Sodium borohydride (Sodium tetrahydroborate; NaBH4) [BH4Na] by Asch

Query Query 1. Query

BH–4

Na +

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Date

1 substances in Reaxys

2018-02-24 07h:05m:14s (EST)

Search as: As drawn AND (IDE.XRN=11343078)

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Reaxys ID 11343078 View in Reaxys

Na +

1/1 CAS Registry Number: 16940-66-2 Chemical Name: sodium tetrahydroborate; sodium tetrahydridoborate; sodium tetra hydroborate; sodium borotetrahydride; sodium tetrahydroboride; sodium tetrahydoborate; natrium boron hydride Linear Structure Formula: Na(1+)*[BH4](1-)=NaBH4 Molecular Formula: BH4*Na Molecular Weight: 37.8325 Type of Substance: Coordination compound; Isotope or isotope containing compound InChI Key: YOQDYZUWIQVZSF-UHFFFAOYSA-N Note:

BH–4

Substance Label (12) Label References SB

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Akent’eva; Makhmudov; Russian Journal of General Chemistry; vol. 87; nb. 7; (2017); p. 1631 - 1633; Zh. Obshch. Khim.; vol. 87; nb. 7; (2017); p. 1204 - 1206,3, View in Reaxys

SBH

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Ia-iii

Patent; Huang Linhai; huang, linhai; (13 pag.); CN105418576; (2016); (A) Chinese, View in Reaxys

NaBH4

Marcus, Andrew P.; Sarpong, Richmond; Organic Letters; vol. 16; nb. 12; (2014); p. 3420 - 3420, View in Reaxys; Hayakawa, Ichiro; Niida, Keisuke; Kigoshi, Hideo; Chemical Communications; vol. 51; nb. 58; (2015); p. 11568 - 11571, View in Reaxys; Placzek, Andrew T.; Scanlan, Thomas S.; Tetrahedron; vol. 71; nb. 35; (2015); p. 5946 - 5951; Art.No: 26767, View in Reaxys; Hojoh, Kentaro; Shido, Yoshinori; Nagao, Kazunori; Mori, Seiji; Ohmiya, Hirohisa; Sawamura, Masaya; Tetrahedron; vol. 71; nb. 37; (2015); p. 6519 - 6533; Art.No: 26766, View in Reaxys; Naveen; Babu, Srinivasarao Arulananda; Tetrahedron; vol. 71; nb. 40; (2015); p. 7758 - 7781; Art.No: 26906, View in Reaxys; Patent; Merck Sharp and Dohme Corp.; TANG, Haifeng; PASTERNAK, Alexander; YANG, Lihu; WALSH, Shawn, P.; PIO, Barbara; SHAHRIPOUR, Aurash; TEUMELSAN, Nardos; (111 pag.); EP2632465; (2015); (B1) English, View in Reaxys; Hunter, A. Christy; Patel, Shreyal; Dedi, Cinzia; Dodd, Howard T.; Bryce, Richard A.; Phytochemistry; vol. 119; (2015); p. 19 - 25, View in Reaxys

sodium borohydride

Picard, Sébastien; Clermont, Guillaume; Genin, Emilie; Blanchard-Desce, Mireille; Tetrahedron; vol. 71; nb. 7; (2015); p. 1088 - 1094, View in Reaxys

Patent; The United States of America, as represented by the Secretary of Agriculture; Sarker, Majher I.; Liu, Lin S.; (28 pag.); US2015/366212; (2015); (A1) English, View in Reaxys

NaBH&4%

Li, Derun; Wu, Zhicai; Yu, Yang; Ball, Richard G.; Guo, Liangqin; Sherer, Edward; He, Shuwen; Hong, Qingmei; Lai, Zhong; Qi, Hongbo; Truong, Quang; Yang, David X.; Chicchi, Gary G.; Tsao, Kwei-Lan; Trusca, Dorina; Trujillo, Maria; Pachanski, Michele; Eiermann, George J.; Howard, Andrew D.; Zhou, Yun-Ping; Zhang, Bei B.; Nargund, Ravi P.; Hagmann, William K.; ACS Medicinal Chemistry Letters; vol. 5; nb. 6; (2014); p. 690 - 695, View in Reaxys

Kiraly, Peter; Magnetic Resonance in Chemistry; vol. 50; nb. 9; (2012); p. 620 - 626, View in Reaxys

XXII

Patent; Chen, Li; Firooznia, Fariborz; Gillespie, Paul; He, Yun; Lin, Tai-An; So, Sung-Sau; Yun, HongYing; US2010/16368; (2010); (A1) English, View in Reaxys

NaBH4, sodium borohydride

Patent; INTERMUNE, INC.; WO2008/100867; (2008); (A2) English, View in Reaxys

iii

Patent; BIOAGENCY AG; WO2005/82873; (2005); (A2) German, View in Reaxys

Patent-Specific Data (17) Location in Patent References Patent; Zhejiang Hisun Pharmaceutical Co., Ltd.; Yan, Wei; Tong, Wanzeng; Wang, Jianping; Yang, Weiqiang; Qian, Hongguan; (7 pag.); US2016/137683; (2016); (A1) English, View in Reaxys

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Claim

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LogP

H Bond Donors

H Bond Acceptors

Rotatable Bonds

TPSA

Lipinski Number

Veber Number

Catalyst Investigation (4) 1 of 4

Investigated characteris- Catalytic activity tic(s) Type of reaction (Catalyst Investigation)

Reduction

Location

supporting information

Meninno, Sara; Volpe, Chiara; Lattanzi, Alessandra; Advanced Synthesis and Catalysis; vol. 358; nb. 17; (2016); p. 2845 - 2848, View in Reaxys 2 of 4

Investigated characteris- Catalytic activity tic(s) Type of reaction (Catalyst Investigation)

Reduction

Co-catalyst/co-substrate nickel boride name Zeynizadeh, Behzad; Zabihzadeh, Mehdi; Journal of the Iranian Chemical Society; vol. 12; nb. 7; (2015); p. 1221 1226; Art.No: 585, View in Reaxys 3 of 4

Investigated characteris- Catalytic activity tic(s) Type of reaction (Catalyst Investigation)

Hydrogenation

Yang, Hailong; Huo, Ningning; Yang, Ping; Pei, Hao; Lv, Hui; Zhang, Xumu; Organic Letters; vol. 17; nb. 17; (2015); p. 4144 - 4147, View in Reaxys 4 of 4

Investigated characteris- Diastereomeric excess tic(s) Type of reaction (Catalyst Investigation)

Reduction

Huy, Peter H.; Westphal, Julia C.; Koskinen, Ari M.P.; Beilstein Journal of Organic Chemistry; vol. 10; (2014); p. 369 - 383, View in Reaxys Purification (2) Purification (method) purification described

References Mirsaidov, U.; Badalov, A.; Khikmatov, M.; Nazarov, K.; Marufi, V. K.; Russian Journal of Physical Chemistry; vol. 65; nb. 11; (1991); p. 1543 - 1545; Zhurnal Fizicheskoi Khimii; vol. 65; (1991); p. 2914 - 2919, View in Reaxys; Borisov, A. P.; Makhaev, V. D.; Lobkovskii, E. B.; Semenenko, K. N.; Russian Journal of

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Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 31; (1986); p. 47 - 51; Zhurnal Neorganicheskoi Khimii; vol. 31; (1986); p. 86 - 92 ; (from Gmelin), View in Reaxys purification described

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209, View in Reaxys; Khain, V. S.; Volkov, A. A.; Martynova, V. F.; Inorganic Materials (Transl. of Neorg. Mater.); vol. 24; (1988); p. 342 346; Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy; vol. 24; (1988); p. 423 - 426, View in Reaxys; vol. Na: SVol.1; 61, page 259 - 261, View in Reaxys; Patent; Banus, M. D.; Gibb, T. R. P.; Metal Hydrides Inc.; US2542746; (1951); C. A.; (1951); p. 4415, View in Reaxys; Patent; Bragdon, R. W.; Metal Hydrides Inc.; US2883263; (1959); C. A.; (1959); p. 15504, View in Reaxys; Patent; Bragdon, R. W.; Metal Hydrides Inc.; US2901333; (1959); C. A.; (1959); p. 22788, View in Reaxys; Patent; Bragdon, R. W.; Metal Hydrides Inc.; US2926991; (1960); C. A.; (1960); p. 11411, View in Reaxys; Patent; Gangl, K.; Koenig, J.; Farbwerke Hoechst A.-G. vorm. Meister Lucius & Bruening; DE939147; (1956); C. A.; (1958); p. 14112, View in Reaxys; Patent; Geyer, A. M.; Societe d'Electrochimie, d'Electrometallurgie et des Acieries El; FR1203918; (1960); C. A.; (1961); p. 20353, View in Reaxys; Patent; Gibb, T. R. P.; Metal Hydrides Inc.; US2615788; (1952); C. A.; (1953); p. 5646, View in Reaxys; Patent; Lang, K.; Schubert, F.; Farbenfabriken Bayer A.-G.; DE1051254; (1959), View in Reaxys; Patent; Lang, K.; Schubert, F.; Farbenfabriken Bayer A.-G.; GB838842; (1960); C. A.; (1960); p. 25629, View in Reaxys; Patent; Vetrano, J. B.; Bragdon, R. W.; Metal Hydrides Inc.; US2856274; (1958); C. A.; (1959); p. 2556, View in Reaxys; Patent; Wade, R. C.; McSharry, J. J.; Banus, M. D.; Metal Hydrides Inc.; US2942934; (1960); C. A.; (1960); p. 25637, View in Reaxys; Patent; Winiarczyk, E. R.; Metal Hydrides Inc.; US2900240; (1959); C. A.; (1959); p. 22788, View in Reaxys; Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 19 ; (from Gmelin), View in Reaxys

Melting Point (5) 1 of 5

Melting Point [°C]

85 - 86

Gangar, Mukesh; Ittuveetil, Avinash; Goyal, Sandeep; Pal, Anang; Harikrishnan; Nair, Vipin A.; RSC Advances; vol. 6; nb. 104; (2016); p. 102116 - 102126, View in Reaxys 2 of 5

Melting Point [°C]

542 - 550

Comment (Melting Point)

with decomposition

Olsen, Jorn Eirik; Sorby, Magnus H.; Hauback, Bjorn C.; Journal of Alloys and Compounds; vol. 509; nb. 24; (2011); p. L228-L231 ; (from Gmelin), View in Reaxys 3 of 5

Melting Point [°C]

496.84

Nakamori, Yuko; Orimo, Shin-ichi; Journal of Alloys and Compounds; vol. 370; nb. 1-2; (2004); p. 271 - 275 ; (from Gmelin), View in Reaxys 4 of 5

Melting Point [°C]

505

Fedneva, E. M.; Alpatova, V. I.; Mikheeva, V. I.; Zhurnal Neorganicheskoi Khimii; vol. 9; (1964); p. 826 - 827; Zhurnal Neorganicheskoi Khimii; vol. 9; (1964); p. 1519 - 1520, View in Reaxys; Mikheeva, V. I.; Arkhipov, S. M.; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 805 - 810; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 1506 1514, View in Reaxys; Mikheeva, V. I.; Selivokhina, M. S.; Kryukovaa, O. N.; Zhurnal Neorganicheskoi Khimii; vol. 7; (1962); p. 838 - 840; Zhurnal Neorganicheskoi Khimii; vol. 7; (1962); p. 1622 - 1627, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 5 of 5

Melting Point [°C]

500

Comment (Melting Point)

with decomposition

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Callery, Chemical, Co.Sodium Borohydride, Techn. Bull. C-110 (1957) 2 ; (from Gmelin), View in Reaxys Refractive Index (3) Refractive Index Temperature (Refractive Index) [°C]

Comment (Refractive Index)

References

1.542

white light

Stockmayer, W. H.; Rice, D. W.; Stephenson, C. C.; Journal of the American Chemical Society; vol. 77; (1955); p. 1980 - 1983, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

Becke-line

Banus, M. D.; Bragdon, R. W.; Hinckley, A. A.; Journal of the American Chemical Society; vol. 76; (1954); p. 3848 - 3849, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

1.547

Banus, M. D.; Bragdon, R. W.; Hinckley, A. A.; Journal of the American Chemical Society; vol. 76; (1954); p. 3848 - 3849,

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2018-02-24 07:07:56

View in Reaxys; vol. B: B-Verb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys Density (6) 1 of 6

Density [g·cm-3]

1.09

Measurement Temperature [°C]

-73.16

Type (Density)

crystallographic

Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys 2 of 6

Density [g·cm-3]

1.08

Type (Density)

crystallographic

Davis, W. D.; Mason, L. S.; Stegemann, G.; Journal of the American Chemical Society; vol. 71; (1949); p. 2775 2781, View in Reaxys; James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; Mikheeva, V. I.; Arkhipov, S. M.; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 805 - 810; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 1506 - 1514, View in Reaxys; vol. B: B-Verb.8; 1.6, page 34 44 ; (from Gmelin), View in Reaxys 3 of 6

Density [g·cm-3]

1.04

Measurement Temperature [°C]

Type (Density)

crystallographic

Density [g·cm-3]

1.06

Type (Density)

crystallographic

Neal, H. R.; Beatty, H. A.; Techn. Rep.; vol. 17; (1952); p. 201, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 1222, View in Reaxys; Neal, H. R.; Beatty, H. A.; PB 106606, LTD 44-20 (1944) 2 ; (from Gmelin), View in Reaxys 5 of 6

Density [g·cm-3]

1.08

Measurement Temperature [°C]

Type (Density)

crystallographic

Davis, W. D.; Mason, L. S.; Stegemann, G.; Journal of the American Chemical Society; vol. 71; (1949); p. 2775 2781, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys 6 of 6

Density [g·cm-3]

1.074

Type (Density)

crystallographic

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Soldate, A. M.; Journal of the American Chemical Society; vol. 69; (1947); p. 987 - 988 ; (from Gmelin), View in Reaxys Adsorption (MCS) (5) 1 of 5

Description (Adsorption (MCS))

Adsorption

Partner (Adsorption (MCS))

Pd nanoparticles on the surface of dextran-coated magnetite particles

Lara, Luciano R. S.; Zottis, Alexandre D.; Elias, Welman C.; Faggion, Deonildo; Maduro De Campos, Carlos Eduardo; Acua, Jose Javier S.; Domingos, Josiel B.; RSC Advances; vol. 5; nb. 11; (2015); p. 8289 - 8296, View in Reaxys 2 of 5

Description (Adsorption (MCS))

Adsorption

Partner (Adsorption (MCS))

CoAl2O4 nanoparticles

Bayal, Nisha; Jeevanandam; Journal of Alloys and Compounds; vol. 516; (2012); p. 27 - 32 ; (from Gmelin), View in Reaxys

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3 of 5

Description (Adsorption (MCS))

Adsorption

Partner (Adsorption (MCS))

NiAl2O4 nanoparticles

Bayal, Nisha; Jeevanandam; Journal of Alloys and Compounds; vol. 516; (2012); p. 27 - 32 ; (from Gmelin), View in Reaxys 4 of 5

Description (Adsorption (MCS))

Adsorption

Partner (Adsorption (MCS))

CuAl2O4 nanoparticles

Bayal, Nisha; Jeevanandam; Journal of Alloys and Compounds; vol. 516; (2012); p. 27 - 32 ; (from Gmelin), View in Reaxys 5 of 5

Description (Adsorption (MCS))

Adsorption to title compound

Comment (Adsorption (MCS))

sorption diagram

Partner (Adsorption (MCS))

Mao; Yu; Guo; Liu; Wu; Ni; Journal of Alloys and Compounds; vol. 479; nb. 1-2; (2009); p. 619 - 623, View in Reaxys; Ampoumogli; Steriotis, Th.; Trikalitis; Giasafaki; Bardaji, E. Gil; Fichtner; Charalambopoulou; Journal of Alloys and Compounds; vol. 509; nb. SUPPL. 2; (2011); p. S705-S708 ; (from Gmelin), View in Reaxys Association (MCS) (3) 1 of 3

Description (Association Association with compound (MCS)) Solvent (Association (MCS))

ethanol; water

Temperature (Association (MCS)) [°C]

Partner (Association (MCS))

C33H45BF2I2N2O8

Keum, Dongho; Kim, Sungwoo; Kim, Youngmi; Chemical Communications; vol. 50; nb. 10; (2014); p. 1268 1270, View in Reaxys 2 of 3

Description (Association Association with compound (MCS)) Solvent (Association (MCS))

chlorobenzene

Partner (Association (MCS))

C32H70O13Si2

Gierczyk, Blazej; Schroeder, Grzegorz; Ceglowski, Michal; Journal of Physical Organic Chemistry; vol. 26; nb. 4; (2013); p. 306 - 314, View in Reaxys 3 of 3

Description (Association Association with compound (MCS)) Solvent (Association (MCS))

chlorobenzene

Partner (Association (MCS))

C60H128O28Si4

Gierczyk, Blazej; Schroeder, Grzegorz; Ceglowski, Michal; Journal of Physical Organic Chemistry; vol. 26; nb. 4; (2013); p. 306 - 314, View in Reaxys Circular Dichroism (1) Comment (Circu- References lar Dichroism) Circular dichroism Kuhn, Alexander; Fischer, Peer; Angewandte Chemie, International Edition; vol. 48; nb. 37; (2009); p. 6857 given - 6860; Angewandte Chemie; vol. 121; nb. 37; (2009); p. 6989 - 6992, View in Reaxys Conformation (1)

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Object of Investigation

References

Conformation

Kawashima, Yoshiyuki; Yamada, Chikashi; Hirota, Eizi; Journal of Chemical Physics; vol. 94; nb. 12; (1991); p. 7707 - 7712, View in Reaxys; Silver, A. H.; Bray, P. J.; Journal of Chemical Physics; vol. 32; (1960); p. 288 - 292, View in Reaxys; vol. B: SVol.1; 4.1.5, page 112 - 115, View in Reaxys; Ogg. R. A.; Journal of Chemical Physics; vol. 22; (1954); p. 1933 - 1935, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 1222, View in Reaxys; Emery, A. R.; Diss. Univ. of Michigan 1957; Diss. Abstr.; vol. 18; (1958); p. 1995, View in Reaxys; Hansen, K. H.; Theoretica Chimica Acta; vol. 6; (1966); p. 437 - 444, View in Reaxys; Coker, E. H.; Hofer, D. E.; Journal of Chemical Physics; vol. 48; (1958); p. 2713 - 2719, View in Reaxys; Harris, P. M.; Meibohm, E. P.; Journal of the American Chemical Society; vol. 69; (1947); p. 1231 - 1232, View in Reaxys; Soldate, A. M.; Journal of the American Chemical Society; vol. 69; (1947); p. 987 - 988, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18, View in Reaxys; Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys

