Sodium borohydride (Sodium tetrahydroborate; NaBH4) [BH4Na] by Asch

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Reactions (166)

Substances (173)

Targets (168)

Citations (200)

Conditions

References

100

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Rx-ID: 26101945 Find similar reactions

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in further solvent(s) solvent: C6Cl6 or fluorinated hydrocarbons, molar ratio NaH:BPO4=3:1, N2-atmosphere, 280-300°C;;

Thiokol Chemical Corp.

Patent: US2849276 , 1958 ; C. A., 1959 , p. 4670 Full Text Show Details

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

in mineral oil

molar ratio NaH:BPO4=3:1, N2-atmosphere, 280-300°C;;

Thiokol Chemical Corp.

Patent: US2849276 , 1958 ; C. A., 1959 , p. 4670 Full Text Show Details Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

in mineral oil

heating BPO4 with NaH in mineral oil;; cooling, extraction with liquid NH3;;

Thiokol Chemical Corp.

Patent: US2849276 , 1958 ; C., 1963 , p. 14823 Full Text Show Details

Hide Details Gmelin Handbook: P: MVol.C, 266, page 611 - 613 Full Text Show Details

in mineral oil heating BPO4 with NaH in mineral oil;; cooling, extraction with liquid NH3;;

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101

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Rx-ID: 26121819 Find similar reactions

in ammonia

byproducts: NH3; B2H6 reacts as amine;

Parry, R. W.; Shore, S. G.

Journal of the American Chemical Society, 1958 , vol. 80, p. 15 - 20 Full Text View citing articles Show Details

in ammonia

byproducts: NH3; NH3 (liquid); B2H6 reacts as amine;

Gmelin Handbook: Na: SVol.3, 1.5.5, page 947 - 953 Full Text Show Details

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102

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Rx-ID: 26121821 Find similar reactions

in ammonia

byproducts: NH3; B2H6 reacts in liquid NH3 as amine;

Parry, R. W.; Shore, S. G.

Journal of the American Chemical Society, 1958 , vol. 80, p. 15 - 20 Full Text View citing articles Show Details

in ammonia

byproducts: NH3; NH3 (liquid); B2H6 reacts in liquid NH3 as amine;

Gmelin Handbook: Na: SVol.3, 1.5.5, page 947 - 953 Full Text Show Details

103

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Rx-ID: 26149304 Find similar reactions

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in neat (no solvent) byproducts: CaO; react. in an autoclave under H2-pressure, 300-600°C, exothermic react. (formation of CaH2 from CaCl2 and H2 during the react. possible); addn. of SiO2 for absorption of CaO;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1036222 , 1958 ; C., 1960 , p. 5610 Full Text Show Details

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104

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A: >99

140-160°C;

Studiengesellschaft Kohle m.b.H.

Patent: DE1018397 , 1957 ; C., 1960 , p. 5610 Full Text Show Details

Studiengesellschaft Kohle m.b.H.

Patent: DE1035109 , 1958 ; C., 1960 , p. 5610 Full Text Show Details

A: >99

140-160°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

105

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Rx-ID: 26452335 Find similar reactions

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With hydrogen

heating in autoclave under H2 pressure at 300 - 600°C, exotherm react.;

Farbenfabriken Bayer A.-G.

Patent: DE1036222 , 1958 ; C, 1960 , p. 5610 Full Text Show Details

With H2

heating in autoclave under H2 pressure at 300 - 600°C, exotherm react.;

Gmelin Handbook: Na: SVol.3, 3.9.1, page 1262 - 1270 Full Text Show Details

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106

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Rx-ID: 26572936 Find similar reactions

Parry, R. W.; Shore, S. G.

Journal of the American Chemical Society, 1958 , vol. 80, p. 15 - 20 Full Text View citing articles Show Details

Shore, S. G.; Parry, R. W.

Journal of the American Chemical Society, 1958 , vol. 80, p. 12 - 15 Full Text View citing articles Show Details

Gmelin Handbook: B: B-Verb.10, 3.2.4, page 42 - 43 Full Text Show Details

in ammonia

107

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Rx-ID: 26101857 Find similar reactions

90%

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With catalyst: Na-alcoholate in neat (no solvent) passing BF3 over NaH in presence of a Na-alcoholate, 250-300°C;;

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Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

E. I. du Pont de Nemours & Co.

Patent: US2684888 , 1954 ; C. A., 1954 , p. 13181 Full Text Show Details

in neat (no solvent) byproducts: B2H6; on passing a mixture of BF3 and H2 (ratio=1:2) over powdered NaH at about 180°C;;

Hurd, D. T.

