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Citations (86)
Conditions
References A
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Tattershall, Bruce W.; Kendall, Nigel L.
Polyhedron, 1994 , vol. 13, p. 1517 - 1522 Full Text View citing articles Show Details
in carbon disulfide
under N2, dropwise addn. of Br2/CS2 to a stirred soln. of P4/CS2 (-10°C, 1 h), yellow soln.; not isolated, identified by 31P-NMR spectroscopy, molar ratio of PBr3, P2Br4, exo,exo-P4Br2 and exo,endo-P4Br2: 95 : 2.7 : 0.48 : 1.9;
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Rx-ID: 26669240 Find similar reactions
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Loennecke, P.; Blachnik, R.; Tattershall, B. W.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1994 , vol. 620, p. 1115 - 1124 Full Text Show Details
in neat (no solvent) addn. of Se and red P to Br2, -40°C; sealing under N2; slowly heating to 200°C; cooling; addn. of CS2; stirring; filtration; all reacts. excluding light; detn. by NMR;
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3
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Rx-ID: 26669241 Find similar reactions
Loennecke, P.; Blachnik, R.; Tattershall, B. W.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1994 , vol. 620, p. 1115 - 1124 Full Text Show Details
in neat (no solvent) addn. of Se and red P to Br2, -40°C; sealing under N2; slowly heating to 250°C; cooling; addn. of CS2; stirring; filtration; not isolated; detn. by NMR;
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Rx-ID: 26486988 Find similar reactions
Demarcq, Michel C.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , p. 35 - 40 Full Text Show Details
in neat (no solvent) Pure PSBr3 is heated in a sealed tube at 140°C for 43 min.; Formed PBr3 is detected by NMR spectrum.;
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5
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Rx-ID: 26368810 Find similar reactions
A: 0%
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Lathrop, David; Eckert, Hellmut
Journal of Physical Chemistry, 1989 , vol. 93, # 23 p. 7895 - 7902 Title/Abstract Full Text View citing articles Show Details
in not given according Penney, Sheldrick, J. Chem. Soc. A 1971, 245;;
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Rx-ID: 26480188 Find similar reactions
Minkwitz, Rolf; Liedtke, Andreas
Inorganic Chemistry, 1989 , vol. 28, p. 4238 - 4242 Full Text View citing articles Show Details
in carbon disulfide
P2H4, CS2 and HBr condensed into a quartz NMR tube at 77°K, slowly warmed to 205°K; observed by P(31)-NMR;
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7
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A: 0%
in not given
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Dillon, Keith B.; Platt, Andrew W. G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details
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Rx-ID: 26368452 Find similar reactions
Dillon, Keith B.; Platt, Andrew W. G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details
in dichloromethane
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9
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Rx-ID: 26368453 Find similar reactions
in dichloromethane
under N2, Br2 added dropwise to soln. of (NEt4)(PCl(CN)3) contg. excessof N(n-C3H7)4Br; monitored by (31)P NMR spectra;
Dillon, Keith B.; Platt, Andrew W. G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details
10
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Rx-ID: 26402573 Find similar reactions
42%
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in neat (no solvent) byproducts: Et4NIBr2; argon atmosphere; org. compd. addn. to PBr5 (cooling to -20°C), reaction vessel connecting to vac. line; PBr3 collection (trap cooled with liq. nitrogen);
Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.
Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details
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11
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Rx-ID: 26453860 Find similar reactions
in neat (no solvent) byproducts: Et4NBr; argon atmosphere; mixing org. compd. and PBr5 (cooling), mixt. leaving for 1 h at room temp., heating (vac., 80°C, 2 h); volatile products collection (trap cooled with liq. nitrogen);
Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.
Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details
12
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Rx-ID: 26368991 Find similar reactions
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93.5%
in benzene
Medoks, G. V.; Maslova, L. A.
Zh. neorgan. Khim., 1956 , vol. 1, p. 1929 - 1930 C. A., 1957 , p. 5609 Full Text Show Details
93.5%
in benzene
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in neat (no solvent) heating red P with I2; react. at the transition point of red P;;
Schroetter, A.
Sitz.-Ber. Akad. Wiss. (wien), 1848 , vol. 1, p. 130 - 137 Full Text Show Details
direct synthesis in null-manometer, according to: O. G. Polyachenok, Author's Abstract of Doctoral Thesis, Leningrad, 1972;
Dudchik, G. P.; Polyachenok, O. G.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1979 , vol. 24, p. 360 - 362 Zhurnal Neorganicheskoi Khimii, 1979 , vol. 24, p. 646 - 650 Full Text Show Details
in neat (no solvent) reaction of Br2 with red P, moistened by PBr3;;
Volhard, J.
