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1
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With chlorine in tetrachloromethane
react. of PCl3 with Cl2 in CCl4;;
Downs, J.; Johnson, R. E.
Journal of Chemical Physics, 1954 , vol. 22, p. 143 - 144 Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 183, page 421 - 424 Full Text Show Details
With chlorine in not given react. with Cl2;;
Skaerblom, K. I.
Tek. Tidskr., 1927 , vol. 57, p. 87 - 90 C. II, 1927 , p. 2033 Full Text Show Details
Gmelin Handbook: P: MVol.C, 183, page 421 - 424 Full Text Show Details
With chlorine
9 h; Reflux; Hide Experimental Procedure
DAIKIN INDUSTRIES LIMITED; MATSUDA, YUKI; SHIMADA, TOMO; HIRAI, MAI
Patent: JP2017/31090 A, 2017 ; Location in patent: Paragraph 0051 ; Title/Abstract Full Text Show Details
1:
97.1 g (0.706 mol) of phosphorus trichloride was added to a 200 ml glass container equipped with a reflux condenser, a thermometer and a stirrer.Thereafter, while stirring, the glass container was heated to 90 ° C. in an oil bath,Under reflux, 30.0 g (0.423 mol) of chlorine gas was fed over 9 hours. The produced phosphorus pentachloride is dissolved in phosphorus trichloride,There was no adhesion of solid phosphorus pentachloride to the wall surface of the glass container. A
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2
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Rx-ID: 23858052 Find similar reactions
Atwal, Karnail S.; Vaccaro, Wayne; Lloyd, John; Finlay, Heather; Yan, Lin; Bhandaru, Rao S.
Patent: US2003/22890 A1, 2003 ; Title/Abstract Full Text Show Details
7-(3,4-Dichlorophenyl)-4,7-dihydro-5-methyl-6-(4-methyl-4H-imidazo[3,4-d][1,2,5]thiadiazol-5-yl)pyrazolo[1,5-a]pyrimidine
7-(3,4-Dichlorophenyl)-4,7-dihydro-5-methyl-6-(4-methyl-4H-imidazo[3,4-d][1,2,5]thiadiazol-5-yl)pyrazolo[1,5-a]pyrimidine Preparation of compound 5: To a suspension of the acid (120 mg, 0.37 mmol) in 5 mL of anhydrou dichloromethane were added trichloroacetonitrile (55.9 mL, 0.56 mmol) and triphenylphosphine (146.2 mg, 0.56 mmol). The mixture became clear and was allowed to stir at room temperature for 1 hour. The reaction mixture was transferred into a solution of 3,4-diamino-1,2,5-thiadiazole (51.7 mg, 0.45 mmol, prepared according to J. Heterocycl. Chem. 1976, 13, 13) and triethylamine (103.6 μL, 0.74 mmol) in 5 mL of dichloromethane. The reaction was monitored using TLC or LC/MS. Upon completion of the coupling, the reaction mixture was loaded directly onto silica gel and eluted with 50percent ethyl acetate/hexanes to yield the desired amide as a yellow solid (56.4 mg, 30percent). Preparation of compound 6: A suspension of the resulting amide (80 mg, 0.19 mmol) and phosphorus pentachloride (79 mg, 0.38 mmol) in chloroform (10 mL) was stirred at room temperature under anhydrous argon for one hour and then heated to reflux for 2 hours. The mixture was allowed to cool down to room temperature and solvent was removed under reduced pressure. The residue was redissolved in ethyl acetate and briefly washed with saturated aqueous sodium bicarbonate solution.
3
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Rx-ID: 24294371 Find similar reactions
Hoechst Aktiengesellschaft
Patent: US3980714 A1, 1976 ; Title/Abstract Full Text Show Details
2:EXAMPLE 2
EXAMPLE 2 By chlorination of the corresponding fluoral-semiacetal with phosphorus pentachloride in a manner analogous to that described in Example 1, (2,2,2-trifluoro-1-chloroethyl)-ethyl ether CF3 CHCl--O--C2 H5 was obtained. Yield: 71percent of the theory. Analysis: Calc.: C, 29.6 percent; H, 3.7 percent; F, 35.1 percent; Cl, 21.8 percent. Found: C, 29.6 percent; H, 3.9 percent; F, 35.4 percent; Cl, 21.5 percent.
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Villalobos; Anabella; Yohannes; Daniel; Nowakowski; Jolanta; Liston; Dane R.
Patent: US6093733 A1, 2000 ; Title/Abstract Full Text Show Details
7.C:N-[Cyclohexylimino-(2-methyl-piperidin-1-yl)-methyl]-N'-(4-fluoro-phenyl)-2,6-dimethyl-benzamidine Step C N-[Cyclohexylimino-(2-methyl-piperidin-1-yl)-methyl]-N'-(4-fluoro-phenyl)-2,6-dimethyl-benzamidine A neat mixture of the product from Step 8 (0.20 g, 0.544 mmol) and phosphorous pentachloride (0.113 g, 0.544 mmol) was heated to 125° C. and the melt obtained was stirred for 1 hour. Toluene was added and the mixture was concentrated (twice).
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Bayer Aktiengesellschaft
Patent: US5095103 A1, 1992 ; Title/Abstract Full Text Show Details
1:EXAMPLE 1
52 g of a compound of the formula STR29 which can be further purified if necessary, by recrystallization from nitrobenzene with the addition of PCl5, are obtained. IR data: 1535, 1292, 1240, 1183, 893 cm-1 UV VIS data: λ=452, 480 nm (19 300) 13 C-NMR data (solid): δ=117.6, 130.11, 132.3, 145.6, 155.3 ppm.
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Allied Corporation
Patent: US4629491 A1, 1986 ; Title/Abstract Full Text Show Details
I:Preparation of N-(Diaminophosphinyl)-p-toluene-sulfonamide
EXAMPLE I Preparation of N-(Diaminophosphinyl)-p-toluene-sulfonamide A mixture of 51.4 g (0.300 mol) of p-toluenes ulfonamide, 62.5 g (0.300 mol) of phosphorus pentachloride, and 500 mL of carbon tetrachloride was prepared under a nitrogen atmosphere in a dry 1000 mL, round bottom flask fitted with a mechanical stirrer and a condenser attached to a sodium hydroxide trap. The stirred mixture was gradually heated to 75° C. During this process hydrogen chloride steadily began to evolve. The mixture was heated for 60 h at 75° C. during which time gas evolution ceased and the solution became homogeneous. Upon cooling, however, the reaction mixture gelled into a slightly pink solid. The flask was rewarmed to 55° C. to redissolve the solid, the heating bath was removed, and 11.8 mL (14.4 g, 0.315 mol) of formic acid was added dropwise over a 20 min period. Gases were vigorously evolved during this process and the color of the solution became yellow. The solution was stirred for another 2 h without external heating and then for 1 h at 55° C. The mixture was cooled to ambient temperature causing two layers to form in the flask. Analysis of each layer, however, showed them to be substantially the desired product, and, upon standing under nitrogen, each layer crystallized into a solid, mp 114°-118° C. and 118°-121° C. (upper and lower layers, respectively). The solids, 64 g from the upper layer and 28 g from the lower layer, were combined and extracted with 1200 mL of hot carbon tetrachloride. The mixture was filtered free from 5-10 g of residue, and 46.7 g (54percent) pure p-toluenesulfonylphosphoramidic dichloride, mp 115.5°-117.5° C. (lit. mp 115°-118° C.) was obtained by allowing the filtrate to crystallize. 1 H NMR (CDCl ): δ 8.82 (S, 1H, NH), 7.83 (d, J=8 Hz, 2H, ArH), 7.28 (d, J=8 Hz, 2H, ArH), and 2.43 ppm (s, 3H, CH ). 3 3
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Idemitsu Kosan Company Limited
Patent: US4680054 A1, 1987 ; Title/Abstract Full Text Show Details
P.13:Preparation of Benzylamine Derivative PREPARATION EXAMPLE 13 Preparation of Benzylamine Derivative A mixture of 49 grams (295 millimoles) of 3-methoxy-4-methylbenzoic acid, 53.9 grams (315 millimoles) of p-toluene-sulfonamide, and 129 grams (619 millimoles) of phosphorus pentachloride was prepared and then heated at 200° C. while stirring. Phosphorus oxychloride was distilled at 106°-112° C.; and the mixture was further heated at 200° C. while stirring until no distillated came out.