Journal of the American Chemical Society, 1949 , vol. 71, p. 20 - 22 Full Text View citing articles Show Details

in diethyl ether

react. of NaH with a soln. of BF3 in ether in an autoclave (about 10 at), 24h, about 120°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Heyl & Co., Chemisch-Pharmazeutische Fabrik

Patent: DE944546 , 1956 ; C. A., 1958 , p. 12341 Full Text Show Details

Heyl & Co., Chemisch-Pharmazeutische Fabrik

Patent: GB711174 , 1954 ; C. A., 1954 , p. 14140 Full Text Show Details

Hide Details

in mineral oil

at 250-265°C;; washing with petroleum ether, extractn. of NaBH4 from the residue with liquid NH3 at -33°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: DE958646 , 1957 ; C., 1957 , p. 10305 Full Text Show Details

Callery Chemical Co.

Patent: GB774728 , 1957 ; C. A., 1957 , p. 14217 Full Text Show Details

in neat (no solvent) byproducts: B2H6; on passing a mixture of BF3 and H2 (ratio=1:2) over powdered NaH at about 180°C;;

Gmelin Handbook: Na: SVol.2, 90, page 801 - 803 Full Text Show Details

108

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Rx-ID: 26101911 Find similar reactions

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Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: DE958646 , 1957 ; C., 1957 , p. 10305 Full Text Show Details

Callery Chemical Co.

Patent: GB774728 , 1957 ; C. A., 1957 , p. 14217 Full Text Show Details

in mineral oil

at 250-265°C;; washing with petroleum ether, extractn. of NaBH4 from the residue with liquid NH3 at -33°C;;

109

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Rx-ID: 26101917 Find similar reactions

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A: 83%

in tetrahydrofuran

with excess NaH; at 65°C;

Gmelin Handbook: B: B-Verb.8, 8.2, page 109 - 115 Full Text Show Details

Petterson, L. L.; Steinberg, H.

in: H. Steinberg, Organoboron Chemistry, Vol. I, Interscience Publishers, John Wiley and Sons Inc., New York London - Sydney 1964, p. 610/24 Full Text Show Details

in tetrahydrofuran

on boiling in THF, pptn. of NaBH4;;

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

Brown, H. C.; Mead, E. J.; Shoaf, C. J.

Journal of the American Chemical Society, 1956 , vol. 78, p. 3616 - 3620 Full Text View citing articles Show Details

in tetrahydrofuran

on boiling in THF, pptn. of NaBH4;;

Brown, H. C.; Mead, E. J.

Journal of the American Chemical Society, 1953 , vol. 75, p. 6263 - 6265 Full Text View citing articles Show Details

Gmelin Handbook: Na: SVol.2, 92, page 805 - 807 Full Text Show Details

110

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Rx-ID: 26101937 Find similar reactions

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in mineral oil

at 250-265°C;; washing with petroleum ether, extractn. of NaBH4 from the residue with liquid NH3 at -33°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: DE958646 , 1957 ; C., 1957 , p. 10305 Full Text Show Details

Callery Chemical Co.

Patent: GB774728 , 1957 ; C. A., 1957 , p. 14217 Full Text Show Details

in neat (no solvent) byproducts: NaOC2H5; molar ratio NaH: B(OC2H5)3=4:1, at 225-275°C in an autoclave, extractn. with liquid NH3 or isopropylamine;; high purity;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C. A., 1951 , p. 4007 Full Text Show Details

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111

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with removing of Na<B(OCH3)4>;

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

Gmelin Handbook: B: B-Verb.8, 8.2, page 109 - 115 Full Text Show Details

in tetrahydrofuran

65°C, disproportionation, Na(BH4) insol. precipitation;

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

in diethylene glycol

disproportionation, Na(B(OCH3)4) precipitation;

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

Hide Details

in tetrahydrofuran

disproportion;

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

Brown, H. C.; Mead, E. J.; Shoaf, C. J.

