Cyclohexanone by Asch

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Reactions (1470)

Yield

Substances (2)

Citations (3478)

Conditions

References

496 Synthesize Find similar 100%

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Rx-ID: 9119595 Find similar reactions

Akbalina; Kabal'nova; Zlotskii; Grigor'ev; Kotlyar; Shereshovets; Tolstikov

Russian Journal of General Chemistry, 2002 , vol. 72, # 3 p. 447 - 448 Title/Abstract Full Text View citing articles Show Details

With 1-oxyl-2,2,5,5-tetramethyl-4-phenyl-Δ3-imidazoline 3-oxide; 15-crown-5; KCrO5Cl in acetonitrile T=60°C; 7 h; Product distribution; Further Variations:Reagents;

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497 Synthesize Find similar Rx-ID: 9214338 Find similar reactions

With oxygen

T=129.85°C; Product distribution;

Puchkov; Buneeva; Perkel'

Russian Journal of Applied Chemistry, 2002 , vol. 75, # 2 p. 248 - 253 Title/Abstract Full Text View citing articles Show Details

498 Synthesize Find similar

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Rx-ID: 9242519 Find similar reactions

A: 22% B: 19% C: 9%

With oxygen; dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide

T=80°C; Heck reaction; 6 h;

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Hosokawa, Takahiro; Kamiike, Taisuke; Murahashi, Shun-Ichi; Shimada, Mamoru; Sugafuji, Toshihiro

Tetrahedron Letters, 2002 , vol. 43, # 51 p. 9323 - 9325 Title/Abstract Full Text View citing articles Show Details

499

B: 100%

Rx-ID: 24075080 Find similar reactions

Suib, Steven L.; Son, Young Chan; Howell, Amy R.

Patent: US2002/128506 A1, 2002 ;

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Title/Abstract Full Text Show Details

5:EXAMPLE 5

In a similar reaction using 0.5 equivalents of H-K-OMS-2 in a 1:1 by weight mixture of H-K-OMS-2 and a strongly acidic sulfonated ion exchange resin (DOWEX-50W-H+) co-ground and dried at 100° C. for 2 days, cyclohexanol was converted to cyclohexanone and cyclohexene in a 100percent yield, with 50percent selectivity.

500 Synthesize Find similar

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Rx-ID: 25399826 Find similar reactions

With hydrogenchloride in toluene

DAINIPPON INK AND CHEMICALS, INC.

Patent: EP1201632 A1, 2002 ;

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Title/Abstract Full Text Show Details

2:(2)

29.3 g of the enamine (J-2) and 20 ml of 3-buten-2-one were dissolved in 150 ml of toluene, and then reacted for 4 hours at 100°C. The solution was then treated with 6N hydrochloric acid, washed with water, and dried, before being purified by silica gel chromatography (hexane:methylenechloride = 1:1) to yield 21.5 g of the cyclohexanone (J-3).

501 Synthesize Find similar 72%

With carbon

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Rx-ID: 103080 Find similar reactions

Marquie; Laporterie; Dubac; Roques

T=450°C; P=300 Torr; 1 h;

Synlett, 2001 , # 4 p. 493 - 496 Title/Abstract Full Text View citing articles Show Details

With potassium fluoride

T=250 - 280°C;

Nesmejanow; Petscherskaja; Urezkaja

Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1948 , p. 240,243 Chem.Abstr., 1948 , p. 4924 Full Text Show Details

beim Erhitzen;

Vogel

Journal of the Chemical Society, 1929 , p. 732 Full Text Show Details

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With barytes; iron

Vogel

Journal of the Chemical Society, 1929 , p. 732 Full Text Show Details

With acetic anhydride

Blanc

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1907 , vol. 144, p. 1357 Bulletin de la Societe Chimique de France, 1908 , vol. <4> 3, p. 779 Full Text Show Details

With methyllithium; calcium carbonate

bei der Destillation;

Baeyer

Justus Liebigs Annalen der Chemie, 1894 , vol. 278, p. 108 Full Text Show Details

bei der thermischen Zersetzung des Thoriumsalzes;

Ruzicka et al.

Helvetica Chimica Acta, 1926 , vol. 9, p. 515 Full Text Show Details

bei der thermischen Zersetzung des Thoriumsalzes unter vermindertem Druck;

Ruzicka et al.

Helvetica Chimica Acta, 1926 , vol. 9, p. 515 Full Text Show Details

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502 Synthesize Find similar

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Rx-ID: 3752946 Find similar reactions

A: 77% B: 13%

With peracetic acid; ruthenium trichloride in dichloromethane; ethyl acetate

T=20°C; Kinetics;

Komiya; Noji; Murahashi

Chemical Communications, 2001 , # 1 p. 65 - 66 Title/Abstract Full Text View citing articles Show Details

With potassium metavanadate

8 h; Irradiationother substrates; Product distribution;

Kats, M. M.; Shul'pin, G. B.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 10.2. p. 2233 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , vol. 39, # 10 p. 2461 Title/Abstract Full Text View citing articles Show Details

With potassium metavanadate

8 h; Irradiation; Yield given. Yields of byproduct given;

Kats, M. M.; Shul'pin, G. B.

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With peracetic acid; ruthenium trichloride in dichloromethane

Ambient temperature; Yield given. Yields of byproduct given;

Murahashi, Shun-Ichi; Oda, Yoshiaki; Komiya, Naruyoshi; Naota, Takeshi

Tetrahedron Letters, 1994 , vol. 35, # 43 p. 7953 - 7956 Title/Abstract Full Text View citing articles Show Details

A: 77 % Chromat. B: 13 % Chromat.

With peracetic acid; ruthenium trichloride in dichloromethane; ethyl acetate

T=20°C; 2 h;

Murahashi; Komiya; Oda; Kuwabara; Naota

Journal of Organic Chemistry, 2000 , vol. 65, # 26 p. 9186 - 9193 Title/Abstract Full Text View citing articles Show Details

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503 Synthesize Find similar

Rx-ID: 8678191 Find similar reactions

Oxley; Smith; Zhang; Bedford

Journal of Physical Chemistry A, 2001 , vol. 105, # 3 p. 579 - 590 Title/Abstract Full Text View citing articles Show Details

T=240°C; Kinetics; Further Variations:TemperaturesSolvents;

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504 Synthesize Find similar Rx-ID: 8734823 Find similar reactions

With air; nitrous acid methyl ester; nitrogen(II) oxide

T=24.85°C; P=760 Torr; KineticsProduct distribution;

Bradley; Wyatt; Wells; Henley; Graziano

International Journal of Chemical Kinetics, 2001 , vol. 33, # 2 p. 108 - 117 Title/Abstract Full Text View citing articles Show Details

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505 Synthesize Find similar

With [(-Ti(H2O)(OH)-O-Ti(H2O)(OH)-O-)*(O*-O-)]n; dihydrogen peroxide in methanol

T=25°C; 0.75 h;

Rx-ID: 8760854 Find similar reactions

Dewkar, Gajanan K.; Nikalje, Milind D.; Ali, Iliyas Sayyed; Paraskar, Abhimanyu S.; Jagtap; Sudalai

Angewandte Chemie - International Edition, 2001 , vol. 40, # 2 p. 405 - 408 Title/Abstract Full Text View citing articles Show Details

506 Synthesize Find similar

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Rx-ID: 8783894 Find similar reactions

With YLK-18-opt peptide in phosphate buffer; dimethyl sulfoxide

T=25°C; pH=7.5; Enzyme kinetics; Further Variations:Reagents;

Tanaka; Barbas III

Chemical Communications, 2001 , # 8 p. 769 - 770 Title/Abstract Full Text View citing articles Show Details

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507 Synthesize Find similar

A: 21% B: 36% C: 6%

Rx-ID: 8806982 Find similar reactions

With 1,3-bis-(diphenylphosphino)propane; caesium carbonate; isopropyl alcohol; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium in toluene

T=80°C; 4 h; A

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Sakaguchi; Yamaga; Ishii

Journal of Organic Chemistry, 2001 , vol. 66, # 13 p. 4710 - 4712 Title/Abstract Full Text View citing articles Show Details

508 Synthesize Find similar

A: 53 % Chromat. B: 46 % Chromat.