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Stauffer Chemical Company
Patent: US4727194 A1, 1988 ; Title/Abstract Full Text Show Details
EXPERIMENT
EXPERIMENT A solution of chlorobenzene (150 ml) and phosphorus trichloride (73 g, 0.532 mole) was placed in a 500 ml four-necked flask under a nitrogen atmosphere. The flask was fitted with an overhead stirrer, reflux condenser, thermometer, and gas inlet tube. Chlorine gas (38 g, 0.535 mole) was blown onto the surface of the stirred solution at a rate of 1 g/min. The reaction temperature increased to 70° C. as the chlorine reacted with the phosphorus trichloride to prepare phosphorus pentachloride. The gas inlet tube was replaced with an addition funnel after the chlorine addition was completed.
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Nazzaro-Porro; Marcella
Patent: US4292326 A1, 1981 ; Title/Abstract Full Text Show Details
1.a:(a) (a) Preparation of the Alpha-Monobromo Derivative 1 mole of dicarboxylic acid (for instance, azelaic acid) is introduced into a 3 liter flask placed on a magnetic agitator provided with a heating plate, and 500 g of phosphorous pentachloride are added. After the reaction has taken place (complete melting), 60 ml of anhydrous bromine are added in small portions in the course of about 6 hours, with continuous agitation. The reaction temperature is maintained at 60° to 70° C. After the reaction is complete, it is cooled and thereupon about 500 ml of distilled water are cautiously added; it is then warmed on the magnetic agitator for about 30 minutes and cooled. The low organic phase, formed of an oily liquid of dark yellow color, constitutes the crude monobromo derivative which is distilled under vacuum.
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Sandoz Pharm. Corp.
Patent: US4808607 A1, 1989 ; Title/Abstract Full Text Show Details
3.5.4:Step 4
Step 4 in 50 ml. of chloroform is added over a 30 minute period to 8.12 g. (39 mmoles) of phosphorus pentachloride in 100 ml. of chloroform stirred at -30° C., and the reaction mixture is allowed to warm to 20°-25° C., stirred at 20°-25° C. for 16 hours and cooled to 0° C., the reaction mixture being stirred under nitrogen throughout. 10 ml. of water is added, the mixture is stirred for 5 minutes, and 200 ml. of 2N. sodium hydroxide solution is added. The organic phase is separated, and the aqueous phase is extracted with chloroform. The chloroform extract and the organic phase are combined, washed twice with saturated sodium chloride solution, dried over anhydrous magnesium sulfate, filtered and evaporated at reduced pressure to a tan solid. The tan solid is recrystallized from benzene to obtain the product as a white solid (2.33 g.). A second crop is obtained from the mother liquor (200 mg.). An analytical sample is recrystallized from aqueous ethanol. M.p. 161°-162° C.
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PFIZER INC.
Patent: EP805153 A1, 1997 ; Title/Abstract Full Text Show Details
7.C:N-[Cyclohexylimino-(2-methyl-piperidin-1-yl)-methy)l-N'-(4-fluoro-phenyl)-2,6-dimethyl-benzamidine Step C N-[Cyclohexylimino-(2-methyl-piperidin-1-yl)-methy)l-N'-(4-fluoro-phenyl)-2,6-dimethyl-benzamidine A neat mixture of the product from Step B (0.20 g, 0.544 mmol) and phosphorous pentachloride (0.113 g, 0.544 mmol) was heated to 125°C and the melt obtained was stirred for 1 hour. Toluene was added and the mixture was concentrated (twice).
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Nelson Research and Development Co.
Patent: US4849436 A1, 1989 ; Title/Abstract Full Text Show Details
12.b:(b) (b) Preparation of (3-Phthalimido)propionyl chloride 87.6 g (0.4 mol) of N-phthalylalanine was added to a stirring suspension of 83.2 g (0.4 mol) of phosphorus pentachloride in toluene at 60° C. under nitrogen. After the mixture was stirred for 2 hours, the solvent and excess phosphorus pentachloride were removed to give a white solid Recrystallization in benzene/petroleum ether yielded 76.0 g of a hygroscopic white powder: mp 94°-99° C.; NMR (CDCl3) 7.7 (4H,m), 3.9 (2H,t), 3.2 (2H,t).
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Pfizer Inc.
Patent: US6251904 B1, 2001 ; Title/Abstract Full Text Show Details
12:3-Bromo-2-chloropyridine-5-sulphonyl Chloride
The residue was dried under vacuum at 70° C. for 72 hours, then a mixture of the resulting solid, phosphorus pentachloride (30 g, 144 mmol) and phosphorus oxychloride (1 ml) was heated at 125° C. for 3 hours and then allowed to cool. A
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4
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Baranov; Khvorykh; Troyanov
Zeitschrift fur Anorganische und Allgemeine Chemie, 1999 , vol. 625, # 8 p. 1240 - 1242 Title/Abstract Full Text View citing articles Show Details
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5
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Rx-ID: 26381377 Find similar reactions
in 1,4-dioxane
Kinetics; byproducts: HCl; addn. of suspn. of (Cl3PNPCl3)PCl6 in dioxane to HN(POCl2)2 in dioxane (molar ratio 1:1) dropwise during 1 h at ambient temp., standing (several days); various product ratio for various conditions; (31)PNMR spectroscopic monitoring;
Heubel, Joseph; Hammoutou, Yahia; Jaeger, Roger De
Phosphorus, Sulfur, and Silicon and the Related Elements, 1991 , vol. 63, p. 19 - 32 Full Text Show Details
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6
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A: 89%
7
in not given exclusion of moisture, stirred for 12 h at room temp.; filtered, dissolved in CH2Cl2, pptd. with CCl4, filtered, washed with CCl4, dried in vac.; elem. anal.;
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Mueller, Ulrich; Conradi, Elke; Patt-Siebel, Ute; Kersting, Meinolf; Schmidt, Inge; et al.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1988 , vol. 560, p. 93 - 104 Full Text Show Details
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With phosphorus trichoride in chloroform
Rx-ID: 26453063 Find similar reactions
Kren, Robert M.; Sisler, Harry H.
Inorganica Chimica Acta, 1986 , vol. 111, p. 31 - 34 Full Text View citing articles Show Details
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A: 40%
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Rx-ID: 25283265 Find similar reactions
Eli Lilly and Company
Patent: US4145538 A1, 1979 ; Title/Abstract Full Text Show Details
5:Preparation of 7-Amino-3-Carbamoyloxymethyl-3-Cephem-4-Carboxylic Acid by Phosphorus Pentachloride Cleavage of 7-(5-Phthalimido-5-Carboxyvaleramido)-3-Carbamoyloxymethyl-3-Cephem-4-Carboxylic Acid
EXAMPLE 5 Preparation of 7-Amino-3-Carbamoyloxymethyl-3-Cephem-4-Carboxylic Acid by Phosphorus Pentachloride Cleavage of 7-(5-Phthalimido-5-Carboxyvaleramido)-3-Carbamoyloxymethyl-3-Cephem-4-Carboxylic Acid To a stirred slurry of 3.0 grams of 7-(5-phthalimido-5-carboxyvaleramido)-3-carbamoyloxymethyl-3-cephem-4-carboxylic acid in 50 milliliters of absolute methylene chloride were added 2.9 milliliters of absolute pyridine and 4.5 milliliters of trimethylchlorosilane, to protect both of the carboxyl groups. The resulting reaction mixture was stirred for two and one-half hours, then cooled to -12° C. in a carbon tetrachloride: dry ice bath. To this were added 5.6 milliliters of absolute pyridine in one lot, and then 36.2 milliliters of a 10 percent solution of phosphorus pentachloride in absolute methylene chloride, dropwise, maintaining the temperature at -12° C. The reaction mixture was stirred for two and one-half hours, 40 milliliters of absolute methanol was added dropwise at -12° C. and stirred for thirty minutes, and for another thirty minutes at room temperature. Then 10 milliliters of 50 percent formic acid was added dropwise, the pH adjusted to 2 by addition of triethylamine, and the reaction mixture stirred for forty-five minutes. The solution became cloudy. Then the pH was adjusted to 3.4, and the reaction mixture was refrigerated overnight and filtered, yielding 600 milligrams of 7-amino-3-carbamoyloxymethyl-3-cephem-4-carboxylic acid, 40 percent yield. This was taken up in 5 milliliters of water, stirred and filtered. The solid was washed with about 2 milliliters of water and 10 milliliters of acetone, yielding 450 milligrams of purified 7-amino-3-carbamoyloxymethyl-3-cephem-4-carboxylic acid, 30 percent yield. Calc., for C9 H11 N3 O5 S: C, 39.56; H, 4.06; N, 15.38; S, 11.73. Found: C, 39.70; H, 4.12; N, 15.34; S, 11.98. A
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Binder, H.; Fluck, E.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1971 , vol. 381, p. 123 - 128 Full Text Show Details
Gmelin Handbook: B: B-Verb.4, 4.4.2.3.1, page 120 - 124 Full Text Show Details
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byproducts: PCl3; Irradiation (UV/VIS); UV; 6h;
Gmelin Handbook: F: PerFHalOrg.3, 1.9, page 70 - 123 Full Text Show Details
byproducts: PCl3; Irradiation (UV/VIS); UV; 6h;
Griffiths, J. E.
