Cyclohexanone by Asch

Reaxys

PubChem

eMolecules

Reactions (1470)

Yield

Substances (2)

Citations (3478)

Conditions

References A

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199 Synthesize Find similar Rx-ID: 38242997 Find similar reactions

With oxygen in neat (no solvent) T=280°C; Gas phaseGreen chemistry; Reagent/catalystTemperature;

Mao, Junjie; Zhao, Guofeng; Wang, Dingsheng; Li, Yadong

RSC Advances, 2014 , vol. 4, # 48 p. 25384 - 25388 Title/Abstract Full Text View citing articles Show Details

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200 Synthesize Find similar Rx-ID: 38243369 Find similar reactions

With 5 ruthenium on aluminium oxide; phosphoric acid; hydrogen in water

T=199.84°C; P=15001.5 Torr; 2 h; Autoclave; Hide Experimental Procedure

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Experimental setup and procedure

General procedure: Stainless-steel autoclaves with an internal volume of 12 mL were used for all reactions. In a typical run, the amount of reactant was 1.6 and 0.8 mmol for monomeric and dimeric compounds, respectively. In each run, 5 mg of catalyst was used. The volume of solvent (water) was 6 mL. After the reactor was loaded with catalyst, reactant and solvent, it was flushed with H2 for 3 times. Then, it was pressurized by H2 to a total pressure 20 bar at room temperature. The autoclave was rapidly heated to 473 K (5 min) under stirring at 1000 rpm with a magnetic stirrer bar. After the reaction, the reactor was quenched in an ice bath. Acidified reaction mixtures were obtained by adding phosphoric acid such that the final concentration was 0.5 wtpercent (pH = 2.1). A

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201 Synthesize Find similar

Rx-ID: 38243375 Find similar reactions

Multi-step reaction with 2 steps 1: 5 wt ruthenium/carbon; hydrogen / water / 4 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: 5 wt ruthenium/carbon; hydrogen / water / 4 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

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202 Synthesize Find similar

Multi-step reaction with 2 steps 1: 5 wt ruthenium/carbon; hydrogen / water / 4 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

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Rx-ID: 38243376 Find similar reactions

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

203 Synthesize Find similar

Rx-ID: 38243386 Find similar reactions

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: palladium on activated carbon; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 1 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: palladium on activated carbon; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: palladium on activated carbon; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Hide Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 4 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: palladium on activated carbon; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: palladium on activated carbon; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

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204 Synthesize Find similar

Rx-ID: 38243388 Find similar reactions

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 1 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Hide Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 4 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 1 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 4 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; phosphoric acid; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

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205 Synthesize Find similar

Rx-ID: 38243389 Find similar reactions

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 1 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Hide Details

Multi-step reaction with 2 steps 1: phosphoric acid; hydrogen; 5 wt Pt/C / water / 4 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: hydrogen; 5 wt Pt/C / water / 0.5 h / 199.84 °C / 15001.5 Torr / |Autoclave 2: 5 ruthenium on aluminium oxide; hydrogen / water / 2 h / 199.84 °C / 15001.5 Torr / |Autoclave View Scheme

Guevenatam, Burcu; Kursun, Osman; Heeres, Erik H.J.; Pidko, Evgeny A.; Hensen, Emiel J.M.

Catalysis Today, 2014 , vol. 233, p. 83 - 91 Title/Abstract Full Text View citing articles Show Details

206 Synthesize Find similar Rx-ID: 38253277 Find similar reactions

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With La0.5Ce0.5NiO3; hydrogen in N-dodecane

T=300°C; P=37503.8 Torr; Inert atmosphereAutoclave; Reagent/catalyst; Hide Experimental Procedure

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Escalona, Nestor; Aranzaez, Wladimir; Leiva, Katherine; Martinez, Natalia; Pecchi, Gina

Applied Catalysis A: General, 2014 , vol. 481, p. 1 - 10 Title/Abstract Full Text View citing articles Show Details

2.3. Catalytic tests

The catalytic conversion of guaiacol was carried out in an autoclave reactor operating in batch mode. Prior to the catalytic test, the perovskites were ex situ activated under H2(AGA Chile, 99.99percent) at 500°C to obtain Ni-reduced catalyst. Guaiacol (0.232 mol L−1) with hexadecane as an internal standard were dissolved in

n-dodecane (80 mL) and introduced into a batch reactor containing freshly reduced 0.20 g of Ni-reduced catalyst. To avoid air contamination, the system was closed and bubbled with nitrogen for 10 min. The reactor was then heated up, with continuous stirring, to the reaction temperature of 300°C under N2with a ramp of 10°C/min. When this temperature was reached the first sample was taken and H2 was introduced into the reactor, up to a total pressure of 5 MPa and kept constant during the course of the experiment. Samples were periodically taken during the reaction and analyzed in a Perkin Elmer (Clarus 400) gas chromatograph equipped with a flame ionization detector (FID) and a CP-Sil 5 CB column (Agilent, 30 m × 0.53 mm × 1.0 m film thickness). A

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207 Synthesize Find similar

A: 8% B: 66% C: 15%

With oxygen; acetonitrile

T=140°C; P=11251.1 Torr; 4 h; Catalytic behaviorMechanism;

Rx-ID: 38342626 Find similar reactions

Zhang, Yicheng; Dai, Weili; Wu, Guangjun; Guan, Naijia; Li, Landong

Chinese Journal of Catalysis, 2014 , vol. 35, # 3 p. 279 - 285 Title/Abstract Full Text Show Details

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208 Synthesize Find similar Rx-ID: 38411797 Find similar reactions

With dihydrogen peroxide in acetonitrile

T=20°C; 3 h; Reagent/catalystTime; Hide Experimental Procedure

Makgwane; Ray

Catalysis Communications, 2014 , vol. 54, p. 118 - 123 Title/Abstract Full Text View citing articles Show Details

2.3. Catalytic activity testing

Catalytic testing was performed in a 50 ml two-necked flask equipped with magnetic stirrer, reflux condenser and thermometer. To a reactor were added cyclohexane (10 mmol, 0.84 g), acetonitrile solvent (5 ml), catalyst (0.05 g) and 50percent H2O2 oxidant (30 mmol). The oxidation products samples were treated with triphenylphosphine before gas chromatograph (GC) coupled to flame ionization detector (FID) analysis using a Supelco SPB-20 column (30 m × 0.25 mm i.d. × 0.25 μm). No differences in product quantitative amounts were observed for the samples analyzed directly without the triphenylphosphine to those treated indicating that the catalyst was effective to decompose readily the formed cyclohexyl peroxide into carbonyls.

With tungsten(VI) oxide; dihydrogen peroxide in acetonitrile

T=20°C; 3 h; Reagent/catalystTime; Hide Experimental Procedure

Makgwane; Ray

Catalysis Communications, 2014 , vol. 54, p. 118 - 123 Title/Abstract Full Text Show Details

Catalytic testing was performed in a 50 ml two-necked flask equipped with magnetic stirrer, reflux condenser and thermometer. To a reactor were added cyclohexane (10 mmol, 0.84 g), acetonitrile solvent (5 ml), catalyst (0.05 g) and 50percent H2O2 oxidant (30 mmol). The oxidation products samples were treated with triphenylphosphine before gas chromatograph (GC) coupled to flame ionization detector (FID) analysis using a Supelco SPB-20 column (30 m × 0.25 mm i.d. ×0.25 μm). No differences in product quantitative amounts were observed for the samples analyzed directly without the triphenylphosphine to those treated indicating that the catalyst was effective to decompose readily the formed cyclohexyl peroxide into carbonyls.

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209 Synthesize Find similar Rx-ID: 38535405 Find similar reactions

With 5,10,15,20-tetrakis-pentafluorophenyl-21H,23H-porphyrin iron(III) chloride; oxygen in chloroform

20 h; UV-irradiation; Catalytic behavior; Reagent/catalyst;

A: 1.39 μmol B: 4.37 μmol C: 8.86 μmol D: 1.5 μmol E: 0.87 μmol F: 1.21 μmol

Teramura, Kentaro; Tsuneoka, Hideo; Ogura, Kentaro; Sugimoto, Takashi; Shishido, Tetsuya; Tanaka, Tsunehiro

ChemCatChem, 2014 , vol. 6, # 8 p. 2276 - 2281 Title/Abstract Full Text View citing articles Show Details

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210 Synthesize Find similar

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Rx-ID: 38845657 Find similar reactions

B: 59%

Korotaev, Vladislav Yu.; Barkov, Alexey Yu.; Matochkina, Evgeniya G.; Kodess, Mikhail I.; Sosnovskikh, Vyacheslav Ya.

Tetrahedron, 2014 , vol. 70, # 34 p. 5161 - 5167 Title/Abstract Full Text Show Details

in acetonitrile

T=20°C; Michael Addition; 0.5 h; diastereoselective reaction; Hide Experimental Procedure

4.2. General procedure for the synthesis of compounds 3a-f

General procedure: A mixture of the corresponding chromene 1 (1.0 mmol) and N-cyclohexenylmorpholine (2a) (0.17 g, 1.0 mmol) was stirred at room temperature in dry acetonitrile (0.6 mL) for 1 h (3a-d) and 0.5 h (3e,f). The solid that formed was filtered and recrystallized from CH2Cl2/hexane (2:3) as a white powder. A

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211 Synthesize Find similar

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Rx-ID: 38845658 Find similar reactions

B: 54%

Korotaev, Vladislav Yu.; Barkov, Alexey Yu.; Matochkina, Evgeniya G.; Kodess, Mikhail I.; Sosnovskikh, Vyacheslav Ya.

Tetrahedron, 2014 , vol. 70, # 34 p. 5161 - 5167 Title/Abstract Full Text Show Details

in acetonitrile

T=20°C; Michael Addition; 0.5 h; diastereoselective reaction; Hide Experimental Procedure

4.2. General procedure for the synthesis of compounds 3a-f

212 Synthesize Find similar Rx-ID: 39209021 Find similar reactions

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With D-glucopyranose; nicotinamide adenine dinucleotide phosphate; lysozyme; DNase I in aq. phosphate buffer

T=25°C; pH=7.4; 20 h; Enzymatic reaction; enantioselective reaction;

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Roiban, Gheorghe-Doru; Agudo, Ruben; Reetz, Manfred T.

Angewandte Chemie - International Edition, 2014 , vol. 53, # 33 p. 8659 - 8663 Title/Abstract Full Text View citing articles Show Details

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213 Synthesize Find similar Rx-ID: 39209026 Find similar reactions

With D-glucopyranose; nicotinamide adenine dinucleotide phosphate; lysozyme; DNase I in aq. phosphate buffer

T=25°C; pH=7.4; 20 h; Enzymatic reaction; enantioselective reaction;

Roiban, Gheorghe-Doru; Agudo, Ruben; Reetz, Manfred T.

Angewandte Chemie - International Edition, 2014 , vol. 53, # 33 p. 8659 - 8663 Title/Abstract Full Text View citing articles Show Details

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214 Synthesize Find similar Rx-ID: 39209035 Find similar reactions

With D-glucopyranose; nicotinamide adenine dinucleotide phosphate; lysozyme; DNase I in aq. phosphate buffer

T=25°C; pH=7.4; 20 h; Enzymatic reaction; enantioselective reaction;

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Roiban, Gheorghe-Doru; Agudo, Ruben; Reetz, Manfred T.

Angewandte Chemie - International Edition, 2014 , vol. 53, # 33 p. 8659 - 8663 Title/Abstract Full Text View citing articles Show Details

215 Synthesize Find similar

A: 58%

Rx-ID: 39286797 Find similar reactions

With 1-deuterio-1-cyclohexanol in chloroform-d1

T=85°C; 18 h; regioselective reaction;

Willoughby, Patrick H.; Niu, Dawen; Wang, Tao; Haj, Moriana K.; Cramer, Christopher J.; Hoye, Thomas R.

Journal of the American Chemical Society, 2014 , vol. 136, # 39 p. 13657 - 13665 Title/Abstract Full Text View citing articles Show Details

216 Synthesize Find similar

A: 53%

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Rx-ID: 39491243 Find similar reactions

Willoughby, Patrick H.; Niu, Dawen; Wang, Tao; Haj, Moriana K.; Cramer, Christopher J.; Hoye, Thomas R.

Journal of the American Chemical Society, 2014 , vol. 136, # 39 p. 13657 - 13665 Title/Abstract Full Text View citing articles Show Details

in chloroform-d1

T=85°C; 18 h; regioselective reaction;

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217 Synthesize Find similar

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Rx-ID: 39533607 Find similar reactions

D: 53%

With disodium hydrogenphosphate; phenylsilane

T=60°C; chemoselective reaction;

Lo, Julian C.; Gui, Jinghan; Yabe, Yuki; Pan, Chung-Mao; Baran, Phil S.

Nature, 2014 , vol. 516, # 7531 p. 343 - 348 Title/Abstract Full Text View citing articles Show Details

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218 Synthesize Find similar

Rx-ID: 824866 Find similar reactions

A: 8.8% B: 39.6%

With HZSM-5(30)

T=180°C; P=760 Torr; 2 h; other catalysts, var. temp.; Product distribution;

Murthy; Srinivas; Kulkarni; Kaushik; Subrahmanyam; Kanta Rao

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 1996 , vol. 35, # 8 p. 649 - 655 Title/Abstract Full Text View citing articles Show Details

T=430 - 500°C;

Yamamoto; Kuraku

Nippon Kagaku Kaishi, 1944 , vol. 65, p. 42,44 Chem.Abstr., 1947 , p. 3768 Full Text Show Details

T=290 - 310°C; Leiten ueber Kupferchromit;

Adkins et al.

