H O

H O

(v3)

(v2)

(v3)

Br11Tc 6( 2-)

Rx-ID: 26741761 View in Reaxys 97/751 Yield

Conditions & References thermolysis of starting material at 540-800°C Kryuchkov, S. V.; German, K. E.; Simonov, A. E.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 255 261; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 480 - 487 ; (from Gmelin) View in Reaxys

(v2)

(v4)

Rx-ID: 26348879 View in Reaxys 98/751 Yield

Conditions & References Kinetics Turnipseed, Andrew A.; Birks, John W.; Calvert, Jack G.; Journal of Physical Chemistry; vol. 94; nb. l; (1990); p. 7477 - 7482 ; (from Gmelin) View in Reaxys

Br( 1-)

Rx-ID: 26063508 View in Reaxys 99/751 Yield

Conditions & References With malonic acid, hydrogen cation in sulfuric acid, byproducts: H2O, Ce(III), bromomalonic acid; Belousov-Zhabotinskii reaction; spectrophotometry at 500 nm Kovalenko, A. S.; Tikhonova, L. P.; Theoretical and Experimental Chemistry; vol. 19; (1983); p. 94 - 97; Teoreticheskaya i Eksperimental'naya Khimiya; vol. 19; (1983); p. 108 - 112 ; (from Gmelin) View in Reaxys

46/201

2017-08-09 05:21:10

in sulfuric acid, Kinetics, byproducts: H2O; equil. react., at 22°C; detected by titration with Ag(1+), spectoscopical determination Foersterling, Horst-Dieter; Muranyi, Szilvia; Schreiber, Helmut; Zeitschrift fuer Naturforschung, Teil A: Physik, Physikalische Chemie, Kosmophysik; vol. 44; (1989); p. 555 - 566 ; (from Gmelin) View in Reaxys With hydrogen cation, Kinetics, byproducts: H2O Alamgir, Mohamed; Orban, Miklos; Epstein, Irving R.; Journal of Physical Chemistry; vol. 87; nb. 19; (1983); p. 3725 - 3728 ; (from Gmelin) View in Reaxys O Br

Br( 1-)

Rx-ID: 26063509 View in Reaxys 100/751 Yield

Conditions & References in sulfuric acid, Kinetics, equil. react., at 20 and 25°C; spectroscopic determination Foersterling, Horst-Dieter; Muranyi, Szilvia; Schreiber, Helmut; Zeitschrift fuer Naturforschung, Teil A: Physik, Physikalische Chemie, Kosmophysik; vol. 44; (1989); p. 555 - 566 ; (from Gmelin) View in Reaxys

SiH

Rx-ID: 26107037 View in Reaxys 101/751 Yield

Conditions & References in neat (no solvent), radiolysis of deoxygenated Et3SiH; various concentrations of EtBr; further unidentified oligomers; GC/MS Lugovoi, Yu. M.; Getoff, N.; Zeitschrift fuer Naturforschung, B: Chemical Sciences; vol. 44; nb. 11; (1989); p. 1373 1376 ; (from Gmelin) View in Reaxys

O Br

Br( 1-)

H( 1+)

Rx-ID: 26109288 View in Reaxys 102/751 Yield

Conditions & References in sulfuric acid, Kinetics, equil. react., at 20°C; spectroscopic determination Foersterling, Horst-Dieter; Muranyi, Szilvia; Schreiber, Helmut; Zeitschrift fuer Naturforschung, Teil A: Physik, Physikalische Chemie, Kosmophysik; vol. 44; (1989); p. 555 - 566 ; (from Gmelin) View in Reaxys

Br (v4)

Mo BrBr

Rx-ID: 26518786 View in Reaxys 103/751 Yield

Conditions & References heating (vac., 90-700°C); TG, mass spectrometry Ryabov, S. A.; Alikhanyan, A. S.; Butskii, V. D.; Pervov, V. S.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 34; (1989); p. 570 - 573; Zhurnal Neorganicheskoi Khimii; vol. 34; (1989); p. 1017 - 1020 ; (from Gmelin) View in Reaxys

47/201

2017-08-09 05:21:10

-1 N

(v4)

-1

H (v4)(v4)

(v4) (v4)

(v4)

Mn2+

BrNa

Mn3+ (v4)

(v4)

Rx-ID: 26281963 View in Reaxys 104/751 Yield

Conditions & References With perchloric acid, sodium perchlorate in perchloric acid, Kinetics, 5 - 40°C; Heyward, Malcolm P.; Wells, Cecil F.; Inorganica Chimica Acta; vol. 148; (1988); p. 241 - 246 ; (from Gmelin) View in Reaxys

O–

Na +

BrNa

Rx-ID: 26357062 View in Reaxys 105/751 Yield

Conditions & References in sodium hydroxide, sulfuric acid, Kinetics, At room temp. solns. of NaBrO2 in aq. NaOH and of NaBr in aq. H2SO4 are subsequently injected into a soln. containing aq. H2SO4.; The formation of Br2 is detected by its absorbance at 401 nm using the dual wavelength technique. Foersterling, H. D.; Schreiber, H.; Zeitschrift fuer Naturforschung, Teil A: Physik, Physikalische Chemie, Kosmophysik; vol. 43; (1988); p. 956 - 960 ; (from Gmelin) View in Reaxys

O–

O Ag+

Na +

O–

BrNa

AgBr

Rx-ID: 26357063 View in Reaxys 106/751 Yield

Conditions & References in sodium hydroxide, sulfuric acid, Kinetics, At room temp. solns. of NaBrO2 in aq. NaOH and of NaBr in aq. H2SO4 are subsequently injected into a soln. containing AgNO3 (in aq. H2SO4) at different initial concentrations.; The formation of Br2 is detected by its absorbance at 401 nm using the dual wavelength technique. Foersterling, H. D.; Schreiber, H.; Zeitschrift fuer Naturforschung, Teil A: Physik, Physikalische Chemie, Kosmophysik; vol. 43; (1988); p. 956 - 960 ; (from Gmelin) View in Reaxys

Br As + Br BrBr

– F As F F F

Rx-ID: 26538481 View in Reaxys 107/751 Yield

Conditions & References slow decompn. at -78°C, rapid at room temp. Klapoetke, Thomas; Passmore, Jack; Awere, Edward G.; Journal of the Chemical Society, Chemical Communications; nb. 21; (1988); p. 1426 - 1427 ; (from Gmelin) View in Reaxys Br

Br Al– Br BrBr

As + BrBr

Br Al

Br Br

Rx-ID: 26539913 View in Reaxys 108/751 Yield

Conditions & References equilibrium at room temp. Klapoetke, Thomas; Passmore, Jack; Awere, Edward G.; Journal of the Chemical Society, Chemical Communications; nb. 21; (1988); p. 1426 - 1427 ; (from Gmelin) View in Reaxys

48/201

2017-08-09 05:21:10

OSr

Br2Sr

Rx-ID: 26540345 View in Reaxys 109/751 Yield

Conditions & References With oxygen, reaction of SrBr2 with traces of oxygen during melting Winkler, A.; Hoebbel, D.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 562; (1988); p. 170 - 174 ; (from Gmelin) View in Reaxys

S S S S S S

Rx-ID: 26168211 View in Reaxys 110/751 Yield

Conditions & References With aluminium, (N2), bomb reed, refluxed at 160°C for 10 min; cooled in liquid air in vac., distd. Schmidt, M.; Froehlich, B.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 553; (1987); p. 239 - 247 ; (from Gmelin) View in Reaxys

S S S S S S

Rx-ID: 26170447 View in Reaxys 111/751 Yield

Conditions & References

>99

(N2), bomb reed, heated at 245°C for 66 h; cooled in liquid air in vac., distd. Schmidt, M.; Froehlich, B.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 553; (1987); p. 239 - 247 ; (from Gmelin) View in Reaxys

S–

O–

–C

O–

–O

S OO

Rx-ID: 26355405 View in Reaxys 112/751 Yield

Conditions & References With perchloric acid in water, Kinetics, oscillatory reaction; flow experiments (continously stirred tank reactor or batch react., 25+/-0.1°C, excess of BrO3(1-);; not isolated, followed by redox potential or absorption measurements; Simoyi, Reuben H.; Journal of Physical Chemistry; vol. 91; nb. 6; (1987); p. 1557 - 1561 ; (from Gmelin) View in Reaxys Br -1Br

Br( 1-)

Rx-ID: 26369122 View in Reaxys 113/751 Yield

Rx-ID: 26405540 View in Reaxys 114/751 Yield

Conditions & References in neat (no solvent), byproducts: N2O5, NO2, O2; at ambient temp. Wilson, William W.; Christe, Karl O.; Inorganic Chemistry; vol. 26; (1987); p. 1573 - 1580 ; (from Gmelin) View in Reaxys

49/201

2017-08-09 05:21:10

Br( 1-)

O–

Cl( 1-)

Rx-ID: 26414482 View in Reaxys 115/751 Yield

Conditions & References in water, Kinetics, byproducts: OH(1-); basic soln.; pseudo first-order conditions (Br(1-) in large excess) Kumar, Krishan; Margerum, Dale W.; Inorganic Chemistry; vol. 26; (1987); p. 2706 - 2711 ; (from Gmelin) View in Reaxys

Br( 1-)

Cl( 1-)

Rx-ID: 26414490 View in Reaxys 116/751 Yield

Conditions & References in water, Kinetics, byproducts: H2O; pseudo first-order conditions (Br(1-) in large excess) Kumar, Krishan; Margerum, Dale W.; Inorganic Chemistry; vol. 26; (1987); p. 2706 - 2711 ; (from Gmelin) View in Reaxys

Rx-ID: 26431263 View in Reaxys 117/751 Yield

Conditions & References in neat (no solvent), Kinetics, Irradiation (UV/VIS); dissocn. of IBr by a pulsed dye laser, pumped by a XeCl excimer laser, dissocn. of Br2 in a furnace at 1100K; double resonance cell; apparatus described; Haugen, Harold K.; Weitz, Eric; Leone, Stephen R.; Chemical Physics Letters; vol. 119; (1985); p. 75 - 80 ; (from Gmelin) View in Reaxys in gas, Irradiation (UV/VIS); Laser irradiation Gordon, E. B.; Boriev, I. A.; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy; vol. 43; (1987); p. 281 - 284 ; (from Gmelin) View in Reaxys

O –O

O–

Na +

HS( 1-)

–O

S OO

Rx-ID: 26448214 View in Reaxys 118/751 Yield

Conditions & References With hydrogen cation in perchloric acid, Kinetics, byproducts: H2O; react. of excess bromate with sulfide in aq. HClO4 (ionic strength: 0.2 M (NaClO4)) at 22°C, Br2 appeared after induction period; SO4(2-) detected with Ba(2+) Simoyi, Reuben H.; Noyes, Richard M.; Journal of Physical Chemistry; vol. 91; nb. 11; (1987); p. 2689 - 2690 ; (from Gmelin) View in Reaxys

Br( 1-)

O Cl

(v1)

Cl( 1-)

Rx-ID: 26380721 View in Reaxys 119/751 Yield

Conditions & References in water, Kinetics, byproducts: H2O; 25.+-.0.5°C; excess of HClO2; pH = 1.00 - 3.00 adjusted with chloroacetic acid, sodium sulfate and sodium bisulfate, pH < 1.00 adjusted with HClO4; ionic strength 1.2 M (NaClO4); monitored by spectrophotometry Valdes-Aguilera, Oscar; Boyd, Donald W.; Epstein, Irving R.; Kustin, Kenneth; Journal of Physical Chemistry; vol. 90; nb. 25; (1986); p. 6702 - 6708 ; (from Gmelin) View in Reaxys

50/201

2017-08-09 05:21:10

–

Br( 1-)

Co 3+

Br Br

Co( 2+)

Rx-ID: 26414432 View in Reaxys 120/751 Yield

Conditions & References in acetic acid, Kinetics, kinetic investigation of reduction of Co(III)-acetate by bromide in thepresence of p-xylene and pyridine at 60-93°C under N2; discussion of react. mechanism; Schlosserova, Julia; Hronec, Milan; Vesely, Vaclav; Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases; vol. 82; (1986); p. 1405 - 1412 ; (from Gmelin) View in Reaxys O

I(1-)

H( 1+)

O–

Rx-ID: 26414672 View in Reaxys 121/751 Yield

Conditions & References in water, Kinetics, initial concns. were 5E-3 M BrO3(1-), 2.5E-3 M I(1-), and 1.5 M H(1+); studied by UV and potentiometry Citri, Ofra; Epstein, Irving R.; Journal of the American Chemical Society; vol. 108; nb. 3; (1986); p. 357 - 363 ; (from Gmelin) View in Reaxys Br

BrLi

Rx-ID: 26097437 View in Reaxys 122/751 Yield

Conditions & References

70 %

With {Py3Co3O(OAc)5OH}PF6 or {Py3Co3O(OAc)6}PF6 in chlorobenzene, refluxing Sumner, Charles E.; Steinmetz, Guy R.; Journal of the American Chemical Society; vol. 107; (1985); p. 6124 6126 ; (from Gmelin) View in Reaxys

Br( 1-)

O–

Cl( 1-)

Rx-ID: 26380586 View in Reaxys 123/751 Yield

Conditions & References With hydrogen cation in perchloric acid, nitric acid, Kinetics, byproducts: H2O; kinetic investigation of the autocatalytic react. at 25°C, pH 0.4-2.5, investigation of influemce of chlorite- and bromide-concn., discussion of mechanism;; not isolated, monitoring of react. by UV (390nm, production of Br2) andpotentiometric measurements; Simoyi, Reuben H.; Journal of Physical Chemistry; vol. 89; nb. 16; (1985); p. 3570 - 3574 ; (from Gmelin) View in Reaxys -1

Br AuBr2( 1-)

(v4)

Au BrBr

Rx-ID: 26535735 View in Reaxys 124/751 Yield

Conditions & References With [131I]-Uracil in water-d2, Kinetics, byproducts: 5-bromo-6-hydroxy-5,6-dihydrouracil, 5-bromouracil; reaction of starting materials in D2O at room temp.; monitored by UV- and (1)H-NMR-spectroscopy Ettorre, Renato; Martelli, Mario; Inorganica Chimica Acta; vol. 108; (1985); p. 73 - 76 ; (from Gmelin) View in Reaxys Br

Au–

(v4)

Au– (v2)

Rx-ID: 26640462 View in Reaxys 125/751

51/201

2017-08-09 05:21:10

Yield

Conditions & References With [131I]-Uracil in water-d2, Kinetics, byproducts: 5-bromouracil; reaction of starting materials in D2O at room temp.; monitored by UV- and (1)H-NMR-spectroscopy Ettorre, Renato; Martelli, Mario; Inorganica Chimica Acta; vol. 108; (1985); p. 73 - 76 ; (from Gmelin) View in Reaxys

K+

–O

O O– S

O S

Rx-ID: 26466849 View in Reaxys 126/751 Yield

Conditions & References With potassium bromide in melt, byproducts: SO4(2-); in the melt at temp. starting from 354°C;; detected by Raman spectroscopy and DTA-expt. Mineely, Patrick J.; Tariq, Shabbir A.; Australian Journal of Chemistry; vol. 37; (1984); p. 191 - 196 ; (from Gmelin) View in Reaxys With CsBr in melt, byproducts: SO4(2-); in the melt at temp. starting from 340°C;; detected by Raman spectroscopy and DTA-expt.; Mineely, Patrick J.; Tariq, Shabbir A.; Australian Journal of Chemistry; vol. 37; (1984); p. 191 - 196 ; (from Gmelin) View in Reaxys With sodium bromide in melt, byproducts: SO4(2-); in the melt at temp. starting from 370°C;; detected by Raman spectroscopy and DTA-expt. Mineely, Patrick J.; Tariq, Shabbir A.; Australian Journal of Chemistry; vol. 37; (1984); p. 191 - 196 ; (from Gmelin) View in Reaxys With rubidium bromide in melt, byproducts: SO4(2-); in the melt at temp. starting from 352°C;; detected by Raman spectroscopy and DTA-expt.; Mineely, Patrick J.; Tariq, Shabbir A.; Australian Journal of Chemistry; vol. 37; (1984); p. 191 - 196 ; (from Gmelin) View in Reaxys O Br

Br( 1-)

O–

Br Br

Rx-ID: 26414426 View in Reaxys 127/751 Yield

Conditions & References With hydrogen cation, Ce(3+), Kinetics, byproducts: H2O, Ce(4+); oscillation reactions Bar-Eli, K.; Geiseler, W.; Journal of Physical Chemistry; vol. 87; nb. 19; (1983); p. 3769 - 3774 ; (from Gmelin) View in Reaxys in the presence of CH3COOH and CH3COONa; somedays Ditz, H.; Margosches, B. M.; Angewandte Chemie; vol. 14; (1901); p. 1089 ; (from Gmelin) View in Reaxys With sulfuric acid, Ce(3+) in not given, at 25°C Orban, Miklos; De Kepper, Patrick; Epstein, Irving R.; Journal of the American Chemical Society; vol. 104; (1982); p. 2657 - 2658 ; (from Gmelin) View in Reaxys With sulfuric acid, manganese cation in not given, at 25°C Orban, Miklos; De Kepper, Patrick; Epstein, Irving R.; Journal of the American Chemical Society; vol. 104; (1982); p. 2657 - 2658 ; (from Gmelin) View in Reaxys in the presence of CH3COOH and CH3COONa; somedays

52/201

2017-08-09 05:21:10

vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin) View in Reaxys K+

Br O

O–

Rx-ID: 26420218 View in Reaxys 128/751 Yield

Conditions & References With hydrogen cation in water, Kinetics, byproducts: water; pH 1-10 (adjusted with H2SO4); GC-MS Duonghong, Dung; Erbs, Wilson; Shuben, Li; Graetzel, Michael; Chemical Physics Letters; vol. 95; (1983); p. 266 - 268 ; (from Gmelin) View in Reaxys With sulfuric acid, byproducts: K2SO4; concd. H2SO4 Loewig, C.; Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, p. 93 ; (from Gmelin) View in Reaxys With nitric acid, byproducts: KNO3; heating Penny, F.; Journal fuer Praktische Chemie (Leipzig); vol. 23; (1841); p. 298 ; (from Gmelin) View in Reaxys With H2SO4 vol. K: MVol.3; 1.6.2, page 580 - 581 ; (from Gmelin) View in Reaxys With HNO3 vol. K: MVol.3; 1.6.2, page 580 - 581 ; (from Gmelin) View in Reaxys

O –O

(v1)

Na +

Br -1 O

(v1)

-1

(v2)

Rx-ID: 26448187 View in Reaxys 129/751 Yield

Conditions & References other Radiation; X-ray irradiation Kishan Rao; Sirdeshmukh; Physica Status Solidi (A) Applied Research; vol. 80; nb. 2; (1983); p. k117-k119 ; (from Gmelin) View in Reaxys

N (v1) –Br (v4)

(v4) (v4)

H N Co23+N H 2N OC-6 (v6) H2 NH 2(v4)

Br( 1-)

(v4)

racemate

Rx-ID: 27067071 View in Reaxys 130/751 Yield

Conditions & References in perchloric acid, 0.1 M HClO4, xenon lamp (315 nm, 300 W); not isolated, reaction followed by UV/VIS spectroscopy Arunachalam, S.; Natarajan, P.; Journal of the Chemical Society, Chemical Communications; nb. 8; (1983); p. 472 473 ; (from Gmelin) View in Reaxys

53/201

2017-08-09 05:21:10

Pb Br

Rx-ID: 26183153 View in Reaxys 131/751 Yield

Conditions & References Irradiation (UV/VIS); 20°C; 525, 475, 350, and 300 nm Chang, S. G.; Dod, R.; Glauque, R.; Novakov, T.; Journal of Physical Chemistry; vol. 86; nb. 11; (1982); p. 1956 1959 ; (from Gmelin) View in Reaxys

Br Br

Rx-ID: 26182392 View in Reaxys 132/751 Yield

Conditions & References in gas, Kinetics, Irradiation (UV/VIS); Cl2 photodissociation by highly defocused UV laser pulses (frequency doubled tunable dye laser, 2 μs/pulse, 1 mJ, 300 nm, or frequency tripled Q-switched Nd:YAG laser, 5 ns/pulse, 1-40 mJ, 355 nm); monitoring by HCl infrared chemiluminiscence detection Nesbitt, David J.; Leone, Stephen R.; Journal of Chemical Physics; vol. 75; nb. 10; (1981); p. 4949 - 4959 ; (from Gmelin) View in Reaxys

F Br

(v3)

Rx-ID: 26349701 View in Reaxys 133/751 Yield

Conditions & References in neat (no solvent), Kinetics, (N2), 20°C Mit'kin, V. N.; Zemskov, S. V.; Journal of Applied Chemistry USSR (English Translation); vol. 54; (1981); p. 1913 1918; Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation); vol. 54; (1981); p. 2180 - 2186 ; (from Gmelin) View in Reaxys

AgF

Rx-ID: 26349705 View in Reaxys 134/751 Yield

Br( 1-)

H( 1+)

O–

I(1-)

Rx-ID: 26414403 View in Reaxys 135/751 Yield

Conditions & References With sulfuric acid in water, Kinetics, iopnic strength 2.0, 23+/-0.1°C; spectrophotometric (ca. 400 nm) monitoring Zaidi, S. A.; Journal of General Chemistry USSR (English Translation); vol. 51; (1981); p. 1665 - 1668; Zhurnal Obshchei Khimii; vol. 51; (1981); p. 1936 - 1940 ; (from Gmelin) View in Reaxys With sulfuric acid in ethanol, water, Kinetics, iopnic strength 2.0, 23+/-0.1°C; spectrophotometric (ca. 400 nm) monitoring Zaidi, S. A.; Journal of General Chemistry USSR (English Translation); vol. 51; (1981); p. 1665 - 1668; Zhurnal Obshchei Khimii; vol. 51; (1981); p. 1936 - 1940 ; (from Gmelin) View in Reaxys

54/201

2017-08-09 05:21:10

Br( 1-)

Rx-ID: 26109310 View in Reaxys 136/751 Yield

Conditions & References With anatase O2Ti in water, Irradiation (UV/VIS); bubbled with oxygen in acidic or basic water; in the absence of TiO2 orof UV light no oxidation occured Herrmann, Jean-Marie; Pichat, Pierre; Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases; vol. 76; (1980); p. 1138 - 1146 ; (from Gmelin) View in Reaxys

O S

O F

F O

O S

O F

S O

O S

Rx-ID: 26753285 View in Reaxys 137/751 Yield 0%

OH HO

S OO

Conditions & References Katsuhara, Y.; Hammaker, R. M.; DesMarteau, D. D.; Inorganic Chemistry; vol. 19; (1980); p. 607 - 615 View in Reaxys vol. F: PerFHalOrg.SVol.3; 6.2.3.1, page 48 - 120 ; (from Gmelin) View in Reaxys Br

O S

P Br

Rx-ID: 26410800 View in Reaxys 138/751 Yield

Conditions & References in further solvent(s), byproducts: bromophosphonium oligomers; dry N2-atmosphere; in 65percent oleum, 1 month; (31)P-NMR detection of byproducts Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1978); p. 1455 - 1460 ; (from Gmelin) View in Reaxys

OH HO

S OO

H O

Br O

P Br Br

H O

P+ O OH H

P+ BrBr

Rx-ID: 26467232 View in Reaxys 139/751 Yield

Conditions & References in sulfuric acid, dry N2-atmosphere; 8 months; product mixt. not isolated, detd. by (31)P-NMR spectroscopy Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1978); p. 1455 - 1460 ; (from Gmelin) View in Reaxys

OH HO

S OO

H O

Br Br PBr Br Br

H O

P+ O OH H

OH Br

P+ BrBr

Rx-ID: 26467251 View in Reaxys 140/751 Yield

Conditions & References in sulfuric acid, dry N2-atmosphere; 4 months; product mixt. not sepd., detd. by (31)P-NMR spectroscopy Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1978); p. 1455 - 1460 ; (from Gmelin) View in Reaxys

55/201

2017-08-09 05:21:10

OH S

O O

Br PBr Br

(v1)

Br– –

(v4)

F (v1)

P5+– – BrBr

(v1) (v1)

Rx-ID: 26485004 View in Reaxys 141/751 Yield

Conditions & References in epoxysulfonyl fluoride, dry N2-atmosphere; 9 days; product mixt. not sepd., detd. by (31)P-NMR spectroscopy Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1978); p. 1455 - 1460 ; (from Gmelin) View in Reaxys

S OO

(v1)

Br–

P Br

(v3)

P2+ OH

(v3)

(v7)

P+ BrBr

(v3)

Rx-ID: 26566590 View in Reaxys 142/751 Yield

Conditions & References in further solvent(s), byproducts: P(OH)4-pyrophosphate salt; dry N2-atmosphere; in 25percent oleum, 8 months; product mixt. not sepd., detd. by (31)P-NMR spectroscopy Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1978); p. 1455 - 1460 ; (from Gmelin) View in Reaxys

F S

Rx-ID: 26753380 View in Reaxys 143/751 Yield

Conditions & References exposed to daylight for a long period Haas,A.; Lieb,M.; Chemische Berichte; vol. 111; (1978); p. 2891 - 2894 ; (from Gmelin) View in Reaxys exposed to daylight for a long period vol. F: PerFHalOrg.SVol.2; 6.2.1.6.8, page 209 - 242 ; (from Gmelin) View in Reaxys

O FK

(v4)F F SP-4 Br– F F

F Br O O (v6) F–

K+

(v1)

Rx-ID: 27325649 View in Reaxys 144/751 Yield

Conditions & References in neat (no solvent), absence of air and moisture, shaking (room remp., 24 h); removal of excess BrO2F (vac.); product mixt. not sepd., detd. by Raman spectroscopy Gillespie, Ronald J.; Spekkens, Paul H.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1977); p. 1539 - 1546 ; (from Gmelin) View in Reaxys F

O O

Rx-ID: 27341406 View in Reaxys 145/751 Yield

Conditions & References With O2 in hydrogen fluoride, HF (liquid); absence of air and moisture Gillespie, Ronald J.; Spekkens, Paul H.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1977); p. 1539 - 1546 ; (from Gmelin) View in Reaxys

56/201

2017-08-09 05:21:10

Rx-ID: 26401585 View in Reaxys 146/751 Yield

Conditions & References Kinetics, 0.2-2percent BrCN in Ne; at 2000-3200°K vol. C: MVol.D3; 6.2.5.6.2, page 229 - 229 View in Reaxys Clark, T. C.; Dove, J. E.; Finkelman, M.; Recent Develop. Shock Tube Res. Proc. 9th Intern. Shock Tube Symp., Stanford, Calif., 1973, S. 196/205; C.A.; vol. 80; (1974); p. 135441 ; (from Gmelin) View in Reaxys

F S

Rx-ID: 26091827 View in Reaxys 147/751 Yield

Conditions & References Siegemund; Angewandte Chemie; vol. 85; (1973); p. 982 View in Reaxys vol. S: SVol.3; 3.1.7.7.1, page 313 - 314 ; (from Gmelin) View in Reaxys

S Br

Rx-ID: 26108461 View in Reaxys 148/751 Yield

Conditions & References Siegemund; Angewandte Chemie; vol. 85; (1973); p. 982 View in Reaxys vol. S: SVol.3; 3.1.7.7.1, page 313 - 314 ; (from Gmelin) View in Reaxys

Rx-ID: 26518661 View in Reaxys 149/751 Yield

Conditions & References Sloan, J. P.; Tedder, J. M.; Walton, J. C.; J. Chem. Soc. Faraday Trans. I; vol. 69; (1973); p. 1143 - 1152 View in Reaxys vol. C: MVol.D2; 4.2.6.3, page 338 - 339 ; (from Gmelin) View in Reaxys

Rx-ID: 26744417 View in Reaxys 150/751 Yield

Conditions & References With sulfur trioxide, byproducts: SO2; addn of SO3 drop by drop in glass apparatous 37-43°C without catalyst; addn. of trichloroethylene to remove Br2, removing SO2 by distn., gaschromy pure product Siegemund; Angewandte Chemie; vol. 85; (1973); p. 982 View in Reaxys vol. C: MVol.D3; 2.5.1, page 118 - 119 ; (from Gmelin) View in Reaxys

Br N

Br O

Rx-ID: 26341807 View in Reaxys 151/751 Yield

Conditions & References Irradiation (UV/VIS); UV photolysis

57/201

2017-08-09 05:21:10

Gottardi, W.; Monatshefte fuer Chemie; vol. 103; (1972); p. 1150 - 1157 View in Reaxys vol. C: MVol.D3; 5.3, page 142 - 143 ; (from Gmelin) View in Reaxys

Br F

Rx-ID: 26385483 View in Reaxys 152/751 Yield

Conditions & References in neat (no solvent), Kinetics, Irradiation (UV/VIS); photolysis with 265nm at 67-180°C and CF2Br2 pressure 5-200 Torr; mechanism discussed;; quantum yield discussed; Walton, J. C.; J. Chem. Soc. Faraday Trans. I; vol. 68; (1972); p. 1559 - 1565 View in Reaxys vol. C: MVol.D2; 4.3.3.3, page 377 - 378 ; (from Gmelin) View in Reaxys

Rx-ID: 26463876 View in Reaxys 153/751 Yield

Conditions & References decompn. by sunlight Dunning, B. K.; Pritchard, H. O.; Journal of Chemical Thermodynamics; vol. 4; (1972); p. 213 - 218 View in Reaxys vol. C: MVol.D3; 2.4.5, page 116 - 118 ; (from Gmelin) View in Reaxys

Br C

Rx-ID: 26463877 View in Reaxys 154/751 Yield

Conditions & References equil., 20 and 100°C 80 and 20-27 days resp. Lenher, S.; Schumacher, H.-J.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 135; (1928); p. 85 - 101 View in Reaxys vol. C: MVol.D3; 2.4.5, page 116 - 118 ; (from Gmelin) View in Reaxys 150-200°C; detected by chromy. Dunning, B. K.; Pritchard, H. O.; Journal of Chemical Thermodynamics; vol. 4; (1972); p. 213 - 218 View in Reaxys vol. C: MVol.D3; 2.4.5, page 116 - 118 ; (from Gmelin) View in Reaxys Irradiation (UV/VIS); irradiation 405 nm, no effect of radiation of equil. Schumacher, H.-J.; Bergmann, P.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 13; (1931); p. 269 - 284 View in Reaxys vol. C: MVol.D3; 2.4.5, page 116 - 118 ; (from Gmelin) View in Reaxys Irradiation (UV/VIS); irradiation by 150 W tungsten lamp, equil. 150 and 200°C 400-500 and 100h resp. Dunning, B. K.; Pritchard, H. O.; Journal of Chemical Thermodynamics; vol. 4; (1972); p. 213 - 218 View in Reaxys vol. C: MVol.D3; 2.4.5, page 116 - 118 ; (from Gmelin)

58/201

2017-08-09 05:21:10

View in Reaxys equil. react. Schumacher, H.-J.; Bergmann, P.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 13; (1931); p. 269 - 284 View in Reaxys Trautz, M.; Zeitschrift fuer Elektrochemie; vol. 21; (1915); p. 329 - 342 View in Reaxys Dunning, B. K.; Pritchard, H. O.; Journal of Chemical Thermodynamics; vol. 4; (1972); p. 213 - 218 View in Reaxys Lenher, S.; Schumacher, H.-J.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 135; (1928); p. 85 - 101 View in Reaxys Reering, E. H.; Recl. Trav. Chim. Pays - Bas; vol. 47; (1928); p. 989 - 999 View in Reaxys vol. C: MVol.D3; 2.4.5, page 116 - 118 ; (from Gmelin) View in Reaxys 0 %, 0 %

With bromine, Irradiation (UV/VIS); photolysis (>350 nm) Schumacher, H.-J.; Bergmann, P.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 13; (1931); p. 269 - 284 View in Reaxys vol. C: MVol.D3; 2.4.5, page 116 - 118 ; (from Gmelin) View in Reaxys Kinetics, equil., faster react. in presence of steam Lenher, S.; Schumacher, H.-J.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 135; (1928); p. 85 - 101 View in Reaxys vol. C: MVol.D3; 2.4.5, page 116 - 118 ; (from Gmelin) View in Reaxys

F F

Rx-ID: 26485578 View in Reaxys 155/751 Yield

Conditions & References in neat (no solvent), other Radiation; γ-radiation; mechanism discussed; McAlpine; Sutcliffe; Journal of Physical Chemistry; vol. 76; (1972); p. 2070 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.2.3.5.3, page 312 - 312 ; (from Gmelin) View in Reaxys

Br Br

Rx-ID: 26485589 View in Reaxys 156/751 Yield

Conditions & References in neat (no solvent), Kinetics, balanced reaction; mechanism discussed; Ferguson, K. C.; Whittle, E.; J. Chem. Soc. Faraday Trans. I; vol. 68; (1972); p. 295 - 305 View in Reaxys Ferguson, K. C.; Whittle, E.; J. Chem. Soc. Faraday Trans. I; vol. 68; (1972); p. 641 - 646 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.2.3.5.8, page 314 - 314 ; (from Gmelin) View in Reaxys

59/201

2017-08-09 05:21:10

Cl Cl Cl

Rx-ID: 26162817 View in Reaxys 157/751 Yield

Conditions & References in tetrachloromethane, other Radiation; γ-radiation of CCl4 and CCl3Br at 25°C; yields given; Bibler; Journal of Physical Chemistry; vol. 75; (1971); p. 24 View in Reaxys vol. C: MVol.D2; 4.1.2.7.4.2, page 222 - 225 ; (from Gmelin) View in Reaxys

Br Br Br

Rx-ID: 26475532 View in Reaxys 158/751 Yield

Conditions & References in neat (no solvent), Irradiation (UV/VIS); photolysis of CBr4 in the presence of CCl4; Hautecloque, S.; Nguyen, T. M. N.; Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques; vol. 273; (1971); p. 569 - 572 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.1.3.7.2, page 270 - 270 ; (from Gmelin) View in Reaxys

Br Br

Rx-ID: 26487112 View in Reaxys 159/751 Yield

Conditions & References in neat (no solvent), pyrolysis at 700°C; main product is C2Br4, also formation of Br2 and C2Br6; Steudel, R.; Zeitschrift fuer Naturforschung; vol. 23 b; (1968); p. 1163 - 1171 View in Reaxys vol. C: MVol.D2; 4.1.3.7.1, page 270 - 270 ; (from Gmelin) View in Reaxys in neat (no solvent), Irradiation (UV/VIS); photolysis of CBr4 at 140-275°C formation of C2Br6, photolysis above 250°C also formation of C2Br4 and Br2; mechanism discussed; Hautecloque, S.; Nguyen, T. M. N.; Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques; vol. 273; (1971); p. 569 - 572 ; (from Gmelin) View in Reaxys

in neat (no solvent), pyrolysis at 140-275°C; Hautecloque, S.; Nguyen, T. M. N.; Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques; vol. 273; (1971); p. 569 - 572 View in Reaxys vol. C: MVol.D2; 4.1.3.7.1, page 270 - 270 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.1.3.7.2, page 270 - 270 ; (from Gmelin) View in Reaxys

AgBr

Rx-ID: 26096267 View in Reaxys 160/751 Yield

Conditions & References Irradiation (UV/VIS); in vac., at room temp.; λ = 280 - 436 nm Luckey, G. W.; Journal of Chemical Physics; vol. 23; (1955); p. 882 - 890

60/201

2017-08-09 05:21:10

View in Reaxys vol. Ag: MVol.B2; 7.2.8.1, page 106 - 109 ; (from Gmelin) View in Reaxys Irradiation (UV/VIS); 2 h Koch, P. P.; Kreiss, B.; Zeitschrift fuer Physik; vol. 32; (1925); p. 384 - 396 View in Reaxys vol. Ag: MVol.B2; 7.2.8.1, page 106 - 109 ; (from Gmelin) View in Reaxys Irradiation (UV/VIS); photolytic decompn. in vac. by λ = 280 - 436 nm Luckey, G. W.; Journal of Physical Chemistry; vol. 57; (1953); p. 791 - 796 View in Reaxys vol. Ag: MVol.B2; 7.2.8.1, page 106 - 109 ; (from Gmelin) View in Reaxys heating to 150-200°C in vac. Masters, J. I.; Nature (London, United Kingdom); vol. 223; (1969); p. 611 - 613 View in Reaxys vol. Ag: MVol.B2; 7.2.8.1, page 106 - 109 ; (from Gmelin) View in Reaxys

Cl Cl

Cl Cl Cl

Rx-ID: 26486336 View in Reaxys 161/751 Yield

Conditions & References in neat (no solvent), Kinetics, Irradiation (UV/VIS); irradiation with 3130-3655Å at 172-295°C; Hautecloque, S.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 256; (1963); p. 2601 - 2603 View in Reaxys Hautecloque, S.; Journal de Chimie Physique et de Physico-Chimie Biologique; vol. 64; (1967); p. 1526 - 1532 View in Reaxys vol. C: MVol.D2; 4.2.8.5.2, page 342 - 343 ; (from Gmelin) View in Reaxys in neat (no solvent), Kinetics, Irradiation (UV/VIS); irradiation with 3650Å at 92-280°C;; yiels and products depending on temp.; Sidebottom, H. W.; Tedder, J. M.; Walton, J. C.; Transactions of the Faraday Society; vol. 65; (1969); p. 755 - 762 View in Reaxys vol. C: MVol.D2; 4.2.8.5.2, page 342 - 343 ; (from Gmelin) View in Reaxys

Cl Cl Cl

Rx-ID: 26486344 View in Reaxys 162/751 Yield

Conditions & References in neat (no solvent), Kinetics, Irradiation (UV/VIS); photochemical teaction below 200°C; mechanism discussed; Sidebottom, H. W.; Tedder, J. M.; Walton, J. C.; Transactions of the Faraday Society; vol. 65; (1969); p. 755 - 762 View in Reaxys vol. C: MVol.D2; 4.2.8.5.2, page 342 - 343 ; (from Gmelin) View in Reaxys