Journal of Chemical Physics, 1964 , vol. 41, p. 3510 - 3516 Full Text View citing articles Show Details
11
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Rx-ID: 26150705 Find similar reactions
in not given react. of an excess of PCl3 with MoF6 forming PF3, MoCl5, Cl2; further react. of an excess of PCl3 with Cl2 forming PCl5;;
O'Donnell, T. A.; Stewart, D. F.
Journal of Inorganic and Nuclear Chemistry, 1962 , vol. 24, p. 309 - 314 Full Text View citing articles Show Details
in not given react. of an excess of PCl3 with
Gmelin Handbook: P: MVol.C, 186, page 429 - 431 Full Text Show Details
MoF6 forming PF3, MoCl5, Cl2; further react. of an excess of PCl3 with Cl2 forming PCl5;;
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12
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in neat (no solvent) decompn. on heating at 140 °C in vac.;;
Glemser, O.; Wyszomirski, E.
Naturwissenschaften, 1961 , vol. 48, p. 25 - 25 Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 233, page 533 - 535 Full Text Show Details
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13
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Rx-ID: 26435511 Find similar reactions
in not given fast react. of PF3 with Cl2 forming PF3Cl2; slow react. of PF3Cl2 forming (PCl4)(PF6) and slow react. forming PCl5 and PF5;; solid (PCl4) (PF6) contains small amounts of PCl5 or PFCl4;;
Muetterties, E. L.; Bither, T. A.; Farlow, M. W.; Coffman, D. D.
Journal of Inorganic and Nuclear Chemistry, 1960 , vol. 16, p. 52 - 59 Full Text View citing articles Show Details
in not given fast react. of PF3 with Cl2 forming PF3Cl2; slow react. of PF3Cl2 forming (PCl4)(PF6) and slow react. forming PCl5 and PF5;; solid (PCl4) (PF6) contains small amounts of PCl5 or PFCl4;;
Gmelin Handbook: P: MVol.C, 211, page 484 - 487 Full Text Show Details
14
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Rx-ID: 26453930 Find similar reactions
-78°C;
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Emeleus,H.J.; Pugh,H.
Journal of the Chemical Society, 1960 , p. 1108 - 1112 Full Text View citing articles Show Details
Gmelin Handbook: F: PerFHalOrg.2, 1.1.6.10, page 27 - 31 Full Text Show Details
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in neat (no solvent) dissociation above 110 °C;;
Kennedy, T.; Payne, D. S.
Journal of the Chemical Society, 1960 , p. 4126 - 4130 Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 211, page 484 - 487 Full Text Show Details
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16
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Rx-ID: 26089281 Find similar reactions
in tetrachloromethane
Perotti, A.
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addn. of a soln. of ClO2 in CCl4 to PCl3 dissolved in CCl4 below 20 °C;;
Gazzetta Chimica Italiana, 1959 , vol. 89, p. 2046 - 2052 Full Text Show Details
in tetrachloromethane
addn. of a soln. of ClO2 in CCl4 to PCl3 dissolved in CCl4 below 20 °C;;
Gmelin Handbook: P: MVol.C, 184, page 424 - 427 Full Text Show Details
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17
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Rx-ID: 26391123 Find similar reactions
in tetrachloromethane
dropping PSCl3 to a soln. of ClO2 in CCl4;;
Perotti, A.
Gazzetta Chimica Italiana, 1959 , vol. 89, p. 2046 - 2052 Full Text Show Details
in tetrachloromethane
dropping PSCl3 to a soln. of ClO2 in CCl4;;
Gmelin Handbook: P: MVol.C, 260, page 594 - 596 Full Text Show Details
18
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Rx-ID: 26448773 Find similar reactions
With aluminium trichloride in neat (no solvent) heating PCl3 with S and AlCl3 (catalyst) under exclusion of H2O; react. with the intermediate AlCl3*PCl3; addn. of AlCl3 in small portions to the boiling mixt. of PCl3 and S, react. on boiling completed after 10 min;; extraction of the cold crude product with H2O and separation with a separatory funnel; drying over CaCl2 and distn. at 125-126 °C at ambient pressure;;
Knotz, F.
Oesterr. Chem. - Ztg., 1949 , vol. 50, p. 128 - 129 Full Text Show Details
Gmelin Handbook: P: MVol.C, 258, page 590 - 592 Full Text Show Details
Knotz, F.
Patent: US2915361 , 1959 ; C. A., 1960 , p. 13579 Full Text Show Details
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in tetrachloromethane
decomposition with deep red color in CCl4 soln., formed PBr5 partially decomposes into Br2 and PBr3;;
Kolditz, L.; Feltz, A.
Z. Anorg. Chem., 1958 , vol. 293, p. 286 - 293 Full Text Show Details
Gmelin Handbook: P: MVol.C, 224, page 513 - 516 Full Text Show Details
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Rx-ID: 26456919 Find similar reactions
Kolditz, L.; Feltz, A.
Z. Anorg. Chem., 1958 , vol. 293, p. 286 - 293 Full Text Show Details
Gmelin Handbook: P: MVol.C, 224, page 513 - 516 Full Text Show Details
21
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Rx-ID: 26540291 Find similar reactions
Groeneveld, W. L.; Visser, J. H.; Seuter, A. M. J. H.
Journal of Inorganic and Nuclear Chemistry, 1958 , vol. 8, p. 245 - 248 Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 233, page 533 - 535 Full Text Show Details
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Rx-ID: 26161293 Find similar reactions
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With carbon in neat (no solvent) passing a mixture of POCl3 vapor and an excess of Cl2 through a porous C mass above 162°C;;
United Kingdom Atomic Energy Authority
Patent: GB786760 , 1957 ; C., 1958 , p. 12800 Full Text Show Details
United Kingdom Atomic Energy Authority
Patent: GB788241 , 1957 ; C. A., 1958 , p. 11374 Full Text Show Details
With C in neat (no solvent) passing a mixture of POCl3 vapor and an excess of Cl2 through a porous C mass above 162°C;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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23
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in neat (no solvent) decompn. above 60 °C; further react. with PF5 forming (PCl4) (PF6);;
Kolditz, L.
Z. Anorg. Chem., 1956 , vol. 286, p. 307 - 316 Full Text Show Details Kolditz, L. Z. Anorg. Chem., 1957 , vol. 289, p. 128 - 140 Full Text Show Details Kolditz, L. Z. Anorg. Chem., 1957 , vol. 293, p. 147 - 154 Full Text Show Details Gmelin Handbook: P: MVol.C, 211, page 484 - 487 Full Text Show Details
in neat (no solvent) react. by liquefaction and solidification;;
Kolditz, L.
