2-Oxo-2-phenylacetic acid (Phenylglyoxylic Acid) by Asch

Reaxys

PubChem

eMolecules

Reactions (272)

Yield

Substances (1)

Citations (298)

Conditions

References

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Rx-ID: 39077 Find similar reactions

With sodium hydroxide; potassium permanganate

T=70°C;

Hurd; McNamee; Green

Journal of the American Chemical Society, 1939 , vol. 61, p. 2979 Full Text View citing articles Show Details

Stage #1: With potassium permanganate; sodium hydroxide in water

T=50°C; 0.333333 h; Stage #2: With hydrogenchloride in water

Jin, Zhe; Yang, Liu; Liu, Si-Jie; Wang, Jian; Li, Shuo; Lin, Huang-Quan; Wan, David Chi Cheong; Hu, Chun

Archives of Pharmacal Research, 2010 , vol. 33, # 10 p. 1641 - 1649 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 5 steps 1.1: tetrabutylammomium bromide; hydrogen bromide; dihydrogen peroxide / water / 12.5 h / 90 °C 2.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C 3.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 4.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 5.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 5.2: 5 h / 25 - 90 °C View Scheme

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 5 steps 1.1: tetrabutyl-ammonium chloride; hydrogen bromide; dihydrogen peroxide / water / 11.5 h / 90 °C 2.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C 3.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 4.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 5.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 5.2: 5 h / 25 - 90 °C View Scheme

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 5 steps 1.1: hydrogen bromide; dihydrogen peroxide / cyclohexane; water / 7.5 h / 90 °C 2.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C 3.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 4.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 5.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 5.2: 5 h / 25 - 90 °C View Scheme

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 6 steps 1.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.33 h 1.2: 6.5 h / 25 - 90 °C 2.1: hydrogen bromide; dihydrogen peroxide / water / 4.5 h / 25 - 90 °C 3.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C 4.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 5.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 6.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 6.2: 5 h / 25 - 90 °C View Scheme

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 6 steps 1.1: tetrabutylammomium bromide; hydrogen bromide; dihydrogen peroxide / water / 12.5 h / 90 °C 2.1: hydrogen bromide; dihydrogen peroxide / water / 4.5 h / 25 - 90 °C 3.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C 4.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 5.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 6.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 6.2: 5 h / 25 - 90 °C View Scheme

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 6 steps 1.1: hydrogen bromide; dihydrogen peroxide / cyclohexane; water / 7.5 h / 90 °C 2.1: hydrogen bromide; dihydrogen peroxide / water / 4.5 h / 25 - 90 °C 3.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C 4.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 5.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 6.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 6.2: 5 h / 25 - 90 °C View Scheme

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: dihydrogen peroxide; Mg10Al2(OH)24CO3 / water; acetonitrile; benzene / 25 - 60 °C 2: N-Bromosuccinimide; ammonium cerium (IV) nitrate; water / acetonitrile / 4 h / 30 °C 3: dihydrogen peroxide; hydrogen bromide / water / 5 h / 25 - 65 °C View Scheme

Peng; Li; Rong; Dong; Tai

Asian Journal of Chemistry, 2015 , vol. 27, # 1 p. 78 - 80 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: dihydrogen peroxide; Mg-Al hydrotalcite / hexane / 60 °C 2: ammonium cerium (IV) nitrate; N-Bromosuccinimide / acetonitrile; water / 50 °C 3: dihydrogen peroxide; hydrogen bromide / water / |Reflux View Scheme

Hefei University of Technology; China Petroleum and Chemical Corporation; Peng, Xinhua; Wu, Xueping; Zheng, Xuegen; Rong, Yuan; Jiang, Ou; Zhu, Sijiu; Peng, Chengjun; Xu, Haoshu; Xiao, Fu

Patent: CN105330533 A, 2016 ; Title/Abstract Full Text Show Details

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Rx-ID: 716475 Find similar reactions

87%

With pyridine; selenium(IV) oxide

T=120°C; 18 h; Inert atmosphere;

Zhuang, Jing; Wang, Changqing; Xie, Fang; Zhang, Wanbin

Tetrahedron, 2009 , vol. 65, # 47 p. 9797 - 9800 Title/Abstract Full Text View citing articles Show Details

85%

With pyridine; selenium(IV) oxide

T=120°C; 18 h; Hide Experimental Procedure

Wu, Quanquan; Liu, Shulei; Wang, Fangyuan; Li, Qingqing; Cheng, Kangli; Li, Juan; Jiang, Jun

Synlett, 2015 , vol. 26, # 17 art. no. ST-2015-W0427-L, p. 2442 - 2446 Title/Abstract Full Text View citing articles Show Details

Typical Experimental Procedure for Preparation of α-keto esters

General procedure: Following reported procedures:1-2 a mixture of acetophenone (1.2 g, 10.0 mmol) andselenium dioxide (2.2 g, 20.0 mmol) in dry pyridine (5.0 mL) was stirred at 120 oCunder nitrogen for 18 h. After the disappearance of acetophenone detected by TLC,the mixture was filtrated and the organic phase was collected, followed by the removeof solvent by evaporation. Then 2M sodium hydroxide solution was added to theresidue and the resulting mixture was extracted with ethyl acetate (3*15 mL). Theaqueous phase was collected and concentrated hydrochloric acid was added dropwiseuntil pH= 1-2. The mixture was filtrated and the 2-oxo-2-phenylacetic acid wasobtained as yellow solid in 85percent yield. 83%

With pyridine; selenium(IV) oxide

T=120°C; 18 h;

Kober, Ute; Knölker, Hans-Joachim

Synlett, 2015 , vol. 26, # 11 art. no. ST-2015-B0162-L, p. 1549 - 1552 Title/Abstract Full Text View citing articles Show Details

55%

With hydrogen iodide in dimethyl sulfoxide

T=115°C; 24 h;

Xiang, Jia-Chen; Cheng, Yan; Wang, Miao; Wu, Yan-Dong; Wu, An-Xin

Organic Letters, 2016 , vol. 18, # 17 p. 4360 - 4363 Title/Abstract Full Text Show Details

32%

With copper(l) iodide; oxygen; acetic acid in dimethyl sulfoxide

T=120°C;

Du, Juan; Zhang, Xiuli; Sun, Xi; Wang, Lei

Chemical Communications, 2015 , vol. 51, # 21 p. 4372 - 4375 Title/Abstract Full Text View citing articles Show Details

With potassium permanganate; water; potassium carbonate

Gluecksmann

Monatshefte fuer Chemie, 1890 , vol. 11, p. 248 Full Text Show Details

Claus; Neukranz

Journal fuer Praktische Chemie (Leipzig), 1891 , vol. <2> 44, p. 80 Full Text Show Details

With pyridine; selenium(IV) oxide

Jerchel et al.

Justus Liebigs Annalen der Chemie, 1958 , vol. 613, p. 153,155, 162 Full Text Show Details

oxidation;

Pontillo, Joseph; Guo, Zhiqiang; Wu, Dongpei; Struthers, R. Scott; Chen, Chen

Bioorganic and Medicinal Chemistry Letters, 2005 , vol. 15, # 19 p. 4363 - 4366 Title/Abstract Full Text View citing articles Show Details

With pyridine; selenium(IV) oxide

Kim, Minyoung; Park, Jihye; Sharma, Satyasheel; Kim, Aejin; Park, Eonjeong; Kwak, Jong Hwan; Jung, Young Hoon; Kim, In Su

Chemical Communications, 2013 , vol. 49, # 9 p. 925 - 927 Title/Abstract Full Text View citing articles Show Details

Park, Jihye; Kim, Minyoung; Sharma, Satyasheel; Park, Eonjeong; Kim, Aejin; Lee, Sang Hwi; Kwak, Jong Hwan; Jung, Young Hoon; Kim, In Su

Chemical Communications, 2013 , vol. 49, # 16 p. 1654 - 1656 Title/Abstract Full Text View citing articles Show Details

With selenium(IV) oxide

Yang, Zhiyong; Chen, Xiang; Liu, Jidan; Gui, Qingwen; Xie, Kai; Li, Miaomiao; Tan, Ze

Chemical Communications, 2013 , vol. 49, # 15 p. 1560 - 1562 Title/Abstract Full Text View citing articles Show Details

With pyridine; selenium(IV) oxide

Sharma, Satyasheel; Kim, Aejin; Park, Eonjeong; Park, Jihye; Kim, Minyoung; Kwak, Jong Hwan; Lee, Sang Hwi; Jung, Young Hoon; Kim, In Su

Advanced Synthesis and Catalysis, 2013 , vol. 355, # 4 p. 667 - 672 Title/Abstract Full Text View citing articles Show Details

With pyridine; selenium(IV) oxide

T=110°C; 4 h; Inert atmosphere;

Yao, Jinzhong; Feng, Ruokun; Wu, Zaihong; Liu, Zhanxiang; Zhang, Yuhong

Advanced Synthesis and Catalysis, 2013 , vol. 355, # 8 p. 1517 - 1522 Title/Abstract Full Text View citing articles Show Details

With potassium permanganate; potassium hydoxide in water

Jiang, Lei; Ma, Nan; Qiu, Jun; Zhang, Ronghua

Journal of Chemical Research, 2013 , vol. 37, # 3 p. 143 - 145 Title/Abstract Full Text View citing articles Show Details

With pyridine; selenium(IV) oxide

Johannes, Eugen; Horbert, Rebecca; Schlosser, Joachim; Schmidt, Dorian; Peifer, Christian

Tetrahedron Letters, 2013 , vol. 54, # 31 p. 4067 - 4072 Title/Abstract Full Text View citing articles Show Details

With selenium(IV) oxide

Schlenk technique;

Liu, Jie; Fan, Chao; Yin, Hongyu; Qin, Chu; Zhang, Guoting; Zhang, Xu; Yi, Hong; Lei, Aiwen

Chemical Communications, 2014 , vol. 50, # 17 p. 2145 - 2147 Title/Abstract Full Text View citing articles Show Details

With selenium(IV) oxide

Schlenk technique;

Ma, Yiyang; Yan, Zhiyuan; Bian, Changliang; Li, Ke; Zhang, Xiaowen; Wang, Mengfan; Gao, Xinlong; Zhang, Heng; Lei, Aiwen

Chemical Communications, 2015 , vol. 51, # 52 p. 10524 - 10527 Title/Abstract Full Text View citing articles Show Details

With pyridine; selenium(IV) oxide

Zhang, Liang; Wang, Zhe; Guo, Peiyu; Sun, Wei; Li, Ya-Min; Sun, Meng; Hua, Chengwen

Tetrahedron Letters, 2016 , vol. 57, # 23 p. 2511 - 2514 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 33905192 Find similar reactions

90.1%

With hydrogen bromide; dihydrogen peroxide in water

T=25 - 65°C; 5 h; Reagent/catalystTime;

Peng; Li; Rong; Dong; Tai

Asian Journal of Chemistry, 2015 , vol. 27, # 1 p. 78 - 80 Title/Abstract Full Text View citing articles Show Details

79.3%

With hydrogen bromide; dihydrogen peroxide in water

Reflux; Temperature; Hide Experimental Procedure

Hefei University of Technology; China Petroleum and Chemical Corporation; Peng, Xinhua; Wu, Xueping; Zheng, Xuegen; Rong, Yuan; Jiang, Ou; Zhu, Sijiu; Peng, Chengjun; Xu, Haoshu; Xiao, Fu

Patent: CN105330533 A, 2016 ; Location in patent: Paragraph 0039-0040 ; Title/Abstract Full Text Show Details

10 mmol of styrene were transferred to the reactor, and 10 mL of n-hexane, 0.10 g of water-soluble Stone, slow dropping 2. 4mL hydrogen peroxide, drop finished, the slow heating temperature to 60 ° C reaction to styrene conversion is complete, After cooling to room temperature, hydrotalcite was separated, followed by the addition of 10 mL of a mixed solution of acetonitrile and water, 0.6 g of ammonium cerium nitrate, L.Og N-bromosuccinimide, control 50 ° C reaction ended, vacuum distillation separation of a-hydroxy acetophenone. Will be separated Of a - light acetophenone was added to a reactor containing 10 mL of water, and under continual stirring, 10 mmol of 48percent hydrobromide Acid slowly dropping 100_0130percent hydrogen peroxide, add slowly after warming up to the end of the reflux reaction. The organic phase was separated to room temperature Phase, the total yield of benzoylformic acid was 79.3percent after distillation, 83 %Chromat.