Journal of the American Chemical Society, 1933 , vol. 55, p. 2993 Full Text Show Details

Hurd; Greengard; Roe

Journal of the American Chemical Society, 1939 , vol. 61, p. 3359 Full Text View citing articles Show Details

Hide Details

With tin(IV) oxide

T=330°C; other catalysts, with water as reagent, other time and temperature; Product distribution;

Hino, Makoto; Arata, Kazushi

Chemistry Letters, 1990 , # 9 p. 1737 - 1740 Title/Abstract Full Text Show Details

With cerium (IV) oxide

Subramanian, A.; Narayanan, K.; Udupa, M. R.

T=360 - 375°C; Product distribution;

Journal of the Indian Chemical Society, 1981 , vol. 58, p. 292 - 293 Title/Abstract Full Text Show Details

A: 52.6 % Turnov. B: 9.3 % Turnov.

With silica gel; copper

T=250°C; other copper catalysts; Product distribution;

Rachel, Anita; Sivaraj, Ch.; Reddy, G. Krishna; Vijayakumar, V.; Rao, P. Kanta

Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1993 , vol. 32, # 10 p. 857 - 860 Title/Abstract Full Text Show Details

With zinc monohydrogen orthophosphate; sodium carbonate

T=349.9°C; var. temp, var. catalysts; Product distributionKineticsMechanism;

Aramendia, M. A.; Borau, V.; Jimenez, C.; Marinas, J. M.; Romero, F. J.

Journal of Catalysis, 1995 , vol. 151, # 1 p. 44 - 49 Title/Abstract Full Text View citing articles Show Details

With CuCr1.75*Fe0.25O4

T=200°C; var. temp. and spinel systems CuCr2-xFexO4 (x=0-1); Product distribution;

Ahmed, Ashfaq; Oak, S. G.; Darshane, V. S.

Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 12 p. 3651 - 3658 Title/Abstract Full Text Show Details

A: 67.4 % Chromat. B: 14.8 % Chromat.

With copper aluminum spinel

T=248°C; Dehydrogenation; 0.000305556 h; Activation energy; Further Variations:Temperaturescontact time;

Srinivasan, Vijayasri; Nagaraju

Journal of the Indian Chemical Society, 1998 , vol. 75, # 7 p. 418 - 420 Title/Abstract Full Text View citing articles Show Details

With samarium sesquioxide; tin(IV) oxide

T=349.85°C; Dehydration; Dehydrogenation; Product distribution; Further Variations:Catalysts;

Jyothi; Rao; Sugunan; Sreekumar

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 1999 , vol. 38, # 12 p. 1253 - 1255 Title/Abstract Full Text View citing articles Show Details

With aluminum oxide; In2O3

T=423°C; Kinetics; Further Variations:Reagents;

Haneda; Joubert; Bion; Hamada; Menezo; Daturi; Duprez; Saussey; Barbier; Lavalley

Physical Chemistry Chemical Physics, 2001 , vol. 3, # 7 p. 1366 - 1370 Title/Abstract Full Text View citing articles Show Details

With samarium sesquioxide; vanadium pentoxide

T=300°C; 1 h; Product distribution; Further Variations:Catalysts;

Sugunan, Sankaran; Renuka, Neeroli Kizhakayil

Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 3 p. 463 - 471 Title/Abstract Full Text View citing articles Show Details

With dysprosium((III) oxide

T=349.85°C; Product distribution; Further Variations:Catalysts;

Sugunan; Renuka

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2002 , vol. 41, # 4 p. 692 - 700 Title/Abstract Full Text View citing articles Show Details

With samarium sesquioxide

T=349.85°C; Product distribution; Further Variations:Catalysts;

Sugunan; Renuka

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2002 , vol. 41, # 2 p. 304 - 307 Title/Abstract Full Text View citing articles Show Details

With Cu(0)/SiO2

T=299.84°C; 0.5 h; Product distribution; Further Variations:Reagents;

Ji; Zou; Zheng; Wang; Liu; Zhu

Polish Journal of Chemistry, 2008 , vol. 82, # 5 p. 1097 - 1104 Title/Abstract Full Text View citing articles Show Details

With Mg/Al-5.0 calcined hydrotalcite T=300°C;

Manivannan; Pandurangan

Kinetics and Catalysis, 2010 , vol. 51, # 1 p. 56 - 62 Title/Abstract Full Text View citing articles Show Details

With Zn/Al-3.0 calcined hydrotalcite T=300°C;

Manivannan; Pandurangan

Kinetics and Catalysis, 2010 , vol. 51, # 1 p. 56 - 62 Title/Abstract Full Text View citing articles Show Details

With TiFeMCM-41 mesoporous material T=239.84°C; P=760.051 Torr; Flow reactor;

Popova; Szegedi; Lazar; Dimitrova

Catalysis Letters, 2011 , vol. 141, # 9 p. 1288 - 1296 Title/Abstract Full Text View citing articles Show Details

With Sc2O3 in ethanol

T=350°C; 5 h; Inert atmosphere;

Abe, Katsutoshi; Ohishi, Yusuke; Okada, Takuto; Yamada, Yasuhiro; Sato, Satoshi

Catalysis Today, 2011 , vol. 164, # 1 p. 419 - 424 Title/Abstract Full Text View citing articles Show Details

With CuO on mesoporous silica

T=239.84°C; P=760.051 Torr; 1 h; Inert atmosphere;

Popova; Dimitrov; Santo, V. Dal; Ravasio; Scotti

Catalysis Communications, 2012 , vol. 17, p. 150 - 153 Title/Abstract Full Text View citing articles Show Details

With copper(II) oxide/cerium(IV) oxide-modified mesoporous SBA-15 silica; oxygen

T=229.84°C; Flow reactor;

Tsoncheva, Tanya; Issa, Gloria; Blasco, Teresa; Dimitrov, Momtchil; Popova, Margarita; Hernandez, Selene; Kovacheva, Daniela; Atanasova, Genoveva; Nieto, Jose M. Lopez

Applied Catalysis A: General, 2013 , vol. 453, p. 1 - 12 Title/Abstract Full Text View citing articles Show Details

T=250°C; P=760.051 Torr; 1 h; Flow reactorInert atmosphere; Hide Experimental Procedure

Tangale, Nilesh P.; Niphadkar, Prashant S.; Deshpande, Shilpa S.; Joshi, Praphulla N.

Applied Catalysis A: General, 2013 , vol. 467, p. 421 - 429 Title/Abstract Full Text View citing articles Show Details

2.4. Catalytic activity

The dehydrogenation of cyclohexanol over Cu/Al2O3catalysts (molar Cu:Al = 1:1) prepared by reduction of mixed oxide precur-sors synthesized using different precipitating agents was carried out in a continuous, down-flow, fixed bed reactor (SS316, 40 cml ength, 2 cm I.D.) at atmospheric pressure. In a reactor, the reduced catalyst (3.0 g, self-bound granules with 20–40 mesh size) was sandwiched at the center by inert ceramic beads. The reactor was heated to the required temperature with an electrical tubu-lar furnace having digital temperature controller cum indicator. The mixed oxide precursor was reduced in situ in a H2 flow of 55 cm3min−1at 250°C for 8 h. The cyclohexanol was fed to the reactor with weight hour space velocity (WHSV) ranging from of 3.0 to 10.0 h−1with nitrogen (50 cm3min−1). The product was collected after 1 h and analyzed by gas chromatography (Shimadzu, HP 5890A) using a flame ionization detector (FID) and carbowax column (30 m length, 0.53 mm I.D. and 1 m film thickness). Quantification of various products was accomplished using response factors of typical standard mixtures. The liquid mass balance was 98 ± 2percent. Based on the product distribution pattern, the cyclohexanol conversion and the selectivity to the products such as, cyclohexanone, phenol, and cyclohexene were calculated.

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90%

With copper(II) sulfate in tetrahydrofuran; methanol; water

4 h; Heating;

Attanasi, Orazio; Gasperoni, Simonetta; Carletti, Claudio

Journal fuer Praktische Chemie (Leipzig), 1980 , vol. 322, # 6 p. 1063 - 1066 Title/Abstract Full Text Show Details

88%

With potassium peroxomonosulphate in water; acetic acid

T=40 - 45°C; Oxidation; 0.85 h;

Bose, D. Subhas; Vanajatha; Srinivas

Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1999 , vol. 38, # 7 p. 835 - 836 Title/Abstract Full Text View citing articles Show Details

85%

With polumer-supported phenyliodine bis(trifluoroacetate); water in tetrahydrofuran

0.416667 h;

Chen; Cheng

Synthetic Communications, 2001 , vol. 31, # 24 p. 3847 - 3850 Title/Abstract Full Text View citing articles Show Details

Hide Details

83%

With bismuth(III) chloride; water in tetrahydrofuran

0.0833333 h; Irradiation;

Boruah, Anima; Baruah, Bipul; Prajapati, Dipak; Sandhu, Jagir S.

Synlett, 1997 , vol. 1997, # 11 p. 1251 - 1252 Title/Abstract Full Text View citing articles Show Details

80%

With iodobenzene; hexafluoroisopropyl alcohol; 3-chloro-benzenecarboperoxoic acid

T=20°C; 6 h; Hide Experimental Procedure

Jia, Xiao-Chuan; Li, Jing; Yu, Zhi-Rui; Wang, Yu-Hu; Zhou, Lei; Yu, Yan-Yan

Journal of Chemical Research, 2013 , vol. 37, # 7 p. 420 - 421 Title/Abstract Full Text View citing articles Show Details

Deprotection of hydrazones; typical procedure:

General procedure: mCPBA (1.5 equiv.) was added to a stirred solution of hydrazone(1 mmol, 1.0 equiv.) and iodobenzene (20 molpercent) in HFIP (2 mL) at room temperature under air. The mixture was stirred and the progress of the reaction was monitored by TLC using ethyl acetate and n-hexane as eluent. After the appropriate time, saturated NaHCO3(5 mL) was added to the reaction mixture. The resulting solution was extracted with ethyl acetate (3 × 10 mL) and washed with brine(2 × 5 mL). Drying over Na2SO4 and evaporation of the solvent gave a residue that was purified on silica gel column chromatography using n-hexane and ethyl acetate as eluent to afford analytically pure carbonyl compounds. 76%

With K-10 clay-supported Fe(NO3)3 ("clayfen" reagent) in dichloromethane

3 h; Heating;

Laszlo, Pierre; Polla, Eugenio

Synthesis, 1985 , # 4 p. 439 - 440 Title/Abstract Full Text Show Details

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Rx-ID: 2676977 Find similar reactions

A: 32% B: 61%

With carbonylchloro[4,5bis(diisopropylphosphinomethyl)acridine]hydridoruthenium(II); water in 1,4-dioxane

T=135°C; 48 h; Schlenk techniqueInert atmosphere; Pressure;

Khusnutdinova, Julia R.; Ben-David, Yehoshoa; Milstein, David

Angewandte Chemie - International Edition, 2013 , vol. 52, # 24 p. 6269 - 6272 Angew. Chem., 2013 , vol. 125, # 24 p. 6389 - 6392,4 Title/Abstract Full Text View citing articles Show Details

A: 13 % Chromat. B: 10 % Chromat.

With air; trans-lt;Ru(VI)(dianion of 5,10,15,20-tetramesitylporphyrin)(O)2gt; in benzene

T=50°C; 24 h; Title compound not separated from byproducts;

Bailey, Alan J.; James, Brian R.

Chemical Communications, 1996 , # 20 p. 2343 - 2344 Title/Abstract Full Text View citing articles Show Details

A: 0.3% B: 0.7%

With hydrogen; magnesium oxide; ruthenium in water

T=99.9°C; P=15001.2 Torr; Product distribution;

Sokol'skii, D. V.; Ualikhanova, A.; Temirbulatova, A. E.; Mailyubaev, B. T.

Journal of Organic Chemistry USSR (English Translation), 1986 , p. 1520 - 1524 Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 8 p. 1693 - 1697 Title/Abstract Full Text Show Details

Hide Details

A: 13 % Chromat. B: 10 % Chromat.

With air; trans-lt;Ru(VI)(dianion of 5,10,15,20-tetramesitylporphyrin)(O)2gt; in benzene

T=50°C; 24 h; Title compound not separated from byproducts;

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Bailey, Alan J.; James, Brian R.

Chemical Communications, 1996 , # 20 p. 2343 - 2344 Title/Abstract Full Text View citing articles Show Details

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With magnesium oxide

T=180°C; var. temperatures; object of study: standard molar reaction enthalpy (ΔrHm0) and entropy (ΔrSm0); Equilibrium constantThermodynamic data;

Kabo, G. J.; Yursha, I. A.; Frenkel, M. L.; Poleshchuk, P. A.; Fedoseenko, V. I.; Ladutko, A. I.

Journal of Chemical Thermodynamics, 1988 , vol. 20, # 4 p. 429 - 438 Title/Abstract Full Text View citing articles Show Details

With potassium hydroxide; Ru(O2CCF3)2(CO)(PPh3)2

T=140°C; ΔG (gas); Equilibrium constantThermodynamic data;

Strohmeier, Walter; Graser, Barbara

Zeitschrift fuer Physikalische Chemie (Muenchen, Germany), 1980 , vol. 121, p. 121 - 130 Title/Abstract Full Text Show Details

With NADP embedded in ketoreductase preparation in phosphate buffer; hexane

T=15.19°C; P=750.075 Torr; pH=7.3; 12 h; Equilibrium constant; Further Variations:TemperaturesSolventsPressures;

Tewari, Yadu B.; Phinney, Karen W.; Liebman, Joel F.