Rx-ID: 8811148 Find similar reactions

With bromine in water; 1,2-dichloro-ethane

T=20°C; 3 h;

Bjorsvik; Fontana; Liguori; Minisci

Chemical Communications, 2001 , # 6 p. 523 - 524 Title/Abstract Full Text View citing articles Show Details

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509 Synthesize Find similar

Rx-ID: 8811562 Find similar reactions

With air; nitrous acid methyl ester; nitrogen(II) oxide

T=22.85°C; P=740 Torr; Irradiation; Kinetics;

Arey; Atkinson; Aschmann

Journal of Physical Chemistry A, 2001 , vol. 105, # 32 p. 7598 - 7606 Title/Abstract Full Text View citing articles Show Details

510 Synthesize Find similar

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Rx-ID: 8864605 Find similar reactions

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Cafferata, Lazaro F. R.; Jefford, Charles W.

Molecules, 2001 , vol. 6, # 8 p. 699 - 709 Title/Abstract Full Text View citing articles Show Details

T=140.05°C; 2 h; Product distributionKineticsActivation energy; Further Variations:SolventsTemperaturesReagents;

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511 Synthesize Find similar Rx-ID: 8874249 Find similar reactions

With acetate buffer; dihydrogen peroxide; sodium nitrite in water

T=25°C; pH=4.3; KineticsProduct distribution;

Rudakov; Lobachev; Geletii

Chemical Research in Toxicology, 2001 , vol. 14, # 9 p. 1232 - 1238 Title/Abstract Full Text View citing articles Show Details

512 Synthesize Find similar

100 % Chromat.

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Rx-ID: 8906266 Find similar reactions

With hydrogenchloride in tetrahydrofuran; water

2 h; Kinetics;

Fataftah; Rawashdeh; Sotiriou-Leventis

Synthetic Communications, 2001 , vol. 31, # 15 p. 2379 - 2389 Title/Abstract Full Text View citing articles Show Details

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513 Synthesize Find similar

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With oxygen; H6[PV3Mo9O40]*aq

T=20°C; P=750.075 Torr; 5 h;

Rx-ID: 8930840 Find similar reactions

El Aakel; Launay; Atlamsani; Bregeault

Chemical Communications, 2001 , # 21 p. 2218 - 2219 Title/Abstract Full Text View citing articles Show Details

514 Synthesize Find similar

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Rx-ID: 8943400 Find similar reactions

With oxygen; H6[PV3Mo9O40]*aq in water; acetic acid

T=20°C; P=750.075 Torr; 5 h;

El Aakel; Launay; Atlamsani; Bregeault

Chemical Communications, 2001 , # 21 p. 2218 - 2219 Title/Abstract Full Text View citing articles Show Details

515 Synthesize Find similar

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Rx-ID: 8955619 Find similar reactions

With sulfuric acid in 1,4-dioxane; toluene

T=24.84°C; Kinetics; Further Variations:Temperatures;

Mallya, M. Narendra; Nagendrappa, Gopalpur

Journal of the Chemical Society. Perkin Transactions 2, 2001 , # 12 p. 2248 2252 Title/Abstract Full Text View citing articles Show Details

516 Synthesize Find similar

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Rx-ID: 8968049 Find similar reactions

With hydrogenchloride; water in diethyl ether; dichloromethane

T=20°C; 1 h;

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Matsuo, Jun-Ichi; Kawana, Asahi; Fukuda, Yoshio; Mukaiyama, Teruaki

Chemistry Letters, 2001 , # 7 p. 712 - 713 Title/Abstract Full Text View citing articles Show Details

517 Synthesize Find similar

A: 21% B: 20%

With [bis(acetoxy)iodo]benzene; iodine in cyclohexane

T=20°C; 3 h; UV-irradiation;

Barluenga, Jose; Gonzalez-Bobes, Francisco; Ananthoju, Sreenivasa R.; Garca-Martn, Miguel A.; Gonzalez, Jose M.

Angewandte Chemie - International Edition, 2001 , vol. 40, # 18 p. 3389 3392 Title/Abstract Full Text View citing articles Show Details

Rx-ID: 8986570 Find similar reactions

518 Synthesize Find similar

A: 5% B: 43%

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Rx-ID: 8986862 Find similar reactions

With sodium hydroxide; potassium hexacyanoferrate(III) in dichloromethane; water

T=20 - 25°C; 0.333333 h;

Al-Khalil; Bowman; Gaitonde; Marley; Richardson

Journal of the Chemical Society, Perkin Transactions 2, 2001 , # 9 p. 1557 1565 Title/Abstract Full Text View citing articles Show Details

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519 Synthesize Find similar

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Rx-ID: 9014669 Find similar reactions

With oxygen; anhydrous sulphate; zirconium oxide; palladium dichloride

T=170°C; P=45003.6 Torr; 3 h; Title compound not separated from byproducts;

Shi, Feng; Deng, Youquan; SiMa, Tianlong; Yang, Hongzhou

Journal of Catalysis, 2001 , vol. 203, # 2 p. 525 - 528 Title/Abstract Full Text View citing articles Show Details

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520 Synthesize Find similar Rx-ID: 10332144 Find similar reactions

With oxone; FePcS (PcS - tetrasodium 2,3-tetrasulfophthalocyaninate) in water

T=20°C; Product distribution; Further Variations:CatalystsReagentsSolventspH-values;

D'Alessandro; Liberatore; Tonucci; Morvillo; Bressan

New Journal of Chemistry, 2001 , vol. 25, # 10 p. 1319 - 1324 Title/Abstract Full Text View citing articles Show Details

521 Synthesize Find similar

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Rx-ID: 15130833 Find similar reactions

Multi-step reaction with 2 steps 1: N-tert-butylphenylsulfinimidoyl chloride; DBU / CH2Cl2 / 1 h / -78 °C 2: HCl; H2O / diethyl ether; CH2Cl2 / 1 h / 20 °C View Scheme

Matsuo, Jun-Ichi; Kawana, Asahi; Fukuda, Yoshio; Mukaiyama, Teruaki

Chemistry Letters, 2001 , # 7 p. 712 - 713 Title/Abstract Full Text View citing articles Show Details

522 Synthesize Find similar

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Rx-ID: 15134804 Find similar reactions

Multi-step reaction with 3 steps 1: 96 percent / Et3N / CH2Cl2 / 1 h / 0 °C 2: N-tert-butylphenylsulfinimidoyl chloride; DBU / CH2Cl2 / 1 h / -78 °C 3: HCl; H2O / diethyl ether; CH2Cl2 / 1 h / 20 °C View Scheme

Matsuo, Jun-Ichi; Kawana, Asahi; Fukuda, Yoshio; Mukaiyama, Teruaki

Chemistry Letters, 2001 , # 7 p. 712 - 713 Title/Abstract Full Text View citing articles Show Details

523 Synthesize Find similar

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Rx-ID: 24066900 Find similar reactions

Ishii, Yasutaka; Nakano, Tatsuya

Patent: US2001/56120 A1, 2001 ;

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Title/Abstract Full Text Show Details

8:EXAMPLE 8

The resulting reaction mixture was concentrated and was purified by column chromatography on a silica gel to thereby yield dimethyl 3-cyclohexylmalate [dimethyl 3-cyclohexyl-2-hydroxysuccinate] in a yield of 31percent, dimethyl 3cyclohexyloxalacetate [dimethyl 3-cyclohexyl-2-oxosuccinate] in a yield of 11percent, cyclohexanol in a trace amount, and cyclohexanone in a yield of 2percent, with a conversion from dimethyl fumarate of 93percent. A

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524

A: 4.4%

Rx-ID: 25471152 Find similar reactions

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Daicel Chemical Industries, Ltd.

