Cyclohexanone by Asch

Reaxys

PubChem

eMolecules

Reactions (1470)

Yield

Substances (2)

Citations (3478)

Conditions

References A

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991 Synthesize Find similar

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Rx-ID: 3843124 Find similar reactions

With lithium diisopropyl amide

1.) THF, -78 deg C, 25 min, 2.) -78 deg C --> room temperature, overnight; Yield given. Multistep reaction;

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Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1539 - 1545 Title/Abstract Full Text View citing articles Show Details

992 Synthesize Find similar

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Rx-ID: 3843189 Find similar reactions

With lithium diisopropyl amide

1.) THF, -78 deg C, 25 min, 2.) -78 deg C --> room temperature, overnight; Yield given. Multistep reaction;

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1539 - 1545 Title/Abstract Full Text View citing articles

Show Details

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993 Synthesize Find similar

Rx-ID: 3855609 Find similar reactions

With dihydrogen peroxide; iron powder in water; acetonitrile

pH 4; Yield given. Yields of byproduct given;

Sugimoto, Hiroshi; Sawyer, Donald T.

Journal of the American Chemical Society, 1984 , vol. 106, # 15 p. 4283 - 4285 Title/Abstract Full Text View citing articles Show Details

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994 Synthesize Find similar Rx-ID: 3856128 Find similar reactions

A: 2 % Turnov. B: 4 % Turnov. C: 40 % Turnov. D: 43 % Turnov.

With pyridine; lead(IV) acetate; lithium chloride in benzene

T=65 - 70°C; 0.25 h; Further byproducts given;

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Nikishin, G. I.; Kapustina, N. I.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1984 , vol. 33, # 6 p. 1235 - 1239 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1984 , # 6 p. 1345 - 1348 Title/Abstract Full Text View citing articles Show Details

995 Synthesize Find similar A: 48.2 % Turnov. B: 51.6 % Turnov.

Rx-ID: 3856131 Find similar reactions

With dihydrogen peroxide; chloroacetic acid

T=120°C; different catalysts; Product distribution;

Neginskaya; Freidin

Journal of applied chemistry of the USSR, 1984 , vol. 57, # 12 pt 2 p. 2525 - 2529 Title/Abstract Full Text View citing articles Show Details

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996 Synthesize Find similar

Rx-ID: 3856135

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A: 23% B: 3% C: 8%

With iodine; mercury(II) oxide in benzene

8 h; Irradiation;

Suginome, Hiroshi; Yamada, Shinji

Journal of Organic Chemistry, 1984 , vol. 49, # 20 p. 3753 - 3762 Title/Abstract Full Text View citing articles Show Details

A: 23% B: 3% C: 8%

With iodine; mercury(II) oxide in benzene

8 h; Irradiation;

Suginome, Hiroshi; Yamada, Shinji

Journal of Organic Chemistry, 1984 , vol. 49, # 20 p. 3753 - 3762 Title/Abstract Full Text View citing articles Show Details

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997 Synthesize Find similar Rx-ID: 3856136 Find similar reactions

A: 25 % Turnov. B: 6 % Turnov. C: 37 % Turnov. D: 3 % Turnov. E: 3 % Turnov.

With pyridine; lead(IV) acetate; copper diacetate in benzene

T=80°C; other ratio of cyclohexanol : LTA-Cu(OAc)2; Product distribution;

Nikishin, G. I.; Kapustina, N. I.

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998 Synthesize Find similar Rx-ID: 3856137 Find similar reactions

A: 4 % Turnov. B: 40 % Turnov. C: 43 % Turnov. D: 2 % Turnov.

With pyridine; lead(IV) acetate; lithium chloride in benzene

T=65 - 70°C; 0.25 h; Further byproducts given;

Nikishin, G. I.; Kapustina, N. I.

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999 Synthesize Find similar

Rx-ID: 3856138 Find similar reactions

A: 92 % Chromat. B: 2 % Chromat. C: 5 % Chromat.

With 98.6 coulombs; water; [ruthenium(III)(2,2':6',2''-terpyridine)(2,2'-bipyridine)(H2O)]

T=25°C; pH 6.8 (0.1 M in (HPO4)2-/(H2PO4)- buffer), at 0.8 V to generate <Ru(trpy)(bpy)O>2+ from <Ru(trpy) (bpy)H2O>2+; Rate constant;

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Thompson, Mark S.; Giovani, Wagner F. De; Moyer, Bruce A.; Meyer, Thomas J.

Journal of Organic Chemistry, 1984 , vol. 49, # 25 p. 4972 - 4977 Title/Abstract Full Text View citing articles Show Details

1000 Synthesize Find similar

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Rx-ID: 3927081 Find similar reactions

Bouchoux, G.; Houriet, R.

Tetrahedron Letters, 1984 , vol. 25, # 50 p. 5755 - 5758 Title/Abstract Full Text View citing articles Show Details

Gas phase. Determ. by ICR spect.; Equilibrium constantThermodynamic data;

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1001 Synthesize Find similar

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Rx-ID: 6727931 Find similar reactions

Harada; Sakakibara; Kunai; Sasaki

Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 2 p. 611 - 612 Title/Abstract Full Text View citing articles Show Details

in acetonitrile

T=5 - 10°C; var. cond. of electrolyses; Product distribution;

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1002 Synthesize Find similar

A: 75%

With pyridine; copper diacetate in benzene

T=20°C; 0.5 h;

1003

Rx-ID: 7054810 Find similar reactions

Kapustina, N. I.; Spektor, S. S.; Nikishin, G. I.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1984 , vol. 33, # 12 p. 2490 - 2497 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1984 , # 12 p. 2721 - 2729 Title/Abstract Full Text View citing articles Show Details

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A: 82% B: 95.5 % Turnov. C: 5 % Turnov.

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With pyridine; copper diacetate in benzene

T=80°C; 2 h;

Rx-ID: 7445230 Find similar reactions

Kapustina, N. I.; Spektor, S. S.; Nikishin, G. I.

1004 Synthesize Find similar

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Rx-ID: 19144912 Find similar reactions

Multi-step reaction with 2 steps 1: Fe(II), H2O2 / acetonitrile; H2O / pH 4 2: Fe(II), H2O2 / acetonitrile View Scheme

Sugimoto, Hiroshi; Sawyer, Donald T.

