Tetrachlorostannane [Tin(IV) chloride] [SnCl4 or Cl4Sn] by Asch

Query Query 1. Query

Cl Cl

Sn ClCl

Results

Date

267 reactions in Reaxys

2017-12-13 01h:43m:17s (EST)

267 reactions in Reaxys

2017-12-13 01h:43m:57s (EST)

Search as: As drawn, No salts, No mixtures, No isotopes, No charges, No radicals 2. Query

(1. Query) AND itemno in (1)

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Cl Sn

Sn ClCl

Rx-ID: 34825799 View in Reaxys 1/267 Yield

Conditions & References Representative procedure for ultrasound assisted indium-mediated reactions. Synthesis of 1-(3-chlorophenyl)butanone (3fa; Table 2, entry 1) General procedure: In a flame dried Schlenk tube (fitted with a Teflon plug valve) 1.2 mmol (0.127 g) of No.15 butanoyl chloride (2a) was added to a stirred mixture of 1.0 mmol (0.402 g) of No.16 tributyl(3-chlorophenyl)stannane (1f) and No.17 indium powder (0.148 g, 1.0 mmol) under a nitrogen gas stream. After purging the system with nitrogen by means of three pump-fill cycles, the tube was capped and immersed in a water–detergent bath at 60 °C. The ultrasonic titanium horn was placed into the bath to a distance of 10 mm to the wall and 5 mm from the bottom of the Schlenk tube and ultrasound was applied in a pulsed mode (duty cycle = 70percent; output power = 70percent) for 10 min. After addition of 10percent (m/v) solution of No.18 NaOH (2 mL) and 10 μL of No.19 tetradecane (internal standard), the mixture was stirred at room temperature for 15 min and then diluted with DCM (5 mL). Once the stirring was stopped for about 5 min, the supernatant liquid mixture was decanted into a separatory funnel. The silverywhite solid, settled at the bottom of the Schlenk tube, was washed with acetone (2 × 5 mL), deionized water (2 × 5 mL), and then vacuum-dried at room temperature. As indicated by DSC analysis, the dried sample (0.133 g) meant a 90percent recovered yield of pure No.20 indium. On the other hand, the organic phase was successively washed with water and brine, dried over Na2SO4, filtered, analyzed by GC, and then concentrated in vacuo. Purification by column chromatography on silica gel (60 Å, 70–230 mesh) doped with 10percent of KF (hexanes/DCM 8:2) gave 0.096 g (53percent) of 3fa as a colorless oil. With indium in neat (no solvent), Time= 0.116667h, T= 80 °C , Inert atmosphere, Sonication Lo Fiego, Marcos J.; Badajoz, Mercedes A.; Domini, Claudia; Chopa, Alicia B.; Lockhart, Maria T.; Ultrasonics Sonochemistry; vol. 20; nb. 3; (2013); p. 826 - 832 View in Reaxys

H O

Sn Cl ClCl Cl 2Sn

Rx-ID: 33296769 View in Reaxys 2/267 Yield

Conditions & References With H2O2 in hydrogenchloride, SnCl2*2H2O dissolved in H2O; concd. HCl and H2O2 added; heated Mamedova; Ragimov; Sadykhov; Aliev; Russian Journal of Inorganic Chemistry; vol. 57; nb. 2; (2012); p. 160 162 ; (from Gmelin) View in Reaxys

Cl Cl

Cl Sn Cl

Cl Sn

Sn ClCl

Rx-ID: 31606073 View in Reaxys 3/267 Yield

Conditions & References With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran, 50°C Cabon, Yves; Gebbink, Robertus J. M. Klein; Deelman, Berth-Jan; Dalton Transactions; vol. 40; nb. 34; (2011); p. 8651 - 8655 ; (from Gmelin) View in Reaxys in tetrahydrofuran, 50°C Cabon, Yves; Gebbink, Robertus J. M. Klein; Deelman, Berth-Jan; Dalton Transactions; vol. 40; nb. 34; (2011); p. 8651 - 8655 ; (from Gmelin) View in Reaxys

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N S

NH 2

Cl Sn Cl ClCl

Rx-ID: 23848811 View in Reaxys 4/267 Yield

Conditions & References 9.1 :(1)4-benzylsulhydryl-3-nitro-1,8-naphthalic anhydride 4-bromo-3-nitro-1,8-naphthalic anhydride (0.0072mol) (4) was dissolved in DMF (45ml) in 100 ml of three-neck flask. After addition of K2CO3 (0.0036mol) and benzyl sulfhydrate (0.0072mol), the solution was stirred at 80°C for 8h until there was no raw material. The reaction mixture was poured into ice-water, then salted out under stirring. A yellow solid precipitated after filtration and washing by water and dried to give khaki solid (2.47g, 83percent): mp 188-193°C (uncorrected). With hydrogenchloride, tin(ll) chloride in water, Time= 2h, T= 90 °C Patent; East China University of Science and Technology; Shanghai Institute of Materia Medica, Chinese Academy of Sciences; Dalian University of Technology; EP1626050; (2006); (A1) English View in Reaxys Cl

Sn ClCl

Rx-ID: 26501768 View in Reaxys 5/267 Yield

Conditions & References in neat (no solvent), byproducts: butane, HCl; Sn compd. was sealed in vac. in NMR tube; heated at 200°C for 48 h; NMR monitoring; not isolated Davies, Alwyn G.; Sella, Andrea; Sivasubramaniam, Rajaveen; Journal of Organometallic Chemistry; vol. 691; nb. 16; (2006); p. 3556 - 3561 ; (from Gmelin) View in Reaxys 4 Cl –

Sn4+

Sn ClCl

Rx-ID: 26254191 View in Reaxys 6/267 Yield

Conditions & References in neat (no solvent, solid phase), byproducts: pyridine; heated at 495-555°C; detd. by thermogravimetry Dunstan, Pedro Oliver; Thermochimica Acta; vol. 398; nb. 1-2; (2003); p. 1 - 7 ; (from Gmelin) View in Reaxys 4 Cl –

2HN

Sn4+

Sn ClCl

Rx-ID: 26254192 View in Reaxys 7/267 Yield

Conditions & References in neat (no solvent, solid phase), byproducts: piperidine; heated at 464-681°C; detd. by thermogravimetry Dunstan, Pedro Oliver; Thermochimica Acta; vol. 398; nb. 1-2; (2003); p. 1 - 7 ; (from Gmelin) View in Reaxys Cl Sn Cl ClCl

Rx-ID: 24145667 View in Reaxys 8/267

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Yield

Conditions & References 7 : Tin Chloride Reduction EXAMPLE 7 Tin Chloride Reduction The Tbags were placed in 2 L bottles (100 bags per 2L bottle). A 2 M solution of tin chloride dihydrate in DMF was prepared and added to the reaction bottles (1L per bottle) containing the T-bags. The reactions were shaken overnight for 24 hours. The Tbags were washed with DMF (6*, 500 mL), MeOH (3*, 500 mL), DMF (3*, 500 mL), 5percent DIEA/DCM (333, 500 mL), DCM (3*, 500 mL), and MeOH (3*, 500 mL). The Tbags were air dried overnight. Patent; Lion Bioscience AG; US6452009; (2002); (B1) English View in Reaxys 5 : Stabilization with SnCl4 Example 5 Stabilization with SnCl4 A tin(IV) chloride solution (0.439 g of SnCl4 *5H2 O in 5 g of H2 O) is added at room temperature to 80 g of titanium dioxide sol prepared by electrolysis (10 g of TiO2) and the mixture is subsequently stirred for 1 hour. A citrate solution (7 g of trisodium citrate dihydrate in 10.5 g of H2 O) is then added, the mixture is subsequently stirred for 15 minutes and the pH is then brought to 6.7 with sodium hydroxide solution (w=32percent). Patent; Merck Patent Gesellschaft Mit Beschrankter Haftung; US5698205; (1997); (A1) English View in Reaxys

2.31 g (80.6% from 1a)

14 : 14. 14. Representative Example of a Preparative Stille Coupling: A sealed tube under nitrogen was charged with tin reactant 1a (2.97 g, 2.40 mmol), 1-bromo-4-nitrobenzene (404 mg, 2.00 mmol), lithium chloride (254 mg, 6.00 mmol), dichlorobis(triphenylphosphine)palladium(II) (28.1 mg, 0.04 mmol), dry DMF (5 mL), and dry THF (5 mL). The mixture was heated to 80° C. and a homogeneous solution resulted. The mixture was stirred at 80° C. for 22 h. After azeotropic evaporation with toluene at 75° C. (to remove THF and some of the DMF), the resulting residue was partitioned between water (40 mL), dichloromethane (60 mL), and FC-72 (40 mL). The three phases were separated. Evaporation of the FC-72 phase provided 2.31 g (80.6percent from 1a) of tin chloride 8 as a colorless oil. The dichloromethane phase was washed three more times with water (40 mL) and FC-72 (40 mL). Evaporation of the combined FC-72 phases (including the first phase) provided 2.85 g (99.4percent from 1a) of tin chloride 8. Patent; University of Pittsburgh; US5777121; (1998); (A1) English View in Reaxys 15 : 15. 15. Representative Example of Recycle of Tin Reactants: The tin chloride 8 (2.85 g) isolated by evaporation of FC-72 phase after the above Stille coupling was treated with a 3M solution of phenyl magnesium bromide in ether (1.04 mL, 3.12 mmol) in dry ether (25 mL) under stirring at 25° C. for 6 h. The reaction mixture was hydrolyzed with NH4 Cl solution and diluted with ether, and the organic phase was washed with deionized water then dried over anhydrous MgSO4. The solvent was evaporated to dryness. Column chromatography on neutral alumina with hexane yielded pure compound la (2.85 g, 96percent overall from 1a in the preceding section) as a colorless oil. Patent; University of Pittsburgh; US5777121; (1998); (A1) English View in Reaxys (e) Bi2 O3 --SnO2 (SnO2:Bi2 O3 =57:43) (e) Bi2 O3 --SnO2 (SnO2:Bi2 O3 =57:43) 19.4 g Bi(NO3)3.5H 2 O were suspended in 300 ml water (with subsequent pH=0.5).

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Using concentrated NH3 (aq) titration was effected to pH=7 and then by simultaneous dripping of NH3 (aq) in 200 ml water, the dissolved SnCl4 (22.1 g) was precipitated at pH=7. The solids were filtered off and washed free of chloride. After 2 h drying at 120° C. calcination was carried out for 16 h at 700° C. in the water jet pump vacuum. Patent; Baerns; Manfred; US4608449; (1986); (A1) English View in Reaxys 4 : Dehydrohalogenation with SnCl4 /Alumina EXAMPLE 4 Dehydrohalogenation with SnCl4 /Alumina A supported catalyst is prepared by slurrying 0.3 g. of SnCl4 and 3.0 g. of the alumina used in Example 2 in 10 ml. of CCl4 and then stirring the slurry at 70° C. for one hour. DCTCB is then dehydrohalogenated using this supported catalyst according to the procedure of Example 3. Analysis of the resulting dehydrohalogenated product shows that it contains 95.7 percent of DCTCS and 3.4 percent of the diene. Patent; The Dow Chemical Company; US4205015; (1980); (A1) English View in Reaxys Cl

Sn Cl

Sn ClCl

Rx-ID: 25360560 View in Reaxys 9/267 Yield

Conditions & References

13.5 g (83%)

Preparation of BuSnCl3from Bu4Sn and SnCl4. Preparation of BuSnCl3from Bu4Sn and SnCl4. In this typical procedure, SnCl4(11.15 g, 0.043 mol) was dissolved in toluene (10 mL). Next, Bu4Sn (4.96 g, 0.0143 mol) was added and reaction mixture was stirred for 2 h at 110°C. After cooling of the reaction mixture to room temperature, the catalyst PtCl2(PPh3)2(3.8 mg, 4.8 μmol) was added and the reaction mixture was stirred for another 12 h at 110°C. Filtration of the reaction mixture gave a slightly yellow solution which was analyzed by 119Sn NMR using SnMe4as external standard. After evaporation of volatiles invacuo, vacuum distillation (90°C/11 mmHg) afforded 13.5 g (83percent) of butyltin trichloride as a colorless liquid. The solid material obtained from the filtrationwas washed twice with toluene (5 mL) and dried in vacuoto give 0.40 g of an off-white solid. The solid was dissolved in acetone-d6and indentified as SnCl2by 119Sn NMR (δ = -235.1). Elemental analysis: Cl, 36.92percent; Sn, 62.40percent. SnCl2requires: Cl, 37.40percent; Sn, 62.60percent. The results of the different experiments are presented in Table 2.x Patent; Atofina Vlissingen B.V.; EP1225177; (2002); (A1) English View in Reaxys Cl

Sn ClCl

Rx-ID: 26139888 View in Reaxys 10/267 Yield

Conditions & References With dihydrogen peroxide, in mixt. of H2O2 and HCl, excess H2O2 Salkowski, E.; Chemiker-Zeitung; vol. 40; (1916); p. 448 - 449 View in Reaxys vol. Sn: MVol.B; 14.7.5, page 368 - 371 ; (from Gmelin) View in Reaxys With nitric acid, in aqua regia; depending of concn. ratio HNO3:HCl Gay-Lussac, L. J.; Ann. Chim. Phys.; vol. 23; (1848); p. 203 - 229 View in Reaxys vol. Sn: MVol.B; 14.7.5, page 368 - 371 ; (from Gmelin)

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View in Reaxys in further solvent(s) Heumann, K.; Koechlin, P.; Ber. Dtsch. Chem. Ges.; vol. 15; (1882); p. 416 - 420 View in Reaxys vol. Sn: MVol.B; 14.4.3, page 357 - 358 ; (from Gmelin) View in Reaxys in hydrogenchloride, metallinc tin dissolved in 9 M HCl Arapnev, A. I.; Yukhin, Yu. M.; Malinovskaya, T. D.; Egorov, Yu. P.; Russian Journal of Applied Chemistry; vol. 75; (2002); p. 1557 - 1561; Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation); vol. 75; (2002); p. 1594 - 1597 ; (from Gmelin) View in Reaxys according to: Yu. V. Karyakin, I. I. Angelov, Chistye Khimicheskie Veshchestva (Pure Chemical Substances), Izd. Khimiya, Moscow, 1974, p. 298 Strizhev, E. F.; Masloboev, D. S.; Kukushkin, Yu. N.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 23; (1978); p. 1178 - 1181; Zhurnal Neorganicheskoi Khimii; vol. 23; (1978); p. 2145 - 2150 ; (from Gmelin) View in Reaxys

2H O 2

S S

Cl 2Cu

Cl 2Sn

Sn Cl Cl

Sn ClCl

Rx-ID: 27137413 View in Reaxys 11/267 Yield

Conditions & References in tetrahydrofuran, (Ar); refluxed for 6 h; filtered; not isolated, detected by MS in the filtrate Sinha, Pradipta; Kundu, Abhijit; Roy, Sujit; Prabhakar, Sripadi; Vairamani; Sankar, A. Ravi; Kunwar; Organometallics; vol. 20; nb. 1; (2001); p. 157 - 162 ; (from Gmelin) View in Reaxys

Si H – (v4) C– HC (v4) Sn4+ (v4) (v4) CH–HC –

Cl (v4)

Zr Cl ClCl

(v4)

(v5)(v5)H (v5) (v5) Si

(v5) H H Cl Zr H (v5) (v5) (v12) Cl H (v5)

Cl Sn Cl ClCl

racemate

Rx-ID: 26600647 View in Reaxys 12/267 Yield

Conditions & References

80 %

in toluene, stirring (16 h); solvent removal (vac.), addn. pentane, filtration, volatiles rremoval (vac.) Huettenhofer, Mario; Schaper, Frank; Brintzinger, Hans H.; Angewandte Chemie - International Edition; vol. 37; nb. 16; (1998); p. 2268 - 2270 ; (from Gmelin) View in Reaxys N

2 N

Sn Cl ClCl

Sn ClCl

Rx-ID: 26061647 View in Reaxys 13/267 Yield

Conditions & References thermal dissociation, 280 to 340°C; reaction monitoring by pressure measurement German; Sevast'yanova; Suvorov; Anatsko; Russian Journal of General Chemistry; vol. 67; nb. 8; (1997); p. 1188 - 1192 ; (from Gmelin)

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View in Reaxys

ClLi

2 Li+ Cl 2Cl SnCl Cl Cl

Cl 2Sn

Cl Cl

Sn ClCl

Rx-ID: 26099489 View in Reaxys 14/267 Yield

Conditions & References in neat (no solvent), fusing tin and alkali metal chloride (sealed quartz ampule), grinding (N2 atmosphere over P2O5), gradual heating (quartz ampule, 110 - 130°C, 1 Pa), cooling (boiling N2 temp., vac., condensation of Cl2 to ampule), storing (4 - 8 d); opening, filling (He); detd. by Raman spectroscopy Salyulev; Vovkotrub; Strekalovskii; Russian Journal of Inorganic Chemistry; vol. 42; nb. 5; (1997); p. 631 - 632 ; (from Gmelin) View in Reaxys

ClNa

2 Cl 2Cl SnCl Cl Cl

Cl 2Sn

K+

Cl Cl

Sn ClCl

Rx-ID: 26100001 View in Reaxys 15/267 Yield

Fe 2O3

Cl Fe

O2Sn Cl

(v3)

Sn ClCl

Rx-ID: 26073322 View in Reaxys 16/267 Yield

Conditions & References Kinetics, chlorination of mechanical SnO2/Fe2O3 mixt. at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction Solov'eva, E. A.; Derlukova, L. E.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 39; (1994); p. 1697 - 1700; Zhurnal Neorganicheskoi Khimii; vol. 39; (1994); p. 1773 - 1776 ; (from Gmelin) View in Reaxys Kinetics, chlorination of SnO2/Fe2O3 mixt. (obtained by copptn. from hydrochloric SnCl4/FeCl3 soln. with concd. ammonia and ppt. calcination in air at 600°C for 24 h) at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction Solov'eva, E. A.; Derlukova, L. E.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 39; (1994); p. 1697 - 1700; Zhurnal Neorganicheskoi Khimii; vol. 39; (1994); p. 1773 - 1776 ; (from Gmelin) View in Reaxys

In2O3

O2Sn

Cl Cl Cl In In (v4) ClCl Cl

(v4)

Cl In

Sn ClCl

Rx-ID: 26078739 View in Reaxys 17/267 Yield

Conditions & References in neat (no solvent), Kinetics, byproducts: O2; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2 flow 100 ml/min); chem. anal. Anufrieva, T. A.; Derlyukova, L. E.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 39; (1994); p. 1559 - 1563; Zhurnal Neorganicheskoi Khimii; vol. 39; (1994); p. 1629 - 1633 ; (from Gmelin)

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View in Reaxys With sulfur dioxide in neat (no solvent), Kinetics, byproducts: O2, SO3, In2(SO4)3; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2/SO2 flow 100 ml/min); chem. anal. Anufrieva, T. A.; Derlyukova, L. E.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 39; (1994); p. 1559 - 1563; Zhurnal Neorganicheskoi Khimii; vol. 39; (1994); p. 1629 - 1633 ; (from Gmelin) View in Reaxys Cl

O2Sn

Sn Cl ClCl

Rx-ID: 26182511 View in Reaxys 18/267 Yield

Conditions & References in neat (no solvent), formation by reaction of SnO2 with Cl2 at red heat; vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys 800°C in presence of Fe2O3 and C Frents, G. S.; Tsvetn. Met.; vol. 16; nb. 4; (1941); p. 25 - 27; C.; (1942); p. 2738 II ; (from Gmelin) View in Reaxys in neat (no solvent), Kinetics, byproducts: O2; react. at 200-1000°C Derylukova, L. E.; Solov'eva, E. A.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 37; (1992); p. 991 - 994; Zhurnal Neorganicheskoi Khimii; vol. 37; (1992); p. 1923 - 1927 ; (from Gmelin) View in Reaxys Kinetics, chlorination at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction Solov'eva, E. A.; Derlukova, L. E.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 39; (1994); p. 1697 - 1700; Zhurnal Neorganicheskoi Khimii; vol. 39; (1994); p. 1773 - 1776 ; (from Gmelin) View in Reaxys 800°C in presence of Fe2O3 and C vol. Sn: MVol.B; 3, page 1 - 41 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by reaction of SnO2 with Cl2 at red heat; Weber, R.; Ann. Physik Chem. (2); vol. 112; (1861); p. 619 - 626 ; (from Gmelin) View in Reaxys Cl

O2Sn

Sn ClCl

Rx-ID: 26186705 View in Reaxys 19/267 Yield

Conditions & References With carbon monoxide, chlorine in neat (no solvent), Kinetics, byproducts: CO2; 400-800°C Evdokimov, V. I.; Kinetics and Catalysis; vol. 35; (1994); p. 312 - 315; Kinetika i Kataliz; vol. 35; (1994); p. 409 412 ; (from Gmelin) View in Reaxys With hydrogenchloride, carbon monoxide in neat (no solvent), formation of SnCl4 in presence of HCl at reaction with CO in absence of further metal-oxides; Lythe, R. G.; Prosser, A. P.; Inst. Mining Met. Trans. C; vol. 79; (1970); p. 109 - 111 View in Reaxys vol. Sn: MVol.C1; 3.7.8.4.5, page 102 - 103 ; (from Gmelin)

