1-(1-(4-Methoxyphenyl)cyclohexyl)piperidine (4-MeO-PCP) [C18H27NO]

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Date

2 substances in Reaxys

2018-03-25 13h:29m:07s (EST)

O

1. Query

N

Search as: As drawn

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Reaxys ID 1252117 View in Reaxys

1/2 CAS Registry Number: 2201-35-6 Chemical Name: 1-[1-(4-methoxy-phenyl)-cyclohexyl]-piperidine; 1-<1-(4-Methoxy-phenyl)-cyclohexyl>-piperidin Linear Structure Formula: C18H27NO Molecular Formula: C18H27NO Molecular Weight: 273.418 Type of Substance: heterocyclic InChI Key: MUZGGFNYVLGUFS-UHFFFAOYSA-N Note:

O N

Substance Label (3) Label References 11 (methylated p-5)

Masumoto; Takeuchi; Ohta; Hirobe; Chemical and Pharmaceutical Bulletin; vol. 37; nb. 7; (1989); p. 1788 1794, View in Reaxys

GK 27

Geneste et al.; European Journal of Medicinal Chemistry; vol. 14; (1979); p. 301,302, View in Reaxys

VI

Kalir et al.; European Journal of Medicinal Chemistry; vol. 13; (1978); p. 17,18, View in Reaxys

Druglikeness (1) 1 of 1

LogP

4.133

H Bond Donors

0

H Bond Acceptors

1

Rotatable Bonds

3

TPSA

12.47

Lipinski Number

4

Veber Number

2

Derivative (2) Comment (Derivative)

References

*HCl: F: 171-172grad (korr.); pK(a)

Geneste et al.; European Journal of Medicinal Chemistry; vol. 14; (1979); p. 301,302, View in Reaxys

Hydrochlorid C18H27NO*HCl: F:186-187grad (unkorr.)

MADDOX; GODEFROI; PARCELL; Journal of medicinal chemistry; vol. 8; (1965); p. 230 - 235, View in Reaxys

Melting Point (1) 1 of 1

Melting Point [°C]

50 - 51

Geneste et al.; European Journal of Medicinal Chemistry; vol. 14; (1979); p. 301,302, View in Reaxys Dissociation Exponent (1) 1 of 1

Comment (Dissociation Exponent)

(pk')pk(a)

Kalir et al.; European Journal of Medicinal Chemistry; vol. 13; (1978); p. 17,18, View in Reaxys Further Information (1) Description (Fur- References ther Information) Further information

MADDOX; GODEFROI; PARCELL; Journal of medicinal chemistry; vol. 8; (1965); p. 230 - 235, View in Reaxys

Liquid/Liquid Systems (MCS) (1) 1 of 1

Description (Liquid/ Liquid Systems (MCS))

Distribution between solvent 1 + 2

Kalir et al.; European Journal of Medicinal Chemistry; vol. 13; (1978); p. 17,18, View in Reaxys Mass Spectrometry (1) Description (Mass References Spectrometry)

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spectrum; electron impact (EI)

Masumoto; Takeuchi; Ohta; Hirobe; Chemical and Pharmaceutical Bulletin; vol. 37; nb. 7; (1989); p. 1788 1794, View in Reaxys

UV/VIS Spectroscopy (1) 1 of 1

Description (UV/VIS Spectroscopy)

UV/VIS

Kalir et al.; European Journal of Medicinal Chemistry; vol. 13; (1978); p. 17,18, View in Reaxys Medchem (5) 1 of 5

Bioassay Category

In Vivo (Animal models)

Bioassay Name

Rotarod test

Biological Species/NCBI Swiss Webster mouse ID Substance RN

1252117View in Reaxys

Substance Name

GK27

Substance Route of Adm.

subcutaneous administration

Substance Dosing Regi- Single men Measurement Parameter

ED50

Unit

mg/kg

Quantitative value

20

Geneste; Kamenka; Ung; et al.; European Journal of Medicinal Chemistry; vol. 14; nb. 4; (1979); p. 301 - 308, View in Reaxys 2 of 5