Crystal Phase (9) Description (Crys- References tal Phase) Interplanar spacing

Zhu, Qi-Yong; Zhu, Chuan-Gao; Wang, Feng-Wu; Wei, Yi-Jun; Asian Journal of Chemistry; vol. 25; nb. 14; (2013); p. 7749 - 7752, View in Reaxys; Wu, Yong; Qi, Yue; Chen, Jun; Fu, He; Zheng, Jie; Li, Xingguo; RSC Advances; vol. 6; nb. 105; (2016); p. 103299 - 103303, View in Reaxys; Huang, Miaojun; Zhong, Hao; Ouyang, Liuzhang; Peng, Chenghong; Zhu, Xiaoke; Zhu, Weiheng; Fang, Fang; Zhu, Min; Journal of Alloys and Compounds; vol. 729; (2017); p. 1079 - 1085, View in Reaxys

Powder X-ray Dif- Mal'tseva; Golovanova; Russian Journal of Inorganic Chemistry; vol. 41; nb. 8; (1996); p. 1221 - 1224, fraction View in Reaxys; Renaudin; Gomes; Hagemann; Keller; Yvon; Journal of Alloys and Compounds; vol. 375; nb. 1-2; (2004); p. 98 - 106, View in Reaxys; Varin; Chiu; Journal of Alloys and Compounds; vol. 397; nb. 1-2; (2005); p. 276 - 281, View in Reaxys; Kumar, Ravhi S.; Cornelius, Andrew L.; Applied Physics Letters; vol. 87; nb. 26; (2005); p. 1 - 3; Art.No: 261916, View in Reaxys; Varin; Chiu; Wronski; Journal of Alloys and Compounds; vol. 462; nb. 1-2; (2008); p. 201 - 208, View in Reaxys; Ravnsbaek, Dorthe B.; Rude, Line H.; Jensen, Torben R.; Journal of Solid State Chemistry; vol. 184; nb. 7; (2011); p. 1858 - 1866, View in Reaxys; Matsuo, Motoaki; Kuromoto, Shingo; Sato, Toyoto; Oguchi, Hiroyuki; Takamura, Hitoshi; Orimo, Shin-Ichi; Applied Physics Letters; vol. 100; nb. 20; (2012); Art.No: 203904 ; (from Gmelin), View in Reaxys Crystal growth forms

Bulavchenko; Demidova; Podlipskaya; Tatarchuk; Druzhinina; Alekseev; Logvinenko; Drebushchak; Russian Journal of Inorganic Chemistry; vol. 57; nb. 6; (2012); p. 769 - 776 ; (from Gmelin), View in Reaxys

NaCl; Powder Xray Diffraction

Olsen, Jorn Eirik; Sorby, Magnus H.; Hauback, Bjorn C.; Journal of Alloys and Compounds; vol. 509; nb. 24; (2011); p. L228-L231 ; (from Gmelin), View in Reaxys

Crystal growth

Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 3133 ; (from Gmelin), View in Reaxys

Single Crystal Xray Diffraction

Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 3133 ; (from Gmelin), View in Reaxys

Structure of the solid

Price, W. C.; Longuet-Higgins, H. C.; Rice, B.; Young, T. F.; Journal of Chemical Physics; vol. 17; (1949); p. 217 - 218, View in Reaxys; Price, W. C.; Journal of Chemical Physics; vol. 17; (1949); p. 1044 - 1052, View in Reaxys; Schrauzer, G. N.; Naturwissenschaften; vol. 42; (1955); p. 438, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Soldate, A. M.; Journal of the American Chemical Society; vol. 69; (1947); p. 987 - 988, View in Reaxys; Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys

crystal defects

Herley, Patrick J.; Jones, William; Zeitschrift fuer Physikalische Chemie (Muenchen, Germany); vol. 147; (1986); p. 147 - 160 ; (from Gmelin), View in Reaxys

crystal energy

Altshuller, A. P.; Journal of the American Chemical Society; vol. 77; (1955); p. 5455 - 5457, View in Reaxys; Mikheeva, V. I.; Arkhipov, S. M.; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 805 - 810; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 1506 - 1514, View in Reaxys; vol. B: B-Verb.8; 1.2.2, page 5 - 6, View in Reaxys; vol. B: B-Verb.8; 1.6, page 34 - 44, View in Reaxys; Rossini, F. D.; Wagman, D. D.; Evans, W. H.; Levine, S.; Jaffe, I.; Natl. Bur. Std. (U.S.) Circ. Nr. 500 (1952) 803, View in Reaxys; Wagman, D. D.; Munson, T.; Evans, W. H.; Prosen, E. J.; Natl. Bur. Std. (U.S.) Rept. Nr. 3456 (1954) ; (from Gmelin), View in Reaxys

Crystal Property Description (4) Colour & Other Point group Properties pink

References McIntosh, John A.; Coelho, Pedro S.; Farwell, Christopher C.; Wang, Z. Jane; Lewis, Jared C.; Brown, Tristan R.; Arnold, Frances H.; Angewandte Chemie - International Edition; vol. 52; nb. 35; (2013); p. 9309 - 9312, View in Reaxys

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white

Patent; WILEY ORGANICS, INC.; US2008/15374; (2008); (A1) English, View in Reaxys; Hurd, D. T.; Journal of the American Chemical Society; vol. 71; (1949); p. 20 - 22, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Gaylord, N. G.; Reduction with Complex Metal Hydrides, New York 1956, S. 17, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Bull. 502-E., View in Reaxys; Gibb, T. R. P.; Journal of Chemical Education; vol. 25; (1948); p. 577 - 582, View in Reaxys; Gibb, T. R. P.; Journal of the Electrochemical Society; vol. 93; (1948); p. 198 - 211, View in Reaxys; Brown, H. C.; Tierney, P. A.; Journal of the American Chemical Society; vol. 80; (1958); p. 1552 - 1558, View in Reaxys; Makhaev, V. D.; Borisov, A. P.; Karpova, T. P.; Petrova, L. A.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 40; (1995); p. 90 - 93; Zhurnal Neorganicheskoi Khimii; vol. 40; (1995); p. 94 - 97, View in Reaxys; Li; Liu; Zhu; Morigasaki; Suda; Journal of Alloys and Compounds; vol. 437; nb. 1-2; (2007); p. 311 - 316, View in Reaxys; Somer, Mehmet; Acar, Selcuk; Koz, Cevriye; Kokal, Ilkin; Hoehn, Peter; Cardoso-Gil, Raul; Aydemir, Umut; Akselrud, Lev; Journal of Alloys and Compounds; vol. 491; nb. 1-2; (2010); p. 98 - 105, View in Reaxys; vol. Na: SVol.2; 90, page 801 - 803 ; (from Gmelin), View in Reaxys Td

pale brown

Heynes, A. M.; Schutte, C. S. H.; Scheuermann, W.; Journal of Molecular Structure; vol. 9; (1971); p. 271 - 281, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Bull. 502-E. ; (from Gmelin), View in Reaxys

Crystal System (2) Crystal System References Cubic

Renaudin; Gomes; Hagemann; Keller; Yvon; Journal of Alloys and Compounds; vol. 375; nb. 1-2; (2004); p. 98 - 106, View in Reaxys; Varin; Chiu; Wronski; Journal of Alloys and Compounds; vol. 462; nb. 1-2; (2008); p. 201 - 208, View in Reaxys; Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133, View in Reaxys; Olsen, Jorn Eirik; Sorby, Magnus H.; Hauback, Bjorn C.; Journal of Alloys and Compounds; vol. 509; nb. 24; (2011); p. L228-L231, View in Reaxys; Ravnsbaek, Dorthe B.; Rude, Line H.; Jensen, Torben R.; Journal of Solid State Chemistry; vol. 184; nb. 7; (2011); p. 1858 - 1866, View in Reaxys; Matsuo, Motoaki; Kuromoto, Shingo; Sato, Toyoto; Oguchi, Hiroyuki; Takamura, Hitoshi; Orimo, Shin-Ichi; Applied Physics Letters; vol. 100; nb. 20; (2012); Art.No: 203904 ; (from Gmelin), View in Reaxys

Rhombic

Kumar, Ravhi S.; Cornelius, Andrew L.; Applied Physics Letters; vol. 87; nb. 26; (2005); p. 1 - 3; Art.No: 261916 ; (from Gmelin), View in Reaxys

Decomposition (3) 1 of 3

Decomposition [°C]

542 - 550

Olsen, Jorn Eirik; Sorby, Magnus H.; Hauback, Bjorn C.; Journal of Alloys and Compounds; vol. 509; nb. 24; (2011); p. L228-L231 ; (from Gmelin), View in Reaxys 2 of 3

Decomposition [°C]

610

Konoplev, V. N.; Silina, T. A.; Sizareva, A. S.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 18; (1992); p. 439 - 440; Koordinatsionnaya Khimiya; vol. 18; (1992); p. 508 - 510 ; (from Gmelin), View in Reaxys 3 of 3

Decomposition [°C]

315

Titova; Russian Journal of Inorganic Chemistry; vol. 47; nb. 8; (2002); p. 1121 - 1129 ; (from Gmelin), View in Reaxys

Electrical Data (3) 1 of 3

Description (Electrical Data)

Electrical conductivity

Electric Conductivity [S/cm]

2E-10

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Temperature of Electric Conductivity [°C]

26.84

Matsuo, Motoaki; Oguchi, Hiroyuki; Sato, Toyoto; Takamura, Hitoshi; Tsuchida, Eiji; Ikeshoji, Tamio; Orimo, Shin-Ichi; Journal of Alloys and Compounds; vol. 580; nb. SUPPL1; (2013); p. S98-S101, View in Reaxys 2 of 3

Description (Electrical Data)

Electrical conductivity

Electric Conductivity [S/cm]

1E-10

Comment (Electrical Da- electric conductivity diagram ta) Matsuo, Motoaki; Kuromoto, Shingo; Sato, Toyoto; Oguchi, Hiroyuki; Takamura, Hitoshi; Orimo, Shin-Ichi; Applied Physics Letters; vol. 100; nb. 20; (2012); Art.No: 203904 ; (from Gmelin), View in Reaxys 3 of 3

Description (Electrical Data)

Electrical conductivity

Comment (Electrical Da- electric conductivity diagram ta) Wakamori; Sawaoka; Filipek; Baranowski; Journal of the less-common metals; vol. 88; nb. 1; (1982); p. 217 220 ; (from Gmelin), View in Reaxys Electrochemical Behaviour (1) Description (Elec- References trochemical Behaviour) acid / base behaviour

vol. Na: SVol.3; 3.6.2, page 1223 - 1233, View in Reaxys; Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 24, View in Reaxys; Neal, H. R.; Beatty, H. A.; PB 106606, LTD 44-20 (1955) 4 ; (from Gmelin), View in Reaxys

Electrochemical Characteristics (6) 1 of 6

Description (Electrochemical Characteristics)

cyclovoltammetry

Solvent (Electrochemical Characteristics)

dimethyl sulfoxide

Comment (Electrochem- Other electrode; potential diagram ical Characteristics) Cardoso; Sequeira; Bateman; Barker; Abbey; Santos; Journal of the Electrochemical Society; vol. 164; nb. 4; (2017); p. H159 - H163, View in Reaxys 2 of 6

Description (Electrochemical Characteristics)

cyclovoltammetry

Solvent (Electrochemical Characteristics)

dichloromethane

Comment (Electrochem- Ferrocene/ferrocenium; potential diagram; 0.1M TBAP ical Characteristics) Baldoli, Clara; Bertuolo, Stefania; Licandro, Emanuela; Viglianti, Lucia; Mussini, Patrizia; Marotta, Gabriele; Salvatori, Paolo; De Angelis, Filippo; Manca, Paola; Manfredi, Norberto; Abbotto, Alessandro; Dyes and Pigments; vol. 121; (2015); p. 351 - 362, View in Reaxys 3 of 6

Description (Electrochemical Characteristics)

cyclovoltammetry

Comment (Electrochem- other electrode; potential diagram; 1 M NaOH ical Characteristics) Kiran, Vankayala; Kalidindi, Suresh Babu; Jagirdar, Balaji Rao; Sampath, Srinivasan; Electrochimica Acta; vol. 56; nb. 28; (2011); p. 10493 - 10499 ; (from Gmelin), View in Reaxys 4 of 6

Description (Electrochemical Characteristics)

cyclovoltammetry

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Solvent (Electrochemical Characteristics)

not given

pH-Value (Electrochemi- 13 cal Characteristics) Temperature (Electrochemical Characteristics) [°C]

19 - 21

Comment (Electrochem- other electrode; potential diagram; 0.1 M NaOH ical Characteristics) Chatenet; Molina-Concha; Diard; Electrochimica Acta; vol. 54; nb. 6; (2009); p. 1687 - 1693 ; (from Gmelin), View in Reaxys 5 of 6

Description (Electrochemical Characteristics)

cyclovoltammetry

Solvent (Electrochemical Characteristics)

sodium hydroxide

Comment (Electrochem- aq. NaOH; saturated silver chloride electrode; potential diagram ical Characteristics) Gyenge, Elod; Electrochimica Acta; vol. 49; nb. 6; (2004); p. 965 - 978 ; (from Gmelin), View in Reaxys 6 of 6

Description (Electrochemical Characteristics)

cyclovoltammetry

Solvent (Electrochemical Characteristics)

not given

Comment (Electrochem- transmitted electrons: 2; saturated calomel electrode (SCE); -0.045 V ical Characteristics) Shundo, Ryushi; Matsubara, Yoshiharu; Nishiguchi, Ikuzo; Hirashima, Tsuneaki; Chemistry Letters; (1989); p. 2033 - 2036 ; (from Gmelin), View in Reaxys Electrochemistry Data (3) Electrochemical References Cell Zn/NaBH4, NaOH/HCl, H2O2/Pt

Santos; Sequeira; Journal of the Electrochemical Society; vol. 157; nb. 1; (2010); p. B13-B19 ; (from Gmelin), View in Reaxys

F-AB2 alloy/ NaBH4 10 wtpercent, NaOH 20 wtpercent, H2 2.1 wtpercent/Pt

Li; Liu; Arai; Morigazaki; Suda; Journal of Alloys and Compounds; vol. 356-357; (2003); p. 469 - 474 ; (from Gmelin), View in Reaxys

ZrCr0.8Ni1.2, Cu or Ni powder, Teflon powder/ NaBH4, 6 M KOH/platinumdispersed carbon (air or O2)

Lee, Sang-Min; Kim, Jin-Ho; Lee, Han-Ho; Lee, Paul S.; Lee, Jai-Young; Journal of the Electrochemical Society; vol. 149; nb. 5; (2002); p. A603-A606 ; (from Gmelin), View in Reaxys

Electron Binding (1) Description (Elec- References tron Binding) Electronic states

Baldoli, Clara; Bertuolo, Stefania; Licandro, Emanuela; Viglianti, Lucia; Mussini, Patrizia; Marotta, Gabriele; Salvatori, Paolo; De Angelis, Filippo; Manca, Paola; Manfredi, Norberto; Abbotto, Alessandro; Dyes and Pigments; vol. 121; (2015); p. 351 - 362, View in Reaxys

Enthalpy of Formation (5) Enthalpy of ForTemperature (Enmation [Jmol-1] thalpy of Formation) [°C]

Pressure (Enthalpy of Formation) [Torr]

References

-190940

760

Davis, W. D.; Mason, L. S.; Stegemann, G.; Journal of the American Chemical Society; vol. 71; (1949); p. 2775 - 2781,

25.01

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View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Pack, D. H.; Hill, G. R.; MCC-1023-TR-169 (1955) 48; N.S.A.; vol. 10; (1956); p. 1721 ; (from Gmelin), View in Reaxys -193160

25.01

760

Gunn, S. R.; Green, L. G.; Journal of the American Chemical Society; vol. 77; (1955); p. 6197 - 6198, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Gunn, S. R.; Green, L. G.; UCRL-4527 (1955) 1/5; N.S.A.; vol. 9; (1955); p. 6599, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 10 ; (from Gmelin), View in Reaxys

-181990

25.01

760

Rossini, F. D.; Wagman, D. D.; Evans, W. E.; Levine, S.; Jaffe, I.; Natl. Bur. Std. Circ. (U. S.); nb. 500; (1952); p. 481 - 481, View in Reaxys; Rossini, F. D.; Wagman, D. D.; Evans, W. E.; Levine, S.; Jaffe, I.; Natl. Bur. Std. (U. S.) Circ.; nb. 500; (1952); p. 1002, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Latimer, W. M.; The Oxidation States of Elements and Their Potentials in Aqueous Solutions, 2. Aufl., New York 1952, S. 332 ; (from Gmelin), View in Reaxys

-183450

25.01

760

Davis, W. D.; Mason, L. S.; Stegemann, G.; Journal of the American Chemical Society; vol. 71; (1949); p. 2775 - 2781, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

-183300

25.01

760

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Bull. 502-E. ; (from Gmelin), View in Reaxys

Comment (Further Information)

References

Further Information (42) Description (Fur- Additional Dether Information) scription Behaviour as catalyst

Becker, Michael H.; Chua, Peter; Downham, Robert; Douglas, Christopher J.; Garg, Neil K.; Hiebert, Sheldon; Jaroch, Stefan; Matsuoka, Richard T.; Middleton, Joy A.; Ng, Fay W.; Overman, Larry E.; Journal of the American Chemical Society; vol. 129; nb. 39; (2007); p. 11987 - 12002 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Organ, Michael G.; Mallik, Debasis; Canadian Journal of Chemistry; vol. 84; nb. 10; (2006); p. 1259 - 1262 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Griffiths, Jon-Paul; Nie, Hui; Brown, R. James; Day, Peter; Wallis, John D.; Organic and Biomolecular Chemistry; vol. 3; nb. 11; (2005); p. 2155 - 2166 ; (from Gmelin), View in Reaxys Economical data

Suda; Morigasaki; Iwase; Li; Journal of Alloys and Compounds; vol. 404-406; nb. SPEC. ISS.; (2005); p. 643 - 647 ; (from Gmelin), View in Reaxys

