Cyclohexanone by Asch

Reaxys

PubChem

eMolecules

Reactions (1470)

Yield

Substances (2)

Citations (3478)

Conditions

References A

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595 Synthesize Find similar Rx-ID: 5180827 Find similar reactions

With air; tris(.mu.-oxo)di[(1,4,7-trimethyl-1,4,7-triazanonane)manganese(IV)] hexafluorophosphate in acetonitrile

T=60°C; 8 h; cyclooctane presence, reaction course with time, other temperature and reaction time; Mechanism;

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Lindsay-Smith; Shul'pin

Russian Chemical Bulletin, 1998 , vol. 47, # 11 p. 2313 2315 Title/Abstract Full Text View citing articles Show Details

596 Synthesize Find similar

With methanol; hydrogen; silica gel; nickel

T=249.85°C; var. reaction temp., time, and alcohols; also other cresols; MechanismProduct distribution;

Rx-ID: 5182484 Find similar reactions

Shin, Eun-Jae; Keane, Mark A.

Journal of Catalysis, 1998 , vol. 173, # 2 p. 450 - 459 Title/Abstract Full Text View citing articles Show Details

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597 Synthesize Find similar Rx-ID: 6212471 Find similar reactions

With O(3P)

T=-78°C; P=2 - 2.5 Torr; effect of acetone as solvent; Product distributionMechanism;

Tanner; Kandanarachchi; Das; Brausen; Vo; Camaioni; Franz

Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4587 - 4593 Title/Abstract Full Text View citing articles Show Details

598 Synthesize Find similar

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Rx-ID: 16390529 Find similar reactions

Multi-step reaction with 2 steps 1: aq. H2O2, peroxyacetic acid, <LMnIV(O)3MnIVL>(PF6) (L=1,4,7-trimethyl-1,4,7-triazacyclononane) / acetonitrile / 1 h / 30 °C / reaction in the presence of m-CPBA as peroxy acid; oxidation of saturated hydrocarbons with "H2O2-manganese(IV)complex-peroxycarboxylic acid" reagent; selectivity; effect of peroxy acid; effect of reaction conditions, additives 2: aq. H2O2, m-CPBA acid, <LMnIV(O)3MnIVL>(PF6) (L=1,4,7-trimethyl-1,4,7-triazacyclononane) / acetonitrile / 1 h / 30 °C / reaction in the presence of

Shul'pin; Lindsay-Smith

Russian Chemical Bulletin, 1998 , vol. 47, # 12 p. 2379 2386 Title/Abstract Full Text View citing articles Show Details

peroxyacetic acid as peroxy acid; oxidation of saturated hydrocarbons with "H2O2-manganese(IV)complex-peroxycarboxylic acid" reagent; selectivity; effect of peroxy acid; effect of reaction conditions, additives View Scheme

599 Synthesize Find similar

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Rx-ID: 16740641 Find similar reactions

Multi-step reaction with 2 steps 1: H2O2, AcOH / <(1,4,7-trimethyl-1,4,7-triazacyclononane)2Mn2O3>(PF6)2 / acetonitrile / 1 h / 30 °C 2: peroxyacetic acid / <(1,4,7-trimethyl-1,4,7-triazacyclononane)2Mn2O3>(PF6)2 / acetonitrile / 1 h / 30 °C View Scheme

Lindsay Smith, John R.; Shul'pin, Georgiy B.

Tetrahedron Letters, 1998 , vol. 39, # 27 p. 4909 - 4912 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 24.4 percent / dimethyldioxurane, CBrCl3 / acetone / 20 °C 2: 45 percent / dimethyldioxirane / acetone / 6 h / 22 °C View Scheme

Bravo, Anna; Fontana, Francesca; Fronza, Giovanni; Minisci, Francesco; Zhao, Lihua

Journal of Organic Chemistry, 1998 , vol. 63, # 2 p. 254 263 Title/Abstract Full Text View citing articles Show Details

600 Synthesize Find similar Rx-ID: 24718121 Find similar reactions

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With oxygen in cyclohexane; acetonitrile

Barton; Derek H. R.

Patent: US5756852 A1, 1998 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

2:EXAMPLE 2

EXAMPLE 2 Fe(ClO4)2.4H2 O (0.363 g, 1 mmol), picolinic acid (0.369 g, 3 mmol) and 4-t-butylpyridine (2 ml, 13.5 mmol) and cyclohexane (1.683 g, 20 mmol) were dissolved in 31 ml of acetonitrile. The reaction mixture was stirred at room temperature under a slow stream of O2, H2 O2 (0.3 ml, 3 mmol) and H2 S (g) (5-6 mmol) were added simultaneously to the reaction mixture, portionwise over 2h. The reaction mixture was stirred for a further 1h. The products of the reaction were analyzed by gas chromatography with naphthalene being used as an internal standard. Yield: cyclohexanone (3.11 mmol), cyclohexanol (0.58 mmol).

601 Synthesize Find similar Rx-ID: 24718122 Find similar reactions

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With oxygen in cyclohexane; acetonitrile

Barton; Derek H. R.

Patent: US5756852 A1, 1998 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

3:EXAMPLE 3

EXAMPLE 3 Fe(ClO4)2. 4H2 O (0.363 g, 1 mmol), picolinic acid (0.369 g, 3 mmol), 4-t-butylpyridine (2 ml, 13.5 mmol and cyclohexane (1.683 g, 20 mmol) were dissolved in 31 ml of acetonitrile. The reaction mixture was stirred at room temperature under a slow stream of O2, H2 S (g) (15-20 mmol) was then added portionwise over 3.5 h. The products of the reaction were analyzed by gas chromatography with naphthalene being used as an internal standard. Yield: cyclohexanone (1.15 mmol), cyclohexanol (1.63 mmol).

602 Synthesize Find similar

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Rx-ID: 24727076 Find similar reactions

With oxygen in pyridine; cyclohexane

Hide Experimental Procedure

1:EXAMPLE 1

EXAMPLE 1 Fe(ClO4)2.4H2 O (0.363 g, 1 mmol), picolinic acid (0.369 g, 3 mmol) and cyclohexane (3.366 g, 40 mmol) were dissolved in 33 ml of pyridine. The solution was cooled to 0° C. A slow stream of H2 S (g) was then continuously bubbled through the reaction mixture. Anhydrous H2 O2 (4*1 mmol) in pyridine (4*2 ml) was then added in four portions at 20 minute intervals. Upon each addition of the H O solution, a stream of O was bubbled through the reaction mixture for 10 minutes.

Barton; Derek H. R.

Patent: US5756852 A1, 1998 ; Title/Abstract Full Text Show Details

The products of the reaction were analyzed by gas chromatography with naphthalene being used as an internal standard. Yield: cyclohexanone (1.65 mmol), cyclohexanol (0.47 mmol), unidentified products (0.25 mmol). Efficiency=94percent.

