Phosphorus tribromide [Phosphorus(III) bromide; PBr3] by Asch

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Date

2 substances in Reaxys

2017-10-13 05h:22m:42s (EST)

1 substances in Reaxys

2017-10-13 05h:23m:36s (EST)

1. Query

Search as: As drawn, No salts, No mixtures, No isotopes, No charges, No radicals 2. Query

(1. Query) AND itemno in (1)

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2017-10-13 05:27:28

Reaxys ID 3903060 View in Reaxys

1/1 CAS Registry Number: 7789-60-8 Chemical Name: phosphorus tribromide; Phosphorus tribromide Linear Structure Formula: Br3P Molecular Formula: Br3P Molecular Weight: 270.686 InChI Key: IPNPIHIZVLFAFP-UHFFFAOYSA-N Note:

Br P

Substance Label (2) Label References 270.69

Patent; Dentsply DeTry GmbH; Klee, Joachim E.; Elsner, Oliver; Pohle, Sven; Ritter, Helmut; Bernert, Dominika; (20 pag.); US9682019; (2017); (B2) English, View in Reaxys

PBr3

Li, Zhao; Gao, Xinghui; Shi, Wen; Li, Xiaohua; Ma, Huimin; Chemical Communications; vol. 49; nb. 52; (2013); p. 5859 - 5861, View in Reaxys

Patent-Specific Data (2) Location in Patent References Page/Page column

Patent; Hoffmann-La Roche Inc.; Dehmlow, Henrietta; Martin, Rainer E.; Mattei, Patrizio; Obst Sander, Ulrike; Richter, Hans; US2013/123267; (2013); (A1) English, View in Reaxys; Patent; GLAXO GROUP LIMITED; Castro Pichel, Julia; Fernandez Menendez, Raquel; Fernandez Velando, Esther Pilar; Gonzalez Del Valle, Silvia; Mallo-Rubio, Araceli; US2013/203802; (2013); (A1) English, View in Reaxys; Patent; Kowa Co., Ltd.; SHIBUYA, Kimiyuki; OHGIYA, Tadaaki; MURAKAMI, Takeshi; EP2626351; (2013); (A1) English, View in Reaxys; Patent; Biota Europe Ltd.; Lunniss, Christopher James; Palmer, James T.; Pitt, Gary Robert William; Davies, David; Axford, Lorraine Claire; US2013/252938; (2013); (A1) English, View in Reaxys; Patent; Kornacker, Michael G.; Mapelli, Claudio; Riexinger, Douglas James; US2013/289238; (2013); (A1) English, View in Reaxys; Patent; NOVARTIS AG; Cotesta, Simona; Furet, Pascal; Guagnano, Vito; Holzer, Philipp; Kallen, Joerg; Mah, Robert; Masuya, Keiichi; Schlapbach, Achim; Stutz, Stefan; Vaupel, Andrea; US2013/317024; (2013); (A1) English, View in Reaxys; Patent; Glaxosmithkline LLC; Aubart, Kelly M.; Benowitz, Andrew B.; Fang, Yuhong; Hoffman, James; Karpinski, Joseph M.; Knox, Andrew Nicholson; Liao, Xiangmin; Qin, Donghui; Shi, Dongchuan; Spletstoser, Jared T.; US2013/345120; (2013); (A1) English, View in Reaxys; Patent; National University Corporation Kagawa University; FUNAHASHI Masahiro; TAKEUCHI Nozomi; EP2695885; (2014); (A1) English, View in Reaxys; Patent; Cadila Healthcare Limited; Pandey, Bipin; Lonray, Vidya Bhushan; Lohray, Braj Bhushan; US2014/88127; (2014); (A1) English, View in Reaxys; Patent; ONO Pharmaceutical Co., Ltd.; OBITSU, Tetsuo; TANI, Kousuke; SUGIHARA, Hikaru; NISHIURA, Akio; FUJIMURA, Shinsei; EP2740724; (2014); (A1) English, View in Reaxys; Patent; The Government of the United States of America, as reperesented by the Secretary of the Navy; Coneski, Peter N.; Lundin, Jeffrey G.; Fulmer, Preston A.; Wynne, James H.; US2014/221495; (2014); (A1) English, View in Reaxys; Patent; Takeda Pharmaceutical Company Limited; Lawson, John David; Sabat, Mark; Scorah, Nicholas; Smith, Christopher; Vu, Phong H.; Wang, Haixia; US2014/256734; (2014); (A1) English, View in Reaxys; Patent; Ren, Pingda; Liu, Yi; Li, Liansheng; Feng, Jun; Wu, Tao; US2014/288045; (2014); (A1) English, View in Reaxys; Patent; GlaxoSmithKline Intellectual Property (No. 2) Limited; Aubart, Kelly M.; Benowitz, Andrew B.; Fang, Yuhong; Hoffman, James; Karpinski, Joseph M.; Knox, Andrew Nicholson; Liao, Xiangmin; Qin, Donghui; Shi, Dongchuan; Spletstoser, Jared T.; US8901119; (2014); (B2) English, View in Reaxys; Patent; Acteon Pharmaceuticals Ltd.; Abele, Stefan; Schmidt, Gunther; US2015/25244; (2015); (A1) English, View in Reaxys; Patent; ACTELION PHARMACEUTICALS LTD.; Bolli, Martin; Boss, Christoph; Brotschi, Christine; Heidmann, Bibia; Sifferlen, Thierry; Williams, Jodi T.; US2015/158855; (2015); (A1) English, View in Reaxys

Claim

Patent; Sotzing, Gregory A.; US2009/326187; (2009); (A1) English, View in Reaxys; Patent; MSN Laboratories Limited; US2012/16129; (2012); (A1) English, View in Reaxys; Patent; The University of Connecticut; US8168671; (2012); (B2) English, View in Reaxys

Druglikeness (1) 1 of 1

LogP

2.961

H Bond Donors

H Bond Acceptors

Rotatable Bonds

TPSA

13.59

Lipinski Number

Veber Number

Purification (2)

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Purification (method)

References

purification described

Driel, M. van; Gerding, H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 60; (1941); p. 943 - 946, View in Reaxys; Rossini, F. D.; Wagman, D. D.; Evans, W. H.; Levine, S.; Jaffe, I.; Selected Values, 1952, S. 848, View in Reaxys; Mitchell; Pure and Applied Chemistry; vol. 54; nb. 4; (1981); p. 819 - 834 ; (from Gmelin), View in Reaxys

purification described

vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

Melting Point (3) 1 of 3

Melting Point [°C]

-40

Pushin, N. A.; Makuc, J.; Glasnik Hemijskog Drustva Beograd; vol. 15; (1950); p. 17 - 25, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494, View in Reaxys; Kafarov, V. V.; Dorokhov, I. N.; Vetokhin, V. N.; Volkov, L. P.; Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk); vol. 314; (1990); p. 683 - 686; Doklady Akademii Nauk SSSR; vol. 314; (1990); p. 201 - 205 ; (from Gmelin), View in Reaxys 2 of 3

Melting Point [°C]

-40.5

vol. P: MVol.C; 214, page 491 - 494, View in Reaxys; Biltz, W.; Jeep, K.; Z. Anorg. Chem.; vol. 162; (1927); p. 32 48 ; (from Gmelin), View in Reaxys 3 of 3

Melting Point [°C]

-41.5

Christomanos, A. C.; Z. Anorg. Chem.; vol. 41; (1904); p. 276 - 290, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys Boiling Point (11) Boiling Point [°C] Pressure (Boiling Point) [Torr] 173.3

References Kafarov, V. V.; Dorokhov, I. N.; Vetokhin, V. N.; Volkov, L. P.; Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk); vol. 314; (1990); p. 683 - 686; Doklady Akademii Nauk SSSR; vol. 314; (1990); p. 201 - 205 ; (from Gmelin), View in Reaxys

171

760

Christomanos, A. C.; Z. Anorg. Chem.; vol. 41; (1904); p. 276 - 290, View in Reaxys; Pushin, N. A.; Makuc, J.; Glasnik Hemijskog Drustva Beograd; vol. 15; (1950); p. 17 25, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

