3-(Diethylamino)-2,2-dimethylpropyl 4-aminobenzoate (Dimethocaine; DMC; Larocaine)

Page 1

Query Query

Results

Date

4 substances in Reaxys

2018-05-13 23h:45m:17s (UTC)

O N

1. Query

O

NH 2

Search as: As drawn ) AND (IDE.XRN=2215967)) OR (IDE.XRN=3730437) OR (IDE.XRN=3876278) OR (IDE.XRN=3881863))

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Reaxys ID 2215967 View in Reaxys

1/4 CAS Registry Number: 94-15-5 Chemical Name: dimethocaine; Dimethocaine; 4-amino-benzoic acid-(3-diethylamino-2,2-dimethyl-propyl ester); 4-Amino-benzoesaeure-(3-diaethylamino-2,2-dimethyl-propylester); 3-Diaethylamino-1-(4-amino-benzoyloxy)-2,2-dimethyl-propan; Larocain Linear Structure Formula: C16H26N2O2 Molecular Formula: C16H26N2O2 Molecular Weight: 278.395 Type of Substance: isocyclic InChI Key: OWQIUQKMMPDHQQ-UHFFFAOYSA-N Note:

O N O

NH 2

Patent-Specific Data (1) Location in Patent References Claim

Patent; Levin, Bruce H.; US2001/4644; (2001); (A1) English, View in Reaxys; Patent; Galin; Miles A.; Salamone; Joseph C.; Israel; Stanley C.; US5972326; (1999); (A) English, View in Reaxys; Patent; Cleary, Gary W.; Mudumba, Sri; Parandoosh, Shohreh; Cleary, Colin J.; Birudaraj, Raj; Park, Pathamar; US2003/27833; (2003); (A1) English, View in Reaxys; Patent; Tsao, Fu-Pao; US2003/133986; (2003); (A1) English, View in Reaxys

Druglikeness (1) 1 of 1

LogP

2.89

H Bond Donors

1

H Bond Acceptors

4

Rotatable Bonds

8

TPSA

55.56

Lipinski Number

4

Veber Number

2

Highest Clinical Phase (1) Highest Clinical Phase Marketed Derivative (2) Comment (Derivative)

References

Hydrochlorid Dusinsky; Chemicke Zvesti; vol. 17; (1963); p. 265; Chem.Abstr.; vol. 59; nb. 12596; (1963), View in Reaxys C16H26N2O2*HCl : Kinetik der alkal. Hydrolyse (oszillopolarogr. ermittelt) 2,4,6-trinitro benzoate (mp: 110-117 degree , yellow red); Further Data see Handbook

Fischer; Reichel; Pharmazeutische Zentralhalle; vol. 85; (1944); p. 8,11, View in Reaxys

Melting Point (3) 1 of 3

Melting Point [°C]

53

Schmidt, Andrea C.; Pharmaceutical Research; vol. 22; nb. 12; (2005); p. 2121 - 2133, View in Reaxys 2 of 3

Melting Point [°C]

199

Brandstaetter-Kuhnert; Kuhnert; Scientia Pharmaceutica; vol. 28; (1960); p. 287,302; Chem.Abstr.; nb. 9210; (1960), View in Reaxys 3 of 3

Melting Point [°C]

54

Brandstaetter-Kuhnert; Grimm; Microchimica Acta; (1957); p. 427,434, View in Reaxys Further Information (1) Description (FurReferences ther Information) Further information Dusinsky; Chemicke Zvesti; vol. 17; (1963); p. 265; Chem.Abstr.; vol. 59; nb. 12596; (1963), View in Reaxys Liquid/Solid Systems (MCS) (1)

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1 of 1

Description (Liquid/Solid Systems (MCS))

Eutectic

Brandstaetter-Kuhnert; Kuhnert; Scientia Pharmaceutica; vol. 28; (1960); p. 287,302; Chem.Abstr.; nb. 9210; (1960), View in Reaxys UV/VIS Spectroscopy (1) 1 of 1

Description (UV/VIS Spectroscopy)

Spectrum

Solvent (UV/VIS Spectroscopy)

H2O (pH 7.1)

Comment (UV/VIS Spectroscopy)

