14_page_Phosphorus trichloride [Phosphorus(III) chloride; PCl3] [CAS 7719-12-2; InChIKey FAIAAWCVCHQ by Asch

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Citations (297)

References A

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T=70°C; P=0.01 - 0.1 Torr;

Gazizov; Khairullin; Karimova

Russian Journal of General Chemistry, 2013 , vol. 83, # 12 p. 2281 - 2292 Zh. Obshch. Khim., 2013 , vol. 83, # 12 p. 1996 - 2007,12 Title/Abstract Full Text View citing articles Show Details

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Henkel and Cie G.m.b.H.

Patent: US3979385 A1, 1976 ; Title/Abstract Full Text Show Details

XIV:EXAMPLE XIV

EXAMPLE XIV 127.2 parts of N-cyclohexylformamide and 81 parts of phosphorous acid were reacted with 137.3 parts of phosphorus trichloride at 70°C, and maintained for 5 hours at this temperature. The reaction product was dissolved in water, treated with acetone and the precipitate separated. A 25percent yield of N-cyclohexyl-1-aminomethane-1,1-diphosphonic acid, based on PCl3, was obtained.

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Hoechst AG

Patent: US5210260 A1, 1993 ; Title/Abstract Full Text Show Details

5:EXAMPLES

5) The mixture of 92.2 g (=0.3 mol) of 2,4-di-tert-butylphenyl dichlorophosphite and 0.1 g (=0.9 mmol) of 4-dimethylaminopyridine was stirred for 6 hours at 190° C. while passing through a gentle stream of nitrogen. In the course of this, PCl3 formed was carried off. The mixture was allowed to cool, the distillative removal of residual starting material was dispensed with and an 31 P-NMR spectrum was prepared.

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Becton Dickinson and Company

Patent: US5503816 A1, 1996 ; Title/Abstract Full Text Show Details

1.C:C. C. Phosphosilicates Phosphosilicates prepared by reacting SiCl4 with 0.1 to 5 equivalents of PCl3 were prepared using the following ratios of PCl3 (2M in CH2 Cl2; Aldrich Chemical Co.) and SiCl4 (Petrarch Systems):

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International Flavors and Fragrances Inc.

Patent: US4985402 A1, 1991 ; Title/Abstract Full Text Show Details

Examples of dehydrating agents useful in this reaction are as follows: (i) mixtures of copper sulfate and acetic anhydride; (ii) phosphorous oxychloride; (iii) phosphorous trichloride; (iv) phosphorous pentoxide; (vi) acetyl chloride.

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Weferling; Norbert; Klose; Werner

Patent: US4752648 A1, 1988 ; Title/Abstract Full Text Show Details

5:(preparation of di-n-butylchlorophosphine)

EXAMPLE 5 (preparation of di-n-butylchlorophosphine) 148 g (1 mol) di-n-butylphosphine was dropped at a maximum reaction temperature of 30° C. into a suspension of 232 g (1.1 mol) PCl5 in 500 ml toluene. HCl and PCl3 formed during the reaction were removed under a vacuum of 130 mbar and condensed in a cooling trap.

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Stauffer Chemical Company

Patent: US3976690 A1, 1976 ; Title/Abstract Full Text Show Details

19.B:B. B. Propylene, PCl3 and Iodine Catalyst In a 316 stainless steel autoclave were placed 45 grams (1.07 moles) of propylene, 135 (0.985 moles) of PCl3 and 0.1 grams of iodine as catalyst. The mixture was reacted for 12 hours at 200°C. Analysis of the products by 31 P-nmr showed that 98percent of the phosphorus was unreacted PCl3.

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Stauffer Chemical Company

Patent: US3976690 A1, 1976 ; Title/Abstract Full Text Show Details

19.C:C. C. Isobutene, PCl3 and Iodine Catalyst In a 316 stainless steel autoclave were placed 47 grams (0.84 moles) of isobutene, 101.6 grams (0.74 moles) of PCl3, and 1 gram of iodine. The mixture of reactants was reacted for 12 hours at 210°C. While 46percent (0.39 moles) of the charged isobutene was consumed in the reaction, no identifiable level of bis-dihalophosphine type product was formed. The reaction formed 16.65 grams (0.18 moles) of tert-butyl chloride and 25.8 grams (0.1 moles) of butenephosphonous dichloride. As is shown in Example 15 in a similar experiment using elemental phosphorus, a yield of 14percent of crude distilled product based on olefin charged is obtained. A

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With trimethylstannyl chloride in carbon disulfide

reaction of P4 with Br2 in CS2, followed by treatment with C(CH3)3SnCl; further products: Cl2P2Br2, ClBrP2ClBr, P2Br4, PBr3, PClBr2, PCl2Br; not isolated, identified by 31P-NMR spectroscopy;

Tattershall, Bruce W.; Kendall, Nigel L.

Polyhedron, 1994 , vol. 13, p. 1517 - 1522 Full Text View citing articles Show Details

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in carbon disulfide

under N2, dropwise addn. of a Br2/CS2 soln. to a vigorously stirred soln. of P4/CS2 reaction of P4 with ICl (molar ratio (1.75:1.5), further Products: ClIP2ClI, ClIP2I2, P2I4, P7I3; not isolated, identified by 31P-NMR spectroscopy;

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Tattershall, Bruce W.; Kendall, Nigel L.

