Phosphorus trichloride [Phosphorus(III) chloride; PCl3] by Asch

Query Query Cl

1. Query

Results

Date

251 reactions in Reaxys

2017-10-13 07h:34m:22s (EST)

251 reactions in Reaxys

2017-10-13 07h:50m:21s (EST)

Cl P Cl

Search as: As drawn, No salts, No mixtures, No isotopes, No charges, No radicals 2. Query

(1. Query) AND itemno in (1)

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Rx-ID: 37410576 View in Reaxys 1/251 Yield

Conditions & References T= 70 °C , p= 0.01 - 0.1Torr Gazizov; Khairullin; Karimova; Russian Journal of General Chemistry; vol. 83; nb. 12; (2013); p. 2281 - 2292; Zh. Obshch. Khim.; vol. 83; nb. 12; (2013); p. 1996 - 2007,12 View in Reaxys Cl

Rx-ID: 24393205 View in Reaxys 2/251 Yield 25%

Conditions & References XIV : EXAMPLE XIV EXAMPLE XIV 127.2 parts of N-cyclohexylformamide and 81 parts of phosphorous acid were reacted with 137.3 parts of phosphorus trichloride at 70°C, and maintained for 5 hours at this temperature. The reaction product was dissolved in water, treated with acetone and the precipitate separated. A 25percent yield of N-cyclohexyl-1-aminomethane-1,1-diphosphonic acid, based on PCl3, was obtained. Patent; Henkel and Cie G.m.b.H.; US3979385; (1976); (A1) English View in Reaxys 5 : EXAMPLES 5) The mixture of 92.2 g (=0.3 mol) of 2,4-di-tert-butylphenyl dichlorophosphite and 0.1 g (=0.9 mmol) of 4-dimethylaminopyridine was stirred for 6 hours at 190° C. while passing through a gentle stream of nitrogen. In the course of this, PCl3 formed was carried off. The mixture was allowed to cool, the distillative removal of residual starting material was dispensed with and an 31 PNMR spectrum was prepared. Patent; Hoechst AG; US5210260; (1993); (A1) English View in Reaxys 1.C : C. C. Phosphosilicates Phosphosilicates prepared by reacting SiCl4 with 0.1 to 5 equivalents of PCl3 were prepared using the following ratios of PCl3 (2M in CH2 Cl2; Aldrich Chemical Co.) and SiCl4 (Petrarch Systems): Patent; Becton Dickinson and Company; US5503816; (1996); (A1) English View in Reaxys Examples of dehydrating agents useful in this reaction are as follows: (i) mixtures of copper sulfate and acetic anhydride; (ii) phosphorous oxychloride; (iii) phosphorous trichloride; (iv) phosphorous pentoxide; (vi) acetyl chloride. Patent; International Flavors and Fragrances Inc.; US4985402; (1991); (A1) English View in Reaxys 5 : (preparation of di-n-butylchlorophosphine) EXAMPLE 5 (preparation of di-n-butylchlorophosphine) 148 g (1 mol) di-n-butylphosphine was dropped at a maximum reaction temperature of 30° C. into a suspension of 232 g (1.1 mol) PCl5 in 500 ml toluene. HCl and PCl3 formed during the reaction were removed under a vacuum of 130 mbar and condensed in a cooling trap.

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Patent; Weferling; Norbert; Klose; Werner; US4752648; (1988); (A1) English View in Reaxys 19.B : B. B. Propylene, PCl3 and Iodine Catalyst In a 316 stainless steel autoclave were placed 45 grams (1.07 moles) of propylene, 135 (0.985 moles) of PCl3 and 0.1 grams of iodine as catalyst. The mixture was reacted for 12 hours at 200°C. Analysis of the products by 31 P-nmr showed that 98percent of the phosphorus was unreacted PCl3. Patent; Stauffer Chemical Company; US3976690; (1976); (A1) English View in Reaxys 19.C : C. C. Isobutene, PCl3 and Iodine Catalyst In a 316 stainless steel autoclave were placed 47 grams (0.84 moles) of isobutene, 101.6 grams (0.74 moles) of PCl3, and 1 gram of iodine. The mixture of reactants was reacted for 12 hours at 210°C. While 46percent (0.39 moles) of the charged isobutene was consumed in the reaction, no identifiable level of bis-dihalophosphine type product was formed. The reaction formed 16.65 grams (0.18 moles) of tert-butyl chloride and 25.8 grams (0.1 moles) of butenephosphonous dichloride. As is shown in Example 15 in a similar experiment using elemental phosphorus, a yield of 14percent of crude distilled product based on olefin charged is obtained. Patent; Stauffer Chemical Company; US3976690; (1976); (A1) English View in Reaxys P P PP

white

P P P Br P

P P P Cl P

P Br Br P P BrP P P P

P Cl Br

Rx-ID: 26997754 View in Reaxys 3/251 Yield

Conditions & References With trimethylstannyl chloride in carbon disulfide, reaction of P4 with Br2 in CS2, followed by treatment with C(CH3)3SnCl; further products: Cl2P2Br2, ClBrP2ClBr, P2Br4, PBr3, PClBr2, PCl2Br; not isolated, identified by 31PNMR spectroscopy Tattershall, Bruce W.; Kendall, Nigel L.; Polyhedron; vol. 13; (1994); p. 1517 - 1522 ; (from Gmelin) View in Reaxys

P P PP

Cl I

white

P ClCl

P I Cl

P Cl

Cl P

P I I

Rx-ID: 27003269 View in Reaxys 4/251 Yield

Conditions & References in carbon disulfide, under N2, dropwise addn. of a Br2/CS2 soln. to a vigorously stirred soln. of P4/CS2 reaction of P4 with ICl (molar ratio (1.75:1.5), further Products: ClIP2ClI, ClIP2I2, P2I4, P7I3; not isolated, identified by 31PNMR spectroscopy Tattershall, Bruce W.; Kendall, Nigel L.; Polyhedron; vol. 13; (1994); p. 1517 - 1522 ; (from Gmelin) View in Reaxys

O P O

P+ O

Cl Cl –

Rx-ID: 1564216 View in Reaxys 5/251

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Yield

Conditions & References With trichloromethane sulphenyl chloride in dichloromethane, Time= 1h, T= 0 °C , other sulfenyl chlorides Gloede, J.; Lutze, G.; Phosphorus, Sulfur and Silicon and the Related Elements; vol. 78; nb. 1-4; (1993); p. 265 270 View in Reaxys Cl

S Cl

Rx-ID: 26125201 View in Reaxys 6/251 Yield

Conditions & References in acetonitrile Woolf, Alfred A.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); nb. 12; (1991); p. 3325 - 3330 ; (from Gmelin) View in Reaxys Cl

Cl Cl

PCl Cl

Cl Cl

P+ ClCl

Cl B

B– ClCl

Rx-ID: 26486094 View in Reaxys 7/251 Yield

Conditions & References With HCl (liquid) in further solvent(s), reaction of a mixt. of PCl5 and B2Cl4 (2:1) in liquid HCl at -196°C; (11)B and (31)P NMR at 0°C Haubold, W.; Kraatz, U.; Einholz, W.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 592; (1991); p. 35 - 41 ; (from Gmelin) View in Reaxys Cl Cl

PCl Cl

Cl 2Sn

Rx-ID: 26139875 View in Reaxys 8/251 Yield

Conditions & References in neat (no solvent), vaporization of Sn metal (1750 K), reaction with 1E-4 Torr PCl5; chemiluminescence monitoring, time-of-flight measurements Wang, J.H.; Cheong, B.S.; Fang, C.C.; Parson, J.M.; Journal of Chemical Physics; vol. 93; nb. 11; (1990); p. 7830 - 7835 ; (from Gmelin) View in Reaxys Cl Cl

PCl Cl

Cl 2Ge

Rx-ID: 26432940 View in Reaxys 9/251 Yield

Conditions & References in neat (no solvent), vaporization of Ge (1850 K), reaction with 1E-4 Torr PCl5; chemiluminescence monitoring, timeof-flight measurements Wang, J.H.; Cheong, B.S.; Fang, C.C.; Parson, J.M.; Journal of Chemical Physics; vol. 93; nb. 11; (1990); p. 7830 - 7835 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl Cl

(v2)

Cl Cl

Rx-ID: 26434204 View in Reaxys 10/251

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Yield

Conditions & References in neat (no solvent), vaporization of Si (2000 K), reaction with 1E-4 Torr PCl5; chemiluminescence monitoring, timeof-flight measurements Wang, J.H.; Cheong, B.S.; Fang, C.C.; Parson, J.M.; Journal of Chemical Physics; vol. 93; nb. 11; (1990); p. 7830 - 7835 ; (from Gmelin) View in Reaxys

S Cl

P Cl

Cl Cl

Rx-ID: 26475677 View in Reaxys 11/251 Yield

Conditions & References in neat (no solvent), Pure PSCl3 is heated in a sealed tube at 150°C for 64 h.; Formed PCl3 is detected by the NMR spectrum. Demarcq, Michel C.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1990); p. 35 - 40 ; (from Gmelin) View in Reaxys Cl

H 2P

PH4+

PH2

Rx-ID: 26480183 View in Reaxys 12/251 Yield

Conditions & References With HCl in carbon disulfide, P2H4, CS2 and HCl condensed into a quartz NMR tube at 77°K, slowly warmed to 205°K; observed by P(31)-NMR Minkwitz, Rolf; Liedtke, Andreas; Inorganic Chemistry; vol. 28; (1989); p. 4238 - 4242 ; (from Gmelin) View in Reaxys Cl

NbTe 2

PCl Cl

(v5)

Cl NbCl Cl

Te ClCl

P Cl

Rx-ID: 26364455 View in Reaxys 13/251 Yield

Conditions & References

82 %

in neat (no solvent), molar ratio niobium ditelluride/PCl5 1/8; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, the residue dried in a vac.; NMR, mass spectra Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 32; (1987); p. 1049 - 1051; Zhurnal Neorganicheskoi Khimii; vol. 32; (1987); p. 1769 - 1771 ; (from Gmelin) View in Reaxys

>99

in neat (no solvent), molar ratio niobium ditelluride/PCl5 1/4; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, the residue dried in a vac.; NMR, mass spectra Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 32; (1987); p. 1049 - 1051; Zhurnal Neorganicheskoi Khimii; vol. 32; (1987); p. 1769 - 1771 ; (from Gmelin) View in Reaxys Cl

MoTe 2

PCl Cl

Cl N

(v4)

Mo Cl ClCl

Cl Te Cl ClCl

Rx-ID: 26486147 View in Reaxys 14/251 Yield 70 %, 98 %, 70 %

Conditions & References With acetonitrile in neat (no solvent), molar ratio molybdenum ditelluride/PCl5 1/8; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot acetonitrile, the residue dried in a vac.; NMR, mass spectra

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Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 32; (1987); p. 1049 - 1051; Zhurnal Neorganicheskoi Khimii; vol. 32; (1987); p. 1769 - 1771 ; (from Gmelin) View in Reaxys Cl PCl Cl

MoTe 2

Cl Cl 2.17MoTe 0.51

Te ClCl

Rx-ID: 26486148 View in Reaxys 15/251 Yield

Conditions & References

95 %, 52 %, >99

in neat (no solvent), molar ratio molybdenum ditelluride/PCl5 1/4; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, the residue dried in a vac.; NMR, mass spectra Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 32; (1987); p. 1049 - 1051; Zhurnal Neorganicheskoi Khimii; vol. 32; (1987); p. 1769 - 1771 ; (from Gmelin) View in Reaxys Cl

Te 2W

PCl Cl

(v4)

W ClCl

Te ClCl

Rx-ID: 26602850 View in Reaxys 16/251 Yield 78 %, 99 %, 87 %

Conditions & References With acetonitrile in neat (no solvent), molar ratio tungsten ditelluride/PCl5 1/8; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot acetonitrile, soln. cooled to -5°C; the residue dried in a vac.; NMR, mass, IR and Raman spectra Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 32; (1987); p. 1049 - 1051; Zhurnal Neorganicheskoi Khimii; vol. 32; (1987); p. 1769 - 1771 ; (from Gmelin) View in Reaxys

>99, 58 %, 45 %

With acetonitrile in neat (no solvent), molar ratio tungsten ditelluride/PCl5 1/4; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot acetonitrile, soln. cooled to -5°C; the residue dried in a vac.; NMR, mass, IR and Raman spectra Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 32; (1987); p. 1049 - 1051; Zhurnal Neorganicheskoi Khimii; vol. 32; (1987); p. 1769 - 1771 ; (from Gmelin) View in Reaxys

Re 6Te 15

PCl Cl Cl

Cl Cl Re (v5)

O Cl

P Cl Cl

Te ClCl

Rx-ID: 26811776 View in Reaxys 17/251 Yield 57 %, 29 %

Conditions & References in neat (no solvent), molar ratio rhenium telluride/PCl5 1/8; heated in evacuated sealed ampoules for 6 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, soln. cooled, resulting crystals filtered off, washed (CH3CN), dried in a vac.; elem.anal., NMR, mass spectra Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 32; (1987); p. 1049 - 1051; Zhurnal Neorganicheskoi Khimii; vol. 32; (1987); p. 1769 - 1771 ; (from Gmelin) View in Reaxys Cl

Re 6Te 15

PCl Cl Cl

Cl Cl 1.47ReTe 0.51

Te ClCl

Rx-ID: 26811777 View in Reaxys 18/251

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Yield

Conditions & References

>99, 98 %

in neat (no solvent), molar ratio rhenium telluride/PCl5 1/4; heated in evacuated sealed ampoules for 6 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, the residue dried in a vac.; NMR, mass spectra Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 32; (1987); p. 1049 - 1051; Zhurnal Neorganicheskoi Khimii; vol. 32; (1987); p. 1769 - 1771 ; (from Gmelin) View in Reaxys

Cl P

Rx-ID: 26170081 View in Reaxys 19/251 Yield

Conditions & References in neat (no solvent), react. of gaseous Cl2 with PH3; Verrier, U. J. J. Le; Ann. Chim. Phys.; vol. 60; (1835); p. 174 - 194 View in Reaxys Verrier, U. J. J. Le; Liebigs Annalen der Chemie; vol. 18; (1836); p. 333 - 338 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of gaseous Cl2 with PH3; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys in neat (no solvent, gas phase), Kinetics, byproducts: HCl; under static conditions and in a jet at temps. from 196 to 585 K, pressure from 0.1 to 10 mm Hg; absorption spectroscopy Azatyan; Gagarin; Zakhar'in; Kalkanov; Kolbanovskii; Kinetics and Catalysis; vol. 26; nb. 1 pt 2; (1985); p. 191 194 ; (from Gmelin) View in Reaxys

Cl Cl

P S

S O

S P

S Cl

P Cl

Rx-ID: 26472608 View in Reaxys 20/251 Yield

Conditions & References in carbon disulfide, soln. of SO2Cl2 added at room temp. to P4S3 soln. over 2 h with stirring, standed for 44 h; not isolated, detected by IR Musa, Faleh H.; Tattershall, Bruce W.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1984); p. 1517 - 1520 ; (from Gmelin) View in Reaxys S

P S P

S P

P Cl

P4S7

Rx-ID: 26486281 View in Reaxys 21/251 Yield

Conditions & References in neat (no solvent), Cl2 condenced onto P4S3 at -196°C under vac., warmed slowly; extd. (CS2), not isolated, detected by IR, MAS Musa, Faleh H.; Tattershall, Bruce W.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1984); p. 1517 - 1520 ; (from Gmelin) View in Reaxys

S Cl

P Cl

Ag2S

Cl AgCl

Rx-ID: 27023134 View in Reaxys 22/251

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Yield

Conditions & References in gas, 1100 K; react. is followed by IR and Raman-spectrometry Schnoeckel, H.; Lakenbrink, M.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 507; (1983); p. 70 76 ; (from Gmelin) View in Reaxys

N F Cl

F P– Cl

F P– F F

P– OC-6 N F

P–

N F

Rx-ID: 27103533 View in Reaxys 23/251 Yield

Conditions & References in dichloromethane, not isolated, detd. by NMR spectroscopy Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Chemical Communications; nb. 19; (1983); p. 1089 - 1090 ; (from Gmelin) View in Reaxys Cl

