2-Oxo-2-phenylacetic acid (Phenylglyoxylic Acid) by Asch

Reaxys

PubChem

eMolecules

Reactions (272)

Yield

Substances (1)

Citations (298)

Conditions

References A

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100

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A: 1.6 % Spectr. B: 62.1% C: 9.9 % Spectr. D: 7.6 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)-nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

101

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A: 2.9 % Spectr. B: 62.1% C: 9.9 % Spectr. D: 7.6 % Spectr.

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With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)-nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

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Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

102

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Rx-ID: 2449193 Find similar reactions

Blanchot, Valerie; Fetizon, Marcel; Hanna, Issam

Synthesis, 1990 , # 9 p. 755 - 756 Title/Abstract Full Text Show Details

With sodium hydroxide; pyridinium chlorochromate

1) CH2Cl2, reflux, 3 d, 2) Et2O, 30 min; Multistep reaction;

103

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With sulfuric acid in tetrahydrofuran

T=50°C; 48 h;

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Rx-ID: 2466551 Find similar reactions

Katritzky, Alan R.; Yang, Zhijun; Lam, Jamshed N.

Synthesis, 1990 , # 8 p. 666 - 669 Title/Abstract Full Text Show Details

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104

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Rx-ID: 21789978 Find similar reactions

Multi-step reaction with 2 steps 1: 1) 2.5 M BuLi / 1) THF, hexane, -78 deg C, 2 h, 2) -78 deg C, 5 h; then rt, 12 h 2: 81 percent / conc. H2SO4 / tetrahydrofuran / 48 h / 50 °C View Scheme

Katritzky, Alan R.; Yang, Zhijun; Lam, Jamshed N.

Synthesis, 1990 , # 8 p. 666 - 669 Title/Abstract Full Text Show Details

Multi-step reaction with 2 steps 1: 93 percent / trans-benzyl(chloro)bis(triphenylphosphine)palladium(II) / benzene / 3 h / Heating 2: 1) pyridinium chlorochromate, 2) aq. NaOH / 1) CH2Cl2, reflux, 3 d, 2) Et2O, 30 min View Scheme

Blanchot, Valerie; Fetizon, Marcel; Hanna, Issam

Synthesis, 1990 , # 9 p. 755 - 756 Title/Abstract Full Text Show Details

105

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Rx-ID: 21840222 Find similar reactions

Multi-step reaction with 2 steps 1: 9.9 percent Spectr. / Et3N, pyridine, O2, H2O / Cu(NO3)2py2 / methanol / 12 h / 25 °C / 1748 Torr 2: 68.6 percent Spectr. / Et3N, pyridine, O2, H2O / Cu(NO3)2py2 / methanol / 12 h / 25 °C / 1748 Torr View Scheme

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 1.6 percent Spectr. / Et3N, pyridine, O2, H2O / Cu(NO3)2py2 / methanol / 12 h / 25 °C / 1748 Torr 2: 68.6 percent Spectr. / Et3N, pyridine, O2, H2O / Cu(NO3)2py2 / methanol / 12 h / 25 °C / 1748 Torr View Scheme

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

106

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Rx-ID: 1987158

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With sodium hydroxide; potassium permanganate

1.) 120-125 deg C, 3 h; 2.) -18-(-20) deg C, 30 min; Yield given. Multistep reaction;

Bandyopadhyay; Bagchi; Podder; Moitra

Journal of the Indian Chemical Society, 1989 , vol. 66, # 4 p. 239 - 240 Title/Abstract Full Text View citing articles Show Details

107

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Rx-ID: 18642802 Find similar reactions

Multi-step reaction with 2 steps 1: 55.2 percent / anhydrous aluminium chloride / 3 h / Ambient temperature 2: 1.) NaOH; 2.) KMnO4 / 1.) 120-125 deg C, 3 h; 2.) -18-(-20) deg C, 30 min View Scheme

Bandyopadhyay; Bagchi; Podder; Moitra

Journal of the Indian Chemical Society, 1989 , vol. 66, # 4 p. 239 - 240 Title/Abstract Full Text View citing articles Show Details

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108

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Rx-ID: 1710650 Find similar reactions

A: 4 % Chromat. B: 53 % Chromat. C: 5 % Chromat.

Itoh, Kenji; Miura, Masahiro; Nomura, Masakatsu

Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 11 p. 4151 - 4152 Title/Abstract Full Text Show Details

With sodium sulfide; CoCl2 in 1,4-dioxane; water

T=20°C; 20 h; other reag.; other solvent; Product distribution;

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109

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Rx-ID: 1793299 Find similar reactions

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A: 3% B: 68% C: 5%

With methyl iodide; sodium tetrahydroborate in 1,4-dioxane; water

T=20°C; 20 h;

Itoh, Kenji; Miura, Masahiro; Nomura, Masakatsu

Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 11 p. 4151 - 4152 Title/Abstract Full Text Show Details

A: 3% B: 64% C: 13%

With methyl iodide; sodium tetrahydroborate in 1,4-dioxane; water

T=20°C; 20 h;

Itoh, Kenji; Miura, Masahiro; Nomura, Masakatsu

Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 11 p. 4151 - 4152 Title/Abstract Full Text Show Details

A: 69.0 % Chromat. B: 3.8 % Chromat. C: 9.3 % Chromat.