Journal of the American Chemical Society, 1984 , vol. 106, # 15 p. 4283 - 4285 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: Fe(II), H2O2 / acetonitrile; H2O / pH 4 2: Fe(II), H2O2 / acetonitrile View Scheme

Sugimoto, Hiroshi; Sawyer, Donald T.

Journal of the American Chemical Society, 1984 , vol. 106, # 15 p. 4283 - 4285 Title/Abstract Full Text View citing articles Show Details

1005 Synthesize Find similar

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Rx-ID: 19441829 Find similar reactions

Multi-step reaction with 2 steps 1: 82 percent / KH / tetrahydrofuran / 1.) 0 degC, 1h, 2.) room temperature, 19h; argon atmosphere 2: 79 percent Spectr. / 4.5M H2SO4 / diethyl ether / Ambient temperature View Scheme

Ogura, K.; Yamashita, M.; Suzuki, M.; Furukawa, S.; Tsuchinashi, G.

Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 6 p. 1637 - 1642 Title/Abstract Full Text Show Details

1006 Synthesize Find similar

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Rx-ID: 19452388 Find similar reactions

Multi-step reaction with 2 steps 1: 80 percent / n-BuLi / tetrahydrofuran; hexane / 17 h / Ambient temperature 2: 79 percent Spectr. / 4.5M H2SO4 / diethyl ether / Ambient temperature View Scheme

Ogura, K.; Yamashita, M.; Suzuki, M.; Furukawa, S.; Tsuchinashi, G.

Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 6 p. 1637 - 1642 Title/Abstract Full Text Show Details

1007 Synthesize Find similar

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Rx-ID: 20598067 Find similar reactions

Multi-step reaction with 2 steps 1: 65 percent / toluene / 1 h / Heating 2: NaOH / H2O; tetrahydrofuran / 18 h / Ambient temperature View Scheme

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1531 - 1537 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 83 percent / toluene / 0.75 h / Heating 2: NaOH / H2O; tetrahydrofuran / 18 h / Ambient temperature View Scheme

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1531 - 1537 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 78 percent / toluene / 0.75 h / Heating 2: NaOH / H2O; tetrahydrofuran / 18 h / Ambient temperature View Scheme

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1531 - 1537 Title/Abstract Full Text View citing articles Show Details

1008 Synthesize Find similar

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Rx-ID: 20601543 Find similar reactions

Multi-step reaction with 4 steps 1: 79 percent / toluene / 20 °C 2: 1,4-diazabicyclo<2.2.2>octane / benzene / 0.07 h / Ambient temperature 3: 65 percent / toluene / 1 h / Heating 4: NaOH / H2O; tetrahydrofuran / 18 h / Ambient temperature View Scheme

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1531 - 1537 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1: 79 percent / toluene / 20 °C 2: 1,4-diazabicyclo<2.2.2>octane / benzene / 0.07 h / Ambient temperature 3: 83 percent / toluene / 0.75 h / Heating 4: NaOH / H2O; tetrahydrofuran / 18 h / Ambient temperature View Scheme

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1531 - 1537 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 4 steps 1: 79 percent / toluene / 20 °C 2: 1,4-diazabicyclo<2.2.2>octane / benzene / 0.07 h / Ambient temperature 3: 78 percent / toluene / 0.75 h / Heating 4: NaOH / H2O; tetrahydrofuran / 18 h / Ambient temperature View Scheme

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1531 - 1537 Title/Abstract Full Text View citing articles Show Details

1009 Synthesize Find similar

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Rx-ID: 20614775 Find similar reactions

Multi-step reaction with 3 steps 1: 1,4-diazabicyclo<2.2.2>octane / benzene / 0.07 h / Ambient temperature 2: 65 percent / toluene / 1 h / Heating 3: NaOH / H2O; tetrahydrofuran / 18 h / Ambient temperature View Scheme

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1531 - 1537 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: 1,4-diazabicyclo<2.2.2>octane / benzene / 0.07 h / Ambient temperature 2: 83 percent / toluene / 0.75 h / Heating 3: NaOH / H2O; tetrahydrofuran / 18 h / Ambient temperature View Scheme

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1531 - 1537 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 3 steps 1: 1,4-diazabicyclo<2.2.2>octane / benzene / 0.07 h / Ambient temperature 2: 78 percent / toluene / 0.75 h / Heating 3: NaOH / H2O; tetrahydrofuran / 18 h / Ambient temperature View Scheme

Ramage, Robert; Griffiths, Gareth J.; Shutt, Fiona E.; Sweeney, John N. A.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1531 - 1537 Title/Abstract Full Text View citing articles Show Details

1010 Synthesize Find similar

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Rx-ID: 1814954 Find similar reactions

With H3(+) P=760 Torr; other reagent and pressure; Product distribution;

Giacomello, Pierluigi; Pizzabiocca, Adriano; Renzi, Gabriele; Speranza, Maurizio

Tetrahedron Letters, 1983 , vol. 24, # 38 p. 4157 - 4160 Title/Abstract Full Text View citing articles Show Details

1011 Synthesize Find similar

85%

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Rx-ID: 1820894 Find similar reactions

Gravel, D.; Herbert, J.; Thoraval, D.

Canadian Journal of Chemistry, 1983 , vol. 61, p. 400 - 410 Title/Abstract Full Text Show Details

in benzene

6 h; Ambient temperatureIrradiation;

1012 Synthesize Find similar

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Rx-ID: 1826681 Find similar reactions

With oxygen; 5,15,10,20-tetraphenylporphyrin

1.) irradiation, -78 deg C, Freon 11/deuterochloroform, 2.) -38 deg C; Yield given. Multistep reaction. Yields of byproduct given;

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Geller, George G.; Foote, Christopher S.; Pechman, David B.

Tetrahedron Letters, 1983 , vol. 24, # 7 p. 673 - 676 Title/Abstract Full Text View citing articles Show Details

1013 Synthesize Find similar

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Rx-ID: 1983942 Find similar reactions

Garst, Michael E.; Arrhenius, Peter

Journal of Organic Chemistry, 1983 , vol. 48, # 1 p. 16 24 Title/Abstract Full Text View citing articles Show Details

Yield given. Multistep reaction. Yields of byproduct given;

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1014 Synthesize Find similar

Rx-ID: 1999515 Find similar reactions

A: 350 mmol B: 132 mmol

With oxygen; anatase TiO2/Pt

20 h; Irradiation;

Giannotti, C.; Greneur, S. Le; Watts, O.