220 - 340 nm

Kalow; Journal of Pharmacology and Experimental Therapeutics; vol. 104; (1952); p. 122,124, View in Reaxys Use (10) Use Pattern

Location

References

Pharmaceuticals

Page/Page column 17-18

Patent; Becton, Dickinson and Company; Kelley, III, John J.; Valdes, Thelma I.; (19 pag.); US9248093; (2016); (B2) English, View in Reaxys

catheter locking solution

Page/Page column 17-18

Patent; Becton, Dickinson and Company; Kelley, III, John J.; Valdes, Thelma I.; (19 pag.); US9248093; (2016); (B2) English, View in Reaxys

local anesthetic

Page/Page column 17-18

Patent; Becton, Dickinson and Company; Kelley, III, John J.; Valdes, Thelma I.; (19 pag.); US9248093; (2016); (B2) English, View in Reaxys

inhibit the feeling of skin irritation

Patent; Ramirez, Jose E.; Faryniarz, Joseph; US2007/190190; (2007); (A1) English, View in Reaxys

anesthetic component of skin composition

Patent; Ramirez, Jose E.; Faryniarz, Joseph; US2007/190190; (2007); (A1) English, View in Reaxys

reducing of pain upon tissue penetration

Patent; Ramirez, Jose E.; Faryniarz, Joseph; US2007/190190; (2007); (A1) English, View in Reaxys

preparing of skin to make it more receptive to the corrective step

Patent; Ramirez, Jose E.; Faryniarz, Joseph; US2007/190190; (2007); (A1) English, View in Reaxys

acne vulgaris

Patent; Ramirez, Jose E.; Faryniarz, Joseph; US2007/190190; (2007); (A1) English, View in Reaxys

local anesthetic

Patent; Cassel, R. Douglas; US2006/29654; (2006); (A1) English, View in Reaxys

pain induced by a sports injury

Patent; Cassel, R. Douglas; US2006/29654; (2006); (A1) English, View in Reaxys

Medchem (31) 1 of 31

Target Name

Sodium-dependent dopamine transporter [Rattus norvegicus]

Target Synonyms

da transporter; dat; slc6a3; sodium-dependent dopamine transporter; solute carrier family 6 member 3

Target Uniprot ID

p23977

Target, Subunit, Species

Sodium-dependent dopamine transporter [Rattus norvegicus]

Target Mutant/Chimera Details

Sodium-dependent dopamine transporter [Rattus norvegicus]:Wild

Target Species (Bioactivity)

Rattus norvegicus

Target Transfection

Non Transfected

Bioassay Category

In Vitro (Efficacy)

Bioassay Name

Binding

Biological Species/NCBI ID

Sprague Dawley rat

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Organs/Tissues

putamen

Substance RN

2215967View in Reaxys

Substance Name

19

Measurement Parameter

Ki (inhibition constant)

Unit

nM

Quantitative value

603

Measurement pX

6.22

Concomitants: Compound RN

91034; 4354534

Concomitants: Compound name

Cocaine; [3H]-WIN 35428

Concomitants: Compound role

NSB; RAD

Izenwasser; Terry; Heller; Witkin; Kats; European Journal of Pharmacology; vol. 263; nb. 3; (1994); p. 277 - 283, View in Reaxys 2 of 31

Bioassay Category

In Vivo (Animal models)

Bioassay Name

Spontaneous activity

Biological Species/NCBI ID

Swiss Webster mouse

Substance RN

2215967View in Reaxys

Substance Name

19

Substance Route of Adm.

intraperitoneal administration

Substance Dosing Regimen

Single

Measurement Parameter

ED50

Unit

mg/kg

Measurement Object

dose which induces locomotor activity in 50% mouse

Quantitative value

8.94

Izenwasser; Terry; Heller; Witkin; Kats; European Journal of Pharmacology; vol. 263; nb. 3; (1994); p. 277 - 283, View in Reaxys 3 of 31

Bioassay Category

In Vivo (Animal models)

Bioassay Name

Spontaneous activity

Biological Species/NCBI ID

Swiss Webster mouse

Substance RN

2215967View in Reaxys

Substance Name

19

Measurement Parameter

ED50

Unit

µmol/kg

Measurement Object

dose which induces locomotor activity in 50% mouse

Quantitative value

36.8

Izenwasser; Terry; Heller; Witkin; Kats; European Journal of Pharmacology; vol. 263; nb. 3; (1994); p. 277 - 283, View in Reaxys 4 of 31