Journal of Chemical Thermodynamics, 2006 , vol. 38, # 4 p. 388 - 395 Title/Abstract Full Text View citing articles Show Details

Rx-ID: 3528204 Find similar reactions

Hide Details

A: 42 %Chromat.

With Zeolite HBEA zeolyst T=75°C; 3 h; Reagent/catalyst; Hide Experimental Procedure

RHODIA OPERATIONS; Jacquot, Roland; Marion, Philippe

Patent: US2013/204046 A1, 2013 ; Location in patent: Paragraph 0072 ; Title/Abstract Full Text Show Details

EXAMPLE 2 [0072] Into a reactor that can operate under pressure, 100 g of cyclohexanol, i.e. 1 mol, and 350 g of acetone, i.e. 6 mol, are introduced. The mixture is stirred and 20 g of catalyst are added. The reaction medium is then heated at 75° C. and at autogenous pressure, and kept under these conditions for 3 h. The reaction medium is then analysed by GC. The results obtained are listed in Table 2. A

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222 Synthesize Find similar Rx-ID: 3855593 Find similar reactions

A: 25.9% B: 3.3% C: 2.3% D: 4.1%

With dihydrogen peroxide in isopropyl alcohol

T=50°C; 15 h; Further byproducts given;

Itoi, Yasushi; Inoue, Masami; Enomoto, Saburo; Watanabe, Yoshihiro

Chemical and Pharmaceutical Bulletin, 1984 , vol. 32, # 2 p. 418 - 423 Title/Abstract Full Text Show Details

A: 0.09% B: 0.03% C: 0.02% D: 0.01%

With hydrogen; oxygen

T=100°C; Hide Experimental Procedure

National Institute of Advanced Industrial Science and Technology; NOK Corporation

Patent: EP1357103 A1, 2003 ; Location in patent: Page/Page column 13-14 ; Title/Abstract Full Text Show Details

[0077] Cyclohexene, oxygen, and nitrogen were supplied to the reaction compound residence section 1 of the apparatus of Example 1 respectively at a rate of 0.72 mmol/min, 0.36 mmol/min, and 1.8 mmol/min. Hydrogen and nitrogen were supplied to the activation substance circulation section 2 respectively at a rate of 0.36 mmol/min and 3.2 mmol/min. The reaction was conducted at 100 DEG C under normal pressure to produce cyclohexene oxide, cyclohexanol, cyclohexanone, and cyclohexenone as the oxygen-containing organic compounds respectively at a yield of 0.03 molpercent, 0.01 molpercent, 0.02 molpercent, and 0.09 molpercent. [0078] This Example confirmed that cyclohexene oxide, cyclohexanol, cyclohexanone, cyclohexenone, and the like were produced using cyclohexene as a raw material.

With tert.-butylhydroperoxide in water

T=70 - 80°C; P=760.051 Torr; 6 h; Catalytic behavior; Hide Experimental Procedure

Ameur; Bedrane; Bachir; Choukchou-Braham

Journal of Molecular Catalysis A: Chemical, 2013 , vol. 374-375, p. 1 - 6 Title/Abstract Full Text View citing articles Show Details

ii:Catalytic tests

General procedure: Catalytic tests were performed using 0.1 g of catalyst, 4 mL ofcyclohexene and 5.5 mL of tert-butyl hydroperoxide [TBHP (70percent) inwater]. The oxidation of cyclohexene was carried out at 70 C for6 h under atmospheric pressure. Hide Details

With tert.-butylhydroperoxide in water

T=70 - 80°C; P=760.051 Torr; 6 h; Catalytic behavior; Hide Experimental Procedure

Ameur; Bedrane; Bachir; Choukchou-Braham

Journal of Molecular Catalysis A: Chemical, 2013 , vol. 374-375, p. 1 - 6 Title/Abstract Full Text View citing articles Show Details

ii:Catalytic tests

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Rx-ID: 18473098 Find similar reactions

Multi-step reaction with 2 steps 1: 1.) pyridine, 2.) CrO3 / 1.) CHCl3, 0 deg C, 3 h, 2.) H2O, CH3COOH, 0 deg C, 1 h 2: 26 percent Chromat. / PhN=NPh / dimethylformamide / 20 °C / electrochemical reaction: 0,1 mol/dm3 Et4NClO4, -1,5 V, mercury pool cathode

Angelis, F. De; Feroci M.; Inesi, A.

Bulletin de la Societe Chimique de France, 1993 , vol. 130, p. 712 - 719 Title/Abstract Full Text Show Details

Multi-step reaction with 2 steps 1: 1.) pyridine, 2.) CrO / 1.) CHCl , 0 deg C, 3 h, 2.) H O, CH COOH, 0 deg C, 1 h

Angelis, F. De; Feroci M.; Inesi, A.

Bulletin de la Societe Chimique de France, 1993 , vol. 130, p. 712 - 719

View Scheme

2: 12 percent Chromat. / PhN=NPh / dimethylformamide / 20 °C / electrochemical reaction: 0.1 mol/dm3 Et4NClO4, -1.5 V, mercury pool cathode

Title/Abstract Full Text Show Details

View Scheme

Burgard, Anthony P.; Osterhout, Robin E.; Pharkya, Priti; Burk, Mark J.

Patent: US2013/144029 A1, 2013 ; Location in patent: Page/Page column ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

I.a:4.2.1.a

In Step C of , the dehydration of 3,6-dihydroxyhexanoyl-CoA to 6-hydroxyhex-2-enoyl-CoA is catalyzed by a 3-hydroxyacyl-CoA dehydratase. In , the conversion of cyclohexane-1,2-diol to cyclohexanone (Step D) is catalyzed by a diol dehydratase in EC class 4.2.1. A

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Rx-ID: 29902217 Find similar reactions

A: 3.51% B: 1.79% C: 17.08%

With hydrogen; oxygen in neat (no solvent) T=249.84°C; Inert atmosphere; Temperature;

Wang, Xiaobin; Tan, Xiaoyao; Meng, Bo; Zhang, Xiongfu; Liang, Qi; Pan, Hui; Liu, Shaomin

Catalysis Science and Technology, 2013 , vol. 3, # 9 p. 2380 - 2391 Title/Abstract Full Text View citing articles Show Details

With hydrogen; oxygen

T=199.84°C; Inert atmosphere;

Guo, Yu; Wang, Xiaobin; Zhang, Xiongfu; Wang, Yao; Liu, Haiou; Wang, Jinqu; Qiu, Jieshan; Yeung, King Lun

Catalysis Today, 2010 , vol. 156, # 3-4 p. 282 - 287 Title/Abstract Full Text View citing articles Show Details

With hydrogen; oxygen

T=199.84°C;

Wang, Xiaobin; Guo, Yu; Zhang, Xiongfu; Wang, Yao; Liu, Haiou; Wang, Jinqu; Qiu, Jieshan; Yeung, King Lun

Catalysis Today, 2010 , vol. 156, # 3-4 p. 288 - 294 Title/Abstract Full Text View citing articles Show Details

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With sodium hydroxide in water

T=20°C; 1.5 h; Hide Experimental Procedure

Rx-ID: 34626750 Find similar reactions

Kolodiazhna, Olga O.; Kolodiazhna, Anastasy O.; Kolodiazhnyi, Oleg I.

Tetrahedron Asymmetry, 2013 , vol. 24, # 1 p. 37 - 42 Title/Abstract Full Text View citing articles Show Details

4.2.1.1 (a) Preparation of 2-halogencycloalkanone

rac-7c. The product was obtained as a mixture of cis- and trans-isomers 7c and 3c. The mixture of 3c and 7c was treated with 1 M sodium hydroxide for 1.5 h at room temperature. The product was extracted with methylene chloride. The solvent was then evaporated. 1H and 13C NMR analyses of the residue showed the presence of cis-2-chlorocyclohexanol 7c, cyclohexene epoxide, cyclohexanone, and only trace amounts (∼1percent) of the trans-isomer 3c. The residue was then distilled under vacuum, bp 70 °С (12 mmHg). After recrystallization from hexane the product was obtained as pure cis-3c. Yield 35percent, colorless prisms, mp 30 °C (hexane, −20 °C), [lit. oil, bp 75 °C (8 mmHg), mixture of cis + trans-isomers].21 A

226

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Rx-ID: 34825886 Find similar reactions

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Perraud, Olivier; Sorokin, Alexander B.; Dutasta, Jean-Pierre; Martinez, Alexandre

Chemical Communications, 2013 , vol. 49, # 13 p. 1288 - 1290 Title/Abstract Full Text View citing articles Show Details

With C57H68CuN4O9(2+)*2ClO4(1-); dihydrogen peroxide in acetonitrile

T=35°C; 4 h; Schlenk techniqueInert atmosphere; Catalytic behavior; Reagent/catalystTime;

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Sengupta, Kushal; Chatterjee, Sudipta; Samanta, Subhra; Bandyopadhyay, Sabyasachi; Dey, Abhishek

Inorganic Chemistry, 2013 , vol. 52, # 4 p. 2000 - 2014 Title/Abstract Full Text View citing articles Show Details

With picket-C11SH linker modified Au electrode in water

pH=7; Electrochemical reaction;

Rx-ID: 34962594 Find similar reactions

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Rx-ID: 35092000 Find similar reactions

With hydrogen in water

T=80°C; P=750.075 Torr; 26 h; Schlenk technique;

Chen, Jinzhu; Zhang, Wei; Chen, Limin; Ma, Longlong; Gao, Hui; Wang, Tiejun

ChemPlusChem, 2013 , vol. 78, # 2 p. 142 - 148 Title/Abstract Full Text View citing articles Show Details

With potassium tetrachloropalladate; H3[PW12O40].xH2O; hydrogen in water

T=100°C; P=1500.15 Torr; 20 h;

Chen, Aibing; Zhao, Guoying; Chen, Jinzhu; Chen, Limin; Yu, Yifeng

RSC Advances, 2013 , vol. 3, # 13 p. 4171 - 4175 Title/Abstract Full Text View citing articles Show Details

With sodium formate in water

T=80°C; 6 h; Sealed tube; chemoselective reaction;

Chen, Aibing; Li, Yonglei; Chen, Jinzhu; Zhao, Guoying; Ma, Longlong; Yu, Yifeng

ChemPlusChem, 2013 , vol. 78, # 11 p. 1370 - 1378 Title/Abstract Full Text View citing articles Show Details

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B: 6 %Spectr.

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Zhang, Guoqi; Hanson, Susan K.

Organic Letters, 2013 , vol. 15, # 3 p. 650 - 653 Title/Abstract Full Text View citing articles Show Details

With [H(3,5-trifluoromethylphenyl)4B]*2Et2O; C32H63CoNP2Si in tetrahydrofuran

T=120°C; 48 h; GloveboxInert atmosphere;

Rx-ID: 35104861 Find similar reactions

230 Synthesize Find similar Rx-ID: 35108498 Find similar reactions

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With tetrachloromethane; hydrotris(3,4,5-tribromo)pyrazolylborate Cu(NCMe); dihydrogen peroxide in water; acetonitrile

T=60°C; 1 h;

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Conde, Ana; Vilella, Laia; Balcells, David; Díaz-Requejo, M. Mar; Lledós, Agustí; Pérez, Pedro J.

Journal of the American Chemical Society, 2013 , vol. 135, # 10 p. 3887 - 3896 Title/Abstract Full Text View citing articles Show Details

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90%

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Rx-ID: 35160032 Find similar reactions

Suzuki, Ken; Watanabe, Tomonari; Murahashi, Shun-Ichi

Journal of Organic Chemistry, 2013 , vol. 78, # 6 p. 2301 - 2310 Title/Abstract Full Text View citing articles Show Details

in acetonitrile

T=25°C; Inert atmosphere;

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Rx-ID: 35228959 Find similar reactions

With potassium tetrachloropalladate; H3[PW12O40].xH2O; hydrogen in water

T=100°C; P=1500.15 Torr; 18 h;

Chen, Aibing; Zhao, Guoying; Chen, Jinzhu; Chen, Limin; Yu, Yifeng

RSC Advances, 2013 , vol. 3, # 13 p. 4171 - 4175 Title/Abstract Full Text View citing articles Show Details

With sodium formate in water

T=80°C; 3 h; Sealed tube; chemoselective reaction;

Chen, Aibing; Li, Yonglei; Chen, Jinzhu; Zhao, Guoying; Ma, Longlong; Yu, Yifeng

ChemPlusChem, 2013 , vol. 78, # 11 p. 1370 - 1378 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 35228960 Find similar reactions

With potassium tetrachloropalladate; H3[PW12O40].xH2O; hydrogen in water

T=80°C; P=1500.15 Torr; 8 h;

Chen, Aibing; Zhao, Guoying; Chen, Jinzhu; Chen, Limin; Yu, Yifeng

RSC Advances, 2013 , vol. 3, # 13 p. 4171 - 4175 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 35228961 Find similar reactions

With potassium tetrachloropalladate; H3[PW12O40].xH2O; hydrogen in water

T=100°C; P=1500.15 Torr; 18 h;

Chen, Aibing; Zhao, Guoying; Chen, Jinzhu; Chen, Limin; Yu, Yifeng

RSC Advances, 2013 , vol. 3, # 13 p. 4171 - 4175 Title/Abstract Full Text View citing articles Show Details

With sodium formate in water

T=80°C; 18 h; Sealed tube; chemoselective reaction;

Chen, Aibing; Li, Yonglei; Chen, Jinzhu; Zhao, Guoying; Ma, Longlong; Yu, Yifeng

ChemPlusChem, 2013 , vol. 78, # 11 p. 1370 - 1378 Title/Abstract Full Text View citing articles Show Details

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A: 27% B: 9% C: 64%

With Mg–Al hydrotalcite supported copper T=180°C; 15 h;

Rx-ID: 35275822 Find similar reactions

Dixit, Manish; Mishra, Manish; Joshi, Pradyuman A.; Shah, Dinesh O.