Cl Cl

P+ ClCl

I–

N+

Al– ClCl

Rx-ID: 26090143 View in Reaxys 24/251 Yield

Conditions & References

45 %

in neat (no solvent), argon atmosphere; org. compd. addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen) Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin) View in Reaxys Cl

Cl Cl

P+ ClCl

BrK

Al– ClCl

Rx-ID: 26097343 View in Reaxys 25/251 Yield 0%

Conditions & References in neat (no solvent), argon atmosphere; KBr addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin) View in Reaxys With triethylamine in neat (no solvent), argon atmosphere; KBr and (C2H5)3N addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen) Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin) View in Reaxys Cl

O Cl

Al– ClCl

P+ ClCl

Cl IK

Rx-ID: 26102363 View in Reaxys 26/251

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Yield

Conditions & References in neat (no solvent), argon atmosphere; KI and org. compd. addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen) Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin) View in Reaxys Cl

Cl Cl

P+ ClCl

Cl –

N+

Cl IK

Al– ClCl

Rx-ID: 26102377 View in Reaxys 27/251 Yield

Conditions & References

25 %

in neat (no solvent), argon atmosphere; KI and org. compd. addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen) Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin) View in Reaxys Cl

Cl Cl

P+ ClCl

Cl IK

Al– ClCl

Rx-ID: 26102389 View in Reaxys 28/251 Yield

Conditions & References

in neat (no solvent), argon atmosphere; KI addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin) View in Reaxys With triethylamine in neat (no solvent), argon atmosphere; KI and (C2H5)3N addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen) Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin) View in Reaxys Cl

Cl Cl

P+ ClCl

Br–

Cl N+

Al– ClCl

Rx-ID: 26102390 View in Reaxys 29/251 Yield 67 %

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Cl Cl Cl

N+

P+ ClCl

Cl –

Al– ClCl

Rx-ID: 26102391 View in Reaxys 30/251 Yield

Conditions & References

81 %

Cl Cl

P+ ClCl

I–

N+

Al– ClCl

Rx-ID: 26105567 View in Reaxys 31/251 Yield

Conditions & References

76-80

Cl Cl

P+ ClCl

Br–

N+

Al– ClCl

Rx-ID: 26153811 View in Reaxys 32/251 Yield

Conditions & References

76-80

Cl Cl

N+

P+ ClCl

Cl Cl –

Al– ClCl

Rx-ID: 26153812 View in Reaxys 33/251 Yield

Conditions & References in neat (no solvent), argon atmosphere; org. compd. addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen) Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin) View in Reaxys

N+

Cl –

Br PBr Br

P ClCl

P BrCl

Cl P

Rx-ID: 26453860 View in Reaxys 34/251

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Yield

Conditions & References in neat (no solvent), byproducts: Et4NBr; argon atmosphere; mixing org. compd. and PBr5 (cooling), mixt. leaving for 1 h at room temp., heating (vac., 80°C, 2 h); volatile products collection (trap cooled with liq. nitrogen) Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.; Journal of General Chemistry USSR (English Translation); vol. 52; (1982); p. 1160 - 1163; Zhurnal Obshchei Khimii; vol. 52; (1982); p. 1318 - 1322 ; (from Gmelin) View in Reaxys

Cl (v4)

P C– N (v4) Cl

Cl –

N+

Cl N Cl – P Cl OC-6 N Cl

Cl Cl P– Cl OC-6 N Cl

Br Br

Cl (v4) N – Br P C Br (v6)

Cl – N Cl P C Cl (v4) Cl (v6) Cl

Cl N

Rx-ID: 27056210 View in Reaxys 35/251 Yield

Conditions & References

in not given, under N2, oxidn. of PCl2(CN)2(1-) with Br2 in presence of NEt4Cl Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys

Cl N

(v4)

P C– N (v4)

N+

Cl N – C P Br (v4) Cl OC-6 (v6)

Cl Br N

N – P C(v4) N (v6)

Cl N – C P Cl (v4) Cl OC-6 (v6)

Rx-ID: 27056220 View in Reaxys 36/251 Yield

Conditions & References in dichloromethane, under N2, react. of (NEt4)(PCl(CN)3) with Br2 in CH2Cl2 in presence of excess of NEt4Cl over 2 d; further products; monitored by (31)P NMR spectra Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys

-1

Ag+ N

S–

N+

Cl Cl PCl Cl Cl (v6)

Cl N – PCl (v3)Cl (v6)Cl

Rx-ID: 27057331 View in Reaxys 37/251 Yield

Conditions & References in dichloromethane, stoich. amt. of AgNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2 Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys

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-1

Ag+

S–

N+

Cl Cl PCl Cl Cl (v6)

N – PCl N OC-6 (v3)Cl (v6) Cl

Cl S

Rx-ID: 27057332 View in Reaxys 38/251 Yield

-1

Ag+ N

S–

N+

Cl Cl PCl Cl Cl (v6)

S N

–N PCl N OC-6 (v3) Cl (v6)

Rx-ID: 27057333 View in Reaxys 39/251 Yield

-1

Ag+ N

S–

N+

(v3) – N

Cl Cl PCl Cl Cl (v6)

S S

N P N ClOC-6 (v6) Cl

Cl S

Rx-ID: 27057334 View in Reaxys 40/251 Yield

-1

Ag+ N

S–

N+

Cl Cl PCl Cl Cl (v6)

(v3) – N

S S

N N P(v6)N Cl

Cl S

Rx-ID: 27057335 View in Reaxys 41/251 Yield

Conditions & References in dichloromethane, stoich. amt. of AgNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2

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Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys S

Cl N – PCl (v3)Cl (v6)Cl

P Cl

Cl Cl

Rx-ID: 27086046 View in Reaxys 42/251 Yield

Conditions & References in not given, decompd. rapidly Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys

N – PCl

N OC-6 (v3)Cl (v6)

P Cl

Cl Cl

Rx-ID: 27086052 View in Reaxys 43/251 Yield

S N

S S

–N PCl N OC-6 (v3) Cl (v6)

P Cl

Cl Cl

Rx-ID: 27086055 View in Reaxys 44/251 Yield

(v3) – N

S S

N P N ClOC-6 (v6) Cl

P Cl

Cl Cl

Rx-ID: 27086064 View in Reaxys 45/251 Yield

(v3) – N

N S

S S

N N P(v6)N Cl

S Cl

P Cl

Cl Cl

Rx-ID: 27086071 View in Reaxys 46/251 Yield

Conditions & References in not given, decompd. rapidly

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Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys

-1

N –

NH +4

N+

Cl Cl PCl Cl Cl (v6)

Cl N – PCl (v3)Cl (v6)Cl

Rx-ID: 27104527 View in Reaxys 47/251 Yield

Conditions & References in dichloromethane, stoich. amt. of NH4NCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2 Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys

-1

N –S

NH +4

N+

Cl Cl PCl Cl Cl (v6)

N – PCl N

OC-6 (v3)Cl (v6) Cl

Cl S

Rx-ID: 27104528 View in Reaxys 48/251 Yield

-1

N –S

NH +4

Cl Cl PCl Cl Cl (v6)

S N

–N PCl N OC-6 (v3) Cl (v6)

P Cl

Rx-ID: 27104529 View in Reaxys 49/251 Yield

-1

N –S

NH +4

N+

Cl Cl PCl Cl Cl (v6)

(v3) – N

S S

N P N ClOC-6 (v6) Cl

Cl S

Rx-ID: 27104530 View in Reaxys 50/251

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Yield

S S

-1

N –

NH +4

N+

(v3) – N

Cl Cl PCl Cl Cl (v6)

N N P(v6)N Cl

Rx-ID: 27104531 View in Reaxys 51/251 Yield

-1

S N+

–N PCl N OC-6 (v3) Cl (v6)

Cl Cl PCl Cl Cl (v6)

Rx-ID: 27106253 View in Reaxys 52/251 Yield

Conditions & References in not given, P(NCS)3 added to concd. soln. of (N(n-C5H11)4)(PCl6) Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys

-1 –S

Li+

N+

Cl Cl PCl Cl Cl (v6)

Cl N – PCl (v3)Cl (v6)Cl

Rx-ID: 27110212 View in Reaxys 53/251 Yield

Conditions & References in dichloromethane, stoich. amt. of LiNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2 Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys

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-1 –S

Li+

N+

Cl Cl PCl Cl Cl (v6)

N – PCl N OC-6 (v3)Cl (v6) Cl

Cl S

Rx-ID: 27110213 View in Reaxys 54/251 Yield

-1 –S

Li+

N+

Cl Cl PCl Cl Cl (v6)

S N

–N PCl N OC-6 (v3) Cl (v6)

P Cl

Rx-ID: 27110214 View in Reaxys 55/251 Yield

-1 –S

Li+

N+

(v3) – N

Cl Cl PCl Cl Cl (v6)

S S

N P N ClOC-6 (v6) Cl

Cl S

Rx-ID: 27110215 View in Reaxys 56/251 Yield

-1 –S

Li+

N+

Cl Cl PCl Cl Cl (v6)

(v3) – N

S S

N N P(v6)N Cl

Cl S

Rx-ID: 27110216 View in Reaxys 57/251 Yield

Conditions & References in dichloromethane, stoich. amt. of LiNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2

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Dillon, Keith B.; Platt, Andrew W. G.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1982); p. 1199 - 1204 ; (from Gmelin) View in Reaxys Cl N Cl

P Cl Cl

H 2N

Cl P Cl

Rx-ID: 27059188 View in Reaxys 58/251 Yield

Conditions & References

37.5 %

4 h; 1,2-dichloroethane added, filtration, solvent and PCl3 distd. off from filtrate, distn. in Vigreux-column; elem. anal. Fluck, E.; Hoesle, R.; Zischka, A.-K.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 474; (1981); p. 105 - 112 ; (from Gmelin) View in Reaxys

Cl red

Rx-ID: 26182464 View in Reaxys 59/251 Yield 94 %

Conditions & References With phosphorus trichoride in neat (no solvent), passing dry Cl2 (dryed over H2SO4) in a suspension of red P (dryed over H2SO4) in PCl3; use of a glass apparatus with reflux condenser and P2O5 drying tube; boiling PCl3 during the rect. to prevent formation of PCl4; vol. P: MVol.C; 179, page 412 - 414 View in Reaxys Forbes, M. C.; Roswell, C. A.; Maxson, R. N.; Fernelius, W. C., Inorganic Syntheses, Bd. 2, New York-London 1946, S. 145/7 ; (from Gmelin) View in Reaxys in neat (no solvent), pptn. of a layer of P4 on the wall on heating red P in an atmosphere of CO2, then passing in Cl2; vol. P: MVol.C; 179, page 412 - 414 View in Reaxys Rekshinskij, V.; Tr. Inst. chistych chim. Reaktivav Nr. 3 (1924) 46/49; C. I; (1925); p. 477 ; (from Gmelin) View in Reaxys direct synthesis in null-manometer, according to: O. G. Polyachenok, Author's Abstract of Doctoral Thesis, Leningrad, 1972 Dudchik, G. P.; Polyachenok, O. G.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 24; (1979); p. 360 - 362; Zhurnal Neorganicheskoi Khimii; vol. 24; (1979); p. 646 - 650 ; (from Gmelin) View in Reaxys With phosphorus trichoride in neat (no solvent), pouring liquid PCl3 upon red P; passing gaseous Cl2 in the liquid; apparatus described; Vanshejdt, A. A.; Tolstopjatov, V. M.; Zh. russk. fiz. chim. Obshch. Chast' chim.; vol. 52; (1920); p. 251 - 269; C. III; (1923); p. 723 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys

>99

With phosphorus trichoride in neat (no solvent), pouring liquid PCl3 upon red P; passing gaseous Cl2 in the liquid; use of a reflux condenser;; quantitative react.; Graebe, C.; Ber. dtsch. chem. Ges.; vol. 34; (1901); p. 645 - 652 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys in neat (no solvent), heating red P in dry Cl2;

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Thorpe, T. E.; Ber. dtsch. chem. Ges.; vol. 8; (1875); p. 326 - 332 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of red P with Cl2 at ambient temp.; Schroetter, A.; Sitz.-Ber. Akad. Wiss. (wien); vol. 1; (1848); p. 130 - 137 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of red P with Cl2 at ambient temp.; vol. P: MVol.C; 159, page 363 - 366 ; (from Gmelin) View in Reaxys Cl

Cl Ga Cl

PCl Cl

Cl Cl

Rx-ID: 26256948 View in Reaxys 60/251 Yield

Conditions & References complex dissociation in temp. range 100-500°C; tensimetric equilibrium monitoring Sevast'yanova, T. N.; Tarasova, A. Sh.; Suvorov, A. V.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 24; (1979); p. 1288 - 1290; Zhurnal Neorganicheskoi Khimii; vol. 24; (1979); p. 2322 - 2326 ; (from Gmelin) View in Reaxys

Cl (v3)

(v3)

(v4) (v6)

Cl P Cl

O (v3)

(v3)

(v5)

(v3)

(v3) (v3) (v3)

(v3)

Rx-ID: 26388068 View in Reaxys 61/251 Yield

Conditions & References in solid matrix, Irradiation (UV/VIS); Ar-matrix, 10 K, 229 - 366 nm; not isolated, detd. by IR spectroscopy Boxhoorn, G.; Stufkens, D. J.; Oskam, A.; Inorganica Chimica Acta; vol. 33; (1979); p. 215 - 226 ; (from Gmelin) View in Reaxys Cl

oil (2-isobornyl-4-chloroanisole)

Rx-ID: 25287686 View in Reaxys 62/251 Yield

Conditions & References 11 : 2-isobornyl-4-chlorophenol EXAMPLE 11 STR12 2-isobornyl-4-chlorophenol 80g 2-isobornyl anisole (0.33 mole) and 76g phosphorus pentachloride (0.36 mole) are heated at 120° C for 2 hours. The PCl3 formed is then distilled under vacuum and the reaction mixture is poured into iced water. The mixture is extracted with ether, the organic phase is washed with water until neutral, dried on sodium sulphate and the ether is evaporated. 90g of a red oil (2-isobornyl-4-chloroanisole) are obtained. Patent; Societe Anonyme dite: MAR-PHA, Societe d'Etude et d'Exploitation de Marques; US4067899; (1978); (A1) English View in Reaxys

Cl Cl

PCl Cl Cl

Rx-ID: 26167817 View in Reaxys 63/251

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Yield

Conditions & References in neat (no solvent), dissociation investigated at 166-358 °C; Holland, C.; Zeitschrift fuer Elektrochemie; vol. 18; (1912); p. 234 - 236 View in Reaxys Nernst, W.; Zeitschrift fuer Elektrochemie; vol. 22; (1916); p. 37 - 38 ; (from Gmelin) View in Reaxys in neat (no solvent), complete dissociation at 300 °C; reversible reaction; Patent; Veron, M.; Soc. Francaise des Constructions Babcock & Wilcox; FR1184469; (1959); C.; (1960); p. 6948 ; (from Gmelin) View in Reaxys in neat (no solvent), decompn. on heating forming Cl2 and PCl3; evolution of yellowish vapors; Sainte-Claire Deville, H.; Liebigs Annalen der Chemie; vol. 140; (1866); p. 166 - 171 View in Reaxys Sainte-Claire Deville, H.; Philosophical Magazine (1798-1977); vol. 32; (1966); p. 387 - 387 ; (from Gmelin) View in Reaxys in neat (no solvent), dissociation at 90-167 °C; dissociation pressure given; Smith, A.; Calvert, R. P.; Journal of the American Chemical Society; vol. 36; (1914); p. 1363 - 1382 View in Reaxys Smith, A.; Lobard, R. H.; Journal of the American Chemical Society; vol. 37; (1915); p. 2055 - 2062 ; (from Gmelin) View in Reaxys in neat (no solvent), dissociation; Bevillard, P.; Bulletin de la Societe Chimique de France; (1954); p. D 40 - D 48 View in Reaxys Bevillard, P.; Bulletin de la Societe Chimique de France; (1954); p. D 55 - D 79 ; (from Gmelin) View in Reaxys in neat (no solvent), evolution of Cl2 starting at 157-158 °C; Fireman, P.; Portner, E. G.; Journal of Physical Chemistry; vol. 8; (1903); p. 500 - 504 ; (from Gmelin) View in Reaxys in neat (no solvent), decompn. on heating forming Cl2 and PCl3; evolution of yellowish vapors; vol. P: MVol.C; 191, page 439 - 441 View in Reaxys Sainte-Claire Deville, H.; C. r. Acad. Sci. (Paris); vol. 62; (1866); p. 1157 - 1160 ; (from Gmelin) View in Reaxys in neat (no solvent), complete dissociation at 300 °C; reversible reaction; vol. P: MVol.C; 191, page 439 - 441 ; (from Gmelin) View in Reaxys in neat (no solvent), dissociation at 100.5-229.1 °C; dissociation pressure given; Fischer, W.; Juebermann, O.; Z. Anorg. Chem.; vol. 235; (1938); p. 337 - 351 View in Reaxys vol. P: MVol.C; 191, page 439 - 441 ; (from Gmelin) View in Reaxys in neat (no solvent), dissociation at 90-167 °C; dissociation pressure given; vol. P: MVol.C; 191, page 439 - 441 ; (from Gmelin) View in Reaxys in neat (no solvent), dissociation investigated at 166-358 °C; vol. P: MVol.C; 191, page 439 - 441 ; (from Gmelin)

