Tetrachlorostannane [Tin(IV) chloride] [SnCl4 or Cl4Sn] by Asch

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With indium in neat (no solvent) T=80°C; 0.116667 h; Inert atmosphereSonication; Hide Experimental Procedure

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Lo Fiego, Marcos J.; Badajoz, Mercedes A.; Domini, Claudia; Chopa, Alicia B.; Lockhart, Maria T.

Ultrasonics Sonochemistry, 2013 , vol. 20, # 3 p. 826 - 832 Title/Abstract Full Text View citing articles Show Details

Representative procedure for ultrasound assisted indium-mediated reactions. Synthesis of 1-(3-chlorophenyl)butanone (3fa; Table 2, entry 1)

General procedure: In a flame dried Schlenk tube (fitted with a Teflon plug valve) 1.2 mmol (0.127 g) of No.15 butanoyl chloride (2a) was added to a stirred mixture of 1.0 mmol (0.402 g) of No.16 tributyl(3-chlorophenyl)stannane (1f) and No.17 indium powder (0.148 g, 1.0 mmol) under a nitrogen gas stream. After purging the system with nitrogen by means of three pump-fill cycles, the tube was capped and immersed in a water–detergent bath at 60 °C. The ultrasonic titanium horn was placed into the bath to a distance of 10 mm to the wall and 5 mm from the bottom of the Schlenk tube and ultrasound was applied in a pulsed mode (duty cycle = 70percent; output power = 70percent) for 10 min. After addition of 10percent (m/v) solution of No.18 NaOH (2 mL) and 10 μL of No.19 tetradecane (internal standard), the mixture was stirred at room temperature for 15 min and then diluted with DCM (5 mL). Once the stirring was stopped for about 5 min, the supernatant liquid mixture was decanted into a separatory funnel. The silvery-white solid, settled at the bottom of the Schlenk tube, was washed with acetone (2 × 5 mL), deionized water (2 × 5 mL), and then vacuum-dried at room temperature. As indicated by DSC analysis, the dried sample (0.133 g) meant a 90percent recovered yield of pure No.20 indium. On the other hand, the organic phase was successively washed with water and brine, dried over Na2SO4, filtered, analyzed by GC, and then concentrated in vacuo. Purification by column chromatography on silica gel (60 Å, 70–230 mesh) doped with 10percent of KF (hexanes/DCM 8:2) gave 0.096 g (53percent) of 3fa as a colorless oil.

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With H2O2 in hydrogenchloride

SnCl2*2H2O dissolved in H2O; concd. HCl and H2O2 added; heated;

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Mamedova; Ragimov; Sadykhov; Aliev

Russian Journal of Inorganic Chemistry, 2012 , vol. 57, # 2 p. 160 - 162 Title/Abstract Full Text View citing articles Show Details

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With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran

50°C;

Cabon, Yves; Gebbink, Robertus J. M. Klein; Deelman, Berth-Jan

Dalton Transactions, 2011 , vol. 40, # 34 p. 8651 - 8655 Title/Abstract Full Text View citing articles Show Details

in tetrahydrofuran

50°C;

Cabon, Yves; Gebbink, Robertus J. M. Klein; Deelman, Berth-Jan

Dalton Transactions, 2011 , vol. 40, # 34 p. 8651 - 8655 Title/Abstract Full Text View citing articles Show Details

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With hydrogenchloride; tin(ll) chloride in water

T=90°C; 2 h; Hide Experimental Procedure

East China University of Science and Technology; Shanghai Institute of Materia Medica, Chinese Academy of Sciences; Dalian University of Technology

Patent: EP1626050 A1, 2006 ; Location in patent: Page/Page column 8 ; Title/Abstract Full Text Show Details

9.1:

(1)4-benzylsulhydryl-3-nitro-1,8-naphthalic anhydride 4-bromo-3-nitro-1,8-naphthalic anhydride (0.0072mol) (4) was dissolved in DMF (45ml) in 100 ml of three-neck flask. After addition of K2CO3 (0.0036mol) and benzyl sulfhydrate (0.0072mol), the solution was stirred at 80°C for 8h until there was no raw material. The reaction mixture was poured into ice-water, then salted out under stirring. A yellow solid precipitated after filtration and washing by water and dried to give khaki solid (2.47g, 83percent): mp 188-193°C (uncorrected). A

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in neat (no solvent) byproducts: butane, HCl; Sn compd. was sealed in vac. in NMR tube; heated at 200°C for 48 h; NMR monitoring; not isolated;

Davies, Alwyn G.; Sella, Andrea; Sivasubramaniam, Rajaveen

Journal of Organometallic Chemistry, 2006 , vol. 691, # 16 p. 3556 - 3561 Title/Abstract Full Text View citing articles Show Details

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Dunstan, Pedro Oliver

Thermochimica Acta, 2003 , vol. 398, # 1-2 p. 1 - 7 Title/Abstract Full Text View citing articles Show Details

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Dunstan, Pedro Oliver

Thermochimica Acta, 2003 , vol. 398, # 1-2 p. 1 - 7 Title/Abstract Full Text View citing articles Show Details

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Lion Bioscience AG

Patent: US6452009 B1, 2002 ; Title/Abstract Full Text Show Details

7:Tin Chloride Reduction

EXAMPLE 7 Tin Chloride Reduction The Tbags were placed in 2 L bottles (100 bags per 2L bottle). A 2 M solution of tin chloride dihydrate in DMF was prepared and added to the reaction bottles (1L per bottle) containing the T-bags. The reactions were shaken overnight for 24 hours. The Tbags were washed with DMF (6*, 500 mL), MeOH (3*, 500 mL), DMF (3*, 500 mL), 5percent DIEA/DCM (333, 500 mL), DCM (3*, 500 mL), and MeOH (3*, 500 mL). The Tbags were air dried overnight.

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Merck Patent Gesellschaft Mit Beschrankter Haftung

Patent: US5698205 A1, 1997 ; Title/Abstract Full Text Show Details

5:Stabilization with SnCl4

Example 5 Stabilization with SnCl4 A tin(IV) chloride solution (0.439 g of SnCl4 *5H2 O in 5 g of H2 O) is added at room temperature to 80 g of titanium dioxide sol prepared by electrolysis (10 g of TiO2) and the mixture is subsequently stirred for 1 hour. A citrate solution (7 g of trisodium citrate dihydrate in 10.5 g of H2 O) is then added, the mixture is subsequently stirred for 15 minutes and the pH is then brought to 6.7 with sodium hydroxide solution (w=32percent). 2.31 g (80.6% from 1a)

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University of Pittsburgh

Patent: US5777121 A1, 1998 ; Title/Abstract Full Text Show Details

14:14.

14. Representative Example of a Preparative Stille Coupling: A sealed tube under nitrogen was charged with tin reactant 1a (2.97 g, 2.40 mmol), 1-bromo-4-nitrobenzene (404 mg, 2.00 mmol), lithium chloride (254 mg, 6.00 mmol), dichlorobis(triphenylphosphine)palladium(II) (28.1 mg, 0.04 mmol), dry DMF (5 mL), and dry THF (5 mL). The mixture was heated to 80° C. and a homogeneous solution resulted. The mixture was stirred at 80° C. for 22 h. After azeotropic evaporation with toluene at 75° C. (to remove THF and some of the DMF), the resulting residue was partitioned between water (40 mL), dichloromethane (60 mL), and FC-72 (40 mL). The three phases were separated. Evaporation of the FC-72 phase provided 2.31 g (80.6percent from 1a) of tin chloride 8 as a colorless oil. The dichloromethane phase was washed three more times with water (40 mL) and FC-72 (40 mL). Evaporation of the combined FC-72 phases (including the first phase) provided 2.85 g (99.4percent from 1a) of tin chloride 8.