61/201

2017-08-09 05:21:10

Cl Cl

Rx-ID: 26486347 View in Reaxys 163/751 Yield

Conditions & References in neat (no solvent), thermal decomposition, 18 h at 205°C in a pyrex vessel; Sidebottom, H. W.; Tedder, J. M.; Walton, J. C.; Transactions of the Faraday Society; vol. 65; (1969); p. 755 - 762 View in Reaxys vol. C: MVol.D2; 4.2.8.5.1, page 342 - 342 ; (from Gmelin) View in Reaxys

O Sb Cl

BrK

Rx-ID: 26675956 View in Reaxys 164/751 Yield

Conditions & References Lehmann, H. A.; Riesel, L.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 371; (1969); p. 281 - 288 View in Reaxys vol. S: SVol.3; 3.1.7.5.10.3, page 302 - 304 ; (from Gmelin) View in Reaxys

O Sb Cl2

BrK

Rx-ID: 26675957 View in Reaxys 165/751 Yield

O S

BrK –O

K+

S OBr

Br Br

Rx-ID: 26097322 View in Reaxys 166/751 Yield

Conditions & References in liquid sulphur dioxide, -25 to -30°C Noel, S.; Delesalle, G.; Heubel, J.; Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques; vol. 267; (1968); p. 398 - 400 View in Reaxys Noel, S.; Wartel, M.; Heubel, J.; Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques; vol. 264; (1967); p. 446 - 448 View in Reaxys vol. S: SVol.3; 3.1.7.6.3.2, page 307 - 309 ; (from Gmelin) View in Reaxys

Rx-ID: 26342685 View in Reaxys 167/751 Yield

Conditions & References in neat (no solvent), thermal decomposition in a quartz tube at 300-500°C; Chaigneau, M.; Moan, G. le; Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques; vol. 266; (1968); p. 1643 - 1645 ; (from Gmelin) View in Reaxys With water in neat (no solvent), decomposition above 300°C;

62/201

2017-08-09 05:21:10

Chaigneau, M.; Moan, G. le; Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques; vol. 266; (1968); p. 1643 - 1645 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.3.7.5, page 384 - 385 ; (from Gmelin) View in Reaxys With H2O vol. C: MVol.D2; 4.3.7.5, page 384 - 385 ; (from Gmelin) View in Reaxys

F Br

F Cl

C 3BrClF 6

Br F

Rx-ID: 26342686 View in Reaxys 168/751 Yield

Conditions & References With carbon monoxide in neat (no solvent), decomposition above 500°C; further products; Chaigneau, M.; Moan, G. le; Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques; vol. 266; (1968); p. 1643 - 1645 ; (from Gmelin) View in Reaxys With CO vol. C: MVol.D2; 4.3.7.5, page 384 - 385 ; (from Gmelin) View in Reaxys

Br Br

Rx-ID: 26431242 View in Reaxys 169/751 Yield

Conditions & References in neat (no solvent), Kinetics, enthalpy and entropy of reaction given; Amphlett, J. C.; Whittle, E.; Transactions of the Faraday Society; vol. 64; (1968); p. 2130 - 2142 View in Reaxys vol. C: MVol.D2; 4.2.3.5.6, page 313 - 313 ; (from Gmelin) View in Reaxys in neat (no solvent), Kinetics, enthalpy and entropy of reaction given; Amphlett, J. C.; Whittle, E.; Transactions of the Faraday Society; vol. 63; (1967); p. 2695 - 2701 ; (from Gmelin) View in Reaxys

Rx-ID: 26485579 View in Reaxys 170/751 Yield

Conditions & References With oxygen in neat (no solvent), on passing CF3Br/O2 through a heated quartz tube, oxidation of C2F6 intermediate above 600°C; Kern, J.; Deut. Luft Raumfahrt Forsch.-Ber.; (1968); p. 1 - 55 View in Reaxys vol. C: MVol.D2; 4.2.3.5.6, page 313 - 313 ; (from Gmelin) View in Reaxys

Rx-ID: 26485580 View in Reaxys 171/751

63/201

2017-08-09 05:21:10

Yield

Conditions & References in neat (no solvent), decomposition on heating in a quartz tube and exclusion of air to 550-1200°C; mechanism discussed; Kern, J.; Deut. Luft-Raumfahrt Forsch. Ber.; (1968); p. 1 - 55 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.2.3.5.1, page 311 - 311 ; (from Gmelin) View in Reaxys

Br Br

Rx-ID: 26487113 View in Reaxys 172/751 Yield

Conditions & References With silver wool in neat (no solvent), reaction at 500-600°C with silver wool; main product is C2Br4; Steudel, R.; Zeitschrift fuer Naturforschung; vol. 23 b; (1968); p. 1163 - 1171 View in Reaxys vol. C: MVol.D2; 4.1.3.7.5, page 271 - 272 ; (from Gmelin) View in Reaxys

Cl Br

Rx-ID: 26598901 View in Reaxys 173/751 Yield

Conditions & References

in neat (no solvent), thermal decomposition on passing through a quartz tube at 900°C;; determination by IR; Steudel, R.; Zeitschrift fuer Naturforschung; vol. 23 b; (1968); p. 1163 - 1171 View in Reaxys vol. C: MVol.D2; 4.3.5.5, page 381 - 382 ; (from Gmelin) View in Reaxys H Br

Br–

NH +4

Br Br

Br Ta Br

(v5)

BrTa

Rx-ID: 26343581 View in Reaxys 174/751 Yield

Conditions & References 325°C Glushkova, M. A.; Ershova, M. M.; Buslaev, Yu. A.; Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy; vol. 3; (1967); p. 1971 - 1972; Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy; vol. 3; (1967); p. 2259 2260 ; (from Gmelin) View in Reaxys 325°C vol. Ta: MVol.B1; 7, page 141 - 159 ; (from Gmelin) View in Reaxys

Cl Cl

Cl Cl Cl

Rx-ID: 26457498 View in Reaxys 175/751 Yield

Conditions & References in neat (no solvent), Irradiation (UV/VIS); photolysis at 248-302°C; further products; mechanism discussed; Hautecloque, S.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 257; (1963); p. 131 - 134

64/201

2017-08-09 05:21:10

View in Reaxys Hautecloque, S.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 261; (1965); p. 3613 - 3616 View in Reaxys Hautecloque, S.; Journal de Chimie Physique et de Physico-Chimie Biologique; vol. 64; (1967); p. 1526 - 1532 View in Reaxys vol. C: MVol.D2; 4.2.8.5.2, page 342 - 343 ; (from Gmelin) View in Reaxys

F F

Rx-ID: 26485581 View in Reaxys 176/751 Yield

Conditions & References in neat (no solvent), Kinetics, determination of the balanced reaction at 621-722°C in a quartz vessel; Coomber, J. W.; Whittle, E.; Transactions of the Faraday Society; vol. 63; (1967); p. 1394 - 1401 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.2.3.5.1, page 311 - 311 ; (from Gmelin) View in Reaxys

Rx-ID: 26486335 View in Reaxys 177/751 Yield

Conditions & References in neat (no solvent), Irradiation (UV/VIS) Hautecloque, S.; Journal de Chimie Physique et de Physico-Chimie Biologique; vol. 64; (1967); p. 1526 - 1532 View in Reaxys vol. C: MVol.D2; 4.2.8.5.2, page 342 - 343 ; (from Gmelin) View in Reaxys

Cl Cl

Cl Cl Cl

Rx-ID: 26486340 View in Reaxys 178/751 Yield

Conditions & References With hydrogen in neat (no solvent), Irradiation (UV/VIS); photolysis at 248-302°C; further products; mechanism discussed; Hautecloque, S.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 257; (1963); p. 131 - 134 View in Reaxys Hautecloque, S.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 261; (1965); p. 3613 - 3616 View in Reaxys Hautecloque, S.; Journal de Chimie Physique et de Physico-Chimie Biologique; vol. 64; (1967); p. 1526 - 1532 View in Reaxys vol. C: MVol.D2; 4.2.8.5.2, page 342 - 343 ; (from Gmelin) View in Reaxys

BrNTa

Rx-ID: 26608424 View in Reaxys 179/751 Yield

Conditions & References decompn. above 450°C

65/201

2017-08-09 05:21:10

Glushkova, M. A.; Ershova, M. M.; Buslaev, Yu. A.; Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy; vol. 3; (1967); p. 1971 - 1972; Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy; vol. 3; (1967); p. 2259 2260 ; (from Gmelin) View in Reaxys decompn. above 450°C vol. Ta: MVol.B1; 7.1, page 159 - 161 ; (from Gmelin) View in Reaxys

N F

Rx-ID: 26640331 View in Reaxys 180/751 Yield

Conditions & References

With aluminum tri-bromide vol. C: MVol.D3; 4.4.3, page 134 - 135 ; (from Gmelin) View in Reaxys

With AlBr3 Fraser, G. W.; Shreeve, J. M.; Inorganic Chemistry; vol. 6; (1967); p. 1711 - 1715 ; (from Gmelin) View in Reaxys

(v3)

Al–

(v4)

Fe +

(v6)

(v3)

(v4)

O(v4) P Fe P (v4)

(v4)

(v3)

Br Cl

(v4)

(v5)

(v6)

(v3)

Rx-ID: 26758098 View in Reaxys 181/751 Yield

Conditions & References

in tetrahydrofuran Hieber, W.; Frey, V.; John, P.; Chemische Berichte; vol. 100; (1967); p. 1961 - 1974 ; (from Gmelin) View in Reaxys

in methanol Hieber, W.; Frey, V.; John, P.; Chemische Berichte; vol. 100; (1967); p. 1961 - 1974 ; (from Gmelin) View in Reaxys vol. Fe: Org.Verb.B1; 1.1.4.4.4.3, page 184 - 185 ; (from Gmelin) View in Reaxys

(v3)

Br Br

(v3)

Al– BrBr

O (v3)

(v6)

Fe +

(v4)

(v3)

(v4)

(v3)

(v4)

O(v4) P Fe P (v4)

(v6)

(v4)

(v5)

(v3)

Rx-ID: 26758477 View in Reaxys 182/751 Yield <1

Conditions & References in tetrahydrofuran

66/201

2017-08-09 05:21:10

Hieber, W.; Frey, V.; John, P.; Chemische Berichte; vol. 100; (1967); p. 1961 - 1974 ; (from Gmelin) View in Reaxys <1

in methanol Hieber, W.; Frey, V.; John, P.; Chemische Berichte; vol. 100; (1967); p. 1961 - 1974 ; (from Gmelin) View in Reaxys

in dichloromethane Hieber, W.; Frey, V.; John, P.; Chemische Berichte; vol. 100; (1967); p. 1961 - 1974 ; (from Gmelin) View in Reaxys vol. Fe: Org.Verb.B1; 1.1.4.4.4.3, page 184 - 185 ; (from Gmelin) View in Reaxys

Rx-ID: 26486341 View in Reaxys 183/751 Yield

Conditions & References in neat (no solvent), Irradiation (UV/VIS); mechanism discussed; Cadman, P.; Simons, J. P.; Transactions of the Faraday Society; vol. 62; (1966); p. 631 - 641 View in Reaxys vol. C: MVol.D2; 4.2.8.5.2, page 342 - 343 ; (from Gmelin) View in Reaxys H

BrK

V(4+)

O10P2V2

Rx-ID: 26560278 View in Reaxys 184/751 Yield

Conditions & References in neat (no solvent) Ladwig, G.; Thilo, E.; Zeitschrift fuer Chemie (Stuttgart, Germany); vol. 4; (1964); p. 350 - 350 ; (from Gmelin) View in Reaxys in neat (no solvent) Ladwig, G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 338; (1965); p. 266 - 278 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. V: MVol.B1; 140, page 361 - 364 ; (from Gmelin) View in Reaxys -1

Br( 1-)

Br Br

(v2)

Rx-ID: 26109273 View in Reaxys 185/751 Yield

Conditions & References With XeO3 in hydrogen bromide, HBr, 1mol/l; fast react.; Koch, C. W.; Williamson, S. M.; Noble-Gas Compounds, Chicago 1963, S. 181 View in Reaxys Williamson, S. M.; Koch, C. W.; Noble-Gas Compounds, Chicago 1963, S. 158 ; (from Gmelin) View in Reaxys With XeO3 in not given, oxidation of bromide at pH 1 - 0 with measurable rate;; photometric determination (Br3(1-)) of proceeding of react. at different temp.; Koch, C. W.; Williamson, S. M.; Noble-Gas Compounds, Chicago 1963, S. 181 ; (from Gmelin)

67/201

2017-08-09 05:21:10

View in Reaxys With XeO3 in not given, oxidation of bromide at pH 1 - 0 with measurable rate;; photometric determination (Br3(1-)) of proceeding of react. at different temp.; vol. He: Edelgasverb.; 1.8.6.2.2, page 103 - 108 ; (from Gmelin) View in Reaxys With XeO3 in hydrogen bromide, aq. HBr; HBr, 1mol/l; fast react.; Appelman, E. H.; Malm, J. G.; Journal of the American Chemical Society; vol. 86; (1964); p. 2141 - 2148 View in Reaxys vol. He: Edelgasverb.; 1.8.6.2.2, page 103 - 108 ; (from Gmelin) View in Reaxys

F F

F S

F F

F N

N H

S–

Na +

S F

F N

F F

Rx-ID: 26344703 View in Reaxys 186/751 Yield

Conditions & References byproducts: N2,SF6,N2F4,, SF4, CO2; at 75-125°C; molar ratio 1-2 Boivin, J. L.; Canadian Journal of Chemistry; vol. 42; (1964); p. 2744 - 2748 View in Reaxys vol. C: MVol.D3; 6.2.5.6.7.12, page 239 - 239 ; (from Gmelin) View in Reaxys

O –O

Na +

Br -1 O

(v1)

Rx-ID: 26448186 View in Reaxys 187/751 Yield

Conditions & References other Radiation Ramasastry, C.; Murty, Y. V. G. S.; Indian Journal of Pure and Applied Physics; vol. 2; (1964); p. 35 - 36 ; (from Gmelin) View in Reaxys other Radiation vol. Na: SVol.5; 7.1, page 1803 - 1805 ; (from Gmelin) View in Reaxys

Br Br

(v3)

Br2V

Rx-ID: 26468443 View in Reaxys 188/751 Yield

Conditions & References in neat (no solvent), equilibrium at 644 - 805°C; McCarley, R. E.; Roddy, J. W.; Inorganic Chemistry; vol. 3; (1964); p. 54 - 59 View in Reaxys Shchukarev, S. A.; Oranskaya, N. A.; Zhurnal Obshchei Khimii; vol. 24; (1954); p. 2077 - 2086; Zhurnal Obshchei Khimii; vol. 24; (1954); p. 2109 - 2119 View in Reaxys McCarley, R. E.; Roddy, J. W.; IS-533 (1962/63) 1/29 ; (from Gmelin) View in Reaxys in neat (no solvent), equilibrium at 644 - 805°C; McCarley, R. E.; Roddy, J. W.; Inorganic Chemistry; vol. 3; (1964); p. 60 - 63 View in Reaxys vol. V: MVol.B1; 96, page 257 - 258 ; (from Gmelin)

68/201

2017-08-09 05:21:10

View in Reaxys McCarley, R. E.; Roddy, J. W.; IS-534 (1962/63) 1/21 ; (from Gmelin) View in Reaxys

(v4)

(v3)

Rx-ID: 26526397 View in Reaxys 189/751 Yield

Conditions & References in neat (no solvent), cooling a gas phase containing VBr4 down from 350°C to ambient temp.; McCarley, R. E.; Roddy, J. W.; Inorganic Chemistry; vol. 3; (1964); p. 54 - 59 ; (from Gmelin) View in Reaxys in neat (no solvent), at -23°C; McCarley, R. E.; Roddy, J. W.; Inorganic Chemistry; vol. 3; (1964); p. 54 - 59 View in Reaxys McCarley, R. E.; Roddy, J. W.; IS-533 (1962/63) 1/29 ; (from Gmelin) View in Reaxys in neat (no solvent), cooling a gas phase containing VBr4 down from 350°C to ambient temp.; vol. V: MVol.B1; 96, page 257 - 258 ; (from Gmelin) View in Reaxys in neat (no solvent), at -23°C; vol. V: MVol.B1; 97, page 258 - 260 ; (from Gmelin) View in Reaxys in neat (no solvent), at 600°K; McCarley, R. E.; Roddy, J. W.; Berry, K. O.; Inorganic Chemistry; vol. 3; (1964); p. 50 - 54 View in Reaxys vol. V: MVol.B1; 97, page 258 - 260 View in Reaxys McCarley, R. E.; Roddy, J. W.; Berry, K. O.; IS-535 (1962/63) 1/24 ; (from Gmelin) View in Reaxys

Cl (v4)

V ClCl

Br Cl

(v3)

Rx-ID: 26836667 View in Reaxys 190/751 Yield

Conditions & References in neat (no solvent), dissociation at 600°K; McCarley, R. E.; Roddy, J. W.; Berry, K. O.; Inorganic Chemistry; vol. 3; (1964); p. 50 - 54 View in Reaxys vol. V: MVol.B1; 98, page 260 - 262 View in Reaxys McCarley, R. E.; Roddy, J. W.; Berry, K. O.; IS-535 (1962/63) 1/24 ; (from Gmelin) View in Reaxys

Br (v4)

V ClCl

V(Cl,Br)3

Br Br

Rx-ID: 26836668 View in Reaxys 191/751 Yield

Conditions & References in neat (no solvent), cooling at ambient temp.; McCarley, R. E.; Roddy, J. W.; Berry, K. O.; Inorganic Chemistry; vol. 3; (1964); p. 50 - 54 View in Reaxys

69/201

2017-08-09 05:21:10

vol. V: MVol.B1; 98, page 260 - 262 View in Reaxys McCarley, R. E.; Roddy, J. W.; Berry, K. O.; IS-535 (1962/63) 1/24 ; (from Gmelin) View in Reaxys Br (v4)

V(Cl,Br)3

V BrCl

Br Br

Rx-ID: 26836671 View in Reaxys 192/751 Yield

Conditions & References in neat (no solvent), cooling at ambient temp.; McCarley, R. E.; Roddy, J. W.; Berry, K. O.; Inorganic Chemistry; vol. 3; (1964); p. 50 - 54 View in Reaxys vol. V: MVol.B1; 98, page 260 - 262 View in Reaxys McCarley, R. E.; Roddy, J. W.; Berry, K. O.; IS-535 (1962/63) 1/24 ; (from Gmelin) View in Reaxys

Br (v4)

V(Cl,Br)3

V BrCl

Br Br

Rx-ID: 26836675 View in Reaxys 193/751 Yield

AgBr

Rx-ID: 26096269 View in Reaxys 194/751 Yield

Conditions & References thermal decompn. above m.p. Matejec, R.; Zeitschrift fuer Physik; vol. 147; (1957); p. 593 - 599 View in Reaxys vol. Ag: MVol.B2; 7.2.8.3, page 111 - 111 ; (from Gmelin) View in Reaxys Irradiation (UV/VIS); photolytic decompn. Chateau, H.; Mailliet, A. M.; Pouradier, J.; Sci. Ind. Phot. (2); vol. 34; (1963); p. 306 - 311 View in Reaxys vol. Ag: MVol.B2; 7.2.8.1, page 106 - 109 ; (from Gmelin) View in Reaxys other Radiation; radiation of positive O or N-ions (4 - 5 kV); several min Trillat, J. J.; Terao, N.; Tertian, L.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 242; (1956); p. 1294 - 1297 View in Reaxys vol. Ag: MVol.B2; 7.2.8.2, page 109 - 111 ; (from Gmelin) View in Reaxys thermal decompn. at 245°C Kordes, E.; Libera, L.; Zeitschrift fuer Physikalische Chemie (Muenchen); vol. 1; (1954); p. 211 - 240 View in Reaxys vol. Ag: MVol.B2; 7.2.8.3, page 111 - 111 ; (from Gmelin)

70/201

2017-08-09 05:21:10

View in Reaxys Br Ta Br

(v3)

Br Br

Rx-ID: 26453329 View in Reaxys 195/751 Yield

Conditions & References With nitric acid Berdonosov, S. S.; Lapitskii, A. V.; Vlasov, L. G.; Zhurnal Neorganicheskoi Khimii; vol. 7; (1962); p. 1125 - 1128; Zhurnal Neorganicheskoi Khimii; vol. 7; (1962); p. 2173 - 2180 ; (from Gmelin) View in Reaxys With HNO3 vol. Ta: MVol.B1; 7, page 141 - 159 ; (from Gmelin) View in Reaxys

Rx-ID: 26486339 View in Reaxys 196/751 Yield

Conditions & References in neat (no solvent), Kinetics, other Radiation; mechanism discussed;; yield of Br2 depending on temp.; Firestone, R. F.; Willard, J. E.; Journal of the American Chemical Society; vol. 83; (1961); p. 3551 - 3554 View in Reaxys vol. C: MVol.D2; 4.2.8.5.3.1, page 344 - 344 ; (from Gmelin) View in Reaxys in neat (no solvent), Kinetics, other Radiation Young; Willard; Journal of Physical Chemistry; vol. 66; (1962); p. 271 View in Reaxys vol. C: MVol.D2; 4.2.8.5.3.1, page 344 - 344 ; (from Gmelin) View in Reaxys

Cl Cl Cl

Rx-ID: 26486342 View in Reaxys 197/751 Yield

Conditions & References in neat (no solvent), Kinetics, Irradiation (UV/VIS); irradiation with 2537Å at 108°C; Young; Willard; Journal of Physical Chemistry; vol. 66; (1962); p. 271 View in Reaxys vol. C: MVol.D2; 4.2.8.5.2, page 342 - 343 View in Reaxys Young, A. H.; Diss. Univ. of Wisconsin 1959, 229 S.; Diss. Abstr.; vol. 19; (1959); p. 3154/5 ; (from Gmelin) View in Reaxys in neat (no solvent), other Radiation; radiation with γ-rays at 108-182°C;; yields depending on temp. and dose of radiation; Young; Willard; Journal of Physical Chemistry; vol. 66; (1962); p. 271 View in Reaxys vol. C: MVol.D2; 4.2.8.5.3.1, page 344 - 344 View in Reaxys Young, A. H.; Diss. Univ. of Wisconsin 1959, 229 S.; Diss. Abstr.; vol. 19; (1959); p. 3154/5 ; (from Gmelin) View in Reaxys

71/201

2017-08-09 05:21:10

Cl Br

Cl Cl

Rx-ID: 26486343 View in Reaxys 198/751 Yield

Conditions & References in neat (no solvent), other Radiation; radiation with γ-rays at 20°C; further products; Young; Willard; Journal of Physical Chemistry; vol. 66; (1962); p. 271 View in Reaxys vol. C: MVol.D2; 4.2.8.5.3.1, page 344 - 344 View in Reaxys Young, A. H.; Diss. Univ. of Wisconsin 1959, 229 S.; Diss. Abstr.; vol. 19; (1959); p. 3154/5 ; (from Gmelin) View in Reaxys

Rx-ID: 26486345 View in Reaxys 199/751 Yield

Conditions & References in neat (no solvent), Irradiation (UV/VIS); mechanism discussed; Young; Willard; Journal of Physical Chemistry; vol. 66; (1962); p. 271 View in Reaxys vol. C: MVol.D2; 4.2.8.5.2, page 342 - 343 ; (from Gmelin) View in Reaxys

(v1)

Rx-ID: 26518660 View in Reaxys 200/751 Yield

Conditions & References in neat (no solvent), Irradiation (UV/VIS); flash photolysis of CFBr3; mechanism discussed; determination by UV; Yarwood; Simons; Proceedings of the Chemical Society, London; (1962); p. 62 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.2.6.3, page 338 - 339 ; (from Gmelin) View in Reaxys

F FK

F F

F V

(v4)

F –F F F V (v6)

K+

Rx-ID: 26559379 View in Reaxys 201/751 Yield

Conditions & References in neat (no solvent), destillation in KF; Cavell, R. G.; Clark, H. C.; Journal of the Chemical Society; (1962); p. 2692 - 2698 View in Reaxys vol. V: MVol.B1; 67, page 187 - 190 ; (from Gmelin) View in Reaxys O Br

Cu( 2+)

O–

CuO

Rx-ID: 26151417 View in Reaxys 202/751 Yield

Conditions & References in melt, Kinetics, at 170 - 210°C; LiNO3/KNO3/NaNO3 melt; Duke, F. R.; Lawrence, W. W.; Journal of the American Chemical Society; vol. 83; (1961); p. 1269 - 1271 ; (from Gmelin) View in Reaxys

72/201

2017-08-09 05:21:10

in melt, Kinetics, at 170 - 210°C; KNO3/NaNO3 melt; Duke, F. R.; Lawrence, W. W.; Journal of the American Chemical Society; vol. 83; (1961); p. 1269 - 1271 ; (from Gmelin) View in Reaxys in melt, Kinetics, at 170 - 210°C; LiNO3/KNO3/NaNO3 melt; vol. Cu: MVol.B3; 203, page 1440 - 1442 ; (from Gmelin) View in Reaxys in melt, Kinetics, at 170 - 210°C; KNO3/NaNO3 melt; vol. Cu: MVol.B3; 203, page 1440 - 1442 ; (from Gmelin) View in Reaxys Br Ru Br

(v3)

Rx-ID: 26342587 View in Reaxys 203/751 Yield

Conditions & References in neat (no solvent), heating to temperatures higher than 400°C; Shchukarev, S. A.; Kolbin, N. I.; Byabov, A. N.; Vestn. Leningr. Univ. Ser. Fiz. i Khim.; nb. 4; (1961); p. 100 - 104; C. A.; (1961); p. 15200 ; (from Gmelin) View in Reaxys vol. Ru: SVol.; 99, page 308 - 309 ; (from Gmelin) View in Reaxys

Br Ru Br

(v3)

Rx-ID: 26342588 View in Reaxys 204/751 Yield

Conditions & References in neat (no solvent) Shchukarev, S. A.; Kolbin, N. I.; Byabov, A. N.; Vestn. Leningr. Univ. Ser. Fiz. i Khim.; nb. 4; (1961); p. 100 - 104; C. A.; (1961); p. 15200 ; (from Gmelin) View in Reaxys vol. Ru: SVol.; 99, page 308 - 309 ; (from Gmelin) View in Reaxys

Br Br

Rx-ID: 26385484 View in Reaxys 205/751 Yield

Conditions & References With oxygen in neat (no solvent), Irradiation (UV/VIS); flash photolysis in the presence of O2; mechanism discussed; Simons, J. P.; Yarwood, A. J.; Nature (London, United Kingdom); vol. 192; (1961); p. 943 - 944 View in Reaxys vol. C: MVol.D2; 4.3.3.3, page 377 - 378 ; (from Gmelin) View in Reaxys

H O

BaBr4Sn

Rx-ID: 26616982 View in Reaxys 206/751

73/201

2017-08-09 05:21:10

Yield

Conditions & References With acetone Gonzales Martin, A.; Acta Salmanticensia Ser. Cienc. (2); vol. 3; nb. 1; (1961); p. 105 - 125; C.A.; vol. 57; (1962); p. 12093 View in Reaxys vol. Sn: MVol.C3; 31.14, page 199 - 199 ; (from Gmelin) View in Reaxys

O (v5)

Br2OV

V BrBr

Rx-ID: 26836677 View in Reaxys 207/751 Yield

Conditions & References in neat (no solvent), heating slowly or at once to 180 °C at atmospheric pressure; Miller, F. A.; Baer, W. K.; Spectrochimica Acta; vol. 17; (1961); p. 112 - 120 View in Reaxys Roscoe, H. E.; Justus Liebigs Annalen der Chemie; vol. 8; (1872); p. 95 - 112 View in Reaxys Roscoe, H. E.; Philosophical Transactions of the Royal Society of London; vol. 160; (1870); p. 317 - 331 View in Reaxys vol. V: MVol.B1; 98, page 260 - 262 ; (from Gmelin) View in Reaxys

Br Br

(v5)

Br UBr Br

Br3OU

O3U

(v4)

U BrBr

Rx-ID: 26467041 View in Reaxys 208/751 Yield

Conditions & References in neat (no solvent), reaction of CBr4 with UO3; products depending on various conditions; Prigent, J.; Ann. Chim. Paris (13); vol. 5; (1960); p. 65 - 106 View in Reaxys vol. C: MVol.D2; 4.1.3.7.7, page 272 - 273 ; (from Gmelin) View in Reaxys

Rx-ID: 26486338 View in Reaxys 209/751 Yield

Conditions & References in neat (no solvent), other Radiation; radiation with neutrons at 15-17°C; formation of products with excited Br; Nesmeyanov, A. N.; Borisov, E. A.; Zvara, I.; Radiokhimiya; vol. 1; (1960); p. 154 - 166; Radiokhimiya; vol. 1; (1959); p. 325 - 335 View in Reaxys vol. C: MVol.D2; 4.2.8.5.3.2, page 344 - 345 ; (from Gmelin) View in Reaxys

Rx-ID: 5574989 View in Reaxys 210/751 Yield

Conditions & References T= 300 °C , Erh. des Hydrobromid Eisch; Chemistry and Industry (London, United Kingdom); (1959); p. 1449 View in Reaxys

74/201

2017-08-09 05:21:10

Cl 2 Cl

(v1)

PBr Br

P Br Br

Rx-ID: 26380473 View in Reaxys 211/751 Yield

Conditions & References in tetrachloromethane, reaction of PBr soln. in CCl4 on dropwise added of a soln. of ClO2 in CCl4; pptn. of Br2 and formation of solid PBr5*2CCl4, liquid phase contains POBr3; Perotti, A.; Gazzetta Chimica Italiana; vol. 89; (1959); p. 2046 - 2052 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys

Br N

Rx-ID: 26159222 View in Reaxys 212/751 Yield

Conditions & References With copper in benzene, in boilig benzene Cairns, T. L.; Carboni, R. A.; Coffman, D. D.; Engelhardt, V. A.; Heckert, R. E.; et al.; Journal of the American Chemical Society; vol. 80; (1958); p. 2775 - 2778 ; (from Gmelin) View in Reaxys With Cu in benzene, in boilig benzene vol. C: MVol.D1; 11, page 106 - 112 ; (from Gmelin) View in Reaxys

Br – Cl Cl P Cl Cl

Cl Cl

P+ ClCl

Rx-ID: 26456917 View in Reaxys 213/751 Yield

Conditions & References With H2O in water, light yellow colored acidic hydrolysate due to loss of Br2; Kolditz, L.; Feltz, A.; Z. Anorg. Chem.; vol. 293; (1958); p. 286 - 293 View in Reaxys vol. P: MVol.C; 224, page 513 - 516 ; (from Gmelin) View in Reaxys

Br – Cl Cl P Cl Cl

Cl Cl

P+

ClCl

PCl Cl

Br PBr Br Br

Rx-ID: 26456918 View in Reaxys 214/751 Yield

Conditions & References in tetrachloromethane, decomposition with deep red color in CCl4 soln., formed PBr5 partially decomposes into Br2 and PBr3; Kolditz, L.; Feltz, A.; Z. Anorg. Chem.; vol. 293; (1958); p. 286 - 293 View in Reaxys vol. P: MVol.C; 224, page 513 - 516 ; (from Gmelin) View in Reaxys

Br Br Br TB-5 P Br Br

Rx-ID: 26535843 View in Reaxys 215/751

75/201

2017-08-09 05:21:10

Yield

Conditions & References in neat (no solvent), decomposition on melting; Chatterjee, S. D.; Journal of the Indian Chemical Society; vol. 19; (1942); p. 49 - 50 ; (from Gmelin) View in Reaxys in neat (no solvent), at 65 °C the decompn. achieves about 98.5percent, at 90°C >99percent; Harries, G. S.; Payne, D. S.; Journal of the Chemical Society; (1958); p. 3732 - 3733 ; (from Gmelin) View in Reaxys in further solvent(s), complete dissociation at higher temperature in liquid PBr3; Baxter, G. P.; Moore, C. J.; Boylston, A. C.; Journal of the American Chemical Society; vol. 34; (1912); p. 259 274 ; (from Gmelin) View in Reaxys in neat (no solvent), at 65 °C the decompn. achieves about 98.5percent, at 90°C >99percent; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin) View in Reaxys in neat (no solvent), decomposition on melting; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin) View in Reaxys in further solvent(s), complete dissociation at higher temperature in liquid PBr3; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin) View in Reaxys

Se Br

Rx-ID: 7054029 View in Reaxys 216/751 Yield

Conditions & References T= 25 °C , Equilibrium constant Tideswell; McCullough; Journal of the American Chemical Society; vol. 79; (1957); p. 1031,1032 View in Reaxys

Br Br

Rx-ID: 26385480 View in Reaxys 217/751 Yield

Conditions & References in neat (no solvent), thermal decomposition on passing through a tube at 900°C; vol. C: MVol.D2; 4.3.3.3, page 377 - 378 ; (from Gmelin) View in Reaxys in neat (no solvent), thermal decomposition on passing through a tube at 900°C; Friederich, M.; Chemiker-Zeitung; vol. 81; (1957); p. 526 - 530 ; (from Gmelin) View in Reaxys

potassium iodide

racemate

Rx-ID: 8213732 View in Reaxys 218/751 Yield

Conditions & References T= 75 - 110 °C , Rate constant

76/201

2017-08-09 05:21:10

Weinstock et al.; Journal of the American Chemical Society; vol. 78; (1956); p. 6072,6075 View in Reaxys Goering; Espy; Journal of the American Chemical Society; vol. 77; (1955); p. 5023,5025 View in Reaxys

sodium iodide

racemate

Rx-ID: 8213735 View in Reaxys 219/751 Yield

Conditions & References T= 62 °C , Rate constant Cristol et al.; Journal of the American Chemical Society; vol. 78; (1956); p. 598,599 View in Reaxys T= 74 °C , Rate constant Cristol et al.; Journal of the American Chemical Society; vol. 78; (1956); p. 598,599 View in Reaxys T= 88 °C , Rate constant Cristol et al.; Journal of the American Chemical Society; vol. 78; (1956); p. 598,599 View in Reaxys O–

O O

3 Na + –O

P O

O P

O–O–

– 4 Na + O

BrNa O

O P

O–

Rx-ID: 26395580 View in Reaxys 220/751 Yield

Conditions & References With oxygen in neat (no solvent), Kinetics, byproducts: Na3PO4; 200-900°C; Hisar, R. S.; Bulletin de la Societe Chimique de France; (1955); p. 916 - 918 View in Reaxys Hisar, R. S.; Istanbul Tek. Univ. Bul.; vol. 9; (1956); p. 1 - 9; C. A.; (1957); p. 8564 ; (from Gmelin) View in Reaxys With O2 in neat (no solvent), Kinetics, byproducts: Na3PO4; 200-900°C; vol. Na: SVol.4; 134, page 1655 - 1657 ; (from Gmelin) View in Reaxys O

O S

Rx-ID: 26401601 View in Reaxys 221/751 Yield

Conditions & References at 120°C vol. C: MVol.D3; 6.2.5.6.7.11, page 238 - 239 View in Reaxys Patent; Graf, R.; Farbwerke Hoechst, vormals Meister Lucius & Bruening; DE940351; (1956); C.; (1956); p. 13555 ; (from Gmelin) View in Reaxys O

O N

O O O

O S N

Rx-ID: 26401602 View in Reaxys 222/751

77/201

2017-08-09 05:21:10

Yield

Conditions & References in liquid sulphur dioxide, at -20°C vol. C: MVol.D3; 6.2.5.6.7.11, page 238 - 239 View in Reaxys Patent; Graf, R.; Farbwerke Hoechst, vormals Meister Lucius & Bruening; DE940351; (1956); C.; (1956); p. 13555 ; (from Gmelin) View in Reaxys O–

O O Br

–O

3 Na +

Na +

–O

P O

– 4 Na + O

O P

O–O– P

O P

O–

Rx-ID: 26448209 View in Reaxys 223/751 Yield

Conditions & References in neat (no solvent), byproducts: O2, Na3PO4; start of react. at 320°C; Hisar, R. S.; Bulletin de la Societe Chimique de France; (1956); p. 1259 - 1262 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: O2, Na3PO4; start of react. at 320°C; vol. Na: SVol.4; 134, page 1655 - 1657 ; (from Gmelin) View in Reaxys

Na +

–O

– 4 Na + O

Na + O

O–O– P

O P

O–

Rx-ID: 26448211 View in Reaxys 224/751 Yield

Conditions & References over at 320°C. Hisar, R. S.; Bulletin de la Societe Chimique de France; (1956); p. 1259 - 1262 ; (from Gmelin) View in Reaxys over at 320°C. vol. Na: SVol.5; 8.1, page 1812 - 1817 ; (from Gmelin) View in Reaxys

potassium iodide

Rx-ID: 7054016 View in Reaxys 225/751 Yield

Conditions & References T= 100 °C , Rate constant Goering; Espy; Journal of the American Chemical Society; vol. 77; (1955); p. 5023,5025 View in Reaxys T= 80 °C , Rate constant Goering; Espy; Journal of the American Chemical Society; vol. 77; (1955); p. 5023,5025 View in Reaxys

oxygen

H 2N 2

Rx-ID: 7060065 View in Reaxys 226/751

78/201

2017-08-09 05:21:10

Yield

Conditions & References T= 30 - 40 °C , UV-Licht.Irradiation Francis; Haszeldine; Journal of the Chemical Society; (1955); p. 2151,2157,2161,2163 View in Reaxys