With calcium hydroxide powder; water; bis(dimethylphenylphosphine) palladium(II) chloride in isopropyl alcohol

T=100°C; 12 h; P(CO) = 150 atm at room temperature; further catalysts, solvents and hydroxide;

Kobayashi, Toshi-aki; Sakakura, Toshiyasu; Tanaka, Masato

Tetrahedron Letters, 1987 , vol. 28, # 24 p. 2721 - 2722 Title/Abstract Full Text View citing articles Show Details

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A: 46.0 % Chromat. B: 8.7 % Chromat. C: 25.5 % Chromat.

With calcium hydroxide powder; water; bis(benzonitrile)palladium(II) dichloride in isopropyl alcohol

T=100°C; 12 h; P(CO) = 150 atm at room temperature; further catalysts, solvents and hydroxide;

Kobayashi, Toshi-aki; Sakakura, Toshiyasu; Tanaka, Masato

Tetrahedron Letters, 1987 , vol. 28, # 24 p. 2721 - 2722 Title/Abstract Full Text View citing articles Show Details

A: 3 % Chromat. B: 62 % Chromat. C: 5 % Chromat.

With sodium sulfide; CoCl2 in 1,4-dioxane; water

T=20°C; 20 h; other reag.; other solvent; Product distribution;

Itoh, Kenji; Miura, Masahiro; Nomura, Masakatsu

Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 11 p. 4151 - 4152 Title/Abstract Full Text Show Details

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110

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With sodium hypochlorite; phosphate buffer; ammonium chloride

1 h; Ambient temperature; Product distribution;

Ohya, Takeshi; Kanno, Saburo

Chemical and Pharmaceutical Bulletin, 1988 , vol. 36, # 10 p. 4095 - 4102 Title/Abstract Full Text Show Details

111

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Rx-ID: 1710411 Find similar reactions

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A: 30 % Spectr. B: 6 % Chromat. C: 13 % Chromat. D: 8 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl; methyl iodide in 1,4-dioxane; water

20 h; Ambient temperature; Title compound not separated from byproducts;

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

A: 30 % Chromat. B: 6 % Chromat. C: 13 % Chromat. D: 8 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl; methyl iodide in 1,4-dioxane; water

20 h; Title compound not separated from byproducts;

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

A: 30 % Spectr. B: 6 % Chromat. C: 13 % Chromat. D: 8 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl; methyl iodide in 1,4-dioxane; water

20 h; Title compound not separated from byproducts;

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

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A: 30 % Spectr. B: 6 % Chromat. C: 13 % Chromat. D: 8 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl; methyl iodide in 1,4-dioxane; water

20 h;

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

112

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Rx-ID: 1793119 Find similar reactions

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A: 1 % Chromat. B: 25 % Chromat. C: 20 % Chromat. D: 23 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl; methyl iodide in 1,4-dioxane; water

20 h; Ambient temperature; Title compound not separated from byproducts;

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

A: 1 % Chromat. B: 25 % Chromat. C: 20 % Chromat. D: 23 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl; methyl iodide in water; N,N-dimethyl-formamide

20 h; Title compound not separated from byproducts;

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

A: 1 % Chromat. B: 25 % Chromat. C: 20 % Chromat. D: 23 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl; methyl iodide in 1,4-dioxane; water

20 h; Title compound not separated from byproducts;

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

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113

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Rx-ID: 1793120 Find similar reactions

A: 16 % Spectr. B: 7 % Chromat. C: 12 % Chromat. D: 13 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl; methyl iodide in 1,4-dioxane; water

20 h;

114

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 1981154 Find similar reactions

A: 5.2 % Chromat. B: 9.7 % Chromat. C: 5.9 % Chromat. D: 5.5 % Chromat. E: 10.4 % Chromat. F: 54.5 % Chromat.

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With oxygen

T=110°C; P=759.8 Torr; 15 h; Product distribution;

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Rao, T. S. S.; Pritzkow, W.

Journal fuer Praktische Chemie (Leipzig), 1987 , vol. 329, # 5 p. 930 - 932 Title/Abstract Full Text Show Details

115

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44%

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Rx-ID: 3365778 Find similar reactions

With potassium permanganate; acetic acid; tri[2-(2-methoxyethoxy)ethyl]amine in dichloromethane

4 h; Ambient temperature;

McKillop, Alexander; Mills, Lester S.

