(2-Amino-5-'XH'phenyl)(2-'XH'phenyl)methanone

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Reactions (329)

Yield

Substances (27)

Citations (284)

Conditions

References A

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298

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With hydrogen in dimethylsulfoxide-d6

96 h; variation of pH, ionic strength, temperatute; δH excit, ΔE excit, ΔS excit, ΔG excit; MechanismThermodynamic data;

Ikeda; Nagai

Chemical and Pharmaceutical Bulletin, 1984 , vol. 32, # 3 p. 1080 - 1090 Title/Abstract Full Text View citing articles Show Details

A

299

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D

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Rx-ID: 1581542 Find similar reactions

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With aluminium trichloride

1) ethylene chloride, 1 h 2) ethylene chloride, 45 min; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;

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Acharya, Baman P.; Rao, Y. Ramachandra

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1987 , vol. 26, # 1-12 p. 1133 - 1139 Title/Abstract Full Text Show Details

300

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Rx-ID: 1253295 Find similar reactions

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Bogatskii,A.V. et al.

Pharmaceutical Chemistry Journal, 1977 , vol. 11, # 11 p. 1520 - 1525 Khimiko-Farmatsevticheskii Zhurnal, 1977 , vol. 11, # 11 p. 85 - 91 Full Text View citing articles Show Details

(i) ZnCl2, (ii) aq. HCl, (iii) H2SO4; Multistep reaction;

301

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Rx-ID: 7743787 Find similar reactions

Bogatskii et al.

Voprosy Stereokhimii, 1977 , vol. 6, p. 74 Chem.Abstr., 1979 , vol. 90, # 168556 Full Text Show Details

p-Bromanilin, o-Brombenzoyl-chlorid, wfr. ZnCl2, 210-215grad;

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302

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Rx-ID: 2675476 Find similar reactions

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A: 5% B: 31% C: 8% D: 28%

in N,N,N',N',N'',N''-hexamethylphosphoric triamide

T=100°C; 7 h; Further byproducts given;

Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

A: 5% B: 31% C: 8% D: 28%

in N,N,N',N',N'',N''-hexamethylphosphoric triamide

T=100°C; 7 h; Further byproducts given;

Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

303

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56%

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Rx-ID: 3591682 Find similar reactions

With iodine cloride in dichloromethane

T=-60°C; 5 h;

Walser; Flynn; Mason; Crowley; Maresca; Yaremko; O'Donnell

Journal of Medicinal Chemistry, 1991 , vol. 34, # 3 p. 1209 - 1221 Title/Abstract Full Text View citing articles Show Details

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B

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304

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B: 20 g (56%)

Hide Experimental Procedure

Rx-ID: 24862866 Find similar reactions

Hoffmann-La Roche Inc.

Patent: US4959361 A1, 1990 ;

Title/Abstract Full Text Show Details

6:(2-Amino-5-iodophenvl)(2-chlorophenyl)methanon

EXAMPLE 6 (2-Amino-5-iodophenvl)(2-chlorophenyl)methanon Iodine monochloride, 15 ml (21 g), was added to a solution of 23 g (0.1 mol) of (2-aminophenyl)(2 chlorophenyl)methanone [ref. E. Reeder and L. H. Sternbach, U.S. Pat. No. 3,371,085; February 1968] in 500 ml of methylene chloride cooled to -60° C. After stirring with cooling for 5 hours, the cooling bath was removed and the temperature of the reaction mixture was allowed to reach 0° C. Following the addition of 300 ml of aqueous sodium bisulfite solution, the two phase system was stirred for 10 minutes. The organic phase was separated, dried over sodium sulfate and evaporated. The residue was crystallized from ether/hexane to yield 20 g (56percent) of (2-amino-5-iodophenyl) (2-chlorophenyl)methanone with m.p. 120°-122° C. A

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305

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With potassium hydroxide

5 h; Heatinghydrolysis;

Schleuder; Patow; Richter

Pharmazie, 1983 , vol. 38, # 12 p. 882 - 883 Title/Abstract Full Text View citing articles Show Details

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B

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306

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A: 8.5% B: 49%

T=230 - 240°C; 3 h;

Acharya, Baman Prasad; Misra, Bijaya Kumar; Rao, Yerramalli Ramachandra

Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 12 p. 4417 - 4420 Title/Abstract Full Text Show Details

A: 8.5% B: 49%

T=230 - 240°C; 3 h;

Acharya, Baman Prasad; Misra, Bijaya Kumar; Rao, Yerramalli Ramachandra

Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 12 p. 4417 - 4420 Title/Abstract Full Text Show Details

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307

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Rx-ID: 3916879 Find similar reactions

A: 5% B: 40% D: 6%

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With aluminium trichloride

2) 30 min, 25 deg C; Yield given. Multistep reaction;

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Misra, B. K.; Rao, Y. R.; Mahapatra, S. N.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 11 p. 1132 - 1138 Title/Abstract Full Text Show Details

A

B

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D

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308

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Rx-ID: 3917639 Find similar reactions

