Query Query
Results
Date
4 substances in Reaxys
2017-10-13 06h:02m:30s (EST)
2 substances in Reaxys
2017-10-13 06h:03m:38s (EST)
Br
1. Query
Br PBr Br Br
Search as: As drawn, No salts, No mixtures, No isotopes, No charges, No radicals 2. Query
(1. Query) AND NOT itemno in (3,4)
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Reaxys ID 3903332 View in Reaxys
1/2 CAS Registry Number: 7789-69-7 Chemical Name: phosphorus pentabromide; phosphorous pentabromide; pentabromophosphorane; phosphorus(V) bromide; phosphorpentabromide; PBr5; Phosphorus pentabromide Linear Structure Formula: PBr5 Molecular Formula: Br5P Molecular Weight: 430.494 InChI Key: QRKVRHZNLKTPGF-UHFFFAOYSA-N Note:
Br Br PBr Br Br
Druglikeness (1) 1 of 1
LogP
4.25
H Bond Donors
0
H Bond Acceptors
0
Rotatable Bonds
0
TPSA
0
Lipinski Number
4
Veber Number
2
Melting Point (1) 1 of 1
Melting Point [°C]
103.7
Kuz'menko, A. A.; Fialkov, Ya. A.; Zh. obshch. Khim.; vol. 19; (1949); p. 1007 - 1013; C.; (1949); p. E 3745, View in Reaxys; vol. P: MVol.C; 232, page 531 - 533 ; (from Gmelin), View in Reaxys Crystal Property Description (1) Colour & Other References Properties orange-red
Rovnanik, Pavel; Zak, Zdirad; Cernik, Milos; Zeitschrift fur Anorganische und Allgemeine Chemie; vol. 632; nb. 7; (2006); p. 1356 - 1362 ; (from Gmelin), View in Reaxys
Dissociation Energy (1) Comment (Disso- References ciation Energy) information on dissociation energy
Jan-Khan, M.; Samuel, R.; Proceedings of the Physical Society, London; vol. 48; (1936); p. 626 - 641, View in Reaxys; vol. P: MVol.C; 165, page 378 - 381 ; (from Gmelin), View in Reaxys
Electrochemical Behaviour (1) Description (Elec- References trochemical Behaviour) acid / base behaviour
Siddiqi, Z. A.; Aslam, Mohammad; Ansari, N. A.; Shakir, M.; Zaidi, S. A. A.; Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical; vol. 20; nb. 8; (1981); p. 773 - 776 ; (from Gmelin), View in Reaxys
Further Information (17) Description (Fur- Comment (Further Information) ther Information)
References
Reaction with substance classes
title compound re- Mikhailov, B. M.; Blokhina, A. N.; Fedotov, N. S.; Izvestiya Akademii Nauk SSSR, Seract with (organiya Khimicheskaya; (1958); p. 891 - 893 ; (from Gmelin), View in Reaxys yl)alkoxyborane to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Blokhina, A. N.; Fedotov, N. S.; Izvestiya Akademii Nauk SSSR, Seract with diborylox- iya Khimicheskaya; (1958); p. 891 - 893 ; (from Gmelin), View in Reaxys ide to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Blokhina, A. N.; Fedotov, N. S.; Izvestiya Akademii Nauk SSSR, Seract with organyliya Khimicheskaya; (1958); p. 891 - 893 ; (from Gmelin), View in Reaxys boroxine to (organyl)bromoborane
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Reaction with substance classes
title compound re- Mikhailov, B. M.; Kostroma, T. V.; Fedotov, N. S.; Izvestiya Akademii Nauk SSSR, Seract with (organiya Khimicheskaya; (1957); p. 589 - 597 ; (from Gmelin), View in Reaxys yl)alkoxyborane to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Kostroma, T. V.; Fedotov, N. S.; Izvestiya Akademii Nauk SSSR, Seract with diborylox- iya Khimicheskaya; (1957); p. 589 - 597 ; (from Gmelin), View in Reaxys ide to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Kostroma, T. V.; Fedotov, N. S.; Izvestiya Akademii Nauk SSSR, Seract with organyliya Khimicheskaya; (1957); p. 589 - 597 ; (from Gmelin), View in Reaxys boroxine to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Fedotov, N. S.; Izvestiya Akademii Nauk SSSR, Seriya Khimicheact