Stage #1: With tetrabutylammomium bromide; hydrogen bromide in water

0.0166667 h;

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985

Stage #2: With dihydrogen peroxide in water

T=25 - 90°C; 5 h;

Title/Abstract Full Text View citing articles Show Details

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A: 91% B: 99%

With methyl 3,5-bis((1H-1,2,4-triazol-1-yl)methyl)benzoate; oxygen; sodium acetate; niobium bromide

T=120°C; P=760.051 - 912.061 Torr; 48 h; chemoselective reaction;

Urgoitia, Garazi; Sanmartin, Raul; Herrero, Mara Teresa; Domnguez, Esther

Advanced Synthesis and Catalysis, 2016 , vol. 358, # 7 p. 1150 - 1156 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: sodium hydrogencarbonate; ruthenium trichloride; potassium peroxymonosulfate / acetonitrile; water; ethyl acetate / 0.3 h 2: Fe[ClO4]2·6H2O; TMAOH*5H2O / acetonitrile; water / 12 h / |Inert atmosphere View Scheme

Allpress, Caleb J.; Grubel, Katarzyna; Szajna-Fuller, Ewa; Arif, Atta M.; Berreau, Lisa M.

Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 659 - 668 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 42180258 Find similar reactions

A: 11%

With methyl 3,5-bis((1H-1,2,4-triazol-1-yl)methyl)benzoate; oxygen; sodium acetate; niobium bromide

T=120°C; P=760.051 - 912.061 Torr; 24 h; chemoselective reaction;

Urgoitia, Garazi; Sanmartin, Raul; Herrero, Mara Teresa; Domnguez, Esther

Advanced Synthesis and Catalysis, 2016 , vol. 358, # 7 p. 1150 - 1156 Title/Abstract Full Text View citing articles Show Details

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With selenium(IV) oxide

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Meena, Samdarshi; Singh, Rohit; Vishwakarma, Ram A.; Aga, Mushtaq A.; Jain, Shreyans K.

Tetrahedron Letters, 2016 , vol. 57, # 33 p. 3715 - 3717 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 43022585 Find similar reactions

With selenium(IV) oxide

Meena, Samdarshi; Singh, Rohit; Vishwakarma, Ram A.; Aga, Mushtaq A.; Jain, Shreyans K.

Tetrahedron Letters, 2016 , vol. 57, # 33 p. 3715 - 3717 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 43480099 Find similar reactions

With oxovanadium(IV) sulfate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen in acetonitrile

T=80°C; P=3000.3 Torr; 2 h;

Wang, Min; Lu, Jianmin; Zhang, Xiaochen; Li, Lihua; Li, Hongji; Luo, Nengchao; Wang, Feng

ACS Catalysis, 2016 , vol. 6, # 9 p. 6086 - 6090 Title/Abstract Full Text Show Details

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Rx-ID: 41527 Find similar reactions

With sodium hydroxide

Bouveault

Bulletin de la Societe Chimique de France, 1896 , vol. <3> 15, p. 1017 Full Text Show Details

With sodium hydroxide in tetrahydrofuran

Hewawasam, Piyasena; Erway, Matthew; Thalody, George; Weiner, Harvey; Boissard, Christopher G.; Gribkoff, Valentin K.; Meanwell, Nicholas A.; Lodge, Nicholas; Starrett, Jr, John E.

Bioorganic and Medicinal Chemistry Letters, 2002 , vol. 12, # 7 p. 1117 - 1120 Title/Abstract Full Text View citing articles Show Details

With water; sodium hydroxide

T=20°C;

Moon, Jong Taik; Jeon, Ji Young; Park, Hang Ah; Noh, Young-Soo; Lee, Kyung-Tae; Kim, Jungahn; Choo, Dong Joon; Lee, Jae Yeol

Bioorganic and Medicinal Chemistry Letters, 2010 , vol. 20, # 2 p. 734 - 737 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide in methanol

T=0°C; 0.5 h; Hide Experimental Procedure

Mahaveer; Kulkarni; Radakrishna; Chandrashekar; Achaiah

Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2013 , vol. 52, # 6 p. 818 - 823 Title/Abstract Full Text View citing articles Show Details

Synthesis of aryl a-keto acid 3a-c

General procedure: Keto ester 2a-c was dissolved in MeOH at 0°C and 4N NaOH was added with stirring over 30 min. Upon completion of reaction, MeOH was removed. Reaction mixture was then neutralized with 1N HCl. The desired compound was extracted into EtOAc and dried over anhydrous Na2SO423. With water; sodium hydroxide

T=20°C; 2 h;

Weng, Jian-Quan; Deng, Qiao-Man; Wu, Liang; Xu, Kai; Wu, Hao; Liu, Ren-Rong; Gao, Jian-Rong; Jia, Yi-Xia

Organic Letters, 2014 , vol. 16, # 3 p. 776 - 779 Title/Abstract Full Text View citing articles Show Details

With water; sodium hydroxide in tetrahydrofuran

6 h; Reflux;

Shirai, Tomohiko; Ito, Hajime; Yamamoto, Yasunori

Angewandte Chemie - International Edition, 2014 , vol. 53, # 10 p. 2658 - 2661 Angew. Chem., 2014 , vol. 126, # 10 p. 2696 - 2699,4 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide

Inert atmosphere;

Enders, Dieter; Stoeckel, Bianca A.; Rembiak, Andreas

Chemical Communications, 2014 , vol. 50, # 34 p. 4489 - 4491 Title/Abstract Full Text View citing articles Show Details

With water; sodium hydroxide

T=20°C; 4 h;

Kim, Kyung Ju; Choi, Min Ji; Shin, Ji-Sun; Kim, Minju; Choi, Hye-Eun; Kang, Seoung Mook; Jin, Jae Ho; Lee, Kyung-Tae; Lee, Jae Yeol

Bioorganic and Medicinal Chemistry Letters, 2014 , vol. 24, # 8 p. 1958 - 1962 Title/Abstract Full Text View citing articles Show Details

With water; lithium hydroxide hydrate in tetrahydrofuran

2 h; Hide Experimental Procedure

BOARD OF REGENTS OF THE UNIVERSITY OF TEXAS SYSTEM; READY, Joseph M.; NIJHAWAN, Deepak; GONZALES, Stephen S.; THEODOROPOULOS, Pano

Patent: WO2015/35051 A1, 2015 ; Location in patent: Page/Page column 263 ; Title/Abstract Full Text Show Details

Step 2 Lithium hydroxide (3 eq) was added to a solution of ester (1 eq) in 3 :3 : 1 THF/MeOH/H20 (2 M). A white precipitate formed and the reaction was finished in 2 hours. 1M HC1 was added until the reaction mixture became acidic. Then, the reaction mixture was extracted into EtOAc. The organic layer was washed with water and brine, dried with Na2S04, and concentrated. The residue was purified by flash chromatography (silica gel, 0→ 30percent EtOAc in hexanes) to give the carboxylic acid. ESI-MS (m/z): [M+H]+.

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Rx-ID: 67384 Find similar reactions

100%

With water; sodium hydroxide

Chiba, Shunsuke; Zhang, Line; Lee, Jian-Yuan

Journal of the American Chemical Society, 2010 , vol. 132, # 21 p. 7266 - 7267 Title/Abstract Full Text View citing articles Show Details

100%

With water; sodium hydroxide in dichloromethane

Zhang, Line; Lee, Jian-Yuan; Yamazaki, Naomi; Chiba, Shunsuke

Synlett, 2011 , # 15 art. no. D14511ST, p. 2167 - 2170 Title/Abstract Full Text View citing articles Show Details

40%

With water; scandium tris(trifluoromethanesulfonate) in methanol

T=30°C; Deacetylation; 24 h; Product distribution; Further Variations:Reagents;

Kajiro, Hiroshi; Mitamura, Shuichi; Mori, Atsunori; Hiyama, Tamejiro

Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 7 p. 1553 - 1560 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide

Baer; Kates

Journal of the American Chemical Society, 1945 , vol. 67, p. 1482 Full Text View citing articles Show Details

Corson; Sanborn; Van Ess

Journal of the American Chemical Society, 1930 , vol. 52, p. 1623,1626 Full Text Show Details

47 % Chromat.

With water; scandium tris(trifluoromethanesulfonate) in methanol

T=30°C; 96 h;

Kajiro, Hiroshi; Mitamura, Shuichi; Mori, Atsunori; Hiyama, Tamejiro

Tetrahedron Letters, 1999 , vol. 40, # 9 p. 1689 - 1692 Title/Abstract Full Text View citing articles Show Details

47 % Chromat.

With water; scandium tris(trifluoromethanesulfonate) in methanol

T=30°C; Hydrolysis; 96 h;

Kajiro, Hiroshi; Mitamura, Shuichi; Mori, Atsunori; Hiyama, Tamejiro

Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 7 p. 1553 - 1560 Title/Abstract Full Text View citing articles Show Details

With potassium hydroxide in ethanol; water

Chen, Chien-Tien; Bettigeri, Sampada; Weng, Shiue-Shien; Pawar, Vijay D.; Lin, Ya-Hui; Liu, Cheng-Yuan; Lee, Way-Zen

Journal of Organic Chemistry, 2007 , vol. 72, # 22 p. 8175 - 8185 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide in water

He, Ming-Hui; Su, Mei-Lin; Yu, Zhao-Hui; Chen, Guang-Xue; Zeng, Zhao-Hua; Yang, Jian-Wen

Chinese Chemical Letters, 2015 , vol. 26, # 1 p. 21 - 25 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 670742 Find similar reactions

98%

With sodium bromate in acetonitrile

52 h; Heating;

Al-Haq, Nazli; Sullivan, Alice C.; Wilson, John R. H.

Tetrahedron Letters, 2003 , vol. 44, # 4 p. 769 - 771 Title/Abstract Full Text View citing articles Show Details

96%

With oxalyl dichloride; methyl dodecyl sulfoxide; triethylamine in dichloromethane

T=-60 - 20°C; Swern oxidation;

Nishide, Kiyoharu; Ohsugi, Shin-Ichi; Fudesaka, Masato; Kodama, Sumiaki; Node, Manabu

Tetrahedron Letters, 2002 , vol. 43, # 29 p. 5177 - 5179 Title/Abstract Full Text View citing articles Show Details

96%

With oxalyl dichloride; methyl dodecyl sulfoxide; triethylamine in dichloromethane

T=-60 - 20°C; Swern oxidation;

Ohsugi, Shin-Ichi; Nishide, Kiyoharu; Oono, Keiji; Okuyama, Kazunori; Fudesaka, Masato; Kodama, Sumiaki; Node, Manabu

Tetrahedron, 2003 , vol. 59, # 42 p. 8393 - 8398 Title/Abstract Full Text View citing articles Show Details

95%

With oxygen; ascorbic acid in toluene

T=65°C; 4 h; Hide Experimental Procedure

COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH

Patent: US2006/167313 A1, 2006 ; Location in patent: Page/Page column 5 ; Title/Abstract Full Text Show Details

B.15:EXAMPLE 15 EXAMPLE 15 Method for oxidation of mandelic acid: Oxygen gas (25 ml min-1) was continuously bubbled through a solution of mandelic acid (5 mmol), polystyrene supported (4-nitro)tetra phenylporphinato nickel (II) (corresponding to 0.056 mol percent of metalloporphyrin) in toluene (30 ml). Ascorbic acid (15 mmol) was added to reaction mixture at intervals of 2.5 hours till maximum conversion of reactant to product was achieved). The reaction mixture was vigorously stirred at 65° C. and the progress of the reaction was monitored by TLC. After stirring the reaction mixture for 4 hrs, it was concentrated to half. Addition of equal volume of methanol precipitated the catalyst that was filtered and the filtrate was evaporated to dryness to give the product. The product was purified by column chromatography and characterized by physical constants and spectroscopic data (IR, 1H-NMR and mass spectra). Yield: 0.72 g (95percent). 91%

With 4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; toluene-4-sulfonic acid in dichloromethane

1) 0 deg C, 1 h, 2) r.t., 6 h;

Ma, Zhenkun; Bobbitt, James M.

