Phosphorus trichloride [Phosphorus(III) chloride; PCl3] by Asch

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Reactions (251)

Substances (1)

Targets (379)

Citations (297)

Conditions

References A

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100

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With carbon dioxide

Danneel, H.; Schlottmann, F.

Z. Anorg. Chem., 1933 , vol. 212, p. 225 - 232 Full Text Show Details

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

101

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Rx-ID: 26479593 Find similar reactions

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in neat (no solvent)

Karantassis, T.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1933 , vol. 196, p. 1894 1896 Full Text Show Details

in neat (no solvent)

Gmelin Handbook: P: MVol.C, 228, page 522 - 524 Full Text Show Details

102

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Rx-ID: 26150292 Find similar reactions

>99

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in neat (no solvent) direct react. of P4 with gaseous Cl2;; purification on digesting with dry P and distn. in presence of P;;

Woodstock, W. H.; Adler, H.

Journal of the American Chemical Society, 1932 , vol. 54, p. 464 - 467 Full Text View citing articles Show Details

Dumas, J. B.

Ann. Chim. Phys., 1859 , vol. 55, p. 129 - 210 Full Text Show Details

Dumas, J. B.

Liebigs Annalen der Chemie, 1860 , vol. 113, p. 20 - 36 Full Text Show Details

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

With phosphorus trichoride in neat (no solvent) pouring liquid PCl3 upon P4; passing gaseous Cl2 in the liquid; apparatus described;;

Vanshejdt, A. A.; Tolstopjatov, V. M.

Zh. russk. fiz. chim. Obshch. Chast' chim., 1920 , vol. 52, p. 251 - 269 C. III, 1923 , p. 723 Full Text Show Details Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

With phosphorus trichoride in neat (no solvent) pouring liquid PCl3 upon P4; passing gaseous Cl2 in the liquid; use of a reflux condenser;; quantitative react.;;

Graebe, C.

Ber. dtsch. chem. Ges., 1901 , vol. 34, p. 645 - 652 Full Text Show Details

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Pierre, I.

Ann. Chim. Phys., 1847 , vol. 20, p. 5 - 53 Full Text Show Details

in neat (no solvent) direct react. of P4 with gaseous Cl2;; purification on digesting with dry P and distn. in presence of P;;

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103

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With ferrophosphorus in not given react. of ferrophosphorus with Cl2 forming PCl3*FeCl3; repeated addn. of ferrophosphorus forming FeCl2 and PCl3;; distn.;;

Urbain, E.

Patent: US1859543 , 1932 ; C. A., 1932 , p. 3881 Full Text Show Details

With ferrophosphorus in not given react. of ferrophosphorus with Cl2 forming PCl3*FeCl3; repeated addn. of ferrophosphorus forming FeCl2 and PCl3;; distn.;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

104

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Rx-ID: 26161228 Find similar reactions

With carbon monoxide in neat (no solvent) react. of POCl3 with CO and charcoal or active carbon above 400 °C;;

I. G. Farbenindustrie A.-G. Patent: DE492061 , 1930 ; C. I, 1930 , p. 2292 Full Text Show Details

With carbon in neat (no solvent) passing POCl3 vapor through a tube witg charcoal at red heat;;

Riban, J.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1882 , vol. 95, p. 1160 1163 Full Text Show Details

With carbon in neat (no solvent) passing gaseous POCl3 through a tube with charcoal heated at red heat;;

Riban, J.

C. r. Acad. Sci. (Paris), 1882 , vol. 95, p. 1160 - 1163 Full Text Show Details

With charcoal in neat (no solvent) passing gaseous POCl3 through a tube with charcoal heated at red heat;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

With CO; charcoal or active carbon in neat (no solvent) react. of POCl3 with CO and charcoal or active carbon above 400 °C;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

With charcoal in neat (no solvent) passing POCl3 vapor through a tube witg charcoal at red heat;;

Gmelin Handbook: P: MVol.C, 204, page 467 - 469 Full Text Show Details

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105

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Gmelin Handbook: C: MVol.C2, 1.10.5, page 150 - 151 Full Text Show Details

I. G. Farbenindustrie Patent: DE492061 , 1930 ;

With carbon monoxide; carbon

above 400°C, with charcoal or activated carbon;

Full Text Show Details

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106

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Raeder, M. G.

Skrifter - det Kongelige Norske Videnskabers Selskab, 1929 , # 3 p. 76 C., 1930 , vol. II, p. 3361 Full Text Show Details

Gmelin Handbook: Ti: MVol., 5.7, page 324 - 332 Full Text Show Details

107

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Rx-ID: 26441565 Find similar reactions

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in neat (no solvent) very fast absorption of gaseous HCl at -30°C with formation of PCl3 and H3PO3;;

Wolf, L.; Kalaehne, E.; Schmager, H.