171.5

763

Vogel, A. I.; Journal of the Chemical Society; (1948); p. 1833 - 1855, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

173.3

760

Driel, M. van; Gerding, H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 60; (1941); p. 943 - 946, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

172.8

760

Arii, K.; Kawabata, M.; Rikagaku Kenkyusho Iho; vol. 17; (1938); p. 299 - 308, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

173

Butkov, K.; Zh. fiz. Khim.; vol. 7; (1936); p. 182 - 190, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

172

762

Biltz, W.; Sapper, A.; Wuennenberg, E.; Z. anorg. allg. Chem.; vol. 203; (1932); p. 277 - 306, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494, View in Reaxys; Biltz, W.; Jeep, K.; Z. Anorg. Chem.; vol. 162; (1927); p. 32 - 48 ; (from Gmelin), View in Reaxys

176 - 177

772

Sugden, S.; Reed, J. B.; Wilkins, H.; Journal of the Chemical Society; vol. 127; (1925); p. 1525 - 1540, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

66.5

Sugden, S.; Reed, J. B.; Wilkins, H.; Journal of the Chemical Society; vol. 127; (1925); p. 1525 - 1540, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

170.2

750

Jaeger, F. M.; Kahn, J.; Proc. Kon. Nederl. Akad. Wetensch.; vol. 19; (1916); p. 397 404, View in Reaxys; Jaeger, F. M.; Kahn, J.; Versl. wis- en naturrk. Afd. Kon. Nederl. Akad. Wetensch.; vol. 25; (1916); p. 301 - 308, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

172

757

Walden, P.; Z. Anorg. Chem.; vol. 25; (1900); p. 209 - 226, View in Reaxys; Walden, P.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 43; (1903); p. 385 - 464, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

Refractive Index (5)

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Refractive Index

Wavelength (Refractive Index) [nm]

Temperature (Refractive Index) [°C]

References

1.69632

589.3

1.6864

656.3

Jones, W. J.; Davies, W. C.; Dycke, W. J. C.; Journal of Physical Chemistry; vol. 37; (1933); p. 583 - 596, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

1.6935

589.3

Jones, W. J.; Davies, W. C.; Dycke, W. J. C.; Journal of Physical Chemistry; vol. 37; (1933); p. 583 - 596, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

1.7178

486.1

Jones, W. J.; Davies, W. C.; Dycke, W. J. C.; Journal of Physical Chemistry; vol. 37; (1933); p. 583 - 596, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

1.6945

589

Vogel, A. I.; Journal of the Chemical Society; (1948); p. 1833 - 1855, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

Christomanos, A. C.; Z. Anorg. Chem.; vol. 41; (1904); p. 276 - 290, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

Density (24) 1 of 24

Density [g·cm-3]

2.85

Location

supporting information

Yuan, Bin-Hua; Zhang, Zhi-Cheng; Liu, Wen-Jie; Sun, Xing-Wen; Tetrahedron Letters; vol. 57; nb. 20; (2016); p. 2147 - 2151, View in Reaxys 2 of 24

Density [g·cm-3]

2.8513

Measurement Temperature [°C]

Weissler, A.; Journal of the American Chemical Society; vol. 71; (1949); p. 1272 - 1274, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 3 of 24

Density [g·cm-3]

2.7364

Measurement Temperature [°C]

Vogel, A. I.; Journal of the Chemical Society; (1948); p. 1833 - 1855, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 4 of 24

Density [g·cm-3]

2.7965

Measurement Temperature [°C]

Vogel, A. I.; Journal of the Chemical Society; (1948); p. 1833 - 1855, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 5 of 24

Density [g·cm-3]

2.842

Measurement Temperature [°C]

Vogel, A. I.; Journal of the Chemical Society; (1948); p. 1833 - 1855, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 6 of 24

Density [g·cm-3]

2.8903

Measurement Temperature [°C]

Vogel, A. I.; Journal of the Chemical Society; (1948); p. 1833 - 1855, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 7 of 24

Density [g·cm-3]

2.8761

Measurement Temperature [°C]

Jones, W. J.; Davies, W. C.; Dycke, W. J. C.; Journal of Physical Chemistry; vol. 37; (1933); p. 583 - 596, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

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8 of 24

Density [g·cm-3]

3.412

Measurement Temperature [°C]

-79

Comment (Density)

Solid

Biltz, W.; Sapper, A.; Wuennenberg, E.; Z. anorg. allg. Chem.; vol. 203; (1932); p. 277 - 306, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 9 of 24

Density [g·cm-3]

3.514

Measurement Temperature [°C]

-183

Comment (Density)

Solid

Biltz, W.; Sapper, A.; Wuennenberg, E.; Z. anorg. allg. Chem.; vol. 203; (1932); p. 277 - 306, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 10 of 24

Comment (Density)

density equation

Sugden, S.; Reed, J. B.; Wilkins, H.; Journal of the Chemical Society; vol. 127; (1925); p. 1525 - 1540, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 11 of 24

Density [g·cm-3]

2.502

Measurement Temperature [°C]

170

Comment (Density)

Liquid

Jaeger, F. M.; Kahn, J.; Proc. Kon. Nederl. Akad. Wetensch.; vol. 19; (1916); p. 397 - 404, View in Reaxys; Jaeger, F. M.; Kahn, J.; Versl. wis- en naturrk. Afd. Kon. Nederl. Akad. Wetensch.; vol. 25; (1916); p. 301 - 308, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 12 of 24

Density [g·cm-3]

2.542

Measurement Temperature [°C]

154

Comment (Density)

Liquid

Density [g·cm-3]

2.577

Measurement Temperature [°C]

140

Comment (Density)

Liquid

Density [g·cm-3]

2.615

Measurement Temperature [°C]

125

Comment (Density)

Liquid

Density [g·cm-3]

2.636

Measurement Temperature [°C]

116

Comment (Density)

Liquid

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16 of 24

Density [g·cm-3]

2.676

Measurement Temperature [°C]

99.8

Comment (Density)

Liquid

Density [g·cm-3]

2.701

Measurement Temperature [°C]

Comment (Density)

Liquid

Density [g·cm-3]

2.735

Measurement Temperature [°C]

75.7

Comment (Density)

Liquid

Density [g·cm-3]

2.762

Measurement Temperature [°C]

64.8

Comment (Density)

Liquid

Density [g·cm-3]

2.799

Measurement Temperature [°C]

50.3

Comment (Density)

Liquid

Density [g·cm-3]

2.837

Measurement Temperature [°C]

35.3

Comment (Density)

Liquid

Density [g·cm-3]

2.871

Measurement Temperature [°C]

20.8

Comment (Density)

Liquid

Density [g·cm-3]

2.923

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Measurement Temperature [°C]

Comment (Density)

Liquid

Density [g·cm-3]

2.972

Measurement Temperature [°C]

-20

Comment (Density)

Liquid

Helferich, B.; Zeitschrift fuer Naturforschung; vol. 1; (1946); p. 666 - 670, View in Reaxys; Emeleus, H. J.; Miall, S.; Journal of the Society of Chemical Industry, London; vol. 56; (1937); p. 33 - 38, View in Reaxys; Walsh, A. D.; Journal of the Chemical Society; (1953); p. 2301 - 2306, View in Reaxys; vol. P: MVol.C; 160, page 366 - 368 ; (from Gmelin), View in Reaxys

Crystal Phase (1) Description (Crys- References tal Phase) Structure of the solid

Galy, Jean; Enjalbert, Renee; Journal of Solid State Chemistry; vol. 44; (1982); p. 1 - 23 ; (from Gmelin), View in Reaxys

Crystal Property Description (3) Colour & Other Point group Properties

Comment (Crystal References Property Description)

C3v

Clotet, A.; Rubio, J.; Illas, F.; Journal of Molecular Structure; vol. 164; (1988); p. 351 - 362, View in Reaxys; Helferich, B.; Zeitschrift fuer Naturforschung; vol. 1; (1946); p. 666 - 670, View in Reaxys; Bhagavantam, S.; Indian Journal of Physics (1926-1976); vol. 5; (1930); p. 73 - 95, View in Reaxys; vol. P: MVol.C; 160, page 366 368 ; (from Gmelin), View in Reaxys

colourless

BrCH2CO2H

Puri,J. K.; Kaur, Jaswinder; Sharma, Vijay; Miller, Jack M.; Polyhedron; vol. 2; (1983); p. 1287 - 1296 ; (from Gmelin), View in Reaxys

yellow

POCl3

Gutmann, V.; Z. Anorg. Chem.; vol. 269; (1952); p. 279 - 291, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys

Dielectric Constant (1) Dielectric ConTemperature (Die- Comment (Dielec- References stant lectric Constant) tric Constant) [°C] 3.88

Liquid

Schlundt, H.; Journal of Physical Chemistry; vol. 8; (1904); p. 122 130, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

Dissociation Energy (1) Comment (Disso- References ciation Energy) information on dissociation energy

Hartley, S. B.; Holmes, W. S.; Jacques, J. K.; Mole, M. F.; McCoubrey, J. C.; Quarterly Reviews, Chemical Society; vol. 17; (1963); p. 204 - 223, View in Reaxys; Jan-Khan, M.; Samuel, R.; Proceedings of the Physical Society, London; vol. 48; (1936); p. 626 - 641, View in Reaxys; vol. P: MVol.C; 159, page 363 - 366, View in Reaxys; Mathur, B. P.; Rothe, Erhard W.; Tang, S. Y.; Reck, Gene P.; Journal of Chemical Physics; vol. 65; (1976); p. 565 - 569 ; (from Gmelin), View in Reaxys

Dynamic Viscosity (8)

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Dynamic Viscosity [P]

Temperature (Dynamic Viscosity) [°C]

References

0.01302

Luchinskii, G. P.; Zh. obshch. Khim.; vol. 7; (1937); p. 2116 - 2127, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494, View in Reaxys; Likhacheva, A. I.; Luchinskii, G. P.; I. Khim. phys.; vol. 33; (1936); p. 488 - 491, View in Reaxys; Luchinskii, G. P.; Likhacheva, A. I.; Zh. fiz. Khim.; vol. 7; (1936); p. 546 - 548 ; (from Gmelin), View in Reaxys

0.01426

0.0156

0.01721

0.01928

0.0217

0.02455

0.0292

-15

Electrical Moment (5) 1 of 5

Description (Electrical Moment)

Dipole moment

Moment (Electrical Moment) [D]

0.54 - 0.78

Method (Electrical Moment)

other methods

Davies, M.S.; Pierens, R.K.; Aroney, M.J.; Journal of Organometallic Chemistry; vol. 458; nb. 1-2; (1993); p. 141 146 ; (from Gmelin), View in Reaxys 2 of 5

Description (Electrical Moment)

Dipole moment

Moment (Electrical Moment) [D]

0.52

Method (Electrical Moment)

not given

Suenaga, K.; Kotera, A.; J. chem. Soc. Japan, Pure Chem. Sect.; vol. 70; (1949); p. 116 - 118, View in Reaxys; vol. P: MVol.C; 161, page 368 - 370 ; (from Gmelin), View in Reaxys 3 of 5

Description (Electrical Moment)

Dipole moment

Moment (Electrical Moment) [D]

0.7

Method (Electrical Moment)

Dielectric constant, permittivity

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Boettcher, C. J. F.; Recueil Trav. chim. Pays-Bas.; vol. 62; (1943); p. 119 - 133, View in Reaxys; vol. P: MVol.C; 161, page 368 - 370 ; (from Gmelin), View in Reaxys 4 of 5

Description (Electrical Moment)

Dipole moment

Moment (Electrical Moment) [D]

0.62

Method (Electrical Moment)

not given

Malone, J. G.; Journal of Chemical Physics; vol. 1; (1933); p. 197 - 199, View in Reaxys; vol. P: MVol.C; 161, page 368 - 370 ; (from Gmelin), View in Reaxys 5 of 5

Description (Electrical Moment)

Dipole moment

Moment (Electrical Moment) [D]

0.61

Method (Electrical Moment)

Dielectric constant, permittivity

Bergmann, E.; Engel, L.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 13; (1931); p. 232 - 246, View in Reaxys; vol. P: MVol.C; 161, page 368 - 370, View in Reaxys; Bergmann, E.; Engel, L.; Phys. Z.; vol. 32; (1931); p. 507 - 509 ; (from Gmelin), View in Reaxys Electrochemical Characteristics (1) 1 of 1

Description (Electrochemical Characteristics)

polarography

Solvent (Electrochemical Characteristics)

acetonitrile

Comment (Electrochem- transmitted electrons: -1; potential diagram; 0.08 M tetraethylammonium perchlorate; -0.6 ical Characteristics) V Kisil'; Osadchenko; Tomilov; Russian Journal of General Chemistry; vol. 73; nb. 5; (2003); p. 695 - 696 ; (from Gmelin), View in Reaxys Electrolytic Conductivity (8) 1 of 8

Electrolytic Conductivity [S·l/(cm·mol)]

0.00178

Temperature (Electrolytic Conductivity) [°C]

Solvent (Electrolytic Conductivity)

acetonitrile

Kind of Conductivity

Molar conductivity

Comment (Electrolytic Conductivity)

0.025 mol/l

Harries, G. S.; Payne, D. S.; Journal of the Chemical Society; (1956); p. 4617 - 4621, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 2 of 8

Description (Electrolytic Conductivity)

Equivalent conductivity

Equivalent Conductivity [S·cm2/val]

0.0001679

Temperature (Electrolytic Conductivity) [°C]

-78.5

Solvent (Electrolytic Conductivity)

further solvent(s)

Comment (Electrolytic Conductivity)

0.162 mol PBr3/l in liquid H2S;

Quam, G. N.; Wilkinson, J. A.; Journal of the American Chemical Society; vol. 47; (1925); p. 989 - 994, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys

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3 of 8

Description (Electrolytic Conductivity)

Equivalent conductivity

Equivalent Conductivity [S·cm2/val]

0.000365

Temperature (Electrolytic Conductivity) [°C]

-78.5

Solvent (Electrolytic Conductivity)

further solvent(s)

Comment (Electrolytic Conductivity)

0.1076 mol PBr3/l in liquid H2S;

Quam, G. N.; Wilkinson, J. A.; Journal of the American Chemical Society; vol. 47; (1925); p. 989 - 994, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 4 of 8

Description (Electrolytic Conductivity)

Equivalent conductivity

Equivalent Conductivity [S·cm2/val]

0.0006643

Temperature (Electrolytic Conductivity) [°C]

-78.5

Solvent (Electrolytic Conductivity)

further solvent(s)

Comment (Electrolytic Conductivity)

0.0538 mol PBr3/l in liquid H2S;

Quam, G. N.; Wilkinson, J. A.; Journal of the American Chemical Society; vol. 47; (1925); p. 989 - 994, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 5 of 8

Description (Electrolytic Conductivity)

Equivalent conductivity

Equivalent Conductivity [S·cm2/val]

8.47E-05

Temperature (Electrolytic Conductivity) [°C]

-78.5

Solvent (Electrolytic Conductivity)

further solvent(s)

Comment (Electrolytic Conductivity)

0.2155 mol PBr3/l H2S;

Quam, G. N.; Wilkinson, J. A.; Journal of the American Chemical Society; vol. 47; (1925); p. 989 - 994, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 6 of 8

Description (Electrolytic Conductivity)

Equivalent conductivity

Equivalent Conductivity [S·cm2/val]

0.151

Temperature (Electrolytic Conductivity) [°C]

Solvent (Electrolytic Conductivity)

liquid sulphur dioxide

Comment (Electrolytic Conductivity)

diln. 24.0 l/val;

Description (Electrolytic Conductivity)

Equivalent conductivity

Equivalent Conductivity [S·cm2/val]

0.346

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Temperature (Electrolytic Conductivity) [°C]

Solvent (Electrolytic Conductivity)

liquid sulphur dioxide

Comment (Electrolytic Conductivity)

diln. 63.5 l/val;

Description (Electrolytic Conductivity)

Equivalent conductivity

Equivalent Conductivity [S·cm2/val]

0.798

Temperature (Electrolytic Conductivity) [°C]