Patent: US6229023 B1, 2001 ; Title/Abstract Full Text Show Details

30:EXAMPLE 30

In the reaction mixture were formed cyclohexanone (yield: 41.7percent on cyclohexanol basis) and ε-caprolactone (yield: 4.4percent on cyclohexanol basis).

A: 4.2%

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31:EXAMPLE 31

In the reaction mixture were formed cyclohexanone (yield: 52.4percent on cyclohexanol basis) and ε-caprolactone (yield: 4.2percent on cyclohexanol basis).

Daicel Chemical Industries, Ltd.

Patent: US6229023 B1, 2001 ; Title/Abstract Full Text Show Details

525 Synthesize Find similar

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Rx-ID: 3774579 Find similar reactions

95%

With methyl(trifluoromethyl)dioxirane in dichloromethane

T=0°C; 0.5 h;

Altamura, Anna; Curci, Ruggero; Edwards, John O.

Journal of Organic Chemistry, 1993 , vol. 58, # 25 p. 7289 - 7293 Title/Abstract Full Text View citing articles Show Details

87%

With ammonium chlorochromate on aluminum oxide in dichloromethane

T=35 - 40°C; 4 h;

Zhang, Gui-Sheng; Gong, Hui; Yang, De-Hong; Chen, Mi-Feng

Synthetic Communications, 1999 , vol. 29, # 7 p. 1165 - 1170 Title/Abstract Full Text View citing articles Show Details

80%

With CPCC in acetonitrile

2 h; Heating;

Baltork; Pouranshirvani

Synthetic Communications, 1996 , vol. 26, # 1 p. 1 - 7 Title/Abstract Full Text View citing articles Show Details

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in dichloromethane

T=35 - 40°C; 4 h; Yield given;

Zhang, Gui-Sheng; Yang, De-Hong; Chen, Mi-Feng; Cai, Kun

Synthetic Communications, 1998 , vol. 28, # 4 p. 607 - 611 Title/Abstract Full Text View citing articles Show Details

With aluminum oxide; dimethylammonium chlorochromate in dichloromethane

T=38°C; 6 h; Yield given;

Zhang, Gui-Sheng; Yang, De-Hong; Chen, Mi-Feng

Synthetic Communications, 1998 , vol. 28, # 20 p. 3721 - 3725 Title/Abstract Full Text View citing articles Show Details

With aluminum oxide; Me3NHCrO3Cl in dichloromethane

T=38°C; 9.5 h; Yield given;

Zhang, Gui-Sheng; Yang, De-Hong; Chen, Mi-Feng

Organic Preparations and Procedures International, 1998 , vol. 30, # 6 p. 713 - 716 Title/Abstract Full Text View citing articles Show Details

With dimethylammonium chlorochromate; silica gel in dichloromethane

T=38 - 40°C; 1.5 h;

Zhang, Gui-Sheng; Chai, Bing

Synthetic Communications, 2000 , vol. 30, # 10 p. 1849 - 1855 Title/Abstract Full Text View citing articles Show Details

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526 Synthesize Find similar

Rx-ID: 4761628 Find similar reactions

A: 76% B: 82%

With oxygen; Cu-X zeolite in 1,2-dichloro-ethane; acetonitrile

T=50°C; Oxidation; Oxidative cleavage; 5 h;

Ebitani, Kohki; Nagashima, Kohji; Mizugaki, Tomoo; Kaneda, Kiyotomi

Chemical Communications, 2000 , # 10 p. 869 - 870 Title/Abstract Full Text View citing articles Show Details

B: 80 % Chromat.

With aluminum oxide; potassium permanganate; neutral in acetone

4 h; Ambient temperature;

Harris, Clifford E.; Chrisman, William; Bickford, Sally A.; Lee, Lawrence Y.; Torreblanca, Antonia E.; Singaram, Bakthan

Tetrahedron Letters, 1997 , vol. 38, # 6 p. 981 - 984 Title/Abstract Full Text View citing articles Show Details

527 Synthesize Find similar

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Rx-ID: 5190396 Find similar reactions

A: 30% B: 25% C: 45%

With palladium on activated charcoal in acetonitrile

T=50°C; Catalytic hydrogenation; 3 h;

Hayashi, Masahiko; Yamada, Kanako; Nakayama, Shuzo

Synthesis, 1999 , # 11 p. 1869 - 1871 Title/Abstract Full Text View citing articles Show Details

A: 28 % Chromat. B: 4 % Chromat. C: 68 % Chromat.

With ethene; palladium diacetate in acetonitrile

T=50°C; Dehydrogenation; Hydrogen-transfer reaction; 30 h; Title compound not separated from byproducts.;

Hayashi, Masahiko; Yamada, Kanako; Nakayama, Shu-Zo

Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 10 p. 1501 1503 Title/Abstract Full Text View citing articles Show Details

A: 40 % Chromat. B: 36 % Chromat. C: 24 % Chromat.

With palladium diacetate in acetonitrile

T=50°C; Dehydrogenation; Hydrogen-transfer reaction; 7 h; Title compound not separated from byproducts.;

Hayashi, Masahiko; Yamada, Kanako; Nakayama, Shu-Zo

Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 10 p. 1501 1503 Title/Abstract Full Text View citing articles Show Details

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528 Synthesize Find similar

Rx-ID: 5317543 Find similar reactions

With hydrogen; rhodium on alumina in sodium hydroxide

T=50°C; Hydrogenolysis; Dehydrochlorination; Electrolysis; Product distribution; Further Variations:CatalystsTemperatures;

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Menard; Cyr; Lessard; Dabo; Laplante; Jean

Environmental Science and Technology, 2000 , vol. 34, # 7 p. 1265 - 1268 Title/Abstract Full Text View citing articles Show Details

529 Synthesize Find similar

A: 0.0008% B: 0.69% C: 0.0002%

in water

T=20°C; Elimination; hydrolysis; 96 h; Irradiation; Product distribution; Further Variations:pH-valueswithout irradiation, time;

530

Rx-ID: 5329302 Find similar reactions

Unterhalt; Bensliman; Deguara; Lahl

Pharmazie, 2000 , vol. 55, # 2 p. 146 - 147 Title/Abstract Full Text View citing articles Show Details

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B: 10%

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With hydrogenchloride

Hydrolysis; pH=3; 3 h; Heating;

Unterhalt; Bensliman; Deguara; Lahl

Pharmazie, 2000 , vol. 55, # 2 p. 146 - 147 Title/Abstract Full Text View citing articles Show Details

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531 Synthesize Find similar

A: 1.4 % Chromat. B: 3.3 % Chromat. C: 0.45 % Chromat.