Ber. dtsch. chem. Ges., 1929 , vol. 62, p. 1441 - 1449 Full Text Show Details

Gmelin Handbook: P: MVol.C, 37, page 74 - 75 Full Text Show Details

in neat (no solvent) byproducts: P, H3PO4; very fast absorption of gaseous HCl with formation of PCl3 and H3PO3, decomposition of small amount of H3PO3 to form P and H3PO4;;

Thorpe, T. E.; Tutton, A. E.

Journal of the Chemical Society, 1891 , vol. 59, p. 1019 - 1029 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 37, page 74 - 75 Full Text Show Details

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108

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in neat (no solvent) exothermic reaction;;

Karantassis, T.

Ann. Chim. Phys., 1927 , vol. 8, p. 71 - 119 Full Text Show Details

Karantassis, T.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1926 , vol. 182, p. 1931 1933 Full Text Show Details

in neat (no solvent) exothermic reaction;;

Gmelin Handbook: P: MVol.C, 228, page 522 - 524 Full Text Show Details

109

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Rx-ID: 26478673 Find similar reactions

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in neat (no solvent) exothermic reaction;;

Karantassis, T.

Ann. Chim. Phys., 1927 , vol. 8, p. 71 - 119 Full Text Show Details

Karantassis, T.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1926 , vol. 182, p. 1931 1933 Full Text Show Details

in neat (no solvent) exothermic reaction;;

Gmelin Handbook: P: MVol.C, 228, page 522 - 524 Full Text Show Details

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110

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Rx-ID: 26486165 Find similar reactions

in neat (no solvent) byproducts: SbCl5*PCl5; vigorous, exothermic reaction with SbCl5;;

Karantassis, T.

Ann. Chim. Phys., 1927 , vol. 8, p. 71 - 119 Full Text Show Details

Karantassis, T.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1926 , vol. 182, p. 1931 1933 Full Text Show Details

in neat (no solvent) byproducts: SbCl5*PCl5; vigorous, exothermic reaction with SbCl5;;

Gmelin Handbook: P: MVol.C, 228, page 522 - 524 Full Text Show Details

111

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Rx-ID: 26146365 Find similar reactions

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in slow reaction;

Lenher, W.; Kao, C. H.

Journal of the American Chemical Society, 1926 , vol. 48, p. 1550 - 1556 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

in neat (no solvent) explosion;;

Gmelin Handbook: Se: MVol.B, 55, page 121 - 123 Full Text Show Details

in neat (no solvent) explosion;;

Lenher, V.; Kao, C. H.

Journal of the American Chemical Society, 1926 , vol. 48, p. 1552 Full Text Show Details

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112

Synthesize Find similar Rx-ID: 26162745 Find similar reactions

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in not given react. with SbI3;;

Karantassis, T.

C. r. Acad. Sci. (Paris), 1926 , vol. 182, p. 1391 - 1393 Full Text Show Details

in not given react. with SbI3;;

Gmelin Handbook: P: MVol.C, 194, page 445 - 447 Full Text Show Details

113

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Rx-ID: 26168050 Find similar reactions

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Lenher, W.; Kao, C. H.

Journal of the American Chemical Society, 1926 , vol. 48, p. 1550 - 1556 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

in slow reaction;

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114

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Rx-ID: 26444087 Find similar reactions

in neat (no solvent) explosion;;

Gmelin Handbook: Se: MVol.B, 55, page 121 - 123 Full Text Show Details

in neat (no solvent) explosion;;

Lenher, V.; Kao, C. H.

Journal of the American Chemical Society, 1926 , vol. 48, p. 1552 Full Text Show Details

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115

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Lenher, W.; Kao, C. H.

Journal of the American Chemical Society, 1926 , vol. 48, p. 1550 - 1556 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

with explosion;

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116

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Rx-ID: 26483986 Find similar reactions

Lenher, W.; Kao, C. H.

Journal of the American Chemical Society, 1926 , vol. 48, p. 1550 - 1556 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

with explosion;

117

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Rx-ID: 26112944 Find similar reactions

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in neat (no solvent) no react. below 600 °C;;

Budnikoff, P. P.; Shilov, E. A.

Journal of the Society of Chemical Industry, London, 1923 , vol. 42, p. 378 - 378 Full Text Show Details

in neat (no solvent) no react. below 600 °C;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

118

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Rx-ID: 26112945 Find similar reactions

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With silica gel in neat (no solvent) byproducts: SiCl4; react. of Ca3(PO4)2 with S2Cl2 at 1000 °C in presence of SiO2;; after 1 h 9.5 percent phosphate are caused to react.;;

Budnikoff, P. P.; Shilov, E. A.

Journal of the Society of Chemical Industry, London, 1923 , vol. 42, p. 378 - 378 Full Text Show Details

in neat (no solvent) react. of Ca3(PO4)2 with S2Cl2 at 1000 °C;; after 1 h 19.5 percent phosphate are caused to react.;;

Budnikoff, P. P.; Shilov, E. A.

