Reaxys
PubChem
eMolecules
Reactions (322)
Yield
Substances (32)
Citations (235)
Conditions
References
298
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Multi-step reaction with 3 steps 1: AlCl3
2: palladium/charcoal; acetic acid / 65 °C / 2206.5 Torr / Hydrogenation 3: AlCl3; benzene View Scheme
299
Rx-ID: 22028268 Find similar reactions
Wasserman; Dawson
Journal of the American Chemical Society, 1950 , vol. 72, p. 4994,4996 Full Text Show Details
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300 mg
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Rx-ID: 498283 Find similar reactions
With hydrogen bromide; acetic acid
Cook; Heilbron; Lewis
Journal of the Chemical Society, 1942 , p. 659 Full Text Show Details
With boron tribromide in dichloromethane
1) -20 deg C, 1 h; 2) rt, 3 h; Yield given;
Shi, Ji-Liang; Chen, Xin; Jiang, Xi-Kui
Journal of Organic Chemistry, 1996 , vol. 61, # 14 p. 4698 - 4702 Title/Abstract Full Text View citing articles Show Details
With boron tribromide in dichloromethane
1.) 0 deg C, 45 min, 2.) RT, 4 h;
Groweiss, Amiram; Cardellina II, John H.; Pannell, Lewis K.; Uyakul, Duangchan; Kashman, Yoel; Boyd, Michael R.
Journal of Natural Products, 1997 , vol. 60, # 2 p. 116 - 121 Title/Abstract Full Text View citing articles Show Details
300
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With hydrogen bromide; acetic acid
Rx-ID: 504114 Find similar reactions
Cook; Heilbron; Lewis
Journal of the Chemical Society, 1942 , p. 659 Full Text Show Details
301
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Rx-ID: 7260015 Find similar reactions
Meiji Dairies Corporation
Patent: EP1854777 A1, 2007 ; Location in patent: Page/Page column 20 ;
95%
Title/Abstract Full Text Show Details
42%
Hide Experimental Procedure
Rhodia Chimie
Patent: US6049015 A1, 2000 ; Title/Abstract Full Text Show Details
5:Synthesis of Hexadecylhydroquinone STR3
The processing and purifications are identical to those above.
A reaction yield of 42percent monohexadecylhydroquinone is obtained, for a 65percent degree of conversion of the hydroquinone.
Neiland; Trybatscha
Patent: SU371196 , 1973 ; Ref. Zh., Khim., 1974 , vol. 8, # N121P Full Text Show Details
Armstrong et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 1928,1932 Full Text Show Details
302
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Rx-ID: 7260016 Find similar reactions
With hydrogenchloride; amalgamated zinc; acetic acid
Asano; Hase
Yakugaku Zasshi, 1940 , vol. 60, p. 650,658 Yakugaku Zasshi, 1941 , vol. 61, p. engl. Ref. S. 1, 5 Chem.Abstr., 1942 , p. 83 Full Text Show Details
303
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Rx-ID: 7988119 Find similar reactions
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Cook; Heilbron; Lewis
Journal of the Chemical Society, 1942 , p. 659 Full Text Show Details
6-stdg. Kochen;
304
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Find similar Rx-ID: 7988120 Find similar reactions
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Cook; Heilbron; Lewis
Journal of the Chemical Society, 1942 , p. 659 Full Text Show Details
305
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Rx-ID: 17046448 Find similar reactions
Multi-step reaction with 2 steps 1: 1.) n-BuLi / 1.) THF, hexane, a) 0 deg C, 30 min, b) reflux, 90 min, 2.) THF, hexane, reflux, 90 min 2: 300 mg / BBr3 / CH2Cl2 / 1.) 0 deg C, 45 min, 2.) RT, 4 h View Scheme
Groweiss, Amiram; Cardellina II, John H.; Pannell, Lewis K.; Uyakul, Duangchan; Kashman, Yoel; Boyd, Michael R.
Journal of Natural Products, 1997 , vol. 60, # 2 p. 116 - 121 Title/Abstract Full Text View citing articles Show Details
306
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Rx-ID: 17046487 Find similar reactions
Multi-step reaction with 2 steps 1: 1.) n-BuLi / 1.) THF, hexane, a) 0 deg C, 30 min, b) reflux, 90 min, 2.) THF, hexane, reflux, 90 min 2: 300 mg / BBr3 / CH2Cl2 / 1.) 0 deg C, 45 min, 2.) RT, 4 h View Scheme
Groweiss, Amiram; Cardellina II, John H.; Pannell, Lewis K.; Uyakul, Duangchan; Kashman, Yoel; Boyd, Michael R.