Economical data

Li; Liu; Arai; Suda; Journal of Alloys and Compounds; vol. 404-406; nb. SPEC. ISS.; (2005); p. 648 - 652 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Dardonville, Christophe; Gilbert, Ian H; Organic and biomolecular chemistry; vol. 1; nb. 3; (2003); p. 552 - 559 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Coquerel, Yoann; Depres, Jean-Pierre; Chemical Communications; nb. 6; (2002); p. 658 - 659 ; (from Gmelin), View in Reaxys Economical data

Doyle, Marc; Arora, Pankaj; Journal of the Electrochemical Society; vol. 148; nb. 11; (2001); p. K1-K41 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Sarkar, Tarun K.; Ghorai, Binay K.; Journal of the Indian Chemical Society; vol. 76; nb. 11-12; (1999); p. 693 - 706 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Ravichandran, Ramaswamy; Divakar, Soundar; Journal of Molecular Catalysis A: Chemical; vol. 137; nb. 1-3; (1999); p. 31 - 39 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Shawkataly; Umathavan; Ramalingam; Fun; Ibrahim; Acta Crystallographica, Section C: Crystal Structure Communications; vol. 53; nb. pt 11; (1997); p. 1543 - 1545 ; (from Gmelin), View in Reaxys

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Behaviour as catalyst

Hill, Angela M.; Levason, William; Webster, Michael; Albers, Isabel; Organometallics; vol. 16; nb. 26; (1997); p. 5641 - 5647 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Shawkataly; Saminathan; Muniswaran; Fun; Sivakumar; Acta Crystallographica, Section C: Crystal Structure Communications; vol. 52; nb. 6; (1996); p. 1352 - 1355 ; (from Gmelin), View in Reaxys

Behaviour as inhibitor

Esteruelas, M. A.; Sola, E.; Oro, L. A.; Werner, H.; Meyer, U.; Journal of Molecular Catalysis; vol. 53; (1989); p. 43 - 52 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Esteruelas, M. A.; Sola, E.; Oro, L. A.; Werner, H.; Meyer, U.; Journal of Molecular Catalysis; vol. 53; (1989); p. 43 - 52 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Yada, Satoru; Yazawa, Naoki; Yamada, Yoshikazu; Sukegawa, Shinobu; Takagi, Yuzuru; Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan); (1989); p. 641 - 647 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Affandi, Salina; Nelson, John H.; Alcock, Nathaniel W.; Howarth, Oliver W.; Alyea, Elmer C.; Sheldrick, George M.; Organometallics; vol. 7; (1988); p. 1724 - 1734 ; (from Gmelin), View in Reaxys

Reaction with substance classes

title compound re- Imamoto, Tsuneo; Kusumoto, Tetsuo; Suzuki, Nobuyo; Sato, Kaact with tertiary or zuhiko; Journal of the American Chemical Society; vol. 107; nb. 18; secondary phos- (1985); p. 5301 - 5303 ; (from Gmelin), View in Reaxys phines in the presence of CeCl3 to phosphine-boranes

Behaviour as catalyst Reaction with substance classes

Boese, Roland; Finke, Norbert; Henkelmann, Jochem; Maier, Guenther; Paetzold, Peter; et al.; Chemische Berichte; vol. 118; nb. 4; (1985); p. 1644 - 1654 ; (from Gmelin), View in Reaxys title compound re- Lee, Hyung Soo; Isagawa, Kazuko; Otsuji, Yoshio; Chemistry Letact with alkene to ters; (1984); p. 363 - 366 ; (from Gmelin), View in Reaxys Na-alkenyl-borohydride

Behaviour as catalyst

Addison, A. W.; Gillard, R. D.; Sheridan, P. S.; Tipping, L. R. H.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); (1974); p. 709 - 716 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

Chatt, J.; Leigh, G. J.; Thankarajan, N.; j. Organometal. Chem.; vol. 29; (1971); p. 105 - 110 ; (from Gmelin), View in Reaxys

Reaction with substance classes

title compound re- Reetz,T.; Journal of the American Chemical Society; vol. 82; (1960); act with P(OR)3 p. 5039 - 5042 ; (from Gmelin), View in Reaxys to (RO)3P*BH3

Reaction with substance classes

title compound re- Reetz,T.; Journal of the American Chemical Society; vol. 82; (1960); act with trialkylp. 5039 - 5042 ; (from Gmelin), View in Reaxys phosphites to (RO)3PBH3

Reaction with substance classes

title compound re- Brown; Zweifel; Journal of the American Chemical Society; vol. 81; act with olefin to (1959); p. 247; Journal of the American Chemical Society; vol. 83; bortrialkyl (1961); p. 2544,2550 ; (from Gmelin), View in Reaxys

Reaction with substance classes

title compound re- Brown, H. C.; Subba Rao, B. C.; Journal of the American Chemical act with olefin to Society; vol. 81; (1959); p. 6423 - 6428 ; (from Gmelin), bortrialkyl View in Reaxys

Reaction with substance classes

title compound re- Brown, H. C.; Subba Rao, B. C.; Journal of the American Chemical act with olefin to Society; vol. 81; (1959); p. 6428 - 6434 ; (from Gmelin), bortrialkyl View in Reaxys

Reaction with substance classes

title compound re- Brown, H. C.; Tierney, P. A.; Journal of Inorganic and Nuclear act with BCl3 to Chemistry; vol. 9; (1959); p. 51 - 55 ; (from Gmelin), View in Reaxys BH2Cl*OR2

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Reaction with substance classes

title compound re- Long, L. H.; Wallbridge, M. G. H.; Chemistry and Industry (London, act with bortrialkyl United Kingdom); (1959); p. 295 - 296 ; (from Gmelin), and borhalogeView in Reaxys nide ( or hydrogen halogenide ) to diborane substitued with alkyl and Na-halogenide

Reaction with substance classes

title compound re- Wartik; Pearson; Journal of Inorganic and Nuclear Chemistry; vol. act with halogeno 5; (1958); p. 250 ; (from Gmelin), View in Reaxys olefine to dialkyl diborane

Reaction with substance classes

title compound re- Brown et al.; Journal of the American Chemical Society; vol. 78; act with alcohol to (1956); p. 3613 ; (from Gmelin), View in Reaxys alkylborates

Reaction with substance classes

title compound re- Brown; Rao; Journal of the American Chemical Society; vol. 78; act with olefin to (1956); p. 5694 ; (from Gmelin), View in Reaxys bortrialkyl

Reaction with substance classes

title compound re- vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), act with alcohol to View in Reaxys alkylborates

Reaction with substance classes

title compound re- vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), act with halogeno View in Reaxys olefine to dialkyl diborane

Reaction with substance classes

title compound re- vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), act with olefin to View in Reaxys bortrialkyl

Reaction with substance classes

title compound re- Brown, H. C.; Zweifel, G.; Subba Rao, B. C.; 135th Meeting Am. act with olefin to Chem. Soc. 1959, Abstr. of Papers, S. 39/40-O ; (from Gmelin), bortrialkyl View in Reaxys

Reaction with substance classes

title compound re- vol. B: B-Verb.3; 6.5.1, page 117 - 129 ; (from Gmelin), act with P(OR)3 View in Reaxys to (RO)3P*BH3

Reaction with substance classes

title compound re- vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), act with trialkylView in Reaxys phosphites to (RO)3PBH3

Reaction with substance classes

title compound re- vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), act with BCl3 to View in Reaxys BH2Cl*OR2

Reaction with substance classes

title compound re- vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), act with bortrialkyl View in Reaxys and borhalogenide ( or hydrogen halogenide ) to diborane substitued with alkyl and Na-halogenide

Behaviour as catalyst

vol. Sb: Org.Comp.1; 1.1.1.1.6.4.4, page 55 - 78 ; (from Gmelin), View in Reaxys

Behaviour as catalyst

vol. Rh: SVol.B2; 1.1.1.3, page 8 - 8 ; (from Gmelin), View in Reaxys

Heat Capacity Cp (52) Heat Capacity Cp Temperature [Jmol-1K-1] (Heat Capacity Cp) [°C]

Comment (Heat Capacity Cp)

References

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111.7

30 - 80

Solid

Liu, Bin Hong; Li, Zhou Peng; Suda; Thermochimica Acta; vol. 471; nb. 1-2; (2008); p. 103 - 105 ; (from Gmelin), View in Reaxys

Cp diagram; |Cp equation

Gorbunov, V. E.; Gavrichev, K. S.; Lazarev, V. B.; Russian Journal of Physical Chemistry; vol. 60; nb. 8; (1986); p. 1240 - 1242; Zhurnal Fizicheskoi Khimii; vol. 60; (1986); p. 2067 - 2069 ; (from Gmelin), View in Reaxys

86.77

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Westrum, E. F.; AECU-3925 (1958) 4; N.S.A.; vol. 13; (1959); p. 3557 ; (from Gmelin), View in Reaxys

100.41

207

Douglas, T. B.; Harman, A. W.; Journal of Research of the National Bureau of Standards (United States); vol. 60; (1958); p. 117 - 124, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

101.83

227

103.21

247

104.6

267

105.98

287

107.32

307

108.66

327

109.99

347

111.33

367

112.67

387

114.01

407

115.31

427

86.51

Douglas, T. B.; Harman, A. W.; Journal of Research of the National Bureau of Standards (United States); vol. 60; (1958); p. 117 - 124,

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View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys 86.68

88.36

89.99

91.54

93.09

107

94.59

127

96.1

147

97.56

167

98.99

187

10.761

-233.04

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

112.76

-82.27

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

136.82

-85.94

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

1.791

-252.04

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

18.579

-219.78

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

26.565

-203.46

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

32.479

-191.58

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

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3.742

-247.32

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

41.675

-169.4

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

425.46

-84.54

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

504.73

-83.73

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

52.36

-139.49

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

6.312

-211.51

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

63.37

-108.52

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

70.65

-79.7

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

71.28

-74.26

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

74.42

-57.41

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

0.753

-257.39

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

77.52

-39.15

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

79.65

-88.06

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

79.9

-24.14

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

82.71

-6.72

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

85.55

13.46

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

86.89

28.11

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

99.28

-80.56

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

86.6

750 Torr

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View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys 85.5 - 88.7

0 - 25

Heat Capacity Cv (1) Comment (Heat References Capacity Cv) Cv equation

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

Interatomic Distances and Angles (4) Description Comment (Intera- References tomic Distances and Angles) Interatomic distances and angles

Single Crystal Xray Diffraction

Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys

Interatomic distances and angles

Microwave Spectroscopy

Kawashima, Yoshiyuki; Yamada, Chikashi; Hirota, Eizi; Journal of Chemical Physics; vol. 94; nb. 12; (1991); p. 7707 - 7712, View in Reaxys; Kawashima, Yoshiyuki; Hirota, Eizi; Journal of Chemical Physics; vol. 102; nb. 18; (1995); p. 6961 - 6965 ; (from Gmelin), View in Reaxys

Interatomic distances and angles

NMR spectroscopy

Ford, P. T.; Richards, R. E.; Discussions of the Faraday Society; vol. 19; (1955); p. 230 238, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Svoboda, J.; Phys. Status Solidi B; vol. 70; (1975); p. K117 - K119, View in Reaxys; vol. B: BVerb.8; 1.3.1, page 6 - 18, View in Reaxys; Ford, P. T.; Richards, R. E.; Discussions Faraday Soc. Nr. 19 (1955) 230/8 ; (from Gmelin), View in Reaxys

Interatomic distances and angles

Harris, P. M.; Meibohm, E. P.; Journal of the American Chemical Society; vol. 69; (1947); p. 1231 - 1232, View in Reaxys; vol. B: B-Verb.8; 1.6, page 34 - 44, View in Reaxys; Rerick, M. N.; Selective Reductions of Organic Compounds with Complex Metal Hydrides, Metal Hydrides Inc., Beverly Mass. ; (from Gmelin), View in Reaxys

Magnetic Data (1) Description (Mag- Location netic Data) Diamagnetic

supporting information

References Tomiyasu, Keisuke; Sato, Toyoto; Orimo, Shin-Ichi; Chemical Communications; vol. 51; nb. 41; (2015); p. 8691 - 8694, View in Reaxys

Molecular Deformation (2) Description (MoReferences lecular Deformation) Fundamental vibrations

Nakamori, Yuko; Orimo, Shin-ichi; Journal of Alloys and Compounds; vol. 370; nb. 1-2; (2004); p. 271 275 ; (from Gmelin), View in Reaxys

Force constants

Shirk, A. E.; Shriver, D. F.; Journal of the American Chemical Society; vol. 95; (1973); p. 5901 - 5904, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys

Other Thermochemical Data (3) Description (Oth- Comment (Other er Thermochemi- Thermochemical cal Data) Data)

References

Enthalpy of crys- molar enthalpy of talline phase tran- transition = 973.5 sition J/mol; -83.2 Deg C from cubic to tetragonal

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

Entropy of crystal- molar entropy of line phase transi- transition = 5.11 tion J/(mol*K); -83.2 Deg C from cubic to tetragonal

Johnston, H. L.; Hallett, N. C.; Journal of the American Chemical Society; vol. 75; (1953); p. 1467 - 1468, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys

Gibbs free energy molar Gibbs ener- Rossini, F. D.; Wagman, D. D.; Evans, W. E.; Levine, S.; Jaffe, I.; Natl. Bur. Std. Circ. gy of formation = (U. S.); nb. 500; (1952); p. 481 - 481, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 1222, View in Reaxys; Latimer, W. M.; The Oxidation States of Elements and Their Po-

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-119580 J/mol; 25.01 Deg C

tentials in Aqueous Solutions, 2. Aufl., New York 1952, S. 332 ; (from Gmelin), View in Reaxys

Solubility (MCS) (176) 1 of 176

Comment (Solubility (MCS))

poor solubility in THF

Fianu, Godfred D.; Schipper, Kyle C.; Flowers, Robert A.; Catalysis Science and Technology; vol. 7; nb. 16; (2017); p. 3469 - 3473, View in Reaxys 2 of 176

Comment (Solubility (MCS))

poorly soluble in organic solvents

Mao, Jianfeng; Gu, Qinfen; Guo, Zaiping; Liu, Hua Kun; Journal of Materials Chemistry A; vol. 3; nb. 21; (2015); p. 11269 - 11276, View in Reaxys 3 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

Comment (Solubility (MCS))

high solubility; Solubility: 24 g/100g solvent

Aslanov; Zakharov; Savilov; Senyavin; Yatsenko; Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya; vol. 40; nb. 9; (2014); p. 607 - 610; Koord. Khim.; vol. 40; nb. 9; (2014); p. 523 - 526,4, View in Reaxys 4 of 176

Comment (Solubility (MCS))

water-soluble

Comment (Solubility (MCS))

insoluble in THF and pentane

Caputo, Riccarda; Guzzetta, Fabrizio; Angerhofer, Alexander; Inorganic Chemistry; vol. 49; nb. 19; (2010); p. 8756 - 8762 ; (from Gmelin), View in Reaxys 6 of 176

Comment (Solubility (MCS))

low soly. in toluene

Kuendig, E. Peter; Chaudhuri, Piyali Datta; House, David; Bernardinelli, Gerald; Angewandte Chemie - International Edition; vol. 45; nb. 7; (2006); p. 1092 - 1095 ; (from Gmelin), View in Reaxys 7 of 176

Temperature (Solubility (MCS)) [°C]

-9

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 2.26E1 weight-percent

Burlakova, A. G.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 38; (1993); p. 219 - 221; Zhurnal Neorganicheskoi Khimii; vol. 38; (1993); p. 237 - 239 ; (from Gmelin), View in Reaxys 8 of 176

Temperature (Solubility (MCS)) [°C]

-5

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 2.62E1 weight-percent

Temperature (Solubility (MCS)) [°C]

-9

Solvent (Solubility (MCS))

liquid ammonia

Comment (Solubility (MCS))

Solubility: 4.98E1 weight-percent

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Temperature (Solubility (MCS)) [°C]

-5

Solvent (Solubility (MCS))

liquid ammonia

Comment (Solubility (MCS))

Solubility: 5.08E1 weight-percent

Comment (Solubility (MCS))

sol. in THF

Kang, Sang Ook; Sneddon, Larry G.; Inorganic Chemistry; vol. 27; (1988); p. 3298 - 3300 ; (from Gmelin), View in Reaxys 12 of 176

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

Comment (Solubility (MCS))

Solubility: 9.1E0 mol-percent

Konoplev, V. N.; Silina, T. A.; Sizareva, A. S.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 33; (1988); p. 433 - 434; Zhurnal Neorganicheskoi Khimii; vol. 33; (1988); p. 769 - 771 ; (from Gmelin), View in Reaxys 13 of 176

Comment (Solubility (MCS))

insol. in Et2O, sol. in isopropylamine, slightly sol. in 1,3-dioxolane;has modest soly. in monoglyme

Brown, Herbert C.; Choi, Yong Moon; Narasimhan, S.; Inorganic Chemistry; vol. 21; (1982); p. 3657 - 3661 ; (from Gmelin), View in Reaxys 14 of 176

Solubility [g·l-1]

41.6158

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

further solvent(s)

Brown, Herbert C.; Choi, Yong Moon; Narasimhan, S.; Inorganic Chemistry; vol. 21; (1982); p. 3657 - 3661 ; (from Gmelin), View in Reaxys 15 of 176

Solubility [g·l-1]

5.67488

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

dimethoxyethane

Brown, Herbert C.; Choi, Yong Moon; Narasimhan, S.; Inorganic Chemistry; vol. 21; (1982); p. 3657 - 3661 ; (from Gmelin), View in Reaxys 16 of 176

Solubility [g·l-1]

0.75665

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

tetrahydrofuran

Brown, Herbert C.; Choi, Yong Moon; Narasimhan, S.; Inorganic Chemistry; vol. 21; (1982); p. 3657 - 3661 ; (from Gmelin), View in Reaxys 17 of 176

Solubility [g·l-1]

0.75665

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

further solvent(s)

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Brown, Herbert C.; Choi, Yong Moon; Narasimhan, S.; Inorganic Chemistry; vol. 21; (1982); p. 3657 - 3661 ; (from Gmelin), View in Reaxys 18 of 176

Comment (Solubility (MCS))

insol. in ethyl ether

Brown, Herbert C.; Choi, Yong Moon; Narasimhan, S.; Inorganic Chemistry; vol. 20; (1981); p. 4454 - 4456 ; (from Gmelin), View in Reaxys 19 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

tetrahydrofuran

Comment (Solubility (MCS))