Z. Anorg. Chem., 1956 , vol. 286, p. 307 - 316 Full Text Show Details Gmelin Handbook: P: MVol.C, 210, page 482 - 484 Full Text Show Details
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Rx-ID: 26150736 Find similar reactions
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in not given prepn. in laboratory; react. of Cl2 with PCl3; apparatus described;;
Lisowski, W.
Roczniki Chemii, 1956 , vol. 30, p. 973 - 976 C. A., 1957 , p. 7061 Full Text Show Details
in trichlorophosphate
passing Cl2 in a soln. of PCl3 in POCl3;;
E. I. du Pont de Nemours & Co. Patent: US1906440 , 1933 ; C. II, 1933 , p. 426 Full Text Show Details
in tetrachloromethane
passing Cl2 in soln. of PCl3 in CCl4 (ratio 1:1) in a vessel cooled with water;; filtration;;
Wazer, J. R. van
Encyclopedia of Chemical Technology, herausgegeben von Kirk, R. E., Othmer, D. F., The Interscience Encyclopedia, Inc., New York, Bd. 10, 1953, S. 479 Full Text Show Details
in neat (no solvent) continous process in a column; passing PCl3 and Cl2 through the column in counterflow; use of Pb tubes and leaded steel;;
Wazer, J. R. van
Encyclopedia of Chemical Technology, herausgegeben von Kirk, R. E., Othmer, D. F., The Interscience Encyclopedia, Inc., New York, Bd. 10, 1953, S. 479 Full Text Show Details
in neat (no solvent) dropping PCl3 in an atmosphere of Cl2 in iron vessels;; product contains 0.07 percent Fe;;
Manoev, D.; Mazel', V.
C. II, SSSR nauchno-tekhn. Otdel VSNKH Nr. 214 (1927) 39/45 1930 , p. 1511 Full Text Show Details
in neat (no solvent) prepn. in laboratory; dropping PCl3 and passing HCl in the reaction vessel; apparatus described;;
Maxson, R. N.; Booth, H. S.; Hermann, C. V.
Booth, H. S., Inorganic syntheses, Bd. 1, Nw York-London 1939, S. 99/100 Full Text Show Details
in neat (no solvent) react. of liquid Cl2 with PCl3 without sublimation of PCl5;;
Hooker Electrochemical Co.
Patent: US1914750 , 1933 ; C. II, 1933 , p. 1912 Full Text Show Details
in not given react. of Cl2 with PCl3 under exclusion of air;; sublimation in a Cl2 stream;;
Fischer, W.; Juebermann, O.
Z. anorg. allg. Chem., 1938 , vol. 235, p. 337 - 351 Full Text Show Details
in not given react. of PCl3 with Cl2 in sealed vessel;;
anonymous
Ind. Chem., 1949 , vol. 25, p. 517 - 520 Full Text Show Details
25
in not given react. of PCl3 with excess Cl2;;
Sorel, J.
Chim. et Ind., 1948 , vol. 60, p. 541 - 549 Full Text Show Details
in not given react. of PCl3 with Cl2 in sealed vessel;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
in neat (no solvent) continous process in a column; passing PCl3 and Cl2 through the column in counterflow; use of Pb tubes and leaded steel;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
in neat (no solvent) dropping PCl3 in an atmosphere of Cl2 in iron vessels;; product contains 0.07 percent Fe;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
in neat (no solvent) prepn. in laboratory; dropping PCl3 and passing HCl in the reaction vessel; apparatus described;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
in neat (no solvent) react. of liquid Cl2 with PCl3 without sublimation of PCl5;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
in not given prepn. in laboratory; react. of Cl2 with PCl3; apparatus described;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
in not given react. of Cl2 with PCl3 under exclusion of air;; sublimation in a Cl2 stream;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
in not given react. of PCl3 with excess Cl2;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
in trichlorophosphate
passing Cl2 in a soln. of PCl3 in POCl3;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
in tetrachloromethane
passing Cl2 in soln. of PCl3 in CCl4 (ratio 1:1) in a vessel cooled with water;; filtration;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
Synthesize Find similar in neat (no solvent) sublimation at 80°C;; compound has nearly composition of PCl5, but x-ray diagram shows some differences to that of tetragonal PCl5;;
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Rx-ID: 26153574 Find similar reactions
Popov, I. A.; Geske, D. H.; Baenziger, N. C.
Journal of the American Chemical Society, 1956 , vol. 78, p. 1793 - 1796 Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 223, page 511 - 513 Full Text Show Details
A
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C
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26
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Rx-ID: 26182465 Find similar reactions
B: <1
in tetrachloromethane
pouring red P with dry CCl4, cooling at 5°C and passing in Cl2; keeping temp. below 70 °C; stirring; standing for 2-3 h and repeating the process;; decanting pptd. PCl5; passing Cl2 through the soln. for 20 min; filtration in vacuum; product contains a small amount of PCl3, traces of POCl3 and 25-40 percent CCl4; distn. in vacuum;;
Bulashevich, E. A.
Zh. prikl. Khim., 1955 , vol. 28, p. 431 - 433 C. A., 1955 , p. 13811 Full Text Show Details
B: <1
in tetrachloromethane
pouring red P with dry CCl4, cooling at 5°C and passing in Cl2; keeping temp. below 70 °C; stirring; standing for 2-3 h and repeating the process;; decanting pptd. PCl5; passing Cl2 through the soln. for 20 min; filtration in vacuum; product contains a small amount of PCl3, traces of POCl3 and 25-40 percent CCl4; distn. in vacuum;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
A
B
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27
Synthesize Find similar Rx-ID: 26144058
Find similar reactions
heating; decompn.;
Groeneveld, W. L.
Diss. Leiden 1953, p. 32, 47 Full Text Show Details
Groeneveld, W. L.
Rec. Trav. Chim., 1952 , vol. 71, p. 1152 - 1156 Full Text Show Details
heating; decompn.;
Gmelin Handbook: Hg: MVol.B4, 3, page 1357 - 1369 Full Text Show Details
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C
D
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28
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Rx-ID: 26144143 Find similar reactions
in neat (no solvent) distilling NO2Cl to an excess of PCl3 at -75 °C; exothermic react.;;
Batey, H. H.; Sisler, H. H.
Journal of the American Chemical Society, 1952 , vol. 74, p. 3408 - 3410 Full Text View citing articles Show Details
in neat (no solvent) reaction of NO2Cl and excess of PCl3 at -75°C;;
Batey, H. H.; Sisler,, H. H.
J. Am. Chem. soc., 1952 , vol. 74, p. 3408 - 3410 Full Text View citing articles Show Details
Gmelin Handbook: Cl: SVol.B2, 99, page 529 - 531 Full Text Show Details
in neat (no solvent) distilling NO2Cl to an excess of PCl3 at -75 °C; exothermic react.;;
Gmelin Handbook: P: MVol.C, 184, page 424 - 427 Full Text Show Details
29
Synthesize Find similar in neat (no solvent) decomposition on heating;;
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Rx-ID: 26171602 Find similar reactions
Groeneveld, W. L.
REcueil Trav. chim. Pays-Bas, 1952 , vol. 71, p. 1152 - 1156 Full Text Show Details
Groeneveld, W. L.
Diss. Leiden 1953, S. 55 Full Text Show Details
in neat (no solvent) decomposition on heating;;
Gmelin Handbook: Bi: SVol., 167, page 681 - 683 Full Text Show Details
A
B
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30
Synthesize Find similar Rx-ID: 26588683 Find similar reactions
in tetrachloromethane
dissociation in CCl4;; detected by spectroscopy;;
Popov; Schmorr
Journal of the American Chemical Society, 1952 , vol. 74, p. 4672 Full Text View citing articles Show Details
in tetrachloromethane
dissociation in CCl4;; detected by spectroscopy;;
Gmelin Handbook: P: MVol.C, 232, page 531 - 533 Full Text Show Details
31
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Rx-ID: 26090333 Find similar reactions
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in neat (no solvent) react. of P4 with molten ICl under explosion;;
Gutmann, V.
