Sodium borohydride (Sodium tetrahydroborate; NaBH4) [BH4Na] by Asch

Reaxys

PubChem

eMolecules

Bioactivities (1284)

Yield

LabNetwork

SigmaAldrich

Reactions (166)

Substances (173)

Targets (168)

Citations (200)

Conditions

References A

Synthesize Find similar

Synthesize Find similar Rx-ID: 45323718 Find similar reactions

Synthesize Find similar

Saldin; Sukhovei; Savchenko; Slobodyuk; Kavun, V. Ya.

Russian Journal of Inorganic Chemistry, 2017 , vol. 62, # 4 p. 489 - 497 Zh. Neorg. Khim., 2017 , vol. 62, # 4 p. 489 - 497,9 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent) T=289.84°C; Inert atmosphere;

Synthesize Find similar

Rx-ID: 45440265 Find similar reactions

Synthesize Find similar

Møller, Kasper T.; Grinderslev, Jakob B.; Jensen, Torben R.

Journal of Alloys and Compounds, 2017 , vol. 720, p. 497 - 501 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent) 1 h; Inert atmosphereMilling; Mechanism; Time; Hide Experimental Procedure

1:1 Mixtures were treated mechanochemically under an argon atmosphere. The powders were ball-milled for 5 min at 350 rpm followed by abreak of 3 min, to prevent sample overheating and possible decomposition of products. The milling program was repeated 12, 36 or 72 times to establish an effective ball-milling time of 1, 3 or 6 h, respectively.

Synthesize Find similar

Rx-ID: 46352773 Find similar reactions

With magnesium silicide; magnesium

T=20°C; 20 h; MillingGloveboxInert atmosphere; Mechanism; ConcentrationTime; Hide Experimental Procedure

Huang, Miaojun; Zhong, Hao; Ouyang, Liuzhang; Peng, Chenghong; Zhu, Xiaoke; Zhu, Weiheng; Fang, Fang; Zhu, Min

Journal of Alloys and Compounds, 2017 , vol. 729, p. 1079 - 1085 Title/Abstract Full Text View citing articles Show Details

2.2 Synthesis of NaBH4

The stoichiometric Mg powders, Mg2Si powders and NaBO2·2H2O powders were placed into a stainless steel reactor and ball milled in a vibrational ball mill (QM-3C, Nanjing, China). The mixture of Mg, Mg2Si and NaBO2·2H2O (0.9:1.8:1M ratio) was ball milled at 1200 cycles per minute. Each sample was obtained by ball milling 1g of reactants (the mixture of Mg, Mg2Si and NaBO2·2H2O), which were loaded into the jar, with a ball to powder ratio of 50:1at ambient temperature. In each experiment, the powders obtained were preserved and manipulated inside a glove box under a high purity argon atmosphere with O2 and H2O levels below 0.1ppm.

Synthesize Find similar

Rx-ID: 46448205 Find similar reactions

Synthesize Find similar

75%

Chen, Xi-Meng; Li, Huizhen; Yang, Qiu-Yu; Wang, Rui-Rui; Hamilton, Ewan J. M.; Zhang, Jie; Chen, Xuenian

European Journal of Inorganic Chemistry, 2017 , vol. 2017, # 38 p. 4541 - 4545 Title/Abstract Full Text View citing articles Show Details

in tetrahydrofuran

T=20°C; 5 h; Inert atmosphere;

Synthesize Find similar

Rx-ID: 46448206 Find similar reactions

78%

Synthesize Find similar

Chen, Xi-Meng; Li, Huizhen; Yang, Qiu-Yu; Wang, Rui-Rui; Hamilton, Ewan J. M.; Zhang, Jie; Chen, Xuenian

European Journal of Inorganic Chemistry, 2017 , vol. 2017, # 38 p. 4541 - 4545 Title/Abstract Full Text View citing articles Show Details

in tetrahydrofuran

5 h; Inert atmosphere;

Synthesize Find similar

Rx-ID: 44273209 Find similar reactions

Wegner; Jaroń; Dobrowolski; Dobrzycki; Cyrański; Grochala

Dalton Transactions, 2016 , vol. 45, # 36 p. 14370 - 14377 Title/Abstract Full Text View citing articles Show Details

in dichloromethane

T=20°C; 1 h; Inert atmosphereGloveboxSchlenk technique;

Synthesize Find similar

Rx-ID: 44273210 Find similar reactions

Wegner; Jaroń; Dobrowolski; Dobrzycki; Cyrański; Grochala

Dalton Transactions, 2016 , vol. 45, # 36 p. 14370 - 14377 Title/Abstract Full Text View citing articles Show Details

in dichloromethane

T=-35 - 20°C; 0.5 h; Inert atmosphereGloveboxSchlenk technique;

Synthesize Find similar

Synthesize Find similar Rx-ID: 39970071 Find similar reactions

Tumanov, Nikolay A.; Safin, Damir A.; Richter, Bo; Łodziana, Zbigniew; Jensen, Torben R.; Garcia, Yann; Filinchuk, Yaroslav

Dalton Transactions, 2015 , vol. 44, # 14 p. 6571 - 6580 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent, solid phase) T=20°C; 60 h; Inert atmosphereSchlenk technique;

Synthesize Find similar

Synthesize Find similar Rx-ID: 41071477 Find similar reactions

B: 4.5 g

With sodium amalgam in neat (no solvent) Inert atmosphere; Hide Experimental Procedure

Schubert, David; Neiner, Doinita; Bowden, Mark; Whittemore, Sean; Holladay, Jamie; Huang, Zhenguo; Autrey, Tom

Journal of Alloys and Compounds, 2015 , vol. 645, # S1 art. no. 33105, p. S196 - S199 Title/Abstract Full Text View citing articles Show Details

Synthesis of NaB3H8

Solvent-free NaB3H8 was synthesized according to a published literature procedure[21]. A Na/Hg amalgam was reacted with THFBH3 under nitrogen to form NaBH4 and NaB3H8. After removal of THF and redissolution in diethyl ether, NaBH4 was removed by filtration. The filtrate was concentrated under vacuum to an oil from which NaB3H8 precipitated upon addition of dichloromethane. Approximately 4.5 g of the white powder was recovered by filtration and vacuum drying. It is notable that Titov has reported the preparation of a variety of cationic octohydrotriborates, i.e., lithium, potassium, magnesium, calcium and strontium, as solvates of dioxane or diglyme [22], while Chong et al. have prepared the unsolvated Mg(B3H8)2 by a diborane-free pathway by thermal decomposition of Mg(BH4)2 [23]. A

Synthesize Find similar Rx-ID: 38069361 Find similar reactions

Synthesize Find similar

Remhof, Arndt; Yan, Yigang; Rentsch, Daniel; Borgschulte, Andreas; Jensen, Craig M.; Zuettel, Andreas

in neat (no solvent) T=150°C;

Journal of Materials Chemistry A, 2014 , vol. 2, # 20 p. 7244 - 7249 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 38863098 Find similar reactions

Fijalkowski; Jaro; Leszczyski; Magos-Palasyuk; Palasyuk; Cyraski; Grochala

Physical Chemistry Chemical Physics, 2014 , vol. 16, # 42 p. 23340 - 23346 Title/Abstract Full Text Show Details

in neat (no solvent, solid phase) T=140 - 160°C;

Synthesize Find similar

Synthesize Find similar Rx-ID: 35012564 Find similar reactions

Electrolysis;

Synthesize Find similar

Shu, Chenhua; Sun, Tonghua; Jia, Jinping; Lou, Ziyang; Shen, Yafei

RSC Advances, 2013 , vol. 3, # 5 p. 1476 - 1485 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 35656697 Find similar reactions

Xia, Guanglin; Li, Li; Guo, Zaiping; Gu, Qinfen; Guo, Yanhui; Yu, Xuebin; Liu, Huakun; Liu, Zongwen

Journal of Materials Chemistry A, 2013 , vol. 1, # 2 p. 250 - 257 Title/Abstract Full Text View citing articles Show Details

T=200°C; Inert atmosphere; Activation energy; Temperature;

Synthesize Find similar

Rx-ID: 36419559 Find similar reactions

0.016g

Synthesize Find similar

Zhu, Qi-Yong; Zhu, Chuan-Gao; Wang, Feng-Wu; Wei, Yi-Jun

Asian Journal of Chemistry, 2013 , vol. 25, # 14 p. 7749 - 7752 Title/Abstract Full Text View citing articles Show Details

T=20°C; Electrochemical reaction; Concentration;

Synthesize Find similar

Synthesize Find similar Rx-ID: 29969309 Find similar reactions

With Na/Hg in tetrahydrofuran

treatment of borane deriv. with sodium amalgam in THF at room temp. for 3 d; evapn., addn. of dry diethyl ether, filtration, evapn., addn. of CH2Cl2,filtration, drying in vac., NMR;

Huang, Zhenguo; King, Graham; Chen, Xuenian; Hoy, Jason; Yisgedu, Teshome; Lingam, Hima K.; Shore, Sheldon G.; Woodward, Patrick M.; Zhao, Ji-Cheng

Inorganic Chemistry, 2010 , vol. 49, # 18 p. 8185 - 8187 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 29974632 Find similar reactions

With TiB2 in neat (no solvent) mixt. of LiBH4 and NaAlH4 contg. TiB2 ball-milled (390 rpm, WC material)under Ar for 2 h; XRD;

Ravnsbaek, Dorthe B.; Jensen, Torben R.