Catalysis Communications, 2013 , vol. 33, p. 80 - 83 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 35304573 Find similar reactions

C: 54%

With potassium iodide in acetonitrile

T=45 - 50°C; 2 h; Hide Experimental Procedure

China Guangdong Nuclear Power Hoiding Corporation; Dayabay Nuclear Power Operations and Management Co., Ltd.; China Institute For Radiation Protection; DU, Jianxing; ZHANG, Dayong; BIAN, Shouli; LIU, Daohe; WU, Yukun; LI, Xianfeng; YANG, Lietang; KONG, Haixia; QIU, Dangui; SHI, Yingxia; GUO, Liangtian; WU, Zhenlong; HAN, Lihong

Patent: EP2581359 A1, 2013 ; Location in patent: Paragraph 0062 ; Title/Abstract Full Text Show Details

13:

Embodiment 13, 8 ml acetonitrile and 5 g non-radioactive potassium iodide are sequentially added into a 50ml round-bottomed reaction flask; subsequently, 3 ml (CH2)5C(OCH3)2 and 4 ml trimethyl chlorosilane are added intothe reaction flask and further mixed to be uniform; after that, such chemicals react with each other at 45 °C for 30 minunder a magnetic stirring, and the reagent for testing purification capacity of radioactive gas in nuclear power plant isobtained thereafter. A reflux condensing is carried out on the reagent at 50°C for 1.5h to collect the non-radioactivemethyl iodide. According to a density analysis, the yield of the nonradioactive methyl iodide in the collected liquid isabout 54percent A

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Rx-ID: 35309411

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Multi-step reaction with 2 steps 1: DBU / dichloromethane / 25 °C 2: iodine / neat (no solvent) / 2 h / 85 °C View Scheme

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Jereb, Marjan; Vrazic, Dejan

Organic and Biomolecular Chemistry, 2013 , vol. 11, # 12 p. 1978 - 1999 Title/Abstract Full Text View citing articles Show Details

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A: 94%

Rx-ID: 35309429 Find similar reactions

With iodine in neat (no solvent) T=85°C; 2 h;

Jereb, Marjan; Vrazic, Dejan

Organic and Biomolecular Chemistry, 2013 , vol. 11, # 12 p. 1978 - 1999 Title/Abstract Full Text View citing articles Show Details

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Rx-ID: 35599726 Find similar reactions

Multi-step reaction with 3 steps 1: acetonitrile-D3; water-d2 / 3 h / 20 °C / |Irradiation 2: toluene-4-sulfonic acid; copper(II) sulfate / benzene / 8 h / 20 °C / |Inert atmosphere 3: acetonitrile-D3; water-d2 / 3 h / 20 °C / |Irradiation View Scheme

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Sugiura, Ryo; Kozaki, Rikio; Kitani, Satoru; Gosho, Yoshinori; Tanimoto, Hiroki; Nishiyama, Yasuhiro; Morimoto, Tsumoru; Kakiuchi, Kiyomi

Tetrahedron, 2013 , vol. 69, # 19 p. 3984 - 3990 Title/Abstract Full Text View citing articles Show Details

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A: 93 %Spectr. B: 70 %Spectr.

in acetonitrile-D3; water-d2

T=20°C; 3 h; Irradiation; Hide Experimental Procedure

Rx-ID: 35599728 Find similar reactions

Sugiura, Ryo; Kozaki, Rikio; Kitani, Satoru; Gosho, Yoshinori; Tanimoto, Hiroki; Nishiyama, Yasuhiro; Morimoto, Tsumoru; Kakiuchi, Kiyomi

Tetrahedron, 2013 , vol. 69, # 19 p. 3984 - 3990 Title/Abstract Full Text View citing articles Show Details

4.4 General procedure for photodeprotection reaction

General procedure: Irradiation reactions were carried out using an ultra-high pressure mercury lamp (SX–UI–500H, USHIO) as a light source. A CH3CN (1.0 vol percent H2O, 1.0×10−2 M) solution of acetal 7 in an NMR tube was irradiated through Pyrex filter until 7 was totally consumed. The field was determined by 1H NMR spectroscopy using 1,3,5-trioxane as an internal standard.

241

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Rx-ID: 35599768 Find similar reactions

Multi-step reaction with 2 steps 1: toluene-4-sulfonic acid; copper(II) sulfate / benzene / 8 h / 20 °C / |Inert atmosphere 2: acetonitrile-D3; water-d2 / 3 h / 20 °C / |Irradiation View Scheme

Sugiura, Ryo; Kozaki, Rikio; Kitani, Satoru; Gosho, Yoshinori; Tanimoto, Hiroki; Nishiyama, Yasuhiro; Morimoto, Tsumoru; Kakiuchi, Kiyomi

Tetrahedron, 2013 , vol. 69, # 19 p. 3984 - 3990 Title/Abstract Full Text View citing articles Show Details

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With titanium dioxide; oxygen

12 h; Molecular sieveSealed tubeUV-irradiation;

Rx-ID: 35865508 Find similar reactions

Choi, Jongmyung; Kang, Donghyeon; Lee, Kyu Hyung; Lee, Byeongno; Kim, Kyung Joong; Hur, Nam Hwi

RSC Advances, 2013 , vol. 3, # 24 p. 9402 - 9407 Title/Abstract Full Text View citing articles Show Details

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With hydrogen in water

T=90°C; P=37503.8 Torr; 0.5 h; Autoclave; Hide Experimental Procedure

Rx-ID: 35947589 Find similar reactions

Antonetti, Claudia; Galletti, Anna Maria Raspolli; Accorinti, Pasquale; Alini, Stefano; Babini, Pierpaolo; Raabova, Katerina; Rozhko, Elena; Caldarelli, Aurora; Righi, Paolo; Cavani, Fabrizio; Concepcion, Patricia

Applied Catalysis A: General, 2013 , vol. 466, p. 21 - 31 Title/Abstract Full Text View citing articles Show Details

Catalytic experiments: catechol hydrogenation

hydrogenationThe hydrogenation reactions were carried out in a 300 mlmechanically stirred Parr 4560 autoclave equipped with a P.I.D.4843 controller. In a typical procedure, the proper amount of thechosen Ru-based catalyst was introduced into the autoclave underinert atmosphere. Then the autoclave was closed, evacuated up to0.5 mm Hg, and a solution containing the substrate (0.6 g of cat-echol) in 50 ml of water was introduced by suction, followed bypressurization with hydrogen to 0.2 MPa. Afterwards, the reactorwas heated up to the chosen temperature and, once it was reached,the autoclave was pressurized with hydrogen to the desired pres-sure, under stirring. The pressure value was held constant at thechosen value manually by repeated hydrogen feeds A

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244 Synthesize Find similar

A: 84 %Chromat. B: 14 %Chromat.

With methanesulfonic acid; 5 palladium on charcoal; hydrogen in hexane

T=20°C; chemoselective reaction;

245

Rx-ID: 36032312 Find similar reactions

Rubio-Marques, Paula; Leyva-Perez, Antonio; Corma, Avelino

Chemical Communications, 2013 , vol. 49, # 74 p. 8160 - 8162 Title/Abstract Full Text View citing articles Show Details

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A: 7.2 %Chromat. B: 12.9 %Chromat. C: 13.7 %Chromat.

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With FeCl3(1-methylbenzotriazole)2; dihydrogen peroxide in water; acetonitrile

T=26°C; 6 h; Inert atmosphere; Hide Experimental Procedure

Rx-ID: 36622451 Find similar reactions

Anastasiadis, Nikolaos C.; Bilis, George; Plakatouras, John C.; Raptopoulou, Catherine P.; Psycharis, Vassilis; Beavers, Christine; Teat, Simon J.; Louloudi, Maria; Perlepes, Spyros P.

Polyhedron, 2013 , vol. 64, p. 189 - 202 Title/Abstract Full Text View citing articles Show Details

2.2. Catalytic experiments

General procedure: All substrates were purchased from Aldrich, in their highest commercial purity, stored at 5 °C and purified by passage through a column of basic alumina prior to use. A 30percent aqueous solution of H2O2 was used as oxidant. For the catalytic evaluation, H2O2 (30percent)diluted in MeCN (1:10 v/v) was slowly added (within a period of10 min) to an MeCN solution of the iron(III) complex (the catalyst) and the substrate under an Ar atmosphere at room temperature (26 °C). Acetophenone or bromobenzene were used as internal standard. Catalytic reactions started by adding the oxidant into the reaction mixture. The catalyst:oxidant:substrate ratio was 1:20:1000 μmol for cyclohexene, 1-methylcyclohexene, cyclooctene, limonene, cyclohexane and n-hexane, and 1:50:1000 μmol for styrene, trans-β-methyl styrene and cis-stilbene. The total volume of the catalytic reaction solution was 1 ml. The large excess of the substrate was expected to minimize over-oxidation of oxidation products and to protect the catalyst from oxidative destruction. The oxidant was added slowly in order to minimize potential iron-catalyzed H2O2 decomposition via catalase activity.The progress of the catalytic reaction was monitored using GC–MS by removing small samples of the reaction mixture. GC analysis was performed using a 8000 Fisons chromatograph witha flame ionization detector and a Shimadzu GC-17A gas chromatograph coupled with a GCMS-QP5000 mass spectrometer. The yields reported herein are based on the amount of H2O2 oxidant converted into oxygenated products. Reactions were complete within 6 h. In some cases, oxidations catalyzed by [FeCl3(5ClbtaH)2]*2(5ClbtaH) were accomplished within 2 h (vide infra). To establish the identity of the products unequivocally, the retention times and spectral data were compared to those of the commercially available compounds. Black experiments revealed that no oxidative reactions took place without the catalyst. A

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246 Synthesize Find similar

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Rx-ID: 36631007 Find similar reactions

With silica-alumina; nickel in α-n-hexadecene

T=159.84°C; 4 h; Inert atmosphere;

Wang, Xingyu; Rinaldi, Roberto

Angewandte Chemie - International Edition, 2013 , vol. 52, # 44 p. 11499 - 11503 Angew. Chem., 2013 , vol. 125, # 44 p. 11713 - 11717,5 Title/Abstract Full Text View citing articles Show Details

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247 Synthesize Find similar

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Rx-ID: 36631008 Find similar reactions

With nickel in α-n-hexadecene

T=159.84°C; 4 h; Inert atmosphere;

Wang, Xingyu; Rinaldi, Roberto

Angewandte Chemie - International Edition, 2013 , vol. 52, # 44 p. 11499 - 11503 Angew. Chem., 2013 , vol. 125, # 44 p. 11713 - 11717,5 Title/Abstract Full Text View citing articles Show Details

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248 Synthesize Find similar Rx-ID: 36641801 Find similar reactions

With hydrogen in N-dodecane

T=350°C; P=41254.1 Torr; AutoclaveInert atmosphere; Reagent/catalyst;

Jongerius, Anna L.; Gosselink, Robert W.; Dijkstra, Jelmer; Bitter, Johannes H.; Bruijnincx, Pieter C. A.; Weckhuysen, Bert M.

ChemCatChem, 2013 , vol. 5, # 10 p. 2964 - 2972 Title/Abstract Full Text View citing articles Show Details

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249 Synthesize Find similar

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Rx-ID: 36694423 Find similar reactions

With ligand-immobilized mesoporous silica gel SBA*-L-4/Co catalyst in dichloromethane; acetonitrile

T=35°C; 3 h; Inert atmosphere; Reagent/catalystTime; Hide Experimental Procedure

Nakazawa, Jun; Yata, Akinori; Hori, Tomoaki; Stack, T. Daniel P.; Naruta, Yoshinori; Hikichi, Shiro

Chemistry Letters, 2013 , vol. 42, # 10 p. 1197 - 1199 Title/Abstract Full Text View citing articles Show Details

Cyclohexane Oxidation

The oxidation of cyclohexane was carried out at 35°C under Ar atmosphere. In a typical reaction, a solution (or suspension) of cobalt catalyst (2.0 μmol, in 1.0 mL of acetonitrile and 1.0mL of dichloromethane) was added to a mixture of cyclohexane (15 mmol, 1.6 mL), mCPBA oxidant (345 mg, 2.0 mmol), and nitrobenzene (10 μL, 100 μmol, for GC standard) in dichloromethane (2.0 mL). To monitor formation of products, 0.2 mL of the reaction mixture was corrected after a certain period and quenched with a dichloromethane solution (0.5 mL) of triphenylphosphine (10 mg), after which the solution was subjected to GC analysis. The averages of three independent reaction measurements are reported. No reactivity change was observed under shaker stirring instead of mechanical stirring with a Teflon-coated magnetic bar.