Liebigs Annalen der Chemie, 1887 , vol. 242, p. 141 - 163 Full Text Show Details
in neat (no solvent) slow admission Br2 to P in a CO2 atmosphere, warming when reaction becomes slower because of formation of a layer of product around the P pieces;;
Rekshinskii, V.
C. I, Tr. Inst. chistykh. khim. Reaktivov Nr. 3 (1924) 46/9 1925 , p. 477 Full Text Show Details
in not given dropping a slurry of Br2 in PBr3 to red P (dried at 105°C for several hours, 25-30percent excess), suspension has to be kept sufficiently liquid to avoid explosions;;
Gay, J. F.; Maxson, R. N.
Fernelius, W. C., Inorganic Syntheses, Bd. 2, New York-London 1946, S. 147/51 Full Text Show Details
in neat (no solvent) heating red P with I2; react. at the transition point of red P;;
Gmelin Handbook: P: MVol.C, 159, page 363 - 366 Full Text Show Details
in neat (no solvent) reaction of Br2 with red P, moistened by PBr3;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in neat (no solvent) slow admission Br2 to P in a CO2 atmosphere, warming when reaction becomes slower because of formation of a layer of product around the P pieces;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in not given dropping a slurry of Br2 in PBr3 to red P (dried at 105°C for several hours, 25-30percent excess), suspension has to be kept sufficiently liquid to avoid explosions;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in carbon disulfide
Giran, H.
Ann. Chim. Phys., 1903 , vol. 30, p. 203 - 288 Full Text Show Details
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in carbon disulfide
reaction in CS2 soln. even in presence of excess despite of Br2;;
Giran, H.
Ann. Chim. Phys., 1903 , vol. 30, p. 203 - 288 Full Text Show Details
Gmelin Handbook: P: MVol.C, 213, page 489 - 491 Full Text Show Details
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Rx-ID: 26401659 Find similar reactions
With aluminium trichloride
at the m.p. of BrCN;
Gana, J.; Fricke, K.; Mueller, H.; Wallenwein, G.
Bol. Soc. Chil. Quim., 1971 , vol. 17, p. 27 - 28 C.A., 1972 , vol. 76, p. 9988 Full Text Show Details Gmelin Handbook: C: MVol.D3, 6.2.5.6.7.10, page 238 - 238 Full Text Show Details
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A: >99 B: >99
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Burg, A. B.; Griffiths, J. E.
Journal of the American Chemical Society, 1960 , vol. 82, p. 3514 - 3517 Full Text View citing articles Show Details
Gmelin Handbook: F: PerFHalOrg.3, 1.9, page 70 - 123 Full Text Show Details
90°C (16 h);
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15
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A: >99 B: >99 C: >99
16
90°C;
Burg, A. B.; Griffiths, J. E.
Journal of the American Chemical Society, 1960 , vol. 82, p. 3514 - 3517 Full Text View citing articles Show Details
Gmelin Handbook: F: PerFHalOrg.3, 1.9, page 70 - 123 Full Text Show Details
room temp.;
Burg, A. B.; Griffiths, J. E.
Journal of the American Chemical Society, 1960 , vol. 82, p. 3514 - 3517 Full Text View citing articles Show Details
Gmelin Handbook: F: PerFHalOrg.3, 1.9, page 70 - 123 Full Text Show Details
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Rx-ID: 7084938 Find similar reactions
Fluck et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 6363 Full Text View citing articles Show Details
T=180°C; Equilibrium constant;
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Rx-ID: 7442181 Find similar reactions
Fluck et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 6363 Full Text View citing articles Show Details
T=180°C; Equilibrium constant;
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Rx-ID: 26385273 Find similar reactions
Delwaulle, M.-L.; Bridoux, M.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1959 , vol. 248, p. 1342 - 1344 Full Text Show Details
Gmelin Handbook: P: MVol.C, 225, page 516 - 517 Full Text Show Details
in neat (no solvent) byproducts: PCl2Br, PClBr2, PFClBr; equilibrium within 4 d;; product mixture obtained; not isolated; detected by Raman spectroscopy;;
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Rx-ID: 26456918 Find similar reactions
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Kolditz, L.; Feltz, A.