Tetrahedron Letters, 1983 , vol. 24, # 46 p. 5071 - 5072 Title/Abstract Full Text View citing articles Show Details

A: 0.350 mmol B: 0.132 mmol

With oxygen; Pt/titania

20 h; Irradiationvar. semiconductors; Product distribution;

Giannotti, C.; Greneur, S. Le; Watts, O.

Tetrahedron Letters, 1983 , vol. 24, # 46 p. 5071 - 5072 Title/Abstract Full Text View citing articles Show Details

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1015 Synthesize Find similar

Rx-ID: 1999516 Find similar reactions

A: 25% B: 10%

With IMn(tetraphenylporphyrinato); iodosylbenzene in dichloromethane; water

12 h;

Hill, Craig L.; Smegal, John A.; Henly, Timothy J.

Journal of Organic Chemistry, 1983 , vol. 48, # 19 p. 3277 - 3281 Title/Abstract Full Text View citing articles Show Details

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1016 Synthesize Find similar Rx-ID: 1999523 Find similar reactions

With MnTPPCl; iodosylbenzene in benzene

T=25°C; 5 h; Further byproducts given;

Hill, Craig L.; Schardt, Bruce C.

Journal of the American Chemical Society, 1980 , vol. 102, # 20 p. 6374 - 6375 Title/Abstract Full Text View citing articles Show Details

With tetraphenylporphinatomanganese(III) bromide; iodosylbenzene in dichloromethane

T=25°C; 5 h; further solvent; Further byproducts given;

Hill, Craig L.; Schardt, Bruce C.

Journal of the American Chemical Society, 1980 , vol. 102, # 20 p. 6374 - 6375 Title/Abstract Full Text View citing articles Show Details

A: 27 % Chromat. B: 1 % Chromat. C: 5 % Chromat. D: 5 % Chromat.

With lt;BrMnIVTPP(OIPh)gt;2O in chlorobenzene

T=25°C; 1 h; further reagents (BrMnIIITPP); Product distributionMechanism;

Smegal, John A.; Hill, Craig L.

Journal of the American Chemical Society, 1983 , vol. 105, # 11 p. 3515 - 3521 Title/Abstract Full Text View citing articles Show Details

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1017 Synthesize Find similar Rx-ID: 1999525 Find similar reactions

With MnTPPCl; iodosylbenzene in benzene

T=25°C; 5 h;

Hill, Craig L.; Schardt, Bruce C.

Journal of the American Chemical Society, 1980 , vol. 102, # 20 p. 6374 - 6375 Title/Abstract Full Text View citing articles Show Details

A: 1 % Chromat. B: 24 % Chromat. C: 5 % Chromat. D: 16 % Chromat.

With lt;ClMnIVTPP(OIPh)gt;2O in chlorobenzene

T=25°C; 1 h; further reagents (2,2-diphenyl-1-picrylhydrazyl, ClMnIIITPP); Product distributionMechanism;

Smegal, John A.; Hill, Craig L.

Journal of the American Chemical Society, 1983 , vol. 105, # 11 p. 3515 - 3521 Title/Abstract Full Text View citing articles Show Details

With MnTPPCl; iodosylbenzene in benzene

T=25°C; 5 h; Further byproducts given;

Hill, Craig L.; Schardt, Bruce C.

Journal of the American Chemical Society, 1980 , vol. 102,

# 20 p. 6374 - 6375 Title/Abstract Full Text View citing articles Show Details

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1018 Synthesize Find similar Rx-ID: 1999527 Find similar reactions

A: 1 % Chromat. B: 3 % Chromat. C: 30 % Chromat. D: 5 % Chromat.

With lt;N3MnIVTPPgt;2O in dichloromethane

T=25°C; 24 h; Product distributionMechanism;

Smegal, John A.; Hill, Craig L.

Journal of the American Chemical Society, 1983 , vol. 105, # 11 p. 3515 - 3521 Title/Abstract Full Text View citing articles Show Details

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1019 Synthesize Find similar

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Rx-ID: 2027393 Find similar reactions

Terman, L. M.; Sedel'nikova, V. N.; Kublanova, N. M.

J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 4 p. 838 - 843,736 - 740 Title/Abstract Full Text Show Details

in benzene

T=59.9°C; 10 h; Product distributionMechanismKinetics;

1020 Synthesize Find similar

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Rx-ID: 2035080 Find similar reactions

With potassium hydroxide

Shiner, Christopher S.; Fisher, Allison M.; Yacoby, Fred

Tetrahedron Letters, 1983 , vol. 24, # 51 p. 5687 - 5690 Title/Abstract Full Text View citing articles Show Details

1021

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A: 0.3% B: 80% C: 18%

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Rx-ID: 2055328 Find similar reactions

With potassium carbonate; palladium on activated charcoal in water

T=300°C; 10 h; Product distribution;

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Paushkin, Ya. M.; Nizova, S. A.; Stytsenko, V. D.; Belov, P. S.; Rozovskii, A. Ya.; D'yakonov, A. Yu.

Doklady Chemistry, 1983 , vol. 271, p. 217 - 219 Dokl. Akad. Nauk SSSR Ser. Khim., 1983 , vol. 271, # 1 p. 110 - 112 Title/Abstract Full Text Show Details

1022 Synthesize Find similar

Rx-ID: 2057867 Find similar reactions

Reinholdt, Karin; Margaretha, Paul

Helvetica Chimica Acta, 1983 , vol. 66, # 8 p. 2534 - 2539 Title/Abstract Full Text Show Details

in cyclohexane

Irradiation;

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1023 Synthesize Find similar

A: 58% B: 22% C: 15%

Rx-ID: 2061696 Find similar reactions

Reinholdt, Karin; Margaretha, Paul

Helvetica Chimica Acta, 1983 , vol. 66, # 8 p. 2534 - 2539 Title/Abstract Full Text Show Details

in isopropyl alcohol

Irradiationfurther solvents; effect of the solvent on the product/yield distribution; Quantum yieldMechanismProduct distribution; A

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1024 Synthesize Find similar Rx-ID: 2143879 Find similar reactions

With di-tert-butyl peroxide in chlorobenzene

T=140°C; 4 h; various temperatures, rates of formation; KineticsMechanismProduct distribution;

1025

Pastushenko, E. V.; Kostyukevich, L. L.; Zlot-skii, S. S.; Rakhmankulov, D. L.