Synthetic Communications, 1987 , vol. 17, # 6 p. 647 - 656 Title/Abstract Full Text Show Details

116

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A: 1 % Chromat. B: 2 % Chromat. C: 3 % Chromat. D: 4 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl in water; N,N-dimethyl-formamide

20 h; Ambient temperature; Title compound not separated from byproducts;

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

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117

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Rx-ID: 3884905 Find similar reactions

A: 1 % Chromat. B: 25 % Chromat. C: 20 % Chromat. D: 23 % Chromat.

With calcium hydroxide powder; dicobalt octacarbonyl in water; N,N-dimethyl-formamide

20 h; Title compound not separated from byproducts;

Miura, Masahiro; Akase, Fumiaki; Nomura, Masakatsu

Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2623 - 2625 Title/Abstract Full Text View citing articles Show Details

118

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Rx-ID: 40676 Find similar reactions

With hydrogenchloride

Oakwood; Weisgerber

Organic Syntheses, 1944 , vol. 24, p. 16 Full Text Show Details

With hydrogenchloride; sulfuric acid in water

Bayer Aktiengesellschaft

Patent: US4596885 A1, 1986 ;

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Title/Abstract Full Text Show Details

i:(i)

(i) Hydrolysis with concentrated hydrochloric acid; esterification in the presence of concentrated sulphuric acid 13.1 g (0.1 mol) of benzoyl cyanide were stirred with 70 ml of concentrated hydrochloric acid for 18 hours at 50° C. After cooling, the mixture was poured into 300 ml of water and extracted with chloroform, the extract was dried over sodium sulphate and evaporated and the residue was distilled in vacuo. This gave 7.0 g (47percent of theory) of phenylglyoxylic acid of boiling point 138°-141° C./12 mm Hg.

The distillate soon solidified and could be recrystallized from ligroin (melting point 64.5°-65.5° C.).

119

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Rx-ID: 2186381 Find similar reactions

With triethylamine in diethyl ether

Yield given;

Cainelli, Gianfranco; Manescalchi, Francesco; Plessi, Laura

Gazzetta Chimica Italiana, 1986 , vol. 116, # 3 p. 163 - 164 Title/Abstract Full Text Show Details

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120

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A: 5.2% B: 1.8%

With copper dichloride in acetonitrile

Irradiationalso in the presence of aq. FeCl3; other similar substrates; Product distribution;

Sharma, K. S.; Kumari, Sharda; Goel, Vijender K.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1986 , vol. 25, p. 743 - 744 Title/Abstract Full Text Show Details

With perchloric acid; vanadium pentoxide

T=28°C; Product distributionMechanism;

Kalidoss, Ponnusamy; Srinivasan, Vangalur S.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 2631 - 2636 Title/Abstract Full Text Show Details

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121

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With sodium hydroxide

Alcaide, Benito; Perez-Ossorio, Rafael; Plumet, Joaquin; Sierra, Miguel A.

Tetrahedron Letters, 1986 , vol. 27, # 14 p. 1627 - 1630 Title/Abstract Full Text View citing articles Show Details

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122

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Rx-ID: 3949405 Find similar reactions

With calcium hydroxide powder; dimethyl sulfate; dicobalt octacarbonyl in water; butan-1-ol

T=20°C; P=760 Torr; 1 atm. of CO; var.: solvent, reagent, temperature; Yield given. Yields of byproduct given;

Francalanci, F.; Bencini, E.; Gardano, A.; Vincenti, M.; Foa, M.

Journal of Organometallic Chemistry, 1986 , vol. 301, p. C27 - C30 Title/Abstract Full Text View citing articles Show Details

With calcium hydroxide powder; dimethyl sulfate; dicobalt octacarbonyl in ethanol; water

T=40°C; P=760 Torr; 1 atm. of CO; var.: solvent, reagent, temperature; Yield given. Yields of byproduct given;

Francalanci, F.; Bencini, E.; Gardano, A.; Vincenti, M.; Foa, M.

Journal of Organometallic Chemistry, 1986 , vol. 301, p. C27 - C30 Title/Abstract Full Text View citing articles Show Details

123

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Multi-step reaction with 2 steps 1: n-Bu4N(+)NO3(-) / tetrahydrofuran / 18 h / Ambient temperature 2: Et3N / diethyl ether View Scheme

Cainelli, Gianfranco; Manescalchi, Francesco; Plessi, Laura

Gazzetta Chimica Italiana, 1986 , vol. 116, # 3 p. 163 - 164 Title/Abstract Full Text Show Details

124

Rx-ID: 18814574 Find similar reactions

Synthesize Find similar Rx-ID: 2061433 Find similar reactions

A: 21.1% B: 19.1% C: 55.9%

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With nitric acid; sodium nitrite in 1,4-dioxane; water