Rx-ID: 5359690 Find similar reactions

With 5,15,10,20-tetraphenylporphyrin in dichloromethane

T=-20 - 20°C; Oxidation; 168000 h; Irradiation; Product distribution; Further Variations:Temperaturesvar. of time; addition of KI;

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Unterhalt; Bensliman; Deguara; Lahl

Pharmazie, 2000 , vol. 55, # 2 p. 146 - 147 Title/Abstract Full Text View citing articles Show Details

532 Synthesize Find similar

A: 12% B: 87.8%

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Rx-ID: 8546892 Find similar reactions

Munavalli; Rohrbaugh; Rossman; Berg; Wagner; Durst

Synthetic Communications, 2000 , vol. 30, # 16 p. 2847 - 2854 Title/Abstract Full Text View citing articles Show Details

in acetonitrile

T=25°C; Hydrolysis; trifluoromethylthiolation; 48 h;

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533 Synthesize Find similar Rx-ID: 8548071 Find similar reactions

With Si-Ilerite in ethanol

T=350°C; Rearrangement; Beckmann rearrangement; 8 h; Product distribution; Further Variations:Catalystsreaction time;

Ko, Younghee; Kim, Myung Hun; Kim, Sun Jin; Seo, Gon; Kim, MiYoung; Uh, Young Sun

Chemical Communications, 2000 , # 10 p. 829 - 830 Title/Abstract Full Text View citing articles Show Details

534 Synthesize Find similar

A: 40 % Spectr. B: 18 % Spectr.

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Rx-ID: 8548712 Find similar reactions

With lithium bromide in 1-methyl-pyrrolidin-2-one

T=100°C; Cyclization; isomerization; P=760 Torr; 24 h;

Iwasaki, Takeshi; Kihara, Nobuhiro; Endo, Takeshi

Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 3 p. 713 - 719 Title/Abstract Full Text View citing articles Show Details

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535 Synthesize Find similar Rx-ID: 8618355 Find similar reactions

With oxygen; nitrogen(II) oxide; chlorine

T=-0.15°C; Oxidation; P=700 Torr; Irradiation; KineticsProduct distribution; Further Variations:PressuresTemperatures;

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Orlando, John J.; Iraci, Laura T.; Tyndall, Geoffrey S.

Journal of Physical Chemistry A, 2000 , vol. 104, # 21 p. 5072 - 5079 Title/Abstract Full Text View citing articles Show Details

536 Synthesize Find similar Rx-ID: 8627119 Find similar reactions

A: 18% B: 32% C: 20% D: 30%

With titanium tetrachloride

T=-78°C; Fragmentation; Product distribution; Further Variations:ReagentsTemperatures;

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Dussault, Patrick H.; Lee, Hyung-Jae; Liu, Xuejun

Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 17 p. 3006 3013 Title/Abstract Full Text View citing articles Show Details

537 Synthesize Find similar

A: 50% B: 50%

Rx-ID: 8627124 Find similar reactions

With trimethylsilyl trifluoromethanesulfonate

T=20°C; Fragmentation; Product distribution; Further Variations:ReagentsTemperatures;

Dussault, Patrick H.; Lee, Hyung-Jae; Liu, Xuejun

Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 17 p. 3006 3013 Title/Abstract Full Text View citing articles Show Details

538 Synthesize Find similar

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Rx-ID: 8634694 Find similar reactions

Tanaka, Fujie; Lerner, Richard A.; Barbas III, Carlos F.

Journal of the American Chemical Society, 2000 , vol. 122, # 19 p. 4835 4836 Title/Abstract Full Text View citing articles Show Details

With aldolase antibody 38C2 in dimethyl sulfoxide

T=25°C; retro-aldolization; pH=7.4; Enzymatic reaction; Kinetics; Further Variations:Catalysts;

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539 Synthesize Find similar Rx-ID: 8639624 Find similar reactions

A: 43% B: 5% C: 11% D: 41%

With titanium tetrachloride

T=-78°C; Fragmentation; Product distribution; Further Variations:ReagentsTemperatures;

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Dussault, Patrick H.; Lee, Hyung-Jae; Liu, Xuejun

Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 17 p. 3006 3013 Title/Abstract Full Text View citing articles Show Details

540 Synthesize Find similar

Rx-ID: 8648728 Find similar reactions

With aldolase antibody Fab 28 in dimethyl sulfoxide

T=25°C; retro-aldolization; pH=7.4; Enzymatic reaction; Kinetics; Further Variations:Reagents;

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Tanaka, Fujie; Lerner, Richard A.; Barbas III, Carlos F.

Journal of the American Chemical Society, 2000 , vol. 122, # 19 p. 4835 4836 Title/Abstract Full Text View citing articles Show Details

541 Synthesize Find similar

Rx-ID: 8648729 Find similar reactions

With aldolase antibody Fab 28 in dimethyl sulfoxide

T=25°C; retro-aldolization; pH=7.4; Enzymatic reaction; Kinetics; Further Variations:Reagents;

Tanaka, Fujie; Lerner, Richard A.; Barbas III, Carlos F.

Journal of the American Chemical Society, 2000 , vol. 122, # 19 p. 4835 4836 Title/Abstract Full Text View citing articles Show Details

542 Synthesize Find similar

A: 57% B: 7%

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Rx-ID: 8734825 Find similar reactions

With potassium permanganate; water; aluminum oxide

0.25 h; Heatingmicrowave;

Nuechter, Matthias; Ondruschka, Bernd; Jungnickel, Anja; Mueller, Ute

Journal of Physical Organic Chemistry, 2000 , vol. 13, # 10 p. 579 - 586 Title/Abstract Full Text View citing articles Show Details

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543 Synthesize Find similar

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Rx-ID: 8738540 Find similar reactions

Stage #1: cyclohexene With aluminum oxide; potassium permanganate; water

0.166667 h; Stage #2: diazomethane in diethyl ether

Nuechter, Matthias; Ondruschka, Bernd; Trotzki, Ronald

Advanced Synthesis and Catalysis, 2000 , vol. 342, # 7 p. 720 - 724 Title/Abstract Full Text View citing articles Show Details

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544 Synthesize Find similar

A: 49 % Chromat. B: 7 % Chromat.

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Stage #1: cyclohexanol With aluminum oxide; potassium permanganate; water

0.166667 h; Stage #2: diazomethane in diethyl ether

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Rx-ID: 8738541 Find similar reactions

Nuechter, Matthias; Ondruschka, Bernd; Trotzki, Ronald

Advanced Synthesis and Catalysis, 2000 , vol. 342, # 7 p. 720 - 724 Title/Abstract Full Text View citing articles Show Details

545 Synthesize Find similar

With borax; dipotassium hydrogenphosphate in water

T=30°C; pH=7; Kinetics;

Rx-ID: 8811226 Find similar reactions

Smirnov; Sevast'yanova

Russian Journal of Organic Chemistry, 2000 , vol. 36, # 12 p. 1703 - 1708 Title/Abstract Full Text View citing articles Show Details

546 Synthesize Find similar

Synthesize Find similar

Rx-ID: 8844967 Find similar reactions

With antibody 24H6 in phosphate buffer

pH=7.4; Kinetics;

Shulman; Makarov; Ogawa; Romesberg; Keinan

Journal of the American Chemical Society, 2000 , vol. 122, # 44 p. 10743 10753 Title/Abstract Full Text View citing articles Show Details

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547 Synthesize Find similar

A: 75 % Chromat. B: 13 % Chromat.