Journal of Organic Chemistry, 1991 , vol. 56, # 21 p. 6110 - 6114 Title/Abstract Full Text View citing articles Show Details

90%

With hydrogenchloride; sodium hypobromide in dichloromethane; water

T=25°C; 5 h;

Chang, Hae Sung; Woo, Jae Chun; Lee, Kyoung Mo; Ko, Young Kwan; Moon, Surk-Sik; Kim, Dae-Whang

Synthetic Communications, 2002 , vol. 32, # 1 p. 31 - 36 Title/Abstract Full Text Show Details

90%

Stage #1: With titanium tetrachloride in chloroform

T=20°C; 1 h; Molecular sieve; Stage #2: With tert.-butylhydroperoxide in chloroform; toluene

24 h; Reflux; chemoselective reaction;

Shei, Chun-Tin; Chien, Hao-Lun; Sung, Kuangsen

Synlett, 2008 , # 7 p. 1021 - 1026 Title/Abstract Full Text View citing articles Show Details

86%

With C14H14N6O2; oxygen; sodium acetate; palladium diacetate

T=120°C; P=760.051 Torr; 72 h;

Urgoitia, Garazi; Maiztegi, Ainhoa; Sanmartin, Raul; Herrero, Mara Teresa; Domnguez, Esther

RSC Advances, 2015 , vol. 5, # 125 p. 103210 - 103217 Title/Abstract Full Text View citing articles Show Details

83%

With Fremy’s salt in water

168 h; pH 10.0;

Garcia-Raso, Angel; Deya, Pedro M.; Saa, Jose M.

Journal of Organic Chemistry, 1986 , vol. 51, # 22 p. 4285 - 4287 Title/Abstract Full Text View citing articles Show Details

82%

With [Pip*(O)][BF4] in water

12 h; Reflux;

Mamros, Audrey N.; Sharrow, Phillip R.; Weller, William E.; Luderer, Mark R.; Fair, Justin D.; Pazehoski, Kristina O.; Luderer, Matthew R.

Arkivoc, 2011 , vol. 2011, # 5 p. 23 - 33 Title/Abstract Full Text View citing articles Show Details

81%

With potassium hydroxide; potassium permanganate

T=25°C; 6 h; other mandelic acids; activation parameters for the oxidation <ΔH(excit.), ΔS(excit.)>; Rate constantMechanism;

Lee, Donald G.; Chen, Tao

Journal of the American Chemical Society, 1993 , vol. 115, # 24 p. 11231 - 11236 Title/Abstract Full Text View citing articles Show Details

70%

With potassium bromate; perchloric acid; mercury(II) diacetate in acetic acid

Sankaran, K. R.; Srinivasan, Vangalur S.

T=50°C; other temperatures; E(activ.), ΔH(excit.), ΔS(excit.), Γ(excit.), various conc. of substrate and HClO4; KineticsMechanismThermodynamic data;

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1989 , vol. 28, # 12 p. 1093 - 1095 Title/Abstract Full Text Show Details

70%

With potassium bromate; perchloric acid; mercury(II) diacetate in acetic acid

T=50°C;

Sankaran, K. R.; Srinivasan, Vangalur S.

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1989 , vol. 28, # 12 p. 1093 - 1095 Title/Abstract Full Text Show Details

70%

With dinitrogen tetroxide impregnated on activated charcoal in dichloromethane

T=20°C; 10 h;

Iranpoor, Nasser; Firouzabadi, Habib; Pourali, Ali Reza

Synthetic Communications, 2005 , vol. 35, # 11 p. 1527 - 1533 Title/Abstract Full Text View citing articles Show Details

50%

With potassium hydroxide; potassium permanganate

T=0°C; 0.5 h;

Lee, Donald G.; Chen, Tao

Journal of Organic Chemistry, 1991 , vol. 56, # 18 p. 5341 - 5345 Title/Abstract Full Text View citing articles Show Details

46%

With potassium permanganate

T=-20 - -18°C; 0.5 h;

Bandyopadhyay; Bagchi; Podder; Moitra

Journal of the Indian Chemical Society, 1989 , vol. 66, # 4 p. 239 - 240 Title/Abstract Full Text View citing articles Show Details

39%

With aqua(2,2'-bipyridine)(2,2':6',2''-terpyridine)ruthenium(II)(2+) in phosphate buffer

pH=7.2; 5 h; Electrolysis;

Geneste, Florence; Moinet, Claude

New Journal of Chemistry, 2004 , vol. 28, # 6 p. 722 - 726 Title/Abstract Full Text View citing articles Show Details

With potassium hydroxide; potassium permanganate in water

T=25°C; primary kinetic isotope effect; other substituted mandelic acids; Rate constantMechanism;

Lee, Donald G.; Chen, Tao

Journal of Organic Chemistry, 1991 , vol. 56, # 18 p. 5341 - 5345 Title/Abstract Full Text View citing articles Show Details

With fructose 1,6-biphosphate; Bacillus stearothermophilus; triethanolamine hydrochloride; NADH

T=25°C; also in presence of Gln102 or Asn enzyme; Rate constantEquilibrium constant;

Luyten, Marcel A.; Bur, Daniel; Wynn, Hla; Parris, Wendy; Glod, Marvin; et al.

Journal of the American Chemical Society, 1989 , vol. 111, # 17 p. 6800 - 6804 Title/Abstract Full Text View citing articles Show Details

With zinc(II) nitrate; triethylamine; 7,14-diethyl-3-(2,2'-bipyridin-6-ylmethyl)-10methylbenzo[1,2-g;4,5-g']dipteridine-2,4,9,11-(3H,7H,10H,14H)-tetraone

other α-hydroxy acids; also in the t-BuOH; also in the presence of O2; deuterium kinetic isotope effect; Rate constant;

Yano, Yumihiko; Mitsui, Keita; Ohsawa, Youichi; Kobayashi, Toshitada; Nabeshima, Tatsuya

Journal of the Chemical Society, Chemical Communications, 1993 , # 23 p. 1719 - 1721 Title/Abstract Full Text View citing articles Show Details

With perchloric acid; chloramine-B in water

T=29.9 - 44.9°C; 10 h; in the dark; activation parameters; different concentrations, further solvents; KineticsThermodynamic dataMechanism;

Jain, Anandi L.; Banerji, Kalyan K.

Journal of the Indian Chemical Society, 1982 , vol. 59, # 5 p. 654 - 656 Title/Abstract Full Text Show Details

With pyridinium hydrobromide perbromide in water; acetic acid

T=49.9°C; ΔH(excit.), ΔS(excit.), ΔG(excit.); Rate constantKineticsThermodynamic data;

Aparna, P; Kothari, Seema; Banerji, Kalyan K

Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1993 , vol. 32, # 12 p. 1086 - 1088 Title/Abstract Full Text Show Details

With sodium hydroxide; potassium hexacyanoferrate(III); ruthenium trichloride in water

T=30°C; MechanismRate constant;

Singh, R. N.; Tikoo, P. K.

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1980 , vol. 19, # 12 p. 1210 - 1212 Title/Abstract Full Text Show Details

With potassium hydroxide; osmium(VIII) oxide in water

T=31.9°C; ΔG (excit.); Thermodynamic dataRate constantMechanism;

Somaiah, P. Veera; Reddy, K. Bal; Sethuram, B.; Rao, T. Navaneeth

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1988 , vol. 27, # 10 p. 876 - 879 Title/Abstract Full Text Show Details

With 1,8-diazabicyclo[5.4.0]undec-7-ene; nickel(II) nitrate; 7,14-diethyl-3-(2,2'bipyridin-6-ylmethyl)-10-methylbenzo[1,2-g;4,5-g']dipteridine-2,4,9,11(3H,7H,10H,14H)-tetraone in N,N-dimethyl-formamide; tert-butyl alcohol

1 h; other α-substituted α-hydroxy acids; Rate constantMechanism;

Ando, Nobuyuki; Osawa, Yohichi; Nabeshima, Tatsuya; Yano, Yumihiko

Chemistry Letters, 1996 , # 5 p. 381 - 382 Title/Abstract Full Text View citing articles Show Details

With chromic acid in water

T=40°C; also with MnSO4 or K2SO4, and in the presence of sodium lauryl sulphate, var. temp.; ΔH (activ.), ΔS (activ.); Rate constantThermodynamic data;

Panigrahi; Sahu, Saroj K.

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 1996 , vol. 35, # 8 p. 660 - 666 Title/Abstract Full Text View citing articles Show Details

With bromine

Ciusa; Piergallini

Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1914 , vol. <5>23 I, p. 825 Gazzetta Chimica Italiana, 1915 , vol. 45 I, p. 63 Full Text Show Details

With sodium hydroxide; potassium permanganate

T=-4 - -2°C;

Dakin; Dudley

Journal of Biological Chemistry, 1913 , vol. 15, p. 137 Full Text Show Details

Darapsky

Journal fuer Praktische Chemie (Leipzig), 1917 , vol. <2> 96, p. 258 Full Text Show Details

Acree

American Chemical Journal, 1913 , vol. 50, p. 393 Full Text Show Details

Meyer,R.; Baur

Chemische Berichte, 1880 , vol. 13, p. 1500 Full Text Show Details

Organic Syntheses

Coll. Vol. 1 <New York 1932>, S. 236 Full Text Show Details

With permanganate(VII) ion

Hurd; McNamee

Organic Syntheses, 1936 , vol. 16, p. 89 Full Text Show Details

With nitric acid

Hunaeus; Zincke

Chemische Berichte, 1877 , vol. 10, p. 1489 Full Text Show Details

With perchloric acid; bis(2,2'-bipyridyl) copper(II) permanganate; acetic acid

T=19.85°C; 24 h; var. pH; MechanismRate constant;

Satsangi, Baljeet Kaur; Kothari, Seema

Journal of the Indian Chemical Society, 1997 , vol. 74, # 1 p. 16 - 20 Title/Abstract Full Text View citing articles Show Details

With toluene-4-sulfonic acid; quinolinium monofluorochromate(VI) in dimethyl sulfoxide

T=29.85°C; Kinetics; Further Variations:var. TsOH conc.;

Dave; Sharma; Banerji

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2000 , vol. 39, # 7 p. 728 - 733 Title/Abstract Full Text View citing articles Show Details

With BTPPD in dimethyl sulfoxide

T=44.85°C; Kinetics; Further Variations:TemperaturesSolvents;

Kothari; Banerji

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2000 , vol. 39, # 7 p. 734 - 739 Title/Abstract Full Text View citing articles Show Details

With tetra-N-butylammonium tribromide; acetic acid; potassium bromide

T=19.85°C; Kinetics; Further Variations:Temperatureskinetic isotope effect;

Baghmar; Sharma

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2001 , vol. 40, # 3 p. 311 - 315 Title/Abstract Full Text View citing articles Show Details

With BPCC in dimethyl sulfoxide

T=29.85°C; 24 h; KineticsThermodynamic dataProduct distribution; Further Variations:TemperaturesReagents;

Kumbhat, Vinita; Sharma, Pradeep K.; Banerji, Kalyan K.

International Journal of Chemical Kinetics, 2002 , vol. 34, # 4 p. 248 - 254 Title/Abstract Full Text View citing articles Show Details

With QBC in dimethyl sulfoxide

T=19.85 - 49.85°C; Kinetics;

Sarswat, Sonu; Sharma, Vinita; Banerji, Kalyan K.

Journal of the Indian Chemical Society, 2002 , vol. 79, # 11 p. 871 - 875 Title/Abstract Full Text View citing articles Show Details

With N,N,N-trimethylbenzenemethanaminium dichloroiodate; acetic acid; zinc(II) chloride

T=24.85°C; Kinetics; Further Variations:Temperatures;

Goyal, Archana; Kothari, Seema

Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 12 p. 2335 - 2340 Title/Abstract Full Text Show Details

With 7,14-di-Et-3-Me-benzo[1,2-g;4,5-g']dipteridine-tetraone; 1,8diazabicyclo[5.4.0]undec-7-ene; nickel(II) nitrate in tert-butyl alcohol

T=25°C; Kinetics;

Ohshiro; Mitsui; Ando; Ohsawa; Koinuma; Takahashi; Kondo; Nabeshima; Yano

Journal of the American Chemical Society, 2001 , vol. 123, # 11 p. 2478 - 2486 Title/Abstract Full Text View citing articles Show Details

With perchloric acid; acetic acid; bis-[(trifluoroacetoxy)iodo]benzene

Banerji, Jayshree; Sharma, Pradeep K.; Banerji, Kalyan K.

99 %Spectr.

T=14.84°C; Kinetics; Further Variations:Temperatures;

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2007 , vol. 46, # 3 p. 445 - 448 Title/Abstract Full Text View citing articles Show Details

With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hydrogencarbonate; sodium carbonate

T=20°C; Electrochemical reaction;

Yoshida, Tomonori; Kuroboshi, Manabu; Oshitani, Jun; Gotoh, Kuniaki; Tanaka, Hideo

Synlett, 2007 , # 17 p. 2691 - 2694 Title/Abstract Full Text View citing articles Show Details

With O2CrClO(1-)*NEt4(1+) in dimethyl sulfoxide 24 h; Darkness; KineticsMechanism; Temperature;

Swami, Preeti; Yajurvedi; Mishra; Sharma, Pradeep K.