T=60°C; 0.5 h; variation of solvents, reactants, concentrations; Product distributionMechanismRate constant;

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Tezuka, Hiroshi; Kato, Megumi; Sonehara, Yukito

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 1643 - 1648 Title/Abstract Full Text Show Details

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125

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A: 19.9% B: 24.4% C: 53%

With nitric acid; sodium nitrite in 1,4-dioxane; water

T=60°C; 2.63333 h; variation of solvents, time; Rate constantMechanismProduct distribution;

Tezuka, Hiroshi; Kato, Megumi; Sonehara, Yukito

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 1643 - 1648 Title/Abstract Full Text Show Details

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126

Synthesize Find similar Rx-ID: 3934044 Find similar reactions

A: 9.7% B: 4.4% C: 68.4%

With nitric acid; sodium nitrite in nitromethane; water

T=60°C; 0.5 h;

Tezuka, Hiroshi; Kato, Megumi; Sonehara, Yukito

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 1643 - 1648 Title/Abstract Full Text Show Details

A: 9.7% B: 4.4% C: 68.4%

With nitric acid; sodium nitrite in nitromethane; water

T=60°C; 0.5 h; variation of solvents, reactants; Product distributionMechanism;

Tezuka, Hiroshi; Kato, Megumi; Sonehara, Yukito

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 1643 - 1648 Title/Abstract Full Text Show Details

127

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B: 89.3%

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With triethylamine in benzene

3 h; Heating;

Baldoli, Clara; Beccalli, Egle M.; Licandro, Emanuela; Marchesini, Alessandro

Gazzetta Chimica Italiana, 1981 , vol. 111, # 7/8 p. 347 - 350 Title/Abstract Full Text Show Details

With hydrogenchloride; sodium hydroxide; water

Mechanism;

Becalli, Egle M.; Marchesini, Alessandro; Sannicolo, Francesco

Journal of Organic Chemistry, 1984 , vol. 49, # 11 p. 2071 - 2073 Title/Abstract Full Text View citing articles Show Details

128

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Rx-ID: 21216070 Find similar reactions

Multi-step reaction with 2 steps 1: 215 mg / acetone / 5 h / Irradiation 2: 1) NaOH/H2O, 2) dilute HCl View Scheme

Becalli, Egle M.; Marchesini, Alessandro; Sannicolo, Francesco

Journal of Organic Chemistry, 1984 , vol. 49, # 11 p. 2071 - 2073 Title/Abstract Full Text View citing articles Show Details

129

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Hide Experimental Procedure

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Rx-ID: 25127857 Find similar reactions

Bayer Aktiengesellschaft

Patent: US4370498 A1, 1983 ; Title/Abstract Full Text Show Details

2.b:(b) (b) Phenylglyoxylic acid (C6 H5 --CO--COOH) The procedure followed is as described in Example B 2. (a), but instead of trimethylpyruvic acid N-acetylamide, the equivalent amount (0.1 mole) of phenylglyoxylic acid N-acetylamide was employed. 13.4 g (89.3percent of theory) of phenylglyoxylic acid were obtained.

130

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Rx-ID: 25123497 Find similar reactions

With sulfuric acid in formaldehyd

Zoecon Corporation

Patent: US4334087 A1, 1982 ;

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Title/Abstract Full Text Show Details

6:EXAMPLE 6

EXAMPLE 6 3 Grams of α-oximinophenylacetic acid is dissolved in 9 ml of 37percent formaldehyde containing a few drops of sulfuric acid. This is stirred overnight at RT, extracted with 3:1 ether:hexane, washed with brine, dried over sodium sulfate, stripped and distilled to yield the final productproduct α-oxophenylacetic acid, b.p.=138°-141°/3.3 mm. A

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131

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Rx-ID: 1581607 Find similar reactions

Chawla, H. M.; Chakrabarty, Kakoli; Prakash, Anil; Chibber, S. S.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1981 , vol. 20, # 6 p. 507 - 508 Title/Abstract Full Text Show Details

in benzene

Irradiationsensitized (rose bengal) photooxygenation; Mechanism;

132

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With 2-hydroxyethanethiol in ethanol

T=30°C; 5 h; Product distribution;

Shinkai, Seiji; Yamashita, Takaharu; Kusano, Yumiko; Manabe, Osamu

Journal of the American Chemical Society, 1981 , vol. 103, # 8 p. 2070 - 2074 Title/Abstract Full Text View citing articles Show Details

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133

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With 2-hydroxyethanethiol; 3-methyltetra-acetylriboflavin in ethanol

T=30°C; 5 h; other reagents, reagents ratio; Product distributionRate constant;

Shinkai, Seiji; Yamashita, Takaharu; Kusano, Yumiko; Manabe, Osamu

Journal of the American Chemical Society, 1981 , vol. 103, # 8 p. 2070 - 2074 Title/Abstract Full Text View citing articles Show Details

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134

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A: 75.4% B: 80%

With potassium hydroxide in water

2.5 h; Heating;

Sokolov, S. D.; Rudchenko, V. F.; Turchin, K. F.; Pleshkova, A. P.; Zolotoi, A. B.; et al.