Journal of the American Chemical Society, 1956 , vol. 78, p. 3616 - 3620 Full Text View citing articles Show Details

210-240°C; in vac.;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Gmelin Handbook: B: B-Verb.8, 8.2, page 109 - 115 Full Text Show Details

230°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

in tetrahydrofuran

230°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Gmelin Handbook: B: B-Verb.8, 8.2, page 109 - 115 Full Text Show Details

in tetrahydrofuran

precipitation of Na(BH4);

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

in tetrahydrofuran

in diethylene glycol

230°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Gmelin Handbook: B: B-Verb.8, 8.2, page 109 - 115 Full Text Show Details

in diethylene glycol

precipitation of Na(BH4);

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

in diethylene glycol

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

230°C;

Brown, H. C.; Schlesinger, H. I.; Sheet, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 192 - 195 Full Text View citing articles Show Details

in tetrahydrofuran

precipitation of Na(BH4);

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

230°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

in tetrahydrofuran

disproportion;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

in tetrahydrofuran

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

in diethylene glycol dimethyl ether

precipitation of Na(BH4);

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

in diethylene glycol dimethyl ether

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

in tetrahydrofuran

65°C, disproportionation, Na(BH4) insol. precipitation;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in diethylene glycol dimethyl ether

disproportionation, Na(B(OCH3)4) precipitation;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

112

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Rx-ID: 26379022 Find similar reactions

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Pearson, R. K.; Edwards, L. J.

N.S.A., CCC-1024-TR-213 (1956) 1/10 1957 , vol. 11, p. 3327 Full Text Show Details

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

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113

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Rx-ID: 26461277 Find similar reactions

A: >99

in further solvent(s) in boiling perhydrocumole;

Studiengesellschaft Kohle m.b.H.

Patent: DE1018397 , 1957 ; C., 1959 , p. 11376 Full Text Show Details

A: >99

in further solvent(s) in boiling perhydrocumole;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

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114

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in ammonia

-78°C;

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Koenig, F. J.

N.S.A., MCC-1023-TR-137 (1955) 17 1955 , vol. 9, p. 7262 Full Text Show Details

Koenig, F. J.

N.S.A., MCC-1023-TR-137 (1955) 57 1955 , vol. 9, p. 7262 Full Text Show Details

in ammonia

NH3 (liquid); Na(BH4) separated from NH2BH2 by evaporation and extraction with diethylene glycol dimethyl ether;

Schaeffer, G. W.; Adams, M. D.; Koenig, F. J.

Journal of the American Chemical Society, 1956 , vol. 78, p. 725 - 728 Full Text View citing articles Show Details

in ammonia

NH3 (liquid); -78°C;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Hide Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in ammonia

NH3 (liquid); Na(BH4) separated from NH2BH2 by evaporation and extraction with diethylene glycol dimethyl ether;

115

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Rx-ID: 26091409 Find similar reactions

>99

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Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schlesinger, H. I.; Brown, H. c.

Patent: US2461661 , 1949 ; C. A., 1949 , p. 4684 Full Text Show Details

Schlesinger,H. I.

N. S. A., A-796 (1943) 6 1956 , vol. 10, p. 3498 Full Text Show Details

in neat (no solvent) byproducts: B(OCH3)3; begin of react. at -80°C, fast react. at ambient temp., exclusion of air;;

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116

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A: >99

exclusion of air, from -80°C to room temp.;

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Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

Hoekstra, H. R.

N.S.A., The Preparation and Properties of Alkali Metal Borohydrides, AECD-2144 (1947) 14 1948 , vol. 1, p. 756 Full Text Show Details

Schlesinger, H. I.; Hoekstra, H. R.; Brown, H. C.

115th Meeting Am. Chem. Soc., 1949, Abstr. of Papers, S. 9-1O Full Text Show Details

A: >99

usual temp.; quick reactn.;

A: >99 B: >99

Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2461661 , 1949 ; C.A., 1949 , p. 4684 Full Text Show Details

Hoekstra, H. R.

N.S.A., AECD-2144 (1947) 1/45 1948 , vol. 1, p. 756 Full Text Show Details

Schlesinger, H. I.

N.S.A., A-796 (1943) 5 1956 , vol. 10, p. 3498 Full Text Show Details Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2461661 , 1949 ; C.A., 1949 , p. 4684 Full Text Show Details

Hide Details

A: >99

exclusion of air, from -80°C to room temp.;

Brown, H. C.; Schlesinger, H. I.; Sheet, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 192 - 195 Full Text View citing articles Show Details

A: >99

usual temp.; quick reactn.;

Brown, H. C.; Schlesinger, H. I.; Sheet, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 192 - 195 Full Text View citing articles Show Details

A: >99

usual temp.; quick reactn.;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

A: >99

exclusion of air, from -80°C to room temp.;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