Synthesize Find similar

Rx-ID: 10325571 Find similar reactions

With peracetic acid; Ru-carbon in dichloromethane

1 h;

Murahashi; Komiya; Oda; Kuwabara; Naota

Journal of Organic Chemistry, 2000 , vol. 65, # 26 p. 9186 - 9193 Title/Abstract Full Text View citing articles Show Details

548 Synthesize Find similar

Synthesize Find similar

Rx-ID: 15632642 Find similar reactions

Multi-step reaction with 2 steps 1: 33 percent Chromat. / cis-[RuII(6,6'-Cl2bpy)2(OH)2](CF3SO3)2; tert-butyl hydroperoxide / acetone / 24 h / 20 °C 2: 78 percent Chromat. / cis-[RuIV(6,6'-Cl2bpy)2O2](ClO4)2 / acetonitrile / 0.5 h / 20 °C View Scheme

Che; Cheng; Chan; Lau; Mak

Journal of Organic Chemistry, 2000 , vol. 65, # 23 p. 7996 - 8000 Title/Abstract Full Text View citing articles Show Details

549 Synthesize Find similar

Synthesize Find similar

Rx-ID: 24347019 Find similar reactions

With hydroxylamine hydrochloride; sodium acetate; potassium carbonate; lithium chloride in ethanol; water; dimethyl sulfoxide; N,Ndimethyl-formamide

G. D. Searle and Co.

Patent: US5854234 A1, 1998 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

G.D. Searle and Co.

Patent: US6046211 A1, 2000 ; Title/Abstract Full Text Show Details

255:2-(2-butynyl)cyclohexanone, oxime STR261

EXAMPLE 255 2-(2-butynyl)cyclohexanone, oxime STR261 A sample of the 2-carboethoxycyclohexanone is reacted with 1-bromo-2-butyne by the method of EXAMPLE 202 using potassium carbonate in DMF at 60° C. followed decarboethoxylation in refluxing mixture of DMSO, lithium chloride, and water followed by conversion to its oxime using a mixture of hydroxylamine hydrochloride, NaOAc, EtOH and water. A

Synthesize Find similar

550 Synthesize Find similar

A: 12% B: 38%

Rx-ID: 36555183 Find similar reactions

With 2-hydroxy-1,3-isoindolinedione; oxygen in acetonitrile

T=75°C; 20 h; Solvent;

Iwahama, Takahiro; Sakaguchi, Satoshi; Ishii, Yasutaka

Organic Process Research and Development, 2000 , vol. 4, # 2 p. 94 - 97 Title/Abstract Full Text View citing articles Show Details

551 Synthesize Find similar

Synthesize Find similar

Rx-ID: 735800 Find similar reactions

71%

With bis(cyclopentadienyl)titanium dichloride; isopropylmagnesium bromide in tetrahydrofuran; diethyl ether

4 h; Ambient temperature;

Yu, Yongping; Zhang, Yongmin

Synthetic Communications, 1999 , vol. 29, # 2 p. 243 - 247 Title/Abstract Full Text View citing articles Show Details

With sulfuric acid

Dieckmann

Justus Liebigs Annalen der Chemie, 1901 , vol. 317, p. 104 Full Text Show Details

84 % Chromat.

With magnesium chloride in N,N,N,N,N,N-hexamethylphosphoric triamide

T=140 - 150°C; 1 h;

Tsuda, Yoshisuke; Sakai, Yuki

Synthesis, 1981 , # 2 p. 119 - 120 Title/Abstract Full Text Show Details

Hide Details

Multi-step reaction with 2 steps 1: NaOH-solution 2: 20 °C View Scheme

Dieckmann

Justus Liebigs Annalen der Chemie, 1901 , vol. 317, p. 104 Full Text Show Details

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552 Synthesize Find similar

A: 60% B: 25 % Chromat.

in hexane

T=20°C; Dehydroiodination; 1.5 h; Irradiation;

Rx-ID: 2057870 Find similar reactions

Ji, Shun-Jun; Takahashi, Eiji; Takahashi, T. Tomoyoshi; Horiuchi, C. Akira

Tetrahedron Letters, 1999 , vol. 40, # 52 p. 9263 - 9266 Title/Abstract Full Text View citing articles Show Details

With triethylamine in cyclohexane

12 h; Irradiation; Yield given. Yields of byproduct given;

Purohit, P.C.; Sonawane, H.R.

Tetrahedron, 1981 , vol. 37, p. 873 - 877 Title/Abstract Full Text View citing articles Show Details

553 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2084535 Find similar reactions

82%

With aluminium; nickel dichloride in tetrahydrofuran

Substitution;

Bezbarua, Maitreyee S.; Bez, Ghanashyam; Barua, Nabin C.

Chemistry Letters, 1999 , # 4 p. 325 - 326 Title/Abstract Full Text View citing articles Show Details

81%

With L-Selectridereg; in tetrahydrofuran

0.5 h;

Mourad, M. Soubei; Varma, Rajender S.; Kabalka, George W.

Synthesis, 1985 , # 6/7 p. 654 - 656 Title/Abstract Full Text Show Details

80%

With water; magnesium; tin(ll) chloride in tetrahydrofuran

0.25 h; Ambient temperatureother conjugated nitroalkenes and 6-nitro-Δ5-steroids; Al instead Mg, also in absence of water; Product distribution;

Das, Nalin B.; Sarangi, Chintamani; Nanda, Bhagabat; Nayak, Amalendu; Sharma, Ram P.

Journal of Chemical Research - Part S, 1996 , # 1 p. 28 - 29 Title/Abstract Full Text View citing articles Show Details

Hide Details

73%

With sodium tetrahydroborate; dihydrogen peroxide; potassium carbonate in methanol

20 h; Ambient temperature;

Ballini; Bosica

Synthesis, 1994 , # 7 p. 723 - 726 Title/Abstract Full Text View citing articles Show Details

554 Synthesize Find similar

Synthesize Find similar

Rx-ID: 4869371 Find similar reactions

85%

With Clayan

0.0333333 h; Irradiationmicrowave irradiation;

Meshram; Reddy, Gondi Sudershan; Sumitra; Yadav

Synthetic Communications, 1999 , vol. 29, # 7 p. 1113 - 1119 Title/Abstract Full Text View citing articles Show Details

83%

With clay supported ammonium nitrate "Clayan" in dichloromethane

16 h; Ambient temperature;

Meshram; Reddy, Gondi Sudershan; Yadav

Tetrahedron Letters, 1997 , vol. 38, # 51 p. 8891 - 8894 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

555 Synthesize Find similar

With tert.-butylhydroperoxide; ruthenium trichloride

T=20°C; Yield given. Yields of byproduct given;

Rx-ID: 4932550 Find similar reactions

Launay, Franck; Roucoux, Alain; Patin, Henri

Tetrahedron Letters, 1998 , vol. 39, # 11 p. 1353 - 1356

Title/Abstract Full Text View citing articles Show Details

With tert.-butylhydroperoxide; iron powder in acetonitrile

T=25°C; 0.0833333 h; Yield givenYields of byproduct given;

Vincent, Jean-Marc; Bearnais-Barbry, Stephane; Pierre, Celine; Verlhac, Jean-Baptiste

Journal of the Chemical Society - Dalton Transactions, 1999 , # 12 p. 1913 1914 Title/Abstract Full Text View citing articles Show Details

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556 Synthesize Find similar Rx-ID: 5069270 Find similar reactions

A: 14 % Chromat. B: 14 % Chromat. C: 28 % Chromat. D: 45 % Chromat.