with (organskaya; (1956); p. 375 - 376 ; (from Gmelin), View in Reaxys yl)alkoxyborane to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Kostroma, T. V.; Izvestiya Akademii Nauk SSSR, Seriya Khimicheact with (organskaya; (1956); p. 1144 - 1146 ; (from Gmelin), View in Reaxys yl)alkoxyborane to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Fedotov, N. S.; Izvestiya Akademii Nauk SSSR, Seriya Khimicheact with diborylox- skaya; (1956); p. 375 - 376 ; (from Gmelin), View in Reaxys ide to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Kostroma, T. V.; Izvestiya Akademii Nauk SSSR, Seriya Khimicheact with diborylox- skaya; (1956); p. 1144 - 1146 ; (from Gmelin), View in Reaxys ide to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Fedotov, N. S.; Izvestiya Akademii Nauk SSSR, Seriya Khimicheact with organylskaya; (1956); p. 375 - 376 ; (from Gmelin), View in Reaxys boroxine to (organyl)bromoborane
Reaction with substance classes
title compound re- Mikhailov, B. M.; Kostroma, T. V.; Izvestiya Akademii Nauk SSSR, Seriya Khimicheact with organylskaya; (1956); p. 1144 - 1146 ; (from Gmelin), View in Reaxys boroxine to (organyl)bromoborane
Behaviour as catalyst
Booth, H. S.; Frary, S. G.; Journal of the American Chemical Society; vol. 61; (1939); p. 2934 - 2937 ; (from Gmelin), View in Reaxys
Behaviour as catalyst
vol. P: MVol.C; 222, page 509 - 511 ; (from Gmelin), View in Reaxys
Reaction with substance classes
title compound re- vol. B: B-Verb.9; 4.2.2.4, page 121 - 122 ; (from Gmelin), View in Reaxys act with (organyl)alkoxyborane to (organyl)bromoborane
Reaction with substance classes
title compound re- vol. B: B-Verb.9; 4.2.2.4, page 121 - 122 ; (from Gmelin), View in Reaxys act with diboryloxide to (organyl)bromoborane
Reaction with substance classes
title compound re- vol. B: B-Verb.9; 4.2.2.4, page 121 - 122 ; (from Gmelin), View in Reaxys act with organylboroxine to (organyl)bromoborane
Solubility (MCS) (6)
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1 of 6
Solvent (Solubility (MCS))
sulfur dioxide
Comment (Solubility (MCS))
Solubility: 1.2E1 weight-percent
Finkelstein, W.; Z. phys. Ch.; vol. 115; (1925); p. 303 - 329, View in Reaxys; Satenshtein, A. I.; Viktorov, M. M.; Acta physicokhim. URSS; vol. 7; (1937); p. 883 - 898, View in Reaxys; Walden, P.; Centnerszwer, A.; Teletow, I.; Z. phys. Ch.; vol. 43; (1903); p. 385 - 464, View in Reaxys; vol. S: MVol.B1; 143, page 310 - 315, View in Reaxys; Behne, W.; Diss. Greifswald 1945 laut Jander, G., Die Grundlagen der Chemie in fluessigem Schwefeldioxyd in: Naturw. 26 (1938) 264/73 ; (from Gmelin), View in Reaxys 2 of 6
Comment (Solubility (MCS))
sol. in liq. Br2
Finkelstein, W.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 55; (1924); p. 84, View in Reaxys; Plotnikow, W. A.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 35; (1903); p. 803 - 805, View in Reaxys; Plotnikow, W. A.; Z. phys. Ch.; vol. 48; (1904); p. 222, View in Reaxys; vol. Br: MVol.; 4.4, page 151 - 156, View in Reaxys; Finkelstein, W.; Z. phys. Ch.; vol. 105; (1923); p. 10 ; (from Gmelin), View in Reaxys 3 of 6
Comment (Solubility (MCS))
sol. in liq. HBr
Archibald, E. H.; McIntosch, D.; Proceedings of the Royal Society of London; vol. 73; (1904); p. 454, View in Reaxys; McIntosch, D.; Steele, B. P.; Proceedings of the Royal Society of London; vol. 73; (1904); p. 453, View in Reaxys; Steele, B. D.; McIntosch, D.; Archibald, E. H.; Philosophical Transactions of the Royal Society of London; vol. A 205; (1906); p. 121, View in Reaxys; Steele, B. D.; McIntosch, D.; Archibald, E. H.; Z. phys. Ch.; vol. 55; (1906); p. 152, View in Reaxys; vol. Br: MVol.; 8.2, page 244 - 249 ; (from Gmelin), View in Reaxys 4 of 6