University of Pittsburgh

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Patent: US5777121 A1, 1998 ; Title/Abstract Full Text Show Details

15:15.

15. Representative Example of Recycle of Tin Reactants: The tin chloride 8 (2.85 g) isolated by evaporation of FC-72 phase after the above Stille coupling was treated with a 3M solution of phenyl magnesium bromide in ether (1.04 mL, 3.12 mmol) in dry ether (25 mL) under stirring at 25° C. for 6 h. The reaction mixture was hydrolyzed with NH4 Cl solution and diluted with ether, and the organic phase was washed with deionized water then dried over anhydrous MgSO4. The solvent was evaporated to dryness. Column chromatography on neutral alumina with hexane yielded pure compound la (2.85 g, 96percent overall from 1a in the preceding section) as a colorless oil.

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Baerns; Manfred

Patent: US4608449 A1, 1986 ; Title/Abstract Full Text Show Details

(e) Bi2 O3 --SnO2 (SnO2:Bi2 O3 =57:43) (e) Bi2 O3 --SnO2 (SnO2:Bi2 O3 =57:43) 19.4 g Bi(NO3)3.5H2 O were suspended in 300 ml water (with subsequent pH=0.5). Using concentrated NH3 (aq) titration was effected to pH=7 and then by simultaneous dripping of NH3 (aq) in 200 ml water, the dissolved SnCl4 (22.1 g) was precipitated at pH=7. The solids were filtered off and washed free of chloride. After 2 h drying at 120° C. calcination was carried out for 16 h at 700° C. in the water jet pump vacuum.

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The Dow Chemical Company

Patent: US4205015 A1, 1980 ; Title/Abstract Full Text Show Details

4:Dehydrohalogenation with SnCl4 /Alumina

EXAMPLE 4 Dehydrohalogenation with SnCl4 /Alumina A supported catalyst is prepared by slurrying 0.3 g. of SnCl4 and 3.0 g. of the alumina used in Example 2 in 10 ml. of CCl4 and then stirring the slurry at 70° C. for one hour. DCTCB is then dehydrohalogenated using this supported catalyst according to the procedure of Example 3. Analysis of the resulting dehydrohalogenated product shows that it contains 95.7 percent of DCTCS and 3.4 percent of the diene. A

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A: 13.5 g (83%)

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Atofina Vlissingen B.V.

Patent: EP1225177 A1, 2002 ; Title/Abstract Full Text Show Details

Preparation of BuSnCl3from Bu4Sn and SnCl4.

Preparation of BuSnCl3from Bu4Sn and SnCl4. In this typical procedure, SnCl4(11.15 g, 0.043 mol) was dissolved in toluene (10 mL). Next, Bu4Sn (4.96 g, 0.0143 mol) was added and reaction mixture was stirred for 2 h at 110°C. After cooling of the reaction mixture to room temperature, the catalyst PtCl2(PPh3)2(3.8 mg, 4.8 μmol) was added and the reaction mixture was stirred for another 12 h at 110°C. Filtration of the reaction mixture gave a slightly yellow solution which was analyzed by 119Sn NMR using SnMe4as external standard. After evaporation of volatiles invacuo, vacuum distillation (90°C/11 mmHg) afforded 13.5 g (83percent) of butyltin trichloride as a colorless liquid. The solid material obtained from the filtrationwas washed twice with toluene (5 mL) and dried in vacuoto give 0.40 g of an off-white solid. The solid was dissolved in acetone-d6and indentified as SnCl2by 119Sn NMR (δ = -235.1).

Elemental analysis: Cl, 36.92percent; Sn, 62.40percent. SnCl2requires: Cl, 37.40percent; Sn, 62.60percent. The results of the different experiments are presented in Table 2.x

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With dihydrogen peroxide

in mixt. of H2O2 and HCl, excess H2O2;

Salkowski, E.

Chemiker-Zeitung, 1916 , vol. 40, p. 448 - 449 Full Text Show Details

Gmelin Handbook: Sn: MVol.B, 14.7.5, page 368 - 371 Full Text Show Details

With nitric acid

in aqua regia; depending of concn. ratio HNO3:HCl;

Gay-Lussac, L. J.

Ann. Chim. Phys., 1848 , vol. 23, p. 203 - 229 Full Text Show Details

Gmelin Handbook: Sn: MVol.B, 14.7.5, page 368 - 371 Full Text Show Details

in further solvent(s)

Heumann, K.; Koechlin, P.

Ber. Dtsch. Chem. Ges., 1882 , vol. 15, p. 416 - 420 Full Text Show Details

Gmelin Handbook: Sn: MVol.B, 14.4.3, page 357 - 358 Full Text Show Details

in hydrogenchloride

metallinc tin dissolved in 9 M HCl;

Arapnev, A. I.; Yukhin, Yu. M.; Malinovskaya, T. D.; Egorov, Yu. P.

Russian Journal of Applied Chemistry, 2002 , vol. 75, p. 1557 - 1561 Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 2002 , vol. 75, p. 1594 - 1597 Title/Abstract Full Text Show Details

according to: Yu. V. Karyakin, I. I. Angelov, Chistye Khimicheskie Veshchestva (Pure Chemical Substances), Izd. Khimiya, Moscow, 1974, p. 298;

Strizhev, E. F.; Masloboev, D. S.; Kukushkin, Yu. N.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1978 , vol. 23, p. 1178 - 1181 Zhurnal Neorganicheskoi Khimii, 1978 , vol. 23, p. 2145 - 2150 Full Text Show Details

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in tetrahydrofuran

(Ar); refluxed for 6 h; filtered; not isolated, detected by MS in the filtrate;

Sinha, Pradipta; Kundu, Abhijit; Roy, Sujit; Prabhakar, Sripadi; Vairamani; Sankar, A. Ravi; Kunwar

Organometallics, 2001 , vol. 20, # 1 p. 157 - 162 Title/Abstract Full Text View citing articles Show Details

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A: 80%

in toluene

stirring (16 h); solvent removal (vac.), addn. pentane, filtration, volatiles rremoval (vac.);

Huettenhofer, Mario; Schaper, Frank; Brintzinger, Hans H.