Journal of the Society of Chemical Industry, London, 1923 , vol. 42, p. 378 - 378 Full Text Show Details

in neat (no solvent) react. of Ca3(PO4)2 with S2Cl2 at 1000 °C;; after 1 h 19.5 percent phosphate are caused to react.;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

With SiO2 in neat (no solvent) byproducts: SiCl4; react. of Ca3(PO4)2 with S2Cl2 at 1000 °C in presence of SiO2;; after 1 h 9.5 percent phosphate are caused to react.;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

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119

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Rx-ID: 26124970 Find similar reactions

in neat (no solvent) prepn. of PCl3 and AsCl3 by react. of a mixt. of powdered dry P and As in a column with Cl2; use of the counterflow principle;; isolation of the chloride by fractionation;;

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

J. Michael & Co. Patent: DE369299 , 1923 ; C. II, 1923 , p. 726 Full Text Show Details

in not given product mixture;;

Gmelin Handbook: As: MVol., 138, page 368 - 369 Full Text Show Details

J. Michael & Co. Patent: DE369299 , 1922 ; C. II, 1923 , p. 726 Full Text Show Details

120

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Rx-ID: 26151173 Find similar reactions

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in neat (no solvent) no react. below 600 °C;;

Budnikoff, P. P.; Shilov, E. A.

Journal of the Society of Chemical Industry, London, 1923 , vol. 42, p. 378 - 378 Full Text Show Details

in neat (no solvent) no react. below 600 °C;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

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121

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Rx-ID: 26151174 Find similar reactions

With silica gel in neat (no solvent) byproducts: SiCl4; react. of Ca(PO3)2 with S2Cl2 at 1000 °C in presence of SiO2;;

Budnikoff, P. P.; Shilov, E. A.

Journal of the Society of Chemical Industry, London, 1923 , vol. 42, p. 378 - 378 Full Text Show Details

With SiO2 in neat (no solvent) byproducts: SiCl4; react. of Ca(PO3)2 with S2Cl2 at 1000 °C in presence of SiO2;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

122

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Rx-ID: 26140769 Find similar reactions

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in neat (no solvent) incineration of a mixture with Si and PCl5 by ignition of a special blaster;;

Berger, E.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1920 , vol. 171, p. 29 - 32 Full Text Show Details

in neat (no solvent) incineration of a mixture with Si and PCl5 by ignition of a special blaster;;

Gmelin Handbook: Si: MVol.B, 47, page 121 - 123 Full Text Show Details

123

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Rx-ID: 26162887 Find similar reactions

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Gmelin Handbook: P: MVol.B, 3.6.1, page 329 - 331 Full Text Show Details

Berger, E.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1920 , vol. 171, p. 29 - 32 Full Text Show Details

mixt. of red P, CCl4, kieselgel and Al;

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124

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in neat (no solvent) excess SOCl2; 125°C;;

North, H. B.; Thomson, J. C.

Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details

in neat (no solvent) excess SOCl2; 125°C;;

Gmelin Handbook: S: MVol.B3, 124, page 1796 - 1798 Full Text Show Details

125

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Rx-ID: 26105601 Find similar reactions

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in neat (no solvent) excess of SOCl2; 180°C;;

North, H. B.; Thomson, J. C.

Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details

in neat (no solvent) excess of SOCl2; 180°C;;

Gmelin Handbook: S: MVol.B3, 124, page 1796 - 1798 Full Text Show Details

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126

Synthesize Find similar Rx-ID: 26144307 Find similar reactions

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in melt at 125°C;

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

North, H. B.; Thomson, J. C.

Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details

in neat (no solvent) excess SOCl2; 125°C;;

North, H. B.; Thomson, J. C.

Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details

in neat (no solvent) excess SOCl2; 125°C;;

Gmelin Handbook: S: MVol.B3, 124, page 1796 - 1798 Full Text Show Details

127

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Rx-ID: 26144308 Find similar reactions

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in neat (no solvent) excess of SOCl2; 180°C;;

North, H. B.; Thomson, J. C.

Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details

in neat (no solvent) excess of SOCl2; 180°C;;

Gmelin Handbook: S: MVol.B3, 124, page 1796 - 1798 Full Text Show Details

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128

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Rx-ID: 26144309 Find similar reactions

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

North, H. B.; Thomson, J. C.

Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details

at 180°C;

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129

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Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

North, H. B.; Thomson, J. C.

Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details

in melt at 125°C;

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130

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Rx-ID: 26441676 Find similar reactions

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

North, H. B.; Thomson, J. C.

Journal of the American Chemical Society, 1918 , vol. 40, p. 774 - 777 Full Text View citing articles Show Details

at 180°C;

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131

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Strecker; Grossmann

Chemische Berichte, 1916 , vol. 49, p. 75 Full Text View citing articles Show Details

T=180°C;

132

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Rx-ID: 26167876 Find similar reactions

A: 0%

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Strecker, W.; Grossmann, C.

