Cyclohexanone by Asch

Reaxys

PubChem

eMolecules

Reactions (1470)

Yield

Substances (2)

Citations (3478)

Conditions

References A

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1090 Synthesize Find similar A: 80% B: 69%

Rx-ID: 2091875 Find similar reactions

With sulfuric acid in ethanol; water

Irradiationother solvents; Product distributionMechanism;

Aoyama, Hiromu; Sakamoto, Masami; Omote, Yoshimori

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1357 - 1359 Title/Abstract Full Text View citing articles Show Details

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1091 Synthesize Find similar A: 35 % Chromat. B: 5 % Chromat.

With triphenylmethane tetrafluoroborate in dichloromethane

Rx-ID: 2130967 Find similar reactions

Manis, Paul A.; Rathke, Michael W.

Journal of Organic Chemistry, 1981 , vol. 46, p. 5348 - 5351 Title/Abstract Full Text View citing articles Show Details

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1092

Rx-ID: 2343308 Find similar reactions

With ozone

T=40°C; 2 h; Further byproducts given;

Korotkova, N. P.; Syroezhko, A. M.; Proskuryakov, V. A. J. Appl. Chem. USSR (Engl. Transl.), 1981 , vol. 54, # 4 p. 861 - 867,705 - 709 Title/Abstract Full Text Show Details

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1093 Synthesize Find similar

Rx-ID: 2645820 Find similar reactions

With pyridine; chromium(VI) oxide in dichloromethane

T=20°C; 2 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Davis, Anthony P.; Hughes, Gwyneth J.; Lowndes, Peter R.; Robbins, Catherine M.; Thomas, Elizabeth J.; Whitham, Gordon H.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1934 - 1941 Title/Abstract Full Text View citing articles Show Details

With pyridine; chromium(VI) oxide in dichloromethane

T=20°C; 2 h; Yield given. Yields of byproduct given;

Davis, Anthony P.; Hughes, Gwyneth J.; Lowndes, Peter R.; Robbins, Catherine M.; Thomas, Elizabeth J.; Whitham, Gordon H.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1934 - 1941 Title/Abstract Full Text View citing articles Show Details

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1094 Synthesize Find similar Rx-ID: 2889939 Find similar reactions

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A: 26%

With titanium(III) chloride; acetic acid

3 h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts;

Citterio, Attilio; Minisci, Francesco; Serravalle, Marco

Journal of Chemical Research, Miniprint, 1981 , # 7 p. 2174 - 2189 Title/Abstract Full Text Show Details

A: 26%

With titanium(III) chloride; acetic acid

3 h; Ambient temperature; Yield given. Title compound not separated from byproducts;

Citterio, Attilio; Minisci, Francesco; Serravalle, Marco

Journal of Chemical Research, Miniprint, 1981 , # 7 p. 2174 - 2189 Title/Abstract Full Text Show Details

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1095 Synthesize Find similar

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Rx-ID: 2890184 Find similar reactions

With titanium(III) chloride; acetic acid

3 h; Ambient temperature; Yield given;

Citterio, Attilio; Minisci, Francesco; Serravalle, Marco

Journal of Chemical Research, Miniprint, 1981 , # 7 p. 2174 - 2189 Title/Abstract Full Text Show Details

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1096 Synthesize Find similar

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Rx-ID: 2894575 Find similar reactions

With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 4 h; Equilibrium constant;

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 30 h; Equilibrium constant;

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

1097 Synthesize Find similar

100 % Chromat.

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Rx-ID: 2978799 Find similar reactions

With hydrogenchloride in tetrahydrofuran

2 h; other hydrolysis conditions; comparison of rates of hydrolysis with the corresponding trimethylsilyl and tert-butyldimethylsilyl enol ethers;

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1098 Synthesize Find similar

Rx-ID: 2978800 Find similar reactions

Manis, Paul A.; Rathke, Michael W.

Journal of Organic Chemistry, 1981 , vol. 46, p. 5348 - 5351 Title/Abstract Full Text View citing articles Show Details

A: 91 % Chromat. B: 6 % Chromat.

With triphenylmethane tetrafluoroborate in dichloromethane

T=25°C; 0.166667 h;

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Manis, Paul A.; Rathke, Michael W.