Target Name

Glutamate receptor ionotropic, NMDA 2A [human];+Glutamate receptor ionotropic, NMDA 1 [human]

Target Synonyms

glun2a; glutamate; glutamate receptor ionotropic, nmda 2a; grin2a; hnr2a; n-methyl d-aspartate receptor subtype 2a; nmdar2a; nr2a + glun1; glutamate; glutamate receptor ionotropic, nmda 1; grin1 (glutamate receptor ionotropic, nmda 1); n-methyl-d-aspartate receptor subunit nr1; nmd-r1; nmdar1

Target Uniprot ID

q12879 + q05586

Target PDB ID

3nfl + 2hqw; 3bya

Target, Subunit, Species Glutamate receptor ionotropic, NMDA 1 [human]; Glutamate receptor ionotropic, NMDA 2A [human] Target Mutant/Chimera Details

Glutamate receptor ionotropic, NMDA 2A [human]:Wild + Glutamate receptor ionotropic, NMDA 1 [human]:Wild

Target Species (Bioactivity)

human

Target Transfection

Transfected

Substance Action on Target

Antagonist

Bioassay Category

In Vitro (Efficacy)

Bioassay Name

Flux uptake

Cells/Cell Lines

U-2 OS

Substance RN

1252117View in Reaxys

Substance Name

Cpd 1

Measurement Parameter

pIC50

Quantitative value

4.8

Deviation

0.270000

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3 of 5

Measurement pX

4.8

Concomitants: Compound RN

4241647

Concomitants: Compound name

Ca2+

Concomitants: Compound role

SUB

Target Name

Glutamate receptor ionotropic, NMDA 2B [human];+Glutamate receptor ionotropic, NMDA 1 [human]

Target Synonyms

glun2b; glutamate; glutamate receptor ionotropic, nmda 2b; grin2b; hnr3; n-methyl d-aspartate receptor subtype 2b; n-methyl-d-aspartate receptor subunit 3; nmdar2b; nr2b; nr3 + glun1; glutamate; glutamate receptor ionotropic, nmda 1; grin1 (glutamate receptor ionotropic, nmda 1); n-methyl-d-aspartate receptor subunit nr1; nmd-r1; nmdar1

Target Uniprot ID

q13224 + q05586

Target PDB ID

2hqw; 3bya

Target, Subunit, Species Glutamate receptor ionotropic, NMDA 1 [human]; Glutamate receptor ionotropic, NMDA 2B [human]

4 of 5

Target Mutant/Chimera Details

Glutamate receptor ionotropic, NMDA 2B [human]:Wild + Glutamate receptor ionotropic, NMDA 1 [human]:Wild

Target Species (Bioactivity)

human

Target Transfection

Transfected

Substance Action on Target

Antagonist

Bioassay Category

In Vitro (Efficacy)

Bioassay Name

Flux uptake

Cells/Cell Lines

U-2 OS

Substance RN

1252117View in Reaxys

Substance Name

Cpd 1

Measurement Parameter

pIC50

Quantitative value

5.4

Deviation

0.270000

Measurement pX

5.4

Concomitants: Compound RN

4241647

Concomitants: Compound name

Ca2+

Concomitants: Compound role

SUB

Target Name

Glutamate receptor ionotropic, NMDA 2A [human];+Glutamate receptor ionotropic, NMDA 1 [human]

Target Synonyms

glun2a; glutamate; glutamate receptor ionotropic, nmda 2a; grin2a; hnr2a; n-methyl d-aspartate receptor subtype 2a; nmdar2a; nr2a + glun1; glutamate; glutamate receptor ionotropic, nmda 1; grin1 (glutamate receptor ionotropic, nmda 1); n-methyl-d-aspartate receptor subunit nr1; nmd-r1; nmdar1

Target Uniprot ID

q12879 + q05586

Target PDB ID

3nfl + 2hqw; 3bya

Target, Subunit, Species Glutamate receptor ionotropic, NMDA 1 [human]; Glutamate receptor ionotropic, NMDA 2A [human]