Bioassay Category

Toxicity/Safety Pharmacology

Bioassay Details

Lowest lethal dose of the compound in rabbit upon subcutaneous administration

Biological Species/NCBI ID

Leporidae

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Substance RN

2215967View in Reaxys

Substance Route of Adm.

subcutaneous administration

Measurement Parameter

LDLo

Unit

mg/kg

Measurement Object

Lowest lethal dose

Quantitative value

150

Physiological reviews; vol. 12; (1932); p. 190, View in Reaxys 5 of 31

Bioassay Category

Toxicity/Safety Pharmacology

Bioassay Details

Lowest lethal dose of the compound in mouse upon intravenous administration

Biological Species/NCBI ID

Mus musculus

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

LDLo

Unit

mg/kg

Measurement Object

Lowest lethal dose

Quantitative value

40

Physiological reviews; vol. 12; (1932); p. 190, View in Reaxys 6 of 31

Bioassay Category

Toxicity/Safety Pharmacology

Bioassay Details

Lowest lethal dose of the compound in rabbit upon intravenous administration

Biological Species/NCBI ID

Leporidae

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

LDLo

Unit

mg/kg

Measurement Object

Lowest lethal dose

Quantitative value

150

Physiological reviews; vol. 12; (1932); p. 190, View in Reaxys 7 of 31

Bioassay Category

Toxicity/Safety Pharmacology

Bioassay Details

Lowest lethal dose of the compound in guinea pig upon subcutaneous administration

Biological Species/NCBI ID

guinea pig

Substance RN

2215967View in Reaxys

Substance Route of Adm.

subcutaneous administration

Measurement Parameter

LDLo

Unit

mg/kg

Measurement Object

Lowest lethal dose

Quantitative value

200

Physiological reviews; vol. 12; (1932); p. 190, View in Reaxys 8 of 31

Substance Action on Target

Inhibitor

Bioassay Category

In Vitro (Efficacy)

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Bioassay Details

In vitro inhibitory concentration of dimethocaine against dopamine uptake in monkey caudate nucleus tissue upon incubated for 10 min at 37 degree C

Substance RN

2215967View in Reaxys

Measurement Parameter

IC50

Unit

µM

Measurement Object

Dopamine uptake

Qualitative value

=

Quantitative value

11

Measurement pX

4.96

Wilcox; Wilcox, Kristin M.; Rowlett; Rowlett, James K.; Paul; Paul, Ian A.; Ordway; Ordway, Gregory A.; Woolverton; Woolverton, William L.; Psychopharmacology; vol. 153; nb. 1; (2000); p. 139 - 147, View in Reaxys 9 of 31

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Effective dose required for local anesthetic effect under a progressive-ratio (PR400) procedure in rhesus monkeys upon intravenous administration

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

ED50

Unit

mg/kg

Measurement Object

Effective dose

Qualitative value

=

Quantitative value

0.29

Wilcox; Wilcox, Kristin M.; Rowlett; Rowlett, James K.; Paul; Paul, Ian A.; Ordway; Ordway, Gregory A.; Woolverton; Woolverton, William L.; Psychopharmacology; vol. 153; nb. 1; (2000); p. 139 - 147, View in Reaxys 10 of 31

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Effective dose required for local anesthetic effect under a progressive-ratio (PR400) procedure in rhesus monkeys upon intravenous administration

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

ED50

Unit

µmol/kg

Measurement Object

Effective dose

Qualitative value

=

Quantitative value

0.95

Wilcox; Wilcox, Kristin M.; Rowlett; Rowlett, James K.; Paul; Paul, Ian A.; Ordway; Ordway, Gregory A.; Woolverton; Woolverton, William L.; Psychopharmacology; vol. 153; nb. 1; (2000); p. 139 - 147, View in Reaxys 11 of 31

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Effective dose required for local anesthetic effect under a progressive-ratio (PR200) procedure in rhesus monkeys upon intravenous administration