Journal of Organic Chemistry, 1981 , vol. 46, p. 5348 - 5351 Title/Abstract Full Text View citing articles Show Details

1099 Synthesize Find similar

Rx-ID: 3015281 Find similar reactions

in N,N,N',N',N'',N''-hexamethylphosphoric triamide

decomposition of Na ,Li and Cs 1-(fluoren-9-yl)cyclohexanolates; reaction of alkaline (Li, Na, K, Cs) and tetrabutylammonim salts of fluorene withb cyclohexanone, role of counterion and solvent; Product distribution;

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Beletskaya, I. P.; Solov'yanov, A. A.; Karpyuk, A. D.; Kucheryavenko, O. P.; Reutov, O. A.

Doklady Chemistry, 1981 , vol. 261, p. 529 - 531 Dokl. Akad. Nauk SSSR Ser. Khim., 1981 , vol. 261, # 5 p. 1138 - 1140 Title/Abstract Full Text Show Details

1100 Synthesize Find similar

A: 23 % Chromat. B: 23 % Chromat. C: 54 % Chromat.

Rx-ID: 3031079 Find similar reactions

With water in gas evidence for cyclohexyl cation existence, structure and isomerisation of the C6H11+ ions; product yield dependence on pressure and composition of the gaseous system; Product distribution;

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Attina, Marina; Cacace, Fulvio; Giacomello, Pierluigi

Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4711 - 4714 Title/Abstract Full Text View citing articles Show Details

1101 Synthesize Find similar

A: 66 % Chromat. B: 69 % Chromat. C: 5 % Chromat.

With tetrachloromethane

1 h; Heating; Product distribution;

Chang, Yau-Min; Profetto, Ralph; Warkentin, John

Journal of the American Chemical Society, 1981 , vol. 103, # 24 p. 7189 - 7195 Title/Abstract Full Text View citing articles Show Details

1102 Synthesize

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Rx-ID: 3124177 Find similar reactions

Find similar

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Rx-ID: 3384151 Find similar reactions

With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 6 h; Equilibrium constantRate constant;

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

With trifluoroacetic acid; Ru(O2CCF3)2(CO)(PPh3)2

T=140°C; ΔG (gas); reaction without reagent or in the presence of KOH, further temp.; Equilibrium constantThermodynamic data;

Strohmeier, Walter; Graser, Barbara

Zeitschrift fuer Physikalische Chemie (Muenchen, Germany), 1980 , vol. 121, p. 121 - 130 Title/Abstract Full Text Show Details

With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 12 h; variat. KOH concentration; Equilibrium constantRate constant;

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

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1103 Synthesize Find similar

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Rx-ID: 3398736 Find similar reactions

Ogawa, Yuji; Iwasaki, Shigeo; Okuda, Shigenobu

Tetrahedron Letters, 1981 , vol. 22, p. 2277 - 2280 Title/Abstract Full Text View citing articles Show Details

in dichloromethane

0.0666667 h; Irradiation; Yield given. Title compound not separated from byproducts;

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1104 Synthesize Find similar

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With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 7 h; Equilibrium constant;

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

With potassium hydroxide; Ru(O2CCF3)2(CO)(PPh3)2

T=140°C; ΔG (gas), further temp.; Equilibrium constantThermodynamic data;

Strohmeier, Walter; Graser, Barbara

Zeitschrift fuer Physikalische Chemie (Muenchen, Germany), 1980 , vol. 121, p. 121 - 130 Title/Abstract Full Text Show Details

1105

Rx-ID: 3756834 Find similar reactions

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A: 76%

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Rx-ID: 3778505 Find similar reactions

With vanadium(II) chloride in tetrahydrofuran

1 h; Heating;

Olah, George A.; Chao, Yah-Lih; Arvanaghi, Massoud; Prakash, G. K. Surya

Synthesis, 1981 , # 6 p. 476 Title/Abstract Full Text Show Details

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1106 Synthesize Find similar

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Rx-ID: 3788942 Find similar reactions

With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 200 h; Equilibrium constant;

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 200 h; Equilibrium constantRate constant;

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

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1107 Synthesize Find similar

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Rx-ID: 3794770 Find similar reactions

With triethylamine

28 h; Irradiation;

Purohit, P.C.; Sonawane, H.R.