With tri-n-butyl-tin hydride in benzene

T=80°C; Reduction; 4 h; Photolysis;

Afzal, Mohammad; Walton, John C.

Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 5 p. 937 - 945 Title/Abstract Full Text View citing articles Show Details

With tri-n-butyl-tin hydride in benzene

T=4.85°C; Reduction; Photolysis; Kinetics; Further Variations:SolventsTemperatures;

Afzal, Mohammad; Walton, John C.

Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 5 p. 937 - 945 Title/Abstract Full Text View citing articles Show Details

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557 Synthesize Find similar

A: 22 % Spectr. B: 17 % Spectr. C: 58 % Spectr.

Rx-ID: 5069271 Find similar reactions

With triphenylstannane in benzene-d6

T=80°C; Reduction; 4 h;

Afzal, Mohammad; Walton, John C.

Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 5 p. 937 - 945 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

558 Synthesize Find similar Rx-ID: 5098808 Find similar reactions

With hydrogen; silica gel; copper in gas T=129.85°C; 3.5 h; other catalysts; also with D2; var. temp. and H2 pressures; Product distribution;

Fasi, Andras; Palinko, Istvan

Journal of Catalysis, 1999 , vol. 181, # 1 art. no. JCAT.1998.2284, p. 28 - 36 Title/Abstract Full Text View citing articles Show Details

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559 Synthesize Find similar

A: 34% B: 58%

Synthesize Find similar

Rx-ID: 5104379 Find similar reactions

With dihydrogen peroxide; methyltrioxorhenium (VII); sodium chloride

10 h; Ambient temperature;

Espenson; Zhu; Zauche

Journal of Organic Chemistry, 1999 , vol. 64, # 4 p. 1191 - 1196 Title/Abstract Full Text View citing articles Show Details

560 Synthesize Find similar

Synthesize Find similar

Rx-ID: 5142376 Find similar reactions

With NiI2; samarium diiodide; COCH(C2H4Cl)(CH2)3

1.) THF, rt, 90 min, 2.) THF, irradiation, 8 h; Yield givenMultistep reaction;

Molander, Gary A.; Machrouhi, Fouzia

Journal of Organic Chemistry, 1999 , vol. 64, # 11 p. 4119 - 4123 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

561 Synthesize Find similar

Synthesize Find similar

Rx-ID: 5188981 Find similar reactions

A: 11 % Chromat. B: 3 % Chromat. C: 31 % Chromat.

With dicobalt octacarbonyl

T=0 - 25°C; silylation;

Sisak, Attila

Journal of Organometallic Chemistry, 1999 , vol. 586, # 1 p. 48 - 53 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

562 Synthesize Find similar Rx-ID: 5193219 Find similar reactions

Synthesize Find similar

With tert.-butylhydroperoxide; iron powder in acetonitrile

T=25°C; 1 h; Yield givenYields of byproduct given;

Vincent, Jean-Marc; Bearnais-Barbry, Stephane; Pierre, Celine; Verlhac, Jean-Baptiste

Journal of the Chemical Society - Dalton Transactions, 1999 , # 12 p. 1913 1914

Title/Abstract Full Text View citing articles Show Details

563 Synthesize Find similar

Synthesize Find similar

Rx-ID: 5199205 Find similar reactions

With chromium(VI) oxide; tert.-butylhydroperoxide in dichloromethane

T=20°C; Oxidation; 12 h;

60%

Synthesize Find similar

Chandrasekhar; Mohanty, Pradyumna K.; Ramachander

Synlett, 1999 , # 7 p. 1063 - 1064 Title/Abstract Full Text View citing articles Show Details

564 Synthesize Find similar

A: 88 % Chromat. B: 11 % Chromat.

Rx-ID: 5199591 Find similar reactions

With zirconium orthophosphate

Dehydration; 15 h; Heating; Product distribution; Further Variations:Reagents;

Al-Qallaf, Fawzia A. H.; Johnstone, Robert A. W.; Liu, Jun-Yao; Lu, Ling; Whittaker, David

Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 7 p. 1421 1423 Title/Abstract Full Text View citing articles Show Details

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565 Synthesize Find similar Rx-ID: 5265480 Find similar reactions

With dihydrogen peroxide; iron (III) perchlorate; tert-butyl alcohol in water

T=23 - 25°C; Oxidation; pH=2.79 - 2.81; UV-irradiation; Kinetics; Further Variations:Reagentswithout UV-irradiation;

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Pignatello, Joseph J.; Liu, Di; Huston, Patrick

Environmental Science and Technology, 1999 , vol. 33, # 11 p. 1832 - 1839 Title/Abstract Full Text View citing articles Show Details

566 Synthesize Find similar

A: 20% B: 60%

With manganese(IV) oxide; aluminium trichloride in acetonitrile

Oxidation; 1 h; Heating;

Rx-ID: 5265608 Find similar reactions

Firouzabadi, Habib; Etemadi, Shahrad; Karimi, Babak; Jarrahpour, Ali Asghar

Synthetic Communications, 1999 , vol. 29, # 24 p. 4333 - 4339 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

567 Synthesize Find similar

A: 5% B: 90%

Rx-ID: 5266256 Find similar reactions

With manganese(IV) oxide; aluminium trichloride in acetonitrile

Hydrolysis; 0.25 h; Heating;

Synthesize Find similar

Firouzabadi, Habib; Etemadi, Shahrad; Karimi, Babak; Jarrahpour, Ali Asghar

Synthetic Communications, 1999 , vol. 29, # 24 p. 4333 - 4339 Title/Abstract Full Text View citing articles Show Details

568 Synthesize Find similar

A: 56 % Chromat. B: 14%

Rx-ID: 5286600 Find similar reactions

Ji, Shun-Jun; Takahashi, Eiji; Takahashi, T. Tomoyoshi; Horiuchi, C. Akira

Tetrahedron Letters, 1999 , vol. 40, # 52 p. 9263 - 9266 Title/Abstract Full Text View citing articles Show Details

in hexane

T=20°C; Dehydroiodination; 1 h; Irradiation;

Synthesize Find similar

569 Synthesize Find similar Rx-ID: 5321831 Find similar reactions

With molecular sieve; air

T=129.85°C; Oxidation; P=11250.9 Torr; Product distribution; Further Variations:Reagentstime;

Synthesize Find similar

Raja, Robert; Sankar, Gopinathan; Thomas, John Meurig

Journal of the American Chemical Society, 1999 , vol. 121, # 50 p. 11926 11927 Title/Abstract Full Text View citing articles Show Details

570 Synthesize Find similar

With oxygen; (nBu4N)4W10O32; silica gel in benzene

T=20°C; P=760 Torr; Irradiationother calalysts and solvents; Product distribution;

Rx-ID: 8515793 Find similar reactions

Molinari, Alessandra; Amadelli, Rossanno; Andreotti, Leonardo; Maldotti, Andrea

Journal of the Chemical Society - Dalton Transactions, 1999 , # 8 p. 1203 1204 Title/Abstract Full Text View citing articles Show Details