Ber. dtsch. chem. Ges., 1916 , vol. 49, p. 63 - 87 Full Text Show Details

Gmelin Handbook: P: MVol.C, 192, page 441 - 443 Full Text Show Details

in not given react. with P2Se5 forming Se2Cl2 and PCl3, no formation of PSeCl3;;

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133

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Rx-ID: 26184784 Find similar reactions

Wolf, L.

Ber. Dtsch. Chem. Ges., 1915 , vol. 48, p. 1272 - 1280 Full Text Show Details

in neat (no solvent) in a sealed tube at 300°C;;

Gmelin Handbook: Hg: MVol.B2, 51, page 503 - 505 Full Text Show Details

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134

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in neat (no solvent) heating red P and HgCl2 in a sealed tube at 300 °C;;

Wolf, L.

Ber. dtsch. chem. Ges., 1915 , vol. 48, p. 1272 - 1280 Full Text Show Details

in neat (no solvent) heating red P and HgCl2 in a sealed tube at 300 °C;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

135

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Rx-ID: 26125235 Find similar reactions

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Baxter, G. P.; Moore, C. J.

Journal of the American Chemical Society, 1912 , vol. 34, p. 1644 - 1657 Full Text View citing articles Show Details

Baxter, G. P.; Moore, C. J.

Z. anorg. allg. Chem., 1913 , vol. 80, p. 185 - 200 Full Text Show Details Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

in neat (no solvent) react. of a small excess of Cl2 with P in vac. under exclusion of H2O;; removal of formed PCl5 by fractional distn..;;

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136

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Besson, A.; Fournier, L.

C. r. Acad. Sci. (Paris), 1910 , vol. 150, p. 102 - 104 Full Text Show Details Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

in neat (no solvent) heating on light at 100 °C; formation of PCl3 and a orange-yellow or light red compound which is a mixt. of red P and P-chlorides;;

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137

Synthesize Find similar Rx-ID: 6208054

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Autenrieth; Geyer

Chemische Berichte, 1908 , vol. 41, p. 4254 Full Text View citing articles Show Details

T=-15°C;

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138

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Rx-ID: 7449690 Find similar reactions

Michaelis; Linke

Chemische Berichte, 1907 , vol. 40, p. 3420 Full Text View citing articles Show Details

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139

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Rx-ID: 7449691 Find similar reactions

Michaelis; Linke

Chemische Berichte, 1907 , vol. 40, p. 3420 Full Text View citing articles Show Details

140

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Rx-ID: 26168997 Find similar reactions

Wichelhaus, H.

Ber., 1905 , vol. 38, p. 1725 - 1728 Full Text Show Details

Gmelin Handbook: P: MVol.B, 3.6.1, page 329 - 331 Full Text Show Details

Cl-poor org. products formed too;

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141

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Rx-ID: 7449692 Find similar reactions

Bourgeois; Petermann

Recueil des Travaux Chimiques des Pays-Bas, 1903 , vol. 22, p. 350 Full Text View citing articles Show Details

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142

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Rx-ID: 26393026 Find similar reactions

in neat (no solvent) heating equimolar amounts of PCl5 and PH4I at 135°C;;

Fireman, E.; Fireman, P.

American Chemical Journal, 1903 , vol. 30, p. 116 - 133 Full Text Show Details

in neat (no solvent) heating equimolar amounts in sealed tube to 120 to 135°C;;

Fireman, E.; Fireman, P.

American Chemical Journal, 1903 , vol. 30, p. 116 - 133 Full Text Show Details

in neat (no solvent) heating equimolar amounts in sealed tube to 120 to 135°C;;

Gmelin Handbook: P: MVol.C, 229, page 525 - 527 Full Text Show Details

in neat (no solvent) heating equimolar amounts of PCl5 and PH4I at 135°C;;

Gmelin Handbook: P: MVol.C, 227, page 520 - 522 Full Text Show Details

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143

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Rx-ID: 26139493 Find similar reactions

in neat (no solvent) 100°C; presence of AlCl3;;

Ruff, O.

Ber., 1901 , vol. 34, p. 1749 - 1758 Full Text Show Details

Gmelin Handbook: S: MVol.B3, 106, page 1761 - 1762 Full Text Show Details

in neat (no solvent) 250°C;;

Gmelin Handbook: S: MVol.B3, 106, page 1761 - 1762 Full Text Show Details

Goldschmidt, H.

C., Jahresber. der Lese- und Redehalle der Deutschen Stud. Prag1880/81 1881 , p. 489/95 Full Text Show Details

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144

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Defacqz, E.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1901 , vol. 132, p. 32 Full Text Show Details

Gmelin Handbook: W: MVol., 2.15, page 205 - 206 Full Text Show Details

With Cl2

at red heat;

145

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Guichard

Chemische Berichte, 1899 , vol. 32, p. 1574 Full Text Show Details

Michaelis

Chemische Berichte, 1880 , vol. 13, p. 2174 Full Text View citing articles Show Details

T=135°C;

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146

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With iron(III) chloride

Granger, A.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1896 , vol. 122, p. 936 937 Full Text Show Details

Gmelin Handbook: P: MVol.B, 3.4.2.3, page 310 - 316 Full Text Show Details

With FeCl3

Granger, A.