International Journal of Chemical Kinetics, 2010 , vol. 42, # 1 p. 50 - 55 Title/Abstract Full Text View citing articles Show Details

With C16H15ClN4O2Pd; oxygen; sodium acetate

T=20 - 120°C; 48 h;

Urgoitia, Garazi; Sanmartin, Raul; Herrero, Maria Teresa; Dominguez, Esther

Green Chemistry, 2011 , vol. 13, # 8 p. 2161 - 2166 Title/Abstract Full Text View citing articles Show Details

With PFC; acetic acid in water

T=29.84°C; KineticsMechanism; ConcentrationSolventReagent/catalystTemperature;

Ahmed, S. Zaheer; Shafi, S. Syed; Mansoor, S. Sheik

Asian Journal of Chemistry, 2013 , vol. 25, # 2 p. 921 - 925 Title/Abstract Full Text View citing articles Show Details

With potassium permanganate; sodium hydroxide in water

T=-4 - 0°C; 2 h; Hide Experimental Procedure

Melnicky, Radek; Grepl, Martin; Lycka, Antonin; Bertolasi, Valerio; Kvapil, Lubomir; Dvorakova, Barbora; Hradil, Pavel

Synthesis (Germany), 2013 , vol. 45, # 17 art. no. SS-2012-Z1009-OP, p. 2447 - 2457 Title/Abstract Full Text View citing articles Show Details

Arylglyoxalic Acid Derivatives 8d–g; General Procedure9,10

General procedure: The oily residue was suspended in H2O (18.0 mL), and NaOH (3.95 g, 98.75 mmol) in H2O (18 mL) and ice (70.0 g) were added. The mixture was cooled in an ice–salt bath and KMnO4 (31.6 g, 200 mmol) was added in small portions over a period of 0.5 h at –4 to –2 °C. Then, the reaction was kept at 0 °C for 1.5 h. At the end of the reaction, the excess KMnO4 was destroyed with sodium sulfite. The mixture was filtered off, and the filtrate was acidified to pH 1 using aq 36percent HCl. The filtrate was extracted into Et2O (3 × 100 mL), dried (Na2SO4) and concentrated using a rotary evaporator. Phenylglyoxalic acids 8d–g were obtained as yellowish oils and were used in the next step without purification (Table 4).

66 %Spectr.

With tert.-butylhydroperoxide; cobalt ferrite in dimethyl sulfoxide

T=90°C; 5 h;

Burange, Anand S.; Kale, Sandip R.; Zboril, Radek; Gawande, Manoj B.; Jayaram, Radha V.

RSC Advances, 2014 , vol. 4, # 13 p. 6597 - 6601 Title/Abstract Full Text View citing articles Show Details

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; laccase from Trametes versicolor; oxygen in aq. acetate buffer T=20°C; pH=4.5; 192 h; Enzymatic reaction;

Galletti, Paola; Pori, Matteo; Funiciello, Federica; Soldati, Roberto; Ballardini, Alberto; Giacomini, Daria

ChemSusChem, 2014 , vol. 7, # 9 p. 2684 - 2689 Title/Abstract Full Text Show Details

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Rx-ID: 32582145 Find similar reactions

Multi-step reaction with 2 steps 1: tetrahydrofuran / 1.08 h / -78 °C 2: water; sodium hydroxide / methanol / 1 h / 20 - 50 °C View Scheme

Watanabe, Nobuko; Hamano, Mitsutaka; Todaka, Shota; Asaeda, Takahiro; Ijuin, Hisako K.; Matsumoto, Masakatsu

Journal of Organic Chemistry, 2012 , vol. 77, # 1 p. 632 - 639 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; benzotriazol-1-ol / tetrahydrofuran; diethyl ether / 2 h / -78 - 0 °C / |Inert atmosphere 2: lithium hydroxide hydrate; water / tetrahydrofuran / 2 h View Scheme

BOARD OF REGENTS OF THE UNIVERSITY OF TEXAS SYSTEM; READY, Joseph M.; NIJHAWAN, Deepak; GONZALES, Stephen S.; THEODOROPOULOS, Pano

Patent: WO2015/35051 A1, 2015 ; Title/Abstract Full Text Show Details

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Rx-ID: 39595264 Find similar reactions

With cobalt phosphide

T=20°C; pH=6; 10 h; Inert atmosphereIrradiationGreen chemistry; Kinetics; pHvalue;

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Cao, Shuang; Chen, Yong; Hou, Chun-Chao; Lv, Xiao-Jun; Fu, Wen-Fu

Journal of Materials Chemistry A, 2015 , vol. 3, # 11 p. 6096 - 6101 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 39595265 Find similar reactions

With cobalt phosphide

T=20°C; pH=6; Inert atmosphereIrradiationGreen chemistry;

Cao, Shuang; Chen, Yong; Hou, Chun-Chao; Lv, Xiao-Jun; Fu, Wen-Fu

Journal of Materials Chemistry A, 2015 , vol. 3, # 11 p. 6096 - 6101 Title/Abstract Full Text View citing articles Show Details

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With Aerococcus viridans L-lactate oxidase, A95G mutant, containing oxidized-state FMN cofactor in aq. phosphate buffer

T=20°C; pH=6.5; Flow reactorEnzymatic reaction; Kinetics; Reagent/catalyst;

Rx-ID: 39607011 Find similar reactions

Stoisser, Thomas; Rainer, Daniela; Leitgeb, Stefan; Wilson, David K.; Nidetzky, Bernd

FEBS Journal, 2015 , vol. 282, # 3 p. 562 - 578 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 39882285 Find similar reactions

With L-amino acid oxidase; L-acylase; N-acetyl amino acid racemase; magnesium chloride; horseradish peroxidase in methanol

Enzymatic reaction;

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Snchez-Carrn, Guiomar; Fleming, Toni; Holt-Tiffin, Karen E.; Campopiano, Dominic J.

Analytical Chemistry, 2015 , vol. 87, # 7 p. 3923 - 3928 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 66208 Find similar reactions

With potassium permanganate

Przewalski

Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1917 , vol. 49, p. 568 Chem. Zentralbl., 1923 , vol. 94, # III p. 664 Full Text Show Details

With selenium(IV) oxide in anhydrous xylene

T=155°C; 5 h;

Seyedsayamdost, Mohammad R.; Wang, Rurun; Kolter, Roberto; Clardy, Jon

Journal of the American Chemical Society, 2014 , vol. 136, # 43 p. 15150 - 15153 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 15174169 Find similar reactions

Nicolaou; Hughes, Robert; Pfefferkorn, Jeffrey A.; Barluenga, Sofia; Roecker

Chemistry - A European Journal, 2001 , vol. 7, # 19 p. 4280 - 4295 Title/Abstract Full Text View citing articles Show Details

With leucine dehydrogenase from Exiguobacterium sibiricum; nicotinamide adenine dinucleotide; water

Li, Jing; Pan, Jiang; Zhang, Jie; Xu, Jian-He

Journal of Molecular Catalysis B: Enzymatic, 2014 , vol. 105, p. 11 - 17 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 21513360 Find similar reactions

Multi-step reaction with 2 steps 1: 1.) Mg / 1.) THF, 2.) -50 deg C up to room temp. within 3h 2: 57 percent / CF3CO2H / 1 h / 0 °C View Scheme

Nimitz, Jonathan S.; Mosher, Harry S.

Journal of Organic Chemistry, 1981 , vol. 46, # 1 p. 211 - 213 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1.1: magnesium / tetrahydrofuran / 1 h / 20 °C 1.2: 1 h / -78 - -10 °C 2.1: sodium hydroxide; water / tetrahydrofuran / 6 h / |Reflux View Scheme

Shirai, Tomohiko; Ito, Hajime; Yamamoto, Yasunori

Angewandte Chemie - International Edition, 2014 , vol. 53, # 10 p. 2658 - 2661 Angew. Chem., 2014 , vol. 126, # 10 p. 2696 - 2699,4 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 22022451 Find similar reactions

Multi-step reaction with 2 steps 1: 220 - 230 °C 2: hydrochloric acid View Scheme

Oakwood; Weisgerber

Organic Syntheses, 1944 , vol. 24, p. 16 Full Text Show Details

Multi-step reaction with 2 steps 1.1: triethylamine / dichloromethane / 2.75 h / 0 - 20 °C 2.1: palladium (II) trifluoroacetate; (NH4)2S2O8 / 1,2-dichloro-ethane / 30 h / 80 °C / |Sealed tube 2.2: 18 h / 120 °C / |Sealed tube View Scheme

Kim, Minyoung; Kumar Mishra, Neeraj; Park, Jihye; Han, Sangil; Shin, Youngmi; Sharma, Satyasheel; Lee, Youngil; Lee, Eui-Kyung; Kwak, Jong Hwan; Kim, In Su

Chemical Communications, 2014 , vol. 50, # 91 p. 14249 - 14252 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 36217013 Find similar reactions

Multi-step reaction with 2 steps 1: AlCl3, aluminium chloride / chloroform / 0 - 5 °C 2: sodium hydroxide / methanol / 0.5 h / 0 °C View Scheme

Mahaveer; Kulkarni; Radakrishna; Chandrashekar; Achaiah

Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2013 , vol. 52, # 6 p. 818 - 823 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: AlCl3, aluminium chloride / dichloromethane / 3 h / 0 °C 2: sodium hydroxide; water / 4 h / 20 °C View Scheme

Kim, Kyung Ju; Choi, Min Ji; Shin, Ji-Sun; Kim, Minju; Choi, Hye-Eun; Kang, Seoung Mook; Jin, Jae Ho; Lee, Kyung-Tae; Lee, Jae Yeol

Bioorganic and Medicinal Chemistry Letters, 2014 , vol. 24, # 8 p. 1958 - 1962 Title/Abstract Full Text View citing articles Show Details

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B: 10% C: 71%

With selenium(IV) oxide in 1,4-dioxane

2 h; Reflux; Hide Experimental Procedure

Nagaraj, Muthupandi; Perumal, Devanathan; Boominathan, Muthusamy; Muthusubramanian, Shanmugam; Bhuvanesh, Nattamai

Journal of Sulfur Chemistry, 2014 , vol. 35, # 1 p. 24 - 30 Title/Abstract Full Text View citing articles Show Details

4.2. General procedure for selenium dioxide oxidation of diphenyl sulfide

General procedure: Selenium dioxide (1.5 mmol) was dissolved in dioxane (10.0 mL) and added to a 50mL RB flask. To this, diphenacyl sulfide derivative 1 (0.5 mmol) was added and the mixture refluxed for 2 h. The course of the reaction was monitored by TLC. After completion, the reaction mixture was filtered and the solvent was removed under vacuum. The crude product was purified by column chromatography using petroleum ether and ethyl acetate mixture (90:10) as the eluent to get 3/5/6. A

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Rx-ID: 38567061 Find similar reactions

A: 19 %Spectr. B: 9 %Spectr. C: 86 %Spectr.

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Yu, Jin-Sheng; Liu, Yun-Lin; Tang, Jing; Zhou, Jian; Wang, Xin

Angewandte Chemie, International Edition, 2014 , vol. 53, # 36 p. 9512 - 9516,5 Angewandte Chemie, 2014 , vol. 126, # 36 Title/Abstract Full Text View citing articles Show Details

in water

T=50°C; Green chemistry;

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A: 26% B: 65%

With ammonium cerium (IV) nitrate; oxygen in acetonitrile

T=60°C;

Chang, Meng-Yang; Tsai, Chung-Yu

Tetrahedron Letters, 2014 , vol. 55, # 40 p. 5548 - 5550 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 38908550 Find similar reactions

62%

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Stage #1: With (NH4)2S2O8; palladium (II) trifluoroacetate in 1,2-dichloro-ethane

T=80°C; 30 h; Sealed tube; Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in 1,2-dichloro-ethane

T=120°C; 18 h; Sealed tube;

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Kim, Minyoung; Kumar Mishra, Neeraj; Park, Jihye; Han, Sangil; Shin, Youngmi; Sharma, Satyasheel; Lee, Youngil; Lee, Eui-Kyung; Kwak, Jong Hwan; Kim, In Su

Chemical Communications, 2014 , vol. 50, # 91 p. 14249 - 14252 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 2132612 Find similar reactions

With potassium hydroxide; potassium permanganate in water

T=25°C; primary kinetic isotope effect; Rate constant;

Lee, Donald G.; Chen, Tao

Journal of Organic Chemistry, 1991 , vol. 56, # 18 p. 5341 - 5345 Title/Abstract Full Text View citing articles Show Details

With potassium hydroxide; potassium manganate(VI)

T=25°C; activation parameters for the oxidation <ΔH(excit.), ΔS(excit.)>; Rate constant;

Lee, Donald G.; Chen, Tao

Journal of the American Chemical Society, 1993 , vol. 115, # 24 p. 11231 - 11236 Title/Abstract Full Text View citing articles Show Details

With perchloric acid; Annogen in water

T=29.9°C; 10 h; in the dark; different concentrations; kinetic isotope effect; Rate constantMechanism;

Jain, Anandi L.; Banerji, Kalyan K.