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5 of 5

Target Mutant/Chimera Details

Glutamate receptor ionotropic, NMDA 2A [human]:Wild + Glutamate receptor ionotropic, NMDA 1 [human]:Wild

Target Species (Bioactivity)

human

Target Transfection

Transfected

Substance Action on Target

Antagonist

Bioassay Category

In Vitro (Efficacy)

Bioassay Name

Flux uptake

Cells/Cell Lines

U-2 OS

Substance RN

1252117View in Reaxys

Substance Name

Cpd 1

Measurement Parameter

Emax(%)

Unit

%

Quantitative value

94 - 100

Concomitants: Compound RN

4241647

Concomitants: Compound name

Ca2+

Concomitants: Compound role

SUB

Target Name

Glutamate receptor ionotropic, NMDA 2B [human];+Glutamate receptor ionotropic, NMDA 1 [human]

Target Synonyms

glun2b; glutamate; glutamate receptor ionotropic, nmda 2b; grin2b; hnr3; n-methyl d-aspartate receptor subtype 2b; n-methyl-d-aspartate receptor subunit 3; nmdar2b; nr2b; nr3 + glun1; glutamate; glutamate receptor ionotropic, nmda 1; grin1 (glutamate receptor ionotropic, nmda 1); n-methyl-d-aspartate receptor subunit nr1; nmd-r1; nmdar1

Target Uniprot ID

q13224 + q05586

Target PDB ID

2hqw; 3bya

Target, Subunit, Species Glutamate receptor ionotropic, NMDA 1 [human]; Glutamate receptor ionotropic, NMDA 2B [human] Target Mutant/Chimera Details

Glutamate receptor ionotropic, NMDA 2B [human]:Wild + Glutamate receptor ionotropic, NMDA 1 [human]:Wild

Target Species (Bioactivity)

human

Target Transfection

Transfected

Substance Action on Target

Antagonist

Bioassay Category

In Vitro (Efficacy)

Bioassay Name

Flux uptake

Cells/Cell Lines

U-2 OS

Substance RN

1252117View in Reaxys

Substance Name

Cpd 1

Measurement Parameter

Emax(%)

Unit

%

Quantitative value

94 - 100

Copyright © 2018 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

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2018-03-25 13:34:16


Concomitants: Compound RN

4241647

Concomitants: Compound name

Ca2+

Concomitants: Compound role

SUB

Reaxys ID 4606236 View in Reaxys Cl

2/2 CAS Registry Number: 2185-93-5 Linear Structure Formula: C18H27NO*ClH Molecular Formula: C18H27NO*ClH Molecular Weight: 309.879 Type of Substance: heterocyclic InChI Key: FYAFJNVLHWQLHK-UHFFFAOYSA-N Note:

H

O N

Substance Label (1) Label References 3a

Brine; Boldt; Coleman; Carroll; Journal of Heterocyclic Chemistry; vol. 21; nb. 1; (1984); p. 71 - 75, View in Reaxys

Druglikeness (1) 1 of 1

LogP

4.645

H Bond Donors

0

H Bond Acceptors

1

Rotatable Bonds

3

TPSA

12.47

Lipinski Number

4

Veber Number

2

Melting Point (1) 1 of 1

Melting Point [°C]

177 - 178.5

Comment (Melting Point)

Details: new mp after resolidification at: 230 C - 232 C

Brine; Boldt; Coleman; Carroll; Journal of Heterocyclic Chemistry; vol. 21; nb. 1; (1984); p. 71 - 75, View in Reaxys NMR Spectroscopy (1) 1 of 1

Description (NMR Spec- Chemical shifts troscopy) Nucleus (NMR Spectroscopy)

13C

Solvents (NMR Spectro- dimethylsulfoxide-d6 scopy) Brine; Boldt; Coleman; Carroll; Journal of Heterocyclic Chemistry; vol. 21; nb. 1; (1984); p. 71 - 75, View in Reaxys Medchem (8) 1 of 8

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Digging activity of the compound was determined as number of gerbils out of 4 which did not pass sand barrier after 30 min at a dose of 10 mg\kg