F O

Rx-ID: 26342702 View in Reaxys 227/751 Yield

Conditions & References in neat (no solvent), Irradiation (UV/VIS); decomposition with UV at 30-40°C;; turnover 58percent in 6.5h; Francis, W. C.; Haszeldine, R. N.; Journal of the Chemical Society; (1955); p. 2151 - 2163 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.3.7.5, page 384 - 385 ; (from Gmelin) View in Reaxys

F O

Rx-ID: 26385489 View in Reaxys 228/751 Yield

Conditions & References in neat (no solvent), Irradiation (UV/VIS); oxidation at 30-40°C for 6.5 h;; turnover 98percent; Francis, W. C.; Haszeldine, R. N.; Journal of the Chemical Society; (1955); p. 2151 - 2163 View in Reaxys vol. C: MVol.D2; 4.3.3.3, page 377 - 378 ; (from Gmelin) View in Reaxys

Rx-ID: 26475531 View in Reaxys 229/751 Yield

Conditions & References in neat (no solvent), other Radiation; radiation of mixtures of CBr4 and CCl4 with Rn-α-rays at 18°C; mechanism discussed; Zimin, A. V.; Egorova, Z. S.; Sb. Rabot Radiats. Khim. Akad. Nauk SSSR; (1955); p. 241 - 248; C. A.; (1956); p. 4650 View in Reaxys vol. C: MVol.D2; 4.1.3.7.3, page 270 - 271 ; (from Gmelin) View in Reaxys

F O

Rx-ID: 26480350 View in Reaxys 230/751 Yield

Conditions & References in neat (no solvent), Irradiation (UV/VIS); UV-radiation for 6 hours; Francis, W. C.; Haszeldine, R. N.; Journal of the Chemical Society; (1955); p. 2151 - 2163 View in Reaxys vol. C: MVol.D2; 4.2.3.5.6, page 313 - 313 ; (from Gmelin) View in Reaxys

Na(x)O(x)P(x)

BrNa

– 4 Na + O

O–O– P

O P

O–

Rx-ID: 26560428 View in Reaxys 231/751

79/201

2017-08-09 05:21:10

Yield

Conditions & References With oxygen in neat (no solvent), Kinetics, at 500°C; increased decompn.-rate in presence of H2O; Hisar, R. S.; Bulletin de la Societe Chimique de France; (1955); p. 916 - 918 ; (from Gmelin) View in Reaxys With O2 in neat (no solvent), Kinetics, at 500°C; increased decompn.-rate in presence of H2O; vol. Na: SVol.4; 131, page 1648 - 1650 ; (from Gmelin) View in Reaxys

–O

Br( 1-)

Na(x)O(x)P(x)

O P

O–

O P

O–

Rx-ID: 26567459 View in Reaxys 232/751 Yield

Conditions & References With oxygen in neat (no solvent), Kinetics, with group I and group II halogenides at 550°C, react.-rate depending on cation; increase of decompn.-rate in presence of H2O; Hisar, R. S.; Bulletin de la Societe Chimique de France; (1955); p. 916 - 918 ; (from Gmelin) View in Reaxys With O2 in neat (no solvent), Kinetics, with group I and group II halogenides at 550°C, react.-rate depending on cation; increase of decompn.-rate in presence of H2O; vol. Na: SVol.4; 131, page 1648 - 1650 ; (from Gmelin) View in Reaxys F

O –O

Na +

+ F Na

O–

Rx-ID: 26448203 View in Reaxys 233/751 Yield

Conditions & References Hara; Cady; Journal of the American Chemical Society; vol. 76; (1954); p. 4285 ; (from Gmelin) View in Reaxys vol. Na: SVol.5; 8.1, page 1812 - 1817 ; (from Gmelin) View in Reaxys

Br2V

Rx-ID: 26637239 View in Reaxys 234/751 Yield

Conditions & References in neat (no solvent), thermal decompn.; Shchukarev, S. A.; Oranskaya, M. A.; Zhurnal Obshchei Khimii; vol. 24; (1954); p. 2109 - 2119; C. A.; (1956); p. 6110 ; (from Gmelin) View in Reaxys in neat (no solvent), thermal decompn.; vol. V: MVol.B1; 95, page 255 - 256 ; (from Gmelin) View in Reaxys

HO Br

N H

Rx-ID: 8213713 View in Reaxys 235/751 Yield

Conditions & References T= 0 °C , sowie bei 100grad, Kinetics

80/201

2017-08-09 05:21:10

Izumiya; Bulletin of the Chemical Society of Japan; vol. 26; (1953); p. 53,54 View in Reaxys

HO Br

H 2N

N H

Rx-ID: 8213727 View in Reaxys 236/751 Yield

Conditions & References T= 0 °C , sowie bei 100grad, Kinetics Izumiya; Bulletin of the Chemical Society of Japan; vol. 26; (1953); p. 53,54 View in Reaxys O (v7)

K+ O Mn O–

Br( 1-)

Rx-ID: 26109320 View in Reaxys 237/751 Yield

Conditions & References

pH >= 4, at 25°C , under CO2 Tolstikov, V. P.; Sb. Statei po Obshch. Khim. Akad. Nauk SSSR; vol. 2; (1953); p. 1249 - 1260 View in Reaxys vol. Mn: MVol.C2; 2.10.3.22.10.3, page 66 - 68 ; (from Gmelin) View in Reaxys O–

O O

3 Na + –O

P O

O P

BrNa

O O–

Rx-ID: 26097619 View in Reaxys 238/751 Yield

Conditions & References Hisar, R. S.; Bulletin de la Societe Chimique de France; (1952); p. 308 View in Reaxys vol. Na: SVol.6; 6.3.3, page 401 - 402 ; (from Gmelin) View in Reaxys

Rx-ID: 26463878 View in Reaxys 239/751 Yield

Conditions & References

0 %, 0 %

heating up to 70-80°C for some days, small amt. of Br2 formed vol. C: MVol.D3; 2.4.5, page 116 - 118 ; (from Gmelin) View in Reaxys

0 %, 0 %

heating up to 70-80°C for some days, small amt. of Br2 formed Hecht, H.; Greese, R.; Jander, G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 269; (1952); p. 262 278 ; (from Gmelin) View in Reaxys

I– (v2)

Br Br Br

P+ BrBr

Rx-ID: 26588688 View in Reaxys 240/751 Yield

Conditions & References in tetrachloromethane, dissociation;; detected by photometry;

81/201

2017-08-09 05:21:10

Popov; Schmorr; Journal of the American Chemical Society; vol. 74; (1952); p. 4672 ; (from Gmelin) View in Reaxys in tetrachloromethane, dissociation;; detected by photometry; vol. P: MVol.C; 232, page 531 - 533 ; (from Gmelin) View in Reaxys Br

Rx-ID: 7053972 View in Reaxys 241/751 Yield

Conditions & References bei Raumtemperatur Henne; Nager; Journal of the American Chemical Society; vol. 73; (1951); p. 1042 View in Reaxys Haszeldine; Journal of the Chemical Society; (1951); p. 2495,2503 View in Reaxys

F S

Rx-ID: 26619356 View in Reaxys 242/751 Yield

Conditions & References With H2O in neat (no solvent), small amount of water; Jonas, H.; Z. Anorg. Chem.; vol. 265; (1951); p. 273 - 283 View in Reaxys vol. S: MVol.B3; 160, page 1868 - 1870 View in Reaxys Jonas, H.; in: FIAT Review, Bd. 23, S. 193 ; (from Gmelin) View in Reaxys

F S

S F

Rx-ID: 26619357 View in Reaxys 243/751 Yield

Conditions & References With quartz in neat (no solvent), byproducts: SiF4; fast decompn. on heating to 340°C; Jonas, H.; Z. Anorg. Chem.; vol. 265; (1951); p. 273 - 283 View in Reaxys vol. S: MVol.B3; 160, page 1868 - 1870 View in Reaxys Jonas, H.; in: FIAT Review, Bd. 23, S. 193 ; (from Gmelin) View in Reaxys

Br+

F F Ta –F F F (v6)

Rx-ID: 26454310 View in Reaxys 244/751 Yield

Conditions & References With H2O, decompn. vol. Ta: MVol.B1; 7.1, page 159 - 161 View in Reaxys Gutmann, V.; Emeleus, H. J.; Journal of the Chemical Society; (1950); p. 1046 - 1050 ; (from Gmelin) View in Reaxys

82/201

2017-08-09 05:21:10

F Br+ F

F F NbF– F F (v6)

Rx-ID: 26456934 View in Reaxys 245/751 Yield

Conditions & References With H2O in water, byproducts: HF; decompn. in H2O; vol. Nb: MVol.B1; 112, page 240 - 242 View in Reaxys Gutmann, V.; Emeleus, H. J.; Journal of the Chemical Society; (1950); p. 1046 - 1050 ; (from Gmelin) View in Reaxys Br

Br2OV

BrOV

(v3)

Rx-ID: 26839157 View in Reaxys 246/751 Yield

Conditions & References in neat (no solvent), at 320°C in vacuum; Brewer, L.; Bromley, L. A.; Gilles, P. W.; Lofgren, N. L.; Natl. Nucl. Energy Ser. Div. IV; vol. 19 B; (1950); p. 76 192 View in Reaxys vol. V: MVol.B1; 97, page 258 - 260 ; (from Gmelin) View in Reaxys

methanol. NaOH

Rx-ID: 7054008 View in Reaxys 247/751 Yield

Conditions & References T= 70 °C , Electrolysis Brintzinger; Schneider; Zeitschrift fuer Elektrochemie und Angewandte Physikalische Chemie; vol. 53; (1949); p. 113 View in Reaxys

Br Cl

Br Se

Rx-ID: 7441577 View in Reaxys 248/751 Yield

Conditions & References Waermetoenung, Equilibrium constant McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys McCullough; Barsh; Journal of the American Chemical Society; vol. 71; (1949); p. 3029 View in Reaxys McCullough; Journal of the American Chemical Society; vol. 64; (1942); p. 2672,2674 View in Reaxys O

Br Cl Cl Br Cl

Rx-ID: 8213714 View in Reaxys 249/751 Yield

Conditions & References Newcomer; McBee; Journal of the American Chemical Society; vol. 71; (1949); p. 946,950 View in Reaxys

83/201

2017-08-09 05:21:10

Br Se

Rx-ID: 8213748 View in Reaxys 250/751 Yield

Conditions & References T= 25 °C , Gleichgewicht und Waermetoenung der Dissoziation McCullough; Barsh; Journal of the American Chemical Society; vol. 71; (1949); p. 3029 View in Reaxys Br Se

Rx-ID: 8213749 View in Reaxys 251/751 Yield

Conditions & References T= 25 °C , Gleichgewicht und Waermetoenung der Dissoziation McCullough; Barsh; Journal of the American Chemical Society; vol. 71; (1949); p. 3029 View in Reaxys

Br Cl

Br Se

Cl Cl

Rx-ID: 8213750 View in Reaxys 252/751 Yield

Conditions & References Campbell; McCullough; Journal of the American Chemical Society; vol. 67; (1945); p. 1965 View in Reaxys McCullough; Barsh; Journal of the American Chemical Society; vol. 71; (1949); p. 3029 View in Reaxys

Br Se

Cl Cl

Rx-ID: 8213751 View in Reaxys 253/751 Yield

Rx-ID: 8213754 View in Reaxys 254/751 Yield

Conditions & References T= 9 °C , Gleichgewicht der Dissoziation; sowie bei 25grad und 32grad McCullough; Barsh; Journal of the American Chemical Society; vol. 71; (1949); p. 3029 View in Reaxys

84/201

2017-08-09 05:21:10

phenyl-<4-chloro-phenyl>-selenide

Rx-ID: 8284937 View in Reaxys 255/751 Yield

Conditions & References McCullough; Barsh; Journal of the American Chemical Society; vol. 71; (1949); p. 3029 View in Reaxys

(v4)

O Cl

Ti ClCl

Rx-ID: 26108286 View in Reaxys 256/751 Yield

Conditions & References in sulfuryl dichloride, deposition of Br2; Hayek, E.; Engelbrecht, A.; Monatshefte fuer Chemie; vol. 80; (1949); p. 640 - 647 ; (from Gmelin) View in Reaxys in sulfuryl dichloride, deposition of Br2; vol. S: MVol.B1; 164, page 361 - 363 ; (from Gmelin) View in Reaxys

82Br 82Br

82Br (v2) Hg 82Br

Br2Hg

Rx-ID: 26167269 View in Reaxys 257/751 Yield

Conditions & References in carbon disulfide, below 0°C; 2.5min; Douglas, D. L.; Cooley, R. A.; Yost, D. M.; Journal of the American Chemical Society; vol. 71; (1949); p. 3238 3238 ; (from Gmelin) View in Reaxys in carbon disulfide, below 0°C; 2.5min; vol. Hg: MVol.B2; 186, page 790 - 792 ; (from Gmelin) View in Reaxys

(v4)

Ti BrBr

O–

O– S

Ti4+

Rx-ID: 26410823 View in Reaxys 258/751 Yield

Conditions & References in sulfuryl dichloride Hayek, E.; Engelbrecht, A.; Monatshefte fuer Chemie; vol. 80; (1949); p. 640 - 647 ; (from Gmelin) View in Reaxys in sulfuryl dichloride vol. Ti: MVol.; 5.7, page 324 - 332 ; (from Gmelin) View in Reaxys

KCl

Rx-ID: 7054005 View in Reaxys 259/751 Yield

Conditions & References T= 25 °C , Mechanism Schenkel; Schenkel-Rudin; Helvetica Chimica Acta; vol. 31; (1948); p. 517,520

85/201

2017-08-09 05:21:10

View in Reaxys Muus; Journal of Physical Chemistry; vol. 40; (1936); p. 123 View in Reaxys O

O O

Br O

O O

Rx-ID: 7054038 View in Reaxys 260/751 Yield

Conditions & References ein Gleichgewicht stellt sich Kobayashi; Nippon Kagaku Zasshi; vol. 69; (1948); p. 37; ; (1953); p. 2706 View in Reaxys

H H

Br H

O Br

Rx-ID: 8213708 View in Reaxys 261/751 Yield

Conditions & References T= 170 - 180 °C Inhoffen; Stoeck; Experientia; vol. 4; (1948); p. 426 View in Reaxys O

air Br

Rx-ID: 8213728 View in Reaxys 262/751 Yield

Conditions & References Elston; Peters; Rowe; Journal of the Chemical Society; (1948); p. 367,369 View in Reaxys

F Br

ClLi

FLi

Rx-ID: 26099448 View in Reaxys 263/751 Yield

Conditions & References

<1, <1

in neat (no solvent), large excess of BrF3 is added to LiCl (quartz vessel); reaction is complete by heating to 120°C after few min.;; impurities: traces of Cl2 and Br2; Sharpe, A. G.; Emeleeus, H. J.; Journal of the Chemical Society; (1948); p. 2135 - 2138 View in Reaxys vol. Li: SVol.; 71, page 305 - 307 ; (from Gmelin) View in Reaxys

alcoholic KOH

Rx-ID: 7053996 View in Reaxys 264/751 Yield

Conditions & References T= 15 - 18 °C Pesez; Annales Pharmaceutiques Francaises; vol. 5; (1947); p. 165; ; (1948); p. 514

86/201

2017-08-09 05:21:10

View in Reaxys –O

Ag+

Br Br

AgBr

Te BrBr

O– Te 2+

I O

(v0)

Rx-ID: 26451976 View in Reaxys 265/751 Yield

Conditions & References in benzene, at room temperature or in boiling benzene Montignie, E.; Bulletin de la Societe Chimique de France; (1947); p. 376 - 377 ; (from Gmelin) View in Reaxys in benzene, at room temperature or in boiling benzene vol. Ag: MVol.B2; 8.25.5.3, page 439 - 440 ; (from Gmelin) View in Reaxys Br

Br PBr Br

Cl Cl

P Cl

S Cl

P Br ClCl

P Br BrCl

P Br

Br Br

Rx-ID: 26455663 View in Reaxys 266/751 Yield

Conditions & References in neat (no solvent), passing a stream of H2S over a mixt. of PCl3 and PBr5;; product poluted with a small amount of bromine; removal of Br2 on shaking with Hg; fractionation at reduced pressure; Delwaulle, M.-L.; Francois, F.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 224; (1947); p. 1422 - 1423 View in Reaxys vol. P: MVol.C; 263, page 602 - 605 ; (from Gmelin) View in Reaxys

Br Br Br

Rx-ID: 26487115 View in Reaxys 267/751 Yield

Conditions & References in further solvent(s), Irradiation (UV/VIS); photolysis of liq. CBr4 in liq. Br2; mechanism discussed; Seely; Willard; Journal of the American Chemical Society; vol. 69; (1947); p. 2061 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.1.3.7.2, page 270 - 270 ; (from Gmelin) View in Reaxys

F F

Br F

Br Br

Rx-ID: 7053965 View in Reaxys 268/751 Yield

Conditions & References Brice; Pearlson; Simons; Journal of the American Chemical Society; vol. 68; (1946); p. 968 View in Reaxys Simons,J.H.; View in Reaxys

Br2Cd

BrCd

Rx-ID: 26185469 View in Reaxys 269/751 Yield

Conditions & References 1250°C Wieland, K.; Herzog, A.; Helvetica Chimica Acta; vol. 29; (1946); p. 1702 - 1717

87/201

2017-08-09 05:21:10

View in Reaxys vol. Cd: SVol.; 11.3.2, page 518 - 529 ; (from Gmelin) View in Reaxys Br

Br O

Rx-ID: 7916002 View in Reaxys 270/751 Yield

Conditions & References T= 25 °C , Gleichgewicht der Dissoziation; sowie bei 30.5grad McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys Br Se

Br Cl

Rx-ID: 7916003 View in Reaxys 271/751 Yield

Conditions & References T= 2 °C , sowie bei 25grad und 32grad; Gleichgewicht der Dissoziation McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys

Br Se

Br Cl

Rx-ID: 7916004 View in Reaxys 272/751 Yield

Conditions & References McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys

Br Cl

Br Se

Rx-ID: 7916008 View in Reaxys 273/751 Yield

Conditions & References T= 30 °C , Gleichgewicht der Dissoziation McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys Br O

2 Br

Br H

Br H 2N

(v3)

NH 2

Rx-ID: 8213720 View in Reaxys 274/751 Yield

Conditions & References T= 110 °C Henry; Journal of the Chemical Society; (1945); p. 870,871; Journal of the Chemical Society; (1946); p. 1156,1158 View in Reaxys

88/201

2017-08-09 05:21:10

Br Cl

Br Se

Br F

Rx-ID: 8213743 View in Reaxys 275/751 Yield

Conditions & References McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys Br

Rx-ID: 8213744 View in Reaxys 276/751 Yield

Conditions & References T= 25 °C , Gleichgewicht der Dissoziation; sowie bei 27.3grad McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys

Br Cl

Br Se

Br Br

Rx-ID: 8213746 View in Reaxys 277/751 Yield

Conditions & References McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys Br

Cl Cl

Rx-ID: 8213752 View in Reaxys 278/751 Yield

Conditions & References McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys Br

Rx-ID: 8213753 View in Reaxys 279/751 Yield

Conditions & References T= 29 °C , Gleichgewicht der Dissoziation McCullough; Eckerson; Journal of the American Chemical Society; vol. 67; (1945); p. 707 View in Reaxys Br O

2 Br

Br H

Br H 2N

(v3)

O NH

dihydrobromide

NH 2

Rx-ID: 8274652 View in Reaxys 280/751

89/201

2017-08-09 05:21:10

Yield

Conditions & References T= 200 °C Henry; Journal of the Chemical Society; (1945); p. 870,871; Journal of the Chemical Society; (1946); p. 1156,1158 View in Reaxys

potassium iodide

Rx-ID: 7054015 View in Reaxys 281/751 Yield

Conditions & References T= 85.4 °C , Kinetics Pressman; Young; Journal of the American Chemical Society; vol. 66; (1944); p. 705 View in Reaxys T= 74.9 °C , Kinetics Pressman; Young; Journal of the American Chemical Society; vol. 66; (1944); p. 705 View in Reaxys

Raney nickel

diluted NaOH

Rx-ID: 6680043 View in Reaxys 282/751 Yield

Conditions & References zuletzt bei 90-95grad Schwenk; Papa; Ginsberg; Industrial and Engineering Chemistry, Analytical Edition; vol. 15; (1943); p. 576 View in Reaxys Br Br

Br–

NH +4

N Br Br P N P N Br P Br Br Br

Br PBr Br Br

N Br

P Br N

PBr

BrP Br

Br P Br

Rx-ID: 26343645 View in Reaxys 283/751 Yield

Conditions & References in further solvent(s), react. of PBr5 with NH4Br in (CHCl2)2 under addn. of consumed NH4Br;; distg. off the solvent; recrystn. of the crystal mass from C6H6; formation of a mixt. of (NPBr2)3 and (NPBr2)4; isolation on sampling the crystals of each compound; Bode, H.; Z. Anorg. Chem.; vol. 252; (1943); p. 113 - 118 View in Reaxys vol. P: MVol.C; 247, page 564 - 567 ; (from Gmelin) View in Reaxys O OH

NaI

Rx-ID: 7054010 View in Reaxys 284/751 Yield

Conditions & References Lespagnol; Merville; Bulletin des Sciences Pharmacologiques; vol. 49; (1942); p. 71; ; (1944); p. 5495 View in Reaxys

90/201

2017-08-09 05:21:10

(+-)-2-bromo-2-phenyl-butyric acid-bromide

Rx-ID: 7916007 View in Reaxys 285/751 Yield

Conditions & References Phillips; Journal of the Chemical Society; (1942); p. 220,222 View in Reaxys -1 (v1)

Br( 1-)

(v7)

Mn OO

Rx-ID: 26414430 View in Reaxys 286/751 Yield

Conditions & References in not given, in acidic soln. Deniges, G.; Bull. Trav. Soc. Pharm. Bordeaux; vol. 80; (1942); p. 97 - 104 View in Reaxys vol. Mn: MVol.C2; 2.10.3.22.10.3, page 66 - 68 ; (from Gmelin) View in Reaxys

KO H

hydrogen

active coal

Rx-ID: 6681465 View in Reaxys 287/751 Yield

Conditions & References T= 425 °C Balandin; Patrikejew; Zhurnal Obshchei Khimii; vol. 11; (1941); p. 225,226; ; vol. 15; (1941); p. 281; ; (1941); p. 7937 View in Reaxys

carbon monoxide

Rx-ID: 6726890 View in Reaxys 288/751 Yield

Conditions & References λ=253.7mμ.Irradiation Gordon; Taylor; Journal of the American Chemical Society; vol. 63; (1941); p. 3435 View in Reaxys

C O

Rx-ID: 7072771 View in Reaxys 289/751 Yield

Conditions & References Belichtung (435.8 mμ) Tuttle; Rollefson; Journal of the American Chemical Society; vol. 63; (1941); p. 1525,1526 View in Reaxys O

Br HO Br

1.3.5.1'.3'.5'-hexabromo-4.4'-dioxo-2.2'-dimethyl-bi<cyclohexadien-(2.5)-yl>

Rx-ID: 8213741 View in Reaxys 290/751

91/201

2017-08-09 05:21:10

Yield

Conditions & References Aufbewahren in geschlossenem Gefaess Goldhahn; ; vol. 44; (1941); p. 244,245 View in Reaxys

Br P

(v1)

Rx-ID: 26469938 View in Reaxys 291/751 Yield

Conditions & References in neat (no solvent), reaction at high temperatures; Johnson, C. R.; Nunn, L. G.; Journal of the American Chemical Society; vol. 63; (1941); p. 141 - 143 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys

Br P

(v1)

O5P2

Rx-ID: 26469939 View in Reaxys 292/751 Yield

Conditions & References in neat (no solvent), explosive reaction; Johnson, C. R.; Nunn, L. G.; Journal of the American Chemical Society; vol. 63; (1941); p. 141 - 143 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys O O

Rx-ID: 5817693 View in Reaxys 293/751 Yield

Conditions & References T= 25 °C , Kinetics Altschul; Bartlett; Journal of Organic Chemistry; vol. 5; (1940); p. 623,628 View in Reaxys O

Rx-ID: 5861530 View in Reaxys 294/751 Yield

Conditions & References T= 25 °C , Equilibrium constant Altschul; Bartlett; Journal of Organic Chemistry; vol. 5; (1940); p. 623,628 View in Reaxys O Br

O O

Rx-ID: 7053995 View in Reaxys 295/751

92/201

2017-08-09 05:21:10

Yield

Conditions & References T= 25 °C , Gleichgewicht der Reaktion Altschul; Bartlett; Journal of Organic Chemistry; vol. 5; (1940); p. 623,628 View in Reaxys O

O O

Rx-ID: 7915999 View in Reaxys 296/751 Yield

Conditions & References T= 25 °C , Kinetics Altschul; Bartlett; Journal of Organic Chemistry; vol. 5; (1940); p. 623,628 View in Reaxys

Br( 1-)

(v4)

Rx-ID: 26069895 View in Reaxys 297/751 Yield

Conditions & References

>99

in not given, reaction in an acid soln., Br(1-) in excess; Taube, H.; Bray, W. C.; Journal of the American Chemical Society; vol. 62; (1940); p. 3357 - 3373 View in Reaxys vol. O: MVol.4; 86, page 1172 - 1173 ; (from Gmelin) View in Reaxys

O S

BrK

K+

–O

S OO

S – OO

Rx-ID: 26097321 View in Reaxys 298/751 Yield

Conditions & References 20°C vol. S: SVol.3; 3.1.7.6.3.2, page 307 - 309 ; (from Gmelin) View in Reaxys 20°C Fioretti, M.; Croatto, U.; Gazzetta Chimica Italiana; vol. 70; (1940); p. 850 - 854 ; (from Gmelin) View in Reaxys

Br3O8

Rx-ID: 26300653 View in Reaxys 299/751 Yield

Conditions & References in neat (no solvent), decompn. above -40 °C; Mungen, R.; Spinks, J. W. T.; Canadian Journal of Research, Section B: Chemical Sciences; vol. 18; (1940); p. 363 - 371 View in Reaxys vol. O: MVol.4; 23, page 1037 - 1038 ; (from Gmelin) View in Reaxys

O –O

Na +

Rx-ID: 26439299 View in Reaxys 300/751 Yield

Conditions & References Fredenhagen, K.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 242; (1939); p. 23 - 32 ; (from Gmelin)

93/201

2017-08-09 05:21:10

View in Reaxys vol. Na: SVol.5; 8.1, page 1812 - 1817 ; (from Gmelin) View in Reaxys F Br PBr Br

Rx-ID: 26453815 View in Reaxys 301/751 Yield

Conditions & References in neat (no solvent), loss of Br2 on heating; Booth, H. S.; Frary, S. G.; Journal of the American Chemical Society; vol. 61; (1939); p. 2934 - 2937 View in Reaxys vol. P: MVol.C; 222, page 509 - 511 ; (from Gmelin) View in Reaxys

F Br PBr Br

Rx-ID: 26453931 View in Reaxys 302/751 Yield

Br 2 O–

2 O

Hg 2+

O– O

Hg 2+

Br Br

Rx-ID: 26469375 View in Reaxys 303/751 Yield

Conditions & References Pierron, P.; Bull. Soc. Chim. France (5); vol. 6; (1939); p. 1047 - 1051 ; (from Gmelin) View in Reaxys vol. Hg: MVol.B2; 196, page 812 - 814 ; (from Gmelin) View in Reaxys

Cl O

Rx-ID: 26480354 View in Reaxys 304/751 Yield

Conditions & References in neat (no solvent), Kinetics, Irradiation (UV/VIS); oxydation in the presence of O2 by irradiation (3130 and 4358Å); mechanism discussed; Franke, W.; Schumacher, H.-J.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 42; (1939); p. 297 - 323 View in Reaxys vol. C: MVol.D2; 4.2.8.5.5, page 346 - 346 ; (from Gmelin) View in Reaxys Ba2+ F 2 F (v4) Br– F FSP-4

Rx-ID: 26585920 View in Reaxys 305/751 Yield

Conditions & References With water in water, decomposition with H2O under formation of Br2 and O2 and an oxybromic acid in solution; Pierron, P.; Bulletin de la Societe Chimique de France; vol. 6; (1939); p. 1051 - 1054 ; (from Gmelin)

94/201

2017-08-09 05:21:10

View in Reaxys With oxybromic acid, H2O in water, decomposition with H2O under formation of Br2 and O2 and an oxybromic acid in solution; vol. Ba: SVol.; 113, page 390 - 392 ; (from Gmelin) View in Reaxys

Br O– Hg 2+

Br–

HgO

Rx-ID: 26600738 View in Reaxys 306/751 Yield

Conditions & References product depending on conditions Lemarchands, M.; Pierron, P.; Bulletin de la Societe Chimique de France; vol. 4; (1937); p. 1773 - 1783 View in Reaxys Pierron, P.; Bulletin de la Societe Chimique de France; vol. 6; (1939); p. 791 - 793 View in Reaxys Lemarchands, M.; Pierron, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 204; (1937); p. 1946 - 1948 ; (from Gmelin) View in Reaxys vol. Hg: MVol.B1; 2.1, page 40 - 54 ; (from Gmelin) View in Reaxys

Rx-ID: 7053968 View in Reaxys 307/751 Yield

Conditions & References am Licht Lecomte; Volkringer; Tchakirian; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 204; (1937); p. 1927 View in Reaxys Volkringer; Lecomte; Tchakirian; Journal de Physique et le Radium; vol. <7>9; p. 105; Chem. Zentralbl.; vol. 109; nb. II; (1938); p. 4210 View in Reaxys in neat (no solvent), elimination of Br2 in the day light; turning yellow; Lecomte, J.; Volkringer, H.; Tchakirian, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 204; (1937); p. 1927 - 1929 View in Reaxys Lecomte, J.; Volkringer, H.; Tchakirian, A.; J. Phys. Radium (7); vol. 9; (1938); p. 105 - 108 View in Reaxys vol. C: MVol.D2; 4.2.10.3, page 351 - 351 ; (from Gmelin) View in Reaxys HO

O O

Rx-ID: 7054046 View in Reaxys 308/751 Yield

Conditions & References des ein kristallines Dibromid liefert bei 25grad Borek; Clarke; Journal of Biological Chemistry; vol. 125; (1938); p. 483 View in Reaxys

95/201

2017-08-09 05:21:10

ethanolic AgNO3-solution

O Br

Rx-ID: 7441574 View in Reaxys 309/751 Yield

Conditions & References Koelsch; Hochman; Journal of Organic Chemistry; vol. 3; (1938); p. 503 View in Reaxys

AgBr

AgCl

Rx-ID: 26096268 View in Reaxys 310/751 Yield

Conditions & References With chlorine, Kinetics, equil. reaction at 500 or 800°C vol. Ag: MVol.B2; 7.2.8.5.2, page 112 - 113 ; (from Gmelin) View in Reaxys With Cl2, Kinetics, equil. reaction at 500 or 800°C Schuetza, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 239; (1938); p. 245 - 256 ; (from Gmelin) View in Reaxys O–

Br( 1-)

O Cr(v6) Cr O

(v6)

O–

Rx-ID: 26109301 View in Reaxys 311/751 Yield

Conditions & References With sulfuric acid Lang, R.; Microchimica Acta; vol. 3; (1938); p. 116 - 125 ; (from Gmelin) View in Reaxys With H2SO4, TeO3 vol. Cr: MVol.A2; 7.5, page 680 - 710 ; (from Gmelin) View in Reaxys

Rx-ID: 7053967 View in Reaxys 312/751 Yield

Conditions & References am Licht Lecomte; Volkringer; Tchakirian; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 204; (1937); p. 1927 View in Reaxys in neat (no solvent), Irradiation (UV/VIS); elimination of Br2 in light; Lecomte, J.; Volkringer, H.; Tchakirian, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 204; (1937); p. 1927 - 1929 View in Reaxys vol. C: MVol.D2; 4.3.5.5, page 381 - 382 ; (from Gmelin) View in Reaxys

Rx-ID: 7053969 View in Reaxys 313/751 Yield

Conditions & References D'Alelio; Reid; Journal of the American Chemical Society; vol. 59; (1937); p. 110

96/201

2017-08-09 05:21:10

View in Reaxys O

OH O

Br O

racemate

Rx-ID: 7054006 View in Reaxys 314/751 Yield

Conditions & References Larsson; Svensk Kemisk Tidskrift; vol. 49; (1937); p. 270; Chem. Zentralbl.; vol. 109; nb. II; (1938); p. 2596 View in Reaxys

Br O

OH HO

S OO

C O

SO2

Rx-ID: 7086657 View in Reaxys 315/751 Yield

Conditions & References T= 160 °C , Prod.5:CO2 Senderens; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 204; (1937); p. 210,211 View in Reaxys Cl

Br Cl

Rx-ID: 8213712 View in Reaxys 316/751 Yield

Conditions & References Umkrystallisieren Ross; Fuson; Journal of the American Chemical Society; vol. 59; (1937); p. 1508 View in Reaxys

NaI

racemate

Rx-ID: 8213731 View in Reaxys 317/751 Yield

Conditions & References Davis; Heggie; Journal of Organic Chemistry; vol. 2; (1937); p. 471,474,475 View in Reaxys -1

Br Br

(v2)

Br( 1-)

Rx-ID: 26483820 View in Reaxys 318/751 Yield

Conditions & References in not given, Kinetics vol. O: MVol.6; 74, page 1996 - 1998 ; (from Gmelin) View in Reaxys

97/201

2017-08-09 05:21:10

in not given, Kinetics Abel, E.; Fabian, F.; Monatshefte fuer Chemie; vol. 71; (1937); p. 241 - 250 ; (from Gmelin) View in Reaxys Cl

LiBr

Rx-ID: 6680041 View in Reaxys 319/751 Yield

Conditions & References zur analogen Reaktion mit NaI in Aceton Perret; Perrot; Biechler; Bulletin de la Societe Chimique de France; vol. <5>3; (1936); p. 350 View in Reaxys Perret; Perrot; Bulletin de la Societe Chimique de France; vol. <5> 1; (1934); p. 1531,1548 View in Reaxys O

O Cl

NaBr

C O

Rx-ID: 6727569 View in Reaxys 320/751 Yield

Conditions & References Geschwindigkeit Perret; Biechler; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 203; (1936); p. 85 View in Reaxys

Cl O

NaBr

Rx-ID: 7054009 View in Reaxys 321/751 Yield

Conditions & References Geschwindigkeit der Abscheidung Perret; Biechler; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 203; (1936); p. 85 View in Reaxys

O Cl

NaBr

C O

Rx-ID: 7072772 View in Reaxys 322/751 Yield

Conditions & References T= 20 °C , Geschwindigkeit Perret; Biechler; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 203; (1936); p. 85 View in Reaxys

N O

H N

Rx-ID: 7918949 View in Reaxys 323/751 Yield

Conditions & References T= 15 °C , Gleichgewicht der Reaktion Bell; Journal of the Chemical Society; (1936); p. 1156 View in Reaxys

98/201

2017-08-09 05:21:10

Br2Hg

HgO

Rx-ID: 26124674 View in Reaxys 324/751 Yield

Conditions & References at 200-300°C;; Br2 frozen out; Roginskii, S.; Shekhter, A.; Acta Physicochimica URSS; vol. 3; (1935); p. 219 - 222 View in Reaxys Roginskii, S.; Shekhter, A.; Zhurnal Fizicheskoi Khimii; vol. 7; (1936); p. 179 - 181 ; (from Gmelin) View in Reaxys at 200-300°C;; Br2 frozen out; vol. Hg: MVol.B2; 169, page 755 - 757 ; (from Gmelin) View in Reaxys Br

Br4Cl 4Ti

Rx-ID: 26310473 View in Reaxys 325/751 Yield

Conditions & References heating Lutschinsky, G. P.; Z. Anorg. Chem.; vol. 224; (1935); p. 420 - 426 View in Reaxys Lutschinsky, G. P.; Zhurnal Obshchei Khimii; vol. 6; (1936); p. 439 - 443 ; (from Gmelin) View in Reaxys With H2O Lutschinsky, G. P.; Z. Anorg. Chem.; vol. 224; (1935); p. 420 - 426 View in Reaxys Lutschinsky, G. P.; Zhurnal Obshchei Khimii; vol. 6; (1936); p. 439 - 443 ; (from Gmelin) View in Reaxys vol. Ti: MVol.; 5.7, page 324 - 332 ; (from Gmelin) View in Reaxys With H2O vol. Ti: MVol.; 5.7, page 324 - 332 ; (from Gmelin) View in Reaxys

Cl BrLi

ClLi

Rx-ID: 26395446 View in Reaxys 326/751 Yield

Conditions & References in acetone Perret, A.; Perrot, R.; Biechler, J.; Bull. Soc. Chim. France (5); vol. 3; (1936); p. 349 - 350 View in Reaxys vol. C: MVol.D3; 2.2.8.7.3, page 98 - 100 ; (from Gmelin) View in Reaxys Br

Br 2 Br

H Br

O N S

air

compound C17H15BrN2OS+Br3+HBr

Rx-ID: 8272119 View in Reaxys 327/751

99/201

2017-08-09 05:21:10

Yield

Conditions & References Ahmad; Desai; Hunter; Journal of the Indian Chemical Society; vol. 12; (1935); p. 237,244 View in Reaxys K+

O Br O

Cr 2O3

O–

Rx-ID: 26360471 View in Reaxys 328/751 Yield

Conditions & References in water, byproducts: K2Cr2O7, CrO3; anhydrous Cr2O3; slowly at 18 °C, quickly at 100 °C Lyden, R.; Z. Anorg. Chem.; vol. 223; (1935); p. 28 ; (from Gmelin) View in Reaxys in water, byproducts: K2Cr2O7, CrO3; anhydrous Cr2O3; slowly at 18 °C, quickly at 100 °C vol. K: MVol.3; 1.6.3, page 582 - 586 ; (from Gmelin) View in Reaxys H