Journal of Physics and Chemistry of Solids, 2010 , vol. 71, # 8 p. 1144 - 1149 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 29974633 Find similar reactions

With TiB2 in neat (no solvent) mixt. of LiBH4 and NaAlH4 (molar ratio = 1:1.5) contg. TiB2 ball-milled (390 rpm, WC material) under Ar for 2 h; resulting mixt. dehydrogenated on slow heating to 500°C under Ar (ca. 1 bar); XRD;

Ravnsbaek, Dorthe B.; Jensen, Torben R.

Journal of Physics and Chemistry of Solids, 2010 , vol. 71, # 8 p. 1144 - 1149 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 28309247 Find similar reactions

Synthesize Find similar

in tetrahydrofuran

under inert atm. soln. BH3 in THF was added dropwise at -80°C to soln. Na salt tetraphosphene in THF, allowed to warm to room temp. and stirred for 2 days; not isolated - identified by NMR;

Lorbach, Andreas; Nadj, Andor; Tuellmann, Sandor; Dornhaus, Franz; Schoedel, Frauke; Saenger, Inge; Margraf, Guenter; Bats, Jan W.; Bolte, Michael; Holthausen, Max C.; Wagner, Matthias; Lerner, Hans-

Wolfram

Inorganic Chemistry, 2009 , vol. 48, # 3 p. 1005 - 1017 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 28738137 Find similar reactions

Synthesize Find similar

With magnesium in solid byproducts: MgO; High Pressure; Mg:B ratio 2:1-4:1; sealed, hydrogen added (3 MPa), heated at 600°C; XRD, SEM;

Liu, Bin Hong; Li, Zhou Peng; Zhu, Jing Ke

Journal of Alloys and Compounds, 2009 , vol. 476, # 1-2 p. L16-L20 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 28738138 Find similar reactions

Synthesize Find similar

With magnesium in solid byproducts: MgO; High Pressure; Mg:B ratio 2:1-4:1; sealed, hydrogen added (3 MPa), heated at 600°C; XRD, SEM;

Liu, Bin Hong; Li, Zhou Peng; Zhu, Jing Ke

Journal of Alloys and Compounds, 2009 , vol. 476, # 1-2 p. L16-L20 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 28738139 Find similar reactions

With magnesium in solid

Synthesize Find similar

Liu, Bin Hong; Li, Zhou Peng; Zhu, Jing Ke

byproducts: MgO; High Pressure; Mg:B ratio 2:1-4:1; sealed, hydrogen added (3 MPa), heated at 600°C; XRD, SEM;

Journal of Alloys and Compounds, 2009 , vol. 476, # 1-2 p. L16-L20 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 28982951 Find similar reactions

32%

Synthesize Find similar

With silica gel in solid powders ball milled for 4 h at 400 rpm, SiO2 added, ball-milled for 2 h more, pressed into pellet under 10, 20 or 30 MPa in Ar-filled box, calcined under 0.1 MPa Ar at 480°C for 5 h; extd. by isopropyl amine in modified Soxlet apparatus for 3 h; filtered,evapd. at 50°C;

Zhang, Hanping; Zheng, Shiyou; Fang, Fang; Chen, Guorong; Sang, Ge; Sun, Dalin

Journal of Alloys and Compounds, 2009 , vol. 484, # 1-2 p. 352 - 355 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 26165622 Find similar reactions

heating at 130°C or dried in vac.;

Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

Neal, H. R.; Beatty, H. A.

PB 106606, LTD 44-20 (1944) 5 Full Text Show Details

heating at 130°C or dried in vac.;

Gmelin Handbook: Na: SVol.3, 3.6.2, page 1223 - 1233 Full Text Show Details

heating at 130°C or dried in vac.;

Davis, W. D.; Mason, L. S.; Stegemann, G.

Journal of the American Chemical Society, 1949 , vol. 71, p. 2775 - 2781 Full Text Show Details

Hide Details

byproducts: H2O; rapid dehydration by vac. drying at 100°C on rotation vaporiser;

Shevchenko, Yu. N.; Sachok, V. V.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1977 , vol. 22, p. 1560 1562 Zhurnal Neorganicheskoi Khimii, 1977 , vol. 22, p. 2872 - 2874 Full Text Show Details

in neat (no solvent) byproducts: H2O; single crystals of NaBH4*2H2O rapidly ground in air; sealed; heated at 313-315 K; detd. by X-ray powder diffraction;

Filinchuk, Yaroslav; Hagemann, Hans

European Journal of Inorganic Chemistry, 2008 , # 20 p. 3127 - 3133 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 23138411 Find similar reactions

Synthesize Find similar

With magnesium

T=400 - 550°C; P=14251.4 - 17251.7 Torr; 2 - 4 h; Hide Experimental Procedure

Suda, Seijirau; Li, Zhoupeng; Iwase, Yasuyoshi; Morigasaki, Nobuto

Patent: US2004/249215 A1, 2004 ; Location in patent: Page 4; 5 ; Title/Abstract Full Text Show Details

1-4; 1:Example 1

This example serves to con effects of the preferred embodiment stated above. 0.35 g of powdery sodium metaborate of average particle diameter of 50 μm and 0.51 g of powdery magnesium of average particle diameter of 100 μm are fully mixed to a mixture and the mixture is filled in a reaction tube made of stainless steel. Then, after hydrogen gas is fed to the reaction tube at 400° C. under hydrogen pressure 2.3 MPa, temperature in the reaction tube or of hydrogen gas is raised to 550° C. The reaction quickly progresses when the temperature becomes over 500° C. With analysis by hydrogen generating method with hydrolysis or iodometric titration, yields are obtained during a period from start of reaction to three hours thereafter. The result is shown in FIG. 2. For example, 67percent yield is shown 2 hours after start of reaction. Percent yield is obtained by actual mol amount produced of product/theoretical reaction mol amount.x.100. Then, it is confirmed that sodium borohydride can be obtained with high yield.

With Mg in ethylenediamine

byproducts: MgO; High Pressure; mixt. of Mg and NaBH2 sealed into steel reactor; degassed; introduced H2into reactor at pressure of 3.1 MPa and at 25, 400 or 550°C; hea ted to 550°C; extd. by anhyd. ethylenediamine; evapd. from soln. under 0.01 MPa at room temp.; SEM, EPMA, XRD;

Li; Liu; Zhu; Morigasaki; Suda

Journal of Alloys and Compounds, 2007 , vol. 437, # 1-2 p. 311 - 316 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 26171624 Find similar reactions

B: 0% D: 0%

Synthesize Find similar

in tetrahydrofuran

byproducts: THF; under N2, equimolar amt. of BH3*THF and alkali-salts were reacted; monitored by (11)B NMR; only NaBH4 isolation was succesfull, B(OBut)3 and HB(OtBu)2 were not formed;

Knizek, Joerg; Noeth, Heinrich; Warchhold, Markus

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2006 , vol. 61, # 9 p. 1079 - 1093 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 26068563 Find similar reactions

90%

Synthesize Find similar

With magnesium in water

byproducts: MgO; process starts from borax and NaOH by exothermal steam process (H2O); dread at 270°C; H2 at surface of Mg particles generated protide to form NaBH4; process dependent on of rate temp. change, size of Mg particles; XRD;

Suda; Morigasaki; Iwase; Li

Journal of Alloys and Compounds, 2005 , vol. 404-406, # SPEC. ISS. p. 643 - 647 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 27438349 Find similar reactions

B: 20%

in tetrahydrofuran

(Ar); a flask charged with Ce complex and THF, C4H4S2(SNa)2 added, stirred for 12 h at 20°C, filtered, 18-crown-6 added; filtered, washed (THF), dried (vac.), crystd. by slow diffusion of pentane into a pyridine soln.;

Synthesize Find similar

Roger, Mathieu; Arliguie, Therese; Thuery, Pierre; Fourmigue, Marc; Ephritikhine, Michel

Inorganic Chemistry, 2005 , vol. 44, # 3 p. 584 - 593 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 27476782 Find similar reactions

B: 99%

Synthesize Find similar

in tetrahydrofuran

(Ar); a flask charged with Nd complex, THF condensed, C4H4S2(SNa)2 added, stirred for 3 d at 20°C; filtered, evapd., extd. (THF), filtered; obtained impure;

Roger, Mathieu; Arliguie, Therese; Thuery, Pierre; Fourmigue, Marc; Ephritikhine, Michel

Inorganic Chemistry, 2005 , vol. 44, # 3 p. 584 - 593 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 23046684 Find similar reactions