Tetrahedron, 1981 , vol. 37, p. 873 - 877 Title/Abstract Full Text View citing articles Show Details

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1108 Synthesize Find similar

Rx-ID: 3794893 Find similar reactions

in cyclohexane

28 h; Irradiationfurther α-halocyclohexanones in presence or absence of triplet quenchers or sensitizers; Product distributionMechanism;

Purohit, P.C.; Sonawane, H.R.

Tetrahedron, 1981 , vol. 37, p. 873 - 877 Title/Abstract Full Text View citing articles Show Details

With zinc in cyclohexane

28 h; Irradiation; Yield given. Yields of byproduct given;

Purohit, P.C.; Sonawane, H.R.

Tetrahedron, 1981 , vol. 37, p. 873 - 877 Title/Abstract Full Text View citing articles Show Details

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1109 Synthesize Find similar

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Rx-ID: 3855113 Find similar reactions

Ogawa, Yuji; Iwasaki, Shigeo; Okuda, Shigenobu

Tetrahedron Letters, 1981 , vol. 22, p. 2277 - 2280 Title/Abstract Full Text View citing articles Show Details

in dichloromethane

Irradiation; Further byproducts given. Title compound not separated from byproducts;

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1110 Synthesize Find similar

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Rx-ID: 3855701 Find similar reactions

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 50 h; Equilibrium constant;

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1111 Synthesize Find similar

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With potassium hydroxide; Ru(O2CCF3)2(CO)(PPh3)2

T=140°C; 24 h; ΔG (gas); Equilibrium constantThermodynamic data;

Strohmeier, Walter; Graser, Barbara

Zeitschrift fuer Physikalische Chemie (Muenchen, Germany), 1980 , vol. 121, p. 121 - 130 Title/Abstract Full Text Show Details

With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 4.5 h; Equilibrium constant;

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

Rx-ID: 3855718 Find similar reactions

1112 Synthesize Find similar

A: 65 % Chromat. B: 35 % Chromat.

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Rx-ID: 3855762 Find similar reactions

in gas Irradiationreaction with H2; gas-phase reaction of radiolytically formed cyclohexyl cation with water; evidence for cyclohexyl cation existence, product yield dependence on pressure and composition of the gaseous system; Product distribution;

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Attina, Marina; Cacace, Fulvio; Giacomello, Pierluigi

Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4711 - 4714 Title/Abstract Full Text View citing articles Show Details

1113 Synthesize Find similar

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Rx-ID: 3856101 Find similar reactions

Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore

Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677 Title/Abstract Full Text Show Details

With potassium hydroxide; Ru(CF3CO2)CO(PPh3)2

T=140°C; 50 h; Equilibrium constant;

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1114 Synthesize Find similar Rx-ID: 3856142 Find similar reactions

With Co(b) T=573°C; variation of temperature, catalyst, carrier gas; Product distribution;

Dobrovolszky, M.; Tetenyi, P.; Paal, Z.

Acta Chimica Academiae Scientiarum Hungaricae, 1981 , vol. 107, p. 343 - 360 Title/Abstract Full Text Show Details

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1115 Synthesize Find similar Rx-ID: 6217776 Find similar reactions

C: 50.6%

With oxygen; ozone

T=40°C; 3 h; oth. temperature, oth. time, presence of CCl4; Product distributionRate constantMechanism;

Korotkova, N. P.; Syroezhko, A. M.; Proskuryakov, V. A. J. Appl. Chem. USSR (Engl. Transl.), 1981 , vol. 54, # 3 p. 660 - 665,520 - 524

Title/Abstract Full Text Show Details

1116 Synthesize Find similar

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Rx-ID: 20548739 Find similar reactions

Multi-step reaction with 2 steps 1: 92.4 percent / lithium aluminium hydride / diethyl ether / 0.17 h 2: chromium trioxide, pyridine / CH2Cl2 / 2 h / 20 °C View Scheme

Davis, Anthony P.; Hughes, Gwyneth J.; Lowndes, Peter R.; Robbins, Catherine M.; Thomas, Elizabeth J.; Whitham, Gordon H.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1934 - 1941 Title/Abstract Full Text View citing articles Show Details