Solvent (Electrolytic Conductivity)

liquid sulphur dioxide

Comment (Electrolytic Conductivity)

diln. 259.0 l/val;

Walden, P.; Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre; vol. 43; (1903); p. 385 - 464, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys Enthalpy of Formation (6) Enthalpy of ForTemperature (Enmation [Jmol-1] thalpy of Formation) [°C]

Comment (Enthalpy of Formation)

-185000

References

Kafarov, V. V.; Dorokhov, I. N.; Vetokhin, V. N.; Volkov, L. P.; Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk); vol. 314; (1990); p. 683 - 686; Doklady Akademii Nauk SSSR; vol. 314; (1990); p. 201 - 205 ; (from Gmelin), View in Reaxys

-194600

Liquid

Charney, I.; Skinner, H. A.; Journal of the Chemical Society; (1953); p. 450 - 452, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

-150300

Gaseous

vol. P: MVol.C; 214, page 491 - 494, View in Reaxys; Rossini, F. D.; Wagman, D. D.; Evans, W. H.; Levine, S.; Jaffe, I.; Selected Values, 1952, S. 79, View in Reaxys; Rossini, F. D.; Wagman, D. D.; Evans, W. H.; Levine, S.; Jaffe, I.; Selected Values, 1952, S. 848 ; (from Gmelin), View in Reaxys

-172400

Gaseous

-188300

Liquid

vol. P: MVol.C; 214, page 491 - 494, View in Reaxys; Bichowsky, F. R.; Rossini, F. D.; The Thermochemistry of the chemical Substances, New York 1936, S. 221, View in Reaxys; Bichowsky, F. R.; Rossini, F. D.; The Thermochemistry of the chemical Substances, New York 1936, S. 39 ; (from Gmelin), View in Reaxys

-198800

Liquid

Enthalpy of Vaporization (3) Enthalpy of VaTemperature (Enporization thalpy of Vapori[Jmol-1] zation) [°C]

Pressure (Enthalpy of Vaporization) [Torr]

References

39762

760

Driel, M. van; Gerding, H.; Recueil des Travaux Chimiques des Pays-Bas; vol. 60; (1941); p. 943 - 946, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

173.3

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40616

172.8

760

Arii, K.; Kawabata, M.; Rikagaku Kenkyusho Iho; vol. 17; (1938); p. 299 - 308, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

40972

172.8

760

Arii, K.; Kawabata, M.; Rikagaku Kenkyusho Iho; vol. 17; (1938); p. 299 - 308, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

Further Information (3) Additional DeReferences scription Health protection

vol. P: MVol.B; 1.6, page 92 - 95 ; (from Gmelin), View in Reaxys

Health protection

Sax, N. I.; Handbook of dangerous Materials, New York 1951, p. 310. ; (from Gmelin), View in Reaxys

Health protection

Sax, N. I.; Handbook of dangerous Materials, New York 1951, p. 311. ; (from Gmelin), View in Reaxys

Heat Capacity Cp (3) Heat Capacity Cp Temperature [Jmol-1K-1] (Heat Capacity Cp) [°C]

112.9

Comment (Heat Capacity Cp)

References

Cp equation; Gaseous

Stolevik, Reidar; Acta Chemica Scandinavica; vol. 43; nb. 8; (1989); p. 758 - 762, View in Reaxys; Spencer, H. M.; Flannagan, G. M.; Journal of the American Chemical Society; vol. 64; (1942); p. 2511 2513 ; (from Gmelin), View in Reaxys

Liquid

Weissler, A.; Journal of the American Chemical Society; vol. 71; (1949); p. 1272 - 1274, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

Cp equation; Gaseous

vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

Interatomic Distances and Angles (5) Description Comment (Intera- References tomic Distances and Angles) Interatomic distances and angles

Empirical calcn. (phys. properties)

Interatomic distances and angles

Ganguly; Journal of the American Chemical Society; vol. 117; nb. 6; (1995); p. 1777 1782, View in Reaxys; Huggins, M. L.; Journal of the American Chemical Society; vol. 75; (1953); p. 4126 - 4133, View in Reaxys; vol. P: MVol.C; 161, page 368 - 370, View in Reaxys; Schomaker, V.; Stevenson, D. P.; Journal of the American Chemical Society; vol. 63; (1941); p. 37 - 40 ; (from Gmelin), View in Reaxys Misawa, M.; Fukunaga, T.; Suzuki, K.; Journal of Chemical Physics; vol. 92; nb. 9; (1990); p. 5486 - 5490, View in Reaxys; Kisliuk, P.; Journal of Chemical Physics; vol. 22.; (1954); p. 86 - 92, View in Reaxys; Bergmann, E.; Engel, L.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 13; (1931); p. 232 - 246, View in Reaxys; Bergmann, E.; Engel, L.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 13; (1931); p. 247 - 267, View in Reaxys; vol. P: MVol.C; 161, page 368 - 370, View in Reaxys; Swingle, S. M.; Allen, P. W., Sutton, L. E., Acta cryst. (Copenhagen) 3 (1950) 46/72, View in Reaxys; Bergmann, E.; Engel, L.; Phys. Z.; vol. 32; (1931); p. 507 - 509 ; (from Gmelin), View in Reaxys

Interatomic distances and angles

Electron Diffraction

Spiridonov, V. P.; Gershikov, A. G.; Journal of Molecular Structure; vol. 140; (1986); p. 173 - 192, View in Reaxys; Gregg, H. A.; Transactions of the Faraday Society; vol. 33; (1937); p. 852 - 874, View in Reaxys; Hassel, O.; Sandbo, A.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 41; (1938); p. 75 - 85, View in Reaxys; vol. P: MVol.C; 161, page 368 - 370, View in Reaxys; Galy, Jean; Enjalbert, Renee; Journal of Solid State Chemistry; vol. 44; (1982); p. 1 23 ; (from Gmelin), View in Reaxys

Interatomic distances and angles

X-ray Diffraction

Galy, Jean; Enjalbert, Renee; Journal of Solid State Chemistry; vol. 44; (1982); p. 1 23 ; (from Gmelin), View in Reaxys

Interatomic distances and angles

Microwave Spectroscopy

Galy, Jean; Enjalbert, Renee; Journal of Solid State Chemistry; vol. 44; (1982); p. 1 23 ; (from Gmelin), View in Reaxys

Ionization Potential (4) Ionization Poten- Method (Ionizatial [eV] tion Potential)

Comment (Ioniza- References tion Potential)

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9.33 - 9.37

Photoelectron Spectroscopy

Adiabatic ionization

Mazyar, Oleg A.; Baer, Tomas; Chemical Physics Letters; vol. 288; nb. 2-4; (1998); p. 327 - 332 ; (from Gmelin), View in Reaxys

Photoelectron Spectroscopy

Adiabatic ionization; higher ionization potentials available

Grodzicki, Michael; Walther, Horst; Elbel, Susanne; Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie; vol. 39; nb. 10; (1984); p. 1319 - 1330 ; (from Gmelin), View in Reaxys

9.99

Photoelectron Spectroscopy

Vertical ionization; Daamen, H.; Boxhoorn, G.; Oskam, A.; Inorganica Chimica Acta; higher ionization vol. 28; (1978); p. 263 - 270 ; (from Gmelin), View in Reaxys potentials available formation of ions described

Mathur, B. P.; Rothe, Erhard W.; Tang, S. Y.; Reck, Gene P.; Journal of Chemical Physics; vol. 65; (1976); p. 565 - 569 ; (from Gmelin), View in Reaxys

Mechanical Properties (2) Description (MeReferences chanical Properties) Molar volume

Sladkov, I. B.; Journal of Applied Chemistry USSR (English Translation); vol. 64; (1991); p. 2273 - 2275; Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation); vol. 64; (1991); p. 2432 - 2434, View in Reaxys; Shulyndin; Inorganic Materials; vol. 41; nb. 6; (2005); p. 666 - 672 ; (from Gmelin), View in Reaxys

Compressibility

Weissler, A.; Journal of the American Chemical Society; vol. 71; (1949); p. 1272 - 1274, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

Molecular Deformation (2) Description (MoReferences lecular Deformation) Force constants