Z. anorg. allg. Chem., 1951 , vol. 264, p. 169 - 173 Full Text Show Details
in neat (no solvent) react. of P4 with molten ICl under explosion;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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32
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Rx-ID: 26090355 Find similar reactions
>99
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byproducts: J2; with explosion;
Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details
Gutmann, V.
Z. Anorg. Chem., 1951 , vol. 264, p. 169 - 173 Full Text Show Details
in neat (no solvent) react. of red P with molten ICl under explosion;;
Gutmann, V.
Z. anorg. allg. Chem., 1951 , vol. 264, p. 169 - 173 Full Text Show Details
in neat (no solvent) react. of red P with molten ICl under explosion;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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33
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Rx-ID: 26382320 Find similar reactions
byproducts: I2;
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Synthesize Find similar
Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details
Gutmann, V.
Z. Anorg. Chem., 1951 , vol. 264, p. 169 - 173 Full Text Show Details
A
34
B
C
D
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Rx-ID: 26364443 Find similar reactions
in neat (no solvent) formation of a mixt. of phosphorus nitride dichlorides with a large amount of (NPCl2)3 and a small amount of PCl5 by react. of P3N5 with Cl2 at 700 °C;;
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A
B
C
D
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Wetroff, G.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1939 , vol. 208, p. 580 - 583 Full Text Show Details
Gmelin Handbook: P: MVol.C, 240, page 549 - 551 Full Text Show Details
35
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Rx-ID: 26441544 Find similar reactions
in neat (no solvent) formation of a mixt. of phosphorus nitride dichlorides with a large amount of (NPCl2)3 and a small amount of PCl5 by react. of P4N6 with Cl2 at 700 °C;;
Wetroff, G.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1939 , vol. 208, p. 580 - 583 Full Text Show Details
Gmelin Handbook: P: MVol.C, 240, page 549 - 551 Full Text Show Details
A
36
B
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in neat (no solvent) decompn. at 25 °C after 30 h;;
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Booth, H. S.; Bozarth, A. R.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2927 - 2934 Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 211, page 484 - 487 Full Text Show Details
A
B
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37
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Rx-ID: 26402938 Find similar reactions
in neat (no solvent) excess of SO2Cl2; sealed tube (180°C);;
Danneel, H.; Schlottmann, F.
Z. Anorg. Chem., 1933 , vol. 212, p. 225 - 232 Full Text Show Details Koechlin, P.; Heumann, K. Ber., 1882 , vol. 15, p. 1736 - 1738 Full Text Show Details Gmelin Handbook: S: MVol.B3, 135, page 1815 - 1817 Full Text Show Details
38
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Rx-ID: 26112960 Find similar reactions
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With silicate; carbon in neat (no solvent) heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C;;
Miner, C. G.
Patent: US1730521 , 1929 ; C. II, 1929 , p. 3174 Full Text Show Details
With silicate; carbon; copper dichloride in neat (no solvent) heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C in presence of a catalyst (CuCl2);;
N. V. Electrochemische Industrie Patent: DE522270 , 1931 ; C. I, 1931 , p. 3496 Full Text Show Details
N. V. Electrochemische Industrie Patent: GB302927 , 1929 ; C. I, 1929 , p. 1851 Full Text Show Details
N. V. Electrochemische Industrie Patent: GB356238 , 1932 ; C. A., 1932 , p. 4422 Full Text Show Details
N. V. Electrochemische Industrie Patent: FR664850 , 1929 ; C. A., 1930 , p. 926 Full Text Show Details
With silicate; carbon; copper dichloride in neat (no solvent) heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C under pressure in vessels lined with insoluble halogenides;;
N. V. Electrochemische Industrie Patent: GB304694 , 1929 ; C. I, 1929 , p. 2564 Full Text Show Details
With silicate; carbon in neat (no solvent) heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C in presence of a dispersion agent (ZnCl2);;
N. V. Electrochemische Industrie Patent: DE522270 , 1931 ; C. I, 1931 , p. 3496 Full Text Show Details
N. V. Electrochemische Industrie Patent: GB302927 , 1929 ; C. I, 1929 , p. 1851 Full Text Show Details
N. V. Electrochemische Industrie Patent: GB356238 , 1932 ; C. A., 1932 , p. 4422 Full Text Show Details
N. V. Electrochemische Industrie Patent: FR664850 , 1929 ; C. A., 1930 , p. 926 Full Text Show Details
With silicate; carbon in not given heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C in presence of a solvent;;
N. V. Electrochemische Industrie Patent: DE522270 , 1931 ; C. I, 1931 , p. 3496 Full Text Show Details
N. V. Electrochemische Industrie Patent: GB302927 , 1929 ; C. I, 1929 , p. 1851 Full Text Show Details
N. V. Electrochemische Industrie Patent: GB356238 , 1932 ; C. A., 1932 , p. 4422 Full Text Show Details
N. V. Electrochemische Industrie Patent: FR664850 , 1929 ; C. A., 1930 , p. 926 Full Text Show Details
With coal; silicate; copper dichloride in neat (no solvent) heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C under pressure in vessels lined with insoluble halogenides;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
With coal; silicate; copper dichloride in neat (no solvent) heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C in presence of a catalyst (CuCl2);;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
With coal; silicate in neat (no solvent) heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C in presence of a dispersion agent (ZnCl2);;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
With coal; silicate in neat (no solvent) heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
With coal; silicate in not given heating a mixture of phosphate and silicate with coal in a stream of Cl2 at 1300 °C in presence of a solvent;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
39
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Rx-ID: 26146644 Find similar reactions
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With charcoal or active carbon in neat (no solvent) react. of POCl3 with COCl2 and charcoal or active carbon above 400 °C;;
I. G. Farbenindustrie A.-G. Patent: DE492061 , 1930 ; C. I, 1930 , p. 2292 Full Text Show Details
With charcoal or active carbon in neat (no solvent) react. of POCl3 with COCl2 and charcoal or active carbon above 400 °C;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
A
40
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B
Synthesize Find similar Rx-ID: 26161239 Find similar reactions
With carbon monoxide; chlorine
above 400°C;
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Synthesize Find similar
Gmelin Handbook: C: MVol.C2, 1.10.5, page 150 - 151 Full Text Show Details
I. G. Farbenindustrie Patent: DE492061 , 1930 ; Full Text Show Details
41
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Rx-ID: 26161273 Find similar reactions
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With charcoal or active carbon in neat (no solvent) react. of POCl3 with CO, Cl2 and charcoal or active carbon above 400 °C;;
I. G. Farbenindustrie A.-G. Patent: DE492061 , 1930 ; C. I, 1930 , p. 2292 Full Text Show Details
With charcoal or active carbon in neat (no solvent) react. of POCl3 with CO, Cl2 and charcoal or active carbon above 400 °C;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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42
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A
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C
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B
C
Rx-ID: 26099668 Find similar reactions
in neat (no solvent) heating phosphate with NaCl and SiO2 at 1100-1400 °C;;
Miner, C. G.
Patent: US1688503 , 1928 ; C. I, 1929 , p. 126 Full Text Show Details
in neat (no solvent) heating phosphate with NaCl and SiO2 at 1100-1400 °C;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
43
Synthesize Find similar in neat (no solvent) pptn. by react. of PCl3 with Cl2;;
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Rx-ID: 26182420 Find similar reactions
Biltz, W.; Jeep, K.
Z. anorg. allg. Chem., 1927 , vol. 162, p. 32 - 48 Full Text Show Details
Gmelin Handbook: P: MVol.C, 188, page 433 - 434 Full Text Show Details
44
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Rx-ID: 26391755 Find similar reactions
in neat (no solvent) react. with CrO2Cl2;;
Oddo, G.; Casalino, A.
Gazzetta Chimica Italiana, 1927 , vol. 57, p. 60 - 74 Full Text Show Details
in neat (no solvent) react. with CrO2Cl2;;
Gmelin Handbook: P: MVol.C, 261, page 596 - 599 Full Text Show Details
A
45
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With Pl3
byproducts: I2; heating (water bath), evolution of heat and I2 vapor;
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Karantassis
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1926 , vol. 182, p. 1392 - 1392 Full Text Show Details
Gmelin Handbook: Sb: MVol.B2, 9.6, page 443 - 447 Full Text Show Details
46
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Rx-ID: 26125236 Find similar reactions
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in neat (no solvent) react. of P distd. under N2 with Cl2 in a stream of N2;;
Holroyd, G. W. F.; Chadwick, H.; Mitchell, J. E. H.