A: >99 B: >99

Gmelin Handbook: B: B-Verb.8, 3.2.1, page 53 - 65 Full Text Show Details

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117

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Rx-ID: 26101914 Find similar reactions

With hydrogen in cyclohexane

3.49parts NaH, 14 parts B(C2H5)3, 50 parts cyclohexane, 240°C, 210 atm. H2-pressure, 3.5h;;

E. I. du Pont de Nemours

Patent: US2729540 , 1956 ; Full Text Show Details

With H2 in cyclohexane

3.49parts NaH, 14 parts B(C2H5)3, 50 parts cyclohexane, 240°C, 210 atm. H2-pressure, 3.5h;;

Gmelin Handbook: Na: SVol.2, 92, page 805 - 807 Full Text Show Details

118

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Rx-ID: 26101916 Find similar reactions

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Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

E. I. du Pont de Nemours & Co.

Patent: US2729540 , 1956 ; C. A., 1956 , p. 6758 Full Text Show Details

in cyclohexane

heating to about 240°C under H2-pressure, pptn. of NaBH4, filtration;; pure product after extractn. with isopropyl amine;;

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119

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120

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in tetrahydrofuran

on boiling;;

Brown, H. C.; Mead, E. J.; Shoaf, C. J.

Journal of the American Chemical Society, 1956 , vol. 78, p. 3616 - 3620 Full Text View citing articles Show Details

in tetrahydrofuran

on boiling;;

Gmelin Handbook: Na: SVol.2, 92, page 805 - 807 Full Text Show Details

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Rx-ID: 26106498 Find similar reactions

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Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2461661 , 1949 ; C.A., 1949 , p. 4684 Full Text Show Details

Hoekstra, H. R.

N.S.A., AECD-2144 (1947) 1/45 1948 , vol. 1, p. 756 Full Text Show Details

Schlesinger, H. I.

N.S.A., A-796 (1943) 5 1956 , vol. 10, p. 3498 Full Text Show Details

Brown, H. C.; Schlesinger, H. I.; Sheet, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 192 - 195 Full Text View citing articles Show Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 3.2.1, page 53 - 65 Full Text Show Details

121

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Rx-ID: 26110978 Find similar reactions

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Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: US2744810 , 1956 ; C. A., 1956 , p. 13386 Full Text Show Details

in neat (no solvent) spraying molten Na with H2 of 150-300°C in a room with BF3;;

122

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Synthesize Find similar Rx-ID: 26121497 Find similar reactions

B: >99

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Koester, R.

Ang. Chem., 1956 , vol. 68, p. 383 Full Text Show Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

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123

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in ammonia

NH3 (liquid);

Schaeffer, G. W.; Adams, M. D.; Koenig, F. J.

Journal of the American Chemical Society, 1956 , vol. 78, p. 725 - 728 Full Text View citing articles Show Details

in ammonia

NH3 (liquid);

Gmelin Handbook: Na: SVol.3, 1.5.5, page 947 - 953 Full Text Show Details

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124

Synthesize Find similar Rx-ID: 26091337 Find similar reactions

With sodium amalgam

by-products higher condensed Na-borhydride;

Stridde, G. E.

Diss. Rensselaer Polytechn. Inst. Troy, N. Y., 1955, S. 16 Full Text Show Details

Stridde, G. E.

N.S.A., MCC-1023-TR-136 (1955) 16 1955 , vol. 9, p. 7261 Full Text Show Details

With sodium amalgam

Stridde, G. E.

Diss. Rensselaer Polytechn. Inst. 1955, S. 16 Full Text Show Details

Stridde, G. E.

N.S.A., MCC-1023-TR-136 (1955) 16 1955 , vol. 9, p. 7261 Full Text Show Details

With Na-amalgam

Gmelin Handbook: Na: SVol.3, 3.6.2, page 1223 - 1233 Full Text Show Details

Hide Details

With Na-amalgam by-products higher condensed Na-borhydride;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

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125

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B: 60%

in neat (no solvent) on trituration at 330-350°C for 20-48h;;

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Gaylord, N. G.

Journal of the American Chemical Society, 1953 , vol. 75, p. 186 - 190 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; Full Text Show Details

Gaylord, N. G.