J. Appl. Chem. USSR (Engl. Transl.), 1983 , vol. 56, # 10 p. 2328 - 2333,2159 - 2163 Title/Abstract Full Text Show Details

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B: 55%

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Rx-ID: 2158571 Find similar reactions

With tert-butylhypochlorite in tetrachloromethane

20 h; Ambient temperatureother reagent;

El-Wassimy, M.T.M.; Joergensen, K.A.; Lawesson S.-O. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2201 - 2204 Title/Abstract Full Text Show Details

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1026 Synthesize Find similar

A: 40 % Chromat. B: 42%

With n-butyllithium in hexane

72 h; Heating;

Rx-ID: 2164475 Find similar reactions

Richey, Herman G.; Cabre, Socorro

Journal of Organic Chemistry, 1983 , vol. 48, # 21 p. 3822 - 3825 Title/Abstract Full Text View citing articles Show Details

1027 Synthesize Find similar

97.5 % Turnov.

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Rx-ID: 2192549 Find similar reactions

With triethylamine in acetonitrile

Ambient temperatureelectrolysis; MechanismProduct distribution;

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Thomas, Hans G.; Gabriel, Juergen; Fleischhauer, Joerg; Raabe, Gerhard

Chemische Berichte, 1983 , vol. 116, # 1 p. 375 - 388 Title/Abstract Full Text Show Details

1028

With phenyl(tribromomethyl)mercury in benzene

T=75 - 80°C; 2 h;

1029

Rx-ID: 2343400 Find similar reactions

Huan, Zhenwei; Landgrebe, John A.; Peterson, Kimberly

Journal of Organic Chemistry, 1983 , vol. 48, # 24 p. 4519 - 4523 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 2560188 Find similar reactions

With tetrabutyl ammonium fluoride in tetrahydrofuran

1 h; Ambient temperature; Product distribution;

Nakamura, Eiichi; Shimizu, Makoto; Kuwajima, Isao; Sakata, J.; Yokoyama, K.; Noyori, R.

Journal of Organic Chemistry, 1983 , vol. 48, # 7 p. 932 945 Title/Abstract Full Text View citing articles Show Details

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1030 Synthesize Find similar

A: 20% B: 30%

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Rx-ID: 2675271 Find similar reactions

Richey, Herman G.; Erickson, Wayne F.

Journal of Organic Chemistry, 1983 , vol. 48, # 23 p. 4349 - 4357 Title/Abstract Full Text View citing articles Show Details

in hexane

1.) ice bath, 2.) reflux, 4 h;

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1031 Synthesize Find similar

Rx-ID: 2720749 Find similar reactions

With pentacyanocobaltate(II)(3-); hydrogen in water

P=760 Torr; 10 h; different reaction times, other solvent, different reagent ratio (effect of 2,2'-bipyridyl on product distribution); Product distributionMechanism;

Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918 Title/Abstract Full Text View citing articles Show Details

1032 Synthesize Find similar

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Rx-ID: 3252814 Find similar reactions

Hand, Vincent C.; Snyder, Martin P.; Margerum, Dale W.

Journal of the American Chemical Society, 1983 , vol. 105, # 12 p. 4022 - 4025 Title/Abstract Full Text View citing articles Show Details

in water

T=25°C; 0.5 M ionic strength; Rate constant;

1033 Synthesize Find similar

A: 80% B: 2% C: 7%

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Rx-ID: 3855607 Find similar reactions

With dipotassium peroxodisulfate; copper(II) sulfate in water; acetonitrile

T=60°C; 6 h;

Arnoldi, Claudio; Citterio, Attilio; Minisci, Francesco

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 531 - 542 Title/Abstract Full Text Show Details

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1034 Synthesize Find similar

Rx-ID: 3926428 Find similar reactions

With hydrogen; Rh/Al2O3

P=760 Torr; Ambient temperaturesolid substrate; solid catalyst; various metal salts of substrate; various conversion rates; various product distributions; various reaction times; other catalysts; catalyst particles coated by teflon; Product distributionMechanism;

Lamartine, Roger; Perrin, Robert; Thozet, Alain; Perrin, Monique

Molecular Crystals and Liquid Crystals (1969-1991), 1983 , vol. 96, p. 57 - 70 Title/Abstract Full Text Show Details

1035 Synthesize Find similar

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Rx-ID: 4070803 Find similar reactions

Shanmuganathan, Sp.; Vivekanandan, S.; Gajalakshmi, G.

Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1983 , vol. 22, # 5 p. 413 - 414 Title/Abstract Full Text Show Details

With sulfuric acid

T=28°C; 0.25 h; various concentrations of oxidant; Ea; KineticsThermodynamic dataMechanism;

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1036 Synthesize Find similar

With hydrogen in water

T=45°C; P=760 Torr; 10 h; Yield given. Yields of byproduct given;

Rx-ID: 7916154 Find similar reactions

Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918 Title/Abstract Full Text View citing articles Show Details

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1037 Synthesize Find similar Rx-ID: 8271618 Find similar reactions

A: 34 % Turnov. B: 15 % Turnov. C: 30 % Turnov. D: 15 % Turnov.

T=270°C; other temperature; Product distribution;

Galoci, Jan; Prochazka, Milos; Klinotova, Eva

Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # l p. 1729 - 1733 Title/Abstract Full Text Show Details

1038 Synthesize Find similar

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Rx-ID: 18604887 Find similar reactions

Multi-step reaction with 2 steps 1: O2, Na ascorbate, trioctylmethylammonium chloride / Mn(tetraphenylporphyrin dianion)(Cl) / 20 °C / 760 Torr / pH 8.5 (tris buffer) 2: O2, Na ascorbate, trioctylmethylammonium chloride / Mn(tetraphenylporphyrin dianion)(Cl) / 20 °C / 760 Torr / pH 8.5 (tris buffer) View Scheme

Mansuy, Daniel; Fontecave, Marc; Bartoli, JeanFrancois

Journal of the Chemical Society, Chemical Communications, 1983 , # 6 p. 253 - 254 Title/Abstract Full Text View citing articles Show Details

1039 Synthesize Find similar

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Rx-ID: 18866460 Find similar reactions

Multi-step reaction with 2 steps 1: 65 percent / pyridinium chlorochromate / CH2Cl2 / 24 h / Ambient temperature 2: cyclohexane / Irradiation View Scheme

Reinholdt, Karin; Margaretha, Paul

Helvetica Chimica Acta, 1983 , vol. 66, # 8 p. 2534 - 2539 Title/Abstract Full Text Show Details