Comment (Solubility (MCS))
sol. in liq. HCl;
Intosh, Mc; Archibald; Proceedings of the Royal Society of London; vol. 73; (1904); p. 454 - 454, View in Reaxys; Intosh, Mc; Archibald; Z. phys. Ch.; vol. 55; (1906); p. 151 - 151, View in Reaxys; vol. Cl: MVol.; 45, page 134 136 ; (from Gmelin), View in Reaxys 5 of 6
Comment (Solubility (MCS))
readily sol. in POCl5;
Oddo, G.; Tealdi, M.; Gazzetta Chimica Italiana; vol. 33; nb. II; (1903); p. 427 - 449, View in Reaxys; vol. P: MVol.C; 207, page 475 - 478 ; (from Gmelin), View in Reaxys 6 of 6
Comment (Solubility (MCS))
soluble in AsCl3;
Walden, P.; Z. phys. Ch.; vol. 43; (1903); p. 383 - 464, View in Reaxys; vol. As: MVol.; 144, page 381 - 382 ; (from Gmelin), View in Reaxys Raman Spectroscopy (1) Description (Ram- References an Spectroscopy) Raman
Use (3) Laboratory Use and Handling thermally unstable
Finch, Arthur; Gates, Peter N.; Muir, Alan S.; Journal of the Chemical Society, Chemical Communications; nb. 15; (1981); p. 812 - 814, View in Reaxys; Gerding, H.; Nobel, P. C.; Recueil Trav. chim. (engl.); vol. 77; (1958); p. 472 - 478, View in Reaxys; vol. P: MVol.C; 164, page 375 - 378 ; (from Gmelin), View in Reaxys Use Pattern
References Rovnanik, Pavel; Zak, Zdirad; Cernik, Milos; Zeitschrift fur Anorganische und Allgemeine Chemie; vol. 632; nb. 7; (2006); p. 1356 - 1362 ; (from Gmelin), View in Reaxys
Brominating Patent; LUPIN LTD; US2005/245738; (2005); (A1) English, View in Reaxys agent in synthesis of highly pure cefdinir decompd. with H2O
Bodenstein, M.; Jost, W.; Journal of the American Chemical Society; vol. 49; (1927); p. 1418, View in Reaxys; vol. Br: MVol.; 6.3, page 208 - 213 ; (from Gmelin), View in Reaxys
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Reaxys ID 16888325 View in Reaxys
2/2 CAS Registry Number: 7789-69-7 Chemical Name: phosphorus(V) bromide; Phosphor(V)-bromid Linear Structure Formula: PBr5 Molecular Formula: Br5P Molecular Weight: 430.494 InChI Key: QRKVRHZNLKTPGF-UHFFFAOYSA-N Note:
Br Br Br TB-5 P Br Br
Druglikeness (1) 1 of 1
LogP
4.25
H Bond Donors
0
H Bond Acceptors
0
Rotatable Bonds
0
TPSA
0
Lipinski Number
4
Veber Number
2
Purification (2) Purification (method)
References
purification described
Harries, G. S.; Payne, D. S.; Journal of the Chemical Society; (1958); p. 3732 - 3733, View in Reaxys; Hoenigschmid, O.; Hirschbold-Wittner, F.; Z. Anorg. Chem.; vol. 243; (1940); p. 355 - 360 ; (from Gmelin), View in Reaxys
purification described
Driel, M. van; MacGillavry, C. H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 62; (1943); p. 167 171, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500, View in Reaxys; vol. P: MVol.C; 220, page 506 508 ; (from Gmelin), View in Reaxys
Density (3) 1 of 3
Density [g·cm-3]
3.574
Measurement Temperature [°C]
-79
Type (Density)
crystallographic
Biltz, W.; Sapper, A.; Wuennenberg, E.; Z. Anorg. Chem.; vol. 203; (1932); p. 277 - 306, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 2 of 3
Density [g·cm-3]
3.707
Measurement Temperature [°C]
-183
Type (Density)
crystallographic
Biltz, W.; Sapper, A.; Wuennenberg, E.; Z. Anorg. Chem.; vol. 203; (1932); p. 277 - 306, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 3 of 3
Density [g·cm-3]
3.74
Measurement Temperature [°C]
-273
Comment (Density)
extrapolated;