Nakazawa, Jun; Hori, Tomoaki; Stack, T. Daniel P.; Hikichi, Shiro

Chemistry - An Asian Journal, 2013 , vol. 8, # 6 p. 1191 - 1199 Title/Abstract Full Text View citing articles Show Details

in dichloromethane; acetonitrile

T=20°C; Inert atmosphere; Catalytic behaviorMechanism; Reagent/catalyst;

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250 Synthesize Find similar

Rx-ID: 36736729 Find similar reactions

Multi-step reaction with 2 steps 1: hydrogen; 1 Ir/C / 0.07 h / 349.84 °C / 30003 Torr 2: hydrogen; 1 Ru/C / 0.07 h / 399.84 °C / 30003 Torr View Scheme

Chang, Jie; Danuthai, Tanate; Dewiyanti, Silvia; Wang, Chuan; Borgna, Armando

ChemCatChem, 2013 , vol. 5, # 10 p. 3041 - 3049 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: hydrogen; / 0.07 h / 349.84 °C / 30003 Torr 2: hydrogen; 1 Ru/C / 0.07 h / 399.84 °C / 30003 Torr View Scheme

Chang, Jie; Danuthai, Tanate; Dewiyanti, Silvia; Wang, Chuan; Borgna, Armando

ChemCatChem, 2013 , vol. 5, # 10 p. 3041 - 3049 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: hydrogen; / 0.07 h / 349.84 °C / 30003 Torr 2: hydrogen; 1 Ru/C / 0.07 h / 399.84 °C / 30003 Torr View Scheme

Chang, Jie; Danuthai, Tanate; Dewiyanti, Silvia; Wang, Chuan; Borgna, Armando

ChemCatChem, 2013 , vol. 5, # 10 p. 3041 - 3049 Title/Abstract Full Text View citing articles Show Details

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251 Synthesize

Find similar Rx-ID: 36736730 Find similar reactions

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With hydrogen

T=349.84°C; P=30003 Torr; 0.067 h;

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Chang, Jie; Danuthai, Tanate; Dewiyanti, Silvia; Wang, Chuan; Borgna, Armando

ChemCatChem, 2013 , vol. 5, # 10 p. 3041 - 3049 Title/Abstract Full Text View citing articles Show Details

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252 Synthesize Find similar Rx-ID: 36736731 Find similar reactions

With 1 Ru/C; hydrogen

T=349.84°C; P=30003 Torr; 0.067 h;

Chang, Jie; Danuthai, Tanate; Dewiyanti, Silvia; Wang, Chuan; Borgna, Armando

ChemCatChem, 2013 , vol. 5, # 10 p. 3041 - 3049 Title/Abstract Full Text View citing articles Show Details

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253 Synthesize Find similar

With 1 Ru/C; hydrogen

T=399.84°C; P=30003 Torr; 0.067 h;

Rx-ID: 36736738 Find similar reactions

Chang, Jie; Danuthai, Tanate; Dewiyanti, Silvia; Wang, Chuan; Borgna, Armando

ChemCatChem, 2013 , vol. 5, # 10 p. 3041 - 3049 Title/Abstract Full Text View citing articles Show Details

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254 Synthesize Find similar

A: 12 %Spectr. B: 23 %Spectr. C: 12 %Spectr.

With methyltrioxorhenium (VII)

T=170°C; 0.5 h; Inert atmosphere;

Shiramizu, Mika; Toste, F. Dean

Angewandte Chemie - International Edition, 2013 , vol. 52, # 49 p. 12905 - 12909 Angew. Chem., 2013 , vol. 125, # 49 p. 13143 - 13147,5 Title/Abstract Full Text View citing articles Show Details

255 Synthesize Find similar

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Rx-ID: 36742973 Find similar reactions

Rx-ID: 36743007 Find similar reactions

Multi-step reaction with 2 steps 1: water; sodium hydroxide / methanol / 0.33 h / |Reflux 2: methyltrioxorhenium (VII) / 0.5 h / 170 °C / |Inert atmosphere View Scheme

Shiramizu, Mika; Toste, F. Dean

Angewandte Chemie - International Edition, 2013 , vol. 52, # 49 p. 12905 - 12909 Angew. Chem., 2013 , vol. 125, # 49 p. 13143 - 13147,5 Title/Abstract Full Text View citing articles Show Details

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256 Synthesize Find similar

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Rx-ID: 36842045 Find similar reactions

With AlCl3, aluminium chloride; Pt; hydrogen in water

T=20°C; P=750.075 Torr; 60 h; Sealed tube;

Yu, Tingting; Wang, Jiaqing; Li, Xinming; Cao, Xueqin; Gu, Hongwei

ChemCatChem, 2013 , vol. 5, # 10 p. 2852 - 2855 Title/Abstract Full Text View citing articles Show Details

With AlCl3, aluminium chloride; Pt; hydrogen

T=20°C; P=750.075 Torr; 60 h; Sealed tube;

Yu, Tingting; Wang, Jiaqing; Li, Xinming; Cao, Xueqin; Gu, Hongwei

ChemCatChem, 2013 , vol. 5, # 10 p. 2852 - 2855 Title/Abstract Full Text View citing articles Show Details

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257 Synthesize Find similar

With COBALT; sodium hydroxide in n-heptane; water

T=25°C; 0.5 h; AutoclaveInert atmosphere; Catalytic behavior; Reagent/catalyst; Hide Experimental Procedure

Rx-ID: 38810788 Find similar reactions

Zheng, Xi; Wang, Min; Sun, Zhiqiang; Liu, Junxia; Ma, Jiping; Xu, Jie

Catalysis Communications, 2013 , vol. 40, p. 55 - 58 Title/Abstract Full Text View citing articles Show Details

2.3. Decomposition procedure

The reaction was carried out in a 50 mL stainless steel autoclave under magnetic stirring. In a typical procedure, 0.02 g catalyst and 10 mL n-heptane solution containing CHHP (0.597 mmol/mL) were added into the reactor. The reaction was conducted at room temperature for 30 min under N2 atmosphere.

258 Synthesize Find similar

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Rx-ID: 1518009 Find similar reactions

96%

Stage #1: in ethanol

T=20°C; Stage #2: With water in ethanol

T=20°C;

Rohman, Md. Rumum; Rajbangshi, Mantu; Laloo, Badaker M.; Sahu, Priti R.; Myrboh, Bekington

Tetrahedron Letters, 2010 , vol. 51, # 21 p. 2862 - 2864 Title/Abstract Full Text View citing articles Show Details

93%

With silica gel; iron nitrate (III) in hexane

T=50°C; 0.0833333 h;

Hirano, Masao; Ukawa, Ken; Yakabe, Shigetaka; Morimoto, Takashi

Organic Preparations and Procedures International, 1997 , vol. 29, # 4 p. 480 - 484 Title/Abstract Full Text View citing articles Show Details

92%

With selenium(IV) oxide in acetic acid

2 h; Ambient temperature;

Haroutounian

Synthesis, 1995 , # 1 p. 39 - 40 Title/Abstract Full Text View citing articles Show Details

Hide Details

92%

With thionyl chloride; dihydrogen peroxide in acetonitrile

T=25°C; 0.05 h;

Bahrami, Kiumars; Khodaei, Mohammad Mehdi; Tajik, Maryam; Shakibaian, Vida

Chinese Chemical Letters, 2012 , vol. 23, # 1 p. 81 - 85 Title/Abstract Full Text View citing articles Show Details

90%

With trichloroisocyanuric acid; silver nitrate in water; acetonitrile

Ambient temperature;

Olah, George A.; Narang, Subhash C.; Salem, George F.

Synthesis, 1980 , p. 657 Title/Abstract Full Text Show Details

90%

With tert.-butylhydroperoxide in methanol; water

Heating;

Barhate, Nivrutti B; Shinde, Popat D; Mahajan, Vishal A; Wakharkar, Radhika D

Tetrahedron Letters, 2002 , vol. 43, # 34 p. 6031 - 6033 Title/Abstract Full Text View citing articles Show Details

88%

With sodium perborate in acetic acid

T=25°C; 2 h;

Bandgar; Kulkarni, Sameer A.; Nigal

Organic Preparations and Procedures International, 1998 , vol. 30, # 6 p. 706 - 709 Title/Abstract Full Text View citing articles Show Details

83%

With dinitrogen tetraoxide; iron nitrate (III)

T=20°C; Oxidation;

Firouzabadi, Habib; Iranpoor, Nasser; Zolfigol, Mohammad Ali

Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 9 p. 2169 - 2173 Title/Abstract Full Text View citing articles Show Details

81%

With sodium hydrogencarbonate; Ledwith–Weitz salt in dichloromethane; water; acetonitrile

Platen, Martin; Steckhan, Eberhard

Chemische Berichte, 1984 , vol. 117, # 5 p. 1679 - 1694 Title/Abstract Full Text Show Details

81%

With Oxonereg;; potassium bromide in water; acetonitrile

T=20°C; 2 h;

Desai; Pore; Tamhankar; Jadhav; Wadgaonkar

Tetrahedron Letters, 2006 , vol. 47, # 48 p. 8559 - 8561 Title/Abstract Full Text View citing articles Show Details

65%

With hydrogenchloride; dihydrogen peroxide in methanol

Ambient temperature;

Olah, George A.; Narang, Subhash C.; Salem, George F.

Synthesis, 1980 , p. 657 Title/Abstract Full Text Show Details

43%

With hydrogenchloride; sodium nitrite in tetrachloromethane; water

4 h; Ambient temperatureother reagent;

El-Wassimy, M.T.M.; Joergensen, K.A.; Lawesson S.-O.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2201 - 2204 Title/Abstract Full Text Show Details

59 % Chromat.

With benzeneseleninic anhydride in tetrahydrofuran

18 h; Ambient temperature;

Cussans, Nigel J.; Ley, Steven V.; Barton, Derek H. R.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 1654 - 1657 Title/Abstract Full Text View citing articles Show Details

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259 Synthesize Find similar

Rx-ID: 4030608 Find similar reactions

With benzyltrimethylammonium tribromide; sodium acetate in water; acetic acid

T=60°C; 1 h;

Kajigaeshi, Shoji; Kawamukai, Hiroshi; Fujisaki, Shizuo

Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 8 p. 2585 - 2588 Title/Abstract Full Text Show Details

With Sodium bromate; sulfuric acid; sodium bromide in water

T=20°C;

Paeaekkoenen, Sanna; Pursiainen, Jouni; Lajunen, Marja

Synthetic Communications, 2012 , vol. 42, # 4 p. 534 - 540 Title/Abstract Full Text View citing articles Show Details

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260 Synthesize Find similar

Rx-ID: 8734824 Find similar reactions

With Cu-Mg

T=250°C; Dehydrogenation; Product distribution; Further Variations:CatalystsTemperatures;

Fridman; Davydov

Journal of Catalysis, 2000 , vol. 195, # 1 p. 20 - 30 Title/Abstract Full Text View citing articles Show Details

With copper oxides/alumina

T=239.84°C; P=760.051 Torr; 1 h; Inert atmosphere;

Popova; Dimitrov; Santo, V. Dal; Ravasio; Scotti

Catalysis Communications, 2012 , vol. 17, p. 150 - 153 Title/Abstract Full Text View citing articles Show Details

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261 Synthesize Find similar Rx-ID: 24790779 Find similar reactions

With peracetic acid; sodium perborate; Na2 tetraborate; acetic acid; FeAlPO in water

T=110°C; 16 h; Product distribution / selectivity; Hide Experimental Procedure

U.S. BORAX, INC.

Patent: WO2006/43075 A1, 2006 ; Location in patent: Page/Page column 13-14 ; Title/Abstract Full Text Show Details

Two runs (each with a reaction time of 16 hours) were carried out a follows.A liquid comprising borax pentahydrate (1.9g) (Neobor ex Borax Europe Limited), sodium perborate monohydrate (0.4g), 25percent peracetic acid solution in acetic acid (4.2g) and double-distilled water (20.5g) was fed slowly by a syringe pump to a stirred reactor containing cyclohexane (2.5g) and FeAlPO-31 catalyst (0.25g), while the temperature was maintained at 1100C.The results were as follows:Conversion of cyclohexane to oxidised products was calculated to be 25.0percent (Run 1) and 26.5percent (Run 2).Product selectivity was as follows: EPO <DP n="15"/>

With peracetic acid; sodium hydroxide; sodium acetate; acetic acid in water

T=110°C; pH=5.1; 16 h; Product distribution / selectivity; Hide Experimental Procedure

U.S. BORAX, INC.

Patent: WO2006/43075 A1, 2006 ; Location in patent: Page/Page column 15-16 ; Title/Abstract Full Text Show Details

The procedure of Example 1 was repeated but using, as oxidant-containing solution, (a) peracetic acid solution containing borax pentahydrate or (b) peracetic acid solution containing sodium acetate.The oxidant solution (a) was obtained from 25percent peracetic acid solution in acetic acid (4.2g), Neobor (Ig), NaOH (I g) and double-distilled water (20.5g)The oxidant solution (b) was obtained from 25percent peracetic acid solution in acetic acid (4.2g), sodium acetate trihydrate (0.934g), NaOH (Ig) and double-distilled water (20.5g).Each run was conducted for 16 hours and the pH was, in each case, 5.1.Product selectivity was as follows: EPO <DP n="17"/>

With peracetic acid; sodium hydroxide; Na2 tetraborate; acetic acid; FeAlPO in water

T=110°C; pH=5.1; 16 h; Product distribution / selectivity; Hide Experimental Procedure

U.S. BORAX, INC.