With methanol; aluminium trichloride

2) 30 min, 25 deg C; Yield given. Multistep reaction. Yields of byproduct given;

Misra, B. K.; Rao, Y. R.; Mahapatra, S. N.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 11 p. 1132 - 1138 Title/Abstract Full Text Show Details

A

B

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309

Synthesize Find similar Rx-ID: 3492759 Find similar reactions

A: 29% B: 36%

With hydrazine hydrate in ethanol; chloroform

15 h; Ambient temperature;

Hirai, Kentaro; Ishiba, Teruyuki; Sugimoto, Hirohiko; Fujishita, Toshio

Journal of Organic Chemistry, 1981 , vol. 46, # 22 p. 4489 - 4493 Title/Abstract Full Text View citing articles Show Details

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A

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D

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310

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C: 30% D: 22%

Park, Kwanghee Koh; Lee, Jin Joo; Ryu, Jaegyung

Tetrahedron, 2003 , vol. 59, # 39 p. 7651 - 7659 Title/Abstract Full Text View citing articles Show Details

in acetonitrile

4 h; Irradiation;

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311

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Rx-ID: 615588 Find similar reactions

Angel

Journal of the Chemical Society, 1912 , vol. 101, p. 516 Full Text Show Details

T=100 - 180°C; Erhitzten dann auf 200-230grad, Zersetzen des Reaktionsproduktes durch Kochen mit alkoh.Salzsaeure oder durch Erhitzen mit verd.Schwefelsaeure;

A

B

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312

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Rx-ID: 615591 Find similar reactions

With zinc(II) chloride

T=100 - 180°C; dann auf 200-230grad und Kochen des Reaktionsproduktes mit Alkohol und konz. Salzsaeure;

Angel

Journal of the Chemical Society, 1912 , vol. 101, p. 516 Full Text Show Details

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313

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With sodium hydroxide; zinc

Carre

Annales de Chimie (Cachan, France), 1910 , vol. <8>19, p. 220 Bulletin de la Societe Chimique de France, 1909 , vol. <4>5, p. 121 Full Text Show Details

Carre

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 148, p. 492,672 Bulletin de la Societe Chimique de France, 1909 , vol. <4> 5, p. 279 Full Text Show Details

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314

Synthesize Find similar Rx-ID: 3809815 Find similar reactions

A: 5% B: 8% C: 3% D: 12%

With manganese triacetate in acetic acid

T=100°C; 0.116667 h; Further byproducts given;

Nishino; Kurosawa

Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1682 - 1687 Title/Abstract Full Text View citing articles Show Details

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315

Synthesize Find similar Rx-ID: 1604197 Find similar reactions

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A: 16% B: 57% C: 13%

Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

in ethanol

T=60°C; 3 h;

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D

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316

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Rx-ID: 3294018 Find similar reactions

A: 5% B: 12% C: 35% D: 7%

in N,N,N',N',N'',N''-hexamethylphosphoric triamide

T=100°C; 5 h;

Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

A: 5% B: 12% C: 35% D: 7%

in N,N,N',N',N'',N''-hexamethylphosphoric triamide

T=100°C; 5 h;

Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

A: 5% B: 12% C: 35% D: 7%

in N,N,N',N',N'',N''-hexamethylphosphoric triamide

T=100°C; 5 h;

Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

A

B

C

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317

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Rx-ID: 2858767 Find similar reactions

A: 17% B: 43% C: 38%

Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

in ethanol

3 h; Heating;

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318

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A: 5% B: 4% C: 8% D: 3% E: 4% F: 12%

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Nishino; Kurosawa

Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1682 - 1687 Title/Abstract Full Text View citing articles Show Details

With manganese triacetate in acetic acid

T=100°C; 0.116667 h; also with formaldehyde and Ac2O; var. times, var. molar ratio of reagents, also methyl-d3-amino compound; Product distributionMechanism;

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319

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A: 6% B: 10% C: 10%

With manganese triacetate in acetic acid

T=100°C; 0.116667 h;

Nishino; Kurosawa

Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1682 - 1687 Title/Abstract Full Text View citing articles Show Details

A

B

C

D

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320

Synthesize Find similar Rx-ID: 3577564 Find similar reactions

A: 4% B: 4%

With manganese triacetate in acetic acid

T=100°C; 0.116667 h; Further byproducts given;

Nishino; Kurosawa

Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1682 - 1687

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C: 7% D: 14%

Title/Abstract Full Text View citing articles Show Details

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321

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A: 6% B: 4% C: 7% D: 14%

With manganese triacetate in acetic acid

T=100°C; 0.116667 h; Further byproducts given;

Nishino; Kurosawa

Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1682 - 1687 Title/Abstract Full Text View citing articles Show Details

A: 6% B: 4% C: 7% D: 14%

With manganese triacetate in acetic acid

T=100°C; 0.116667 h; Further byproducts given;

Nishino; Kurosawa

Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1682 - 1687 Title/Abstract Full Text View citing articles Show Details

A

B

C

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322

Synthesize Find similar Rx-ID: 3358302 Find similar reactions

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With PPA

T=85 - 90°C; 18 h; Yield given. Yields of byproduct given;

Peet, Norton P.; Sunder, Shyam; Barbuch, Robert J.; Whalon, Michael R.; Huber, Edward W.; Huffman, John C.