1040 Synthesize Find similar

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Rx-ID: 18867181 Find similar reactions

Multi-step reaction with 3 steps 1: 60 percent / KF / bis-(2-hydroxy-ethyl) ether / 5 h / 140 °C 2: 65 percent / pyridinium chlorochromate / CH2Cl2 / 24 h / Ambient temperature 3: cyclohexane / Irradiation

Reinholdt, Karin; Margaretha, Paul

Helvetica Chimica Acta, 1983 , vol. 66, # 8 p. 2534 - 2539 Title/Abstract Full Text Show Details

View Scheme

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1041 Synthesize Find similar

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Rx-ID: 26937647 Find similar reactions

Rosenblum; Bucheister; Chang; Cohen; Marsi; Samuels; Scheck; Sofen; Watkins

Pure and Applied Chemistry, 1983 , vol. 56, # 1 p. 129 136 Title/Abstract Full Text View citing articles Show Details

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1042 Synthesize Find similar

B: 80%

Rx-ID: 1533409 Find similar reactions

With boron trifluoride diethyl etherate; lead dioxide in tetrahydrofuran; water

0.5 h; Ambient temperature; Yields of byproduct given;

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Ghiringhelli, Dario

Synthesis, 1982 , # 7 p. 580 - 582 Title/Abstract Full Text Show Details

1043 Synthesize Find similar

Rx-ID: 1624978 Find similar reactions

With PPA T=200°C; 10 h; Product distribution;

Kukharev, B. F.; Stankevich, V. K.

Chemistry of Heterocyclic Compounds (New York, NY, United States), 1982 , vol. 18, # 11 p. 1215 Khimiya Geterotsiklicheskikh Soedinenii, 1982 , vol. 18, # 11 p. 1560 - 1561 Title/Abstract Full Text View citing articles Show Details

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1044 Synthesize Find similar Rx-ID: 1641573 Find similar reactions

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in ammonia

T=-40°C; electrolysis, platinum working electrode, 0.1M KBr; Title compound not separated from byproducts;

Amatore, Christian; Badoz-Lambling, Janine; BonnelHuyghes, Claudine; Pinson, Jean; Saveant, Jean Michel; Thiebault, Andre

Journal of the American Chemical Society, 1982 , vol. 104, # 7 p. 1979 - 1986 Title/Abstract Full Text View citing articles Show Details

With potassium bromide in ammonia

T=-40°C; cyclovoltammetry; other aromatic halides; hydrogen atom transfer oxidation of primary and secondary alcoholates into aldehydes and ketones by aromatic halides; electrochemically induceable reaction; rate constants of H-atom transfer reaction; Rate constantProduct distribution;

Amatore, Christian; Badoz-Lambling, Janine; BonnelHuyghes, Claudine; Pinson, Jean; Saveant, Jean Michel; Thiebault, Andre

Journal of the American Chemical Society, 1982 , vol. 104, # 7 p. 1979 - 1986 Title/Abstract Full Text View citing articles Show Details

1045 Synthesize Find similar

Synthesize Find similar

Rx-ID: 1766331 Find similar reactions

With H2Se; triethylamine in methanol

T=0°C; 1 h; Yield given;

Asinger, Friedrich; Schmitz, Maria Karoline

Monatshefte fuer Chemie, 1982 , vol. 113, p. 1191 - 1212 Title/Abstract Full Text View citing articles Show Details

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1046 Synthesize Find similar

A: 50 % Chromat. B: 50 % Chromat.

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Rx-ID: 1781622 Find similar reactions

With molecular sieve; BnNMe3(+)F(-) in tetrahydrofuran

1.) room temperature, overnight, 2.) 0 deg C, 10 min, 3.) room temperature, ,24 h;

Kuwajima, Isao; Nakamura, Eiichi; Shimizu, Makoto

Journal of the American Chemical Society, 1982 , vol. 104, # 4 p. 1025 - 1030 Title/Abstract Full Text View citing articles Show Details

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1047 Synthesize Find similar

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Rx-ID: 1994981 Find similar reactions

A: 61 % Chromat. B: 28 % Chromat.

in dichloromethane

T=20°C; 3 h;

Kashin, A. N.; Tul'chinskii, M. L.; Bumagin, N. A.; Beletskaya, I. P.; Reutov, O. A.

Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1390 - 1395 Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1588 - 1595 Title/Abstract Full Text Show Details

A: 61 %

in dichloromethane

Kashin, A. N.; Tul'chinskii, M. L.; Bumagin, N. A.;

Chromat. B: 28 % Chromat.

Beletskaya, I. P.; Reutov, O. A.

Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1390 - 1395 Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1588 - 1595 Title/Abstract Full Text Show Details

T=20°C; 3 h;

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1048 Synthesize Find similar

Rx-ID: 1999521 Find similar reactions

With oxygen

T=24.9°C; P=3.8 - 3.9 Torr; Irradiationtime dependence of products yields; Rate constantProduct distribution;

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Washida; Takagi

Journal of the American Chemical Society, 1982 , vol. 104, # 1 p. 168 - 173 Title/Abstract Full Text View citing articles Show Details

1049 Synthesize Find similar

A: 79%

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Rx-ID: 2011625 Find similar reactions

Ando, Wataru; Tsumaki, Hidetoshi

Tetrahedron Letters, 1982 , vol. 23, # 30 p. 3073 - 3076 Title/Abstract Full Text View citing articles Show Details

in dichloromethane

120 h; Heating;

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1050 Synthesize Find similar

Rx-ID: 2033286 Find similar reactions

With bentonite K 10 in hexane

Heatingproving as intermediate in the conversion of cyclohexanol to cylohexanone by clay-supported ferric nitrate; Product distributionMechanism;

Cornelis, Andre; Herze, Pierre-Yves; Laszlo, Pierre

Tetrahedron Letters, 1982 , vol. 23, # 48 p. 5035 - 5038 Title/Abstract Full Text View citing articles Show Details

1051 Synthesize Find similar

96 %

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Rx-ID: 2101699 Find similar reactions

With tetrakis(triphenylphosphine) palladium(0); hexamethyl-silane in benzene

Urata, Hisao; Suzuki, Hiroharu; Moro-Oka, Yoshihiko;

Spectr.