Br Ir Br

(v3)

Rx-ID: 26391631 View in Reaxys 329/751 Yield

Conditions & References

in water Delepine-Tard, M.; Annales de Chimie (Cachan, France); vol. 4; (1935); p. 284 - 285 ; (from Gmelin) View in Reaxys

in water Krauss, F.; Gerlach, H.; Z. Anorg. Chem.; vol. 147; (1925); p. 269 - 283 View in Reaxys vol. Ir: MVol.; 5.6, page 71 - 73 ; (from Gmelin) View in Reaxys in water, by heating with chlorine water Birnbaum, C.; Liebigs Annalen der Chemie; vol. 133; (1865); p. 166 - 167 View in Reaxys vol. Ir: MVol.; 5.6, page 71 - 73 ; (from Gmelin) View in Reaxys

O N

Rx-ID: 26517820 View in Reaxys 330/751 Yield

Conditions & References Gleu, K.; Hubold, R.; Z. Anorg. Chem.; vol. 223; (1935); p. 309 - 315 View in Reaxys Raschig, F.; Angewandte Chemie; vol. 17; (1904); p. 1419 View in Reaxys Raschig, F.; Ber.; vol. 40; (1907); p. 4585 View in Reaxys vol. N: MVol.4; 6.7, page 941 - 942 ; (from Gmelin) View in Reaxys

100/201

2017-08-09 05:21:10

4 K+ Br Br

(v2)

4Br RhBr RhBr Br Br (v6) Br (v6) (v2) Br Br

Rx-ID: 26586880 View in Reaxys 331/751 Yield

Conditions & References in neat (no solvent), decomposition with evolution of Br2 >120°C; Poulenc, P.; Annales de Chimie (Cachan, France); vol. 4; (1935); p. 581 - 581 ; (from Gmelin) View in Reaxys in neat (no solvent), decomposition with evolution of Br2 >120°C; vol. Rh: MVol.; 32, page 80 - 81 ; (from Gmelin) View in Reaxys

O Cl

O S

Cl Cl

LiBr

Rx-ID: 6680042 View in Reaxys 332/751 Yield

Conditions & References Perret; Perrot; Bulletin de la Societe Chimique de France; vol. <5> 1; (1934); p. 1531,1548 View in Reaxys

Br Br

diluted NaOH

Br Br

Rx-ID: 7054034 View in Reaxys 333/751 Yield

Conditions & References Kinetics Taylor; Ward; Journal of the Chemical Society; (1934); p. 2007 View in Reaxys

BrLi

Rx-ID: 26097473 View in Reaxys 334/751 Yield

Conditions & References in acetone, byproducts: bromoacetone Perret, A.; Perrot, R.; Bulletin de la Societe Chimique de France; vol. 1; (1934); p. 1531 - 1548 ; (from Gmelin) View in Reaxys in acetone, byproducts: bromoacetone vol. S: MVol.B3; 115, page 1776 - 1778 ; (from Gmelin) View in Reaxys

Br2Cu

BrCu

Rx-ID: 26185493 View in Reaxys 335/751 Yield

Conditions & References in water, on boiling, concd. aq. soln., pptn. on dilution; Riley, H. L.; Smith, H. C.; Journal of the Chemical Society; (1934); p. 1448 - 1449 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: Cu-oxide bromide; on heating in the air; Rammelsberg, C.; Annalen der Physik (Weinheim, Germany); vol. 55; (1842); p. 237 - 253 ; (from Gmelin) View in Reaxys

101/201

2017-08-09 05:21:10

in neat (no solvent), decompn. on heating, equilibrium at temperatures higher than 250°C; Jackson, C. G.; Journal of the Chemical Society; vol. 99; (1911); p. 1066 - 1071 ; (from Gmelin) View in Reaxys in neat (no solvent), on heating to temperatures lower than red heat; Berthemot; Ann. Chim. Phys.; vol. 44; (1830); p. 382 - 396 ; (from Gmelin) View in Reaxys in neat (no solvent), decompn. on heating, equilibrium at temperatures higher than 250°C; vol. Cu: MVol.B1; 167, page 369 - 371 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: Cu-oxide bromide; on heating in the air; vol. Cu: MVol.B1; 167, page 369 - 371 ; (from Gmelin) View in Reaxys in neat (no solvent), on heating to temperatures lower than red heat; vol. Cu: MVol.B1; 167, page 369 - 371 ; (from Gmelin) View in Reaxys in water, on boiling, concd. aq. soln., pptn. on dilution; vol. Cu: MVol.B1; 169, page 373 - 375 ; (from Gmelin) View in Reaxys Br (v5)

Br PaBr Br

Rx-ID: 26477679 View in Reaxys 336/751 Yield

Conditions & References in neat (no solvent), decompn. of the halogenide on a electrically heated tungsten wire in high vacuum (10E-6 10E-5 mm Hg);; layer of Pa on tungsten formed; Grosse, A. v.; Journal of the American Chemical Society; vol. 56; (1934); p. 2200 - 2200 ; (from Gmelin) View in Reaxys in neat (no solvent), decompn. of the halogenide on a electrically heated tungsten wire in high vacuum (10E-6 10E-5 mm Hg);; layer of Pa on tungsten formed; Grosse, A. v.; Science (Washington, DC, United States); vol. 80; (1934); p. 513 - 513 View in Reaxys vol. Pa: MVol.; 10, page 36 - 43 ; (from Gmelin) View in Reaxys

Rx-ID: 7053974 View in Reaxys 337/751 Yield

Conditions & References in halbneutralisierter Loesung Larsson; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 165; (1933); p. 56,59 View in Reaxys

alkali chloride

Rx-ID: 7053998 View in Reaxys 338/751

102/201

2017-08-09 05:21:10

Yield

Conditions & References Larsson; Zeitschrift fuer Physikalische Chemie, Abteilung A: Chemische Thermodynamik, Kinetik, Elektrochemie, Eigenschaftslehre; vol. 165; (1933); p. 56,59 View in Reaxys

AgBr

Br Br

AgCl

Rx-ID: 26096362 View in Reaxys 339/751 Yield

Conditions & References in melt Jellinek, K.; Weberbauer, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 212; (1933); p. 337 - 355 View in Reaxys vol. Ag: MVol.B1; 6.2.3.9, page 381 - 381 ; (from Gmelin) View in Reaxys O I

Br( 1-)

O–

Br Br

Rx-ID: 26414419 View in Reaxys 340/751 Yield

Conditions & References With hydrogen cation in water, byproducts: H2O; equilibrium; Schwicker, A.; Schay, G.; Z. phys. Ch.; vol. 122; (1926); p. 482 - 482 View in Reaxys vol. I: MVol.2; 147, page 572 - 573 ; (from Gmelin) View in Reaxys With hydrogen cation in water, byproducts: H2O; equilibrium at 25°C observed; Schwicker, A.; Schay, G.; Z. phys. Ch.; vol. 122; (1926); p. 482 - 482 View in Reaxys vol. I: MVol.2; 147, page 572 - 573 ; (from Gmelin) View in Reaxys With hydrogen cation in water, byproducts: H2O; equilibrium discussed; Schulek; Zeitschrift fuer Analytische Chemie; vol. 66; nb. 4-5; (1925); p. 161 - 169 View in Reaxys Skopintzew, B. A.; Zeitschrift fuer Analytische Chemie; vol. 92; (1933); p. 178 - 178 View in Reaxys vol. I: MVol.2; 147, page 572 - 573 ; (from Gmelin) View in Reaxys With hydrogen cation in water, Kinetics, byproducts: H2O; equilibrium; Skrabal, A.; Rieder, R.; Zeitschrift fuer Elektrochemie; vol. 30; (1924); p. 115 - 115 View in Reaxys Skrabal, A.; Rieder, R.; Zeitschrift fuer Elektrochemie; vol. 30; (1924); p. 121 - 121 View in Reaxys Skrabal, A.; Rieder, R.; Zeitschrift fuer Elektrochemie; vol. 30; (1924); p. 123 - 123 View in Reaxys vol. I: MVol.2; 147, page 572 - 573 View in Reaxys vol. I: MVol.2; 148, page 574 - 576 ; (from Gmelin) View in Reaxys

O Br O

K+ Se

O–

Rx-ID: 26420250 View in Reaxys 341/751 Yield

Conditions & References in water, redn.

103/201

2017-08-09 05:21:10

Montignie, E.; Bulletin de la Societe Chimique de France; vol. 53; (1933); p. 1392 - 1392 ; (from Gmelin) View in Reaxys in water, redn. vol. K: MVol.3; 1.6.3, page 582 - 586 ; (from Gmelin) View in Reaxys O (v6)

O2Re

Re BrBr

Rx-ID: 26453697 View in Reaxys 342/751 Yield

Conditions & References in neat (no solvent), decompn. on heating above 100 °C in N2; Brukl, A.; Ziegler, K.; Monatshefte fuer Chemie; vol. 63; (1933); p. 331 - 331 ; (from Gmelin) View in Reaxys in neat (no solvent), decompn. on heating above 100 °C in N2; vol. Re: MVol.; 32, page 115 - 116 ; (from Gmelin) View in Reaxys K+

Br – I (v2)

–O

(v4)

O K+

Rx-ID: 26548601 View in Reaxys 343/751 Yield

Conditions & References in neat (no solvent), byproducts: KBr, IBr Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 182 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: KBr, IBr Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 183 - 183 View in Reaxys vol. I: MVol.2; 76, page 415 - 417 ; (from Gmelin) View in Reaxys

K+

Br –I

(v2)

Cl (v2)

K+

–I

Rx-ID: 26604565 View in Reaxys 344/751 Yield

Conditions & References With chlorine Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 182 View in Reaxys Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 184 ; (from Gmelin) View in Reaxys With chlorine, mechanism discussed; Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 182 ; (from Gmelin) View in Reaxys With Cl2 vol. K: MVol.3; 2.6, page 660 - 667 ; (from Gmelin) View in Reaxys With Cl2, mechanism discussed; Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 183 - 183

104/201

2017-08-09 05:21:10

View in Reaxys vol. I: MVol.2; 76, page 415 - 417 ; (from Gmelin) View in Reaxys –O

K+

Br –I

(v2)

O K+

Rx-ID: 26604566 View in Reaxys 345/751 Yield

Conditions & References With ozone Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 182 View in Reaxys Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 184 ; (from Gmelin) View in Reaxys With O3 vol. K: MVol.3; 2.6, page 660 - 667 ; (from Gmelin) View in Reaxys -1

(v2)

air

As +

Rx-ID: 8213729 View in Reaxys 346/751 Yield

Conditions & References Capatos; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 194; (1932); p. 1658 View in Reaxys 2 H+ Br 2Br OsBr Br Br (v6)

O (v8)

O Os

Rx-ID: 26166380 View in Reaxys 347/751 Yield

Conditions & References in water, byproducts: H2O; equilibrium depends on HBr-concentration; Crowell, W. R.; Kirschman, H. D.; Journal of the American Chemical Society; vol. 51; (1929); p. 1696 - 1699 View in Reaxys Crowell, W. R.; Journal of the American Chemical Society; vol. 54; (1932); p. 1324 - 1324 ; (from Gmelin) View in Reaxys in water, byproducts: H2O; equilibrium depends on HBr-concentration; vol. Os: MVol.; 24, page 43 - 45 ; (from Gmelin) View in Reaxys

Br2Hg

2 O

O– O

Hg 2+

Rx-ID: 26185525 View in Reaxys 348/751 Yield

Conditions & References in nitric acid, Electrolysis; anodic oxidation with Pt electrodes; 125V, 0.3A, ambient temp.; Illari, G.; Gazzetta Chimica Italiana; vol. 62; (1932); p. 1166 - 1176 ; (from Gmelin) View in Reaxys in nitric acid, Electrolysis; 12h; anodic oxidation at ambient temp., 125V, 0.3A; Illari, G.; Gazzetta Chimica Italiana; vol. 62; (1932); p. 1166 - 1176 ; (from Gmelin) View in Reaxys in nitric acid, Electrolysis; anodic oxidation with Pt electrodes; 125V, 0.3A, ambient temp.;

105/201

2017-08-09 05:21:10

vol. Hg: MVol.B2; 169, page 755 - 757 ; (from Gmelin) View in Reaxys in nitric acid, Electrolysis; 12h; anodic oxidation at ambient temp., 125V, 0.3A; vol. Hg: MVol.B2; 196, page 812 - 814 ; (from Gmelin) View in Reaxys Br Te

(v1)

Te Te

(v1)

Rx-ID: 26385000 View in Reaxys 349/751 Yield

Conditions & References in neat (no solvent), decomposition above 750°C; Yost, D. M.; Hatcher, J. B.; Journal of the American Chemical Society; vol. 54; (1932); p. 152 - 152 View in Reaxys vol. Te: MVol.; 103, page 337 - 340 ; (from Gmelin) View in Reaxys -1

Br I

Br Br

(v2)

O–

Rx-ID: 26405398 View in Reaxys 350/751 Yield

Conditions & References

With potassium permanganate in water, acidic soln.; Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1932); p. 2037 - 2037 View in Reaxys vol. I: MVol.2; 82, page 427 - 429 ; (from Gmelin) View in Reaxys -1

Br I

(v2)

Br Br

O–

Rx-ID: 26405399 View in Reaxys 351/751 Yield

Conditions & References With water, chlorine in water, passing chlorine through IBr2(1-)-soln.; Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1932); p. 2037 - 2037 View in Reaxys vol. I: MVol.2; 82, page 427 - 429 ; (from Gmelin) View in Reaxys

Br (v4)

Ti BrBr

O2Ti

Rx-ID: 26483556 View in Reaxys 352/751 Yield

Conditions & References With HNO3, byproducts: NO2; concd. HNO3 Olsen, J. C.; Ryan, E. P.; Journal of the American Chemical Society; vol. 54; (1932); p. 2215 - 2218 ; (from Gmelin) View in Reaxys With HNO3 vol. Ti: MVol.; 5.7, page 324 - 332 ; (from Gmelin) View in Reaxys

Br Te Br BrBr

Br Te

Rx-ID: 26518845 View in Reaxys 353/751

106/201

2017-08-09 05:21:10

Yield

Conditions & References

>99, >99

in neat (no solvent), complete dissociation at 600°C; Yost, D. M.; Hatcher, J. B.; Journal of the American Chemical Society; vol. 54; (1932); p. 153 - 153 View in Reaxys vol. Te: MVol.; 105, page 342 - 344 ; (from Gmelin) View in Reaxys in melt, partial decompn. on melting at ambient pressure; Brauner, B.; Journal of the Chemical Society; vol. 55; (1889); p. 396 - 396 View in Reaxys Brauner, B.; Monatshefte fuer Chemie; vol. 10; (1889); p. 432 - 432 View in Reaxys vol. Te: MVol.; 105, page 342 - 344 ; (from Gmelin) View in Reaxys in neat (no solvent), investigation of dissociation at temp. between 432 and 1034°C; Yost, D. M.; Hatcher, J. B.; Journal of the American Chemical Society; vol. 54; (1932); p. 153 - 153 View in Reaxys vol. Te: MVol.; 105, page 342 - 344 ; (from Gmelin) View in Reaxys in neat (no solvent), partial decompn. on distillation at ambient pressure; Brauner, B.; Journal of the Chemical Society; vol. 55; (1889); p. 396 - 396 View in Reaxys Brauner, B.; Monatshefte fuer Chemie; vol. 10; (1889); p. 432 - 432 View in Reaxys vol. Te: MVol.; 105, page 342 - 344 ; (from Gmelin) View in Reaxys

Br Br

As HO

S OO

Rx-ID: 7053976 View in Reaxys 354/751 Yield

Conditions & References Dyke; Davies; Jones; Journal of the Chemical Society; (1931); p. 187 View in Reaxys

Br Br

O N

Rx-ID: 7053985 View in Reaxys 355/751 Yield

Conditions & References Dyke; Davies; Jones; Journal of the Chemical Society; (1931); p. 187 View in Reaxys

Br Br

Rx-ID: 7053987 View in Reaxys 356/751 Yield

Conditions & References Dyke; Davies; Jones; Journal of the Chemical Society; (1931); p. 187 View in Reaxys

107/201

2017-08-09 05:21:10

NH4Br

Rx-ID: 7082269 View in Reaxys 357/751 Yield

Conditions & References T= 90 °C , unter Atmosphaerendruck Birckenbach; Sennewald; Justus Liebigs Annalen der Chemie; vol. 489; (1931); p. 22; Chemische Berichte; vol. 65; (1932); p. 550,551 View in Reaxys

(v4)

Rx-ID: 26070072 View in Reaxys 358/751 Yield

Conditions & References in neat (no solvent), reaction with detonation at -104 °C, mechanism discussed (chain reaction); Lewis, B.; Feitknecht, W.; Journal of the American Chemical Society; vol. 53; (1931); p. 3565 - 3566 View in Reaxys vol. O: MVol.4; 79, page 1157 - 1160 ; (from Gmelin) View in Reaxys

H HO

S OO

Rx-ID: 26342901 View in Reaxys 359/751 Yield

Conditions & References in sulfuric acid, ambient temp. Gleu, K.; Z. Anorg. Chem.; vol. 195; (1931); p. 61 - 74 ; (from Gmelin) View in Reaxys Br

Ag+

Br N–

(v3)

Rx-ID: 26445813 View in Reaxys 360/751 Yield

Conditions & References above 150°C Pohland, E.; Z. Anorg. Chem.; vol. 201; (1931); p. 282 - 288 View in Reaxys vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys

F F F Br

Rx-ID: 26518615 View in Reaxys 361/751 Yield

Conditions & References With H2O Ruff, O.; Menzel, W.; Z. Anorg. Chem.; vol. 202; (1931); p. 49 - 58 View in Reaxys vol. Br: MVol.; 13.2, page 337 - 342 ; (from Gmelin) View in Reaxys

B (v1) Br Ag Br

Rx-ID: 26734904 View in Reaxys 362/751

108/201

2017-08-09 05:21:10

Yield

Conditions & References in neat (no solvent), heating at 150°C; Pohland, E.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 201; (1931); p. 282 - 288 View in Reaxys vol. Ag: MVol.B3; 16.4.10, page 319 - 319 ; (from Gmelin) View in Reaxys

Br Al

potassium bromide

Rx-ID: 5817700 View in Reaxys 363/751 Yield

Conditions & References Platin-Elektroden.Electrolysis Plotnikow; Kikez; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 47; (1930); p. 1005,220 View in Reaxys

copper-zinc

Rx-ID: 7054002 View in Reaxys 364/751 Yield

Conditions & References Landa; Landova; Collection of Czechoslovak Chemical Communications; vol. 2; (1930); p. 32; Chemicke Listy; vol. 24; (1930); p. 221; Chem. Zentralbl.; vol. 101; nb. II; (1930); p. 543 View in Reaxys

OH H 2N 2

Br O

Rx-ID: 7060067 View in Reaxys 365/751 Yield

Conditions & References Grard; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 190; (1930); p. 187; Annales de Chimie (Cachan, France); vol. <10>13; (1930); p. 363 View in Reaxys

Br O

H 2N 2

Rx-ID: 7060068 View in Reaxys 366/751 Yield

Cr2O3-H2SO4

Br O

H 2N 2

Rx-ID: 7060069 View in Reaxys 367/751 Yield

sulfate permanganate

Br O

H 2N 2

Rx-ID: 7060070 View in Reaxys 368/751

109/201

2017-08-09 05:21:10

Yield

S OO

(v1)

Cu 2+ S O O

K2S2O8

KMnO4

Rx-ID: 7441575 View in Reaxys 369/751 Yield

Conditions & References Thompson; Oakdale; Journal of the American Chemical Society; vol. 52; (1930); p. 1195,1198 View in Reaxys

F F F F I F F

BrK

Rx-ID: 26097374 View in Reaxys 370/751 Yield

Conditions & References warming Ruff, O.; Keim, R.; Z. Anorg. Chem.; vol. 193; (1930); p. 186 ; (from Gmelin) View in Reaxys vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys

Br(x)O(x)

Rx-ID: 26153960 View in Reaxys 371/751 Yield

Conditions & References in neat (no solvent) Lewis, B.; Schumacher, H. -J.; Nature (London, United Kingdom); vol. 125; (1930); p. 129 View in Reaxys Lewis, B.; Schumacher, H.-J.; Zeitschrift fuer Elektrochemie; vol. 35; (1929); p. 648 - 652 View in Reaxys Lewis, B.; Schumacher, H.-J.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 6; (1929); p. 423 - 440 View in Reaxys vol. O: MVol.4; 14, page 1014 - 1017 ; (from Gmelin) View in Reaxys

Br3O8

Rx-ID: 26300652 View in Reaxys 372/751 Yield

Conditions & References With ozone, Kinetics, byproducts: O2 Lewis, B.; Schumacher, H. -J.; Z. Anorg. Chem.; vol. 182; (1929); p. 182 View in Reaxys Lewis, B.; Schumacher, H. -J.; Nature (London, United Kingdom); vol. 125; (1930); p. 129 View in Reaxys Lewis, B.; Schumacher, H. -J.; Zeitschrift fuer Elektrochemie; vol. 35; (1929); p. 651 View in Reaxys Lewis, B.; Schumacher, H. -J.; Z. phys. Ch.; vol. B 6; (1929); p. 435 ; (from Gmelin) View in Reaxys With O3, Kinetics, byproducts: O2 vol. Br: MVol.; 10.3, page 285 - 291 ; (from Gmelin)

110/201

2017-08-09 05:21:10

View in Reaxys Br Br

Se BrBr

Rx-ID: 26343500 View in Reaxys 373/751 Yield

Conditions & References With air in neat (no solvent), passing of dry air over SeBr4; acceleration of react. rate on heating; Meyer, J.; Wurm, V.; Z. Anorg. Chem.; vol. 190; (1930); p. 91 - 91 ; (from Gmelin) View in Reaxys With SO3*HCl in not given Prandtl, W.; Borinski, P.; Z. Anorg. Chem.; vol. 62; (1909); p. 240 - 240 View in Reaxys Borinski, P.; Dissert. Muenchen 1909, S. 37 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. Se: MVol.B; 70, page 152 - 153 ; (from Gmelin) View in Reaxys in not given vol. Se: MVol.B; 70, page 152 - 153 ; (from Gmelin) View in Reaxys Br

(v4)

Pt BrBr

Rx-ID: 26344238 View in Reaxys 374/751 Yield

Conditions & References in CO2 flow, 90-110°C Manchot, W.; Lehmann, G.; Ber. Dtsch. Chem. Ges.; vol. 63; (1930); p. 1221 - 1224 ; (from Gmelin) View in Reaxys in CO2 flow, 90-110°C vol. C: MVol.D3; 2.4.2, page 110 - 112 ; (from Gmelin) View in Reaxys

K+

2Br SeBr Br Br

(v6)

BrK

Rx-ID: 26450747 View in Reaxys 375/751 Yield

Conditions & References staying in air for several days Meyer, J.; Wurm, V.; Z. Anorg. Chem.; vol. 190; (1930); p. 92 ; (from Gmelin) View in Reaxys staying in air for several days vol. K: MVol.3; 10.5, page 796 - 797 ; (from Gmelin) View in Reaxys Br

Br11K2Sb3

Sb Br Br

Rx-ID: 26606553 View in Reaxys 376/751

111/201

2017-08-09 05:21:10

Yield

Conditions & References in acetone, Electrolysis; 8percent aceton soln, Pt electrode, 6.5 Amp Vournazos, A. C.; Z. Anorg. Chem.; vol. 192; (1930); p. 374 View in Reaxys Vournazos, A. C.; Praktika tes Akademias Athenon; vol. 5; (1930); p. 329 View in Reaxys Vournazos, A. C.; Praktika tes Akademias Athenon; vol. 5; (1930); p. 331 View in Reaxys vol. K: MVol.5; 5.4.3, page 1047 - 1048 View in Reaxys Vournazos, A. C.; Z. Anorg. Chem.; vol. 192; (1930); p. 372 ; (from Gmelin) View in Reaxys

Rx-ID: 7053977 View in Reaxys 377/751 Yield

Conditions & References Kirrmann; Annales de Chimie (Cachan, France); vol. <10>11; (1929); p. 232,271; Bulletin de la Societe Chimique de France; vol. <4>41; (1927); p. 319,320 View in Reaxys Br OH

Br Br

O Ag+

O–

Rx-ID: 7053993 View in Reaxys 378/751 Yield

Conditions & References T= 18 °C , Geschwindigkeit der Abspaltung Petrenko-Kritschenko; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 61; (1929); p. 1781; Chem. Zentralbl.; vol. 102; nb. I; (1931); p. 440 View in Reaxys

potassium carbonate Br

Rx-ID: 7054011 View in Reaxys 379/751 Yield

Conditions & References Krestinski; Bashenowa-Koslowskaja; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 61; (1929); p. 1697; Chem. Zentralbl.; vol. 101; nb. I; (1930); p. 3170 View in Reaxys Br OH

potassium hydroxide

Rx-ID: 7054012 View in Reaxys 380/751 Yield

sulfur

S2br2

coal Rx-ID: 7086050 View in Reaxys 381/751

112/201

2017-08-09 05:21:10

Yield

Conditions & References Briscoe; Peel; Rowlands; Journal of the Chemical Society; (1929); p. 1766 View in Reaxys

O O

Br Br H

(v3)

H N

HO O

Rx-ID: 8213725 View in Reaxys 382/751 Yield

Conditions & References Fischer; Schormueller; Justus Liebigs Annalen der Chemie; vol. 473; (1929); p. 211,234 View in Reaxys

BrK

Rx-ID: 26097363 View in Reaxys 383/751 Yield

Conditions & References With water in water, Kinetics, Sonication; ultrasonic treatment of KBr containing CCl4-H2O;; soln. turns yellow by formed Br2; Schmitt, F. O.; Johnson, C. H.; Olson, A. R.; J. Am. Chem. soc.; vol. 51; (1929); p. 370 - 375 View in Reaxys vol. C: MVol.D2; 4.1.2.7.11.3, page 251 - 254 ; (from Gmelin) View in Reaxys O

Br( 1-)

–O

H( 1+)

Cl( 1-)

Rx-ID: 26109287 View in Reaxys 384/751 Yield

Conditions & References With ruthenium(4+) cation in not given, byproducts: H2O; 100 °C Crowell, W. R.; Yost, D. M.; Carter, M.; Journal of the American Chemical Society; vol. 51; (1929); p. 786 - 786 ; (from Gmelin) View in Reaxys With ruthenium(III) cation in not given, byproducts: H2O; 100 °C Crowell, W. R.; Yost, D. M.; Carter, M.; Journal of the American Chemical Society; vol. 51; (1929); p. 786 - 786 ; (from Gmelin) View in Reaxys With ruthenium(4+) cation in not given, byproducts: H2O; 100 °C vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With ruthenium(III) cation in not given, byproducts: H2O; 100 °C vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys

CrO 3

Br( 1-)

Rx-ID: 26109291 View in Reaxys 385/751

113/201

2017-08-09 05:21:10

Yield

Conditions & References With sulfuric acid in not given, at room temp.; with dild. H2SO4 soln., CO2 flow; retardation effect in presence of alkali sulfates; activation effect with 2 and 3 valent metal sulfates except CdSO4 (retarding); strong activating by MnSO4 Bobtelsky, M.; Rosenberg, A.; Z. Anorg. Chem.; vol. 177; (1929); p. 137 ; (from Gmelin) View in Reaxys With sulfuric acid in not given, activation effect with 4 N soln. of HCl, MgCl2, NiCl2, AlCl3, CrCl3, FeCl3, MnCl2; retardation effect with neutral or N soln. of HCl, MgCl2, NiCl2, AlCl3, CrCl3, FeCl3, MnCl2 Bobtelsky, M.; Rosenberg, A.; Z. Anorg. Chem.; vol. 182; (1929); p. 74 ; (from Gmelin) View in Reaxys With H2SO4 in not given, at room temp.; with dild. H2SO4 soln., CO2 flow; retardation effect in presence of alkali sulfates; activation effect with 2 and 3 valent metal sulfates except CdSO4 (retarding); strong activating by MnSO4 vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With H2SO4 in not given, activation effect with 4 N soln. of HCl, MgCl2, NiCl2, AlCl3, CrCl3, FeCl3, MnCl2; retardation effect with neutral or N soln. of HCl, MgCl2, NiCl2, AlCl3, CrCl3, FeCl3, MnCl2 vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys

Rx-ID: 26144184 View in Reaxys 386/751 Yield

Conditions & References in diethyl ether, Electrolysis; Electrolysis with platinum anodes. Rodebush; Peterson; Journal of the American Chemical Society; vol. 51; (1929); p. 638 ; (from Gmelin) View in Reaxys in diethyl ether, Electrolysis; Electrolysis with platinum anodes. vol. Mg: MVol.A2; 35, page 291 - 293 ; (from Gmelin) View in Reaxys Cl

Ru Cl

(v3)

Rx-ID: 26147528 View in Reaxys 387/751 Yield 0%

Conditions & References in not given, heating (1 h, 98 °C) in sealed tube Crowell, W. R.; Yost, D. M.; Carter, J. M.; Journal of the American Chemical Society; vol. 51; (1929); p. 788 ; (from Gmelin) View in Reaxys

in not given, heating (1 h, 98 °C) in sealed tube vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys

Cl Ru

(v4)

Rx-ID: 26165639 View in Reaxys 388/751 Yield 0%

Conditions & References in not given, heating (1 h, 98 °C) in sealed tube

114/201

2017-08-09 05:21:10

Crowell, W. R.; Yost, D. M.; Carter, J. M.; Journal of the American Chemical Society; vol. 51; (1929); p. 788 ; (from Gmelin) View in Reaxys 0%

in not given, heating (1 h, 98 °C) in sealed tube vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys

Cl( 1-)

Rx-ID: 26179629 View in Reaxys 389/751 Yield

Conditions & References With perchloric acid, ruthenium(III) cation in not given, Kinetics, byproducts: H2O Crowell, W. R.; Yost, D. M.; Carter, M.; Journal of the American Chemical Society; vol. 51; (1929); p. 786 - 786 ; (from Gmelin) View in Reaxys With perchloric acid, ruthenium(4+) cation in not given, byproducts: H2O Crowell, W. R.; Yost, D. M.; Carter, M.; Journal of the American Chemical Society; vol. 51; (1929); p. 786 - 786 ; (from Gmelin) View in Reaxys With HClO4, ruthenium(4+) cation in not given, byproducts: H2O vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys With HClO4, ruthenium(III) cation in not given, Kinetics, byproducts: H2O vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys

K+

Br O

O–

K+

BrK

O–

Rx-ID: 26420215 View in Reaxys 390/751 Yield

Conditions & References

discharge without electrodes Mahant, S. D.; Journal of the Indian Chemical Society; vol. 6; (1929); p. 706 View in Reaxys Bhatnagar, S. S.; Sharma, R. K.; Mitra, N. G.; Journal of the Indian Chemical Society; vol. 5; (1928); p. 382 ; (from Gmelin) View in Reaxys vol. K: MVol.3; 1.6.2, page 580 - 581 ; (from Gmelin) View in Reaxys -3 (v1)

O Br

AsH 3

O–

Br Br

O (v1)

As OO

H( 1+)

(v1)

Rx-ID: 26457029 View in Reaxys 391/751 Yield

Conditions & References in not given, byproducts: H2O; with excess of HBrO3, in acid soln. Kubina, H.; Zeitschrift fuer Analytische Chemie; vol. 76; (1929); p. 41 View in Reaxys Reckleben, H.; Lockemann, G.; Angewandte Chemie; vol. 19; (1906); p. 281 View in Reaxys Reckleben, H.; Lockemann, G.; Zeitschrift fuer Analytische Chemie; vol. 47; (1908); p. 116 ; (from Gmelin)

115/201

2017-08-09 05:21:10

View in Reaxys in not given, byproducts: H2O; with excess of HBrO3, in acid soln. vol. Br: MVol.; 12, page 310 - 314 ; (from Gmelin) View in Reaxys -3 (v1)

AsH 3

O (v1)

As OO

H( 1+)

(v1)

Rx-ID: 26484215 View in Reaxys 392/751 Yield

Conditions & References in not given, byproducts: H2O; in acid soln. Kubina, H.; Zeitschrift fuer Analytische Chemie; vol. 76; (1929); p. 41 View in Reaxys Reckleben, H.; Lockemann, G.; Angewandte Chemie; vol. 19; (1906); p. 281 View in Reaxys Reckleben, H.; Lockemann, G.; Zeitschrift fuer Analytische Chemie; vol. 47; (1908); p. 116 ; (from Gmelin) View in Reaxys in not given, byproducts: H2O; in acid soln. vol. Br: MVol.; 12, page 310 - 314 ; (from Gmelin) View in Reaxys

Br–

H +N (v2)

Rx-ID: 26601671 View in Reaxys 393/751 Yield

Conditions & References in water, Kinetics, byproducts: H2O Moldenhauer, W.; Burger, M.; Ber.; vol. 62; (1929); p. 1615 View in Reaxys vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys With HCl in diethyl ether, shaking Moldenhauer, W.; Burger, M.; Ber.; vol. 62; (1929); p. 1615 View in Reaxys vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys in diethyl ether, byproducts: N2, NH4Br; evapn. Moldenhauer, W.; Burger, M.; Ber.; vol. 62; (1929); p. 1615 View in Reaxys vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys

Br HO

Br Br

Rx-ID: 7053980 View in Reaxys 394/751 Yield

Conditions & References Geschwindigkeit der Abspaltung bei verschiedenen Konzentrationen und Temperaturen Petrenko-Kritschenko; Chemische Berichte; vol. 61; (1928); p. 849; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 61; (1929); p. 34 View in Reaxys

116/201

2017-08-09 05:21:10

H N

Br HO

Br H

Rx-ID: 7053981 View in Reaxys 395/751 Yield

N+

Br H

Rx-ID: 7053982 View in Reaxys 396/751 Yield

Br HO

Br Br

O Ag+

O–

Rx-ID: 7053994 View in Reaxys 397/751 Yield

Br HO

Br Br

barium hydroxide

Rx-ID: 7054000 View in Reaxys 398/751 Yield

diluted alcoholic KOH-solution

Rx-ID: 7054003 View in Reaxys 399/751 Yield

Conditions & References Prevost; Bulletin de la Societe Chimique de France; vol. <4>43; (1928); p. 1016 View in Reaxys

Br HO

Br Br

potassium hydroxide

Rx-ID: 7054013 View in Reaxys 400/751 Yield

Conditions & References Geschwindigkeit der Abspaltung bei verschiedenen Konzentrationen und Temperaturen

117/201

2017-08-09 05:21:10

Petrenko-Kritschenko; Chemische Berichte; vol. 61; (1928); p. 849; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 61; (1929); p. 34 View in Reaxys O

potassium iodide

Rx-ID: 7054014 View in Reaxys 401/751 Yield

Conditions & References T= 25 °C , Geschwindigkeit, inactive α.β-dibromo-propionic acid van Duin; Recueil des Travaux Chimiques des Pays-Bas; vol. 43; (1924); p. 347,352,353; Recueil des Travaux Chimiques des Pays-Bas; vol. 45; (1926); p. 354 View in Reaxys van Duin; Recueil des Travaux Chimiques des Pays-Bas; vol. 47; (1928); p. 734 View in Reaxys Kruyt; van Duin; Recueil des Travaux Chimiques des Pays-Bas; vol. 40; (1921); p. 253,254 View in Reaxys T= 25 °C , Geschwindigkeit im Licht.Irradiation, inactive α.β-dibromo-propionic acid van Duin; Recueil des Travaux Chimiques des Pays-Bas; vol. 43; (1924); p. 347,352,353; Recueil des Travaux Chimiques des Pays-Bas; vol. 45; (1926); p. 354 View in Reaxys O

potassium iodide

Rx-ID: 7054017 View in Reaxys 402/751 Yield

potassium iodide

blood coal

Rx-ID: 7054018 View in Reaxys 403/751 Yield

Conditions & References T= 25 °C , Geschwindigkeit, inactive α.β-dibromo-propionic acid Kruyt; van Duin; Verslag van de Gewone Vergadering van de Afdeling Natuurkunde, Koninklijke Nederlandse Akademie van Wetenschappen; vol. 31; p. 400; Recueil des Travaux Chimiques des Pays-Bas; vol. 40; (1921); p. 262 View in Reaxys van Duin; Recueil des Travaux Chimiques des Pays-Bas; vol. 47; (1928); p. 734 View in Reaxys

118/201

2017-08-09 05:21:10

O Br

potassium iodide

blood coal

Rx-ID: 7054019 View in Reaxys 404/751 Yield

Br HO

Br H

silver nitrite

Rx-ID: 7054020 View in Reaxys 405/751 Yield

Br HO

Br H

silver

Rx-ID: 7054021 View in Reaxys 406/751 Yield

Cu 2+

(v1)

S OO

Rx-ID: 26179665 View in Reaxys 407/751 Yield 0%

Conditions & References in neat (no solvent) Ephraim, F.; Schaerer, A.; Ber.; vol. 61; (1928); p. 2161 - 2173 View in Reaxys vol. Cu: MVol.B1; 224, page 498 - 500 ; (from Gmelin) View in Reaxys

Rx-ID: 26349514 View in Reaxys 408/751 Yield

Conditions & References With hydrogen sulfide, byproducts: H2O Wachholtz, F.; Z. phys. Ch.; vol. 135; (1928); p. 170 View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys

119/201

2017-08-09 05:21:10

O– Br

O–

–O

S OO

Rx-ID: 26349541 View in Reaxys 409/751 Yield

Conditions & References byproducts: H2O Wachholtz, F.; Z. phys. Ch.; vol. 135; (1928); p. 170 View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys

(v4) (v4)

H O

3 Cl – (v3)

(v4)

H2 NHN2 (v4) Co 3+ Co (v6) O O O (v3) H 2N NH H

H2 N H 2N

2 (v4)

BrK

(v6)

(v4)

Rx-ID: 26560197 View in Reaxys 410/751 Yield

Conditions & References

in not given Bucknall, W. R.; Wardlaw, W.; Journal of the Chemical Society; (1928); p. 2649 - 2649 View in Reaxys Bucknall, W. R.; Wardlaw, W.; Journal of the Chemical Society; (1928); p. 2652 - 2652 View in Reaxys vol. Co: MVol.B; 163, page 364 - 365 ; (from Gmelin) View in Reaxys

Br Br

tri-o-phenylenediarsine

As Br Br

arsanthrene dibromide

1.2-dibromo-benzene (?) Rx-ID: 5747646 View in Reaxys 411/751

Yield

Conditions & References T= 260 °C , unter vermindertem Druck McCleland; Whitworth; Journal of the Chemical Society; (1927); p. 2757 View in Reaxys O Br

N O

O N

bromodinitrophenole

O Br

N O

Rx-ID: 6210709 View in Reaxys 412/751 Yield

Conditions & References Scheidt; ; vol. 3; p. 1203; Chem. Zentralbl.; vol. 98; nb. I; (1927); p. 2465 View in Reaxys Magidson; Konowal; ; vol. 4; p. 153; Chem. Zentralbl.; vol. 98; nb. II; (1927); p. 1993 View in Reaxys

Rx-ID: 7053971 View in Reaxys 413/751

120/201

2017-08-09 05:21:10

Yield

Conditions & References Gryszkiewicz-Trochimowski; Zambrzycki; Roczniki Chemii; vol. 6; p. 800; Chem. Zentralbl.; vol. 98; nb. II; (1927); p. 912 View in Reaxys Br

alcoholic silver nitrate

Rx-ID: 7053997 View in Reaxys 414/751 Yield

Conditions & References dextrorotatory form of 2-bromo-2-nitro-butane Kuhn; Albrecht; Chemische Berichte; vol. 60; (1927); p. 1303 View in Reaxys

H 2N

NH 2

tin (II)-chloride

Rx-ID: 7916001 View in Reaxys 415/751 Yield

Conditions & References Geschwindigkeit Nicolet; Ray; Journal of the American Chemical Society; vol. 49; (1927); p. 1805 View in Reaxys

S OO

Rx-ID: 8213757 View in Reaxys 416/751 Yield

Conditions & References Fries; Justus Liebigs Annalen der Chemie; vol. 454; (1927); p. 306 View in Reaxys

Cl Cl Br

triphenylbromoethylene

Rx-ID: 8289953 View in Reaxys 417/751 Yield

Conditions & References Meisenheimer; Justus Liebigs Annalen der Chemie; vol. 456; (1927); p. 147 View in Reaxys

121/201

2017-08-09 05:21:10

triphenylbromoethylene

Rx-ID: 8289954 View in Reaxys 418/751 Yield

Conditions & References Meisenheimer; Justus Liebigs Annalen der Chemie; vol. 456; (1927); p. 147 View in Reaxys

triphenylbromoethylene

Rx-ID: 8289955 View in Reaxys 419/751 Yield

Conditions & References Meisenheimer; Justus Liebigs Annalen der Chemie; vol. 456; (1927); p. 147 View in Reaxys O

N O

Rx-ID: 26092035 View in Reaxys 420/751 Yield

Conditions & References

50 %

With nitric acid Magidson, O.; Konowal, R.; Zh. Khim. Prom - sti.; vol. 4; (1927); p. 153 View in Reaxys vol. Br: MVol.; 1.2, page 40 - 44 ; (from Gmelin) View in Reaxys

>99

With nitric acid Scheidt, K.; Zh. Khim. Prom - sti.; vol. 3; (1926); p. 1200 View in Reaxys vol. Br: MVol.; 1.2, page 40 - 44 ; (from Gmelin) View in Reaxys

Br Br Fe (v4) Br

(v4) (v4) Br

Fe Br

Br Fe

Rx-ID: 26159552 View in Reaxys 421/751 Yield

Conditions & References thermal decompn. Hoefer, P.; Kali; vol. 21; (1927); p. 223 ; (from Gmelin) View in Reaxys vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys

122/201

2017-08-09 05:21:10

Br Al

Rx-ID: 26159604 View in Reaxys 422/751 Yield

Conditions & References With oxygen, red heating in dry O2 Berthelot, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 86; (1878); p. 791 ; (from Gmelin) View in Reaxys in nitrobenzene, Electrolysis Plotnikow, W. A.; Bendetzky, M. A.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 59; (1927); p. 493 View in Reaxys Plotnikow, W. A.; Bendetzky, M. A.; Z. phys. Ch.; vol. 127; (1927); p. 225 View in Reaxys vol. Al: MVol.B1; 7.1.2, page 219 - 230 ; (from Gmelin) View in Reaxys With O2, red heating in dry O2 vol. Al: MVol.B1; 7.1.2, page 219 - 230 ; (from Gmelin) View in Reaxys

Br Al

Rx-ID: 26159605 View in Reaxys 423/751 Yield

Conditions & References in nitrobenzene, Electrolysis; Ag-anode, Pt-cathode; generation of Br at the anode; Plotnikow, W. A.; Bendetzky, M. A.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 59; (1927); p. 493 - 493 View in Reaxys Plotnikow, W. A.; Bendetzky, M. A.; Z. phys. Ch.; vol. 127; (1927); p. 231 - 231 ; (from Gmelin) View in Reaxys in nitrobenzene, Electrolysis; Ag-anode, Pt-cathode; generation of Br at the anode; vol. Al: MVol.A1; 39, page 122 - 124 ; (from Gmelin) View in Reaxys

Br–

NH +4

Rx-ID: 26179624 View in Reaxys 424/751 Yield

Conditions & References in presence of "active nitrogen" Willey, E. J. B.; Rideal, E. K.; Journal of the Chemical Society; (1927); p. 672 - 677 ; (from Gmelin) View in Reaxys in presence of "active nitrogen" vol. N: MVol.1; 1.7, page 273 - 281 ; (from Gmelin) View in Reaxys

Rx-ID: 26527192 View in Reaxys 425/751 Yield

Conditions & References With nitric acid, byproducts: H2O Briner, E.; Bulletin des Societes Chimiques Belges; vol. 36; (1927); p. 88 ; (from Gmelin) View in Reaxys

123/201

2017-08-09 05:21:10

With HNO3, byproducts: H2O vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys Ag+

O Cl

O–

Rx-ID: 26566053 View in Reaxys 426/751 Yield

Conditions & References in ethanol, addition of AgClO2 into a solution of C2H5Br in ethanol; Levi, G. R.; Gazzetta Chimica Italiana; vol. 53; (1927); p. 40 - 42 View in Reaxys vol. Ag: MVol.B1; 6.12.5, page 497 - 498 ; (from Gmelin) View in Reaxys 2 Rb + Br 2Br SnBr Br Br

Rx-ID: 26597466 View in Reaxys 427/751 Yield

Conditions & References in nitric acid, in cold Costeanu, G. I.; Ber. Dtsch. Chem. Ges. B; vol. 60; (1927); p. 1312 - 1315 ; (from Gmelin) View in Reaxys in sulfuric acid, in cold Costeanu, G. I.; Ber. Dtsch. Chem. Ges. B; vol. 60; (1927); p. 1312 - 1315 ; (from Gmelin) View in Reaxys in sulfuric acid, in cold vol. Sn: MVol.C3; 24.11, page 137 - 137 ; (from Gmelin) View in Reaxys in nitric acid, in cold vol. Sn: MVol.C3; 24.11, page 137 - 137 ; (from Gmelin) View in Reaxys Br

–O

Na +

Rx-ID: 7053986 View in Reaxys 428/751 Yield

Conditions & References Gruen; Ulbrich; Krczil; Angewandte Chemie; vol. 39; (1926); p. 424 View in Reaxys Br O K+

O–

Rx-ID: 7053988 View in Reaxys 429/751 Yield

Conditions & References T= 200 °C Gruen; Ulbrich; Krczil; Angewandte Chemie; vol. 39; (1926); p. 424 View in Reaxys

124/201

2017-08-09 05:21:10

Br Br

higher-melting (trans)-1.1.2.3.4.4-hexabromo-butene-(2)

Rx-ID: 7077664 View in Reaxys 430/751 Yield

Conditions & References bei der Destillation, lower-melting (cis)-1.1.2.3.4.4-hexabromo-butene-(2) Straus; Kollek; Chemische Berichte; vol. 59; (1926); p. 1679 View in Reaxys O Br

Rx-ID: 7916005 View in Reaxys 431/751 Yield

Conditions & References Schmidt; Ascherl; v. Knilling; Chemische Berichte; vol. 59; (1926); p. 1886 View in Reaxys

Br HO

Rx-ID: 26092034 View in Reaxys 432/751 Yield >99

Conditions & References complete decompn. Scheidt, K.; Zh. Khim. Prom - sti.; vol. 3; (1926); p. 1200 View in Reaxys vol. Br: MVol.; 1.2, page 40 - 44 ; (from Gmelin) View in Reaxys

BrK

ClK

Rx-ID: 26097267 View in Reaxys 433/751 Yield

Conditions & References With chlorine Balard, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 356 View in Reaxys Balard, A. J.; Annalen der Physik (Weinheim, Germany); vol. 8; (1926); p. 327 View in Reaxys Balard, A. J.; Philosophical Magazine (1798-1977); vol. 12; (1826); p. 412 ; (from Gmelin) View in Reaxys

>99

With water, chlorine, moderate heating Kuester, F. W.; Z. Anorg. Chem.; vol. 18; (1898); p. 78 ; (from Gmelin) View in Reaxys With water, chlorine, H2O containing Cl2 Parsons, L. B.; Journal of the American Chemical Society; vol. 47; (1925); p. 1817 View in Reaxys Potylizyn, A.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 11; (1879); p. 86 ; (from Gmelin) View in Reaxys With H2O, Cl2 vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys

125/201

2017-08-09 05:21:10

With chlorine vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys With chlorine, H2O vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys Br Al

BrK

Rx-ID: 26097352 View in Reaxys 434/751 Yield

Conditions & References Electrolysis; platinum cathode; Treadwell, W. D.; Stern, H.; Helvetica Chimica Acta; vol. 7; (1924); p. 628 - 628 View in Reaxys Treadwell, W. D.; Stern, H.; Helvetica Chimica Acta; vol. 7; (1924); p. 636 - 636 ; (from Gmelin) View in Reaxys Electrolysis; platinum cathode; Dadieu, A.; Monatshefte fuer Chemie; vol. 47; (1926); p. 501 - 501 View in Reaxys vol. Al: MVol.B2; 63, page 451 - 453 ; (from Gmelin) View in Reaxys

BrK

Rx-ID: 26342883 View in Reaxys 435/751 Yield

Conditions & References in not given Fichter, F.; Humpert, K.; Helvetica Chimica Acta; vol. 9; (1926); p. 602 - 611 ; (from Gmelin) View in Reaxys in not given vol. S: MVol.B2; 5, page 798 - 808 ; (from Gmelin) View in Reaxys

H Br

Rx-ID: 26441706 View in Reaxys 436/751 Yield

Conditions & References in neat (no solvent), introduction of HBr into SOCl2 at room temp.;; fractionation at reduced pressure to remove unreacted SOCl2 and Br2; Mayes, H. A.; Partington, J. R.; Journal of the Chemical Society; (1926); p. 2594 - 2605 View in Reaxys vol. S: MVol.B3; 159, page 1866 - 1868 ; (from Gmelin) View in Reaxys

O Br

O–

Rx-ID: 26457019 View in Reaxys 437/751 Yield

Conditions & References in not given, in acidic soln.

126/201

2017-08-09 05:21:10

Mason, C. W.; Chamot, E. M.; Mikrochemie; vol. 4; (1926); p. 148 ; (from Gmelin) View in Reaxys in not given, in acidic soln. vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin) View in Reaxys O Br

Rx-ID: 26518114 View in Reaxys 438/751 Yield

Conditions & References in neat (no solvent), decompn. on storage with discoloration to red; Mayes, H. A.; Partington, J. R.; Journal of the Chemical Society; (1926); p. 2594 - 2605 View in Reaxys vol. S: MVol.B3; 159, page 1866 - 1868 ; (from Gmelin) View in Reaxys

O Br

Br S

Rx-ID: 26518115 View in Reaxys 439/751 Yield

Conditions & References in neat (no solvent), distillation (common pressure/b.p. 140°C); Mayes, H. A.; Partington, J. R.; Journal of the Chemical Society; (1926); p. 2594 - 2605 View in Reaxys vol. S: MVol.B3; 159, page 1866 - 1868 ; (from Gmelin) View in Reaxys S N

Rx-ID: 7053984 View in Reaxys 440/751 Yield

Conditions & References Soederbaeck; Justus Liebigs Annalen der Chemie; vol. 443; (1925); p. 151; Justus Liebigs Annalen der Chemie; vol. 465; (1928); p. 187 View in Reaxys Br OH

N O

H 2N

NH 2

Rx-ID: 7053990 View in Reaxys 441/751 Yield

Conditions & References Macbeth; Traill; Journal of the Chemical Society; vol. 127; (1925); p. 896 View in Reaxys

O N O

O Br

O N

O Br

Br O

OH Br

Br O

H 2N 2

Rx-ID: 7060066 View in Reaxys 442/751 Yield

Conditions & References Produkt5: salpetrige Saeure Wieland; Jung; Justus Liebigs Annalen der Chemie; vol. 445; (1925); p. 86 View in Reaxys

127/201

2017-08-09 05:21:10

O N

O Br

nitrogen dioxide

Rx-ID: 7082400 View in Reaxys 443/751 Yield

Conditions & References zersetzt sich ueber den Schmelzpunkt explosionsartig Wieland; Jung; Justus Liebigs Annalen der Chemie; vol. 445; (1925); p. 86 View in Reaxys

O O

Rx-ID: 7447119 View in Reaxys 444/751 Yield

Conditions & References Sonnenlicht.Irradiation Stobbe; Chemische Berichte; vol. 58; (1925); p. 2863 View in Reaxys

Br Br

dry air

P Br Br

Rx-ID: 8213760 View in Reaxys 445/751 Yield

Conditions & References T= 100 °C Lindner; Fresenius' Zeitschrift fuer Analytische Chemie; vol. 66; (1925); p. 314 View in Reaxys

Br Br

moist air

P Br Br

Rx-ID: 8213761 View in Reaxys 446/751 Yield

Conditions & References T= 100 °C Lindner; Fresenius' Zeitschrift fuer Analytische Chemie; vol. 66; (1925); p. 314 View in Reaxys

6 O

Cl O–

H O

Na +

Cl 2Mg bischofite

Rx-ID: 26069213 View in Reaxys 447/751 Yield

Conditions & References With hydrogenchloride, melting with small amt. of HCl; heating upto 140 °C; Br2 mixed with H2O and acid vapor Patent; Buechner, P. C.; Preuzsische Bergwerks- und Huetten-A. G., Abt. Salz- und Braunko; DE43586; (1925) ; (from Gmelin) View in Reaxys With HCl vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys

128/201

2017-08-09 05:21:10

(v2)

Br– Br

Br–

NH +4

N+ HH

Rx-ID: 26147102 View in Reaxys 448/751 Yield

Conditions & References Ephraim, F.; Schliessmann, O.; Ber.; vol. 50; (1917); p. 1087 View in Reaxys Huettig, G. F.; Schliessmann, O.; Z. Anorg. Chem.; vol. 148; (1925); p. 91 ; (from Gmelin) View in Reaxys Bakhuis Roozeboom, H. W.; Z. phys. Ch.; vol. 2; (1888); p. 460 - 462 View in Reaxys vol. NH4: MVol.1; 2.9.3, page 215 - 222 ; (from Gmelin) View in Reaxys

Br (v4)

PtBr4#PtBr2

Pt BrBr

Rx-ID: 26344227 View in Reaxys 449/751 Yield

Conditions & References heating over 335 °C Woehler, L.; Mueller, F.; Z. Anorg. Chem.; vol. 149; (1925); p. 379 - 381 ; (from Gmelin) View in Reaxys heating over 335 °C vol. Pt: MVol.C1; 7.1, page 94 - 99 ; (from Gmelin) View in Reaxys

Br Ir Br

(v3)

H O

Br2Ir

Rx-ID: 26391588 View in Reaxys 450/751 Yield

Conditions & References byproducts: H2O; at 335°C Krauss, F.; Gerlach, H.; Z. Anorg. Chem.; vol. 147; (1925); p. 269 - 283 View in Reaxys vol. Ir: MVol.; 5.6, page 71 - 73 ; (from Gmelin) View in Reaxys

– Br+ N

N+ N–

(v0)

Yield

Rx-ID: 26603057 View in Reaxys 451/751 Conditions & References in diethyl ether, byproducts: N2; explosion by shaking Spencer, D. A.; Journal of the Chemical Society; vol. 127; (1925); p. 216 ; (from Gmelin) View in Reaxys in diethyl ether, byproducts: N2; explosion by standing Spencer, D. A.; Journal of the Chemical Society; vol. 127; (1925); p. 216 ; (from Gmelin) View in Reaxys in benzene, byproducts: N2; explosion by shaking Spencer, D. A.; Journal of the Chemical Society; vol. 127; (1925); p. 216 ; (from Gmelin) View in Reaxys in benzene, byproducts: N2; explosion by standing

129/201

2017-08-09 05:21:10

Spencer, D. A.; Journal of the Chemical Society; vol. 127; (1925); p. 216 ; (from Gmelin) View in Reaxys in Petroleum ether, byproducts: N2; explosion by shaking Spencer, D. A.; Journal of the Chemical Society; vol. 127; (1925); p. 216 ; (from Gmelin) View in Reaxys in Petroleum ether, byproducts: N2; explosion by standing Spencer, D. A.; Journal of the Chemical Society; vol. 127; (1925); p. 216 ; (from Gmelin) View in Reaxys in diethyl ether, byproducts: N2; explosion by standing vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys in petroleum ether, byproducts: N2; explosion by shaking vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys in petroleum ether, byproducts: N2; explosion by standing vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys in diethyl ether, byproducts: N2; explosion by shaking vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys in benzene, byproducts: N2; explosion by shaking vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys in benzene, byproducts: N2; explosion by standing vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys Br Br

O3V2

(v3)

Rx-ID: 26468444 View in Reaxys 452/751 Yield

Conditions & References With air, decompn. to form Br2 even in dry air even at ambient temp.; on mild heating formation of V2O3 occurs; Meyer, J.; Backa, R.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 135; (1924); p. 177 - 193 ; (from Gmelin) View in Reaxys With dry air, decompn. to form Br2 even in dry air even at ambient temp.; on mild heating formation of V2O3 occurs; Roscoe, H. E.; Justus Liebigs Annalen der Chemie; vol. 8; (1872); p. 95 - 112 View in Reaxys Roscoe, H. E.; Philosophical Transactions of the Royal Society of London; vol. 160; (1870); p. 317 - 331 View in Reaxys vol. V: MVol.B1; 97, page 258 - 260 ; (from Gmelin) View in Reaxys

130/201

2017-08-09 05:21:10

O Br

Rx-ID: 5574983 View in Reaxys 453/751 Yield

Conditions & References Zersetzung bei Belichtung mit ultraviolettem Licht Pucher; Johnson; Journal of the American Chemical Society; vol. 44; (1922); p. 823 View in Reaxys Beim Stehenlassen an feuchter Luft Pucher; Johnson; Journal of the American Chemical Society; vol. 44; (1922); p. 823 View in Reaxys Hopkins; Journal of the American Chemical Society; vol. 45; (1923); p. 542 View in Reaxys -1 OH

Br–

(v2)

Br Br

N+

Rx-ID: 8214962 View in Reaxys 454/751 Yield

Conditions & References Chattaway; Hoyle; Journal of the Chemical Society; vol. 123; (1923); p. 657 View in Reaxys

Br( 1-)

H( 1+)

Rx-ID: 26109285 View in Reaxys 455/751 Yield

Conditions & References With dihydrogen peroxide in not given, byproducts: H2O Bray, W. C.; Livingston, R. S.; Journal of the American Chemical Society; vol. 45; (1923); p. 1251 ; (from Gmelin) View in Reaxys With H2O2 in not given, byproducts: H2O vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys O O–

Mn( 2+)

H( 1+)

Rx-ID: 26457034 View in Reaxys 456/751 Yield

Conditions & References With water in not given, byproducts: MnO2; in acidic soln. Smith, G. F.; Journal of the American Chemical Society; vol. 45; (1923); p. 1116 View in Reaxys Smith, G. F.; Journal of the American Chemical Society; vol. 45; (1923); p. 1420 ; (from Gmelin) View in Reaxys With H2O in not given, byproducts: MnO2; in acidic soln. vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin) View in Reaxys O Br

O N

Rx-ID: 5574985 View in Reaxys 457/751

131/201

2017-08-09 05:21:10

Yield

Conditions & References Pucher; Johnson; Journal of the American Chemical Society; vol. 44; (1922); p. 823 View in Reaxys O

OH H 2N 2

N O

titanium (III)-chloride

Rx-ID: 5574988 View in Reaxys 458/751 Yield

Conditions & References Black; Hirst; Macbeth; Journal of the Chemical Society; vol. 121; (1922); p. 2532 View in Reaxys

H 2N 2

H O

H N

titanium (II)-chloride

Rx-ID: 6680044 View in Reaxys 459/751 Yield

Conditions & References Black; Hirst; Macbeth; Journal of the Chemical Society; vol. 121; (1922); p. 2531 View in Reaxys

Se Se

Rx-ID: 7053966 View in Reaxys 460/751 Yield

Conditions & References Morgan; Drew; Barker; Journal of the Chemical Society; vol. 121; (1922); p. 2457 View in Reaxys O Br

O O

H 2N

H O

NH 2

Rx-ID: 7053991 View in Reaxys 461/751 Yield

Conditions & References Hirst; Macbeth; Journal of the Chemical Society; vol. 121; (1922); p. 911 View in Reaxys

titanium (II)-chloride

NHH22N

Rx-ID: 7054022 View in Reaxys 462/751 Yield

Conditions & References Black; Hirst; Macbeth; Journal of the Chemical Society; vol. 121; (1922); p. 2532 View in Reaxys O Br

O O

titanium (II)-chloride

Rx-ID: 7054023 View in Reaxys 463/751 Yield

Conditions & References spaltet die Nitrogruppe ab Black; Hirst; Macbeth; Journal of the Chemical Society; vol. 121; (1922); p. 2532

132/201

2017-08-09 05:21:10

View in Reaxys NH 2

NH 2

H 2N 2

titanium (II)-chloride

Rx-ID: 7054024 View in Reaxys 464/751 Yield

Conditions & References Black; Hirst; Macbeth; Journal of the Chemical Society; vol. 121; (1922); p. 2532 View in Reaxys O

N H

OH O

H 2N 2

titanium (III)-chloride

Rx-ID: 7054025 View in Reaxys 465/751 Yield

Conditions & References Black; Hirst; Macbeth; Journal of the Chemical Society; vol. 121; (1922); p. 2532 View in Reaxys O

O Br

Rx-ID: 7916006 View in Reaxys 466/751 Yield

Conditions & References Gupta; Thorpe; Journal of the Chemical Society; vol. 121; (1922); p. 1901 View in Reaxys

BrK

Rx-ID: 26097387 View in Reaxys 467/751 Yield

Conditions & References in not given Maass; Hatcher; Journal of the American Chemical Society; vol. 44; (1922); p. 2472 View in Reaxys vol. O: MVol.7; 18, page 2196 - 2198 ; (from Gmelin) View in Reaxys

Rx-ID: 26178379 View in Reaxys 468/751 Yield

Conditions & References in neat (no solvent), introduction of dry HBr into dry H2O2; Maass; Hatcher; Journal of the American Chemical Society; vol. 44; (1922); p. 2472 View in Reaxys vol. O: MVol.7; 18, page 2196 - 2198 ; (from Gmelin) View in Reaxys

O Cl

O–

Rx-ID: 26380565 View in Reaxys 469/751 Yield

Conditions & References With bromide in sulfuric acid, using alkali bromides; no reaction in neutral solns.; Levi, G. R.; Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti; vol. 31; nb. I; (1922); p. 372 - 372 View in Reaxys Levi, G. R.; Gazzetta Chimica Italiana; vol. 52; nb. II; (1922); p. 58 - 58 ; (from Gmelin)

133/201

2017-08-09 05:21:10

View in Reaxys With bromate anion in sulfuric acid, using alkali bromates; no reaction in neutral solns.; Levi, G. R.; Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti; vol. 31; nb. I; (1922); p. 372 - 372 View in Reaxys Levi, G. R.; Gazzetta Chimica Italiana; vol. 52; nb. II; (1922); p. 58 - 58 ; (from Gmelin) View in Reaxys With BrO3 (1-) in sulfuric acid, aq. H2SO4; using alkali bromates; no reaction in neutral solns.; vol. Cl: MVol.; 113, page 303 - 306 ; (from Gmelin) View in Reaxys With Br(1-) in sulfuric acid, aq. H2SO4; using alkali bromides; no reaction in neutral solns.; vol. Cl: MVol.; 113, page 303 - 306 ; (from Gmelin) View in Reaxys Br

Ge Br

Rx-ID: 26484354 View in Reaxys 470/751 Yield

Conditions & References in acetone, dissolving in acetone; slow formation of Br2; Dennis, L. M.; Hance, F. E.; Z. Anorg. Chem.; vol. 122; (1922); p. 270 - 270 View in Reaxys Dennis, L. M.; Hance, F. E.; Journal of the American Chemical Society; vol. 44; (1922); p. 303 - 303 ; (from Gmelin) View in Reaxys in acetone, dissolving in acetone; slow formation of Br2; vol. Ge: MVol.; 16, page 46 - 49 ; (from Gmelin) View in Reaxys

Rx-ID: 26484842 View in Reaxys 471/751 Yield >99

Conditions & References With potassium chlorate in not given, careful warming; Lenher, V.; Journal of the American Chemical Society; vol. 44; (1922); p. 1670 - 1670 ; (from Gmelin) View in Reaxys in not given vol. Se: MVol.B; 71, page 153 - 156 ; (from Gmelin) View in Reaxys

NH 2

aqueous methanolic NaOH-solution

Rx-ID: 5817695 View in Reaxys 472/751 Yield

Conditions & References T= 185 °C Meyer; Chemische Berichte; vol. 54; (1921); p. 2273 View in Reaxys

134/201

2017-08-09 05:21:10

tin (II)-chloride

NH 2

Rx-ID: 5817699 View in Reaxys 473/751 Yield

Conditions & References Nicolet; Journal of the American Chemical Society; vol. 43; (1921); p. 2083 View in Reaxys 1 Br

chloronitrogen

Cl –

(v4)

N HH

nitrogen

Rx-ID: 6729967 View in Reaxys 474/751 Yield

Conditions & References Coleman; Noyes; Journal of the American Chemical Society; vol. 43; (1921); p. 2215 View in Reaxys

Br HO

KOH-solution

Rx-ID: 7054007 View in Reaxys 475/751 Yield

Conditions & References Hlawatsch; zit.bei Kohn;Mendelewitsch; Monatshefte fuer Chemie; vol. 42; (1921); p. 230 View in Reaxys

Cl Br

Rx-ID: 7054028 View in Reaxys 476/751 Yield

Conditions & References T= 100 °C , im Dunkeln v.Ranke; Zeitschrift fuer Elektrochemie und Angewandte Physikalische Chemie; vol. 27; (1921); p. 365 View in Reaxys im Licht Nernst; ; vol. 21; p. 602; Chem. Zentralbl.; vol. 92; nb. I; (1921); p. 704 View in Reaxys

aqueous methanolic NaOH-solution

Rx-ID: 7441573 View in Reaxys 477/751 Yield

Conditions & References T= 175 °C Meyer; Chemische Berichte; vol. 54; (1921); p. 2273 View in Reaxys

H N

tin (II)-chloride

Rx-ID: 7916000 View in Reaxys 478/751 Yield

Conditions & References Nicolet; Journal of the American Chemical Society; vol. 43; (1921); p. 2083 View in Reaxys

135/201

2017-08-09 05:21:10

O (v4)

P HO

O P HO

bromo hydrogen

Rx-ID: 8270160 View in Reaxys 479/751 Yield

Conditions & References Conant; Bump; Holt; Journal of the American Chemical Society; vol. 43; (1921); p. 1683 View in Reaxys

Na +

Br( 1-)

O–

Rx-ID: 26109292 View in Reaxys 480/751 Yield

Conditions & References With sulfuric acid in water, modified Frank`s method; from mother liquor of stassfurtic salt by evapn., adding NaClO3 and 66 °Be H2SO4; distn.; removing Cl2 with lime milk; condensation of Br2 by cooling Phalen, W. C.; Chemiker-Zeitung; vol. 45; (1921); p. 1089 View in Reaxys Phalen, W. C.; Technology of salt making in the United States, Bl. Bur. Mines Nr. 146 {1917} 85 ; (from Gmelin) View in Reaxys With H2SO4 in water vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys SH

O Br

S HO

O O

S OO

Rx-ID: 26453311 View in Reaxys 481/751 Yield

Conditions & References With water in not given, Kinetics, in presence of acid Kolthoff, I. M.; Chemisch Weekblad; vol. 17; (1920); p. 82 - 85 View in Reaxys Kolthoff, I. M.; Pharmaceutisch Weekblad; vol. 56; (1919); p. 426 - 438 View in Reaxys Kolthoff; Zeitschrift fuer Analytische Chemie; vol. 60; nb. 9-10; (1921); p. 338 - 353 ; (from Gmelin) View in Reaxys With H2O in not given, Kinetics, in presence of acid vol. S: MVol.B2; 7.5.3, page 910 - 913 ; (from Gmelin) View in Reaxys

Rx-ID: 26486346 View in Reaxys 482/751 Yield

Conditions & References With chlorine in tetrachloromethane, reaction on heating Cl2 and CCl3Br in CCl4;; soln. turns brown; Ranke, A. v.; Zeitschrift fuer Elektrochemie; vol. 27; (1921); p. 365 - 367 ; (from Gmelin) View in Reaxys With chlorine in neat (no solvent), reaction on heating a soln. of Cl2 in CCl3Br;; soln. turns brown;

136/201

2017-08-09 05:21:10

Ranke, A. v.; Zeitschrift fuer Elektrochemie; vol. 27; (1921); p. 365 - 367 ; (from Gmelin) View in Reaxys With Cl2 vol. C: MVol.D2; 4.2.8.5.6, page 346 - 347 ; (from Gmelin) View in Reaxys With Cl2 in tetrachloromethane vol. C: MVol.D2; 4.2.8.5.6, page 346 - 347 ; (from Gmelin) View in Reaxys H N

sodium

Rx-ID: 7441576 View in Reaxys 483/751 Yield

Conditions & References Dains; Brewster; Journal of the American Chemical Society; vol. 42; (1920); p. 1578 View in Reaxys

Br SbBr Br

Rx-ID: 8213736 View in Reaxys 484/751 Yield

Conditions & References beim Aufbewahren Raynaud; Bulletin de la Societe Chimique de France; vol. <4>27; (1920); p. 411 View in Reaxys

O Br

O–

Br Br O

Rx-ID: 26456995 View in Reaxys 485/751 Yield

Conditions & References With iodine Gruber, G.; Z. phys. ch. Unterr.; vol. 33; (1920); p. 107 View in Reaxys Guareschi, I.; Zeitschrift fuer Analytische Chemie; vol. 52; (1913); p. 612 View in Reaxys Kaemmerer, H.; Journal fuer Praktische Chemie (Leipzig); vol. 85; (1862); p. 455 ; (from Gmelin) View in Reaxys With I2 vol. Br: MVol.; 12, page 310 - 314 ; (from Gmelin) View in Reaxys O

O Br

O–

Rx-ID: 26484192 View in Reaxys 486/751 Yield

Conditions & References With iodine Gruber, G.; Z. phys. ch. Unterr.; vol. 33; (1920); p. 107 View in Reaxys Guareschi, I.; Zeitschrift fuer Analytische Chemie; vol. 52; (1913); p. 612 View in Reaxys

137/201

2017-08-09 05:21:10

Kaemmerer, H.; Journal fuer Praktische Chemie (Leipzig); vol. 85; (1862); p. 455 ; (from Gmelin) View in Reaxys With I2 vol. Br: MVol.; 12, page 310 - 314 ; (from Gmelin) View in Reaxys O

N O

NH HO

HN O

Rx-ID: 5574986 View in Reaxys 487/751 Yield

Conditions & References Dakin; Biochemical Journal; vol. 13; (1919); p. 423 View in Reaxys

HO NH

Br O

H 2N 2

Rx-ID: 5684088 View in Reaxys 488/751 Yield

Conditions & References T= 100 °C Dakin; Biochemical Journal; vol. 13; (1919); p. 423 View in Reaxys

O N

Rx-ID: 26423861 View in Reaxys 489/751 Yield

Conditions & References in nitric acid, byproducts: H2O, O2, NO2 Anschuetz, R.; Kallen, J.; Riepenkroeger, K.; Ber.; vol. 52; (1919); p. 1861 - 1861 ; (from Gmelin) View in Reaxys in nitric acid, byproducts: H2O, O2, NO2; aq. HNO3 vol. Se: MVol.B; 36, page 76 - 78 ; (from Gmelin) View in Reaxys

Br Au Br Br

(v3)

AuBr

Rx-ID: 26436276 View in Reaxys 490/751 Yield

Conditions & References With sulfuric acid, anhydrous AuBr3 and concd. H2SO4 at 180°C Schmidt, F. W.; Chemiker-Zeitung; vol. 20; (1896); p. 483 View in Reaxys Spiegel, E.; Diss. Bern 1896, p. 20 ; (from Gmelin) View in Reaxys dissocn. 160°C, equil. reaction Schmidt, F. W.; Chemiker-Zeitung; vol. 20; (1896); p. 483 ; (from Gmelin) View in Reaxys With H2SO4, anhydrous AuBr3 and concd. H2SO4 at 180°C vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin)

138/201

2017-08-09 05:21:10

View in Reaxys dissocn. 160°C, equil. reaction vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin) View in Reaxys heating in boiling naphtalin bath (Br2 escaped) in sealed tube, 6h Ephraim, F.; Ber.; vol. 52; (1919); p. 241 - 254 View in Reaxys vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin) View in Reaxys O Br

–O

Na +

BrNa

Rx-ID: 26097568 View in Reaxys 491/751 Yield

Conditions & References With sulfuric acid, sodium chloride in water, byproducts: NaCl, Na2SO4, H2O vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Jones, C. W.; AU38117; (1918) ; (from Gmelin) View in Reaxys With sulfuric acid in water, byproducts: Na2SO4, H2O; in concd. aq. bromid and bromate soln. vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Barstow, E. O.; AU14922; (1911) ; (from Gmelin) View in Reaxys

BrK

Rx-ID: 26097268 View in Reaxys 492/751 Yield

Conditions & References over 825 °C Jaeger, F. M.; Z. Anorg. Chem.; vol. 101; (1917); p. 186 ; (from Gmelin) View in Reaxys vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys

(v2)

Br– Cl

H H

N+ HH

Rx-ID: 26149074 View in Reaxys 493/751 Yield

Conditions & References byproducts: Cl2 Ephraim, F.; Ber.; vol. 50; (1917); p. 1069 ; (from Gmelin) View in Reaxys byproducts: Cl2 vol. Br: MVol.; 10.1, page 275 - 280 ; (from Gmelin) View in Reaxys

Cl – Br Cs + (v2)

ClCs

Rx-ID: 26633050 View in Reaxys 494/751

139/201

2017-08-09 05:21:10

Yield

Conditions & References in neat (no solvent), CsBr2Cl -> CsCl + Br2 : examination of the dissociation pressure dependent on the temp.; Ephraim, F.; Ber.; vol. 50; (1917); p. 1083 - 1083 ; (from Gmelin) View in Reaxys in neat (no solvent), CsBr2Cl -> CsCl + Br2 : examination of the dissociation pressure dependent on the temp.; vol. Cs: MVol.2; 42, page 187 - 188 ; (from Gmelin) View in Reaxys

Rx-ID: 5817694 View in Reaxys 495/751 Yield

Conditions & References durch Belichtung mit UV-Licht v. Euler; Chemische Berichte; vol. 49; (1916); p. 1370 View in Reaxys

Rx-ID: 5817696 View in Reaxys 496/751 Yield

Conditions & References Busch; Stoeve; Chemische Berichte; vol. 49; (1916); p. 1069 View in Reaxys

palladium

hydrogen

Rx-ID: 5817701 View in Reaxys 497/751 Yield

Conditions & References in Gegenwart von KOH Busch; Stoeve; Chemische Berichte; vol. 49; (1916); p. 1069 View in Reaxys Br O

palladium

hydrogen

aqueous-alcoholic KOH-solution

Rx-ID: 7054047 View in Reaxys 498/751 Yield

Conditions & References Busch; Stoeve; Chemische Berichte; vol. 49; (1916); p. 1069 View in Reaxys O

0.5

Br Al

Rx-ID: 26173075 View in Reaxys 499/751 Yield

Conditions & References heating vol. Al: MVol.B1; 7.2.1, page 230 - 236 View in Reaxys Ephraim, F.; Kornblum, I.; Ber.; vol. 49; (1916); p. 2020 ; (from Gmelin)