With sodium hydride

Millennium Cell, Inc.; US Borax

Patent: US6706909 B1, 2004 ; Location in patent: Page column 5 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

8:Equation (8)

The improvement in the formation of trialkyl borates afforded by the present invention is advantageous in that it also represents an improvement in the overall process of regenerating the borohydride material that is utilized as fuel in hydrogen generators. In the current commercial process, trimethyl borate is reacted with four equivalents of sodium hydride to form one equivalent of sodium borohydride and three equivalents of sodium methoxide. This reaction is shown in equation (8): [00036] B(OCH3)3+4NaH-->NaBH4+3NaOCH3 (8) A

Synthesize Find similar

Rx-ID: 26874209 Find similar reactions

A: 70% C: 69%

in tetrahydrofuran

byproducts: H2; under inert atm.; excess of alcohol in THF added dropwise at room temp. to stirred soln. of tetrahydroborate complex in THF (accompanied by vigorous gas evolution); stirring was continued for 1 h; mixt. allowed to stand for the reaction to be completed; within 5 ds ppt. sepd. by filtration (identified as NaBH4 by X-ray diffraction and IR spectroscopy); filtrate was distd. (vac., 0.1 mmHg) at room temp. to remove solvent and at 50°C; residue pumped out at 100-115°C; volatile collected ...; A

Synthesize Find similar

Makhaev; Antsyshkina; Petrova; Sadikov

Russian Journal of Inorganic Chemistry, 2004 , vol. 49, # 8 p. 1154 - 1157 Title/Abstract Full Text View citing articles Show Details

Rx-ID: 26898298 Find similar reactions

A: 66% C: 65%

in tetrahydrofuran

Makhaev; Antsyshkina; Petrova; Sadikov

Russian Journal of Inorganic Chemistry, 2004 , vol. 49, # 8 p. 1154 - 1157 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 26172316 Find similar reactions

Synthesize Find similar

78%

With sodium carbonate in neat (no solvent) byproducts: MgO, CO2; ball milled at room temp. for 60 min; extn. by anhyd. ethylendiamine under Ar; filtered soln. evapd. in vac. at room temp.; detn. by XRD;

Li; Morigazaki; Liu; Suda

Journal of Alloys and Compounds, 2003 , vol. 349, # 1-2 p. 232 - 236 Title/Abstract Full Text View citing articles Show Details

67%

With sodium peroxide in neat (no solvent) byproducts: MgO, H2; ball milled at room temp. for 60 min; extn. by anhyd. ethylendiamine under Ar, soln. evapd. in vac. at room temp.; detn. by XRD;

Li; Morigazaki; Liu; Suda

Journal of Alloys and Compounds, 2003 , vol. 349, # 1-2 p. 232 - 236 Title/Abstract Full Text View citing articles Show Details

64%

With sodium hydroxide in neat (no solvent) byproducts: MgO, H2; ball milled at room temp. for 60 min; extn. by anhyd. ethylendiamine under Ar; filtered soln. evapd. in vac. at room temp.; detn. by XRD;

Li; Morigazaki; Liu; Suda

Journal of Alloys and Compounds, 2003 , vol. 349, # 1-2 p. 232 - 236 Title/Abstract Full Text View citing articles Show Details

Hide Details

43%

Li; Morigazaki; Liu; Suda

Journal of Alloys and Compounds, 2003 , vol. 349, # 1-2 p. 232 - 236 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent) byproducts: MgO, B2O3; ball milled at room temp. for 60 min; extn. by anhyd. ethylendiamine under Ar; filtered soln. evapd. in vac. at room temp.; detn. by XRD;

Synthesize Find similar

Rx-ID: 26172317 Find similar reactions

in neat (no solvent, solid phase) by ball milling from MgH2 (1.25 excess) and NaBO2; extd. with ethylenediamine; evapn.;

Li; Liu; Arai; Morigazaki; Suda

Journal of Alloys and Compounds, 2003 , vol. 356-357, p. 469 - 474 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 26613824 Find similar reactions

Titov

Russian Journal of Inorganic Chemistry, 2003 , vol. 48, # 10 p. 1471 - 1479 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent) byproducts: dioxane; heating at 96-100°C;

Synthesize Find similar

Synthesize Find similar Rx-ID: 27068165 Find similar reactions

Titov

Russian Journal of Inorganic Chemistry, 2003 , vol. 48, # 10 p. 1471 - 1479 Title/Abstract Full Text View citing articles Show Details

in neat (no solvent) byproducts: dioxane; heating under atmospheric pressure at 140°C (Zh. Neorg. Khim., 1982, vol. 27, no. 4, p. 891);

Synthesize Find similar

Synthesize Find similar Rx-ID: 27232697 Find similar reactions

Synthesize Find similar

in dichloromethane

CH2Cl2 was added to mixt. NaTm(BH4)4*3DME and Ph4PBH4 and stirred for several minutes; NaBH4 was filtered off, soln. was concd., Et2O was added, ppt. was separated, washed with Et2O and dried in vac.;

Antsyshkina; Sadikov; Borisov; Makhaev

Russian Journal of Inorganic Chemistry, 2001 , vol. 46, # 8 p. 1141 - 1146 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 27232698 Find similar reactions

B: 68.5%

in dichloromethane

CH2Cl2 was added to mixt. NaLu(BH4)4*4DME andPh4PBH4 and stirred for several minutes; NaBH4 was filtered off, soln. was concd., Et2O was added, ppt. was separated, washed with Et2O and dried in vac.; elem. anal.;

Synthesize Find similar

Antsyshkina; Sadikov; Borisov; Makhaev

Russian Journal of Inorganic Chemistry, 2001 , vol. 46, # 8 p. 1141 - 1146 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 27232699 Find similar reactions

in dichloromethane

CH2Cl2 was added to mixt. NaY(BH4)4*4DME and Ph4PBH4 and stirred for several minutes; NaBH4 was filtered off, soln. was concd., Et2O was added, ppt. was separated, washed with Et2O and dried in vac.;

Synthesize Find similar

Antsyshkina; Sadikov; Borisov; Makhaev

Russian Journal of Inorganic Chemistry, 2001 , vol. 46, # 8 p. 1141 - 1146 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26525321 Find similar reactions

in tetrahydrofuran

Noeth, Heinrich; Thomas, Steffen

N2 atmosphere; (11)B-NMR-monitoring;

European Journal of Inorganic Chemistry, 1999 , # 8 p. 1373 - 1380 Title/Abstract Full Text Show Details

Synthesize Find similar

Rx-ID: 27096990 Find similar reactions

A: 77% B: 97%

in benzene

org. compd. soln. addn. dropwise (magnetic stirring) to Zn-complex soln., NaBH4 ppt. filtration off after 1 h, solvent evapn. from filtrate (vac.); residue washing (pentane), drying (vac.); elem. anal; thermal anal.;

Synthesize Find similar

Makhaev, V. D.; Borisov, A. P.; Karpova, T. P.; Petrova, L. A.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1995 , vol. 40, p. 90 - 93 Zhurnal Neorganicheskoi Khimii, 1995 , vol. 40, p. 94 - 97 Full Text Show Details

Synthesize Find similar Rx-ID: 27154002 Find similar reactions

in tetrahydrofuran

several d;

McGaff, Robert W.; Gaines, Donald F.

Inorganic Chemistry, 1995 , vol. 34, p. 1009 - 1010 Full Text View citing articles Show Details

in 1,2-dimethoxyethane

several d;

McGaff, Robert W.; Gaines, Donald F.

Inorganic Chemistry, 1995 , vol. 34, p. 1009 - 1010 Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 26101898 Find similar reactions

Synthesize Find similar

With hydrogen in neat (no solvent) byproducts: NaCl, Na2B12H(12-n)Cln, n=1-6; High Pressure; under inert atm., NaH transferred in fixed bed cartridge, rammed, purified reactor vessel heated to selected temp.(between 270 and 350.degree,.C), while the system was kept at constant pressure (0.1-4MPa), gas mixt. (H2-contg. 1-4 vol percentBCl3) introduced; reaction finished, when first traces of BCl3 were detected by gas analyzer at the end of the column; elem. anal.; A

Synthesize Find similar

Gruener, B.; Prochazka, V.; Shubrt, J.; Herhmanek, S.; Pospech, R.

European Journal of Solid State and Inorganic Chemistry, 1991 , vol. 28, p. 597 - 610 Full Text Show Details

Synthesize Find similar Rx-ID: 26745322 Find similar reactions

Makhaev, V. D.; Borisov, A. P.; Boiko, G. N.; Tarasov, B. P.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 6 p. 1081 - 1087 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 6 p. 1207 - 1214 Title/Abstract Full Text View citing articles Show Details

compound was placed in a Schlenk tube connected to a trap cooled to -196°C, vacuum of 100 Pa was pulled on the system and tube was heated to 150°C, 1 h; IR, x-Ray;

Synthesize Find similar

Synthesize Find similar Rx-ID: 26303073 Find similar reactions

With NaNH2 in tetrahydrofuran; ammonia

NH3 (liquid); (inert atmosphere); onto Na boranate and NaNH2 was condensed NH3 at -78°C and stirred for 2 h, volatiles were removed at room temp. in vac.,; residue was extd. with THF, products were identified by (11)B-NMR;

Getman, Thomas D.; Krause, Jeanette A.; Niedenzu, Philipp M.; Shore, Sheldon G.