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View in Reaxys in neat (no solvent), dissociation; vol. P: MVol.C; 191, page 439 - 441 ; (from Gmelin) View in Reaxys in neat (no solvent), evolution of Cl2 starting at 157-158 °C; vol. P: MVol.C; 191, page 439 - 441 ; (from Gmelin) View in Reaxys in further solvent(s), dissociation in SiCl4; Harold, J. F. X.; Journal of the American Chemical Society; vol. 20; (1898); p. 13 - 29 View in Reaxys vol. P: MVol.C; 196, page 449 - 451 ; (from Gmelin) View in Reaxys Cl

Cl (v4)

UCl4(PCl3)(x) x:0-1.4;

U ClCl

Rx-ID: 26758686 View in Reaxys 64/251 Yield

Conditions & References warming, or in vac. O'Donnell, T. A.; Stewart, D. F.; Wilson, P. W.; Inorganic Chemistry; vol. 5; (1966); p. 1438 - 1441 ; (from Gmelin) View in Reaxys warming, or in vac. vol. U: SVol.C8; 5.1.5.3, page 139 - 163 ; (from Gmelin) View in Reaxys

Cl Cl

red

Cl Cl Cl

Rx-ID: 26454697 View in Reaxys 65/251 Yield

Conditions & References in tetrachloromethane, Kinetics, Irradiation (UV/VIS); photolysis of P4 in CCl4; main product is red P;; yields depending on temp.; Perner, P. D.; Henglein, A.; Zeitschrift fuer Naturforschung; vol. 17 b; (1962); p. 703 - 711 View in Reaxys vol. C: MVol.D2; 4.1.2.7.7.10, page 238 - 239 ; (from Gmelin) View in Reaxys in tetrachloromethane, Kinetics, other Radiation; radiation with γ-rays of a soln. of P4 in CCl4 (in vac.); mechanism discussed;; yields depending on temp.; Perner, P. D.; Henglein, A.; Zeitschrift fuer Naturforschung; vol. 17 b; (1962); p. 703 - 711 View in Reaxys vol. C: MVol.D2; 4.1.2.7.7.10, page 238 - 239 ; (from Gmelin) View in Reaxys in tetrachloromethane, Kinetics, thermal reaction of P4 with CCl4 above 140°C;; soln. turning black; yields given; Perner, P. D.; Henglein, A.; Zeitschrift fuer Naturforschung; vol. 17 b; (1962); p. 703 - 711 View in Reaxys vol. C: MVol.D2; 4.1.2.7.7.10, page 238 - 239 ; (from Gmelin) View in Reaxys

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Cl P

Rx-ID: 26125234 View in Reaxys 66/251 Yield

Conditions & References in not given, contact of P and Cl2 in a liquid medium containing P-halogenides at 70 °C; vol. P: MVol.C; 179, page 412 - 414 View in Reaxys Patent; Britton, E. C.; Slagh, H. R.; Dow Chemical Co.; US1888713; (1932); C. I; (1933); p. 655 ; (from Gmelin) View in Reaxys With phosphorus trichoride in neat (no solvent), passing Cl2 in a 5-10 percent soln. of P in PCl3; keeping the boiling temp. constant; conducting the reaction heat by volatilization of PCl3; vol. P: MVol.C; 179, page 412 - 414 View in Reaxys Patent; Baerwind, H.; Reinshagen, P.; Zimpell, K.; Schmidt, H.; Farbwerke Hoechst A.-G. vorm. Meister Lucius & Bruening; DE1104931; (1961); C.; (1961); p. 14055 ; (from Gmelin) View in Reaxys With phosphorus trichoride in neat (no solvent), passing Cl2 in a mixt. of P with boiling PCl3; addn. of P during the react.;; distn. of PCl3 during the react.; Milobedzki, T.; Friedman, M.; Chemik polski; vol. 15; (1917); p. 76 - 79 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys With phosphorus trichoride in not given, prepn. in laboratory; addn. of PCl3 at the beginning of the react.; Saunders, B. C.; Worthy, T. S.; Journal of the Chemical Society; (1950); p. 1320 - 1322 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: POCl3; react. of an excess of P with Cl2 in leaded vessels under exclusion of H2O and under evolution of heat; an amount of PCl3 remains in the react. vessel on boiling;; distn. of formed PCl3, react. with Cl2 to remove remained P; removal of impurities by fractionation; vol. P: MVol.C; 179, page 412 - 414 View in Reaxys Wazer, J. R. van; Encyclopedia of Chemical Technology, herausgegeben von R. E. Kirk, D. F. Othmer. The Interscience Encyclopedia, Inc., New York 1953, Bd. 10, S. 478 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of P (distd. in a N2 atmosphere) with a corresponding amount of Cl2 in an atmosphere of N2; Holroyd, G. W. F.; Chadwick, H.; Mitchell, J. E. H.; Journal of the Chemical Society; vol. 127; (1925); p. 2492 2493 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of an excess of P with Cl2 in leaded vessels under exclusion of H2O under evolution of heat; Sorel, J.; Chim. et Ind.; vol. 60; (1948); p. 541 - 549 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of molten P with Cl2; preventing contact of Cl2 with P, addn. of Cl2 to formed PCl3; vol. P: MVol.C; 179, page 412 - 414

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View in Reaxys Patent; Batuner, L. M.; RU47291; (1936); C. I; (1937); p. 400 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of molten P with Cl2; react. temp. for formation of gaseous PCl3; addn. of liquid P in distance to the reaction center;; washing formed PCl3 vapor with liquid P and liquid PCl3; vol. P: MVol.C; 179, page 412 - 414 View in Reaxys Patent; Schmidt, H.; Teske, W.; Farbwerke Hoechst A.-G. vorm. Meister Lucius & Bruening; DE878489; (1953); C.; (1954); p. 6312 View in Reaxys Patent; Schmidt, H.; Teske, W.; Farbwerke Hoechst A.-G. vorm. Meister Lucius & Bruening; GB688525; (1953); C. A.; (1954); p. 9638 ; (from Gmelin) View in Reaxys in not given, react. in a retort; use of an excess of P; vol. P: MVol.C; 179, page 412 - 414 View in Reaxys Patent; anonymous; Fahlberg, List & Co.; DE44832; (1887); C. I; (1889); p. 88 ; (from Gmelin) View in Reaxys

F Cl

PCl Cl

Rx-ID: 26453930 View in Reaxys 67/251 Yield

Conditions & References -78°C Emeleus,H.J.; Pugh,H.; Journal of the Chemical Society; (1960); p. 1108 - 1112 View in Reaxys vol. F: PerFHalOrg.2; 1.1.6.10, page 27 - 31 ; (from Gmelin) View in Reaxys

F F

S F

F F

Rx-ID: 26454411 View in Reaxys 68/251 Yield

Conditions & References With chlorine, at -74°C; detection of products by IR-spectroscopy Emeleus, H. J.; Nabi, S. N.; Journal of the Chemical Society; (1960); p. 1103 - 1108 View in Reaxys vol. F: PerFHalOrg.2; 1.1.6.10, page 27 - 31 ; (from Gmelin) View in Reaxys

P Cl

2 P(OC6HS)3 Rx-ID: 7066845 View in Reaxys 69/251

Yield

Conditions & References T= 180 °C , Equilibrium constant Fluck et al.; Journal of the American Chemical Society; vol. 81; (1959); p. 6363 View in Reaxys

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P(OC6H5)2Cl

Rx-ID: 7084939 View in Reaxys 70/251 Yield

Conditions & References T= 180 °C , Equilibrium constant Fluck et al.; Journal of the American Chemical Society; vol. 81; (1959); p. 6363 View in Reaxys

P(OC6H5)3 Rx-ID: 7084941 View in Reaxys 71/251

Yield

Conditions & References T= 180 °C , Equilibrium constant Fluck et al.; Journal of the American Chemical Society; vol. 81; (1959); p. 6363 View in Reaxys Cl

Rx-ID: 26182404 View in Reaxys 72/251 Yield

Conditions & References With titanium, silicon in not given, byproducts: POCl3, TiCl4; react. of ferrophosphorus containing Ti and Si with Cl2; Patent; Barth-Wehrenalp, G.; Kowalski, A.; Pennsylvania Salt Mfg. Co.; US2797980; (1957); C. A.; (1957); p. 15080 View in Reaxys Patent; Barth-Wehrenalp, G.; Kowalski, A.; Pennsylvania Salt Mfg. Co.; DE1065817; (1959); C.; (1960); p. 13811 View in Reaxys Patent; Gall, J. F.; Kowalski, A.; Barth-Wehrenalp, G.; Pennsylvania Salt Mfg. Co.; DE1040516; (1958); C.; (1959); p. 4934 View in Reaxys Patent; Gall, J. F.; Kowalski, A.; Barth-Wehrenalp, G.; Pennsylvania Salt Mfg. Co.; GB812801; (1959); C.; (1960); p. 8645 View in Reaxys Patent; Gall, J. F.; Kowalski, A.; Barth-Wehrenalp, G.; Pennsylvania Salt Mfg. Co.; FR1163391; (1958); C.; (1960); p. 12468 View in Reaxys Patent; anonymous; Pennsalt Corp. Chemical; GB805153; (1958); C. A.; (1959); p. 5609 ; (from Gmelin) View in Reaxys With ferrophosphorus in not given, react. of ferrophosphorus with Cl2;; distn. of formed PCl3 by react. heat; Patent; Urbain, E.; DE489933; (1930); C. I; (1930); p. 1989 View in Reaxys Patent; Urbain, E.; GB312685; (1929); C. II; (1930); p. 3182 View in Reaxys Patent; Urbain, E.; FR669099; (1929); C. I; (1930); p. 724 ; (from Gmelin) View in Reaxys With ferrophosphorus, Ti, Si in not given, byproducts: POCl3, TiCl4; react. of ferrophosphorus containing Ti and Si with Cl2; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys With ferrophosphorus in not given, react. of ferrophosphorus with Cl2;; distn. of formed PCl3 by react. heat;

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vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

PCl Cl

chloro-triethylamin-adduct

Rx-ID: 6211462 View in Reaxys 73/251 Yield

Conditions & References Holmes; Bertaut; Journal of the American Chemical Society; vol. 80; (1958); p. 2980 View in Reaxys

Cl P

Br As

Rx-ID: 26451151 View in Reaxys 74/251 Yield

Conditions & References in neat (no solvent), mixing starting material; Delwaulle, M. L.; Bulletin de la Societe Chimique de France; (1958); p. 278 - 279 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys

PCl Cl

Rx-ID: 26138520 View in Reaxys 75/251 Yield

Conditions & References in not given, react. with Hg; Downs, J. J.; Johnson, R. E.; Journal of the American Chemical Society; vol. 77; (1955); p. 2098 - 2102 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys Cl

red

PCl Cl Cl

Cl P

Rx-ID: 26182465 View in Reaxys 76/251 Yield <1

Conditions & References in tetrachloromethane, pouring red P with dry CCl4, cooling at 5°C and passing in Cl2; keeping temp. below 70 °C; stirring; standing for 2-3 h and repeating the process;; decanting pptd. PCl5; passing Cl2 through the soln. for 20 min; filtration in vacuum; product contains a small amount of PCl3, traces of POCl3 and 25-40 percent CCl4; distn. in vacuum; Bulashevich, E. A.; Zh. prikl. Khim.; vol. 28; (1955); p. 431 - 433; C. A.; (1955); p. 13811 ; (from Gmelin) View in Reaxys

in tetrachloromethane, pouring red P with dry CCl4, cooling at 5°C and passing in Cl2; keeping temp. below 70 °C; stirring; standing for 2-3 h and repeating the process;; decanting pptd. PCl5; passing Cl2 through the soln. for 20 min; filtration in vacuum; product contains a small amount of PCl3, traces of POCl3 and 25-40 percent CCl4; distn. in vacuum; vol. P: MVol.C; 189, page 434 - 437 ; (from Gmelin) View in Reaxys

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Cl O P

Rx-ID: 7066844 View in Reaxys 77/251 Yield

Conditions & References T= 20 °C , Zersetzung Forsman; Lipkin; Journal of the American Chemical Society; vol. 75; (1953); p. 3145,3146 View in Reaxys O

Cl Al

O 3 O Al3+

N–

Rx-ID: 26150195 View in Reaxys 78/251 Yield

Conditions & References in not given, formation of PCl3 and Al(NCO)3 by react. of P(NCO)3 with AlCl3; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys in not given, formation of PCl3 and Al(NCO)3 by react. of P(NCO)3 with AlCl3; Anderson; Journal of the American Chemical Society; vol. 75; (1953); p. 1576 ; (from Gmelin) View in Reaxys Anderson; Journal of the American Chemical Society; vol. 75; (1953); p. 1576 View in Reaxys vol. P: MVol.C; 271, page 622 - 624 ; (from Gmelin) View in Reaxys Cl

OH HO

P OH O

Rx-ID: 26154874 View in Reaxys 79/251 Yield

Conditions & References With sawdust or active carbon in neat (no solvent), react. of a heated mixt. of phosphoric acid and sawdust or phosphoric acid and active carbon with Cl2 at 250-600 °C; Patent; Tidwell, C. M.; International Minrals & Chemical Corp.; US2622965; (1952); C. A.; (1953); p. 3531 ; (from Gmelin) View in Reaxys With sawdust or active carbon in neat (no solvent), react. of a heated mixt. of phosphoric acid and sawdust or phosphoric acid and active carbon with Cl2 at 250-600 °C; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

O HO

Rx-ID: 7449689 View in Reaxys 80/251 Yield

Conditions & References With bromine, Erhitzen des Reaktionsprodukts mit 2,4,6-Trimethyl-pyridin Ungnade; Ortega; Journal of the American Chemical Society; vol. 73; (1951); p. 1564; Journal of the American Chemical Society; vol. 74; (1952); p. 6313 View in Reaxys

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F–

NH +4

P Cl F

Cl F

Rx-ID: 26090281 View in Reaxys 81/251 Yield

Conditions & References in neat (no solvent), heating with dry NH4F with a reflux condenser; Wilkins, C. J.; Journal of the Chemical Society; (1951); p. 2726 - 2728 ; (from Gmelin) View in Reaxys in neat (no solvent), heating with dry NH4F with a reflux condenser; vol. P: MVol.C; 206, page 471 - 475 ; (from Gmelin) View in Reaxys