140/201

2017-08-09 05:21:10

View in Reaxys O Br

Rx-ID: 26484191 View in Reaxys 500/751 Yield

Conditions & References With sulfur dioxide in water Balard, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 337 - 384 View in Reaxys Balard, A. J.; Annalen der Physik (Weinheim, Germany); vol. 8; (1826); p. 461 - 474 View in Reaxys vol. S: MVol.B2; 1.6.2.4, page 519 - 520 ; (from Gmelin) View in Reaxys byproducts: oxygen, H2O Feit, W.; Kubierschky, K.; Chemiker-Zeitung; vol. 15; (1891); p. 351 ; (from Gmelin) View in Reaxys With H2C2O4, byproducts: CO2, H2O Debourdeaux; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 138; (1904); p. 147 ; (from Gmelin) View in Reaxys With water, sulfur, byproducts: H2SO4; at cold Feit, W.; Kubierschky, K.; Chemiker-Zeitung; vol. 15; (1891); p. 351 ; (from Gmelin) View in Reaxys With hydrogen sulfide, byproducts: H2SO4, H2O Feit, W.; Kubierschky, K.; Chemiker-Zeitung; vol. 15; (1891); p. 351 ; (from Gmelin) View in Reaxys With hydrogen bromide Monnier, A.; Ann. Chim. anal.; vol. 21; (1916); p. 239 View in Reaxys Vitali, D.; Bollettino Chimico Farmaceutico; vol. 37; (1898); p. 545; C.; vol. I; (1910); p. 1105 View in Reaxys Vitali, D.; Bollettino Chimico Farmaceutico; vol. 38; (1899); p. 202; C.; vol. I; (1910); p. 1105 ; (from Gmelin) View in Reaxys With HNO2, byproducts: HNO3, H2O; at cold with excess of HBrO3 or with very dild. HBrO3 soln. Kurtenacker, A.; Monatshefte fuer Chemie; vol. 35; (1914); p. 925 View in Reaxys Schwicker, A.; Chemiker-Zeitung; vol. 15; (1891); p. 846 ; (from Gmelin) View in Reaxys With nitric acid, boiling with concd. HNO3 Jannasch, P.; Jahn, A.; Ber.; vol. 38; (1905); p. 1579 ; (from Gmelin) View in Reaxys With HNO2, byproducts: HNO3, H2O; at cold with excess of HBrO3 or with very dild. HBrO3 soln. Feit, W.; Kubierschky, K.; Chemiker-Zeitung; vol. 15; (1891); p. 352 View in Reaxys Vitali, D.; G. Farm., Chim. Sci. Affini; vol. 59; (1910); p. 18; C.; vol. I; (1910); p. 1105 View in Reaxys vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin)

141/201

2017-08-09 05:21:10

View in Reaxys With H2C2O4, byproducts: CO2, H2O Feit, W.; Kubierschky, K.; Chemiker-Zeitung; vol. 15; (1891); p. 352 View in Reaxys vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin) View in Reaxys With HBr vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin) View in Reaxys With HNO3, boiling with concd. HNO3 vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin) View in Reaxys byproducts: oxygen, H2O vol. Br: MVol.; 12, page 310 - 314 ; (from Gmelin) View in Reaxys With H2O, S, byproducts: H2SO4; at cold vol. Br: MVol.; 12, page 310 - 314 ; (from Gmelin) View in Reaxys With H2S, byproducts: H2SO4, H2O vol. Br: MVol.; 12, page 310 - 314 ; (from Gmelin) View in Reaxys With HNO2, byproducts: HNO3, H2O; at cold with excess of HBrO3 or with very dild. HBrO3 soln. Kurtenacker, A.; Ber. Wien. Akad.; vol. 122 IIb; (1913); p. 1635 ; (from Gmelin) View in Reaxys HO

Rx-ID: 7441570 View in Reaxys 501/751 Yield

Conditions & References chaulmoogric acid Ostromysslenski; Bergman; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 47; (1915); p. 328; Chem. Zentralbl.; vol. 87; nb. I; (1916); p. 695 View in Reaxys

Rx-ID: 7441572 View in Reaxys 502/751

142/201

2017-08-09 05:21:10

Yield

Conditions & References Kishner; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 47; (1915); p. 1102; Chem. Zentralbl.; vol. 87; nb. I; (1916); p. 1063 View in Reaxys

Br2Hg

Rx-ID: 26185526 View in Reaxys 503/751 Yield

Conditions & References With Cl2 in aq. soln.; in water Chateau; Bull. Soc. Chim. France (4); vol. 17; (1915); p. 121 - 124 View in Reaxys Vicario, A.; Journal de Pharmacie et de Chimie; vol. 26; (1907); p. 145 - 152 ; (from Gmelin) View in Reaxys With chromium(VI) oxide, heating with CrO3 and some drops H2O or saturated CrO3 soln.; Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 49; (1913); p. 834 - 844 ; (from Gmelin) View in Reaxys With iodine in water, at ambient temp.; Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1912); p. 4 - 14 ; (from Gmelin) View in Reaxys

With chromic acid soln.;, heating with <50percent chromic acid soln.; Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 49; (1913); p. 834 - 844 ; (from Gmelin) View in Reaxys in nitric acid, heating with concd. HNO3; Balard, A. J.; Ann. Chim. Phys.; vol. 32; (1826); p. 337 - 381 View in Reaxys Balard, A. J.; Ann. Physik (2); vol. 8; (1826); p. 319 - 336 View in Reaxys Loewig, C.; Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, S. 143 ; (from Gmelin) View in Reaxys With Cl2 in aq. soln.; in water vol. Hg: MVol.B2; 177, page 771 - 772 ; (from Gmelin) View in Reaxys With I2 in water, at ambient temp.; vol. Hg: MVol.B2; 177, page 771 - 772 ; (from Gmelin) View in Reaxys With CrO3 vol. Hg: MVol.B2; 170, page 757 - 759 ; (from Gmelin) View in Reaxys With chromic acid soln.; vol. Hg: MVol.B2; 170, page 757 - 759 ; (from Gmelin) View in Reaxys in nitric acid vol. Hg: MVol.B2; 170, page 757 - 759 ; (from Gmelin) View in Reaxys

143/201

2017-08-09 05:21:10

O Br( 1-)

H( 1+)

O–

Br Br

Rx-ID: 26414405 View in Reaxys 504/751 Yield

Conditions & References byproducts: H2O Feit, W.; Kubierschky, K.; Chemiker-Zeitung; vol. 15; (1891); p. 351 View in Reaxys Koppeschaar, W. F.; Zeitschrift fuer Analytische Chemie; vol. 15; (1876); p. 237 ; (from Gmelin) View in Reaxys Kinetics, byproducts: H2O Luther, R.; Sammet, G. V.; Zeitschrift fuer Elektrochemie; vol. 11; (1905); p. 295 - 295 View in Reaxys Clark, R. H.; Journal of Physical Chemistry; vol. 10; (1906); p. 686 View in Reaxys Judson, W.; Walker, J. W.; Journal of the Chemical Society; vol. 73; (1898); p. 417 View in Reaxys Sammet, V.; Z. phys. Ch.; vol. 53; (1905); p. 682 View in Reaxys Skrabal, A.; Weberitsch, S. R.; Monatshefte fuer Chemie; vol. 36; (1915); p. 212 ; (from Gmelin) View in Reaxys Kinetics, byproducts: H2O vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin) View in Reaxys byproducts: H2O vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin) View in Reaxys

N O

Rx-ID: 6680039 View in Reaxys 505/751 Yield

Conditions & References Bei der Bromtitration Meyer,K. H.; Wertheimer; Chemische Berichte; vol. 47; (1914); p. 2383 View in Reaxys

chromic acid

Rx-ID: 7054001 View in Reaxys 506/751 Yield

Conditions & References Kuester; Thiel; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 35; (1903); p. 43 View in Reaxys Guareschi; Fresenius' Zeitschrift fuer Analytische Chemie; vol. 53; (1914); p. 495 View in Reaxys

OH (v6)

Cr HO OO

Cr 2O3

Rx-ID: 26375754 View in Reaxys 507/751 Yield

Conditions & References in not given, in the cold Guareschi, I.; Zeitschrift fuer Analytische Chemie; vol. 53; (1914); p. 490 - 495 View in Reaxys

144/201

2017-08-09 05:21:10

vol. C: MVol.D3; 6.2.5.6.7.15, page 240 - 240 ; (from Gmelin) View in Reaxys Cl

Br Cl

Rx-ID: 7053962 View in Reaxys 508/751 Yield

Conditions & References T= 190 °C , sublimiert Boeeseken; Recueil des Travaux Chimiques des Pays-Bas; vol. 32; (1913); p. 12 View in Reaxys

Rx-ID: 7053973 View in Reaxys 509/751 Yield

Conditions & References T= 25 °C Staudinger; Anthes; Chemische Berichte; vol. 46; (1913); p. 1435 View in Reaxys

C O Rx-ID: 7072770 View in Reaxys 510/751

Yield

Conditions & References beim Aufbewahren Staudinger; Anthes; Chemische Berichte; vol. 46; (1913); p. 1435 View in Reaxys

C O

COBr2 Rx-ID: 7072834 View in Reaxys 511/751

Yield

Conditions & References T= 150 - 200 °C Staudinger; Anthes; Chemische Berichte; vol. 46; (1913); p. 1435 View in Reaxys

BrCs

Rx-ID: 26097635 View in Reaxys 512/751 Yield

Conditions & References With iodine in neat (no solvent), heating of a mixture of CsBr with iodine generated bromine; Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1913); p. 739 - 739 ; (from Gmelin) View in Reaxys With iodine in not given, heating of a soln. CsBr with iodine generated only little bromine; Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1913); p. 739 - 739 ; (from Gmelin) View in Reaxys With iodine vol. Cs: MVol.2; 38, page 180 - 182 ; (from Gmelin) View in Reaxys

145/201

2017-08-09 05:21:10

BrCu

Rx-ID: 26097672 View in Reaxys 513/751 Yield

Conditions & References in neat (no solvent), on melting; Guareschi, J.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1913); p. 735 - 749; C. II; (1913); p. 20 ; (from Gmelin) View in Reaxys With chromium(VI) oxide in water, on warming with 25percent CrO3-soln.; Guareschi, J.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1913); p. 735 - 749; C. II; (1913); p. 20 ; (from Gmelin) View in Reaxys With CrO3 in water, on warming with 25percent CrO3-soln.; vol. Cu: MVol.B1; 162, page 357 - 360 ; (from Gmelin) View in Reaxys in neat (no solvent), on melting; vol. Cu: MVol.B1; 162, page 357 - 360 ; (from Gmelin) View in Reaxys

Br (v4)

Pt BrBr

Br2Pt

Rx-ID: 26344224 View in Reaxys 514/751 Yield

Conditions & References heating at 180 °C Gutbier, A.; Heinrich, F.; Blumer, M.; Z. Anorg. Chem.; vol. 81; (1913); p. 382 View in Reaxys Pullinger, W.; Ber.; vol. 24; (1891); p. 2294 View in Reaxys Pullinger, W.; Journal of the Chemical Society; vol. 59; (1891); p. 602 - 603 ; (from Gmelin) View in Reaxys in not given, Electrolysis; in concd. soln. Halberstadt, W.; Ber.; vol. 17; (1884); p. 2962 - 2964 View in Reaxys vol. Pt: MVol.C1; 7.1, page 94 - 99 ; (from Gmelin) View in Reaxys heating at 180 °C Gutbier, A.; Blumer, M.; Sitzungsber. phys.-med. Soz. Erlangen; vol. 44; (1912); p. 109 - 112 View in Reaxys vol. Pt: MVol.C1; 7.1, page 94 - 99 ; (from Gmelin) View in Reaxys

BrRb

Rx-ID: 26395179 View in Reaxys 515/751 Yield

Conditions & References With iodine in neat (no solvent), formation of Br2 by heating of RbBr with I2 at dry state; Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1913); p. 739 - 739 ; (from Gmelin) View in Reaxys With I2 in neat (no solvent), formation of Br2 by heating of RbBr with I2 at dry state; vol. Rb: MVol.; 60, page 172 - 174 ; (from Gmelin)

146/201

2017-08-09 05:21:10

View in Reaxys O O–

H( 1+)

Rx-ID: 26418361 View in Reaxys 516/751 Yield

Conditions & References With dihydrogen peroxide in not given, byproducts: O2, H2O; in acidic soln. Bray, W. C.; Livingston, R. S.; Journal of the American Chemical Society; vol. 45; (1913); p. 1254 ; (from Gmelin) View in Reaxys With H2O2 in not given, byproducts: O2, H2O; in acidic soln. vol. Br: MVol.; 12, page 310 - 314 ; (from Gmelin) View in Reaxys

Br2Sr

Rx-ID: 26540344 View in Reaxys 517/751 Yield

Conditions & References in neat (no solvent), decomposition on heating to the melting point; Schulze, H.; Journal fuer Praktische Chemie (Leipzig); vol. 21; (1880); p. 419 - 419 View in Reaxys Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1913); p. 929 - 929 ; (from Gmelin) View in Reaxys in neat (no solvent), decomposition on heating to the melting point; vol. Sr: MVol.; 58, page 148 - 149 ; (from Gmelin) View in Reaxys

Rx-ID: 26542099 View in Reaxys 518/751 Yield

Conditions & References in liquid sulphur dioxide, Electrolysis; silver electrodes; anodic formation of Br2 and I2;; pptn.; Bruner, L.; Bekier, E.; Z. phys. Ch.; vol. 84; (1913); p. 582 - 582 ; (from Gmelin) View in Reaxys in nitrobenzene, Electrolysis; silver electrodes; anodic formation of Br2 and I2;; pptn.; Bruner, L.; Galecki, A.; Z. phys. Ch.; vol. 84; (1913); p. 534 - 534 ; (from Gmelin) View in Reaxys in nitrobenzene Bruner, L.; Galecki, A.; Z. phys. Ch.; vol. 84; (1913); p. 542 - 542 ; (from Gmelin) View in Reaxys in sulfur dioxide vol. I: MVol.2; 177, page 636 - 637 ; (from Gmelin) View in Reaxys in nitrobenzene vol. I: MVol.2; 177, page 636 - 637 ; (from Gmelin) View in Reaxys

147/201

2017-08-09 05:21:10

Br 3 Br

Br– O

Fe 3+

H N H

N H

Rx-ID: 26588823 View in Reaxys 519/751 Yield

Conditions & References in neat (no solvent), fast loss of bromine on drying; Barbieri, G. A.; Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti; vol. 22; nb. I; (1913); p. 870 - 870 View in Reaxys vol. Fe: MVol.B2; 11, page 335 - 336 ; (from Gmelin) View in Reaxys

HO Al

Br O

H 2N 2

Rx-ID: 7060064 View in Reaxys 520/751 Yield

Conditions & References Staudinger; Chemische Berichte; vol. 45; (1912); p. 1594 View in Reaxys

Br2Hg

HgI 2

Rx-ID: 26083493 View in Reaxys 521/751 Yield

Conditions & References at heating; Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1912); p. 4 - 14 ; (from Gmelin) View in Reaxys at heating; vol. Hg: MVol.B2; 169, page 755 - 757 ; (from Gmelin) View in Reaxys

O S

BrNa

Rx-ID: 26097562 View in Reaxys 522/751 Yield

Conditions & References in further solvent(s), fast dissolving of NaBr in liquid SO3, decompn.;; violent generation of Br2; Beckmann, E.; Z. Anorg. Chem.; vol. 77; (1912); p. 90 - 102 View in Reaxys Haring, K.; Diss. Leipzig 1910, S. 20 ; (from Gmelin) View in Reaxys in further solvent(s), fast dissolving of NaBr in boiling SO3, decompn.;; violent generation of Br2; Beckmann, E.; Z. Anorg. Chem.; vol. 77; (1912); p. 90 - 102 View in Reaxys Haring, K.; Diss. Leipzig 1910, S. 20 ; (from Gmelin) View in Reaxys in further solvent(s), fast dissolving of NaBr in liquid SO3, decompn.;; violent generation of Br2; vol. S: MVol.B1; 164, page 361 - 363 ; (from Gmelin) View in Reaxys in further solvent(s), fast dissolving of NaBr in boiling SO3, decompn.;; violent generation of Br2; vol. S: MVol.B1; 164, page 361 - 363 ; (from Gmelin)

148/201

2017-08-09 05:21:10

View in Reaxys Br

Br2Co

Rx-ID: 26185437 View in Reaxys 523/751 Yield

Conditions & References With air in neat (no solvent), decompn. at heating on air under developement of bromine; Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1912); p. 941 - 941 View in Reaxys Schulze, H.; Journal fuer Praktische Chemie (Leipzig); vol. 21; (1880); p. 420 - 420 ; (from Gmelin) View in Reaxys With air in neat (no solvent), decompn. at heating on air under developement of bromine; vol. Co: MVol.A2; 30, page 302 - 304 ; (from Gmelin) View in Reaxys

Br2Hg 2

HgI 2

Rx-ID: 26366862 View in Reaxys 524/751 Yield

Conditions & References at heating with excess of iodine; Guareschi, I.; Atti Accad. Sci. Torino; vol. 48; (1912); p. 735 - 749 ; (from Gmelin) View in Reaxys vol. Hg: MVol.B2; 156, page 728 - 730 ; (from Gmelin) View in Reaxys

Br2Hg 2

Rx-ID: 26533273 View in Reaxys 525/751 Yield 0%

Conditions & References at fast heating to temp. above sublimation temp.; Guareschi, I.; Atti Accad. Sci. Torino; vol. 48; (1912); p. 735 - 749 ; (from Gmelin) View in Reaxys With chromium(VI) oxide, water Guareschi, I.; Atti Accad. Sci. Torino; vol. 48; (1912); p. 735 - 749 ; (from Gmelin) View in Reaxys

With chromic acid, heating with 25-50percent chromic acid soln.; Guareschi, I.; Atti Accad. Sci. Torino; vol. 48; (1912); p. 735 - 749 ; (from Gmelin) View in Reaxys vol. Hg: MVol.B2; 156, page 728 - 730 ; (from Gmelin) View in Reaxys With CrO3, H2O vol. Hg: MVol.B2; 156, page 728 - 730 ; (from Gmelin) View in Reaxys With chromic acid vol. Hg: MVol.B2; 156, page 728 - 730 ; (from Gmelin) View in Reaxys

Br2Ca

Rx-ID: 26540365 View in Reaxys 526/751

149/201

2017-08-09 05:21:10

Yield

Conditions & References in neat (no solvent), formation of Br2 at heating under melting point; Guareschi, I.; Atti R. Accad. Sci. Torino, Cl. Sci. Fis., Mat. Nat.; vol. 48; (1912); p. 929 - 947 ; (from Gmelin) View in Reaxys in neat (no solvent), formation of Br2 at smelting in air; Schulze, H.; Journal fuer Praktische Chemie (Leipzig); vol. 21; nb. 2; (1880); p. 407 - 443 ; (from Gmelin) View in Reaxys in neat (no solvent), formation of Br2 at smelting in air; vol. Ca: MVol.B2; 140, page 587 - 589 ; (from Gmelin) View in Reaxys With air in neat (no solvent), formation of Br2 at heating in air; Richards, T. W.; Hoenigschmid, O.; Journal of the American Chemical Society; vol. 32; (1910); p. 1577 - 1590 View in Reaxys Richards, T. W.; Hoenigschmid, O.; Monatshefte fuer Chemie; vol. 31; (1910); p. 1203 - 1226 View in Reaxys vol. Ca: MVol.B2; 140, page 587 - 589 ; (from Gmelin) View in Reaxys in neat (no solvent), formation of Br2 at heating under melting point; vol. Ca: MVol.B2; 140, page 587 - 589 ; (from Gmelin) View in Reaxys

Br Fe Br

(v3)

Rx-ID: 26158499 View in Reaxys 527/751 Yield

Conditions & References With chlorine in water, byproducts: FeCl3; introducing Br2 into concd. aq. FeBr3 soln.; introducing Cl2 isolated Br2 vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Barstow, E. O.; AU14921; (1911) ; (from Gmelin) View in Reaxys

Br2Hg

Br2Hg 2

Rx-ID: 26185527 View in Reaxys 528/751 Yield

Conditions & References in further solvent(s), Electrolysis; in molten AlBr3; Pt electrodes;; bromine precipitated on anode, Hg on cathode; Izbekov, V. A.; Plotnikov, V. A.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 71; (1911); p. 328 - 346 View in Reaxys Izbekov, V. A.; Plotnikov, V. A.; Zh. Russk. Fiz.-Khim. Obshchestva (Chast Khim.); vol. 43; (1911); p. 18 - 37 ; (from Gmelin) View in Reaxys in further solvent(s), Electrolysis; in molten AlBr3; Pt electrodes;; bromine precipitated on anode, Hg on cathode; vol. Hg: MVol.B2; 169, page 755 - 757 ; (from Gmelin) View in Reaxys

Br O

OH HO

Rx-ID: 7053975 View in Reaxys 529/751

150/201

2017-08-09 05:21:10

Yield

Conditions & References Quensell; Chemische Berichte; vol. 42; (1909); p. 2444 View in Reaxys

Br H

Rx-ID: 7053979 View in Reaxys 530/751 Yield

Conditions & References Rosenmund; Chemische Berichte; vol. 42; (1909); p. 4472 View in Reaxys O

tribromoresorcinol

O Br

Rx-ID: 7458700 View in Reaxys 531/751 Yield

Conditions & References T= 160 °C Zincke; Schwabe; Chemische Berichte; vol. 42; (1909); p. 802 View in Reaxys Liebermann; Dittler; Justus Liebigs Annalen der Chemie; vol. 169; (1873); p. 256 View in Reaxys Meyer,R.; Desamari; Chemische Berichte; vol. 41; (1908); p. 2443; Chemische Berichte; vol. 42; (1909); p. 2817 View in Reaxys Cl

Cl Cl

O O

O Cl

Rx-ID: 8213756 View in Reaxys 532/751 Yield

Conditions & References T= 175 °C Zincke; Schwabe; Chemische Berichte; vol. 42; (1909); p. 802 View in Reaxys

Br O

Na +

Br O

–

H 2N 2

carbon monoxide Rx-ID: 8270856 View in Reaxys 533/751

Yield

Conditions & References weitere Produkte:Sauerstoff,Bromwasserstoff.Electrolysis Kaufler; Herzog; Chemische Berichte; vol. 42; (1909); p. 3868 View in Reaxys

NH 2

Br O

N O

nitrogen oxides

NH 2

Rx-ID: 8282403 View in Reaxys 534/751 Yield

Conditions & References beim Erhitzen ueber den Schmelzpunkt van Peski junior; Chemische Berichte; vol. 42; (1909); p. 2764

151/201

2017-08-09 05:21:10

View in Reaxys K+

Br O

BrK

O–

Rx-ID: 26111329 View in Reaxys 535/751 Yield

Conditions & References

>99

With cobalt(II) dibromide in water, at room temp. slow, at b.p. fast reaction; instead of KBrO3 also possible to use other alkali or alkaline earth bromates; isolation of Br2 directly from vapor; crystn. of KBr after filtering vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Jones, C. W.; Schaefer, A. E.; AU03121; (1909) ; (from Gmelin) View in Reaxys

>99

With FeBr2 in water, byproducts: Fe2O3; at room temp. slow, at b.p. fast reaction; instead of KBrO3 also possible to use other alkali or alkaline earth bromates; isolation of Br2 directly from vapor; crystn. of KBr after filtering of Fe2O3 vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Jones, C. W.; Schaefer, A. E.; AU03121; (1909) ; (from Gmelin) View in Reaxys

>99

With niobium bromide in water, at room temp. slow, at b.p. fast reaction; instead of KBrO3 also possible to use other alkali or alkaline earth bromates; isolation of Br2 directly from vapor; crystn. of KBr after filtering vol. Br: MVol.; 1.2, page 40 - 44 View in Reaxys Patent; Jones, C. W.; Schaefer, A. E.; AU03121; (1909) ; (from Gmelin) View in Reaxys With chlorine, byproducts: chloride; heating in closed tube at 200 ° C Potylizyn, A.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 19; (1887); p. 361 ; (from Gmelin) View in Reaxys With chlorine vol. K: MVol.3; 1.6.2, page 580 - 581 ; (from Gmelin) View in Reaxys

Na +

O–

Rx-ID: 26166741 View in Reaxys 536/751 Yield

Conditions & References in water, Electrolysis Kaufler, F.; Herzog, C.; Ber.; vol. 42; (1909); p. 3868 ; (from Gmelin) View in Reaxys in water vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys

Br -1 O

(v1)

Rx-ID: 26349260 View in Reaxys 537/751 Yield

Conditions & References With carbon dioxide in not given Dancer, W.; Journal of the Chemical Society; vol. 15; (1862); p. 479

152/201

2017-08-09 05:21:10

View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys With acids, also with very weak acids (e.g. H2CO3) Dancer, W.; Journal of the Chemical Society; vol. 15; (1862); p. 479 View in Reaxys Schoenbein, C. F.; Justus Liebigs Annalen der Chemie; vol. 2; (1863); p. 217 - 218 View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys With cellulose Dehn, W. M.; Journal of the American Chemical Society; vol. 31; (1909); p. 527 ; (from Gmelin) View in Reaxys With acids, also with very weak acids (e.g. H2CO3) Balard, A. J.; Journal fuer Praktische Chemie (Leipzig); vol. 4; (1835); p. 172 View in Reaxys Dancer, W.; Liebigs Annalen der Chemie; vol. 125; (1863); p. 239 ; (from Gmelin) View in Reaxys With CO2 in not given Balard, A. J.; Journal fuer Praktische Chemie (Leipzig); vol. 4; (1835); p. 172 View in Reaxys Dancer, W.; Liebigs Annalen der Chemie; vol. 125; (1863); p. 239 ; (from Gmelin) View in Reaxys With cellulose vol. Br: MVol.; 11.3, page 299 - 303 ; (from Gmelin) View in Reaxys

N O

H N

Br Cl

2.4.6-trichloro-benzenediazonium salt

Rx-ID: 7054039 View in Reaxys 538/751 Yield

Conditions & References die Gegenwart von Salpetersaeure wirkt aehnlich Orton; Pearson; Journal of the Chemical Society; vol. 93; (1908); p. 735 View in Reaxys

N O

H N

Br Cl

2.4.6-trichloro-benzenediazonium salt

Br Br

Rx-ID: 7054040 View in Reaxys 539/751 Yield

Conditions & References die Gegenwart von Salpetersaeure wirkt aehnlich Orton; Pearson; Journal of the Chemical Society; vol. 93; (1908); p. 735 View in Reaxys

153/201

2017-08-09 05:21:10

N O

H N

H 2N

Br N

NH 2

O Br

Rx-ID: 7054042 View in Reaxys 540/751 Yield

Conditions & References Orton; Pearson; Journal of the Chemical Society; vol. 93; (1908); p. 735 View in Reaxys

N O

H N

H 2N

Br H

NH 2

O Br

Rx-ID: 7054043 View in Reaxys 541/751 Yield

Conditions & References Orton; Pearson; Journal of the Chemical Society; vol. 93; (1908); p. 735 View in Reaxys

N O

H N

H 2N

Br O

NH 2

O Br

Rx-ID: 7054044 View in Reaxys 542/751 Yield

Conditions & References Orton; Pearson; Journal of the Chemical Society; vol. 93; (1908); p. 735 View in Reaxys O Br

O O

nitrogen oxides

Rx-ID: 8282404 View in Reaxys 543/751 Yield

Conditions & References beim Erhitzen auf den Schmelzpunkt Wislicenus; Waldmueller; Chemische Berichte; vol. 41; (1908); p. 3338 View in Reaxys

N O Br

Br O

Br N

nitrogen oxides

Rx-ID: 8282405 View in Reaxys 544/751 Yield

Conditions & References Wislicenus,W.; Elvert; Chemische Berichte; vol. 41; (1908); p. 4131 View in Reaxys

N Br O

N O O

4-nitro-benzoyl cyanide (?)

nitrogen oxides

Rx-ID: 8282408 View in Reaxys 545/751

154/201

2017-08-09 05:21:10

Yield

Conditions & References Wislicenus; Schaefer; Chemische Berichte; vol. 41; (1908); p. 4170 View in Reaxys H

Br2Ra

Rx-ID: 26604053 View in Reaxys 546/751 Yield

Conditions & References With oxygen, gradual decompn.; Ramsay, W.; Monatshefte fuer Chemie; vol. 29; (1908); p. 1013 - 1013 ; (from Gmelin) View in Reaxys With O2, gradual decompn.; vol. Ra: MVol.; 17, page 61 - 63 ; (from Gmelin) View in Reaxys O

Rx-ID: 5574984 View in Reaxys 547/751 Yield

Conditions & References Tafel; Wassmuth; Chemische Berichte; vol. 40; (1907); p. 2840 View in Reaxys

Rx-ID: 7054027 View in Reaxys 548/751 Yield

Conditions & References Lespieau; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 144; (1907); p. 1161 View in Reaxys O

Br H

Br2

(v3)

air

Rx-ID: 8213758 View in Reaxys 549/751 Yield

Conditions & References Feist; Chemische Berichte; vol. 40; (1907); p. 3649,3650 View in Reaxys O

Br H

(v3)

Br2

air

Rx-ID: 8213759 View in Reaxys 550/751 Yield

Conditions & References Feist; Chemische Berichte; vol. 40; (1907); p. 3649,3650 View in Reaxys

155/201

2017-08-09 05:21:10

(v4)

NH 3 (v4) (v6) (v4) H 3N Co NH 3H NH O H 3 (v4) H 3N (v3) (v3) NH (v4) H 3 (v3)Co NH 6 Br– O (v3) CoO6+ O (v6) 3 (v3)O (v6) H H (v4) H N(v6) O H NH 3 (v4) Co (v3) 3 NH H 3N 3 (v4) (v4)

Br + N CoBr 3H NH 3N (v6) 3 (v4) NH 3 (v4)

(v4) BrH –

(v4)

NH 3 (v4)

H O

Rx-ID: 26312990 View in Reaxys 551/751 Yield

Conditions & References in water, heating {Co(NH3)4Br2}Br carefully in a small amount of water; formation of Br2; the dark green educt becomes red brown and dissolves fastly with dark colour; fast filtration; ppt. of crude product; Werner, A.; Ber.; vol. 40; (1907); p. 2113 - 2113 View in Reaxys vol. Co: MVol.B; 166, page 370 - 372 ; (from Gmelin) View in Reaxys O Cl

Br( 1-)

O–

Br Br

Rx-ID: 26414402 View in Reaxys 552/751 Yield

Conditions & References With V(III)-salt in water Luther; Zeitschrift fuer Elektrochemie; vol. 13; (1907); p. 437 - 437 View in Reaxys vol. Cl: MVol.; 122, page 324 - 326 View in Reaxys Rutter; Dissert. Leipzig 1906, S. 60 ; (from Gmelin) View in Reaxys

Br H

BrH N 2

(v3)

Rx-ID: 8213719 View in Reaxys 553/751 Yield

Conditions & References T= 120 °C Fries; Justus Liebigs Annalen der Chemie; vol. 346; (1906); p. 195; Chemische Berichte; vol. 37; (1904); p. 2342 View in Reaxys Br

Br H

BrH N 2

(v3)

Rx-ID: 8213722 View in Reaxys 554/751 Yield

Conditions & References T= 110 °C Fries; Justus Liebigs Annalen der Chemie; vol. 346; (1906); p. 195; Chemische Berichte; vol. 37; (1904); p. 2342 View in Reaxys Br

Br H

(v3)

air

Rx-ID: 8213730 View in Reaxys 555/751

156/201

2017-08-09 05:21:10

Yield

Conditions & References Fries; Justus Liebigs Annalen der Chemie; vol. 346; (1906); p. 195; Chemische Berichte; vol. 37; (1904); p. 2342 View in Reaxys

Br 2

HO Br

Rx-ID: 8213755 View in Reaxys 556/751 Yield

Conditions & References Zincke; Fischer; Justus Liebigs Annalen der Chemie; vol. 350; (1906); p. 261 View in Reaxys

Br H

(v3)

air

C8H9NBr2+HBr

Rx-ID: 8270545 View in Reaxys 557/751 Yield

Conditions & References Fries; Justus Liebigs Annalen der Chemie; vol. 346; (1906); p. 195; Chemische Berichte; vol. 37; (1904); p. 2342 View in Reaxys

Br H

BrH N 2

(v3)

air

hydrobromide of 3.5-dibromo-2-amino-toluene

Rx-ID: 8277286 View in Reaxys 558/751 Yield

Conditions & References Fries; Justus Liebigs Annalen der Chemie; vol. 346; (1906); p. 195; Chemische Berichte; vol. 37; (1904); p. 2342 View in Reaxys

Br H

air

hydrobromide of 5-bromo-2-methyl-amino-toluene

(v3)

Rx-ID: 8277292 View in Reaxys 559/751 Yield

Conditions & References Fries; Justus Liebigs Annalen der Chemie; vol. 346; (1906); p. 195; Chemische Berichte; vol. 37; (1904); p. 2342 View in Reaxys

Br H

BrH 2N

hydrobromide of asymm. m-xylidine

(v3)

Rx-ID: 8277302 View in Reaxys 560/751 Yield

Conditions & References an der Luft Fries; Justus Liebigs Annalen der Chemie; vol. 346; (1906); p. 195; Chemische Berichte; vol. 37; (1904); p. 2342 View in Reaxys

(v4)

Rx-ID: 26070073 View in Reaxys 561/751 Yield 0%

Conditions & References in not given, reaction in acidic soln.; Inglis, J. K. H.; Journal of the Chemical Society; vol. 83; (1903); p. 1010 - 1014

157/201

2017-08-09 05:21:10

View in Reaxys Treadwell, F. P.; Anneler, E.; Z. Anorg. Chem.; vol. 48; (1906); p. 86 - 97 View in Reaxys vol. O: MVol.4; 87, page 1174 - 1176 ; (from Gmelin) View in Reaxys

Br (v0)

F SbFF

Rx-ID: 26170211 View in Reaxys 562/751 Yield

Conditions & References at >140 °C Ruff, O.; Graf, H; Heller, W.; Knoch; Ber.; vol. 39; (1906); p. 4315 ; (from Gmelin) View in Reaxys Br2 gas in wet air Ruff, O.; Graf, H; Heller, W.; Knoch; Ber.; vol. 39; (1906); p. 4315 ; (from Gmelin) View in Reaxys at >140 °C vol. Sb: MVol.B2; 8.4, page 399 - 405 ; (from Gmelin) View in Reaxys Br2 gas in wet air vol. Sb: MVol.B2; 8.4, page 399 - 405 ; (from Gmelin) View in Reaxys

H N

AuBr

Rx-ID: 26447162 View in Reaxys 563/751 Yield

Conditions & References byproducts: NH3, NH4Br; by heating Meyer, F.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 143; (1906); p. 280 282 View in Reaxys Meyer, F.; These Paris 1912, p.71/72 ; (from Gmelin) View in Reaxys byproducts: NH3, NH4Br; by heating vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin) View in Reaxys

Rx-ID: 26487114 View in Reaxys 564/751 Yield 0%

Conditions & References With oleum or CrO3 Bartal, A. v.; Liebigs Annalen der Chemie; vol. 345; (1906); p. 334 - 353 View in Reaxys vol. C: MVol.D3; 2.4.2, page 110 - 112 ; (from Gmelin) View in Reaxys

158/201

2017-08-09 05:21:10

O O

S OO

Rx-ID: 8213707 View in Reaxys 565/751 Yield

Conditions & References Ullmann; Lehner; Chemische Berichte; vol. 38; (1905); p. 735 View in Reaxys O

2 NH –+O 4

O O

O–

Br( 1-)

Rx-ID: 26109308 View in Reaxys 566/751 Yield

Conditions & References With nitric acid in not given, heating Dittrich, M.; Bollenbach, H.; Ber.; vol. 38; (1905); p. 784 ; (from Gmelin) View in Reaxys With HNO3 in not given, heating vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys Br

Br2Ra

Rx-ID: 26160757 View in Reaxys 567/751 Yield

Conditions & References by storage Bellini, G.; Vazzari, M.; Gazzetta Chimica Italiana; vol. 35 II; (1905); p. 64 ; (from Gmelin) View in Reaxys vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys

F Br

F F

F Br

Rx-ID: 26456818 View in Reaxys 568/751 Yield

Conditions & References With iodine, heating from -10°C Prideaux, E. B. R.; Proceedings of the Chemical Society, London; vol. 21; (1905); p. 240 ; (from Gmelin) View in Reaxys With I2, heating from -10°C vol. Br: MVol.; 13.2, page 337 - 342 ; (from Gmelin) View in Reaxys O

2 NH –+O 4

S O

O O

O–

Rx-ID: 26516812 View in Reaxys 569/751 Yield

Conditions & References With potassium bromide in water, soln. slightly acidified by HNO3 Dittrich, M.; Bollenbach, H.; Ber.; vol. 38; (1905); p. 747 - 751 ; (from Gmelin) View in Reaxys With KBr in water, soln. slightly acidified by HNO3

159/201

2017-08-09 05:21:10

vol. S: MVol.B2; 6, page 808 - 852 ; (from Gmelin) View in Reaxys O 2 NH –+O 4

O O

Ag+

O–

Rx-ID: 26516813 View in Reaxys 570/751 Yield

Conditions & References With silver nitrate, potassium bromide in water, byproducts: AgBr Dittrich, M.; Bollenbach, H.; Ber.; vol. 38; (1905); p. 747 - 751 ; (from Gmelin) View in Reaxys With KBr, AgNO3 in water, byproducts: AgBr vol. S: MVol.B2; 6, page 808 - 852 ; (from Gmelin) View in Reaxys 2

K+

2Br PdBr Br Br

(v6)