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View in Reaxys With chlorine in neat (no solvent), Kinetics, byproducts: O2; 400-1000°C Evdokimov, V. I.; Kinetics and Catalysis; vol. 35; (1994); p. 312 - 315; Kinetika i Kataliz; vol. 35; (1994); p. 409 412 ; (from Gmelin) View in Reaxys With chlorine in neat (no solvent), Kinetics, byproducts: O2; chlorination at 750-850°C; examination of the equilibrium reaction; DARADIMOS G; KUXMANN U; Erzmetall: Journal for Exploration, Mining and Metallurgy; vol. 24; nb. 4; (1971); p. 163 - 172 ; (from Gmelin) View in Reaxys With sulfur dioxide, chlorine in neat (no solvent), Kinetics, byproducts: SO3; 400-1000°C Evdokimov, V. I.; Kinetics and Catalysis; vol. 35; (1994); p. 312 - 315; Kinetika i Kataliz; vol. 35; (1994); p. 409 412 ; (from Gmelin) View in Reaxys With iron(III) chloride in neat (no solvent) Frents, G. S.; Izv. Akad. Nauk SSSR Otd. Tekhn. Nauk; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys in neat (no solvent), pptd. SnO2; 250°C; Hecht, H.; Jander, G.; Schlapmann, H.; Z. Anorg. Chem.; vol. 254; (1947); p. 255 - 264 ; (from Gmelin) View in Reaxys With Cl2 in neat (no solvent), Kinetics, byproducts: O2; chlorination at 750-850°C; examination of the equilibrium reaction; vol. Sn: MVol.C1; 3.7.8.3, page 98 - 100 ; (from Gmelin) View in Reaxys in neat (no solvent), pptd. SnO2; 250°C; vol. S: MVol.B3; 125, page 1798 - 1799 ; (from Gmelin) View in Reaxys Cl Sn

Cl Cl

Sn ClCl

Rx-ID: 26139930 View in Reaxys 20/267 Yield

Conditions & References 120-150°C Evdokimov, A. I.; Morozov, I. S.; Chimie et Industrie (Paris); vol. 88; (1962); p. 115 - 119 View in Reaxys Evdokimov, A. I.; Morozov, I. S.; Vestn. Akad. Nauk SSSR; vol. 31; nb. 2; (1961); p. 44 - 47; C.A.; (1961); p. 15282 ; (from Gmelin) View in Reaxys 120°C, in autoclave vol. Sn: MVol.B; 14.2.4, page 352 - 353 View in Reaxys Rondelli, T.; Atti Congr. Nazl. Chim. Ind. Milano 1924, S. 343/52 ; (from Gmelin) View in Reaxys Lorenz, R.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 10; (1895); p. 44 - 46 View in Reaxys vol. Sn: MVol.B; 14.2.4, page 352 - 353 ; (from Gmelin)

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View in Reaxys With sulfur in neat (no solvent), dissolution of excess Cl2 in some SnCl4 under addn. of a small amount of S; effect of the soln. on pure Sn (casual shaking, several weeks); vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 View in Reaxys Brallier, P. S.; Trans. Am. Electrochem. Soc.; vol. 49; (1926); p. 257 - 266 ; (from Gmelin) View in Reaxys With SbCl3 or SbCl5 in neat (no solvent), formation by chlorination of molten Sn in presence of SbCl3 or SbCl5;; free from SnCl2; vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 View in Reaxys Patent; Wolf, J.; Favre, G. A.; US1937419; (1933); C. II; (1934); p. 1974 ; (from Gmelin) View in Reaxys in melt, melting of Sn by chlorination under formation of SnCl4; vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 View in Reaxys Patent; Tyson, P. L.; General Chemical Co.; US2061816; (1936); C. I; (1937); p. 2427 ; (from Gmelin) View in Reaxys in tetrachloromethane, in presence of small amts. of S Ochi, S.; J. Chem. Ind. Japan; vol. 23; (1920); p. 583 - 594 View in Reaxys vol. Sn: MVol.B; 14.2.4, page 352 - 353 View in Reaxys Brallier, P. S.; Trans. Am. Electrochem. Soc.; vol. 49; (1926); p. 257 - 266 ; (from Gmelin) View in Reaxys in tetrachloromethane vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 View in Reaxys Rondelli, T.; Atti Congr. Nazl. Chim. Ind., Milan 1924, S. 343/52 ; (from Gmelin) View in Reaxys in neat (no solvent), dissolution of excess Cl2 in some SnCl4; effect of the soln. on pure Sn (casual shaking, several weeks); Baxter, G. P.; Starkweather, H. W.; Journal of the American Chemical Society; vol. 42; (1920); p. 583 - 594 View in Reaxys vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by chlorination of Sn at 40-70°C; Stepin, B. D.; Grinshtein, S. A.; Khimicheskaya Promyshlennost (St. Petersburg, Russian Federation); (1961); p. 46 - 51 View in Reaxys vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by chlorination of Sn melts at 260-410°C; Zvezdin, A. G.; Ketov, A. N.; Fomin, V. K.; Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation); vol. 43; (1970); p. 2569 - 2571; Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation); vol. 43; (1970); p. 2541 - 2543 View in Reaxys vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 ; (from Gmelin) View in Reaxys

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in neat (no solvent), formation by passing dry Cl2 under exclusion of moisture over granulated Sn; Loon, C. van; Chemisch Weekblad; vol. 17; (1920); p. 664 - 664 View in Reaxys Taverne, H. J.; Chemisch Weekblad; vol. 17; (1920); p. 610 - 610 View in Reaxys vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by spraying molten Sn in Cl2 atmosphere; vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 View in Reaxys Patent; Lienhardt, W. S.; US1826800; (1931); C. II; (1931); p. 3648 ; (from Gmelin) View in Reaxys in neat (no solvent), formation in an exothermic reaction by heating of metallic Sn with Cl2 gas; Berzelius, J. J.; Schweiggers J. Chem. Physik; vol. 6; (1812); p. 284 - 322 View in Reaxys Davy, J.; Philosophical Transactions of the Royal Society of London; vol. 102; (1812); p. 169 - 204 View in Reaxys Davy, J.; Schweiggers J. Chem. Physik; vol. 10; (1814); p. 311 - 354 View in Reaxys Proust, J. L.; J. Phys. Chim. Hist. Nat.; vol. 51; (1800); p. 173 - 184 View in Reaxys Proust, J. L.; J. Phys. Chim. Hist. Nat.; vol. 61; (1804); p. 338 - 349 View in Reaxys vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 ; (from Gmelin) View in Reaxys in neat (no solvent), formation in an exothermic reaction by heating of metallic Sn with very dry Cl2 gas; Cowper, R.; Journal of the Chemical Society; vol. 43; (1883); p. 153 - 155 View in Reaxys vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 ; (from Gmelin) View in Reaxys in neat (no solvent), passing dry Cl2 through a reaction tube filled with granulated Sn also contg. some SnCl4; reaction temp. of 110-115°C; gathering under moisture exclusion after cooling; Lorenz, R.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 10; (1895); p. 44 - 46 View in Reaxys Tseng, Fan-Chieh; Chiang, Li-Chin; Hua Hsueh Tung Pao; (1961); p. 506 - 509; C. A.; vol. 58; (1963); p. 13416 View in Reaxys vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 ; (from Gmelin) View in Reaxys in neat (no solvent), passing dry Cl2 under tin metal Kanjolia, R. K.; Gupta, V. D.; Journal of the Indian Chemical Society; vol. 58; (1981); p. 340 - 342 ; (from Gmelin) View in Reaxys 120-150°C vol. Sn: MVol.B; 3, page 1 - 41 ; (from Gmelin) View in Reaxys in neat (no solvent), passing dry chlorine over tin metal; distn., filtn. Gupta, K. L.; Srivastava, P.; Saxena, G. C.; Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry; vol. 23; (1993); p. 177 - 184 ; (from Gmelin) View in Reaxys

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Cl SnH 4

(v4)

Sn ClCl

Rx-ID: 26315862 View in Reaxys 21/267 Yield

Conditions & References in further solvent(s), byproducts: toluene, HCl; atmosphere of N2 contg. 0.1percent of O2; liquid N2-bath, 3 h, in benzylchloride Reifenberg, Gerald H.; Considine, William J.; Organometallics; vol. 12; (1993); p. 3015 - 3018 ; (from Gmelin) View in Reaxys Cl

O4Sb2

.alpha.

Cl Sb Cl

O2Sn Cl

Sn ClCl

Rx-ID: 26182438 View in Reaxys 22/267 Yield

Conditions & References in neat (no solvent), Kinetics, byproducts: O2; react. at 700-900°C Derylukova, L. E.; Solov'eva, E. A.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 37; (1992); p. 991 - 994; Zhurnal Neorganicheskoi Khimii; vol. 37; (1992); p. 1923 - 1927 ; (from Gmelin) View in Reaxys Cl Si S

Sn ClCl

Rx-ID: 24822542 View in Reaxys 23/267 Yield

Conditions & References

95%

6 : Materials and Instrumentation EXAMPLE 6 Materials and Instrumentation 1 H NMR spectra were taken on either a Varian XL-200 or XL-400 spectrometer. 13 C NMR spectra were taken on a Varian XL-400 spectrometer. IR spectra were taken on either a Perkin-Elmer 299B or a Mattson Polaris FT-IR spectrophotometer. Mass spectra were taken on either a Finnigan 3300 or an AEI MS-902 mass spectrometer. Hydrogenations were carried out on a Series 3910 Parr Hydrogenator. Trimethylsilyl cyanide (98percent), boron trifluoride etherate (purified and redistilled), and tin (IV) chloride (anhydrous, 99percent) were obtained from Aldrich Chemical Company. Methylthiotrimethylsilane (approximately 95percent) was obtained from Fluka. Silica gel (approximately 40 μm average particle diameter) was obtained from J. T. Baker Chemical Company. A reaction run under dry conditions signifies a reaction run in flame- or oven-dried glassware and under an argon or nitrogen atmosphere. Patent; The United States of America as represented by the Secretary of Agriculture; Cornell Research Foundation, Inc.; US4942247; (1990); (A1) English View in Reaxys

N 2

Cl Cl SnCl 2Cl Cl Cl

Cl Cl

Sn ClCl

H+

Rx-ID: 26178016 View in Reaxys 24/267 Yield

Conditions & References byproducts: HCl, 3,4-dimethylpyridine; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys

12/80

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Cl Cl SnCl 2Cl Cl Cl

Cl Cl

Sn ClCl

2 H+

Rx-ID: 26178017 View in Reaxys 25/267 Yield

Conditions & References byproducts: HCl, 2,4-dimethylpyridine; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys

Cl Cl SnCl 2Cl Cl Cl

Cl Cl

Sn ClCl

2 H+

Rx-ID: 26178018 View in Reaxys 26/267 Yield

Conditions & References byproducts: HCl, 3,5-dimethylpyridine; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys -2 Cl

Cl SnCl Cl Cl (v6) N 2

Sn ClCl

H+

Rx-ID: 26178025 View in Reaxys 27/267 Yield

Conditions & References byproducts: HCl, 2,4,6-trimethylpyridine; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys

2Cl SnCl Cl Cl

2 N

Sn ClCl

2 H+

Rx-ID: 26178110 View in Reaxys 28/267 Yield

Conditions & References byproducts: HCl, 2-methylquinoline; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys

2 N 2

Cl 2Cl SnCl Cl Cl Cl

Cl Cl

Sn ClCl

H+

Rx-ID: 26178142 View in Reaxys 29/267 Yield

Conditions & References byproducts: HCl, acridine; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys

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Cl 2

2Cl SnCl Cl Cl

N 2

Sn ClCl

H+

Rx-ID: 26178178 View in Reaxys 30/267 Yield

Conditions & References byproducts: HCl, 4-methylpyridine; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys

2 N

Cl Cl SnCl 2Cl Cl Cl

Cl Cl

Sn ClCl

2 H+

Rx-ID: 26178179 View in Reaxys 31/267 Yield

Conditions & References byproducts: HCl, 3-methylpyridine; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys

(v1)

(v3)

H OHO O (v4) (v4) Cl H N 99Tc N (v4) (v6) O (v4) Sn HO N (v7)N O Cl (v4) O (v4) NO H Cl

(v1)

OHO (v4) N

(v4) N(v7) 99 (v4) HO HO (v4) Tc N (v4)N ClOH (v4) N O

Sn ClCl

(v1)

(v1)(v3)

Rx-ID: 26333834 View in Reaxys 32/267 Yield

Conditions & References

82 %

With HCl in acetonitrile, room temp., 30 min. (crystn.); cooling (-20°C), decantation, washing (cold MeCN, cold 1 M HCl), drying (vac., 6 h), recrystn. (EtOH/HCl); elem. anal. Linder, Karen E.; Malley, Mary F.; Gougoutas, Jack Z.; Unger, Steve E.; Nunn, Adrian D.; Inorganic Chemistry; vol. 29; (1990); p. 2428 - 2434 ; (from Gmelin) View in Reaxys -2

2 N 2

Cl Cl SnCl Cl Cl (v6) Cl

Cl Sn Cl ClCl

H+

Rx-ID: 26421946 View in Reaxys 33/267 Yield

Conditions & References byproducts: HCl, pyridine; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys -2 Cl Cl SnCl Cl Cl

2 N

(v6)

Cl Cl

Sn ClCl

2 H+

Rx-ID: 26617405 View in Reaxys 34/267 Yield

Conditions & References byproducts: HCl, quinoline; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys

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-2 2 N

Cl Cl SnCl Cl Cl (v6) Cl

Cl Sn Cl ClCl

2 H+

Rx-ID: 26617416 View in Reaxys 35/267 Yield

Conditions & References byproducts: HCl, isoquinoline; thermal decomposition; studied by thermal analysis Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 157; (1990); p. 137 - 154 ; (from Gmelin) View in Reaxys

H O

(v3)

OHH O O (v4) (v4) Cl N N 99 (v4) (v6) OHO (v4) Tc Sn (v7) N N Cl O (v4) (v4) NO H Cl (v3)

(v1)

OH (v1) Cl O (v4) (v4)

N N 99 (v4) (v4) Tc HO N (v7) N (v4) HO (v4) N O

Sn Cl ClCl

(v1)

Rx-ID: 26748690 View in Reaxys 36/267 Yield

Conditions & References

75 %

With HCl in acetonitrile, stirring (30 min., pptn.); addn. of excess 1 M HCl, collection (after 15 min.), washing (1 M HCl, H2O), drying (vac.), recrystn. (MeCN/1 M HCl); elem. anal. Linder, Karen E.; Malley, Mary F.; Gougoutas, Jack Z.; Unger, Steve E.; Nunn, Adrian D.; Inorganic Chemistry; vol. 29; (1990); p. 2428 - 2434 ; (from Gmelin) View in Reaxys

(v3)

O O

(v3)

(v3) (v3) (v6) O Mn (v6) O (v3) O

(v3)

Cl 2Sn

(v3)(v3)O

(v3)

(v6)

Sn Cl (v6) (v6)

Mn O

(v3)

O (v3) (v3) Cl O Sn

O O

(v3)

Sn Cl O

O (v3) (v3)

(v3)

Cl Cl

Sn ClCl

(v3)

Rx-ID: 26179898 View in Reaxys 37/267 Yield

Conditions & References

73 %

in N,N-dimethyl-formamide, byproducts: CO; Ar atmosphere, 150°C, 24 h; pptn. on addn. of H2O, washing (dild. HCl and cyclohexane), drying (vac.); elem. anal. Haupt, H.-J.; Keppler, T.; Floerke, U.; Calage, Y.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 571; (1989); p. 51 - 59 ; (from Gmelin) View in Reaxys Cl

2NH 2ClClSnCl Cl

Cl 2

H Cl

Sn ClCl

H 2N

H+

Rx-ID: 26412886 View in Reaxys 38/267 Yield

Conditions & References in neat (no solvent), Kinetics, byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 141; (1989); p. 93 - 112 ; (from Gmelin) View in Reaxys

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Cl 2

2Cl SnCl Cl Cl

NH 2 2

NH 2

Sn Cl ClCl

H+

Rx-ID: 26413891 View in Reaxys 39/267 Yield

Conditions & References in neat (no solvent), Kinetics, thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 141; (1989); p. 93 - 112 ; (from Gmelin) View in Reaxys -2 Cl

Cl SnCl Cl Cl (v6)

H Cl

Sn ClCl

2 H+

Rx-ID: 26413892 View in Reaxys 40/267 Yield

H N

Cl 2

NH ClClSnClCl (v6)

H Cl

Cl 2

Sn ClCl

H+

Rx-ID: 26413924 View in Reaxys 41/267 Yield

N+

Cl 2Cl SnCl Cl Cl Cl

Cl Cl

Sn ClCl

Rx-ID: 26414064 View in Reaxys 42/267 Yield

2 N H 2 H+

2Cl SnCl Cl Cl

H N

Sn Cl ClCl

Rx-ID: 26415368 View in Reaxys 43/267 Yield

Conditions & References in neat (no solvent), Kinetics, byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements

16/80

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Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 141; (1989); p. 93 - 112 ; (from Gmelin) View in Reaxys -2 Cl 2

Cl SnClCl Cl (v6) Cl

Sn Cl ClCl

H+

Rx-ID: 26415369 View in Reaxys 44/267 Yield

Conditions & References in neat (no solvent), Kinetics, byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 141; (1989); p. 93 - 112 ; (from Gmelin) View in Reaxys

Cl 2NH Cl SnCl Cl Cl

N H

Sn ClCl

2 H+

Rx-ID: 26415370 View in Reaxys 45/267 Yield

Cl Cl SnCl Cl Cl (v6)

N+

Sn Cl ClCl

Rx-ID: 26417309 View in Reaxys 46/267 Yield

N+

Cl Cl SnCl Cl Cl Cl

(v6)

Sn ClCl

Rx-ID: 26417365 View in Reaxys 47/267 Yield

2 N 2

Cl SnCl Cl Cl (v6) Cl

Sn Cl ClCl

H+

Rx-ID: 26419847 View in Reaxys 48/267

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Yield

2Cl SnCl Cl Cl NH 2 Cl

NH 2

2 H+

Sn ClCl

Rx-ID: 26420600 View in Reaxys 49/267 Yield

Conditions & References in neat (no solvent), Kinetics, thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 141; (1989); p. 93 - 112 ; (from Gmelin) View in Reaxys Cl

2Cl SnCl Cl Cl

NH 2 2

NH 2

Sn ClCl

H+

Rx-ID: 26421844 View in Reaxys 50/267 Yield

Cl 2

Cl 2Cl NH 2 ClSn Cl

Cl 2

H 2N

Sn ClCl

H+

Rx-ID: 26421845 View in Reaxys 51/267 Yield

2Cl SnCl Cl Cl

NH 2

2 H+

Sn Cl ClCl

H 2N

Rx-ID: 26421846 View in Reaxys 52/267 Yield

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-2 Cl 2

Cl SnCl Cl Cl (v6)

H Cl

N H

Sn ClCl

2 H+

Rx-ID: 26421847 View in Reaxys 53/267 Yield

Cl 2

2Cl SnCl Cl Cl

N H 2

N H

Sn ClCl

H+

Rx-ID: 26421911 View in Reaxys 54/267 Yield

Cl SnCl Cl Cl (v6)

H Cl

N H

Sn ClCl

2 H+

Rx-ID: 26421912 View in Reaxys 55/267 Yield

NH Cl SnCl Cl Cl (v6)

Cl 2

N H

Sn Cl ClCl

H+

Rx-ID: 26424221 View in Reaxys 56/267 Yield

2 N

Cl Cl SnCl Cl Cl (v6) Cl

H Cl

Sn ClCl

2 H+

Rx-ID: 26424929 View in Reaxys 57/267 Yield

Conditions & References in neat (no solvent), Kinetics, byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements

19/80

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Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 141; (1989); p. 93 - 112 ; (from Gmelin) View in Reaxys -2 2

N+

Cl Cl SnCl Cl Cl (v6)

Sn ClCl

Rx-ID: 26426151 View in Reaxys 58/267 Yield

H N

2NH Cl ClSnCl Cl

H Cl

2 H+

Sn ClCl

Rx-ID: 26426271 View in Reaxys 59/267 Yield

NH 2 2

Cl Cl SnClCl Cl (v6)

H Cl

Sn ClCl

H 2N

2 H+

Rx-ID: 26616908 View in Reaxys 60/267 Yield

Conditions & References in solid, Kinetics, heating up to 773 K under N2; DTG-DTA-TG anal. Janiak, Tadeusz; Blazejowski, Jerzy; Thermochimica Acta; vol. 156; (1989); p. 27 - 44 ; (from Gmelin) View in Reaxys

O2Sn

Sn ClCl

Rx-ID: 26162907 View in Reaxys 61/267 Yield

Conditions & References in gas, chemical transport reaction proceeded in tranparent fused silica ampoules (1070-1110°C, 1-1.5 atm, 250h) Toshev, A.; Peshev, P.; Materials Research Bulletin; vol. 23; (1988); p. 1045 - 1052 ; (from Gmelin) View in Reaxys Cl

O2Sn

Sn ClCl

Rx-ID: 26182512 View in Reaxys 62/267 Yield

Conditions & References in gas, chemical transport reaction proceeded in tranparent fused silica ampoules (1010-1070°C, 1 atm, 310-400h) Toshev, A.; Peshev, P.; Materials Research Bulletin; vol. 23; (1988); p. 1045 - 1052 ; (from Gmelin) View in Reaxys