Biltz, W.; Sapper, A.; Wuennenberg, E.; Z. Anorg. Chem.; vol. 203; (1932); p. 277 - 306, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys Crystal Phase (3) Description (Crys- References tal Phase) Crystal growth
Driel, M. van; MacGillavry, C. H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 62; (1943); p. 167 171, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys
Structure of the solid
Driel, M. van; MacGillavry, C. H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 62; (1943); p. 167 171, View in Reaxys; Powell, H. M.; Clark, D.; Nature (London, United Kingdom); vol. 145; (1940); p. 971 971, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys
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Single Crystal Xray Diffraction
Driel, M. van; MacGillavry, C. H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 62; (1943); p. 167 171, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys
Crystal Property Description (4) Colour & Other Comment (Crystal References Properties Property Description) red
SbBr3
Jander, C.; Weis, J.; Zeitschrift fuer Elektrochemie; vol. 61; (1957); p. 1275 - 1283, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys
red
Balard, A.-J.; Ann. Chim. Phys.; vol. 32; (1826); p. 337 - 381, View in Reaxys; Driel, M. van; Gerding, H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 60; (1941); p. 869 - 876, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys
brownyellow
Driel, M. van; Gerding, H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 60; (1941); p. 869 - 876, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys
yellow
Balard, A.-J.; Ann. Chim. Phys.; vol. 32; (1826); p. 337 - 381, View in Reaxys; Kastle, J. H.; Beatty, L. O.; American Chemical Journal; vol. 23; (1900); p. 505 - 509, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503, View in Reaxys; vol. P: MVol.C; 219, page 503 - 506 ; (from Gmelin), View in Reaxys
Crystal System (1) Crystal System References Rhombic
Powell, H. M.; Clark, D.; Nature (London, United Kingdom); vol. 145; (1940); p. 971 - 971, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys
Electrolytic Conductivity (11) 1 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
1.226E-06
Temperature (Electrolytic Conductivity) [°C]
25
Solvent (Electrolytic Conductivity)
acetonitrile
Kind of Conductivity
Molar conductivity
Comment (Electrolytic Conductivity)
0.0296 mol/l;
Harries, G. S.; Payne, D. S.; Journal of the Chemical Society; (1956); p. 4617 - 4621, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys 2 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
1.395E-06
Temperature (Electrolytic Conductivity) [°C]
25
Solvent (Electrolytic Conductivity)
acetonitrile
Kind of Conductivity
Molar conductivity
Comment (Electrolytic Conductivity)
0.0152 mol/l;
Harries, G. S.; Payne, D. S.; Journal of the Chemical Society; (1956); p. 4617 - 4621, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys 3 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
1.425E-06
Temperature (Electrolytic Conductivity) [°C]
25
Solvent (Electrolytic Conductivity)
acetonitrile
Kind of Conductivity
Molar conductivity
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Comment (Electrolytic Conductivity)
0.0195 mol/l;
Harries, G. S.; Payne, D. S.; Journal of the Chemical Society; (1956); p. 4617 - 4621, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys 4 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
7.86E-07
Temperature (Electrolytic Conductivity) [°C]
25
Solvent (Electrolytic Conductivity)
acetonitrile
Kind of Conductivity
Molar conductivity
Comment (Electrolytic Conductivity)
0.0729 mol/l;