Angewandte Chemie - International Edition, 1998 , vol. 37, # 16 p. 2268 - 2270 Title/Abstract Full Text View citing articles Show Details

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thermal dissociation, 280 to 340°C; reaction monitoring by pressure measurement;

German; Sevast'yanova; Suvorov; Anatsko

Russian Journal of General Chemistry, 1997 , vol. 67, # 8 p. 1188 - 1192 Title/Abstract Full Text View citing articles Show Details

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in neat (no solvent) fusing tin and alkali metal chloride (sealed quartz ampule), grinding (N2 atmosphere over P2O5), gradual heating (quartz ampule, 110 - 130°C, 1 Pa), cooling (boiling N2 temp., vac., condensation of Cl2 to ampule), storing (4 - 8 d); opening, filling (He); detd. by Raman spectroscopy;

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Salyulev; Vovkotrub; Strekalovskii

Russian Journal of Inorganic Chemistry, 1997 , vol. 42, # 5 p. 631 - 632 Title/Abstract Full Text View citing articles Show Details

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Salyulev; Vovkotrub; Strekalovskii

Russian Journal of Inorganic Chemistry, 1997 , vol. 42, # 5 p. 631 - 632 Title/Abstract Full Text View citing articles Show Details

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Kinetics; chlorination of mechanical SnO2/Fe2O3 mixt. at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction;

Solov'eva, E. A.; Derlukova, L. E.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1994 , vol. 39, p. 1697 - 1700 Zhurnal Neorganicheskoi Khimii, 1994 , vol. 39, p. 1773 - 1776 Full Text Show Details

Kinetics; chlorination of SnO2/Fe2O3 mixt. (obtained by copptn. from hydrochloric SnCl4/FeCl3 soln. with

Solov'eva, E. A.; Derlukova, L. E.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1994 , vol. 39, p. 1697 - 1700 Zhurnal Neorganicheskoi Khimii, 1994 , vol. 39, p. 1773 - 1776

concd. ammonia and ppt. calcination in air at 600°C for 24 h) at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction;

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in neat (no solvent) Kinetics; byproducts: O2; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2 flow 100 ml/min); chem. anal.;

Anufrieva, T. A.; Derlyukova, L. E.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1994 , vol. 39, p. 1559 - 1563 Zhurnal Neorganicheskoi Khimii, 1994 , vol. 39, p. 1629 - 1633 Full Text Show Details

With sulfur dioxide in neat (no solvent) Kinetics; byproducts: O2, SO3, In2(SO4)3; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2/SO2 flow 100 ml/min); chem. anal.;

Anufrieva, T. A.; Derlyukova, L. E.

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in neat (no solvent) formation by reaction of SnO2 with Cl2 at red heat;;

Gmelin Handbook: Sn: MVol.C1, 6.9.1.4, page 254 - 254 Full Text Show Details

800°C in presence of Fe2O3 and C;

Frents, G. S.

Tsvetn. Met., 1941 , vol. 16, # 4 p. 25 - 27 C., 1942 , p. 2738 II Full Text Show Details

in neat (no solvent) Kinetics; byproducts: O2; react. at

Derylukova, L. E.; Solov'eva, E. A.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1992 , vol. 37, p. 991 - 994

200-1000°C;

Zhurnal Neorganicheskoi Khimii, 1992 , vol. 37, p. 1923 - 1927 Full Text Show Details

Kinetics; chlorination at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction;

Solov'eva, E. A.; Derlukova, L. E.

800°C in presence of Fe2O3 and C;

Gmelin Handbook: Sn: MVol.B, 3, page 1 - 41 Full Text Show Details

in neat (no solvent) formation by reaction of SnO2 with Cl2 at red heat;;

Weber, R.

Ann. Physik Chem. (2), 1861 , vol. 112, p. 619 - 626 Full Text Show Details

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With carbon monoxide; chlorine in neat (no solvent) Kinetics; byproducts: CO2; 400800°C;

Evdokimov, V. I.

Kinetics and Catalysis, 1994 , vol. 35, p. 312 - 315 Kinetika i Kataliz, 1994 , vol. 35, p. 409 - 412 Full Text Show Details

With hydrogenchloride; carbon monoxide in neat (no solvent) formation of SnCl4 in presence of HCl at reaction with CO in absence of further metal-oxides;;

Lythe, R. G.; Prosser, A. P.

Inst. Mining Met. Trans. C, 1970 , vol. 79, p. 109 - 111 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.4.5, page 102 - 103 Full Text Show Details

With chlorine in neat (no solvent) Kinetics; byproducts: O2; 4001000°C;

Evdokimov, V. I.

Kinetics and Catalysis, 1994 , vol. 35, p. 312 - 315 Kinetika i Kataliz, 1994 , vol. 35, p. 409 - 412 Full Text Show Details

With chlorine in neat (no solvent) Kinetics; byproducts: O2; chlorination at 750-850°C; examination of the equilibrium reaction;;

DARADIMOS G; KUXMANN U

Erzmetall: Journal for Exploration, Mining and Metallurgy, 1971 , vol. 24, # 4 p. 163 - 172 Title/Abstract Full Text View citing articles Show Details

With sulfur dioxide; chlorine in neat (no solvent) Kinetics; byproducts: SO3; 4001000°C;

Evdokimov, V. I.

Kinetics and Catalysis, 1994 , vol. 35, p. 312 - 315 Kinetika i Kataliz, 1994 , vol. 35, p. 409 - 412 Full Text Show Details

With iron(III) chloride in neat (no solvent)

Frents, G. S.

Izv. Akad. Nauk SSSR Otd. Tekhn. Nauk, 1948 , p. 235 - 238 C. A., 1948 , p. 6690

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Gmelin Handbook: Sn: MVol.C1, 6.9.1.4, page 254 - 254 Full Text Show Details

in neat (no solvent) pptd. SnO2; 250°C;;

Hecht, H.; Jander, G.; Schlapmann, H.

Z. Anorg. Chem., 1947 , vol. 254, p. 255 - 264 Full Text Show Details

With Cl2 in neat (no solvent) Kinetics; byproducts: O2; chlorination at 750-850°C; examination of the equilibrium reaction;;

Gmelin Handbook: Sn: MVol.C1, 3.7.8.3, page 98 - 100 Full Text Show Details

in neat (no solvent) pptd. SnO2; 250°C;;

Gmelin Handbook: S: MVol.B3, 125, page 1798 - 1799 Full Text Show Details

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120-150°C;

120°C, in autoclave;

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Evdokimov, A. I.; Morozov, I. S.

Chimie et Industrie (Paris), 1962 , vol. 88, p. 115 - 119 Full Text Show Details

Evdokimov, A. I.; Morozov, I. S.

Vestn. Akad. Nauk SSSR, 1961 , vol. 31, # 2 p. 44 - 47 C.A., 1961 , p. 15282 Full Text Show Details

Gmelin Handbook: Sn: MVol.B, 14.2.4, page 352 - 353 Full Text Show Details

Rondelli, T.

Atti Congr. Nazl. Chim. Ind. Milano 1924, S. 343/52 Full Text Show Details

Lorenz, R.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1895 , vol. 10, p. 44 - 46 Full Text Show Details

Gmelin Handbook: Sn: MVol.B, 14.2.4, page 352 - 353 Full Text Show Details

With sulfur in neat (no solvent) dissolution of excess Cl2 in some SnCl4 under addn. of a small amount of S; effect of the soln. on pure Sn (casual shaking, several weeks);;

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

Brallier, P. S.

Trans. Am. Electrochem. Soc., 1926 , vol. 49, p. 257 - 266 Full Text Show Details

With SbCl3 or SbCl5 in neat (no solvent) formation by chlorination of molten Sn in presence of SbCl3 or SbCl5;; free

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

Wolf, J.; Favre, G. A.

Patent: US1937419 , 1933 ; C. II, 1934 , p. 1974

from SnCl2;;

Full Text Show Details

in melt melting of Sn by chlorination under formation of SnCl4;;

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

General Chemical Co.

Patent: US2061816 , 1936 ; C. I, 1937 , p. 2427 Full Text Show Details

in tetrachloromethane

in presence of small amts. of S;

Ochi, S.

J. Chem. Ind. Japan, 1920 , vol. 23, p. 583 - 594 Full Text Show Details Gmelin Handbook: Sn: MVol.B, 14.2.4, page 352 - 353 Full Text Show Details Brallier, P. S. Trans. Am. Electrochem. Soc., 1926 , vol. 49, p. 257 - 266 Full Text Show Details

in tetrachloromethane

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

Rondelli, T.