Doklady Chemistry, 1981 , vol. 258, p. 249 - 252 Dokl. Akad. Nauk SSSR Ser. Khim., 1981 , vol. 258, # 4 p. 906 - 911 Title/Abstract Full Text Show Details

135

Synthesize Find similar Rx-ID: 3571434 Find similar reactions

A: 70%

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With 2,6-dichloro-benzonitrile in benzene

0.5 h; Heating;

Baldoli, Clara; Beccalli, Egle M.; Licandro, Emanuela; Marchesini, Alessandro

Gazzetta Chimica Italiana, 1981 , vol. 111, # 7/8 p. 347 - 350 Title/Abstract Full Text Show Details

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136

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Rx-ID: 3763694 Find similar reactions

Chawla, H. M.; Chakrabarty, Kakoli; Prakash, Anil; Chibber, S. S.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1981 , vol. 20, # 6 p. 507 - 508 Title/Abstract Full Text Show Details

Irradiationsensitized (rose bengal) photooxygenation; Mechanism;

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137

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in benzene

Irradiationsensitized (rose bengal) photooxygenation;

Chawla, H. M.; Chakrabarty, Kakoli; Prakash, Anil; Chibber, S. S.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1981 , vol. 20, # 6 p. 507 - 508 Title/Abstract Full Text Show Details

Chawla, H. M.; Chakrabarty, Kakoli; Prakash, Anil; Chibber, S. S.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1981 , vol. 20, # 6 p. 507 - 508 Title/Abstract Full Text Show Details

in benzene

Irradiationsensitized (rose bengal) photooxygenation; Mechanism;

138

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Rx-ID: 19063338 Find similar reactions

Multi-step reaction with 2 steps 1: 93.6 percent / m-CPBA / CH2Cl2 / 12 h / Ambient temperature 2: 89.3 percent / Et3N / benzene / 3 h / Heating View Scheme

Baldoli, Clara; Beccalli, Egle M.; Licandro, Emanuela; Marchesini, Alessandro

Gazzetta Chimica Italiana, 1981 , vol. 111, # 7/8 p. 347 - 350 Title/Abstract Full Text Show Details

139

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Rx-ID: 19089681 Find similar reactions

Multi-step reaction with 2 steps 1: 35 percent / NH2OH*HCl / acetic acid; H2O / 8 h / 50 - 60 °C 2: 80 percent / KOH / H2O / 2.5 h / Heating View Scheme

Sokolov, S. D.; Rudchenko, V. F.; Turchin, K. F.; Pleshkova, A. P.; Zolotoi, A. B.; et al.

Doklady Chemistry, 1981 , vol. 258, p. 249 - 252 Dokl. Akad. Nauk SSSR Ser. Khim., 1981 , vol. 258, # 4 p. 906 - 911 Title/Abstract Full Text Show Details

140

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Multi-step reaction with 3 steps 1: 45.8 percent / SO2Cl2, azodiisobutyronitrile / 5.5 h / Heating 2: 35 percent / NH2OH*HCl / acetic acid; H2O / 8 h / 50 - 60 °C 3: 80 percent / KOH / H2O / 2.5 h / Heating

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Rx-ID: 19102519 Find similar reactions

Sokolov, S. D.; Rudchenko, V. F.; Turchin, K. F.; Pleshkova, A. P.; Zolotoi, A. B.; et al.

Doklady Chemistry, 1981 , vol. 258, p. 249 - 252 Dokl. Akad. Nauk SSSR Ser. Khim., 1981 , vol. 258, # 4 p. 906 - 911 Title/Abstract Full Text Show Details

View Scheme

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141

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Rx-ID: 1502443 Find similar reactions

A: 8% B: 1% C: 24% D: 4%

Fisera, L.; Kovac, J.; Poliacikova, J.; Lesko, J.