Polyhedron, 1994 , vol. 13, p. 1517 - 1522 Full Text View citing articles Show Details

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With trichloromethane sulphenyl chloride in dichloromethane

T=0°C; 1 h; other sulfenyl chlorides;

Gloede, J.; Lutze, G.

Phosphorus, Sulfur and Silicon and the Related Elements, 1993 , vol. 78, # 1-4 p. 265 - 270 Title/Abstract Full Text Show Details

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in acetonitrile

Woolf, Alfred A.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , # 12 p. 3325 - 3330 Title/Abstract Full Text View citing articles Show Details

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With HCl (liquid) in further solvent(s) reaction of a mixt. of PCl5 and B2Cl4 (2:1) in liquid HCl at -196°C; (11)B and (31)P NMR at 0°C;

Haubold, W.; Kraatz, U.; Einholz, W.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1991 , vol. 592, p. 35 - 41 Full Text Show Details

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in neat (no solvent) vaporization of Sn metal (1750 K), reaction with 1E-4 Torr PCl5; chemiluminescence monitoring, time-of-flight measurements;

Wang, J.H.; Cheong, B.S.; Fang, C.C.; Parson, J.M.

Journal of Chemical Physics, 1990 , vol. 93, # 11 p. 7830 - 7835 Title/Abstract Full Text View citing articles Show Details

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in neat (no solvent) vaporization of Ge (1850 K), reaction with 1E-4 Torr PCl5; chemiluminescence monitoring, time-of-flight measurements;

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Wang, J.H.; Cheong, B.S.; Fang, C.C.; Parson, J.M.

Journal of Chemical Physics, 1990 , vol. 93, # 11 p. 7830 - 7835 Title/Abstract Full Text View citing articles Show Details

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in neat (no solvent) vaporization of Si (2000 K), reaction with 1E-4 Torr PCl5; chemiluminescence monitoring, time-of-flight measurements;

Wang, J.H.; Cheong, B.S.; Fang, C.C.; Parson, J.M.

Journal of Chemical Physics, 1990 , vol. 93, # 11 p. 7830 - 7835 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar in neat (no solvent) Pure PSCl3 is heated in a sealed tube at 150°C for 64 h.; Formed PCl3 is detected by the NMR spectrum.;

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Demarcq, Michel C.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , p. 35 - 40 Full Text Show Details

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With HCl in carbon disulfide

P2H4, CS2 and HCl condensed into a quartz NMR tube at 77°K, slowly warmed to 205°K; observed by P(31)-NMR;

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Minkwitz, Rolf; Liedtke, Andreas

Inorganic Chemistry, 1989 , vol. 28, p. 4238 - 4242 Full Text View citing articles Show Details

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C: 82%

in neat (no solvent) molar ratio niobium ditelluride/PCl5 1/8; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, the residue dried in a vac.; NMR, mass spectra;

Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1987 , vol. 32, p. 1049 - 1051 Zhurnal Neorganicheskoi Khimii, 1987 , vol. 32, p. 1769 - 1771 Full Text Show Details

C: >99

in neat (no solvent) molar ratio niobium ditelluride/PCl5 1/4; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, the residue dried in a vac.; NMR, mass spectra;

Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.

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A: 70% B: 98% C: 70%

With acetonitrile in neat (no solvent) molar ratio molybdenum ditelluride/PCl5 1/8; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot acetonitrile, the residue dried in a vac.; NMR, mass spectra;

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Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.

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A: 95% B: 52% C: >99

in neat (no solvent) molar ratio molybdenum ditelluride/PCl5 1/4; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, the residue dried in a vac.; NMR, mass spectra;

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Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.

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A: 87% B: 99% C: 78%

With acetonitrile in neat (no solvent) molar ratio tungsten ditelluride/PCl5 1/8; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot acetonitrile, soln. cooled to -5°C; the residue dried in a vac.; NMR, mass, IR and Raman spectra;

Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.

A: 45% B: 58% C: >99

With acetonitrile in neat (no solvent) molar ratio tungsten ditelluride/PCl5 1/4; heated in evacuated sealed ampoules for 2 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot acetonitrile, soln. cooled to -5°C; the residue dried in a vac.; NMR, mass, IR and Raman spectra;

Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.

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B: 29% C: 57%

in neat (no solvent) molar ratio rhenium telluride/PCl5 1/8; heated in evacuated sealed ampoules for 6 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, soln. cooled, resulting crystals filtered off, washed (CH3CN), dried in a vac.; elem.anal., NMR, mass spectra;

Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.

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A: 98% C: >99

in neat (no solvent) molar ratio rhenium telluride/PCl5 1/4; heated in evacuated sealed ampoules for 6 h at 170°C, cooled; PCl3 removed in a vac. at 80°C, extd. with hot monoglyme, the residue dried in a vac.; NMR, mass spectra;

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Sheer, M.; Fedin, V. P.; Fedorov, V. E.; Fedotov, M. A.; Semyannikov, P. P.