1117 Synthesize Find similar

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Rx-ID: 20554451 Find similar reactions

Multi-step reaction with 3 steps 1: 83 percent / 49percent peracetic acid, sodium acetate / CH2Cl2 / 0.5 h / 20 °C 2: 92.4 percent / lithium aluminium hydride / diethyl ether / 0.17 h 3: chromium trioxide, pyridine / CH2Cl2 / 2 h / 20 °C View Scheme

Davis, Anthony P.; Hughes, Gwyneth J.; Lowndes, Peter R.; Robbins, Catherine M.; Thomas, Elizabeth J.; Whitham, Gordon H.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1934 - 1941 Title/Abstract Full Text View citing articles Show Details

1118 Synthesize Find similar

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Rx-ID: 20750043 Find similar reactions

Multi-step reaction with 2 steps 1: chromic acid 2: Et3N / cyclohexane / 40 h / Irradiation View Scheme

Purohit, P.C.; Sonawane, H.R.

Tetrahedron, 1981 , vol. 37, p. 873 - 877 Title/Abstract Full Text View citing articles Show Details

1119 Synthesize Find similar

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Multi-step reaction with 2 steps 1: chromic acid

Rx-ID: 20752187 Find similar reactions

Purohit, P.C.; Sonawane, H.R.

Tetrahedron, 1981 , vol. 37, p. 873 - 877

2: Et3N / cyclohexane / 12 h / Irradiation View Scheme

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Title/Abstract Full Text View citing articles Show Details

1120

Rx-ID: 25060227 Find similar reactions

The Upjohn Company

Patent: US4282383 A1, 1981 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

6:EXAMPLE 6

The dicyclohexylbenzene hydroperoxide obtained as described above was rearranged to yield hydroquinone and cyclohexanone using the following procedure. A

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1121 Synthesize Find similar

B: 47%

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Rx-ID: 27050639 Find similar reactions

With cyclohexanol in 1,2-dichloro-ethane

byproducts: BF3-pyridine complex, H2O; under Ar addn. of BF3*Et2O to mixt. of alcohol and complex in (CH2)2Cl2, further addn. of BF3*Et2O, heating in 60°C oil bath for 20 min,addn. 1 drop of pyridine in hexane, removing BF3-pyridine complex pptd.; solvent removing in vac., addn. of petroleum ether to resulting oil, filtration, drying under Ar;

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Tovrog,Benjamin S.; Diamond, Steven E.; Mares, Frank; Szalkiewicz, Andrew

Journal of the American Chemical Society, 1981 , vol. 103, # 12 p. 3522 - 3526 Title/Abstract Full Text View citing articles Show Details

1122 Synthesize Find similar

A: 17% B: 45%

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Rx-ID: 27127461 Find similar reactions

Tatsumi, T.; Tominaga, H.; Hidai, M.; Uchida, Y.

Journal of Organometallic Chemistry, 1981 , vol. 215, # 1 p. 67 - 76 Title/Abstract Full Text View citing articles Show Details

in benzene

refluxed under nitrogen for 15 min; cooling, addn. of n-hexane, ppt. filtered, washed with n-hexane;

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1123 Synthesize Find similar

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Rx-ID: 1515129 Find similar reactions

Bauduin, G.; Bondon, D.; Pietrasanta, Y.; Pucci, B.

Tetrahedron, 1980 , vol. 36, # 2 p. 245 - 254 Title/Abstract Full Text View citing articles Show Details

Product distribution;

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1124 Synthesize Find similar

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Rx-ID: 1517979 Find similar reactions

Bauduin, G.; Bondon, D.; Pietrasanta, Y.; Pucci, B.

Tetrahedron, 1980 , vol. 36, # 2 p. 245 - 254 Title/Abstract Full Text View citing articles Show Details

Product distribution;

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1125 Synthesize Find similar

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Rx-ID: 1517983 Find similar reactions

Bauduin, G.; Bondon, D.; Pietrasanta, Y.; Pucci, B.