Monatshefte fuer Chemie, 1980 , vol. 111, p. 909 - 920 Title/Abstract Full Text View citing articles Show Details

in toluene

1) 60 deg C, 18 h, 2) 10 d, 25 deg C; Further byproducts given;

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142

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A: 16% B: 17% C: 16%

With N(Et)4ClO4 in acetonitrile

T=20°C; 0.0833333 h; Hg-cathode; Title compound not separated from byproducts;

Kistenbruegger, Lothar; Mischke, Peter; Voss, Juergen; Wiegand, Gabriele

Liebigs Annalen der Chemie, 1980 , # 3 p. 461 - 471 Title/Abstract Full Text Show Details

A: 16% B: 17% C: 16%

With N(Et)4ClO4 in acetonitrile

T=20°C; 0.0833333 h; Hg-cathode; Title compound not separated from byproducts;

Kistenbruegger, Lothar; Mischke, Peter; Voss, Juergen; Wiegand, Gabriele

Liebigs Annalen der Chemie, 1980 , # 3 p. 461 - 471 Title/Abstract Full Text Show Details

143

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A: 52% B: 3.3% E: 0.6%

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With oxygen in dichloromethane

Irradiationeffect of dye sensitizer; Product distributionMechanism;

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Kato, Hiroshi; Tani, Kazue; Kurumisawa, Haruki; Tamura, Yoshiko

Chemistry Letters, 1980 , p. 717 - 720 Title/Abstract Full Text Show Details

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144

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Rx-ID: 3737361 Find similar reactions

A: 16% B: 15% C: 16%

With N(Et)4ClO4

T=20°C; 0.0833333 h; Hg-cathode;

Kistenbruegger, Lothar; Mischke, Peter; Voss, Juergen; Wiegand, Gabriele

Liebigs Annalen der Chemie, 1980 , # 3 p. 461 - 471 Title/Abstract Full Text Show Details

145

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Rx-ID: 528914 Find similar reactions

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Edward; Nielsen

Journal of the Chemical Society, 1959 , p. 2327,2328,2330 Full Text Show Details

T=100°C;

146

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Rx-ID: 5690917 Find similar reactions

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Hurd; Prapas

Journal of the American Chemical Society, 1958 , vol. 80, p. 6053,6054,6055 Full Text View citing articles Show Details

T=165°C; Produkt 5:CO2;

147

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Rx-ID: 370453 Find similar reactions

With sodium hydroxide

Garg et al.

Agra University Journal of Research, Science, 1957 , vol. 6, p. 19,22 Full Text Show Details

148

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Rx-ID: 51639 Find similar reactions

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Huenig; Peilstoecker

Justus Liebigs Annalen der Chemie, 1955 , vol. 598, p. 105,108 Full Text Show Details

T=40°C; pH 3.3; Rate constant;

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149

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Wenuss-Danilowa; Pawlowa

Zhurnal Obshchei Khimii, 1949 , vol. 19, p. 1755,1759 Chem.Abstr., 1950 , p. 3472 Full Text Show Details

150

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Rx-ID: 396877 Find similar reactions

With boric acid; oxalic acid

T=100°C;

Kroehnke

Chemische Berichte, 1947 , vol. 80, p. 298,310 Full Text View citing articles Show Details

151

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Rx-ID: 7918958 Find similar reactions

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Kroehnke

Chemische Berichte, 1947 , vol. 80, p. 298,310 Full Text View citing articles Show Details

152

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Multi-step reaction with 2 steps 1: ethanol

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Rx-ID: 22299869 Find similar reactions

Kroehnke

Chemische Berichte, 1947 , vol. 80, p. 298,310

2: oxalic acid-dihydrate; boric acid / 100 °C View Scheme

Full Text View citing articles Show Details

153

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Rx-ID: 22307233 Find similar reactions

Multi-step reaction with 2 steps 1: aqueous ethanol 2: oxalic acid-dihydrate; boric acid / 100 °C View Scheme

Kroehnke

Chemische Berichte, 1947 , vol. 80, p. 298,310 Full Text View citing articles Show Details

154

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Rx-ID: 22308881 Find similar reactions

Multi-step reaction with 2 steps 1: aq.-ethanolic alkaline solution 2: oxalic acid-dihydrate; boric acid / 100 °C View Scheme

Kroehnke

Chemische Berichte, 1947 , vol. 80, p. 298,310 Full Text View citing articles Show Details

155

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Multi-step reaction with 2 steps 1: aqueous ethanol 2: oxalic acid-dihydrate; boric acid / 100 °C View Scheme

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Rx-ID: 22309287 Find similar reactions

Kroehnke

Chemische Berichte, 1947 , vol. 80, p. 298,310 Full Text View citing articles Show Details

156

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Rx-ID: 5931662 Find similar reactions

Iselin; Zeller

Helvetica Chimica Acta, 1946 , vol. 29, p. 1510 Full Text Show Details

157

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Rx-ID: 5931664 Find similar reactions

Blanchard et al.