Reduction with Complex Metal Hydrides, New York-London 1956, S. 15 Full Text Show Details

B: 60%

in neat (no solvent) on trituration at 330-350°C for 20-48h;;

Gmelin Handbook: Na: SVol.2, 90, page 801 - 803 Full Text Show Details

heating at 330 - 350°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Hide Details

126

heating at 330 - 350°C;

Gmelin Handbook: Na: SVol.3, 3.9.1, page 1262 - 1270 Full Text Show Details

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Rx-ID: 26088881 Find similar reactions

byproducts: Na(B(OC2H5)4); disproportionation;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

byproducts: Na(B(OC2H5)4); disproportionation;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

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127

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A: <=85

exclusion of air, above -80°C;

Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

Hoekstra, H. R.

N.S.A., The Preparation and Properties of Alkali Metal Borohydrides, AECD-2144 (1947) 1/45 1948 , vol. 1, p. 756 Full Text Show Details

over -80°C;

Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

Hoekstra, H. R.

N.S.A., AECD-2144 (1947) 17 1948 , vol. 1, p. 756 Full Text Show Details

over -80°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

Hide Details

A: <=85

exclusion of air, above -80°C;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

128

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Rx-ID: 26088901 Find similar reactions

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78%

in neat (no solvent) heating to 250-270°C, excess NaH;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C. A., 1951 , p. 4007 Full Text Show Details

66%

in neat (no solvent) molar ratio NaH:NaB(OCH3)4=4:1, 250.C;; 91percent NaBH4;;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Brown, H. C.; Sheft, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 186 - 190 Full Text View citing articles Show Details

66%

in neat (no solvent) molar ratio NaH:NaB(OCH3)4=4:1, 250.C;; 91percent NaBH4;;

Gmelin Handbook: Na: SVol.2, 92, page 805 - 807 Full Text Show Details

Synthesize Find similar

129

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Rx-ID: 26088902 Find similar reactions

A: <=78

excess of NaH, 250 - 270°C; separated with isopropyl amine;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

250-270°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

A: <=78

excess of NaH, 250 - 270°C; separated with isopropyl amine;

Brown, H. C.; Schlesinger, H. I.; Sheet, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 192 - 195 Full Text View citing articles Show Details

Hide Details

250-270°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

A: <=78

excess of NaH, 250 - 270°C; separated with isopropyl amine;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

130

Synthesize Find similar

Rx-ID: 26091428 Find similar reactions

ambient temp., exothermic reaction;

Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

Hoekstra, H. R.

N.S.A., The Preparation and Properties of Alkali Metal Borohydrides, AECD-2144 (1947) S. 16 1948 , vol. 1, p. 756 Full Text Show Details

Schlesinger, H. I.; Hoekstra, H. R.; Brown, H. C.

115th Meeting Am. Chem. Soc., 1949, Abstr. of Papers, S. 9-1O Full Text Show Details

ambient temp., exothermic reaction;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

131

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Rx-ID: 26091638 Find similar reactions

byproducts: Na(B(OC4H9)4); disproportionation;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

byproducts: Na(B(OC4H9)4); disproportionation;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

132

Synthesize Find similar

Rx-ID: 26101906 Find similar reactions

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78%

in neat (no solvent) molar ratio NaH:NaBH(OCH3)3=3:1, 250-270°C;;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Brown, H. C.; Sheft, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 186 - 190 Full Text View citing articles Show Details

78%

in neat (no solvent) heating to 250-270°C, excess NaH;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C. A., 1951 , p. 4007 Full Text Show Details

78%

in neat (no solvent) molar ratio NaH:NaBH(OCH3)3=3:1, 250-270°C;;

Gmelin Handbook: Na: SVol.2, 92, page 805 - 807 Full Text Show Details

Hide Details

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

Brown, H. C.; Schlesinger, H. I.; Sheet, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 192 - 195 Full Text View citing articles Show Details

Gmelin Handbook: B: B-Verb.8, 3.2.1, page 53 - 65 Full Text Show Details

Synthesize Find similar

133

Synthesize Find similar

Rx-ID: 26101907 Find similar reactions

A: <=78

excess of NaH, 250 - 270°C; separated with isopropyl amine;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

250-270°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C.A., 1951 , p. 4007 Full Text Show Details

A: <=78

excess of NaH, 250 - 270°C; separated with isopropyl amine;

Brown, H. C.; Schlesinger, H. I.; Sheet, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 192 - 195 Full Text View citing articles Show Details

Hide Details

250-270°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

Sodium Trimethoxy Borohydride, Bull. 504-C Full Text Show Details

A: <=78

excess of NaH, 250 - 270°C; separated with isopropyl amine;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

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134

Synthesize Find similar Rx-ID: 26101922 Find similar reactions

Synthesize Find similar

molar ratio of NaH : B(OCH3)3 = 4 : 1, at 225 - 275°C, in low-pressure autoclave; extraction with NH3 (liquid) or isopropyl amine;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Hoekstra, H. R.; Brown, H. C.