Spiridonov, V. P.; Gershikov, A. G.; Journal of Molecular Structure; vol. 140; (1986); p. 173 - 192, View in Reaxys; Edwards, H. G. M.; Journal of Molecular Structure; vol. 156; (1987); p. 137 - 142, View in Reaxys; Ohwada, Ken; Suzuki, Kazuya; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy; vol. 50; nb. 6; (1994); p. 1057 - 1064, View in Reaxys; Davis, P. W.; Oetjen, R. A.; J. mol. Spectroscopy; vol. 2; (1958); p. 253 - 258, View in Reaxys; Venkateswarlu, K.; Sundaram, S.; Proc. Phys. Soc., London, Sect. A; vol. 69; (1956); p. 180 - 183, View in Reaxys; vol. P: MVol.C; 162, page 370 - 372, View in Reaxys; Herzberg, G.; Infrared and Raman spectra of polyatomic molecules, New York-Toronto-London 1945, S. 177, View in Reaxys; Howard, J. B.; Wilson, E. B.; Journal of Chemical Physics; vol. 2; (1934); p. 630 - 634, View in Reaxys; Edwards, Howell G. M.; Fawcett, Victor; Inorganica Chimica Acta; vol. 197; (1992); p. 89 - 94, View in Reaxys; Kozulin, A. T.; Karmanov, V. I.; Theoretical and Experimental Chemistry; vol. 16; (1980); p. 83 - 87; Teoreticheskaya i Eksperimental'naya Khimiya; vol. 16; (1980); p. 97 102 ; (from Gmelin), View in Reaxys

Fundamental vibrations

Francois, F.; Delwaulle, M. L.; Journal de Chimie Physique et de Physico-Chimie Biologique; vol. 46; (1949); p. 80 - 86, View in Reaxys; Burkard, O.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 30; (1935); p. 298 - 304, View in Reaxys; Cabannes, J.; Rousset, A.; Ann. Phys. (Paris) (10); vol. 19; (1933); p. 229 - 303, View in Reaxys; Cabannes, J.; Rousset, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 194; (1932); p. 79 - 81, View in Reaxys; Daure, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 187; (1928); p. 940 - 941, View in Reaxys; Davis, P. W.; Oetjen, R. A.; J. molec. Spectroscopy; vol. 2; (1958); p. 253 - 258, View in Reaxys; Delwaulle, M.-L.; Bridoux, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 248; (1959); p. 1342 - 1344, View in Reaxys; Delwaulle, M.-L.; Francois, F.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 223; (1946); p. 796 - 798, View in Reaxys; Delwaulle, M.-L.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 222; (1946); p. 1391 - 1392, View in Reaxys; Delwaulle, M.-L.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 224; (1947); p. 389 - 391, View in Reaxys; Schilling, G.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 245; (1957); p. 2499 - 2502, View in Reaxys; vol. P: MVol.C; 163, page 372 - 375, View in Reaxys; Trumpy, B.; Zeitschrift fuer Physik; vol. 68; (1931); p. 675 - 682, View in Reaxys; Kozulin, A. T.; Karmanov, V. I.; Theoretical and Experimental Chemistry; vol. 16; (1980); p. 83 - 87; Teoreticheskaya i Eksperimental'naya Khimiya; vol. 16; (1980); p. 97 - 102, View in Reaxys; Daure, P.; Ann. Phys. (Paris) (10); vol. 12; (1929); p. 375 - 441 ; (from Gmelin), View in Reaxys

Other Thermochemical Data (1) Description (Oth- Comment (Other er Thermochemi- Thermochemical cal Data) Data)

References

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Entropy of vapori- molar entropy of zation vaporization = 89 J/(mol*K); 173 Deg C

Stoelevik, Reidar; Acta Chemica Scandinavica; vol. 43; nb. 9; (1989); p. 860 - 867 ; (from Gmelin), View in Reaxys

Solubility (MCS) (11) 1 of 11

Comment (Solubility (MCS))

sol. in CH2BrCO2H

Puri,J. K.; Kaur, Jaswinder; Sharma, Vijay; Miller, Jack M.; Polyhedron; vol. 2; (1983); p. 1287 - 1296 ; (from Gmelin), View in Reaxys 2 of 11

Comment (Solubility (MCS))

well sol. in SbBr3

Jander, C.; Weis, J.; Zeitschrift fuer Elektrochemie; vol. 61; (1957); p. 1275 - 1283, View in Reaxys; vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 3 of 11

Comment (Solubility (MCS))

readily sol. in I2;

Fialkov, Ya. A.; Kuz'menko, A. A.; Zh. obshch. Khim.; vol. 19; (1949); p. 812 - 825; C.; (1949); p. E 4783, View in Reaxys; vol. P: MVol.C; 232, page 531 - 533 ; (from Gmelin), View in Reaxys 4 of 11

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

liquid sulphur dioxide

Comment (Solubility (MCS))

Solubility: 1.1E1 weight-percent - 1.2E1 weight-percent

Shatenshtein, A. I.; Viktorov, M. M.; Acta physicochim. URSS (dtsch.); vol. 7; (1937); p. 883 - 898, View in Reaxys; Shatenshtein, A. I.; Viktorov, M. M.; Zh. fiz. Khim.; vol. 11; (1938); p. 18 - 27; C. II; (1939); p. 1843 ; (from Gmelin), View in Reaxys 5 of 11

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

liquid sulphur dioxide

Comment (Solubility (MCS))

Solubility: 1.9E1 weight-percent - 2.0E1 weight-percent

Solvent (Solubility (MCS))

sulfur dioxide

Comment (Solubility (MCS))

Solubility: 1.2E1 weight-percent

Satenshtein, A. I.; Viktorov, M. M.; Acta physicokhim. URSS; vol. 7; (1937); p. 883 - 898, View in Reaxys; Walden, P.; Centnerszwer, A.; Teletow, I.; Z. phys. Ch.; vol. 43; (1903); p. 385 - 464, View in Reaxys; vol. S: MVol.B1; 143, page 310 - 315, View in Reaxys; Behne, W.; Diss. Greifswald 1945 laut Jander, G., Die Grundlagen der Chemie in fluessigem Schwefeldioxyd in: Naturw. 26 (1938) 264/73 ; (from Gmelin), View in Reaxys 7 of 11

Solvent (Solubility (MCS))

sulfur dioxide

Comment (Solubility (MCS))

Solubility: 2.0E1 weight-percent

Comment (Solubility (MCS))

soluble in acetone, CHCl3, C6H6 and CS2;

Christomanos, A. C.; Z. Anorg. Chem.; vol. 41; (1904); p. 280 - 290, View in Reaxys; vol. P: MVol.C; 216, page 496 - 498 ; (from Gmelin), View in Reaxys

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9 of 11

Comment (Solubility (MCS))

soluble in AsCl3;

Walden, P.; Z. phys. Ch.; vol. 43; (1903); p. 383 - 464, View in Reaxys; vol. As: MVol.; 143, page 379 - 381 ; (from Gmelin), View in Reaxys 10 of 11

Solvent (Solubility (MCS))

sulfur dioxide

Comment (Solubility (MCS))

Solubility: 1.1E1 weight-percent - 1.2E1 weight-percent

vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys 11 of 11

Solvent (Solubility (MCS))

sulfur dioxide

Comment (Solubility (MCS))

Solubility: 1.9E1 weight-percent - 2.0E1 weight-percent

vol. P: MVol.C; 217, page 498 - 500 ; (from Gmelin), View in Reaxys Space Group (1) Comment (Space Group)

References

atomic positions available

Misawa, M.; Fukunaga, T.; Suzuki, K.; Journal of Chemical Physics; vol. 92; nb. 9; (1990); p. 5486 - 5490 ; (from Gmelin), View in Reaxys

Surface Tension (21) Surface Tension Temperature [g·s-2] (Surface Tension) [°C]

References

35.8 - 37.8

Joliet, J.-F.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 236; (1953); p. 1259 - 1261, View in Reaxys; vol. P: MVol.C; 214, page 491 494 ; (from Gmelin), View in Reaxys

37.16

59.5

Vogel, A. I.; Journal of the Chemical Society; (1948); p. 1833 - 1855, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

43.29

15.6

Vogel, A. I.; Journal of the Chemical Society; (1948); p. 1833 - 1855, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

37.1

Sugden, S.; Reed, J. B.; Wilkins, H.; Journal of the Chemical Society; vol. 127; (1925); p. 1525 - 1540, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

38.4

59.5

Sugden, S.; Reed, J. B.; Wilkins, H.; Journal of the Chemical Society; vol. 127; (1925); p. 1525 - 1540, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

44.1

Sugden, S.; Reed, J. B.; Wilkins, H.; Journal of the Chemical Society; vol. 127; (1925); p. 1525 - 1540, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

45.8

Sugden, S.; Reed, J. B.; Wilkins, H.; Journal of the Chemical Society; vol. 127; (1925); p. 1525 - 1540, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

26.3

170

28.4

154

30.4

140

32.6

125

Jaeger, F. M.; Kahn, J.; Proc. Kon. Nederl. Akad. Wetensch.; vol. 19; (1916); p. 397 404, View in Reaxys; Jaeger, F. M.; Kahn, J.; Versl. wis- en naturrk. Afd. Kon. Nederl.