Journal of Natural Products, 1997 , vol. 60, # 2 p. 116 - 121 Title/Abstract Full Text View citing articles Show Details
A
B
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307
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With Re2(CO)10 in toluene
T=150°C; 24 h; Inert atmosphereSealed tube; regioselective reaction;
Kuninobu, Yoichiro; Matsuki, Takashi; Takai, Kazuhiko
Journal of the American Chemical Society, 2009 , vol. 131, # 29 p. 9914 - 9915 Title/Abstract Full Text View citing articles Show Details
308
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73%
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Rx-ID: 5124805 Find similar reactions
With boron tribromide in dichloromethane
3 h; Ambient temperature;
Jinno, Shuji; Okita, Takaaki
Chemical and Pharmaceutical Bulletin, 1998 , vol. 46, # 11 p. 1688 - 1694 Title/Abstract Full Text View citing articles Show Details
309
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Rx-ID: 16427560 Find similar reactions
Multi-step reaction with 3 steps 1: 1.) NaCH2SOMe / 1.) DMSO, 60 deg, 30 min, 2.) DMSO, 50 deg C, overnight 2: H2 / PtO2 / ethyl acetate / 1 h 3: 73 percent / BBr3 / CH2Cl2 / 3 h / Ambient temperature View Scheme
Jinno, Shuji; Okita, Takaaki
Chemical and Pharmaceutical Bulletin, 1998 , vol. 46, # 11 p. 1688 - 1694 Title/Abstract Full Text View citing articles Show Details
310
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Multi-step reaction with 3 steps 1: 1.) NaCH2SOMe / 1.) DMSO, 60 deg, 30 min, 2.) DMSO, 50 deg C, overnight
Rx-ID: 16436930 Find similar reactions
Jinno, Shuji; Okita, Takaaki
Chemical and Pharmaceutical Bulletin, 1998 , vol. 46, # 11 p. 1688 - 1694
Title/Abstract Full Text View citing articles Show Details
2: H2 / PtO2 / ethyl acetate / 1 h 3: 73 percent / BBr3 / CH2Cl2 / 3 h / Ambient temperature View Scheme
311
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Rx-ID: 16457126 Find similar reactions
Multi-step reaction with 2 steps 1: H2 / PtO2 / ethyl acetate / 1 h 2: 73 percent / BBr3 / CH2Cl2 / 3 h / Ambient temperature View Scheme
Jinno, Shuji; Okita, Takaaki
Chemical and Pharmaceutical Bulletin, 1998 , vol. 46, # 11 p. 1688 - 1694 Title/Abstract Full Text View citing articles Show Details
312
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Rx-ID: 298826 Find similar reactions
With aluminium trichloride; benzene
Asano; Hase
Yakugaku Zasshi, 1940 , vol. 60, p. 650,658 Yakugaku Zasshi, 1941 , vol. 61, p. engl. Ref. S. 1, 5 Chem.Abstr., 1942 , p. 83 Full Text Show Details
313
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With palladium on activated charcoal; acetic acid
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Rx-ID: 313701 Find similar reactions
Eastman Kodak Co.
Patent: US2728659 , 1953 ; Full Text Show Details
With hydrogen; copper (II) chromite in ethanol
Vandenberghe,A.; Willems,J.F.
Bulletin des Societes Chimiques Belges, 1965 , vol. 74, p. 397 - 406 Full Text View citing articles Show Details
314
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Rx-ID: 504133 Find similar reactions
With hydrogen bromide; acetic acid
Cook; Heilbron; Lewis
Journal of the Chemical Society, 1942 , p. 659 Full Text Show Details
315
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With hydrogen bromide; acetic acid
Rx-ID: 508988 Find similar reactions
Cook; Heilbron; Lewis
Journal of the Chemical Society, 1942 , p. 659 Full Text Show Details
316
Synthesize Find similar /BRN= 58415/, HSiEt3 (Eg.);
Rx-ID: 7261166 Find similar reactions
Neiland; Trybatscha
Patent: SU371196 , 1973 ; Ref. Zh., Khim., 1974 , vol. 8, # N121P Full Text Show Details
Fuji Photo Film Co.
Patent: JP461464 , 1961 ; Chem.Abstr., 1965 , vol. 63, # 1736c Full Text Show Details
Hydrochinon, Octadecen, H+;
317
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Rx-ID: 22407348 Find similar reactions
Multi-step reaction with 2 steps 1: BF3
2: H2 / copper-chromite / ethanol View Scheme
Vandenberghe,A.; Willems,J.F.
Bulletin des Societes Chimiques Belges, 1965 , vol. 74, p. 397 - 406 Full Text View citing articles Show Details
318
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Rx-ID: 22407974 Find similar reactions
Multi-step reaction with 2 steps 1: BF3
2: H2 / copper-chromite / ethanol View Scheme
Vandenberghe,A.; Willems,J.F.
Bulletin des Societes Chimiques Belges, 1965 , vol. 74, p. 397 - 406 Full Text View citing articles Show Details
A
B
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319
Synthesize Find similar Rx-ID: 34289222 Find similar reactions
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With perchloric acid in 1,4-dioxane
T=20°C;
Tell, Volkmar; Mahmoud, Kazem Ahmed; Hilgeroth, Andreas; Holzer, Max; Herrmann, Lydia; Schaechtele, Christoph; Totzke, Frank
Bioorganic and Medicinal Chemistry Letters, 2012 , vol. 22, # 22 p. 6914 - 6918,5 Title/Abstract Full Text Show Details
320
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Rx-ID: 4709165 Find similar reactions
52%
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With lithium chloride in pyridine
1 h; Heating;
Ozaki, Yutaka; Hosoya, Ayako; Okamura, Kyouko; Kim, Sang-Won
Synlett, 1997 , vol. 1997, # 4 p. 365 - 366 Title/Abstract Full Text View citing articles Show Details
A
B
C
D
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321
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Rx-ID: 3771968 Find similar reactions
With trifluoroacetic acid
1.) CH2Cl2, -20 deg C, 6 h, 2.) CH2Cl2, -20 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given;
Haga, Naoki; Endo, Yasuyuki; Kataoka, Ken-Ichiro; Yamaguchi, Kentaro; Shudo, Koichi
Journal of the American Chemical Society, 1992 , vol. 114, # 25 p. 9795 - 9806 Title/Abstract Full Text View citing articles Show Details
322
Synthesize Find similar With hydrogen; palladium on activated charcoal
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Rx-ID: 9029258 Find similar reactions
Tziveleka, Leto-A; Kourounakis, Angeliki P; Kourounakis, Panos N; Roussis, Vassilios; Vagias, Constantinos
Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 4 p. 935 - 939 Title/Abstract Full Text View citing articles Show Details