Tetrahedron, 1980 , vol. 36, # 2 p. 245 - 254 Title/Abstract Full Text View citing articles Show Details

Product distribution;

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1126 Synthesize Find similar

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Rx-ID: 1517994 Find similar reactions

B: 40%

in tetrahydrofuran

1 h; Ambient temperatureother reaction time; Product distribution;

Cussans, Nigel J.; Ley, Steven V.; Barton, Derek H. R.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 1654 - 1657 Title/Abstract Full Text View citing articles Show Details

B: 40%

in tetrahydrofuran

1 h; Ambient temperature;

Cussans, Nigel J.; Ley, Steven V.; Barton, Derek H. R.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 1654 - 1657 Title/Abstract Full Text View citing articles

Show Details

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1127 Synthesize Find similar

Rx-ID: 1533408 Find similar reactions

With tri(4-methylphenyl)amine

electrochemical oxidation; Yield given. Multistep reaction. Title compound not separated from byproducts;

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Platen, Martin; Steckhan, Eberhard

Tetrahedron Letters, 1980 , vol. 21, p. 511 - 514 Title/Abstract Full Text View citing articles Show Details

1128 Synthesize Find similar

Rx-ID: 1550186 Find similar reactions

A: 22% B: 78%

With sulfuric acid; sodium iodide in 1,4-dioxane; water

2 h; Heating;

Gemal, A.L.; Luche, J.L.

Tetrahedron Letters, 1980 , vol. 21, p. 3195 - 3198 Title/Abstract Full Text View citing articles Show Details

A: 22% B: 78%

With sulfuric acid; sodium iodide in 1,4-dioxane; water

2 h; Heating;

Gemal, A.L.; Luche, J.L.

Tetrahedron Letters, 1980 , vol. 21, p. 3195 - 3198 Title/Abstract Full Text View citing articles Show Details

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1129 Synthesize Find similar

Rx-ID: 1564311 Find similar reactions

With pyridinium p-toluenesulfonate in water

T=100°C; 5 h; Variation of dioxolanne.; Product distribution;

Thuy, Vu Moc; Petit, Huguette; Maitte, Pierre

Bulletin des Societes Chimiques Belges, 1980 , vol. 89, # 9 p. 759 - 762 Title/Abstract Full Text Show Details

With pyridinium p-toluenesulfonate in water

T=100°C; 5 h;

Thuy, Vu Moc; Petit, Huguette; Maitte, Pierre

Bulletin des Societes Chimiques Belges, 1980 , vol. 89, # 9 p. 759 - 762 Title/Abstract Full Text Show Details

1130 Synthesize Find similar

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Rx-ID: 1581946 Find similar reactions

A: 1.9% B: 1.7% C: 38.3% D: 1%

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Tomioka, Hideo; Okuno, Hiroshi; Izawa, Yasuji

Journal of Organic Chemistry, 1980 , vol. 45, # 26 p. 5278 - 5283 Title/Abstract Full Text View citing articles Show Details

Irradiationbenzophenone as sensitizer, var. additives, var. solvents; Product distributionMechanism;

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1131 Synthesize Find similar

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Rx-ID: 1581947 Find similar reactions

A: 3.3% B: 2.5% C: 1% D: 59.3%

in benzene

Irradiationaddition of methanol in the dark after irradiation, nondegassed solvent; Product distributionMechanism;

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Tomioka, Hideo; Okuno, Hiroshi; Izawa, Yasuji

Journal of Organic Chemistry, 1980 , vol. 45, # 26 p. 5278 - 5283 Title/Abstract Full Text View citing articles Show Details

1132 Synthesize Find similar

Rx-ID: 1739606 Find similar reactions

A: 61% B: 30%

With antimony(V) pentachloride in dichloromethane

T=20°C; 0.75 h;

Miura, Masahiro; Nojima, Masamoto; Kusabayashi, Shigekazu

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 1950 - 1954 Title/Abstract Full Text View citing articles Show Details

A: 61% B: 30%

With antimony(V) pentachloride in dichloromethane

T=20°C; 0.75 h;

Miura, Masahiro; Nojima, Masamoto; Kusabayashi, Shigekazu

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 1950 - 1954 Title/Abstract Full Text View citing articles Show Details

1133 Synthesize Find similar

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Rx-ID: 1801004 Find similar reactions