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Akad. Wetensch.; vol. 25; (1916); p. 301 - 308, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys 33.8

116

99.8

38.9

75.7

40.1

64.8

41.3

50.3

42.3

35.3

43.2

20.8

44.7

45.8

-20

Vapour Pressure (2) Comment (VaReferences pour Pressure) vapor pressure di- Dudchik, G. P.; Polyachenok, O. G.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neoagram rganicheskoi Khimii); vol. 24; (1979); p. 360 - 362; Zhurnal Neorganicheskoi Khimii; vol. 24; (1979); p. 646 650 ; (from Gmelin), View in Reaxys vapor pressure equation

Arii, K.; Kawabata, M.; Rikagaku Kenkyusho Iho; vol. 17; (1938); p. 299 - 308, View in Reaxys; vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys

NMR Spectroscopy (14) 1 of 14

Description (NMR Spec- Chemical shifts; Spectrum troscopy) Nucleus (NMR Spectroscopy)

31P

Frequency (NMR Spectroscopy) [MHz]

121.5

Location

supporting information

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Wolff, Alexander; Pallmann, Julia; Brunner, Eike; Doert, Thomas; Ruck, Michael; Zeitschrift fur Anorganische und Allgemeine Chemie; vol. 643; nb. 1; (2017); p. 20 - 24, View in Reaxys 2 of 14

Description (NMR Spec- Chemical shifts troscopy) Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- chloroform-d1 scopy) Temperature (NMR Spectroscopy) [°C]

26.84

Frequency (NMR Spectroscopy) [MHz]

101.2

Original Text (NMR Spectroscopy)

31P{1H} NMR (CDCl3, 300 K): δ = 227 ppm.

Mourgas, Georgios; Tiritiris, Ioannis; Nieger, Martin; Gudat, Dietrich; Zeitschrift fur Anorganische und Allgemeine Chemie; vol. 639; nb. 3-4; (2013); p. 517 - 523, View in Reaxys 3 of 14

Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- chloroform-d1 scopy) Temperature (NMR Spectroscopy) [°C]

22.84

Comment (NMR Spectroscopy)

Signals given

Boshaala, Ahmed M. A.; Simpson, Stephen J.; Autschbach, Jochen; Zheng, Shaohui; Inorganic Chemistry; vol. 47; nb. 20; (2008); p. 9279 - 9292 ; (from Gmelin), View in Reaxys 4 of 14

Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- tetrahydrofuran scopy) Comment (NMR Spectroscopy)

Signals given

Brunet, Jean-Jacques; Diallo, Ousmane; Roblou, Emmanuel; Organometallics; vol. 22; nb. 9; (2003); p. 1796 1798 ; (from Gmelin), View in Reaxys 5 of 14

Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- CS2 scopy) Comment (NMR Spectroscopy)

Signals given

Tattershall, Bruce W.; Kendall, Nigel L.; Polyhedron; vol. 13; (1994); p. 1517 - 1522 ; (from Gmelin), View in Reaxys 6 of 14

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- (CD3)2CO=acetone-d6 scopy) Temperature (NMR Spectroscopy) [°C]

-70.15

Buckingham, Malcolm J.; Hawkes, Geoffrey E.; Ismail, Ismail M.; Sadler, Peter J.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1167 - 1168 ; (from Gmelin), View in Reaxys

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7 of 14

Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- not given scopy) Comment (NMR Spectroscopy)

Signals given

Wazer, J. R. van; Callis, C. F.; Shoolery, J. N.; Jones, R. C.; Journal of the American Chemical Society; vol. 78; (1956); p. 5715 - 5726, View in Reaxys; vol. P: MVol.C; 160, page 366 - 368, View in Reaxys; Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin), View in Reaxys 8 of 14

Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- CS2 scopy) Temperature (NMR Spectroscopy) [°C]

34.05

Comment (NMR Spectroscopy)

Signals given

Dillon, Keith B.; Platt, Andrew W. G.; Waddington, Thomas C.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1980); p. 1036 - 1041 ; (from Gmelin), View in Reaxys 9 of 14

Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- methylene chloride=methylene dichloride scopy) Temperature (NMR Spectroscopy) [°C]

34.05

Comment (NMR Spectroscopy)

Signals given

Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- nitrobenzene scopy) Temperature (NMR Spectroscopy) [°C]

34.05

Comment (NMR Spectroscopy)

Signals given

Nucleus (NMR Spectroscopy)

31P

Solvents (NMR Spectro- acetonitrile scopy) Temperature (NMR Spectroscopy) [°C]

34.05

Comment (NMR Spectroscopy)

Signals given

Nucleus (NMR Spectroscopy)

31P

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Solvents (NMR Spectro- not given scopy) Comment (NMR Spectroscopy)

Signals given

Gutowsky; McCall; Journal of Chemical Physics; vol. 22; (1954); p. 162, View in Reaxys; Muller, N.; Lauterbur, P. C.; Goldenson, J.; Journal of the American Chemical Society; vol. 78; (1956); p. 3557 - 3561, View in Reaxys; Parks, J. R.; Journal of the American Chemical Society; vol. 79; (1957); p. 757 - 757 ; (from Gmelin), View in Reaxys 13 of 14

Nucleus (NMR Spectroscopy)

81Br

Solvents (NMR Spectro- H2O scopy) Comment (NMR Spectroscopy)

Signals given

Dickinson, W. C.; Physical Review; vol. 81; (1951); p. 717 - 731 ; (from Gmelin), View in Reaxys 14 of 14

Nucleus (NMR Spectroscopy)

81Br

Solvents (NMR Spectro- water scopy) Comment (NMR Spectroscopy)

Signals given

vol. P: MVol.C; 160, page 366 - 368 ; (from Gmelin), View in Reaxys IR Spectroscopy (1) 1 of 1

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

neat (no solvent, gas phase)

Comment (IR Spectroscopy)

108 cm**-1 - 396 cm**-1

Kozulin, A. T.; Karmanov, V. I.; Theoretical and Experimental Chemistry; vol. 16; (1980); p. 83 - 87; Teoreticheskaya i Eksperimental'naya Khimiya; vol. 16; (1980); p. 97 - 102 ; (from Gmelin), View in Reaxys UV/VIS Spectroscopy (2) 1 of 2

Solvent (UV/VIS Spectroscopy)

gas

Comment (UV/VIS Spectroscopy)

249.5 nm - 269.5 nm

Jan-Khan, M.; Samuel, R.; Proceedings of the Physical Society, London; vol. 48; (1936); p. 626 - 641 ; (from Gmelin), View in Reaxys 2 of 2

Solvent (UV/VIS Spectroscopy)

neat (no solvent, gas phase)

Comment (UV/VIS Spectroscopy)

249.5 nm - 269.5 nm

vol. P: MVol.C; 214, page 491 - 494 ; (from Gmelin), View in Reaxys NQR Spectroscopy (3) Description (NQR Nucleus (NQR Spectroscopy) Spectroscopy)

Comment (NQR Spectroscopy)