Solubility: 0.04 weight-percent

Mirsaidov, U.; Kurbobekov, A.; Khikmatov, M.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 26; (1981); p. 1538 - 1539; Zhurnal Neorganicheskoi Khimii; vol. 26; (1981); p. 2875 2876, View in Reaxys; Mirsaidov, U.; Kurbonbekov, A.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 25; (1980); p. 769 - 771; Zhurnal Neorganicheskoi Khimii; vol. 25; (1980); p. 1386 - 1389 ; (from Gmelin), View in Reaxys 20 of 176

Comment (Solubility (MCS))

insoluble in THF

Mirsaidov, U.; Rakhkmova, A.; Dymova, T. N.; Inorganic Materials (Transl. of Neorg. Mater.); vol. 15; (1979); p. 1248 - 1251; Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy; vol. 15; (1979); p. 1585 - 1588 ; (from Gmelin), View in Reaxys 21 of 176

Comment (Solubility (MCS))

almost insol. in tetrahydrofuran

Mirsadov, U.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 22; (1977); p. 1555 - 1556; Zhurnal Neorganicheskoi Khimii; vol. 22; (1977); p. 2862 - 2864 ; (from Gmelin), View in Reaxys 22 of 176

Temperature (Solubility (MCS)) [°C]

19.9 - 20.1

Solvent (Solubility (MCS))

tetrahydrofuran

Comment (Solubility (MCS))

Solubility: 0.07 weight-percent

Mikheeva, V. I.; Sizareva, A. S.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 22; (1977); p. 486 - 487; Zhurnal Neorganicheskoi Khimii; vol. 22; (1977); p. 874 - 875 ; (from Gmelin), View in Reaxys 23 of 176

Comment (Solubility (MCS))

sol. in ethylene glycol monoethylether, in triglyme, in tetraglyme, in ethylamine, in n-propylamine, in isopropylamine, in n-butylamine

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44, View in Reaxys; Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 24 of 176

Comment (Solubility (MCS))

sol. in morpholyne, in cyclohexylamine

Solubility [g·l-1]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233, View in Reaxys; James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: B-Verb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 26 of 176

Solvent (Solubility (MCS))

ammonia

Comment (Solubility (MCS))

NH3 (liquid); Solubility: 1.04E2 g/100g solvent

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James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 27 of 176

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

Comment (Solubility (MCS))

Solubility: 1.10E1 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 28 of 176

Solvent (Solubility (MCS))

#tert!-butyl alcohol

Comment (Solubility (MCS))

Solubility: 1.1E-1 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 29 of 176

Solvent (Solubility (MCS))

methanol

Comment (Solubility (MCS))

Solubility: 1.64E1 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 30 of 176

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

Comment (Solubility (MCS))

Solubility: 1.7E0 g/100g solvent

Solvent (Solubility (MCS))

N,N-dimethyl-formamide

Comment (Solubility (MCS))

Solubility: 1.80E1 g/100g solvent

Solvent (Solubility (MCS))

#tert!-butyl alcohol

Comment (Solubility (MCS))

Solubility: 1.8E-1 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 33 of 176

Solvent (Solubility (MCS))

tetrahydrofuran

Comment (Solubility (MCS))

Solubility: 1.E-1 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 34 of 176

Solvent (Solubility (MCS))

acetonitrile

Comment (Solubility (MCS))

Solubility: 2.0E0 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 35 of 176

Solvent (Solubility (MCS))

ethylenediamine

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Comment (Solubility (MCS))

Solubility: 2.20E1 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 36 of 176

Solvent (Solubility (MCS))

water

Comment (Solubility (MCS))

Solubility: 2.50E1 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 37 of 176

Solvent (Solubility (MCS))

isopropyl alcohol

Comment (Solubility (MCS))

Solubility: 2.5E-1 g/100g solvent

Solvent (Solubility (MCS))

1,2-dimethoxyethane

Comment (Solubility (MCS))

Solubility: 2.6E0 g/100g solvent

Solvent (Solubility (MCS))

methylamine

Comment (Solubility (MCS))

Solubility: 2.76E1 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 40 of 176

Solvent (Solubility (MCS))

pyridine

Comment (Solubility (MCS))

Solubility: 3.1E0 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 41 of 176

Solvent (Solubility (MCS))

pyridine

Comment (Solubility (MCS))

Solubility: 3.4E0 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 42 of 176

Solvent (Solubility (MCS))

ethanol

Comment (Solubility (MCS))

Solubility: 4.0E0 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 43 of 176

Solvent (Solubility (MCS))

water

Comment (Solubility (MCS))

Solubility: 5.50E1 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys

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44 of 176

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

Comment (Solubility (MCS))

Solubility: 5.5E0 g/100g solvent

Solvent (Solubility (MCS))

dimethyl sulfoxide

Comment (Solubility (MCS))

Solubility: 5.8E0 g/100g solvent

James, B. D.; Wallbridge, M. G. H.; Progr. Inorg. Chem.; vol. 11; (1970); p. 99 - 230, View in Reaxys; vol. B: BVerb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys 46 of 176

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

Comment (Solubility (MCS))

Solubility: 8.0E0 g/100g solvent

Solvent (Solubility (MCS))

water

Comment (Solubility (MCS))

Solubility: 8.85E1 g/100g solvent

Solvent (Solubility (MCS))

1,2-dimethoxyethane

Comment (Solubility (MCS))

Solubility: 8.E-1 g/100g solvent

Solubility [g·l-1]

8.81497

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

propan-2-ol

Brown, H. C.; Tierney, P. A.; Journal of the American Chemical Society; vol. 80; (1958); p. 1551 - 1558 ; (from Gmelin), View in Reaxys 50 of 176

Solubility [g·l-1]

1.09714

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

2-methyl-propan-2-ol

Brown, H. C.; Tierney, P. A.; Journal of the American Chemical Society; vol. 80; (1958); p. 1551 - 1558 ; (from Gmelin), View in Reaxys 51 of 176

Solubility [g·l-1]

1.81596

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

2-methyl-propan-2-ol

Brown, H. C.; Tierney, P. A.; Journal of the American Chemical Society; vol. 80; (1958); p. 1551 - 1558 ; (from Gmelin), View in Reaxys 52 of 176

Solubility [g·l-1]

3.70759

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Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

propan-2-ol

Brown, H. C.; Tierney, P. A.; Journal of the American Chemical Society; vol. 80; (1958); p. 1551 - 1558 ; (from Gmelin), View in Reaxys 53 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

N,N-dimethylformamide=DMF

Comment (Solubility (MCS))

Solubility: 2.5495E1 g/100g solvent

Patent; Cunningham, G. L.; Bryant, J. M.; Gause, E. M.; Callery Chemical Co.; US2829946; (1958); C.A.; (1958); p. 13206 ; (from Gmelin), View in Reaxys 54 of 176

Comment (Solubility (MCS))

insol. in THF

Brown, H. C.; Mead, E. J.; Tierney, P. A.; Journal of the American Chemical Society; vol. 79; (1957); p. 5400 5404, View in Reaxys; Brown, H. C.; Mead, E. J.; Journal of the American Chemical Society; vol. 75; (1953); p. 6263 - 6265, View in Reaxys; vol. Na: SVol.2; 92, page 805 - 807, View in Reaxys; Brown, H. C.; Mead, E. J.; Shoaf, C. J.; Journal of the American Chemical Society; vol. 78; (1956); p. 3616 - 3620 ; (from Gmelin), View in Reaxys 55 of 176

Comment (Solubility (MCS))

very slightly soluble in tetrahydrofurane

Brown, H. C.; Mead, E. J.; Tierney, P. A.; Journal of the American Chemical Society; vol. 79; (1957); p. 5400 5404, View in Reaxys; vol. Na: SVol.3; 3.6.2, page 1223 - 1233, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Bull. 502-E, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 9 ; (from Gmelin), View in Reaxys 56 of 176

Solubility [g·l-1]

4.31291

Temperature (Solubility (MCS)) [°C]

100

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 57 of 176

Solubility [g·l-1]

49.5606

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 58 of 176

Solubility [g·l-1]

54.1005

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 59 of 176

Solubility [g·l-1]

71.8818

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 60 of 176

Solubility [g·l-1]

7.41517

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Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 61 of 176

Solubility [g·l-1]

88.1497

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 62 of 176

Solubility [g·l-1]

99.4995

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 63 of 176

Solubility [g·l-1]

101.391

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 64 of 176

Solubility [g·l-1]

13.2414

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 65 of 176

Solubility [g·l-1]

24.5911

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 66 of 176

Solubility [g·l-1]

33.2926

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209 ; (from Gmelin), View in Reaxys 67 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 1.55E1 mol/kg solvent

Gunn, S. R.; Green, L. G.; Journal of the American Chemical Society; vol. 77; (1955); p. 6197 - 6198 ; (from Gmelin), View in Reaxys

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68 of 176

Comment (Solubility (MCS))

moderately soluble in diethylen triamine, triethylen tetramine, tetraethylen pentamine

vol. Na: SVol.3; 3.6.2, page 1223 - 1233, View in Reaxys; Tieckelmann, H.; Mattern, J. A.; Garner, W.; MCC-1023TR-99 (1954) 16/27; N.S.A.; vol. 9; (1955); p. 2615 ; (from Gmelin), View in Reaxys 69 of 176

Comment (Solubility (MCS))

very slightly soluble in monoglyme, very soluble in diglyme and triglyme

Brown et al.; Journal of the American Chemical Society; vol. 77; (1955); p. 6209, View in Reaxys; vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 70 of 176

Solvent (Solubility (MCS))

diethyl ether

Comment (Solubility (MCS))

insol. in diethyl ether; Solubility: 2.E-2 g/100g solvent

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

liquid ammonia

Comment (Solubility (MCS))

very readily soluble in liq. NH3; Solubility: 1.04E2 g/100g solvent

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

ethane-1,2-diamine

Comment (Solubility (MCS))

Solubility: 2.2E1 g/100g solvent

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.; Journal of the American Chemical Society; vol. 75; (1953); p. 205 209, View in Reaxys; Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.; Journal of the American Chemical Society; vol. 75; (1953); p. 199 - 204, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Bull. 502E, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 9 ; (from Gmelin), View in Reaxys 73 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

methylamine

Comment (Solubility (MCS))

Solubility: 2.76E1 g/100g solvent

Comment (Solubility (MCS))

very sol. in liq. NH3

Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.; Journal of the American Chemical Society; vol. 75; (1953); p. 199 - 204, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys 75 of 176

Comment (Solubility (MCS))

slightly soluble in diethylamine and triethylamine

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Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.; Journal of the American Chemical Society; vol. 75; (1953); p. 205 209, View in Reaxys; vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 76 of 176

Comment (Solubility (MCS))

soluble in pyridine, Morpholine, acetonitrile, ethylcellosolve, diethylcellosolve; insol. in ethylacetate, methylborate, methylcianide

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.; Journal of the American Chemical Society; vol. 75; (1953); p. 205 209, View in Reaxys; Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.; Journal of the American Chemical Society; vol. 75; (1953); p. 199 - 204, View in Reaxys; vol. Na: SVol.3; 3.6.2, page 1223 - 1233, View in Reaxys; Patent; Schlesinger, H. I.; Brown, H. C.; US2461661; (1949); C.A.; (1949); p. 4684, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Bull. 502-E, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 9 ; (from Gmelin), View in Reaxys 77 of 176

Comment (Solubility (MCS))

very slightly sol. in dioxan

Comment (Solubility (MCS))

very sol. in ethylamine, n-propylamine, isopropylamine, n-butylamine, cyclohexylamine, aniline

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.; Journal of the American Chemical Society; vol. 75; (1953); p. 205 209, View in Reaxys; Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.; Journal of the American Chemical Society; vol. 75; (1953); p. 199 - 204, View in Reaxys; vol. Na: SVol.3; 3.6.2, page 1223 - 1233, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Bull. 502-E, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 9 ; (from Gmelin), View in Reaxys 79 of 176

Comment (Solubility (MCS))

sol. in cold water

Davis, W. D.; Mason, L. S.; Stegemann, G.; Journal of the American Chemical Society; vol. 71; (1949); p. 2775 2781, View in Reaxys; Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.; Journal of the American Chemical Society; vol. 75; (1953); p. 199 - 204, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Hoekstra, H. R.; The Preparation and Properties of Alkali Metal Borohydrides, AECD-2144 (1947) S. 17; N.S.A.; vol. 1; (1948); p. 756, View in Reaxys; Schlesinger, H. I.; Hoekstra, H. R.; Brown, H. C.; 115th Meeting Am. Chem. Soc., 1949, Abstr. of Papers, S. 9-1O ; (from Gmelin), View in Reaxys 80 of 176

Solubility [g·l-1]

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 9, View in Reaxys; Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 81 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Comment (Solubility (MCS))

Solubility: 1.11E1 g/100g solvent

Callery Chemical Co.Sodium Borohydride Techn. Bull. C-110 (1957) 3 ; (from Gmelin), View in Reaxys 82 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Comment (Solubility (MCS))

Solubility: 1.7E0 g/100g solvent

Temperature (Solubility (MCS)) [°C]

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Solvent (Solubility (MCS))

N,N-dimethylformamide=DMF

Comment (Solubility (MCS))

Solubility: 1.80E1 g/100g solvent

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Comment (Solubility (MCS))

Solubility: 1.9E0 g/100g solvent

Callery Chemical Co.Sodium Borohydride Techn. Bull. C-110 (1957) 3 ; (from Gmelin), View in Reaxys 85 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 2.48E1 g/100g solvent

Callery Chemical Co.Sodium Borohydride Techn. Bull. C-110 (1957) 3, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 9 ; (from Gmelin), View in Reaxys 86 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

N,N-dimethylformamide=DMF

Comment (Solubility (MCS))

Solubility: 2.4E1 g/100g solvent

Tieckelmann, H.; Mattern, J. A.; Garner, W.; MCC-1023-TR-99 (1954) 17 ; (from Gmelin), View in Reaxys 87 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

propan-2-ol

Comment (Solubility (MCS))

Solubility: 2.5E-1 g/100g solvent

Callery Chemical Co.Sodium Borohydride Techn. Bull. C-110 (1957) 3, View in Reaxys; Metal Hydrides Inc.MHI Sodium Borohydride.SWS, Techn. Bull. 550 (1958) 3, View in Reaxys; Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 88 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

methanol

Comment (Solubility (MCS))

Solubility: 2.5E1 g/100g solvent

Callery Chemical Co.Sodium Borohydride Techn. Bull. C-110 (1957) 3, View in Reaxys; Metal Hydrides Inc.MHI Sodium Borohydride.SWS, Techn. Bull. 550 (1958) 3 ; (from Gmelin), View in Reaxys 89 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

dimethoxyethane

Comment (Solubility (MCS))

Solubility: 2.6E0 g/100g solvent

Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 9, View in Reaxys; Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys

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90 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 2.84E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 91 of 176

Temperature (Solubility (MCS)) [°C]

7.5

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 2.98E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 92 of 176

Temperature (Solubility (MCS)) [°C]

8.5

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 3.00E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 93 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 3.06E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 94 of 176

Temperature (Solubility (MCS)) [°C]

15.8

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 3.26E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 95 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 3.59E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 96 of 176

Temperature (Solubility (MCS)) [°C]

30.8

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 3.98E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 97 of 176

Temperature (Solubility (MCS)) [°C]

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Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 4.35E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 98 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 4.48E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 99 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Comment (Solubility (MCS))

Solubility: 4.4E0 g/100g solvent

Callery Chemical Co.Sodium Borohydride Techn. Bull. C-110 (1957) 3 ; (from Gmelin), View in Reaxys 100 of 176 Temperature (Solubility (MCS)) [°C]

36.4

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 4.52E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 101 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 4.54E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 102 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 4.56E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 103 of 176 Temperature (Solubility (MCS)) [°C]

40.8

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 4.63E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 104 of 176 Temperature (Solubility (MCS)) [°C] Solvent (Solubility (MCS))

44.1 H2O

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Comment (Solubility (MCS))

Solubility: 4.81E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 105 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

ethanol

Comment (Solubility (MCS))

Solubility: 4.E0 g/100g solvent

Callery Chemical Co.Sodium Borohydride Techn. Bull. C-110 (1957) 3, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Bull. 502-E, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 9 ; (from Gmelin), View in Reaxys 106 of 176 Temperature (Solubility (MCS)) [°C]

47.6

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 5.07E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 107 of 176 Temperature (Solubility (MCS)) [°C]

50.1

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 5.34E1 g/100g solvent

Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 28 ; (from Gmelin), View in Reaxys 108 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 5.51E1 g/100g solvent

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Comment (Solubility (MCS))

Solubility: 5.5E0 g/100g solvent

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Comment (Solubility (MCS))

Solubility: 6.5E0 g/100g solvent

Callery Chemical Co.Sodium Borohydride Techn. Bull. C-110 (1957) 3 ; (from Gmelin), View in Reaxys 111 of 176

Temperature (Solubility (MCS)) [°C]

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Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Comment (Solubility (MCS))

Solubility: 8.0E0 g/100g solvent

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 8.85E1 g/100g solvent

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

dimethoxyethane

Comment (Solubility (MCS))

Solubility: 8.E-1 g/100g solvent

Temperature (Solubility (MCS)) [°C]

-33.3

Solvent (Solubility (MCS))

liquid ammonia

Comment (Solubility (MCS))

Solubility: 1.04E2 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 115 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

diethylene glycol dimethyl ether=diglyme

Comment (Solubility (MCS))

Solubility: 1.10E1 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 116 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

2-methyl-propan-2-ol

Comment (Solubility (MCS))

Solubility: 1.1E-1 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 117 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

methanol

Comment (Solubility (MCS))

Solubility: 1.64E1 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys

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118 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

2-methyl-propan-2-ol

Comment (Solubility (MCS))

Solubility: 1.8E-1 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 119 of 176

Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

tetrahydrofuran

Comment (Solubility (MCS))

Solubility: 1.E-1 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 120 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

acetonitrile

Comment (Solubility (MCS))

Solubility: 2.0E0 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 121 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

ethane-1,2-diamine

Comment (Solubility (MCS))

Solubility: 2.20E1 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 122 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 2.50E1 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 123 of 176 Temperature (Solubility (MCS)) [°C]

-20

Solvent (Solubility (MCS))

methylamine

Comment (Solubility (MCS))

Solubility: 2.76E1 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 124 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

pyridine

Comment (Solubility (MCS))

Solubility: 3.1E0 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 125 of 176 Temperature (Solubility (MCS)) [°C]

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Solvent (Solubility (MCS))

pyridine

Comment (Solubility (MCS))

Solubility: 3.4E0 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 126 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

ethanol

Comment (Solubility (MCS))