603 Synthesize Find similar

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Rx-ID: 36555110 Find similar reactions

Stage #1: With bromine in dichloromethane; water

1 h; Reflux; Stage #2: With dihydrogen peroxide in dichloromethane; water

4 h; Reflux;

93%

Amati, Alessandro; Dosualdo, Gabriele; Zhao, Lihua; Bravo, Anna; Fontana, Francesca; Minisci, Francesco; Bjorsvik, Hans-Rene

Organic Process Research and Development, 1998 , vol. 2, # 4 p. 261 - 269 Title/Abstract Full Text View citing articles Show Details

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604 Synthesize Find similar Rx-ID: 36603276 Find similar reactions

A: 9% B: 65% C: 6% D: 19%

With 2-hydroxy-1,3-isoindolinedione; manganese(II) 2,4-pentanedionate; oxygen; acetic acid

T=80°C; P=760.051 Torr; 14 h; Time;

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Iwahama, Takahiro; Syojyo, Kouichi; Sakaguchi, Satoshi; Ishii, Yasutaka

Organic Process Research and Development, 1998 , vol. 2, # 4 p. 255 - 260 Title/Abstract Full Text View citing articles Show Details

605 Synthesize Find similar

A: 60 %Spectr. B: 12 %Spectr.

Rx-ID: 36603279 Find similar reactions

With carbon dioxide; hydrogen

T=400°C; P=90009 Torr; Supercritical conditionsFlow reactor;

Hitzler, Martin G.

Organic Process Research and Development, 1998 , vol. 2, # 3 p. 137 - 146 Title/Abstract Full Text View citing articles Show Details

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606 Synthesize Find similar

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Rx-ID: 4509362 Find similar reactions

With [(tris(2-pyridylmethyl)amine)Fe(III)Cl2]ClO4 in acetonitrile

T=25°C; var. Fe-tris(2-pyridylmethyl)amine complexes; other cycloalkanes and alkyl hydroperoxides; Product distributionMechanism;

Kim, Jinheung; Harrison, Roger G.; Kim, Cheal; Que Jr., Lawrence

Journal of the American Chemical Society, 1996 , vol. 118, # 18 p. 4373 - 4379 Title/Abstract Full Text View citing articles Show Details

With FeCl2(tris(2-pyridylmethyl)amine) in acetonitrile

T=25°C; further catalysts; Product distributionMechanismKinetics;

MacFaul, Philip A.; Arends, Isabella W. C. E.; Ingold, Keith U.; Wayner, Danial D. M.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1997 , # 2 p. 135 - 146 Title/Abstract Full Text Show Details

607 Synthesize Find similar

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Rx-ID: 4617901 Find similar reactions

With Na2[Fe(CO)4]

1) MeOMe, -80 deg C, 3 h, 2) MeOMe, CH2Cl2, -80 deg C; Yield given. Multistep reaction;

Lindner, Ekkehard; Leibfritz, Thomas; Fawzi, Riad; Steimann, Manfred

Chemische Berichte/Recueil, 1997 , vol. 130, # 3 p. 347 356 Title/Abstract Full Text View citing articles Show Details

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608 Synthesize Find similar

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Rx-ID: 4664011 Find similar reactions

With pyridine-2-carboxylic acid; dihydrogen peroxide; iodine; iron(III) chloride; lithium chloride; lithium bromide

T=0°C; Product distributionKinetics;

Barton, Derek H.R.; Costas Salgueiro, Miquel; MacKinnon, John

Tetrahedron, 1997 , vol. 53, # 22 p. 7417 - 7428 Title/Abstract Full Text View citing articles Show Details

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609 Synthesize Find similar

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Rx-ID: 4673552 Find similar reactions

in acetonitrile

T=34°C; Product distributionMechanism;

MacFaul, Philip A.; Arends, Isabella W. C. E.; Ingold, Keith U.; Wayner, Danial D. M.

Journal of the Chemical Society, Perkin Transactions 2:

Physical Organic Chemistry (1972-1999), 1997 , # 2 p. 135 - 146 Title/Abstract Full Text Show Details

610 Synthesize Find similar

76 % Chromat.

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Rx-ID: 4684258 Find similar reactions

With sodium hydroxide in water

T=200°C; 1 h;

An, Jingyi; Bagnell, Laurence; Cablewski, Teresa; Strauss, Christopher R.; Trainor, Robert W.

Journal of Organic Chemistry, 1997 , vol. 62, # 8 p. 2505 - 2511 Title/Abstract Full Text View citing articles Show Details

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611 Synthesize Find similar

Rx-ID: 4699446 Find similar reactions

With triphenylphosphine in chloroform-d1

T=50°C; 24 h; Product distribution;

Griesbaum, Karl; Liu, Xuejun; Dong, Yuxiang

Tetrahedron, 1997 , vol. 53, # 15 p. 5463 - 5470 Title/Abstract Full Text View citing articles Show Details

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612 Synthesize Find similar

With triphenylphosphine in chloroform-d1

T=50°C; 48 h; Product distribution;

Rx-ID: 4699688 Find similar reactions

Griesbaum, Karl; Liu, Xuejun; Dong, Yuxiang

Tetrahedron, 1997 , vol. 53, # 15 p. 5463 - 5470 Title/Abstract Full Text View citing articles Show Details

613 Synthesize Find similar

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With triethylamine in dichloromethane

T=-70 - 20°C; Yield given;

Rx-ID: 4707290 Find similar reactions

Nenajdenko, Valentine G.; Vertelezkij, Pavel V.; Koldobskij, Andrej B.; Alabugin, Igor V.; Balenkova, Elizabeth S.