Atti Congr. Nazl. Chim. Ind., Milan 1924, S. 343/52 Full Text Show Details

in neat (no solvent) dissolution of excess Cl2 in some SnCl4; effect of the soln. on pure Sn (casual shaking, several weeks);;

Baxter, G. P.; Starkweather, H. W.

Journal of the American Chemical Society, 1920 , vol. 42, p. 583 - 594 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

in neat (no solvent) formation by chlorination of Sn at 4070°C;;

Stepin, B. D.; Grinshtein, S. A.

Khimicheskaya Promyshlennost (St. Petersburg, Russian Federation), 1961 , p. 46 - 51 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

in neat (no solvent) formation by chlorination of Sn melts at 260-410°C;;

Zvezdin, A. G.; Ketov, A. N.; Fomin, V. K.

Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1970 , vol. 43, p. 2569 - 2571 Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1970 , vol. 43, p. 2541 - 2543 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

in neat (no solvent) formation by passing dry Cl2 under exclusion of moisture over granulated Sn;;

Loon, C. van

Chemisch Weekblad, 1920 , vol. 17, p. 664 - 664 Full Text Show Details

Taverne, H. J.

Chemisch Weekblad, 1920 , vol. 17, p. 610 - 610 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

in neat (no solvent) formation by spraying molten Sn in Cl2 atmosphere;;

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

Lienhardt, W. S.

Patent: US1826800 , 1931 ; C. II, 1931 , p. 3648 Full Text Show Details

in neat (no solvent) formation in an exothermic reaction by heating of metallic Sn with Cl2 gas;;

Berzelius, J. J.

Schweiggers J. Chem. Physik, 1812 , vol. 6, p. 284 - 322 Full Text Show Details

Davy, J.

Philosophical Transactions of the Royal Society of London, 1812 , vol. 102, p. 169 - 204 Full Text Show Details

Davy, J.

Schweiggers J. Chem. Physik, 1814 , vol. 10, p. 311 - 354 Full Text Show Details

Proust, J. L.

J. Phys. Chim. Hist. Nat., 1800 , vol. 51, p. 173 - 184

Full Text Show Details

Proust, J. L.

J. Phys. Chim. Hist. Nat., 1804 , vol. 61, p. 338 - 349 Full Text Show Details Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

in neat (no solvent) formation in an exothermic reaction by heating of metallic Sn with very dry Cl2 gas;;

Cowper, R.

Journal of the Chemical Society, 1883 , vol. 43, p. 153 - 155 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

in neat (no solvent) passing dry Cl2 through a reaction tube filled with granulated Sn also contg. some SnCl4; reaction temp. of 110-115°C; gathering under moisture exclusion after cooling;;

Lorenz, R.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1895 , vol. 10, p. 44 - 46 Full Text Show Details

Tseng, Fan-Chieh; Chiang, Li-Chin

Hua Hsueh Tung Pao, 1961 , p. 506 - 509 C. A., 1963 , vol. 58, p. 13416 Full Text Show Details Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

in neat (no solvent) passing dry Cl2 under tin metal;

Kanjolia, R. K.; Gupta, V. D.

Journal of the Indian Chemical Society, 1981 , vol. 58, p. 340 - 342 Title/Abstract Full Text Show Details

120-150°C;

in neat (no solvent) passing dry chlorine over tin metal; distn., filtn.;

Gmelin Handbook: Sn: MVol.B, 3, page 1 - 41 Full Text Show Details

Gupta, K. L.; Srivastava, P.; Saxena, G. C.

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1993 , vol. 23, p. 177 - 184 Full Text Show Details

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Rx-ID: 26315862 Find similar reactions

in further solvent(s) byproducts: toluene, HCl; atmosphere of N2 contg. 0.1percent of O2; liquid N2-bath, 3 h, in benzylchloride;

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Reifenberg, Gerald H.; Considine, William J.

Organometallics, 1993 , vol. 12, p. 3015 - 3018 Full Text View citing articles Show Details

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Rx-ID: 26182438 Find similar reactions

in neat (no solvent) Kinetics; byproducts: O2; react. at 700-900°C;

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Derylukova, L. E.; Solov'eva, E. A.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1992 , vol. 37, p. 991 - 994 Zhurnal Neorganicheskoi Khimii, 1992 , vol. 37, p. 1923 - 1927 Full Text Show Details

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B: 95%

Hide Experimental Procedure

Rx-ID: 24822542 Find similar reactions

The United States of America as represented by the Secretary of Agriculture; Cornell Research Foundation, Inc.

Patent: US4942247 A1, 1990 ; Title/Abstract Full Text Show Details

6:Materials and Instrumentation

EXAMPLE 6 Materials and Instrumentation 1 H NMR spectra were taken on either a Varian XL-200 or XL-400 spectrometer. 13 C NMR spectra were taken on a Varian XL-400 spectrometer. IR spectra were taken on either a Perkin-Elmer 299B or a Mattson Polaris FT-IR spectrophotometer. Mass spectra were taken on either a Finnigan 3300 or an AEI MS-902 mass spectrometer. Hydrogenations were carried out on a Series 3910 Parr Hydrogenator. Trimethylsilyl cyanide (98percent), boron trifluoride etherate (purified and redistilled), and tin (IV) chloride (anhydrous, 99percent) were obtained from Aldrich Chemical Company. Methylthiotrimethylsilane (approximately 95percent) was obtained from Fluka. Silica gel (approximately 40 μm average particle diameter) was obtained from J. T. Baker Chemical Company. A reaction run under dry conditions signifies a reaction run in flame- or oven-dried glassware and under an argon or nitrogen atmosphere.

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Rx-ID: 26178016 Find similar reactions

byproducts: HCl, 3,4-dimethylpyridine; thermal decomposition; studied by thermal analysis;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

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Rx-ID: 26178017 Find similar reactions

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

Synthesize Find similar byproducts: HCl, 3,5-dimethylpyridine; thermal decomposition; studied by thermal analysis;

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Rx-ID: 26178018 Find similar reactions

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

Synthesize Find similar byproducts: HCl, 2,4,6trimethylpyridine; thermal decomposition; studied by thermal analysis;

Synthesize Find similar Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

Rx-ID: 26178025 Find similar reactions

Synthesize Find similar byproducts: HCl, 2-methylquinoline; thermal decomposition; studied by thermal analysis;

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Rx-ID: 26178110 Find similar reactions

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

Synthesize Find similar byproducts: HCl, acridine; thermal decomposition; studied by thermal analysis;

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Rx-ID: 26178142 Find similar reactions

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

Synthesize Find similar byproducts: HCl, 4-methylpyridine; thermal decomposition; studied by thermal analysis;

Synthesize Find similar Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

Rx-ID: 26178178 Find similar reactions

Synthesize Find similar byproducts: HCl, 3-methylpyridine; thermal decomposition; studied by thermal analysis;

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Rx-ID: 26178179 Find similar reactions

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 26333834 Find similar reactions

A: 82%

With HCl in acetonitrile

room temp., 30 min. (crystn.); cooling (-20°C), decantation, washing (cold MeCN, cold 1 M HCl), drying (vac., 6 h), recrystn. (EtOH/HCl); elem. anal.;

Linder, Karen E.; Malley, Mary F.; Gougoutas, Jack Z.; Unger, Steve E.; Nunn, Adrian D.