Journal of Heterocyclic Chemistry, 1989 , vol. 26, p. 1611 - 1618 Title/Abstract Full Text Show Details

C: 0.34 g

With PPA

T=85 - 90°C; 18 h; Yields of byproduct given;

Peet, Norton P.; Sunder, Shyam; Barbuch, Robert J.; Whalon, Michael R.; Huber, Edward W.; Huffman, John C.

Journal of Heterocyclic Chemistry, 1989 , vol. 26, p. 1611 - 1618 Title/Abstract Full Text Show Details

B: 0.27 g

With PPA

T=85 - 90°C; 18 h; Yields of byproduct given;

Peet, Norton P.; Sunder, Shyam; Barbuch, Robert J.; Whalon, Michael R.; Huber, Edward W.; Huffman, John C.

Journal of Heterocyclic Chemistry, 1989 , vol. 26, p. 1611 - 1618 Title/Abstract Full Text Show Details

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B

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323

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Rx-ID: 3307903 Find similar reactions

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A: 28% B: 31% C: 36%

in propan-1-ol

8 h; Heating;

Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

A: 28% B: 31% C: 36%

in propan-1-ol

8 h; Heating;

Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

A

B

C

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F

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324

Synthesize Find similar Rx-ID: 41573828 Find similar reactions

With iron oxide incorporated titania nanoparticle 0.333333 h; UV-irradiation; Catalytic behaviorKinetics; Reagent/catalyst; Hide Experimental Procedure

Chang, Ya-Hui; Ou, Chun-Chang; Yeh, Hui-Wen; Yang, Chung-Sung

Journal of Molecular Catalysis A: Chemical, 2016 , vol. 412, p. 67 - 77 Title/Abstract Full Text View citing articles Show Details

3.2. Photocatalytic degradation of anthranilic acid

The photoluminescence (PL) emission spectra were used to explore the adsorption ability and the photocatalytic mechanismof the organic anthranilic acid (AA) over FIT. The FIT samples werecalcinated at 400C for 1 h before used in the photo-degradationreaction. The organic acid AA is an amphoteric species with com-plicate metabolism intermediates in organism beings. If releasedto air, AA will exist solely as a vapor in the atmosphere untilphoto-degraded by photochemically-produced hydroxyl radicalsin air. A

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325

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Rx-ID: 2675477 Find similar reactions

A: 31% B: 8% C: 28% D: 3%

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Yamamoto

Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 8 p. 2135 - 2156 Title/Abstract Full Text View citing articles Show Details

in N,N,N',N',N'',N''-hexamethylphosphoric triamide

T=100°C; 7 h; Further byproducts given;

A

B

C

D

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326

Synthesize Find similar Rx-ID: 9495115 Find similar reactions

C: 14% D: 24%

Park, Kwanghee Koh; Lee, Jin Joo; Ryu, Jaegyung

Tetrahedron, 2003 , vol. 59, # 39 p. 7651 - 7659 Title/Abstract Full Text View citing articles Show Details

in acetonitrile

4 h; Irradiation;

A

B

C

D

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327

Synthesize Find similar Rx-ID: 3917638 Find similar reactions

A: 5% B: 3% C: 6% D: 79%

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With aluminium trichloride

T=18 - 20°C; 0.75 h; Further byproducts given;

Misra, B. K.; Rao, Y. R.; Mahapatra, S. N.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 11 p. 1132 - 1138 Title/Abstract Full Text Show Details

A

328

B

C

D

E

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Rx-ID: 3917640 Find similar reactions

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With aluminium trichloride

T=18 - 20°C; 0.75 h; other aromatic compounds, other temperatures; Product distribution;

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Misra, B. K.; Rao, Y. R.; Mahapatra, S. N.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 11 p. 1132 - 1138 Title/Abstract Full Text Show Details

A

B

C

D

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329

Synthesize Find similar Rx-ID: 3917642 Find similar reactions

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A: 3% B: 7% C: 29% D: 40%

With aluminium trichloride

T=5 - 8°C; 0.75 h;

Misra, B. K.; Rao, Y. R.; Mahapatra, S. N.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 11 p. 1132 - 1138 Title/Abstract Full Text Show Details

A: 3% B: 7% C: 29% D: 40%

With aluminium trichloride

T=18 - 20°C; 0.75 h;

Misra, B. K.; Rao, Y. R.; Mahapatra, S. N.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 11 p. 1132 - 1138 Title/Abstract Full Text Show Details

A: 3% B: 7% C: 29% D: 40%

With aluminium trichloride

T=5 - 8°C; 0.75 h;

Misra, B. K.; Rao, Y. R.; Mahapatra, S. N.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 11 p. 1132 - 1138 Title/Abstract Full Text Show Details

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