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in neat (no solvent) react. of gaseous Cl2 with PH3;;

Verrier, U. J. J. Le

Ann. Chim. Phys., 1835 , vol. 60, p. 174 - 194 Full Text Show Details

Verrier, U. J. J. Le

Liebigs Annalen der Chemie, 1836 , vol. 18, p. 333 - 338 Full Text Show Details

in neat (no solvent) react. of gaseous Cl2 with PH3;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

in neat (no solvent, gas phase) Kinetics; byproducts: HCl; under static conditions and in a jet at temps. from 196 to 585 K, pressure from 0.1 to 10 mm Hg; absorption spectroscopy;

Azatyan; Gagarin; Zakhar'in; Kalkanov; Kolbanovskii

Kinetics and Catalysis, 1985 , vol. 26, # 1 pt 2 p. 191 - 194 Title/Abstract Full Text View citing articles Show Details

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in carbon disulfide

Musa, Faleh H.; Tattershall, Bruce W.

soln. of SO2Cl2 added at room temp. to P4S3 soln. over 2 h with stirring, standed for 44 h; not isolated, detected by IR;

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 1517 - 1520 Title/Abstract Full Text View citing articles Show Details

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in neat (no solvent) Cl2 condenced onto P4S3 at -196°C under vac., warmed slowly; extd. (CS2), not isolated, detected by IR, MAS;

Musa, Faleh H.; Tattershall, Bruce W.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 1517 - 1520 Title/Abstract Full Text View citing articles Show Details

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in gas 1100 K; react. is followed by IR and Raman-spectrometry;

Schnoeckel, H.; Lakenbrink, M.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1983 , vol. 507, p. 70 - 76 Full Text Show Details

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in dichloromethane

not isolated, detd. by NMR spectroscopy;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Chemical Communications, 1983 , # 19 p. 1089 - 1090 Title/Abstract Full Text View citing articles Show Details

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45%

in neat (no solvent) argon atmosphere; org. compd. addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen);

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Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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in neat (no solvent) argon atmosphere; KBr addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C;

Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

With triethylamine in neat (no solvent) argon atmosphere; KBr and (C2H5)3N addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen);

Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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in neat (no solvent) argon atmosphere; KI and org. compd. addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen);

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Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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25%

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Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

Rx-ID: 26102389

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in neat (no solvent) argon atmosphere; KI addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C;

Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

With triethylamine in neat (no solvent) argon atmosphere; KI and (C2H5)3N addn. to PCl4AlCl4 (cooling), reaction vessel connecting to vac. line (2 mm Hg), mixt. heating to 80°C, liquefaction; volatiles collection (trap cooled with liq. nitrogen);

Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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67%

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Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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81%

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Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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76-80

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Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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76-80

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Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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in neat (no solvent) byproducts: Et4NBr; argon atmosphere; mixing org. compd. and PBr5 (cooling), mixt. leaving for 1 h at room temp., heating (vac., 80°C, 2 h); volatile products collection (trap cooled with liq. nitrogen);

Vengel'nikova, V. N.; Timokhin, B. V.; Kalabina, A. V.; Donskikh, V. I.

Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 1160 - 1163 Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 1318 - 1322 Full Text Show Details

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D: 0%

in not given under N2, oxidn. of PCl2(CN)2(1-) with Br2 in presence of NEt4Cl;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

under N2, react. of (NEt4) (PCl(CN)3) with Br2 in CH2Cl2 in presence of excess of NEt4Cl over 2 d; further products; monitored by (31)P NMR spectra;

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Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of AgNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

Dillon, Keith B.; Platt, Andrew W. G.

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stoich. amt. of AgNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of AgNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of AgNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 27057335 Find similar reactions

in dichloromethane

stoich. amt. of AgNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in not given decompd. rapidly;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in not given decompd. rapidly;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in not given decompd. rapidly;

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Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in not given decompd. rapidly;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in not given decompd. rapidly;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of NH4NCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

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Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 27104528 Find similar reactions

in dichloromethane

stoich. amt. of NH4NCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of NH4NCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

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Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 27104530 Find similar reactions

in dichloromethane

stoich. amt. of NH4NCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

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Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of NH4NCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in not given P(NCS)3 added to concd. soln. of (N(n-C5H11)4)(PCl6);

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Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of LiNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of LiNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of LiNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of LiNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

stoich. amt. of LiNCS added to soln. of (N(n-C5H11)4)(PCl6) in CH2Cl2;

Dillon, Keith B.; Platt, Andrew W. G.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1199 - 1204 Title/Abstract Full Text View citing articles Show Details

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A: 37.5%

4 h; 1,2-dichloroethane added, filtration, solvent and PCl3 distd. off from filtrate, distn. in Vigreuxcolumn; elem. anal.;

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Fluck, E.; Hoesle, R.; Zischka, A.-K.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1981 , vol. 474, p. 105 - 112 Full Text Show Details

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94%

>99

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With phosphorus trichoride in neat (no solvent) passing dry Cl2 (dryed over H2SO4) in a suspension of red P (dryed over H2SO4) in PCl3; use of a glass apparatus with reflux condenser and P2O5 drying tube; boiling PCl3 during the rect. to prevent formation of PCl4;;

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Forbes, M. C.; Roswell, C. A.; Maxson, R. N.

Fernelius, W. C., Inorganic Syntheses, Bd. 2, New York-London 1946, S. 145/7 Full Text Show Details

in neat (no solvent) pptn. of a layer of P4 on the wall on heating red P in an atmosphere of CO2, then passing in Cl2;;

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Rekshinskij, V.

C. I, Tr. Inst. chistych chim. Reaktivav Nr. 3 (1924) 46/49 1925 , p. 477 Full Text Show Details

direct synthesis in null-manometer, according to: O. G. Polyachenok, Author's Abstract of Doctoral Thesis, Leningrad, 1972;

Dudchik, G. P.; Polyachenok, O. G.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1979 , vol. 24, p. 360 - 362 Zhurnal Neorganicheskoi Khimii, 1979 , vol. 24, p. 646 - 650 Full Text Show Details

With phosphorus trichoride in neat (no solvent) pouring liquid PCl3 upon red P; passing gaseous Cl2 in the liquid; apparatus described;;

Vanshejdt, A. A.; Tolstopjatov, V. M.