Inorganic Chemistry, 1990 , vol. 29, p. 2428 - 2434 Full Text View citing articles Show Details

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Synthesize Find similar Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

Rx-ID: 26421946 Find similar reactions

Synthesize Find similar byproducts: HCl, quinoline; thermal decomposition; studied by thermal analysis;

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Rx-ID: 26617405 Find similar reactions

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

Synthesize Find similar byproducts: HCl, isoquinoline; thermal decomposition; studied by thermal analysis;

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Rx-ID: 26617416 Find similar reactions

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1990 , vol. 157, p. 137 - 154 Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 26748690 Find similar reactions

A: 75%

With HCl in acetonitrile

stirring (30 min., pptn.); addn. of excess 1 M HCl, collection (after 15 min.), washing (1 M HCl, H2O), drying (vac.), recrystn. (MeCN/1 M HCl); elem. anal.;

Linder, Karen E.; Malley, Mary F.; Gougoutas, Jack Z.; Unger, Steve E.; Nunn, Adrian D.

Inorganic Chemistry, 1990 , vol. 29, p. 2428 - 2434 Full Text View citing articles Show Details

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Rx-ID: 26179898 Find similar reactions

A: 73%

in N,N-dimethyl-formamide

byproducts: CO; Ar atmosphere, 150°C, 24 h; pptn. on addn. of H2O, washing (dild. HCl and cyclohexane), drying (vac.); elem. anal.;

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Haupt, H.-J.; Keppler, T.; Floerke, U.; Calage, Y.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1989 , vol. 571, p. 51 - 59 Full Text Show Details

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Synthesize Find similar Rx-ID: 26412886 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

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in neat (no solvent)

Janiak, Tadeusz; Blazejowski, Jerzy

Kinetics; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 26413892 Find similar reactions

in neat (no solvent) Kinetics; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26413924 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

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in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements;

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Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26415368 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

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in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

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in neat (no solvent) Kinetics; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

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Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26417309 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

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in neat (no solvent)

Janiak, Tadeusz; Blazejowski, Jerzy

Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 26419847 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26420600 Find similar reactions

in neat (no solvent) Kinetics; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTGmeasurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26421844 Find similar reactions

in neat (no solvent) Kinetics; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTGmeasurements;

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Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26421845 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26421846 Find similar reactions

in neat (no solvent) Kinetics; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTGmeasurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26421847 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

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Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26421911 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26421912 Find similar reactions

in neat (no solvent)

Janiak, Tadeusz; Blazejowski, Jerzy

Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements;

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 26424221 Find similar reactions

in neat (no solvent) Kinetics; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26424929 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26426151 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG measurements;

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Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26426271 Find similar reactions

in neat (no solvent) Kinetics; byproducts: SnO2; thermal dissociation (heating rate ca. 5 K/min); not isolated, analyzed by TG, DTA, DTG-measurements;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 141, p. 93 - 112 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26616908 Find similar reactions

in solid Kinetics; heating up to 773 K under N2; DTG-DTA-TG anal.;

Janiak, Tadeusz; Blazejowski, Jerzy

Thermochimica Acta, 1989 , vol. 156, p. 27 - 44 Full Text View citing articles Show Details

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Rx-ID: 26162907 Find similar reactions

in gas chemical transport reaction proceeded in tranparent fused silica ampoules (1070-1110°C, 1-1.5 atm, 250h);

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Toshev, A.; Peshev, P.

Materials Research Bulletin, 1988 , vol. 23, p. 1045 - 1052 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 26182512 Find similar reactions

in gas chemical transport reaction proceeded in tranparent fused silica ampoules (1010-1070°C, 1 atm, 310-400h);

Toshev, A.; Peshev, P.

Materials Research Bulletin, 1988 , vol. 23, p. 1045 - 1052 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar With sulfur dioxide in hydrogenchloride

formation by oxidation of SnCl2 in a HCl contg. soln. with SO2;;

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Rx-ID: 26185643 Find similar reactions

Durrant, R. G.

Journal of the Chemical Society, 1915 , vol. 107, p. 622 - 638 Full Text View citing articles Show Details

Wardlaw, W.

J. Soc. Chem. Ind. (London), 1926 , vol. 45, p. 210 T - 214 T Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.3, page 253 - 254 Full Text Show Details

>99

With chlorine in neat (no solvent) slowly reaction in coldness;;

Brewer, F. M.

Journal of Physical Chemistry, 1927 , vol. 31, p. 1817 - 1823 Full Text Show Details

With chlorine in neat (no solvent)

Ladenburg, A.

Liebigs Ann. Chem. Suppl., 1872 , vol. 8, p. 55 - 80 Full Text Show Details

With sulfuric acid in water

formation by heating a concd. aq. SnCl2 soln. with concd. H2SO4;;

Davy, J.

Philosophical Transactions of the Royal Society of London, 1812 , p. 169 - 204 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.3, page 253 - 254 Full Text Show Details

With hydrogenchloride; ozone in water

byproducts: H2O; oxidation with O3 of SnCl2 under formation of SnCl4 and H2O;;

Briner, E.; Bever, B.

Helvetica Chimica Acta, 1936 , vol. 19, p. 369 - 369 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.6.8.4, page 234 - 234 Full Text Show Details

With hydrogenchloride; ammonium pertechnetate-(99)Tc in hydrogenchloride; ethanol

Kinetics; byproducts: (CH3)2NC6H3NHSC6H3NH(CH3)2(1+); reduction of ethanolic soln. of methylene blue by SnCl2 catalyzed by (99)Tc; monitored by UVspectroscopy;

Amat, E.; March, J. G.; Grases, F.

Journal of Molecular Catalysis, 1986 , vol. 35, p. 1 - 8 Full Text View citing articles Show Details

With mercury dichloride in pyridine

byproducts: Hg; reaction with HgCl2 in pyridine under formation of Hg and SnCl4;;

Naumann, A.

Ber. Dtsch. Chem. Ges., 1904 , vol. 37, p. 4609 - 4614 Full Text Show Details

With hydrogenchloride; KIO3 in hydrogenchloride

byproducts: H2O, KCl, ICl; 15°C, fast;

Azim, S. M. A.; Rehman, A.

Journal of the Indian Chemical Society, 1955 , vol. 32, p. 708 - 710 Full Text Show Details

Singh, B.; Ilahi, I.

Journal of the Indian Chemical Society, 1936 , vol. 13, p. 717 - 722 Full Text Show Details

With Nitrous oxide in hydrogenchloride

byproducts: NH2OH; reduction of N2O in HCl-containing soln. under formation of SnCl4 and NH2OH;;

Nichols, M. L.; Derbigny, I. A.

Journal of Physical Chemistry, 1926 , vol. 30, p. 491 - 506 Full Text Show Details

With hydrogenchloride; oxygen; copper dichloride

byproducts: H2O;

Haring, R. C.; Walton, J. H.

Journal of Physical Chemistry, 1933 , vol. 37, p. 133 - 145 Full Text View citing articles Show Details

Haring, R. C.; Walton, J. H.

Journal of Physical Chemistry, 1933 , vol. 37, p. 375 - 380 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.B, 16.1.5.4, page 398 - 400 Full Text Show Details

With ozone in hydrogenchloride

formation by oxidation of SnCl2 in a HCl contg. soln. with O3;;

Yamauchi, Y.

American Chemical Journal, 1913 , vol. 49, p. 55 - 68 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.3, page 253 - 254 Full Text Show Details

With oxygen difluoride in hydrogenchloride

byproducts: HF, H2O;

Ishikawa, F.; Takai, T.