Patent: WO2006/43075 A1, 2006 ; Location in patent: Page/Page column 15-16 ; Title/Abstract Full Text Show Details

With oxygen

T=160°C; P=7500.75 Torr; 6 h; AutoclaveGreen chemistry; PressureTemperatureReagent/catalyst;

Lue, Hongying; Ren, Wanzhong; Liu, Pengfei; Qi, Shixue; Wang, Wenhua; Feng, Yongmei; Sun, Fengxin; Wang, Yuanwei

Applied Catalysis A: General, 2012 , vol. 441-442, p. 136 - 141 Title/Abstract Full Text View citing articles Show Details

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262 Synthesize Find similar

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Rx-ID: 29622289 Find similar reactions

A: 63%

With lithium perchlorate; trifluoroacetic acid

T=20°C; 2 h;

Seifert, Andrea; Rohr, Kerstin; Mahrwald, Rainer

Tetrahedron, 2012 , vol. 68, # 4 p. 1137 - 1144 Title/Abstract Full Text View citing articles Show Details

With lithium perchlorate; trifluoroacetic acid

T=20°C; Acid-catalyzed Meerwein-Ponndorf-Verley aldol etherification; 2 h; optical yield given as percent de;

Seifert, Andrea; Scheffler, Ulf; Markert, Morris; Mahrwald, Rainer

Organic Letters, 2010 , vol. 12, # 8 p. 1660 - 1663 Title/Abstract Full Text View citing articles Show Details

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263 Synthesize Find similar

Rx-ID: 32605766 Find similar reactions

Sanchez, Dani; Bastida, David; Bures, Jordi; Isart, Carles; Pineda, Oriol; Vilarrasa, Jaume

Organic Letters, 2012 , vol. 14, # 2 p. 536 - 539 Title/Abstract Full Text View citing articles Show Details

in dimethylsulfoxide-d6

T=25°C; Equilibrium constant;

264 Synthesize Find similar

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Rx-ID: 32605826 Find similar reactions

Multi-step reaction with 3 steps 1: 1H-imidazole / dichloromethane / 4 h / 0 - 20 °C 2: dimethylsulfoxide-d6 / 25 °C 3: dimethylsulfoxide-d6 / 25 °C View Scheme

265 Synthesize Find similar

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Rx-ID: 32605830 Find similar reactions

Sanchez, Dani; Bastida, David; Bures, Jordi; Isart, Carles; Pineda, Oriol; Vilarrasa, Jaume

Organic Letters, 2012 , vol. 14, # 2 p. 536 - 539 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: dimethylsulfoxide-d6 / 25 °C 2: dimethylsulfoxide-d6 / 25 °C View Scheme

Sanchez, Dani; Bastida, David; Bures, Jordi; Isart, Carles; Pineda, Oriol; Vilarrasa, Jaume

Organic Letters, 2012 , vol. 14, # 2 p. 536 - 539 Title/Abstract Full Text View citing articles Show Details

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266 Synthesize Find similar

Rx-ID: 32639852 Find similar reactions

With CuO on mesoporous silica

T=239.84°C; P=760.051 Torr; 1 h; Inert atmosphere;

Popova; Dimitrov; Santo, V. Dal; Ravasio; Scotti

Catalysis Communications, 2012 , vol. 17, p. 150 - 153 Title/Abstract Full Text View citing articles Show Details

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267 Synthesize Find similar Rx-ID: 32645852 Find similar reactions

A: 23 %Chromat. B: 26 %Chromat. C: 6 %Chromat. D: 19 %Chromat.

With hydrogen in decane

T=20 - 250°C;

Lee, Cho Rim; Yoon, Ji Sun; Suh, Young-Woong; Choi, Jae-Wook; Ha, Jeong-Myeong; Suh, Dong Jin; Park, Young-Kwon

Catalysis Communications, 2012 , vol. 17, p. 54 - 58 Title/Abstract Full Text View citing articles Show Details

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268 Synthesize Find similar

C: 88%

With sodium hydrogen sulphate in water

T=260°C; Rupe reaction; 1 h; high-pressure stainless steel bath reactor; chemoselective reaction;

269 Synthesize Find similar

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Rx-ID: 32991138 Find similar reactions

Rx-ID: 32753922 Find similar reactions

Chang, Yong-Juan; Wang, Zhi-Zhong; Luo, Li-Gang; Dai, Li-Yi

Chemical Papers, 2012 , vol. 66, # 1 p. 33 - 38 Title/Abstract Full Text View citing articles Show Details

With water in dimethyl sulfoxide

T=30°C; pH=7; 18 h; aq. phosphate bufferEnzymatic reaction;

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Leisch, Hannes; Grosse, Stephan; Iwaki, Hiroaki; Hasegawa, Yoshie; Lau, Peter C.K.

Canadian Journal of Chemistry, 2012 , vol. 90, # 1 p. 39 - 45 Title/Abstract Full Text View citing articles Show Details

270 Synthesize Find similar

Rx-ID: 33122058 Find similar reactions

With calcium sulfate; benzeneseleninic acid; dihydrogen peroxide in methanol; dichloromethane

T=20°C;

Mercier, Eric A.; Smith, Chris D.; Parvez, Masood; Back, Thomas G.

Journal of Organic Chemistry, 2012 , vol. 77, # 7 p. 3508 - 3517 Title/Abstract Full Text View citing articles Show Details

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271 Synthesize Find similar

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Rx-ID: 33176494 Find similar reactions

With [Fe(III)(dpaq)(H2O)](ClO4)2*H2O in acetonitrile

T=20°C;

Hitomi, Yutaka; Arakawa, Kengo; Funabiki, Takuzo; Kodera, Masahito

Angewandte Chemie - International Edition, 2012 , vol. 51, # 14 p. 3448 - 3452 Title/Abstract Full Text View citing articles Show Details

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272 Synthesize Find similar

With hydrogen in water

T=29.84°C; P=760.051 Torr; 4 h; Kinetics; ConcentrationReagent/catalystTemperatureTime; Hide Experimental Procedure

Rx-ID: 33910703 Find similar reactions

Baeza; Calvo; Gilarranz; Mohedano; Casas; Rodriguez

Journal of Catalysis, 2012 , vol. 293, p. 85 - 93 Title/Abstract Full Text View citing articles Show Details

2.3. HDC experiments

Catalytic HDC runs were carried out during 4 h in a three-necked jacketed glass reactor where H2 was continuously fed at 50 N mL/min flow rate under vigorous stirring (600-800 rpm) in order to facilitate hydrogen distribution through the 4-CP solution (150 mL). The reaction temperature (303-323 K) was controlled by a thermostatic bath connected to the reactor jacket. The system was equipped with a cold trap at the vent to check any possible stripping; no significant stripping was detected. The initial concentration of 4-CP was 100 mg/L, and the catalyst load was 2.45 .x. 10-3 g/L of Pd.A sampling system consisting in a thin tube connected to a syringe allowed taking liquid samples (1 mL), which were collected through previous filtering (PTFE filter, pore size 0.45 μm). The samples were analyzed by high-performance liquid chromatography (Varian Prostar equipped with a UV-VIS detector) using a C18 column as stationary phase and a mixture of acetonitrile and water (1:1, v/v) as mobile phase. Cyclohexanone and cyclohexanol were analyzed by a GC/FID device (GC 3900 Varian) using a 30 m long .x. 0.25 mm i.d. capillary column (CP-Wax 52 CB, Varian) and nitrogen as carrier gas. The quantification of chloride ion was performed by ion chromatography (Metrohm 790 Personal IC). The carbon and chlorine balances matched always between 90percent and 95percent, respectively, at the least. A

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273 Synthesize

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A: 11 %Chromat. B: 64 %Chromat.

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Rx-ID: 34054633 Find similar reactions

With C12H36Cl2O4RuS4; hydrogen in benzene

T=190°C; P=5168.35 Torr; 8 h;

Murru, Siva; Nicholas, Kenneth M.; Srivastava, Radhey S.

Journal of Molecular Catalysis A: Chemical, 2012 , vol. 363-364, p. 460 - 464 Title/Abstract Full Text View citing articles Show Details

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274 Synthesize Find similar

Rx-ID: 34112153 Find similar reactions

A: 33 %Chromat. B: 46 %Chromat.

With Pd/Al2O3; hydrogen; oxygen in acetonitrile

T=59.84°C; 6 h; chemoselective reaction;

Mori, Kohsuke; Furubayashi, Ken; Okada, Shusuke; Yamashita, Hiromi

Chemical Communications, 2012 , vol. 48, # 71 p. 8886 - 8888 Title/Abstract Full Text View citing articles Show Details

A: 72 %Chromat. B: 21 %Chromat.

With hydrogen in acetonitrile

T=59.84°C; 6 h; chemoselective reaction;

Mori, Kohsuke; Furubayashi, Ken; Okada, Shusuke; Yamashita, Hiromi

Chemical Communications, 2012 , vol. 48, # 71 p. 8886 - 8888 Title/Abstract Full Text View citing articles Show Details

With hydrogen; oxygen in methanol; acetonitrile

T=59.84°C; P=760.051 Torr; 6 h;

Okada, Shusuke; Fujiwara, Kensei; Kamegawa, Takashi; Mori, Kohsuke; Yamashita, Hiromi

Bulletin of the Chemical Society of Japan, 2012 , vol. 85, # 9 p. 1057 - 1059,3 Title/Abstract Full Text Show Details

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275 Synthesize Find similar Rx-ID: 34126713 Find similar reactions

With oxygen

T=145°C; P=18751.9 Torr; Temperature;

Lue, Hongying; Ren, Wanzhong; Liu, Pengfei; Qi, Shixue; Wang, Wenhua; Feng, Yongmei; Sun, Fengxin; Wang, Yuanwei

Applied Catalysis A: General, 2012 , vol. 441-442, p. 136 - 141 Title/Abstract Full Text View citing articles Show Details

276 Synthesize Find similar

97%

Synthesize Find similar

Rx-ID: 34127128 Find similar reactions

With C53H46ClN3P2Ru; potassium tert-butylate; acetone

T=56°C; Oppenauer Oxidation; P=750.075 Torr; 0.666667 h;

Du, Wangming; Wang, Liandi; Wu, Ping; Yu, Zhengkun

Chemistry - A European Journal, 2012 , vol. 18, # 37 p. 11550 - 11554 Title/Abstract Full Text View citing articles Show Details

277 Synthesize Find similar

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Rx-ID: 34318277 Find similar reactions

A: 30% B: 20% C: 50%

With copper acetylacetonate; carbon tetrabromide

T=150°C; 8 h; Inert atmosphereSealed tube;

Khusnutdinov, R. I.; Bayguzina, A. R.; Gimaletdinova, L. I.; Dzhemilev, U. M.

Russian Journal of Organic Chemistry, 2012 , vol. 48, # 9 p. 1191 - 1196,6 Zhurnal Organicheskoi Khimii, 2012 , vol. 48, # 9 p. 1191 - 1196,6 Title/Abstract Full Text Show Details

A: 22% B: 38% C: 7%

With copper acetylacetonate; carbon tetrabromide

T=150°C; 8 h; Inert atmosphereSealed tube;

Khusnutdinov, R. I.; Bayguzina, A. R.; Gimaletdinova, L. I.; Dzhemilev, U. M.

Russian Journal of Organic Chemistry, 2012 , vol. 48, # 9 p. 1191 - 1196,6 Zhurnal Organicheskoi Khimii, 2012 , vol. 48, # 9 p. 1191 - 1196,6 Title/Abstract Full Text Show Details

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278 Synthesize Find similar

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Rx-ID: 34385699 Find similar reactions

With hydrogen

T=80°C; P=3750.38 Torr; 4 h; Autoclave; chemoselective reaction;

Guan, Yejun; Zhang, Damin; Wang, Yimeng

Catalysis Letters, 2012 , vol. 142, # 10 p. 1225 - 1233 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

279 Synthesize Find similar

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Rx-ID: 34385700 Find similar reactions

A: 13.5%

With hydrogen

T=80°C; P=3750.38 Torr; 4 h; Autoclave; chemoselective reaction;

Synthesize Find similar

Guan, Yejun; Zhang, Damin; Wang, Yimeng

Catalysis Letters, 2012 , vol. 142, # 10 p. 1225 - 1233 Title/Abstract Full Text View citing articles Show Details

280 Synthesize Find similar

A: 55% B: 8

Rx-ID: 34449036 Find similar reactions

With oxygen; 1,8-diazabicyclo[5.4.0]undec-7-ene; copper dichloride in N,N-dimethylformamide

Do, Hien-Quang; Tran-Vu, Hung; Daugulis, Olafs

Organometallics, 2012 , vol. 31, # 22 p. 7816 - 7818

%Chromat.

T=20°C;

Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

281 Synthesize Find similar Rx-ID: 34550287 Find similar reactions

D: 48.2%

Long, Jilan; Wang, Liming; Gao, Xingfa; Bai, Cuihua; Jiang, Huanfeng; Li, Yingwei

Chemical Communications, 2012 , vol. 48, # 99 p. 12109 - 12111 Title/Abstract Full Text View citing articles Show Details

With C12H6N2O4(2-)*Al(3+)*HO(1-)*0.5H2O; oxygen

T=0 - 160°C; P=7500.75 Torr; 4 h; Autoclave; Reagent/catalystTemperature; A

Synthesize Find similar

282 Synthesize Find similar

A: 0.006 mmol B: 0.06 μmol

Rx-ID: 34815658 Find similar reactions

With P25; sulfur dioxide; oxygen in neat (no solvent) 2 h; Irradiation; chemoselective reaction;

Parrino, Francesco; Ramakrishnan, Ayyappan; Damm, Cornelia; Kisch, Horst

ChemPlusChem, 2012 , vol. 77, # 8 p. 713 - 720 Title/Abstract Full Text View citing articles Show Details

Synthesize Find similar

283 Synthesize Find similar Rx-ID: 35112278 Find similar reactions

A: 10% B: 8% C: 5% D: 26% E: 24%

Abdel-Wahab, Aboel-Magd A.; Mohamed, Omima S.; Ahmed, Saleh A.; Mostafa, Mostafa F.