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571 Synthesize Find similar

A: 0.2% B: 78%

Synthesize Find similar

Rx-ID: 8569161 Find similar reactions

With potassium hydroxide in dimethyl sulfoxide

T=20 - 35°C; Etherification; Alkylation; 2.5 h;

Tarasova; Shmidt; Sinegovskaya; Petrova; Sobenina; Mikhaleva; Brandsma; Trofimov

Russian Journal of Organic Chemistry, 1999 , vol. 35, # 11 p. 1581 - 1586 Title/Abstract Full Text View citing articles Show Details

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572 Synthesize Find similar

A: 83%

Synthesize Find similar

Rx-ID: 8572832 Find similar reactions

With potassium hydroxide in dimethyl sulfoxide

T=20 - 35°C; Etherification; Alkylation; Hydrolysis; 2.5 h;

Tarasova; Shmidt; Sinegovskaya; Petrova; Sobenina; Mikhaleva; Brandsma; Trofimov

Russian Journal of Organic Chemistry, 1999 , vol. 35, # 11 p. 1581 - 1586 Title/Abstract Full Text View citing articles Show Details

573 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2005066 Find similar reactions

With chromium(III) stearate; cyclohexanol in cyclohexane

T=76.9°C; var. amount of cyclohexanol; Rate constant;

Petrov, L. V.; Solyanikov, V. M.

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 10 p. 1958 - 1960 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 10 p. 2239 2242 Title/Abstract Full Text View citing articles Show Details

With pyridine-D5; iron(III) chloride in tetradeuterioacetic acid T=25°C; 5 h; var. reaction times, bases, also in the presence of H2O2 or FeCl2 or Zn; Product distributionMechanism;

Mark, Scott B.; Richens, David T.

ACH - Models in Chemistry, 1998 , vol. 135, # 5 p. 821 - 836 Title/Abstract Full Text View citing articles Show Details

in cyclohexane

Sun Company, Inc. (R and M)

Patent: US5672778 A1, 1997 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

3:Example 3

Example 3 Dry cyclohexyl hydroperoxide (54percent), 0.5 ml, was added to a stirred solution of cyclohexane, 2.6 ml, containing Fe(TPPF20 Cl8)Cl, 1.2 mg. The reaction mixture was stirred for 5 hours at room temperature. Iodometric titration showed that over 99percent of the hydroperoxide had reacted. Gas chromatography of the reaction mixture showed that the major product of reaction was cyclohexanol and the minor product was cyclohexanone formed in a 9/1 ratio. The combination of cyelohexanol and cyelohexanone formed was greater than the amount of cyclohexyl hydroperoxide used (determined by iodometric titration of starting material) on a molar basis.

574 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2039662 Find similar reactions

67%

With hexaaquairon(III) perchlorate

2 h;

Parmar, Anupama; Goyal, Rita; Kumar, Baldev; Kumar, Harish

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1998 , vol. 37, # 9 p. 941 - 942 Title/Abstract Full Text Show Details

49.23%

With nickel(II) nitrate hexahydrate in ethanol

4 h; Heating;

Cabrera, Armando; Diaz-Tejeda, Alfonso; Marquez, Carmen; ValdesMartinez, Jesus

Monatshefte fuer Chemie, 1991 , vol. 122, # 4 p. 235 - 240 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

575 Synthesize Find similar

Rx-ID: 4821920 Find similar reactions

With 4-(tert-butyl)pyridine; hydrogen sulfide; oxygen; iron(II) chloride in acetonitrile

4 h; Ambient temperatureother reagents; Product distribution;

Synthesize Find similar

Barton, Derek H.R.; Li, Tingsheng

Chemical Communications, 1998 , # 7 p. 821 - 822 Title/Abstract Full Text View citing articles Show Details

576 Synthesize Find similar

Rx-ID: 4839756 Find similar reactions

T=25°C; binding of cyclodextrins to various guests; formation of 1:1 complexes; dissociation constants of CD-guest complexes; effect of guests on the CD-retarded hydrolysis of benzaldehyde dimethyl acetal; Equilibrium constant;

Synthesize Find similar

Tee, Oswald S.; Fedortchenko, Alexei A.; Soo, Patrick Lim

Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 1 p. 123 - 128 Title/Abstract Full Text View citing articles Show Details

577 Synthesize Find similar Rx-ID: 4854038 Find similar reactions

With Ti-MCM-48; dihydrogen peroxide

T=49.9°C; 3 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Tatsumi, Takashi; Koyano, Keiko A.; Igarashi, Naoko

Chemical Communications, 1998 , # 3 p. 325 - 326 Title/Abstract Full Text View citing articles Show Details

With dihydrogen peroxide; Ti-MCM-41

T=49.9°C; 3 h; various catalysts and time; Product distribution;

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Tatsumi, Takashi; Koyano, Keiko A.; Igarashi, Naoko

Chemical Communications, 1998 , # 3 p. 325 - 326 Title/Abstract Full Text View citing articles Show Details

578 Synthesize Find similar

Rx-ID: 4876910 Find similar reactions

A: 16 % Chromat. B: 84 % Chromat.

With hydrogen; montmorillonite-(OSi(OMe)2CH2CH2PPh2lt;Rugt;)x in benzene

T=75°C; P=25857.4 Torr; 48 h;

Aldea, Raluca; Alper, Howard

Journal of Organometallic Chemistry, 1998 , vol. 551, # 1-2 p. 349 - 354 Title/Abstract Full Text View citing articles Show Details

A: 16 % Chromat. B: 84 % Chromat.

With hydrogen; montmorillonite-(OSi(OMe)2CH2CH2PPh2lt;Rugt;)x in benzene

T=75°C; P=25857.4 Torr; 48 h;

Aldea, Raluca; Alper, Howard

Journal of Organometallic Chemistry, 1998 , vol. 551, # 1-2 p. 349 - 354 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

579 Synthesize Find similar

Rx-ID: 4968084 Find similar reactions

Abraham, Michael H.; Prior, David V.; Schulz, Ronald A.; Morris, Jeffrey J.; Taylor, Peter J.

Journal of the Chemical Society - Faraday Transactions, 1998 , vol. 94, # 7 p. 879 - 885 Title/Abstract Full Text View citing articles Show Details

in cyclohexane

T=24.9°C; Equilibrium constant;

Synthesize Find similar

580 Synthesize Find similar

Abraham, Michael H.; Prior, David V.; Schulz, Ronald A.; Morris, Jeffrey J.; Taylor, Peter J.

Journal of the Chemical Society - Faraday Transactions, 1998 , vol. 94, # 7 p. 879 - 885 Title/Abstract Full Text View citing articles Show Details

in cyclohexane

T=24.9°C; Equilibrium constant;

581

Rx-ID: 4968113 Find similar reactions

Synthesize Find similar

Rx-ID: 4975292 Find similar reactions

Synthesize Find similar

Zinov'eva; Dolganova; Dodonov; Prezhbog

Russian Chemical Bulletin, 1998 , vol. 47, # 4 p. 659 - 662 Title/Abstract Full Text View citing articles Show Details

T=10 - 15°C; 30 h; alsoin toluene, other reaction time; Product distribution;

Synthesize Find similar

582 Synthesize Find similar

Rx-ID: 4983837 Find similar reactions

With phenyl silane; water; nickel; triphenylphosphine

1.) THF, reflux, 1 h; Yield given. Multistep reaction;

Boudjouk, Philip; Choi, Seok-Bong; Hauck, Brian J.; Rajkumar, Amirthini B.