Journal of Organic Chemistry, 1997 , vol. 62, # 8 p. 2483

- 2486 Title/Abstract Full Text View citing articles Show Details

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614 Synthesize Find similar

Rx-ID: 4710694 Find similar reactions

With triphenylphosphine in chloroform-d1

48 h; Ambient temperature; Product distribution;

Griesbaum, Karl; Liu, Xuejun; Dong, Yuxiang

Tetrahedron, 1997 , vol. 53, # 15 p. 5463 - 5470 Title/Abstract Full Text View citing articles Show Details

615 Synthesize Find similar

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Rx-ID: 4760803 Find similar reactions

With potassium permanganate on Y-Zeolite in 1,2-dichloro-ethane

6 h; Ambient temperature;

91%

Sreekumar; Padmakumar, Raghavakaimal

Tetrahedron Letters, 1997 , vol. 38, # 29 p. 5143 - 5146 Title/Abstract Full Text View citing articles Show Details

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616 Synthesize Find similar Rx-ID: 4762512 Find similar reactions

With air; cyclohexane; ozone

T=16.9 - 19.9°C; P=760 Torr; Rate constantMechanism;

Grosjean

International Journal of Chemical Kinetics, 1997 , vol. 29, # 11 p. 855 - 860 Title/Abstract Full Text View citing articles Show Details

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617 Synthesize Find similar

B: 90%

With hydrogen; palladium on activated charcoal in tetrahydrofuran

6 h;

Rx-ID: 4763812 Find similar reactions

Chandrasekhar; Muralidhar; Sarkar, Sanjita

Synthetic Communications, 1997 , vol. 27, # 15 p. 2691 -

2694 Title/Abstract Full Text View citing articles Show Details

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618 Synthesize Find similar

A: 12% B: 67%

Rx-ID: 4767245 Find similar reactions

With tris(cetyl)pyridinium 12-tungstophosphate; dihydrogen peroxide in dichloromethane

T=20°C; 9 h;

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Yamamoto, Hiroyo; Tsuda, Masaya; Sakaguchi, Satoshi; Ishii, Yasutaka

Journal of Organic Chemistry, 1997 , vol. 62, # 21 p. 7174 - 7177 Title/Abstract Full Text View citing articles Show Details

619 Synthesize Find similar

Rx-ID: 4790750 Find similar reactions

Couture, Philippe; Warkentin, John

Canadian Journal of Chemistry, 1997 , vol. 75, # 9 p. 1264 - 1280 Title/Abstract Full Text View citing articles Show Details

in benzene-d6

T=90°C; 24 h; Rate constant;

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620 Synthesize Find similar

With air; cyclohexane; ozone

T=16.9 - 19.9°C; P=760 Torr; Rate constantMechanism;

Rx-ID: 4791448 Find similar reactions

Grosjean

International Journal of Chemical Kinetics, 1997 , vol. 29, # 11 p. 855 - 860 Title/Abstract Full Text View citing articles Show Details

621 Synthesize Find similar

86%

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Rx-ID: 4792443 Find similar reactions

With cerium(III) chloride; sodium iodide in acetonitrile

Marcantoni, Enrico; Nobili, Francesco; Bartoli,

Giuseppe; Bosco, Marcella; Sambri, Letizia

Journal of Organic Chemistry, 1997 , vol. 62, # 12 p. 4183 - 4184 Title/Abstract Full Text Show Details

3 h; Heating;

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622 Synthesize Find similar Rx-ID: 4851157 Find similar reactions

Zhao, Wenyi; Shine, Henry J.; Whittlesey, Bruce R.

Journal of Organic Chemistry, 1997 , vol. 62, # 25 p. 8693 - 8701 Title/Abstract Full Text View citing articles Show Details

With DTMBP in acetonitrile

T=100°C; 0.5 h; other reaction time, temperature; effect of addition of K2CO3; other reaction conditions; Product distribution;

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623 Synthesize Find similar Rx-ID: 4851158 Find similar reactions

Zhao, Wenyi; Shine, Henry J.; Whittlesey, Bruce R.

Journal of Organic Chemistry, 1997 , vol. 62, # 25 p. 8693 - 8701 Title/Abstract Full Text View citing articles Show Details

With DTMBP in acetonitrile

T=100°C; 0.5 h; other reaction time, temperature; effect of addition of K2CO3; other reaction conditions; Product distribution;

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624 Synthesize Find similar Rx-ID: 4854037 Find similar reactions

B: 36% C: 20% D: 2% F: 34%

With K2[PtCl6]; dihydroxo[tetraphenylporphyrinato]antimony(V) hexafluorophosphate; water in acetonitrile

1 h; Irradiationvarious reaction conditions; Product distributionMechanism;

Takagi, Shinsuke; Suzuki, Minako; Shiragami, Tsutomu; Inoue, Haruo

Journal of the American Chemical Society, 1997 , vol. 119, # 37 p. 8712 - 8713 Title/Abstract Full Text View citing articles Show Details

625 Synthesize Find similar

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Rx-ID: 4868483 Find similar reactions

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Asensio, Gregorio; Mello, Rossella; Gonzalez-Nunez, M. Elena; Boix, Carmen; Royo, Jorge

Tetrahedron Letters, 1997 , vol. 38, # 13 p. 2373 - 2376 Title/Abstract Full Text View citing articles Show Details

in acetone

T=0°C; 240 h; in absence and presence of O2; deuterium labelling; kinetic isotope effect; Mechanism;

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626 Synthesize Find similar

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Rx-ID: 4868484 Find similar reactions

Asensio, Gregorio; Mello, Rossella; Gonzalez-Nunez, M. Elena; Boix, Carmen; Royo, Jorge

Tetrahedron Letters, 1997 , vol. 38, # 13 p. 2373 - 2376 Title/Abstract Full Text View citing articles Show Details

in gas T=25°C; 144 h; deuterium labeling; kinetic isotope effect; Mechanism;

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627 Synthesize Find similar Rx-ID: 4868488 Find similar reactions

With nitrous acid methyl ester; oxygen

T=24.9°C; P=740 Torr; Irradiation; Quantum yield;

Aschmann, Sara M.; Chew, Andrew A.; Arey, Janet; Atkinson, Roger

Journal of Physical Chemistry A, 1997 , vol. 101, # 43 p. 8042 - 8048 Title/Abstract Full Text View citing articles Show Details

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628 Synthesize Find similar

A: 5 % Chromat.

With water; nitrogen(IV) oxide; ozone in dichloromethane

T=0°C; Oxidation; nitration; 1 h;

Rx-ID: 5052829 Find similar reactions

Suzuki, Hitomi; Takeuchi, Toyomi; Mori, Tadashi

Bulletin of the Chemical Society of Japan, 1997 , vol. 70, #

B: 88 % Chromat.

12 p. 3111 - 3115 Title/Abstract Full Text View citing articles Show Details

A: 67 % Chromat. B: 2 % Chromat.

With nitrogen(IV) oxide; ozone in dichloromethane

T=-20°C; Nitration; oxidation; 2 h;

Suzuki, Hitomi; Takeuchi, Toyomi; Mori, Tadashi

Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 12 p. 3111 - 3115 Title/Abstract Full Text View citing articles Show Details

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629 Synthesize Find similar

A: 40 % Chromat. B: 51 % Chromat.

Rx-ID: 5052832 Find similar reactions

With nitrogen(IV) oxide; ozone in dichloromethane

T=0°C; Oxidation; nitration; 3 h;

Suzuki, Hitomi; Takeuchi, Toyomi; Mori, Tadashi

Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 12 p. 3111 - 3115 Title/Abstract Full Text View citing articles Show Details

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630 Synthesize Find similar

A: 70 % Chromat. B: 20 % Chromat.