Ikawa, Tsuneo

Journal of Organometallic Chemistry, 1982 , vol. 234, # 3 p. 367 - 374 Title/Abstract Full Text View citing articles Show Details

T=160°C; 10 h;

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1052 Synthesize Find similar

B: 90%

Rx-ID: 2105375 Find similar reactions

With potassium hydroxide in methanol

T=65°C; 0.25 h; Product distribution;

Vit, Zdenek; Nondek, Lubomir; Malek, Jaroslav

Collection of Czechoslovak Chemical Communications, 1982 , vol. 47, # 8 p. 2235 - 2245 Title/Abstract Full Text Show Details

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1053 Synthesize Find similar Rx-ID: 2126789 Find similar reactions

Yankelevich, A. Z.; Potapov, V. K.; Hagemann, H. J.; Kuznets, V. K.; Pershin, A. D.; Buchachenko, A. L.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 3 p. 460 - 466 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 3 p. 513 - 521 Title/Abstract Full Text View citing articles Show Details

T=20°C; Irradiation; Mechanism;

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1054 Synthesize Find similar

Bourgeois, Marie-Josephe; Campagnole, Monique; Filliatre, Claude; Maillard, Bernard; Villenave, JeanJaques

Bulletin de la Societe Chimique de France, 1982 , vol. 2, # 3-4 p. 111 - 115 Title/Abstract Full Text Show Details

decomposition;

Rx-ID: 2132702 Find similar reactions

1055 Synthesize Find similar Rx-ID: 2152068 Find similar reactions

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Starostin, E. K.; Aleksandrov, A. V.; Ignatenko, A. V.; Nikitin, G. I.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 1 p. 133 - 136 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 1 p. 141 - 144 Title/Abstract Full Text View citing articles Show Details

in various solvent(s) T=180 - 200°C; 3 h; Mechanism;

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1056 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2279813 Find similar reactions

A: 48 % Chromat. B: 25 % Chromat. D: 7 % Chromat.

in dichloromethane

0.5 h; Ambient temperature;

Kashin, A. N.; Tul'chinskii, M. L.; Bumagin, N. A.; Beletskaya, I. P.; Reutov, O. A.

Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1390 - 1395 Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1588 - 1595 Title/Abstract Full Text Show Details

A: 48 % Chromat. B: 25 % Chromat. D: 7 % Chromat.

in dichloromethane

0.5 h; Ambient temperature;

Kashin, A. N.; Tul'chinskii, M. L.; Bumagin, N. A.; Beletskaya, I. P.; Reutov, O. A.

Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1390 - 1395 Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1588 - 1595 Title/Abstract Full Text Show Details

A: 48 % Chromat. B: 25 % Chromat. D: 7 % Chromat.

in dichloromethane

0.5 h; Ambient temperature;

Kashin, A. N.; Tul'chinskii, M. L.; Bumagin, N. A.; Beletskaya, I. P.; Reutov, O. A.

Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1390 - 1395 Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1588 - 1595 Title/Abstract Full Text Show Details

Hide Details

A: 48 % Chromat. B: 25 % Chromat. D: 7 % Chromat.

Kashin, A. N.; Tul'chinskii, M. L.; Bumagin, N. A.; Beletskaya, I. P.; Reutov, O. A.

Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1390 - 1395 Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1588 - 1595 Title/Abstract Full Text Show Details

in dichloromethane

0.5 h; Ambient temperature; Mechanism;

1057 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2551368 Find similar reactions

With PPA T=200°C; 10 h;

Kukharev, B. F.; Stankevich, V. K.

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1058 Synthesize Find similar

Rx-ID: 2551463 Find similar reactions

With PPA T=200°C; 10 h; Product distribution;

Kukharev, B. F.; Stankevich, V. K.

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1059 Synthesize Find similar

Rx-ID: 2565851 Find similar reactions

With hydrogenchloride

T=105°C; overnight;

Pellacani, Lucio; Pulcini, Patrizio; Tardella, Paolo A.

Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 5023 - 5025 Title/Abstract Full Text View citing articles Show Details

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1060 Synthesize Find similar

A: 66%

in dichloromethane

20 h; Heating;

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Rx-ID: 2707662 Find similar reactions

Ando, Wataru; Tsumaki, Hidetoshi

Tetrahedron Letters, 1982 , vol. 23, # 30 p. 3073 - 3076 Title/Abstract Full Text View citing articles

Show Details

1061 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2820372 Find similar reactions

With hydrogenchloride in methanol

3 h; Heating;

93%

Ogura, Katsuyuki; Suzuki, Michiyo; Watanabe, Junichi; Yamashita, Mitsuo; Iida, Hirotada; Tsuchihashi, Gen-ichi

Chemistry Letters, 1982 , p. 813 - 814 Title/Abstract Full Text Show Details

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1062 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2948114 Find similar reactions

With cyclohexanol; bis(triphenylphosphine)carbonylrhodium(I) chloride; potassium acetate

T=150°C; 7 h; average rate; reduction of various substituted nitro compounds; different alcohols, catalysts, and times, the other temp.; Product distribution;

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Liou, K. F.; Cheng, C. H.

Journal of Organic Chemistry, 1982 , vol. 47, # 15 p. 3018 - 3021 Title/Abstract Full Text View citing articles Show Details

1063 Synthesize Find similar

Rx-ID: 2953626 Find similar reactions

With lithium perchlorate in acetonitrile

mode of cell; Product distribution;

Becker, James Y.; Zinger, Baruch

Journal of the American Chemical Society, 1982 , vol. 104, # 8 p. 2327 - 2329 Title/Abstract Full Text View citing articles Show Details

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1064 Synthesize Find similar

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Rx-ID: 3316335 Find similar reactions

B: 65 % Chromat.

With antimony trichloride in dichloromethane

T=0°C; 1 h;

Tirpak, Robin E.; Rathke, Michael W.

Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5099

D: 15 % Chromat.

- 5102 Title/Abstract Full Text View citing articles Show Details

B: 71 % Chromat. D: 5 % Chromat.

With zinc(II) chloride in diethyl ether; dichloromethane

T=0°C; 1 h;

Tirpak, Robin E.; Rathke, Michael W.

Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5099 - 5102 Title/Abstract Full Text View citing articles Show Details

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1065 Synthesize Find similar

A: 7.1 % Chromat. B: 91.9 % Chromat. C: 0.7 % Chromat.

Rx-ID: 3377123 Find similar reactions

With hydrogen; rhodium in ethanol

T=49.9°C; P=15001.2 Torr; Title compound not separated from byproducts;

Sokol'skii, D. V.; Ualikhanova, A.; Temirbulatova, A. E.

Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 10 p. 1828 - 1832 Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 10 p. 2078 - 2081 Title/Abstract Full Text Show Details

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1066 Synthesize Find similar Rx-ID: 3445927 Find similar reactions

A: 16 % Chromat. B: 52 % Chromat. C: 90 % Chromat. D: 4 % Chromat.

With lithium perchlorate in acetonitrile

anodic oxidation;

Becker, James Y.; Zinger, Baruch

Journal of the American Chemical Society, 1982 , vol. 104, # 8 p. 2327 - 2329 Title/Abstract Full Text View citing articles Show Details

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1067 Synthesize Find similar

A: 68%

Rx-ID: 3611300 Find similar reactions

Obafemi, Craig A.

Phosphorus and Sulfur and the Related Elements, 1982 , vol. 13, p. 119 - 132 Title/Abstract Full Text Show Details

in ethanol; water

1068 Synthesize Find similar

B: 75%

Synthesize Find similar

Rx-ID: 3615827 Find similar reactions

Obafemi, Craig A.

Phosphorus and Sulfur and the Related Elements, 1982 , vol. 13, p. 119 - 132 Title/Abstract Full Text Show Details

in ethanol; water

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1069 Synthesize Find similar

Rx-ID: 3856132 Find similar reactions

With Clayfen; ferric nitrate impregnated on K 10 bentonite clay in hexane

24 h; Heating; Product distributionMechanism;

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Cornelis, Andre; Herze, Pierre-Yves; Laszlo, Pierre

Tetrahedron Letters, 1982 , vol. 23, # 48 p. 5035 - 5038 Title/Abstract Full Text View citing articles Show Details

1070 Synthesize Find similar

A: 23 % Chromat. B: 90%

Rx-ID: 3856134 Find similar reactions

With N,N-dichloro-t-butylamine in tetrachloromethane

T=20°C; 1 h; Irradiationother alcohol; MechanismProduct distribution;

Ogata, Yoshiro; Kimura, Makoto

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1982 , p. 947 - 950 Title/Abstract Full Text Show Details

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1071 Synthesize Find similar

Rx-ID: 3856139 Find similar reactions

Irradiation;

Balsells, R. Erra; Frasca, A. R.

Tetrahedron, 1982 , vol. 38, # 16 p. 2525 - 2538 Title/Abstract Full Text View citing articles Show Details

A: 55 % Turnov. B: 5 % Turnov.

T=60 - 70°C; 18 h; IrradiationHg high pressure lamp;

Balsells, R. Erra; Frasca, A. R.

Tetrahedron, 1982 , vol. 38, # 2 p. 245 - 255 Title/Abstract Full Text View citing articles Show Details

C: 37 % Turnov.

A: 55 % Turnov. B: 5 % Turnov. C: 37 % Turnov.

Balsells, R. Erra; Frasca, A. R.

Tetrahedron, 1982 , vol. 38, # 2 p. 245 - 255 Title/Abstract Full Text View citing articles Show Details

T=60 - 70°C; 18 h; IrradiationHg high pressure lamp;

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1072 Synthesize Find similar Rx-ID: 3856141 Find similar reactions

Chukovskaya, E. Ts.; Rozhkova, M. A.; Freidlina, R. Kh.

With pentacarbonyliron(0); 1-chloro-3,3,3-trichloropropane

further reagents; Product distribution;

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 7 p. 1406 - 1409 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 7 p. 1582 - 1585 Title/Abstract Full Text View citing articles Show Details

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1073 Synthesize Find similar

Synthesize Find similar

Rx-ID: 3886192 Find similar reactions

A: 10 % Chromat. B: 90 % Chromat.

With molecular sieve; BnNMe3(+)F(-) in ethylene glycol dimethyl ether

1.) room temperature, overnight, 2.) -78 deg C, 5 min, 3.) 0 deg C, 6 h;

Kuwajima, Isao; Nakamura, Eiichi; Shimizu, Makoto

Journal of the American Chemical Society, 1982 , vol. 104, # 4 p. 1025 - 1030 Title/Abstract Full Text View citing articles Show Details

With molecular sieve; BnNMe3(+)F(-) in ethylene glycol dimethyl ether

T=0°C; 8 h; different reaction conditions, various solvents, regiospecificity; Product distribution;

Kuwajima, Isao; Nakamura, Eiichi; Shimizu, Makoto

Journal of the American Chemical Society, 1982 , vol. 104, # 4 p. 1025 - 1030 Title/Abstract Full Text View citing articles Show Details

1074 Synthesize Find similar

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With carbon dioxide; zinc oxide

multistep reaction; Product distribution;

Rx-ID: 6727464 Find similar reactions

Vasina, T. V.; Chelmakova, S. A.; Lutovinova, V. N.; Liberman, A. L.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 10 p. 2046 - 2048 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 10 p. 2325 - 2327 Title/Abstract Full Text View citing articles Show Details

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1075 Synthesize Find similar

A: 12.0 % Chromat. B: 43.4 % Chromat.

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in acetonitrile

Irradiationother reagents ratio; Product distributionQuantum yield;

Rx-ID: 6727929 Find similar reactions

Pienta, Norbert J.; McKimmey, Jennifer E.

Journal of the American Chemical Society, 1982 , vol. 104, # 20 p. 5501 - 5502 Title/Abstract Full Text View citing articles Show Details

1076 Synthesize Find similar

Synthesize Find similar

Rx-ID: 18901478 Find similar reactions

Multi-step reaction with 2 steps 1: 24 h / 130 - 140 °C 2: ethanol; H2O View Scheme

Obafemi, Craig A.