References

Nuclear quadrupole coupling constants

81Br

Robinson, H.; Dehmelt, H. G.; Gordy, W.; Journal of Chemical Physics; vol. 22; (1954); p. 511 - 515, View in Reaxys; vol. P: MVol.C; 159, page 363 - 366 ; (from Gmelin), View in Reaxys

Nuclear quadrupole coupling constants

79Br

Robinson, H.; Dehmelt, H. G.; Gordy, W.; Journal of Chemical Physics; vol. 22; (1954); p. 511 - 515, View in Reaxys; vol. P: MVol.C; 159, page 363 - 366 ; (from Gmelin), View in Reaxys

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not given

Nuclear quadrupole resonance

Kojima et al.; Journal of Chemical Physics; vol. 21; (1953); p. 1415, View in Reaxys; vol. P: MVol.C; 159, page 363 - 366 ; (from Gmelin), View in Reaxys

Rotational Spectroscopy (1) Description (Rota- References tional Spectroscopy) Microwave spectrum

Williams, Q.; Gordy, W.; Physical Review; vol. 79; (1950); p. 225 - 225, View in Reaxys; vol. P: MVol.C; 161, page 368 - 370 ; (from Gmelin), View in Reaxys

Raman Spectroscopy (2) Description (Ram- References an Spectroscopy) Spectrum

Wolff, Alexander; Pallmann, Julia; Brunner, Eike; Doert, Thomas; Ruck, Michael; Zeitschrift fur Anorganische und Allgemeine Chemie; vol. 643; nb. 1; (2017); p. 20 - 24, View in Reaxys

Raman

Burkard, O.; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 30; (1935); p. 298 - 304, View in Reaxys; Cabannes, J.; Rousset, A.; Ann. Phys. (Paris) (10); vol. 19; (1933); p. 229 - 303, View in Reaxys; Cabannes, J.; Rousset, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 194; (1932); p. 79 - 81, View in Reaxys; Daure, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 187; (1928); p. 940 - 941, View in Reaxys; vol. P: MVol.C; 163, page 372 - 375, View in Reaxys; Trumpy, B.; Zeitschrift fuer Physik; vol. 68; (1931); p. 675 - 682, View in Reaxys; Mikov, S. N.; Kozulin, A. T.; Journal of Applied Spectroscopy; vol. 47; (1987); p. 1140 - 1143; Zhurnal Prikladnoi Spektroskopii; vol. 47; (1987); p. 765 - 768, View in Reaxys; Daure, P.; Ann. Phys. (Paris) (10); vol. 12; (1929); p. 375 - 441 ; (from Gmelin), View in Reaxys

Luminescence Spectroscopy (1) Description (LuReferences minescence Spectroscopy) X-ray emission spectrum

Dolenko, G. N.; Journal of Molecular Structure; vol. 291; nb. 1; (1993); p. 23 - 58 ; (from Gmelin), View in Reaxys

Fluorescence Spectroscopy (1) Description (Fluo- References rescence Spectroscopy) Fluorescence

Bramwell, M. J.; Hughes, C.; Jaeger, S. E.; Whitehead, J. C.; Chemical Physics; vol. 183; (1994); p. 127 134 ; (from Gmelin), View in Reaxys

Other Spectroscopic Methods (1) Description (Oth- References er Spectroscopic Methods) Photoelectron spectrum

Use (18) Laboratory Use and Handling

Grodzicki, Michael; Walther, Horst; Elbel, Susanne; Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie; vol. 39; nb. 10; (1984); p. 1319 - 1330, View in Reaxys; Boyle, Kenneth J.; Jarvis, Gary K.; Tuckett, Richard P.; Journal of the Chemical Society - Faraday Transactions; vol. 94; nb. 8; (1998); p. 1045 - 1050, View in Reaxys; Daamen, H.; Boxhoorn, G.; Oskam, A.; Inorganica Chimica Acta; vol. 28; (1978); p. 263 - 270 ; (from Gmelin), View in Reaxys Use Pattern

References

halogenating agent

Patent; SUMITOMO CHEMICAL COMPANY, LIMITED; WO2009/14267; (2009); (A2) English, View in Reaxys

Brominating Patent; LUPIN LTD; US2005/245738; (2005); (A1) English, View in Reaxys agent in synthesis of highly pure cefdinir Brominating agent moisture sensitive

Patent; BOEHRINGER INGELHEIM PHARMA GMBH and CO. KG; DAHMANN, Georg; WO2004/56784; (2004); (A1) German, View in Reaxys Aubauer, Christoph; Engelhardt, Guenter; Klapoetke, Thomas M.; Noeth, Heinrich; Schulz, Axel; Warchhold, Marcus; European Journal of Inorganic Chemistry; nb. 10; (2000); p. 2245 - 2253 ; (from Gmelin), View in Reaxys

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readily decomp. at room temp.

Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin), View in Reaxys

handling described

Weisert, E. D.; Corrosion (Houston); vol. 13; (1957); p. 659 - 671, View in Reaxys; vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin), View in Reaxys

stable against Te;

Montignie, E.; Bull. Soc. chim. France (5); vol. 15; (1948); p. 180 - 181, View in Reaxys; vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin), View in Reaxys

explosion in mixture with Na or K on impact;

vol. P: MVol.C; 216, page 496 - 498, View in Reaxys; Cueilleron, J.; Bull. Soc. chim. France (5); vol. 12; (1945); p. 88 - 89 ; (from Gmelin), View in Reaxys

information on use

Dufraisse, C.; Horcloi, R.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 192; (1931); p. 564 - 566, View in Reaxys; vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin), View in Reaxys

not inflammable;

Christomanos, A. C.; Z. Anorg. Chem.; vol. 41; (1904); p. 276 - 290, View in Reaxys; vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin), View in Reaxys

stable against O2 in the cold;

Christomanos, A. C.; Z. Anorg. Chem.; vol. 41; (1904); p. 276 - 290, View in Reaxys; vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin), View in Reaxys

decomposition with aq. saturated soln. of HBr;

Damoiseau, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 91; (1880); p. 883 - 886, View in Reaxys; vol. P: MVol.C; 215, page 494 496 ; (from Gmelin), View in Reaxys

decompn. with Cl2;

Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355, View in Reaxys; Gladstone, J. H.; Journal fuer Praktische Chemie (Leipzig); vol. 49; (1850); p. 40 - 51, View in Reaxys; vol. P: MVol.C; 159, page 363 - 366 ; (from Gmelin), View in Reaxys

unstable against gaseous NH3 forming a white powder;

Rose, H.; Ann. Phys. Chem. (2); vol. 28; (1833); p. 529 - 550, View in Reaxys; vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin), View in Reaxys

fumes in contact with air;

Balard, A.-J.; Ann. Chim. Phys.; vol. 32; (1826); p. 337 - 381, View in Reaxys; vol. P: MVol.C; 215, page 494 - 496, View in Reaxys; Gay, J. F.; Maxson, R. N.; Fernelius, W. C., Inorganic Syntheses, Bd. 2, New York-London 1946, S. 147/51 ; (from Gmelin), View in Reaxys

slow decomposition with H2O at 8°C while shaking, becomes vigorous at 25°C;

vol. P: MVol.C; 215, page 494 - 496, View in Reaxys; Loewig, C.; Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, S. 1/174 ; (from Gmelin), View in Reaxys

formation of light green compounds on heating with Cu2Cl2 or Cu2Br2 at 100°C in a sealed tube;

vol. P: MVol.C; 216, page 496 - 498, View in Reaxys; Wolf, L.; Diss. Berlin T. H. 1915, S. 1/40 ; (from Gmelin), View in Reaxys

stable when shaking with AgBr at 100°C;

vol. P: MVol.C; 216, page 496 - 498, View in Reaxys; Wolf, L.; Diss. Berlin T. H. 1915, S. 1/40 ; (from Gmelin), View in Reaxys

Quantum Chemical Calculations (25) Calculated Prop- Method (Quantum References erties Chemical Calculations) Population analysis, charge distribution; Dipole moment, dipole moment derivative

Electron correlation and CI calcn.