Zh. russk. fiz. chim. Obshch. Chast' chim., 1920 , vol. 52, p. 251 - 269 C. III, 1923 , p. 723 Full Text Show Details Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

With phosphorus trichoride in neat (no solvent) pouring liquid PCl3 upon red P; passing gaseous Cl2 in the liquid; use of a reflux condenser;; quantitative react.;;

Graebe, C.

Ber. dtsch. chem. Ges., 1901 , vol. 34, p. 645 - 652 Full Text Show Details

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

in neat (no solvent) heating red P in dry Cl2;;

Thorpe, T. E.

Ber. dtsch. chem. Ges., 1875 , vol. 8, p. 326 - 332 Full Text Show Details

Gmelin Handbook: P: MVol.C, 179, page 412 - 414

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Full Text Show Details

in neat (no solvent) react. of red P with Cl2 at ambient temp.;;

Schroetter, A.

Sitz.-Ber. Akad. Wiss. (wien), 1848 , vol. 1, p. 130 - 137 Full Text Show Details

in neat (no solvent) react. of red P with Cl2 at ambient temp.;;

Gmelin Handbook: P: MVol.C, 159, page 363 - 366 Full Text Show Details

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complex dissociation in temp. range 100-500°C; tensimetric equilibrium monitoring;

Sevast'yanova, T. N.; Tarasova, A. Sh.; Suvorov, A. V.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1979 , vol. 24, p. 1288 - 1290 Zhurnal Neorganicheskoi Khimii, 1979 , vol. 24, p. 2322 - 2326 Full Text Show Details

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in solid matrix Irradiation (UV/VIS); Ar-matrix, 10 K, 229 - 366 nm; not isolated, detd. by IR spectroscopy;

Boxhoorn, G.; Stufkens, D. J.; Oskam, A.

Inorganica Chimica Acta, 1979 , vol. 33, p. 215 - 226 Full Text View citing articles Show Details

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Hide Experimental Procedure

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Societe Anonyme dite: MAR-PHA, Societe d'Etude et d'Exploitation de Marques

Patent: US4067899 A1, 1978 ; Title/Abstract Full Text Show Details

11:2-isobornyl-4-chlorophenol

EXAMPLE 11 STR12 2-isobornyl-4-chlorophenol 80g 2-isobornyl anisole (0.33 mole) and 76g phosphorus pentachloride (0.36 mole) are heated at 120° C for 2 hours. The PCl3 formed is then distilled under vacuum and the reaction mixture is poured into iced water. The mixture is extracted with ether, the organic phase is washed with water until neutral, dried on sodium sulphate and the ether is evaporated. 90g of a red oil (2-isobornyl-4-chloroanisole) are obtained. A

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in neat (no solvent) dissociation investigated at 166358 °C;;

Holland, C.

Zeitschrift fuer Elektrochemie, 1912 , vol. 18, p. 234 - 236 Full Text Show Details

Nernst, W.

Zeitschrift fuer Elektrochemie, 1916 , vol. 22, p. 37 - 38 Full Text Show Details

in neat (no solvent) complete dissociation at 300 °C; reversible reaction;;

Soc. Francaise des Constructions Babcock & Wilcox

Patent: FR1184469 , 1959 ; C., 1960 , p. 6948 Full Text Show Details

in neat (no solvent) decompn. on heating forming Cl2 and PCl3; evolution of yellowish vapors;;

Sainte-Claire Deville, H.

Liebigs Annalen der Chemie, 1866 , vol. 140, p. 166 - 171 Full Text Show Details

Sainte-Claire Deville, H.

Philosophical Magazine (1798-1977), 1966 , vol. 32, p. 387 - 387 Full Text Show Details

in neat (no solvent) dissociation at 90-167 °C; dissociation pressure given;;

Smith, A.; Calvert, R. P.

Journal of the American Chemical Society, 1914 , vol. 36, p. 1363 - 1382 Full Text View citing articles Show Details

Smith, A.; Lobard, R. H.

Journal of the American Chemical Society, 1915 , vol. 37, p. 2055 - 2062 Full Text View citing articles Show Details

in neat (no solvent) dissociation;;

Bevillard, P.

Bulletin de la Societe Chimique de France, 1954 , p. D 40 - D 48 Full Text Show Details

Bevillard, P.

Bulletin de la Societe Chimique de France, 1954 , p. D 55 - D 79 Full Text Show Details

in neat (no solvent) evolution of Cl2 starting at 157158 °C;;

Fireman, P.; Portner, E. G.

Journal of Physical Chemistry, 1903 , vol. 8, p. 500 - 504 Full Text View citing articles Show Details

in neat (no solvent) decompn. on heating forming Cl2 and PCl3; evolution of yellowish vapors;;

Gmelin Handbook: P: MVol.C, 191, page 439 - 441 Full Text Show Details

Sainte-Claire Deville, H.

C. r. Acad. Sci. (Paris), 1866 , vol. 62, p. 1157 - 1160 Full Text Show Details

in neat (no solvent) complete dissociation at 300 °C; reversible reaction;;

Gmelin Handbook: P: MVol.C, 191, page 439 - 441 Full Text Show Details

in neat (no solvent) dissociation at 100.5-229.1 °C; dissociation pressure given;;

Fischer, W.; Juebermann, O.