Journal of the Indian Chemical Society, 1982 , vol. 59, # 5 p. 654 - 656 Title/Abstract Full Text Show Details

With pyridinium hydrobromide perbromide in water

T=49.9°C; deuterium isotope effect; also in D2O: no solvent isotope effect; Rate constant;

Aparna, P; Kothari, Seema; Banerji, Kalyan K

Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1993 , vol. 32, # 12 p. 1086 - 1088 Title/Abstract Full Text Show Details

With quinolinium monofluorochromate(VI) in dimethyl sulfoxide

T=29.85°C; Kinetics; Further Variations:kinetic isotope effect;

Dave; Sharma; Banerji

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2000 , vol. 39, # 7 p. 728 - 733 Title/Abstract Full Text View citing articles Show Details

With BTPPD in dimethyl sulfoxide

T=44.85°C; Kinetics; Further Variations:Temperatureskinetic isotope effect;

Kothari; Banerji

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2000 , vol. 39, # 7 p. 734 - 739 Title/Abstract Full Text View citing articles Show Details

With tetra-n-butylammonium tribromide; acetic acid; potassium bromide

T=19.85°C; Kinetics; Further Variations:Temperatures;

Baghmar; Sharma

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2001 , vol. 40, # 3 p. 311 - 315 Title/Abstract Full Text View citing articles Show Details

With BPCC in dimethyl sulfoxide

T=29.85°C; 24 h; KineticsThermodynamic data; Further Variations:Temperatures;

Kumbhat, Vinita; Sharma, Pradeep K.; Banerji, Kalyan K.

International Journal of Chemical Kinetics, 2002 , vol. 34, # 4 p. 248 - 254 Title/Abstract Full Text View citing articles Show Details

With QBC in dimethyl sulfoxide

T=19.85 - 49.85°C; KineticsActivation energy;

Sarswat, Sonu; Sharma, Vinita; Banerji, Kalyan K.

Journal of the Indian Chemical Society, 2002 , vol. 79, # 11 p. 871 - 875 Title/Abstract Full Text View citing articles Show Details

With N,N,N-trimethylbenzenemethanaminium dichloroiodate; acetic acid; zinc(II) chloride

T=24.85°C; Kinetics; Further Variations:Temperatures;

Goyal, Archana; Kothari, Seema

Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 12 p. 2335 - 2340 Title/Abstract Full Text Show Details

With perchloric acid; acetic acid; bis-[(trifluoroacetoxy)iodo]benzene

T=14.84°C; Kinetics; Further Variations:Temperatures;

Banerji, Jayshree; Sharma, Pradeep K.; Banerji, Kalyan K.

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2007 , vol. 46, # 3 p. 445 - 448 Title/Abstract Full Text View citing articles Show Details

With O2CrClO(1-)*NEt4(1+) in dimethyl sulfoxide 24 h; Darkness; KineticsMechanism; Temperature;

Swami, Preeti; Yajurvedi; Mishra; Sharma, Pradeep K.

International Journal of Chemical Kinetics, 2010 , vol. 42, # 1 p. 50 - 55 Title/Abstract Full Text View citing articles Show Details

With PFC; acetic acid in water

T=29.84°C; KineticsMechanism; Temperature;

Ahmed, S. Zaheer; Shafi, S. Syed; Mansoor, S. Sheik

Asian Journal of Chemistry, 2013 , vol. 25, # 2 p. 921 - 925 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 3436641 Find similar reactions

With Fremy’s salt in water

60 h; pH 10.0;

Garcia-Raso, Angel; Deya, Pedro M.; Saa, Jose M.

Journal of Organic Chemistry, 1986 , vol. 51, # 22 p. 4285 - 4287 Title/Abstract Full Text View citing articles Show Details

With ω-transaminase

Park, Eul-Soo; Dong, Joo-Young; Shin, Jong-Shik

ChemCatChem, 2013 , vol. 5, # 12 p. 3538 - 3542 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 28590813 Find similar reactions

With Fe2(S04)3; water

T=25°C; pH=4; 2 h;

Mecinovic, Jasmin; Hamed, Refaat B.; Schofield, Christopher J.

Angewandte Chemie, International Edition, 2009 , vol. 48, # 15 p. 2796 - 2800 Title/Abstract Full Text View citing articles Show Details

With [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Fe(II) (acetonitrile)](perchlorate)2; dihydrogen peroxide; triethylamine in acetonitrile

12 h; regioselective reaction;

Allpress, Caleb J.; Grubel, Katarzyna; Szajna-Fuller, Ewa; Arif, Atta M.; Berreau, Lisa M.

Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 659 - 668 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: water / ethanol 2: [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Fe(II) (acetonitrile)](perchlorate)2; dihydrogen peroxide; triethylamine / acetonitrile; water / 12 h View Scheme

Allpress, Caleb J.; Grubel, Katarzyna; Szajna-Fuller, Ewa; Arif, Atta M.; Berreau, Lisa M.

Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 659 - 668 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 34821278 Find similar reactions

With oxygen in water; acetonitrile

12 h; regioselective reaction;

Allpress, Caleb J.; Grubel, Katarzyna; Szajna-Fuller, Ewa; Arif, Atta M.; Berreau, Lisa M.

Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 659 - 668 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 34821281 Find similar reactions

Allpress, Caleb J.; Grubel, Katarzyna; Szajna-Fuller, Ewa; Arif, Atta M.; Berreau, Lisa M.

Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 659 - 668 Title/Abstract Full Text View citing articles Show Details

With oxygen in acetonitrile

12 h; Reagent/catalyst; regioselective reaction;

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Synthesize Find similar Rx-ID: 34821284 Find similar reactions

With [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Fe(II) (acetonitrile)](perchlorate)2; dihydrogen peroxide; triethylamine in water; acetonitrile

12 h; regioselective reaction;

Allpress, Caleb J.; Grubel, Katarzyna; Szajna-Fuller, Ewa; Arif, Atta M.; Berreau, Lisa M.

Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 659 - 668 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 34821285 Find similar reactions

Allpress, Caleb J.; Grubel, Katarzyna; Szajna-Fuller, Ewa; Arif, Atta M.; Berreau, Lisa M.

Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 659 - 668 Title/Abstract Full Text View citing articles Show Details

With Fe(ClO4)2·6H2O; TMAOH*5H2O in water; acetonitrile

12 h; Inert atmosphere; regioselective reaction;

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Synthesize Find similar Rx-ID: 35134792 Find similar reactions

With carbon tetrabromide; water; oxygen in ethyl acetate

10 h; Irradiation; TimeReagent/catalyst;

Yamaguchi, Tomoaki; Nobuta, Tomoya; Kudo, Yasuhisa; Hirashima, Shin-Ichi; Tada, Norihiro; Miura, Tsuyoshi; Itoh, Akichika

Synlett, 2013 , vol. 24, # 5 art. no. ST-2013-U0018-L, p. 607 - 610 Title/Abstract Full Text View citing articles Show Details

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Multi-step reaction with 3 steps 1.1: water / 0 - 20 °C 1.2: 1 h / 20 °C 2.1: hydrogenchloride; water / 12 h / 25 °C 3.1: sodium hydroxide; potassium permanganate / water / 2 h / -4 - 0 °C View Scheme

Rx-ID: 36327870 Find similar reactions

Melnicky, Radek; Grepl, Martin; Lycka, Antonin; Bertolasi, Valerio; Kvapil, Lubomir; Dvorakova, Barbora; Hradil, Pavel

Synthesis (Germany), 2013 , vol. 45, # 17 art. no. SS-2012-Z1009-OP, p. 2447 - 2457 Title/Abstract Full Text View citing articles Show Details

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Multi-step reaction with 2 steps 1: hydrogenchloride; water / 12 h / 25 °C 2: sodium hydroxide; potassium permanganate / water / 2 h / -4 - 0 °C View Scheme

Rx-ID: 36327983 Find similar reactions

Melnicky, Radek; Grepl, Martin; Lycka, Antonin; Bertolasi, Valerio; Kvapil, Lubomir; Dvorakova, Barbora; Hradil, Pavel

Synthesis (Germany), 2013 , vol. 45, # 17 art. no. SS-2012-Z1009-OP, p. 2447 - 2457 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 37381818 Find similar reactions

A: 45% B: 28% C: 30%

With Pseudomonas sp. isolated from coastal waters and soils of the Absheron peninsula at the Caspian Sea in water

T=28°C; Microbiological reaction;

Veliev; Salmanov; Babashly; Alieva; Bektashi

Petroleum Chemistry, 2013 , vol. 53, # 6 p. 426 - 430 Neftekhimiya, 2013 , vol. 53, # 6 p. 476 - 480,4 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Multi-step reaction with 2 steps 1: sodium hydrogencarbonate; aqueous ethanol 2: oxalic acid-dihydrate; boric acid / 100 °C View Scheme

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Rx-ID: 22314062 Find similar reactions

Kroehnke

Chemische Berichte, 1947 , vol. 80, p. 298,310 Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C 2.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 3.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 4.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 4.2: 5 h / 25 - 90 °C View Scheme

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar 98%

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With water; sodium hydroxide in methanol

T=20 - 50°C; 1 h;

Rx-ID: 32582110 Find similar reactions

Watanabe, Nobuko; Hamano, Mitsutaka; Todaka, Shota; Asaeda, Takahiro; Ijuin, Hisako K.; Matsumoto, Masakatsu

Journal of Organic Chemistry, 2012 , vol. 77, # 1 p. 632 - 639 Title/Abstract Full Text View citing articles Show Details

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Multi-step reaction with 2 steps 1: tetrahydrofuran / 1 h / -78 °C / Inert atmosphere 2: water; sodium hydroxide / methanol / 1 h / 20 - 50 °C View Scheme

Rx-ID: 32582142 Find similar reactions

Watanabe, Nobuko; Hamano, Mitsutaka; Todaka, Shota; Asaeda, Takahiro; Ijuin, Hisako K.; Matsumoto, Masakatsu

Journal of Organic Chemistry, 2012 , vol. 77, # 1 p. 632 - 639 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Multi-step reaction with 2 steps 1.1: oxalic acid / dichloromethane; water / 5 h / 25 °C

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Rx-ID: 33905181 Find similar reactions

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985

2.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 2.2: 5 h / 25 - 90 °C View Scheme

Title/Abstract Full Text View citing articles Show Details

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Multi-step reaction with 3 steps 1.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 2.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 3.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 3.2: 5 h / 25 - 90 °C View Scheme

Rx-ID: 33905185 Find similar reactions

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985 Title/Abstract Full Text View citing articles Show Details

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Multi-step reaction with 5 steps 1.1: hydrogen bromide; dihydrogen peroxide / water / 4.5 h / 25 - 90 °C 2.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C 3.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 4.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 5.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 5.2: 5 h / 25 - 90 °C View Scheme

Rx-ID: 33905190 Find similar reactions

Dai, Zhihong; Peng, Xinhua; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

Asian Journal of Chemistry, 2012 , vol. 24, # 11 p. 4979 - 4985 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 267096 Find similar reactions

78%

Stage #1: With silver perchlorate; sodium hydroxide in water

T=20°C; Inert atmosphere; Stage #2: With hydrogenchloride in water

Inert atmosphere;

Guo, Xingwei; Li, Wenjuan; Li, Zhiping

European Journal of Organic Chemistry, 2010 , # 30 p. 5787 - 5790 Title/Abstract Full Text View citing articles Show Details

bei der Einw. von gaerender Hefe;

Dakin

Journal of Biological Chemistry, 1914 , vol. 18, p. 91 Full Text Show Details

Multi-step reaction with 2 steps 1: 26.5 percent Spectr. / Et3N, pyridine, O2, 3-Angstroem sieves / Cu(NO3)2py2 / methanol / 12 h / 25 °C / 1748 Torr 2: 68.6 percent Spectr. / Et3N, pyridine, O2, H2O / Cu(NO3)2py2 / methanol / 12 h / 25 °C / 1748 Torr View Scheme

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 37.4 percent Spectr. / Et3N, pyridine / Cu(NO3)2py2 / methanol / 12 h / 25 °C 2: 68.6 percent Spectr. / Et3N, pyridine, O2, H2O / Cu(NO3)2py2 / methanol / 12 h / 25 °C / 1748 Torr View Scheme

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

With oxygen in dichloromethane

T=14.84°C; P=759.826 Torr; 24 h;