115th Meeting Am. Chem. Soc., 1949, Abstr. of Papers, S. 9-1O Full Text Show Details

molar ratio of NaH : B(OCH3)3 = 4 : 1, at 225 - 275°C, in low-pressure autoclave; extraction with NH3 (liquid) or isopropyl amine;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

135

Synthesize Find similar

Rx-ID: 26101925 Find similar reactions

Synthesize Find similar

molar ratio of NaH : B(OCH3)3 = 4 : 1, at 225 - 275°C, in low-pressure autoclave;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Hoekstra, H. R.; Brown, H. C.

115th Meeting Am. Chem. Soc., 1949, Abstr. of Papers, S. 9-1O Full Text Show Details

molar ratio of NaH : B(OCH3)3 = 4 : 1, at 225 - 275°C, in low-pressure autoclave;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

136

Synthesize Find similar

Rx-ID: 26101938 Find similar reactions

molar ratio of NaH : B(OCH3)3 = 4 : 1, at 225 - 275°C, in low-pressure autoclave;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Hoekstra, H. R.; Brown, H. C.

115th Meeting Am. Chem. Soc., 1949, Abstr. of Papers, S. 9-1O Full Text Show Details

molar ratio of NaH : B(OCH3)3 = 4 : 1, at 225 - 275°C, in low-pressure autoclave;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

137

Synthesize Find similar Rx-ID: 26154035 Find similar reactions

Synthesize Find similar

byproducts: (CH3)2BH; equilibrium reaction, 230°C, disproportionation;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Hoekstra, H. R.; Brown, H. C.

115th Meeting Am. Chem. Soc., 1949, Abstr. of Papers, S. 9-1O Full Text Show Details

byproducts: (CH3)2BH; equilibrium reaction, 230°C, disproportionation;

Brown, H. C.; Schlesinger, H. I.; Sheet, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 192 - 195 Full Text View citing articles Show Details

byproducts: (CH3)2BH; equilibrium reaction, 230°C, disproportionation;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

138

Synthesize Find similar Rx-ID: 26375060 Find similar reactions

250°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

250°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

139

Synthesize Find similar Rx-ID: 26375062 Find similar reactions

Synthesize Find similar

240°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

240°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

Synthesize Find similar

140

Synthesize Find similar Rx-ID: 26384558 Find similar reactions

250°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

250°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

250°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

141

Synthesize Find similar Rx-ID: 26461269 Find similar reactions

Synthesize Find similar

230°C;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Hoekstra, H. R.; Brown, H. C.

115th Meeting Am. Chem. Soc., 1949, Abstr. of Papers, S.9-0 Full Text Show Details

230°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

142

Synthesize Find similar

Rx-ID: 26101893 Find similar reactions

Synthesize Find similar

85-90

in diethyl ether

0.05mol BF3*O(C2H5)2, 0.33mol NaH, abs. ether, at 125°C in a closed tube;;

Wittig, G.; Hornberger, P.

Liebigs Annalen der Chemie, 1952 , vol. 577, p. 11 - 25 Full Text Show Details

85-90

in diethyl ether

in abs. ether, at 125°C, in bomb-tube;

Wittig, G.; Hornberger, P.

Liebigs Annalen der Chemie, 1952 , vol. 577, p. 11 - 25 Full Text Show Details

85-90

in diethyl ether

in abs. ether, at 125°C, in bomb-tube;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Hide Details

85-90

Gmelin Handbook: Na: SVol.2, 90, page 801 - 803 Full Text Show Details

in diethyl ether

0.05mol BF3*O(C2H5)2, 0.33mol NaH, abs. ether, at 125°C in a closed tube;; A

143

Synthesize Find similar

Rx-ID: 26088049 Find similar reactions

Synthesize Find similar

in neat (no solvent) at 110°C;;

Gmelin Handbook: Na: SVol.2, 92, page 805 - 807 Full Text Show Details

in neat (no solvent) at 110°C;;

Burg, A. B.; Randolph, C. L.

Journal of the American Chemical Society, 1951 , vol. 73, p. 953 - 957 Full Text View citing articles Show Details

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144

Synthesize Find similar Rx-ID: 26101855 Find similar reactions

Synthesize Find similar

in neat (no solvent) byproducts: Na-hydrido fluoroborates; at 150-200°C;;

Bergmann, R.