Z. Anorg. Chem., 1938 , vol. 235, p. 337 - 351 Full Text Show Details Gmelin Handbook: P: MVol.C, 191, page 439 - 441 Full Text Show Details

in neat (no solvent) dissociation at 90-167 °C; dissociation pressure given;;

Gmelin Handbook: P: MVol.C, 191, page 439 - 441 Full Text Show Details

in neat (no solvent) dissociation investigated at 166358 °C;;

Gmelin Handbook: P: MVol.C, 191, page 439 - 441 Full Text Show Details

in neat (no solvent) dissociation;;

Gmelin Handbook: P: MVol.C, 191, page 439 - 441 Full Text Show Details

in neat (no solvent) evolution of Cl2 starting at 157158 °C;;

Gmelin Handbook: P: MVol.C, 191, page 439 - 441 Full Text Show Details

in further solvent(s) dissociation in SiCl4;;

Harold, J. F. X.

Journal of the American Chemical Society, 1898 , vol. 20, p. 13 - 29 Full Text Show Details

Gmelin Handbook: P: MVol.C, 196, page 449 - 451 Full Text Show Details

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warming, or in vac.;

O'Donnell, T. A.; Stewart, D. F.; Wilson, P. W.

Inorganic Chemistry, 1966 , vol. 5, p. 1438 - 1441 Full Text View citing articles Show Details

warming, or in vac.;

Gmelin Handbook: U: SVol.C8, 5.1.5.3, page 139 - 163 Full Text Show Details

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in tetrachloromethane

Kinetics; Irradiation (UV/VIS); photolysis of P4 in CCl4; main product is red P;; yields depending on temp.;;

Perner, P. D.; Henglein, A.

Zeitschrift fuer Naturforschung, 1962 , vol. 17 b, p. 703 - 711 Full Text Show Details

Gmelin Handbook: C: MVol.D2, 4.1.2.7.7.10, page 238 - 239 Full Text Show Details

in tetrachloromethane

Kinetics; other Radiation; radiation with γ-rays of a soln. of P4 in CCl4 (in vac.); mechanism discussed;; yields depending on temp.;;

Perner, P. D.; Henglein, A.

Zeitschrift fuer Naturforschung, 1962 , vol. 17 b, p. 703 - 711 Full Text Show Details

Gmelin Handbook: C: MVol.D2, 4.1.2.7.7.10, page 238 - 239 Full Text Show Details

in tetrachloromethane

Kinetics; thermal reaction of P4 with CCl4 above 140°C;; soln. turning black; yields given;;

Perner, P. D.; Henglein, A.

Zeitschrift fuer Naturforschung, 1962 , vol. 17 b, p. 703 - 711 Full Text Show Details

Gmelin Handbook: C: MVol.D2, 4.1.2.7.7.10, page 238 - 239 Full Text Show Details

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in not given contact of P and Cl2 in a liquid medium containing P-halogenides at 70 °C;;

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Dow Chemical Co.

Patent: US1888713 , 1932 ; C. I, 1933 , p. 655 Full Text Show Details

With phosphorus trichoride in neat (no solvent) passing Cl2 in a 5-10 percent soln. of P in PCl3; keeping the boiling temp. constant; conducting the reaction heat by volatilization of PCl3;;

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Farbwerke Hoechst A.-G. vorm. Meister Lucius & Bruening

Patent: DE1104931 , 1961 ; C., 1961 , p. 14055 Full Text Show Details

With phosphorus trichoride in neat (no solvent) passing Cl2 in a mixt. of P with boiling PCl3; addn. of P during the react.;; distn. of PCl3 during the react.;;

Milobedzki, T.; Friedman, M.

Chemik polski, 1917 , vol. 15, p. 76 - 79 Full Text Show Details

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

With phosphorus trichoride in not given prepn. in laboratory; addn. of PCl3 at the beginning of the react.;;

Saunders, B. C.; Worthy, T. S.

Journal of the Chemical Society, 1950 , p. 1320 - 1322 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

in neat (no solvent) byproducts: POCl3; react. of an excess of P with Cl2 in leaded vessels under exclusion of H2O and under evolution of heat; an amount of PCl3 remains in the react. vessel on boiling;; distn. of formed PCl3, react. with Cl2 to remove remained P; removal of impurities by fractionation;;

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Wazer, J. R. van

Encyclopedia of Chemical Technology, herausgegeben von R. E. Kirk, D. F. Othmer. The Interscience Encyclopedia, Inc., New York 1953, Bd. 10, S. 478 Full Text Show Details

in neat (no solvent) react. of P (distd. in a N2 atmosphere) with a corresponding amount of Cl2 in an atmosphere of N2;;

Holroyd, G. W. F.; Chadwick, H.; Mitchell, J. E. H.

Journal of the Chemical Society, 1925 , vol. 127, p. 2492 - 2493 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

in neat (no solvent) react. of an excess of P with Cl2 in leaded vessels under exclusion of H2O under evolution of heat;;

Sorel, J.

Chim. et Ind., 1948 , vol. 60, p. 541 - 549 Full Text Show Details

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

in neat (no solvent) react. of molten P with Cl2; preventing contact of Cl2 with P, addn. of Cl2 to formed PCl3;;

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Batuner, L. M.