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

ED50

Unit

mg/kg

Measurement Object

Effective dose

Qualitative value

=

Quantitative value

0.26

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Wilcox; Wilcox, Kristin M.; Rowlett; Rowlett, James K.; Paul; Paul, Ian A.; Ordway; Ordway, Gregory A.; Woolverton; Woolverton, William L.; Psychopharmacology; vol. 153; nb. 1; (2000); p. 139 - 147, View in Reaxys 12 of 31

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Effective dose required for local anesthetic effect under a progressive-ratio (PR200) procedure in rhesus monkeys upon intravenous administration

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

ED50

Unit

µmol/kg

Measurement Object

Effective dose

Qualitative value

=

Quantitative value

0.82

Wilcox; Wilcox, Kristin M.; Rowlett; Rowlett, James K.; Paul; Paul, Ian A.; Ordway; Ordway, Gregory A.; Woolverton; Woolverton, William L.; Psychopharmacology; vol. 153; nb. 1; (2000); p. 139 - 147, View in Reaxys 13 of 31

Bioassay Category

In Vivo (Animal models)

Bioassay Details

Effective dose required for local anesthetic effect under a progressive-ratio (PR50) procedure in rhesus monkeys upon intravenous administration

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

ED50

Unit

mg/kg

Measurement Object

Effective dose

Qualitative value

=

Quantitative value

0.19

Wilcox; Wilcox, Kristin M.; Rowlett; Rowlett, James K.; Paul; Paul, Ian A.; Ordway; Ordway, Gregory A.; Woolverton; Woolverton, William L.; Psychopharmacology; vol. 153; nb. 1; (2000); p. 139 - 147, View in Reaxys 14 of 31

Bioassay Category

In Vivo (Animal models)

Bioassay Details

Effective dose required for local anesthetic effect under a progressive-ratio (PR50) procedure in rhesus monkeys upon intravenous administration

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

ED50

Unit

µmol/kg

Measurement Object

Effective dose

Qualitative value

=

Quantitative value

0.6

Wilcox; Wilcox, Kristin M.; Rowlett; Rowlett, James K.; Paul; Paul, Ian A.; Ordway; Ordway, Gregory A.; Woolverton; Woolverton, William L.; Psychopharmacology; vol. 153; nb. 1; (2000); p. 139 - 147, View in Reaxys 15 of 31

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Effective dose required for local anesthetic effect under a progressive-ratio (PR100) procedure in rhesus monkeys upon intravenous administration

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

ED50

Unit

mg/kg

Qualitative value

=

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Quantitative value

0.41

Wilcox; Wilcox, Kristin M.; Rowlett; Rowlett, James K.; Paul; Paul, Ian A.; Ordway; Ordway, Gregory A.; Woolverton; Woolverton, William L.; Psychopharmacology; vol. 153; nb. 1; (2000); p. 139 - 147, View in Reaxys 16 of 31

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Effective dose required for local anesthetic effect under a progressive-ratio (PR100) procedure in rhesus monkeys upon intravenous administration

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

ED50

Unit

µmol/kg

Qualitative value

=

Quantitative value

1.3

Wilcox; Wilcox, Kristin M.; Rowlett; Rowlett, James K.; Paul; Paul, Ian A.; Ordway; Ordway, Gregory A.; Woolverton; Woolverton, William L.; Psychopharmacology; vol. 153; nb. 1; (2000); p. 139 - 147, View in Reaxys 17 of 31

Bioassay Category

Toxicity/Safety Pharmacology

Bioassay Details

Lowest lethal dose of the compound in frog upon parenteral administration

Biological Species/NCBI ID

Anura

Substance RN

2215967View in Reaxys

Substance Route of Adm.

intravenous administration

Measurement Parameter

LDLo

Unit

mg/kg

Measurement Object

Lowest lethal dose

Quantitative value

860

Naunyn-Schmiedebergs Arch. Exp. Pathol. Pharmakol.(1925-1966) ; vol. 168; (1932); p. 447, View in Reaxys 18 of 31

Bioassay Category

Toxicity/Safety Pharmacology

Bioassay Details

Lowest lethal dose of the compound in mouse upon subcutaneous administration

Biological Species/NCBI ID

Mus musculus

Substance RN

2215967View in Reaxys

Substance Route of Adm.