Inorganic Chemistry, 1989 , vol. 28, p. 1507 - 1510 Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 26484753 Find similar reactions

Synthesize Find similar

With sodium acetate in diethylene glycol

N2-atmosphere, 25°C, 0.25 h, 1 equiv. AcONa, stirring; not isolated, reaction followed by (11)B-NMR spectroscopy;

Cole, Thomas E.; Bakshi, Raman K.; Srebnik, Morris; Singaram, Bakhtan; Brown, Herbert C.

Organometallics, 1986 , vol. 5, p. 2303 - 2307 Full Text View citing articles Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 26278415 Find similar reactions

Titov, L. V.; Eremin, E. R.; Rosolovskii, V. Ya.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1982 , vol. 27, p. 500 502 Zhurnal Neorganicheskoi Khimii, 1982 , vol. 27, p. 891 - 895 Full Text Show Details

in neat (no solvent) byproducts: H2, dioxane; at 140°C for 6 h in vac. (0.1 mmHg); fractional distillation;

Synthesize Find similar

Synthesize Find similar Rx-ID: 26613825 Find similar reactions

in solid 80-100°C; IR, chromatography;

Rozenberg, A. S.; Nechiporenko, G. N.; Titov, L. V.; Levicheva, M. D.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1982 , vol. 27, p. 1527 1529

Zhurnal Neorganicheskoi Khimii, 1982 , vol. 27, p. 2695 - 2698 Full Text Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 27068164 Find similar reactions

Titov, L. V.; Eremin, E. R.; Rosolovskii, V. Ya.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1982 , vol. 27, p. 500 502 Zhurnal Neorganicheskoi Khimii, 1982 , vol. 27, p. 891 - 895 Full Text Show Details

in diethylene glycol dimethyl ether

byproducts: H2, dioxane; N2 (700 mmHg); at 160°C; ppt. separated, detected by NMR, IR;

Synthesize Find similar

Synthesize Find similar Rx-ID: 26644771 Find similar reactions

B: 89%

With tetrahydrofuran in neat (no solvent) byproducts: DME; 140-160°C, vac., 2 h; extn. (THF), filtration off of NaBH4, distn. off of solvent; elem. anal.;

Makhaev, V. D.; Borisov, A. P.; Tarasov, B. P.; Semenenko, K. N.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1981 , vol. 26, p. 1417 1421 Zhurnal Neorganicheskoi Khimii, 1981 , vol. 26, p. 2645 - 2651 Full Text Show Details

Synthesize

Synthesize Find similar

Find similar

Rx-ID: 27097051 Find similar reactions

B: 78%

Find similar

With tetrahydrofuran in neat (no solvent) byproducts: DME; 140-160°C, vac., 2 h; extn. (THF), filtration off of NaBH4, distn. off of solvent, drying (vac., 1 h); elem. anal.;

Makhaev, V. D.; Borisov, A. P.; Tarasov, B. P.; Semenenko, K. N.

Synthesize Find similar

Synthesize Find similar Rx-ID: 26540039 Find similar reactions

in neat (no solvent) byproducts: H2; vac. (closed vessel), 100°C; fractional freezing of gaseous products (-78 to -196°C); washing residue with Et2O; elem. anal.;

Titov, L. V.; Levicheva, M. D.; Rosolovskii, V. Ya.

Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1980 , vol. 25, p. 1625 1627 Zhurnal Neorganicheskoi Khimii, 1980 , vol. 25, p. 2953 - 2958 Full Text Show Details

Synthesize Find similar

Rx-ID: 26101921 Find similar reactions

Synthesize Find similar

94%

in neat (no solvent) 1mol B(OCH3)3, 4mol NaH, 225-275°C;; 90-96percent NaBH4;;

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

Schlesinger, H. I.; Brown, H. C.; Sheft, I.; Ritter, D. M.

Journal of the American Chemical Society, 1953 , vol. 75, p. 186 - 190 Full Text View citing articles Show Details

94%

in neat (no solvent) 1mol B(OCH3)3, 4mol NaH, 225-275°C;; 90-96percent NaBH4;;

Gmelin Handbook: Na: SVol.2, 92, page 805 - 807 Full Text Show Details

in presence of small amounts of LiH;; high-purity product;;

Kimura, Y.

Patent: JP724440 , 1972 ; C. A., 1973 , vol. 79, p. 127892 Full Text Show Details

Hide Details

in tetrahydrofuran

byproducts: Na{B(OCH3)4};

Wiberg, E.; Amberger, E.

Hydrides of the Elementes of Main Groups I-IV, Elsevier Publishing Company, Amsterdam-London-New York 1971, pp. 288/96 Full Text Show Details

Wiberg, E.; Amberger, E.

Hydrides of the Elements of Main Groups I-IV, Elsevier Publishing Company, Amsterdam - London - New York 1971, pp. 119/36 Full Text Show Details

Bayer Natriumboranat-Informationen 1975 Full Text Show Details

in neat (no solvent) byproducts: NaOCH3; molar ratio NaH: B(OCH3)3=4:1, at 225-275°C in an autoclave, extractn. with liquid NH3 or isopropylamine;; high purity;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C. A., 1951 , p. 4007 Full Text Show Details

in neat (no solvent) react. of NaH (dild. with powdered NaOCH3) with B(OCH3)3-vapor, molar ratio Na:B(OCH3)3=2:1, about 250°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

American Potash and Chemical Corp.

Patent: US2898184 , 1959 ; C. A., 1959 , p. 22790 Full Text Show Details

in further solvent(s) heating in mineral oil;;

Fedor, W. S.; Banus, M. D.; Ingalls, D. P.

Industrial and Engineering Chemistry, 1957 , vol. 49, p. 1664 - 1672 Full Text Show Details

Metal Hydrides Incorp.

Patent: US2720444 , 1955 ; Full Text Show Details

in mineral oil

at 250-265°C;; washing with petroleum ether, extractn. of NaBH4 from the residue with liquid NH3 at -33°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: DE958646 , 1957 ; C., 1957 , p. 10305 Full Text Show Details

Callery Chemical Co.

Patent: GB774728 , 1957 ; C. A., 1957 , p. 14217 Full Text Show Details

in diethylene glycol

byproducts: Na{B(OCH3)4};

Wiberg, E.; Amberger, E.

Hydrides of the Elementes of Main Groups I-IV, Elsevier Publishing Company, Amsterdam-London-New York 1971, pp. 288/96 Full Text Show Details

Wiberg, E.; Amberger, E.

Hydrides of the Elements of Main Groups I-IV, Elsevier Publishing Company, Amsterdam - London - New York 1971, pp. 119/36 Full Text Show Details

Bayer Natriumboranat-Informationen 1975 Full Text Show Details

in further solvent(s) heating in mineral oil;;

Gmelin Handbook: Na: SVol.2, 92, page 805 - 807 Full Text Show Details

in tetrahydrofuran

byproducts: Na{B(OCH3)4};

James, B. D.; Wallbridge, M. G. H.

Progr. Inorg. Chem., 1970 , vol. 11, p. 99 - 230 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.6, page 34 - 44 Full Text Show Details

in diethylene glycol dimethyl ether

byproducts: Na{B(OCH3)4};

James, B. D.; Wallbridge, M. G. H.

Progr. Inorg. Chem., 1970 , vol. 11, p. 99 - 230 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.6, page 34 - 44 Full Text Show Details

Gmelin Handbook: B: B-Verb.13, 2.2.7, page 71 - 82 Full Text Show Details

Synthesize Find similar

Rx-ID: 26384123 Find similar reactions

byproducts: Na(CH3)2N*(BH3)2;

Keller, P. C.

Inorganic Chemistry, 1971 , vol. 10, p. 1528 - 1529 Full Text View citing articles Show Details

byproducts: Na(CH3)2N*(BH3)2;

Gmelin Handbook: B: B-Verb.4, 4.2.3, page 99 - 108 Full Text Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 26672773 Find similar reactions

Synthesize Find similar

Keller, P. C.

Inorganic Chemistry, 1971 , vol. 10, p. 1528 - 1529 Full Text View citing articles Show Details

Gmelin Handbook: B: B-Verb.8, 10.2, page 150 - 154 Full Text Show Details

with 0.5 mole B2H6;

Synthesize Find similar

Rx-ID: 26672780 Find similar reactions

Synthesize Find similar

Szarvas, P.; Gyoeri, B.; Emri, J.