Cl Cl Cl P (v4) Cl (v4) Cl NiCl (v4)Cl PP Cl P (v4) (v4) Cl Cl Cl Cl

F F

F F F P F F (v4) (v4) (v4) F P Ni P F (v4) F F (v4) P F F F

P F

Rx-ID: 26435453 View in Reaxys 82/251 Yield

Conditions & References in neat (no solvent), react. at >100°C and 50-100 atm in a pressure pipe; Wilkinson, G.; Journal of the American Chemical Society; vol. 73; (1951); p. 5501 - 5502 ; (from Gmelin) View in Reaxys in neat (no solvent), react. at >100°C and 50-100 atm in a pressure pipe; vol. P: MVol.C; 171, page 393 - 395 ; (from Gmelin) View in Reaxys

Cl PCl Cl

I– (v2)

Cl Cl Cl

P+ ClCl

Rx-ID: 26551918 View in Reaxys 83/251 Yield

Conditions & References in neat (no solvent), react. in the system PCl5#I2; react. of PCl5 with I2 forming ICl and PCl3; react. of ICl with PCl5 forming PCl6I; Fialkov, Ya. A.; Kuz'menko, A. A.; Zh. obshch. Khim.; vol. 19; (1949); p. 1645 - 1652; C. A.; (1950); p. 1354 View in Reaxys vol. P: MVol.C; 231, page 529 - 530 ; (from Gmelin) View in Reaxys

Cl B

P Cl

Cl B

Rx-ID: 26146588 View in Reaxys 84/251 Yield

Conditions & References in neat (no solvent), decompn. at -6 °C; Baumgarten, P.; Bruns, W.; Ber.; vol. 80; (1947); p. 517 - 520 ; (from Gmelin) View in Reaxys above -6°C Baumgarten, P.; Bruns, W.; Ber.; vol. 80; (1947); p. 517 - 520 ; (from Gmelin) View in Reaxys above -6°C vol. B: SVol.1; 4.4.4, page 177 - 187 ; (from Gmelin)

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View in Reaxys in neat (no solvent), decompn. at -6 °C; vol. P: MVol.C; 269, page 618 - 620 ; (from Gmelin) View in Reaxys Cl –C

K+

PCl Cl

ClK

Rx-ID: 26167912 View in Reaxys 85/251 Yield

Conditions & References in neat (no solvent), byproducts: paracyanogen; react. with KCN on heating; Bert, L.; C. r. Acad. Sci. (Paris); vol. 222; (1946); p. 1117 - 1118 View in Reaxys vol. P: MVol.C; 195, page 447 - 449 ; (from Gmelin) View in Reaxys O

Cl O

Rx-ID: 7066843 View in Reaxys 86/251 Yield

Conditions & References T= 25 °C Anderson; Journal of the American Chemical Society; vol. 67; (1945); p. 224,2177 View in Reaxys T= 143 °C Anderson; Journal of the American Chemical Society; vol. 67; (1945); p. 224,2177 View in Reaxys

P ClCl

Rx-ID: 26453721 View in Reaxys 87/251 Yield

Conditions & References in neat (no solvent), decomposition at 148°C; Anderson, H. H.; Journal of the American Chemical Society; vol. 67; (1945); p. 2176 - 2177 View in Reaxys vol. P: MVol.C; 276, page 633 - 634 ; (from Gmelin) View in Reaxys

O5P2

ClNa

P Cl

Rx-ID: 26099841 View in Reaxys 88/251 Yield

Conditions & References in neat (no solvent), reaction in iron or steel vessel; reaction starts at 250°C, reaction of formed POCl3 with Fe (from basin) yields PCl3; Tarbutton, G.; Egan, E. P.; Frary, S. G.; Journal of the American Chemical Society; vol. 63; (1941); p. 1782 - 1789 View in Reaxys vol. P: MVol.C; 200, page 458 - 460 ; (from Gmelin) View in Reaxys in neat (no solvent), react. starting at 250 °C; formation of POCl3 and a small amount of PCl3;

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vol. P: MVol.C; 45, page 90 - 93 ; (from Gmelin) View in Reaxys in neat (no solvent), react. starting at 250 °C; formation of POCl3 and a small amount of PCl3; Tarbutton, G.; Egan, E. P.; Frary, S. G.; Journal of the American Chemical Society; vol. 63; (1941); p. 1782 - 1789 ; (from Gmelin) View in Reaxys

O5P2

CaCl 2

Cl P

Rx-ID: 26144596 View in Reaxys 89/251 Yield

Conditions & References in neat (no solvent), reaction in iron or steel vessel; reaction starts at 400°C, reaction of formed POCl3 with Fe (from vessel) yields PCl3; Tarbutton, G.; Egan, E. P.; Frary, S. G.; Journal of the American Chemical Society; vol. 63; (1941); p. 1782 - 1789 View in Reaxys vol. P: MVol.C; 200, page 458 - 460 ; (from Gmelin) View in Reaxys in neat (no solvent), react. starting at 400 °C; vol. P: MVol.C; 45, page 90 - 93 ; (from Gmelin) View in Reaxys in neat (no solvent), react. starting at 400 °C; Tarbutton, G.; Egan, E. P.; Frary, S. G.; Journal of the American Chemical Society; vol. 63; (1941); p. 1782 - 1789 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl TB-5

Rx-ID: 26487214 View in Reaxys 90/251 Yield

Conditions & References in neat (no solvent), dissociation at 160 °C; Fischer, W.; Juebermann, O.; Z. Anorg. Chem.; vol. 235; (1938); p. 337 - 351 View in Reaxys vol. P: MVol.C; 191, page 439 - 441 ; (from Gmelin) View in Reaxys

P P

red

Rx-ID: 26150293 View in Reaxys 91/251 Yield

Conditions & References in not given, react. of a mixt. of P4 and red P with Cl2; Teodoreanu, I.; Bull. Sect. sci. Acad. Roum.; vol. 17; (1936); p. 38 - 40 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys

Cl P Cl

Cl Cl 2Cu 2

Rx-ID: 26174055 View in Reaxys 92/251

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Yield

Conditions & References in neat (no solvent), in vac. or on warming in a stream of CO2 or on washing with benzene; Davis, T. L.; Ehrlich, P.; Journal of the American Chemical Society; vol. 58; (1936); p. 2151 - 2153 View in Reaxys vol. Cu: MVol.B1; 110, page 240 - 242 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Cl P

PH2

Rx-ID: 26486063 View in Reaxys 93/251 Yield

Conditions & References in neat (no solvent), passing PH3 over PCl5 at -90 °C; Royen, P.; Hill, K.; Z. anorg. allg. Chem.; vol. 229; (1936); p. 112 - 128 ; (from Gmelin) View in Reaxys vol. P: MVol.C; 197, page 451 - 452 ; (from Gmelin) View in Reaxys Cl

Cl Fe

Cl Cl

(v3)

Rx-ID: 26182405 View in Reaxys 94/251 Yield

Conditions & References With ferrophosphorus in not given, react. of ferrophosphorus with Cl2; addn. of alkali chlorides to prevent distn. of FeCl3;; distn. of formed PCl3; Patent; Mueller, R.; Chemische Fabrik von Heyden A.-G.; DE622648; (1935); C. I; (1936); p. 1936 ; (from Gmelin) View in Reaxys With ferrophosphorus in not given, react. of ferrophosphorus with Cl2; addn. of alkali chlorides to prevent distn. of FeCl3;; distn. of formed PCl3; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Rx-ID: 26119927 View in Reaxys 95/251 Yield

Conditions & References in diethyl ether, incomplete react. with Mg powder in ether at ambient temp. or at boiling point forming a small amount of PCl3; Rheinboldt, H.; Schwenzer, K.; Bunge, R.; J. prakt. Chem. (2); vol. 140; (1934); p. 273 - 290 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys in diethyl ether, PCl5 is reduced incomplete to PCl3. Rheinboldt, H.; Schwenzer, K.; Journal fuer Praktische Chemie (Leipzig); vol. 140; nb. 2; (1934); p. 279 - 289 View in Reaxys vol. Mg: MVol.A2; 41, page 307 - 309 ; (from Gmelin) View in Reaxys

S Cl

red

Rx-ID: 26161033 View in Reaxys 96/251

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Yield

Conditions & References in not given, react. of red P with SO2Cl2; Koechlin, P.; Heumann, K.; Ber. dtsch. chem. Ges.; vol. 15; (1882); p. 1736 - 1738 ; (from Gmelin) View in Reaxys With carbon dioxide Danneel, H.; Schlottmann, F.; Z. Anorg. Chem.; vol. 212; (1933); p. 225 - 232 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of P with SO2Cl2 vapor even diluted with CO2 at ambient temp.; Daneel, H.; Schlottmann, F.; Z. anorg. allg. Chem.; vol. 212; (1933); p. 225 - 232 ; (from Gmelin) View in Reaxys in not given, react. of red P with SO2Cl2; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of P with SO2Cl2 vapor even diluted with CO2 at ambient temp.; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

S Cl

Cl red

Rx-ID: 26161034 View in Reaxys 97/251 Yield

Conditions & References in neat (no solvent), sealed tube (125°C); Danneel, H.; Schlottmann, F.; Z. Anorg. Chem.; vol. 212; (1933); p. 225 - 232 View in Reaxys Koechlin, P.; Heumann, K.; Ber.; vol. 15; (1882); p. 1736 - 1738 View in Reaxys vol. S: MVol.B3; 135, page 1815 - 1817 ; (from Gmelin) View in Reaxys in neat (no solvent), in coldness; Danneel, H.; Schlottmann, F.; Z. Anorg. Chem.; vol. 212; (1933); p. 225 - 232 View in Reaxys Koechlin, P.; Heumann, K.; Ber.; vol. 15; (1882); p. 1736 - 1738 View in Reaxys vol. S: MVol.B3; 135, page 1815 - 1817 ; (from Gmelin) View in Reaxys

S Cl

Cl white

Rx-ID: 26402937 View in Reaxys 98/251 Yield

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S Cl

PCl Cl

white

Rx-ID: 26402938 View in Reaxys 99/251 Yield

Conditions & References in neat (no solvent), excess of SO2Cl2; sealed tube (180°C); Danneel, H.; Schlottmann, F.; Z. Anorg. Chem.; vol. 212; (1933); p. 225 - 232 View in Reaxys Koechlin, P.; Heumann, K.; Ber.; vol. 15; (1882); p. 1736 - 1738 View in Reaxys vol. S: MVol.B3; 135, page 1815 - 1817 ; (from Gmelin) View in Reaxys P P PP

Cl S Cl

white

Rx-ID: 26472605 View in Reaxys 100/251 Yield

Conditions & References With carbon dioxide Danneel, H.; Schlottmann, F.; Z. Anorg. Chem.; vol. 212; (1933); p. 225 - 232 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys

Cl P

Ge Cl ClCl

Cl I

Rx-ID: 26479593 View in Reaxys 101/251 Yield

Conditions & References in neat (no solvent) Karantassis, T.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 196; (1933); p. 1894 - 1896 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. P: MVol.C; 228, page 522 - 524 ; (from Gmelin) View in Reaxys Cl

P P

Rx-ID: 26150292 View in Reaxys 102/251 Yield

Conditions & References in neat (no solvent), direct react. of P4 with gaseous Cl2;; purification on digesting with dry P and distn. in presence of P; Woodstock, W. H.; Adler, H.; Journal of the American Chemical Society; vol. 54; (1932); p. 464 - 467 View in Reaxys Dumas, J. B.; Ann. Chim. Phys.; vol. 55; (1859); p. 129 - 210 View in Reaxys Dumas, J. B.; Liebigs Annalen der Chemie; vol. 113; (1860); p. 20 - 36 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys With phosphorus trichoride in neat (no solvent), pouring liquid PCl3 upon P4; passing gaseous Cl2 in the liquid; apparatus described;

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Vanshejdt, A. A.; Tolstopjatov, V. M.; Zh. russk. fiz. chim. Obshch. Chast' chim.; vol. 52; (1920); p. 251 - 269; C. III; (1923); p. 723 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys >99

With phosphorus trichoride in neat (no solvent), pouring liquid PCl3 upon P4; passing gaseous Cl2 in the liquid; use of a reflux condenser;; quantitative react.; Graebe, C.; Ber. dtsch. chem. Ges.; vol. 34; (1901); p. 645 - 652 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys in neat (no solvent), direct react. of P4 with gaseous Cl2;; purification on digesting with dry P and distn. in presence of P; Pierre, I.; Ann. Chim. Phys.; vol. 20; (1847); p. 5 - 53 ; (from Gmelin) View in Reaxys Cl

Cl 2Fe

Rx-ID: 26182406 View in Reaxys 103/251 Yield

Conditions & References With ferrophosphorus in not given, react. of ferrophosphorus with Cl2 forming PCl3*FeCl3; repeated addn. of ferrophosphorus forming FeCl2 and PCl3;; distn.; Patent; Urbain, E.; US1859543; (1932); C. A.; (1932); p. 3881 ; (from Gmelin) View in Reaxys With ferrophosphorus in not given, react. of ferrophosphorus with Cl2 forming PCl3*FeCl3; repeated addn. of ferrophosphorus forming FeCl2 and PCl3;; distn.; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

Cl P

Rx-ID: 26161228 View in Reaxys 104/251 Yield

Conditions & References With carbon monoxide in neat (no solvent), react. of POCl3 with CO and charcoal or active carbon above 400 °C; Patent; Klebert, L.; I. G. Farbenindustrie A.-G.; DE492061; (1930); C. I; (1930); p. 2292 ; (from Gmelin) View in Reaxys With carbon in neat (no solvent), passing POCl3 vapor through a tube witg charcoal at red heat; Riban, J.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 95; (1882); p. 1160 1163 ; (from Gmelin) View in Reaxys With carbon in neat (no solvent), passing gaseous POCl3 through a tube with charcoal heated at red heat; Riban, J.; C. r. Acad. Sci. (Paris); vol. 95; (1882); p. 1160 - 1163 ; (from Gmelin) View in Reaxys With charcoal in neat (no solvent), passing gaseous POCl3 through a tube with charcoal heated at red heat; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys With CO, charcoal or active carbon in neat (no solvent), react. of POCl3 with CO and charcoal or active carbon above 400 °C;

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vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys With charcoal in neat (no solvent), passing POCl3 vapor through a tube witg charcoal at red heat; vol. P: MVol.C; 204, page 467 - 469 ; (from Gmelin) View in Reaxys

P Cl

Rx-ID: 26161229 View in Reaxys 105/251 Yield

Conditions & References With carbon monoxide, carbon, above 400°C, with charcoal or activated carbon vol. C: MVol.C2; 1.10.5, page 150 - 151 View in Reaxys Patent; Kleber, L.; I. G. Farbenindustrie; DE492061; (1930) ; (from Gmelin) View in Reaxys Cl

Br P

Cl (v4)

Ti ClCl

Br (v4)

Ti BrBr

Rx-ID: 26159558 View in Reaxys 106/251 Yield

Conditions & References Raeder, M. G.; Skrifter - det Kongelige Norske Videnskabers Selskab; nb. 3; (1929); p. 76; C.; vol. II; (1930); p. 3361 ; (from Gmelin) View in Reaxys vol. Ti: MVol.; 5.7, page 324 - 332 ; (from Gmelin) View in Reaxys Cl

O3P2

P OH OH

Rx-ID: 26441565 View in Reaxys 107/251 Yield

Conditions & References in neat (no solvent), very fast absorption of gaseous HCl at -30°C with formation of PCl3 and H3PO3; Wolf, L.; Kalaehne, E.; Schmager, H.; Ber. dtsch. chem. Ges.; vol. 62; (1929); p. 1441 - 1449 View in Reaxys vol. P: MVol.C; 37, page 74 - 75 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: P, H3PO4; very fast absorption of gaseous HCl with formation of PCl3 and H3PO3, decomposition of small amount of H3PO3 to form P and H3PO4; Thorpe, T. E.; Tutton, A. E.; Journal of the Chemical Society; vol. 59; (1891); p. 1019 - 1029 View in Reaxys vol. P: MVol.C; 37, page 74 - 75 ; (from Gmelin) View in Reaxys

Sb Cl Cl

I P

Cl Sb

Rx-ID: 26475224 View in Reaxys 108/251 Yield

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View in Reaxys in neat (no solvent), exothermic reaction; vol. P: MVol.C; 228, page 522 - 524 ; (from Gmelin) View in Reaxys I