Rx-ID: 26542760 View in Reaxys 571/751 Yield

Conditions & References With H2O or H2SO4, with hot H2O or concd. H2SO4 soln., decompn. with evolving of bromine; Gutbier, A.; Krell, A.; Ber.; vol. 38; (1905); p. 2386 - 2386 View in Reaxys Gutbier, A.; Krell, A.; Ber.; vol. 38; (1905); p. 2388 - 2388 ; (from Gmelin) View in Reaxys With H2O or H2SO4, with hot H2O or concd. H2SO4 soln., decompn. with evolving of bromine; vol. Pd: MVol.2; 84, page 315 - 318 ; (from Gmelin) View in Reaxys H

2 Br 2Br PdBr Br Br (v6) Br

N+ HH

Br–

NH +4

Rx-ID: 26617682 View in Reaxys 572/751 Yield

Conditions & References in neat (no solvent), on heating in dry tube, first evolving of Br2, then of NH4Br, pptn. of Pd sponge; Gutbier, A.; Krell, A.; Ber.; vol. 38; (1905); p. 2387 - 2387 ; (from Gmelin) View in Reaxys in neat (no solvent), on heating in dry tube, first evolving of Br2, then of NH4Br, pptn. of Pd sponge; vol. Pd: MVol.2; 87, page 322 - 324 ; (from Gmelin) View in Reaxys O

HO O

N H

H N

Br O

Rx-ID: 7053978 View in Reaxys 573/751 Yield

Conditions & References Fischer,E.; Chemische Berichte; vol. 37; (1904); p. 2505 View in Reaxys

160/201

2017-08-09 05:21:10

O HO O

H N

N H

Rx-ID: 7053989 View in Reaxys 574/751 Yield

Conditions & References Fischer,E.; Chemische Berichte; vol. 37; (1904); p. 2505 View in Reaxys O

Br -1 O

Br Br

(v1)

O–

Rx-ID: 26349270 View in Reaxys 575/751 Yield

Conditions & References byproducts: H2O; this side reation in synthesis of BrO(1-) results const. free bromine concn. Kretschmar, H.; Zeitschrift fuer Elektrochemie; vol. 10; (1904); p. 798 ; (from Gmelin) View in Reaxys byproducts: H2O; this side reation in synthesis of BrO(1-) results const. free bromine concn. vol. Br: MVol.; 11.1, page 291 - 294 ; (from Gmelin) View in Reaxys O

Br( 1-)

O–

Rx-ID: 26349543 View in Reaxys 576/751 Yield

Conditions & References Kretschmar, H.; Zeitschrift fuer Elektrochemie; vol. 10; (1904); p. 799 View in Reaxys Pauli, H.; Zeitschrift fuer Elektrochemie; vol. 3; (1896); p. 476 View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys byproducts: H2O Kretschmar, H.; Zeitschrift fuer Elektrochemie; vol. 10; (1904); p. 798 View in Reaxys Schoenbein, C. F.; Justus Liebigs Annalen der Chemie; vol. 2; (1863); p. 218 View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys

Br2In

BrIn

Rx-ID: 26441317 View in Reaxys 577/751 Yield

Conditions & References in vapour state Thiel, A.; Z. Anorg. Chem.; vol. 40; (1904); p. 329 ; (from Gmelin) View in Reaxys in vapour state vol. In: MVol.; 3.7.2, page 87 - 90 ; (from Gmelin) View in Reaxys Cu 2+

-1

Br P Br

O 2

Br2Cu 2

(v1)

Rx-ID: 26463411 View in Reaxys 578/751

161/201

2017-08-09 05:21:10

Yield

Conditions & References in neat (no solvent), vigorous reaction releasing gaseous Br2; discoloration; Christomanos, A. C.; Z. Anorg. Chem.; vol. 41; (1904); p. 280 - 290 ; (from Gmelin) View in Reaxys in not given, vigorous reaction releasing gaseous Br2; discoloration; Christomanos, A. C.; Z. Anorg. Chem.; vol. 41; (1904); p. 280 - 290 ; (from Gmelin) View in Reaxys in not given, vigorous reaction releasing gaseous Br2; discoloration; vol. P: MVol.C; 216, page 496 - 498 ; (from Gmelin) View in Reaxys in neat (no solvent), vigorous reaction releasing gaseous Br2; discoloration; vol. P: MVol.C; 216, page 496 - 498 ; (from Gmelin) View in Reaxys

Br P

O5P2

Rx-ID: 26469893 View in Reaxys 579/751 Yield

Conditions & References With oxygen in neat (no solvent), reaction with boiling PBr3; Christomanos, A. C.; Z. Anorg. Chem.; vol. 41; (1904); p. 276 - 290 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys Br OH

Rx-ID: 7054045 View in Reaxys 580/751 Yield

Conditions & References beim Erhitzen, dibromide of/the/ trans-α.α.γ-trimethyl-glutaconic acid Perkin; Smith; Journal of the Chemical Society; vol. 83; (1903); p. 779 View in Reaxys

Rx-ID: 8213709 View in Reaxys 581/751 Yield

Conditions & References an feuchter Luft Slosson; American Chemical Journal; vol. 29; (1903); p. 302 View in Reaxys O

H 2N

NH 2

O Br

Rx-ID: 8213711 View in Reaxys 582/751 Yield

Conditions & References Moore; Journal of the American Chemical Society; vol. 25; (1903); p. 627 View in Reaxys

162/201

2017-08-09 05:21:10

O O

K+

(v6) – O

O–

(v6)

Rx-ID: 26102508 View in Reaxys 583/751 Yield

Conditions & References

in melt, melting of K2Cr2O7 with KI and some KBr; no formation of Br2; Koninck, L. L. de; Bulletin des Societes Chimiques Belges; vol. 17; (1903); p. 157 - 165 View in Reaxys vol. Cr: MVol.B; 251, page 556 - 558 ; (from Gmelin) View in Reaxys

O O

K+

(v6) – O

(v6)

+ 2 O– K

Cr 2O3

O–

(v6)

O–

Rx-ID: 26183832 View in Reaxys 584/751 Yield

Conditions & References With potassium bromide in melt, melting of educts; Koninck, L. L. de; Bulletin des Societes Chimiques Belges; vol. 17; (1903); p. 157 - 165 View in Reaxys vol. Cr: MVol.B; 251, page 556 - 558 ; (from Gmelin) View in Reaxys H

2 Br 2

Br SbBr Br

Br3Cs 3

Rx-ID: 26633653 View in Reaxys 585/751 Yield

Conditions & References in neat (no solvent), 3CsBr*2SbBr5*2H2O looses rapidly Br2 in air with discoloration towards yellow; Weinland, R. F.; Feige, C.; Ber.; vol. 36; (1903); p. 257 - 257 ; (from Gmelin) View in Reaxys in neat (no solvent), 3CsBr*2SbBr5*2H2O looses rapidly Br2 in air with discoloration towards yellow; vol. Cs: MVol.2; 73, page 248 - 250 ; (from Gmelin) View in Reaxys Br

OH Br

alkalies

Rx-ID: 7053999 View in Reaxys 586/751 Yield

Conditions & References Doebner; Chemische Berichte; vol. 35; (1902); p. 1137 View in Reaxys Br

H N

Br O

Rx-ID: 8213747 View in Reaxys 587/751 Yield

Conditions & References T= 190 °C

163/201

2017-08-09 05:21:10

Chattaway; Journal of the Chemical Society; vol. 81; (1902); p. 819 View in Reaxys O

Rx-ID: 26062193 View in Reaxys 588/751 Yield

Conditions & References Wedekind, E.; Ber.; vol. 35; (1902); p. 2267 ; (from Gmelin) View in Reaxys vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys –O

K+

S O

O–

S OO

Rx-ID: 26082189 View in Reaxys 589/751 Yield

Conditions & References with concd. HBr, at ambient temp. under warm evolution Wedekind, E.; Ber.; vol. 35; (1902); p. 2267 - 2269 View in Reaxys Wedekind, E.; Bulletin de la Societe Chimique de France; vol. 27; (1902); p. 712 - 714 ; (from Gmelin) View in Reaxys at ambient temp. under warm evolution Wedekind, E.; Ber.; vol. 35; (1902); p. 2267 - 2269 View in Reaxys Wedekind, E.; Bulletin de la Societe Chimique de France; vol. 27; (1902); p. 712 - 714 ; (from Gmelin) View in Reaxys at ambient temp. under warm evolution vol. S: MVol.B2; 5, page 798 - 808 ; (from Gmelin) View in Reaxys with concd. HBr, at ambient temp. under warm evolution vol. S: MVol.B2; 5, page 798 - 808 ; (from Gmelin) View in Reaxys

Br O

(v6)

Rx-ID: 26159212 View in Reaxys 590/751 Yield

Conditions & References thermal decompn. Oechsner de Coninck; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 135; (1902); p. 900 ; (from Gmelin) View in Reaxys vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys

Br Al Br

S S

Br4

Rx-ID: 26326486 View in Reaxys 591/751

164/201

2017-08-09 05:21:10

Yield

Conditions & References With water, byproducts: HBr; decompn.; violent Plotnikow, W.; Z. Anorg. Chem.; vol. 31; (1902); p. 130 ; (from Gmelin) View in Reaxys With H2O, byproducts: HBr; decompn.; violent vol. Al: MVol.B1; 7.2.1, page 230 - 236 ; (from Gmelin) View in Reaxys

Br Al

S S

Br4

Rx-ID: 26328612 View in Reaxys 592/751 Yield

Conditions & References With water, byproducts: HBr; decompn.; violent Plotnikow, W.; Z. Anorg. Chem.; vol. 31; (1902); p. 128 ; (from Gmelin) View in Reaxys With H2O, byproducts: HBr; decompn.; violent vol. Al: MVol.B1; 7.2.1, page 230 - 236 ; (from Gmelin) View in Reaxys K+

O (v6)

Cr – OBr

Rx-ID: 26393078 View in Reaxys 593/751 Yield

Conditions & References in water, heating; Ditte, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 134; (1902); p. 336 343 ; (from Gmelin) View in Reaxys in neat (no solvent), at ambient temp.; Heintze, L. J.; Journal fuer Praktische Chemie (Leipzig); vol. 4; (1871); p. 211 - 226 ; (from Gmelin) View in Reaxys in water, heating; vol. Cr: MVol.B; 271, page 600 - 602 ; (from Gmelin) View in Reaxys in neat (no solvent), at ambient temp.; vol. Cr: MVol.B; 271, page 600 - 602 ; (from Gmelin) View in Reaxys

Rx-ID: 26436589 View in Reaxys 594/751 Yield

Conditions & References Chattaway, F. D.; Wadmore, J. M.; Journal of the Chemical Society; vol. 81; (1902); p. 197 - 197 View in Reaxys vol. I: MVol.2; 96, page 456 - 457 ; (from Gmelin) View in Reaxys

165/201

2017-08-09 05:21:10

Cl H 2N

O Br

Rx-ID: 7441571 View in Reaxys 595/751 Yield

Conditions & References Chattaway; Orton; Journal of the Chemical Society; vol. 79; (1901); p. 818 View in Reaxys Cl

H 2N

Rx-ID: 7441578 View in Reaxys 596/751 Yield

Conditions & References Chattaway; Orton; Journal of the Chemical Society; vol. 79; (1901); p. 467,827 View in Reaxys

Rx-ID: 8213710 View in Reaxys 597/751 Yield

Conditions & References Kaufler; Monatshefte fuer Chemie; vol. 22; (1901); p. 1081 View in Reaxys O

(v4)

BrK

Br -1 O

(v1)

O–

Rx-ID: 26069859 View in Reaxys 598/751 Yield

Conditions & References in not given, reaction by introducing of O3 in a 5percent KBr soln.; Garzarolli-Thurnlackh, K.; Ber. Wien. Akad.; vol. 110; nb. II b; (1901); p. 787 - 807 View in Reaxys Garzarolli-Thurnlackh, K.; Monatshefte fuer Chemie; vol. 22; (1901); p. 955 - 975 View in Reaxys vol. O: MVol.4; 87, page 1174 - 1176 ; (from Gmelin) View in Reaxys O

Br( 1-)

H( 1+)

O–

Br Br

Rx-ID: 26109286 View in Reaxys 599/751 Yield

Conditions & References in not given, byproducts: H2O, I2; excess of H(1+) Ditz, H.; Margosches, B. M.; Angewandte Chemie; vol. 14; (1901); p. 1083 ; (from Gmelin) View in Reaxys in not given, byproducts: H2O, I2; excess of H(1+) vol. Br: MVol.; 7.5, page 233 - 239 ; (from Gmelin) View in Reaxys

166/201

2017-08-09 05:21:10

Cl 3KMg carnallite

Rx-ID: 26179031 View in Reaxys 600/751 Yield

Conditions & References from final liquor of carnallite fabricating (0.2-0.3 percent Br); sepn. by distn. Wuensche, A.; Jb. Elektroch.; vol. 7; (1901); p. 347 View in Reaxys Schloetter, M.; Ueber die elektrolytische Gewinnung von Brom und Jod in: Engelhardt, V., Monographien ueber angewandte Elektrochemie, Knapp, W., Halle a. S. 1907, Bd. 27, S. 4, 13 ; (from Gmelin) View in Reaxys With chlorine in water, pure product with Cl2 Braeuer, A.; D'Ans, J.; Fortschritte in der anorganisch-chemischen Industrie an Hand der Deutschen Reichs-Patente, Springer, J., Berlin 1921, Bd. 1, S. 351 ; (from Gmelin) View in Reaxys vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys With Cl2, acid in water vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys

(v2)

Br– Br Br

P+

BrBr

P Br Br

Rx-ID: 26586605 View in Reaxys 601/751 Yield

Conditions & References

With water in carbon disulfide, shaking aq. soln. with CS2; Kastle, J. H.; Beatty, L. O.; American Chemical Journal; vol. 23; (1900); p. 505 - 509 ; (from Gmelin) View in Reaxys

With H2O in carbon disulfide, shaking aq. soln. with CS2; vol. P: MVol.C; 219, page 503 - 506 ; (from Gmelin) View in Reaxys S N (v4)

(v4)

– 3N CoNH + 3 BrH NH 3 H 3N (v6) (v4)

(v4)

N O O

Rx-ID: 26615846 View in Reaxys 602/751 Yield

Conditions & References With sulfuric acid, with cold concd. H2SO4 vigorous formation of Br2; Werner, A.; Klien, R.; Z. Anorg. Chem.; vol. 22; (1900); p. 115 - 115 ; (from Gmelin) View in Reaxys With H2SO4, with cold concd. H2SO4 vigorous formation of Br2; vol. Co: MVol.B; 114, page 266 - 268 ; (from Gmelin) View in Reaxys

167/201

2017-08-09 05:21:10

O Ag+

O–

Rx-ID: 7053992 View in Reaxys 603/751 Yield

Conditions & References Bergesio; Sabbatani; Chem. Zentralbl.; vol. 70; nb. I; (1899); p. 596 View in Reaxys

O O S HO O

alkali

Rx-ID: 8470388 View in Reaxys 604/751 Yield

Conditions & References Lapworth; Journal of the Chemical Society; vol. 75; (1899); p. 559 View in Reaxys

BaBr2

Rx-ID: 26452016 View in Reaxys 605/751 Yield 6.45 %

Conditions & References With chlorine, 100°C; 3.5 h Potilitzin, A.; G. Wagner (Ber. 12 {1879} 695 ) View in Reaxys Potilitzin, A.; G. Wagner (Ber. 12 {1879} 697 ) ; (from Gmelin) View in Reaxys

6.45 %

With chlorine, 100°C; 3.5 h vol. Ba: MVol.; 8.2.1, page 223 - 231 ; (from Gmelin) View in Reaxys in water, Electrolysis; max. yield at 16 °C Sarghel, J.; Zeitschrift fuer Elektrochemie; vol. 6; (1899); p. 186 View in Reaxys Sarghel, J.; Dissert. Berlin 1899, S. 57 ; (from Gmelin) View in Reaxys in water, Electrolysis; max. yield at 16 °C vol. Br: MVol.; 7.4, page 226 - 233 ; (from Gmelin) View in Reaxys O

Br2Mg

Br -1 O

(v1)

O–

Rx-ID: 26540401 View in Reaxys 606/751 Yield

Conditions & References in water, Electrolysis; better yield with increasing c.d. and adding alkali; excess of alkali decreases the yield Sarghel, I.; Zeitschrift fuer Elektrochemie; vol. 6; (1899); p. 177 - 177 View in Reaxys Sarghel, J.; Dissert. Berlin 1899, S. 36 ; (from Gmelin) View in Reaxys in water, Electrolysis; better yield with increasing c.d. and adding alkali; excess of alkali decreases the yield vol. Br: MVol.; 7.4, page 226 - 233 ; (from Gmelin) View in Reaxys

168/201

2017-08-09 05:21:10

Br Cl

Rx-ID: 7053970 View in Reaxys 607/751 Yield

Conditions & References T= 200 °C Mouneyrat; Bulletin de la Societe Chimique de France; vol. <3>19; (1898); p. 499 View in Reaxys

OH OH

Rx-ID: 7063201 View in Reaxys 608/751 Yield

Conditions & References auf dem Wasserbade Lobry de Bruyn; Adriani; Recueil des Travaux Chimiques des Pays-Bas; vol. 17; (1898); p. 259 Anm. View in Reaxys H N

Br H

(v3)

Rx-ID: 8213716 View in Reaxys 609/751 Yield

Conditions & References Samtleben; Chemische Berichte; vol. 31; (1898); p. 1144 View in Reaxys H N

Br H

(v3)

Rx-ID: 8213717 View in Reaxys 610/751 Yield

Conditions & References Samtleben; Chemische Berichte; vol. 31; (1898); p. 1144 View in Reaxys H N

Br H

(v3)

Rx-ID: 8213718 View in Reaxys 611/751 Yield

Conditions & References Samtleben; Chemische Berichte; vol. 31; (1898); p. 1144 View in Reaxys

O O -1 Br

(v2)

Br Br

N+

O O

Rx-ID: 8213721 View in Reaxys 612/751 Yield

Conditions & References Martindale; Archiv der Pharmazie (Weinheim, Germany); vol. 236; (1898); p. 217 View in Reaxys

169/201

2017-08-09 05:21:10

-1 Br

(v2)

Br Br

N+

Rx-ID: 8213726 View in Reaxys 613/751 Yield

Conditions & References Tafel; Chemische Berichte; vol. 31; (1898); p. 1152 View in Reaxys 2 Fe 3+

6 3

O– N

–

S OO

BrK

Rx-ID: 26281834 View in Reaxys 614/751 Yield

Conditions & References in water Blau, F.; Monatshefte fuer Chemie; vol. 19; (1898); p. 659 - 659 ; (from Gmelin) View in Reaxys in water vol. Fe: MVol.B2; 71, page 462 - 464 ; (from Gmelin) View in Reaxys

O– K+

S O

O– S

Br( 1-)

Rx-ID: 26364145 View in Reaxys 615/751 Yield

Conditions & References in water, activated by Fe salts or Cu salts Price, T. S.; Z. phys. Ch.; vol. 27; (1898); p. 510 ; (from Gmelin) View in Reaxys in water, activated by Fe salts or Cu salts vol. K: MVol.3; 6.9, page 758 - 763 ; (from Gmelin) View in Reaxys

O Br

2+ O– Cu

Rx-ID: 26365385 View in Reaxys 616/751 Yield

Conditions & References in neat (no solvent), byproducts: basic bromate; on heating at ambient pressure; Bourgeois, L.; Bulletin de la Societe Chimique de France; vol. 19; (1898); p. 949 - 953 View in Reaxys vol. Cu: MVol.B1; 176, page 387 - 388 ; (from Gmelin) View in Reaxys

Br Fe Br

(v3)

Br2Fe

Rx-ID: 26468131 View in Reaxys 617/751 Yield

Conditions & References in water, decompn. by boiling; not at common and lower temperature; Koninck, L. L. de; Angewandte Chemie; vol. 2; (1889); p. 149 - 149 ; (from Gmelin)

170/201

2017-08-09 05:21:10

View in Reaxys in water, decompn. by boiling; not at common and lower temperature; Bolschakow, I.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 30; (1898); p. 389 - 389 View in Reaxys vol. Fe: MVol.B2; 10, page 333 - 334 ; (from Gmelin) View in Reaxys 2 Br–

2 Cl –

Pd4+

Rx-ID: 26613791 View in Reaxys 618/751 Yield

Conditions & References on dryining, loss of Br2; Rosenheim, A.; Maass, Th. A.; Z. Anorg. Chem.; vol. 18; (1898); p. 335 - 335 ; (from Gmelin) View in Reaxys vol. Pd: MVol.2; 136, page 433 - 435 ; (from Gmelin) View in Reaxys

O O Br

N Br

Rx-ID: 6680040 View in Reaxys 619/751 Yield

Conditions & References Zersetzt sich im Sonnenlicht Kastle; Beatty; American Chemical Journal; vol. 19; (1897); p. 139 View in Reaxys

Br Br– N+

silver nitrate solution

Rx-ID: 8213733 View in Reaxys 620/751 Yield

Conditions & References in der Kaelte van Son; Archiv der Pharmazie (Weinheim, Germany); vol. 235; (1897); p. 685; Chem. Zentralbl.; vol. 69; nb. II; (1898); p. 889 View in Reaxys

O O S

O S

Rx-ID: 26062840 View in Reaxys 621/751 Yield

Conditions & References byproducts: SO3, SO2, HCl; 50 °C Besson, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 124; (1897); p. 402 ; (from Gmelin) View in Reaxys byproducts: HSO3Cl, SO2, HCl; 50 °C Besson, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 124; (1897); p. 402 ; (from Gmelin)

171/201

2017-08-09 05:21:10

View in Reaxys byproducts: SO3, SO2, HCl; 50 °C vol. Br: MVol.; 6.3, page 208 - 213 ; (from Gmelin) View in Reaxys byproducts: HSO3Cl, SO2, HCl; 50 °C vol. Br: MVol.; 6.3, page 208 - 213 ; (from Gmelin) View in Reaxys

O O S

S O

H HO

S OO

O S

Rx-ID: 26345164 View in Reaxys 622/751 Yield

Conditions & References in neat (no solvent), 50°C; dry HBr; Besson, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 124; (1897); p. 401 403 View in Reaxys vol. S: MVol.B3; 141, page 1826 - 1828 ; (from Gmelin) View in Reaxys

(v3) Br–

(v3)

N+ S

Rx-ID: 26625384 View in Reaxys 623/751 Yield

Conditions & References in neat (no solvent), deflagrates on heating; Muthmann, W.; Seitter, E.; Ber.; vol. 30; (1897); p. 627 - 631 ; (from Gmelin) View in Reaxys in neat (no solvent), deflagrates on heating; vol. S: MVol.B3; 160, page 1868 - 1870 ; (from Gmelin) View in Reaxys

(v3)

Br6N 4S4

Br– (v3)

(v2)

S+

S N

(v3)

Rx-ID: 26626167 View in Reaxys 624/751 Yield

Conditions & References in neat (no solvent), on storage in air;; contaminated by S4N3Br; Muthmann, W.; Seitter, E.; Ber.; vol. 30; (1897); p. 627 - 631 ; (from Gmelin) View in Reaxys in neat (no solvent), on storage in air;; contaminated by S4N3Br; vol. S: MVol.B3; 160, page 1868 - 1870 ; (from Gmelin) View in Reaxys Br N O

alcoholic KOH-solution

Br Br

Rx-ID: 5574987 View in Reaxys 625/751

172/201

2017-08-09 05:21:10

Yield

Conditions & References Brunner; Monatshefte fuer Chemie; vol. 17; (1896); p. 484 View in Reaxys

BrK

Rx-ID: 26097269 View in Reaxys 626/751 Yield

Conditions & References With tetrachloromethane, byproducts: KCl; heated for some hours at 200 °C in closed tube Snape, H. L.; Chem. News J. Ind. Sci.; vol. 74; (1896); p. 27 ; (from Gmelin) View in Reaxys With CCl4 vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys

Br–

Br Br

P+

BrBr

Br S

S Br

P Br Br

Rx-ID: 26409755 View in Reaxys 627/751 Yield

Conditions & References

in neat (no solvent), water bath; Besson, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 122; (1896); p. 320 322 ; (from Gmelin) View in Reaxys

in neat (no solvent), water bath; vol. S: MVol.B3; 159, page 1866 - 1868 ; (from Gmelin) View in Reaxys Cu 2+

O–

K+

–O

O–

S OO

Cu 2O2

Rx-ID: 26601497 View in Reaxys 628/751 Yield

Conditions & References With CuSO4 in not given, byproducts: K2SO4, O2 Pauli, H.; Zeitschrift fuer Elektrochemie; vol. 3; (1896); p. 477 View in Reaxys vol. Br: MVol.; 11.3, page 299 - 303 ; (from Gmelin) View in Reaxys

(v1)

(v4)

S N

Rx-ID: 26619105 View in Reaxys 629/751 Yield

Conditions & References in carbon disulfide, digestion; Clever, A.; Muthmann, W.; Ber.; vol. 29; (1896); p. 340 - 343 ; (from Gmelin) View in Reaxys in carbon disulfide, digestion; vol. S: MVol.B3; 159, page 1866 - 1868 ; (from Gmelin) View in Reaxys

173/201

2017-08-09 05:21:10

Br6N 4S4

Rx-ID: 26626168 View in Reaxys 630/751 Yield

Conditions & References With carbon disulfide in neat (no solvent) Clever, A.; Muthmann, W.; Ber.; vol. 29; (1896); p. 340 - 343 ; (from Gmelin) View in Reaxys With CS2 in neat (no solvent) vol. S: MVol.B3; 160, page 1868 - 1870 ; (from Gmelin) View in Reaxys O

O Br

zinc

Rx-ID: 7054026 View in Reaxys 631/751 Yield

Conditions & References T= 90 °C Michael; Clark; Journal fuer Praktische Chemie (Leipzig); vol. <2>52; (1895); p. 530 View in Reaxys

Br Br Br

Rx-ID: 7053963 View in Reaxys 632/751 Yield

Conditions & References T= 140 °C Besson; Bulletin de la Societe Chimique de France; vol. <3>11; (1894); p. 920 View in Reaxys

Br Cu – Br Br

(v3)

K+

BrK

BrCu

Rx-ID: 26315215 View in Reaxys 633/751 Yield

Conditions & References With water in neat (no solvent), heating under melting; addn. of water to solidified melt; Sabatier, P.; Bulletin de la Societe Chimique de France; vol. 11; (1894); p. 676 - 683 ; (from Gmelin) View in Reaxys With H2O in neat (no solvent), heating under melting; addn. of water to solidified melt; vol. Cu: MVol.B3; 23, page 1025 - 1027 ; (from Gmelin) View in Reaxys

K+

Br O

BrK

O–

Rx-ID: 26420216 View in Reaxys 634/751 Yield 0.08 %, 29.56 %

Conditions & References at 180 °C Cook, E. H.; Journal of the Chemical Society; vol. 65; (1894); p. 811 ; (from Gmelin) View in Reaxys vol. K: MVol.3; 1.6.2, page 580 - 581 ; (from Gmelin) View in Reaxys

174/201

2017-08-09 05:21:10

Cl Br

Rx-ID: 8213742 View in Reaxys 635/751 Yield

Conditions & References T= 105 - 106 °C Zincke; Guenther; Justus Liebigs Annalen der Chemie; vol. 272; (1893); p. 257 View in Reaxys

Br B

B2O3

O5P2

Rx-ID: 26365858 View in Reaxys 636/751 Yield

Conditions & References in neat (no solvent), decompn. in a stream of O2 at elevated temp. under inflammation; Tarible, J.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 116; (1893); p. 1521 1524 View in Reaxys vol. P: MVol.C; 269, page 618 - 620 ; (from Gmelin) View in Reaxys Br

O O

Rx-ID: 8213745 View in Reaxys 637/751 Yield

Conditions & References Miller; Journal of the Chemical Society; vol. 61; (1892); p. 1029 View in Reaxys

Cl Cl

BrK

Si Cl Cl

Rx-ID: 26097359 View in Reaxys 638/751 Yield

Conditions & References byproducts: KCl; heated for some days at 400 °C in a closed tube Rauter, G.; Liebigs Annalen der Chemie; vol. 270; (1892); p. 246 ; (from Gmelin) View in Reaxys vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys

(v2)

Br–

Cs +

Rx-ID: 26605780 View in Reaxys 639/751 Yield

Conditions & References in neat (no solvent), CsBr3 looses Br2 on heating at 160 °C in an open tube; Wells, H. L.; Am. J. Sci.; vol. 43; (1892); p. 18 - 18 View in Reaxys Wells, H. L.; Z. Anorg. Chem.; vol. 1; (1892); p. 86 - 86 ; (from Gmelin) View in Reaxys in neat (no solvent), CsBr3 looses Br2 on heating at 160 °C in an open tube; vol. Cs: MVol.2; 41, page 185 - 187 ; (from Gmelin) View in Reaxys

175/201

2017-08-09 05:21:10

(v2)

Br–

Rb +

BrRb

Rx-ID: 26605781 View in Reaxys 640/751 Yield

Conditions & References

100 %

in neat (no solvent), decompn. of RbBr3 in RbBr and Br2 by heating; Wells, H. L.; Wheeler, H. L.; Am. J. Sci.; vol. 43; (1892); p. 444 - 444 ; (from Gmelin) View in Reaxys

100 %

in neat (no solvent), decompn. of RbBr3 in RbBr and Br2 by heating; Wells, H. L.; Wheeler, H. L.; Am. J. Sci.; vol. 43; (1892); p. 477 - 477 ; (from Gmelin) View in Reaxys vol. Rb: MVol.; 64, page 179 - 180 ; (from Gmelin) View in Reaxys

Cl – Br Cs +

(v2)

Rx-ID: 26633049 View in Reaxys 641/751 Yield

Conditions & References

>99

in neat (no solvent), CsBr2Cl looses completely its Br2 on heating at 150 °C in an open tube; Wells, H. L.; Am. J. Sci.; vol. 43; (1892); p. 18 - 18 View in Reaxys Wells, H. L.; Z. Anorg. Chem.; vol. 1; (1892); p. 86 - 86 ; (from Gmelin) View in Reaxys

>99

in neat (no solvent), CsBr2Cl looses completely its Br2 on heating at 150 °C in an open tube; vol. Cs: MVol.2; 42, page 187 - 188 ; (from Gmelin) View in Reaxys Br

Br2Cu

Rx-ID: 26185492 View in Reaxys 642/751 Yield

Conditions & References

in neat (no solvent), in the air at ambient temp.; Richards, T. W.; Chem. News J. Ind. Sci.; vol. 63; (1891); p. 20 - 23 View in Reaxys Richards, T. W.; Proc. Am. Acad. Arts Sci.; vol. 25; (1889); p. 195 - 214 ; (from Gmelin) View in Reaxys

in neat (no solvent), in the air at ambient temp.; vol. Cu: MVol.B1; 167, page 369 - 371 ; (from Gmelin) View in Reaxys

O– S O

O O–

Br O

O– HO

S OO

Rx-ID: 26410991 View in Reaxys 643/751 Yield

Conditions & References in sulfuric acid, ambient temp. Schwicker, A.; Chemiker-Zeitung; vol. 15; (1891); p. 845 - 846 View in Reaxys vol. S: MVol.B2; 1.6.2.4, page 519 - 520 ; (from Gmelin) View in Reaxys in sulfuric acid, slow temp. enhancing to boiling Feit, W.; Kubierschky, K.; Chemiker-Zeitung; vol. 15; (1891); p. 351 - 352

176/201

2017-08-09 05:21:10

View in Reaxys vol. S: MVol.B2; 1.6.2.4, page 519 - 520 ; (from Gmelin) View in Reaxys O Br

Br( 1-)

H( 1+)

Rx-ID: 26414408 View in Reaxys 644/751 Yield

Br6Mg2Pb

Rx-ID: 26448503 View in Reaxys 645/751 Yield

Conditions & References above 140°C Otto, R.; Drewes, D.; Archiv der Pharmazie (Weinheim, Germany); vol. 229; (1891); p. 585 - 588 View in Reaxys vol. Pb: MVol.C3; 13, page 1161 - 1178 ; (from Gmelin) View in Reaxys

OH HO

S OO

Rx-ID: 26484193 View in Reaxys 646/751 Yield

Conditions & References

99 %

With anhydrous sulfurous acid, byproducts: H2O Schwicker, A.; Chemiker-Zeitung; vol. 15; (1891); p. 845 ; (from Gmelin) View in Reaxys

99 %

With H2SO3, byproducts: H2O Feit, W.; Kubierschky, K.; Chemiker-Zeitung; vol. 15; (1891); p. 352 View in Reaxys vol. Br: MVol.; 12.1, page 314 - 320 ; (from Gmelin) View in Reaxys

O O

S O

diluted NaOH-solution

O O S

S HO

S OO

Rx-ID: 7054041 View in Reaxys 647/751 Yield

Conditions & References beim Erwaermen Fromm; Justus Liebigs Annalen der Chemie; vol. 253; (1889); p. 155 View in Reaxys

177/201

2017-08-09 05:21:10

N O

S N

Rx-ID: 8213724 View in Reaxys 648/751 Yield

Conditions & References Hoogewerff; van Dorp; Recueil des Travaux Chimiques des Pays-Bas; vol. 8; (1889); p. 178 View in Reaxys O

O Cl

Br Br

Rx-ID: 8213737 View in Reaxys 649/751 Yield

Conditions & References beim Schmelzen Roser; Haselhoff; Justus Liebigs Annalen der Chemie; vol. 247; (1888); p. 149 View in Reaxys Zincke; Froelich; Chemische Berichte; vol. 20; (1887); p. 2055 View in Reaxys O

O Cl

Br Cl

Rx-ID: 8213738 View in Reaxys 650/751 Yield

Conditions & References Roser; Haselhoff; Justus Liebigs Annalen der Chemie; vol. 247; (1888); p. 149 View in Reaxys

H O

Cl 2

O–

Mg2+

Cl 3KMg carnallite

Rx-ID: 26083622 View in Reaxys 651/751 Yield

Conditions & References With acid in water, distn. Patent; Salzbergwerk Neu-Stassfurt; DE46320; (1888) ; (from Gmelin) View in Reaxys With acid in water vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys

6 O 2

Cl O–

H O

Mg2+

Cl 3KMg carnallite

Rx-ID: 26175352 View in Reaxys 652/751 Yield

Conditions & References With acid in water, distn. Patent; Salzbergwerk Neu-Stassfurt; DE46320; (1888) ; (from Gmelin) View in Reaxys

178/201

2017-08-09 05:21:10

With acid in water vol. Br: MVol.; 1.1, page 34 - 40 ; (from Gmelin) View in Reaxys O

O Cl

Br Br

Rx-ID: 8213739 View in Reaxys 653/751 Yield

Conditions & References Zincke; Froelich; Chemische Berichte; vol. 20; (1887); p. 2055 View in Reaxys O

O Cl

SO2

Rx-ID: 8213740 View in Reaxys 654/751 Yield

Conditions & References Zincke; Froelich; Chemische Berichte; vol. 20; (1887); p. 2055 View in Reaxys K+

Br O

BrNa

O–

Rx-ID: 26420217 View in Reaxys 655/751 Yield

Conditions & References With chlorine in not given, byproducts: HClO3, KCl; in dark (50 d) at room temp. Potylizyn, A.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 19; (1887); p. 359 ; (from Gmelin) View in Reaxys With Cl2 in not given, byproducts: HClO3, KCl; in dark (50 d) at room temp. vol. Br: MVol.; 11.4, page 303 - 309 ; (from Gmelin) View in Reaxys O

O –O

Na +

BrNa

Rx-ID: 26448190 View in Reaxys 656/751 Yield

Conditions & References With chlorine in not given, byproducts: HClO3, NaCl; in dark (50 d) at room temp. Potylizyn, A.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 19; (1887); p. 359 ; (from Gmelin) View in Reaxys With Cl2 in not given, byproducts: HClO3, NaCl; in dark (50 d) at room temp. vol. Br: MVol.; 11.4, page 303 - 309 ; (from Gmelin) View in Reaxys O

Ba+ (v0)

Br O

O–

BrNa

Rx-ID: 26470957 View in Reaxys 657/751 Yield

Conditions & References With chlorine in not given, byproducts: HClO3, BaCl2; in dark (50 d) at room temp.