Acta Chimica Academiae Scientiarum Hungaricae, 1971 , vol. 70, p. 1 - 8 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 10.3, page 154 - 157 Full Text Show Details

Synthesize Find similar

Rx-ID: 26088899 Find similar reactions

Synthesize Find similar

>99

in neat (no solvent) byproducts: B(OCH3)3; begin of react. at -80°C, fast react. at ambient temp., exclusion of air;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2461663 , 1949 ; C. A., 1949 , p. 4684 Full Text Show Details

in tetrahydrofuran

byproducts: B(OCH3)3;

Wiberg, E.; Amberger, E.

Hydrides of the Elementes of Main Groups I-IV, Elsevier Publishing Company, Amsterdam-London-New York 1971, pp. 288/96 Full Text Show Details

Wiberg, E.; Amberger, E.

Hydrides of the Elements of Main Groups I-IV, Elsevier Publishing Company, Amsterdam - London - New York 1971, pp. 119/36 Full Text Show Details

Bayer Natriumboranat-Informationen 1975 Full Text Show Details

in neat (no solvent) byproducts: B(OCH3)3;

Wiberg, E.; Amberger, E.

Hydrides of the Elementes of Main Groups I-IV, Elsevier Publishing Company, Amsterdam-London-New York 1971, pp. 288/96 Full Text Show Details

Wiberg, E.; Amberger, E.

Hydrides of the Elements of Main Groups I-IV, Elsevier Publishing Company, Amsterdam - London - New York 1971, pp. 119/36 Full Text Show Details

Bayer Natriumboranat-Informationen 1975

Full Text Show Details

Hide Details

>99

in diethylene glycol

excess of B2H6;

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

in not given

Brown, H. C.; Mead, E. J.; Tierney, P. A.

Journal of the American Chemical Society, 1957 , vol. 79, p. 5400 - 5404 Full Text View citing articles Show Details

in not given

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

>99

in diethylene glycol dimethyl ether

excess of B2H6;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in tetrahydrofuran

byproducts: B(OCH3)3;

James, B. D.; Wallbridge, M. G. H.

Progr. Inorg. Chem., 1970 , vol. 11, p. 99 - 230 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.6, page 34 - 44 Full Text Show Details

in neat (no solvent) byproducts: B(OCH3)3;

James, B. D.; Wallbridge, M. G. H.

Progr. Inorg. Chem., 1970 , vol. 11, p. 99 - 230 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.6, page 34 - 44 Full Text Show Details

Synthesize Find similar

Rx-ID: 26091365 Find similar reactions

98%

Synthesize Find similar

in further solvent(s) react. of NaH with B2H6 in alkylene glycol dialkylether at 35-75°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Olin Mathieson Chemical Corp.

Patent: DE1072597 , 1960 ; Full Text Show Details

Olin Mathieson Chemical Corp.

Patent: GB835869 , 1960 ; C. A., 1960 , p. 23226 Full Text Show Details

93%

in tetrahydrofuran

in abs. tetrahydrofurane; 4 h, under shaking; good yield; Na(BH4) suspension distilled, filtered and dried in oil pump vacuum at 130°C; purity = 97.5 percent;

Noeth,H.; Beyer,H.

Chemische Berichte, 1960 , vol. 93, p. 928 - 938 Full Text View citing articles Show Details

93%

in tetrahydrofuran

in abs. tetrahydrofurane; 4 h, under shaking; good yield; Na(BH4) suspension distilled, filtered and dried in oil pump vacuum at 130°C; purity = 97.5 percent;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Hide Details

in diethylene glycol

at ambient temp.;;

Brown, H. C.; Tierney, P. A.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1552 - 1558 Full Text View citing articles Show Details

James, B. D.; Wallbridge, M. G. H.

Progress Inorg. Chem., 1970 , vol. 11, p. 99 - 231 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

in diethyl ether

introduction of B2H6 into NaH in ether; react. in several steps: formation of B2H6 from BF3-etherate, NaH and NaBH4;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Metallgesellschaft A.-G.

Patent: DE947702 , 1956 ; C., 1957 , p. 2838 Full Text Show Details

in diethyl ether

Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

in diethylene glycol

at ambient temp.;

Schlesinger, H. I.; Brown, H. C.; Hoekstra, H. R.; Rapp, L. R.

Journal of the American Chemical Society, 1953 , vol. 75, p. 199 - 204 Full Text View citing articles Show Details

in not given

Wiberg, E.; Amberger, E.

Hydrides of the Elementes of Main Groups I-IV, Elsevier Publishing Company, Amsterdam-London-New York 1971, pp. 288/96 Full Text Show Details

Wiberg, E.; Amberger, E.

Hydrides of the Elements of Main Groups I-IV, Elsevier Publishing Company, Amsterdam - London - New York 1971, pp. 119/36 Full Text Show Details

Bayer Natriumboranat-Informationen 1975 Full Text Show Details

in diethyl ether

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in diethylene glycol dimethyl ether

at ambient temp.;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in not given

James, B. D.; Wallbridge, M. G. H.

Progr. Inorg. Chem., 1970 , vol. 11, p. 99 - 230 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.6, page 34 - 44 Full Text Show Details

in diethylene glycol

at ambient temp.;;

Gmelin Handbook: Na: SVol.2, 90, page 801 - 803 Full Text Show Details

Synthesize Find similar

Rx-ID: 26091372 Find similar reactions

Synthesize Find similar

James, B. D.; Wallbridge, M. G. H.

Progress Inorg. Chem., 1970 , vol. 11, p. 99 - 231 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

Synthesize Find similar

Rx-ID: 26101842 Find similar reactions

With B halogenide

James, B. D.; Wallbridge, M. G. H.

Progress Inorg. Chem., 1970 , vol. 11, p. 99 - 231 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

With B compounds B compounds forming B2H6;

James, B. D.; Wallbridge, M. G. H.

Progress Inorg. Chem., 1970 , vol. 11, p. 99 - 231 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

With boron halogenides or boron halogenide etherates in further solvent(s) solvent: suspending material which doesn not dissolve NaBH4, in presence of organic N-base, boron amides, B-alkyls, 100-200°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1108188 , 1961 ; C. A., 1962 , vol. 56, p. 15154 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1129935 , 1962 ; C. A., 1962 , vol. 57, p. 14708 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1136314 , 1962 ; Full Text Show Details

Hide Details

With boron hydrides in further solvent(s) react. of NaH with polymeric boron hydrides (from pyrolysis of B2H6) under H2-pressure at 50°C, solvent: ethylene glycol dialkylether;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: US2889194 , 1959 ; C. A., 1959 , p. 19328 Full Text Show Details

Callery Chemical Co.

Patent: DE1082579 , 1960 ; Full Text Show Details

With specific alkoxy-boron compounds

James, B. D.; Wallbridge, M. G. H.

Progress Inorg. Chem., 1970 , vol. 11, p. 99 - 231 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

>99

in diethyl ether

heating above 100°C with N-trialkylborazane;

Koester, R.

Andew. Chem., 1957 , vol. 69, p. 94 Full Text Show Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

>99

in further solvent(s) in hydrocarbon, heating above 100°C with N-trialkylborazane;

Koester, R.

Andew. Chem., 1957 , vol. 69, p. 94 Full Text Show Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

Rx-ID: 26101897 Find similar reactions

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Kali-Chemie A.-G.

Patent: DE1079008 , 1960 ; C. A., 1962 , vol. 56, p. 5636 Full Text Show Details

in toluene

in presence of Al(C2H5)3;

Wiberg, E.; Amberger, E.

Hydrides of the Elementes of Main Groups I-IV, Elsevier Publishing Company, Amsterdam-London-New York 1971, pp. 288/96 Full Text Show Details

Wiberg, E.; Amberger, E.

Hydrides of the Elements of Main Groups I-IV, Elsevier Publishing Company, Amsterdam - London - New York 1971, pp. 119/36 Full Text Show Details

Bayer Natriumboranat-Informationen 1975 Full Text Show Details

in diethyl ether

react. of NaH with a soln. of BCl3 in ether in an autoclave (about 10 at), 24h, about 120°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Heyl & Co., Chemisch-Pharmazeutische Fabrik

Patent: DE944546 , 1956 ; C. A., 1958 , p. 12341 Full Text Show Details

Heyl & Co., Chemisch-Pharmazeutische Fabrik

Patent: GB711174 , 1954 ; C. A., 1954 , p. 14140 Full Text Show Details

Hide Details

in mineral oil

at 250-265°C;; washing with petroleum ether, extractn. of NaBH4 from the residue with liquid NH3 at -33°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: DE958646 , 1957 ; C., 1957 , p. 10305 Full Text Show Details

Callery Chemical Co.

Patent: GB774728 , 1957 ; C. A., 1957 , p. 14217 Full Text Show Details

in toluene

in presence of Al(C2H5)3;

James, B. D.; Wallbridge, M. G. H.