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Cl Cl 2Sn

Sn ClCl

Rx-ID: 26185643 View in Reaxys 63/267 Yield

Conditions & References With sulfur dioxide in hydrogenchloride, formation by oxidation of SnCl2 in a HCl contg. soln. with SO2; Durrant, R. G.; Journal of the Chemical Society; vol. 107; (1915); p. 622 - 638 View in Reaxys Wardlaw, W.; J. Soc. Chem. Ind. (London); vol. 45; (1926); p. 210 T - 214 T View in Reaxys vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys With chlorine in neat (no solvent), slowly reaction in coldness; Brewer, F. M.; Journal of Physical Chemistry; vol. 31; (1927); p. 1817 - 1823 ; (from Gmelin) View in Reaxys With chlorine in neat (no solvent) Ladenburg, A.; Liebigs Ann. Chem. Suppl.; vol. 8; (1872); p. 55 - 80 ; (from Gmelin) View in Reaxys With sulfuric acid in water, formation by heating a concd. aq. SnCl2 soln. with concd. H2SO4; Davy, J.; Philosophical Transactions of the Royal Society of London; (1812); p. 169 - 204 View in Reaxys vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys With hydrogenchloride, ozone in water, byproducts: H2O; oxidation with O3 of SnCl2 under formation of SnCl4 and H2O; Briner, E.; Bever, B.; Helvetica Chimica Acta; vol. 19; (1936); p. 369 - 369 View in Reaxys vol. Sn: MVol.C1; 6.6.8.4, page 234 - 234 ; (from Gmelin) View in Reaxys With hydrogenchloride, ammonium pertechnetate-(99)Tc in hydrogenchloride, ethanol, Kinetics, byproducts: (CH3)2NC6H3NHSC6H3NH(CH3)2(1+); reduction of ethanolic soln. of methylene blue by SnCl2 catalyzed by (99)Tc; monitored by UV-spectroscopy Amat, E.; March, J. G.; Grases, F.; Journal of Molecular Catalysis; vol. 35; (1986); p. 1 - 8 ; (from Gmelin) View in Reaxys With mercury dichloride in pyridine, byproducts: Hg; reaction with HgCl2 in pyridine under formation of Hg and SnCl4; Naumann, A.; Ber. Dtsch. Chem. Ges.; vol. 37; (1904); p. 4609 - 4614 ; (from Gmelin) View in Reaxys

>99

With hydrogenchloride, KIO3 in hydrogenchloride, byproducts: H2O, KCl, ICl; 15°C, fast Azim, S. M. A.; Rehman, A.; Journal of the Indian Chemical Society; vol. 32; (1955); p. 708 - 710 View in Reaxys Singh, B.; Ilahi, I.; Journal of the Indian Chemical Society; vol. 13; (1936); p. 717 - 722 ; (from Gmelin) View in Reaxys With Nitrous oxide in hydrogenchloride, byproducts: NH2OH; reduction of N2O in HCl-containing soln. under formation of SnCl4 and NH2OH; Nichols, M. L.; Derbigny, I. A.; Journal of Physical Chemistry; vol. 30; (1926); p. 491 - 506 ; (from Gmelin) View in Reaxys With hydrogenchloride, oxygen, copper dichloride, byproducts: H2O

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Haring, R. C.; Walton, J. H.; Journal of Physical Chemistry; vol. 37; (1933); p. 133 - 145 View in Reaxys Haring, R. C.; Walton, J. H.; Journal of Physical Chemistry; vol. 37; (1933); p. 375 - 380 View in Reaxys vol. Sn: MVol.B; 16.1.5.4, page 398 - 400 ; (from Gmelin) View in Reaxys With ozone in hydrogenchloride, formation by oxidation of SnCl2 in a HCl contg. soln. with O3; Yamauchi, Y.; American Chemical Journal; vol. 49; (1913); p. 55 - 68 View in Reaxys vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys With oxygen difluoride in hydrogenchloride, byproducts: HF, H2O Ishikawa, F.; Takai, T.; Sci. Rep. Tohoku Imp. Univ., Ser. 1; vol. 24; (1935); p. 98 - 106 View in Reaxys vol. F: SVol.1; 64, page 231 - 233 ; (from Gmelin) View in Reaxys With sulfur in water, byproducts: H2S; boiling with S in acid soln. forms SnCl4 and H2S; Hoenig, Alfred; Zeitschrift fuer Analytische Chemie; vol. 54; nb. 9; (1915); p. 441 - 457 View in Reaxys Vortmann, G.; Padberg, C.; Ber. Dtsch. Chem. Ges.; vol. 22; (1889); p. 2642 - 2644 View in Reaxys vol. Sn: MVol.C1; 6.6.8.5, page 234 - 235 ; (from Gmelin) View in Reaxys With sulfur in water, formation by heating an aq. SnCl2 soln. with S; Vortmann, G.; Padberg, C.; Ber. Dtsch. Chem. Ges.; vol. 22; (1889); p. 2642 - 2644 View in Reaxys vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys With sulfur in neat (no solvent), formation by heating solid SnCl2 with S; Davy, J.; Philosophical Transactions of the Royal Society of London; (1812); p. 169 - 204 View in Reaxys vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys With selenium in neat (no solvent), formation by heating solid SnCl2 with Se; vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys With air, carbon in hydrogenchloride, formation by oxidation of SnCl2 in HCl contg. soln. with air in presence of charcoal at 80-90°C; vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 View in Reaxys Patent; Sapadinski, M. B.; SU13078; (1930); C. I; (1931); p. 3497 ; (from Gmelin) View in Reaxys With chloride of lime in neat (no solvent), oxydation of SnCl2 with chloride of lime to SnCl4; Goepner, C.; Dinglers Polytech. J.; vol. 209; (1873); p. 204 - 224 ; (from Gmelin) View in Reaxys in hydrogenchloride, Kinetics, byproducts: H2; Irradiation (UV/VIS); flash photolysis; fused quartz tube, addn. of SnCl2 to a deaereted soln. of hydrochlorid acid; detn. by absorption spectroscopy Shinohara, Nobuyoshi; Mori, Katsuhiko; Inoue, Makoto; Chemistry Letters; (1986); p. 661 - 664 ; (from Gmelin)

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View in Reaxys With chloride of lime in neat (no solvent), oxydation of SnCl2 with chloride of lime to SnCl4; vol. Ca: MVol.B2; 133, page 571 - 573 ; (from Gmelin) View in Reaxys With HgCl2 in pyridine, byproducts: Hg; reaction with HgCl2 in pyridine under formation of Hg and SnCl4; vol. Sn: MVol.C1; 6.7.2.9, page 243 - 244 ; (from Gmelin) View in Reaxys With N2O in hydrogenchloride, byproducts: NH2OH; reduction of N2O in HCl-containing soln. under formation of SnCl4 and NH2OH; vol. Sn: MVol.C1; 6.6.8.7, page 235 - 236 ; (from Gmelin) View in Reaxys With Se in neat (no solvent), formation by heating solid SnCl2 with Se; Schneider, R.; Ann. Physik Chem. (2); vol. 127; (1866); p. 624 - 638 ; (from Gmelin) View in Reaxys in neat (no solvent, gas phase), byproducts: Cl2; Electrolysis; fusion electrolysis forms Cl2 at the anode which reacts with molten SnCl2 to SnCl4; vol. Sn: MVol.C1; 6.3.8, page 215 - 216 ; (from Gmelin) View in Reaxys >99

With CuCl2 in acetone, excess of CuCl2 soln.; Naumann, A.; Ber.; vol. 32; (1899); p. 999 - 1004 View in Reaxys vol. Cu: MVol.B1; 132, page 289 - 291 ; (from Gmelin) View in Reaxys in neat (no solvent, gas phase), byproducts: Cl2; Electrolysis; fusion electrolysis forms Cl2 at the anode which reacts with molten SnCl2 to SnCl4; Helfenstein, A.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 23; (1900); p. 255 - 316 ; (from Gmelin) View in Reaxys With KIO3, HCl in hydrogenchloride vol. Sn: MVol.B; 16.1.5.9, page 401 - 402 ; (from Gmelin) View in Reaxys With Cl2 vol. Sn: MVol.C1; 6.3.9.4, page 217 - 218 View in Reaxys vol. Cl: SVol.A; 155, page 365 - 368 ; (from Gmelin) View in Reaxys Cl

Cl 2Sn

Cl 2Pd

Sn ClCl

Rx-ID: 26185670 View in Reaxys 64/267 Yield

Conditions & References in neat (no solvent), molar ratio=1:1, evacuated ampoule, 120°C Mireev, V. A.; Safonov, V. V.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 31; (1986); p. 1559 - 1561; Zhurnal Neorganicheskoi Khimii; vol. 31; (1986); p. 2702 - 2704 ; (from Gmelin) View in Reaxys

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(v4) (v5) (v1) H (v5) (v5) (v1) (v5)CHCl – – (v4) (v5) – (v5) C Cl – (v4) (v1) 4+ (v5) 0.5(v11) Fe 2+ Sn 2+ –Cl Sn Cl 4+– Fe (v1) (v11) Cl – (v1) Cl – (v4) ––HC (v4) CH(v1) – Cl (v5) (v5) (v5) (v1) (v5) (v5) (v5) (v5)(v5) (v5) (v5)

(v5) (v5) (v5)

(v5)

(v10)

(v5) (v5)(v5)

Sn Cl ClCl

(v5)

H O

Rx-ID: 26272118 View in Reaxys 65/267 Yield

Conditions & References in N,N-dimethyl-formamide, dissolving in N,N-dimethylformamide Watanabe, Masanobu; Motoyama, Izumi; Sano, Hirotoshi; Bulletin of the Chemical Society of Japan; vol. 59; nb. 7; (1986); p. 2109 - 2114 ; (from Gmelin) View in Reaxys Cl

Sn Cl

(v2)

Hg Cl

Cl 2Hg

Sn ClCl

Rx-ID: 26465551 View in Reaxys 66/267 Yield

Conditions & References With sodium chloride in further solvent(s), (CH3)SnCl3 was added to a soln. of HgCl2 in aq. NaCl (artificial seawater), the flask was sealed from light, shaken for 30 d at room temp.; monitored by 199Hg NMR Howell, Gregory N.; O'Connor, Maxwell J.; Bond, Alan M.; Hudson, Henry A.; Hanna, Peter J.; Strother, Stan; Australian Journal of Chemistry; vol. 39; (1986); p. 1167 - 1176 ; (from Gmelin) View in Reaxys

(v5) (v5)

0.5 (v11) (v5)

(v4) (v5) (v5) (v1)– (v4) H (v5) (v1) (v5)CHCl – (v5) – C Cl – (v4) (v5) 4+ (v1) (v5) Sn 2+ – 4+– Ru 2+ – Ru (v1) Cl SnCl (v11) Cl – (v1) Cl –– (v4) (v4) CH(v1) HC – Cl (v5) (v5) (v5)(v5) (v5) (v5) (v1) (v5)

(v5) (v5) (v5)

(v5)

CH –

(v5)

Ru 2+

Sn Cl ClCl

(v10)

(v5)CH –

(v5)

Cl (v4)

(v5)

(v4)

Rx-ID: 26980124 View in Reaxys 67/267 Yield

Conditions & References in acetonitrile, dissolving Ru-Sn-compound in acetonitrile and standing in air for a fewminutes; Watanabe, Masanobu; Motoyama, Izumi; Sano, Hirotoshi; Bulletin of the Chemical Society of Japan; vol. 59; nb. 7; (1986); p. 2109 - 2114 ; (from Gmelin) View in Reaxys

Cl B

Sn ClCl

Rx-ID: 26149032 View in Reaxys 68/267 Yield

Conditions & References in dichloromethane, sealed tube, room temp.; Sn:B molar ratio >1:1 Dillon, Keith B.; Hewitson, Geoffrey F.; Polyhedron; vol. 3; (1984); p. 957 - 962 ; (from Gmelin) View in Reaxys

Cl Cl SbCl Cl Cl

Cl Sn

Cl Sb

Sn ClCl

Rx-ID: 26167080 View in Reaxys 69/267

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Yield

Conditions & References in neat (no solvent), SbCl5 was added dropwise; N2 atm., NMR tube Dillon, Keith B.; Hewitson, Geoffrey F.; Polyhedron; vol. 3; (1984); p. 957 - 962 ; (from Gmelin) View in Reaxys

Cl Cl SbCl Cl

Sn Cl ClCl

Rx-ID: 26167084 View in Reaxys 70/267 Yield

Cl Sn

Cl B

Sn Cl ClCl

Rx-ID: 26451611 View in Reaxys 71/267 Yield

Cl Sn

Cl SbCl Cl

Sn ClCl

Rx-ID: 26483873 View in Reaxys 72/267 Yield

Conditions & References in dichloromethane, a soln. of SbCl5 was added to a soln. of PhSnCl3; N2 atm., NMR tube; evapn. in vac. Dillon, Keith B.; Hewitson, Geoffrey F.; Polyhedron; vol. 3; (1984); p. 957 - 962 ; (from Gmelin) View in Reaxys

Cl Cl

Cl Sn

Cl SbCl Cl

Cl Cl

Sn ClCl

Rx-ID: 26483874 View in Reaxys 73/267 Yield

Cl SbCl Cl Cl

Sn ClCl

Rx-ID: 26483884 View in Reaxys 74/267 Yield

Conditions & References in neat (no solvent), SbCl5 was added dropwise; N2 atm., NMR tube Dillon, Keith B.; Hewitson, Geoffrey F.; Polyhedron; vol. 3; (1984); p. 957 - 962 ; (from Gmelin)

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View in Reaxys Cl

Sn Cl

Sn ClCl

Rx-ID: 26153877 View in Reaxys 75/267 Yield

Conditions & References in tetrachloromethane, Kinetics, Irradiation (UV/VIS) Blunden, Stephen J.; Journal of Organometallic Chemistry; vol. 248; nb. 2; (1983); p. 149 - 160 ; (from Gmelin) View in Reaxys Cl

Sn ClCl

Rx-ID: 26139666 View in Reaxys 76/267 Yield

Conditions & References in neat (no solvent), formation by passing Cl2 into molten Sn; vol. Sn: MVol.C1; 6.9.1.1, page 252 - 253 View in Reaxys Patent; Alexander, W. P.; Burgess, L.; US1999179; (1935); C. I; (1936); p. 2410 View in Reaxys Patent; Smith, W. S.; US1777132; (1930); C. II; (1930); p. 3325 ; (from Gmelin) View in Reaxys With Cl2 in neat (no solvent), dry Cl2 Chandra, K.; Garg, A. K.; Jain, M. C.; Journal of the Indian Chemical Society; vol. 57; (1980); p. 378 - 381 ; (from Gmelin) View in Reaxys

Cl S

O2Sn

Sn ClCl

Rx-ID: 26107886 View in Reaxys 77/267 Yield

Conditions & References Kinetics, chlorination at const. temp. in range 650-850°C (gas flow 5-6 l/h); gravimetric monitoring Derlyukova, L. E.; Evdokimov, V. I.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 23; (1978); p. 962 - 964; Zhurnal Neorganicheskoi Khimii; vol. 23; (1978); p. 1750 - 1753 ; (from Gmelin) View in Reaxys

Cl Al

O2Sn

ClNa Cl

Sn ClCl

Rx-ID: 26099800 View in Reaxys 78/267 Yield

Conditions & References in neat (no solvent), chlorination with an eutectic AlCl3-NaCl-mixture (63 mol-percent AlCl3) to SnCl4; Sherer, C. S.; Journal of Inorganic and Nuclear Chemistry; vol. 34; (1972); p. 1615 - 1619 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

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Cl B

Sn Cl ClCl

Rx-ID: 26438977 View in Reaxys 79/267 Yield

Conditions & References in neat (no solvent), boiling under reflux, molar ratio of Sn(C6H4-p-CH3):BCl3 = 1:4 Hooz, J.; Calzada, J. G.; Org. Prep. Proced. Intern.; vol. 4; (1972); p. 219 - 223 ; (from Gmelin) View in Reaxys in neat (no solvent), boiling under reflux, molar ratio of Sn(C6H4-p-CH3):BCl3 = 1:4 vol. Sn: Org.Verb.1; 1.1.1.16.4, page 165 - 168 ; (from Gmelin) View in Reaxys Cl Cl

Cl B

Sn ClCl

Rx-ID: 26441926 View in Reaxys 80/267 Yield

Conditions & References in neat (no solvent), 4 fold excess of BCl3, -78-0°C Hooz, J.; Calzada, J. G.; Org. Prep. Proced. Intern.; vol. 4; (1972); p. 219 - 223 ; (from Gmelin) View in Reaxys in neat (no solvent), 4 fold excess of BCl3, -78-0°C vol. Sn: Org.Verb.1; 1.1.1.16.6, page 169 - 176 ; (from Gmelin) View in Reaxys

Cl B

Sn ClCl

Rx-ID: 26448544 View in Reaxys 81/267 Yield

Conditions & References in neat (no solvent), boiling under reflux, 4 h Hooz, J.; Calzada, J. G.; Org. Prep. Proced. Intern.; vol. 4; (1972); p. 219 - 223 ; (from Gmelin) View in Reaxys in neat (no solvent), boiling under reflux, 4 h vol. Sn: Org.Verb.1; 1.1.1.16.6, page 169 - 176 ; (from Gmelin) View in Reaxys

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O2Sn

Sn ClCl

Rx-ID: 26171968 View in Reaxys 82/267 Yield

Conditions & References With hydrogen in neat (no solvent), reaction with HCl in presence of H2; examination of the reaction in presence of catalysts at 500-630°C; Lythe, R. G.; Prosser, A. P.; Inst. Mining Met. Trans. C; vol. 78; (1969); p. 206 - 213 View in Reaxys vol. Sn: MVol.C1; 3.7.8.4.2, page 101 - 101 ; (from Gmelin) View in Reaxys With carbon monoxide in neat (no solvent), reaction with HCl-CO-mixtures forms SnCl4 at 700°C; Lythe, R. G.; Prosser, A. P.; Inst. Mining Met. Trans. C; vol. 79; (1970); p. 109 - 111 View in Reaxys vol. Sn: MVol.C1; 3.7.8.4.2, page 101 - 101 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: H2O; reaction with HCl (gas-stream) at 400°C under formation of SnCl4 and H2O; examination of reaction; Ivashentsev, Ya. I.; Ivantsova, V. I.; Zhurnal Fizicheskoi Khimii; vol. 43; (1969); p. 505 - 508; Zhurnal Fizicheskoi Khimii; vol. 43; (1969); p. 917 - 921 View in Reaxys vol. Sn: MVol.C1; 3.7.8.4.2, page 101 - 101 ; (from Gmelin) View in Reaxys Cl

O2Sn

Sn Cl ClCl

Cl 2Sn

Rx-ID: 26171969 View in Reaxys 83/267 Yield

Conditions & References With carbon monoxide, bismuth in neat (no solvent), catalysis of reduction to SnO or Sn with Bi; formation of SnCl4 and SnCl2; Lythe, R. G.; Prosser, A. P.; Inst. Mining Met. Trans. C; vol. 79; (1970); p. 109 - 111 View in Reaxys vol. Sn: MVol.C1; 3.7.8.4.2, page 101 - 101 ; (from Gmelin) View in Reaxys With carbon monoxide, iron(III) oxide in neat (no solvent), catalysis of reduction to SnO or Sn with Fe2O3; formation of SnCl4 and SnCl2; Lythe, R. G.; Prosser, A. P.; Inst. Mining Met. Trans. C; vol. 79; (1970); p. 109 - 111 View in Reaxys vol. Sn: MVol.C1; 3.7.8.4.2, page 101 - 101 ; (from Gmelin) View in Reaxys With carbon monoxide, bismuth(III)oxide in neat (no solvent), catalysis of reduction to SnO or Sn with Bi2O3; formation of SnCl4 and SnCl2; Lythe, R. G.; Prosser, A. P.; Inst. Mining Met. Trans. C; vol. 79; (1970); p. 109 - 111 View in Reaxys vol. Sn: MVol.C1; 3.7.8.4.2, page 101 - 101 ; (from Gmelin) View in Reaxys With carbon monoxide, iron in neat (no solvent), catalysis of reduction to SnO or Sn with Fe; formation of SnCl4 and SnCl2; Lythe, R. G.; Prosser, A. P.; Inst. Mining Met. Trans. C; vol. 79; (1970); p. 109 - 111 View in Reaxys vol. Sn: MVol.C1; 3.7.8.4.2, page 101 - 101 ; (from Gmelin) View in Reaxys

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With carbon monoxide, platinum in neat (no solvent), catalysis of reduction to SnO or Sn with Pt; formation of SnCl4 and SnCl2; Lythe, R. G.; Prosser, A. P.; Inst. Mining Met. Trans. C; vol. 79; (1970); p. 109 - 111 View in Reaxys vol. Sn: MVol.C1; 3.7.8.4.2, page 101 - 101 ; (from Gmelin) View in Reaxys Cl 2S3Sn2

S2Sn

white

Sn ClCl

Rx-ID: 26636808 View in Reaxys 84/267 Yield

Conditions & References

>99, >99

in neat (no solvent), decompn. at 120 °C; Stapfer; Dworkin; Inorganic Chemistry; vol. 9; (1970); p. 421 ; (from Gmelin) View in Reaxys

>99, >99

in neat (no solvent), decompn. at 120 °C; vol. Sn: MVol.C2; 9.27.1, page 75 - 75 ; (from Gmelin) View in Reaxys

Cl Cl

Cl 2Sn

Te ClCl

Cl Te

Sn ClCl

Rx-ID: 26168028 View in Reaxys 85/267 Yield

Conditions & References in neat (no solvent), equilibrium; vol. Sn: MVol.C2; 11.5.2, page 210 - 210 ; (from Gmelin) View in Reaxys in neat (no solvent), equilibrium; Safonov, V. V.; Konov, A. V.; Korshunov, B. G.; Izv. Vysshikh Uchebn. Zavedenii Tsvent. Met.; vol. 12; nb. 5; (1969); p. 83 - 85; C. A.; vol. 72; (1970); p. 48221 ; (from Gmelin) View in Reaxys

OSn

Sn Cl ClCl

Rx-ID: 26182432 View in Reaxys 86/267 Yield

Conditions & References in neat (no solvent), formation by passing a Cl2-stream (10 Torr) through Sn at 100°C; FONSTAD CG; LINZ A; REDIKER RH; Journal of the Electrochemical Society; vol. 116; nb. 9; (1969); p. 1269 1271 View in Reaxys vol. Sn: MVol.C1; 3.7.1.5.3.1, page 63 - 64 ; (from Gmelin) View in Reaxys