Tada, Mizuki; Muratsugu, Satoshi; Kinoshita, Mutsuo; Sasaki, Takehiko; Iwasawa, Yasuhiro

Journal of the American Chemical Society, 2010 , vol. 132, # 2 p. 713 - 724 Title/Abstract Full Text View citing articles Show Details

With carbon dioxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,3-bis(2,6diisopropylphenyl)imidazolinium chloride in tetrahydrofuran

T=20 - 25°C; 2 h; Inert atmosphere; Product distribution / selectivity; Hide Experimental Procedure

SUMITOMO CHEMICAL COMPANY, LIMITED; HAGIYA, Koji

Patent: WO2011/162404 A1, 2011 ; Location in patent: Page/Page column 37 ; Title/Abstract Full Text Show Details

Example 1)A 50 ml schrenck tube equipped with a magnetic rotor was charged with phenylglyoxal monohydrate (260 mg) , 1,3- bis [ (2, 6-diisopropyl) phenyl] imidazolium chloride (50 mg) and tetrahydrofuran (5 g) under a nitrogen atmosphere, and the resulting mixture was stirred while maintaining the temperature of the mixture in a water bath at 25°C. Dry ice (1.0 g) was added to the mixture, and 1,8- diazabicyclo [ 5, 4 , 0 ] -7-undecene (23 mg) was further added thereto so as to initiate the reaction, and the mixture was stirred for 2 hours at a room temperature. At 30 minutes and 1 hour following the start of reaction, dry ice (1 g) was added to the reaction mixture, respectively. After completion of the reaction, the solvent was distilled off from the reaction mixture to obtain a yellow solid containing benzoylformic acid. A

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A: 66 %Chromat. B: 96

With dichloro bis(acetonitrile) palladium(II); tris(acetonitrile)(η5-2,4-cyclopentadien1-yl)ruthenium(1+) hexafluorophosphate(1-); diethylene glycol dimethyl ether; 1,6bis-(diphenylphosphino)-hexane; water in ethylene glycol dimethyl

Nakamura, Asami; Hamasaki, Akiyuki; Goto, Sachihiko; Utsunomiya, Masaru; Tokunaga, Makoto

Advanced Synthesis and Catalysis, 2011 , vol. 353, # 6 p. 973 - 984 Title/Abstract Full Text View citing articles Show Details

%Chromat.

ether; dichloromethane

T=20 - 85°C; 0.5 h; Inert atmosphere;

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Synthesize Find similar Rx-ID: 32102849 Find similar reactions

A: 63% B: 30%

With Oxonereg;; 2-iodo-3,4,5,6-tetramethylbenzoic acid in water; acetonitrile

T=20°C; 3 h;

Moorthy, Jarugu Narasimha; Senapati, Kalyan; Parida, Keshaba Nanda; Jhulki, Samik; Sooraj, Kunnikuruvan; Nair, Nisanth N.

Journal of Organic Chemistry, 2011 , vol. 76, # 23 p. 9593 - 9601 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 32104940 Find similar reactions

With iodine; oxygen in ethyl acetate

Mercury lamp irradiation;

Tada, Norihiro; Shomura, Motoki; Cui, Lei; Nobuta, Tomoya; Miura, Tsuyoshi; Itoh, Akichika

Synlett, 2011 , # 19 art. no. U06311ST, p. 2896 - 2900 Title/Abstract Full Text View citing articles Show Details

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With tert.-butylhydroperoxide; anhydrous iron chloride; 2-(1'-thyminyl)acetic acid in decane; acetonitrile

T=80°C; 6 h;

Rx-ID: 1744160 Find similar reactions

Al-Hunaiti, Afnan; Niemi, Teemu; Sibaouih, Ahlam; Pihko, Petri; Leskelae, Markku; Repo, Timo

Chemical Communications, 2010 , vol. 46, # 48 p. 9250 - 9252 Title/Abstract Full Text View citing articles Show Details

94%

With Oxonereg;; 2-iodo benzoic acid in water; acetonitrile

T=70°C; 6 h;

Thottumkara, Arun P.; Bowsher, Michael S.; Vinod, Thottumkara K.

Organic Letters, 2005 , vol. 7, # 14 p. 2933 - 2936 Title/Abstract Full Text View citing articles Show Details

91%

With sodium tetrahydroborate; 1 Pd/C; water; potassium hydroxide in methanol

T=20°C; 15 h; In air;

An, Gwangil; Ahn, Hyunseok; De Castro, Kathlia A.; Rhee, Hakjune

Synthesis, 2010 , # 3 art. no. F19009SS, p. 477 - 485 Title/Abstract Full Text View citing articles Show Details

71%

With potassium permanganate; acetic acid; tri[2-(2-methoxyethoxy)ethyl]amine in dichloromethane

4 h; Ambient temperature;

McKillop, Alexander; Mills, Lester S.

Synthetic Communications, 1987 , vol. 17, # 6 p. 647 - 656 Title/Abstract Full Text Show Details

47%

With [ruthenium(III)(2,2':6',2''-terpyridine)(2,2'-bipyridine)(H2O)] in phosphate buffer

pH=7.2; 6 h; Electrolysis;

Geneste, Florence; Moinet, Claude

New Journal of Chemistry, 2004 , vol. 28, # 6 p. 722 - 726 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 29351743 Find similar reactions

A: 9% B: 43% C: 47%

With sodium tetrahydroborate; 1 Pd/C; water; potassium hydroxide in methanol

T=20°C; 9 h; In air;

An, Gwangil; Ahn, Hyunseok; De Castro, Kathlia A.; Rhee, Hakjune

Synthesis, 2010 , # 3 art. no. F19009SS, p. 477 - 485 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar

Rx-ID: 2087711 Find similar reactions

With trifluoroacetic acid

T=0°C; 1 h;

Nimitz, Jonathan S.; Mosher, Harry S.

Journal of Organic Chemistry, 1981 , vol. 46, # 1 p. 211 - 213 Title/Abstract Full Text View citing articles Show Details

With trifluoroacetic acid

T=0°C; 5 h;

Hameury, Thomas; Guillemont, Jerome; Hijfte, Luc Van; Bellosta, Veronique; Cossy, Janine

Organic Letters, 2009 , vol. 11, # 11 p. 2397 - 2400

Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 28590820 Find similar reactions

With Fe2(S04)3; water

T=25°C; pH=4; 2 h;

Mecinovic, Jasmin; Hamed, Refaat B.; Schofield, Christopher J.

Angewandte Chemie, International Edition, 2009 , vol. 48, # 15 p. 2796 - 2800 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 29159416 Find similar reactions

A: 28% B: 42%

With potassium meta-periodate; DPC; potassium nitrate; potassium hydroxide in water

T=12 - 37°C; 2 h; Inert atmosphere; KineticsMechanismThermodynamic data;

Shetti, Nagaraj P.; Hegde, Rajesh N.; Nandibewoor, Sharanappa T.

Journal of Molecular Structure, 2009 , vol. 930, # 1-3 p. 180 - 186 Title/Abstract Full Text View citing articles Show Details

With diperiodoargentate(III)(1-); AgH4I2O12(3-); potassium nitrate; potassium hydroxide in water

T=24.84°C; Inert atmosphere; KineticsMechanismThermodynamic data; ConcentrationTemperature;

Hosamani, Ragunatharaddi R.; Shetti, Nagaraj P.; Nandibewoor, Sharanappa T.

Journal of Physical Organic Chemistry, 2009 , vol. 22, # 3 p. 234 - 240 Title/Abstract Full Text View citing articles Show Details

Synthesize

Rx-ID: 304509

Find similar 73.5%

Find similar

Find similar reactions

With hydrogenchloride; water; sodium nitrite

T=80°C; 4 h;

Li, Gui-Yin; Jiang, Yu-Ren; Huang, Ke-Long; Liu, Zuo-Zhou; Ding, Ping

Journal of the Indian Chemical Society, 2008 , vol. 85, # 5 p. 552 - 554 Title/Abstract Full Text View citing articles Show Details

With acetic anhydride

bei der Destillation u. Verseifen mit Salzsaeure;

Soederbaum

Chemische Berichte, 1891 , vol. 24, p. 1384 Oef. Sv., 1893 , p. 201 Full Text Show Details

Claisen

Chemische Berichte, 1877 , vol. 10, p. 430,431 Full Text Show Details

Claus; Manasse

Chemische Berichte, 1887 , vol. 20, p. 2196 Full Text Show Details

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Rx-ID: 27983754 Find similar reactions

With sodium hydroxide

0.0166667 h; microwave irradiation;

Moghaddam, Firouz Matloubi; Mirjafary, Zohreh; Saeidian, Hamdollah; Javan, Marjan Jebeli

Synlett, 2008 , # 6 p. 892 - 896 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide

0.5 h; Heating;

Moghaddam, Firouz Matloubi; Mirjafary, Zohreh; Saeidian, Hamdollah; Javan, Marjan Jebeli

Synlett, 2008 , # 6 p. 892 - 896 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 11325919 Find similar reactions

Multi-step reaction with 2 steps 1: VOCl3; O2 / acetonitrile 2: KOH / H2O; ethanol View Scheme

Chen, Chien-Tien; Bettigeri, Sampada; Weng, Shiue-Shien; Pawar, Vijay D.; Lin, Ya-Hui; Liu, Cheng-Yuan; Lee, Way-Zen

Journal of Organic Chemistry, 2007 , vol. 72, # 22 p. 8175 - 8185 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: lead (IV)-acetate; benzene 2: aq. NaOH solution View Scheme

Baer; Kates

Journal of the American Chemical Society, 1945 , vol. 67, p. 1482 Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 9890060 Find similar reactions

C: 2%

Huang, Han-Rong; Xu, Jian-He; Xu, Yi; Pan, Jiang; Liu, Xiang

Tetrahedron Asymmetry, 2005 , vol. 16, # 12 p. 2113 - 2117 Title/Abstract Full Text View citing articles Show Details

With potassium phosphate buffer; Pseudomonas putida ECU1009

T=30°C; pH=6.0; 6 h;

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Synthesize Find similar Rx-ID: 10141296 Find similar reactions

A: 5% B: 5% C: 51% D: 13%

With 3,3-dimethyldioxirane in acetone

T=4°C; 22 h; Product distribution; Further Variations:time;

Zeller, Klaus-Peter; Kowallik, Meike; Haiss, Peter

Organic and Biomolecular Chemistry, 2005 , vol. 3, # 12 p. 2310 - 2318 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 9406701 Find similar reactions

With bismuth; oxygen; acetic acid in water; dimethyl sulfoxide

T=125°C; P=760 Torr; Kinetics;

Favier, Isabelle; Dunach, Elisabet

Tetrahedron, 2003 , vol. 59, # 10 p. 1823 - 1830 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide; oxygen; CoCl2 in water; dimethyl sulfoxide

T=125°C; P=760.051 Torr; 24 h; Product distribution; Further Variations:ReagentsSolventsTemperaturesreaction time;

Favier, Isabelle; Dunach, Elisabet; Hebrault, Dominique; Desmurs, Jean-Roger

New Journal of Chemistry, 2004 , vol. 28, # 1 p. 62 - 66 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 5931659 Find similar reactions

Herstellung von Phenyl-<1-14C>glyoxylsaeure;

Fingerman; Lemmon

U.S. Atomic Energy Comm., UCRL-8731 <1959> Full Text Show Details

Banholzer; Schmid

Helvetica Chimica Acta, 1956 , vol. 39, p. 548,553 Full Text Show Details

Burger,K.; Eggersdorfer,M.

Liebigs Annalen der Chemie, 1979 , p. 1547 - 1553 Full Text View citing articles Show Details

Gross,H.; Freiberg,J.

Chemische Berichte, 1967 , vol. 100, p. 3777 - 3781 Full Text View citing articles Show Details

Koebrich,G.; Fischer,R.H.

Chemische Berichte, 1968 , vol. 101, p. 3208 - 3218 Full Text View citing articles Show Details

McKillop,A. et al.

Journal of the American Chemical Society, 1973 , vol. 95, p. 3635 - 3640 Full Text View citing articles Show Details

Weygand,F. et al.

Justus Liebigs Annalen der Chemie, 1962 , vol. 658, p. 128 - 150 Full Text View citing articles Show Details

Hansen,J.F.; Wang,S.