subcutaneous administration

Measurement Parameter

LDLo

Unit

mg/kg

Measurement Object

Lowest lethal dose

Quantitative value

380

Naunyn-Schmiedebergs Arch. Exp. Pathol. Pharmakol.(1925-1966) ; vol. 168; (1932); p. 447, View in Reaxys 19 of 31

Target Name

Sodium-dependent dopamine transporter

Target Synonyms

da transporter; dat; dat-1; dat1; fmn; protein fumin; slc6a3; sodium-dependent dopamine transporter; solute carrier family 6 member 3

Target, Subunit, Species

Sodium-dependent dopamine transporter

Target Mutant/Chimera Details

Sodium-dependent dopamine transporter:Wild

Substance Action on Target

Inhibitor

Bioassay Category

In Vitro (Efficacy)

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Bioassay Details

Inhibition of 30 nM [3H]CFT binding at dopamine transporter upon incubation in 50 mM Tris-HCl, pH 7.4 for 2 h at 0 degree C

Substance RN

2215967View in Reaxys

Measurement Parameter

Ki (inhibition constant)

Unit

nM

Qualitative value

=

Quantitative value

1400

Measurement pX

5.85

Concomitants: Compound name

[3H]CFT

Concomitants: Compound role

RAD

Woodward; Compton; Balster; Martin; European Journal of Pharmacology; vol. 277; nb. 1; (1995); p. 7 - 13, View in Reaxys 20 of 31

Target Name

Sodium-dependent dopamine transporter

Target Synonyms

da transporter; dat; dat-1; dat1; fmn; protein fumin; slc6a3; sodium-dependent dopamine transporter; solute carrier family 6 member 3

Target, Subunit, Species

Sodium-dependent dopamine transporter

Target Mutant/Chimera Details

Sodium-dependent dopamine transporter:Wild

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Inhibitory concentration of the compound against [3H]dopamine uptake by dopamine transporter

Substance RN

2215967View in Reaxys

Measurement Parameter

IC50

Unit

µM

Qualitative value

=

Quantitative value

1.2

Measurement pX

5.92

Woodward; Compton; Balster; Martin; European Journal of Pharmacology; vol. 277; nb. 1; (1995); p. 7 - 13, View in Reaxys 21 of 31

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Inhibition constant of the compound against 30 nM [3H]CFT binding to rat striatal homogenate upon incubation in 50 mM Tris-HCl, pH 7.4 for 2 h at 0 degree C

Biological Species/NCBI ID

Rattus norvegicus

Substance RN

2215967View in Reaxys

Measurement Parameter

Ki (inhibition constant)

Unit

µM

Qualitative value

=

Quantitative value

1.4

Measurement pX

5.85

Concomitants: Compound name

[3H]CFT

Concomitants: Compound role

RAD

Woodward; Compton; Balster; Martin; European Journal of Pharmacology; vol. 277; nb. 1; (1995); p. 7 - 13, View in Reaxys 22 of 31

Target Name

Sodium-dependent dopamine transporter

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Target Synonyms

23 of 31

da transporter; dat; dat-1; dat1; fmn; protein fumin; slc6a3; sodium-dependent dopamine transporter; solute carrier family 6 member 3

Target, Subunit, Species

Sodium-dependent dopamine transporter

Target Mutant/Chimera Details

Sodium-dependent dopamine transporter:Wild

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Dopamine transporter occupancy by displacing FECNT in monkey striatum measured by neuroimaging with positron emission tomography (PET); Value range = <10-41

Substance RN

2215967View in Reaxys

Measurement Parameter

percentage

Unit

%

Measurement Object

Occupancy rate

Qualitative value

=

Quantitative value

41

Target Name

Sodium-dependent dopamine transporter

Target Synonyms

da transporter; dat; dat-1; dat1; fmn; protein fumin; slc6a3; sodium-dependent dopamine transporter; solute carrier family 6 member 3

Target, Subunit, Species

Sodium-dependent dopamine transporter

Target Mutant/Chimera Details

Sodium-dependent dopamine transporter:Wild

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Inhibitory concentration against dopamine uptake by dopamine transporter

Substance RN

2215967View in Reaxys

Measurement Parameter

IC50

Unit

µM

Qualitative value

=

Quantitative value

1.2

Measurement pX

5.92

Woodward; Compton; Balster; Martin; European Journal of Pharmacology; vol. 277; nb. 1; (1995); p. 7 - 13, View in Reaxys 24 of 31