Solubility: 4.0E0 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 127 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

H2O

Comment (Solubility (MCS))

Solubility: 5.50E1 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 128 of 176 Temperature (Solubility (MCS)) [°C]

Solvent (Solubility (MCS))

dimethylsulfoxide=DMSO

Comment (Solubility (MCS))

Solubility: 5.8E0 g/100g solvent

Bayer A. G. LeverkusenBayer Natriumboranat-Informationen 1975 ; (from Gmelin), View in Reaxys 129 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

diethyl ether insol. in diethyl ether; Solubility: 2.E-2 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 130 of 176 Comment (Solubility (MCS))

sol. in tetrahydrofuryl alcohol

vol. Na: SVol.3; 3.6.2, page 1223 - 1233, View in Reaxys; Metal Hydrides Inc.MHI Sodium Borohydride.SWS, Techn. Bull. 550 (1958) 3 ; (from Gmelin), View in Reaxys 131 of 176 Comment (Solubility (MCS))

sol. in triglyme and tetraglyme

vol. Na: SVol.3; 3.6.2, page 1223 - 1233, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 9 ; (from Gmelin), View in Reaxys 132 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

ammonia very readily soluble in liq. NH3; NH3 (liquid); Solubility: 1.04E2 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 133 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

4.31291 diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 134 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

49.5606 diethylene glycol dimethyl ether

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vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 135 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

54.1005 diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 136 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

71.8818 diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 137 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

7.41517 diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 138 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

8.81497 isopropyl alcohol

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 139 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

88.1497 diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 140 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

99.4995 diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 141 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

101.391 diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 142 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

1.09714 #tert!-butyl alcohol

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 143 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

13.2414 diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 144 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

1.81596 #tert!-butyl alcohol

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 145 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

24.5911 diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 146 of 176 Solubility [g·l-1]

33.2926

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Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 147 of 176 Solubility [g·l-1] Solvent (Solubility (MCS))

3.70759 isopropyl alcohol

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 148 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

diethylene glycol dimethyl ether Solubility: 1.11E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 149 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 1.55E1 mol/kg solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 150 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

diethylene glycol dimethyl ether Solubility: 1.9E0 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 151 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

ethylenediamine Solubility: 2.2E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 152 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 2.48E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 153 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

N,N-dimethyl-formamide Solubility: 2.4E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 154 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

N,N-dimethyl-formamide Solubility: 2.5495E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 155 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

methanol Solubility: 2.5E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 156 of 176 Solvent (Solubility (MCS))

methylamine

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Comment (Solubility (MCS))

Solubility: 2.76E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 157 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 2.84E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 158 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 2.98E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 159 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 3.00E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 160 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 3.06E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 161 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 3.26E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 162 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 3.59E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 163 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 3.98E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 164 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 4.35E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 165 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 4.48E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 166 of 176 Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

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Comment (Solubility (MCS))

Solubility: 4.4E0 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 167 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 4.52E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 168 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 4.54E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 169 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 4.56E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 170 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 4.63E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 171 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 4.81E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 172 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

ethanol Solubility: 4.E0 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 173 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 5.07E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 174 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 5.34E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 175 of 176 Solvent (Solubility (MCS)) Comment (Solubility (MCS))

water Solubility: 5.51E1 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys 176 of 176 Solvent (Solubility (MCS))

diethylene glycol dimethyl ether

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Comment (Solubility (MCS))

Solubility: 6.5E0 g/100g solvent

vol. Na: SVol.3; 3.6.2, page 1223 - 1233 ; (from Gmelin), View in Reaxys Space Group (11) Space Group Comment (Space Group)

References

Method = Powder Wu, Yong; Qi, Yue; Chen, Jun; Fu, He; Zheng, Jie; Li, Xingguo; RSC Advances; vol. X-ray diffraction 6; nb. 105; (2016); p. 103299 - 103303, View in Reaxys 225

225

221

a = 0.61571 nm

Matsuo, Motoaki; Kuromoto, Shingo; Sato, Toyoto; Oguchi, Hiroyuki; Takamura, Hitoshi; Orimo, Shin-Ichi; Applied Physics Letters; vol. 100; nb. 20; (2012); Art.No: 203904 ; (from Gmelin), View in Reaxys

a = 6.15714 Angstroem; T = 25 Deg C

Ravnsbaek, Dorthe B.; Rude, Line H.; Jensen, Torben R.; Journal of Solid State Chemistry; vol. 184; nb. 7; (2011); p. 1858 - 1866 ; (from Gmelin), View in Reaxys

a = 6.15928 Angstroem; T = 25 Deg C

Ravnsbaek, Dorthe B.; Rude, Line H.; Jensen, Torben R.; Journal of Solid State Chemistry; vol. 184; nb. 7; (2011); p. 1858 - 1866 ; (from Gmelin), View in Reaxys

a = 6.13080 Ang- Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. stroem; Z = 4; T = 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys 200 K a = 0.6163 nm; Face-centered cubic

Varin; Chiu; Wronski; Journal of Alloys and Compounds; vol. 462; nb. 1-2; (2008); p. 201 - 208 ; (from Gmelin), View in Reaxys

a = 0.61626 nm

Varin; Chiu; Journal of Alloys and Compounds; vol. 397; nb. 1-2; (2005); p. 276 - 281 ; (from Gmelin), View in Reaxys

a = 7.3890 Angstroem, b = 4.1660 Angstroem, c = 5.6334 Angstroem

Kumar, Ravhi S.; Cornelius, Andrew L.; Applied Physics Letters; vol. 87; nb. 26; (2005); p. 1 - 3; Art.No: 261916 ; (from Gmelin), View in Reaxys

atomic positions available

Mal'tseva; Golovanova; Russian Journal of Inorganic Chemistry; vol. 41; nb. 8; (1996); p. 1221 - 1224 ; (from Gmelin), View in Reaxys

Face-centered cubic

Banus, M. D.; Bragdon, R. W.; Hinckley, A. A.; Journal of the American Chemical Society; vol. 76; (1954); p. 3848 - 3849, View in Reaxys; Abrahams, S. C.; Kalnajs, J.; Journal of Chemical Physics; vol. 22; (1954); p. 434 - 436, View in Reaxys; Ford, P. T.; Powell, H. M.; Acta Cryct.; vol. 7; (1954); p. 604 - 605, View in Reaxys; Harris, P. M.; Meibohm, E. P.; Journal of the American Chemical Society; vol. 69; (1947); p. 1231 - 1232, View in Reaxys; Soldate, A. M.; Journal of the American Chemical Society; vol. 69; (1947); p. 987 - 988, View in Reaxys; vol. B: B-Verb.8; 1.6, page 34 - 44 ; (from Gmelin), View in Reaxys

Face-centered cubic

vol. B: SVol.1; 4.1.5, page 112 - 115, View in Reaxys; Harris, P. M.; Meibohm, E. P.; Journal of the American Chemical Society; vol. 69; (1947); p. 1231 - 1232, View in Reaxys; Soldate, A. M.; Journal of the American Chemical Society; vol. 69; (1947); p. 987 - 988 ; (from Gmelin), View in Reaxys

Thermal Expansion (1) Coefficient [1/K] Kind of Expansion Temperature (Thermal Expansion) [°C] 0.000536

linear expansion

46 - 200

References

Ravnsbaek, Dorthe B.; Rude, Line H.; Jensen, Torben R.; Journal of Solid State Chemistry; vol. 184; nb. 7; (2011); p. 1858 - 1866 ; (from Gmelin), View in Reaxys

Transition Point(s) of Crystalline Modification(s) (6) Temperature Change of Modifi- Comment (Transi- References (Transition cation tion Point(s) of Point(s) of CrysCrystalline Modifitalline Modificacation(s)) tion(s)) [°C]

43/68

2018-02-24 07:07:56

from cubic to tetragonal

5.4 GPa - 6.3 GPa

Kim, Eunja; Kumar, Ravhi; Weck, Philippe F.; Cornelius, Andrew L.; Nicol, Malcolm; Vogel, Sven C.; Zhang, Jianzhong; Hartl, Monika; Stowe, Ashley C.; Daemen, Luke; Zhao, Yusheng; Journal of Physical Chemistry B; vol. 111; nb. 50; (2007); p. 13873 13876 ; (from Gmelin), View in Reaxys

from tetragonal to orthorhombic

8.9 GPa

from cubic to tetragonal

6.3 GPa

Kumar, Ravhi S.; Cornelius, Andrew L.; Applied Physics Letters; vol. 87; nb. 26; (2005); p. 1 - 3; Art.No: 261916 ; (from Gmelin), View in Reaxys

from tetragonal to orthorhombic

8.9 GPa

Kumar, Ravhi S.; Cornelius, Andrew L.; Applied Physics Letters; vol. 87; nb. 26; (2005); p. 1 - 3; Art.No: 261916 ; (from Gmelin), View in Reaxys

-182

from face-centered cubic (high temp.) to rhombic (low temp.)

Mikheeva, V. I.; Arkhipov, S. M.; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 805 - 810; Zhurnal Neorganicheskoi Khimii; vol. 11; (1966); p. 1506 - 1515, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys

-83

from cubic to tetragonal

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Abrahams, S. C.; Kalnajs, J.; NP-5263 (1954) 1/9; N.S.A.; vol. 8; (1954); p. 5613, View in Reaxys; Abrahams, S. C.; Kalnajs, J.; Journal of Chemical Physics; vol. 22; (1954); p. 434 - 436 ; (from Gmelin), View in Reaxys

NMR Spectroscopy (66) 1 of 66

Description (NMR Spec- MAS (Magic-Angle Spinning); Chemical shifts troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- neat (no solvent) scopy) Temperature (NMR Spectroscopy) [°C]

31.84

Saldin; Sukhovei; Savchenko; Slobodyuk; Kavun, V. Ya.; Russian Journal of Inorganic Chemistry; vol. 62; nb. 4; (2017); p. 489 - 497; Zh. Neorg. Khim.; vol. 62; nb. 4; (2017); p. 489 - 497,9, View in Reaxys 2 of 66

Description (NMR Spec- Chemical shifts; Spectrum troscopy) Nucleus (NMR Spectroscopy)

Solvents (NMR Spectro- dichloromethane-d2; methanol scopy) Sun, Jian-Ke; Kochovski, Zdravko; Zhang, Wei-Yi; Kirmse, Holm; Lu, Yan; Antonietti, Markus; Yuan, Jiayin; Journal of the American Chemical Society; vol. 139; nb. 26; (2017); p. 8971 - 8976, View in Reaxys 3 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Frequency (NMR Spectroscopy) [MHz]

128

Location

supporting information

Chen, Xi-Meng; Li, Huizhen; Yang, Qiu-Yu; Wang, Rui-Rui; Hamilton, Ewan J. M.; Zhang, Jie; Chen, Xuenian; European Journal of Inorganic Chemistry; vol. 2017; nb. 38; (2017); p. 4541 - 4545, View in Reaxys 4 of 66

Description (NMR Spec- Chemical shifts troscopy)

44/68

2018-02-24 07:07:56

Nucleus (NMR Spectroscopy)

Solvents (NMR Spectro- dimethylsulfoxide-d6 scopy) Frequency (NMR Spectroscopy) [MHz]

400

Cellier, Marie; James, Arthur L.; Lowe, Jonathan; Orenga, Sylvain; Perry, John D.; Rasul, Ari K.; Stanforth, Stephen P.; Bioorganic and Medicinal Chemistry; vol. 24; nb. 18; (2016); p. 4066 - 4074, View in Reaxys 5 of 66

Description (NMR Spec- Solid state NMR; Chemical shifts troscopy) Nucleus (NMR Spectroscopy)

11B

Wu, Yong; Qi, Yue; Chen, Jun; Fu, He; Zheng, Jie; Li, Xingguo; RSC Advances; vol. 6; nb. 105; (2016); p. 103299 - 103303, View in Reaxys 6 of 66

Description (NMR Spec- Chemical shifts; Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- tetrahydrofuran-d8 scopy) Frequency (NMR Spectroscopy) [MHz]

Location

supporting information

Ramachandran, P. Veeraraghavan; Kulkarni, Ameya S.; Dalton Transactions; vol. 45; nb. 41; (2016); p. 16433 16440, View in Reaxys 7 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Naka, Takashi; Ozawa, Hiroki; Toyama, Ken-Ichi; Shirasaka, Tadashi; Organic Process Research and Development; vol. 19; nb. 11; (2015); p. 1747 - 1751, View in Reaxys 8 of 66

Description (NMR Spec- Chemical shifts; Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- water; sodium hydroxide scopy) Frequency (NMR Spectroscopy) [MHz]

128

Shu, Chenhua; Sun, Tonghua; Jia, Jinping; Lou, Ziyang; Shen, Yafei; RSC Advances; vol. 3; nb. 5; (2013); p. 1476 - 1485, View in Reaxys 9 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

Solvents (NMR Spectro- dichloromethane-d2 scopy) Location

supporting information

Nelson, David J.; Egbert, Jonathan D.; Nolan, Steven P.; Dalton Transactions; vol. 42; nb. 12; (2013); p. 4105 4109, View in Reaxys 10 of 66

Description (NMR Spec- MAS (Magic-Angle Spinning); Solid state NMR; Chemical shifts; Spectrum troscopy)

45/68

2018-02-24 07:07:56

Nucleus (NMR Spectroscopy)

11B

Xia, Guanglin; Li, Li; Guo, Zaiping; Gu, Qinfen; Guo, Yanhui; Yu, Xuebin; Liu, Huakun; Liu, Zongwen; Journal of Materials Chemistry A; vol. 1; nb. 2; (2013); p. 250 - 257, View in Reaxys 11 of 66

Description (NMR Spec- Chemical shifts troscopy) Nucleus (NMR Spectroscopy)

11B

Jepsen; Skibsted; Jensen; Journal of Alloys and Compounds; vol. 580; nb. SUPPL1; (2013); p. S287-S291, View in Reaxys 12 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- diethylene glycol dimethyl ether scopy) Temperature (NMR Spectroscopy) [°C]

100

Comment (NMR Spectroscopy)

Signals given

Bykov; Razgonyaeva; Mal'Tseva; Zhizhin; Kuznetsov; Russian Journal of Inorganic Chemistry; vol. 57; nb. 4; (2012); p. 471 - 473 ; (from Gmelin), View in Reaxys 13 of 66

Description (NMR Spec- Chemical shifts troscopy) Nucleus (NMR Spectroscopy)

10B

Frequency (NMR Spectroscopy) [MHz]

64.4

Kiraly, Peter; Magnetic Resonance in Chemistry; vol. 50; nb. 9; (2012); p. 620 - 626, View in Reaxys 14 of 66

Description (NMR Spec- MAS (Magic-Angle Spinning); Solid state NMR; Spectrum troscopy) Nucleus (NMR Spectroscopy)

10B

Frequency (NMR Spectroscopy) [MHz]

42.9

Kiraly, Peter; Magnetic Resonance in Chemistry; vol. 50; nb. 9; (2012); p. 620 - 626, View in Reaxys 15 of 66

Description (NMR Spec- Chemical shifts troscopy) Nucleus (NMR Spectroscopy)

11B

Frequency (NMR Spectroscopy) [MHz]

192.4

Kiraly, Peter; Magnetic Resonance in Chemistry; vol. 50; nb. 9; (2012); p. 620 - 626, View in Reaxys 16 of 66

Description (NMR Spec- MAS (Magic-Angle Spinning); Solid state NMR; Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Frequency (NMR Spectroscopy) [MHz]

128.3

Kiraly, Peter; Magnetic Resonance in Chemistry; vol. 50; nb. 9; (2012); p. 620 - 626, View in Reaxys 17 of 66

Nucleus (NMR Spectroscopy)

11B

46/68

2018-02-24 07:07:56

Solvents (NMR Spectro- neat (no solvent, solid phase) scopy) Comment (NMR Spectroscopy)

Signals given

Filinchuk, Yaroslav; Ravnsbk, Dorthe; Jakobsen, Hans J.; Skibsted, Jorgen; Jensen, Torben R.; Cerenius, Yngve; Besenbacher, Flemming; Angewandte Chemie, International Edition; vol. 48; nb. 36; (2009); p. 6659 6663, View in Reaxys; Graham, Kathryn R.; Bowden, Mark E.; Kemmitt, Tim; Inorganic Chemistry; vol. 50; nb. 3; (2011); p. 932 - 936, View in Reaxys; Borsacchi; Calucci; Geppi; Chemical Physics Letters; vol. 508; nb. 1-3; (2011); p. 63 - 66 ; (from Gmelin), View in Reaxys 18 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- tetrahydrofuran-d8 scopy) Comment (NMR Spectroscopy)

Signals given

Huang, Zhenguo; Chen, Xuenian; Yisgedu, Teshome; Meyers, Edward A.; Shore, Sheldon G.; Zhao, JiCheng; Inorganic Chemistry; vol. 50; nb. 8; (2011); p. 3738 - 3742 ; (from Gmelin), View in Reaxys 19 of 66

Nucleus (NMR Spectroscopy)

23Na

Solvents (NMR Spectro- chloroform-d1 scopy) Comment (NMR Spectroscopy)

Signals given

Aguilar-Martinez, Milagros; Felix-Baez, Genaro; Perez-Martinez, Cesar; Noeth, Heinrich; Flores-Parra, Angelina; Colorado, Raul; Galvez-Ruiz, Juan Carlos; European Journal of Inorganic Chemistry; nb. 13; (2010); p. 1973 1982 ; (from Gmelin), View in Reaxys 20 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- chloroform-d1 scopy) Comment (NMR Spectroscopy)

Signals given

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- neat (no solvent, solid phase) scopy) Temperature (NMR Spectroscopy) [°C]

Weng; Yu; Wu; Li; Huan; Xu; Ni; Journal of Alloys and Compounds; vol. 503; nb. 2; (2010); p. 345 - 349 ; (from Gmelin), View in Reaxys 22 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- solid scopy) Comment (NMR Spectroscopy)

Signals given

47/68

2018-02-24 07:07:56

Hayashi, Shigenobu; Hayamizu, Kikuko; Bulletin of the Chemical Society of Japan; vol. 62; nb. 7; (1989); p. 2429 - 2430, View in Reaxys; Stringfellow; Wu; Wasylishen; Journal of Physical Chemistry B; vol. 101; nb. 46; (1997); p. 9651 - 9656, View in Reaxys; Filinchuk, Yaroslav; Ravnsbk, Dorthe; Jakobsen, Hans J.; Skibsted, Jorgen; Jensen, Torben R.; Cerenius, Yngve; Besenbacher, Flemming; Angewandte Chemie, International Edition; vol. 48; nb. 36; (2009); p. 6659 - 6663 ; (from Gmelin), View in Reaxys 23 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- dimethylformamide scopy) Comment (NMR Spectroscopy)

Signals given

Titova; Belykh; Belonogova; Shmidt; Russian Journal of Applied Chemistry; vol. 82; nb. 11; (2009); p. 1978 1985 ; (from Gmelin), View in Reaxys 24 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- tetrahydrofuran-d8 scopy) Comment (NMR Spectroscopy)

Signals given

Lorbach, Andreas; Nadj, Andor; Tuellmann, Sandor; Dornhaus, Franz; Schoedel, Frauke; Saenger, Inge; Margraf, Guenter; Bats, Jan W.; Bolte, Michael; Holthausen, Max C.; Wagner, Matthias; Lerner, Hans-Wolfram; Inorganic Chemistry; vol. 48; nb. 3; (2009); p. 1005 - 1017 ; (from Gmelin), View in Reaxys 25 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

23Na

Solvents (NMR Spectro- neat (no solvent, solid phase) scopy) Comment (NMR Spectroscopy)

Signals given

Seballos, Leo; Zhang, Jin Z.; Roennebro, Ewa; Herberg, Julie L.; Majzoub; Journal of Alloys and Compounds; vol. 476; nb. 1-2; (2009); p. 446 - 450 ; (from Gmelin), View in Reaxys 26 of 66

Nucleus (NMR Spectroscopy)

Solvents (NMR Spectro- chloroform-d1 scopy) Frequency (NMR Spectroscopy) [MHz]

300

Original Text (NMR Spectroscopy)

NMR (300 MHz, CDCl3) δ ppm 8.16 (d, J=2.37 Hz, 1H) 8.05 (d, J=8.82 Hz, 1H) 7.93 (dd, J=3.73, 1.70 Hz, 1H) 7.70 (dd, J=8.82, 2.03 Hz, 1H) 7.25-7.30 (m, 1H) 7.08 (dd, J=9.49, 1.70 Hz, 1H) 4.38 (m, 1H) 3.37-3.54 (m, 1H) 2.90-3.05 (m, 2H) 2.31-2.46 (m, 2H) 2.19-2.28 (m, 1H).