Journal of Physical Organic Chemistry, 2012 , vol. 25, # 12 p. 1418 - 1421 Title/Abstract Full Text View citing articles Show Details

Stage #1: in acetonitrile

0.25 h; Sonication; Stage #2: With oxygen in acetonitrile

20 h; Irradiation; KineticsMechanism; Time;

284 Synthesize Find similar

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With calcium hexaammine; diethyl ether

anschl. Erhitzen mit wss. H2SO4;

Rx-ID: 657757 Find similar reactions

Birch

Journal of the Chemical Society, 1946 , p. 593,597 Journal of the Chemical Society, 1947 , p. 1642,1644, 1648

Full Text Show Details

Multi-step reaction with 2 steps 1: phosphoric acid; water / 149.84 °C 2: Pd/SiO2; hydrogen; acetic acid / water / 0.5 h / 199.84 °C / 37503.8 Torr / Autoclave View Scheme

Zhao, Chen; He, Jiayue; Lemonidou, Angeliki A.; Li, Xuebing; Lercher, Johannes A.

Journal of Catalysis, 2011 , vol. 280, # 1 p. 8 - 16 Title/Abstract Full Text View citing articles Show Details

285 Synthesize Find similar

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Rx-ID: 827530 Find similar reactions

96%

With dihydrogen peroxide

T=20°C; 3 h; Ionic liquidAlkaline conditions;

Bortolini, Olga; Nino, Antonio De; Garofalo, Angelo; Maiuolo, Loredana; Russo, Beatrice

Synthetic Communications, 2010 , vol. 40, # 16 p. 2483 - 2487 Title/Abstract Full Text View citing articles Show Details

92%

Stage #1: With potassium hydoxide in methanol

Nef reaction; Continuous flow conditions; Stage #2: With potassium permanganate; water in methanol

T=25°C; Nef reaction; SonicationContinuous flow conditions; chemoselective reaction;

Sedelmeier, Joerg; Ley, Steven V.; Baxendale, Ian R.; Baumann, Marcus

Organic Letters, 2010 , vol. 12, # 16 p. 3618 - 3621 Title/Abstract Full Text View citing articles Show Details

88%

With dihydrogen peroxide; potassium carbonate

1. MeOH, H2O, 0 deg C 2. 8h, room temp.;

Olah, George A.; Narang, Subhash C.; Salem, George F.

Synthesis, 1980 , p. 657 Title/Abstract Full Text Show Details

Hide Details

80%

With ammonium cerium(IV) nitrate; triethylamine in water; acetonitrile

T=50°C; 2 h;

Olah, George A.; Gupta, B. G. Balaram

Synthesis, 1980 , # 1 p. 44 - 45 Title/Abstract Full Text Show Details

80%

With (cetyl)Me3N(1+)MnO4(1-); triethylamine in dichloromethane

4 h;

Vankar, Padma S.; Rathore, R.; Chandrasekaran, S.

Synthetic Communications, 1987 , vol. 17, # 2 p. 195 - 202 Title/Abstract Full Text Show Details

72%

Stage #1: With sodium hydroxide in water

T=20°C; Nef reaction; Stage #2: With sulfuric acid in water

T=20°C; Nef reaction; 24 h;

Liguori, Lucia; Bjorsvik, Hans-Rene

Organic Process Research and Development, 2011 , vol. 15, # 5 p. 997 - 1009 Title/Abstract Full Text Show Details

70%

With tetrabutylammomium bromide; oxygen in acetonitrile

2 h; electrolysis;

Monte, William T.; Baizer, Manuel M.; Little, R. Daniel

Journal of Organic Chemistry, 1983 , vol. 48, # 6 p. 803 - 806 Title/Abstract Full Text View citing articles Show Details

70%

With bis-trimethylsilanyl peroxide; sodium hydride in tetrahydrofuran

T=20°C; Hydrolysis; 20 h;

Shahi, Shatrughan P.; Vankar, Yashwant D.

Synthetic Communications, 1999 , vol. 29, # 24 p. 4321 - 4325 Title/Abstract Full Text View citing articles Show Details

16%

With glucose-6-phosphate dehydrogenase; D-glucose 6-phosphate; nicotinamide adenine dinucleotide phosphate

T=30°C; pH=7.5; 24 h; aq. buffer;

Durchschein, Katharina; Ferreira-Da Silva, Bianca; Wallner, Silvia; MacHeroux, Peter; Kroutil, Wolfgang; Glueck, Silvia Maria; Faber, Kurt

Green Chemistry, 2010 , vol. 12, # 4 p. 616 - 619 Title/Abstract Full Text View citing articles Show Details

With water; nickel; carbon

T=150°C; P=51485.6 Torr; Hydrogenation.anschl. mit wss. H2SO4 bei 100grad;

Union Oil Co. of California

Patent: US2423180 , 1944 ; Full Text Show Details

With acetic acid; zinc

Markownikow

Justus Liebigs Annalen der Chemie, 1898 , vol. 302, p. 20 Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1898 , vol. 30, p. 167 Chem. Zentralbl., 1898 , vol. 69, # II p. 578 Full Text Show Details

With potassium permanganate

Nametkin; Posdnjakowa

Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1913 , vol. 45, p. 1422 Chem. Zentralbl., 1914 , vol. 85, # I p. 757 Full Text Show Details

With n-butyllithium; hexane 2. MoO5.Pyr.HMPA; diisopropylamine

1. in THF, -78 deg C, 5 min 2. the mixture was allowed to warm to room temperature for 3 h; Yield given. Multistep reaction;

Galobardes, Mercedes R.; Pinnick, Harold W.

Tetrahedron Letters, 1981 , vol. 22, # 52 p. 5235 - 5238 Title/Abstract Full Text View citing articles Show Details

Multi-step reaction with 2 steps 1: Li2S / 8 h / 25 °C 2: 92 percent / Ce(NH4)2(NO3)6 / acetonitrile; H2O / 0.08 h / 25 °C View Scheme

Olah, George A.; Gupta, B. G. Balaram

Synthesis, 1980 , # 1 p. 44 - 45 Title/Abstract Full Text Show Details

286 Synthesize Find similar

Synthesize Find similar

Rx-ID: 1550183 Find similar reactions

96%

With hydrogen iodide

0.0166667 h; Ambient temperature;

Penso; Mottadelli; Albanese

Synthetic Communications, 1993 , vol. 23, # 10 p. 1385 - 1391 Title/Abstract Full Text View citing articles Show Details

93%

With DMBI in 1,4-dioxane

15 h; Heating;

Chikashita, Hidenori; Ide, Hisao; Itoh, Kazuyoshi

Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5400 - 5405 Title/Abstract Full Text View citing articles Show Details

90%

With sodium dithionite in water

5 h; Ambient temperature;

Chung, Sung-Kee; Hu, Qing-Yu

Synthetic Communications, 1982 , vol. 12, # 4 p. 261 - 266 Title/Abstract Full Text Show Details

Hide Details

90%

With diammonium oxalate; aluminium in methanol

2.5 h; Heating;

Nagaraja; Pasha

Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2002 , vol. 41, # 12 p. 2602 - 2603 Title/Abstract Full Text View citing articles Show Details

89%

With trimethylsilyl iodide in chloroform

Ambient temperatureor reflux;

Ho, Tse-Lok

Synthetic Communications, 1981 , vol. 11, # 2 p. 101 - 104 Title/Abstract Full Text Show Details

80%

With triphenylphosphine hydroiodide in acetonitrile

4 h; Ambient temperature;

Kamiya, Naoshi; Tanmatu, Hiroshi; Ishii, Yasutaka

Chemistry Letters, 1992 , p. 293 - 296 Title/Abstract Full Text Show Details

50%

With [Ru(II)(2,2’-bipyridine)3]Cl2; DNP; ascorbic acid powder in methanol; water

24 h; Inert atmosphereIrradiation;

Maji, Tapan; Karmakar, Ananta; Reiser, Oliver

Journal of Organic Chemistry, 2011 , vol. 76, # 2 p. 736 - 739 Title/Abstract Full Text View citing articles Show Details

287 Synthesize Find similar

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Rx-ID: 1731931 Find similar reactions

A: 96% B: 1% C: 1%

With ammonium chloride in methanol

Electrochemical reaction;

Santana, Diogo S.; Lima, Marcio V. F.; Daniel, Jorge R. R.; Navarro, Marcelo

Tetrahedron Letters, 2003 , vol. 44, # 25 p. 4725 - 4727 Title/Abstract Full Text View citing articles Show Details

A: 68% B: 1% C: 2%

With {(.eta.6-C6H6)Ru(NCCH3)3}{BF4}2; water; hydrogen in benzene

T=110°C; P=30400 Torr; 4 h;

Chan, Wai-Chung; Lau, Chak-Po; Cheng, Lin; Leung, Yin-Shan

Journal of Organometallic Chemistry, 1994 , vol. 464, # 1 p. 103 - 106 Title/Abstract Full Text View citing articles Show Details

With Li(1+)*C12H28AlO3(1-) in tetrahydrofuran; hexane

T=-78°C; 3 h; Yield given. Yields of byproduct given;

Kim, Sunggak; Ahn, Kyo Han

Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1717 - 1724 Title/Abstract Full Text View citing articles Show Details

Hide Details

B: 83 % Chromat.

With lithium aluminium tetrahydride in tetrahydrofuran

0.166667 h; Ambient temperature;

Fukuzawa, Shin-ichi; Fujinami, Tatsuo; Yamauchi, Shoji; Sakai, Shizuyoshi

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1929 - 1932 Title/Abstract Full Text View citing articles Show Details

With lithium aluminium tetrahydride; cryptand 211 in tetrahydrofuran

0.0166667 h; Ambient temperature; Yield given. Yields of byproduct given;

Loupy, Andre; Seyden-Penne, Jacqueline

Tetrahedron, 1980 , vol. 36, p. 1937 - 1942 Title/Abstract Full Text View citing articles Show Details

B: 83 % Chromat.

With lithium aluminium tetrahydride in tetrahydrofuran

0.166667 h; Ambient temperature; Yield given;

Fukuzawa, Shin-ichi; Fujinami, Tatsuo; Yamauchi, Shoji; Sakai, Shizuyoshi

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1929 - 1932 Title/Abstract Full Text View citing articles Show Details

With lithium borohydride; cryptand 211 in tetrahydrofuran

0.0166667 h; Ambient temperature; Yield given. Yields of byproduct given;

Loupy, Andre; Seyden-Penne, Jacqueline

Tetrahedron, 1980 , vol. 36, p. 1937 - 1942 Title/Abstract Full Text View citing articles Show Details

A: 30 % Chromat. B: 10 % Chromat. C: 60 % Chromat.

With tetrabutylammonium borohydride in nitromethane

20 h; Ambient temperatureexamination with further reagents, effect of solvent, reaction time; Product distribution;

D'Incan, E.; Loupy, A.

Tetrahedron, 1981 , vol. 37, p. 1171 - 1180 Title/Abstract Full Text View citing articles Show Details

A: 1 % Chromat. B: 98 % Chromat. C: 1 % Chromat.

With lithium aluminium tetrahydride; cerium(III) chloride in tetrahydrofuran

0.166667 h; Ambient temperatureWithout catalyst; Product distribution;

Fukuzawa, Shin-ichi; Fujinami, Tatsuo; Yamauchi, Shoji; Sakai, Shizuyoshi

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1929 - 1932 Title/Abstract Full Text View citing articles Show Details

With lithium aluminium tetrahydride; (1,4,7,10-tetraoxacyclododecane)

0.0166667 h; Ambient temperatureother conditions, other derivates; Product distributionMechanism;

Loupy, Andre; Seyden-Penne, Jacqueline

Tetrahedron, 1980 , vol. 36, p. 1937 - 1942 Title/Abstract Full Text View citing articles Show Details

A: 91 % Chromat. B: 2 % Chromat. C: 3 % Chromat.

With copper(l) iodide; lithium aluminium tetrahydride in tetrahydrofuran; N,N,N,N,N,Nhexamethylphosphoric triamide

T=-78°C; 1 h; var. α,β-unsaturated carbonyl compounds; other cond.: var. educt/LiAlH4 and CuI/LiAlH4 ratios, without HMPA, other time: 10 min; Product distribution;

Tsuda, Tetsuo; Fujii, Tomoyuki; Kawasaki, Kaoru; Saegusa, Takeo

Journal of the Chemical Society, Chemical Communications, 1980 , # 21 p. 1013 - 1014 Title/Abstract Full Text View citing articles Show Details

A: 99.4 % Chromat. B: 0.2 % Chromat. C: 0.4 % Chromat.

With hydrogen; H2Ru2Rh2(CO)12 in tetrahydrofuran

T=50°C; P=98800 Torr; 24 h; further catalysts, temperatures; Product distribution;

Piacenti, Franco; Matteoli, Ugo; Bianchi, Mario; Frediani, Piero; Menchi, Gloria

Gazzetta Chimica Italiana, 1988 , vol. 118, # 4 p. 305 - 308 Title/Abstract Full Text Show Details

With sodium tetrahydroborate; SmCpCl2(THF)3 in dimethyl sulfoxide

6 h; Ambient temperaturefurther solvents; further α,β-unsaturated ketones; Product distribution;

Komiya, Sanshiro; Tsutsumi, Osamu

Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3423 - 3424 Title/Abstract Full Text Show Details

A: 47.4 % Chromat. B: 38.4 % Chromat. C: 14.2 % Chromat.

With diphenylsilane; sodium hydride; potassium carbonate in neat (no solvent) 100 h; different amount of reagent, different reaction times; Product distribution;

Cullen, William R.; Wickenheiser, Eugene B.

Journal of Organometallic Chemistry, 1989 , vol. 370, p. 141 - 154 Title/Abstract Full Text View citing articles Show Details

With diisobutylaluminium hydride in hexane; toluene

T=-78°C; 3 h; Yield given. Yields of byproduct given;

Kim, Sunggak; Ahn, Kyo Han

Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1717 - 1724 Title/Abstract Full Text View citing articles Show Details

B: 57 % Chromat.