Journal of the Chemical Society, 1925 , vol. 127, p. 2492 - 2493 Full Text View citing articles Show Details
in neat (no solvent) react. of P distd. under N2 with Cl2 in a stream of N2;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
47
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Rx-ID: 26150638
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Find similar With chlorine in neat (no solvent) react. of PCl3 with Cl2 under exclusion of H2O at ambient temp.; formation of an white oversaturated vapor;;
Find similar
Find similar reactions
Taylor, H. A.
Journal of Physical Chemistry, 1924 , vol. 28, p. 510 - 513 Full Text Show Details
Gmelin Handbook: P: MVol.C, 183, page 421 - 424 Full Text Show Details
48
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Rx-ID: 26170032 Find similar reactions
With chlorine in neat (no solvent) igniting in Cl2-atmosphere; formation of PCl5;;
Thomson, T.
Philosophical Magazine (1798-1977), 1816 , vol. 8, p. 87 - 93 Full Text Show Details
Gmelin Handbook: P: MVol.C, 20, page 39 - 40 Full Text Show Details
With chlorine in neat (no solvent) vigorous react. of PH3 with Cl2 even at -100°C;;
Stock, A.
Ber. Dtsch. Chem. Ges., 1920 , vol. 53, p. 837 - 842 Full Text Show Details
Gmelin Handbook: P: MVol.C, 20, page 39 - 40 Full Text Show Details
49
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With chlorine in further solvent(s) react. of a suspension of PH4Cl in liquid HCl with an excess of Cl2 at -100 °C;
Stock, A.
Ber. dtsch. chem. Ges., 1920 , vol. 53, p. 837 - 842 Full Text Show Details
With Cl2
Gmelin Handbook: P: MVol.C, 197, page 451 - 452 Full Text Show Details
Rx-ID: 26391202 Find similar reactions
A
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C
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E
50
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Rx-ID: 26105601 Find similar reactions
in neat (no solvent) excess of SOCl2; 180°C;;
North, H. B.; Thomson, J. C.
Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details
in neat (no solvent) excess of SOCl2; 180°C;;
Gmelin Handbook: S: MVol.B3, 124, page 1796 - 1798 Full Text Show Details
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A
B
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A
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51
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Rx-ID: 26125200 Find similar reactions
52
in not given react. of P with SO2Cl2 under evolution of SO2; intermediate PCl3;;
North, H. B.; Thomson, J. C.
Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details
in not given react. of P with SO2Cl2 under evolution of SO2; intermediate PCl3;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
C
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Rx-ID: 26144249 Find similar reactions
in neat (no solvent) slowly at 80-160°C;; POCl3 only supposed;;
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A
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C
D
E
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North, H. B.; Thomson, J. C.
Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details
Michaelis, A.
Jena. Z. Med. Naturwiss., 1870 , vol. 6, p. 239 - 241 Full Text Show Details
Gmelin Handbook: S: MVol.B3, 126, page 1800 - 1801 Full Text Show Details
53
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Rx-ID: 26144308 Find similar reactions
in neat (no solvent) excess of SOCl2; 180°C;;
North, H. B.; Thomson, J. C.
Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details
in neat (no solvent) excess of SOCl2; 180°C;;
Gmelin Handbook: S: MVol.B3, 124, page 1796 - 1798 Full Text Show Details
54
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Rx-ID: 26144309 Find similar reactions
at 180°C;
Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details
North, H. B.; Thomson, J. C.
Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details
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B
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A
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55
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Rx-ID: 26150688 Find similar reactions
in not given react. with SO2Cl2;;
North, H. B.; Thomson, J. C.
Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details
in not given react. with SO2Cl2;;
Gmelin Handbook: P: MVol.C, 184, page 424 - 427 Full Text Show Details
56
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Rx-ID: 26441676 Find similar reactions
at 180°C;
Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details
North, H. B.; Thomson, J. C.
Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details
57
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Find similar reactions
in tetrachloromethane
react. of equimolar amount of PCl3 and CrO2Cl2 in CCl4; pptn. of CrOCl*POCl3;;
Fry, H. S.; Donelly, J. L.
Journal of the American Chemical Society, 1916 , vol. 38, p. 1923 - 1928 Full Text View citing articles Show Details
in tetrachloromethane
react. of equimolar amount of PCl3 and CrO2Cl2 in CCl4; pptn. of CrOCl*POCl3;;
Gmelin Handbook: P: MVol.C, 186, page 429 - 431 Full Text Show Details
58
Synthesize Find similar With alkali chloride in neat (no solvent) heating Ca-phosphate and alkali chloride in a sealed vessel under exclusion of air; fast react. at 1100 °C;; sucking off the gaseous products;;
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Rx-ID: 26112931 Find similar reactions
Agricultural Research Corp.
Patent: US1147183 , 1915 ; C. A., 1915 , p. 2433 Full Text Show Details Agricultural Research Corp. Patent: DE276024 , 1914 ; C. II, 1914 , p. 364 Full Text Show Details Agricultural Research Corp. Patent: GB23023 , 1913 ; Full Text Show Details
Agricultural Research Corp.
Patent: FR463497 , 1913 ; C. A., 1914 , p. 2785 Full Text Show Details
With alkali chloride in neat (no solvent) heating Ca-phosphate and alkali chloride in a sealed vessel under exclusion of air; fast react. at 1100 °C;; sucking off the gaseous products;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
A
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59
Synthesize Find similar Rx-ID: 26125235
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Find similar reactions
in neat (no solvent) react. of a small excess of Cl2 with P in vac. under exclusion of H2O;; removal of formed PCl5 by fractional distn..;;
Baxter, G. P.; Moore, C. J.
Journal of the American Chemical Society, 1912 , vol. 34, p. 1644 - 1657 Full Text View citing articles Show Details
Baxter, G. P.; Moore, C. J.
Z. anorg. allg. Chem., 1913 , vol. 80, p. 185 - 200 Full Text Show Details
Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details
A
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C
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60
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Rx-ID: 5809426 Find similar reactions
T=-15 - -10°C;
Autenrieth; Geyer
Chemische Berichte, 1908 , vol. 41, p. 4254 Full Text View citing articles Show Details
A
B
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61
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Einw. von NH3;
Bamberger; Demuth
Chemische Berichte, 1902 , vol. 35, p. 1895 Full Text View citing articles Show Details
A
62
B
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Rx-ID: 26147000 Find similar reactions
in neat (no solvent) react. of Cl2 with dry P4O;;
Michaelis, A.; Pitsch, M.
Liebigs. Ann. Chem., 1900 , vol. 310, p. 45 - 74 Full Text Show Details
B: 0%
in tetrachloromethane
react. of an excess of Cl2 with P4O in CCl4; no formation of POCl3;;
Besson, A.
C. r. Acad. Sci. (Paris), 1897 , vol. 124, p. 763 - 765 Full Text Show Details
B: 0%
in neat (no solvent) react. of an excess of Cl2 with P4O under inflammation; no formation of POCl3;;
Besson, A.
C. r. Acad. Sci. (Paris), 1897 , vol. 124, p. 763 - 765 Full Text Show Details
in neat (no solvent) reaction of Cl2 with dry P4O;;
Gmelin Handbook: P: MVol.C, 200, page 458 - 460 Full Text Show Details
in neat (no solvent) reaction of Cl2 with dry P4O;;
Michaelis, A.; Pitsch, M.
Liebigs Annalen der Chemie, 1900 , vol. 310, p. 45 - 74 Full Text Show Details
in neat (no solvent) react. of Cl2 with dry P4O;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
B: 0%
in neat (no solvent) react. of an excess of Cl2 with P4O under inflammation; no formation of POCl3;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
B: 0%
in tetrachloromethane
react. of an excess of Cl2 with P4O in CCl4; no formation of POCl3;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
A
63
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Synthesize Find similar Rx-ID: 26446445 Find similar reactions
With Cl2 in neat (no solvent) reaction of Cl2 with dry P4O;;
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Michaelis, A.; Pitsch, M.