Comment (NMR Spectroscopy)

Signals given

Patent; Cowart, Marlon D.; Sun, Minghua; Zhao, Chen; Zheng, Guo Zhu; US2007/66588; (2007); (A1) English, View in Reaxys 27 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- solid scopy)

48/68

2018-02-24 07:07:56

Temperature (NMR Spectroscopy) [°C]

25.04

Comment (NMR Spectroscopy)

Signals given

Guella; Zanchetta; Patton; Miotello; Journal of Physical Chemistry B; vol. 110; nb. 34; (2006); p. 17024 - 17033 ; (from Gmelin), View in Reaxys 28 of 66

Nucleus (NMR Spectroscopy)

Coupling Nuclei

11B

Solvents (NMR Spectro- tetrahydrofuran-d8 scopy) Temperature (NMR Spectroscopy) [°C]

Comment (NMR Spectroscopy)

Signals given

Roger, Mathieu; Arliguie, Therese; Thuery, Pierre; Fourmigue, Marc; Ephritikhine, Michel; Inorganic Chemistry; vol. 44; nb. 3; (2005); p. 584 - 593 ; (from Gmelin), View in Reaxys 29 of 66

Nucleus (NMR Spectroscopy)

Coupling Nuclei

11B

Solvents (NMR Spectro- perdeuteriopyridine scopy) Temperature (NMR Spectroscopy) [°C]

Comment (NMR Spectroscopy)

Signals given

Roger, Mathieu; Arliguie, Therese; Thuery, Pierre; Fourmigue, Marc; Ephritikhine, Michel; Inorganic Chemistry; vol. 44; nb. 3; (2005); p. 584 - 593 ; (from Gmelin), View in Reaxys 30 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- neat (no solvent) scopy) Comment (NMR Spectroscopy)

Signals given

Dillon; Waddington; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy; vol. 30; (1974); p. 1873, View in Reaxys; Schurko, Robert W.; Hung, Ivan; Schauff, Siri; Macdonald, Charles L.B.; Cowley, Alan H.; Journal of Physical Chemistry A; vol. 106; nb. 43; (2002); p. 10096 - 10107 ; (from Gmelin), View in Reaxys 31 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- tetrahydrofuran scopy) Comment (NMR Spectroscopy)

Signals given

Noeth, Heinrich; Thomas, Steffen; European Journal of Inorganic Chemistry; nb. 8; (1999); p. 1373 - 1380 ; (from Gmelin), View in Reaxys 32 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- H2O scopy) Comment (NMR Spectroscopy)

Signals given

Stringfellow; Wu; Wasylishen; Journal of Physical Chemistry B; vol. 101; nb. 46; (1997); p. 9651 - 9656 ; (from Gmelin), View in Reaxys

49/68

2018-02-24 07:07:56

33 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- dimethyl sulfoxide scopy) Comment (NMR Spectroscopy)

Signals given

Shevchenko; Yashina; Markova; Trachevskii; Russian Journal of General Chemistry; vol. 66; nb. 7; (1996); p. 1171 - 1177 ; (from Gmelin), View in Reaxys 34 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- 1,2-dimethoxyethane scopy) Comment (NMR Spectroscopy)

Signals given

Shevchenko; Yashina; Markova; Trachevskii; Russian Journal of General Chemistry; vol. 66; nb. 7; (1996); p. 1171 - 1177 ; (from Gmelin), View in Reaxys 35 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- tetrahydrofuran scopy) Comment (NMR Spectroscopy)

Signals given

Bakum, S. I.; Bolotina, I. V.; Kuznetsova, S. F.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 39; (1994); p. 1119 - 1128; Zhurnal Neorganicheskoi Khimii; vol. 39; (1994); p. 1173 1183 ; (from Gmelin), View in Reaxys 36 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- diethyl ether scopy) Comment (NMR Spectroscopy)

Signals given

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- bis-(2-methoxy-ethyl) ether scopy) Comment (NMR Spectroscopy)

Signals given

50/68

2018-02-24 07:07:56

38 of 66

Description (NMR Spec- Linewidth of NMR absorption troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- solid scopy) Temperature (NMR Spectroscopy) [°C]

-128 - 37

Tarasov, V. P.; Bakum, S. I.; Privalov, V. I.; Shamov, A. A.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 35; (1990); p. 1195 - 1197; Zhurnal Neorganicheskoi Khimii; vol. 35; (1990); p. 2096 - 2099 ; (from Gmelin), View in Reaxys 39 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- N,N-dimethyl-formamide scopy) Temperature (NMR Spectroscopy) [°C]

-58

Comment (NMR Spectroscopy)

Signals given

Linti, Gerald; Noeth, Heinrich; Thomann, Martina; Zeitschrift fuer Naturforschung, B: Chemical Sciences; vol. 45; nb. 11; (1990); p. 1463 - 1471 ; (from Gmelin), View in Reaxys 40 of 66

Nucleus (NMR Spectroscopy)

23Na

Solvents (NMR Spectro- neat (no solvent, solid phase) scopy) Comment (NMR Spectroscopy)

Signals given

Tabeta, Ryoko; Aida, Misako; Saito, Hazime; Bulletin of the Chemical Society of Japan; vol. 59; nb. 6; (1986); p. 1957 - 1966 ; (from Gmelin), View in Reaxys 41 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- further solvent(s) scopy) Comment (NMR Spectroscopy)

Signals given

Titov, L. V.; Eremin, E. R.; Rosolovskii, V. Ya.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 27; (1982); p. 500 - 502; Zhurnal Neorganicheskoi Khimii; vol. 27; (1982); p. 891 - 895 ; (from Gmelin), View in Reaxys 42 of 66

Description (NMR Spec- Linewidth of NMR absorption troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- solid scopy) Temperature (NMR Spectroscopy) [°C]

-103.16 - -92.16

Trokiner, A.; Theveneau, H.; Papon, P.; Journal of Chemical Physics; vol. 69; (1978); p. 742 - 747 ; (from Gmelin), View in Reaxys 43 of 66

Nucleus (NMR Spectroscopy)

51/68

2018-02-24 07:07:56

Comment (NMR Spectroscopy)

Ogg. R. A.; Journal of Chemical Physics; vol. 22; (1954); p. 1933 - 1935, View in Reaxys; Svoboda, J.; Phys. Status Solidi B; vol. 70; (1975); p. K117 - K119, View in Reaxys; Tung Tsang; Farrar, T. C.; Journal of Chemical Physics; vol. 50; (1969); p. 3498 - 3502, View in Reaxys; Ford, P. T.; Richards, R. E.; Discussions Faraday Soc. Nr. 19 (1955) 230/8, View in Reaxys; Shoolery, J. N.; Discussions Faraday Soc. Nr. 19 (1955) 215/25 ; (from Gmelin), View in Reaxys 44 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- H2O scopy) Comment (NMR Spectroscopy)

Signals given

Onak et al.; Journal of Physical Chemistry; vol. 63; (1959); p. 1533, View in Reaxys; Dillon; Waddington; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy; vol. 30; (1974); p. 1873 ; (from Gmelin), View in Reaxys 45 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- diethylene glycol dimethyl ether=diglyme scopy) Comment (NMR Spectroscopy)

Signals given

Dillon; Waddington; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy; vol. 30; (1974); p. 1873, View in Reaxys; Schaeffer, R.; Progr. Boron Chem.; vol. 1; (1964); p. 417 - 460 ; (from Gmelin), View in Reaxys 46 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- neat (no solvent) scopy) Temperature (NMR Spectroscopy) [°C]

Dillon; Waddington; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy; vol. 30; (1974); p. 1873, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 47 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- not given scopy) Ogg. R. A.; Journal of Chemical Physics; vol. 22; (1954); p. 1933 - 1935, View in Reaxys; Shore, S. G.; Hickam, C. W.; Cowles, D.; Journal of the American Chemical Society; vol. 87; (1965); p. 2755 - 2756, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 48 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- not given scopy) Gardiner, J. A.; Collat, J. W.; Journal of the American Chemical Society; vol. 86; (1964); p. 3165 - 3166, View in Reaxys; vol. B: B-Verb.8; 3.2.1, page 53 - 65 ; (from Gmelin), View in Reaxys 49 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- aq. NaOH scopy)

52/68

2018-02-24 07:07:56

Philips, W. D.; Miller, H. C.; Muetterties, E. L.; Journal of the American Chemical Society; vol. 81; (1959); p. 4496 4500 ; (from Gmelin), View in Reaxys 50 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- H2O scopy) Onak et al.; Journal of Physical Chemistry; vol. 63; (1959); p. 1533, View in Reaxys; Ogg. R. A.; Journal of Chemical Physics; vol. 22; (1954); p. 1933 - 1935 ; (from Gmelin), View in Reaxys 51 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- aq. NaOH scopy) Comment (NMR Spectroscopy)

Signals given

Philips, W. D.; Miller, H. C.; Muetterties, E. L.; Journal of the American Chemical Society; vol. 81; (1959); p. 4496 4500, View in Reaxys; Eaton, G. R.; Lipscomb, W. N.; NMR Studies of Boron Hydrides and Related Compounds, W. A. Benjamin Inc., New York - Amsterdam 1969, p. 445 ; (from Gmelin), View in Reaxys 52 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

Solvents (NMR Spectro- H2O scopy) Comment (NMR Spectroscopy)

Signals given

Ogg. R. A.; Journal of Chemical Physics; vol. 22; (1954); p. 1933 - 1935 ; (from Gmelin), View in Reaxys 53 of 66

Nucleus (NMR Spectroscopy)

11B

Comment (NMR Spectroscopy)

Ogg. R. A.; Journal of Chemical Physics; vol. 22; (1954); p. 1933 - 1935, View in Reaxys; Shoolery, J. N.; Discussions Faraday Soc. Nr. 19 (1955) 215/25 ; (from Gmelin), View in Reaxys 54 of 66

Nucleus (NMR Spectroscopy)

Solvents (NMR Spectro- H2O scopy) Comment (NMR Spectroscopy)

Signals given

Pople, J. A.; Schneider, W. G.; Bernstein, H. J.; High Resolution Nuclear Magnetic Resonance, McGraw-Hill Book Company Inc., New York - Toronto- London 1959, pp. 297/307 ; (from Gmelin), View in Reaxys 55 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- H2O scopy) Comment (NMR Spectroscopy)

Signals given

Nucleus (NMR Spectroscopy)

Comment (NMR Spectroscopy)

description given

53/68

2018-02-24 07:07:56

vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 57 of 66

Description (NMR Spec- Spectrum troscopy) Nucleus (NMR Spectroscopy)

Solvents (NMR Spectro- water scopy) Comment (NMR Spectroscopy)

Signals given

vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 58 of 66

Nucleus (NMR Spectroscopy)

Solvents (NMR Spectro- water scopy) Comment (NMR Spectroscopy)

Signals given

vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 59 of 66

Description (NMR Spec- Linewidth of NMR absorption troscopy) Nucleus (NMR Spectroscopy)

Solvents (NMR Spectro- neat (no solvent) scopy) Temperature (NMR Spectroscopy) [°C]

-253 - 20

vol. B: B-Verb.8; 1.3.1, page 6 - 18, View in Reaxys; Ford, P. T.; Richards, R. E.; Discussions Faraday Soc. Nr. 19 (1955) 230/8 ; (from Gmelin), View in Reaxys 60 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- sodium hydroxide scopy) Comment (NMR Spectroscopy)

aq. NaOH

vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 61 of 66

Nucleus (NMR Spectroscopy)

11B

Coupling Nuclei

Solvents (NMR Spectro- water scopy) vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 62 of 66

Nucleus (NMR Spectroscopy)

11B

Comment (NMR Spectroscopy)

description given

vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 63 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- sodium hydroxide scopy)

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Comment (NMR Spectroscopy)

aq. NaOH; Signals given

vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 64 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- water scopy) Comment (NMR Spectroscopy)

Signals given

vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 65 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- neat (no solvent) scopy) Comment (NMR Spectroscopy)

Signals given

vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 66 of 66

Nucleus (NMR Spectroscopy)

11B

Solvents (NMR Spectro- diethylene glycol dimethyl ether scopy) Comment (NMR Spectroscopy)

Signals given

vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys IR Spectroscopy (38) 1 of 38

Description (IR Spectroscopy)

Bands; Spectrum

Zhang, Liuting; Xiao, Xuezhang; Fan, Xiulin; Li, Shouquan; Ge, Hongwei; Wang, Qidong; Chen, Lixin; RSC Advances; vol. 4; nb. 5; (2014); p. 2550 - 2556, View in Reaxys; Mao, Jianfeng; Gu, Qinfen; Guo, Zaiping; Liu, Hua Kun; Journal of Materials Chemistry A; vol. 3; nb. 21; (2015); p. 11269 - 11276, View in Reaxys; Zheng, Jiaguang; Xiao, Xuezhang; Zhang, Liuting; Li, Shouquan; Ge, Hongwei; Chen, Lixin; Journal of Materials Chemistry A; vol. 5; nb. 20; (2017); p. 9723 - 9732, View in Reaxys; Huang, Miaojun; Zhong, Hao; Ouyang, Liuzhang; Peng, Chenghong; Zhu, Xiaoke; Zhu, Weiheng; Fang, Fang; Zhu, Min; Journal of Alloys and Compounds; vol. 729; (2017); p. 1079 - 1085, View in Reaxys 2 of 38

Description (IR Spectroscopy)

Bands; Spectrum

Solvent (IR Spectroscopy)

potassium bromide

Murariu, Manuela; Stoica, Iuliana; Gradinaru, Robert; Drochioiu, Gabi; Mangalagiu, Ionel; Revue Roumaine de Chimie; vol. 59; nb. 10; (2014); p. 867 - 874, View in Reaxys; Saldin; Sukhovei; Savchenko; Slobodyuk; Kavun, V. Ya.; Russian Journal of Inorganic Chemistry; vol. 62; nb. 4; (2017); p. 489 - 497; Zh. Neorg. Khim.; vol. 62; nb. 4; (2017); p. 489 - 497,9, View in Reaxys 3 of 38

Description (IR Spectroscopy)

ATR (attenuated total reflectance); Spectrum

Location

supporting information

Kadota, Kentaro; Sivaniah, Easan; Bureekaew, Sareeya; Kitagawa, Susumu; Horike, Satoshi; Inorganic Chemistry; vol. 56; nb. 15; (2017); p. 8744 - 8747, View in Reaxys 4 of 38

Description (IR Spectroscopy)

Spectrum

Location

supporting information

Jepsen; Skibsted; Jensen; Journal of Alloys and Compounds; vol. 580; nb. SUPPL1; (2013); p. S287-S291, View in Reaxys; Byeon; Park, Joonho; Baik, Seoyeon; Jung, Yousung; Lee, Jae W.; Journal of Materials Chemistry A; vol. 3; nb. 11; (2015); p. 5843 - 5849, View in Reaxys; Dovgaliuk, Iurii; Jepsen, Lars H.; Safin, Damir A.; Łodziana, Zbigniew; Dyadkin, Vadim; Jensen, Torben R.; Devillers, Michel; Filinchuk, Yaroslav; Chemistry - A

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European Journal; vol. 21; nb. 41; (2015); p. 14562 - 14570, View in Reaxys; Sharma, Manish; Didelot, Emilie; Spyratou, Alexandra; Lawson Daku, Latévi Max; Černý, Radovan; Hagemann, Hans; Inorganic Chemistry; vol. 55; nb. 14; (2016); p. 7090 - 7097, View in Reaxys 5 of 38

Description (IR Spectroscopy)

ATR (attenuated total reflectance); Bands; Spectrum

Hino; Ichikawa; Kojima; Sørby; Hauback; RSC Advances; vol. 6; nb. 34; (2016); p. 28761 - 28766, View in Reaxys 6 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

potassium bromide

Original Text (IR Spectroscopy)

IR (KBr) νmax 3422, 1673 cm-1

Signals [cm-1]

3422; 1673

Uchimasu, Hajime; Matsumura, Ken; Tsuda, Masashi; Kumagai, Keiko; Akakabe, Mai; Fujita, Masaki J.; Sakai, Ryuichi; Tetrahedron; vol. 72; nb. 45; (2016); p. 7185 - 7193, View in Reaxys 7 of 38