Harries, G. S.; Payne, D. S.; Journal of the Chemical Society; (1956); p. 4617 - 4621, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys 5 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
0.023
Temperature (Electrolytic Conductivity) [°C]
18
Solvent (Electrolytic Conductivity)
not given
Kind of Conductivity
Molar conductivity
Comment (Electrolytic Conductivity)
419 ml Br2/mol PBr5;
Plotnikov, V. A.; Izv. Kievsk. politekhn. Inst.; (1904); p. 1 - 18, View in Reaxys; Plotnikov, V. A.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 48; (1904); p. 220 - 236, View in Reaxys; Plotnikov, V. A.; Zap. Inst. Chem. (ukrain.); vol. 5; (1938); p. 271 - 358, View in Reaxys; Plotnikov, V. A.; Zh. russk. fiz-khim. Obshch.; vol. 35; (1903); p. 794 - 810, View in Reaxys; vol. P: MVol.C; 219, page 503 - 506 ; (from Gmelin), View in Reaxys 6 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
0.026
Temperature (Electrolytic Conductivity) [°C]
18
Solvent (Electrolytic Conductivity)
not given
Kind of Conductivity
Molar conductivity
Comment (Electrolytic Conductivity)
1030 ml Br2/mol PBr5;
Plotnikov, V. A.; Izv. Kievsk. politekhn. Inst.; (1904); p. 1 - 18, View in Reaxys; Plotnikov, V. A.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 48; (1904); p. 220 - 236, View in Reaxys; Plotnikov, V. A.; Zap. Inst. Chem. (ukrain.); vol. 5; (1938); p. 271 - 358, View in Reaxys; Plotnikov, V. A.; Zh. russk. fiz-khim. Obshch.; vol. 35; (1903); p. 794 - 810, View in Reaxys; vol. P: MVol.C; 219, page 503 - 506 ; (from Gmelin), View in Reaxys 7 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
0.028
Temperature (Electrolytic Conductivity) [°C]
18
Solvent (Electrolytic Conductivity)
not given
Kind of Conductivity
Molar conductivity
Comment (Electrolytic Conductivity)
491 ml Br2/mol PBr5;
Plotnikov, V. A.; Izv. Kievsk. politekhn. Inst.; (1904); p. 1 - 18, View in Reaxys; Plotnikov, V. A.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 48; (1904); p. 220 - 236, View in Reaxys;
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Plotnikov, V. A.; Zap. Inst. Chem. (ukrain.); vol. 5; (1938); p. 271 - 358, View in Reaxys; Plotnikov, V. A.; Zh. russk. fiz-khim. Obshch.; vol. 35; (1903); p. 794 - 810, View in Reaxys; vol. P: MVol.C; 219, page 503 - 506 ; (from Gmelin), View in Reaxys 8 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
2.9E-06
Temperature (Electrolytic Conductivity) [°C]
18
Solvent (Electrolytic Conductivity)
not given
Kind of Conductivity
Molar conductivity
Comment (Electrolytic Conductivity)
2460 ml Br2/mol PBr5;
Plotnikov, V. A.; Izv. Kievsk. politekhn. Inst.; (1904); p. 1 - 18, View in Reaxys; Plotnikov, V. A.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 48; (1904); p. 220 - 236, View in Reaxys; Plotnikov, V. A.; Zap. Inst. Chem. (ukrain.); vol. 5; (1938); p. 271 - 358, View in Reaxys; Plotnikov, V. A.; Zh. russk. fiz-khim. Obshch.; vol. 35; (1903); p. 794 - 810, View in Reaxys; vol. P: MVol.C; 219, page 503 - 506 ; (from Gmelin), View in Reaxys 9 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
0.034
Temperature (Electrolytic Conductivity) [°C]
18
Solvent (Electrolytic Conductivity)
not given
Kind of Conductivity
Molar conductivity
Comment (Electrolytic Conductivity)
680 ml Br2/mol PBr5;
Plotnikov, V. A.; Izv. Kievsk. politekhn. Inst.; (1904); p. 1 - 18, View in Reaxys; Plotnikov, V. A.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 48; (1904); p. 220 - 236, View in Reaxys; Plotnikov, V. A.; Zap. Inst. Chem. (ukrain.); vol. 5; (1938); p. 271 - 358, View in Reaxys; Plotnikov, V. A.; Zh. russk. fiz-khim. Obshch.; vol. 35; (1903); p. 794 - 810, View in Reaxys; vol. P: MVol.C; 219, page 503 - 506 ; (from Gmelin), View in Reaxys 10 of 11