Cl P

Sn Cl ClCl

Sn I I

Rx-ID: 26478673 View in Reaxys 109/251 Yield

Conditions & References in neat (no solvent), exothermic reaction; Karantassis, T.; Ann. Chim. Phys.; vol. 8; (1927); p. 71 - 119 View in Reaxys Karantassis, T.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 182; (1926); p. 1931 - 1933 ; (from Gmelin) View in Reaxys in neat (no solvent), exothermic reaction; vol. P: MVol.C; 228, page 522 - 524 ; (from Gmelin) View in Reaxys

Cl SbCl Cl TB-5

I P

Cl Sb

Rx-ID: 26486165 View in Reaxys 110/251 Yield

Conditions & References in neat (no solvent), byproducts: SbCl5*PCl5; vigorous, exothermic reaction with SbCl5; Karantassis, T.; Ann. Chim. Phys.; vol. 8; (1927); p. 71 - 119 View in Reaxys Karantassis, T.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 182; (1926); p. 1931 - 1933 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: SbCl5*PCl5; vigorous, exothermic reaction with SbCl5; vol. P: MVol.C; 228, page 522 - 524 ; (from Gmelin) View in Reaxys

red

Se Cl

Rx-ID: 26146365 View in Reaxys 111/251 Yield

Conditions & References in slow reaction Lenher, W.; Kao, C. H.; Journal of the American Chemical Society; vol. 48; (1926); p. 1550 - 1556 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys in neat (no solvent), explosion; vol. Se: MVol.B; 55, page 121 - 123 ; (from Gmelin) View in Reaxys in neat (no solvent), explosion; Lenher, V.; Kao, C. H.; Journal of the American Chemical Society; vol. 48; (1926); p. 1552 ; (from Gmelin) View in Reaxys

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Cl Cl PCl Cl

SbCl Cl TB-5 Cl

I Sb

PCl Cl Cl

Rx-ID: 26162745 View in Reaxys 112/251 Yield

Conditions & References in not given, react. with SbI3; Karantassis, T.; C. r. Acad. Sci. (Paris); vol. 182; (1926); p. 1391 - 1393 ; (from Gmelin) View in Reaxys in not given, react. with SbI3; vol. P: MVol.C; 194, page 445 - 447 ; (from Gmelin) View in Reaxys

Cl red

Se Cl ClCl

Rx-ID: 26168050 View in Reaxys 113/251 Yield

P P

Se Cl

Rx-ID: 26444087 View in Reaxys 114/251 Yield

Conditions & References in neat (no solvent), explosion; vol. Se: MVol.B; 55, page 121 - 123 ; (from Gmelin) View in Reaxys in neat (no solvent), explosion; Lenher, V.; Kao, C. H.; Journal of the American Chemical Society; vol. 48; (1926); p. 1552 ; (from Gmelin) View in Reaxys

P P PP white

Se Cl

Rx-ID: 26444105 View in Reaxys 115/251 Yield

Conditions & References with explosion Lenher, W.; Kao, C. H.; Journal of the American Chemical Society; vol. 48; (1926); p. 1550 - 1556 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys

P P PP white

Cl Se Cl ClCl

Rx-ID: 26483986 View in Reaxys 116/251 Yield

Conditions & References with explosion

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Lenher, W.; Kao, C. H.; Journal of the American Chemical Society; vol. 48; (1926); p. 1550 - 1556 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys

3 Ca 2+ – O 2

O– P

O–

Rx-ID: 26112944 View in Reaxys 117/251 Yield

Conditions & References

in neat (no solvent), no react. below 600 °C; Budnikoff, P. P.; Shilov, E. A.; Journal of the Society of Chemical Industry, London; vol. 42; (1923); p. 378 - 378 ; (from Gmelin) View in Reaxys

in neat (no solvent), no react. below 600 °C; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

3 Ca 2+ – O 2 O

O– P

O–

P Cl

Rx-ID: 26112945 View in Reaxys 118/251 Yield

Conditions & References With silica gel in neat (no solvent), byproducts: SiCl4; react. of Ca3(PO4)2 with S2Cl2 at 1000 °C in presence of SiO2;; after 1 h 9.5 percent phosphate are caused to react.; Budnikoff, P. P.; Shilov, E. A.; Journal of the Society of Chemical Industry, London; vol. 42; (1923); p. 378 - 378 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of Ca3(PO4)2 with S2Cl2 at 1000 °C;; after 1 h 19.5 percent phosphate are caused to react.; Budnikoff, P. P.; Shilov, E. A.; Journal of the Society of Chemical Industry, London; vol. 42; (1923); p. 378 - 378 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of Ca3(PO4)2 with S2Cl2 at 1000 °C;; after 1 h 19.5 percent phosphate are caused to react.; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys With SiO2 in neat (no solvent), byproducts: SiCl4; react. of Ca3(PO4)2 with S2Cl2 at 1000 °C in presence of SiO2;; after 1 h 9.5 percent phosphate are caused to react.; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys Cl

Cl As

Rx-ID: 26124970 View in Reaxys 119/251 Yield

Conditions & References in neat (no solvent), prepn. of PCl3 and AsCl3 by react. of a mixt. of powdered dry P and As in a column with Cl2; use of the counterflow principle;; isolation of the chloride by fractionation; vol. P: MVol.C; 179, page 412 - 414 View in Reaxys Patent; anonymous; J. Michael & Co.; DE369299; (1923); C. II; (1923); p. 726 ; (from Gmelin)

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View in Reaxys in not given, product mixture; vol. As: MVol.; 138, page 368 - 369 View in Reaxys Patent; anonymous; J. Michael & Co.; DE369299; (1922); C. II; (1923); p. 726 ; (from Gmelin) View in Reaxys Cl Cl

CaO 6P2

Rx-ID: 26151173 View in Reaxys 120/251 Yield

Conditions & References

in neat (no solvent), no react. below 600 °C; Budnikoff, P. P.; Shilov, E. A.; Journal of the Society of Chemical Industry, London; vol. 42; (1923); p. 378 - 378 ; (from Gmelin) View in Reaxys

in neat (no solvent), no react. below 600 °C; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys S

CaO 6P2

P Cl

Cl P

Rx-ID: 26151174 View in Reaxys 121/251 Yield

Conditions & References With silica gel in neat (no solvent), byproducts: SiCl4; react. of Ca(PO3)2 with S2Cl2 at 1000 °C in presence of SiO2; Budnikoff, P. P.; Shilov, E. A.; Journal of the Society of Chemical Industry, London; vol. 42; (1923); p. 378 - 378 ; (from Gmelin) View in Reaxys With SiO2 in neat (no solvent), byproducts: SiCl4; react. of Ca(PO3)2 with S2Cl2 at 1000 °C in presence of SiO2; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Si Cl Cl

Rx-ID: 26140769 View in Reaxys 122/251 Yield

Conditions & References in neat (no solvent), incineration of a mixture with Si and PCl5 by ignition of a special blaster; Berger, E.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 171; (1920); p. 29 32 ; (from Gmelin) View in Reaxys in neat (no solvent), incineration of a mixture with Si and PCl5 by ignition of a special blaster; vol. Si: MVol.B; 47, page 121 - 123 ; (from Gmelin) View in Reaxys

Cl Cl

Cl red

Rx-ID: 26162887 View in Reaxys 123/251

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Yield

Conditions & References mixt. of red P, CCl4, kieselgel and Al vol. P: MVol.B; 3.6.1, page 329 - 331 View in Reaxys Berger, E.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 171; (1920); p. 29 32 ; (from Gmelin) View in Reaxys

white

P Cl

Rx-ID: 26105600 View in Reaxys 124/251 Yield

Conditions & References in neat (no solvent), excess SOCl2; 125°C; North, H. B.; Thomson, J. C.; Journal of the American Chemical Society; vol. 40; (1918); p. 774 - 777 ; (from Gmelin) View in Reaxys in neat (no solvent), excess SOCl2; 125°C; vol. S: MVol.B3; 124, page 1796 - 1798 ; (from Gmelin) View in Reaxys

white

PCl Cl

Rx-ID: 26105601 View in Reaxys 125/251 Yield

Conditions & References in neat (no solvent), excess of SOCl2; 180°C; North, H. B.; Thomson, J. C.; Journal of the American Chemical Society; vol. 40; (1918); p. 774 - 777 ; (from Gmelin) View in Reaxys in neat (no solvent), excess of SOCl2; 180°C; vol. S: MVol.B3; 124, page 1796 - 1798 ; (from Gmelin) View in Reaxys

red

Rx-ID: 26144307 View in Reaxys 126/251 Yield

Conditions & References in melt, at 125°C vol. P: MVol.B; 3.4.2.2, page 307 - 310 View in Reaxys North, H. B.; Thomson, J. C.; Journal of the American Chemical Society; vol. 40; (1918); p. 774 - 777 ; (from Gmelin) View in Reaxys in neat (no solvent), excess SOCl2; 125°C; North, H. B.; Thomson, J. C.; Journal of the American Chemical Society; vol. 40; (1918); p. 774 - 777 ; (from Gmelin) View in Reaxys in neat (no solvent), excess SOCl2; 125°C; vol. S: MVol.B3; 124, page 1796 - 1798 ; (from Gmelin)

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View in Reaxys

red

P Cl

PCl Cl

Rx-ID: 26144308 View in Reaxys 127/251 Yield

red

PCl Cl

Rx-ID: 26144309 View in Reaxys 128/251 Yield

Conditions & References at 180°C vol. P: MVol.B; 3.4.2.2, page 307 - 310 View in Reaxys North, H. B.; Thomson, J. C.; Journal of the American Chemical Society; vol. 40; (1918); p. 774 - 777 ; (from Gmelin) View in Reaxys

P P PP

white

Rx-ID: 26441675 View in Reaxys 129/251 Yield

S O

P P PP

Cl Cl

white

PCl Cl

Rx-ID: 26441676 View in Reaxys 130/251 Yield

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O P Se

P O

phosphorus

selenium

Rx-ID: 7457786 View in Reaxys 131/251 Yield

Conditions & References T= 180 °C Strecker; Grossmann; Chemische Berichte; vol. 49; (1916); p. 75 View in Reaxys Cl Cl

P2Se5

PCl Cl

Se Cl

P ClCl

Rx-ID: 26167876 View in Reaxys 132/251 Yield

Conditions & References

in not given, react. with P2Se5 forming Se2Cl2 and PCl3, no formation of PSeCl3; Strecker, W.; Grossmann, C.; Ber. dtsch. chem. Ges.; vol. 49; (1916); p. 63 - 87 View in Reaxys vol. P: MVol.C; 192, page 441 - 443 ; (from Gmelin) View in Reaxys

(v2) (v2)

Cl 2Hg

red

Cl Hg Hg Cl

Rx-ID: 26184784 View in Reaxys 133/251 Yield

Conditions & References in neat (no solvent), in a sealed tube at 300°C; Wolf, L.; Ber. Dtsch. Chem. Ges.; vol. 48; (1915); p. 1272 - 1280 ; (from Gmelin) View in Reaxys vol. Hg: MVol.B2; 51, page 503 - 505 ; (from Gmelin) View in Reaxys

Cl Cl 2Hg 2

Cl 2Hg

red

Rx-ID: 26184785 View in Reaxys 134/251 Yield

Conditions & References in neat (no solvent), heating red P and HgCl2 in a sealed tube at 300 °C; Wolf, L.; Ber. dtsch. chem. Ges.; vol. 48; (1915); p. 1272 - 1280 ; (from Gmelin) View in Reaxys in neat (no solvent), heating red P and HgCl2 in a sealed tube at 300 °C; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys Cl

PCl Cl Cl

Rx-ID: 26125235 View in Reaxys 135/251 Yield

Conditions & References in neat (no solvent), react. of a small excess of Cl2 with P in vac. under exclusion of H2O;; removal of formed PCl5 by fractional distn..; Baxter, G. P.; Moore, C. J.; Journal of the American Chemical Society; vol. 34; (1912); p. 1644 - 1657

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View in Reaxys Baxter, G. P.; Moore, C. J.; Z. anorg. allg. Chem.; vol. 80; (1913); p. 185 - 200 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys Cl

Cl P

Cl red

Rx-ID: 26294774 View in Reaxys 136/251 Yield

Conditions & References in neat (no solvent), heating on light at 100 °C; formation of PCl3 and a orange-yellow or light red compound which is a mixt. of red P and P-chlorides; Besson, A.; Fournier, L.; C. r. Acad. Sci. (Paris); vol. 150; (1910); p. 102 - 104 View in Reaxys vol. P: MVol.C; 179, page 412 - 414 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Rx-ID: 6208054 View in Reaxys 137/251 Yield

Conditions & References T= -15 °C Autenrieth; Geyer; Chemische Berichte; vol. 41; (1908); p. 4254 View in Reaxys

Rx-ID: 7449690 View in Reaxys 138/251 Yield

Conditions & References Michaelis; Linke; Chemische Berichte; vol. 40; (1907); p. 3420 View in Reaxys

S P

Rx-ID: 7449691 View in Reaxys 139/251 Yield

Conditions & References Michaelis; Linke; Chemische Berichte; vol. 40; (1907); p. 3420 View in Reaxys Cl Cl

red Cl

Rx-ID: 26168997 View in Reaxys 140/251 Yield

Conditions & References Cl-poor org. products formed too Wichelhaus, H.; Ber.; vol. 38; (1905); p. 1725 - 1728

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View in Reaxys vol. P: MVol.B; 3.6.1, page 329 - 331 ; (from Gmelin) View in Reaxys O

O S

Cl Cl

PCl Cl

S O

P Cl

Rx-ID: 7449692 View in Reaxys 141/251 Yield

Conditions & References Bourgeois; Petermann; Recueil des Travaux Chimiques des Pays-Bas; vol. 22; (1903); p. 350 View in Reaxys

H H

I– Cl

P+

PCl Cl

Cl P

red

Rx-ID: 26393026 View in Reaxys 142/251 Yield

Conditions & References in neat (no solvent), heating equimolar amounts of PCl5 and PH4I at 135°C; Fireman, E.; Fireman, P.; American Chemical Journal; vol. 30; (1903); p. 116 - 133 ; (from Gmelin) View in Reaxys in neat (no solvent), heating equimolar amounts in sealed tube to 120 to 135°C; Fireman, E.; Fireman, P.; American Chemical Journal; vol. 30; (1903); p. 116 - 133 ; (from Gmelin) View in Reaxys in neat (no solvent), heating equimolar amounts in sealed tube to 120 to 135°C; vol. P: MVol.C; 229, page 525 - 527 ; (from Gmelin) View in Reaxys in neat (no solvent), heating equimolar amounts of PCl5 and PH4I at 135°C; vol. P: MVol.C; 227, page 520 - 522 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Cl S

Rx-ID: 26139493 View in Reaxys 143/251 Yield

Conditions & References in neat (no solvent), 100°C; presence of AlCl3; Ruff, O.; Ber.; vol. 34; (1901); p. 1749 - 1758 View in Reaxys vol. S: MVol.B3; 106, page 1761 - 1762 ; (from Gmelin) View in Reaxys in neat (no solvent), 250°C; vol. S: MVol.B3; 106, page 1761 - 1762 View in Reaxys Goldschmidt, H.; Jahresber. der Lese- und Redehalle der Deutschen Stud. Prag1880/81; C.; (1881); p. 489/95 ; (from Gmelin) View in Reaxys

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Cl Cl Cl

(v6)

W Cl

Cl Cl

Rx-ID: 26401464 View in Reaxys 144/251 Yield

Conditions & References With Cl2, at red heat Defacqz, E.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 132; (1901); p. 32 View in Reaxys vol. W: MVol.; 2.15, page 205 - 206 ; (from Gmelin) View in Reaxys

Rx-ID: 7066842 View in Reaxys 145/251 Yield

Conditions & References T= 135 °C Guichard; Chemische Berichte; vol. 32; (1899); p. 1574 View in Reaxys Michaelis; Chemische Berichte; vol. 13; (1880); p. 2174 View in Reaxys Cl