Z. Anorg. Chem., 1958 , vol. 293, p. 286 - 293 Full Text Show Details
Gmelin Handbook: P: MVol.C, 224, page 513 - 516 Full Text Show Details
in tetrachloromethane
decomposition with deep red color in CCl4 soln., formed PBr5 partially decomposes into Br2 and PBr3;;
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20
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21
in neat (no solvent) decomposition on melting;;
Chatterjee, S. D.
Journal of the Indian Chemical Society, 1942 , vol. 19, p. 49 - 50 Full Text Show Details
in neat (no solvent) at 65 °C the decompn. achieves about 98.5percent, at 90°C >99percent;;
Harries, G. S.; Payne, D. S.
Journal of the Chemical Society, 1958 , p. 3732 - 3733 Full Text View citing articles Show Details
in further solvent(s) complete dissociation at higher temperature in liquid PBr3;;
Baxter, G. P.; Moore, C. J.; Boylston, A. C.
Journal of the American Chemical Society, 1912 , vol. 34, p. 259 - 274 Full Text View citing articles Show Details
in neat (no solvent) at 65 °C the decompn. achieves about 98.5percent, at 90°C >99percent;;
Gmelin Handbook: P: MVol.C, 218, page 501 - 503 Full Text Show Details
in neat (no solvent) decomposition on melting;;
Gmelin Handbook: P: MVol.C, 217, page 498 - 500 Full Text Show Details
in further solvent(s) complete dissociation at higher temperature in liquid PBr3;;
Gmelin Handbook: P: MVol.C, 218, page 501 - 503 Full Text Show Details
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Rx-ID: 26184762 Find similar reactions
With bromine in benzene
Medoks, G. V.; Maslova, L. A.
Zhurnal Neorganicheskoi Khimii, 1956 , vol. 1, p. 1929 - 1930 C. A., 1957 , p. 5609/10 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
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Gerrard; Herbst
Journal of the Chemical Society, 1955 , p. 277 Full Text View citing articles Show Details
T=160°C; beim Erhitzen;
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Gerrard; Herbst
Journal of the Chemical Society, 1955 , p. 277 Full Text View citing articles Show Details
T=22°C;
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Rx-ID: 7055026 Find similar reactions
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Gerrard; Herbst
Journal of the Chemical Society, 1955 , p. 277 Full Text View citing articles Show Details
T=100°C; beim Erhitzen;
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Gerrard; Herbst
Journal of the Chemical Society, 1955 , p. 277 Full Text View citing articles Show Details
T=160°C;
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T=100°C;
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Gerrard; Herbst
Journal of the Chemical Society, 1955 , p. 277 Full Text View citing articles Show Details
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Gerrard; Herbst
Journal of the Chemical Society, 1955 , p. 277 Full Text View citing articles Show Details
T=118°C;
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Rx-ID: 7057775 Find similar reactions
Gerrard; Herbst
Journal of the Chemical Society, 1955 , p. 277 Full Text View citing articles Show Details
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in tetrachloromethane
dissociation;; detected by photometry;;
Popov; Schmorr
Journal of the American Chemical Society, 1952 , vol. 74, p. 4672 Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 232, page 531 - 533 Full Text Show Details
in tetrachloromethane
dissociation;; detected by photometry;;
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Rx-ID: 26368527 Find similar reactions
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in neat (no solvent) reaction of Br2 in CO2 (as carrier gas) with dry P;;
Lieben, A.
Liebigs Annalen der Chemie, 1868 , vol. 146, p. 180 - 233 Full Text Show Details
in tetrachloromethane
slowly dropping Br2 to P in CCl4;;
Koskoski, W.; Fowler, R. D.
Journal of the American Chemical Society, 1942 , vol. 64, p. 850 - 852 Full Text View citing articles Show Details
in neat (no solvent) reaction in CO2 atmosphere;;
Balard, A.-J.
Ann. Chim. Phys., 1826 , vol. 32, p. 337 - 381 Full Text Show Details
in neat (no solvent) reaction with excess P in sealed tube;;
Rose, H.
Ann. Phys. Chem. (2), 1833 , vol. 28, p. 529 - 550 Full Text Show Details
in further solvent(s) dropping Br2 slowly onto small pieces of P using PBr3 as a solvent;;
Balard
Baudrimont, E., Ann. Chim. Phys. (4) 2 (1864) 5/67 Full Text Show Details
in carbon disulfide
mixing solns. of elements in CS2;; distillation;;
Kekule, A.
Liebigs Annalen der Chemie, 1864 , vol. 130, p. 1 - 31 Full Text Show Details
Oddo, G.; Tealdi, M.