Description (IR Spectroscopy)

Spectrum

Solvent (IR Spectroscopy)

potassium bromide

Location

supporting information

Jaro, Tomasz; Orlowski, Piotr A.; Wegner, Wojciech; Fijalkowski, Karol J.; Leszczyski, Piotr J.; Grochala, Wojciech; Angewandte Chemie - International Edition; vol. 54; nb. 4; (2015); p. 1236 - 1239; Angew. Chem.; vol. 127; nb. 4; (2015); p. 1252 - 1255,4, View in Reaxys 8 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

potassium bromide

Comment (IR Spectroscopy)

400 cm**-1 - 4000 cm**-1

Buhl, Josef-C.; Gesing, Thorsten M.; Hoefs, Tanja; Ruescher, Claus H.; Journal of Solid State Chemistry; vol. 179; nb. 12; (2006); p. 3877 - 3882, View in Reaxys; Llamas-Jansa, Isabel; Aliouane, Nadir; Deledda, Stefano; Fonnelop, Jon Erling; Frommen, Christoph; Humphries, Terry; Lieutenant, Klaus; Sartori, Sabrina; Sorby, Magnus H.; Hauback, Bjorn C.; Journal of Alloys and Compounds; vol. 530; (2012); p. 186 - 192 ; (from Gmelin), View in Reaxys 9 of 38

Description (IR Spectroscopy)

Spectrum

Solvent (IR Spectroscopy)

potassium bromide

Comment (IR Spectroscopy)

400 cm**-1 - 4000 cm**-1

Llamas-Jansa, Isabel; Aliouane, Nadir; Deledda, Stefano; Fonnelop, Jon Erling; Frommen, Christoph; Humphries, Terry; Lieutenant, Klaus; Sartori, Sabrina; Sorby, Magnus H.; Hauback, Bjorn C.; Journal of Alloys and Compounds; vol. 530; (2012); p. 186 - 192 ; (from Gmelin), View in Reaxys 10 of 38

Description (IR Spectroscopy)

Spectrum

Solvent (IR Spectroscopy)

potassium bromide

Comment (IR Spectroscopy)

400 cm**-1 - 4000 cm**-1

Buhl, Josef-C.; Gesing, Thorsten M.; Hoefs, Tanja; Ruescher, Claus H.; Journal of Solid State Chemistry; vol. 179; nb. 12; (2006); p. 3877 - 3882, View in Reaxys; Caputo, Riccarda; Guzzetta, Fabrizio; Angerhofer, Alexander; Inorganic Chemistry; vol. 49; nb. 19; (2010); p. 8756 - 8762 ; (from Gmelin), View in Reaxys

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11 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

KBr

Comment (IR Spectroscopy)

400 cm**-1 - 4000 cm**-1

Buhl, Josef-C.; Gesing, Thorsten M.; Hoefs, Tanja; Ruescher, Claus H.; Journal of Solid State Chemistry; vol. 179; nb. 12; (2006); p. 3877 - 3882, View in Reaxys; Zhang, Hanping; Zheng, Shiyou; Fang, Fang; Chen, Guorong; Sang, Ge; Sun, Dalin; Journal of Alloys and Compounds; vol. 484; nb. 1-2; (2009); p. 352 - 355 ; (from Gmelin), View in Reaxys 12 of 38

Description (IR Spectroscopy)

Spectrum

Solvent (IR Spectroscopy)

neat (no solvent, solid phase)

Temperature (IR Spectroscopy) [°C]

21.84

Comment (IR Spectroscopy)

700 cm**-1 - 2500 cm**-1

Hagemann; D'Anna; Carbonniere; Gil Bardaji; Fichtner; Journal of Physical Chemistry A; vol. 113; nb. 50; (2009); p. 13932 - 13936 ; (from Gmelin), View in Reaxys 13 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

neat (no solvent, solid phase)

Temperature (IR Spectroscopy) [°C]

21.84

Comment (IR Spectroscopy)

700 cm**-1 - 2500 cm**-1

Hagemann; D'Anna; Carbonniere; Gil Bardaji; Fichtner; Journal of Physical Chemistry A; vol. 113; nb. 50; (2009); p. 13932 - 13936 ; (from Gmelin), View in Reaxys 14 of 38

Description (IR Spectroscopy)

Spectrum

Solvent (IR Spectroscopy)

neat (no solvent, solid phase)

Temperature (IR Spectroscopy) [°C]

Comment (IR Spectroscopy)

500 cm**-1 - 4000 cm**-1

Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys 15 of 38

Description (IR Spectroscopy)

Spectrum

Solvent (IR Spectroscopy)

water

Temperature (IR Spectroscopy) [°C]

Comment (IR Spectroscopy)

500 cm**-1 - 4000 cm**-1

Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys 16 of 38

Description (IR Spectroscopy)

Bands

57/68

2018-02-24 07:07:56

Solvent (IR Spectroscopy)

neat (no solvent, solid phase)

Temperature (IR Spectroscopy) [°C]

Comment (IR Spectroscopy)

500 cm**-1 - 4000 cm**-1

Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys 17 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

water

Temperature (IR Spectroscopy) [°C]

Comment (IR Spectroscopy)

500 cm**-1 - 4000 cm**-1

Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys 18 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

potassium bromide

Comment (IR Spectroscopy)

1110 cm**-1 - 2284 cm**-1

Chater, Philip A.; Anderson, Paul A.; Prendergast, James W.; Walton, Allan; Mann, Vicky S.J.; Book, David; David, William I.F.; Johnson, Simon R.; Edwards, Peter P.; Journal of Alloys and Compounds; vol. 446-447; (2007); p. 350 - 354 ; (from Gmelin), View in Reaxys 19 of 38

Description (IR Spectroscopy)

Spectrum

Solvent (IR Spectroscopy)

solid

Comment (IR Spectroscopy)

1000 cm**-1 - 4000 cm**-1

Jeon, Eun; Cho, YoungWhan; Journal of Alloys and Compounds; vol. 422; nb. 1-2; (2006); p. 273 - 275 ; (from Gmelin), View in Reaxys 20 of 38

Description (IR Spectroscopy)

Spectrum

Solvent (IR Spectroscopy)

neat (no solvent, solid phase)

Temperature (IR Spectroscopy) [°C]

Comment (IR Spectroscopy)

500 cm**-1 - 4400 cm**-1

Renaudin; Gomes; Hagemann; Keller; Yvon; Journal of Alloys and Compounds; vol. 375; nb. 1-2; (2004); p. 98 106 ; (from Gmelin), View in Reaxys 21 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

neat (no solvent, solid phase)

Temperature (IR Spectroscopy) [°C]

Comment (IR Spectroscopy)

500 cm**-1 - 4400 cm**-1

58/68

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Renaudin; Gomes; Hagemann; Keller; Yvon; Journal of Alloys and Compounds; vol. 375; nb. 1-2; (2004); p. 98 106 ; (from Gmelin), View in Reaxys 22 of 38

Description (IR Spectroscopy)

Spectrum

Solvent (IR Spectroscopy)

diethyl ether

Comment (IR Spectroscopy)

400 cm**-1 - 2600 cm**-1

Bulychev; Burlakova; Storozhenko; Russian Journal of Inorganic Chemistry; vol. 43; nb. 5; (1998); p. 752 - 758 ; (from Gmelin), View in Reaxys 23 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

diethyl ether

Comment (IR Spectroscopy)

400 cm**-1 - 2600 cm**-1

Bulychev; Burlakova; Storozhenko; Russian Journal of Inorganic Chemistry; vol. 43; nb. 5; (1998); p. 752 - 758 ; (from Gmelin), View in Reaxys 24 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

further solvent(s)

Comment (IR Spectroscopy)

1800 cm**-1 - 2700 cm**-1

Mal'tseva, N. N.; Myakishev, K. G.; Saidov, B. I.; Kedrova, N. S.; Gorbacheva, I. I.; et al.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 34; (1989); p. 806 - 808; Zhurnal Neorganicheskoi Khimii; vol. 34; (1989); p. 1430 - 1434 ; (from Gmelin), View in Reaxys 25 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

H2O

Comment (IR Spectroscopy)

2200 cm**-1 - 2272 cm**-1

X; Journal of the American Chemical Society; vol. 104; (1982); p. 6247 - 6251 ; (from Gmelin), View in Reaxys 26 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

not given

Comment (IR Spectroscopy)

1120 cm**-1 - 2420 cm**-1

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

not given

Comment (IR Spectroscopy)

1120 cm**-1 - 2380 cm**-1

Bhattacharjee, Mitra; Bhattacharjee, Apurba K.; Mahanti, Mahendra K.; Bulletin of the Chemical Society of Japan; vol. 54; nb. 11; (1981); p. 3566 - 3569 ; (from Gmelin), View in Reaxys 28 of 38

Description (IR Spectroscopy)

Bands

59/68

2018-02-24 07:07:56

Solvent (IR Spectroscopy)

paraffin

Comment (IR Spectroscopy)

400 cm**-1 - 4000 cm**-1

Titov, L. V.; Levicheva, M. D.; Rosolovskii, V. Ya.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 25; (1980); p. 1625 - 1627; Zhurnal Neorganicheskoi Khimii; vol. 25; (1980); p. 2953 2958 ; (from Gmelin), View in Reaxys 29 of 38

Description (IR Spectroscopy)

Coker, E. H.; Hofer, D. E.; Journal of Chemical Physics; vol. 48; (1958); p. 2713 - 2719, View in Reaxys; Davis, R. E.; Kenson, R. E.; Proceedings of the Indiana Academy of Science; vol. 76; (1966); p. 236 - 239, View in Reaxys; Schutte, C. J. H.; Spectrochimica Acta; vol. 16; (1960); p. 1054 - 1059, View in Reaxys; Shirk, A. E.; Shriver, D. F.; Journal of the American Chemical Society; vol. 95; (1973); p. 5901 - 5904, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 30 of 38

Solvent (IR Spectroscopy)

not given

Temperature (IR Spectroscopy) [°C]

-193

Comment (IR Spectroscopy)

500 cm**-1 - 4000 cm**-1

Harvey, K. B.; McQuaker, N, R.; Canadian Journal of Chemistry; vol. 49; (1971); p. 3272 - 3281 ; (from Gmelin), View in Reaxys 31 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

not given

Comment (IR Spectroscopy)

1119 cm**-1 - 2393 cm**-1

Harvey, K. B.; McQuaker, N, R.; Canadian Journal of Chemistry; vol. 49; (1971); p. 3272 - 3281, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 32 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

not given

Comment (IR Spectroscopy)

1121 cm**-1 - 2398 cm**-1

Volkov, V. V.; Sobolev, E. V.; Grankina, Z. A.; Kalinina, I. S.; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 343 - 347; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 659 - 664, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18 ; (from Gmelin), View in Reaxys 33 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

not given

Comment (IR Spectroscopy)

1125 cm**-1 - 2375 cm**-1

Goubeau, J.; Kallfass, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 299; (1959); p. 160 - 169, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys 34 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

not given

Comment (IR Spectroscopy)

600 cm**-1 - 4000 cm**-1

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2018-02-24 07:07:56

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Waddington, T. C.; Journal of the Chemical Society; (1958); p. 4783 - 4784 ; (from Gmelin), View in Reaxys 35 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

further solvent(s)

Signals [cm-1]

2240

Hough, W. V.; Edwards, L. J.; McElroy, A. D.; Journal of the American Chemical Society; vol. 80; (1958); p. 1828 1829, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys 36 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

potassium bromide

Comment (IR Spectroscopy)

1125 cm**-1 - 2280 cm**-1

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

not given

Comment (IR Spectroscopy)

1121 cm**-1 - 2298 cm**-1

Hornig, D. F.; Discussions of the Faraday Society; vol. 9; (1950); p. 115 - 124, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys 38 of 38

Description (IR Spectroscopy)

Bands

Solvent (IR Spectroscopy)

not given

Comment (IR Spectroscopy)

900 cm**-1 - 2700 cm**-1

Price, W. C.; Longuet-Higgins, H. C.; Rice, B.; Young, T. F.; Journal of Chemical Physics; vol. 17; (1949); p. 217 218, View in Reaxys; Price, W. C.; Journal of Chemical Physics; vol. 17; (1949); p. 1044 - 1052, View in Reaxys; vol. Na: SVol.3; 3.6.1, page 1212 - 1222 ; (from Gmelin), View in Reaxys Mass Spectrometry (1) Comment (Mass References Spectrometry) Molecular peak

Patent; Cowart, Marlon D.; Sun, Minghua; Zhao, Chen; Zheng, Guo Zhu; US2007/66588; (2007); (A1) English, View in Reaxys; Patent; Boddupalli, Sekhar; Walkinshaw, Gail; Wang, Bing; US2004/63975; (2004); (A1) English, View in Reaxys

UV/VIS Spectroscopy (2) 1 of 2

Description (UV/VIS Spectroscopy)

Spectrum

Zhang, Song-Song; Song, Ji-Ming; Niu, He-Lin; Mao, Chang-Jie; Zhang, Sheng-Yi; Shen, Yu-Hua; Journal of Alloys and Compounds; vol. 585; (2014); p. 40 - 47, View in Reaxys; Khan, Zaheer; Ahmed Al-Thabaiti, Shaeel; Hussain, Shokit; RSC Advances; vol. 6; nb. 9; (2016); p. 7267 - 7278, View in Reaxys 2 of 2

Absorption Maxima (UV/ 284 VIS) [nm] Log epsilon

3.46

Uchimasu, Hajime; Matsumura, Ken; Tsuda, Masashi; Kumagai, Keiko; Akakabe, Mai; Fujita, Masaki J.; Sakai, Ryuichi; Tetrahedron; vol. 72; nb. 45; (2016); p. 7185 - 7193, View in Reaxys Rotational Spectroscopy (1)

61/68

2018-02-24 07:07:56

Description (Rota- References tional Spectroscopy) Microwave spectrum

Kawashima, Yoshiyuki; Yamada, Chikashi; Hirota, Eizi; Journal of Chemical Physics; vol. 94; nb. 12; (1991); p. 7707 - 7712 ; (from Gmelin), View in Reaxys

Raman Spectroscopy (2) Description (Ram- References an Spectroscopy) Spectrum

Olsen, Jorn Eirik; Karen, Pavel; Sorby, Magnus H.; Hauback, Bjorn C.; Journal of Alloys and Compounds; vol. 587; (2014); p. 374 - 379, View in Reaxys

Raman

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Coker, E. H.; Campbell, B. H.; Proc. S. Dakota Acad. Sci.; vol. 44; (1965); p. 128 - 139, View in Reaxys; Emery, A. R.; Taylor, R. C.; Journal of Chemical Physics; vol. 28; (1958); p. 1029 - 1032, View in Reaxys; Harvey, K. B.; McQuaker, N, R.; Canadian Journal of Chemistry; vol. 49; (1971); p. 3272 - 3281, View in Reaxys; Shirk, A. E.; Shriver, D. F.; Journal of the American Chemical Society; vol. 95; (1973); p. 5901 - 5904, View in Reaxys; Taylor, R. C.; Schultz, D. R.; Emery, A. R.; Journal of the American Chemical Society; vol. 80; (1958); p. 27 - 30, View in Reaxys; Volkov, V. V.; Sobolev, E. V.; Grankina, Z. A.; Kalinina, I. S.; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 343 - 347; Zhurnal Neorganicheskoi Khimii; vol. 13; (1968); p. 659 - 664, View in Reaxys; Watanabe, H.; Nagasawa, K.; Inorganic Chemistry; vol. 6; (1967); p. 1068 - 1070, View in Reaxys; vol. B: B-Verb.8; 1.3.1, page 6 - 18, View in Reaxys; Nibler, J. W.; Coe, J.; in: J. W. Nibler, D. F. Shriver, T. H. Cook, J. Chem. Phys. 54 (1971) 5257/66, 5260, View in Reaxys; X; Journal of the American Chemical Society; vol. 104; (1982); p. 6247 - 6251, View in Reaxys; Nakamori, Yuko; Orimo, Shin-ichi; Journal of Alloys and Compounds; vol. 370; nb. 1-2; (2004); p. 271 - 275, View in Reaxys; Renaudin; Gomes; Hagemann; Keller; Yvon; Journal of Alloys and Compounds; vol. 375; nb. 1-2; (2004); p. 98 - 106, View in Reaxys; Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133, View in Reaxys; Seballos, Leo; Zhang, Jin Z.; Roennebro, Ewa; Herberg, Julie L.; Majzoub; Journal of Alloys and Compounds; vol. 476; nb. 1-2; (2009); p. 446 - 450 ; (from Gmelin), View in Reaxys

Other Spectroscopic Methods (2) Description (Oth- References er Spectroscopic Methods) ESCA

Kuznetsov, N. T.; Saidov, B. I.; Kedrova, N. S.; Shevchenko, Yu. N.; Chuvaev, A. V.; Maltseva, N. N.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 17; (1991); p. 218 - 223; Koordinatsionnaya Khimiya; vol. 17; (1991); p. 110 - 416, View in Reaxys; Schreifels, J. A.; Maybury, P. C.; Swartz, W. E. Jr.; Journal of Catalysis; vol. 65; (1980); p. 195 - 206 ; (from Gmelin), View in Reaxys

Electron energy loss spectrum

Herley, Patrick J.; Jones, William; Zeitschrift fuer Physikalische Chemie (Muenchen, Germany); vol. 147; (1986); p. 147 - 160 ; (from Gmelin), View in Reaxys

Use (45) Laboratory Use and Handling

Use Pattern

Location

References

Chemical processes/laboratory use

Page/Page column 34

Patent; Clariant Finance (BVI) Limited; Hill, Michael; Bauer, Harald; Krause, Werner; Sicken, Martin; (21 pag.); US9279085; (2016); (B2) English, View in Reaxys

catalyst for proPage/Page colducing monofunc- umn 34 tionalized dialkylphosphinic acids, esters or salts

Patent; Clariant Finance (BVI) Limited; Hill, Michael; Bauer, Harald; Krause, Werner; Sicken, Martin; (21 pag.); US9279085; (2016); (B2) English, View in Reaxys

Medical equipment

Page/Page column 57; 59; 60

Patent; LIFE TECHNOLOGIES CORPORATION; HU, Yi-Zhen; CHEN, Aimei; KANG, Hee Chol; GEE, Kyle; MANDAVILLI, Bhaskar; WO2013/148038; (2013); (A1) English, View in Reaxys

reducing agent in Page/Page colkit for detecting umn 57; 59; 60 reactive oxygen species (ROS) for diagnose a disease or disorder

Patent; LIFE TECHNOLOGIES CORPORATION; HU, Yi-Zhen; CHEN, Aimei; KANG, Hee Chol; GEE, Kyle; MANDAVILLI, Bhaskar; WO2013/148038; (2013); (A1) English, View in Reaxys

thermal stable up to 230°C

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Catalyst for synthesis of phytosterol esters

Patent; WILEY ORGANICS, INC.; US2008/15374; (2008); (A1) English, View in Reaxys

Reductive bleaching agent

Patent; WILEY ORGANICS, INC.; US2008/15374; (2008); (A1) English, View in Reaxys

Catalyst for transesterificatio reaction

Patent; WILEY ORGANICS, INC.; US2008/15374; (2008); (A1) English, View in Reaxys

agent for selective reducing carboxyl groups on the carboxyl-containing polymer surface to surface hydroxymethyl groups without altering the nature of the bulk of the polymer

Patent; RESEARCH FOUNDATION OF CITY UNIVERSITY OF NEW YORK; WO2008/18890; (2008); (A2) English, View in Reaxys

pharmacophore modification reagent of a secured transdermal delivery system

Patent; Todhunter, John A.; US2008/286348; (2008); (A1) English, View in Reaxys

stable in alkaline aq. soln. at room temp.