Rx-ID: 5053751 Find similar reactions

With nitrogen(IV) oxide; ozone in dichloromethane

T=0°C; Nitration; oxidation; 1 h;

Suzuki, Hitomi; Takeuchi, Toyomi; Mori, Tadashi

Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 12 p. 3111 - 3115 Title/Abstract Full Text View citing articles Show Details

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631 Synthesize Find similar

A: 79 % Chromat. B: 19 % Chromat.

With nitrogen(IV) oxide; ozone in dichloromethane

T=0°C; Nitration; oxidation; 3 h;

632

Rx-ID: 5070016 Find similar reactions

Suzuki, Hitomi; Takeuchi, Toyomi; Mori, Tadashi

Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 12 p. 3111 - 3115 Title/Abstract Full Text View citing articles Show Details

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A: 37 % Chromat. B: 43 % Chromat.

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Rx-ID: 5071029 Find similar reactions

With nitrogen(IV) oxide; ozone in dichloromethane

T=0°C; Oxidation; nitration; 5 h;

Suzuki, Hitomi; Takeuchi, Toyomi; Mori, Tadashi

Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 12 p. 3111 - 3115 Title/Abstract Full Text View citing articles Show Details

633 Synthesize Find similar

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Rx-ID: 24656376 Find similar reactions

Sun Company, Inc. (R and M)

Patent: US5672778 A1, 1997 ;

in cyclohexane

Hide Experimental Procedure

Title/Abstract Full Text Show Details

4:Example 4

Example 4 Dry cyclohexyl hydroperoxide (54percent), 0.5 ml, was added to a stirred solution of cyclohexane, 2.6 ml, containing a mixture of ruthenium triacetylacetonate, 1.1 mg, and cobalt bisacetylacetonate, 1.0 mg. The reaction mixture was stirred for 5 hours at room temperature. Iodometric titration showed that over 97percent of the hydroperoxide had reacted. Gas chromatography of the reaction mixture showed that the major product of reaction was cyclohexanol and the minor product was cyclohexanone formed in a 9.5/1 ratio. A

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634 Synthesize Find similar

Rx-ID: 1999535 Find similar reactions

A: 1.548 mmol B: 0.124 mmol C: 0.504 mmol

With tert.-butylhydroperoxide; sodium nitrite; iron nitrate (III) in pyridine; acetic acid

T=60°C; 11 h;

Barton, Derek H. R.; Warinthorn, Chavasiri

Tetrahedron, 1994 , vol. 50, # 1 p. 47 - 60 Title/Abstract Full Text View citing articles Show Details

A: 0.39 mmol B: 0.13 mmol C: 1.15 mmol

With pyridine; pyridine-2-carboxylic acid; [iron(II)(H2O)6](perchlorate)2; dihydrogen peroxide; ascorbic acid powder; sodium nitrite

Ambient temperaturevar. anion, saturated hydrocarbon, oxidant, additive; Mechanism;

Barton; Chabot; Delanghe; Hu; Le Gloahec; Wahl

Tetrahedron Letters, 1995 , vol. 36, # 39 p. 7007 - 7010 Title/Abstract Full Text View citing articles Show Details

With acetate buffer; dihydrogen peroxide; sodium nitrite in water

T=25°C; Oxidation; pH=4.27; Kinetics; Further Variations:pH-valuesReagents;

Rudakov; Lobachev; Geletii; Balavoine

Russian Journal of Organic Chemistry, 1996 , vol. 32, # 4 p. 500 - 507 Title/Abstract Full Text View citing articles Show Details

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635 Synthesize Find similar

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Rx-ID: 4414909 Find similar reactions

With pyridine-2-carboxylic acid; air; acetic acid; iron nitrate (III)

Ambient temperature; Product distributionMechanism;

Snelgrove, Darren W.; MacFaul, Philip A.; Ingold, Keith U.; Wayner, Danial D. M.

Tetrahedron Letters, 1996 , vol. 37, # 6 p. 823 - 826 Title/Abstract Full Text View citing articles Show Details

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636 Synthesize Find similar

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Rx-ID: 4414917 Find similar reactions

A: 0.16 mmol B: 0.22 mmol C: 0.07 mmol D: 0.08 mmol E: 1.40 mmol

With ferric picolinate complexes; dihydrogen peroxide; phosphorous acid trimethyl ester in acetic acid

T=0 - 20°C; 3 h; depends on reaction conditions (reagents, temperature etc.); Product distributionKinetics;

Barton, Derek H. R.; Beck, Albert H.; Delanghe, Nathalie C.

Tetrahedron Letters, 1996 , vol. 37, # 10 p. 1555 - 1558 Title/Abstract Full Text View citing articles Show Details

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637 Synthesize Find similar

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Rx-ID: 4423583 Find similar reactions

A: 0.22 mmol B: 0.07 mmol C: 0.08 mmol D: 1.40 mmol

With ferric picolinate complexes; dihydrogen peroxide; phosphorous acid trimethyl ester in pyridine; acetic acid

T=0°C; 3 h; Further byproducts given;

Barton, Derek H. R.; Beck, Albert H.; Delanghe, Nathalie C.

Tetrahedron Letters, 1996 , vol. 37, # 10 p. 1555 - 1558 Title/Abstract Full Text View citing articles Show Details

638 Synthesize Find similar

A: 60 % Spectr. B: 40 % Spectr.

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Rx-ID: 4430629 Find similar reactions

With acetic acid in acetonitrile-D3; water

Deslongchamps, Pierre; Dory, Yves L.; Li, Shigui

Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 41 - 50 Title/Abstract Full Text View citing articles Show Details

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639 Synthesize Find similar

A: 57 % Spectr. B: 43 % Spectr.

Rx-ID: 4435542 Find similar reactions

With acetic acid in [D3]acetonitrile; water

Deslongchamps, Pierre; Dory, Yves L.; Li, Shigui

Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 41 - 50 Title/Abstract Full Text View citing articles Show Details

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640 Synthesize Find similar

A: 50 % Spectr. B: 50 % Spectr.

Rx-ID: 4442336 Find similar reactions

With acetic acid in acetonitrile-D3; water

Deslongchamps, Pierre; Dory, Yves L.; Li, Shigui

Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 41 - 50 Title/Abstract Full Text View citing articles Show Details

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641 Synthesize Find similar

A: 80 % Spectr. B: 20 % Spectr.

Rx-ID: 4443563 Find similar reactions

With acetic acid in acetonitrile-D3; water

Deslongchamps, Pierre; Dory, Yves L.; Li, Shigui

Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 41 - 50 Title/Abstract Full Text View citing articles Show Details

642 Synthesize Find similar

B: 20%

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Rx-ID: 4553398 Find similar reactions

Lorber, Christian Y.; Pauls, Irene; Osborn, John A.

Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 7-8 p. 755 - 758 Title/Abstract Full Text View citing articles Show Details

With MoVIO2(acetylacetone)2; diphenylether; toluene-4-sulfonic acid in toluene

T=100°C; 10 h; Product distribution;

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643 Synthesize Find similar

A: 29% B: 70%

Rx-ID: 4561337 Find similar reactions

With chloroperoxidase from fungus Caldaromyces fumago; potassium chloride; dihydrogen peroxide in water

4 h;

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Zaks, Aleksey; Yabannavar, Asha V.; Dodds, David R.; Evans, C. Anderson; Das, Pradip R.; Malchow, Rodney

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8692 - 8695 Title/Abstract Full Text View citing articles Show Details

644 Synthesize Find similar

A: 46% B: 52%

Rx-ID: 4561338 Find similar reactions

With chloroperoxidase from fungus Caldaromyces fumago; dihydrogen peroxide; potassium bromide in water

4 h;

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Zaks, Aleksey; Yabannavar, Asha V.; Dodds, David R.; Evans, C. Anderson; Das, Pradip R.; Malchow, Rodney

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8692 - 8695 Title/Abstract Full Text View citing articles Show Details

645 Synthesize Find similar

B: 70%

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Rx-ID: 4576160 Find similar reactions

With zirconium tetra-t-butoxide in toluene

T=0°C; 9 h; other primary and secondary alcohols; var. zirconium catalysts; var. reaction conditions; Product distribution;

Krohn, Karsten; Knauer, Birgit; Kuepke, Jochen; Seebach, Dieter; Beck, Albert K.; Hayakawa, Michyay

Synthesis, 1996 , # 11 p. 1341 - 1344 Title/Abstract Full Text View citing articles Show Details

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646 Synthesize Find similar Rx-ID: 4584873 Find similar reactions

With sodium hydroxide; potassium carbonate

1) heating, 2) drying; Yield given. Multistep reaction;

Kukharev

Russian Chemical Bulletin, 1996 , vol. 45, # 4 p. 885 - 889 Title/Abstract Full Text View citing articles Show Details

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647 Synthesize Find similar Rx-ID: 4588211 Find similar reactions

A: 33% B: 32% C: 6%

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio; Giordano, Federico; Scarpati, Rachele

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8677 - 8680 Title/Abstract Full Text View citing articles Show Details

in benzene

0.5 h; Heating; Further byproducts given;

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648 Synthesize Find similar Rx-ID: 4588212 Find similar reactions

A: 32% B: 6% C: 32%

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio; Giordano, Federico; Scarpati, Rachele

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8677 - 8680 Title/Abstract Full Text View citing articles Show Details

in benzene

0.5 h; Heating; Further byproducts given;

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649 Synthesize

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A: 6% B: 32%

Find similar

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio; Giordano, Federico; Scarpati, Rachele

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8677 - 8680 Title/Abstract Full Text View citing articles Show Details

in benzene

0.5 h; Heating; Further byproducts given. Title compound not separated from byproducts;

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650 Synthesize Find similar

B: 84%

Rx-ID: 4588214 Find similar reactions

With diethyl-sulphide in tetrachloromethane

0.5 h;

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio; Giordano, Federico; Scarpati, Rachele

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8677 - 8680 Title/Abstract Full Text View citing articles Show Details

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651 Synthesize Find similar Rx-ID: 4592840 Find similar reactions

With sodium hydroxide; potassium carbonate

1) heating, 2) drying; Yield given. Multistep reaction;

Kukharev

Russian Chemical Bulletin, 1996 , vol. 45, # 4 p. 885 - 889 Title/Abstract Full Text View citing articles Show Details

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652 Synthesize Find similar Rx-ID: 4604612 Find similar reactions

Synthesize Find similar

Barton, Derek H. R.; Delanghe, Nathalie C.

Tetrahedron Letters, 1996 , vol. 37, # 45 p. 8137 - 8140 Title/Abstract Full Text View citing articles Show Details

With pentacarbonyliron(0); dihydrogen peroxide in acetic acid

Mechanism;

653 Synthesize Find similar

Synthesize Find similar

Rx-ID: 4604613 Find similar reactions

Synthesize Find similar

Barton, Derek H. R.; Delanghe, Nathalie C.

Tetrahedron Letters, 1996 , vol. 37, # 45 p. 8137 - 8140 Title/Abstract Full Text View citing articles Show Details

With sodium azide; pentacarbonyliron(0); dihydrogen peroxide in acetic acid

further inorganic salts; Product distributionMechanism;

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654 Synthesize Find similar

Synthesize Find similar

Rx-ID: 4616256 Find similar reactions

With chlorine

T=298°C; Irradiation; Rate constant;

Villenave, Eric; Lesclaux, Robert

Journal of Physical Chemistry, 1996 , vol. 100, # 34 p. 14372 - 14382 Title/Abstract Full Text View citing articles Show Details

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655 Synthesize Find similar

Synthesize Find similar

Rx-ID: 4616261 Find similar reactions

With oxygen; chlorine

T=298°C; P=760 Torr; Irradiation; Rate constant;

Villenave, Eric; Lesclaux, Robert

Journal of Physical Chemistry, 1996 , vol. 100, # 34 p. 14372 - 14382 Title/Abstract Full Text View citing articles Show Details

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656 Synthesize Find similar

A: 57% B: 37%

in benzene

T=25°C; Irradiation; Quantum yieldRate constant;

Rx-ID: 4618762 Find similar reactions

Hu, Shengkui; Neckers, Douglas C.

Journal of Organic Chemistry, 1996 , vol. 61, # 18 p. 6407

- 6415 Title/Abstract Full Text View citing articles Show Details

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657 Synthesize Find similar

Rx-ID: 4660029 Find similar reactions

With triethylammonium phosphinate; tris(triphenylphosphine)ruthenium(II) chloride

T=40°C; 3 h; Yield given. Yields of byproduct given;

Khai, Bui The; Arcelli, Antonio

Tetrahedron Letters, 1996 , vol. 37, # 36 p. 6599 - 6602 Title/Abstract Full Text View citing articles Show Details

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658 Synthesize Find similar Rx-ID: 4755368 Find similar reactions

With dihydrogen peroxide; n-dipropylamine; molecular sieve in acetone

T=80°C; 20 h; other catalysts and solvents; Product distribution;

Kulkarni; Murthy; Ramachandra Rao; Subrahmanyam; Rama Rao

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 1996 , vol. 35, # 10 p. 875 - 877 Title/Abstract Full Text View citing articles Show Details

659 Synthesize Find similar

Synthesize Find similar

Rx-ID: 4955069 Find similar reactions

With (1'-14C)-dodecanoic acid; dimethyl sulfoxide in chlorobenzene

T=12 - 30°C; 0.05 h; Equilibrium constantRate constant;

Shumkina; Voronina; Perkel'

Russian Journal of Applied Chemistry, 1996 , vol. 69, # 2 p. 255 - 262 Title/Abstract Full Text View citing articles Show Details

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660 Synthesize Find similar Rx-ID: 6713134

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With dihydrogen peroxide in pyridine; acetic acid

Yield given. Yields of byproduct given;

Barton, Derek H. R.; Delanghe, Nathalie C.