Gazzetta Chimica Italiana, 1903 , vol. 33, # II p. 427 - 449 Full Text Show Details
Volhard, J.
Liebigs Annalen der Chemie, 1887 , vol. 242, p. 141 - 163 Full Text Show Details
in benzene
adding Br2 dropwise to P in C4H4S free benzene;; separating liquid from slurry and distilling several times;;
Christomanos, A. C.
Z. Anorg. Chem., 1904 , vol. 41, p. 276 - 290 Full Text Show Details
in neat (no solvent) reaction of Br2 in CO2 (as carrier gas) with dry P;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in neat (no solvent) reaction in CO2 atmosphere;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in neat (no solvent) reaction with excess P in sealed tube;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in further solvent(s) dropping Br2 slowly onto small pieces of P using PBr3 as a solvent;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in carbon disulfide
mixing solns. of elements in CS2;; distillation;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in benzene
adding Br2 dropwise to P in C4H4S free benzene;; separating liquid from slurry and distilling several times;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in tetrachloromethane
slowly dropping Br2 to P in CCl4;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in neat (no solvent) product is digested for several days with P to remove intermediately formed PBr5;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
Pierre, I.
Ann. Chim. Phys., 1847 , vol. 20, p. 5 - 53 Full Text Show Details
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31
Synthesize Find similar Rx-ID: 26385052 Find similar reactions
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937 Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 222, page 509 - 511 Full Text Show Details
in neat (no solvent) partial decomposition on standing;;
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32
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Milobedzki; Krakoviecki
Bulletin de la Societe Chimique de France, 1927 , vol. <4> 41, p. 932 Full Text View citing articles Show Details
33
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Rx-ID: 26454678 Find similar reactions
With carbon dioxide; bromine
100°C;
Boeeseken, J.
Recueil des Travaux Chimiques des Pays-Bas, 1926 , vol. 45, p. 458 - 474 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
With bromine in carbon disulfide
Kekule, A.
Justus Liebigs Annalen der Chemie, 1864 , vol. 130, p. 1 - 31 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
With bromine in benzene
byproducts: C5H5PBr2, PBr5;
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
Christomanos, A. C.
Z. Anorg. Chem., 1904 , vol. 41, p. 276 - 290 Full Text Show Details
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Synthesize Find similar Rx-ID: 7055023 Find similar reactions
Strecker; Grossmann
Chemische Berichte, 1916 , vol. 49, p. 75 Full Text View citing articles Show Details
beim Erwaermen;
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Strecker; Grossmann
Chemische Berichte, 1916 , vol. 49, p. 75 Full Text View citing articles Show Details
Zerfaellt beim Erhitzen;
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B
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36
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Rx-ID: 26184783 Find similar reactions
at higher temp. and reduced pressure;;
Wolf, L.
Ber. Dtsch. Chem. Ges., 1915 , vol. 48, p. 1272 - 1280 Full Text Show Details
at higher temp. and reduced pressure;;
Gmelin Handbook: Hg: MVol.B2, 169, page 755 - 757 Full Text Show Details
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Rx-ID: 26517493 Find similar reactions
in neat (no solvent)
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Wolf, L.
reaction under reduced pressure;;
Ber., 1915 , vol. 48, p. 1272 - 1280 Full Text Show Details
in neat (no solvent) reaction under reduced pressure;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
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Rx-ID: 26368661 Find similar reactions
in neat (no solvent) adding small excess Br2 to P4 while cooling with ice water in vacuum in anhydrous atmosphere;; formed PBr5 dissociates into PBr3 and Br2, which can be easily removed via fractionating;;
Baxter, G. P.; Moore, C. J.; Boylston, A. C.
Journal of the American Chemical Society, 1912 , vol. 34, p. 259 - 274 Full Text View citing articles Show Details
in neat (no solvent) adding small excess Br2 to P4 while cooling with ice water in vacuum in anhydrous atmosphere;; formed PBr5 dissociates into PBr3 and Br2, which can be easily removed via fractionating;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
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Rx-ID: 26368660 Find similar reactions
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in carbon disulfide
Giran, H.
Ann. Chim. Phys., 1903 , vol. 30, p. 203 - 288 Full Text Show Details
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in carbon disulfide
reaction in CS2 soln. even in presence of excess Br2;;
Giran, H.