Filinchuk, Yaroslav; Hagemann, Hans; European Journal of Inorganic Chemistry; nb. 20; (2008); p. 3127 - 3133 ; (from Gmelin), View in Reaxys reducing agent

information on use

Patent; Suda, Seijirau; Li, Zhoupeng; Iwase, Yasuyoshi; Morigasaki, Nobuto; US2004/249215; (2004); (A1) English, View in Reaxys; Patent; DSM FINE CHEMICALS AUSTRIA NFG GMBH and CO KG; WO2005/63682; (2005); (A1) German, View in Reaxys; Patent; Grancharov, Stephanie; O'Brien, Stephen; Held, Glenn; Murray, Christopher Bruce; US2006/140868; (2006); (A1) English, View in Reaxys; Patent; Wella Aktiengesellschaft; EP1704847; (2006); (A1) English, View in Reaxys; Patent; AUROBINDO PHARMA LIMITED; WO2008/72078; (2008); (A1) English, View in Reaxys; Patent; Todhunter, John A.; US2008/286348; (2008); (A1) English, View in Reaxys; Patent; CHUGAI SEIYAKU KABUSHIKI KAISHA; EP1593378; (2005); (A1) English, View in Reaxys; Patent; TAISHO PHARMACEUTICAL CO., LTD; Sato, Fumie; EP1598335; (2005); (A1) English, View in Reaxys; Patent; Smith, Vanessa; Nigro, Anthony; Mulvihill, Mark; Cesario, Cara; Beck, Patricia Anne; Castelhano, Arlindo L.; US2006/9645; (2006); (A1) English, View in Reaxys Apeloig; Karni; Stang; Fox; Journal of the American Chemical Society; vol. 105; nb. 14; (1983); p. 4781 - 4792, View in Reaxys; Verkoyen, Carl; Rademacher, Paul; Chemische Berichte; vol. 117; nb. 5; (1984); p. 1659 - 1670, View in Reaxys; Heinzman, Stephen W.; Ganem, Bruce; Journal of the American Chemical Society; vol. 104; nb. 24; (1982); p. 6801 - 6802, View in Reaxys; Ward, Dale E.; Rhee, Chung K.; Canadian Journal of Chemistry; vol. 67; (1989); p. 1206 - 1211, View in Reaxys; Lin, Ronghui; Zhang, Yongmin; Synthetic Communications; vol. 17; nb. 12; (1987); p. 1403 - 1408, View in Reaxys; Ono, Aoi; Maruyama, Tamiko; Suzuki, Nobuko; Synthetic Communications; vol. 17; nb. 8; (1987); p. 1001 - 1006, View in Reaxys; Kanai, Hiroyoshi; Sakai, Shigeyoshi; Sakatani, Takenobu; Bulletin of the Chemical Society of Japan; vol. 60; (1987); p. 1589 - 1594, View in Reaxys; Butlin, Roger J.; Linney, Ian D.; Mahon, Mary F.; Tye, Heather; Wills, Martin; Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999); nb. 1; (1996); p. 95 - 106, View in Reaxys; Barbero, Asun; Blakemore, David C.; Fleming, Ian; Wesley, Robert N.; Journal of the Chemical Society - Perkin Transactions 1; nb. 9; (1997); p. 1329 - 1352, View in Reaxys; Inoue, Katsuyuki; Sawada, Akemi; Shibata, Ikuya; Baba, Akio; Journal of the American

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Chemical Society; vol. 124; nb. 6; (2002); p. 906 - 907, View in Reaxys; Pasniczek, Konrad; Socha, Dariusz; Jurczak, Margarita; Solecka, Jolanta; Chmielewski, Marek; Canadian Journal of Chemistry; vol. 84; nb. 4; (2006); p. 534 - 539, View in Reaxys; Siwicka, Aleksandra; Wojtasiewicz, Krystyna; Leniewski, Andrzej; Maurin, Jan K.; Zawadzka, Anna; Czarnocki, Zbigniew; Canadian Journal of Chemistry; vol. 85; nb. 12; (2007); p. 1033 - 1036, View in Reaxys; Jursic, Branko; Sunko, Dionis E.; Journal of Chemical Research, Synopses; (1988); p. 202 - 203, View in Reaxys; Abdel-Akher, M.; Hamilton, J. K.; Montgomery, R.; Smith, F.; Journal of the American Chemical Society; vol. 74; (1952); p. 4970 4971, View in Reaxys; Lindberg, B.; Misiorny, A.; Svensk Papperstid.; vol. 55; (1952); p. 13 - 14, View in Reaxys; Skell, P. S.; Crist, J. G.; Nature (London, United Kingdom); vol. 173; (1954); p. 401, View in Reaxys; vol. Na: SVol.3; 3.6.2, page 1223 - 1233, View in Reaxys; Ookawa, Atsuhiro; Hiratsuka, Hiroshi; Soai, Kenso; Watanabe, Kenji; Takeda, Akira; Bulletin of the Chemical Society of Japan; vol. 60; (1987); p. 1813 - 1818, View in Reaxys; Doyle, Marc; Arora, Pankaj; Journal of the Electrochemical Society; vol. 148; nb. 11; (2001); p. K1-K41, View in Reaxys; Li; Liu; Arai; Morigazaki; Suda; Journal of Alloys and Compounds; vol. 356-357; (2003); p. 469 - 474, View in Reaxys; Li; Liu; Arai; Suda; Journal of Alloys and Compounds; vol. 404-406; nb. SPEC. ISS.; (2005); p. 648 - 652, View in Reaxys; Liu, Zhen-Jiang; Liu, Jin-Tao; Chemical Communications; nb. 41; (2008); p. 5233 - 5235 ; (from Gmelin), View in Reaxys Reducing agent

Patent; BOEHRINGER INGELHEIM INTERNATIONAL GMBH; BOEHRINGER INGELHEIM PHARMA GMBH and CO. KG; WO2005/92880; (2005); (A1) German, View in Reaxys; Patent; Thippannachar, Vijayavitthal Mathad; Jayantilal, Pravinchandra Vankawala; Elati, Chandrasekhar Ravi Ram; Kolla, Naveen Kumar; Chlamala, Subrahmanyeswara Rao; US2006/264637; (2006); (A1) English, View in Reaxys; Patent; Board of Regents, The University of Texas System; US2007/82881; (2007); (A1) English, View in Reaxys

Reducing agent in preparation of highly pure Fexofenadine

Patent; IND-SWIFT LABORATORIES LIMITED; WO2007/49303; (2007); (A2) English, View in Reaxys

Hydrogen storage in thermally-recoverable fuel compositions

Patent; Kelly, Michael T.; McNamara, Kevin W.; Sun, Xiaolei; US2007/68071; (2007); (A1) English, View in Reaxys

Reducing agent for preparation of catalyst for producing aliphatic amines

Patent; KAO CORPORATION; WO2007/77903; (2007); (A2) English, View in Reaxys

preparing taxoid Page/Page colderivative covaumn 2 lently linked to tumor-specific antibody useful as anticancer agents

Patent; Hamada, Hiroki; Mikuni, Katsuhiko; Nakanishi, Katsuyoshi; Mandai, Tadakatsu; US2007/25995; (2007); (A1) English, View in Reaxys

reducing agent

Patent; Hamada, Hiroki; Mikuni, Katsuhiko; Nakanishi, Katsuyoshi; Mandai, Tadakatsu; US2007/25995; (2007); (A1) English, View in Reaxys

Page/Page column 2

handling described

Nakamori, Yuko; Orimo, Shin-ichi; Journal of Alloys and Compounds; vol. 370; nb. 1-2; (2004); p. 271 - 275, View in Reaxys; Simagina; Storozhenko; Netskina; Komova; Odegova; Samoilenko; Gentsler; Kinetics and Catalysis; vol. 48; nb. 1; (2007); p. 168 175 ; (from Gmelin), View in Reaxys Reagent

Patent; ZENYAKU KOGYO KABUSHIKIKAISHA; WO2006/62201; (2006); (A1) Japanese, View in Reaxys

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reducing agent in liquid catalytic composition which allows selective hydrogenation of polyunsaturated compounds to monounsaturated compounds

Patent; INSTITUTE FRANCAIS DU PETROLE; US2006/129010; (2006); (A1) English, View in Reaxys

Sacrificial reductant required for oxidizing alcohol over polystyrene encapsulated catalyst containing metalloporphyrin to obtain corresponding ketone

Patent; COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH; US2006/167313; (2006); (A1) English, View in Reaxys

compositions comprising choline hydroxide

Patent; AKZO NOBEL N.V.; WO2006/5692; (2006); (A1) English, View in Reaxys

stabilizer

Patent; AKZO NOBEL N.V.; WO2006/5692; (2006); (A1) English, View in Reaxys

production of paper

Patent; AKZO NOBEL N.V.; WO2006/5692; (2006); (A1) English, View in Reaxys

biomagnetic nanoparticles

Patent; Grancharov, Stephanie; O'Brien, Stephen; Held, Glenn; Murray, Christopher Bruce; US2006/140868; (2006); (A1) English, View in Reaxys

Neutralizing additive

Patent; Viswanathan, Krishnan; US2005/85673; (2005); (A1) English, View in Reaxys

producing chiral or enantiomer-enriched γ-amino alcohols

Patent; DSM FINE CHEMICALS AUSTRIA NFG GMBH and CO KG; WO2005/63682; (2005); (A1) German, View in Reaxys

compositions for deodorization of natural pigments from fish

Patent; Song, Leila; Turner, Dennis F.; Lewis, Robert A.; US2005/142083; (2005); (A1) English, View in Reaxys

reduction of nitro group

Patent; TIBOTEC PHARMACEUTICALS LTD.; WO2005/63770; (2005); (A1) English, View in Reaxys

Reductant

Patent; TIBOTEC PHARMACEUTICALS LTD.; WO2005/63770; (2005); (A1) English, View in Reaxys

stable in aq. alkaline soln.

Oezkar; Zahmakiran; Journal of Alloys and Compounds; vol. 404-406; nb. SPEC. ISS.; (2005); p. 728 - 731 ; (from Gmelin), View in Reaxys reducing agent for preparing silver/ polymer composite nanospheres for preservation of cosmetics

Patent; AMOREPACIFIC CORPORATION; WO2005/77329; (2005); (A1) English, View in Reaxys

reducing agent for hair or make-up cosmetic composition

Patent; Mathonneau, Estelle; Rollat, Isabelle; Giroud, Franck; US2005/186165; (2005); (A1) English, View in Reaxys

reagent for trifluoroacetate group removing

Patent; MERCK and CO., INC.; WO2005/110409; (2005); (A2) English, View in Reaxys

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Reagent for the synthesis of catalysts for the oligoor polymerisation of olefines

Patent; ERNST MORITZ ARNDT UNIVERSITAeT GREIFSWALD; WO2005/123752; (2005); (A1) German, View in Reaxys; Patent; ERNST MORITZ ARNDT UNIVERSITAeT GREIFSWALD; WO2005/123753; (2005); (A1) German, View in Reaxys

reduction

Patent; Kuraray Co., Ltd.; SAGAMI CHEMICAL RESEARCH CENTER; EP1352907; (2003); (A1) English, View in Reaxys

complete decomposition in methanol in 30 min

Sim, Tae Bo; Yoon, Nung Min; Bulletin of the Chemical Society of Japan; vol. 70; nb. 5; (1997); p. 1101 - 1107 ; (from Gmelin), View in Reaxys

alkaline solns. are fairly stable at room temp. and on heating to 100°C

Khain, V. S.; Volkov, A. A.; Journal of Applied Chemistry USSR (English Translation); vol. 53; (1980); p. 1765 - 1768; Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation); vol. 53; (1980); p. 2404 - 2407 ; (from Gmelin), View in Reaxys

bedded Na(BH4) insensitive to atmospheric hunidity

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Patent; Seemuller, J. R.; Siciete Monsavon-lOreal; GB828208; (1960); C.A.; (1960); p. 25642, View in Reaxys; Patent; Seemuller, J. R.; Societe Monsavon-lOreal; FR1123235; (1956); C.; (1960); p. 609, View in Reaxys; Seemuller, J. R. Societe Monsavon-lOreal; D. A. S. 1069588 (1956/59) ; (from Gmelin), View in Reaxys

stable in He-atm. at 400°C

purple-color by Xray, slowly disappeared with sunlight illumination, quickly by heating at 120°C

p(H2O) >= 8.1 Torr (steam-pressure) deliquesce at 24°C; stable under p(H2O) = 7.19 Torr at 24°C

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Jensen, E. H.; A Study on Sodium Borohydride, Copenhagen 1954, S. 31 ; (from Gmelin), View in Reaxys

very stable on dry air, decompn. very slowly on moist air, stable on air till 300°C, with flame light up

vol. Na: SVol.3; 3.6.1, page 1212 - 1222, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Bull. 502-E., View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 8, View in Reaxys; Metal Hydrides Inc.Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1978, S.11 ; (from Gmelin), View in Reaxys

Quantum Chemical Calculations (8) Calculated Prop- Method (Quantum References erties Chemical Calculations) Elastic constants

Ab initio calcns. Zhang, Xiao-Dong; Hou, Zhu-Feng; Jiang, Zhen-Yi; Hou, Yu-Qing; Physica B: Con(LCAO, GO SCF, densed Matter; vol. 406; nb. 11; (2011); p. 2196 - 2199 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Total energy; Atom distances, angles; Heat capacity cp, cv; IR bands, intensities, transition moments; Density of states

Ab initio calcns. Caputo, Riccarda; Tekin, Adem; Journal of Solid State Chemistry; vol. 184; nb. 7; (LCAO, GO SCF, (2011); p. 1622 - 1630 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Total energy; Elastic constants

Ab initio calcns. (LCAO, GO SCF,

Kim, Eunja; Kumar, Ravhi; Weck, Philippe F.; Cornelius, Andrew L.; Nicol, Malcolm; Vogel, Sven C.; Zhang, Jianzhong; Hartl, Monika; Stowe, Ashley C.; Daemen, Luke;

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DIM, SAMO, X-al- Zhao, Yusheng; Journal of Physical Chemistry B; vol. 111; nb. 50; (2007); p. 13873 pha, Hartree13876 ; (from Gmelin), View in Reaxys Fock) Density of states; Elastic constants; Total energy

Ab initio calcns. Vajeeston; Ravindran; Kjekshus; Fjellvag; Journal of Alloys and Compounds; vol. 387; (LCAO, GO SCF, nb. 1-2; (2005); p. 97 - 104 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Density of states; Band structure

Ab initio calcns. Orgaz; Membrillo; Castaneda; Aburto; Journal of Alloys and Compounds; vol. (LCAO, GO SCF, 404-406; nb. SPEC. ISS.; (2005); p. 176 - 180 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Vibrational constants

Ab initio calcns. Allis, Damian G.; Hudson, Bruce S.; Chemical Physics Letters; vol. 385; nb. 3-4; (LCAO, GO SCF, (2004); p. 166 - 172 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Atom distances, angles; IR bands, intensities, transition moments

Ab initio calcns. Bremer, Mathias; Noeth, Heinrich; Warchhold, Marcus; European Journal of Inorganic (LCAO, GO SCF, Chemistry; nb. 1; (2003); p. 111 - 119 ; (from Gmelin), View in Reaxys DIM, SAMO, X-alpha, HartreeFock)

Electronegativity

Other semi-empir- Kaganyuk, D. S.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neoical calcns. rganicheskoi Khimii); vol. 22; (1977); p. 1247 - 1248; Zhurnal Neorganicheskoi Khimii; (Hueckel, PPP) vol. 22; (1977); p. 2305 - 2306 ; (from Gmelin), View in Reaxys

Medchem (4) 1 of 4

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

pyruvate level; decrease ofserum of Calf

Substance RN

11343078View in Reaxys

Qualitative Results

molecular target: pyruvate

Measurement Parameter

Qualitative

Qualitative value

Naka, Tomoko; Ito, Tomokazu; Hemmi, Hisashi; Yoshimura, Tohru; Journal of Molecular Catalysis B: Enzymatic; vol. 67; nb. 1-2; (2010); p. 150 - 154, View in Reaxys 2 of 4

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

pyruvate level; decrease ofserum of Calf

Substance RN

11343078View in Reaxys

Measurement Parameter

% Inhibition

Unit

percent

Quantitative value

Naka, Tomoko; Ito, Tomokazu; Hemmi, Hisashi; Yoshimura, Tohru; Journal of Molecular Catalysis B: Enzymatic; vol. 67; nb. 1-2; (2010); p. 150 - 154, View in Reaxys 3 of 4

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

neurotensin (NT) binding to cells; effect onPC3

Substance RN

11343078View in Reaxys

Measurement Parameter

Qualitative

Qualitative value

Patent; Carraway, Robert E.; US2006/62729; (2006); (A1) English, View in Reaxys 4 of 4

Bioassay Category

In Vitro (Efficacy)

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Bioassay Details

aortic vasorelaxation; effect onaortic rings of Lewis rat

Substance RN

11343078View in Reaxys

Measurement Parameter

Qualitative

Qualitative value

Patent; NORTHWICK PARK INSTITUTE FOR MEDICAL RESEARCH; UNIVERSITY OF ZURICH; WO2005/13691; (2005); (A1) English, View in Reaxys

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