Cl O

Cl O2Sn

Sn ClCl

Rx-ID: 26445160 View in Reaxys 87/267 Yield

Conditions & References heating Kretov, A. E.; Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation); vol. 2; (1929); p. 483 - 501; C.A.; (1930); p. 313 View in Reaxys

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Kuznetsov, Yu. P.; Petrov, E. S.; Vakhrusheva, A. I.; Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk; (1969); p. 317 - 320; Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk; nb. 3; (1969); p. 60 - 65 View in Reaxys vol. C: MVol.D3; 2.2.8.7.1, page 97 - 97 ; (from Gmelin) View in Reaxys Cl

Cl Sn

Sn ClCl

Rx-ID: 26433729 View in Reaxys 88/267 Yield

Conditions & References longer heating at 430°C Kuznetsov, Yu. P.; Petrov, E. S.; Vakhrusheva, A. I.; Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk; (1968); p. 501 - 503; Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk; nb. 5; (1968); p. 30 - 33 View in Reaxys vol. C: MVol.D3; 2.2.8.5.5, page 93 - 93 ; (from Gmelin) View in Reaxys

Cl Cl 2Sn

Sn ClCl

Rx-ID: 26445157 View in Reaxys 89/267 Yield

Conditions & References from 535 K Kuznetsov, Yu. P.; Petrov, E. S.; Vakhrusheva, A. I.; Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk; (1968); p. 464 - 466; Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk; nb. 4; (1968); p. 137 - 140 View in Reaxys vol. C: MVol.D3; 2.2.8.7.3, page 98 - 100 ; (from Gmelin) View in Reaxys O

2 Cl

P ClCl

Sn ClCl

Cl P

Sn ClCl

Rx-ID: 26456516 View in Reaxys 90/267 Yield

Conditions & References in benzene Smitskamp, C. C.; Olie, K.; Gerding, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 359; (1968); p. 318 - 325 View in Reaxys vol. Sn: MVol.C2; 16.18.2, page 262 - 264 ; (from Gmelin) View in Reaxys in tetrachloromethane Smitskamp, C. C.; Olie, K.; Gerding, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 359; (1968); p. 318 - 325 View in Reaxys vol. Sn: MVol.C2; 16.18.2, page 262 - 264 ; (from Gmelin) View in Reaxys H

2 Cl 2Cl SnCl Cl Cl Cl

N+ HH

N H

Cl Cl

Sn ClCl

Rx-ID: 26468438 View in Reaxys 91/267

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Yield

Conditions & References decompn. in satd. vapor state Suvorov, A. V.; Shutaev, V. L.; Probl. Sovrem. Khim. Koord. Soedin.; nb. 2; (1968); p. 76 - 90; C.A.; vol. 70; (1969); p. 6961 View in Reaxys vol. Sn: MVol.C3; 23.5.1.1.3, page 99 - 100 ; (from Gmelin) View in Reaxys Cl

Cl 4Cs 2OSn

Sn Cl ClCl

Rx-ID: 26616885 View in Reaxys 92/267 Yield

Conditions & References heating vol. Sn: MVol.C3; 25.9, page 150 - 150 ; (from Gmelin) View in Reaxys heating Morozov, A. I.; Morozov, I. S.; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 519 - 521; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 992 - 997 ; (from Gmelin) View in Reaxys Cl

ClK

Cl 4K2OSn

O2Sn

Sn ClCl

Rx-ID: 26616886 View in Reaxys 93/267 Yield

Conditions & References heating Morozov, A. I.; Morozov, I. S.; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 519 - 521; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 992 - 997 View in Reaxys vol. Sn: MVol.C3; 22.17, page 62 - 63 ; (from Gmelin) View in Reaxys 1

H Cl –

Cl 4H 8N 2OSn

(v4)

N HH

Sn ClCl

O2Sn

Rx-ID: 26618313 View in Reaxys 94/267 Yield

Conditions & References Morozov, A. I.; Morozov, I. S.; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 519 - 521; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 992 - 997 View in Reaxys vol. Sn: MVol.C3; 23.5.10, page 110 - 110 ; (from Gmelin) View in Reaxys

2 Rb +

ClSn2Cl ClCl

Cl Cl

Sn ClCl

Rx-ID: 26618541 View in Reaxys 95/267 Yield

Conditions & References decompn. at 637-663°C Morozov, A. I.; Morozov, I. S.; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 519 - 521; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 992 - 997 View in Reaxys vol. Sn: MVol.C3; 24.8, page 135 - 135 ; (from Gmelin) View in Reaxys

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ClNa

Cl 2Sn

Sn ClCl

Rx-ID: 26100040 View in Reaxys 96/267 Yield

Conditions & References in melt Karpenko, N. V.; Zhurnal Neorganicheskoi Khimii; vol. 12; (1967); p. 1556 - 1559; Zhurnal Neorganicheskoi Khimii; vol. 12; (1967); p. 2940 - 2945 ; (from Gmelin) View in Reaxys in melt vol. Sn: MVol.C3; 21.12, page 23 - 23 ; (from Gmelin) View in Reaxys

Cl Cl Cl

(v6)

W Cl Cl Cl

Sn ClCl

Rx-ID: 26170142 View in Reaxys 97/267 Yield

Conditions & References in neat (no solvent), byproducts: WCl5; formation by reaction of SCl6 with SnCl2 at 140-150°C in N2 stream; Korshunov, B. G.; Beznevskaya, V. N.; Zhurnal Neorganicheskoi Khimii; vol. 12; (1967); p. 1736 - 1737; Zhurnal Neorganicheskoi Khimii; vol. 12; (1967); p. 3280 - 3282 View in Reaxys vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys

Cl Cl Cl

(v6)

W Cl

Cl Cl 2Sn

Cl Cl

Sn Cl ClCl

Rx-ID: 26170171 View in Reaxys 98/267 Yield

Conditions & References in neat (no solvent), byproducts: WCl5; reaction with WCl6 at .>.140°C under formation of WCl5 and SnCl4; Korshunov, B. G.; Bezuevskaya, V. N.; Zhurnal Neorganicheskoi Khimii; vol. 12; (1967); p. 1736 - 1737; Zhurnal Neorganicheskoi Khimii; vol. 12; (1967); p. 3280 - 3282 View in Reaxys vol. Sn: MVol.C1; 6.3.9.7, page 219 - 221 ; (from Gmelin) View in Reaxys

Cl (v5)

Cl NbCl Cl Cl

Cl Cl 2Sn

Sn ClCl

Rx-ID: 26167616 View in Reaxys 99/267 Yield

Conditions & References in neat (no solvent), reaction with NbCl5 at 200-220°C in an inclose tube under formation of lower chlorides and SnCl4; Morozov, I. S.; Ch'ih-Fa Li; Zhurnal Neorganicheskoi Khimii; vol. 8; (1963); p. 1432 - 1434; Zhurnal Neorganicheskoi Khimii; vol. 8; (1963); p. 2733 - 2736 View in Reaxys vol. Sn: MVol.C1; 6.3.9.7, page 219 - 221 ; (from Gmelin) View in Reaxys in neat (no solvent), reaction with NbCl5 at 200-220°C in an inclose tube under formation of lower chlorides and SnCl4; Morozov, I. S.; Lipatova, N. P.; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 550 - 553; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 1018 - 1024 ; (from Gmelin) View in Reaxys

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Cl 2Sn

Sn ClCl

Rx-ID: 26182492 View in Reaxys 100/267 Yield

Conditions & References in neat (no solvent), formation by reaction of solid SnCl2 with Cl2 gas; vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys Savelsberg, W.; Chem. - Metall. Z.; vol. 22; (1932); p. 833 - 834 View in Reaxys Savelsberg, W.; Chem. - Metall. Z.; vol. 22; (1932); p. 865 View in Reaxys Savelsberg, W.; Chem. - Metall. Z.; vol. 22; (1932); p. 897 - 898 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by passing Cl2 under cooling in a suspension of SnCl2 in SnCl4; vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 View in Reaxys Patent; anonymous; Soc. des Produits Chimiques de Clamency S. A.; FR866886; (1941); C. I; (1942); p. 2811 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by reaction of pure solid SnCl2 with Cl2 gas;; very pure; Klofach, J.; Chem. Prumysl; vol. 17; (1966); p. 683 - 684 View in Reaxys vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys vol. Sn: MVol.B; 3, page 1 - 41 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by reaction of solid SnCl2 with Cl2 gas; Ladenburg, A.; Liebigs Ann. Chem. Suppl. Bd.; vol. 8; (1872); p. 55 - 80 ; (from Gmelin) View in Reaxys

Cl B

Sn Cl

Sn ClCl

Rx-ID: 26437931 View in Reaxys 101/267 Yield

Conditions & References in Petroleum ether, byproducts: CH2C(CH3)BCl2; under N2 Braun,J.; Normant,H.; Bulletin de la Societe Chimique de France; (1966); p. 2557 - 2564 ; (from Gmelin) View in Reaxys in petroleum ether, byproducts: CH2C(CH3)BCl2; under N2 vol. Sn: Org.Verb.1; 1.1.1.14.3, page 136 - 139 ; (from Gmelin) View in Reaxys

Cl B

Sn ClCl

Rx-ID: 26437939 View in Reaxys 102/267 Yield

Conditions & References in Petroleum ether, byproducts: CH3CHCHBCl2, (CH3CHCH)3SnCl; under N2

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Braun,J.; Normant,H.; Bulletin de la Societe Chimique de France; (1966); p. 2557 - 2564 View in Reaxys Braun, J.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 256; (1963); p. 2422 2425 ; (from Gmelin) View in Reaxys in petroleum ether, byproducts: CH3CHCHBCl2, (CH3CHCH)3SnCl; under N2 vol. Sn: Org.Verb.1; 1.1.1.14.3, page 136 - 139 ; (from Gmelin) View in Reaxys

Cl Sn

Cl B

B Cl

Cl Sn Cl

Cl Sn

Sn ClCl

Rx-ID: 26451752 View in Reaxys 103/267 Yield

Conditions & References in benzene, boiling Burch, J. E.; Gerrard, W.; Howarth, M.; Mooney, E. F.; Journal of the Chemical Society; (1960); p. 4916 - 4918 View in Reaxys vol. Sn: Org.Verb.1; 1.1.1.16.1.4.4, page 157 - 159 ; (from Gmelin) View in Reaxys in tetrachloromethane, boiling Burch, J. E.; Gerrard, W.; Howarth, M.; Mooney, E. F.; Journal of the Chemical Society; (1960); p. 4916 - 4918 View in Reaxys vol. Sn: Org.Verb.1; 1.1.1.16.1.4.4, page 157 - 159 ; (from Gmelin) View in Reaxys in neat (no solvent), boiling Burch, J. E.; Gerrard, W.; Howarth, M.; Mooney, E. F.; Journal of the Chemical Society; (1960); p. 4916 - 4918 View in Reaxys vol. Sn: Org.Verb.1; 1.1.1.16.1.4.4, page 157 - 159 ; (from Gmelin) View in Reaxys in dichloromethane, boiling Burch, J. E.; Gerrard, W.; Howarth, M.; Mooney, E. F.; Journal of the Chemical Society; (1960); p. 4916 - 4918 View in Reaxys vol. Sn: Org.Verb.1; 1.1.1.16.1.4.4, page 157 - 159 ; (from Gmelin) View in Reaxys in neat (no solvent), boiling Noeth, H.; Lukas, S.; Schweizer, P.; Chemische Berichte; vol. 98; (1965); p. 962 - 968 ; (from Gmelin) View in Reaxys in tetrachloromethane, boiling Noeth, H.; Lukas, S.; Schweizer, P.; Chemische Berichte; vol. 98; (1965); p. 962 - 968 ; (from Gmelin) View in Reaxys in benzene, boiling Noeth, H.; Lukas, S.; Schweizer, P.; Chemische Berichte; vol. 98; (1965); p. 962 - 968 ; (from Gmelin) View in Reaxys in dichloromethane, boiling Noeth, H.; Lukas, S.; Schweizer, P.; Chemische Berichte; vol. 98; (1965); p. 962 - 968 ; (from Gmelin)

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View in Reaxys in neat (no solvent), boiling Niedenzu,K.; Dawson,J.W.; Journal of the American Chemical Society; vol. 82; (1960); p. 4223 - 4228 ; (from Gmelin) View in Reaxys in dichloromethane, boiling Niedenzu,K.; Dawson,J.W.; Journal of the American Chemical Society; vol. 82; (1960); p. 4223 - 4228 ; (from Gmelin) View in Reaxys in benzene, boiling Niedenzu,K.; Dawson,J.W.; Journal of the American Chemical Society; vol. 82; (1960); p. 4223 - 4228 ; (from Gmelin) View in Reaxys in tetrachloromethane, boiling Niedenzu,K.; Dawson,J.W.; Journal of the American Chemical Society; vol. 82; (1960); p. 4223 - 4228 ; (from Gmelin) View in Reaxys in neat (no solvent), boiling Niedenzu, K.; Beyer, H.; Dawson, J. W.; Inorganic Chemistry; vol. 1; (1962); p. 738 - 742 ; (from Gmelin) View in Reaxys in tetrachloromethane, boiling Niedenzu, K.; Beyer, H.; Dawson, J. W.; Inorganic Chemistry; vol. 1; (1962); p. 738 - 742 ; (from Gmelin) View in Reaxys in dichloromethane, boiling Niedenzu, K.; Beyer, H.; Dawson, J. W.; Inorganic Chemistry; vol. 1; (1962); p. 738 - 742 ; (from Gmelin) View in Reaxys in benzene, boiling Niedenzu, K.; Beyer, H.; Dawson, J. W.; Inorganic Chemistry; vol. 1; (1962); p. 738 - 742 ; (from Gmelin) View in Reaxys F

Sn Cl ClCl

Sn Cl Cl F

Rx-ID: 26453297 View in Reaxys 104/267 Yield

Conditions & References in neat (no solvent), thermic decomposition at 153°C under normal pressure in SnF4 and SnCl4; Dehnicke, K.; Chemische Berichte; vol. 98; (1965); p. 280 - 289 ; (from Gmelin) View in Reaxys vol. Sn: MVol.C1; 6.35.1, page 368 - 368 ; (from Gmelin) View in Reaxys

F Cl

Sn Cl F

Cl P

Sn ClCl

Rx-ID: 26453298 View in Reaxys 105/267 Yield

Conditions & References in trichlorophosphate, byproducts: POCl2F; decomposition under formation of SnCl4 and POCl2F at storing in POCl3 for a longer period of time;

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Dehnicke, K.; Chemische Berichte; vol. 98; (1965); p. 280 - 289 ; (from Gmelin) View in Reaxys in trichlorophosphate vol. Sn: MVol.C1; 6.35.1, page 368 - 368 ; (from Gmelin) View in Reaxys Cl

Cl 2Eu

Eu Cl

Sn ClCl

(v3)

Rx-ID: 26139803 View in Reaxys 106/267 Yield

Conditions & References high temp. Polyachenok, O. G.; Novikov, G. I.; Zhurnal Neorganicheskoi Khimii; vol. 9; (1964); p. 429 - 431; Zhurnal Neorganicheskoi Khimii; vol. 9; (1964); p. 773 - 777 View in Reaxys vol. Sn: MVol.B; 14.5.4, page 361 - 363 ; (from Gmelin) View in Reaxys Cl

Cl Yb Cl

Cl 2Yb

(v3)

Sn ClCl

Rx-ID: 26139849 View in Reaxys 107/267 Yield

Cl 2Sn

Sn Cl ClCl

Rx-ID: 26151243 View in Reaxys 108/267 Yield

Conditions & References in not given, equilibrium; Fortunatov, N. S.; Fokina, Z. A.; Ukr. Khim. Zh.; vol. 30; (1964); p. 780 - 784; C. A.; vol. 61; (1964); p. 13932 View in Reaxys vol. Sn: MVol.C1; 6.3.9.7, page 219 - 221 ; (from Gmelin) View in Reaxys

ClCl Cl Sn Sn Cl ClCl

Cl Cl

Sn ClCl

Rx-ID: 26156389 View in Reaxys 109/267 Yield

Conditions & References in neat (no solvent), byproducts: SnCl2; formation by decomposition of Sn2Cl6*2HCl above -65°C under formation of SnCl4 and SnCl2; vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 View in Reaxys Wiberg, E.; Behringer, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 329; (1964); p. 290 - 300 ; (from Gmelin) View in Reaxys

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Cl 2 H

ClCl Cl Sn

Sn Cl ClCl

Cl 2Sn

Sn ClCl

Rx-ID: 26594698 View in Reaxys 110/267 Yield

Conditions & References in neat (no solvent), disproportion above -79°C in SnCl2 and SnCl4; Behringer, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 329; (1964); p. 290 - 300 View in Reaxys vol. Sn: MVol.C1; 6.19, page 357 - 357 ; (from Gmelin) View in Reaxys

(v3)

3 Cl –

(v3)

Cl Sn Sn Cl Cl Cl O O

–O

(v5) (v5)

O– Sn4+

– 2 O Cl

Sn ClCl

Sn4+

Rx-ID: 26636190 View in Reaxys 111/267 Yield

Conditions & References

With chlorine in tetrachloromethane Wiberg, E.; Behringer, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 329; (1964); p. 290 - 300 View in Reaxys vol. Sn: MVol.C2; 14.14, page 222 - 222 ; (from Gmelin) View in Reaxys -2

N+

Cl Cl SnCl Cl Cl (v6)

Cl Sn Cl ClCl

Rx-ID: 26158510 View in Reaxys 112/267 Yield

Conditions & References in neat (no solvent), formation by heating (C6H5N2)2SnCl6 at 78°C; Korewa, R.; Roczniki Chemii; vol. 37; (1963); p. 1565 - 1570 View in Reaxys vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 ; (from Gmelin) View in Reaxys 2 Cl 2Cl SnCl Cl Cl

K+

ClK Cl

Sn ClCl

Rx-ID: 26404767 View in Reaxys 113/267 Yield

Conditions & References 586-624°C Morozov, I. S.; Chi'ih-Fa, Li; Zhurnal Neorganicheskoi Khimii; vol. 8; (1963); p. 330 - 332; Zhurnal Neorganicheskoi Khimii; vol. 8; (1963); p. 651 - 654 View in Reaxys vol. Sn: MVol.C3; 22.15.1.3, page 61 - 62 ; (from Gmelin) View in Reaxys 2 Rb + Cl 2Cl SnCl Cl Cl

ClRb

Sn ClCl

Rx-ID: 26597469 View in Reaxys 114/267 Yield

Conditions & References byproducts: Cl2, Sn-oxide; decompn. at 407°C Duval, Therese; Duval, Clement; Analytica Chimica Acta; vol. 2; nb. C; (1948); p. 110 - 114 View in Reaxys

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vol. Sn: MVol.C3; 24.7.1.3, page 134 - 135 ; (from Gmelin) View in Reaxys decompn. vol. Sn: MVol.C3; 24.7.1.3, page 134 - 135 ; (from Gmelin) View in Reaxys decompn. Morozov, I. S.; Ch'ih-Fa, Li; Zhurnal Neorganicheskoi Khimii; vol. 8; (1963); p. 330 - 332; Zhurnal Neorganicheskoi Khimii; vol. 8; (1963); p. 651 - 654 ; (from Gmelin) View in Reaxys Cl O2Sn

Cl 2Fe

Cl 2Sn

Sn ClCl

Rx-ID: 26185837 View in Reaxys 115/267 Yield

Conditions & References With catalysts: metal oxides in neat (no solvent), byproducts: Fe3O4; chlorination with FeCl2 under formation of SnCl2 and SnCl4 in presence of metal oxides; reaction begins at 500°C, enough speed above 800°C; Evdokimov, A. I.; Morozov, I. S.; Chimie et Industrie (Paris); vol. 88; (1962); p. 115 - 119 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys Cl

Cl Cr

Sn( 2+)

(v3)

CrF 2

Sn( 4+)

Sn ClCl

Rx-ID: 26457199 View in Reaxys 116/267 Yield

Conditions & References in melt, 1100°C Sturm, B. J.; Inorganic Chemistry; vol. 1; (1962); p. 665 - 672 View in Reaxys vol. Sn: MVol.B; 16.1.5.10.7, page 404 - 409 ; (from Gmelin) View in Reaxys Cl

Cl Cr

F2Sn Cl

(v3)

CrF 2

Sn ClCl

Cl 2Sn

Rx-ID: 26457210 View in Reaxys 117/267 Yield

Conditions & References in melt, 1100°C Sturm, B. J.; Inorganic Chemistry; vol. 1; (1962); p. 665 - 672 View in Reaxys vol. Sn: MVol.B; 16.1.5.10.7, page 404 - 409 ; (from Gmelin) View in Reaxys Cl

AgCl

Sn Cl ClCl

Rx-ID: 26096458 View in Reaxys 118/267 Yield

Conditions & References in neat (no solvent), byproducts: SnCl2; formation by reaction of Sn with AgCl at ca. 350°C;; SnCl2 formed; not isolated; Lieser, K. H.; Elias, H.; Kohlschuetter, H. W.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 313; (1961); p. 199 - 206 View in Reaxys vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 ; (from Gmelin)

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View in Reaxys 80-90

in neat (no solvent), prepn. of labelled SnCl4 from Cl labelled AgCl or Sn isotope; formation by slow heating metallic Sn with anhyd. AgCl above ca. 450°C;; freezing out in a cooling-trap; distillation in vac.; pure SnCl4; Lieser, K. H.; Elias, H.; Journal of Inorganic and Nuclear Chemistry; vol. 23; (1961); p. 139 View in Reaxys vol. Sn: MVol.C1; 6.9.1.7, page 255 - 255 ; (from Gmelin) View in Reaxys Cl