Tetrahedron Letters, 1998 , vol. 39, # 23 p. 3951 - 3952 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

583 Synthesize Find similar

Rx-ID: 4990247 Find similar reactions

With XeF2 in dichloromethane

var. solv. and material of vessel; Mechanism;

Ramsden; Smith

Journal of the American Chemical Society, 1998 , vol. 120, # 27 p. 6842 6843 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

584 Synthesize Find similar Rx-ID: 4990627 Find similar reactions

With CoAPO-5; oxygen; acetaldehyde in acetic acid

T=109.9°C; P=15751.3 Torr; role of cobalt molecular sieves;

585

Belkhir, Ines; Germain, Alain; Fajula, Francois; Fache, Eric

Journal of the Chemical Society - Faraday Transactions, 1998 , vol. 94, # 12 p. 1761 - 1764 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 5006980 Find similar reactions

Synthesize Find similar

With pyridine-2-carboxylic acid; dihydrogen peroxide; oxygen; iron(III) chloride in pyridine

5 h; Ambient temperaturecompetitive oxidation of cyclohexane and various aromatic derivatives; Product distributionKineticsMechanism;

Synthesize Find similar

Barton, Derek H.R.; Launay, Franck

Tetrahedron, 1998 , vol. 54, # 14 p. 3379 - 3390 Title/Abstract Full Text View citing articles Show Details

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586 Synthesize Find similar Rx-ID: 5043748 Find similar reactions

With air; sodium acetate; palladium diacetate; bathophenanthroline disulfonate disodium salt in water

T=100°C; P=22501.8 Torr; 10 h; Yield given. Further byproducts given. Title compound not separated from byproducts;

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Brink, Gerd-Jan Ten; Arends, Isabel W. C. E.; Papadogianakis, Georgios; Sheldon, Roger A.

Chemical Communications, 1998 , # 21 p. 2359 - 2360 Title/Abstract Full Text View citing articles Show Details

587 Synthesize Find similar

Synthesize Find similar

Rx-ID: 5053120 Find similar reactions

C: 48%

With meso-tetrakis(pentafluorophenyl)porphyrinatoiron(II) in dichloromethane

Oxidation;

Assis, Marilda Das Dores; Lindsay Smith, John R.

Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 10 p. 2221 2226 Title/Abstract Full Text View citing articles Show Details

C: 42%

With iron 5(pentafluorophenyl)-10,15,20-tris(2,6-dichloropheny.. in dichloromethane

Oxidation; iron 5-(pentafluorophenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin was used as catalyst;

Assis, Marilda Das Dores; Lindsay Smith, John R.

Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 10 p. 2221 2226 Title/Abstract Full Text View citing articles Show Details

C: 32%

With iron 5,10,15,20-tetrakis-(2',6'-dichlorophenyl)porphyrinate in dichloromethane

Oxidation;

Assis, Marilda Das Dores; Lindsay Smith, John R.

Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 10 p. 2221 2226 Title/Abstract Full Text View citing articles Show Details

588 Synthesize Find similar

Synthesize Find similar

Rx-ID: 5070444 Find similar reactions

With bismuth(III) chloride in tetrahydrofuran; water

catalysed cleavage; 0.166667 h; microwave irradiation;

70%

Baruah, Mukulesh; Prajapati, Dipak; Sandhu, Jagir S.

Synthetic Communications, 1998 , vol. 28, # 22 p. 4157 - 4163 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

589 Synthesize Find similar

Synthesize Find similar

Rx-ID: 5087532 Find similar reactions

A: 90%

With oxygen; thiamine diphosphate in dichloromethane

T=-20°C; 1.5 h; Irradiation;

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio

Journal of Organic Chemistry, 1998 , vol. 63, # 25 p. 9528 - 9532 Title/Abstract Full Text View citing articles Show Details

With oxygen; thiamine diphosphate in chloroform-d1; monofluoro-trichloromethane

T=-70 - 0°C; NMR monitoring; Product distribution;

Iesce, M. Rosaria; Cermola, Flavio; Guitto, Antonio

Journal of Organic Chemistry, 1998 , vol. 63, # 25 p. 9528 - 9532 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

590 Synthesize Find similar

Synthesize Find similar

Rx-ID: 5092976 Find similar reactions

With pyridine-2-carboxylic acid; tributylphosphine; dihydrogen peroxide; iron(III) chloride; lithium iodide in pyridine; water

T=-20°C; 3 h; other temperature, reaction time, various amounts of reagents; Product distribution;

Synthesize Find similar

Barton, Derek H.R.; Li, Tingsheng; Peralez, Eric

Tetrahedron, 1998 , vol. 54, # 50 p. 15087 - 15096 Title/Abstract Full Text View citing articles Show Details

591 Synthesize Find similar Rx-ID: 5092979 Find similar reactions

With pyridine-2-carboxylic acid; dihydrogen peroxide; lithium chloride; lithium iodide; iron(II) chloride in pyridine; water

T=-20°C; 0.166667 h; other reagents, temperature, reaction time, various amounts of reagents; Product distribution;

592

Barton, Derek H.R.; Li, Tingsheng; Peralez, Eric

Tetrahedron, 1998 , vol. 54, # 50 p. 15087 - 15096 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

Rx-ID: 5113464 Find similar reactions

Synthesize Find similar

A: 4% B: 60% C: 10%

With 9,10-anthracenedicarbonitrile; triphenylphosphine in water; N,N-dimethyl-formamide; isopropyl alcohol

Irradiation;

Pandey, Ganesh; Ghorai, Manas K.; Hajra, Saumen

Tetrahedron Letters, 1998 , vol. 39, # 45 p. 8341 - 8344 Title/Abstract Full Text View citing articles Show Details

A: 4% B: 60% C: 10%

With 9,10-anthracenedicarbonitrile; triphenylphosphine in water; N,N-dimethyl-formamide; isopropyl alcohol

Irradiation;

Pandey, Ganesh; Ghorai, Manas K.; Hajra, Saumen

Tetrahedron Letters, 1998 , vol. 39, # 45 p. 8341 - 8344 Title/Abstract Full Text View citing articles Show Details

A: 4% B: 60% C: 10%

With 9,10-anthracenedicarbonitrile; triphenylphosphine in water; N,N-dimethyl-formamide; isopropyl alcohol

Irradiation;

Pandey, Ganesh; Ghorai, Manas K.; Hajra, Saumen

Tetrahedron Letters, 1998 , vol. 39, # 45 p. 8341 - 8344 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

593 Synthesize Find similar Rx-ID: 5143286 Find similar reactions

With tert.-butylhydroperoxide; molecular sieve in tert-butyl alcohol

T=60°C; 40 h; other metal substituted octahedral molecular sieves as catalysts; var. temp. and time, effect of tert-butyl hydrogen peroxide, catalyst and solvent amounts; Product distribution;

Wang, Jin-Yun; Xia, Guan-Guang; Yin, Yuan-Gen; Suib, Steven L.; O'Young

Journal of Catalysis, 1998 , vol. 176, # 2 p. 275 - 284 Title/Abstract Full Text View citing articles Show Details

594 Synthesize Find similar 48%

Synthesize Find similar

With hexaaquairon(III) perchlorate

2 h;

Rx-ID: 5150599 Find similar reactions

Parmar, Anupama; Goyal, Rita; Kumar, Baldev; Kumar, Harish

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1998 , vol. 37, # 9 p. 941 - 942 Title/Abstract Full Text Show Details