Fe 2P3

Rx-ID: 26124846 View in Reaxys 146/251 Yield

Conditions & References With iron(III) chloride Granger, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 122; (1896); p. 936 937 View in Reaxys vol. P: MVol.B; 3.4.2.3, page 310 - 316 ; (from Gmelin) View in Reaxys With FeCl3 Granger, A.; Ann. Chim. Phys.; vol. 14; (1898); p. 5 - 90 ; (from Gmelin) View in Reaxys Cl

CuP 2

Rx-ID: 26124850 View in Reaxys 147/251 Yield

Conditions & References With copper dichloride, by heating at red heat vol. P: MVol.B; 3.4.2.3, page 310 - 316 ; (from Gmelin) View in Reaxys With CuCl2, by heating at red heat Granger, A.; Ann. Chim. Phys.; vol. 14; (1898); p. 5 - 90 ; (from Gmelin) View in Reaxys Cl

OP4

Rx-ID: 26146999 View in Reaxys 148/251 Yield

Conditions & References in not given, react. of Cl2 with phosphorus suboxide;

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Besson, A.; C. r. Acad. Sci. (Paris); vol. 124; (1897); p. 763 - 765 View in Reaxys Verrier, Le; Liebigs Annalen der Chemie; vol. 27; (1838); p. 167 - 182 View in Reaxys Verrier, U. J. J. Le; Ann. Chim. Phys.; vol. 65; (1837); p. 257 - 279 ; (from Gmelin) View in Reaxys in not given, react. of Cl2 with phosphorus suboxide; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys I

I P

Hg 2I2

Cl 2Hg 2

Cl red

Rx-ID: 26343487 View in Reaxys 149/251 Yield

Conditions & References in neat (no solvent), fast reaction at temperature of water bath; Besson, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 124; (1897); p. 1346 - 1349 ; (from Gmelin) View in Reaxys in neat (no solvent), fast reaction at temperature of water bath; vol. P: MVol.C; 227, page 520 - 522 ; (from Gmelin) View in Reaxys Cl

N P

H 2N

Rx-ID: 6711952 View in Reaxys 150/251 Yield

Conditions & References Michaelis; Schroeter; Chemische Berichte; vol. 27; (1894); p. 494 View in Reaxys F

PF Cl TB-5 F

F F

P F

Rx-ID: 26125209 View in Reaxys 151/251 Yield

Conditions & References in neat (no solvent), heating PF3Cl2 with P at 120 °C; Poulenc, C.; Ann. Chim. Phys.; vol. 24; (1891); p. 548 - 570 View in Reaxys vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys in neat (no solvent), decompn. with P at 110 °C; Poulenc, C.; Ann. Chim. Phys.; vol. 24; (1891); p. 548 - 570 View in Reaxys Poulenc, C.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 113; (1891); p. 75 78 View in Reaxys vol. P: MVol.C; 211, page 484 - 487 ; (from Gmelin) View in Reaxys

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F F

P F

Rx-ID: 26125240 View in Reaxys 152/251 Yield

Conditions & References vol. P: MVol.B; 3.4.2.2, page 307 - 310 View in Reaxys Moissan, H.; Das Fluor und seine Verbindungen, Berlin 1900, p. 167 ; (from Gmelin) View in Reaxys Poulenc, C.; Ann. Chim. Phys.; vol. 24; (1891); p. 548 - 570 View in Reaxys Poulenc, C.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 113; (1891); p. 75 78 ; (from Gmelin) View in Reaxys

O P

P O

O P

PCl Cl

P Cl

Rx-ID: 26167840 View in Reaxys 153/251 Yield

Conditions & References in not given, react. of PCl5 with P4O6; Thorpe, T. E.; Tutton, A. E.; Journal of the Chemical Society; vol. 59; (1891); p. 1019 - 1029 ; (from Gmelin) View in Reaxys in not given, react. with P4O6 under evolution of heat; Thorpe, T. E.; Tutton, A. E.; Journal of the Chemical Society; vol. 59; (1891); p. 1019 - 1029 View in Reaxys vol. P: MVol.C; 192, page 441 - 443 ; (from Gmelin) View in Reaxys in not given, react. of PCl5 with P4O6; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys O

P O

O P

P OH OH

Rx-ID: 26168482 View in Reaxys 154/251 Yield

Conditions & References in neat (no solvent), react. of gaseous HCl with P4O6; Thorpe, T. E.; Tutton, A. E.; Journal of the Chemical Society; vol. 59; (1891); p. 1019 - 1029 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of gaseous HCl with P4O6; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

Cl 2

Cl P

(v4)

Cl Cl

Ir ClCl

Rx-ID: 26281822 View in Reaxys 155/251 Yield

Conditions & References in vac. Geisenheimer, G.; Ann. Chim. Phys.; vol. 23; (1891); p. 246 - 282 View in Reaxys vol. Ir: MVol.; 5.12, page 83 - 86 ; (from Gmelin)

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View in Reaxys With Cl2 Geisenheimer, G.; Ann. Chim. Phys.; vol. 23; (1891); p. 246 - 282 View in Reaxys vol. Ir: MVol.; 5.12, page 83 - 86 ; (from Gmelin) View in Reaxys

Cl Cl

Cl Ir

(v3)

Cl3

PCl Cl

Rx-ID: 26284121 View in Reaxys 156/251 Yield

Conditions & References under reduced pressure Geisenheimer, G.; Ann. Chim. Phys.; vol. 23; (1891); p. 246 - 282 View in Reaxys vol. Ir: MVol.; 5.12, page 83 - 86 ; (from Gmelin) View in Reaxys Cl

O3P2

PCl Cl

Cl P

Rx-ID: 26441564 View in Reaxys 157/251 Yield

Conditions & References in neat (no solvent), vigorous exothermic reaction at ambient temperature (cooling with ice is necessary); Thorpe, T. E.; Tutton, A. E.; Journal of the Chemical Society; vol. 59; (1891); p. 1019 - 1029 View in Reaxys vol. P: MVol.C; 37, page 74 - 75 ; (from Gmelin) View in Reaxys Cl

Cl P

Rx-ID: 7920553 View in Reaxys 158/251 Yield

Conditions & References 4-<Dimethylanilin-phenyl>-dichlorphosphin bewirkt Spaltung Michaelis; Schenk; Justus Liebigs Annalen der Chemie; vol. 260; (1890); p. 6; Chemische Berichte; vol. 21; (1888); p. 1501 View in Reaxys Cl

P P

Rx-ID: 6208053 View in Reaxys 159/251 Yield

Conditions & References T= 280 - 300 °C Doerken; Chemische Berichte; vol. 21; (1888); p. 1507 View in Reaxys Broglie; Chemische Berichte; vol. 10; (1877); p. 628 View in Reaxys

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O Cl

N O

PCl Cl

isocyanuric acid tris-chloromethyl ester

Rx-ID: 5735882 View in Reaxys 160/251 Yield

Conditions & References T= 220 - 230 °C Hofmann,A.W.; Chemische Berichte; vol. 19; (1886); p. 2092 View in Reaxys Hofmann,A.W.; Chemische Berichte; vol. 18; (1885); p. 2800 View in Reaxys

Cl P

Rx-ID: 26435482 View in Reaxys 161/251 Yield

Conditions & References in neat (no solvent), byproducts: HF; heating with gaseous HCl; Moissan, H.; Das Fluor und seine Verbindungen, Berlin 1900, S. 170 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: HF; heating with gaseous HCl; Moissan, H.; Ann. Chim. Phys.; vol. 6; (1885); p. 433 - 467 View in Reaxys vol. P: MVol.C; 171, page 393 - 395 ; (from Gmelin) View in Reaxys O O

S O

Rx-ID: 26062834 View in Reaxys 162/251 Yield

Conditions & References in not given, react. of P with S2O5Cl2; Heumann, K.; Koechlin, P.; Ber. dtsch. chem. Ges.; vol. 16; (1883); p. 479 - 483 ; (from Gmelin) View in Reaxys in not given, react. of P with S2O5Cl2; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

O O

O S

Cl red

Rx-ID: 26062844 View in Reaxys 163/251 Yield

Conditions & References Heumann, K.; Koechlin, P.; Ber.; vol. 16; (1883); p. 479 - 483 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys

O O S

O S

red

Cl S

Rx-ID: 26345170 View in Reaxys 164/251 Yield

Conditions & References in neat (no solvent)

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Heumann, K.; Koechlin, P.; Ber.; vol. 16; (1883); p. 479 - 483 View in Reaxys vol. S: MVol.B3; 141, page 1826 - 1828 ; (from Gmelin) View in Reaxys Cl

red

Rx-ID: 26144306 View in Reaxys 165/251 Yield

Conditions & References in cold vol. P: MVol.B; 3.4.2.2, page 307 - 310 View in Reaxys Koechlin, P.; Heumann, K.; Ber.; vol. 15; (1882); p. 1736 - 1738 ; (from Gmelin) View in Reaxys

P P PP

white

Rx-ID: 26441674 View in Reaxys 166/251 Yield

Conditions & References by heating vol. P: MVol.B; 3.4.2.2, page 307 - 310 View in Reaxys Koechlin, P.; Heumann, K.; Ber.; vol. 15; (1882); p. 1736 - 1738 ; (from Gmelin) View in Reaxys

Cl Cl

Cl O

PCl Cl

Cl Cl

Cl P

Rx-ID: 7920555 View in Reaxys 167/251 Yield

Conditions & References T= 200 °C Michaelis; Paneck; Chemische Berichte; vol. 14; (1881); p. 405 View in Reaxys Cl

PCl Cl

Cl 2Pb

Rx-ID: 26127052 View in Reaxys 168/251 Yield

Conditions & References in neat (no solvent), heating PCl5 with Pb at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys in neat (no solvent), heating at 250°C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. Pb: MVol.B1; 13.6.10, page 324 - 324 ; (from Gmelin) View in Reaxys

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Cl Cl

PCl Cl

Cl As

Rx-ID: 26128952 View in Reaxys 169/251 Yield

Conditions & References in neat (no solvent), equilibrium; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. As: MVol.; 50, page 179 - 181 ; (from Gmelin) View in Reaxys in neat (no solvent), at room temp.; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. As: MVol.; 50, page 179 - 181 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Cl Al

Rx-ID: 26130736 View in Reaxys 170/251 Yield

Conditions & References in neat (no solvent), heating PCl5 with Al at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Cl Cu

Cl 2Cu 2

Rx-ID: 26133496 View in Reaxys 171/251 Yield

Conditions & References in neat (no solvent), heating PCl5 with Cu at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Cl Cu

Cl 2Cu 2

Cl 2Cu

Rx-ID: 26133497 View in Reaxys 172/251 Yield

Conditions & References in neat (no solvent), heating an excess of PCl5 with Cu at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl Cl

Cl 2Fe

Rx-ID: 26136808 View in Reaxys 173/251

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Yield

Conditions & References in neat (no solvent), heating PCl5 with Fe at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Cl 2Hg

Rx-ID: 26138521 View in Reaxys 174/251 Yield

Conditions & References in neat (no solvent), heating PCl5 with Hg at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys Cl Cl

PCl Cl

Sn Cl ClCl

Rx-ID: 26139874 View in Reaxys 175/251 Yield

Conditions & References in neat (no solvent), react. with Sn on heating; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys Goldschmidt, H.; Chem. Centralbl. Repertorium (3); vol. 12; (1881); p. 489 - 495 View in Reaxys vol. Sn: MVol.B; 14.4.8, page 360 - 360 ; (from Gmelin) View in Reaxys in neat (no solvent), heating PCl5 with Sn at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Cl 2Zn

Rx-ID: 26142568 View in Reaxys 176/251 Yield

Conditions & References in neat (no solvent), heating PCl5 with Zn at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: Zn-phosphide; heating with Zn in a sealing tube at 100 °C; Casselmann, W.; Liebigs Annalen der Chemie; vol. 98; (1856); p. 213 - 236 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin)

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View in Reaxys in neat (no solvent), moderate heating with Zn; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys Cl Cl

PCl Cl

Rx-ID: 26167891 View in Reaxys 177/251 Yield

Conditions & References in neat (no solvent), byproducts: Pt-chloride; heating PCl5 with Pt at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

AgCl

Rx-ID: 26167892 View in Reaxys 178/251 Yield

Conditions & References in neat (no solvent), heating PCl5 with Ag at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys Cl

Cl SbCl Cl

Cl Sb Cl

Cl Cl

Rx-ID: 8265003 View in Reaxys 179/251 Yield

Conditions & References beim Erhitzen Koehler; Chemische Berichte; vol. 13; (1880); p. 1626 View in Reaxys

O Mg

Cl P

3 Mg2+ – O 2 O

O– P

O–

Cl 2Mg

Rx-ID: 26119866 View in Reaxys 180/251 Yield

Conditions & References at room temperature also formation of unknown red substance; vol. Mg: MVol.A2; 41, page 307 - 309 ; (from Gmelin) View in Reaxys at room temperature also formation of unknown red substance; Reinitzer, B.; Goldschmidt, H.; Ber. Wien. Akad.; vol. 81; (1880); p. 831 - 831 ; (from Gmelin) View in Reaxys

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Cl P

O Cl

P O Cl

O P

Cl As

O5P2

Rx-ID: 26128935 View in Reaxys 181/251 Yield

Conditions & References in neat (no solvent), react. on heating at 250 °C for a longer period of time; Reinitzer, B.; Goldschmidt, H.; Ber.; vol. 13; (1880); p. 845 - 851 ; (from Gmelin) View in Reaxys in neat (no solvent), react. on heating at 250 °C for a longer period of time; vol. P: MVol.C; 204, page 467 - 469 ; (from Gmelin) View in Reaxys

O Al

Cl P

Cl Cl (v4) Al (v4)Cl Cl Cl (v2) (v2)

Al3+ –O

O– P – OO

Rx-ID: 26130699 View in Reaxys 182/251 Yield

Conditions & References in neat (no solvent), react. with Al at 100 °C; formation of PCl3, Al2Cl6, Al2(PO4)2 and a yellow mass; Reinitzer, B.; Golschmidt, H.; Ber.; vol. 13; (1880); p. 845 - 851 ; (from Gmelin) View in Reaxys in neat (no solvent), react. with Al at 100 °C; formation of PCl3, Al2Cl6, Al2(PO4)2 and a yellow mass; vol. P: MVol.C; 206, page 471 - 475 ; (from Gmelin) View in Reaxys

Cl P

3 Fe 2+ 2 –O

O– P

O5P2

Cl 2Fe

O–

Rx-ID: 26136780 View in Reaxys 183/251 Yield

Conditions & References in neat (no solvent), react. with powdered Fe starting at 100 °C, react. accelerated at 120 °C; Reinitzer, B.; Golschmidt, H.; Ber.; vol. 13; (1880); p. 845 - 851 ; (from Gmelin) View in Reaxys in neat (no solvent), react. with powdered Fe starting at 100 °C, react. accelerated at 120 °C; vol. P: MVol.C; 206, page 471 - 475 ; (from Gmelin) View in Reaxys

O Hg

Cl P Cl

Cl 2Hg 2

P O Cl

O P

Cl Cl

O5P2

Rx-ID: 26138489 View in Reaxys 184/251 Yield

Conditions & References in neat (no solvent), heating with an excess of Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2; Reinitzer, B.; Golschmidt, H.; Ber.; vol. 13; (1880); p. 845 - 851 ; (from Gmelin) View in Reaxys in neat (no solvent), heating with an excess of Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2; vol. P: MVol.C; 206, page 471 - 475 ; (from Gmelin) View in Reaxys

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O Hg

Cl 2Hg 2

P Cl

P O

Cl Cl

O5P2

Cl 2Hg

Rx-ID: 26138490 View in Reaxys 185/251 Yield

Conditions & References in neat (no solvent), byproducts: Hg-phosphate; heating with an excess of POCl3 with Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2, HgCl2 and Hg-phosphate; Reinitzer, B.; Golschmidt, H.; Ber.; vol. 13; (1880); p. 845 - 851 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: Hg-phosphate; heating with an excess of POCl3 with Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2, HgCl2 and Hg-phosphate; vol. P: MVol.C; 206, page 471 - 475 ; (from Gmelin) View in Reaxys