Journal of Organic Chemistry, 1976 , vol. 41, p. 3635 - 3637 Full Text View citing articles Show Details

Anatol; Medete

Synthesis, 1971 , p. 538 Full Text Show Details

Howe; Johnson

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1972 , p. 977 Full Text Show Details

Raap

Tetrahedron Letters, 1969 , p. 3493 Full Text View citing articles Show Details

Pechiney Ugine Kuhlmann

Patent: DE2208568 , 1972 ; Chem.Abstr., vol. 77, # 151684 Full Text Show Details

Anatol; Medete

Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1971 , vol. 272, p. 1157 Full Text Show Details

Anatol; Medete

Bulletin de la Societe Chimique de France, 1972 , p. 189 Full Text Show Details

Adembri

Annali di Chimica (Rome, Italy), 1960 , vol. 50, p. 374,379 Full Text Show Details

Fisera; Kovac

Heterocycles, 1978 , vol. 9, p. 1508 Full Text Show Details

Koebrich et al.

Chemische Berichte, 1966 , vol. 99, p. 1793,1802 Full Text Show Details

Oguri et al.

Chemical and Pharmaceutical Bulletin, 1975 , vol. 23, p. 167,170,171

Full Text View citing articles Show Details

Wolinski et al.

Acta Poloniae Pharmaceutica, 1976 , vol. 33, p. 541,544 Chem.Abstr., 1977 , vol. 86, # 171176 Full Text Show Details

Walborsky; Niznik

Journal of the American Chemical Society, 1969 , vol. 91, p. 7778 Full Text View citing articles Show Details

Mangat Rai; Ajit Singh

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1979 , vol. 17, p. 169 Full Text Show Details

Leermakers; Vesley

Journal of the American Chemical Society, 1963 , vol. 85, p. 3776 Full Text View citing articles Show Details

Veenstra; Zwanenburg

Tetrahedron, 1978 , vol. 34, p. 1585,1590 Full Text Show Details

Azizov; Khodzhaev

Uzb. Khim. Zh., 1971 , vol. 15, # 3 p. 55 Chem.Abstr., 1971 , vol. 75, # 110014p Full Text Show Details

Oda; Hayashi

Nippon Kagaku Zasshi, 1967 , vol. 88, p. 1202,1203, 1207 Full Text Show Details

Lapkin; Karawanow

Zhurnal Organicheskoi Khimii, 1966 , vol. 2, p. 17,14 Full Text Show Details

Madoery et al.

Anales de la Asociacion Quimica Argentina (1921-2001), 1975 , vol. 63, p. 95,101 Full Text Show Details

Sliwa; Tartar

Journal of Organic Chemistry, 1976 , vol. 41, p. 160,161 - 163 Full Text View citing articles Show Details

Barker et al.

Journal of the Chemical Society, 1963 , p. 5117,5119 Full Text Show Details

Heyns et al.

Chemische Berichte, 1960 , vol. 93, p. 2057,2058-2062 Full Text Show Details

Kratzl et al.

Monatshefte fuer Chemie, 1960 , vol. 91, p. 219,220, 226 Full Text View citing articles Show Details

BASF A.-G.

Patent: DE1259885 , 1964 ; Chem.Abstr., 1968 , vol. 68, # 95982n Full Text Show Details

BAYER AG

Patent: DE2708189 , 1978 ; Chem.Abstr., vol. 90, # 22622 Full Text Show Details

Hodson; Holt

Journal of the Chemical Society [Section] C: Organic, 1968 , p. 1602 Full Text View citing articles Show Details

Patent: FR2276283 , 1976 ; Chem.Abstr., vol. 84, # 150492 Full Text Show Details

Banci

Annali di Chimica (Rome, Italy), 1968 , vol. 58, p. 999 Full Text Show Details

Hide Experimental Procedure

Rhodia Chimie; Centre National de la Recherche Scientifique (CNRS)

Patent: US6610875 B1, 2003 ; Title/Abstract Full Text Show Details

Examples of these are: 2-acetylbenzoic acid, pyruvic acid, 2-oxobutanoic acid, 3-methyl-2-oxobutanoic acid, phenylglyoxylic acid, phenylpyruvic acid, p-methoxyphenylpyruvic acid, 3,4-dimethoxyphenylpyruvic acid, methyl acetoacetate, ...

Rhodia Chimie

Patent: US6166257 A1, 2000 ;

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The following may be mentioned as more particular examples of compounds of formula (Va3) or (Va4): 2-acetylbenzoic acid, pyruvic acid, 2-oxobutanoic acid, 3-methyl-2-oxobutanoic acid, phenylglyoxylic acid, phenylpyruvic acid, p-methoxyphenylpyruvic acid, 3,4-dimethoxyphenylpyruvic acid, methyl acetoacetate, ... Rhodia Chimie

Patent: US6166257 A1, 2000 ;

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Title/Abstract Full Text Show Details

Process according to claim 15, wherein the ketonic compound of formula (Va3) or (Va4) is selected from: 2-acetylbenzoic acid, pyruvic acid, 2-oxobutanoic acid, 3-methyl-2oxobutanoic acid, phenylglyoxylic acid, phenylpyruvic acid, p-methoxyphenylpyruvic acid, 3,4-dimethoxyphenylpyruvic acid, methyl acetoacetate, ... Unilever Home and Personal Care USA, division of Conopco, Inc.

Patent: US6287582 B1, 2001 ;

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Unilever Home and Personal Care USA, division of Conopco, Inc.

Patent: US6294182 B1, 2001 ; Title/Abstract Full Text Show Details

Unilever Home and Personal Care USA, Division of Conopco, Inc.

Patent: US2003/44362 A1, 2003 ; Title/Abstract Full Text Show Details

Representative alpha ketoacids useful for the present invention are as follows. ... 2-Ketopropanoic acid (Pyruvic acid) Methyl 2-ketopropanoate (Methyl pyruvate) Ethyl 2-ketopropanoate (Ethyl pyruvate) Propyl 2ketopropanoate (Propyl pyruvate) 2-Phenyl-2-ketoethanoic acid (Benzoylformic acid) Methyl 2-phenyl-2-ketoethanoate (Methyl benzoylformate) Ethyl 2-phenyl-2-ketoethanoate (Ethyl benzoylformate) 3-Phenyl-2-ketopropanoic acid (Phenylpyruvic acid) ...

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Rx-ID: 9250250

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With H3[PW12O40]; iron nitrate (III)

T=55 - 60°C; 0.166667 h;

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Firouzabadi, Habib; Iranpoor, Nasser; Amani, Kamal

Synthesis, 2003 , # 3 p. 408 - 412 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 23917288 Find similar reactions

With hydrogenchloride; sodium hydroxide; palladium monocarbide; titanium tetrachloride in methanol; water; hydrogen; chlorobenzene; toluene; cyclohexene

Sumika Fine Chemicals Co., Ltd.

Patent: US2003/13911 A1, 2003 ;

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18:Optically active 2-cyclohexyl-2-hydroxy-2-phenylacetic acid

The obtained methyl (S)-2-(benzoylformyloxy)propionate (7.4 g) was dissolved in monochlorobenzene (74 ml), and cyclohexene (5.2 g) and titanium tetrachloride (7.8 g) were added. The reaction mixture was stirred at 20-25° C. for 15 h. The reaction mixture was poured into 6N hydrochloric acid (74 ml) and extracted with toluene (37 ml). The extract was washed with 6N hydrochloric acid (37 ml). To the organic layer were added 25percent aqueous sodium hydroxide solution (20 g) and methanol (74 ml) and the reaction mixture was stirred at 60-65° C. for 2 h. Water (74 ml) and toluene (74 ml) were added to the reaction mixture and the partitioned organic layer was combined with the extract obtained by extracting the aqueous layer again with toluene (74 ml) and concentrated. 6N Hydrochloric acid (29 g) was added to the concentrated residue and the mixture was extracted with ethyl acetate (74 ml). The organic layer was washed with water and concentrated to give a diastereomer mixture (5.2 g) of crude optically active 2-(2'-cyclohexen-1'-yl)-2-hydroxy-2-phenylacetic acid. This (4.1 g) was dissolved in methanol (40 ml) and 5percent palladium carbon (Kawaken Fine Chemicals Co., Ltd., type M, 3 g) was added. The mixture was stirred at atmospheric pressure in a hydrogen gas for 15 min. The catalyst was filtered off and the solvent was evaporated. The residue was purified by silica gel column chromatography (eluent: toluene/ethyl acetate) to give the title compound (3.3 g, yield from benzoylformic acid: 31percent). This was amidated with (S)-phenylethylamine by a conventional method and the optical purity was measured by HPLC, which was found to be 22percent e.e. A

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A: 60% B: 25%

With modified o-iodoxybenzoic acid in water

T=60°C; 3 h;

Thottumkara, Arun P; Vinod, Thottumkara K

Tetrahedron Letters, 2002 , vol. 43, # 4 p. 569 - 572 Title/Abstract Full Text View citing articles Show Details

With nitric acid

Zincke

Justus Liebigs Annalen der Chemie, 1883 , vol. 216, p. 303 Justus Liebigs Annalen der Chemie, 1887 , vol. 240, p. 137 Full Text Show Details

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With potassium tert-butylate; oxygen in N,N-dimethyl-formamide

T=25°C; 6 h; Product distribution; Further Variations:solvent dependence;

Rx-ID: 9331164 Find similar reactions

Czaun, Miklos; Speier, Gabor

Tetrahedron Letters, 2002 , vol. 43, # 34 p. 5961 - 5963 Title/Abstract Full Text View citing articles Show Details

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With potassium tert-butylate; oxygen in N,N-dimethyl-formamide

T=25°C; 6 h; Product distribution; Further Variations:solvent dependence;

Rx-ID: 9341477 Find similar reactions

Czaun, Miklos; Speier, Gabor

Tetrahedron Letters, 2002 , vol. 43, # 34 p. 5961 - 5963 Title/Abstract Full Text View citing articles Show Details

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With potassium tert-butylate; oxygen in N,N-dimethyl-formamide

T=25°C; 6 h; Product distribution; Further Variations:solvent dependence;

Rx-ID: 9353849 Find similar reactions

Czaun, Miklos; Speier, Gabor

Tetrahedron Letters, 2002 , vol. 43, # 34 p. 5961 - 5963 Title/Abstract Full Text View citing articles Show Details

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Multi-step reaction with 2 steps 1.1: Mg / diethyl ether 1.2: diethyl ether / -78 °C 2.1: aq. NaOH / tetrahydrofuran View Scheme

Rx-ID: 14728659 Find similar reactions

Hewawasam, Piyasena; Erway, Matthew; Thalody, George; Weiner, Harvey; Boissard, Christopher G.; Gribkoff, Valentin K.; Meanwell, Nicholas A.; Lodge, Nicholas; Starrett, Jr, John E.

Bioorganic and Medicinal Chemistry Letters, 2002 , vol. 12, # 7 p. 1117 - 1120 Title/Abstract Full Text View citing articles Show Details

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With trifluoroacetic acid

T=23°C; 24 h;

Rx-ID: 8906915 Find similar reactions

Nicolaou; Hughes, Robert; Pfefferkorn, Jeffrey A.; Barluenga, Sofia; Roecker

Chemistry - A European Journal, 2001 , vol. 7, # 19 p. 4280 - 4295 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 25404020 Find similar reactions

91%

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With hydrogenchloride; sodium hypobromide; sodium thiosulfate in dichloromethane; water

KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY

Patent: EP1097917 A1, 2001 ;

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Title/Abstract Full Text Show Details

3:Example 3

Example 3 Preparation of Benzoyl Formic Acid(Compound No. 2)

After putting sodium hypobromite solution (17.5ml of water and 3.54g (0.03mol) of NaOBr) into a 50ml three-necked flask, the temperature was lowered to-5°C. 17.5ml of dichloromethane and 3.8g (0.025mol) of mandelic acid were added slowly, keeping the temperature of the reaction mixture in the range of -5~0°C. 0.65ml of concentrated hydrochloric acid was added dropwise for 5 minutes, keeping the temperature of the reaction mixture at 0°C. After removing the cooler, the reaction mixture was stirred for 5 hours at room temperature. After adding sodium thiosulfate (5ml of water and 1.5g of Na2S2O3*5H2O) to the reaction mixture, the reaction mixture was stirred for 15 minutes. The organic layer was separated, and the aqueous layer was extracted twice with dichloromethane. The combined organic layers were dried over magnesium sulfate, and 3.41g (91percent yield) of the target compound (m.p. = 64 ~ 66°C) was obtained by evaporation.