Diss. Goettingen 1950, S. 11 Full Text Show Details

excess of NaH, 180 - 190°C;

Goubeau, J.; Bergmann, R.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1950 , vol. 163, p. 69 - 81 Full Text Show Details

excess of NaH, 180 - 190°C;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Hide Details

in neat (no solvent) byproducts: Na-hydrido fluoroborates; at 150-200°C;;

Gmelin Handbook: Na: SVol.2, 90, page 801 - 803 Full Text Show Details

145

Synthesize Find similar

Rx-ID: 26101926 Find similar reactions

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C. A., 1951 , p. 4007 Full Text Show Details

in neat (no solvent) molar ratio NaH: B(OC4H9)3=4:1, at 225-275°C in an autoclave, extractn. with liquid NH3 or isopropylamine;; high purity;;

146

Synthesize Find similar

Rx-ID: 26121841 Find similar reactions

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C. A., 1951 , p. 4007 Full Text Show Details

in neat (no solvent) molar ratio NaH: B(OC4H9)3=4:1, at 225-275°C in an autoclave, extractn. with liquid NH3 or isopropylamine;; high purity;;

147

Synthesize Find similar

Rx-ID: 26121879 Find similar reactions

in neat (no solvent)

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259

byproducts: NaOC2H5; molar ratio NaH: B(OC2H5)3=4:1, at 225-275°C in an autoclave, extractn. with liquid NH3 or isopropylamine;; high purity;;

Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C. A., 1951 , p. 4007 Full Text Show Details

Synthesize Find similar

148

Synthesize Find similar

Rx-ID: 26088898 Find similar reactions

Schlesinger, H. I.; Brown, H. C.

Patent: US2461661/3 , 1949 ; C.A., 1949 , p. 4684 Full Text Show Details

Gmelin Handbook: B: SVol.1, 4.1.5, page 112 - 115 Full Text Show Details

149

Synthesize Find similar

Rx-ID: 26091336 Find similar reactions

With sodium amalgam

X-ray;

Kasper, J. S.; McCarty, L. V.; Newkirk, A. E.

Journal of the American Chemical Society, 1949 , vol. 71, p. 2583 Full Text View citing articles Show Details

With sodium amalgam

shaking many hours;

Kasper, J. S.; McCarty, L. V.; Newkirk, A. E.

Journal of the American Chemical Society, 1949 , vol. 71, p. 2583 Full Text View citing articles Show Details

With sodium amalgam

ambient temp.;

Stock, A.; Laudenklos, H.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1936 , vol. 228, p. 178 - 192 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.1, page 1 - 2 Full Text Show Details

Stock, A.

Hydrides of Boron and Silicon, Cornell University Press, Ithaca - New York - London - Oxford 1933, p.138 Full Text Show Details

Stock, A.

Hydrides of Boron and Silicon, Cornell University Press, Ithaca - New York - London - Oxford 1933, pp. 141/9 Full Text Show Details

Hide Details

With sodium amalgame X-ray;

Gmelin Handbook: B: SVol.1, 4.1.5, page 112 - 115 Full Text Show Details

With Na-amalgam shaking many hours;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

150

Synthesize Find similar

Rx-ID: 26091408 Find similar reactions

Schlesinger, H. I.; Brown, H. C.

Patent: US2461661/3 , 1949 ; C.A., 1949 , p. 4684 Full Text Show Details

Gmelin Handbook: B: SVol.1, 4.1.5, page 112 - 115 Full Text Show Details

Synthesize Find similar

151

Synthesize Find similar Rx-ID: 26091426 Find similar reactions

Synthesize Find similar

Schlesinger, H. I.; Brown, H. C.

Patent: US2461661/3 , 1949 ; C.A., 1949 , p. 4684 Full Text Show Details

Gmelin Handbook: B: SVol.1, 4.1.5, page 112 - 115 Full Text Show Details

152

Synthesize Find similar

Rx-ID: 26091427 Find similar reactions

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2561662 , 1949 ; C. A., 1949 , p. 4684 Full Text Show Details

in neat (no solvent) byproducts: B(OCH3)3; at ambient temp., fast react., exothermic react.;;

153

Synthesize Find similar

Rx-ID: 26091407 Find similar reactions

Synthesize Find similar

Stock, A.; Laudenklos, H.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1936 , vol. 228, p. 178 - 192 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.1, page 1 - 2 Full Text Show Details

Stock, A.