Progr. Inorg. Chem., 1970 , vol. 11, p. 99 - 230 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.6, page 34 - 44 Full Text Show Details

Synthesize Find similar

Rx-ID: 26121877 Find similar reactions

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1108188 , 1961 ; C. A., 1962 , vol. 56, p. 15154 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1129935 , 1962 ; C. A., 1962 , vol. 57, p. 14708 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1136314 , 1962 ; Full Text Show Details

With B compounds B compound forming B2H6;

James, B. D.; Wallbridge, M. G. H.

Progress Inorg. Chem., 1970 , vol. 11, p. 99 - 231 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

With B halogenide

James, B. D.; Wallbridge, M. G. H.

Progress Inorg. Chem., 1970 , vol. 11, p. 99 - 231 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

Hide Details

With Na-borate-silicate in neat (no solvent) react. of Na-borate-silicate with Na and H2 at 400-500°C, H2-pressure: several atm;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1088930 , 1961 ; C. A., 1961 , p. 22733 Full Text Show Details

With Na-borate in neat (no solvent) at 350-400°C, in presence of SiO2, cyclic process;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1108670 , 1961 ; C. A., 1962 , vol. 56, p. 11216 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1142845 , 1963 ; Full Text Show Details

With specific alkoxy-boron compounds

James, B. D.; Wallbridge, M. G. H.

Progress Inorg. Chem., 1970 , vol. 11, p. 99 - 231 Full Text Show Details

Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5 Full Text Show Details

With bortrialkyl

Koester, R.

Ang. Chem., 1956 , vol. 68, p. 383 Full Text Show Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 26672774 Find similar reactions

Synthesize Find similar

Keller,P.C.

Journal of the American Chemical Society, 1969 , vol. 91, p. 1231 Full Text View citing articles Show Details

Gmelin Handbook: B: B-Verb.8, 10.2, page 150 - 154 Full Text Show Details

Synthesize Find similar

Rx-ID: 26101920 Find similar reactions

Synthesize Find similar

Mikheeva, V. I.; Dymova, T. N.; Vysheslavtsev, A. A.; Eliseeva, N. G.

Z. Neorgan. Khim., 1967 , vol. 12, p. 2019 - 2024 Full Text Show Details

Gmelin Handbook: B: B-Verb.13, 2.3.3, page 91 - 93 Full Text Show Details

in neat (no solvent) molar ratio NaH:borane=4:1 to 8:1, 225-280°C, under H2/N2, 1h;; product mixture; extractn. with liquid NH3;;

Synthesize Find similar

Rx-ID: 26572943 Find similar reactions

Koester, R.; Grassberger, M. A.

Angewandte Chemie, 1965 , vol. 77, p. 457 - 458 Full Text Show Details

Koester, R.; Grassberger, M. A.

Angewandte Chemie, 1967 , vol. 79, p. 197 - 218 Full Text Show Details

Gmelin Handbook: B: B-Verb.14, 4.4.2.8, page 195 - 196 Full Text Show Details

in mixture with alkyl derivates of 2-carbahexaborane(9) and 2.4-dicarba-closo-heptaborane(7);;

Koester, R.

Angewandte Chemie, 1956 , vol. 68, p. 383 - 383 Full Text Show Details

Gmelin Handbook: B: B-Verb.14, 4.4.2.8, page 195 - 196 Full Text Show Details

Koester, R.

16e Congr. Intern. Chim. Pure Appl., Paris 1957 (1958), Mem. Sect. Chim. Minerale, S. 462/5 Full Text Show Details

Synthesize Find similar

Rx-ID: 26572944 Find similar reactions

in mixture with alkyl derivates of 2-carbahexaborane(9) and 2.4-dicarba-closo-heptaborane(7);;

Koester; Grassberger; Hoffmann; Rotermund

Tetrahedron Letters, 1966 , vol. 7, # 9 p. 905 - 913 Full Text View citing articles Show Details

Koester, R.; Grassberger, M. A.

Angewandte Chemie, 1965 , vol. 77, p. 457 - 458 Full Text Show Details

Koester, R.; Grassberger, M. A.

Angewandte Chemie, 1967 , vol. 79, p. 197 - 218 Full Text Show Details

Gmelin Handbook: B: B-Verb.14, 4.4.2.8, page 195 - 196 Full Text Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 26618730 Find similar reactions

With NaC2H in ammonia

byproducts: NH3, C2H2;

Shore, S. G.; Hickham, C. W.

Inorganic Chemistry, 1963 , vol. 2, p. 638 - 640 Full Text View citing articles Show Details

Hickam, C. W.

Diss. Abstr., Diss. Ohio State Univ., Columbus 1965, S. 1/112 1965 , vol. 25, p. 6946 Full Text Show Details

With sodium

byproducts: NH3, H2;

Shore, S. G.; Hickham, C. W.

Inorganic Chemistry, 1963 , vol. 2, p. 638 - 640 Full Text View citing articles Show Details

Hickam, C. W.

Diss. Abstr., Diss. Ohio State Univ., Columbus 1965, S. 1/112 1965 , vol. 25, p. 6946 Full Text Show Details

With Na byproducts: NH3, H2;

Gmelin Handbook: B: B-Verb.4, 4.2.1, page 92 - 95 Full Text Show Details

Hide Details

With NaC2H in ammonia

byproducts: NH3, C2H2; NH3 (liquid);

Gmelin Handbook: B: B-Verb.4, 4.2.1, page 92 - 95 Full Text Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 26626990 Find similar reactions

With sodium

Koester, R.; Grassberger, M. A.

Angewandte Chemie, 1965 , vol. 77, p. 457 - 458 Full Text Show Details

With Na

Gmelin Handbook: B: B-Verb.14, 5.6, page 212 - 224 Full Text Show Details

Synthesize Find similar

Rx-ID: 26445347 Find similar reactions

Shore, S. G.; Hickham, C. W.

Inorganic Chemistry, 1963 , vol. 2, p. 638 - 640 Full Text View citing articles Show Details

Gmelin Handbook: B: B-Verb.1, 3.5.3.1, page 255 - 258 Full Text Show Details

in ammonia

byproducts: NH3;

Synthesize Find similar

Rx-ID: 26075933 Find similar reactions

Synthesize Find similar

60%

in neat (no solvent) heating to >330°C for 20-48h;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C. A., 1951 , p. 4007 Full Text Show Details

With catalyst: Na-alcoholate in neat (no solvent) at about 350°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

E. I. du Pont de Nemours & Co.

Patent: US2715057 , 1955 ; C. A., 1955 , p. 16372 Full Text Show Details

E. I. du Pont de Nemours & Co.

Patent: US2926989 , 1960 ; C. A., 1960 , p. 12517 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.; Finholt, A. E.

Journal of the American Chemical Society, 1953 , vol. 75, p. 205 - 209 Full Text View citing articles Show Details

heating above 330°C;

Hide Details

in mineral oil

at 250-265°C;; washing with petroleum ether, extractn. of NaBH4 from the residue with liquid NH3 at -33°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: DE958646 , 1957 ; C., 1957 , p. 10305 Full Text Show Details

Callery Chemical Co.

Patent: GB774728 , 1957 ; C. A., 1957 , p. 14217 Full Text Show Details

heating above 330°C;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

Rx-ID: 26087221 Find similar reactions

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Kali-Chemie A.-G.

Patent: DE1079008 , 1960 ; C. A., 1962 , vol. 56, p. 5636 Full Text Show Details

NaH activated with B- or Al-alkyls;;

Synthesize Find similar

Rx-ID: 26087599 Find similar reactions

75%

Synthesize Find similar

in neat (no solvent) react. of Na-borate with Na and H2 at 400-500°C, H2-pressure: several atm, addn. of SiO2 to separate excess Na in form of Na2SiO3;; purity up to 96percent;;

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1067005 , 1960 ; C. A., 1961 , p. 11778

Full Text Show Details

Synthesize Find similar

Rx-ID: 26121756 Find similar reactions

75%

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1067005 , 1960 ; C. A., 1961 , p. 11778 Full Text Show Details

in neat (no solvent) react. of Na-borate with Na and H2 at 400-500°C, H2-pressure: several atm, addn. of SiO2 to separate excess Na in form of Na2SiO3;; purity up to 96percent;;

Synthesize Find similar

Rx-ID: 26121757 Find similar reactions

75%

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1067005 , 1960 ; C. A., 1961 , p. 11778 Full Text Show Details

in neat (no solvent) react. of Na-borate with Na and H2 at 400-500°C, H2-pressure: several atm, addn. of SiO2 to separate excess Na in form of Na2SiO3;; purity up to 96percent;;

Rx-ID: 26121788

Synthesize Find similar

Find similar reactions

75%

in further solvent(s) introduction of dry H2 under pressure in a dispersion of Na in an inert solvent at 275°C, simultanuous addn. of NaBF4;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: US2929676 , 1960 ; C. A., 1960 , p. 14602 Full Text Show Details

in further solvent(s) introduction of dry H2 under pressure in a dispersion of Na in an inert solvent at 250-350°C, simultanuous addn. of NaBF4;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: US2929676 , 1960 ; C. A., 1960 , p. 14602 Full Text Show Details

Synthesize Find similar

Rx-ID: 26121813 Find similar reactions

Synthesize Find similar

in further solvent(s) byproducts: NaOCH3; formation of NaH from Na in mineral oil and H2 at 250-300°C, react. with B(OCH3)3, molar ratio NaH:B(OCH3)3=4:1, 250°C;;

Fedor, W. S.; Banus, M. D.; Ingalls, D. P.

