6. Chloroiodomethane [ClCH2I]

Page 1

Query Query 1. Query

I

Cl

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Date

11 reactions in Reaxys

2016-09-13 04h:20m:40s (EST)

Search as: As drawn, No salts, No mixtures, No isotopes, No charges, No radicals

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Cl

Cl

Cl

I

Rx-ID: 209825 View in Reaxys 1/11 Yield

Conditions & References With methanol, sodium iodide Henry; Chemische Berichte; 24 Ref. <1891>,74 View in Reaxys With methanol, sodium iodide, T= 130 °C Bacher; Wagner; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 43; (1939); p. 195,197 View in Reaxys With methyl iodide, Wilkinson's catalyst, Time= 2h, T= 100 °C Lyons,J.E.; Journal of the Chemical Society, Chemical Communications; (1975); p. 418 - 419 View in Reaxys With methyl iodide, tris(triphenylphosphine)ruthenium(II) chloride, Time= 2h, T= 100 °C Lyons,J.E.; Journal of the Chemical Society, Chemical Communications; (1975); p. 418 - 419 View in Reaxys

I

I

Cl

Cl

Cl

I

Rx-ID: 170691 View in Reaxys 2/11 Yield

Conditions & References With aluminium trichloride, potassium chloride, T= 114 °C Forbes; Anderson; Journal of the American Chemical Society; vol. 67; (1945); p. 1912 View in Reaxys

Cl

Cl

I

I

I

Cl

I

Rx-ID: 3885690 View in Reaxys 3/11 Yield

Conditions & References

50 % Spectr., 36 % Spectr.

9% Spectr., 34 % Spectr.

I

I

With neutral alumina 90 + Bu4P(1+)I(1-) in gas, Time= 1.25h, T= 195 °C , p= 760Torr Tundo, Pietro; Venturello, Paolo; Angeletti, Enrico; Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999); (1983); p. 485 - 492 View in Reaxys With neutral alumina 90 + Bu4P(1+)I(1-) in gas, T= 195 °C , p= 760Torr Tundo, Pietro; Venturello, Paolo; Angeletti, Enrico; Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999); (1983); p. 485 - 492 View in Reaxys Cl

I

Rx-ID: 170767 View in Reaxys 4/11 Yield

Conditions & References With pyridine, tributyltin chloride, T= 100 °C , Δ G, Thermodynamic data, Equilibrium constant Friedrich, Edwin C.; Abma, Charles B.; Journal of the American Chemical Society; vol. 102; nb. 4; (1980); p. 1367 - 1371 View in Reaxys With iodine cloride

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Bacher; Wagner; Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie; vol. 43; (1939); p. 195,197 View in Reaxys With iodine cloride Sakurai; Journal of the Chemical Society; vol. 47; (1885); p. 198 Anm. View in Reaxys Cl

Br

Cl

Cl

Cl

I

Rx-ID: 1897637 View in Reaxys 5/11 Yield

Conditions & References With Amberlyst A-26 (chloride form), methyl iodide, Time= 9h, T= 27 - 70 °C , Yield given. Yields of byproduct given Hahn, Roger C.; Journal of Organic Chemistry; vol. 53; nb. 6; (1988); p. 1331 - 1333 View in Reaxys Cl

ClCH2HgI

I

Rx-ID: 6946404 View in Reaxys 6/11 Yield

Conditions & References With iodine, potassium iodide Sakurai; Journal of the Chemical Society; vol. 41; (1882); p. 362 View in Reaxys

Cl

(v2)

Cl

Hg

I

Cl

Rx-ID: 1163758 View in Reaxys 7/11 Yield

Conditions & References With iodine Wittig,G.; Schwarzenbach,K.; Justus Liebigs Annalen der Chemie; vol. 650; (1961); p. 1 - 20 View in Reaxys

I

I

Cl

Cl

Cl

I

Rx-ID: 1847988 View in Reaxys 8/11 Yield

Conditions & References

34 %, 50 %

With ICl3, further iodoalkanes, Product distribution Amriev, R. A.; Velichko, F. K.; Baibuz, O. P.; Rilo, R. P.; Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation); vol. 33; nb. 12; (1984); p. 2501 - 2504; Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya; nb. 12; (1984); p. 2732 - 2736 View in Reaxys

Cl

Se

I

H

Cl

I

I

Rx-ID: 8258547 View in Reaxys 9/11 Yield

Conditions & References Williams; Ravve; Journal of the American Chemical Society; vol. 70; (1948); p. 1244 View in Reaxys

Copyright © 2016 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

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H 2C

Cl

I

I

Rx-ID: 2054600 View in Reaxys 10/11 Yield

Conditions & References With chlorine, Irradiation, poly(tetrafluoroethylene)-coated Pyrex or uncoated quartz reactor, temperatures 295 - 524 K, Rate constant, Thermodynamic data Seetula, J. A.; Gutman, D.; Lightfoot, P. D.; Rayes, M. T.; Senkan, S. M.; Journal of Physical Chemistry; vol. 95; nb. 26; (1991); p. 10688 - 10693 View in Reaxys Cl

I

Rx-ID: 6946403 View in Reaxys 11/11 Yield

Conditions & References Kosower; Schwager; Journal of the American Chemical Society; vol. 86; (1964); p. 5528,5529 View in Reaxys Miyano; Hashimoto; Bulletin of the Chemical Society of Japan; vol. 44; (1971); p. 2864 View in Reaxys Hoberg; Justus Liebigs Annalen der Chemie; vol. 656; (1962); p. 15,16 View in Reaxys Wittig; Wingler; Justus Liebigs Annalen der Chemie; vol. 656; (1962); p. 18,21 View in Reaxys Landini; Rolla; Chemistry and Industry (London, United Kingdom); (1974); p. 533 View in Reaxys Altabev et al.; Chemistry and Industry (London, United Kingdom); (1973); p. 331 View in Reaxys Dilling; Edamura; Chemical Communications (London); (1967); p. 183 View in Reaxys Miyano et al.; Journal of Organometallic Chemistry; vol. 12; (1968); p. 263 View in Reaxys

Copyright © 2016 Reed Elsevier Properties SA. All rights reserved. Authorized use only. Reaxys® and the Reaxys® trademark are owned and protected by Reed Elsevier Properties SA and used under license.

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