Patent: RU47291 , 1936 ; C. I, 1937 , p. 400 Full Text Show Details

in neat (no solvent) react. of molten P with Cl2; react. temp. for formation of gaseous PCl3; addn. of liquid P in distance to the reaction center;; washing formed PCl3 vapor with liquid P and liquid PCl3;;

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Farbwerke Hoechst A.-G. vorm. Meister Lucius & Bruening

Patent: DE878489 , 1953 ; C., 1954 , p. 6312 Full Text Show Details

Farbwerke Hoechst A.-G. vorm. Meister Lucius & Bruening

Patent: GB688525 , 1953 ; C. A., 1954 , p. 9638 Full Text Show Details

in not given react. in a retort; use of an excess of P;;

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Fahlberg, List & Co.

Patent: DE44832 , 1887 ; C. I, 1889 , p. 88 Full Text Show Details

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-78°C;

Emeleus,H.J.; Pugh,H.

Journal of the Chemical Society, 1960 , p. 1108 - 1112 Full Text View citing articles Show Details

Gmelin Handbook: F: PerFHalOrg.2, 1.1.6.10, page 27 - 31 Full Text Show Details

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With chlorine

at -74°C; detection of products by IR-spectroscopy;

Emeleus, H. J.; Nabi, S. N.

Journal of the Chemical Society, 1960 , p. 1103 - 1108 Full Text View citing articles Show Details

Gmelin Handbook: F: PerFHalOrg.2, 1.1.6.10, page 27 - 31 Full Text Show Details

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Fluck et al.

Journal of the American Chemical Society, 1959 , vol. 81, p. 6363 Full Text View citing articles Show Details

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Fluck et al.

Journal of the American Chemical Society, 1959 , vol. 81, p. 6363 Full Text View citing articles Show Details

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Rx-ID: 7084941 Find similar reactions

Fluck et al.

Journal of the American Chemical Society, 1959 , vol. 81, p. 6363 Full Text View citing articles Show Details

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With titanium; silicon in not given byproducts: POCl3, TiCl4; react. of ferrophosphorus containing Ti and Si with Cl2;;

Pennsylvania Salt Mfg. Co.

Patent: US2797980 , 1957 ; C. A., 1957 , p. 15080 Full Text Show Details Pennsylvania Salt Mfg. Co. Patent: DE1065817 , 1959 ; C., 1960 , p. 13811 Full Text Show Details Pennsylvania Salt Mfg. Co. Patent: DE1040516 , 1958 ; C., 1959 , p. 4934 Full Text Show Details Pennsylvania Salt Mfg. Co. Patent: GB812801 , 1959 ; C., 1960 , p. 8645 Full Text Show Details Pennsylvania Salt Mfg. Co. Patent: FR1163391 , 1958 ; C., 1960 , p. 12468 Full Text Show Details Pennsalt Corp. Chemical Patent: GB805153 , 1958 ; C. A., 1959 , p. 5609 Full Text Show Details

With ferrophosphorus in not given react. of ferrophosphorus with Cl2;; distn. of formed PCl3 by react. heat;;

Urbain, E.

Patent: DE489933 , 1930 ; C. I, 1930 , p. 1989 Full Text Show Details Urbain, E. Patent: GB312685 , 1929 ; C. II, 1930 , p. 3182 Full Text Show Details Urbain, E. Patent: FR669099 , 1929 ; C. I, 1930 , p. 724 Full Text Show Details

With ferrophosphorus; Ti; Si in not given byproducts: POCl3, TiCl4; react. of ferrophosphorus containing Ti and Si with Cl2;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

With ferrophosphorus in not given react. of ferrophosphorus with Cl2;; distn. of formed PCl3 by react. heat;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

Rx-ID: 26182404 Find similar reactions

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Rx-ID: 6211462 Find similar reactions

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Holmes; Bertaut

Journal of the American Chemical Society, 1958 , vol. 80, p. 2980 Full Text View citing articles Show Details

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Rx-ID: 26451151 Find similar reactions

in neat (no solvent) mixing starting material;;

Delwaulle, M. L.

Bulletin de la Societe Chimique de France, 1958 , p. 278 - 279 Full Text Show Details

Gmelin Handbook: P: MVol.C, 215, page 494 - 496 Full Text Show Details

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Rx-ID: 26138520 Find similar reactions

in not given react. with Hg;;

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Downs, J. J.; Johnson, R. E.

Journal of the American Chemical Society, 1955 , vol. 77, p. 2098 - 2102 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 193, page 443 - 445

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Full Text Show Details

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Rx-ID: 26182465 Find similar reactions

B: <1

in tetrachloromethane

pouring red P with dry CCl4, cooling at 5°C and passing in Cl2; keeping temp. below 70 °C; stirring; standing for 2-3 h and repeating the process;; decanting pptd. PCl5; passing Cl2 through the soln. for 20 min; filtration in vacuum; product contains a small amount of PCl3, traces of POCl3 and 25-40 percent CCl4; distn. in vacuum;;

Bulashevich, E. A.

Zh. prikl. Khim., 1955 , vol. 28, p. 431 - 433 C. A., 1955 , p. 13811 Full Text Show Details

B: <1

in tetrachloromethane

Gmelin Handbook: P: MVol.C, 189, page 434 - 437 Full Text Show Details

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T=20°C; Zersetzung;

Forsman; Lipkin

Journal of the American Chemical Society, 1953 , vol. 75, p. 3145,3146 Full Text View citing articles Show Details

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Rx-ID: 26150195 Find similar reactions

in not given formation of PCl3 and Al(NCO)3 by react. of P(NCO)3 with AlCl3;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

in not given formation of PCl3 and Al(NCO)3 by react. of P(NCO)3 with AlCl3;;

Anderson

Journal of the American Chemical Society, 1953 , vol. 75, p. 1576 Full Text View citing articles Show Details

Anderson

Journal of the American Chemical Society, 1953 , vol. 75, p. 1576 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 271, page 622 - 624 Full Text Show Details

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Rx-ID: 26154874 Find similar reactions

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With sawdust or active carbon in neat (no solvent) react. of a heated mixt. of phosphoric acid and sawdust or phosphoric acid and active carbon with Cl2 at 250-600 °C;;

International Minrals & Chemical Corp.