With perchloric acid in ethanol

mechanism, energy and entropy of activation; Rate constantKineticsThermodynamic data;

Ganapathy, K.; Kumarachakravarthy, T.; Vijayan, B.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1980 , vol. 19, # 1 p. 76 77 Title/Abstract Full Text Show Details

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1134 Synthesize Find similar Rx-ID: 1815546 Find similar reactions

With hydrogen; palladium in tert-butyl alcohol

T=30°C; further catalyst, deuterium labelling experiment; Product distributionMechanism;

Teratani, Shousuke; Chihara, Teiji

Chemistry Letters, 1980 , p. 807 - 808 Title/Abstract Full Text Show Details

With hydrogen; palladium in tert-butyl alcohol

T=30°C; Yield given. Yields of byproduct given;

Teratani, Shousuke; Chihara, Teiji

Chemistry Letters, 1980 , p. 807 - 808 Title/Abstract Full Text Show Details

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1135 Synthesize Find similar Rx-ID: 1826076 Find similar reactions

A: 2.8 % Chromat. B: 73.1 % Chromat. C: 5.4 % Chromat. D: 3.6 % Chromat.

With aluminum oxide; monoaluminum phosphate in benzene

T=320°C; Further byproducts given;

1136

Costa, A.; Deya, P.M.; Sinisterra, J.V.; Marinas, J.M.

Canadian Journal of Chemistry, 1980 , vol. 58, p. 1266 1270 Title/Abstract Full Text Show Details

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Rx-ID: 1854792 Find similar reactions

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T=24.9°C; 0.833333 h; Irradiationvar. wavelenghts, var. reaction time; Product distributionMechanismQuantum yield;

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Marciniak, Bronislaw; Paszyc, Stefan

Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, 1980 , vol. 28, # 7-8 p. 473 - 480 Title/Abstract Full Text Show Details

1137 Synthesize Find similar

Rx-ID: 1936740 Find similar reactions

A: 19.6% B: 3.2% C: 30.9%

With 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in cyclohexane

T=70°C; Title compound not separated from byproducts;

Walsh Jr.; Messinger II; Grudoski; Allchin

Tetrahedron Letters, 1980 , vol. 21, # 46 p. 4409 - 4412 Title/Abstract Full Text View citing articles Show Details

A: 19.6% B: 3.2% C: 30.9%

With 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in cyclohexane

T=70°C; Title compound not separated from byproducts;

Walsh Jr.; Messinger II; Grudoski; Allchin

Tetrahedron Letters, 1980 , vol. 21, # 46 p. 4409 - 4412 Title/Abstract Full Text View citing articles Show Details

A: 19.6% B: 3.2% C: 30.9%

With 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in cyclohexane

T=70°C; other solvents, temperatures and concentrations; Mechanism;

Walsh Jr.; Messinger II; Grudoski; Allchin

Tetrahedron Letters, 1980 , vol. 21, # 46 p. 4409 - 4412 Title/Abstract Full Text View citing articles Show Details

Hide Details

A: 19.6% B: 3.2% C: 30.9%

With 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in cyclohexane

T=70°C; Title compound not separated from byproducts;

Walsh Jr.; Messinger II; Grudoski; Allchin

Tetrahedron Letters, 1980 , vol. 21, # 46 p. 4409 - 4412 Title/Abstract Full Text View citing articles Show Details

1138 Synthesize Find similar

100%

1139

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Rx-ID: 1980606 Find similar reactions

With copper(II) sulfate in tetrahydrofuran; methanol; water

2 h; Heating;

Attanasi, Orazio; Gasperoni, Simonetta; Carletti, Claudio

Journal fuer Praktische Chemie (Leipzig), 1980 , vol. 322, # 6 p. 1063 - 1066 Title/Abstract Full Text Show Details

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Rx-ID: 1982208 Find similar reactions

Encinas, Maria V.; Scaiano, Juan C.

Journal of the Chemical Society, Perkin Transactions 2, 1980 , # 1 p. 56 - 60 Title/Abstract Full Text View citing articles Show Details

in water; acetonitrile

Ambient temperatureIrradiationother solvents; Quantum yieldMechanism;

1140 Synthesize Find similar

Synthesize Find similar

Rx-ID: 1988349 Find similar reactions

Encinas, Maria V.; Scaiano, Juan C.