AgCl

Sn Cl ClCl

Cl 2Sn

Rx-ID: 26096459 View in Reaxys 119/267 Yield

Conditions & References in neat (no solvent), heating at 350°C or above; Lieser, K. H.; Elias, H.; Kohlschuetter, H. W.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 313; (1961); p. 199 - 206 ; (from Gmelin) View in Reaxys in neat (no solvent), heating at 350°C or above; vol. Ag: MVol.B1; 6.2.9.5.5, page 442 - 444 ; (from Gmelin) View in Reaxys Cl

ClCu

Sn ClCl

Rx-ID: 26100301 View in Reaxys 120/267 Yield

Conditions & References in neat (no solvent), prepn. of labelled SnCl4 from Cl labelled AgCl or Sn isotope; formation by slow heating metallic Sn with CuCl2;; freezing out in a cooling-trap; distillation in vac.; pure SnCl4; Lieser, K. H.; Elias, H.; Journal of Inorganic and Nuclear Chemistry; vol. 23; (1961); p. 139 View in Reaxys vol. Sn: MVol.C1; 6.9.1.7, page 255 - 255 ; (from Gmelin) View in Reaxys Cl 2

2Al3+ 3 Cl ClSnCl Cl Cl

Cl Al

Al2O3

H O

Sn ClCl

Rx-ID: 26180232 View in Reaxys 121/267 Yield

Conditions & References in neat (no solvent), thermic decomposition; Angoso y Catalina, A.; Acta Salmanticensia Ser. Cienc. (2); vol. 3; nb. 1; (1961); p. 77 - 103 View in Reaxys vol. Sn: MVol.C4; 35.12, page 103 - 103 ; (from Gmelin) View in Reaxys Cl 2 Ce 3+ 3 Cl SnCl 2Cl Cl Cl

Ce 2O3

H O

(v3)

Sn ClCl

Rx-ID: 26180233 View in Reaxys 122/267 Yield

Conditions & References in neat (no solvent), thermic decomposition;

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Angoso y Catalina, A.; Acta Salmanticensia Ser. Cienc. (2); vol. 3; nb. 1; (1961); p. 77 - 103; C. A.; vol. 57; (1962); p. 12093 View in Reaxys vol. Sn: MVol.C4; 39.7.3, page 153 - 153 ; (from Gmelin) View in Reaxys H

H Cl

Cl 23 Cl SnCl Cl Cl Cl

Cl Y

O3Y2

Y3+

(v3)

Sn ClCl

Rx-ID: 26180235 View in Reaxys 123/267 Yield

Conditions & References in neat (no solvent), thermic decomposition; Angoso y Catalina, A.; Acta Salmanticensia Ser. Cienc. (2); vol. 3; nb. 1; (1961); p. 77 - 103; C. A.; vol. 57; (1962); p. 12093 View in Reaxys vol. Sn: MVol.C4; 39.7.1, page 153 - 153 ; (from Gmelin) View in Reaxys H

H Cl

2 La 3+ Cl 23 Cl SnCl Cl Cl

Cl La

La 2O3 Cl

(v3)

Sn ClCl

Rx-ID: 26180240 View in Reaxys 124/267 Yield

Cl 2OSn

O2Sn

Sn ClCl

Rx-ID: 26456803 View in Reaxys 125/267 Yield

Conditions & References in neat (no solvent), thermic decomposition in SnO2 and SnCl4 at 155°C under normal pressure and also in an inclose tube; Dehnicke, K.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 308; (1961); p. 72 - 78 View in Reaxys vol. Sn: MVol.C1; 6.28, page 362 - 364 ; (from Gmelin) View in Reaxys H

Sn ClCl

O2Sn

Cl 2Sn

Rx-ID: 26087677 View in Reaxys 126/267 Yield

Conditions & References With oxygen in neat (no solvent), heating in presence of air or oxygen forms SnCl4 and SnO2; Cueilleron, J.; Hartmannshenn, O.; Bulletin de la Societe Chimique de France; (1959); p. 172 - 176 ; (from Gmelin) View in Reaxys With O2

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vol. Sn: MVol.C1; 6.5.2.9, page 226 - 227 ; (from Gmelin) View in Reaxys Cl

Br I

Sn BrBr

Sn BrCl

Cl Cl

Sn ClCl

Rx-ID: 26166905 View in Reaxys 127/267 Yield

Conditions & References in acetic acid, byproducts: ICl, BrCl, Br2; titration of a SnBr4 soln. in acetic acid with ICl3 soln. forms SnCl4, ICl, BrCl, and SnBrCl3;; determination by cryoscopic examinations; vol. Sn: MVol.C1; 7.10.2.4, page 420 - 421 ; (from Gmelin) View in Reaxys in acetic acid Graulier, M.; Ann. Chim. (Paris) (13); vol. 4; (1959); p. 427 - 478 ; (from Gmelin) View in Reaxys Cl

Cl 2Sn

O2Sn

Sn ClCl

Rx-ID: 26185646 View in Reaxys 128/267 Yield

Conditions & References With oxygen in neat (no solvent), oxidation in O2 or air at under formation of SnO2 and SnCl4; catalysation with platinized asbestos; Schulze, H.; J. Prakt. Chem. (2); vol. 21; (1880); p. 407 - 439 ; (from Gmelin) View in Reaxys With oxygen in neat (no solvent), heating to 500°C in a sealed tube; Berthelot, M.; Ann. Chim. Phys.; vol. 15; (1878); p. 215 - 215 View in Reaxys vol. Cl: MVol.; 79, page 220 - 222 ; (from Gmelin) View in Reaxys With oxygen in neat (no solvent), very slow oxidation in O2 or air at 220-240°C under formation of SnO2 and SnCl4; quick oxidation at 300-350°C; Cueilleron, J.; Hartmannshenn, O.; Bulletin de la Societe Chimique de France; (1959); p. 172 - 176 ; (from Gmelin) View in Reaxys With O2 vol. Sn: MVol.C1; 6.3.9.4, page 217 - 218 ; (from Gmelin) View in Reaxys With O2, catalyst: platinized asbestos vol. Sn: MVol.C1; 6.3.9.4, page 217 - 218 ; (from Gmelin) View in Reaxys

Cl S

Sn ClCl

Rx-ID: 26109596 View in Reaxys 129/267 Yield

Conditions & References excess SCl2 vol. Sn: MVol.B; 14.4.4.1, page 358 - 359 View in Reaxys Paul, R. C.; Singh, G.; Journal of the Indian Chemical Society; vol. 35; (1958); p. 909 - 910; C. A.; (1959); p. 16786 ; (from Gmelin)

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View in Reaxys in neat (no solvent), fast formation by reaction of Sn with SCl2; vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 View in Reaxys Paul, R. C.; Singh, G.; Journal of the Indian Chemical Society; vol. 35; (1958); p. 909 - 910; C. A.; (1959); p. 16786 ; (from Gmelin) View in Reaxys

Cl Sn (v2)

Sn ClCl

Rx-ID: 26440592 View in Reaxys 130/267 Yield

Conditions & References

90.5 %

With mercury dichloride in ethanol, 20h heating in sealed tube to 120°C; absol. ethanol; Baehr, G.; Gelius, R.; Chemische Berichte; vol. 91; (1958); p. 812 - 818 ; (from Gmelin) View in Reaxys

90.5 %

With HgCl2 in ethanol, 20h heating in sealed tube to 120°C; absol. ethanol; vol. Hg: MVol.B2; 105, page 617 - 619 ; (from Gmelin) View in Reaxys

– Cl SnCl Cl

Sn ClCl

H+

Rx-ID: 26613009 View in Reaxys 131/267 Yield

Conditions & References recrystn. from soln. Sharp, D. W. A.; Chemistry and Industry (London, United Kingdom); (1958); p. 1235 - 1236 View in Reaxys vol. Sn: MVol.C3; 23.5.4.2, page 101 - 101 ; (from Gmelin) View in Reaxys H

Cl 2Sn

O Cl

Cl Sn Cl ClCl

Rx-ID: 26087698 View in Reaxys 132/267 Yield

Conditions & References in not given, chlorination at treatment with benzoyl chloride to SnCl4; Gutmann, V.; Tannenberg, H.; Monatshefte fuer Chemie; vol. 88; (1957); p. 216 - 227 ; (from Gmelin) View in Reaxys vol. Sn: MVol.C1; 6.5.2.9, page 226 - 227 ; (from Gmelin) View in Reaxys

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Cl Cl

Sn ClCl

Rx-ID: 26139814 View in Reaxys 133/267 Yield

Conditions & References in neat (no solvent), formation by reaction of powdered Sn with S2Cl2 on heating for a short period of time; Funk, H.; Berndt, K. H.; Henze, G.; Reihe Wissenschaftliche Zeitschrift - Martin-Luther-Universitaet Halle-Wittenberg, Mathematisch-Naturwissenschaftliche Reihe; vol. 6; (1957); p. 815 - 822; C.A.; (1960); p. 12860 View in Reaxys vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 ; (from Gmelin) View in Reaxys Cl

O2Sn

Sn ClCl

Rx-ID: 26151248 View in Reaxys 134/267 Yield

Conditions & References in neat (no solvent), red heat; Hall, R. D.; Journal of the American Chemical Society; vol. 26; (1904); p. 1235 View in Reaxys Bourion, F.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 148; (1909); p. 170 171 View in Reaxys Bourion, F.; Ann. Chim. Phys.; vol. 21; (1910); p. 49 - 131 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by reaction of SnO2 with S2Cl2 on heating; vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 View in Reaxys Matignon, C.; Bourion, F.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 138; (1904); p. 760 - 762 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by reaction of dry SnO2 powder with S2Cl2 at 350°C in 8 h; Funk, H.; Berndt, K. H.; Henze, G.; Reihe Wissenschaftliche Zeitschrift - Martin-Luther-Universitaet Halle-Wittenberg, Mathematisch-Naturwissenschaftliche Reihe; vol. 6; (1957); p. 815 - 822; C.A.; (1960); p. 12860 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys in neat (no solvent), formation of SnCl4 at heating with dry S2Cl2 for 8 h at 350°C; Funk, H.; Berndt, K. H.; Henze, G.; Reihe Wissenschaftliche Zeitschrift - Martin-Luther-Universitaet Halle-Wittenberg, Mathematisch-Naturwissenschaftliche Reihe; vol. 6; (1956); p. 815 - 822 ; (from Gmelin) View in Reaxys in neat (no solvent), formation of SnCl4 at heating with dry S2Cl2 for 8 h at 350°C; vol. Sn: MVol.C1; 3.7.8.4.3, page 101 - 102 ; (from Gmelin) View in Reaxys in neat (no solvent), red heat; vol. S: MVol.B3; 114, page 1775 - 1776 ; (from Gmelin) View in Reaxys

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Cl Cl

Cl Al

Cl Sn Cl 2Sn

Sn ClCl

Rx-ID: 26456248 View in Reaxys 135/267 Yield

Conditions & References in chloroform Manulkin, Z. M.; Tatarenko, A. N.; Yusupov, V. Yu.; Tr. Tashkent. Farm. Inst.; vol. 1; (1957); p. 291 - 295; C.A.; vol. 57; (1962); p. 9869 View in Reaxys Manulkin, Z. M.; Zhurnal Obshchei Khimii; vol. 18; (1948); p. 299 - 305; C.A.; (1948); p. 6742 View in Reaxys vol. Sn: Org.Verb.1; 1.1.1.16.1.4.5, page 159 - 161 ; (from Gmelin) View in Reaxys

Cl Sn

Sn ClCl

(v1)

–Cl

(v2)

Hg +

Rx-ID: 26539777 View in Reaxys 136/267 Yield

Conditions & References With mercury dichloride in chloroform Kocheshkov, A. N.; Nesmeyanov, A. N.; Zhurnal Obshchei Khimii; vol. 4; (1934); p. 1102 - 1113 View in Reaxys Manulkin, Z. M.; Tatarenko, A. N.; Yusupov, V. Yu.; Tr. Tashkent. Farm. Inst.; vol. 1; (1957); p. 291 - 295; C.A.; vol. 57; (1962); p. 9869 View in Reaxys vol. Sn: Org.Verb.1; 1.1.1.16.1.4.5, page 159 - 161 View in Reaxys Patent; Kharasch, M. S.; E. I. Du Pont de Nemours & Co.; US1987685; (1935); C; vol. II; (1935); p. 437 View in Reaxys Nesmeyanov, A. N.; Kocheshkov, K. A.; Ber. Dtsch. Chem. Ges.; vol. 67; (1934); p. 317 - 324 ; (from Gmelin) View in Reaxys With mercury dichloride in ethanol Kocheshkov, A. N.; Nesmeyanov, A. N.; Zhurnal Obshchei Khimii; vol. 4; (1934); p. 1102 - 1113 View in Reaxys Manulkin, Z. M.; Tatarenko, A. N.; Yusupov, V. Yu.; Tr. Tashkent. Farm. Inst.; vol. 1; (1957); p. 291 - 295; C.A.; vol. 57; (1962); p. 9869 View in Reaxys vol. Sn: Org.Verb.1; 1.1.1.16.1.4.5, page 159 - 161 View in Reaxys Patent; Kharasch, M. S.; E. I. Du Pont de Nemours & Co.; US1987685; (1935); C; vol. II; (1935); p. 437 View in Reaxys Nesmeyanov, A. N.; Kocheshkov, K. A.; Ber. Dtsch. Chem. Ges.; vol. 67; (1934); p. 317 - 324 ; (from Gmelin) View in Reaxys

Sn ClCl

Rx-ID: 26114819 View in Reaxys 137/267

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Yield

Conditions & References in neat (no solvent), formation by heating Sn(C6H4)4 with acetylchloride at 100-130°C; Koton, M. M.; Zhurnal Obshchei Khimii; vol. 26; (1956); p. 3212 - 3214 View in Reaxys vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 ; (from Gmelin) View in Reaxys 2 F F F Sn2- F F F

Cl Al

K+

Cl Sn Cl ClCl

Rx-ID: 26150958 View in Reaxys 138/267 Yield

Conditions & References

60 %

in neat (no solvent), formation by reaction of K2SnF6 with AlCl3; vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 View in Reaxys Patent; Schmeisser, M.; Jenkner, H.; Kali-Chemie A.-G.; DE945757; (1956); C. A.; (1958); p. 20943 ; (from Gmelin) View in Reaxys

Cl Sn

Sn ClCl

Rx-ID: 26427031 View in Reaxys 139/267 Yield

Conditions & References 50 to 130°C Bost, R. W.; Borgstrom, P.; Journal of the American Chemical Society; vol. 51; (1929); p. 1922 - 1925 View in Reaxys Koton, M. M.; Journal of General Chemistry USSR (English Translation); vol. 28; (1956); p. 3581 - 3583 View in Reaxys Koton, M. M.; Zhurnal Obshchei Khimii; vol. 26; (1956); p. 3212 - 3214 View in Reaxys Skoldinov, A. P.; Kocheshkov, K. A.; Zhurnal Obshchei Khimii; vol. 12; (1942); p. 398 - 401 View in Reaxys vol. Sn: Org.Verb.1; 1.1.1.16.1.4.4, page 157 - 159 ; (from Gmelin) View in Reaxys

Sn .alpha., gray

Cl Sn Cl ClCl

Rx-ID: 26721460 View in Reaxys 140/267 Yield

Conditions & References in hydrogenchloride, 37percent HCl, -17+/-2°C; removing of O2 Gela, T.; Journal of Chemical Physics; vol. 24; (1956); p. 1009 - 1011 View in Reaxys vol. Sn: MVol.B; 14.7.5, page 368 - 371 ; (from Gmelin) View in Reaxys

Sn .beta., white

Sn ClCl

Cl 2Sn

Rx-ID: 26821186 View in Reaxys 141/267 Yield

Conditions & References in hydrogenchloride, 37percent HCl, -17+/-2°C; removing of O2

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Gela, T.; Journal of Chemical Physics; vol. 24; (1956); p. 1009 - 1011 View in Reaxys vol. Sn: MVol.B; 14.7.5, page 368 - 371 ; (from Gmelin) View in Reaxys Ce 4+

2 O

2 Ce 3+ – O 3

O S

O–

Cl 2Sn

O–

O– S O

Cl Sn Cl ClCl

Rx-ID: 26143472 View in Reaxys 142/267 Yield

Conditions & References in hydrogenchloride, byproducts: H2SO4 Stolyarov, K. P.; Zhurnal Analiticheskoi Khimii; vol. 9; (1954); p. 159 - 166; Zhurnal Analiticheskoi Khimii; vol. 9; (1954); p. 141 - 149 View in Reaxys vol. Sn: MVol.B; 16.1.5.10.1, page 402 - 404 ; (from Gmelin) View in Reaxys

Cl Al

Sn ClCl

Rx-ID: 26151003 View in Reaxys 143/267 Yield

Conditions & References in neat (no solvent), formation by heating Sn(C6H5)4 with AlCl3; Manulkin, Z. M.; Zhurnal Obshchei Khimii; vol. 18; (1948); p. 299 - 305; C.A.; (1948); p. 6742 View in Reaxys Razuvaev, G. A.; Fedotov, M. S.; Zaichenko, T. N.; Kul'vinskaya, N. A.; Sb. Statei Obshch. Khim. Akad. Nauk SSSR; vol. 2; (1953); p. 1514 - 1516 View in Reaxys vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 ; (from Gmelin) View in Reaxys

Cl Fe

(v3)

Sn ClCl

Rx-ID: 26152882 View in Reaxys 144/267 Yield

Conditions & References in neat (no solvent), formation by heating Sn(C6H5)4 with FeCl3; Manulkin, Z. M.; Zhurnal Obshchei Khimii; vol. 18; (1948); p. 299 - 305; C.A.; (1948); p. 6742 View in Reaxys Razuvaev, G. A.; Fedotov, M. S.; Zaichenko, T. N.; Kul'vinskaya, N. A.; Sb. Statei Obshch. Khim. Akad. Nauk SSSR; vol. 2; (1953); p. 1514 - 1516 View in Reaxys vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 ; (from Gmelin) View in Reaxys

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Cl Sn

Sn ClCl

Rx-ID: 26162895 View in Reaxys 145/267 Yield

Conditions & References

>99

in tetrachloromethane, in presence of benzoylperoxide; Oldekop, Yu. A.; Sokolova, R. F.; Zhurnal Obshchei Khimii; vol. 23; (1953); p. 1159 - 1162 View in Reaxys vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 ; (from Gmelin) View in Reaxys

Sn Cl

Cl Cl Cl

Sn Cl ClCl

O O

Rx-ID: 26475588 View in Reaxys 146/267 Yield

Conditions & References

84.1 %

50h boiling Oldekop, Yu. A.; Sokolova, R. F.; Zhurnal Obshchei Khimii; vol. 23; (1953); p. 1159 - 1162 View in Reaxys vol. Sn: Org.Verb.1; 1.1.1.16.1.4.4, page 157 - 159 ; (from Gmelin) View in Reaxys Cl

Cl 2Sn

Sn ClCl

Rx-ID: 26090359 View in Reaxys 147/267 Yield

Conditions & References in hydrogenchloride, byproducts: HI; reaction with ICl in HCl-containing soln. under formation of HI and SnCl4; Fialkov, Ya. A.; Kagan, F. E.; Ukr. Khim. Zh.; vol. 18; (1952); p. 55 - 63 ; (from Gmelin) View in Reaxys in hydrogenchloride, byproducts: HI; reaction with ICl in HCl-containing soln. under formation of HI and SnCl4; vol. Sn: MVol.C1; 6.6.8.7, page 235 - 236 ; (from Gmelin) View in Reaxys

Cl Cl

Cl O2Sn

Sn ClCl

Rx-ID: 26150226 View in Reaxys 148/267 Yield 25 %

Conditions & References in neat (no solvent), formation by chlorination of SnO2 with C3Cl8 at 325°C for 16 h; Atkinson, R. H.; Steigmann, J.; Hiskey, C. F.; Analytical Chemistry; vol. 24; (1952); p. 480 - 484 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys

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5-10

in neat (no solvent), formation by chlorination of SnO2 with C3Cl8 at 300°C for 2 h; Atkinson, R. H.; Steigmann, J.; Hiskey, C. F.; Analytical Chemistry; vol. 24; (1952); p. 480 - 484 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys

Cl I

Cl 2Sn

Sn Cl ClCl

Rx-ID: 26166909 View in Reaxys 149/267 Yield

Conditions & References in hydrogenchloride, byproducts: HI; reaction with ICl3 in HCl-containing soln. under formation of HI and SnCl4; Fialkov, Ya. A.; Kagan, F. E.; Ukr. Khim. Zh.; vol. 18; (1952); p. 55 - 63 ; (from Gmelin) View in Reaxys in hydrogenchloride, byproducts: HI; reaction with ICl3 in HCl-containing soln. under formation of HI and SnCl4; vol. Sn: MVol.C1; 6.6.8.7, page 235 - 236 ; (from Gmelin) View in Reaxys

Cl Cl

Sn ClCl

PCl Cl

H HO

P OH O

Sn Cl ClCl

Rx-ID: 26455859 View in Reaxys 150/267 Yield

Conditions & References in water Casselmann, W.; Liebigs Annalen der Chemie; vol. 83; (1952); p. 257 - 275 View in Reaxys vol. Sn: MVol.C2; 16.16.1, page 259 - 260 ; (from Gmelin) View in Reaxys

Cl Cl ClSe Cl(v3) O SnOCl Se ClOC-6 (v3) (v6) Cl

Sn ClCl

Rx-ID: 26636210 View in Reaxys 151/267 Yield

Conditions & References in neat (no solvent), heating;; distillation; Sheldon, J. C.; Tyree, S. Y.; Journal of the American Chemical Society; vol. 81; (1952); p. 2290 - 2296 View in Reaxys vol. Sn: MVol.C2; 10.7.1, page 125 - 126 ; (from Gmelin) View in Reaxys Cl