Sci. Rep. Tohoku Imp. Univ., Ser. 1, 1935 , vol. 24, p. 98 - 106 Full Text Show Details

Gmelin Handbook: F: SVol.1, 64, page 231 - 233 Full Text Show Details

With sulfur in water

byproducts: H2S; boiling with S in acid soln. forms SnCl4 and H2S;;

Hoenig, Alfred

Zeitschrift fuer Analytische Chemie, 1915 , vol. 54, # 9 p. 441 - 457 Full Text View citing articles Show Details

Vortmann, G.; Padberg, C.

Ber. Dtsch. Chem. Ges., 1889 , vol. 22, p. 2642 - 2644 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.6.8.5, page 234 - 235 Full Text Show Details

With sulfur in water

formation by heating an aq. SnCl2 soln. with S;;

Vortmann, G.; Padberg, C.

Ber. Dtsch. Chem. Ges., 1889 , vol. 22, p. 2642 - 2644 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.3, page 253 - 254 Full Text Show Details

With sulfur in neat (no solvent) formation by heating solid SnCl2 with S;;

Davy, J.

Philosophical Transactions of the Royal Society of London, 1812 , p. 169 - 204 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.3, page 253 - 254 Full Text Show Details

With selenium in neat (no solvent) formation by heating solid SnCl2 with Se;;

Gmelin Handbook: Sn: MVol.C1, 6.9.1.3, page 253 - 254 Full Text Show Details

With air; carbon in hydrogenchloride

Gmelin Handbook: Sn: MVol.C1, 6.9.1.3, page 253 - 254 Full Text Show Details

Sapadinski, M. B.

Patent: SU13078 , 1930 ; C. I, 1931 , p. 3497 Full Text Show Details

formation by oxidation of SnCl2 in HCl contg. soln. with air in presence of charcoal at 80-90°C;;

With chloride of lime in neat (no solvent) oxydation of SnCl2 with chloride of lime to SnCl4;;

Goepner, C.

Dinglers Polytech. J., 1873 , vol. 209, p. 204 - 224 Full Text Show Details

in hydrogenchloride

Kinetics; byproducts: H2; Irradiation (UV/VIS); flash photolysis; fused quartz tube, addn. of SnCl2 to a deaereted soln. of hydrochlorid acid; detn. by absorption spectroscopy;

Shinohara, Nobuyoshi; Mori, Katsuhiko; Inoue, Makoto

Chemistry Letters, 1986 , p. 661 - 664 Title/Abstract Full Text Show Details

With chloride of lime in neat (no solvent) oxydation of SnCl2 with chloride of lime to SnCl4;;

Gmelin Handbook: Ca: MVol.B2, 133, page 571 - 573 Full Text Show Details

With HgCl2 in pyridine

byproducts: Hg; reaction with HgCl2 in pyridine under formation of Hg and SnCl4;;

Gmelin Handbook: Sn: MVol.C1, 6.7.2.9, page 243 - 244 Full Text Show Details

With N2O in hydrogenchloride

byproducts: NH2OH; reduction of N2O in HCl-containing soln. under formation of SnCl4 and NH2OH;;

Gmelin Handbook: Sn: MVol.C1, 6.6.8.7, page 235 - 236 Full Text Show Details

>99

With Se in neat (no solvent) formation by heating solid SnCl2 with Se;;

Schneider, R.

Ann. Physik Chem. (2), 1866 , vol. 127, p. 624 - 638 Full Text Show Details

in neat (no solvent, gas phase) byproducts: Cl2; Electrolysis; fusion electrolysis forms Cl2 at the anode which reacts with molten SnCl2 to SnCl4;;

Gmelin Handbook: Sn: MVol.C1, 6.3.8, page 215 - 216 Full Text Show Details

With CuCl2 in acetone

excess of CuCl2 soln.;;

Naumann, A.

Ber., 1899 , vol. 32, p. 999 - 1004 Full Text Show Details

Gmelin Handbook: Cu: MVol.B1, 132, page 289 - 291 Full Text Show Details

in neat (no solvent, gas phase) byproducts: Cl2; Electrolysis; fusion electrolysis forms Cl2 at the anode which reacts with molten SnCl2 to SnCl4;;

Helfenstein, A.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1900 , vol. 23, p. 255 - 316 Full Text Show Details

With KIO3; HCl in hydrogenchloride

Gmelin Handbook: Sn: MVol.B, 16.1.5.9, page 401 - 402 Full Text Show Details

With Cl2

Gmelin Handbook: Sn: MVol.C1, 6.3.9.4, page 217 - 218 Full Text Show Details

Gmelin Handbook: Cl: SVol.A, 155, page 365 - 368 Full Text Show Details

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Rx-ID: 26185670 Find similar reactions

in neat (no solvent) molar ratio=1:1, evacuated ampoule, 120°C;

Mireev, V. A.; Safonov, V. V.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1986 , vol. 31, p. 1559 - 1561 Zhurnal Neorganicheskoi Khimii, 1986 , vol. 31, p. 2702 - 2704 Full Text Show Details

Synthesize Find similar Rx-ID: 26272118 Find similar reactions

in N,N-dimethyl-formamide

dissolving in N,N-dimethylformamide;

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Watanabe, Masanobu; Motoyama, Izumi; Sano, Hirotoshi

Bulletin of the Chemical Society of Japan, 1986 , vol. 59, # 7 p. 2109 - 2114 Title/Abstract Full Text Show Details

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Rx-ID: 26465551 Find similar reactions

With sodium chloride in further solvent(s) (CH3)SnCl3 was added to a soln. of HgCl2 in aq. NaCl (artificial seawater), the flask was sealed from light, shaken for 30 d at room temp.; monitored by 199Hg NMR;

Howell, Gregory N.; O'Connor, Maxwell J.; Bond, Alan M.; Hudson, Henry A.; Hanna, Peter J.; Strother, Stan

Australian Journal of Chemistry, 1986 , vol. 39, p. 1167 - 1176 Full Text Show Details

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Synthesize Find similar Rx-ID: 26980124 Find similar reactions

in acetonitrile

dissolving Ru-Sn-compound in acetonitrile and standing in air for a fewminutes;;

Watanabe, Masanobu; Motoyama, Izumi; Sano, Hirotoshi

Bulletin of the Chemical Society of Japan, 1986 , vol. 59, # 7 p. 2109 - 2114 Title/Abstract Full Text Show Details

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Rx-ID: 26149032 Find similar reactions

in dichloromethane

sealed tube, room temp.; Sn:B molar ratio >1:1;

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Dillon, Keith B.; Hewitson, Geoffrey F.

Polyhedron, 1984 , vol. 3, p. 957 - 962 Full Text View citing articles Show Details

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Rx-ID: 26167080 Find similar reactions

in neat (no solvent) SbCl5 was added dropwise; N2 atm., NMR tube;

Dillon, Keith B.; Hewitson, Geoffrey F.

Polyhedron, 1984 , vol. 3, p. 957 - 962 Full Text View citing articles Show Details

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Rx-ID: 26167084 Find similar reactions

in neat (no solvent) SbCl5 was added dropwise; N2 atm., NMR tube;

Dillon, Keith B.; Hewitson, Geoffrey F.

Polyhedron, 1984 , vol. 3, p. 957 - 962 Full Text View citing articles Show Details

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Rx-ID: 26451611 Find similar reactions

in dichloromethane

sealed tube, room temp.; Sn:B molar ratio >1:1;

Dillon, Keith B.; Hewitson, Geoffrey F.