Journal of Biological Chemistry, 1946 , vol. 163, p. 142 Full Text Show Details

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158

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Rx-ID: 5931668 Find similar reactions

MacMahon; Srivastava

Journal of the Indian Chemical Society, 1946 , vol. 23, p. 262 Current Science, 1946 , vol. 15, p. 249 Chem.Abstr., 1947 , p. 1921 Full Text Show Details

Gluehlampenlicht.Irradiation;

159

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Eskola

Annales Academiae Scientiarum Fennicae, Series A2: Chemica, 1946 , # 18 p. 11 Chem.Abstr., 1947 , p. 949 Full Text Show Details

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160

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Cordier; Moreau

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1942 , vol. 214, p. 621 Full Text View citing articles Show Details

161

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Rx-ID: 6682968 Find similar reactions

Hurd; McNamee; Green

Journal of the American Chemical Society, 1939 , vol. 61, p. 2979 Full Text View citing articles Show Details

162

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Rx-ID: 8258729 Find similar reactions

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Lutz; Smith

Journal of the American Chemical Society, 1939 , vol. 61, p. 1465,1468, 1474 Full Text View citing articles Show Details

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163

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Rx-ID: 8259801 Find similar reactions

Lutz; Smith

Journal of the American Chemical Society, 1939 , vol. 61, p. 1465,1468, 1474 Full Text View citing articles Show Details

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164

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Lutz; Smith

Journal of the American Chemical Society, 1939 , vol. 61, p. 1465,1468, 1474 Full Text View citing articles Show Details

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165

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Randall; Benger; Groocock

Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1938 , vol. 165, p. 439 Chem. Zentralbl., 1939 , vol. 110, # I p. 911 Full Text Show Details

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166

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Randall; Benger; Groocock

Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1938 , vol. 165, p. 439 Chem. Zentralbl., 1939 , vol. 110, # I p. 911 Full Text Show Details

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167

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Randall; Benger; Groocock

Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1938 , vol. 165, p. 439 Chem. Zentralbl., 1939 , vol. 110, # I p. 911

Full Text Show Details

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168

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Randall; Benger; Groocock

Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1938 , vol. 165, p. 439 Chem. Zentralbl., 1939 , vol. 110, # I p. 911 Full Text Show Details

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169

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Rx-ID: 8259828 Find similar reactions

Burton; Shoppee

Journal of the Chemical Society, 1937 , p. 546,548 Journal of the Chemical Society, 1939 , p. 1408,1415 Full Text Show Details

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170

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Schoeberl; Berninger; Harren

Chemische Berichte, 1934 , vol. 67, p. 1545,1550 Full Text Show Details

Schoeberl; Eck

Justus Liebigs Annalen der Chemie, 1936 , vol. 522, p. 97,107 Full Text Show Details

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171

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Rx-ID: 670705 Find similar reactions

Oxydation an Eisen-Anoden;

Tommila

Annales Academiae Scientiarum Fennicae, Series A, 1936 , vol. 46, # 6 p. 83 Chem. Zentralbl., 1937 , vol. 108, # II p. 204 Full Text Show Details

Oxydation an Nickel-Anoden;

Tommila

Annales Academiae Scientiarum Fennicae, Series A, 1936 , vol. 46, # 6 p. 83 Chem. Zentralbl., 1937 , vol. 108, # II p. 204 Full Text Show Details

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172

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Kohler et al.

Journal of the American Chemical Society, 1936 , vol. 58, p. 264,266 Full Text View citing articles Show Details

173

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Rx-ID: 8258731 Find similar reactions

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Lutz; Stuart

Journal of the American Chemical Society, 1936 , vol. 58, p. 1885,1887, 1889 Journal of the American Chemical Society, 1939 , vol. 61, p. 1465,1467, 1469 Full Text View citing articles Show Details

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174

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Rx-ID: 8258737 Find similar reactions

Lutz; Stuart

Journal of the American Chemical Society, 1936 , vol. 58, p. 1885,1887, 1889 Journal of the American Chemical Society, 1939 , vol. 61, p. 1465,1467, 1469 Full Text View citing articles Show Details

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175

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Lutz; Stuart

Journal of the American Chemical Society, 1936 , vol. 58, p. 1885,1887, 1889 Journal of the American Chemical Society, 1939 , vol. 61, p. 1465,1467, 1469

Full Text View citing articles Show Details

176

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Rx-ID: 8258733 Find similar reactions

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Kohler, Tishler

Journal of the American Chemical Society, 1935 , vol. 57, p. 217,222 Full Text View citing articles Show Details

anschliessendes Behandeln mit wss. Na2CO3-Loesung;

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177

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Rx-ID: 266851 Find similar reactions

Schoeberl; Berninger; Harren

Chemische Berichte, 1934 , vol. 67, p. 1545,1550 Full Text Show Details

Schuetteln der mit Kupfer(II)-chlorid versetzten Reaktionsloesung mit Sauerstoff;

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178

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Ainley; Robinson

Journal of the Chemical Society, 1934 , p. 1508,1517

Full Text Show Details

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179

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Rx-ID: 5958132 Find similar reactions

Lutz et al.