O Sn

Cl P

Sn Cl ClCl

Rx-ID: 26139852 View in Reaxys 186/251 Yield

Conditions & References 100°C Goldschmidt, H.; Chem. Centralbl. Repertorium (4); vol. 2; (1864); p. 492 View in Reaxys Reinitzer, B.; Goldschmidt, H.; Sitz.-Ber. Akad. Wiss. Wien Math.-Naturw. KI. II; vol. 81; (1880); p. 820 - 836 View in Reaxys vol. Sn: MVol.B; 14.4.8, page 360 - 360 ; (from Gmelin) View in Reaxys

OP4

P Cl

OZn

O6P2Zn

Cl 2Zn

Rx-ID: 26142518 View in Reaxys 187/251 Yield

Conditions & References in neat (no solvent), byproducts: P2O5, P2O3Cl4; react. of Zn dust with POCl3 at 250 °C; Reinitzer, B.; Golschmidt, H.; Ber.; vol. 13; (1880); p. 845 - 851 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: P2O5, P2O3Cl4; react. of Zn dust with POCl3 at 250 °C; vol. P: MVol.C; 206, page 471 - 475 ; (from Gmelin) View in Reaxys

P P

Cl P Cl

OP4

Rx-ID: 26150277 View in Reaxys 188/251 Yield

Conditions & References in neat (no solvent), react. starting at 200 °C; Reinitzer, B.; Goldschmidt, H.; Ber.; vol. 13; (1880); p. 845 - 851 ; (from Gmelin) View in Reaxys in neat (no solvent), react. starting at 200 °C; vol. P: MVol.C; 204, page 467 - 469 ; (from Gmelin) View in Reaxys

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3 Ag+ O–

Cl P

O–

O– P

4 Ag+ O

O–

Cl O

O5P2

O–

AgCl

Rx-ID: 26161305 View in Reaxys 189/251 Yield

Conditions & References in neat (no solvent), byproducts: P2O3Cl4; heating with Ag in a sealing tube at 250 °C; react. of POCl3 with Ag forming Ag2O and PCl3, react. of Ag2O with POCl3 forming Ag3PO4 and AgCl or Ag4P2O7 and AgCl, react. of POCl3 with Ag3PO4 forming P2O5 and AgCl and with P2O5 forming P2O3Cl4; Reinitzer, B.; Golschmidt, H.; Ber.; vol. 13; (1880); p. 845 - 851 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: P2O3Cl4; heating with Ag in a sealing tube at 250 °C; react. of POCl3 with Ag forming Ag2O and PCl3, react. of Ag2O with POCl3 forming Ag3PO4 and AgCl or Ag4P2O7 and AgCl, react. of POCl3 with Ag3PO4 forming P2O5 and AgCl and with P2O5 forming P2O3Cl4; vol. P: MVol.C; 206, page 471 - 475 ; (from Gmelin) View in Reaxys

O Mg

3 Mg2+ – O 2

Cl P

O– P

OP4

O–

Cl 2Mg

Rx-ID: 26428490 View in Reaxys 190/251 Yield

Conditions & References reaction of Mg with POCl3; Reinitzer, B.; Goldschmidt, H.; Ber.; vol. 13; (1880); p. 850 - 850 View in Reaxys vol. Mg: MVol.B3; 36, page 397 - 398 ; (from Gmelin) View in Reaxys

P P PP

white

OP4

P Cl

Rx-ID: 26473182 View in Reaxys 191/251 Yield

Conditions & References at 250°C vol. P: MVol.B; 3.4.2.2, page 307 - 310 View in Reaxys Reinitzer, B.; Goldschmidt, H.; Ber.; vol. 13; (1880); p. 845 - 851 ; (from Gmelin) View in Reaxys

P Cl

O Cl

PCl Cl Cl

P Cl

Rx-ID: 7066846 View in Reaxys 192/251 Yield

Conditions & References Geuther; Hergt; Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften; (1876); p. 206 View in Reaxys

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H N Cl

HN N

P2O5

Rx-ID: 7084162 View in Reaxys 193/251 Yield

Conditions & References T= 165 °C Chambon; Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften; (1876); p. 205 View in Reaxys

Cl Cl

Rx-ID: 7920554 View in Reaxys 194/251 Yield

Conditions & References T= 180 °C Michaelis; Justus Liebigs Annalen der Chemie; vol. 181; (1876); p. 322; Chemische Berichte; vol. 6; (1873); p. 819 View in Reaxys

Cl Cl

PCl Cl Cl

(v5)

Cl P

phenylphosphinic acid dichloride Rx-ID: 7924794 View in Reaxys 195/251

Yield

Conditions & References Michaelis; Ananow; Chemische Berichte; vol. 7; (1874); p. 1688 View in Reaxys Michaelis; Justus Liebigs Annalen der Chemie; vol. 181; (1876); p. 322; Chemische Berichte; vol. 6; (1873); p. 819 View in Reaxys

O H

P OH OH

P Cl

HO 3P

Rx-ID: 26115045 View in Reaxys 196/251 Yield

Conditions & References in not given, react. at ambient temp.; exothermic react.; Chambon, E.; Jenaische Z. Med. Naturw. (2) 2. Suppl.-H.; vol. 3; (1876); p. 92 - 103 ; (from Gmelin) View in Reaxys in neat (no solvent), react. on heating moderately; Geuther, A.; Jena. Z. Med. Naturwiss.; vol. 7; (1873); p. 380 - 390 View in Reaxys Geuther, A.; J. prakt. Chem. (2); vol. 8; (1874); p. 359 - 372 ; (from Gmelin) View in Reaxys in not given, react. at ambient temp.; exothermic react.; Geuther, A.; Journal fuer Praktische Chemie (Leipzig); vol. 8; (1874); p. 359 - 372 View in Reaxys vol. P: MVol.C; 57, page 122 - 124 ; (from Gmelin) View in Reaxys

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in neat (no solvent), react. on heating moderately; vol. P: MVol.C; 205, page 469 - 471 ; (from Gmelin) View in Reaxys Cl

O H

P OH OH

PCl Cl

P Cl

Rx-ID: 26115051 View in Reaxys 197/251 Yield

Conditions & References in not given, react. with PCl5; Chambon, E.; Jenaische Z. Med. Naturw. (2) 2. Suppl.-H.; vol. 3; (1876); p. 92 - 103 ; (from Gmelin) View in Reaxys in not given, react. with H3PO3 at ambient temp.; Geuther, A.; Jena. Z. Med. Naturwiss.; vol. 7; (1873); p. 380 - 390 View in Reaxys Geuther, A.; J. prakt. Chem. (2); vol. 8; (1874); p. 359 - 372 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys in not given, react. with PCl5; Geuther, A.; Journal fuer Praktische Chemie (Leipzig); vol. 8; (1874); p. 359 - 372 View in Reaxys vol. P: MVol.C; 57, page 122 - 124 ; (from Gmelin) View in Reaxys Cl

Br–

Br Br

P+

BrBr

PCl Cl

Br4Cl 3P

Rx-ID: 26150365 View in Reaxys 198/251 Yield

Conditions & References in neat (no solvent), react. with PBr5 in a sealing tube at ambient temp. or at 40 °C; Geuther, A.; Jena. Z. Med. Naturwiss.; vol. 10; (1876); p. 128 - 140 View in Reaxys vol. P: MVol.C; 192, page 441 - 443 ; (from Gmelin) View in Reaxys

P ClBr

P OH O

HO 3P

Cl P

Rx-ID: 26453649 View in Reaxys 199/251 Yield

Conditions & References in neat (no solvent), reaction starting at 60°C with evolution of gas; Chambon, E.; Jenaische Z. Naturwiss. (Suppl. 2.-H.); vol. 10; (1876); p. 92 - 96 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction starting at 60°C with evolution of gas; vol. P: MVol.C; 225, page 516 - 517 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl TB-5 Cl

Br Br Br TB-5 P Br Br

Cl Br4Cl 3P

Rx-ID: 26487220 View in Reaxys 200/251

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Yield

Conditions & References in neat (no solvent), reaction in sealed tube in a temp. range from ambient temp. to 40°C; Geuther, A.; Jenaische Z. Naturwiss.; vol. 10; (1876); p. 128 - 140 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction in sealed tube in a temp. range from ambient temp. to 40°C; vol. P: MVol.C; 218, page 501 - 503 ; (from Gmelin) View in Reaxys

PCl Cl

Br PBr Br

P+ ClBr

(v2)

Br Br– Br

Rx-ID: 26620733 View in Reaxys 201/251 Yield

Conditions & References in neat (no solvent), mixing starting material and warming to 40°C, formation as lower layer, which solidifies on cooling, upper layer contains PCl3; Geuther, A.; Jenaische Z. Naturwiss.; vol. 10; (1876); p. 128 - 140 ; (from Gmelin) View in Reaxys in neat (no solvent), mixing starting material and warming to 40°C, formation as lower layer, which solidifies on cooling, upper layer contains PCl3; vol. P: MVol.C; 224, page 513 - 516 ; (from Gmelin) View in Reaxys

I P

Cl AgCl

AgI

Rx-ID: 26062237 View in Reaxys 202/251 Yield

Conditions & References in neat (no solvent), heating P2I4 with AgCl; Gautier, A.; C. r. Acad. Sci. (Paris); vol. 78; (1874); p. 286 - 288 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction at 280 to 300°C; Gautier, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 78; (1874); p. 286 288 ; (from Gmelin) View in Reaxys in neat (no solvent), heating P2I4 with AgCl; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction at 280 to 300°C; vol. P: MVol.C; 227, page 520 - 522 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl Cl

OH O

Cl P

red Cl

Rx-ID: 26166071 View in Reaxys 203/251 Yield

Conditions & References in not given, react. with H3PO2 under pptn. of red P forming POCl3, PCl3 and HCl; Geuther, A.; Jena. Z. Med. Naturwiss.; vol. 7; (1873); p. 380 - 390 View in Reaxys

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Geuther, A.; J. prakt. Chem. (2); vol. 8; (1874); p. 359 - 372 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys OH O

HO 3P

Rx-ID: 26473181 View in Reaxys 204/251 Yield

Conditions & References in not given, reaction with POCl3; primary reaction of POCl3 with H3PO2 forming HPO3, H3PO3, P and HCl; Geuther, A.; Journal fuer Praktische Chemie (Leipzig); vol. 8; (1874); p. 359 - 372 View in Reaxys vol. P: MVol.C; 48, page 98 - 101 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Cl P

Rx-ID: 26481721 View in Reaxys 205/251 Yield

Conditions & References in not given, react. with PCl5; at first formation of POCl3, PCl3, HCl and red phosphorus, then react. of red P with PCl5 forming PCl3; Geuther, A.; Journal fuer Praktische Chemie (Leipzig); vol. 8; (1874); p. 359 - 372 View in Reaxys vol. P: MVol.C; 48, page 98 - 101 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

P O

P OH

O HO 3P

Cl P

Rx-ID: 26486137 View in Reaxys 206/251 Yield

Conditions & References in neat (no solvent), heating with PCl5; Geuther, A.; Journal fuer Praktische Chemie (Leipzig); vol. 8; (1874); p. 359 - 372 View in Reaxys vol. P: MVol.C; 101, page 224 - 227 ; (from Gmelin) View in Reaxys

Cl Cl

P+ ClBr

Cl (v2)

Br Br– Br

Br 2 Br

P+ Cl (v2) ClBr Br Br– Br

Rx-ID: 26586276 View in Reaxys 207/251 Yield

Conditions & References in neat (no solvent), decomposition beginning at 60°C; Prinvault; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 74; (1872); p. 868 870 ; (from Gmelin) View in Reaxys in neat (no solvent), decomposition beginning at 60°C; vol. P: MVol.C; 223, page 511 - 513 ; (from Gmelin) View in Reaxys

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Cl Cl

PCl Cl

Cl SiH4

Si Cl Cl

Rx-ID: 26167844 View in Reaxys 208/251 Yield

Conditions & References in neat (no solvent), heating with SiH4; Mahn, R.; Jena. Z. Med. Naturwiss.; vol. 5; (1870); p. 158 - 166 View in Reaxys Mahn, R.; Zeitschrift fuer Chemie (Stuttgart, Germany); vol. 12; (1869); p. 729 - 731 View in Reaxys vol. P: MVol.C; 192, page 441 - 443 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

SiH4

H Cl

Si Cl Cl

Rx-ID: 26167845 View in Reaxys 209/251 Yield

Conditions & References in not given, react. of PCl5 with SiH4; formation of PCl3, SiCl4 and gaseous HCl; Mahn, R.; Jena. Z. Med. Naturwiss.; vol. 5; (1870); p. 158 - 166 View in Reaxys Mahn, R.; Z. Chem. (2); vol. 12; (1869); p. 729 - 731 ; (from Gmelin) View in Reaxys in not given, react. of PCl5 with SiH4; formation of PCl3, SiCl4 and gaseous HCl; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl Cl

Cl P

Rx-ID: 26167849 View in Reaxys 210/251 Yield

Conditions & References in neat (no solvent), byproducts: HCl; react. of PH3 with PCl5; Mahn, R.; Jena. Z. Med. Naturw.; vol. 5; (1870); p. 158 - 166 View in Reaxys Mahn, R.; Z. Chem. (2); vol. 5; (1869); p. 729 - 731 View in Reaxys Rose, H.; Ann. Physik (2); vol. 24; (1832); p. 109 - 165 View in Reaxys Rose, H.; Ann. Physik (2); vol. 24; (1832); p. 295 - 341 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: HCl; react. of PH3 with PCl5; vol. P: MVol.C; 22, page 42 - 43 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl Cl

Cl P

Rx-ID: 26167850 View in Reaxys 211/251 Yield

Conditions & References in not given, react. of PCl5 with PH3; Mahn, R.; Jena. Z. Med. Naturwiss.; vol. 5; (1870); p. 158 - 166 View in Reaxys

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Mahn, R.; Z. Chem. (2); vol. 12; (1869); p. 729 - 731 ; (from Gmelin) View in Reaxys in not given, react. with PH3; Mahn, R.; Jena. Z. Med. Naturwiss.; vol. 5; (1870); p. 158 - 166 View in Reaxys Rose, H.; Annalen der Physik (Weinheim, Germany); vol. 24; (1832); p. 295 - 341 View in Reaxys vol. P: MVol.C; 192, page 441 - 443 ; (from Gmelin) View in Reaxys in not given, react. of PCl5 with PH3; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys Cl Cl

H 3Sb

PCl Cl

Cl Sb Cl

H Cl

Rx-ID: 26167863 View in Reaxys 212/251 Yield

Conditions & References in not given, incomplete react. with SbH3; Mahn, R.; Jena. Z. Med. Naturwiss.; vol. 5; (1870); p. 158 - 166 View in Reaxys Mahn, R.; Zeitschrift fuer Chemie (Stuttgart, Germany); vol. 12; (1869); p. 729 - 731 ; (from Gmelin) View in Reaxys in not given, react. of PCl5 with SbH3; formation of PCl3, SbCl3 and gaseous HCl; Mahn, R.; Jena. Z. Med. Naturwiss.; vol. 5; (1870); p. 158 - 166 View in Reaxys Mahn, R.; Z. Chem. (2); vol. 12; (1869); p. 729 - 731 ; (from Gmelin) View in Reaxys in not given, incomplete react. with SbH3; vol. P: MVol.C; 194, page 445 - 447 ; (from Gmelin) View in Reaxys in not given, react. of PCl5 with SbH3; formation of PCl3, SbCl3 and gaseous HCl; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

S Cl

P Cl

Cl Cl

Rx-ID: 26162927 View in Reaxys 213/251 Yield

Conditions & References in neat (no solvent), passing PSCl3 vapor through a tube heated at red heat; Chevrier; C. r. Acad. Sci. (Paris); vol. 68; (1869); p. 1174 - 1176 ; (from Gmelin) View in Reaxys in neat (no solvent), decompn. on passing through a tube with porcelain pieces at red heat; Chevrier; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 68; (1869); p. 1174 1176 ; (from Gmelin) View in Reaxys in neat (no solvent), passing PSCl3 vapor through a tube heated at red heat; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin)