179/201

2017-08-09 05:21:10

Potylizyn, A.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 19; (1887); p. 359 ; (from Gmelin) View in Reaxys With Cl2 in not given, byproducts: HClO3, BaCl2; in dark (50 d) at room temp. vol. Br: MVol.; 11.4, page 303 - 309 ; (from Gmelin) View in Reaxys

O O

S O

diluted NaOH-solution

Rx-ID: 7054004 View in Reaxys 658/751 Yield

Conditions & References Baumann; Chemische Berichte; vol. 19; (1886); p. 2811 View in Reaxys Cl

Br Br

9.10-dichloro-x-bromo-anthracene

Br Cl

Rx-ID: 8263869 View in Reaxys 659/751 Yield

Conditions & References T= 190 °C Hammerschlag; Chemische Berichte; vol. 19; (1886); p. 1108 View in Reaxys

BeBr2

BeO

Rx-ID: 26401562 View in Reaxys 660/751 Yield

Conditions & References With oxygen, by heating in air or oxygen; partial decompn. Carnelley, T.; Ber.; vol. 17; (1884); p. 1359 View in Reaxys Humpidge, T. S.; Proceedings of the Royal Society of London; vol. 39; (1886); p. 12 ; (from Gmelin) View in Reaxys With oxigen, by heating in air or oxygen; partial decompn. vol. Be: MVol.; 3.6, page 121 - 124 ; (from Gmelin) View in Reaxys

Rx-ID: 7053983 View in Reaxys 661/751 Yield

Conditions & References Sandmeyer; Chemische Berichte; vol. 18; (1885); p. 1768; Chemische Berichte; vol. 19; (1886); p. 858 View in Reaxys

Br (v4)

Pt BrBr

Br2Pt

Rx-ID: 26344225 View in Reaxys 662/751 Yield

Conditions & References in water, Electrolysis; product depends on number of Bunsen cells Halberstadt, W.; Ber.; vol. 17; (1884); p. 2962 - 2964 View in Reaxys vol. Pt: MVol.C1; 7.1, page 94 - 99 ; (from Gmelin)

180/201

2017-08-09 05:21:10

View in Reaxys

(v4)

Rx-ID: 26598784 View in Reaxys 663/751 Yield

Conditions & References Froelich, O.; Liebigs Annalen der Chemie; vol. 224; (1884); p. 270 ; (from Gmelin) View in Reaxys vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys O

Br O

bromohydroquinone diacetate

Rx-ID: 6210714 View in Reaxys 664/751 Yield

Conditions & References Schulz; Chemische Berichte; vol. 15; (1882); p. 652 View in Reaxys

H N

Rx-ID: 6680045 View in Reaxys 665/751 Yield

Conditions & References Hofmann,A.W.; Chemische Berichte; vol. 15; (1882); p. 408 View in Reaxys

H N

H 2N

hypobromous acid

H 2N

Rx-ID: 6729116 View in Reaxys 666/751 Yield

Conditions & References beim Kochen;Produkt5:Methylacetylharnstoff Hofmann,A.W.; Chemische Berichte; vol. 15; (1882); p. 408 View in Reaxys

H 2N

N Br

H N

Rx-ID: 7054037 View in Reaxys 667/751 Yield

Conditions & References Hofmann,A.W.; Chemische Berichte; vol. 15; (1882); p. 415 View in Reaxys

NH 2

H N

Br O

diisobutyramide

Rx-ID: 7074284 View in Reaxys 668/751

181/201

2017-08-09 05:21:10

Yield

Conditions & References bei der Destillation Hofmann; Chemische Berichte; vol. 15; (1882); p. 755 View in Reaxys H

Br–

NH +4

Br Br

Rx-ID: 26062249 View in Reaxys 669/751 Yield

Conditions & References byproducts: H2; Electrolysis; with parchment diaphragm Bakhuis Roozeboom, H. W.; Ber.; vol. 14; (1881); p. 2398 ; (from Gmelin) View in Reaxys byproducts: H2; Electrolysis; with parchment diaphragm vol. NH4: MVol.1; 2.9.2, page 210 - 215 ; (from Gmelin) View in Reaxys

S Cl

S Br

Rx-ID: 26472631 View in Reaxys 670/751 Yield

Conditions & References

in neat (no solvent) Schulze, H.; Journal fuer Praktische Chemie (Leipzig); vol. 24; (1881); p. 168 - 183 View in Reaxys vol. S: MVol.B3; 159, page 1866 - 1868 ; (from Gmelin) View in Reaxys Br Br Br TB-5 P Br Br

Br P

P Br Br

Rx-ID: 26469894 View in Reaxys 671/751 Yield

Conditions & References With oxygen in neat (no solvent), passing dry O2 at 175°C through PBr3; explosive reaction with formation of Br2, POBr3 and PBr5; Demole, E.; Bull. Soc. chim. France (2); vol. 34; (1880); p. 201 - 207 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys

Br Cl

Rx-ID: 7053964 View in Reaxys 672/751 Yield

Conditions & References T= 175 °C Denzel; Chemische Berichte; vol. 12; (1879); p. 2208 View in Reaxys

C2Br4

perbromobenzene Rx-ID: 7084532 View in Reaxys 673/751

182/201

2017-08-09 05:21:10

Yield

Conditions & References durch Hitze Wahl; Chemische Berichte; vol. 11; (1878); p. 2239 View in Reaxys

H 2N Br

Br H

NH 2

(v3)

Rx-ID: 8213715 View in Reaxys 674/751 Yield

Conditions & References an der Luft Kamenski; Chemische Berichte; vol. 11; (1878); p. 619,1600 View in Reaxys

Br O

Br Br

2.4.6-tribromo-orcin

O Br

Rx-ID: 8213762 View in Reaxys 675/751 Yield

Conditions & References Claassen; Chemische Berichte; vol. 11; (1878); p. 1440 View in Reaxys

Br2Hg

Cl 2Hg

Rx-ID: 26182490 View in Reaxys 676/751 Yield

Conditions & References Berthelot, M.; Ann. Chim. Phys.; vol. 15; (1878); p. 185 - 220 ; (from Gmelin) View in Reaxys vol. Hg: MVol.B2; 169, page 755 - 757 ; (from Gmelin) View in Reaxys

S Br

Rx-ID: 26410852 View in Reaxys 677/751 Yield

Conditions & References

in neat (no solvent), 0°C; Clausnizer, F.; Ber.; vol. 11; (1878); p. 2012 - 2013 ; (from Gmelin) View in Reaxys

in neat (no solvent), 0°C; vol. S: MVol.B3; 159, page 1866 - 1868 ; (from Gmelin) View in Reaxys

Br–

Br P+ Br BrBr

S OO

O S Br

P OH O

Rx-ID: 26455088 View in Reaxys 678/751 Yield 0%

Conditions & References in neat (no solvent), concd. H2SO4; Clausnizer, F.; Ber.; vol. 11; (1878); p. 2012 - 2013 ; (from Gmelin) View in Reaxys

in neat (no solvent), concd. H2SO4;

183/201

2017-08-09 05:21:10

vol. S: MVol.B3; 159, page 1866 - 1868 ; (from Gmelin) View in Reaxys

Br2Hg 2

(v2) (v2)

Cl Hg Hg Cl

Rx-ID: 26533284 View in Reaxys 679/751 Yield

Conditions & References Berthelot, M.; Ann. Chim. Phys.; vol. 15; (1878); p. 185 - 220 ; (from Gmelin) View in Reaxys vol. Hg: MVol.B2; 156, page 728 - 730 ; (from Gmelin) View in Reaxys

Br Br Br TB-5 P Br Br

O S

Rx-ID: 26535842 View in Reaxys 680/751 Yield

Conditions & References

With sulfuric acid in neat (no solvent), byproducts: sulfur bromide; heating PBr5 in H2SO4; Clausnitzer, F.; Ber.; vol. 11; (1878); p. 2012 - 2013 ; (from Gmelin) View in Reaxys

With H2SO4 in neat (no solvent), byproducts: sulfur bromide; heating PBr5 in H2SO4; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin) View in Reaxys

Hg 2+

O–

Rx-ID: 26367880 View in Reaxys 681/751 Yield

Conditions & References in hydrogen bromide Cameron, C. A.; Analyst (Cambridge, United Kingdom); vol. 1; (1877); p. 95 - 97 ; (from Gmelin) View in Reaxys in hydrogen bromide, aq. HBr vol. Hg: MVol.B2; 248, page 925 - 927 ; (from Gmelin) View in Reaxys

Br 5 H

O Se

Br Br

Rx-ID: 26618414 View in Reaxys 682/751 Yield

Conditions & References in neat (no solvent), byproducts: H2O; decomposition above 65°C; Ditte, A.; Ann. Chim. Phys.; vol. 10; (1877); p. 89 - 89 View in Reaxys Ditte, A.; Ann. Chim. Phys.; vol. 10; (1877); p. 90 - 90 View in Reaxys Ditte, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 83; (1876); p. 223 223 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. Se: MVol.B; 72, page 156 - 157 ; (from Gmelin) View in Reaxys

184/201

2017-08-09 05:21:10

P Br

P ClBr

P BrBr

Cl P

Rx-ID: 26356030 View in Reaxys 683/751 Yield

Conditions & References in neat (no solvent), stepwise heating in a sealed tube at 50 or 90°C for 3h; Geuther, A.; Jenaische Z. Naturwiss. (2. Suppl.-H.); vol. 10; (1876); p. 128 - 140 View in Reaxys vol. P: MVol.C; 221, page 508 - 509 ; (from Gmelin) View in Reaxys in neat (no solvent), heating POBr3 in sealed tube with BrCl at 50 to 90°C; Geuther, A.; Jenaische Z. Med. Naturw. (2) (2. Suppl.-H.); vol. 3; (1876); p. 128 - 140 ; (from Gmelin) View in Reaxys in neat (no solvent), heating POBr3 in sealed tube with BrCl at 50 to 90°C; vol. P: MVol.C; 225, page 516 - 517 ; (from Gmelin) View in Reaxys

AuBr

Rx-ID: 26444884 View in Reaxys 684/751 Yield

Conditions & References 210°C Thomsen, J.; Journal fuer Praktische Chemie (Leipzig); vol. 13; (1876); p. 337 - 347 View in Reaxys Spiegel, E.; Diss. Bern 1896, p. 20 ; (from Gmelin) View in Reaxys at 200-210°C Spiegel, E.; Diss. Bern 1896, p. 20 ; (from Gmelin) View in Reaxys dissocn. by heating Thomsen, J.; Journal fuer Praktische Chemie (Leipzig); vol. 13; (1876); p. 337 - 347 ; (from Gmelin) View in Reaxys at 200-210°C vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin) View in Reaxys 210°C vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin) View in Reaxys dissocn. by heating vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin) View in Reaxys

(v4)Br Br SP-4 Au– Br Br

H+

AuBr

Rx-ID: 26511578 View in Reaxys 685/751 Yield

Conditions & References byproducts: HBr; H{AuBr4} melting and the product heating at 115°C Thomsen, J.; Journal fuer Praktische Chemie (Leipzig); vol. 13; (1876); p. 337 - 347

185/201

2017-08-09 05:21:10

View in Reaxys Thomsen, J.; Thermochemische Untersuchungen, Vol. 3, Leipzig 1883 p. 390/1 ; (from Gmelin) View in Reaxys byproducts: HBr; H{AuBr4} melting and the product heating at 115°C vol. Au: MVol.3; 9.1, page 702 - 711 ; (from Gmelin) View in Reaxys

Rx-ID: 6680046 View in Reaxys 686/751 Yield

Conditions & References T= 190 °C Sabanejew; Justus Liebigs Annalen der Chemie; vol. 178; (1875); p. 115 View in Reaxys

Br Cl

C2Cl4

Rx-ID: 7070481 View in Reaxys 687/751 Yield

Conditions & References T= 200 °C Bourgoin; Bulletin de la Societe Chimique de France; vol. <2>24; (1875); p. 115 View in Reaxys

H 2N

Br Cl

C2Cl4

Rx-ID: 7070482 View in Reaxys 688/751 Yield

Conditions & References Bourgoin; Bulletin de la Societe Chimique de France; vol. <2>24; (1875); p. 115 View in Reaxys

Br Br Cl

zinc

S OO

C2Cl4

Rx-ID: 7070483 View in Reaxys 689/751 Yield

Conditions & References Bourgoin; Bulletin de la Societe Chimique de France; vol. <2>24; (1875); p. 115 View in Reaxys

OH O

sodium amalgam

Rx-ID: 8213734 View in Reaxys 690/751 Yield

Conditions & References Boettinger; Chemische Berichte; vol. 7; (1874); p. 1782; Justus Liebigs Annalen der Chemie; vol. 191; (1878); p. 14 View in Reaxys

S O

O B

O S

Rx-ID: 26410802 View in Reaxys 691/751

186/201

2017-08-09 05:21:10

Yield

Conditions & References

in neat (no solvent), on heating; Gustavson, G.; Ber.; vol. 6; (1873); p. 9 - 11 ; (from Gmelin) View in Reaxys

in neat (no solvent), on heating; vol. S: MVol.B3; 159, page 1866 - 1868 ; (from Gmelin) View in Reaxys

Br Br

OH Cl

Rx-ID: 7054035 View in Reaxys 692/751 Yield

Conditions & References bei der Destillation Sarnow; Justus Liebigs Annalen der Chemie; vol. 164; (1872); p. 105 View in Reaxys Cl

zinc

Rx-ID: 7054036 View in Reaxys 693/751 Yield

Conditions & References bei der Destillation Sarnow; Justus Liebigs Annalen der Chemie; vol. 164; (1872); p. 105 View in Reaxys Cl

P+ ClBr

(v2)

Br Br– Br

H HO

P OH O

Rx-ID: 26586274 View in Reaxys 694/751 Yield

Conditions & References With water in neat (no solvent), decompsition with excess H2O; Michaelis, A.; Ber.; vol. 5; (1872); p. 411 - 417 ; (from Gmelin) View in Reaxys With H2O in neat (no solvent), decompsition with excess H2O; vol. P: MVol.C; 223, page 511 - 513 ; (from Gmelin) View in Reaxys

Cl Cl

P+

(v2)

Br Br– Br

Br Cl

ClBr

Cl P Cl

Br O

P Br Br

Rx-ID: 26586275 View in Reaxys 695/751 Yield

Conditions & References With water in neat (no solvent), decomposition with little H2O; Michaelis, A.; Ber.; vol. 5; (1872); p. 411 - 417 ; (from Gmelin) View in Reaxys With H2O in neat (no solvent), decomposition with little H2O; vol. P: MVol.C; 223, page 511 - 513 ; (from Gmelin) View in Reaxys

187/201

2017-08-09 05:21:10

Br 2 Br

P+ Cl (v2) ClBr Br Br– Br

P OH O

Rx-ID: 26587603 View in Reaxys 696/751 Yield

Conditions & References With water in water Prinvault; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 74; (1872); p. 868 870 ; (from Gmelin) View in Reaxys With H2O in water vol. P: MVol.C; 223, page 511 - 513 ; (from Gmelin) View in Reaxys

O S

Rx-ID: 26108065 View in Reaxys 697/751 Yield

Conditions & References With alkali bromides, absorption of SO3-vapor by alkali bromides, partial decompn.;; generation of Br2; Schultz-Sellack, C.; Ber.; vol. 4; (1871); p. 109 - 114 View in Reaxys Schultz-Sellack, C.; Bulletin de la Societe Chimique de France; vol. 15; (1871); p. 46 - 48 View in Reaxys Schultz-Sellack, C.; Journal of the Chemical Society; vol. 24; (1871); p. 193 - 195 ; (from Gmelin) View in Reaxys With alkali bromides, absorption of SO3-vapor by alkali bromides, partial decompn.;; generation of Br2; vol. S: MVol.B1; 164, page 361 - 363 ; (from Gmelin) View in Reaxys

Br2Cu

CuI

Rx-ID: 26180997 View in Reaxys 698/751 Yield

Conditions & References in ethanol, byproducts: allyl bromide; pptn.; Oppenheim, A.; Ber.; vol. 3; (1870); p. 442 - 443 ; (from Gmelin) View in Reaxys in ethanol, byproducts: allyl bromide; pptn.; vol. Cu: MVol.B1; 169, page 373 - 375 ; (from Gmelin) View in Reaxys

B2O3

P Cl

Rx-ID: 26344387 View in Reaxys 699/751 Yield

Conditions & References in neat (no solvent) Gustavson, G.; Zeitschrift fuer Chemie (Stuttgart, Germany); vol. 13; (1870); p. 521 - 522 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. P: MVol.C; 224, page 513 - 516 ; (from Gmelin)

188/201

2017-08-09 05:21:10

View in Reaxys O

Br( 1-)

Rx-ID: 26414497 View in Reaxys 700/751 Yield

Conditions & References in not given Fremy, E.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 70; (1870); p. 64 View in Reaxys vol. N: MVol.4; 6.5, page 915 - 929 ; (from Gmelin) View in Reaxys Br Br

Rx-ID: 7441579 View in Reaxys 701/751 Yield

Conditions & References bei der Destillation, isomer of mp: 237 degree Limpricht; Schwanert; Justus Liebigs Annalen der Chemie; vol. 145; (1868); p. 342; Justus Liebigs Annalen der Chemie; vol. 160; (1871); p. 178 View in Reaxys H

Br Ir Br

(v3)

Rx-ID: 26391632 View in Reaxys 702/751 Yield

Conditions & References at glowing Birnbaum, C.; Liebigs Annalen der Chemie; vol. 133; (1865); p. 166 - 167 View in Reaxys vol. Ir: MVol.; 5.6, page 71 - 73 ; (from Gmelin) View in Reaxys Br Br 3 H

Ir Br

(v3)

Rx-ID: 26404097 View in Reaxys 703/751 Yield

Conditions & References by heating Birnbaum, C.; Liebigs Annalen der Chemie; vol. 133; (1865); p. 166 - 167 View in Reaxys vol. Ir: MVol.; 5.6, page 71 - 73 ; (from Gmelin) View in Reaxys

P Br

Br Br

O N O

P OH O

S OO

Rx-ID: 26423869 View in Reaxys 704/751 Yield

Conditions & References in not given, react. with concd. HNo3; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 ; (from Gmelin)

189/201

2017-08-09 05:21:10

View in Reaxys in not given, react. with concd. HNo3; vol. P: MVol.C; 262, page 599 - 602 ; (from Gmelin) View in Reaxys

P Br

Br Br

P Cl

Rx-ID: 26486985 View in Reaxys 705/751 Yield

Conditions & References With chlorine in not given, react. with Cl2; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 ; (from Gmelin) View in Reaxys With Cl2 in not given, react. with Cl2; vol. P: MVol.C; 262, page 599 - 602 ; (from Gmelin) View in Reaxys

P Br

Br Br

P Cl

PCl Cl

Rx-ID: 26486986 View in Reaxys 706/751 Yield

Conditions & References With chlorine in not given, react. with an excess of Cl2; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 ; (from Gmelin) View in Reaxys With Cl2 in not given, react. with an excess of Cl2; vol. P: MVol.C; 262, page 599 - 602 ; (from Gmelin) View in Reaxys

Br -1 O

Br 2 O–

(v1)

Ca 2+

Rx-ID: 26349261 View in Reaxys 707/751 Yield

Conditions & References With carbon dioxide in not given, slow introducing of CO2 flow into very dild. Ca(BrO)2 soln.; distn. in vac. Dancer, W.; Journal of the Chemical Society; vol. 15; (1862); p. 479 View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys With CO2 in not given, slow introducing of CO2 flow into very dild. Ca(BrO)2 soln.; distn. in vac. Balard, A. J.; Journal fuer Praktische Chemie (Leipzig); vol. 4; (1835); p. 172 View in Reaxys Dancer, W.; Liebigs Annalen der Chemie; vol. 125; (1863); p. 239 ; (from Gmelin) View in Reaxys

Rx-ID: 26349512 View in Reaxys 708/751 Yield

Conditions & References With hydrogenchloride Dancer, W.; Journal of the Chemical Society; vol. 15; (1862); p. 479 View in Reaxys

190/201

2017-08-09 05:21:10

Schoenbein, C. F.; Justus Liebigs Annalen der Chemie; vol. 2; (1863); p. 218 View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys With chlorine in water, with chlorine water Schoenbein, C. F.; Justus Liebigs Annalen der Chemie; vol. 2; (1863); p. 218 View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys With HCl Dancer, W.; Liebigs Annalen der Chemie; vol. 125; (1863); p. 239 ; (from Gmelin) View in Reaxys

Br( 1-)

HO( 1-)

Br Br

Rx-ID: 26349544 View in Reaxys 709/751 Yield

Conditions & References in equilibrium Schoenbein, C. F.; Justus Liebigs Annalen der Chemie; vol. 2; (1863); p. 218 View in Reaxys vol. Br: MVol.; 11.2, page 294 - 298 ; (from Gmelin) View in Reaxys

Br 2 O–

Ca 2+

Rx-ID: 26587620 View in Reaxys 710/751 Yield

Conditions & References in not given, in dild. Ca(OBr)2-solution no complete decomposition with a slow CO2-stream under formation of Br2; Dancer, W.; Journal of the Chemical Society; vol. 15; (1862); p. 477 - 488 View in Reaxys Dancer, W.; Liebigs Annalen der Chemie; vol. 125; (1863); p. 237 - 249 ; (from Gmelin) View in Reaxys in not given, in concd. Ca(OBr)2-solution formation of Br2 with excess CO2; Dancer, W.; Journal of the Chemical Society; vol. 15; (1862); p. 477 - 488 View in Reaxys Dancer, W.; Liebigs Annalen der Chemie; vol. 125; (1863); p. 237 - 249 ; (from Gmelin) View in Reaxys vol. Ca: MVol.B2; 150, page 607 - 609 ; (from Gmelin) View in Reaxys

Br Br Br

Rx-ID: 7054033 View in Reaxys 711/751 Yield

Conditions & References T= 200 - 210 °C Reboul; Justus Liebigs Annalen der Chemie; vol. 124; (1862); p. 270 View in Reaxys

Br (v3)

Mo Br

Br Br2Mo

Rx-ID: 26405758 View in Reaxys 712/751

191/201

2017-08-09 05:21:10

Yield

Conditions & References in neat (no solvent), calcination of MoBr3; Blomstrand, C. W.; Journal fuer Praktische Chemie (Leipzig); vol. 82; (1861); p. 436 - 436 View in Reaxys vol. Mo: MVol.; 63, page 177 - 179 ; (from Gmelin) View in Reaxys

O Br

N BrBr

(v2)

Rx-ID: 26598939 View in Reaxys 713/751 Yield

Conditions & References slow heating Landolt, H.; Liebigs Annalen der Chemie; vol. 116; (1860); p. 191 View in Reaxys vol. Br: MVol.; 13.1, page 326 - 337 ; (from Gmelin) View in Reaxys

Br–

N+

Ag+

O–

Rx-ID: 8213723 View in Reaxys 714/751 Yield

Conditions & References Hofmann,A.W.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 47; (1858); p. 559; Annales de Chimie (Cachan, France); vol. <3>54; (1858); p. 359 View in Reaxys Hofmann,A.W.; Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften; (1858); p. 339 View in Reaxys Br

O N

P Br

Rx-ID: 26423851 View in Reaxys 715/751 Yield

Conditions & References in neat (no solvent), decomposition with evolution of Br2; Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys Gladstone, J. H.; Journal fuer Praktische Chemie (Leipzig); vol. 49; (1850); p. 40 - 51 View in Reaxys vol. P: MVol.C; 221, page 508 - 509 ; (from Gmelin) View in Reaxys

OH (v6)

U OO

BrK

Rx-ID: 26062216 View in Reaxys 716/751 Yield

Conditions & References warming Schoenbein, C. F.; Annalen der Physik (Weinheim, Germany); vol. 78; (1849); p. 519 ; (from Gmelin) View in Reaxys vol. K: MVol.3; 1.1.2.7, page 536 - 538 ; (from Gmelin) View in Reaxys

192/201

2017-08-09 05:21:10

3 H+

O–

BrK

–O Sb O–O

Rx-ID: 26097339 View in Reaxys 717/751 Yield

Cl Fe Cl

(v3)

BrK

Rx-ID: 26097342 View in Reaxys 718/751 Yield

Conditions & References in neat (no solvent), an anhydrous mixture of FeCl3 and KBr is warmed, evolution of Br2; Schoenbein, C. F.; Annalen der Physik (Weinheim, Germany); vol. 78; (1849); p. 520 - 520 View in Reaxys vol. Fe: MVol.B1; 107, page 238 - 239 ; (from Gmelin) View in Reaxys O–

3 H+

BrK

As O O–O

–

Rx-ID: 26097357 View in Reaxys 719/751 Yield

OH (v6)

BrK

Cr HO OO

Rx-ID: 26097368 View in Reaxys 720/751 Yield

BrK

(v4)

Rx-ID: 26097369 View in Reaxys 721/751 Yield

193/201

2017-08-09 05:21:10

OH (v6)

BrK

Mo HO OO

Rx-ID: 26097370 View in Reaxys 722/751 Yield

(v6)

BrK

Rx-ID: 26097405 View in Reaxys 723/751 Yield

Cl P

Rx-ID: 26469892 View in Reaxys 724/751 Yield

Conditions & References With chlorine in neat (no solvent) Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys With chlorine Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys

O Br

2+ O– Co

O 6

Co 3O4

H O

Rx-ID: 26365379 View in Reaxys 725/751 Yield

Conditions & References in water, byproducts: Co-oxide; decompn. of the aqueous soln. at slight warming under developement of Br2 and pptn. of black Co-oxide; Rammelsberg, C.; Annalen der Physik (Weinheim, Germany); vol. 55; (1842); p. 71 - 71 ; (from Gmelin) View in Reaxys in water, byproducts: Co-oxide; decompn. of the aqueous soln. at slight warming under developement of Br2 and pptn. of black Co-oxide; vol. Co: MVol.A2; 34, page 310 - 312 ; (from Gmelin) View in Reaxys

194/201

2017-08-09 05:21:10

2+ O– Co

Rx-ID: 26365380 View in Reaxys 726/751 Yield

Conditions & References in neat (no solvent), byproducts: Co-oxide; at heating decomposition in Br2, O2 and black Co-oxide; Rammelsberg, C.; Annalen der Physik (Weinheim, Germany); vol. 55; (1842); p. 71 - 71 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: Co-oxide; at heating decomposition in Br2, O2 and black Co-oxide; vol. Co: MVol.A2; 34, page 310 - 312 ; (from Gmelin) View in Reaxys

O Br

2+ O– Cd

Br2Cd

CdO

H O

Rx-ID: 26608495 View in Reaxys 727/751 Yield

Conditions & References decomposition by heating under formation of O2, Br2, CdO, CdBr2; Rammelsberg; Annalen der Physik (Weinheim, Germany); vol. 55; (1842); p. 74 - 74 View in Reaxys Groth, P.; Chemische Krystallographie, Bd. 2, W. Engelmann, Leipzig, S. 117 ; (from Gmelin) View in Reaxys decomposition by heating under formation of O2, Br2, CdO, CdBr2; vol. Cd: MVol.; 39, page 100 - 102 ; (from Gmelin) View in Reaxys

O 2

Br(v1) O–2+Hg Hg

(v1)

2 O

O– O

Hg 2+

Rx-ID: 26621443 View in Reaxys 728/751 Yield

Conditions & References in water, at concentrating acidic mother liquor; Rammelsberg, C.; Ann. Physik (2); vol. 55; (1842); p. 63 - 88 ; (from Gmelin) View in Reaxys in water vol. Hg: MVol.B2; 195, page 810 - 812 ; (from Gmelin) View in Reaxys H

O 2

Br(v1) O–2+Hg Hg O

(v1)

O 2

Hg 2+ Br

O–

Rx-ID: 26621444 View in Reaxys 729/751 Yield

Conditions & References in water, evaporation of mother liquor; Rammelsberg, C.; Ann. Physik (2); vol. 55; (1842); p. 63 - 88 ; (from Gmelin) View in Reaxys in water, evaporation of mother liquor;

195/201

2017-08-09 05:21:10

vol. Hg: MVol.B2; 196, page 812 - 814 ; (from Gmelin) View in Reaxys O Ag+

O–

AgBr

Rx-ID: 26440162 View in Reaxys 730/751 Yield

Conditions & References byproducts: O2; thermal decompn. (Br2 developing in case of explosion) Rammelsberg, C.; Ann. Physik Chem. (2); vol. 52; (1841); p. 79 - 97 ; (from Gmelin) View in Reaxys byproducts: O2; thermal decompn. (Br2 developing in case of explosion) vol. Ag: MVol.B2; 7.16.3, page 175 - 176 ; (from Gmelin) View in Reaxys

NH +4

O–

Rx-ID: 26448349 View in Reaxys 731/751 Yield

Conditions & References byproducts: H2O; moderate heating causes deflegration Rammelsberg, C.; Annalen der Physik (Weinheim, Germany); vol. 52; (1841); p. 85 ; (from Gmelin) View in Reaxys byproducts: H2O, NH4Br; moderate heating causes deflegration Loewig, C.; Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, S. 69. ; (from Gmelin) View in Reaxys byproducts: H2O; moderate heating causes deflegration vol. NH4: MVol.1; 2.9.3, page 215 - 222 ; (from Gmelin) View in Reaxys byproducts: H2O, NH4Br; moderate heating causes deflegration vol. NH4: MVol.1; 2.9.3, page 215 - 222 ; (from Gmelin) View in Reaxys H

O 2

Zn 2+ Br

H H

OZn

O–

Rx-ID: 26476152 View in Reaxys 732/751 Yield

Conditions & References complete loss of water of crystallization and decompn. at 200 °C; Rammelsberg; Annalen der Physik (Weinheim, Germany); vol. 52; (1841); p. 90 - 90 ; (from Gmelin) View in Reaxys complete loss of water of crystallization and decompn. at 200 °C; vol. Zn: MVol.; 66, page 185 - 187 ; (from Gmelin) View in Reaxys

196/201

2017-08-09 05:21:10

2+ O– Cu

CuO

Rx-ID: 26603012 View in Reaxys 733/751 Yield

Conditions & References in neat (no solvent), byproducts: basic Cu(II) bromate; on heating to ca 200°C in a closed vessel at ambient pressure; Rammelsberg, C.; Annalen der Physik (Weinheim, Germany); vol. 52; (1841); p. 79 - 97 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: basic Cu(II) bromate; on heating to ca 200°C in a closed vessel at ambient pressure; vol. Cu: MVol.B1; 176, page 387 - 388 ; (from Gmelin) View in Reaxys H

O 2

O–

Br Br

O H 2

Zn 2+

Rx-ID: 26611801 View in Reaxys 734/751 Yield

Conditions & References heated moderately, slow reaction even when stored; Rammelsberg; Annalen der Physik (Weinheim, Germany); vol. 52; (1841); p. 90 - 90 ; (from Gmelin) View in Reaxys heated moderately, slow reaction even when stored; vol. Zn: MVol.; 66, page 185 - 187 ; (from Gmelin) View in Reaxys O

Br–

NH +4

Br Br

Rx-ID: 26062318 View in Reaxys 735/751 Yield

Conditions & References in neat (no solvent), decompn. of NH4Br by SO3-vapor;; generation of Br2-vapor, formation of a yellow brown substance; Rose, H.; Ann. Chim. Phys.; vol. 63; (1836); p. 80 - 86 View in Reaxys Rose, H.; Annalen der Physik (Weinheim, Germany); vol. 38; (1836); p. 117 - 123 View in Reaxys vol. S: MVol.B1; 164, page 361 - 363 ; (from Gmelin) View in Reaxys

O O

O (v6)

K+

(v6) Cr O–

O–

Rx-ID: 26183846 View in Reaxys 736/751 Yield

Conditions & References With potassium bromide in sulfuric acid, addn. of concd. H2SO4 to K2Cr2O7/KBr mixt.; Rose, H.; Annalen der Physik (Weinheim, Germany); vol. 27; (1834); p. 565 - 575 View in Reaxys vol. Cr: MVol.B; 251, page 556 - 558 ; (from Gmelin)

197/201

2017-08-09 05:21:10

View in Reaxys OH O

Cl OO

Br( 1-)

Rx-ID: 26109295 View in Reaxys 737/751 Yield

Conditions & References

in water Serullas; Ann. Chim. Phys.; vol. 46; (1831); p. 297 - 297 View in Reaxys vol. Cl: MVol.; 143, page 387 - 388 ; (from Gmelin) View in Reaxys Cl

Br Br Br TB-5 P Br Br

PCl Cl TB-5

Rx-ID: 26535844 View in Reaxys 738/751 Yield

Conditions & References With chlorine in neat (no solvent) Balard, A.-J.; Ann. Chim. Phys.; vol. 32; (1826); p. 337 - 381 View in Reaxys Loewig, C.; Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, 1/74 ; (from Gmelin) View in Reaxys With Cl2 in neat (no solvent) vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin) View in Reaxys 2

K+ –O

BrK

O S

–O

S Br

Rx-ID: 26097314 View in Reaxys 739/751 Yield

Conditions & References in liquid sulphur dioxide, solvolysis vol. S: SVol.3; 2.1.10.4, page 233 - 234 View in Reaxys Jander, G.; Die Chemie in wasseraehnlichen Loesungsmitteln, Berlin - Goettingen - Heildelberg 1949, S. 209/307 ; (from Gmelin) View in Reaxys in sulfur dioxide, solvolysis Karcher, W.; Hecht, H.; in: G. Jander, H. Spandau, C. C. Addison, Chemie in nichtwaessrigen ionisierenden Loesungsmitteln, Bd. 3, Tl. 2. London - New York - Sydney 1967, S. 79/193 View in Reaxys Karcher, W.; Diss. Berlin 1961 ; (from Gmelin) View in Reaxys

Rx-ID: 26342687 View in Reaxys 740/751 Yield

Conditions & References in neat (no solvent), thermal decomposition above 450°C; mechanism discussed; Kern, J.; Deut. Luft-Raumfahrt Forschungsber. DLR-FB-68-04 (1968) 1/55 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.3.7.5, page 384 - 385 ; (from Gmelin)

198/201

2017-08-09 05:21:10

View in Reaxys F

Rx-ID: 26342688 View in Reaxys 741/751 Yield

Conditions & References With oxygen in neat (no solvent), reaction with O2 at 400-900°C; mechanism discussed; Kern, J.; Deut. Luft-Raumfahrt Forschungsber. DLR-FB-68-04 (1968) 1/55 ; (from Gmelin) View in Reaxys With O2 vol. C: MVol.D2; 4.3.7.5, page 384 - 385 ; (from Gmelin) View in Reaxys Br

Br2Hg 3Se2

Rx-ID: 26359441 View in Reaxys 742/751 Yield

Conditions & References With manganese(IV) oxide in sulfuric acid, boiling in aq.H2SO4 Fonzes-Diacon, H.; These Paris 1901, pp. 1/117, 96 ; (from Gmelin) View in Reaxys With MnO2 in sulfuric acid, aq. H2SO4; boiling in aq.H2SO4 vol. Hg: MVol.B3; 2.6.4, page 1105 - 1107 ; (from Gmelin) View in Reaxys

Br F

Rx-ID: 26385481 View in Reaxys 743/751 Yield

Conditions & References in neat (no solvent), thermal decomposition on passing through a tube at 400-1200°C;; products depending on temp.; vol. C: MVol.D2; 4.3.3.3, page 377 - 378 View in Reaxys Kern, J.; Deut. Luft Raumfahrt Forschungsber. DLR-FB-68-04 (1968) 1/55 ; (from Gmelin) View in Reaxys

Rx-ID: 26385482 View in Reaxys 744/751 Yield

Conditions & References With oxygen in neat (no solvent), oxidation at 300-650°C; vol. C: MVol.D2; 4.3.3.3, page 377 - 378 View in Reaxys Kern, J.; Deut. Luft Raumfahrt Forschungsber. DLR-FB-68-04 (1968) 1/55 ; (from Gmelin) View in Reaxys

Br P

Cu 2P

Rx-ID: 26431618 View in Reaxys 745/751 Yield <1

Conditions & References in neat (no solvent), heating starting material in a sealed tube at 100°C;

199/201

2017-08-09 05:21:10

Wolf, L.; Diss. Berlin T. H. 1915, S. 1/40 ; (from Gmelin) View in Reaxys <1

in neat (no solvent), heating starting material in a sealed tube at 100°C; vol. P: MVol.C; 216, page 496 - 498 ; (from Gmelin) View in Reaxys O

Ag+

O–

AgBr

Br Br

S OO

Rx-ID: 26440163 View in Reaxys 746/751 Yield

Conditions & References With sulfur dioxide, no Br2 formed with excess SO2 vol. S: MVol.B2; 1.6.2.4, page 519 - 520 View in Reaxys Stas, J. S.; Untersuchungen ueber die Gestze der chemischen Promotionen, Leipzig 1867, p. 77 ; (from Gmelin) View in Reaxys O

O N

Rx-ID: 26441270 View in Reaxys 747/751 Yield

Conditions & References in neat (no solvent), at -130°C; vol. Cl: SVol.B2; 98, page 527 - 529 View in Reaxys Elischer, S.; Diss. Muenchen 1954, S. 27 View in Reaxys Elischer, S.; Diss. Muenchen 1954, S. 52 ; (from Gmelin) View in Reaxys

Br P

Rx-ID: 26469891 View in Reaxys 748/751 Yield

Conditions & References With chlorine vol. P: MVol.C; 215, page 494 - 496 View in Reaxys Loewig, C.; Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, S. 1/174 ; (from Gmelin) View in Reaxys With chlorine in neat (no solvent) vol. P: MVol.C; 215, page 494 - 496 View in Reaxys Loewig, C.; Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, S. 1/174 ; (from Gmelin) View in Reaxys

Br O

OH HO

S OO

Rx-ID: 26484194 View in Reaxys 749/751 Yield

Conditions & References With sulfur dioxide in water vol. S: MVol.B2; 1.6.2.4, page 519 - 520 View in Reaxys

200/201

2017-08-09 05:21:10

Rose, H.; Ausfuerliches Handbuch der analytischen Chemie, 5. ed., vol. 1, Braunschweig 1851, p. 573 ; (from Gmelin) View in Reaxys F Br

F4ORu

O2Si

Si FF

Rx-ID: 26573274 View in Reaxys 750/751 Yield

Conditions & References in neat (no solvent), react. of Ru with BrF3 and SiO2 from the pyrex glass of the app.; Bartlett, N.; Jolly, W. L., Preparative Inorganic Reactions, Bd. 2, New York-London-Sydney, S. 301/335 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of Ru with BrF3 and SiO2 from the pyrex glass of the app.; vol. Ru: SVol.; 83, page 273 - 274 ; (from Gmelin) View in Reaxys

Br Cl

Rx-ID: 26598900 View in Reaxys 751/751 Yield

Conditions & References in neat (no solvent), Kinetics, other Radiation; γ-radiolysis at -196 and 131°C; vol. C: MVol.D2; 4.3.5.5, page 381 - 382 View in Reaxys Schwartz, L. L.; Firestone, R. F.; TID-16579 (1962) 6 S. ; (from Gmelin) View in Reaxys

201/201

2017-08-09 05:21:10