Ann. Chim. Phys., 1898 , vol. 14, p. 5 - 90 Full Text Show Details

147

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With copper dichloride

by heating at red heat;

Gmelin Handbook: P: MVol.B, 3.4.2.3, page 310 - 316 Full Text Show Details

With CuCl2

by heating at red heat;

Granger, A.

Ann. Chim. Phys., 1898 , vol. 14, p. 5 - 90 Full Text Show Details

148

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Rx-ID: 26146999 Find similar reactions

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in not given react. of Cl2 with phosphorus suboxide;;

Besson, A.

C. r. Acad. Sci. (Paris), 1897 , vol. 124, p. 763 - 765 Full Text Show Details Verrier, Le Liebigs Annalen der Chemie, 1838 , vol. 27, p. 167 - 182 Full Text Show Details Verrier, U. J. J. Le Ann. Chim. Phys., 1837 , vol. 65, p. 257 - 279 Full Text Show Details

in not given react. of Cl2 with phosphorus suboxide;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

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149

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in neat (no solvent) fast reaction at temperature of water bath;;

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Besson, A.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1897 , vol. 124, p. 1346 1349 Full Text Show Details

Gmelin Handbook: P: MVol.C, 227, page 520 - 522 Full Text Show Details

in neat (no solvent) fast reaction at temperature of water bath;;

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150

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Rx-ID: 6711952 Find similar reactions

Michaelis; Schroeter

Chemische Berichte, 1894 , vol. 27, p. 494 Full Text View citing articles Show Details

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151

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in neat (no solvent) heating PF3Cl2 with P at 120 °C;;

Poulenc, C.

Ann. Chim. Phys., 1891 , vol. 24, p. 548 - 570 Full Text Show Details

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

in neat (no solvent) decompn. with P at 110 °C;;

Poulenc, C.

Ann. Chim. Phys., 1891 , vol. 24, p. 548 - 570 Full Text Show Details

Poulenc, C.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 113, p. 75 - 78 Full Text Show Details

Gmelin Handbook: P: MVol.C, 211, page 484 - 487 Full Text Show Details

152

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Rx-ID: 26125240 Find similar reactions

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Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

Moissan, H.

Das Fluor und seine Verbindungen, Berlin 1900, p. 167 Full Text Show Details

Poulenc, C.

Ann. Chim. Phys., 1891 , vol. 24, p. 548 - 570 Full Text Show Details

Poulenc, C.

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 113, p. 75 - 78 Full Text Show Details

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153

Synthesize Find similar Rx-ID: 26167840 Find similar reactions

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in not given react. of PCl5 with P4O6;;

Thorpe, T. E.; Tutton, A. E.

Journal of the Chemical Society, 1891 , vol. 59, p. 1019 - 1029 Full Text View citing articles Show Details

in not given react. with P4O6 under evolution of heat;;

Thorpe, T. E.; Tutton, A. E.

Journal of the Chemical Society, 1891 , vol. 59, p. 1019 - 1029 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 192, page 441 - 443 Full Text Show Details

in not given react. of PCl5 with P4O6;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

154

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Rx-ID: 26168482 Find similar reactions

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in neat (no solvent) react. of gaseous HCl with P4O6;;

Thorpe, T. E.; Tutton, A. E.

Journal of the Chemical Society, 1891 , vol. 59, p. 1019 - 1029 Full Text View citing articles Show Details

in neat (no solvent) react. of gaseous HCl with P4O6;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

155

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in vac.;

Geisenheimer, G.

Ann. Chim. Phys., 1891 , vol. 23, p. 246 - 282 Full Text Show Details

Gmelin Handbook: Ir: MVol., 5.12, page 83 - 86 Full Text Show Details

With Cl2

Geisenheimer, G.

Ann. Chim. Phys., 1891 , vol. 23, p. 246 - 282 Full Text Show Details

Gmelin Handbook: Ir: MVol., 5.12, page 83 - 86 Full Text Show Details

156

Rx-ID: 26281822 Find similar reactions

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Rx-ID: 26284121 Find similar reactions

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Geisenheimer, G.

Ann. Chim. Phys., 1891 , vol. 23, p. 246 - 282 Full Text Show Details

Gmelin Handbook: Ir: MVol., 5.12, page 83 - 86 Full Text Show Details

under reduced pressure;

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157

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Rx-ID: 26441564 Find similar reactions

Thorpe, T. E.; Tutton, A. E.