I Cl

Sn ClCl

Rx-ID: 26090328 View in Reaxys 152/267 Yield

Conditions & References vigorous react. vol. Sn: MVol.B; 14.4.3, page 357 - 358 View in Reaxys Gutmann, V.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 264; (1951); p. 169 - 173 ; (from Gmelin) View in Reaxys in neat (no solvent), fizzing; formation of heat;

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Hannay, J. B.; Journal of the Chemical Society; vol. 26; (1873); p. 822 - 822 ; (from Gmelin) View in Reaxys in neat (no solvent), fizzing; formation of heat; vol. I: MVol.2; 166, page 614 - 616 ; (from Gmelin) View in Reaxys Cl Sn

Sn ClCl

Rx-ID: 26090330 View in Reaxys 153/267 Yield

Conditions & References

>99

in neat (no solvent), molten ICl; vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 View in Reaxys Gutmann, V.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 264; (1951); p. 169 - 173 ; (from Gmelin) View in Reaxys Cl

Cl Sn Cl ClCl

Rx-ID: 26139791 View in Reaxys 154/267 Yield

Conditions & References in neat (no solvent), byproducts: S8, SO2; Sn powder; vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 View in Reaxys Hubbard, R. A.; Luder, W. F.; Journal of the American Chemical Society; vol. 73; (1951); p. 1327 - 1329 ; (from Gmelin) View in Reaxys excess SOCl2, 150°C, several h vol. Sn: MVol.B; 14.4.4.1, page 358 - 359 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: S2Cl2, SO2 vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: SO; formation by reaction of tin sheet with SOCl2 below 200°C; Schenk, P. W.; Platz, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 215; (1933); p. 113 - 128 View in Reaxys vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: S2Cl2, SO2 North, H. B.; Hageman, A. M.; Journal of the American Chemical Society; vol. 34; (1912); p. 890 - 890 ; (from Gmelin) View in Reaxys excess SOCl2, 150°C, several h North, H. B.; Hageman, A. M.; Journal of the American Chemical Society; vol. 34; (1912); p. 890 - 890 ; (from Gmelin) View in Reaxys

Cl Cl

O2Sn

Sn Cl ClCl

Rx-ID: 26162906 View in Reaxys 155/267

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Yield

Conditions & References in neat (no solvent), chlorination with CCl4 in an inclosed tube at 380°C in 10 h to SnCl4; Schaefer, H.; Bayer, L.; Pietruck, Ch.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 266; (1951); p. 140 - 150 View in Reaxys vol. Sn: MVol.C1; 3.7.8.8, page 112 - 113 ; (from Gmelin) View in Reaxys in neat (no solvent), formation by reaction of SnO2 with CCl4 at red heat; Renz, C.; Ber. Dtsch. Chem. Ges.; vol. 39; (1906); p. 249 - 250 View in Reaxys Watts, C. W.; Bell, C. A.; Journal of the Chemical Society; (1878); p. 442 - 444 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys in neat (no solvent), passing steam of CCl4 over SnO2 at 398 °C; Camboulives; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 150; (1910); p. 176 - 176 View in Reaxys vol. Cl: MVol.; 65, page 183 - 186 ; (from Gmelin) View in Reaxys Cl

O2Sn

CaCl 2

Sn ClCl

Rx-ID: 26144721 View in Reaxys 156/267 Yield 52.9 %

Conditions & References With carbon in neat (no solvent), heating of a mixture of SnO2 with double excess of CaCl2 forms 52.9 percent SnCl4 at 800°C in presence of C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

7.18 %

in neat (no solvent), heating of a mixture of SnO2 with double excess of CaCl2 forms 7.18 percent SnCl4 at 800°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

5.6 %

in neat (no solvent), heating of a mixture of SnO2 with double excess of CaCl2 forms 5.60 percent SnCl4 at 700°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

4.6 %

in neat (no solvent), heating of a mixture of SnO2 with double excess of CaCl2 forms 4.60 percent SnCl4 at 600°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

3.76 %

in neat (no solvent), heating of a mixture of SnO2 with double excess of CaCl2 forms 3.76 percent SnCl4 at 500°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin)

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View in Reaxys Cl O2Sn

Cl 2Zn

Sn ClCl

Rx-ID: 26185747 View in Reaxys 157/267 Yield 97.87 %

Conditions & References With carbon in neat (no solvent), byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 97.87 percent SnCl4 at 800°C in presence of C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

5.2 %

in neat (no solvent), byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 5.2 percent SnCl4 at 800°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

4.3 %

in neat (no solvent), byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 4.3 percent SnCl4 at 600°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

4.4 %

in neat (no solvent), byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 4.4 percent SnCl4 at 700°C; equilibrium reaction examinated; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

3.8 %

in neat (no solvent), byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 3.8 percent SnCl4 at 500°C; equilibrium reaction examinated; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms SnCl4 at 300°C; equilibrium reaction examinated; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys in neat (no solvent) Frents, G. S.; Izv. Akad. Nauk SSSR Otd. Tekhn. Nauk; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys

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Cl O2Sn

Cl 2Fe

Sn ClCl

Rx-ID: 26185836 View in Reaxys 158/267 Yield 98.97 %

Conditions & References With carbon in neat (no solvent), byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 98.97 percent SnCl4 at 800°C in presence of C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

76.1 %

in neat (no solvent), byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 76.10 percent SnCl4 at 800°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

27.2 %

in neat (no solvent), byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 27.20 percent SnCl4 at 700°C; equilibrium reaction discussed; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

12.01 %

in neat (no solvent), byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 12.01 percent SnCl4 at 600°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

in neat (no solvent), byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 0 percent SnCl4 at 500°C; equilibrium reaction examinated; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms SnCl4 at 300 and 1000°C; examination of equilibrium reaction; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys Cl

O2Sn

Cl 2Mg

Sn ClCl

Rx-ID: 26186229 View in Reaxys 159/267 Yield 98.3 %

Conditions & References With carbon in neat (no solvent), byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 98.3 percent SnCl4 at 800°C in presence of C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

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74.6 %

in neat (no solvent), byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 74.60 percent SnCl4 at 800°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

58.79 %

in neat (no solvent), byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 58.79 percent SnCl4 at 700°C; equilibrium reaction examinated; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

16.8 %

in neat (no solvent), byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 16.8 percent SnCl4 at 600°C; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys

0.13 %

in neat (no solvent), byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 0.13 percent SnCl4 at 500°C; equilibrium reaction examinated; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms SnCl4 at 300 and 1000°C; equilibrium reaction examinated; Frents, G. S.; Nachr. Akad. Wiss. UdSSR; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 3.7.8.6.3, page 109 - 110 ; (from Gmelin) View in Reaxys in neat (no solvent), low reaction rate at 300 - 500°C, high at 700°C; Frents, G. S.; Izv. Akad. Nauk SSSR Otd. Tekhn. Nauk; (1948); p. 235 - 238; C. A.; (1948); p. 6690 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys

5H O 2

Cl Sn Cl Cl

Sn ClCl

Rx-ID: 26082053 View in Reaxys 160/267 Yield

Conditions & References With SOCl2 or COCl2 in neat (no solvent) Hecht, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 254; (1947); p. 37 - 51 View in Reaxys vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 ; (from Gmelin) View in Reaxys With COCl2 in neat (no solvent), complete draining with COCl2 at 100°C in 24 h; Hecht, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 254; (1947); p. 37 - 51 ; (from Gmelin) View in Reaxys With thionyl chloride in neat (no solvent), complete draining with boiling SOCl2 in some hours;

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Hecht, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 254; (1947); p. 37 - 51 ; (from Gmelin) View in Reaxys in melt, byproducts: H2O; dissociation in SnCl4 and H2O at 66-111°C; Smirnoff, W.; Z. Physik. Chem.; vol. 58; (1907); p. 373 - 380 View in Reaxys Smirnoff, W.; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 38; (1906); p. 1172 - 1172; C. A.; (1907); p. 1220 View in Reaxys vol. Sn: MVol.C1; 6.10.1, page 313 - 313 ; (from Gmelin) View in Reaxys With COCl2 vol. Sn: MVol.C1; 6.10.5, page 315 - 316 ; (from Gmelin) View in Reaxys With SOCl2 vol. Sn: MVol.C1; 6.10.5, page 315 - 316 ; (from Gmelin) View in Reaxys

H O

Sn ClCl

Cl 2Sn

Rx-ID: 26087691 View in Reaxys 161/267 Yield

Conditions & References in neat (no solvent), room temp.; Hecht, H.; Z. Anorg. Chem.; vol. 254; (1947); p. 37 - 51 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: SO2, S; reaction with SOCl2 forms SnCl2 which reacts to SnCl4; Hecht, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 254; (1947); p. 37 - 51 ; (from Gmelin) View in Reaxys in neat (no solvent), room temp.; vol. S: MVol.B3; 124, page 1796 - 1798 ; (from Gmelin) View in Reaxys vol. Sn: MVol.C1; 6.5.2.9, page 226 - 227 ; (from Gmelin) View in Reaxys

S O

-1

H O -1 O2Sn

Sn ClCl

Rx-ID: 26144290 View in Reaxys 162/267 Yield

Conditions & References in neat (no solvent), formation by reaction of SOCl2 with tin dioxide hydrate at 250°C; Hecht, H.; Jander, G.; Schlapmann, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 254; (1947); p. 255 - 264 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys

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5H O 2

Cl Sn Cl

Sn Cl ClCl

Rx-ID: 26363168 View in Reaxys 163/267 Yield

Conditions & References in neat (no solvent), dehydratation; on boiling; Hecht, H.; Z. Anorg. Chem.; vol. 254; (1947); p. 37 - 51 ; (from Gmelin) View in Reaxys in neat (no solvent), dehydratation; on boiling; vol. S: MVol.B3; 124, page 1796 - 1798 ; (from Gmelin) View in Reaxys

5H O 2

Cl Sn Cl

Sn ClCl

Rx-ID: 26363169 View in Reaxys 164/267 Yield

Conditions & References hydrolysis, heating in a bomb tube, 100°C, 24 h Hecht, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 254; (1947); p. 37 - 51 ; (from Gmelin) View in Reaxys hydrolysis, heating in a bomb tube, 100°C, 24 h vol. C: MVol.D3; 2.2.8.6.1, page 94 - 95 ; (from Gmelin) View in Reaxys Cl

OSn

Sn ClCl

O2Sn

Rx-ID: 26104130 View in Reaxys 165/267 Yield

Conditions & References in neat (no solvent) Forbes, G. S.; Anderson, H. A.; Journal of the American Chemical Society; vol. 67; (1945); p. 1911 - 1914 ; (from Gmelin) View in Reaxys vol. Cl: SVol.A; 154, page 361 - 364 ; (from Gmelin) View in Reaxys Cl

F2Sn

Cl Cl

Sn ClCl

Rx-ID: 26182487 View in Reaxys 166/267 Yield

Conditions & References in neat (no solvent), byproducts: SnF4; under inflammation; Forbes, G. S.; Anderson, H. A.; Journal of the American Chemical Society; vol. 67; (1945); p. 1911 - 1914 ; (from Gmelin) View in Reaxys vol. Cl: SVol.A; 155, page 365 - 368 ; (from Gmelin) View in Reaxys F

F2Sn

Sn F

Sn ClCl

Rx-ID: 26540167 View in Reaxys 167/267 Yield

Conditions & References With chlorine in neat (no solvent), reaction with Cl2 at heating under formation of SnF4 and SnCl4;

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Forbes, G. S.; Anderson, H. A.; Journal of the American Chemical Society; vol. 67; (1945); p. 1911 - 1914 ; (from Gmelin) View in Reaxys With Cl2 in neat (no solvent), reaction with Cl2 at heating under formation of SnF4 and SnCl4; vol. Sn: MVol.C1; 5.2.7, page 162 - 163 ; (from Gmelin) View in Reaxys OSn

Cl I

O2Sn

Sn ClCl

Rx-ID: 26937324 View in Reaxys 168/267 Yield

Conditions & References With Cl2 in neat (no solvent), reaction with excess Cl2 at 550-600°C; SnO2 and SnCl4 are formed; Forbes, G. S.; Anderson, H. A.; Journal of the American Chemical Society; vol. 67; (1945); p. 1911 - 1914 View in Reaxys vol. Sn: MVol.C1; 3.2.8.3, page 44 - 45 ; (from Gmelin) View in Reaxys -2

Fe( 3+)

Fe( 2+)

Sn Cl ClCl

Sn ClCl

Rx-ID: 26289594 View in Reaxys 169/267 Yield

Conditions & References at low concn. of Cl(1-) Robinson, R. A.; Law, N. H.; Transactions of the Faraday Society; vol. 31; (1935); p. 899 - 906 View in Reaxys vol. Sn: MVol.B; 16.1.5.10.7, page 404 - 409 ; (from Gmelin) View in Reaxys in hydrogenchloride, Kinetics, neutral or weakly acidic soln. Weiss, J.; Journal of the Chemical Society; (1944); p. 309 - 311 View in Reaxys vol. Sn: MVol.B; 16.1.5.10.7, page 404 - 409 ; (from Gmelin) View in Reaxys Cl

Cl Cl

Sn ClCl

Rx-ID: 26139789 View in Reaxys 170/267 Yield

Conditions & References in neat (no solvent), 150°C; excess of SOCl2; North, H. B.; Hageman, A. M.; Journal of the American Chemical Society; vol. 34; (1912); p. 890 - 890 View in Reaxys Booth, H. S.; Mericola, F. C.; Journal of the American Chemical Society; vol. 62; (1940); p. 640 - 642 ; (from Gmelin) View in Reaxys in neat (no solvent), 150°C; excess of SOCl2; vol. S: MVol.B3; 124, page 1796 - 1798 ; (from Gmelin) View in Reaxys Cl

Cl 2Sn

Sn ClCl

Rx-ID: 26185625 View in Reaxys 171/267

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Yield

Conditions & References in neat (no solvent, gas phase), Electrolysis; formation of metallic Sn with a cathodic current-yield of 88.0 percent at using of a coal-anode at melt-stream electrolysis at 460°C; formation of gaseous SnCl4 at the anode; Drossbach, P.; Zeitschrift fuer Elektrochemie; vol. 44; (1938); p. 288 - 291 View in Reaxys vol. Sn: MVol.C1; 6.3.8, page 215 - 216 ; (from Gmelin) View in Reaxys Cl

N 4Sn3

Sn Cl ClCl

Rx-ID: 26454946 View in Reaxys 172/267 Yield

Conditions & References With hydrogenchloride in hydrogenchloride, byproducts: NH4Cl; reaction with HCl soln., SnCl4 and NH4Cl formed; Berraz, G.; Anales Inst. Invest. Cient. Tecnol.; vol. 5/6; (1937); p. 78 - 82; C. A.; (1937); p. 8415 View in Reaxys Berraz, G.; Anales Soc. Cient. Arg. Seccion Santa Fe; vol. 7; (1935); p. 6 - 7; C. A.; (1937); p. 949 ; (from Gmelin) View in Reaxys With HCl in hydrogenchloride, byproducts: NH4Cl; reaction with HCl soln., SnCl4 and NH4Cl formed; vol. Sn: MVol.C1; 4.1.2, page 145 - 145 ; (from Gmelin) View in Reaxys

Cl S O

Sn OCl O SO

Cl S

Sn ClCl

Rx-ID: 26636195 View in Reaxys 173/267 Yield

Conditions & References in neat (no solvent), decompn. on heating; Likhacheva, A. I.; Zhurnal Obshchei Khimii; vol. 7; (1937); p. 959 - 961; C. A.; (1937); p. 6127 View in Reaxys vol. Sn: MVol.C2; 9.32, page 77 - 77 ; (from Gmelin) View in Reaxys

Cl Cl Fe (v4)

-2

Cl Fe Cl Cl

(v4)

Cl Sn Cl ClCl

Fe( 2+)

Sn ClCl

Rx-ID: 26301779 View in Reaxys 174/267 Yield

Conditions & References at high concn. of Cl(1-) Robinson, R. A.; Law, N. H.; Transactions of the Faraday Society; vol. 31; (1935); p. 899 - 906 View in Reaxys vol. Sn: MVol.B; 16.1.5.10.7, page 404 - 409 ; (from Gmelin) View in Reaxys

mercury (II)-chloride

Cl Cl

Sn ClCl

(v1)

–Cl

(v2)

Hg +

Rx-ID: 8240711 View in Reaxys 175/267 Yield

Conditions & References Nesmejanow; Kozeschkow; Chemische Berichte; vol. 67; (1934); p. 317,320; Zhurnal Obshchei Khimii; vol. 4; (1934); p. 1102,1108; Chem. Zentralbl.; vol. 107; nb. I; (1936); p. 2737

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View in Reaxys

Si Cl H

Sn F

Cl Cl

Sn ClCl

Rx-ID: 26455201 View in Reaxys 176/267 Yield

Conditions & References in neat (no solvent), byproducts: SiHF3 Ruff, O.; Albert, C.; Ber. Dtsch. Chem. Ges.; vol. 38; (1905); p. 53 - 64 View in Reaxys vol. Sn: MVol.C1; 5.6.6, page 176 - 177 View in Reaxys Booth, H. S.; Stillwell, W. D.; Journal of the American Chemical Society; vol. 56; (1934); p. 1531 - 1535 ; (from Gmelin) View in Reaxys

Cl Cl 2Sn

Sn ClCl

Rx-ID: 26144314 View in Reaxys 177/267 Yield

Conditions & References in neat (no solvent), formation by reaction of anhyd. SnCl2 with SOCl2 at 60°C; Schenk, P. W.; Platz, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 215; (1933); p. 113 - 128 View in Reaxys vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys

Br As

Sn BrBr

Sn ClCl

Rx-ID: 26148789 View in Reaxys 178/267 Yield

Conditions & References in not given, byproducts: AsBr3; reaction with AsCl3 gives a reaction mixture contg. AsBr3, SnCl4, and bromide chloride of As and Sn; equilibrium; Raeder, M. G.; Kgl. Norske Videnskab. Selskabs Skrifter; nb. 3; (1929); p. 1 - 118; C. II; (1930); p. 3361 View in Reaxys Raeder, M. G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 210; (1933); p. 145 - 160 ; (from Gmelin) View in Reaxys in not given, byproducts: AsBr3; reaction with AsCl3 gives a reaction mixture contg. AsBr3, SnCl4, and bromide chloride of As and Sn; equilibrium; vol. Sn: MVol.C1; 7.7.7.8.4, page 410 - 410 ; (from Gmelin) View in Reaxys

H O

2 Cl

+ K Cl

Sn ClCl

Sn2ClCl

Rx-ID: 26083429 View in Reaxys 179/267 Yield >99, >99

Conditions & References in hydrogenchloride, byproducts: KCl, H2O; HCl acidic soln.; Karantassis, T.; Capatos, L.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 194; (1932); p. 1938 - 1938 ; (from Gmelin) View in Reaxys

>99, >99

in hydrogenchloride, byproducts: KCl, H2O; HCl acidic soln.;

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vol. I: MVol.2; 184, page 652 - 655 ; (from Gmelin) View in Reaxys Cl Cl 2Cu 2H 2O2

Sn ClCl

Rx-ID: 26139845 View in Reaxys 180/267 Yield

Conditions & References in neat (no solvent), fast formation by heating of powdered Sn with CuCl2*Cu(OH)2; Nicholas; Nature; vol. 129; nb. 3259; (1932); p. 581 - 581 View in Reaxys vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 ; (from Gmelin) View in Reaxys Cl

ClNSn

N 4Sn3

Sn ClCl

Rx-ID: 26587428 View in Reaxys 181/267 Yield

Conditions & References in neat (no solvent), decomposition at elevated temperature under formation of Sn3N4 and SnCl4; Schwarz, R.; Jeanmaire, A.; Ber. Dtsch. Chem. Ges.; vol. 65; (1932); p. 1443 - 1448 View in Reaxys vol. Sn: MVol.C1; 6.29, page 364 - 364 ; (from Gmelin) View in Reaxys 2 H+ Cl 2Cl SnCl Cl Cl

Cl Cl

Sn ClCl

Rx-ID: 26106019 View in Reaxys 182/267 Yield

Conditions & References With diethyl ether in diethyl ether, formation by reaction of H2SnCl6 with ether; Demetrios, A. G.; Ladikos, E.; Praktika tes Akademias Athenon; vol. 5; (1930); p. 224 - 228; C. A.; (1933); p. 3193 View in Reaxys vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 ; (from Gmelin) View in Reaxys O

Cl N H

Sn ClCl

Rx-ID: 8240708 View in Reaxys 183/267 Yield

Conditions & References beim Erhitzen Schmitz-Dumont; Chemische Berichte; vol. 62; (1929); p. 232 View in Reaxys Cl

Cl Fe

(v3)

Sn ClCl

Cl 2Fe

Rx-ID: 26139822 View in Reaxys 184/267 Yield

Conditions & References Kinetics, excess FeCl3 Heller, W.; Roczniki Chemii; vol. 8; (1928); p. 445 - 474 View in Reaxys Heller, W.; Z. Physik Chem. A; vol. 142; (1929); p. 431 - 452 ; (from Gmelin)

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View in Reaxys excess FeCl3 Biltz, W.; Holverscheit, W.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 140; (1924); p. 261 - 276 ; (from Gmelin) View in Reaxys vol. Sn: MVol.B; 14.8.1, page 375 - 378 ; (from Gmelin) View in Reaxys Cl

Br Br

Sn BrBr

Cl Cl

Sn ClCl

Rx-ID: 26150703 View in Reaxys 185/267 Yield

Conditions & References in not given, byproducts: PBr3; reaction with PCl3 gives a reaction mixture contg. PBr3, SnCl4, and bromide chlorides of P and Sn; equilibrium; Raeder, M. G.; Kgl. Norske Videnskab. Selskabs Skrifter; nb. 3; (1929); p. 1 - 118; C. II; (1930); p. 3361 ; (from Gmelin) View in Reaxys in not given, byproducts: PBr3; reaction with PCl3 gives a reaction mixture contg. PBr3, SnCl4, and bromide chlorides of P and Sn; equilibrium; vol. Sn: MVol.C1; 7.7.7.8.4, page 410 - 410 ; (from Gmelin) View in Reaxys