Bioassay Category

In Vivo (Animal models)

Bioassay Details

Antinociceptive response of the compound in mice upon s.c. administration; Induced dose-dependently

Biological Species/NCBI ID

Mus musculus

Substance RN

2215967View in Reaxys

Substance Route of Adm.

subcutaneous administration

Measurement Parameter

Activity

Measurement Object

Effect

Qualitative value

ND

Rigon, Adriana Regina; Takahashi, Reinaldo Naoto; General Pharmacology; vol. 27; nb. 4; (1996); p. 647 - 650, View in Reaxys 25 of 31

Bioassay Category

In Vivo (Animal models)

Bioassay Details

Effect of the compound on locomotor activity of mice upon i.p. administration; Significantly increased

Biological Species/NCBI ID

Mus musculus

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Substance RN

2215967View in Reaxys

Substance Route of Adm.

intraperitoneal administration

Measurement Parameter

Activity

Measurement Object

Effect

Qualitative value

ND

Rigon, Adriana R.; Takahashi, Reinaldo N.; Psychopharmacology; vol. 127; nb. 4; (1996); p. 323 - 327, View in Reaxys 26 of 31

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Effect on tail-flick and paw-licking hot plate responses of mice; Significantly inhibited

Biological Species/NCBI ID

Mus musculus

Substance RN

2215967View in Reaxys

Measurement Parameter

Activity

Measurement Object

Effect

Qualitative value

ND

Rigon, Adriana Regina; Takahashi, Reinaldo Naoto; General Pharmacology; vol. 27; nb. 4; (1996); p. 647 - 650, View in Reaxys 27 of 31

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Inhibition of 50 nM [3H]dopamine uptake in rat striatal synaptosomes upon incubation in 10 mM Tris, pH 7.65 at RT

Biological Species/NCBI ID

Rattus norvegicus

Substance RN

2215967View in Reaxys

Measurement Parameter

% Inhibition

Unit

%

Qualitative value

=

Quantitative value

100

Woodward; Compton; Balster; Martin; European Journal of Pharmacology; vol. 277; nb. 1; (1995); p. 7 - 13, View in Reaxys 28 of 31

Target Name

Sodium-dependent dopamine transporter [Rattus norvegicus]

Target Synonyms

da transporter; dat; slc6a3; sodium-dependent dopamine transporter; solute carrier family 6 member 3

Target Uniprot ID

p23977

Target, Subunit, Species

Sodium-dependent dopamine transporter [Rattus norvegicus]

Target Mutant/Chimera Details

Sodium-dependent dopamine transporter [Rattus norvegicus]:Wild

Target Species (Bioactivity)

Rattus norvegicus

Substance Action on Target

Inhibitor

Substance Effect

inhibitory activity

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Inhibition of 0.15 nM [125I]RTI-55 binding to Dopamine reuptake in rat striatum

Organs/Tissues

neostriatum

Substance RN

2215967View in Reaxys

Measurement Parameter

IC50

Unit

nM

Qualitative value

=

Copyright © 2018 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

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29 of 31

30 of 31

31 of 31

Quantitative value

460.74

Measurement pX

6.34

Target Name

Sodium-dependent serotonin transporter [Rattus norvegicus]

Target Synonyms

5ht transporter; 5htt; sert; slc6a4; sodium-dependent serotonin transporter; solute carrier family 6 member 4

Target Uniprot ID

p31652

Target, Subunit, Species

Sodium-dependent serotonin transporter [Rattus norvegicus]

Target Mutant/Chimera Details

Sodium-dependent serotonin transporter [Rattus norvegicus]:Wild

Target Species (Bioactivity)

Rattus norvegicus

Substance Action on Target

Inhibitor

Substance Effect

inhibitory activity

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Inhibition of 0.15 nM [125I]RTI-55 binding to Serotonin reuptake in rat cerebral cortex

Organs/Tissues

brain cortex

Substance RN

2215967View in Reaxys

Measurement Parameter

IC50

Unit

nM

Qualitative value

=

Quantitative value

34572.3

Measurement pX

4.46

Target Name

Sodium-dependent dopamine transporter [Rattus norvegicus]