Journal of the Chemical Society, Perkin Transactions 2, 1980 , # 1 p. 56 - 60 Title/Abstract Full Text View citing articles Show Details

in water; acetonitrile

Ambient temperatureIrradiationother solvents; Quantum yield;

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1141 Synthesize Find similar

A: 1% B: 4%

Rx-ID: 1993358 Find similar reactions

With methanol; cesium fluoride

T=65°C; 72 h;

Mitsuo, Naoki; Abe, Yoshihiro; Takizawa, Takeo; Kunieda, Takehisa

Chemical and Pharmaceutical Bulletin, 1980 , vol. 28, # 4 p. 1327 - 1330 Title/Abstract Full Text Show Details

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1142 Synthesize Find similar Rx-ID: 1999526 Find similar reactions

With IMn(tetraphenylporphyrinato); iodosylbenzene in benzene

T=25°C; 5 h; Further byproducts given;

1143

Hill, Craig L.; Schardt, Bruce C.

Journal of the American Chemical Society, 1980 , vol. 102, # 20 p. 6374 - 6375 Title/Abstract Full Text View citing articles Show Details

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A: 32 % Chromat. B: 14 % Chromat. C: 54 % Chromat.

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Rx-ID: 2004089 Find similar reactions

With 3-chloro-benzenecarboperoxoic acid in dichloromethane

T=27°C; 0.133333 h; Product distribution;

Macdonald, Timothy L.; Narasimhan, N.; Burka, Leo T.

Journal of the American Chemical Society, 1980 , vol. 102, # 26 p. 7760 - 7765 Title/Abstract Full Text View citing articles Show Details

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1144 Synthesize Find similar Rx-ID: 2005067 Find similar reactions

With ozone in tetrachloromethane

T=20°C; Kinetics;

Vikhorev, A. A.; Syroezhko, A. M.; Proskuryakov, V. A.; Korotkova, N. P.

Russian Journal of Physical Chemistry, 1980 , vol. 54, # 2 p. 251 - 253 Zhurnal Fizicheskoi Khimii, 1980 , vol. 54, # 2 p. 443 - 447 Title/Abstract Full Text Show Details

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1145 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2006028 Find similar reactions

Schulz, Manfred; Missol, Udo

Journal fuer Praktische Chemie (Leipzig), 1980 , vol. 322, # 3 p. 417 - 422 Title/Abstract Full Text Show Details

T=80°C; other temp., energy data: activation energy, δH(excit.), ΔS(excit.); Product distributionMechanismRate constant;

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1146 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2006030 Find similar reactions

T=70°C; energy data: activation energy, ΔS(excit.), ΔH(excit.); other temp., var. solvents; Product distributionMechanismRate constant;

Schulz, Manfred; Missol, Udo

Journal fuer Praktische Chemie (Leipzig), 1980 , vol. 322, # 3 p. 417 - 422 Title/Abstract Full Text Show Details

1147 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2031097 Find similar reactions

B: 8% C: 63%

With potassium hydroxide in water

T=0°C; 10 h;

Reeve, Wilkins; McKee, James R.; Brown, Robert; Lakshmanan, Sitarama; McKee, Gertrude A.

Canadian Journal of Chemistry, 1980 , vol. 58, p. 485 - 493 Title/Abstract Full Text Show Details

B: 8% C: 63%

With potassium hydroxide in water

T=0°C; 10 h;

Reeve, Wilkins; McKee, James R.; Brown, Robert; Lakshmanan, Sitarama; McKee, Gertrude A.

Canadian Journal of Chemistry, 1980 , vol. 58, p. 485 - 493 Title/Abstract Full Text Show Details

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1148 Synthesize Find similar Rx-ID: 2033320 Find similar reactions

With di-tert-butyl peroxide

T=120°C; rates of product formation and kinetic parameters of fragmentation in homolytic liquid-phase reaction; MechanismRate constantKinetics;

Imashev, U. B.; Kalashnikov, S. M.; Zlot-skii, S. S.; Karakhanov, R. A.; Rakhmankulov, D. L.