Electrolytic Conductivity [S·l/(cm·mol)]
3.8E-06
Temperature (Electrolytic Conductivity) [°C]
18
Solvent (Electrolytic Conductivity)
not given
Kind of Conductivity
Molar conductivity
Comment (Electrolytic Conductivity)
4340 ml Br2/mol PBr5;
Plotnikov, V. A.; Izv. Kievsk. politekhn. Inst.; (1904); p. 1 - 18, View in Reaxys; Plotnikov, V. A.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 48; (1904); p. 220 - 236, View in Reaxys; Plotnikov, V. A.; Zap. Inst. Chem. (ukrain.); vol. 5; (1938); p. 271 - 358, View in Reaxys; Plotnikov, V. A.; Zh. russk. fiz-khim. Obshch.; vol. 35; (1903); p. 794 - 810, View in Reaxys; vol. P: MVol.C; 219, page 503 - 506 ; (from Gmelin), View in Reaxys 11 of 11
Description (Electrolytic Conductivity)
Equivalent conductivity
Equivalent Conductivity [S·cm2/val]
11.36
Temperature (Electrolytic Conductivity) [°C]
0
Solvent (Electrolytic Conductivity)
liquid sulphur dioxide
Comment (Electrolytic Conductivity)
diln. 1715 l/val;
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Walden, P.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 43; (1903); p. 385 - 464, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys Enthalpy of Formation (3) Enthalpy of ForTemperature (Enmation [Jmol-1] thalpy of Formation) [°C]
Comment (Enthalpy of Formation)
References
-234400 -222600
25
Solid
Finch, A.; Gardner, P. J.; Wood, I. H.; Journal of the Chemical Society; (1965); p. 40 - 43, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys
-253600
18
Solid
vol. P: MVol.C; 217, page 498 - 500, View in Reaxys; Bichowsky, F. R.; Rossini, F. D.; The Thermochemistry of the chemical Substances, New York 1936, S. 222, View in Reaxys; Bichowsky, F. R.; Rossini, F. D.; The Thermochemistry of the chemical Substances, New York 1936, S. 39 ; (from Gmelin), View in Reaxys
-276200
25
Solid
vol. P: MVol.C; 217, page 498 - 500, View in Reaxys; Rossini, F. D.; Wagmann, D. D.; Evans, W. H.; Levine, S.; Jaffe, I.; Circ. Bur. Stand. Nr. 500 (1952) 79, View in Reaxys; Rossini, F. D.; Wagmann, D. D.; Evans, W. H.; Levine, S.; Jaffe, I.; Circ. Bur. Stand. Nr. 500 (1952) 848 ; (from Gmelin), View in Reaxys
Solubility (MCS) (4) 1 of 4
Comment (Solubility (MCS))
easily soluble in SbBr3;
Jander, C.; Weis, J.; Zeitschrift fuer Elektrochemie; vol. 61; (1957); p. 1275 - 1283, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys 2 of 4
Comment (Solubility (MCS))
sparingly soluble in CCl4, CS2 and C6H6 at ambient temperature;
Kolditz, L.; Feltz, A.; Z. Anorg. Chem.; vol. 293; (1957); p. 155 - 167, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys 3 of 4
Comment (Solubility (MCS))
easily soluble in CS2;
Popov, A. I.; Skelly, N. E.; Journal of the American Chemical Society; vol. 76; (1954); p. 3916 - 3919, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 4 of 4
Comment (Solubility (MCS))
soluble in liquid HCl, HBr and H2S;
Steele, B. D.; McIntosh, D.; Archibald, E. H.; Philosophical Transactions of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 205; (1905); p. 99 - 137, View in Reaxys; Steele, B. D.; McIntosh, D.; Archibald, E. H.; Z. physik. chem.; vol. 55; (1906); p. 129 - 199, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys Space Group (2) Space Group
57
Comment (Space Group)
References
a = 5.62 Angstroem, b = 16.91 Angstroem, c = 8.29 Angstroem; atomic positions available
Driel, M. van; MacGillavry, C. H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 62; (1943); p. 167 - 171, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys
a = 5.6 Angstroem, b = 16.9 Angstroem, c = 8.3 Angstroem; Z =4
Powell, H. M.; Clark, D.; Nature (London, United Kingdom); vol. 145; (1940); p. 971 971, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys
UV/VIS Spectroscopy (6) 1 of 6
Solvent (UV/VIS Spectroscopy)
CCl4
Comment (UV/VIS Spectroscopy)
300 nm - 600 nm
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Popov, A. I.; Skelly, N. E.; Journal of the American Chemical Society; vol. 76; (1954); p. 3916 - 3919 ; (from Gmelin), View in Reaxys 2 of 6
Solvent (UV/VIS Spectroscopy)
dichloroethane=1,2-dichloroethane
Comment (UV/VIS Spectroscopy)
300 nm - 600 nm
Popov, A. I.; Skelly, N. E.; Journal of the American Chemical Society; vol. 76; (1954); p. 3916 - 3919 ; (from Gmelin), View in Reaxys 3 of 6
Description (UV/VIS Spectroscopy)
Band assignment
Solvent (UV/VIS Spectroscopy)
gas
Absorption Maxima (UV/ 274.4 VIS) [nm] Jan-Khan, M.; Samuel, R.; Proceedings of the Physical Society, London; vol. 48; (1936); p. 626 - 641 ; (from Gmelin), View in Reaxys 4 of 6
Description (UV/VIS Spectroscopy)
Band assignment
Solvent (UV/VIS Spectroscopy)
neat (no solvent, gas phase)
Absorption Maxima (UV/ 274.4 VIS) [nm] vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 5 of 6
Solvent (UV/VIS Spectroscopy)
tetrachloromethane
Comment (UV/VIS Spectroscopy)
300 nm - 600 nm
vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys 6 of 6
Solvent (UV/VIS Spectroscopy)
1,2-dichloro-ethane
Comment (UV/VIS Spectroscopy)
300 nm - 600 nm
vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys Use (6) Laboratory Use and Handling
References
stable against IBr in 0.064 to 0.081 m solns. in CS2;
Gutmann, V.; Monatshefte fuer Chemie; vol. 82; (1951); p. 156 - 169, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys
explosive in mixture with alkali metals on impact;
vol. P: MVol.C; 218, page 501 - 503, View in Reaxys; Cueilleron, J.; Bull. Soc. chim. France (5); vol. 12; (1945); p. 88 - 89 ; (from Gmelin), View in Reaxys
vigorous, even Fry, H. S.; Donelly, J. L.; Journal of the American Chemical Society; vol. 38; (1916); p. 1923 - 1928, explosive reaction View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys with CrO2Cl2; deliquescent in air;
Thorpe, T. E.; Tutton, A. E.; Journal of the Chemical Society; vol. 59; (1891); p. 1019 - 1029, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys
reaction with PbO Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67, View in Reaxys; vol. P: MVol.C; 218, page 501 with glowing; 503 ; (from Gmelin), View in Reaxys stable against H2 at ambient temperature, stable against S in the cold, formation of liquid with smell
Gladstone, J. H.; Journal fuer Praktische Chemie (Leipzig); vol. 49; (1850); p. 40 - 51, View in Reaxys; Gladstone, J. H.; Philosophical Magazine (1798-1977); (1849); p. 345 - 355, View in Reaxys; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin), View in Reaxys
Copyright © 2017 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.
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of S-bromide when heating with S; Quantum Chemical Calculations (1) Calculated Prop- Method (Quantum References erties Chemical Calculations) Total energy
Semi-empirical NDO calcns. (CNDO, INDO, MINDO, PCILO)
Dewar, Michael J. S.; Jie, Caoxian; Journal of Molecular Structure; vol. 187; (1989); p. 1 - 14 ; (from Gmelin), View in Reaxys
Copyright © 2017 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.
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