Target Synonyms

da transporter; dat; slc6a3; sodium-dependent dopamine transporter; solute carrier family 6 member 3

Target Uniprot ID

p23977

Target, Subunit, Species

Sodium-dependent dopamine transporter [Rattus norvegicus]

Target Mutant/Chimera Details

Sodium-dependent dopamine transporter [Rattus norvegicus]:Wild

Target Species (Bioactivity)

Rattus norvegicus

Substance Action on Target

Inhibitor

Substance Effect

inhibitory activity

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Dopamine transporter activity was determined by inhibition of [125I]RTI-55 (0.15 nM) binding in rat cerebral cortex

Organs/Tissues

brain cortex

Substance RN

2215967View in Reaxys

Measurement Parameter

IC50

Unit

nM

Qualitative value

=

Quantitative value

34572.3

Measurement pX

4.46

Target Name

Sodium-dependent dopamine transporter [Rattus norvegicus]

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Target Synonyms

da transporter; dat; slc6a3; sodium-dependent dopamine transporter; solute carrier family 6 member 3

Target Uniprot ID

p23977

Target, Subunit, Species

Sodium-dependent dopamine transporter [Rattus norvegicus]

Target Mutant/Chimera Details

Sodium-dependent dopamine transporter [Rattus norvegicus]:Wild

Target Species (Bioactivity)

Rattus norvegicus

Substance Action on Target

Inhibitor

Substance Effect

inhibitory activity

Bioassay Category

In Vitro (Efficacy)

Bioassay Details

Dopamine transporter activity was determined by inhibition of [125I]RTI-55 (0.15 nM) binding in rat striatum

Organs/Tissues

neostriatum

Substance RN

2215967View in Reaxys

Measurement Parameter

IC50

Unit

nM

Qualitative value

=

Quantitative value

460.74

Measurement pX

6.34

Reaxys ID 3730437 View in Reaxys

2/4

H 2N

N

Cl

CAS Registry Number: 553-63-9 Chemical Name: dimethocaine hydrochloride; 4-amino-benzoic acid-(3-diethylamino-2,2-dimethyl-propylester); hydrochloride; 4Amino-benzoesaeure-(3-diaethylamino-2,2-dimethyl-propylester); Hydrochlorid; Larocain Linear Structure Formula: C16H26N2O2*ClH Molecular Formula: C16H26N2O2*ClH Molecular Weight: 314.856 Type of Substance: isocyclic InChI Key: WWTWKTDXBNHESE-UHFFFAOYSA-N Note:

H

O O

Druglikeness (1) 1 of 1

LogP

3.402

H Bond Donors

1

H Bond Acceptors

4

Rotatable Bonds

8

TPSA

55.56

Lipinski Number

4

Veber Number

2

Melting Point (3) 1 of 3

Melting Point [°C]

199

Schmidt, Andrea C.; Pharmaceutical Research; vol. 22; nb. 12; (2005); p. 2121 - 2133, View in Reaxys 2 of 3

Melting Point [°C]

197 - 199

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Fischer; Reichel; Pharmazeutische Zentralhalle; vol. 85; (1944); p. 8,11, View in Reaxys; Brandstaetter-Kuhnert; Grimm; Microchimica Acta; (1957); p. 427,434, View in Reaxys 3 of 3

Melting Point [°C]

195 - 196

Solvent (Melting Point)

propan-2-ol

Lesser,B.; Diss. <Frankfurt 1930> S. 29, View in Reaxys Crystal System (1) Crystal System References rhombic

Wickstroem; Journal of Pharmacy and Pharmacology; vol. 5; (1953); p. 158,163, View in Reaxys

Medchem (2) 1 of 2

Substance Effect

Dopaminergic

Bioassay Category

In Vivo (Animal models)

Bioassay Name

In vivo Measurement

Bioassay Details

Bioassay : levels of dopamine (DA) and its metabolites 3-methoxytyramine (3-MT) and dihydroxyphenylacetic acid (DOPAC) in the striatum (STR), nucleus accumbens (NAcc) and prefrontal cortex PFC) rats weighing 185 to 310 g; food and water ad libitum; 12 h light-dark cycle; sacrificed; time course (dose of title comp.: 88 μmol/kg) and dose response study; reverse-phase HPLC with electrochemical detection and gas chromatography-mass spectrometry