Scheiner, Steve; Chemical Physics; vol. 387; nb. 1-3; (2011); p. 79 - 84 ; (from Gmelin), View in Reaxys

Atom distances, angles; Population analysis,

Electron correlation and CI calcn.

Raabe, Ines; Roehr, Caroline; Krossing, Ingo; Dalton Transactions; nb. 46; (2007); p. 5376 - 5386 ; (from Gmelin), View in Reaxys

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charge distribution Atom distances, angles

Electron correlation and CI calcn.

See, Ronald F.; Baker, Thomas A.; Kahler, Pamela; Inorganic Chemistry; vol. 44; nb. 14; (2005); p. 4961 - 4968 ; (from Gmelin), View in Reaxys

NMR shifts, signals, intensities, transition moments

Ab initio calcns. Patchkovskii, Serguei; Ziegler, Tom; Journal of Physical Chemistry A; vol. 106; nb. 6; (LCAO, GO SCF, (2002); p. 1088 - 1099 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Atom distances, angles; Population analysis, charge distribution; Vibrational constants; Rotational constants

Ab initio calcns. Heil, Terry E.; Check, Catherine E.; Lobring, Kim C.; Sunderlin, Lee S.; Journal of (LCAO, GO SCF, Physical Chemistry A; vol. 106; nb. 42; (2002); p. 10043 - 10048 ; (from Gmelin), DIM, SAMO, X-al- View in Reaxys pha, HartreeFock)

Atom distances, angles; Population analysis, charge distribution; Electronegativity; Force constant

Ab initio calcns. Atanasov; Reinen; Journal of Physical Chemistry A; vol. 105; nb. 22; (2001); p. 5450 (LCAO, GO SCF, 5467 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Atom distances, angles

Ab initio calcns. (LCAO, GO SCF, DIM, SAMO, X-alpha, HartreeFock)

Transition energies

Other semi-empir- Cavell, Ronald G.; Juergensen, Astrid; Journal of Electron Spectroscopy and Related ical calcns. Phenomena; vol. 101-103; (1999); p. 125 - 129 ; (from Gmelin), View in Reaxys (Hueckel, PPP)

Atom distances, angles; Dipole moment, dipole moment derivative; IR bands, intensities, transition moments

Electron correlation and CI calcn.

Timoshkin, Alexey Y.; Suvorov, Andrew V.; Bettinger, Holger F.; Schaefer III, Henry F.; Journal of the American Chemical Society; vol. 121; nb. 24; (1999); p. 5687 - 5699 ; (from Gmelin), View in Reaxys

Atom distances, angles; Dipole moment, dipole moment derivative; IR bands, intensities, transition moments

Ab initio calcns. (LCAO, GO SCF, DIM, SAMO, X-alpha, HartreeFock)

Timoshkin; Suvorov; Shaefer III; Russian Journal of General Chemistry; vol. 69; nb. 4; (1999); p. 544 - 550, View in Reaxys; Timoshkin, Alexey Y.; Suvorov, Andrew V.; Bettinger, Holger F.; Schaefer III, Henry F.; Journal of the American Chemical Society; vol. 121; nb. 24; (1999); p. 5687 - 5699 ; (from Gmelin), View in Reaxys

Atom distances, angles; Ionization potential, orbital energy

Electron correlation and CI calcn.

Mazyar, Oleg A.; Baer, Tomas; Chemical Physics Letters; vol. 288; nb. 2-4; (1998); p. 327 - 332 ; (from Gmelin), View in Reaxys

Aubauer, Christoph; Engelhardt, Guenter; Klapoetke, Thomas M.; Noeth, Heinrich; Schulz, Axel; Warchhold, Marcus; European Journal of Inorganic Chemistry; nb. 10; (2000); p. 2245 - 2253, View in Reaxys; See; Dutoi; McConnell; Naylor; Journal of the American Chemical Society; vol. 123; nb. 12; (2001); p. 2839 - 2848 ; (from Gmelin), View in Reaxys

Ionization poten- Ab initio calcns. Mazyar, Oleg A.; Baer, Tomas; Chemical Physics Letters; vol. 288; nb. 2-4; (1998); p. tial, orbital energy (LCAO, GO SCF, 327 - 332 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock) Molecular orbitals; Electronic energy levels; Ionization potential, orbital energy; Vibrational constants

Ab initio calcns. Creve, Steven; Nguyen, Minh Tho; Journal of Physical Chemistry A; vol. 102; nb. 32; (LCAO, GO SCF, (1998); p. 6549 - 6557 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

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Vibrational constants

Electron correlation and CI calcn.

Creve, Steven; Nguyen, Minh Tho; Journal of Physical Chemistry A; vol. 102; nb. 32; (1998); p. 6549 - 6557 ; (from Gmelin), View in Reaxys

Fine/ hyper fine coupling constants

Semi-empirical NDO calcns. (CNDO, INDO, MINDO, PCILO)

Lobayan, R. M.; Aucar, G. A.; Journal of Molecular Structure; vol. 452; (1998); p. 1 12 ; (from Gmelin), View in Reaxys

Atom distances, angles; Molecular orbitals; Electron distribution

Semi-empirical NDO calcns. (CNDO, INDO, MINDO, PCILO)

Timokhin; Golubin; Ratovskii; Safronov; Ignat'ev; Russian Journal of General Chemistry; vol. 66; nb. 2; (1996); p. 278 - 284 ; (from Gmelin), View in Reaxys

Polarizability, polarizability derivatives; Rotational constants

Electron correlation and CI calcn.

Stoecklin, T.; Clary, D. C.; Journal of Molecular Structure; vol. 341; (1995); p. 53 - 62 ; (from Gmelin), View in Reaxys

Electronegativity

Semi-empirical NDO calcns. (CNDO, INDO, MINDO, PCILO)

Datta, Dipankar; Inorganic Chemistry; vol. 31; (1992); p. 2797 - 2800 ; (from Gmelin), View in Reaxys

Electronic energy levels; Atom distances, angles

Ab initio calcns. Novak, Igor; Phosphorus, Sulfur and Silicon and the Related Elements; vol. 68; nb. 1-4; (LCAO, GO SCF, (1992); p. 15 - 24 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Ionization potential, orbital energy; Dipole moment, dipole moment derivative; Atom distances, angles

Semi-empirical NDO calcns. (CNDO, INDO, MINDO, PCILO)

Equilibrium internuclear distance; Atom distances, angles; Electronic energy levels; Excited states; Vibrational constants

Ab initio calcns. Clotet, A.; Rubio, J.; Illas, F.; Journal of Molecular Structure; vol. 164; (1988); p. 351 (LCAO, GO SCF, 362 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Dewar, Michael J. S.; Jie, Caoxian; Journal of Molecular Structure; vol. 187; (1989); p. 1 - 14 ; (from Gmelin), View in Reaxys

Ionization poten- Other semi-empir- El-Issa, Basheer D.; Zanati, Huda M.; Journal of the Chemical Society, Faraday Transtial, orbital energy ical calcns. actions 2: Molecular and Chemical Physics; vol. 82; (1986); p. 93 - 100 ; (from Gmelin), (Hueckel, PPP) View in Reaxys Ionization potential, orbital energy; Molecular orbitals

Other semi-empir- Min Xin; Lue-Yung Chow Chiu; Li, Du; Pan, Yuh-Kang; Journal of Electron Spectroical calcns. scopy and Related Phenomena; vol. 33; (1984); p. 93 - 106 ; (from Gmelin), (Hueckel, PPP) View in Reaxys

Electronic energy levels; Molecular orbitals

Semi-empirical NDO calcns. (CNDO, INDO, MINDO, PCILO)

Kharabaev, N. N.; Breus, S. F.; Kogan, V. A.; Osipov, O. A.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 9; (1983); p. 194 - 196; Koordinatsionnaya Khimiya; vol. 9; (1983); p. 322 - 325 ; (from Gmelin), View in Reaxys

Dipole moment, dipole moment derivative

further quantum chemical calcns.

vol. P: MVol.C; 159, page 363 - 366, View in Reaxys; Murayama, N.; Proc. Imp. Acad. (tokyo); vol. 20; (1944); p. 93 - 99 ; (from Gmelin), View in Reaxys

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