Patent: US2622965 , 1952 ; C. A., 1953 , p. 3531 Full Text Show Details

With sawdust or active carbon in neat (no solvent) react. of a heated mixt. of phosphoric acid and sawdust or phosphoric acid and active carbon with Cl2 at 250-600 °C;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

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With bromine

Erhitzen des Reaktionsprodukts mit 2,4,6-Trimethyl-pyridin;

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Ungnade; Ortega

Journal of the American Chemical Society, 1951 , vol. 73, p. 1564 Journal of the American Chemical Society, 1952 , vol. 74, p. 6313 Full Text View citing articles Show Details

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Rx-ID: 26090281 Find similar reactions

in neat (no solvent) heating with dry NH4F with a reflux condenser;;

Wilkins, C. J.

Journal of the Chemical Society, 1951 , p. 2726 - 2728 Full Text View citing articles Show Details

in neat (no solvent) heating with dry NH4F with a reflux condenser;;

Gmelin Handbook: P: MVol.C, 206, page 471 - 475 Full Text Show Details

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in neat (no solvent) react. at >100°C and 50-100 atm in a pressure pipe;;

Wilkinson, G.

Journal of the American Chemical Society, 1951 , vol. 73, p. 5501 - 5502 Full Text View citing articles Show Details

in neat (no solvent) react. at >100°C and 50-100 atm in a pressure pipe;;

Gmelin Handbook: P: MVol.C, 171, page 393 - 395 Full Text Show Details

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Rx-ID: 26551918 Find similar reactions

in neat (no solvent) react. in the system PCl5#I2; react. of PCl5 with I2 forming ICl and PCl3; react. of ICl with PCl5 forming PCl6I;;

Fialkov, Ya. A.; Kuz'menko, A. A.

Zh. obshch. Khim., 1949 , vol. 19, p. 1645 - 1652 C. A., 1950 , p. 1354 Full Text Show Details Gmelin Handbook: P: MVol.C, 231, page 529 - 530 Full Text Show Details

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in neat (no solvent) decompn. at -6 °C;;

Baumgarten, P.; Bruns, W.

Ber., 1947 , vol. 80, p. 517 - 520 Full Text Show Details

above -6°C;

Baumgarten, P.; Bruns, W.

Ber., 1947 , vol. 80, p. 517 - 520 Full Text Show Details

above -6°C;

Gmelin Handbook: B: SVol.1, 4.4.4, page 177 - 187 Full Text Show Details

in neat (no solvent) decompn. at -6 °C;;

Gmelin Handbook: P: MVol.C, 269, page 618 - 620 Full Text Show Details

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Rx-ID: 26167912 Find similar reactions

in neat (no solvent) byproducts: paracyanogen; react. with KCN on heating;;

Bert, L.

C. r. Acad. Sci. (Paris), 1946 , vol. 222, p. 1117 - 1118 Full Text Show Details

Gmelin Handbook: P: MVol.C, 195, page 447 - 449 Full Text Show Details

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T=25°C;

Anderson

Journal of the American Chemical Society, 1945 , vol. 67, p. 224,2177 Full Text Show Details

T=143°C;

Anderson

Journal of the American Chemical Society, 1945 , vol. 67, p. 224,2177 Full Text Show Details

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in neat (no solvent) decomposition at 148°C;;

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Anderson, H. H.

Journal of the American Chemical Society, 1945 , vol. 67, p. 2176 - 2177 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 276, page 633 - 634 Full Text Show Details

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Rx-ID: 26099841 Find similar reactions

in neat (no solvent) reaction in iron or steel vessel; reaction starts at 250°C, reaction of formed POCl3 with Fe (from basin) yields PCl3;;

Tarbutton, G.; Egan, E. P.; Frary, S. G.

Journal of the American Chemical Society, 1941 , vol. 63, p. 1782 - 1789 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 200, page 458 - 460 Full Text Show Details

in neat (no solvent) react. starting at 250 °C; formation of POCl3 and a small amount of PCl3;;

Gmelin Handbook: P: MVol.C, 45, page 90 - 93 Full Text Show Details

in neat (no solvent) react. starting at 250 °C; formation of POCl3 and a small amount of PCl3;;

Tarbutton, G.; Egan, E. P.; Frary, S. G.

Journal of the American Chemical Society, 1941 , vol. 63, p. 1782 - 1789 Full Text View citing articles Show Details

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Rx-ID: 26144596 Find similar reactions

in neat (no solvent) reaction in iron or steel vessel; reaction starts at 400°C, reaction of formed POCl3 with Fe (from vessel) yields PCl3;;

Tarbutton, G.; Egan, E. P.; Frary, S. G.