Industrial and Engineering Chemistry, 1957 , vol. 49, p. 1664 - 1672 Full Text Show Details

anonymous

Chem. Week, 1956 , vol. 78, # 21 p. 38 - 40 Full Text Show Details

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Metal Hydrides Inc.

Patent: US2720444 , 1955 ; C. A., 1956 , p. 3718 Full Text Show Details

Metal Hydrides Inc.

Patent: FR1144169 , 1957 ; C., 1960 , p. 1640 Full Text Show Details

in tetrahydrofuran

byproducts: NaOCH3; stoichiometric excess of about 650percent B(OCH3)3 in a >50percent THF-soln., boiling, react. at 65°C, filtration of NaBH4;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: US2939762 , 1960 ; C. A., 1960 , p. 18910 Full Text Show Details

in neat (no solvent) byproducts: NaOCH3; molar ratio NaH: B(OCH3)3=4:1, at 225-275°C in an autoclave, extractn. with liquid NH3 or isopropylamine;; high purity;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Schlesinger, H. I.; Brown, H. C.

Patent: US2534533 , 1950 ; C. A., 1951 , p. 4007 Full Text Show Details

Hide Details

in neat (no solvent) react. of Na and H2 (dild. with powdered NaOCH3) with B(OCH3)3-vapor, molar ratio Na:B(OCH3)3=2:1, about 250°C;;

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

American Potash and Chemical Corp.

Patent: US2898184 , 1959 ;

C. A., 1959 , p. 22790 Full Text Show Details

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Callery Chemical Co.

Patent: US2744810 , 1956 ; C. A., 1956 , p. 13386 Full Text Show Details

in neat (no solvent) spraying molten Na with H2 of 150-300°C in a room with B(OCH3)3;;

Synthesize Find similar

Rx-ID: 26121878 Find similar reactions

75%

Synthesize Find similar

in neat (no solvent) react. of Na-borate with Na and H2 at 400-500°C, H2-pressure: several atm, addn. of SiO2 to separate excess Na in form of Na2SiO3;; purity up to 96percent;;

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1067005 , 1960 ; C. A., 1961 , p. 11778 Full Text Show Details

Synthesize Find similar

Rx-ID: 26144158 Find similar reactions

Synthesize Find similar

in water

byproducts: H2; treatment of MgB2 with 4n NaOH at temperatures lower 100°C, formation of H2, filtration, evapn. of filtrate;; pure product;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Olin Mathieson Chemical Corp.

Patent: US2942935 , 1960 ; C. A., 1960 , p. 25630 Full Text Show Details

Synthesize Find similar

Rx-ID: 26076271 Find similar reactions

Synthesize Find similar

With Al or Mg-Al-alloy; mercury dichloride in neat (no solvent) react. with Al-powder or Mg-Al-alloy at 600-850°C under pressure (60 at);; purity up to 96percent;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schubert, F.; Lang, K.; Schabacher, W.; Goerrig, D.

Patent: DE1053476 , 1959 ; C., 1960 , p. 7640 Full Text Show Details

With Al or Mg-Al-alloy; mercury in neat (no solvent) react. with Al-powder or Mg-Al-alloy at 600-850°C under pressure (60 at);; purity up to 96percent;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schubert, F.; Lang, K.; Schabacher, W.; Goerrig, D.

Patent: DE1053476 , 1959 ; C., 1960 , p. 7640 Full Text Show Details

With Al or Mg-Al-alloy; silica gel in neat (no solvent) react. with Al-powder or Mg-Al-alloy at 600-850°C under pressure (60 at);; purity up to 96percent;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schubert, F.; Lang, K.; Schabacher, W.; Goerrig, D.

Patent: DE1053476 , 1959 ; C., 1960 , p. 7640 Full Text Show Details

Hide Details

With Al or Mg-Al-alloy; catalysts: Al- or Si-or Ca-halogenides in neat (no solvent) react. with Al-powder or Mg-Al-alloy at 600-850°C under pressure (60 at);; purity up to 96percent;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schubert, F.; Lang, K.; Schabacher, W.; Goerrig, D.

Patent: DE1053476 , 1959 ; C., 1960 , p. 7640 Full Text Show Details

Synthesize Find similar

Rx-ID: 26089003 Find similar reactions

Synthesize Find similar

in tetrahydrofuran

react. at 20°C (water-cooling), washing of raw product with xylol and THF for several times; extractn. with pyridine;;

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Carlo Erba S. A.

Patent: IT584522 , 1959 ; C. A., 1959 , p. 15504 Full Text Show Details

Synthesize Find similar

Rx-ID: 26091236 Find similar reactions

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Kali-Chemie A.-G.

Patent: DE1061301 , 1959 ; C. A., 1961 , p. 7778 Full Text Show Details

in octanol

at 30-40°C;;

Synthesize Find similar

Rx-ID: 26101887 Find similar reactions

25%

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Thiokol Chemical Corp.

Patent: US2880058 , 1959 ; C. A., 1959 , p. 15503 Full Text Show Details

in diethylene glycol

heating to 151-157°C for 2h;;

Synthesize

Find similar Rx-ID: 26101930 Find similar reactions

>99

Find similar

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Studiengesellschaft Kohle m. b. H.

Patent: DE1035109 , 1958 ; C., 1960 , p. 5610 Full Text Show Details

Studiengesellschaft Kohle m. b. H.

Patent: FR1180077 , 1959 ; C., 1961 , p. 974 Full Text Show Details

in further solvent(s) solvent: ethyl cyclohexane, on boiling;;

Synthesize Find similar

Rx-ID: 26121807 Find similar reactions

Synthesize Find similar

in ammonia

-78°C, excess of Na;

Kodama, G.; Parry, R. W.; Carter, J. C.

Journal of the American Chemical Society, 1959 , vol. 81, p. 3534 - 3538 Full Text View citing articles Show Details

in ammonia

NH3 (liquid); -78°C, excess of Na;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

Rx-ID: 26154036 Find similar reactions

>99

in further solvent(s) solvent: perhydrocumol, on boiling;;

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Studiengesellschaft Kohle m. b. H.

Patent: DE1035109 , 1958 ; C., 1960 , p. 5610 Full Text Show Details

Studiengesellschaft Kohle m. b. H.

Patent: FR1180077 , 1959 ; C., 1961 , p. 974 Full Text Show Details

Synthesize Find similar

>99

Synthesize Find similar

Rx-ID: 26171599 Find similar reactions

With Na-alcoholates in further solvent(s) solvent: ethyl cyclohexane, on boiling;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Studiengesellschaft Kohle m. b. H.

Patent: DE1035109 , 1958 ; C., 1960 , p. 5610 Full Text Show Details

Studiengesellschaft Kohle m. b. H.

Patent: FR1180077 , 1959 ; C., 1961 , p. 974 Full Text Show Details

Synthesize Find similar

Rx-ID: 26171600 Find similar reactions

>99

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Studiengesellschaft Kohle m. b. H.

Patent: DE1035109 , 1958 ; C., 1960 , p. 5610 Full Text Show Details

Studiengesellschaft Kohle m. b. H.

Patent: FR1180077 , 1959 ; C., 1961 , p. 974 Full Text Show Details

in further solvent(s) solvent: ethyl cyclohexane, on boiling;;

Synthesize

Find similar Rx-ID: 26174760 Find similar reactions

Find similar

With Al or Mg-Al-alloy; mercury dichloride in neat (no solvent) react. with Al-powder or Mg-Al-alloy at 600-850°C under pressure (60 at);; purity up to 96percent;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schubert, F.; Lang, K.; Schabacher, W.; Goerrig, D.

Patent: DE1053476 , 1959 ; C., 1960 , p. 7640 Full Text Show Details

With Al or Mg-Al-alloy; silica gel in neat (no solvent) react. with Al-powder or Mg-Al-alloy at 600-850°C under pressure (60 at);; purity up to 96percent;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schubert, F.; Lang, K.; Schabacher, W.; Goerrig, D.

Patent: DE1053476 , 1959 ; C., 1960 , p. 7640 Full Text Show Details

With Al or Mg-Al-alloy; catalysts: Al- or Si-or Ca-halogenides in neat (no solvent) react. with Al-powder or Mg-Al-alloy at 600-850°C under pressure (60 at);; purity up to 96percent;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schubert, F.; Lang, K.; Schabacher, W.; Goerrig, D.

Patent: DE1053476 , 1959 ; C., 1960 , p. 7640 Full Text Show Details

Hide Details

With Al pr Mg-Al-alloy; mercury in neat (no solvent) react. with Al-powder or Mg-Al-alloy at 600-850°C under pressure (60 at);; purity up to 96percent;;

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Schubert, F.; Lang, K.; Schabacher, W.; Goerrig, D.