Biological Species/NCBI ID

Rattus norvegicus

Substance RN

3730437View in Reaxys

Substance Name

1484799

Substance Dose

56 µmol/kg

Substance Route of Adm.

intraperitoneal administration

Qualitative Results

increase the synaptic presence of DA; numerical data and diagrams given

Measurement Parameter

qualitative

Graham III; Maher; Robinson; Journal of Pharmacology and Experimental Therapeutics; vol. 274; nb. 2; (1995); p. 707 - 717, View in Reaxys 2 of 2

Substance Effect

Anaesthesic

Bioassay Category

In Vivo (Animal models)

Bioassay Name

In vivo Measurement

Bioassay Details

Bioassay : behavior maintained by food presentation under a fixed ratio 32 schedule of reinforcement; four daily (sunday-friday) behavioral session for substitution and antagonism tests monkeys, trained to discriminate sympathomimetic stimulant cocaine from saline, injected with title comp. 10 min before the session alone in various concns. or with saline

Biological Species/NCBI ID

squirrel monkey

Substance RN

3730437View in Reaxys

Substance Name

1484799

Substance Dose

0.0100000 mg/kg

Substance Route of Adm.

intramuscular administration

Measurement Parameter

ED50

Unit

µmol/kg

Quantitative value

2.29

Mansbach; Jortani; Balster; European Journal of Pharmacology; vol. 274; nb. 1-3; (1995); p. 167 - 173, View in Reaxys

Reaxys ID 3876278 View in Reaxys

Copyright © 2018 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

3/4

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2018-05-13 23:45:48


O O

Chemical Name: 4-amino-benzoic acid-(3-diethylamino-2,2-dimethyl-propylester); picrate; 4-Amino-benzoesaeure-(3-diaethylamino-2,2dimethyl-propylester); Picrat Linear Structure Formula: C16H26N2O2*C6H3N3O7 Molecular Formula: C6H3N3O7*C16H26N2O2 Molecular Weight: 507.5 Type of Substance: isocyclic InChI Key: JAVSCQSYKWVESR-UHFFFAOYSA-N Note:

N O

HO

N O

O

N O O

N O

NH 2

Druglikeness (1) 1 of 1

H Bond Donors

2

H Bond Acceptors

4

Rotatable Bonds

11

TPSA

213.25

Lipinski Number

2

Veber Number

0

Melting Point (2) 1 of 2

Melting Point [°C]

164 - 165

Fischer; Reichel; Pharmazeutische Zentralhalle; vol. 85; (1944); p. 8,11, View in Reaxys 2 of 2

Melting Point [°C]

166

Fischer; Archiv der Pharmazie (Weinheim, Germany); vol. 271; (1933); p. 466,469, View in Reaxys

Reaxys ID 3881863 View in Reaxys

4/4

O

O

N

N

O

Chemical Name: 4-amino-benzoic acid-(3-diethylamino-2,2-dimethyl-propylester); compound with 2,4,6-trinitro-resorcinol; 4-Aminobenzoesaeure-(3-diaethylamino-2,2-dimethyl-propylester); Verbindung mit 2,4,6-Trinitro-resorcin Linear Structure Formula: C16H26N2O2*C6H3N3O8 Molecular Formula: C6H3N3O8*C16H26N2O2 Molecular Weight: 523.5 Type of Substance: isocyclic InChI Key: KQELRHUHJCLXSX-UHFFFAOYSA-N Note:

O

HO

OH N O

O O

N O

NH 2

Druglikeness (1) 1 of 1

H Bond Donors

3

H Bond Acceptors

4

Rotatable Bonds

11

TPSA

233.48

Lipinski Number

2

Veber Number

0

Melting Point (2) 1 of 2

Melting Point [°C]

147 - 151

Copyright © 2018 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

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Fischer; Reichel; Pharmazeutische Zentralhalle; vol. 85; (1944); p. 8,11, View in Reaxys 2 of 2

Melting Point [°C]

149 - 150

Fischer; Archiv der Pharmazie (Weinheim, Germany); vol. 271; (1933); p. 466,469, View in Reaxys

Copyright © 2018 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

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