Br Sb Cl

Sn BrBr

Sn ClCl

Rx-ID: 26162571 View in Reaxys 186/267 Yield

Conditions & References in neat (no solvent), byproducts: SbBr3; reaction with SbCl3 gives a mixture of SnCl4, SbBr3 and bromide chloride of Sb and Sn; equilibrium; Raeder, M. G.; Kgl. Norske Videnskab. Selskabs Skrifter; nb. 3; (1929); p. 1 - 118; C. II; (1930); p. 3361 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: SbBr3; reaction with SbCl3 gives a mixture of SnCl4, SbBr3 and bromide chloride of Sb and Sn; equilibrium; vol. Sn: MVol.C1; 7.7.7.8.5, page 410 - 411 ; (from Gmelin) View in Reaxys

Cl (v4)

Ti ClCl

Sn Br BrBr

Sn Cl ClCl

Rx-ID: 26163164 View in Reaxys 187/267 Yield

Conditions & References in neat (no solvent), byproducts: TiBr4; reaction with TiCl4 gives a mixture of SnCl4, TiBr4, and various bromide chlorides of Sn and Ti; equilibrium; Raeder, M. G.; Kgl. Norske Videnskab. Selskabs Skrifter; nb. 3; (1929); p. 1 - 118; C. II; (1930); p. 3361 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: TiBr4; reaction with TiCl4 gives a mixture of SnCl4, TiBr4, and various bromide chlorides of Sn and Ti; equilibrium; vol. Sn: MVol.C1; 7.7.7.8.5, page 410 - 411 ; (from Gmelin) View in Reaxys

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HO S O

O O

Cl 2Sn

S OO

Sn ClCl

Rx-ID: 26345613 View in Reaxys 188/267 Yield

Conditions & References

>99%

in hydrogenchloride, room temp.; 10-15 min. Schwicker, A.; Zeitschrift fuer Analytische Chemie; vol. 74; (1928); p. 433 - 441 ; (from Gmelin) View in Reaxys

>99%

in hydrogenchloride, room temp.; 10-15 min. vol. S: MVol.B2; 6, page 808 - 852 ; (from Gmelin) View in Reaxys I

Cl 2Sn

Sn ClCl

Sn I I

Rx-ID: 26083498 View in Reaxys 189/267 Yield

Conditions & References in neat (no solvent), effect of Br2 forms a mixture of SnCl4 and SnI4; Raeder, M. G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 162; (1927); p. 222 - 230 ; (from Gmelin) View in Reaxys vol. Sn: MVol.C1; 6.3.9.4, page 217 - 218 ; (from Gmelin) View in Reaxys

Cl 2Sn

Sn Cl ClCl

Sn Br BrBr

Rx-ID: 26087098 View in Reaxys 190/267 Yield

Conditions & References in neat (no solvent), effect of Br2 forms a mixture of SnCl4 and SnBr4; Raeder, M. G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 162; (1927); p. 222 - 230 ; (from Gmelin) View in Reaxys vol. Sn: MVol.C1; 6.3.9.4, page 217 - 218 ; (from Gmelin) View in Reaxys I

Cl As

Sn I I

Cl Cl

Sn ClCl

Rx-ID: 26451163 View in Reaxys 191/267 Yield

Conditions & References in neat (no solvent), byproducts: AsI3 vol. Sn: MVol.C1; 8.7.7.5, page 475 - 477 View in Reaxys Karantassis, T.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 182; (1926); p. 699 - 701 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: AsI3 Karantassis, T.; Ann. Chim. (Paris) (10); vol. 8; (1927); p. 71 - 119 ; (from Gmelin) View in Reaxys I

Cl Sb Cl Cl

Sn I I

Cl Cl

Sn ClCl

Rx-ID: 26475230 View in Reaxys 192/267

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Yield

Conditions & References in neat (no solvent), byproducts: SbI3 vol. Sn: MVol.C1; 8.7.7.5, page 475 - 477 View in Reaxys Karantassis, T.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 182; (1926); p. 699 - 701 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: SbI3 Karantassis, T.; Ann. Chim. (Paris) (10); vol. 8; (1927); p. 71 - 119 ; (from Gmelin) View in Reaxys

Cl SbCl Cl TB-5 Cl

Cl Sn Cl ClCl

Sn I I

Rx-ID: 26487047 View in Reaxys 193/267 Yield

Conditions & References in neat (no solvent), byproducts: SbCl3, I2 vol. Sn: MVol.C1; 8.7.7.5, page 475 - 477 View in Reaxys Karantassis, T.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 182; (1926); p. 699 - 701 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: SbCl3, I2 Karantassis, T.; Ann. Chim. (Paris) (10); vol. 8; (1927); p. 71 - 119 ; (from Gmelin) View in Reaxys

I I

Sn I I

Cl Cl 2Pb

Sn ClCl

Rx-ID: 26488869 View in Reaxys 194/267 Yield

Conditions & References in neat (no solvent), byproducts: PbI2 vol. Sn: MVol.C1; 8.7.7.5, page 475 - 477 View in Reaxys Karantassis, T.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 182; (1926); p. 699 - 701 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: PbI2 Karantassis, T.; Ann. Chim. (Paris) (10); vol. 8; (1927); p. 71 - 119 ; (from Gmelin) View in Reaxys

Cl Sn Cl I I

Cl Sn Cl ClCl

Sn I I

Rx-ID: 26590589 View in Reaxys 195/267 Yield

Conditions & References in neat (no solvent), distillation forms a mixture of SnI4 and SnCl4; Raeder, M. G.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 162; (1927); p. 222 - 230 View in Reaxys vol. Sn: MVol.C1; 8.19, page 499 - 500 ; (from Gmelin) View in Reaxys

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Sn ClCl

Rx-ID: 26139801 View in Reaxys 196/267 Yield

Conditions & References Lehner, V.; Kao, C. H.; Journal of the American Chemical Society; vol. 48; (1926); p. 1550 - 1556 View in Reaxys vol. Sn: MVol.B; 14.4.4.2, page 359 - 359 ; (from Gmelin) View in Reaxys

Se Cl

Cl 2Sn

Sn ClCl

Rx-ID: 26444142 View in Reaxys 197/267 Yield

Conditions & References in not given Lenher, V.; Kao, C. H.; Journal of the American Chemical Society; vol. 48; (1926); p. 1554 - 1554 View in Reaxys Lenher, V.; Kao, C. H.; Journal of the American Chemical Society; vol. 48; (1926); p. 1552 View in Reaxys vol. Se: MVol.B; 56, page 124 - 126 ; (from Gmelin) View in Reaxys

Se2Sn

Sn ClCl

Rx-ID: 26444147 View in Reaxys 198/267 Yield

Conditions & References in neat (no solvent) Lenher, W.; Kao, C. H.; Journal of the American Chemical Society; vol. 48; (1926); p. 1550 - 1556 View in Reaxys vol. Sn: MVol.C2; 10.4.7, page 121 - 121 ; (from Gmelin) View in Reaxys Cl

Sn( 2+)

Sn ClCl

Rx-ID: 26530436 View in Reaxys 199/267 Yield

Conditions & References With sulfur, colloid S produced by boiling Na2S3O3, K2S2 or (NH4)2S2 in strong HCl soln. Komaretzky, S.; Zeitschrift fuer Analytische Chemie; vol. 69; (1926); p. 257 - 260 ; (from Gmelin) View in Reaxys With S vol. Sn: MVol.B; 16.1.5.6, page 400 - 400 ; (from Gmelin) View in Reaxys

Se O

Sn ClCl

Se Cl

Rx-ID: 26139868 View in Reaxys 200/267 Yield

Conditions & References cold SeOCl2 Ray, W. A.; Journal of the American Chemical Society; vol. 45; (1923); p. 2090 - 2094 View in Reaxys vol. Sn: MVol.B; 14.4.4.2, page 359 - 359 ; (from Gmelin) View in Reaxys

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Se O

Sn ClCl

Rx-ID: 26139869 View in Reaxys 201/267 Yield

Conditions & References in neat (no solvent), solution of Sn in SeOCl2; Ray, W. A.; Journal of the American Chemical Society; vol. 45; (1923); p. 2090 - 2094 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. Se: MVol.B; 63, page 140 - 142 ; (from Gmelin) View in Reaxys

Sn F

Cl Cl

Sn ClCl

Rx-ID: 26455625 View in Reaxys 202/267 Yield

Conditions & References in neat (no solvent), byproducts: PF3; reaction with PCl3 under formation of SnCl4 and PF3; Furman, N. H.; Journal of the American Chemical Society; vol. 40; (1918); p. 906 - 914 View in Reaxys vol. Sn: MVol.C1; 5.6.6, page 176 - 177 View in Reaxys Wolter, L.; Chemiker-Zeitung; vol. 36; (1912); p. 165 - 165 ; (from Gmelin) View in Reaxys

Sn F

Cl P Cl

Sn ClCl

Rx-ID: 26460745 View in Reaxys 203/267 Yield

Conditions & References in neat (no solvent), byproducts: POF3; reaction with POCl3 under formation of SnCl4 and POF3; Furman, N. H.; Journal of the American Chemical Society; vol. 40; (1918); p. 906 - 914 View in Reaxys vol. Sn: MVol.C1; 5.6.6, page 176 - 177 View in Reaxys Wolter, L.; Chemiker-Zeitung; vol. 36; (1912); p. 165 - 165 ; (from Gmelin) View in Reaxys

F Cl

Sn F

PCl Cl

Sn Cl ClCl

Rx-ID: 26460748 View in Reaxys 204/267 Yield

Conditions & References in neat (no solvent), byproducts: PF5; reaction with PCl5 under formation of SnCl4 and PF5; Furman, N. H.; Journal of the American Chemical Society; vol. 40; (1918); p. 906 - 914 View in Reaxys vol. Sn: MVol.C1; 5.6.6, page 176 - 177 View in Reaxys Wolter, L.; Chemiker-Zeitung; vol. 36; (1912); p. 165 - 165 ; (from Gmelin) View in Reaxys Cl

Cl 2Sn

Cl 2Hg 2

Sn ClCl

Rx-ID: 26185645 View in Reaxys 205/267 Yield

Conditions & References With mercury dichloride in ethyl acetate

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Naumann, A.; Hamers, M.; Henninger, E.; Ber. Dtsch. Chem. Ges.; vol. 43; (1910); p. 313 - 321 View in Reaxys Naumann, A.; Ber. Dtsch. Chem. Ges.; vol. 32; (1899); p. 999 - 1004 View in Reaxys Naumann, A.; Ber. Dtsch. Chem. Ges.; vol. 37; (1904); p. 3600 - 3605 View in Reaxys Alexander, E.; Diss. Giessen 1899, S. 7 View in Reaxys Alexander, E.; Diss. Giessen 1899, S. 9 ; (from Gmelin) View in Reaxys With mercury dichloride in water Linhart, G. A.; Adams, E. Q.; Journal of the American Chemical Society; vol. 39; (1917); p. 948 - 950 View in Reaxys vol. Hg: MVol.B2; 76, page 556 - 558 ; (from Gmelin) View in Reaxys With HgCl2 in ethyl acetate vol. Hg: MVol.B2; 113, page 635 - 637 ; (from Gmelin) View in Reaxys O

2 Cl

Sn ClCl

Rx-ID: 8240709 View in Reaxys 206/267 Yield

Conditions & References Zonew; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 48; (1916); p. 567; Chem. Zentralbl.; vol. 94; nb. I; (1923); p. 1497 View in Reaxys O

2 Cl

Sn ClCl

Rx-ID: 8240710 View in Reaxys 207/267 Yield

Conditions & References bei hoeherer Temperatur Zonew; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 48; (1916); p. 567; Chem. Zentralbl.; vol. 94; nb. I; (1923); p. 1497 View in Reaxys O

Sn Cl ClCl

di-g-pentyl ether

Sn Cl ClCl

Rx-ID: 8274597 View in Reaxys 208/267 Yield

Conditions & References bei der Destillation Zonew; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 48; (1916); p. 567; Chem. Zentralbl.; vol. 94; nb. I; (1923); p. 1497 View in Reaxys

Cl Cl SbCl Cl Cl

Br Sn Br BrBr

Cl Sb Cl

Sn ClCl

Rx-ID: 26167060 View in Reaxys 209/267 Yield

Conditions & References byproducts: Br2; heating

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Moles, E.; Z. phys. Ch.; vol. 90; (1915); p. 83 ; (from Gmelin) View in Reaxys vol. Sb: MVol.B2; 9.6, page 443 - 447 ; (from Gmelin) View in Reaxys Cl Cl SbCl Cl TB-5 Cl

Br Br

Sn BrBr

Sn ClCl

Rx-ID: 26167684 View in Reaxys 210/267 Yield

Conditions & References in neat (no solvent), byproducts: SbCl3, Br2; dissolution of SnBr4 in excess molten SBCl5 gives SnCl4, SbCl3, and Br2 when moderately heated; Moles, E.; Z. Physik. Chem.; vol. 90; (1915); p. 70 - 88 ; (from Gmelin) View in Reaxys in neat (no solvent), byproducts: SbCl3, Br2; dissolution of SnBr4 in excess molten SBCl5 gives SnCl4, SbCl3, and Br2 when moderately heated; vol. Sn: MVol.C1; 7.7.7.8.5, page 410 - 411 ; (from Gmelin) View in Reaxys Cl

S2Sn

Cl 2Sn

Sn ClCl

Rx-ID: 26185647 View in Reaxys 211/267 Yield

Conditions & References With sulfur dioxide in hydrogenchloride Pelletier, B.; Annales de Chimie (Cachan, France); vol. 12; p. 225 - 240 ; (from Gmelin) View in Reaxys With sulfur in water, boiling with S forms SnS2 and SnCl4; Hoenig, Alfred; Zeitschrift fuer Analytische Chemie; vol. 54; nb. 9; (1915); p. 441 - 457 View in Reaxys Vortmann, G.; Padberg, C.; Ber. Dtsch. Chem. Ges.; vol. 22; (1889); p. 2642 - 2644 View in Reaxys vol. Sn: MVol.C1; 6.6.8.5, page 234 - 235 ; (from Gmelin) View in Reaxys With sulfur in water, boiling; no formed SnS2 in presence of free acids (may formed from SnCl4) Vortmann, G.; Padberg, C.; Ber.; vol. 22; (1889); p. 2642 - 2644 View in Reaxys vol. S: MVol.A3; 5.3.4, page 713 - 718 ; (from Gmelin) View in Reaxys With SO2 in hydrogenchloride vol. S: MVol.B2; 1.6.5, page 552 - 562 ; (from Gmelin) View in Reaxys

(v4)

Cl 2Sn

Cl Sn Cl ClCl

Rx-ID: 26070132 View in Reaxys 212/267 Yield

Conditions & References With hydrogenchloride, oxygen in not given, redn. of O3 by SnCl2 in a HCl-containing soln. by shaking in a O2-O3 mixture for a period of 90 min.; Yamauchi, Y.; American Chemical Journal; vol. 49; (1913); p. 55 - 68 View in Reaxys

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vol. O: MVol.4; 89, page 1178 - 1180 ; (from Gmelin) View in Reaxys O– Ba2+ O

Cl O

Cl 2Sn

Sn Cl ClCl

O–

O2Sn

Rx-ID: 26183493 View in Reaxys 213/267 Yield

Conditions & References in neat (no solvent), byproducts: BaSO3; the SnCl2-melt reduces BaSO4 to BaSO3 under formation of SnCl4 and SnO2; Sandonnini, C.; Aureggi, P. C.; Gazzetta Chimica Italiana; vol. 42; nb. I; (1912); p. 227 - 233 View in Reaxys vol. Sn: MVol.C1; 6.3.9.7, page 219 - 221 ; (from Gmelin) View in Reaxys

Cl O2Sn

Sn Cl ClCl

Rx-ID: 26146668 View in Reaxys 214/267 Yield

Conditions & References in neat (no solvent), passing stream of COCl2 over SnO2 at 400 °C; Chauvenet, E.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 152; (1911); p. 87 View in Reaxys vol. Cl: MVol.; 65, page 183 - 186 ; (from Gmelin) View in Reaxys Cl

OSn

Cl Cl

Sn ClCl

Rx-ID: 26104129 View in Reaxys 215/267 Yield

Conditions & References in tetrachloromethane, formation by reaction of SnO and Cl2 dissolved in CCl4 at room temperature under inflammation; Michael, A.; Murphy, A.; American Chemical Journal; vol. 44; (1910); p. 365 - 384 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys Cl

OSn

Sn ClCl

Rx-ID: 26400948 View in Reaxys 216/267 Yield

Conditions & References With chlorine in tetrachloromethane, byproducts: Sn-oxide; at usual temps.; Michael; Murphy; American Chemical Journal; vol. 44; (1910); p. 376 - 376 View in Reaxys vol. Cl: MVol.; 22, page 74 - 77 ; (from Gmelin) View in Reaxys

3 Cl Cl

Sn ClCl

H O

Sn ClCl

Rx-ID: 26416378 View in Reaxys 217/267 Yield

Conditions & References in water, byproducts: H2O; formation of two lyers at heating above 83°C of SnCl4-satd. H2O and with H2O-satd. SnCl4;

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Meyerhoffer, W.; Bull. Soc. Chim. France (3); vol. 6; (1891); p. 85 - 86 View in Reaxys vol. Sn: MVol.C1; 6.10.1, page 313 - 313 ; (from Gmelin) View in Reaxys in melt, byproducts: H2O; dissociation in SnCl4 and H2O at 66-111°C; Smirnoff, W.; Z. Physik. Chem.; vol. 58; (1907); p. 373 - 380 View in Reaxys Smirnoff, W.; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 38; (1906); p. 1172 - 1172; C. A.; (1907); p. 1220 View in Reaxys vol. Sn: MVol.C1; 6.10.1, page 313 - 313 ; (from Gmelin) View in Reaxys H

Cl Cl

Sn ClCl

Rx-ID: 26507286 View in Reaxys 218/267 Yield

Conditions & References in melt, byproducts: H2O; dissociation in SnCl4 and H2O at 66-111°C; Smirnoff, W.; Z. Physik. Chem.; vol. 58; (1907); p. 373 - 380 View in Reaxys Smirnoff, W.; Zhurnal Russkago Fiziko-Khimicheskago Obshchestva; vol. 38; (1906); p. 1172 - 1172; C. A.; (1907); p. 1220 View in Reaxys vol. Sn: MVol.C1; 6.10.1, page 313 - 313 ; (from Gmelin) View in Reaxys

Si Cl H

Si FH

Sn F

Cl Sn ClCl

Rx-ID: 26455200 View in Reaxys 219/267 Yield

Conditions & References in neat (no solvent), byproducts: SnCl4; heating of the mixture in a bomb tube at 220 °C for a period of 1 day; vol. Si: MVol.B; 258, page 701 - 703 View in Reaxys Ruff, O.; Albert, C.; Ber.; vol. 38; (1905); p. 53 - 64 ; (from Gmelin) View in Reaxys O

O N O

Cl Cl 2Sn

N O

Sn ClCl

Rx-ID: 26472377 View in Reaxys 220/267 Yield

Conditions & References With hydrogenchloride, byproducts: H2O Raschig, F.; Angewandte Chemie; vol. 18; (1905); p. 1300 View in Reaxys vol. N: MVol.4; 6.5, page 915 - 929 ; (from Gmelin) View in Reaxys O

O S

tin

Sn Cl ClCl

SO2 Rx-ID: 7086615 View in Reaxys 221/267

Yield

Conditions & References T= 130 °C Willcox; American Chemical Journal; vol. 32; (1904); p. 468

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View in Reaxys Cl

S Cl

S2Sn

Sn ClCl

Rx-ID: 26472648 View in Reaxys 222/267 Yield

Conditions & References in sulfuryl dichloride, solubilization process; Ruff, O.; Ber. Dtsch. Chem. Ges.; vol. 34; (1901); p. 1749 - 1758 View in Reaxys vol. Sn: MVol.C2; 9.7.7.10, page 55 - 55 ; (from Gmelin) View in Reaxys Cl

S2Sn

Sn Cl ClCl

Rx-ID: 26171974 View in Reaxys 223/267 Yield

Conditions & References in neat (no solvent), formation by passing HCl gas over SnS2; vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 View in Reaxys Kelley, J.; Smith, E. F.; Journal of the American Chemical Society; vol. 18; (1896); p. 1096 - 1098 ; (from Gmelin) View in Reaxys in gas, reaction in a HCl vapor stream; Kelley, J.; Smith, E. F.; Journal of the American Chemical Society; vol. 18; (1896); p. 1096 - 1098 View in Reaxys vol. Sn: MVol.C2; 9.7.7.10, page 55 - 55 ; (from Gmelin) View in Reaxys Cl

Cl 2Sn

Sn Cl ClCl

Rx-ID: 26139931 View in Reaxys 224/267 Yield

Conditions & References in neat (no solvent), passing over Cl2 over warmed Sn;; product mixture obtained; Lorenz, R.; Z. Anorg. Chem.; vol. 10; (1895); p. 44 - 44 ; (from Gmelin) View in Reaxys in neat (no solvent), passing over Cl2 over warmed Sn;; product mixture obtained; vol. Cl: MVol.; 21, page 71 - 74 ; (from Gmelin) View in Reaxys

