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8 reactions in Reaxys
2017-11-15 01h:27m:07s (EST)
O
1. Query
O O
Search as: Product, As drawn
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OH
O
HO
Br
Br O
O
O
Rx-ID: 844582 View in Reaxys 1/8 Yield
Conditions & References With potassium carbonate Trikojus; White; Journal of the Chemical Society; (1949); p. 436,437 View in Reaxys Surrey; Journal of the American Chemical Society; vol. 70; (1948); p. 2887,2889 View in Reaxys Rao et al.; Proceedings - Indian Academy of Sciences, Section A; vol. <A> 30; (1949); p. 114,118 View in Reaxys 1 : Methylenation: myristicin (II) Methylenation: myristicin (II)The dihydroxy compound (6 g) was dissolved in anhydrous acetone (200 cc), treated with methylene bromide (7.5 cc) and potassium carbonate (30 g) and refluxed for twenty hours. The solvent was then distilled off, the residue treated with water and themixture extracted with ether. The ether extract was shaken with aqueous alkali, washed with water, dried over calcium chloride and distilled. The pale yellow oil left behind was distilled under reduced pressure (10 mm) when myristicin passed over at 138°. Yield, 2 g. Its refractive index was 1.5368 at 31° for white light,and 1.5343 at 30° and 1.54 12 at 20° for the D line. When treated with a slight excess ofbromine in petroleum ether solution it yielded dibromo-myristicin-dibromide whichcrystallised from acetone-methylalcohol mixture as colourless prismatic needles and melted at 128-29° alone or in admixture with a sample made from natural myristicin. With potassium carbonate in acetone, Time= 20h, Reflux Patent; LA GRANGE, Martin James; WO2013/133723; (2013); (A1) English View in Reaxys
O
O
O O
HO
O
Rx-ID: 22364930 View in Reaxys 2/8 Yield
Conditions & References Reaction Steps: 2 1: 170 - 200 °C / unter Wasserstoff 2: potassium carbonate With potassium carbonate Trikojus; White; Journal of the Chemical Society; (1949); p. 436,437 View in Reaxys Surrey; Journal of the American Chemical Society; vol. 70; (1948); p. 2887,2889 View in Reaxys Reaction Steps: 2 1: 170 - 200 °C / unter Wasserstoff 2: potassium carbonate With potassium carbonate Trikojus; White; Journal of the Chemical Society; (1949); p. 436,437 View in Reaxys Surrey; Journal of the American Chemical Society; vol. 70; (1948); p. 2887,2889 View in Reaxys
Copyright © 2017 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.
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2017-11-15 01:27:40
O
O
O
O
O
OH
Rx-ID: 22364942 View in Reaxys 3/8 Yield
Conditions & References Reaction Steps: 2 1: 170 - 200 °C / unter Wasserstoff 2: potassium carbonate With potassium carbonate Trikojus; White; Journal of the Chemical Society; (1949); p. 436,437 View in Reaxys Surrey; Journal of the American Chemical Society; vol. 70; (1948); p. 2887,2889 View in Reaxys Reaction Steps: 2 1: 170 - 200 °C / unter Wasserstoff 2: potassium carbonate With potassium carbonate Trikojus; White; Journal of the Chemical Society; (1949); p. 436,437 View in Reaxys Surrey; Journal of the American Chemical Society; vol. 70; (1948); p. 2887,2889 View in Reaxys OH
I
I
O
HO
O O
O
Rx-ID: 170715 View in Reaxys 4/8 Yield
Conditions & References With potassium carbonate Trikojus; White; Journal of the Chemical Society; (1949); p. 436,437 View in Reaxys Surrey; Journal of the American Chemical Society; vol. 70; (1948); p. 2887,2889 View in Reaxys Rao et al.; Proceedings - Indian Academy of Sciences, Section A; vol. <A> 30; (1949); p. 114,118 View in Reaxys
HO
O
O O O
Rx-ID: 22075541 View in Reaxys 5/8 Yield
Conditions & References Reaction Steps: 3 2: alkaline aqueous H2O2 3: potassium carbonate With alkaline aqueous H2O2, potassium carbonate Rao et al.; Proceedings - Indian Academy of Sciences, Section A; vol. <A> 30; (1949); p. 114,118 View in Reaxys Reaction Steps: 3 2: alkaline aqueous H2O2 3: potassium carbonate With alkaline aqueous H2O2, potassium carbonate
Copyright © 2017 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.
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Rao et al.; Proceedings - Indian Academy of Sciences, Section A; vol. <A> 30; (1949); p. 114,118 View in Reaxys Reaction Steps: 3 1: 1-Hexylamine / 6 h / |Heating 2: dihydrogen peroxide; pyridine; sodium hydroxide / water / 1.5 h / 20 °C 3: potassium carbonate / acetone / 20 h / |Reflux With pyridine, 1-Hexylamine, dihydrogen peroxide, potassium carbonate, sodium hydroxide in water, acetone Patent; LA GRANGE, Martin James; WO2013/133723; (2013); (A1) English View in Reaxys
O
O
O
HO
O O
Rx-ID: 22081861 View in Reaxys 6/8 Yield
Conditions & References Reaction Steps: 2 1: alkaline aqueous H2O2 2: potassium carbonate With alkaline aqueous H2O2, potassium carbonate Rao et al.; Proceedings - Indian Academy of Sciences, Section A; vol. <A> 30; (1949); p. 114,118 View in Reaxys Reaction Steps: 2 1: alkaline aqueous H2O2 2: potassium carbonate With alkaline aqueous H2O2, potassium carbonate Rao et al.; Proceedings - Indian Academy of Sciences, Section A; vol. <A> 30; (1949); p. 114,118 View in Reaxys Reaction Steps: 2 1: dihydrogen peroxide; pyridine; sodium hydroxide / water / 1.5 h / 20 °C 2: potassium carbonate / acetone / 20 h / |Reflux With pyridine, dihydrogen peroxide, potassium carbonate, sodium hydroxide in water, acetone Patent; LA GRANGE, Martin James; WO2013/133723; (2013); (A1) English View in Reaxys OH
I
I
HO
O
O
K2CO3
O
O
O
Rx-ID: 7155655 View in Reaxys 7/8 Yield
Conditions & References unter Wasserstoff Trikojus; White; Journal of the Chemical Society; (1949); p. 436,437 View in Reaxys Surrey; Journal of the American Chemical Society; vol. 70; (1948); p. 2887,2889 View in Reaxys
Copyright © 2017 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.
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O O O
Rx-ID: 5457488 View in Reaxys 8/8 Yield
Conditions & References Dallacker et al.; Monatshefte fuer Chemie; vol. 91; (1960); p. 1089,1096 View in Reaxys Moltrasio et al.; Organic Preparations and Procedures International; vol. 4; (1972); p. 13 View in Reaxys Fujita; Yamashita; Bulletin of the Chemical Society of Japan; vol. 46; (1973); p. 3553 View in Reaxys To repeat, the "active" stress reactivity-reducing substances of our invention, to wit: ... Valerian Oil; Myristicin; Elemicin; and Isoelemicin Patent; International Flavors and Fragrances Inc.; Yale University; US4670264; (1987); (A1) English View in Reaxys
Copyright © 2017 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.
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