Tetrahedron Letters, 1996 , vol. 37, # 45 p. 8137 - 8140 Title/Abstract Full Text View citing articles Show Details

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661 Synthesize Find similar

Rx-ID: 7076586 Find similar reactions

With oxygen; zeolite NaY

Ambient temperatureIrradiation; Mechanism;

Sun, Hai; Blatter, Fritz; Frei, Heinz

Journal of the American Chemical Society, 1996 , vol. 118, # 29 p. 6873 - 6879 Title/Abstract Full Text View citing articles Show Details

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662 Synthesize Find similar Rx-ID: 7449953 Find similar reactions

With sodium azide; dihydrogen peroxide in pyridine; acetic acid

Yield given. Further byproducts given. Yields of byproduct given;

Barton, Derek H. R.; Delanghe, Nathalie C.

Tetrahedron Letters, 1996 , vol. 37, # 45 p. 8137 - 8140 Title/Abstract Full Text View citing articles Show Details

663 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17586498 Find similar reactions

Multi-step reaction with 2 steps 1: 45 percent / oxygen, tetraphenylporphyrine / CH2Cl2 / 6 h / -20 °C / Irradiation 2: 6 percent / benzene / 0.5 h / Heating View Scheme

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio; Giordano, Federico; Scarpati, Rachele

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8677 - 8680 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 45 percent / oxygen, tetraphenylporphyrine / CH2Cl2 / 6 h / -20 °C / Irradiation 2: Et2S / CCl4 / 0.5 h View Scheme

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio; Giordano, Federico; Scarpati, Rachele

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8677 - 8680 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 65 percent / oxygen, tetraphenylporphyrine / CH Cl / 1.5 h / -20 °C / Irradiation

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio; Giordano, Federico; Scarpati, Rachele

2: 6 percent / benzene / 0.5 h / Heating View Scheme

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8677 - 8680 Title/Abstract Full Text View citing articles Show Details

Hide Details

Multi-step reaction with 2 steps 1: 65 percent / oxygen, tetraphenylporphyrine / CH2Cl2 / 1.5 h / -20 °C / Irradiation 2: Et2S / CCl4 / 0.5 h View Scheme

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio; Giordano, Federico; Scarpati, Rachele

Journal of Organic Chemistry, 1996 , vol. 61, # 24 p. 8677 - 8680 Title/Abstract Full Text View citing articles Show Details

664 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17877302 Find similar reactions

Multi-step reaction with 2 steps 1: 1.) (i-Pr)2NEt, Me3SiOTf; 2.) Bu4F / 1.) 0 deg C to room temp., dichloromethane, overnight; 2.) 3 h, room temp., dichloromethane 2: 43 percent Spectr. / AcOH / H2O; CD3CN View Scheme

Deslongchamps, Pierre; Dory, Yves L.; Li, Shigui

Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 41 - 50 Title/Abstract Full Text View citing articles Show Details

665 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17877396 Find similar reactions

Multi-step reaction with 2 steps 1: 82 percent / (i-Pr)3Al / toluene; CH2Cl2 / -78 deg C to room temp., then 12 h 2: 40 percent Spectr. / AcOH / H2O; CD3CN View Scheme

Deslongchamps, Pierre; Dory, Yves L.; Li, Shigui

Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 41 - 50 Title/Abstract Full Text View citing articles Show Details

666 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17877459 Find similar reactions

Multi-step reaction with 2 steps 1: 78 percent / (i-Pr)3Al / toluene; CH2Cl2 / -78 deg C to room temp., then 12 h 2: 50 percent Spectr. / AcOH / H2O; CD3CN View Scheme

Deslongchamps, Pierre; Dory, Yves L.; Li, Shigui

Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 41 - 50 Title/Abstract Full Text View citing articles Show Details

667 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17880117 Find similar reactions

Multi-step reaction with 2 steps 1: 94 percent / (i-Pr)3Al / toluene; CH2Cl2 / -78 deg C to room temp., then 12 h 2: 20 percent Spectr. / AcOH / H2O; CD3CN View Scheme

Deslongchamps, Pierre; Dory, Yves L.; Li, Shigui

Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 41 - 50 Title/Abstract Full Text View citing articles Show Details

668 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17913083 Find similar reactions

Multi-step reaction with 3 steps 1: 1.) NBS; 2.) triethylamine / 1.) CD3CN, MeOH, 10 min, NMR tube; 2.) CD3CN, MeOH, NMR tube 2: 94 percent / (i-Pr)3Al / toluene; CH2Cl2 / -78 deg C to room temp., then 12 h 3: 20 percent Spectr. / AcOH / H2O; CD3CN View Scheme

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Deslongchamps, Pierre; Dory, Yves L.; Li, Shigui

Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 41 - 50 Title/Abstract Full Text View citing articles Show Details

669

A: 79.5%

Rx-ID: 24543278 Find similar reactions

Kuraray Co., Ltd.

Patent: US5500484 A1, 1996 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

23:EXAMPLE 23

EXAMPLE 23 To 100 g of 1N hydrochloric acid, 50 g of the 2,2-spirocyclohexyl-5-phenyl-1,3-dioxane obtained in Example 20 was added, and the mixture was stirred at 30° C. for 12 hours. Gas chromatography was carried out to make sure that the reaction was completed, cyclohexanone formed was separated azeotropically with water, and 50 g of toluene was added to the resulting residue, followed by cooling. The, the crystals deposited were collected by filtration, followed by drying to obtain 26 g of 2-phenyl-1,3-propanediol (yield: 79.5percent). A

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670 Synthesize Find similar

B: 8%

With ozone in pentane

T=-78°C; Yield given;

Rx-ID: 3788767 Find similar reactions

Hon, Yung-Son; Lu, Ling

Tetrahedron Letters, 1993 , vol. 34, # 33 p. 5309 - 5312 Title/Abstract Full Text View citing articles

Show Details

With ozone in pentane

T=-78°C;

B: 8%

Hon, Yung-Son; Lin, Sheng-Wun; Lu, Ling; Chen, YaoJung

Tetrahedron, 1995 , vol. 51, # 17 p. 5019 - 5034 Title/Abstract Full Text View citing articles Show Details

671 Synthesize Find similar

Synthesize Find similar

Rx-ID: 3788782 Find similar reactions

17 % Chromat.