Cl Cl

Si Cl Cl

Cl O2Sn

Sn ClCl

Rx-ID: 26161890 View in Reaxys 225/267 Yield

Conditions & References in neat (no solvent), formation by reaction of SnO2 with SiCl4 on heating for 40 h at 350-360°C; Rauter, G.; Liebigs Annalen der Chemie; vol. 270; (1892); p. 235 - 266 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys

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Cl N

Cl 2Sn

Sn ClCl

Rx-ID: 26113657 View in Reaxys 226/267 Yield

Conditions & References With hydrogenchloride, byproducts: H2O; a mixt. of 5 parts cryst. SnCl2, 10 parts aq. HCl (D=1.21) and 0.9 parts aq. HNO3 (D=1.38) is heated; after a first vigorous evolution of gas N2O forms in a steady reaction; Ratio of components must be carefully checked, danger of explosion; Campari, G.; Ann. Chim. Farmacol. {4}; vol. 8; (1888); p. 253 View in Reaxys vol. N: MVol.3; 1.1.2, page 512 - 515 ; (from Gmelin) View in Reaxys Cl

S2Sn

ClCu

Cu 2S

Sn ClCl

Rx-ID: 26397936 View in Reaxys 227/267 Yield

Conditions & References in not given, uncomplete reaction of SnS2 in a CuCl soln.; vol. Sn: MVol.C2; 9.7.7.9, page 54 - 54 ; (from Gmelin) View in Reaxys in not given, uncomplete reaction of SnS2 in a CuCl soln.; Raschig, F.; Liebigs Annalen der Chemie; vol. 228; (1885); p. 1 - 29 ; (from Gmelin) View in Reaxys

H Cl 2Sn

NH 2

Cl Cl

Sn ClCl

Rx-ID: 26436344 View in Reaxys 228/267 Yield

Conditions & References

90 %, <1

With hydrogenchloride in hydrogenchloride, byproducts: C2H5OH, H2O; in concd. HCl soln.; evapn. of the alcohol,diluting with water,pptg. of the Sn with H2S,evapn. and crystn. from alcohol Divers, E.; Haga, T.; Journal of the Chemical Society; vol. 47; (1885); p. 626 View in Reaxys Dumreicher, O. v.; Monatshefte fuer Chemie; vol. 1; (1880); p. 743 View in Reaxys vol. N: MVol.4; 2.1, page 857 - 866 ; (from Gmelin) View in Reaxys

Cl Cl 2Sn

H 2N

Sn ClCl

Rx-ID: 26436345 View in Reaxys 229/267 Yield

Conditions & References With hydrogenchloride, byproducts: ethanol, H2O Divers, E.; Haga, T.; Journal of the Chemical Society; vol. 47; (1885); p. 626 View in Reaxys Dumreicher, O. v.; Monatshefte fuer Chemie; vol. 1; (1880); p. 743 View in Reaxys vol. N: MVol.4; 2.1, page 857 - 866 ; (from Gmelin) View in Reaxys Cl

SSn

Cl 2Cu

Cu 2S

Sn ClCl

Rx-ID: 26506445 View in Reaxys 230/267

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Yield

Conditions & References in not given, reaction at heating of a diluted CuCl2 soln.; vol. Sn: MVol.C2; 9.3.9.10, page 34 - 35 ; (from Gmelin) View in Reaxys in not given, reaction at heating of a diluted CuCl2 soln.; Raschig, F.; Liebigs Annalen der Chemie; vol. 228; (1885); p. 1 - 29 ; (from Gmelin) View in Reaxys Cl

S2Sn

CuS

Cl 2Cu

Sn ClCl

Rx-ID: 26540583 View in Reaxys 231/267 Yield

Conditions & References in not given, complete reaction of SnS2 in a warm CuCl2 soln.; vol. Sn: MVol.C2; 9.7.7.9, page 54 - 54 ; (from Gmelin) View in Reaxys in not given, complete reaction of SnS2 in a warm CuCl2 soln.; Raschig, F.; Liebigs Annalen der Chemie; vol. 228; (1885); p. 1 - 29 ; (from Gmelin) View in Reaxys Cl

S Cl

Sn ClCl

Rx-ID: 26139850 View in Reaxys 232/267 Yield

Conditions & References in neat (no solvent) Koechlin, P.; Heumann, K.; Ber.; vol. 15; (1882); p. 1736 - 1738 View in Reaxys vol. S: MVol.B3; 135, page 1815 - 1817 ; (from Gmelin) View in Reaxys Koechlin, P.; Heumann, K.; Ber. Dtsch. Chem. Ges.; vol. 15; (1882); p. 1736 - 1738 View in Reaxys vol. Sn: MVol.B; 14.4.4.1, page 358 - 359 ; (from Gmelin) View in Reaxys in neat (no solvent), slow formation by reaction of Sn with SO2Cl2; Koechlin, P.; Heumann, K.; Ber. Dtsch. Chem. Ges.; vol. 15; (1882); p. 1736 - 1738 View in Reaxys vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 ; (from Gmelin) View in Reaxys

Cl O

S OH O

OH Sn

S OO

Cl Sn Cl ClCl

Rx-ID: 26139937 View in Reaxys 233/267 Yield

Conditions & References byproducts: SO2; cold (without heating) Heumann, K.; Koechlin, P.; Ber. Dtsch. Chem. Ges.; vol. 15; (1882); p. 416 - 420 ; (from Gmelin) View in Reaxys vol. Sn: MVol.B; 14.7.9, page 371 - 375 ; (from Gmelin) View in Reaxys

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Cl O

Cl Sn

S OH O

Sn ClCl

Rx-ID: 26139938 View in Reaxys 234/267 Yield

Conditions & References in neat (no solvent), formation by reaction of Sn with HSO3Cl at low temperature; Heumann, K.; Koechlin, P.; Ber. Dtsch. Chem. Ges.; vol. 15; (1882); p. 416 - 420 View in Reaxys vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 ; (from Gmelin) View in Reaxys Cl

Cl 2Sn

Sn ClCl

Rx-ID: 26185620 View in Reaxys 235/267 Yield

Conditions & References With sulfur dioxide in water, boiling SnCl2 soln.; Guyard, A.; Monit. sci. (3); vol. 12; (1882); p. 783 - 784 ; (from Gmelin) View in Reaxys With SO2 in water, boiling SnCl2 soln.; vol. S: MVol.B2; 1.6.5, page 552 - 562 ; (from Gmelin) View in Reaxys

Cl O

OH Sn

S OH O

S OO

Cl Cl

Sn ClCl

Rx-ID: 26433825 View in Reaxys 236/267 Yield

Conditions & References in neat (no solvent) Heumann, K.; Koechlin, P.; Ber.; vol. 15; (1882); p. 416 - 420 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. S: MVol.B3; 146, page 1839 - 1840 ; (from Gmelin) View in Reaxys Cl

PCl Cl Cl

Cl Cl

Sn ClCl

Rx-ID: 26139874 View in Reaxys 237/267 Yield

Conditions & References in neat (no solvent), react. with Sn on heating; Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys Goldschmidt, H.; Chem. Centralbl. Repertorium (3); vol. 12; (1881); p. 489 - 495 View in Reaxys vol. Sn: MVol.B; 14.4.8, page 360 - 360 ; (from Gmelin) View in Reaxys in neat (no solvent), heating PCl5 with Sn at 200-250 °C; Goldschmidt, H.; C.; (1881); p. 489 - 495 View in Reaxys

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vol. P: MVol.C; 193, page 443 - 445 ; (from Gmelin) View in Reaxys Cl Cl

PCl Cl

Sn ClCl

Rx-ID: 26139877 View in Reaxys 238/267 Yield

Conditions & References

>99

in neat (no solvent), formation by reaction of PCl5 with huge excess of Sn; Goldschmidt, H.; Chem. Centralbl. Repertorium (3); vol. 12; (1881); p. 489 - 495 View in Reaxys vol. Sn: MVol.C1; 6.9.1.2, page 253 - 253 ; (from Gmelin) View in Reaxys

O Sn

Cl P

Sn ClCl

Rx-ID: 26139852 View in Reaxys 239/267 Yield

Conditions & References 100°C Goldschmidt, H.; Chem. Centralbl. Repertorium (4); vol. 2; (1864); p. 492 View in Reaxys Reinitzer, B.; Goldschmidt, H.; Sitz.-Ber. Akad. Wiss. Wien Math.-Naturw. KI. II; vol. 81; (1880); p. 820 - 836 View in Reaxys vol. Sn: MVol.B; 14.4.8, page 360 - 360 ; (from Gmelin) View in Reaxys Cl

O N

Cl 2Sn

Sn ClCl

Rx-ID: 26185674 View in Reaxys 240/267 Yield

Conditions & References With hydrogenchloride, byproducts: H2O Dumreicher, O. v.; Ber. Wien. Akad.; vol. 82, II; (1880); p. 566 View in Reaxys vol. N: MVol.3; 1.1.1, page 508 - 511 ; (from Gmelin) View in Reaxys With hydrogenchloride in not given, byproducts: H2O; in concd. or very dild. soln. Dumreicher, O. v.; Ber. Wien. Akad.; vol. 82 II; (1880); p. 560 View in Reaxys vol. N: MVol.4; 6.5, page 915 - 929 ; (from Gmelin) View in Reaxys H

H 2N

Cl 2Sn

Cl Cl

Sn ClCl

Rx-ID: 26516734 View in Reaxys 241/267 Yield

Conditions & References With hydrogenchloride in further solvent(s), byproducts: water; in HCl soln. Dumreicher, O. v.; Monatshefte fuer Chemie; vol. 1; (1880); p. 727 View in Reaxys Dumreicher, O. v.; Monatshefte fuer Chemie; vol. 1; (1880); p. 729 ; (from Gmelin) View in Reaxys With HCl in further solvent(s), byproducts: water; in HCl soln. vol. NH4: MVol.2; 14, page 569 - 586 ; (from Gmelin)

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View in Reaxys Cl O2Sn

O5P2

Sn ClCl

Cl 2Sn

Rx-ID: 26150755 View in Reaxys 242/267 Yield

Conditions & References in neat (no solvent), heating at 160 °C for 2 days; Michaelis, A.; Jena. Z. Med. Naturwiss.; vol. 7; (1873); p. 110 - 117 View in Reaxys Michaelis, A.; J. prakt. Chem. (2); vol. 4; (1871); p. 449 - 457 ; (from Gmelin) View in Reaxys in neat (no solvent), heating at 160 °C for 2 days; vol. P: MVol.C; 185, page 427 - 429 ; (from Gmelin) View in Reaxys Cl

O2Sn

Cl Cl

Sn ClCl

Rx-ID: 26150756 View in Reaxys 243/267 Yield

Conditions & References in neat (no solvent), formation by reaction of PCl3 with SnO2 at 160°C; Michaelis, A.; J. Prakt. Chem. (2); vol. 4; (1871); p. 449 - 457 View in Reaxys vol. Sn: MVol.C1; 6.9.1.4, page 254 - 254 ; (from Gmelin) View in Reaxys

2 Ca 2+ Cl 2 O– 2 Cl –

Cl Cl

Sn ClCl

Rx-ID: 26613127 View in Reaxys 244/267 Yield

Conditions & References With hydrogenchloride, tin(ll) chloride in not given, byproducts: CaCl2, H2O Herreshoff; Am. Chem.; vol. 1; (1871); p. 279 - 279 View in Reaxys Herreshoff; Chem. News J. Ind. Sci.; vol. 23; (1871); p. 293 - 293 ; (from Gmelin) View in Reaxys With HCl, SnCl2 in not given, byproducts: CaCl2, H2O vol. Cl: MVol.; 97, page 262 - 264 ; (from Gmelin) View in Reaxys Cl

Bi(3+)

Cl 2Sn

Bi2S3

Sn ClCl

Rx-ID: 26114388 View in Reaxys 245/267 Yield

Conditions & References With sulfur dioxide Fedorow, N.; Z. Ch. (2); vol. 5; (1869); p. 15 - 17 ; (from Gmelin) View in Reaxys With SO2 vol. S: MVol.B2; 1.6.5, page 552 - 562 ; (from Gmelin) View in Reaxys

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As( 3+)

Cl 2Sn

As 2S3

Sn ClCl

Rx-ID: 26175045 View in Reaxys 246/267 Yield

Sb( 3+)

Cl 2Sn

S3Sb2

Sn ClCl

Rx-ID: 26175057 View in Reaxys 247/267 Yield

Cu( 2+)

Cl 2Sn

CuS

Sn ClCl

Rx-ID: 26180833 View in Reaxys 248/267 Yield

Pt(4+)

Cl 2Sn

Sn Cl ClCl

PtS2

Rx-ID: 26181743 View in Reaxys 249/267 Yield

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Cl 22+ Cl SnCl Cl Co Cl

Sn Cl ClCl

Rx-ID: 26150353 View in Reaxys 250/267 Yield

Conditions & References in neat (no solvent), decompn. below 100°C; evolution of H2O and tin chloride; Joergensen, S. M.; K. Dan. Vidensk. Selsk. Skr., Naturwidensk. Math. Afd.; vol. 6; (1867); p. 454 - 454 View in Reaxys vol. Co: MVol.A2; 112, page 473 - 475 ; (from Gmelin) View in Reaxys Cl

PCl Cl

S2Sn

P Cl

P2S5

Sn ClCl

Rx-ID: 26486146 View in Reaxys 251/267 Yield

Conditions & References in neat (no solvent) Baudrimont, E.; Ann. Chim. Phys.; vol. 2; (1864); p. 5 - 67 View in Reaxys vol. Sn: MVol.C2; 9.7.7.10, page 55 - 55 ; (from Gmelin) View in Reaxys Cl

OSn

O2Sn

Sn ClCl

Rx-ID: 26400949 View in Reaxys 252/267 Yield

Conditions & References With chlorine in neat (no solvent), heating in a stream of Cl2;; SnCl4 distills off; Weber, R.; Annalen der Physik (Weinheim, Germany); vol. 112; (1861); p. 621 View in Reaxys vol. Cl: MVol.; 22, page 74 - 77 ; (from Gmelin) View in Reaxys

H O

O–

2 –

P OH O O–

Cl 5

O5P2

Sn2+

Sn ClCl

P – (v0) OO

Rx-ID: 26171615 View in Reaxys 253/267 Yield

Conditions & References in neat (no solvent), calcinating; Lensen, E.; Liebigs Annalen der Chemie; vol. 114; (1860); p. 113 - 118 View in Reaxys Lenssen, E.; Journal fuer Praktische Chemie (Leipzig); vol. 80; (1860); p. 447 - 448 View in Reaxys vol. Sn: MVol.C2; 16.8.7, page 248 - 248 ; (from Gmelin) View in Reaxys

O O

(v6)

O O

K+

O–

Cl Cr

Cl 2Sn

(v3)

Sn Cl ClCl

Rx-ID: 26183908 View in Reaxys 254/267

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Yield

Conditions & References With hydrogenchloride, byproducts: KCl, H2O Scheurer-Kestner, A.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 50; (1860); p. 50 - 52 ; (from Gmelin) View in Reaxys With HCl, byproducts: KCl, H2O Penny, F.; Journal of the Chemical Society; vol. 4; (1851); p. 239 - 251 View in Reaxys vol. Cr: MVol.A2; 7.5, page 680 - 710 ; (from Gmelin) View in Reaxys H

Sn Cl ClCl

O2Sn

Sn ClCl

Rx-ID: 26416379 View in Reaxys 255/267 Yield

Conditions & References in neat (no solvent), byproducts: H2O, HCl; decomposition at heating under formation of SnO2, H2O, HCl and SnCl4; vol. Sn: MVol.C1; 6.10.7, page 316 - 317 View in Reaxys Casselmann, W.; Liebigs Annalen der Chemie; vol. 83; (1852); p. 257 - 275 ; (from Gmelin) View in Reaxys Cl

2 Cl

S ClCl

Sn ClCl

Cl Cl

Sn ClCl

Rx-ID: 26594274 View in Reaxys 256/267 Yield

Conditions & References in neat (no solvent), decompn. at about 40 °C; Casselmann, W.; Liebigs Annalen der Chemie; vol. 83; (1852); p. 257 - 275 View in Reaxys vol. Sn: MVol.C2; 9.27.2, page 75 - 75 ; (from Gmelin) View in Reaxys

2 Cl

S ClCl

Sn Cl ClCl

O S

S HO

S OO

Sn Cl ClCl

Rx-ID: 26594276 View in Reaxys 257/267 Yield

Conditions & References With water in water, decompn. in water; Casselmann, W.; Liebigs Annalen der Chemie; vol. 83; (1852); p. 257 - 275 View in Reaxys Rose, H.; Ann. Physik Chem. (2); vol. 42; (1837); p. 517 - 546 View in Reaxys vol. Sn: MVol.C2; 9.27.2, page 75 - 75 ; (from Gmelin) View in Reaxys 1

H Cl –

(v4)

N HH

O2Sn

Sn Cl ClCl

Rx-ID: 26062698 View in Reaxys 258/267 Yield

Conditions & References in neat (no solvent), calcination of SnO2 and NH4Cl; Rose, H.; Annalen der Physik (Weinheim, Germany); vol. 73; (1848); p. 582 - 582

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View in Reaxys Rose, H.; Annalen der Physik (Weinheim, Germany); vol. 74; (1849); p. 562 - 562 View in Reaxys vol. Cl: MVol.; 65, page 183 - 186 ; (from Gmelin) View in Reaxys O

Cl Cl

Sn ClCl

Rx-ID: 26414993 View in Reaxys 259/267 Yield

Conditions & References With Sn(OH)2 in water, byproducts: Sn(OH)4, HClO4; dissolving Sn(OH)2 in H2O; reaction after some minutes with detonation and generation of warmth; Waechter, A.; Journal fuer Praktische Chemie (Leipzig); vol. 30; (1843); p. 321 - 321 ; (from Gmelin) View in Reaxys With Sn(OH)2 in water, byproducts: Sn(OH)4, HClO4; dissolving Sn(OH)2 in H2O; reaction after some minutes with detonation and generation of warmth; vol. Cl: MVol.; 134, page 348 - 351 ; (from Gmelin) View in Reaxys O

OH Cl

H 2O2Sn

Cl OO

Sn OH OH

Sn ClCl

Rx-ID: 26415028 View in Reaxys 260/267 Yield

Conditions & References in not given, detonation; Waechter, A.; Journal fuer Praktische Chemie (Leipzig); vol. 30; (1843); p. 321 - 321 View in Reaxys vol. Cl: MVol.; 123, page 326 - 328 ; (from Gmelin) View in Reaxys

H O

Cl 2 Na + Cl 2Cl SnCl Cl Cl Cl

ClNa

Sn Cl ClCl

Rx-ID: 26606299 View in Reaxys 261/267 Yield

Conditions & References byproducts: H2O; at 100°C Bolley, P. A.; Liebigs Annalen der Chemie; vol. 39; (1841); p. 100 - 106 View in Reaxys vol. Sn: MVol.C3; 21.14.1, page 24 - 24 ; (from Gmelin) View in Reaxys Cl

Cl 2Sn

S2Sn

Sn Cl ClCl

Rx-ID: 26185621 View in Reaxys 262/267 Yield <1

Conditions & References With sulfur dioxide Hering, E.; Liebigs Annalen der Chemie; vol. 29; (1839); p. 90 - 93 ; (from Gmelin) View in Reaxys

With SO2 vol. S: MVol.B2; 1.6.5, page 552 - 562 ; (from Gmelin)

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View in Reaxys O–

O– S

Sn4+

ClNa

Sn ClCl

Rx-ID: 26099982 View in Reaxys 263/267 Yield

Conditions & References in neat (no solvent), formation by heating Sn(SO4)2 with NaCl; Kraskowitz, J. v.; Ann. Physik Chem. (2); vol. 35; (1835); p. 517 - 519 View in Reaxys Kraskowitz, J. v.; Liebigs Annalen der Chemie; vol. 16; (1835); p. 195 - 197 View in Reaxys vol. Sn: MVol.C1; 6.9.1.5, page 254 - 254 ; (from Gmelin) View in Reaxys Cl

Cl 2Hg

Cl 2Sn

Sn ClCl

Rx-ID: 26185665 View in Reaxys 264/267 Yield

Conditions & References in neat (no solvent), formation by heating solid SnCl2 with HgCl2; Davy, J.; Philosophical Transactions of the Royal Society of London; (1812); p. 169 - 204 View in Reaxys vol. Sn: MVol.C1; 6.9.1.3, page 253 - 254 ; (from Gmelin) View in Reaxys

F F

F Sn

PCl Cl

P FF TB-5

Cl Cl

Sn ClCl

Rx-ID: 26153836 View in Reaxys 265/267 Yield

Conditions & References in neat (no solvent), heating with Sn-fluoride in a sealing tube; Wolter, L.; Diss. Berlin 1908, S. 1/55 ; (from Gmelin) View in Reaxys in neat (no solvent), heating with Sn-fluoride in a sealing tube; vol. P: MVol.C; 194, page 445 - 447 ; (from Gmelin) View in Reaxys

Cl 2Sn

(v2) (v2)

Cl Hg Hg Cl

Sn ClCl

Rx-ID: 26185644 View in Reaxys 266/267 Yield

Conditions & References With mercury dichloride in acetone, excess of HgCl2; Eidmann, W.; Diss. Giessen 1899, S. 40 ; (from Gmelin) View in Reaxys With HgCl2 in acetone, excess of HgCl2; vol. Hg: MVol.B2; 109, page 625 - 628 ; (from Gmelin) View in Reaxys

79/80

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Cl Cl

Sn ClCl

Cl Cl

PCl Cl

Sn Cl ClCl

Rx-ID: 26455857 View in Reaxys 267/267 Yield

Conditions & References in neat (no solvent), at 400°C; vol. Sn: MVol.C2; 16.16.1, page 259 - 260 View in Reaxys Groeneveld, W. L.; Diss. Leiden 1953, S. 58/61 ; (from Gmelin) View in Reaxys

80/80

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