Polyhedron, 1984 , vol. 3, p. 957 - 962 Full Text View citing articles Show Details

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Rx-ID: 26483873 Find similar reactions

in dichloromethane

a soln. of SbCl5 was added to a soln. of PhSnCl3; N2 atm., NMR tube; evapn. in vac.;

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Dillon, Keith B.; Hewitson, Geoffrey F.

Polyhedron, 1984 , vol. 3, p. 957 - 962 Full Text View citing articles Show Details

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Rx-ID: 26483874 Find similar reactions

in neat (no solvent) SbCl5 was added dropwise; N2 atm., NMR tube;

Dillon, Keith B.; Hewitson, Geoffrey F.

Polyhedron, 1984 , vol. 3, p. 957 - 962 Full Text View citing articles Show Details

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Rx-ID: 26483884 Find similar reactions

in neat (no solvent) SbCl5 was added dropwise; N2 atm., NMR tube;

Dillon, Keith B.; Hewitson, Geoffrey F.

Polyhedron, 1984 , vol. 3, p. 957 - 962 Full Text View citing articles Show Details

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in tetrachloromethane

Kinetics; Irradiation (UV/VIS);

Blunden, Stephen J.

Journal of Organometallic Chemistry, 1983 , vol. 248, # 2 p. 149 - 160 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 26139666 Find similar reactions

Gmelin Handbook: Sn: MVol.C1, 6.9.1.1, page 252 - 253 Full Text Show Details

Alexander, W. P.; Burgess, L.

Patent: US1999179 , 1935 ; C. I, 1936 , p. 2410 Full Text Show Details

Smith, W. S.

Patent: US1777132 , 1930 ; C. II, 1930 , p. 3325 Full Text Show Details

With Cl2 in neat (no solvent) dry Cl2;

Chandra, K.; Garg, A. K.; Jain, M. C.

Journal of the Indian Chemical Society, 1980 , vol. 57, p. 378 - 381 Full Text Show Details

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Rx-ID: 26107886 Find similar reactions

Kinetics; chlorination at const. temp. in range 650-850°C (gas flow 5-6 l/h); gravimetric monitoring;

Derlyukova, L. E.; Evdokimov, V. I.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1978 , vol. 23, p. 962 - 964 Zhurnal Neorganicheskoi Khimii, 1978 , vol. 23, p. 1750 - 1753 Full Text Show Details

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Rx-ID: 26099800 Find similar reactions

in neat (no solvent) chlorination with an eutectic AlCl3NaCl-mixture (63 mol-percent AlCl3) to SnCl4;;

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Sherer, C. S.

Journal of Inorganic and Nuclear Chemistry, 1972 , vol. 34, p. 1615 - 1619 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.6.3, page 109 - 110 Full Text Show Details

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Rx-ID: 26438977 Find similar reactions

in neat (no solvent) boiling under reflux, molar ratio of Sn(C6H4-p-CH3):BCl3 = 1:4;

Hooz, J.; Calzada, J. G.

Org. Prep. Proced. Intern., 1972 , vol. 4, p. 219 - 223 Full Text Show Details

in neat (no solvent) boiling under reflux, molar ratio of Sn(C6H4-p-CH3):BCl3 = 1:4;

Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.4, page 165 - 168 Full Text Show Details

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Rx-ID: 26441926 Find similar reactions

in neat (no solvent) 4 fold excess of BCl3, -78-0°C;

Hooz, J.; Calzada, J. G.

Org. Prep. Proced. Intern., 1972 , vol. 4, p. 219 - 223 Full Text Show Details

in neat (no solvent) 4 fold excess of BCl3, -78-0°C;

Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.6, page 169 - 176 Full Text Show Details

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Rx-ID: 26448544 Find similar reactions

in neat (no solvent) boiling under reflux, 4 h;

Hooz, J.; Calzada, J. G.

Org. Prep. Proced. Intern., 1972 , vol. 4, p. 219 - 223 Full Text Show Details

in neat (no solvent) boiling under reflux, 4 h;

Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.6, page 169 - 176 Full Text Show Details

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Rx-ID: 26171968 Find similar reactions

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With hydrogen in neat (no solvent) reaction with HCl in presence of H2; examination of the reaction in presence of catalysts at 500-630°C;;

Lythe, R. G.; Prosser, A. P.

Inst. Mining Met. Trans. C, 1969 , vol. 78, p. 206 - 213 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.4.2, page 101 - 101 Full Text Show Details

With carbon monoxide in neat (no solvent) reaction with HCl-CO-mixtures forms SnCl4 at 700°C;;

Lythe, R. G.; Prosser, A. P.

Inst. Mining Met. Trans. C, 1970 , vol. 79, p. 109 - 111 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.4.2, page 101 - 101 Full Text Show Details

in neat (no solvent) byproducts: H2O; reaction with HCl (gas-stream) at 400°C under formation of SnCl4 and H2O; examination of reaction;;

Ivashentsev, Ya. I.; Ivantsova, V. I.

Zhurnal Fizicheskoi Khimii, 1969 , vol. 43, p. 505 - 508 Zhurnal Fizicheskoi Khimii, 1969 , vol. 43, p. 917 - 921 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.4.2, page 101 - 101 Full Text Show Details

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Synthesize Find similar Rx-ID: 26171969 Find similar reactions

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With carbon monoxide; bismuth in neat (no solvent) catalysis of reduction to SnO or Sn with Bi; formation of SnCl4 and SnCl2;;

Lythe, R. G.; Prosser, A. P.

Inst. Mining Met. Trans. C, 1970 , vol. 79, p. 109 - 111 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.4.2, page 101 - 101 Full Text Show Details

With carbon monoxide; iron(III) oxide in neat (no solvent) catalysis of reduction to SnO or Sn with Fe2O3; formation of SnCl4 and SnCl2;;

Lythe, R. G.; Prosser, A. P.

Inst. Mining Met. Trans. C, 1970 , vol. 79, p. 109 - 111 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.4.2, page 101 - 101 Full Text Show Details

With carbon monoxide; bismuth(III)oxide in neat (no solvent) catalysis of reduction to SnO or Sn with Bi2O3; formation of SnCl4 and SnCl2;;

Lythe, R. G.; Prosser, A. P.

Inst. Mining Met. Trans. C, 1970 , vol. 79, p. 109 - 111 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.4.2, page 101 - 101 Full Text Show Details

With carbon monoxide; iron in neat (no solvent) catalysis of reduction to SnO or Sn with Fe; formation of SnCl4 and SnCl2;;

Lythe, R. G.; Prosser, A. P.

Inst. Mining Met. Trans. C, 1970 , vol. 79, p. 109 - 111 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.4.2, page 101 - 101 Full Text Show Details

With carbon monoxide; platinum in neat (no solvent) catalysis of reduction to SnO or Sn with Pt; formation of SnCl4 and SnCl2;;

Lythe, R. G.; Prosser, A. P.

Inst. Mining Met. Trans. C, 1970 , vol. 79, p. 109 - 111 Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.8.4.2, page 101 - 101 Full Text Show Details

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Synthesize Find similar Rx-ID: 26636808 Find similar reactions

A: >99 B: >99

in neat (no solvent) decompn. at 120 °C;;

Stapfer; Dworkin

Inorganic Chemistry, 1970 , vol. 9, p. 421 Full Text View citing articles Show Details

A: >99 B: >99

in neat (no solvent) decompn. at 120 °C;;

Gmelin Handbook: Sn: MVol.C2, 9.27.1, page 75 - 75 Full Text Show Details

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Rx-ID: 26168028 Find similar reactions

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in neat (no solvent) equilibrium;;

Gmelin Handbook: Sn: MVol.C2, 11.5.2, page 210 - 210 Full Text Show Details

in neat (no solvent) equilibrium;;

Safonov, V. V.; Konov, A. V.; Korshunov, B. G.