With air; GifIV = pyridine; acetic acid; iron(II) chloride; zinc

further oxidizing systems;

Barton, Derek H. R.; Lee, Kyu Wan; Mehl, Wolf; Ozbalik, Nubar; Zhang, Li

Tetrahedron, 1990 , vol. 46, # 11 p. 3753 - 3768 Title/Abstract Full Text View citing articles Show Details

With 4 A molecular sieve; ozone; diisopropylamine

1.) pentane, -78 deg C then to room temp.; 2.) CH2Cl2, reflux; Yield given. Multistep reaction;

Hon, Yung-Son; Lin, Sheng-Wun; Lu, Ling; Chen, YaoJung

Tetrahedron, 1995 , vol. 51, # 17 p. 5019 - 5034 Title/Abstract Full Text View citing articles Show Details

17 % Chromat.

With pyridine; air; GifIV = FeCl2*4H2O; acetic acid; zinc

further oxidizing systems and other hydrocarbons with C=CH2 group; Product distributionMechanism;

Barton, Derek H. R.; Lee, Kyu Wan; Mehl, Wolf; Ozbalik, Nubar; Zhang, Li

Tetrahedron, 1990 , vol. 46, # 11 p. 3753 - 3768 Title/Abstract Full Text View citing articles Show Details

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672 Synthesize Find similar Rx-ID: 3856143 Find similar reactions

With thiophene; Pd-MoO3-Al2O3

T=399.9°C; var. sulfided and unsulfided catalysts; Product distribution;

Dobrovolszky, Maria; Paal, Zoltan

Bulletin des Societes Chimiques Belges, 1987 , vol. 96, # 11-12 p. 1009 - 1016 Title/Abstract Full Text Show Details

With nickel

T=200°C; 1.25 h; activities and selectivities of catalyst; further catalysts; effect of reaction temperature on the catalytic activity and selectivity to cyclohexanone;

Uemichi, Yoshio; Sakai, Takeshi; Kanazuka, Takaji

Chemistry Letters, 1989 , p. 777 - 780 Title/Abstract Full Text Show Details

With potassium hydroxide; aluminium-chromium

T=250 - 450°C; other catalyst; Product distribution;

Sibarov, D. A.; Dokuchaeva, T. G.; Lezdin, S. U.; Titova, A. V.; Karpenko, E. V.

J. Appl. Chem. USSR (Engl. Transl.), 1988 , vol. 61, # 4 p. 811 - 815,731 - 734 Title/Abstract Full Text Show Details

Hide Details

With cobalt; carbon

T=200°C; var. catalysts, temp.; Product distribution;

Uemichi, Yoshio; Shouji, Kiyoshi; Sugioka, Masatoshi; Kanazuka, Takaji

Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 1 p. 385 - 387 Title/Abstract Full Text Show Details

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673 Synthesize Find similar

Synthesize Find similar

Rx-ID: 3959439 Find similar reactions

A: 59% B: 6% C: 21%

With oxygen in acetonitrile

Irradiation; Quantum yield;

Mella, Mariella; Freccero, Mauro; Albini, Angelo

Journal of the Chemical Society, Chemical Communications, 1995 , # 1 p. 41 - 42 Title/Abstract Full Text View citing articles Show Details

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674 Synthesize Find similar

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Rx-ID: 3983632 Find similar reactions

B: 65%

With 2-(1,3-dioxolan-2-ylidene)malononitrile in N,N-dimethyl-formamide

49 h; Ambient temperature;

Miura, Tsuyoshi; Masaki, Yukio

Tetrahedron Letters, 1994 , vol. 35, # 43 p. 7961 - 7964 Title/Abstract Full Text View citing articles Show Details

B: 65%

With 2-(1,3-dioxolan-2-ylidene)malononitrile in N,N-dimethyl-formamide

49 h; Ambient temperature;

Miura, Tsuyoshi; Masaki, Yukio

Tetrahedron, 1995 , vol. 51, # 38 p. 10477 - 10486 Title/Abstract Full Text View citing articles Show Details

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675 Synthesize Find similar Rx-ID: 4030583 Find similar reactions

With tert.-butylhydroperoxide; molecular sieve in chlorobenzene

T=29.9°C; 6 h; var. of catalyst; Product distribution;

Venkatathri, N.; Hegde, S. G.; Sivasanker, S.

Journal of the Chemical Society, Chemical Communications, 1995 , # 2 p. 151 - 152 Title/Abstract Full Text View citing articles Show Details

676 Synthesize Find similar

A: 1% B: 64% C: 31%

Synthesize Find similar

Rx-ID: 4074182 Find similar reactions

Lau, Tai-Chu; Mak, Chi-Keung

Journal of the Chemical Society, Chemical Communications, 1995 , # 9 p. 943 - 944 Title/Abstract Full Text View citing articles Show Details

With [2,2']bipyridinyl; Balt;RuO3(OH)2gt;; trifluoroacetic acid in dichloromethane

T=22°C; 0.216667 h; other ligands: none, pyridine, 1,10-phenanthroline; var. 'terminal oxidants'; Product distribution;

677 Synthesize Find similar

Synthesize Find similar

Rx-ID: 4151454 Find similar reactions

With potassium dichromate; sulfuric acid in diethyl ether

T=25°C; 1 h;

37%

Harris; Lee; Dorr; Singaram

Tetrahedron Letters, 1995 , vol. 36, # 17 p. 2921 - 2924 Title/Abstract Full Text View citing articles Show Details

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678 Synthesize Find similar

Rx-ID: 4152764 Find similar reactions

With 4,4'-diaminostilbene-2,2'-disulfonic acid in dichloromethane

0.5 h; Yield given. Yields of byproduct given;

Shellhamer, Dale F.; Anstine, D. Timothy; Gallego, Kelly M.; Ganesh, Brian R.; Hanson, Aaron A.; et al.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1995 , # 4 p. 861 - 866 Title/Abstract Full Text View citing articles Show Details

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679 Synthesize Find similar

Synthesize Find similar

Rx-ID: 4159317 Find similar reactions

B: 33 % Chromat. C: 36 % Chromat. D: 31 %

in acetone

48 h; Ambient temperature; Further byproducts given;

Bravo, Anna; Fontana, Francesca; Fronza, Giovanni; Mele, Andrea; Minisci, Francesco

Journal of the Chemical Society, Chemical Communications, 1995 , # 15 p. 1573 - 1574 Title/Abstract Full Text View citing articles

Chromat.

Show Details

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680 Synthesize Find similar

B: 64 % Chromat.