Hydrides of Boron and Silicon, Cornell University Press, Ithaca - New York - London - Oxford 1933, p.138 Full Text Show Details

Stock, A.

Hydrides of Boron and Silicon, Cornell University Press, Ithaca - New York - London - Oxford 1933, pp. 141/9 Full Text Show Details

ambient temp.;

154

Synthesize Find similar

Rx-ID: 26070296 Find similar reactions

Schrauzer, G.

Diss. Muenchen 1956, S. 130 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 52 Full Text Show Details

in tetrahydrofuran

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in tetrahydrofuran

155

Synthesize Find similar

Rx-ID: 26070311 Find similar reactions

Synthesize Find similar

Schrauzer, G.

Diss. Muenchen 1956, S. 130 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 52 Full Text Show Details

in tetrahydrofuran

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in tetrahydrofuran

Synthesize Find similar

156

Synthesize Find similar Rx-ID: 26101942 Find similar reactions

A: 86-94

Synthesize Find similar

NaH heating in N2 atmoshpere to 220°C, addn. of B(OCH3) by stirring dropwisse (20-40 min) at 230-270°C, stirring 1 h, cooling, yield depending on quality of NaH; extraction with dry isopropyl amine or NH3, filtering, solvent evapn., purity 90-96 percent;

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

Becher, H. J.

in: G. Brauer, Handbuch der Praeparativen Anorganischen Chemie, 2. Edn., Vol. 1, Ferdinand Enke, Stuttgart 1960, pp.689/91 Full Text Show Details

157

Synthesize Find similar

Rx-ID: 26121919 Find similar reactions

Synthesize Find similar

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

Hinkley, A. A.

in: Kirk-Othmer, Encyclopedia of Chemical Technology, 2. Edn., Vol. 11, Interscience Publishers, New York London - Sidney 1966, pp. 210/7 Full Text Show Details

in water; mineral oil

Na suspended in mineral oil with water; yield depending on temp.; extraction with i-propylamine, drying, purity 98 percent;

158

Synthesize Find similar

Rx-ID: 26161996 Find similar reactions

Synthesize Find similar

Schrauzer, G.

Diss. Muenchen 1956, S. 130 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 52 Full Text Show Details

in tetrahydrofuran

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in tetrahydrofuran

Synthesize

159

Synthesize

Find similar Rx-ID: 26165427 Find similar reactions

Find similar

in tetrahydrofuran

ambient temp.;

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

in tetrahydrofuran

ambient temp.;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

160

Synthesize Find similar Rx-ID: 26165865 Find similar reactions

in tetrahydrofuran

ambient temp.;

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

in tetrahydrofuran

ambient temp.;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

161

Synthesize Find similar Rx-ID: 26167020 Find similar reactions

in tetrahydrofuran

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

thermic decompn.;

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

in tetrahydrofuran

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Hide Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

thermic decompn.;

Synthesize Find similar

162

Synthesize Find similar Rx-ID: 26167022 Find similar reactions

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

in tetrahydrofuran

thermic decompn.;

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

in tetrahydrofuran

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Hide Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

thermic decompn.;

163

Synthesize Find similar Rx-ID: 26167023 Find similar reactions

Synthesize Find similar

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

in tetrahydrofuran

thermic decompn.;

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

thermic decompn.;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Hide Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in tetrahydrofuran

Synthesize Find similar

164

Synthesize Find similar Rx-ID: 26167025 Find similar reactions

in tetrahydrofuran

thermic decompn.;

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

in tetrahydrofuran

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Hide Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

thermic decompn.;

Synthesize Find similar

165

Synthesize Find similar Rx-ID: 26167103 Find similar reactions

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

in tetrahydrofuran

thermic decompn.;

Schrauzer, G.

Diss. Muenchen 1956, S. 119/20 Full Text Show Details

Schrauzer, G.

Diss. Muenchen 1956, S. 46/7 Full Text Show Details

in tetrahydrofuran

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Hide Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

thermic decompn.;

166

Synthesize Find similar Rx-ID: 26484225 Find similar reactions

Synthesize Find similar

With NaC2H in ammonia

byproducts: C2H4;

Shore, S. G.; Hickam, C. W.

Abstr. Papers 141st Meeting Am. Chem. Soc., Washington, D.C., 1962, S. 5 M Full Text Show Details

With NaC2H in ammonia

byproducts: C2H4; NH3 (liquid);

Gmelin Handbook: B: B-Verb.4, 4.2.1, page 92 - 95 Full Text Show Details