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With copper diacetate in methanol; water; acetic acid

Henry reaction; 4 h; Heating;

Rx-ID: 8557483 Find similar reactions

Nikalje, Milind D.; Ali, Iliyas Sayyed; Dewkar, Gajanan K.; Sudalai

Tetrahedron Letters, 2000 , vol. 41, # 6 p. 959 - 961 Title/Abstract Full Text View citing articles Show Details

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With hydrogenchloride

2 h; Heating;

Rx-ID: 4586812 Find similar reactions

Imada, Yasushi; Mitsue, Yo; Ike, Kazuo; Washizuka, Ken-Ichi; Murahashi, Shun-Ichi

Bulletin of the Chemical Society of Japan, 1996 , vol. 69, # 7 p. 2079 - 2090 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 24520066 Find similar reactions

Warner-Lambert Company

Patent: US5491172 A1, 1996 ; Title/Abstract Full Text Show Details

22:Synthesis of sulfamic acid(oxophenylacetyl)-2,6-bis(1-methylethyl)phenyl ester

EXAMPLE 22 Synthesis of sulfamic acid(oxophenylacetyl)-2,6-bis(1-methylethyl)phenyl ester This compound was prepared in the same manner as for the title compound of Example 1, except that 2,6-diisopropylphenylacetic acid was replaced with benzoylformic acid, mp 106°-109° C.

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Rx-ID: 4171856 Find similar reactions

39%

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With tetra-n-butylammonium tetrafluoroborate in N,N-dimethyl-formamide

electrochemical synthesis with Pt cathod and Zn anod (3 mA/cm2);

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Pokhodenko, Vitaly D.; Koshechko, Vjacheslav G.; Titov, Vladimir E.; Lopushanskaja, Victorija A.

Tetrahedron Letters, 1995 , vol. 36, # 18 p. 3277 - 3278 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 4437139 Find similar reactions

A: 21% B: 68%

With dihydrogen peroxide; methyltrioxorhenium (VII) in dichloromethane

48 h;

Zhu, Zuolin; Espenson, James H.

Journal of Organic Chemistry, 1995 , vol. 60, # 24 p. 7728 - 7732 Title/Abstract Full Text View citing articles Show Details

A: 65% B: 11%

With dihydrogen peroxide; methyltrioxorhenium (VII) in acetone

48 h;

Zhu, Zuolin; Espenson, James H.

Journal of Organic Chemistry, 1995 , vol. 60, # 24 p. 7728 - 7732 Title/Abstract Full Text View citing articles Show Details

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A: 54% B: 5%

With aluminum oxide; potassium permanganate; water in 1,2-dichloro-ethane

24 h; Ambient temperature;

Zhao; Lee

Synthesis, 1994 , # 9 p. 915 - 916 Title/Abstract Full Text View citing articles Show Details

A: 54% B: 5%

With aluminum oxide; potassium permanganate; water in 1,2-dichloro-ethane

24 h; Ambient temperature;

Zhao; Lee

Synthesis, 1994 , # 9 p. 915 - 916 Title/Abstract Full Text View citing articles Show Details

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With water; ozone

1.) CH2Cl2, -78 deg C; Yield given. Multistep reaction;

Rx-ID: 2175641 Find similar reactions

Wasserman, Harry H.; Ho, Wen-Bin

Journal of Organic Chemistry, 1994 , vol. 59, # 16 p. 4364 - 4366 Title/Abstract Full Text View citing articles Show Details

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Multi-step reaction with 2 steps 1: 95 percent / BSA / CH2Cl2

2: 1). O3, 2.) H2O / 1.) CH2Cl2, -78 deg C View Scheme

Wasserman, Harry H.; Ho, Wen-Bin

Journal of Organic Chemistry, 1994 , vol. 59, # 16 p. 4364 - 4366 Title/Abstract Full Text View citing articles Show Details

Rx-ID: 18352008 Find similar reactions

Synthesize Find similar Rx-ID: 1744161 Find similar reactions

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in ethanol; water

T=30°C; 168 h; Bacillus subtilis subsp. niger IFO 3108, on nutrient agar plates pH 7.0; other solvents, other microorganisms; stereoselectivity; Product distributionMechanism;

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Oda, Shinobu; Kikuchi, Yutaka; Nanishi, Yasushi

Bioscience, Biotechnology, and Biochemistry, 1992 , vol. 56, # 8 p. 1216 - 1220 Title/Abstract Full Text Show Details

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in ethanol; water

T=30°C; 168 h; Bacillus subtilis subsp. niger IFO 3108, on nutrient agar plates pH 7.0; Yield given. Further byproducts given. Yields of byproduct given;

Oda, Shinobu; Kikuchi, Yutaka; Nanishi, Yasushi

Bioscience, Biotechnology, and Biochemistry, 1992 , vol. 56, # 8 p. 1216 - 1220 Title/Abstract Full Text Show Details

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With acetate buffer; bromine in water

T=40°C; var. conc and pH, primary kinetic hydrogen isotope effect; Rate constant;

Rx-ID: 2141662 Find similar reactions

Palou, Josefina; Watt, C. Ian F.

Journal of Chemical Research, Miniprint, 1992 , # 4 p. 977 - 982 Title/Abstract Full Text Show Details

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Synthesize Find similar Rx-ID: 3365755 Find similar reactions

A: 5 % Chromat. B: 64 % Chromat. C: 20 % Chromat. D: 2 % Chromat.

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With 3,3-dimethyldioxirane in acetone

T=0°C; 6 h; other dioxirane (in another solvent), other alkynes, other temperature, other times; Product distribution;

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Curci, Ruggero; Fiorentino, Michele; Fusco, Caterina; Mello, Rossella; Ballistreri, Francesco; et al.

Tetrahedron Letters, 1992 , vol. 33, # 51 p. 7929 - 7932 Title/Abstract Full Text View citing articles Show Details

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With sodium hydrogencarbonate

0.5 h;

Rx-ID: 2806213 Find similar reactions

Kremlev, M. M.; Maznyi, I. S.; Yagupol'skii, L. M.

Journal of Organic Chemistry USSR (English Translation), 1991 , vol. 27, # 1.2 p. 105 - 108 Zhurnal Organicheskoi Khimii, 1991 , vol. 27, # 1 p. 121 - 124 Title/Abstract Full Text Show Details

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Rx-ID: 11716346 Find similar reactions

Kremlev, M. M.; Maznyi, I. S.; Yagupol'skii, L. M.

Journal of Organic Chemistry USSR (English Translation), 1991 , vol. 27, # 1.2 p. 105 - 108 Zhurnal Organicheskoi Khimii, 1991 , vol. 27, # 1 p. 121 - 124 Title/Abstract Full Text Show Details

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Synthesize Find similar Rx-ID: 1551581 Find similar reactions

A: 58.3% B: 4.1 % Spectr. C: 7.4 % Spectr. D: 10.2 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 58.3% B: 4.1 % Spectr. C: 7.4 % Spectr. D: 10.2 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 58.3% B: 4.1 % Spectr. C: 7.4 % Spectr. D: 10.2 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 58.3% B: 4.1 % Spectr. C: 7.4 % Spectr. D: 10.2 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 1551582 Find similar reactions

A: 1.6 % Spectr. B: 3.7 % Spectr. C: 58.3% D: 4.1 % Spectr. E: 7.4 % Spectr. F: 10.2 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Mechanism;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 1551583 Find similar reactions

A: 1.6 % Spectr. B: 58.3% C: 7.4 % Spectr. D: 10.2 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 1551584 Find similar reactions

A: 1.1 % Spectr. B: 58.3% C: 7.4 % Spectr. D: 10.2 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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A: 3.7 % Spectr. B: 58.3% C: 7.4 % Spectr. D: 10.2 % Spectr.

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With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

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Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 1569609 Find similar reactions

31%

fungus Mortierella isabellina;

Holland, Herbert L.; Chernishenko, Michael J.; Conn, Morgan; Munoz, Anthony; Manoharan, T. Samuel; Zawadski, Michael A.

Canadian Journal of Chemistry, 1990 , vol. 68, # 5 p. 696 - 700 Title/Abstract Full Text Show Details

31%

fungus Mortierella isabellina;

Holland, Herbert L.; Chernishenko, Michael J.; Conn, Morgan; Munoz, Anthony; Manoharan, T. Samuel; Zawadski, Michael A.

Canadian Journal of Chemistry, 1990 , vol. 68, # 5 p. 696 - 700 Title/Abstract Full Text Show Details

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Synthesize Find similar Rx-ID: 1627316 Find similar reactions

A: 68.8 % Spectr. B: 3.3 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 68.6 % Spectr. B: 3.3 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 1981157 Find similar reactions

A: 0.5 % Spectr. B: 26.5 % Spectr. C: 14.6 % Spectr. D: 24.6 % Spectr.

With pyridine; 3 A molecular sieve; oxygen; triethylamine; pyridine; compound with copper (II)-nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 1981158 Find similar reactions

A: 21.8 % Spectr. B: 9.1 % Spectr. C: 18% D: 32.9 % Spectr.

With pyridine; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 26.5 % Spectr. B: 11.2 % Spectr. C: 14.6 %

With pyridine; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

Spectr. D: 24.6 % Spectr.

A: 37.4 % Spectr. B: 17.9 % Spectr. C: 11.4 % Spectr. D: 14.3 % Spectr.

With pyridine; triethylamine; pyridine; compound with copper (II)-nitrate in methanol

T=25°C; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 37.4 % Spectr. B: 17.9 % Spectr. C: 11.4 % Spectr. D: 14.3 % Spectr.

With pyridine; triethylamine; pyridine; compound with copper (II)-nitrate in methanol

T=25°C; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 1981159 Find similar reactions

A: 0.5 % Spectr. B: 26.5 % Spectr. C: 11.2 % Spectr. D: 14.6 % Spectr. E: 24.6 % Spectr. F: 5.1 % Spectr.

With pyridine; 3 A molecular sieve; oxygen; triethylamine; pyridine; compound with copper (II)-nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Product distribution;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Find similar Rx-ID: 1981160 Find similar reactions

A: 21.8 % Spectr. B: 9.1 % Spectr. C: 18 % Spectr. D: 32.9 % Spectr. E: 3.7 % Spectr.

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With pyridine; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; or under N2 with or without 3-Angstroem sieves (with a varying amount of Cu(II) oxidant); Product distribution;

Find similar

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 1981163 Find similar reactions

A: 37.4 % Spectr. B: 17.9 % Spectr. C: 14.3 % Spectr. D: 5.4 % Spectr.

With pyridine; triethylamine; pyridine; compound with copper (II)-nitrate in methanol

T=25°C; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 2070569 Find similar reactions

A: 14.0 % Spectr. B: 14.8 % Spectr. C: 27.4 % Spectr. D: 6.1 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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A: 14.0 % Spectr. B: 14.8 % Spectr. C: 27.4 % Spectr. D: 6.1 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 14.0 % Spectr. B: 14.8 % Spectr. C: 27.4 % Spectr. D: 6.1 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 19.5 % Spectr. B: 9.9 % Spectr. C: 9.6 % Spectr. D: 4.6 % Spectr.

With pyridine; water; triethylamine; pyridine; compound with copper (II)-nitrate in methanol

T=25°C; 12 h; Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

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Synthesize Find similar Rx-ID: 2157291 Find similar reactions

A: 5.2 % Spectr. B: 34.8% C: 25.7 % Spectr. D: 19.3 % Spectr.

With pyridine; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 5.2 % Spectr. B: 34.8% C: 25.7 % Spectr. D: 19.3 % Spectr.

With pyridine; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 5.2 % Spectr. B: 34.8% C: 25.7 % Spectr. D: 19.3 % Spectr.

With pyridine; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 5.2 % Spectr. B: 34.8% C: 25.7 % Spectr. D: 19.3 % Spectr.

With pyridine; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 2157292 Find similar reactions

A: 3.5 % Spectr. B: 34.8% C: 25.7 % Spectr. D: 19.3 % Spectr.

With pyridine; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 2157293 Find similar reactions

A: 1.3 % Spectr. B: 34.8% C: 25.7 % Spectr. D: 19.3 % Spectr.

With pyridine; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar Rx-ID: 2393571 Find similar reactions

Synthesize Find similar

A: 62.1% B: 5.2 % Spectr. C: 9.9 % Spectr. D: 7.6 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 62.1% B: 5.2 % Spectr. C: 9.9 % Spectr. D: 7.6 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

A: 62.1% B: 5.2 % Spectr. C: 9.9 % Spectr. D: 7.6 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Synthesize Find similar Rx-ID: 2393573 Find similar reactions

A: 1.5 % Spectr. B: 62.1% C: 9.9 % Spectr. D: 7.6 % Spectr.

With pyridine; water; oxygen; triethylamine; pyridine; compound with copper (II)nitrate in methanol

T=25°C; P=1748 Torr; 12 h; Further byproducts given. Title compound not separated from byproducts;

Jin, Shiow-Jen; Arora, Pramod K.; Sayre, Lawrence M.

Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3011 - 3018 Title/Abstract Full Text View citing articles Show Details