Patent: DE1053476 , 1959 ; C., 1960 , p. 7640 Full Text Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 26618230 Find similar reactions

byproducts: H2O; 170-360°C;

Goubeau, J.; Kallfass, H.

Zeitschrift fuer Anorganische und Allgemeine Chemie, 1959 , vol. 299, p. 160 - 169 Full Text Show Details

byproducts: H2O; 170-360°C;

Gmelin Handbook: Na: SVol.3, 3.7, page 1233 - 1245 Full Text Show Details

Synthesize Find similar

Rx-ID: 26076112 Find similar reactions

Synthesize Find similar

in neat (no solvent) byproducts: CaO; react. in an autoclave under H2-pressure, 300-600°C, exothermic react. (formation of CaH2 from CaCl2 and H2 during the react. possible), addn. of SiO2 for absorption of CaO;;

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Farbenfabriken Bayer A.-G.

Patent: DE1036222 , 1958 ; C., 1960 , p. 5610 Full Text Show Details

Synthesize Find similar Rx-ID: 26081971 Find similar reactions

in ammonia

Synthesize Find similar

Schultz, D. R.; Parry, R. W.; Koenig, F. J.

Journal of the American Chemical Society, 1958 , vol. 80, p. 4 - 8 Full Text View citing articles Show Details

in ammonia

NH3 (liquid);

Schaeffer, G. W.; Adams, M. D.; Koenig, F. J.

Journal of the American Chemical Society, 1956 , vol. 78, p. 725 - 728 Full Text View citing articles Show Details

in ammonia

NH3 (liquid);

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Gmelin Handbook: Na: SVol.3, 4.2.3, page 1297 - 1304 Full Text Show Details

Synthesize Find similar

Rx-ID: 26082047 Find similar reactions

>99

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 61, page 259 - 261 Full Text Show Details

Studiengesellschaft Kohle m. b. H.

Patent: DE1034596 , 1958 ; C., 1960 , p. 4962 Full Text Show Details

in neat (no solvent) heating to 200-230°C under a H2-pressure of 200 at for 8-10h;;

Synthesize Find similar

Synthesize Find similar Rx-ID: 26091338 Find similar reactions

With sodium amalgam

Hough, W. V.; Edwards, L. J.; McElroy, A. D.

Journal of the American Chemical Society, 1956 , vol. 78, p. 689 Full Text View citing articles Show Details

With sodium amalgam in dibutyl ether

at room temp.;

Hough, W. V.; Edwards, L. J.; McElroy, A. D.

Journal of the American Chemical Society, 1956 , vol. 78, p. 689 Full Text View citing articles Show Details

With sodium amalgam in diethyl ether

at room temp.;

Hough, W. V.; Edwards, L. J.; McElroy, A. D.

Journal of the American Chemical Society, 1956 , vol. 78, p. 689 Full Text View citing articles Show Details

Hide Details

With Na-amalgam

Hough, W. V.; Edwards, L. J.; McElroy, A. D.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1828 - 1829 Full Text View citing articles Show Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Gmelin Handbook: Na: SVol.3, 3.6.2, page 1223 - 1233 Full Text Show Details

With Na-amalgam in diethyl ether

at ambient temp.;

Hough, W. V.; Edwards, L. J.; McElroy, A. D.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1828 - 1829

Full Text View citing articles Show Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

With Na-amalgam in diethyl ether

at room temp.;

Hough, W. V.; Edwards, L. J.; McElroy, A. D.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1828 - 1829 Full Text View citing articles Show Details

Gmelin Handbook: Na: SVol.3, 3.6.2, page 1223 - 1233 Full Text Show Details

With Na-amalgam in dibutyl ether

at room temp.;

Hough, W. V.; Edwards, L. J.; McElroy, A. D.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1828 - 1829 Full Text View citing articles Show Details

Gmelin Handbook: Na: SVol.3, 3.6.2, page 1223 - 1233 Full Text Show Details

With Na-amalgam in dibutyl ether

Hough, W. V.; Edwards, L. J.; McElroy, A. D.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1828 - 1829 Full Text View citing articles Show Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

Rx-ID: 26091373 Find similar reactions

-110°C, in eutectic mixture of Na and NH3;

Koenig, F. J.

Diss. Abstr., Diss. St.Louis Univ. 1957 1958 , vol. 18, p. 386/7 Full Text Show Details

-110°C, in eutectic mixture of Na and NH3;

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 26091432 Find similar reactions

Synthesize Find similar

Schultz, D. R.; Parry, R. W.; Koenig, F. J.

Journal of the American Chemical Society, 1958 , vol. 80, p. 4 - 8 Full Text View citing articles Show Details

Schaeffer, G. W.; Adams, M. D.; Koenig, F. J.

Journal of the American Chemical Society, 1956 , vol. 78, p. 725 - 728 Full Text View citing articles Show Details

Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

Gmelin Handbook: Na: SVol.3, 4.2.3, page 1297 - 1304 Full Text Show Details

Synthesize Find similar

Rx-ID: 26101883 Find similar reactions

99%

Synthesize Find similar

in tetrahydrofuran

byproducts: NaF; addn. of B(OCH3)3*THF to NaH at 60-65°C (stirring, N2-atmosphere), NaH dissolves, boiling, cooling to ambient temp., addn. of BF3*THF, distn. of THF and B(OCH3), extractn. of residue with isopropyl amine;; pure product;;

Synthesize Find similar

Gmelin Handbook: Na: SVol.1, 60, page 257 - 259 Full Text Show Details

Deutsche Gold- und Silber-Scheideanstalt vorm. Roessler

Patent: DE956037 , 1957 ; C., 1957 , p. 9748 Full Text Show Details

Deutsche Gold- und Silber-Scheideanstalt vorm. Roessler

Patent: GB790164 , 1958 ; C. A., 1958 , p. 14998 Full Text Show Details

Synthesize Find similar

Rx-ID: 26101888 Find similar reactions

in diethylene glycol

addn. of BF3-etherate (frehly distd.) to excess NaH in diglyme;;

Brown, H. C.; Tierney, P. A.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1552 - 1558 Full Text View citing articles Show Details

in diethylene glycol

addn. of BF3-etherate (frehly distd.) to excess NaH in diglyme;;

Gmelin Handbook: Na: SVol.2, 90, page 801 - 803 Full Text Show Details

Synthesize Find similar

Rx-ID: 26101891 Find similar reactions

B: 92%

in diethylene glycol

method for preparation of diborane, addn. of BF3-etherate (frehly distd.) to NaH in diglyme;;

Brown, H. C.; Tierney, P. A.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1552 - 1558 Full Text View citing articles Show Details

B: 92%

in diethylene glycol

method for preparation of diborane, addn. of BF3-etherate (frehly distd.) to NaH in diglyme;;

Gmelin Handbook: Na: SVol.2, 90, page 801 - 803 Full Text Show Details

in diethyl ether

at 110°C, method for preparation of diborane;;

Schlesinger, H. I.; Brown, H. C.; Gilbreath, J. R.; Katz, J. J.

Journal of the American Chemical Society, 1953 , vol. 75, p. 195 - 199 Full Text View citing articles Show Details

Hide Details

Gmelin Handbook: Na: SVol.2, 90, page 801 - 803 Full Text Show Details

in diethyl ether

at 110°C, method for preparation of diborane;; A

Synthesize Find similar

Synthesize Find similar Rx-ID: 26101892 Find similar reactions

Synthesize Find similar

in diethylene glycol

excess of NaH;

Brown, H. C.; Tierney, P. A.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1552 - 1558 Full Text View citing articles Show Details

in diethylene glycol

excess of NaH at ambient temp.;

Brown, H. C.; Tierney, P. A.

Journal of the American Chemical Society, 1958 , vol. 80, p. 1551 - 1558 Full Text Show Details

in diethylene glycol dimethyl ether

excess of NaH at ambient temp.;

Gmelin Handbook: Na: SVol.3, 3.6.2, page 1223 - 1233 Full Text Show Details

Hide Details Gmelin Handbook: Na: SVol.3, 3.6.1, page 1212 - 1222 Full Text Show Details

in diethylene glycol dimethyl ether

excess of NaH;

Synthesize Find similar

Synthesize Find similar Rx-ID: 26101944 Find similar reactions

Synthesize Find similar

in further solvent(s) on heating in inert solvents (mineral oil or hexachloro benzene or perfluoro anthracene) to 280°C for 40min and to 300°C for 80min;;

Thiokol Chemical Corp.

Patent: US2849276 , 1958 ; C. A., 1959 , p. 4670 Full Text Show Details

in further solvent(s) on heating in inert solvents (mineral oil or hexachloro benzene or perfluoro anthracene) to 280°C for 40min and to 300°C for 80min;;

Gmelin Handbook: Na: SVol.2, 90, page 801 - 803 Full Text Show Details