With tetrabutylammonium borohydride in methanol

Ambient temperature;

D'Incan, E.; Loupy, A.

Tetrahedron, 1981 , vol. 37, p. 1171 - 1180 Title/Abstract Full Text View citing articles Show Details

A: 1 % Chromat. B: 98 % Chromat. C: 1 % Chromat.

With lithium aluminium tetrahydride; cerium(III) chloride in tetrahydrofuran

0.166667 h; Ambient temperature;

Fukuzawa, Shin-ichi; Fujinami, Tatsuo; Yamauchi, Shoji; Sakai, Shizuyoshi

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1929 - 1932 Title/Abstract Full Text View citing articles Show Details

With lithium aluminium tetrahydride in tetrahydrofuran

0.0166667 h; Ambient temperature; Yield given. Yields of byproduct given;

Loupy, Andre; Seyden-Penne, Jacqueline

Tetrahedron, 1980 , vol. 36, p. 1937 - 1942 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide; sodium tetrahydroborate; tris(triphenylphosphine)ruthenium(II) chloride

multistep reaction: 1.) diisopropyl ether, reflux, 2.) 40 deg C, 1 h; various catalytic systems; selective reduction of various carbonyl compounds by polymethylhydrosiloxane in the presence of metal hydride catalysts; conversion; selectivity; Product distribution;

Mimoun

Journal of Organic Chemistry, 1999 , vol. 64, # 7 p. 2582 - 2589 Title/Abstract Full Text View citing articles Show Details

With hydrogen; Ru(CO)2(OAc)2(Pn-Bu3)(PPh3) in toluene

T=60°C; P=18751.9 Torr; 3 h; Product distribution; Further Variations:PressuresTemperaturesCatalystsreagents;

Micoli, Francesca; Oberhauser, Werner; Salvini, Antonella; Bianchini, Claudio

Journal of Organometallic Chemistry, 2007 , vol. 692, # 11 p. 2334 - 2341 Title/Abstract Full Text View citing articles Show Details

With .kappa.2-P,N-[(.eta.6-p-cymene)RuCl(1-methylimidazolyl(1,3,5-triaza-7phosphatricyclo[3.3.1.1(3,7)]dec-6-yl)methanol)]Cl; potassium tert-butylate; hydrogen in isopropyl alcohol

T=25°C; P=22502.3 Torr; 4 h; Inert atmosphereAutoclave;

Krogstad, Donald A.; Guerriero, Antonella; Ienco, Andrea; Manca, Gabriele; Peruzzini, Maurizio; Reginato, Gianna; Gonsalvi, Luca

Organometallics, 2011 , vol. 30, # 22 p. 6292 - 6302 Title/Abstract Full Text View citing articles Show Details

A: 2 % Chromat. B: 45 % Chromat. C: 44 % Chromat.

With zinc-modified cyanoborohydride, aldehydes, ketones, tosylhydrazones, acid chlorides and amines in diethyl ether

4 h; other enonesAmbient temperature; Product distribution;

Kim, Sunggak; Oh, Chang Ho; Ko, Jae Suk; Ahn, Kyo Han; Kim, Yong Jin

Journal of Organic Chemistry, 1985 , vol. 50, # 11 p. 1927 - 1932 Title/Abstract Full Text View citing articles Show Details

288 Synthesize Find similar

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Rx-ID: 1984094 Find similar reactions

93%

With [(CH3)2N](CH3)2N=C-C=N(CH3)2[N(CH3)2](2+)*2F(1-) in acetonitrile

T=20°C; desilylation; 96 h;

Chambers, Richard D.; Gray, William K.; Sandford, Graham; Vaughan, Julian F.S.

Journal of Fluorine Chemistry, 1999 , vol. 94, # 2 p. 213 - 215 Title/Abstract Full Text View citing articles Show Details

87%

With 2-Chloro-2-methylpropane; silica gel in tetrahydrofuran

T=59.84°C; 16 h;

Sasidharan, Manickam; Bhaumik, Asim

Journal of Molecular Catalysis A: Chemical, 2011 , vol. 346, # 1-2 p. 87 - 93 Title/Abstract Full Text View citing articles Show Details

With 9-bromo-9-bora-bicyclo[3.3.1]nonane in dichloromethane

0.333333 h; Ambient temperature; Yield given;

WADA, Makoto

Chemistry Letters, 1981 , p. 153 - 156 Title/Abstract Full Text Show Details

289 Synthesize Find similar

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Rx-ID: 2117372 Find similar reactions

in dichloromethane

Ambient temperature; Yield given;

Moriarty, Robert M.; Prakash, Om; Vavilikolanu, Pushra R.

Synthetic Communications, 1986 , vol. 16, # 10 p. 1247 - 1254 Title/Abstract Full Text Show Details

With sodium hydroxide in methanol; water

Banerjee, Ranjan; Bruce King

Organic Letters, 2009 , vol. 11, # 20 p. 4580 - 4583 Title/Abstract Full Text View citing articles Show Details

With sodium hydroxide in methanol

Shoman, Mai E.; Dumond, Jenna F.; Isbell; Crawford; Brandon, Angela; Honovar, Jaideep; Vitturi, Dario A.; White; Patel; King, S. Bruce

Journal of Medicinal Chemistry, 2011 , vol. 54, # 4 p. 1059 - 1070 Title/Abstract Full Text View citing articles Show Details

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290 Synthesize Find similar Rx-ID: 4465934 Find similar reactions

With Hβ zeolite

T=349.9°C; P=750.06 Torr; various diluents; other catalysts; Product distribution;

Dai, Lian-Xin; Hayasaka, Raita; Iwaki, Yoshihide; Koyano, Keiko A.; Tatsumi, Takashi

Chemical Communications, 1996 , # 9 p. 1071 - 1072 Title/Abstract Full Text View citing articles Show Details

With silica gel-supported [(Ta6Cl12)Cl2(H2O)4]*4H2O in methanol

T=300°C; Beckmann rearrangement; P=760.051 Torr; 3 h;

Nagashima, Sayoko; Kamiguchi, Satoshi; Ohguchi, Satoshi; Chihara, Teiji

Catalysis Today, 2011 , vol. 164, # 1 p. 135 - 138 Title/Abstract Full Text View citing articles Show Details

With silica gel-supported Re3Cl9 in methanol

T=300°C; Beckmann rearrangement; P=760.051 Torr; 3 h;

Nagashima, Sayoko; Kamiguchi, Satoshi; Ohguchi, Satoshi; Chihara, Teiji

Catalysis Today, 2011 , vol. 164, # 1 p. 135 - 138 Title/Abstract Full Text View citing articles Show Details

291 Synthesize Find similar

Synthesize Find similar

Rx-ID: 5081315 Find similar reactions

43%

With air; tetrabutyl ammonium fluoride in tetrahydrofuran

T=0 - 20°C; deformylation;

Kuroda, Chiaki; Murase, Atsushi; Suzuki, Hideyuki; Endo, Toru; Anzai, Shuzo

Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 7 p. 1639 - 1647 Title/Abstract Full Text View citing articles Show Details

40%

With K[Mn(II)H2bupa] in N,N-dimethyl acetamide

T=20°C; 3 h;

Shook, Ryan L.; Gunderson, William A.; Greaves, John; Ziller, Joseph W.; Hendrich, Michael P.; Borovik

Journal of the American Chemical Society, 2008 , vol. 130, # 28 p. 8888 - 8889 Title/Abstract Full Text View citing articles Show Details

50 %Spectr.

With C17H22MnN4O2*ClHO4 in acetonitrile

T=-40°C; Kinetics;

Geiger, Robert A.; Chattopadhyay, Swarup; Day, Victor W.; Jackson, Timothy A.

Dalton Transactions, 2011 , vol. 40, # 8 p. 1707 - 1715 Title/Abstract Full Text View citing articles Show Details

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292 Synthesize Find similar

Rx-ID: 9901328 Find similar reactions

A: 83% B: 6.8%

With Au/Al2O3; hydrogen in ethanol

T=100°C; P=4500.45 Torr; 6 h; Autoclave; chemoselective reaction;

Shimizu, Ken-Ichi; Yamamoto, Takumi; Tai, Yutaka; Satsuma, Atsushi

Journal of Molecular Catalysis A: Chemical, 2011 , vol. 345, # 1-2 p. 54 - 59 Title/Abstract Full Text View citing articles Show Details

A: 22% B: 36%

Stage #1: With potassium tert-butylate in diethyl ether

T=0°C; 1 h; Stage #2: With oxalyl dichloride

T=0°C; 1 h; Stage #3: With isopropenylbenzene

T=20°C; 48 h;

Bou-Moreno, Rafael; Luengo-Arratta, Sandra; Motherwell, William B.

Tetrahedron Letters, 2011 , vol. 52, # 17 p. 2097 - 2099 Title/Abstract Full Text View citing articles Show Details

A: 10 % Chromat. B: 85 % Chromat.

With acetic acid; sodium nitrite in dimethyl sulfoxide

T=95°C; 21 h; Product distribution; Further Variations:ReagentsTemperaturesSolvents;

Gissot, Arnaud; N'Gouela, Silvere; Matt, Christophe; Wagner, Alain; Mioskowski, Charles

Journal of Organic Chemistry, 2004 , vol. 69, # 26 p. 8997 - 9001 Title/Abstract Full Text View citing articles Show Details

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293 Synthesize Find similar Rx-ID: 29107664

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With gold nanoparticles supported on titanium oxide; hydrogen in ethanol

T=139.84°C; P=11251.1 Torr; 1.75 h;

Serna, Pedro; Lopez-Haro; Calvino; Corma, Avelino

Journal of Catalysis, 2009 , vol. 263, # 2 p. 328 - 334 Title/Abstract Full Text View citing articles Show Details

With Au-TiO2 nanoparticles; hydrogen in ethanol

T=100°C; P=4500.45 Torr; 12 h; Autoclave; chemoselective reaction;

Shimizu, Ken-Ichi; Yamamoto, Takumi; Tai, Yutaka; Satsuma, Atsushi

Journal of Molecular Catalysis A: Chemical, 2011 , vol. 345, # 1-2 p. 54 - 59 Title/Abstract Full Text View citing articles Show Details

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294

A: 93% B: 69%

Rx-ID: 30275825 Find similar reactions

National University Corporation Nara Institute of Science and Technology

Patent: US2011/28738 A1, 2011 ; Location in patent: Page/Page column 38 ;

Title/Abstract Full Text Show Details

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295 Synthesize Find similar

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Rx-ID: 30468866 Find similar reactions

A: 17 %Chromat. B: 10 %Chromat. C: 42 %Chromat.

With [(iPrPNP)FeH(CO)Br]; potassium tert-butylate; hydrogen

T=26 - 28°C; P=3116.21 Torr; 21 h;

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Langer, Robert; Leitus, Gregory; Ben-David, Yehoshoa; Milstein, David

Angewandte Chemie - International Edition, 2011 , vol. 50, # 9 p. 2120 - 2124 Title/Abstract Full Text View citing articles Show Details

296 Synthesize Find similar

With hydrogenchloride in methanol

With N-acetyl-(R)-cysteine in methanol

aq. buffer;

Rx-ID: 30546642 Find similar reactions

Shoman, Mai E.; Dumond, Jenna F.; Isbell; Crawford; Brandon, Angela; Honovar, Jaideep; Vitturi, Dario A.; White; Patel; King, S. Bruce

Journal of Medicinal Chemistry, 2011 , vol. 54, # 4 p. 1059 - 1070 Title/Abstract Full Text View citing articles Show Details

Shoman, Mai E.; Dumond, Jenna F.; Isbell; Crawford; Brandon, Angela; Honovar, Jaideep; Vitturi, Dario A.; White; Patel; King, S. Bruce

Journal of Medicinal Chemistry, 2011 , vol. 54, # 4 p. 1059 - 1070 Title/Abstract Full Text View citing articles Show Details

Shoman, Mai E.; Dumond, Jenna F.; Isbell; Crawford; Brandon, Angela; Honovar, Jaideep; Vitturi, Dario A.; White; Patel; King, S. Bruce

Journal of Medicinal Chemistry, 2011 , vol. 54, # 4 p. 1059 - 1070 Title/Abstract Full Text View citing articles Show Details

in methanol

T=20°C; pH=7.6; aq. buffer; Kinetics;

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297 Synthesize Find similar

Rx-ID: 30546645 Find similar reactions

With thiophenol in methanol

T=20°C; pH=7.6; aq. buffer; Kinetics;

Shoman, Mai E.; Dumond, Jenna F.; Isbell; Crawford; Brandon, Angela; Honovar, Jaideep; Vitturi, Dario A.; White; Patel; King, S. Bruce

Journal of Medicinal Chemistry, 2011 , vol. 54, # 4 p. 1059 - 1070 Title/Abstract Full Text View citing articles Show Details

With N-acetyl-(R)-cysteine; cyclopentanone in methanol

Shoman, Mai E.; Dumond, Jenna F.; Isbell; Crawford; Brandon, Angela; Honovar, Jaideep; Vitturi, Dario A.; White; Patel; King, S. Bruce

Journal of Medicinal Chemistry, 2011 , vol. 54, # 4 p. 1059 - 1070 Title/Abstract Full Text View citing articles Show Details

With N-acetyl-(R)-cysteine in methanol

aq. buffer;

Shoman, Mai E.; Dumond, Jenna F.; Isbell; Crawford; Brandon, Angela; Honovar, Jaideep; Vitturi, Dario A.; White; Patel; King, S. Bruce

Journal of Medicinal Chemistry, 2011 , vol. 54, # 4 p. 1059 - 1070 Title/Abstract Full Text View citing articles Show Details