Biological Species/NCBI gerbil ID Substance RN

4606236View in Reaxys

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Measurement Parameter

Number

Measurement Object

Number of animals

Quantitative value

2

Kalir; Edery; Pelah; Balderman; Porath; Journal of medicinal chemistry; vol. 12; nb. 3; (1969); p. 473 - 477, View in Reaxys 2 of 8

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Percent reduction in performance of forced motor activity in mice after 30 min at a dose of 10 mg\kg

Biological Species/NCBI Mus musculus ID Substance RN

4606236View in Reaxys

Measurement Parameter

%

Unit

%

Measurement Object

Reduction activity

Qualitative value

=

Quantitative value

0

Kalir; Edery; Pelah; Balderman; Porath; Journal of medicinal chemistry; vol. 12; nb. 3; (1969); p. 473 - 477, View in Reaxys 3 of 8

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Digging activity of the compound was determined as number of gerbils out of 4 which did not pass sand barrier after 60 min at a dose of 10 mg\kg

Biological Species/NCBI gerbil ID Substance RN

4606236View in Reaxys

Measurement Parameter

Number

Measurement Object

Number of animals

Quantitative value

2

Kalir; Edery; Pelah; Balderman; Porath; Journal of medicinal chemistry; vol. 12; nb. 3; (1969); p. 473 - 477, View in Reaxys 4 of 8

Bioassay Category

In Vivo (Animal models)

Bioassay Details

Tested for main behavioral changes of cats at a intraventricular dose of 200 microg; None

Biological Species/NCBI domestic cat ID Substance RN

4606236View in Reaxys

Measurement Parameter

Qualitative

Measurement Object

Main behavioral changes

Qualitative value

Not Published

Kalir; Edery; Pelah; Balderman; Porath; Journal of medicinal chemistry; vol. 12; nb. 3; (1969); p. 473 - 477, View in Reaxys 5 of 8

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Percent reduction in performance of forced motor activity in mice after 60 min at a dose of 10 mg\kg

Biological Species/NCBI Mus musculus ID

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Substance RN

4606236View in Reaxys

Measurement Parameter

%

Unit

%

Measurement Object

Reduction activity

Qualitative value

=

Quantitative value

0

Kalir; Edery; Pelah; Balderman; Porath; Journal of medicinal chemistry; vol. 12; nb. 3; (1969); p. 473 - 477, View in Reaxys 6 of 8

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Digging activity of the compound was determined as number of gerbils out of 4 which did not pass sand barrier after 60 min at a dose of 5 mg\kg

Biological Species/NCBI gerbil ID Substance RN

4606236View in Reaxys

Measurement Parameter

Number

Measurement Object

Number of animals

Quantitative value

0

Kalir; Edery; Pelah; Balderman; Porath; Journal of medicinal chemistry; vol. 12; nb. 3; (1969); p. 473 - 477, View in Reaxys 7 of 8

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Percent reduction in response of conditioned avoidance response (CAR) in rats at a dose of 10 mg\kg

Biological Species/NCBI Rattus norvegicus ID Substance RN

4606236View in Reaxys

Measurement Parameter

%

Unit

%

Measurement Object

Reduction activity

Qualitative value

=

Quantitative value

0

Kalir; Edery; Pelah; Balderman; Porath; Journal of medicinal chemistry; vol. 12; nb. 3; (1969); p. 473 - 477, View in Reaxys 8 of 8

Bioassay Category

In Vivo (Animal models)

Bioassay Details

Compound was tested for cataleptic activity by measuring loss of righting reflex without head drop in pigeon upon intramuscular injection at the dose of 6-25 mg/kg; active members exhibiting maximum activity at the above mentioned dose

Biological Species/NCBI pigeon ID Substance RN

4606236View in Reaxys

Substance Route of Adm.

intramuscular administration

Measurement Parameter

Activity

Measurement Object

Cataleptic activity by measuring loss of righting reflex without head drop in pigeon

Qualitative value

ND

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MADDOX; GODEFROI; PARCELL; Journal of medicinal chemistry; vol. 8; (1965); p. 230 - 235, View in Reaxys

Copyright © 2018 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

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