Journal of the American Chemical Society, 1941 , vol. 63, p. 1782 - 1789 Full Text View citing articles Show Details

Gmelin Handbook: P: MVol.C, 200, page 458 - 460 Full Text Show Details

in neat (no solvent) react. starting at 400 °C;;

Gmelin Handbook: P: MVol.C, 45, page 90 - 93 Full Text Show Details

in neat (no solvent) react. starting at 400 °C;;

Tarbutton, G.; Egan, E. P.; Frary, S. G.

Journal of the American Chemical Society, 1941 , vol. 63, p. 1782 - 1789 Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 26487214 Find similar reactions

in neat (no solvent) dissociation at 160 °C;;

Fischer, W.; Juebermann, O.

Z. Anorg. Chem., 1938 , vol. 235, p. 337 - 351 Full Text Show Details Gmelin Handbook: P: MVol.C, 191, page 439 - 441 Full Text Show Details

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Rx-ID: 26150293 Find similar reactions

in not given react. of a mixt. of P4 and red P with Cl2;;

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Teodoreanu, I.

Bull. Sect. sci. Acad. Roum., 1936 , vol. 17, p. 38 - 40 Full Text Show Details

Gmelin Handbook: P: MVol.C, 179, page 412 - 414 Full Text Show Details

Synthesize Find similar in neat (no solvent) in vac. or on warming in a stream of CO2 or on washing with benzene;;

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Rx-ID: 26174055 Find similar reactions

Davis, T. L.; Ehrlich, P.

Journal of the American Chemical Society, 1936 , vol. 58, p. 2151 - 2153 Full Text View citing articles Show Details

Gmelin Handbook: Cu: MVol.B1, 110, page 240 - 242 Full Text Show Details

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Rx-ID: 26486063 Find similar reactions

in neat (no solvent) passing PH3 over PCl5 at -90 °C;;

Royen, P.; Hill, K.

Z. anorg. allg. Chem., 1936 , vol. 229, p. 112 - 128 Full Text Show Details

Gmelin Handbook: P: MVol.C, 197, page 451 - 452 Full Text Show Details

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Synthesize Find similar Rx-ID: 26182405 Find similar reactions

With ferrophosphorus in not given react. of ferrophosphorus with Cl2; addn. of alkali chlorides to prevent distn. of FeCl3;; distn. of formed PCl3;;

Chemische Fabrik von Heyden A.-G.

Patent: DE622648 , 1935 ; C. I, 1936 , p. 1936 Full Text Show Details

With ferrophosphorus in not given react. of ferrophosphorus with Cl2; addn. of alkali chlorides to prevent distn. of FeCl3;; distn. of formed PCl3;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

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Rx-ID: 26119927 Find similar reactions

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in diethyl ether

incomplete react. with Mg powder in ether at ambient temp. or at boiling point forming a small amount of PCl3;;

Rheinboldt, H.; Schwenzer, K.; Bunge, R.

J. prakt. Chem. (2), 1934 , vol. 140, p. 273 - 290 Full Text Show Details Gmelin Handbook: P: MVol.C, 193, page 443 - 445 Full Text Show Details

in diethyl ether

PCl5 is reduced incomplete to PCl3.;

Rheinboldt, H.; Schwenzer, K.

Journal fuer Praktische Chemie (Leipzig), 1934 , vol. 140, # 2 p. 279 - 289 Full Text Show Details

Gmelin Handbook: Mg: MVol.A2, 41, page 307 - 309 Full Text Show Details

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Rx-ID: 26161033 Find similar reactions

in not given react. of red P with SO2Cl2;;

Koechlin, P.; Heumann, K.

Ber. dtsch. chem. Ges., 1882 , vol. 15, p. 1736 - 1738 Full Text Show Details

With carbon dioxide

Danneel, H.; Schlottmann, F.

Z. Anorg. Chem., 1933 , vol. 212, p. 225 - 232 Full Text Show Details

Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310 Full Text Show Details

in neat (no solvent) react. of P with SO2Cl2 vapor even diluted with CO2 at ambient temp.;;

Daneel, H.; Schlottmann, F.

Z. anorg. allg. Chem., 1933 , vol. 212, p. 225 - 232 Full Text Show Details

in not given react. of red P with SO2Cl2;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

in neat (no solvent) react. of P with SO2Cl2 vapor even diluted with CO2 at ambient temp.;;

Gmelin Handbook: P: MVol.C, 180, page 414 - 416 Full Text Show Details

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Rx-ID: 26161034 Find similar reactions

in neat (no solvent) sealed tube (125°C);;

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Danneel, H.; Schlottmann, F.

Z. Anorg. Chem., 1933 , vol. 212, p. 225 - 232 Full Text Show Details

Koechlin, P.; Heumann, K.

Ber., 1882 , vol. 15, p. 1736 - 1738 Full Text Show Details

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Gmelin Handbook: S: MVol.B3, 135, page 1815 - 1817 Full Text Show Details

in neat (no solvent) in coldness;;

Danneel, H.; Schlottmann, F.

Z. Anorg. Chem., 1933 , vol. 212, p. 225 - 232 Full Text Show Details Koechlin, P.; Heumann, K. Ber., 1882 , vol. 15, p. 1736 - 1738 Full Text Show Details Gmelin Handbook: S: MVol.B3, 135, page 1815 - 1817 Full Text Show Details

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Rx-ID: 26402937 Find similar reactions

in neat (no solvent) sealed tube (125°C);;

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Danneel, H.; Schlottmann, F.

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Rx-ID: 26402938 Find similar reactions

in neat (no solvent) excess of SO2Cl2; sealed tube (180°C);;

Danneel, H.; Schlottmann, F.