Liebigs Annalen der Chemie, 1900 , vol. 310, p. 45 - 74 Full Text Show Details
Gmelin Handbook: P: MVol.C, 31, page 60 - 62 Full Text Show Details
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64
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Rx-ID: 26150706 Find similar reactions
in neat (no solvent) heating PCl3 with P4O6 in a melting tube at 180 °C;;
Thorpe, T. E.; Tutton, A. E.
Journal of the Chemical Society, 1891 , vol. 59, p. 1019 - 1029 Full Text View citing articles Show Details
in neat (no solvent) heating PCl3 with P4O6 in a sealing tube at 180 °C;;
Thorpe, T. E.; Tutton, A. E.
Journal of the Chemical Society, 1891 , vol. 59, p. 1019 - 1029 Full Text View citing articles Show Details
in neat (no solvent) heating PCl3 with P4O6 in a melting tube at 180 °C;;
Gmelin Handbook: P: MVol.C, 184, page 424 - 427 Full Text Show Details
in neat (no solvent) heating PCl3 with P4O6 in a sealing tube at 180 °C;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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65
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Rx-ID: 26168118 Find similar reactions
in neat (no solvent) heating at 200-250 °C;;
Pulenc, C.
C. r. Acad. Sci. (Paris), 1891 , vol. 113, p. 75 - 78 Full Text Show Details
in neat (no solvent) heating at 200-250 °C;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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66
Synthesize Find similar Rx-ID: 26284121 Find similar reactions
under reduced pressure;
Geisenheimer, G.
Ann. Chim. Phys., 1891 , vol. 23, p. 246 - 282 Full Text Show Details
Gmelin Handbook: Ir: MVol., 5.12, page 83 - 86 Full Text Show Details
67
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Synthesize Find similar Geisenheimer, G.
Rx-ID: 26390651 Find similar reactions
to 150°C;
Ann. Chim. Phys., 1891 , vol. 23, p. 246 - 282 Full Text Show Details
Geisenheimer, G.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1890 , vol. 110, p. 1004 Full Text Show Details
Gmelin Handbook: Ir: MVol., 5.12, page 83 - 86 Full Text Show Details
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68
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Rx-ID: 26390654 Find similar reactions
Geisenheimer, G.
Ann. Chim. Phys., 1891 , vol. 23, p. 246 - 282 Full Text Show Details
Geisenheimer, G.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1890 , vol. 110, p. 1004 Full Text Show Details
Gmelin Handbook: Ir: MVol., 5.12, page 83 - 86 Full Text Show Details
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C
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69
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Rx-ID: 26441561 Find similar reactions
in neat (no solvent) reaction after heating over period of several hours to 180°C in closed tube there is formation of solid mixture;;
Thorpe, T. E.; Tutton, A. E.
Journal of the Chemical Society, 1891 , vol. 59, p. 1019 - 1029 Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 37, page 74 - 75 Full Text Show Details
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70
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in neat (no solvent) decompon. starting at 200 °C under inluence of an electric spark;;
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Poulenc, C.
Ann. Chim. Phys., 1891 , vol. 24, p. 548 - 570 Full Text Show Details
Poulenc, C.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 113, p. 75 - 78 Full Text Show Details
Gmelin Handbook: P: MVol.C, 211, page 484 - 487 Full Text Show Details
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71
Synthesize Find similar Rx-ID: 26506182 Find similar reactions
With chlorine in not given react. with Cl2;;
Moissan, H.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 113, p. 726 - 729 Full Text Show Details
With Cl2 in not given react. with Cl2;;
Gmelin Handbook: P: MVol.C, 265, page 608 - 611 Full Text Show Details
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72
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in neat (no solvent) decompn. of PF3Cl on heating up to 250°C or by electric sparks;;
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Poulenc, C.
C. r. Acad. Sci. (Paris), 1891 , vol. 113, p. 75 - 78 Full Text Show Details
Gmelin Handbook: P: MVol.C, 172, page 395 - 397 Full Text Show Details
73
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Rx-ID: 26112951 Find similar reactions
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in neat (no solvent) react. of CCl4 vapor with Ca3(PO4)2 at red heat;;
Quantin, H.
C. r. Acad. Sci. (Paris), 1888 , vol. 106, p. 1074 - 1076 Full Text Show Details
in neat (no solvent) react. of CCl4 vapor with Ca3(PO4)2 at red heat;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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74
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Rx-ID: 26061712 Find similar reactions
in neat (no solvent) passing CCl4 over FePO4 below red heat;;
Quantin, H.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1887 , vol. 104, p. 223 - 223 Full Text Show Details
Gmelin Handbook: Cl: MVol., 65, page 183 - 186 Full Text Show Details
in neat (no solvent) react. of CCl4 vapor with FePO4 below the decompn. temp. of CCl4;; removal of FeCl3 with a layer of KCl heated at 200 °C;;
Quantin, H.
C. r. Acad. (Paris), 1887 , vol. 104, p. 223 - 224 Full Text Show Details
in neat (no solvent) react. of CCl4 vapor with FePO4 below the decompn. temp. of CCl4;; removal of FeCl3 with a layer of KCl heated at 200 °C;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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75
Synthesize Find similar Rx-ID: 26440965 Find similar reactions
120°C; reaction started at ambient temp. (PCl5 gas developed);
Lindet, L.
Ann. Chim. Phys., 1887 , vol. 11, p. 177 - 220 Full Text Show Details
Lindet, L.
Bulletin de la Societe Chimique de France, 1884 , vol. 42, p. 70 - 74 Full Text Show Details
Lindet, L.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1884 , vol. 98, p. 1382 - 1384 Full Text Show Details
120°C; reaction started at ambient temp. (PCl5 gas developed);
Gmelin Handbook: Au: MVol.3, 8.4, page 693 - 702 Full Text Show Details
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76
Synthesize Find similar Rx-ID: 26161238 Find similar reactions
in neat (no solvent) decompn.;;
Divers, E.; Shimidzu, T.
Journal of the Chemical Society, 1886 , vol. 49, p. 533 - 590 Full Text View citing articles Show Details
Gmelin Handbook: S: MVol.B3, 122, page 1791 - 1793 Full Text Show Details
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C
77
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Rx-ID: 26062838 Find similar reactions
in not given react. with S2O5Cl2 in coldness;;
Michaelis, A.
Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 110 - 117 Full Text Show Details
Michaelis, A.
J. prakt. Chem. (2), 1871 , vol. 4, p. 449 - 457 Full Text Show Details
in neat (no solvent)
Michaelis, A.
Jena. Z. Med. Naturwiss., 1871 , vol. 7, p. 110 - 117 Full Text Show Details
Gmelin Handbook: S: MVol.B3, 141, page 1826 - 1828 Full Text Show Details
in not given react. with S2O5Cl2 in coldness;;
Gmelin Handbook: P: MVol.C, 184, page 424 - 427 Full Text Show Details
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78
Synthesize Find similar Rx-ID: 26588381 Find similar reactions
With potassium chloride
byproducts: Cl; react. with KCl on heating;;
Cronander, A. W.
Bulletin de la Societe Chimique de France, 1873 , vol. 19, p. 500 Full Text Show Details
Cronander, A. W.
Uppsala Univ. Arsskr., 1873 , p. 1 Full Text Show Details
With KCl byproducts: Cl; react. with KCl on heating;;
Gmelin Handbook: U: MVol., 42, page 130 - 132 Full Text Show Details
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79
Synthesize Find similar Rx-ID: 26729328 Find similar reactions
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in not given very instable;;
Cronander, A. W.
Uppsala Univ. Arsskr., 1873 , p. 1 - 36 Full Text Show Details
Cronander, A. W.
Bulletin de la Societe Chimique de France, 1873 , vol. 19, p. 499 - 501 Full Text Show Details
in not given very instable;;
Gmelin Handbook: As: MVol., 148, page 388 - 390 Full Text Show Details
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A
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80
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Rx-ID: 26150650 Find similar reactions
81
A: >99 B: >99
in neat (no solvent) 6h, 160°C;;
Michaelis, A.