Ann. Chim. Phys., 1903 , vol. 30, p. 203 - 288 Full Text Show Details
Gmelin Handbook: P: MVol.C, 213, page 489 - 491 Full Text Show Details
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Rx-ID: 26179639 Find similar reactions
With phosphorus trichoride
Matignon, C.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1900 , vol. 130, p. 1393 Full Text Show Details
With PCl3
Gmelin Handbook: Br: MVol., 6.3, page 208 - 213 Full Text Show Details
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Rx-ID: 7442179 Find similar reactions
Moureu
Bulletin de la Societe Chimique de France, 1897 , vol. <3> 17, p. 552 Full Text View citing articles Show Details
o-bromo-camphor;
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42
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in tetrachloromethane
reaction of Br2 with excess P4O;;
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Besson, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1897 , vol. 124, p. 763 - 765 Full Text Show Details
Gmelin Handbook: P: MVol.C, 213, page 489 - 491 Full Text Show Details
in tetrachloromethane
reaction of Br2 with excess P4O;;
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43
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Rx-ID: 26368690 Find similar reactions
in tetrachloromethane
additional formation of either PBr3 or PBr5 depends on ratio of starting materials;;
Besson, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1897 , vol. 124, p. 763 - 765 Full Text Show Details
in tetrachloromethane
Gmelin Handbook: P: MVol.C, 220, page 506 - 508 Full Text Show Details
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Rx-ID: 26455718 Find similar reactions
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Besson, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1896 , vol. 122, p. 814 - 817 Full Text Show Details
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in neat (no solvent)
A
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With bromine
at room temp.;
Schroetter, A.
Annalen der Physik (Weinheim, Germany), 1850 , vol. 81, p. 276 - 298 Full Text Show Details
Volhard, J.
Annalen der Physik (Weinheim, Germany), 1887 , vol. 242, p. 141 - 163 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
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46
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Rx-ID: 26453390 Find similar reactions
in neat (no solvent) reaction at 60°C;;
Geuther, A.; Hergt, O.
Jenaische Z. Naturwiss. (2. Suppl.-H.), 1876 , vol. 10, p. 104 - 106 Full Text Show Details
in neat (no solvent) reaction at 60°C;;
Gmelin Handbook: P: MVol.C, 225, page 516 - 517 Full Text Show Details
A
B
C
D
E
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47
Synthesize Find similar Rx-ID: 26453649 Find similar reactions
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in neat (no solvent) reaction starting at 60°C with evolution of gas;;
Chambon, E.
Jenaische Z. Naturwiss. (Suppl. 2.-H.), 1876 , vol. 10, p. 92 - 96 Full Text Show Details
in neat (no solvent) reaction starting at 60°C with evolution of gas;;
Gmelin Handbook: P: MVol.C, 225, page 516 - 517 Full Text Show Details
48
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Rx-ID: 26359748 Find similar reactions
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in neat (no solvent) formation of small amount PBr3;;
Gustavson, G.
Z. chem., 1870 , vol. 13, p. 521 - 522 Full Text Show Details
in neat (no solvent) formation of small amount PBr3;;
Gmelin Handbook: P: MVol.C, 218, page 501 - 503 Full Text Show Details
49
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Rx-ID: 26125210 Find similar reactions
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Lieben, A.
Justus Liebigs Annalen der Chemie, 1868 , vol. 146, p. 180 - 233 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details
in further solvent(s) in PBr3 soln.;
A
B
C
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50
Synthesize Find similar Rx-ID: 26086772 Find similar reactions
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in neat (no solvent) heating an excess of H3PO3 with Br2 in a sealed tube at 100 °C;;
Gustavson, G.
Bull. Acad. Imp. Sci. St. - Petersbourg, 1867 , vol. 11, p. 299 - 301 Full Text Show Details
Gustavson, G.
J. prf. Ch., 1867 , vol. 101, p. 123 - 125 Full Text Show Details
in neat (no solvent) heating an excess of H3PO3 with Br2 in a sealed tube at 100 °C;;
Gmelin Handbook: P: MVol.C, 57, page 122 - 124 Full Text Show Details
51
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Rx-ID: 26487912 Find similar reactions
With hydrogen sulfide in neat (no solvent) byproducts: HBr; react. of dry H2S with PBr5;;
Baudrimont, E.
Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67 Full Text Show Details
Gmelin Handbook: S: MVol.B1, 30, page 67 - 69 Full Text Show Details
52
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Rx-ID: 26535849 Find similar reactions
in neat (no solvent) passing CO2 over PBr5 at 100°C on a water bath;;
Baudrimont, E.
Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67 Full Text Show Details
in neat (no solvent) heating on water bath in stream of CO2;;
Baudrimont, E.
Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67 Full Text Show Details
in neat (no solvent) passing CO2 over PBr5 at 100°C on a water bath;;
Gmelin Handbook: P: MVol.C, 214, page 491 - 494 Full Text Show Details
in neat (no solvent) heating on water bath in stream of CO2;;
Gmelin Handbook: P: MVol.C, 218, page 501 - 503 Full Text Show Details
A
B
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53
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Rx-ID: 26366640 Find similar reactions
Gladstone, J.
Journal fuer Praktische Chemie (Leipzig), 1850 , vol. 49, p. 49 - 49 Full Text Show Details
Gladstone, J.
Philosophical Magazine (1798-1977), 1849 , vol. 35, p. 345 - 345 Full Text Show Details
Gmelin Handbook: I: MVol.1, 55, page 182 - 183 Full Text Show Details
in not given
A
B
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54
Synthesize Find similar Rx-ID: 26366885 Find similar reactions
55
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in neat (no solvent) formation of red liquid containing PBr3 and IBr5;;
Gladstone, J. H.
Journal fuer Praktische Chemie (Leipzig), 1850 , vol. 49, p. 40 - 51 Full Text Show Details
Gladstone, J. H.
Philosophical Magazine (1798-1977), 1849 , p. 345 - 355 Full Text Show Details
in neat (no solvent) formation of red liquid containing PBr3 and IBr5;;
Gmelin Handbook: P: MVol.C, 218, page 501 - 503 Full Text Show Details
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Rx-ID: 26429834 Find similar reactions
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in neat (no solvent) reaction at ambient temperature;;
Gladstone, J. H.
Journal fuer Praktische Chemie (Leipzig), 1850 , vol. 49, p. 40 - 51 Full Text Show Details
Gladstone, J. H.
Philosophical Magazine (1798-1977), 1849 , p. 345 - 355 Full Text Show Details
in neat (no solvent) reaction at ambient temperature;;
Gmelin Handbook: P: MVol.C, 218, page 501 - 503 Full Text Show Details
56
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Rx-ID: 26494404 Find similar reactions
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in neat (no solvent)
Gladstone, J. H.
Journal fuer Praktische Chemie (Leipzig), 1850 , vol. 49, p. 40 - 51 Full Text Show Details
in neat (no solvent)
Gmelin Handbook: P: MVol.C, 218, page 501 - 503 Full Text Show Details
57
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Rx-ID: 26125279 Find similar reactions
in gas by distn. over HgBr2;
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Gladstone, J. H.
Philosophical Magazine (1798-1977), 1849 , vol. 35, p. 345 - 355 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.2.3, page 310 - 316 Full Text Show Details
58
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Rx-ID: 26368766 Find similar reactions
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in neat (no solvent)
Gladstone, J. H.
Philosophical Magazine (1798-1977), 1849 , vol. 35, p. 345 - 355 Full Text Show Details
in neat (no solvent)
Gmelin Handbook: P: MVol.C, 228, page 522 - 524 Full Text Show Details
59
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Rx-ID: 26483987 Find similar reactions
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Gladstone, J. H.
Philosophical Magazine (1798-1977), 1849 , vol. 35, p. 345 - 355 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details
Berzelius, J. J.
Lehrbuch der Chemie, 5. Ed., Vol. 1, Dresden-Leipzig 1843, p. 249 Full Text Show Details
A
B
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60
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Rx-ID: 26454679 Find similar reactions
With bromine
in CO2 atmosphere;
Balard
Ann. Chim. Phys., 1826 , vol. 32, p. 337 - 381 Full Text Show Details
Balard
Annalen der Physik (Weinheim, Germany), 1826 , vol. 8, p. 461 - 473 Full Text Show Details
Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285 Full Text Show Details
Berzelius, J. J.
Lehrbuch der Chemie, 5.Ed., Vol. 1, Dresden-Leipzig 1843, p. 249 Full Text Show Details
61
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Rx-ID: 26125231 Find similar reactions
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Gmelin Handbook: P: MVol.B, 3.4.2.3, page 310 - 316 Full Text Show Details
Loewig, C.
Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, p. 51 Full Text Show Details
in gas by distn. over Hg2Br2;
62
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Rx-ID: 26401658 Find similar reactions
only a few product;
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Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details
Loewig, C.
Das Brom und seine chemischen Verhaeltnisse, Heidelberg 1829, p. 71 Full Text Show Details