Journal of the Chemical Society, 1891 , vol. 59, p. 1019 - 1029 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 37, page 74 - 75 Full Text Show Details

in neat (no solvent) vigorous exothermic reaction at ambient temperature (cooling with ice is necessary);;

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158

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Rx-ID: 7920553 Find similar reactions

Michaelis; Schenk

Justus Liebigs Annalen der Chemie, 1890 , vol. 260, p. 6 Chemische Berichte, 1888 , vol. 21, p. 1501 Full Text View citing articles Show Details

4-<Dimethylanilin-phenyl>-dichlorphosphin bewirkt Spaltung;

159

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Doerken

Chemische Berichte, 1888 , vol. 21, p. 1507 Full Text View citing articles Show Details

Broglie

Chemische Berichte, 1877 , vol. 10, p. 628 Full Text View citing articles Show Details

T=280 - 300°C;

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160

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Rx-ID: 5735882 Find similar reactions

Hofmann,A.W.

Chemische Berichte, 1886 , vol. 19, p. 2092 Full Text View citing articles Show Details

Hofmann,A.W.

Chemische Berichte, 1885 , vol. 18, p. 2800 Full Text View citing articles Show Details

T=220 - 230°C;

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161

Synthesize Find similar Rx-ID: 26435482 Find similar reactions

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in neat (no solvent) byproducts: HF; heating with gaseous HCl;;

Moissan, H.

Das Fluor und seine Verbindungen, Berlin 1900, S. 170 Full Text Show Details

in neat (no solvent) byproducts: HF; heating with gaseous HCl;;

Moissan, H.

Ann. Chim. Phys., 1885 , vol. 6, p. 433 - 467 Full Text Show Details

Gmelin Handbook: P: MVol.C, 171, page 393 - 395 Full Text Show Details

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162

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Rx-ID: 26062834 Find similar reactions

in not given react. of P with S2O5Cl2;;

Heumann, K.; Koechlin, P.

Ber. dtsch. chem. Ges., 1883 , vol. 16, p. 479 - 483 Full Text Show Details

in not given react. of P with S2O5Cl2;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

163

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Rx-ID: 26062844 Find similar reactions

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Heumann, K.; Koechlin, P.

Ber., 1883 , vol. 16, p. 479 - 483 Full Text Show Details

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

164

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Rx-ID: 26345170 Find similar reactions

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Heumann, K.; Koechlin, P.

Ber., 1883 , vol. 16, p. 479 - 483 Full Text Show Details

Gmelin Handbook: S: MVol.B3, 141, page 1826 - 1828 Full Text Show Details

in neat (no solvent)

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165

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Rx-ID: 26144306 Find similar reactions

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

Koechlin, P.; Heumann, K.

Ber., 1882 , vol. 15, p. 1736 - 1738 Full Text Show Details

in cold;

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166

Synthesize Find similar Rx-ID: 26441674 Find similar reactions

by heating;

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Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310

Full Text Show Details

Koechlin, P.; Heumann, K.

Ber., 1882 , vol. 15, p. 1736 - 1738 Full Text Show Details

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167

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Rx-ID: 7920555 Find similar reactions

Michaelis; Paneck

Chemische Berichte, 1881 , vol. 14, p. 405 Full Text View citing articles Show Details

T=200°C;

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168

Synthesize Find similar Rx-ID: 26127052 Find similar reactions

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in neat (no solvent) heating PCl5 with Pb at 200-250 °C;;

Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) heating at 250°C;;

Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: Pb: MVol.B1, 13.6.10, page 324 - 324 Full Text Show Details

169

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Rx-ID: 26128952 Find similar reactions

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in neat (no solvent) equilibrium;;

Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: As: MVol., 50, page 179 - 181 Full Text Show Details

in neat (no solvent) at room temp.;;

Baudrimont, E.

Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67 Full Text Show Details

Gmelin Handbook: As: MVol., 50, page 179 - 181 Full Text Show Details

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170

Synthesize Find similar Rx-ID: 26130736 Find similar reactions

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Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) heating PCl5 with Al at 200-250 °C;;

171

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Rx-ID: 26133496 Find similar reactions

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Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) heating PCl5 with Cu at 200-250 °C;;

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172

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Rx-ID: 26133497 Find similar reactions

Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) heating an excess of PCl5 with Cu at 200-250 °C;;

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173

Synthesize Find similar Rx-ID: 26136808 Find similar reactions

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Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) heating PCl5 with Fe at 200-250 °C;;

174

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Rx-ID: 26138521 Find similar reactions

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Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) heating PCl5 with Hg at 200-250 °C;;

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175

Synthesize Find similar Rx-ID: 26139874 Find similar reactions

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Baudrimont, E.

Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) react. with Sn on heating;;

Goldschmidt, H.