Izv. Vysshikh Uchebn. Zavedenii Tsvent. Met., 1969 , vol. 12, # 5 p. 83 - 85 C. A., 1970 , vol. 72, p. 48221 Full Text Show Details

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Rx-ID: 26182432 Find similar reactions

in neat (no solvent) formation by passing a Cl2-stream (10 Torr) through Sn at 100°C;;

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FONSTAD CG; LINZ A; REDIKER RH

Journal of the Electrochemical Society, 1969 , vol. 116, # 9 p. 1269 - 1271 Title/Abstract Full Text View citing articles Show Details

Gmelin Handbook: Sn: MVol.C1, 3.7.1.5.3.1, page 63 - 64 Full Text Show Details

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Synthesize Find similar Rx-ID: 26445160 Find similar reactions

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heating;

Kretov, A. E.

Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1929 , vol. 2, p. 483 - 501 C.A., 1930 , p. 313 Full Text Show Details Kuznetsov, Yu. P.; Petrov, E. S.; Vakhrusheva, A. I. Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk, 1969 , p. 317 - 320 Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk, 1969 , # 3 p. 60 - 65 Full Text Show Details Gmelin Handbook: C: MVol.D3, 2.2.8.7.1, page 97 - 97 Full Text Show Details

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Rx-ID: 26433729 Find similar reactions

longer heating at 430°C;

Kuznetsov, Yu. P.; Petrov, E. S.; Vakhrusheva, A. I.

Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk, 1968 , p. 501 - 503 Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk, 1968 , # 5 p. 30 - 33 Full Text Show Details

Gmelin Handbook: C: MVol.D3, 2.2.8.5.5, page 93 - 93 Full Text Show Details

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Rx-ID: 26445157 Find similar reactions

from 535 K;

Kuznetsov, Yu. P.; Petrov, E. S.; Vakhrusheva, A. I.

Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk, 1968 , p. 464 - 466 Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk, 1968 , # 4 p. 137 - 140 Full Text Show Details

Gmelin Handbook: C: MVol.D3, 2.2.8.7.3, page 98 - 100 Full Text Show Details

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in benzene

Smitskamp, C. C.; Olie, K.; Gerding, H.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1968 , vol. 359, p. 318 - 325 Full Text Show Details

Gmelin Handbook: Sn: MVol.C2, 16.18.2, page 262 - 264 Full Text Show Details

in tetrachloromethane

Smitskamp, C. C.; Olie, K.; Gerding, H.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1968 , vol. 359, p. 318 - 325 Full Text Show Details

Gmelin Handbook: Sn: MVol.C2, 16.18.2, page 262 - 264 Full Text Show Details

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Synthesize Find similar Rx-ID: 26468438 Find similar reactions

decompn. in satd. vapor state;

Suvorov, A. V.; Shutaev, V. L.

Probl. Sovrem. Khim. Koord. Soedin., 1968 , # 2 p. 76 - 90 C.A., 1969 , vol. 70, p. 6961 Full Text Show Details Gmelin Handbook: Sn: MVol.C3, 23.5.1.1.3, page 99 - 100 Full Text Show Details

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Rx-ID: 26616885 Find similar reactions

heating;

Gmelin Handbook: Sn: MVol.C3, 25.9, page 150 - 150 Full Text Show Details

heating;

Morozov, A. I.; Morozov, I. S.

Zhurnal Neorganicheskoi Khimii, 1968 , vol. 13, p. 519 - 521 Zhurnal Neorganicheskoi Khimii, 1968 , vol. 13, p. 992 - 997 Full Text Show Details

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Synthesize Find similar Rx-ID: 26616886 Find similar reactions

heating;

Morozov, A. I.; Morozov, I. S.

Zhurnal Neorganicheskoi Khimii, 1968 , vol. 13, p. 519 - 521 Zhurnal Neorganicheskoi Khimii, 1968 , vol. 13, p. 992 - 997 Full Text Show Details

Gmelin Handbook: Sn: MVol.C3, 22.17, page 62 - 63 Full Text Show Details

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Morozov, A. I.; Morozov, I. S.

Zhurnal Neorganicheskoi Khimii, 1968 , vol. 13, p. 519 - 521 Zhurnal Neorganicheskoi Khimii, 1968 , vol. 13, p. 992 - 997 Full Text Show Details

Gmelin Handbook: Sn: MVol.C3, 23.5.10, page 110 - 110 Full Text Show Details

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decompn. at 637-663°C;

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Rx-ID: 26618541 Find similar reactions

Morozov, A. I.; Morozov, I. S.

Zhurnal Neorganicheskoi Khimii, 1968 , vol. 13, p. 519 - 521 Zhurnal Neorganicheskoi Khimii, 1968 , vol. 13, p. 992 - 997 Full Text Show Details

Gmelin Handbook: Sn: MVol.C3, 24.8, page 135 - 135 Full Text Show Details

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Rx-ID: 26100040 Find similar reactions

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in melt

Karpenko, N. V.

Zhurnal Neorganicheskoi Khimii, 1967 , vol. 12, p. 1556 - 1559 Zhurnal Neorganicheskoi Khimii, 1967 , vol. 12, p. 2940 - 2945 Full Text Show Details

in melt

Gmelin Handbook: Sn: MVol.C3, 21.12, page 23 - 23 Full Text Show Details

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in neat (no solvent) byproducts: WCl5; formation by

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Rx-ID: 26170142 Find similar reactions

Korshunov, B. G.; Beznevskaya, V. N.

Zhurnal Neorganicheskoi Khimii, 1967 , vol. 12, p. 1736 - 1737

reaction of SCl6 with SnCl2 at 140150°C in N2 stream;;

Zhurnal Neorganicheskoi Khimii, 1967 , vol. 12, p. 3280 - 3282 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.9.1.3, page 253 - 254 Full Text Show Details

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Rx-ID: 26170171 Find similar reactions

in neat (no solvent) byproducts: WCl5; reaction with WCl6 at .>.140°C under formation of WCl5 and SnCl4;;

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Korshunov, B. G.; Bezuevskaya, V. N.

Zhurnal Neorganicheskoi Khimii, 1967 , vol. 12, p. 1736 - 1737 Zhurnal Neorganicheskoi Khimii, 1967 , vol. 12, p. 3280 - 3282 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.3.9.7, page 219 - 221 Full Text Show Details

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Rx-ID: 26167616 Find similar reactions

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in neat (no solvent) reaction with NbCl5 at 200-220°C in an inclose tube under formation of lower chlorides and SnCl4;;

Morozov, I. S.; Ch'ih-Fa Li

Zhurnal Neorganicheskoi Khimii, 1963 , vol. 8, p. 1432 - 1434 Zhurnal Neorganicheskoi Khimii, 1963 , vol. 8, p. 2733 - 2736 Full Text Show Details

Gmelin Handbook: Sn: MVol.C1, 6.3.9.7, page 219 - 221 Full Text Show Details

in neat (no solvent) reaction with NbCl5 at 200-220°C in an inclose tube under formation of lower chlorides and SnCl4;;

Morozov, I. S.; Lipatova, N. P.

Zhurnal Neorganicheskoi Khimii, 1966 , vol. 11, p. 550 - 553 Zhurnal Neorganicheskoi Khimii, 1966 , vol. 11, p. 1018 - 1024 Full Text Show Details

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