Journal of the American Chemical Society, 1934 , vol. 56, p. 1980,1986 Full Text View citing articles Show Details

T=0°C; Erhitzen des Reaktionsprodukts mit Wasser;

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180

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Rx-ID: 7061834 Find similar reactions

Kohler, Barnes

Journal of the American Chemical Society, 1934 , vol. 56, p. 211,214 Full Text Show Details

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181

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tautomer(ic) mixture;

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Lutz et al.

Journal of the American Chemical Society, 1934 , vol. 56, p. 1980,1986 Full Text View citing articles Show Details

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182

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Rx-ID: 7447240 Find similar reactions

Lutz et al.

Journal of the American Chemical Society, 1934 , vol. 56, p. 1980,1986 Full Text View citing articles Show Details

tautomer(ic) mixture;

183

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Rx-ID: 7919321 Find similar reactions

Lutz et al.

Journal of the American Chemical Society, 1934 , vol. 56, p. 1980,1986 Full Text View citing articles Show Details

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184

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cis-β-bromo-α-phenyl-β-benzoyl-acrylic acid;

Kohler, Peterson, Bickel

Journal of the American Chemical Society, 1934 , vol. 56, p. 2000,2005 Full Text Show Details

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185

Synthesize Find similar Rx-ID: 8259810 Find similar reactions

Tommila

Annales Academiae Scientiarum Fennicae, Series A, 1934 , vol. 39, # 11 p. 60 Chem. Zentralbl., 1934 , vol. 105, # II p. 1758 Full Text Show Details

Oxydation in alkal. Loesung;

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186

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Tommila

Annales Academiae Scientiarum Fennicae, Series A, 1934 , vol. 39, # 11 p. 60 Chem. Zentralbl., 1934 , vol. 105, # II p. 1758 Full Text Show Details

Oxydation in saurer oder alkal. Loesung;

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187

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Henze; Mueller

Hoppe-Seyler's Zeitschrift fuer Physiologische Chemie, 1931 , vol. 200, p. 106 Full Text Show Details

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188

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With sodium methylate

Kohler, Addinall

Journal of the American Chemical Society, 1930 , vol. 52, p. 1590,1602 Full Text Show Details

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189

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Rx-ID: 8287981 Find similar reactions

Kohler, Addinall

Journal of the American Chemical Society, 1930 , vol. 52, p. 1590,1602 Full Text Show Details

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190

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Rx-ID: 26086952 Find similar reactions

Kinetics; byproducts: CO2, benzoic acid; Irradiation (UV/VIS); in light;

Purakyastha, R. M.; Ghosh, I. Ch.

Z. phys. Ch., 1930 , vol. B 7, p. 285 - 287 Full Text Show Details

Purakyastha, R. M.

Journal of the Indian Chemical Society, 1929 , vol. 6, p. 375 Full Text Show Details

Purakyastha, R. M.

Journal of the Indian Chemical Society, 1929 , vol. 6, p. 380 Full Text Show Details

Purakyastha, R. M.

Journal of the Indian Chemical Society, 1930 , vol. 7, p. 991 Full Text Show Details

Bacher, F.

Chemische Reaktionen organischer Koerper im ultravioletten Licht und im Licht der Sonne in: E. Abderhalden, Handbuch der biologischen Arbeitsmethoden Abt. 1, Tl. 2, II, 1, Berlin 1929, S. 1677 Full Text Show Details

Kinetics; byproducts: CO2, benzoic acid; Irradiation (UV/VIS); in light;

Gmelin Handbook: Br: MVol., 4.1, page 134 - 140 Full Text Show Details

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191

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Fuchs

Monatshefte fuer Chemie, 1929 , vol. 53/54, p. 443 Full Text View citing articles Show Details

bei der thermischen Zersetzung;

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192

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Baker

Journal of the Chemical Society, 1929 , p. 2260 Full Text Show Details

T=100°C;

193

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Rx-ID: 8279352 Find similar reactions

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Baker

Journal of the Chemical Society, 1929 , p. 2260 Full Text Show Details

194

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Rx-ID: 330879 Find similar reactions

Kohler, Blatt

Journal of the American Chemical Society, 1928 , vol. 50, p. 508 Full Text Show Details

bei der Ozonspaltung;

195

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Rx-ID: 5688084 Find similar reactions

Kohler

Journal of the American Chemical Society, 1928 , vol. 50, p. 224 Full Text Show Details

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196

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Skraup; Schwamberger

Justus Liebigs Annalen der Chemie, 1928 , vol. 462, p. 147 Full Text Show Details

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197

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Skraup; Schwamberger

Justus Liebigs Annalen der Chemie, 1928 , vol. 462, p. 147 Full Text Show Details

198

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Rx-ID: 7918957 Find similar reactions

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Barre

Annales de Chimie (Cachan, France), 1928 , vol. <10> 9, p. 236 Full Text Show Details