Chem. Centralbl. Repertorium (3), 1881 , vol. 12, p. 489 - 495 Full Text Show Details

Gmelin Handbook: Sn: MVol.B, 14.4.8, page 360 - 360 Full Text Show Details

Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) heating PCl5 with Sn at 200-250 °C;;

176

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Rx-ID: 26142568 Find similar reactions

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in neat (no solvent) heating PCl5 with Zn at 200-250 °C;;

Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) byproducts: Zn-phosphide; heating with Zn in a sealing tube at 100 °C;;

Casselmann, W.

Liebigs Annalen der Chemie, 1856 , vol. 98, p. 213 - 236 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) moderate heating with Zn;;

Baudrimont, E.

Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

177

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Rx-ID: 26167891 Find similar reactions

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Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) byproducts: Pt-chloride; heating PCl5 with Pt at 200-250 °C;;

178

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Rx-ID: 26167892 Find similar reactions

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Goldschmidt, H.

C., 1881 , p. 489 - 495 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in neat (no solvent) heating PCl5 with Ag at 200-250 °C;;

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179

Synthesize Find similar Rx-ID: 8265003 Find similar reactions

Koehler

Chemische Berichte, 1880 , vol. 13, p. 1626 Full Text View citing articles Show Details

beim Erhitzen;

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180

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Rx-ID: 26119866 Find similar reactions

at room temperature also formation of unknown red substance;;

Gmelin Handbook: Mg: MVol.A2, 41, page 307 - 309 Full Text Show Details

Reinitzer, B.; Goldschmidt, H.

Ber. Wien. Akad., 1880 , vol. 81, p. 831 - 831 Full Text Show Details

at room temperature also formation of unknown red substance;;

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181

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Rx-ID: 26128935 Find similar reactions

in neat (no solvent) react. on heating at 250 °C for a longer period of time;;

Reinitzer, B.; Goldschmidt, H.

Ber., 1880 , vol. 13, p. 845 - 851 Full Text Show Details

in neat (no solvent) react. on heating at 250 °C for a longer period of time;;

Gmelin Handbook: P: MVol.C, 204, page 467 - 469 Full Text Show Details

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182

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Rx-ID: 26130699 Find similar reactions

in neat (no solvent) react. with Al at 100 °C; formation of PCl3, Al2Cl6, Al2(PO4)2 and a yellow mass;;

Reinitzer, B.; Golschmidt, H.

Ber., 1880 , vol. 13, p. 845 - 851 Full Text Show Details

in neat (no solvent) react. with Al at 100 °C; formation of PCl3, Al2Cl6, Al2(PO4)2 and a yellow mass;;

Gmelin Handbook: P: MVol.C, 206, page 471 - 475 Full Text Show Details

183

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Rx-ID: 26136780 Find similar reactions

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in neat (no solvent) react. with powdered Fe starting at 100 °C, react. accelerated at 120 °C;;

Reinitzer, B.; Golschmidt, H.

Ber., 1880 , vol. 13, p. 845 - 851 Full Text Show Details

in neat (no solvent) react. with powdered Fe starting at 100 °C, react. accelerated at 120 °C;;

Gmelin Handbook: P: MVol.C, 206, page 471 - 475 Full Text Show Details

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184

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Rx-ID: 26138489 Find similar reactions

in neat (no solvent) heating with an excess of Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2;;

Reinitzer, B.; Golschmidt, H.

Ber., 1880 , vol. 13, p. 845 - 851 Full Text Show Details

in neat (no solvent) heating with an excess of Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2;;

Gmelin Handbook: P: MVol.C, 206, page 471 - 475 Full Text Show Details

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185

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Rx-ID: 26138490 Find similar reactions

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in neat (no solvent) byproducts: Hg-phosphate; heating with an excess of POCl3 with Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2, HgCl2 and Hg-phosphate;;

Reinitzer, B.; Golschmidt, H.

Ber., 1880 , vol. 13, p. 845 - 851 Full Text Show Details

Gmelin Handbook: P: MVol.C, 206, page 471 - 475 Full Text Show Details

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Find similar

186

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Rx-ID: 26139852 Find similar reactions

Goldschmidt, H.

Chem. Centralbl. Repertorium (4), 1864 , vol. 2, p. 492 Full Text Show Details

Reinitzer, B.; Goldschmidt, H.

Sitz.-Ber. Akad. Wiss. Wien Math.-Naturw. KI. II, 1880 , vol. 81, p. 820 - 836 Full Text Show Details

Gmelin Handbook: Sn: MVol.B, 14.4.8, page 360 - 360 Full Text Show Details

100°C;

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187

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Rx-ID: 26142518 Find similar reactions

in neat (no solvent) byproducts: P2O5, P2O3Cl4; react. of Zn dust with POCl3 at 250 °C;;

Reinitzer, B.; Golschmidt, H.

Ber., 1880 , vol. 13, p. 845 - 851 Full Text Show Details

in neat (no solvent) byproducts: P2O5, P2O3Cl4; react. of Zn dust with POCl3 at 250 °C;;

Gmelin Handbook: P: MVol.C, 206, page 471 - 475 Full Text Show Details

188

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Rx-ID: 26150277 Find similar reactions

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in neat (no solvent) react. starting at 200 °C;;

Reinitzer, B.; Goldschmidt, H.