Rx-ID: 4159321 Find similar reactions

With oxygen; 3,3-dimethyldioxirane in acetone

P=760 Torr; 48 h; Ambient temperature;

Bravo, Anna; Fontana, Francesca; Fronza, Giovanni; Mele, Andrea; Minisci, Francesco

Journal of the Chemical Society, Chemical Communications, 1995 , # 15 p. 1573 - 1574 Title/Abstract Full Text View citing articles Show Details

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681 Synthesize Find similar

A: 33 % Chromat. B: 36 % Chromat. C: 31 % Chromat.

Rx-ID: 4159323 Find similar reactions

With 3,3-dimethyldioxirane in acetone

48 h; Ambient temperature;

Bravo, Anna; Fontana, Francesca; Fronza, Giovanni; Mele, Andrea; Minisci, Francesco

Journal of the Chemical Society, Chemical Communications, 1995 , # 15 p. 1573 - 1574 Title/Abstract Full Text View citing articles Show Details

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682 Synthesize Find similar

Al-Awadi, Nouria A.; Mathew, Tommy

International Journal of Chemical Kinetics, 1995 , vol. 27, # 9 p. 843 - 848 Title/Abstract Full Text Show Details

T=440.6°C; var. temp., Ea; Rate constantThermodynamic data;

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Rx-ID: 4251108 Find similar reactions

683 Synthesize Find similar

A: 3% B: 90%

With KSF clay; dimethyl sulfoxide

0.05 h; Irradiation;

Rx-ID: 4258464 Find similar reactions

Villemin; Hammadi

Synthetic Communications, 1995 , vol. 25, # 20 p. 3141 -

3144 Title/Abstract Full Text View citing articles Show Details

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684 Synthesize Find similar

Rx-ID: 4334772 Find similar reactions

With benzophenone in hexane

Irradiation; Mechanism;

Post, Alan J.; Morrison, Harry

Journal of the American Chemical Society, 1995 , vol. 117, # 29 p. 7812 - 7813 Title/Abstract Full Text View citing articles Show Details

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685 Synthesize Find similar

A: 6% B: 58%

Rx-ID: 4362984 Find similar reactions

With potassium tert-butylate in tetrahydrofuran

T=24 - 26°C; 0.333333 h;

Trofimov, Boris A.; Tarasova, Ol'ga A.; Sigalov, Mark V.; Mikhaleva, Al'bina I.

Tetrahedron Letters, 1995 , vol. 36, # 50 p. 9181 - 9184 Title/Abstract Full Text View citing articles Show Details

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686 Synthesize Find similar

Rx-ID: 4448653 Find similar reactions

With air

Yield given. Yields of byproduct given;

Blankespoor, Ronald L.; Smart, Robert P.; Batts, Eric D.; Kiste, Alan A.; Lew, Rebecca E.; Vliet, Marc E. Vander

Journal of Organic Chemistry, 1995 , vol. 60, # 21 p. 6852 - 6859 Title/Abstract Full Text View citing articles Show Details

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687 Synthesize Find similar

Rx-ID: 4454945 Find similar reactions

A: 90 % Chromat. B: 55 % Chromat.

With sulfuric acid

2 h; Heating; Title compound not separated from byproducts;

Chiba, Toshiro; Sakagami, Hirotoshi; Murata, Miki; Okimoto, Mitsuhiro

Journal of Organic Chemistry, 1995 , vol. 60, # 21 p. 6764 - 6770 Title/Abstract Full Text View citing articles Show Details

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688 Synthesize Find similar

Synthesize Find similar

Rx-ID: 4457693 Find similar reactions

D: 2.4%

Kukharev, B. F.

Russian Chemical Bulletin, 1995 , vol. 44, # 9 p. 1769 1770 Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 9 p. 1838 - 1839 Title/Abstract Full Text Show Details

T=190°C; 36 h; Further byproducts given. Yields of byproduct given;

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689 Synthesize Find similar

With (1'-14C)-dodecanoic acid; 4,4'-diphenylsulfide in chlorobenzene

T=18°C; Equilibrium constant;

Rx-ID: 4491244 Find similar reactions

Shumkina, T. F.; Voronina, S. G.; Krut-skii, D. L.; Perkel', A. L.

Russian Journal of Applied Chemistry, 1995 , vol. 68, # 2.2 p. 251 - 257 Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1995 , vol. 68, # 2 p. 290 - 297 Title/Abstract Full Text Show Details

690 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17812146 Find similar reactions

Multi-step reaction with 2 steps 1: 88 percent / 0.8 M aq. NaOCl / 0.5 h / Ambient temperature 2: 90 percent Chromat. / 3 N aq. H2SO4 / 2 h / Heating View Scheme

Chiba, Toshiro; Sakagami, Hirotoshi; Murata, Miki; Okimoto, Mitsuhiro

Journal of Organic Chemistry, 1995 , vol. 60, # 21 p. 6764 - 6770 Title/Abstract Full Text View citing articles Show Details

691 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17815616 Find similar reactions

Multi-step reaction with 2 steps 1: 6.25 h / Ambient temperature; Irradiation 2: air View Scheme

Blankespoor, Ronald L.; Smart, Robert P.; Batts, Eric D.; Kiste, Alan A.; Lew, Rebecca E.; Vliet, Marc E. Vander

Journal of Organic Chemistry, 1995 , vol. 60, # 21 p. 6852 - 6859 Title/Abstract Full Text View citing articles Show Details

692 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17831819 Find similar reactions

Multi-step reaction with 3 steps 1: 59 percent / DEAD, PPh3 / tetrahydrofuran / 1.) room temp., 2 h, 2.) 50 deg C, 16 h 2: 6.25 h / Ambient temperature; Irradiation 3: air View Scheme

Blankespoor, Ronald L.; Smart, Robert P.; Batts, Eric D.; Kiste, Alan A.; Lew, Rebecca E.; Vliet, Marc E. Vander

Journal of Organic Chemistry, 1995 , vol. 60, # 21 p. 6852 - 6859 Title/Abstract Full Text View citing articles Show Details

693 Synthesize Find similar

Synthesize Find similar

Rx-ID: 17966371 Find similar reactions

Multi-step reaction with 2 steps 1: tert-butyl hydroperoxide, manganese complex / acetonitrile / 6 h / Ambient temperature; depends on type of manganese Schiff base complex 2: 23 percent / tert-butyl hydroperoxide, manganese Schiff base complex / acetonitrile / 6 h / Ambient temperature View Scheme

Ganeshpure, Pralhad A.; Tembe, Gopal L.; Satish, Sheo

Tetrahedron Letters, 1995 , vol. 36, # 48 p. 8861 - 8864 Title/Abstract Full Text View citing articles Show Details