Phosphorus and Sulfur and the Related Elements, 1982 , vol. 13, p. 119 - 132 Title/Abstract Full Text Show Details

1077 Synthesize Find similar

Synthesize Find similar

Rx-ID: 20745269 Find similar reactions

Multi-step reaction with 2 steps 1: 68 percent / 50percent aq. NaOH / trioctylmethylammonium chloride / toluene / 64 h / 60 °C 2: 93 percent / conc. hydrochloric acid / methanol / 3 h / Heating View Scheme

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1078

Rx-ID: 25060228 Find similar reactions

Ogura, Katsuyuki; Suzuki, Michiyo; Watanabe, Junichi; Yamashita, Mitsuo; Iida, Hirotada; Tsuchihashi, Gen-ichi

Chemistry Letters, 1982 , p. 813 - 814 Title/Abstract Full Text Show Details

Petrolite Corporation

Patent: US4311841 A1, 1982 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

5:2-Isopropyl 4,4-pentamethylene 5,6-tetramethylene hexahydropyrimidine

EXAMPLE 5 2-Isopropyl 4,4-pentamethylene 5,6-tetramethylene hexahydropyrimidine A mixture of 137.2 grams of 2,2,4,4-dipentamethylene 5,6-tetramethylene hexahydropyrimidine, prepared as described in example 1, and 36 grams of isobutyraldehyde was heated and refluxed for 5 hours. The mixture was distilled at atmospheric pressure until a head distillation temperature of 118° C. was reached. Distillation, under diminished pressure was continued. The low boiling fraction 44.6 grams of product was identified as cyclohexanone. The fraction b.5 155°-170° C. was identified as 80.7 grams of 2-isopropyl 4,4-pentamethylene 5,6-tetramethylene hexahydropyrimidine, C13 nuclear magnetic resonance spectrum showed two isomers present,

with the major isomer fused in trans fashion at the 5,6 position; solvent CDCl3, δ in ppm. Anal. Calc.ed for C16 H30 N2; N, 11.20percent. Found: N, 11.1percent. A

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1079 Synthesize Find similar

Synthesize Find similar

Rx-ID: 1470410 Find similar reactions

With lithium aluminium tetrahydride; boron trifluoride diethyl etherate

1a) ether, 0 deg C, 45 min, b) reflux, 2 h; Yield given. Multistep reaction;

Kirmse, Wolfgang; Sandkuehler, Peter

Liebigs Annalen der Chemie, 1981 , # 8 p. 1394 - 1406 Title/Abstract Full Text Show Details

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1080 Synthesize Find similar

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With chlorosulfonic acid; WO3

1) CH2Cl2, 20 deg C, 3 h, 2) CH2Cl2, 2 h; Yield given. Multistep reaction. Yields of byproduct given;

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Rx-ID: 1501278 Find similar reactions

Miura, Masahiro; Nojima, Masatomo; Kusabayashi, Shigekazu

Journal of the Chemical Society, Chemical Communications, 1981 , # 12 p. 581 - 582 Title/Abstract Full Text View citing articles Show Details

1081 Synthesize Find similar

With ammonium cerium(IV) nitrate in water; acetonitrile

1 h; Product distribution;

Rx-ID: 1533411 Find similar reactions

Cristau, Henri-Jean; Chabaud, Bernard; Labaudiniere, Richard; Christol, Henri

Synthetic Communications, 1981 , vol. 11, # 6 p. 423 428 Title/Abstract Full Text Show Details

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1082 Synthesize Find similar

Rx-ID: 1550184 Find similar reactions

With triethylamine in cyclohexane

40 h; Irradiation;

Purohit, P.C.; Sonawane, H.R.

Tetrahedron, 1981 , vol. 37, p. 873 - 877 Title/Abstract Full Text View citing articles Show Details

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1083 Synthesize Find similar

A: 7 % Spectr. B: 47 % Spectr. C: 46 % Spectr.

Rx-ID: 1720671 Find similar reactions

Cameron, Tim B.; El-Kabbani, Fiesal M.; Pinnick, Harold W.

Journal of the American Chemical Society, 1981 , vol. 103, # 18 p. 5414 - 5417 Title/Abstract Full Text View citing articles Show Details

T=750°C; other temperatures; Product distribution;

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1084 Synthesize Find similar

Synthesize Find similar

Rx-ID: 1731273 Find similar reactions

A: 7 % Chromat. B: 57 % Chromat. C: 12 % Chromat.

Tsuda, Tetsuo; Yazawa, Tetsuo; Watanabe, Katsuhiko; Fujii, Tomoyuki; Saegusa, Takeo

Journal of Organic Chemistry, 1981 , vol. 46, p. 192 - 194 Title/Abstract Full Text View citing articles Show Details

in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide

T=-78°C; 3 h; var. solv., var. times; Product distribution;

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1085 Synthesize Find similar

A: 93%

T=800°C; other temperatures; Product distribution;

Rx-ID: 1739531 Find similar reactions

Cameron, Tim B.; El-Kabbani, Fiesal M.; Pinnick, Harold W.

Journal of the American Chemical Society, 1981 , vol. 103, # 18 p. 5414 - 5417

Title/Abstract Full Text View citing articles Show Details

1086 Synthesize Find similar

Synthesize Find similar

Rx-ID: 1978919 Find similar reactions

With sulfuric acid in water

T=25°C; Rate constant;

Dubois, Jaques-Emile; El-Alaoui, Mohiedine; Toullec, Jean

Journal of the American Chemical Society, 1981 , vol. 103, # 18 p. 5393 - 5401 Title/Abstract Full Text View citing articles Show Details

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1087 Synthesize Find similar Rx-ID: 1999520 Find similar reactions

A: 6.5% B: 2% C: 20% D: 43% E: 1.5%

With water; nitrogen(II) oxide

5.71667 h; Irradiationfurther reaction times, initial conc.,; Product distribution;

Takagi, H.; Washida, N.; Banbow, H.; Akimoto, H.; Okuda, M.

Journal of Physical Chemistry, 1981 , vol. 85, # 18 p. 2701 - 2705 Title/Abstract Full Text View citing articles Show Details

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1088 Synthesize Find similar Rx-ID: 2033322 Find similar reactions

With chloroform; di-tert-butyl peroxide

T=130°C; 1.5 h; glass ampul; Product distributionMechanism;

1089

Rol'nik, L.Z.,; Kalashnikov, S.M.; Pastushenko, E.V.; Zlotskii, S.S.; Imashev, U.B.,; Rakhmankulov, D.L.

Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, p. 457 - 459 Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 3 p. 539 540 Title/Abstract Full Text Show Details

Synthesize Find similar A: 40 % Chromat. B: 16 % Chromat. C: 16%

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With jones reagent in acetone

T=0°C; 12 h; Product distribution;

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Rx-ID: 2041052 Find similar reactions

Bal, Balkrishna S.; Kochhar, Kanwarpal S.; Pinnick, Harold W.

Journal of Organic Chemistry, 1981 , vol. 46, # 7 p. 1492 - 1493 Title/Abstract Full Text View citing articles Show Details