Jena. Z. Med. Naturwiss., 1870 , vol. 6, p. 239 - 241 Full Text Show Details
A: >99 B: >99
in neat (no solvent) 6h, 160°C;;
Gmelin Handbook: S: MVol.B3, 115, page 1776 - 1778 Full Text Show Details
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Rx-ID: 26167068 Find similar reactions
byproducts: HCl;
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C
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Mahn, R.
Jena. Z. Med. Naturwiss., 1870 , vol. 5, p. 159 - 164 Full Text Show Details
Gmelin Handbook: Sb: MVol.B2, 9.6, page 443 - 447 Full Text Show Details
82
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Rx-ID: 26168204 Find similar reactions
in not given react. under evolution of HCl;;
Rose, H.
Ann. Physik (2), 1832 , vol. 24, p. 109 - 165 Full Text Show Details
Gmelin Handbook: P: MVol.C, 23, page 44 - 46 Full Text Show Details
in neat (no solvent) passing PH3 in SbCl5;;
Mahn, R.
Zeitschrift fuer Chemie (Stuttgart, Germany), 1869 , vol. 12, p. 729 - 731 Full Text Show Details
Mahn, r.
Jena. Z. Med. Naturwiss., 1870 , vol. 5, p. 158 - 166 Full Text Show Details
in neat (no solvent) passing PH3 in SbCl5;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
83
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in not given react. of PSCl3 with Cl2;;
Chevrier
C. r. Acad. Sci. (Paris), 1869 , vol. 68, p. 1174 - 1176 Full Text Show Details
in not given react. of PSCl3 with Cl2;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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84
Synthesize Find similar Rx-ID: 26475678 Find similar reactions
With chlorine in not given react. with Cl2;;
Baudrimont, E.
Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67 Full Text Show Details
Chevrier
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1869 , vol. 68, p. 1174 - 1176 Full Text Show Details
With Cl2 in not given react. with Cl2;;
Gmelin Handbook: P: MVol.C, 260, page 594 - 596 Full Text Show Details
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B
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85
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Rx-ID: 26150666 Find similar reactions
in not given react. with PCl5*ICl;;
Baudrimont, E.
Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67 Full Text Show Details
in not given react. with PCl5*ICl;;
Gmelin Handbook: P: MVol.C, 184, page 424 - 427 Full Text Show Details
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86
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With chlorine in not given react. with an excess of Cl2;;
Baudrimont, E.
Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67 Full Text Show Details
With Cl2 in not given react. with an excess of Cl2;;
Gmelin Handbook: P: MVol.C, 262, page 599 - 602 Full Text Show Details
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87
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Rx-ID: 26182466 Find similar reactions
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in neat (no solvent) inflammation of red P in Cl2 at ambient temp.;;
Personne, J.
C. r. Acad. Sci. (Paris), 1857 , vol. 45, p. 113 - 117 Full Text Show Details
in neat (no solvent) react. of red P with Cl2 at ambient temp.;;
Schroetter, A.
Sitz.-Ber. Akad. Wiss. (wien), 1848 , vol. 1, p. 130 - 137 Full Text Show Details
in not given at first prepn. of PCl3; passing Cl2 in PCl3;;
Mueller, H.
Dinglers politechn. J., 1862 , vol. 164, p. 385 - 386 Full Text Show Details
Mueller, H.
Zeitschrift fuer Chemie (Stuttgart, Germany), 1862 , vol. 5, p. 295 - 297 Full Text Show Details
in neat (no solvent) react. of red P with Cl2 at ambient temp.;;
Gmelin Handbook: P: MVol.C, 159, page 363 - 366 Full Text Show Details
in neat (no solvent)
Gmelin Handbook: P: MVol.C, 189, page 434 - 437
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inflammation of red P in Cl2 at ambient temp.;;
Full Text Show Details
in not given at first prepn. of PCl3; passing Cl2 in PCl3;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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D
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88
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Carius
Justus Liebigs Annalen der Chemie, 1860 , vol. 114, p. 145 Full Text View citing articles Show Details
89
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byproducts: HCl;
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Rx-ID: 26184764 Find similar reactions
Personne, J.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1857 , vol. 45, p. 113 - 117 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
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90
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Find similar
in neat (no solvent) disproportionation on storing for a longer period of time;;
Gmelin Handbook: P: MVol.C, 183, page 421 - 424 Full Text Show Details
Casselmann, W.
Liebigs Annalen der Chemie, 1852 , vol. 83, p. 257 - 275 Full Text Show Details
in neat (no solvent) disproportionation on storing for a longer period of time;;
Casselmann, W.
Liebigs Annalen der Chemie, 1852 , vol. 83, p. 257 - 275 Full Text Show Details
in neat (no solvent) disproportionation on storing for a longer period of time;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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91
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Rx-ID: 26582829 Find similar reactions
With hydrogenchloride in neat (no solvent) reaction on warming of SnCl4*2SCl4 with PCl3 in a HCl stream;;
Casselmann, W.
Liebigs Annalen der Chemie, 1852 , vol. 83, p. 257 - 275 Full Text Show Details
Gmelin Handbook: Sn: MVol.C2, 9.27.2, page 75 - 75 Full Text Show Details
92
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Rx-ID: 26124862 Find similar reactions
Corenwinder, B.
Ann. Chim. Phys., 1850 , vol. 30, p. 242 - 243 Full Text Show Details
Corenwinder, B.
Justus Liebigs Annalen der Chemie, 1851 , vol. 78, p. 76 - 84 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
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93
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With chlorine
at room temp.;
Schroetter, A.
Annalen der Physik (Weinheim, Germany), 1850 , vol. 81, p. 276 - 298 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
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94
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Rx-ID: 26456731 Find similar reactions
at light warming of Co3P2 in a chlorine stream formation of PCl5 and CoCl2 under fire phenomenon;;
Rose, H.
Annalen der Physik (Weinheim, Germany), 1832 , vol. 24, p. 331 - 331 Full Text Show Details
at light warming of Co3P2 in a chlorine stream formation of PCl5 and CoCl2 under fire phenomenon;;
Gmelin Handbook: Co: MVol.A2, 75, page 388 - 389 Full Text Show Details
95
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Find similar Rx-ID: 26150366 Find similar reactions
Find similar
in not given react. of Cl2 with PBr5;;
Balard, A.-J.
Ann. Chim. Phys., 1826 , vol. 32, p. 337 - 381 Full Text Show Details
in not given react. of Cl2 with PBr5;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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96
Synthesize Find similar Rx-ID: 26535844 Find similar reactions
With chlorine in neat (no solvent)
Balard, A.-J.
Ann. Chim. Phys., 1826 , vol. 32, p. 337 - 381 Full Text Show Details
Loewig, C.
Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, 1/74 Full Text Show Details
With Cl2 in neat (no solvent)
Gmelin Handbook: P: MVol.C, 218, page 501 - 503 Full Text Show Details
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97
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Rx-ID: 26170082 Find similar reactions
in neat (no solvent) oxidation of PH3 in Cl2;;
Thomson, T.
Schweiggers J. Chem. Phys., 1816 , vol. 18, p. 357 - 364 Full Text Show Details
in neat (no solvent) oxidation of PH3 in Cl2;;
Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details
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98
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With chlorine
depending on Cl2 volume;
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
Berzelius, J. J.
Lehrbuch der Chemie, 5.Ed., Vol. 1, Dresden-Leipzig 1843, p. 235 Full Text Show Details
Berzelius, J. J.
Lehrbuch der Chemie, 5.Ed., Vol. 1, Dresden-Leipzig 1843, p. 236 Full Text Show Details
Berzelius, J. J.
Lehrbuch der Chemie, 5.Ed., Vol. 1, Dresden-Leipzig 1843, p. 239 Full Text Show Details
99
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Rx-ID: 26585292 Find similar reactions
Gmelin Handbook: P: MVol.C, 233, page 533 - 535 Full Text Show Details
Paddock, N. L.; Searle, H. T.
Emeleus, H. J., Sharpe, A. G., Advances in inorganic chemistry and radiochemistry, Bd. 1, New York 1959, S. 347/83 Full Text Show Details