3. 1-Isopropoxypropane [Isopropyl propyl ether; i-PrO-n-Pr]

Page 1

Query Query 1. Query O

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Date

13 reactions in Reaxys

2016-09-13 03h:00m:37s (EST)

Search as: As drawn, No salts, No mixtures, No isotopes, No charges, No radicals

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OH

HO

O

Rx-ID: 23309783 View in Reaxys 1/13 Yield

Conditions & References

41 %

3 : Mixed Ether Formation Isopropanol and n-propanol in the ratio of 1.2 parts isopropanol to 1.0 parts n-propanol were exposed to a Deloxan ASP 1/7 acid catalyst (Degussa-Huels AG) under the conditions given below in a continuous flow reactor. The reactor volume was 20 ml and the flow rate of the solvent was 0.65 L/min. With Deloxan ASP 1/7 acid catalyst in carbon dioxide, T= 150 °C , p= 150015Torr Patent; THOMAS SWAN AND CO., LTD.; EP1185492; (2005); (B1) English View in Reaxys

O

HO

O

Rx-ID: 57787 View in Reaxys 2/13 Yield

Conditions & References With sulfuric acid Wuyts; Lacourt; Bulletin des Societes Chimiques Belges; vol. 39; (1930); p. 161,165, 172 View in Reaxys

60 % Turn- With DELOXAN ASP in carbon dioxide, T= 150 °C , p= 200Torr ov., 8 % Gray, William K.; Smail, Fiona R.; Hitzler, Martin G.; Ross, Stephen K.; Poliakoff, Martyn; Journal of the AmeriTurnov. can Chemical Society; vol. 121; nb. 46; (1999); p. 10711 - 10718 View in Reaxys

OH

HO

O O

Rx-ID: 8960164 View in Reaxys 3/13 Yield

Conditions & References

41 % Turn- With DELOXAN ASP in carbon dioxide, T= 150 °C , p= 200Torr ov., 12 % Gray, William K.; Smail, Fiona R.; Hitzler, Martin G.; Ross, Stephen K.; Poliakoff, Martyn; Journal of the AmeriTurnov. can Chemical Society; vol. 121; nb. 46; (1999); p. 10711 - 10718 View in Reaxys

O

HO

O

Rx-ID: 1603980 View in Reaxys 4/13 Yield

Conditions & References With Al3+-montmorillonite, Time= 4h, T= 200 °C , Yield given. Yields of byproduct given Ballantine, James A.; Davies, Mary; Purnell, Howard; Rayanakorn, Mongkon; Thomas, John M.; Williams, Kevin J.; Journal of the Chemical Society, Chemical Communications; nb. 9; (1981); p. 427 - 428 View in Reaxys O

O S

O– Na +

O

O

Rx-ID: 674498 View in Reaxys 5/13 Yield

Conditions & References With isopropyl alcohol, acetone

Copyright © 2016 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

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Drahowzal; Klamann; Monatshefte fuer Chemie; vol. 82; (1951); p. 588,592 View in Reaxys

O–

O

I

Na +

Rx-ID: 632715 View in Reaxys 6/13 Yield

Conditions & References T= 100 °C Michael; Wilson; Chemische Berichte; vol. 29; (1896); p. 2575 View in Reaxys

O

O Cl

Cl

OH

OH

Rx-ID: 2616075 View in Reaxys 7/13 Yield

Conditions & References in cyclohexane, T= 20 °C , Equilibrium constant Bellon, Louis; Taft, Robert W.; Abboud, Jose-Luis M.; Journal of Organic Chemistry; vol. 45; nb. 6; (1980); p. 1166 - 1168 View in Reaxys

OH

I

O

Rx-ID: 1224737 View in Reaxys 8/13 Yield

Conditions & References (i) KOH, DMSO, (ii) /BRN= 505937/, Multistep reaction Benedict,D.R. et al.; Synthesis; (1979); p. 428 - 429 View in Reaxys O

O S

–O

O

Na +

O

Rx-ID: 70157 View in Reaxys 9/13 Yield

Conditions & References Truchet; Graves; Bulletin de la Societe Chimique de France; vol. <4> 51; (1932); p. 688 View in Reaxys O

O S O

O– Na +

O

Rx-ID: 70696 View in Reaxys 10/13 Yield

Conditions & References Truchet; Graves; Bulletin de la Societe Chimique de France; vol. <4> 51; (1932); p. 688 View in Reaxys

Copyright © 2016 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

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O

OH

O O

N

O O

S O

Rx-ID: 4891574 View in Reaxys 11/13 Yield

Conditions & References T= 40 - 70 °C , Ea, ΔF(excit.), ΔH(excit.), -ΔS(excit.), Rate constant, Thermodynamic data Sendega; Makitra; Pirig; Russian Journal of Organic Chemistry; vol. 32; nb. 10; (1996); p. 1438 - 1446 View in Reaxys

CH 2

O

H

O

O

O

O

O

Rx-ID: 1844998 View in Reaxys 12/13 Yield

Conditions & References T= 20 °C , Irradiation, Kinetics Mehta, R. K. S.; Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry; vol. 25; (1986); p. 60 - 62 View in Reaxys T= 100 °C , Irradiation, Kinetics Mehta, R. K. S.; Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry; vol. 25; (1986); p. 60 - 62 View in Reaxys

OH

HO HO

O O

S OO

Rx-ID: 6672904 View in Reaxys 13/13 Yield

Conditions & References Geschwindigkeit der Veresterung Wuyts; Lacourt; Bulletin des Societes Chimiques Belges; vol. 39; (1930); p. 161,165, 172 View in Reaxys

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