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View in Reaxys in neat (no solvent), decompn. on passing through a tube with porcelain pieces at red heat; vol. P: MVol.C; 260, page 594 - 596 ; (from Gmelin) View in Reaxys

P P PP

S Cl

white

P Cl

Rx-ID: 26456371 View in Reaxys 214/251 Yield

Conditions & References

Chevrier,; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 63; (1866); p. 1003 1005 View in Reaxys Chevrier,; Journal fuer Praktische Chemie (Leipzig); vol. 100; (1867); p. 481 - 483 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys S

P Cl

Cl S

Rx-ID: 26125183 View in Reaxys 215/251 Yield

Conditions & References in neat (no solvent), addn. of P (excess) to boiling S2Cl2; Chevrier,; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 63; (1866); p. 1003 1005 View in Reaxys vol. S: MVol.B3; 113, page 1773 - 1775 ; (from Gmelin) View in Reaxys Cl

PCl Cl

Sb2Se3

Sb Cl

Rx-ID: 26081776 View in Reaxys 216/251 Yield

Conditions & References in neat (no solvent), react. on heating; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.C; 195, page 447 - 449 ; (from Gmelin) View in Reaxys

Se Cl

Rx-ID: 26125174 View in Reaxys 217/251 Yield

Conditions & References Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys in neat (no solvent) Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 11 - 11 View in Reaxys vol. Se: MVol.B; 55, page 121 - 123 ; (from Gmelin) View in Reaxys

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Cl P

Se Cl ClCl

Rx-ID: 26125208 View in Reaxys 218/251 Yield

Conditions & References Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys in neat (no solvent) Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 11 - 11 View in Reaxys Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 36 - 36 View in Reaxys vol. Se: MVol.B; 58, page 128 - 130 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Cl Fe

(v3)

Cl 2Fe

Rx-ID: 26136807 View in Reaxys 219/251 Yield

Conditions & References in neat (no solvent), react. with Fe at ambient temp.; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys Cl Cl

PCl Cl

Cl Sb Cl

Rx-ID: 26140447 View in Reaxys 220/251 Yield

Conditions & References in neat (no solvent), react. with Sb at ambient temp.; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl TB-5

Cl P

red

Rx-ID: 26168230 View in Reaxys 221/251 Yield

Conditions & References in neat (no solvent), formation of PCl3, HCl, red P and probably PH3 on passing PCl5 vapor and H2 through a tube at red heat; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys Baudrimont, E.; C. r. Acad. Sci. (Paris); vol. 51; (1860); p. 823 - 825 ; (from Gmelin) View in Reaxys in neat (no solvent), formation of PCl3, HCl, red P and probably PH3 on passing PCl5 vapor and H2 through a tube at red heat; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

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red

Rx-ID: 26171930 View in Reaxys 222/251 Yield

Conditions & References in not given, heating red P with concd. HCl in a sealed tube; Oppenheim; Bull. Soc. chim. Paris (2); vol. 1; (1864); p. 163 - 165 ; (from Gmelin) View in Reaxys in not given, heating red P with concd. HCl in a sealed tube; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys

Cl P

red

Rx-ID: 26171931 View in Reaxys 223/251 Yield

Conditions & References in not given, heating red P with concd. HCl in a sealed tube at 200 ° for 16 h; Oppenheim, A.; Bull. Soc. Chim. France (2); vol. 1; (1864); p. 163 - 165 View in Reaxys vol. P: MVol.C; 4, page 7 - 9 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl TB-5

Cl Al

Rx-ID: 26430759 View in Reaxys 224/251 Yield

Conditions & References in neat (no solvent), byproducts: Al-phosphide; react. with heated Al; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl TB-5 Cl

Cl Cl 2Pb

Se Cl ClCl

Rx-ID: 26487212 View in Reaxys 225/251 Yield

Conditions & References With Pb-selenide in neat (no solvent), react. of PCl5 vapor with Pb-selenide at red heat; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.C; 195, page 447 - 449 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl TB-5

H H

Cl P

red

Rx-ID: 26487213 View in Reaxys 226/251 Yield

Conditions & References With hydrogen in neat (no solvent), passing H2 and PCl5 vapor through a tube at red heat; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 ; (from Gmelin) View in Reaxys

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With H2 in neat (no solvent), passing H2 and PCl5 vapor through a tube at red heat; vol. P: MVol.C; 191, page 439 - 441 ; (from Gmelin) View in Reaxys

Cl 2Hg 2

Cl red

Rx-ID: 26173873 View in Reaxys 227/251 Yield

Conditions & References in neat (no solvent), heating red P with Hg2Cl2; Dumas, J. B.; Ann. Chim. Phys.; vol. 55; (1859); p. 129 - 210 View in Reaxys Dumas, J. B.; Liebigs Annalen der Chemie; vol. 113; (1860); p. 20 - 36 ; (from Gmelin) View in Reaxys in neat (no solvent), heating red P with Hg2Cl2; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys Cl

Cl Al

PCl Cl

Rx-ID: 26321087 View in Reaxys 228/251 Yield

Conditions & References With P, decompn. Weber, R.; Annalen der Physik (Weinheim, Germany); vol. 107; (1859); p. 377 ; (from Gmelin) View in Reaxys With P, decompn. vol. Al: MVol.B1; 7.1.1, page 206 - 219 ; (from Gmelin) View in Reaxys Cl

Cl Cl

PCl Cl

S– K+

Rx-ID: 26158220 View in Reaxys 229/251 Yield

Conditions & References in neat (no solvent), heating at higher temp.; formation of solid (CNCl)3, PCl3 and a large amount of S2Cl2; Schiff, H.; Liebigs Annalen der Chemie; vol. 106; (1858); p. 116 - 118 View in Reaxys vol. P: MVol.C; 195, page 447 - 449 ; (from Gmelin) View in Reaxys Cl

Cl Au Cl

(v3)

Rx-ID: 26125207 View in Reaxys 230/251 Yield

Conditions & References in not given, react. of P with AuCl3; Faraday, M.; Philosophical Transactions of the Royal Society of London; vol. 147; (1857); p. 145 - 181 ; (from Gmelin) View in Reaxys in not given, react. of P with AuCl3;

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vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys S Cl

red

P Cl

Cl Cl

Rx-ID: 26151235 View in Reaxys 231/251 Yield

Conditions & References in neat (no solvent), in coldness under inflammation; Woehler, F.; Hiller; Liebigs Annalen der Chemie; vol. 93; (1855); p. 274 - 276 View in Reaxys vol. S: MVol.B3; 113, page 1773 - 1775 ; (from Gmelin) View in Reaxys

S Cl

P Cl

Cl P

Rx-ID: 26429794 View in Reaxys 232/251 Yield

Conditions & References in not given, boiling with P for a longer period of time; formation of PCl3 and a yellow sublimate; Woehler, F.; Hiller; Liebigs Annalen der Chemie; vol. 93; (1855); p. 274 - 276 ; (from Gmelin) View in Reaxys in not given, boiling with P for a longer period of time; formation of PCl3 and a yellow sublimate; vol. P: MVol.C; 260, page 594 - 596 ; (from Gmelin) View in Reaxys

P P PP

S Cl

white

P Cl

Cl red

Rx-ID: 26456372 View in Reaxys 233/251 Yield

Conditions & References in melt Woehler,; Hiller,; Ann. Chim. Phys.; vol. 44; (1855); p. 56 - 57 View in Reaxys Woehler,; Hiller,; Justus Liebigs Annalen der Chemie; vol. 93; (1855); p. 274 - 276 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys in not given, in CO2 atm. Woehler,; Hiller,; Ann. Chim. Phys.; vol. 44; (1855); p. 56 - 57 View in Reaxys Woehler,; Hiller,; Justus Liebigs Annalen der Chemie; vol. 93; (1855); p. 274 - 276 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys P P PP

S Cl

P Cl

white

Rx-ID: 26475688 View in Reaxys 234/251 Yield

Conditions & References a yellow P-sulfide also formed Woehler,; Hiller,; Justus Liebigs Annalen der Chemie; vol. 93; (1855); p. 274 - 276

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View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys Cl

Cl Fe

(v3)

Rx-ID: 26125190 View in Reaxys 235/251 Yield

Conditions & References in not given, react. of FeCl3 with P; Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys Gladstone, J. H.; Journal fuer Praktische Chemie (Leipzig); vol. 49; (1850); p. 40 - 51 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction of FeCl3 with P to PCl3; Gladstone, J.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 345 View in Reaxys Gladstone, J. H.; Journal fuer Praktische Chemie (Leipzig); vol. 49; (1850); p. 41 - 41 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction of FeCl3 with P to PCl3; vol. Fe: MVol.B1; 106, page 236 - 238 ; (from Gmelin) View in Reaxys in not given, react. of FeCl3 with P; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys Cl Cl 2Cu

Rx-ID: 26125283 View in Reaxys 236/251 Yield

Conditions & References in not given, react. of CuCl2 with P; Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys Gladstone, J. H.; Journal fuer Praktische Chemie (Leipzig); vol. 49; (1850); p. 40 - 51 ; (from Gmelin) View in Reaxys in not given, react. of CuCl2 with P; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys Cl

red

PCl Cl Cl

Rx-ID: 26184757 View in Reaxys 237/251 Yield

Conditions & References With chlorine, at room temp. Schroetter, A.; Annalen der Physik (Weinheim, Germany); vol. 81; (1850); p. 276 - 298 View in Reaxys vol. P: MVol.B; 3.4.1.6, page 282 - 285 ; (from Gmelin) View in Reaxys

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Cl Cl 2Hg

Rx-ID: 26125286 View in Reaxys 238/251 Yield

Conditions & References in gas, by distn. over HgCl2 Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys vol. P: MVol.B; 3.4.2.3, page 310 - 316 ; (from Gmelin) View in Reaxys

Cl P

Rx-ID: 26469892 View in Reaxys 239/251 Yield

Conditions & References With chlorine in neat (no solvent) Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys With chlorine Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys vol. P: MVol.C; 215, page 494 - 496 ; (from Gmelin) View in Reaxys

P P PP

white

Rx-ID: 26483965 View in Reaxys 240/251 Yield

Conditions & References With iron(III) chloride, by heating Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys vol. P: MVol.B; 3.4.2.3, page 310 - 316 ; (from Gmelin) View in Reaxys With dimercury dichloride, heating vol. P: MVol.B; 3.4.2.3, page 310 - 316 View in Reaxys Gay-Lussac,; Thenard,; Recherches physico chimiques, Vol. 2, Paris 1811, p. 98, 176/80 ; (from Gmelin) View in Reaxys

P P PP white

Cl Cl

PCl Cl Cl

Rx-ID: 26483979 View in Reaxys 241/251 Yield

Conditions & References by heating Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 View in Reaxys vol. P: MVol.B; 3.4.2.2, page 307 - 310 ; (from Gmelin) View in Reaxys

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Cl P

Rx-ID: 26486160 View in Reaxys 242/251 Yield

Conditions & References With chlorine in neat (no solvent) Gladstone, J. H.; Philosophical Magazine (1798-1977); vol. 35; (1849); p. 345 - 355 ; (from Gmelin) View in Reaxys With Cl2 in neat (no solvent) vol. P: MVol.C; 228, page 522 - 524 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

(v2)

Cl N

Rx-ID: 26166868 View in Reaxys 243/251 Yield

Conditions & References in neat (no solvent), react. with Hg(CN)2 on heating; Wurtz, A.; Ann. Chim. Phys.; vol. 20; (1847); p. 471 - 481 View in Reaxys Wurtz, A.; Liebigs Annalen der Chemie; vol. 64; (1847); p. 245 - 247 View in Reaxys vol. P: MVol.C; 195, page 447 - 449 ; (from Gmelin) View in Reaxys

Cl Cl

PCl Cl

Rx-ID: 26167884 View in Reaxys 244/251 Yield

Conditions & References in water, decompn. with aq. HI; Gore, G.; Ann. Chim. Phys.; vol. 20; (1847); p. 472 - 481 View in Reaxys Wurtz, A.; Liebigs Annalen der Chemie; vol. 64; (1847); p. 245 - 247 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys Cl

O5P2

OP4

Rx-ID: 26446441 View in Reaxys 245/251 Yield

Conditions & References With Cl2 in neat (no solvent), reaction of Cl2 with dry P4O; Verrier, Le; Ann. Chim. Phys.; vol. 65; (1839); p. 257 - 279 View in Reaxys Verrier, Le; Liebigs Annalen der Chemie; vol. 27; (1838); p. 167 - 182 View in Reaxys vol. P: MVol.C; 31, page 60 - 62 ; (from Gmelin) View in Reaxys

Cl red

Rx-ID: 26151234 View in Reaxys 246/251

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Yield

Conditions & References in neat (no solvent), in coldness under inflammation; Gauthier de Chaubry; Ann. Chim. Phys.; vol. 7; (1818); p. 213 - 217 View in Reaxys vol. S: MVol.B3; 113, page 1773 - 1775 ; (from Gmelin) View in Reaxys Cl

Rx-ID: 26125182 View in Reaxys 247/251 Yield

Conditions & References in not given, react. of P with S2Cl2 at 40 °C; Gaultier de Claubry, H. F.; Ann. Chim. Phys.; vol. 7; (1817); p. 213 - 217 ; (from Gmelin) View in Reaxys in not given, react. of P with S2Cl2 at 40 °C; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys Cl Cl 2Hg 2

Rx-ID: 26125218 View in Reaxys 248/251 Yield

Conditions & References in neat (no solvent), react. of P vapor with heated Hg2Cl2; Berzelius, J. J.; Annalen der Physik (Weinheim, Germany); vol. 53; (1816); p. 393 - 446 ; (from Gmelin) View in Reaxys in neat (no solvent), react. of P vapor with heated Hg2Cl2; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys Cl

P P

Cl 2Hg 2

Rx-ID: 26150284 View in Reaxys 249/251 Yield

Conditions & References in neat (no solvent), heating P4 with Hg2Cl2; Davy, H.; Schweiggers J. Chem. Phys.; vol. 3; (1811); p. 79 - 120 View in Reaxys Gay-Lussac; Thenard; Recherches physico-chimiques, Bd. 2, Paris 1811, S. 177 View in Reaxys Gay-Lussac; Thenard; Recherches physico-chimiques, Bd. 2, Paris 1811, S. 179 View in Reaxys Gay-Lussac; Thenard; Recherches physico-chimiques, Bd. 2, Paris 1811, S. 98 ; (from Gmelin) View in Reaxys in neat (no solvent), heating P4 with Hg2Cl2; vol. P: MVol.C; 180, page 414 - 416 ; (from Gmelin) View in Reaxys Cl

P P

PCl Cl Cl

Rx-ID: 26454674 View in Reaxys 250/251

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Yield

Conditions & References With chlorine, depending on Cl2 volume vol. P: MVol.B; 3.4.1.6, page 282 - 285 View in Reaxys Berzelius, J. J.; Lehrbuch der Chemie, 5.Ed., Vol. 1, Dresden-Leipzig 1843, p. 235 View in Reaxys Berzelius, J. J.; Lehrbuch der Chemie, 5.Ed., Vol. 1, Dresden-Leipzig 1843, p. 236 View in Reaxys Berzelius, J. J.; Lehrbuch der Chemie, 5.Ed., Vol. 1, Dresden-Leipzig 1843, p. 239 ; (from Gmelin) View in Reaxys

Cl Cl

Sn ClCl

Cl Cl

PCl Cl

Sn Cl ClCl

Rx-ID: 26455857 View in Reaxys 251/251 Yield

Conditions & References in neat (no solvent), at 400°C; vol. Sn: MVol.C2; 16.16.1, page 259 - 260 View in Reaxys Groeneveld, W. L.; Diss. Leiden 1953, S. 58/61 ; (from Gmelin) View in Reaxys

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