Ber., 1880 , vol. 13, p. 845 - 851 Full Text Show Details

in neat (no solvent) react. starting at 200 °C;;

Gmelin Handbook: P: MVol.C, 204, page 467 - 469 Full Text Show Details

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189

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Rx-ID: 26161305 Find similar reactions

in neat (no solvent) byproducts: P2O3Cl4; heating with Ag in a sealing tube at 250 °C; react. of POCl3 with Ag forming Ag2O and PCl3, react. of Ag2O with POCl3 forming Ag3PO4 and AgCl or Ag4P2O7 and AgCl, react. of POCl3 with Ag3PO4 forming P2O5 and AgCl and with P2O5 forming P2O3Cl4;;

Reinitzer, B.; Golschmidt, H.

Ber., 1880 , vol. 13, p. 845 - 851 Full Text Show Details

Gmelin Handbook: P: MVol.C, 206, page 471 - 475 Full Text Show Details

190

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Rx-ID: 26428490 Find similar reactions

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Reinitzer, B.; Goldschmidt, H.

Ber., 1880 , vol. 13, p. 850 - 850 Full Text Show Details

Gmelin Handbook: Mg: MVol.B3, 36, page 397 - 398 Full Text Show Details

reaction of Mg with POCl3;;

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191

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Rx-ID: 26473182 Find similar reactions

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

Reinitzer, B.; Goldschmidt, H.

Ber., 1880 , vol. 13, p. 845 - 851 Full Text Show Details

at 250°C;

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192

Synthesize Find similar Rx-ID: 7066846 Find similar reactions

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Geuther; Hergt

Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1876 , p. 206 Full Text View citing articles Show Details

193

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Rx-ID: 7084162 Find similar reactions

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Chambon

Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1876 , p. 205 Full Text View citing articles Show Details

T=165°C;

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194

Synthesize Find similar Rx-ID: 7920554 Find similar reactions

Michaelis

Justus Liebigs Annalen der Chemie, 1876 , vol. 181, p. 322 Chemische Berichte, 1873 , vol. 6, p. 819 Full Text View citing articles Show Details

T=180°C;

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195

Synthesize Find similar Rx-ID: 7924794 Find similar reactions

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Michaelis; Ananow

Chemische Berichte, 1874 , vol. 7, p. 1688 Full Text View citing articles Show Details

Michaelis

Justus Liebigs Annalen der Chemie, 1876 , vol. 181, p. 322 Chemische Berichte, 1873 , vol. 6, p. 819 Full Text View citing articles Show Details

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196

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Rx-ID: 26115045 Find similar reactions

in not given react. at ambient temp.; exothermic react.;;

Chambon, E.

Jenaische Z. Med. Naturw. (2) 2. Suppl.-H., 1876 , vol. 3, p. 92 - 103 Full Text Show Details

in neat (no solvent) react. on heating moderately;;

Geuther, A.

Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 380 - 390 Full Text Show Details

Geuther, A.

J. prakt. Chem. (2), 1874 , vol. 8, p. 359 - 372 Full Text Show Details

in not given react. at ambient temp.; exothermic react.;;

Geuther, A.

Journal fuer Praktische Chemie (Leipzig), 1874 , vol. 8, p. 359 - 372 Full Text Show Details

Gmelin Handbook: P: MVol.C, 57, page 122 - 124 Full Text Show Details

in neat (no solvent) react. on heating moderately;;

Gmelin Handbook: P: MVol.C, 205, page 469 - 471 Full Text Show Details

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197

Synthesize Find similar Rx-ID: 26115051 Find similar reactions

in not given react. with PCl5;;

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Chambon, E.

Jenaische Z. Med. Naturw. (2) 2. Suppl.-H., 1876 , vol. 3, p. 92 - 103 Full Text Show Details

in not given react. with H3PO3 at ambient temp.;;

Geuther, A.

Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 380 - 390 Full Text Show Details

Geuther, A.

J. prakt. Chem. (2), 1874 , vol. 8, p. 359 - 372 Full Text Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in not given react. with PCl5;;

Geuther, A.

Journal fuer Praktische Chemie (Leipzig), 1874 , vol. 8, p. 359 - 372 Full Text Show Details

Gmelin Handbook: P: MVol.C, 57, page 122 - 124 Full Text Show Details

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198

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Rx-ID: 26150365 Find similar reactions

in neat (no solvent) react. with PBr5 in a sealing tube at ambient temp. or at 40 °C;;

Geuther, A.

Jena. Z. Med. Naturwiss., 1876 , vol. 10, p. 128 - 140 Full Text Show Details

Gmelin Handbook: P: MVol.C, 192, page 441 - 443 Full Text Show Details