Doklady Chemistry, 1980 , vol. 250, p. 34 - 36 Dokl. Akad. Nauk SSSR Ser. Khim., 1980 , vol. 250, # 3 p. 630 - 632 Title/Abstract Full Text Show Details

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1149 Synthesize Find similar Rx-ID: 2033321 Find similar reactions

With di-tert-butyl peroxide

T=130°C; other temperatures.; Product distributionRate constantMechanism;

1150 Synthesize

Synthesize

Rx-ID: 2040427

Kalashnikov, S. M.; Imashev, U. B.; Zlot-skii, S. S.; Rakhmankulov, D. L.

J. Gen. Chem. USSR (Engl. Transl.), 1980 , vol. 50, # 12 p. 2798 - 2802,2267 - 2271 Title/Abstract Full Text Show Details

Find similar

92%

Find similar

Find similar reactions

With ammonium cerium(IV) nitrate in water; acetonitrile

T=25°C; 0.0833333 h;

Olah, George A.; Gupta, B. G. Balaram

Synthesis, 1980 , # 1 p. 44 - 45 Title/Abstract Full Text Show Details

1151 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2060857 Find similar reactions

Encinas, Maria V.; Scaiano, Juan C.

Journal of the Chemical Society, Perkin Transactions 2, 1980 , # 1 p. 56 - 60 Title/Abstract Full Text View citing articles Show Details

in water; acetonitrile

Ambient temperatureIrradiationother solvents; Quantum yield;

Synthesize Find similar

1152 Synthesize Find similar

Rx-ID: 2068874 Find similar reactions

With lead(IV) acetate in acetic acid

Kirk, David N.; Slade, Christopher J.

Tetrahedron Letters, 1980 , vol. 21, p. 651 - 654 Title/Abstract Full Text View citing articles Show Details

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1153 Synthesize Find similar

Rx-ID: 2113994 Find similar reactions

With hydrogen; palladium in tert-butyl alcohol

T=30°C; Yield given. Yields of byproduct given;

Teratani, Shousuke; Chihara, Teiji

Chemistry Letters, 1980 , p. 807 - 808 Title/Abstract Full Text Show Details

With hydrogen; palladium in tert-butyl alcohol

T=30°C; further catalyst, further 4-substituted cyclohexanone; Product distribution;

Teratani, Shousuke; Chihara, Teiji

Chemistry Letters, 1980 , p. 807 - 808 Title/Abstract Full Text Show Details

1154 Synthesize

Find similar Rx-ID: 2328783 Find similar reactions

A: 5 % Chromat. B: 14 % Chromat. C: 48 % Chromat. D: 19 % Chromat. E: 2 % Chromat.

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With magnesium oxide; silica gel; Titanium(IV) oxide in toluene

T=108°C; 2 h; other epoxide, var. acidic and basic catalysts, var. time; Product distribution;

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Arata, Kazushi; Tanabe, Kozo

Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 2 p. 299 - 303 Title/Abstract Full Text Show Details

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1155 Synthesize Find similar Rx-ID: 2328785 Find similar reactions

A: 15 % Chromat. B: 15 % Chromat. C: 5 % Chromat. D: 65 % Chromat.

With hydrogen; palladium on activated charcoal in ethanol

T=20°C; P=760 Torr; 1 h; various solvents; MechanismProduct distribution;

Accrombessi, Georges C.; Geneste, Patrick; Olive, Jean-Louis; Pavia, Andre A.

Journal of Organic Chemistry, 1980 , vol. 45, # 21 p. 4139 - 4143 Title/Abstract Full Text View citing articles Show Details

1156 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2531201 Find similar reactions

T=56 - 77°C; chemiluminescence with or whitout fluorescer, yield of singlet and triplet ketones, Echl, Ea, log A; KineticsThermodynamic data;

Bechara, Etelvino J. H.; Wilson, Therese

Journal of Organic Chemistry, 1980 , vol. 45, # 26 p. 5261 - 5268 Title/Abstract Full Text View citing articles Show Details

1157 Synthesize Find similar

10%

Synthesize Find similar

Rx-ID: 2533562 Find similar reactions

With NOBF4 in acetonitrile

T=0°C; 0.0833333 h; various other β-azido tertiary alcohols; Product distribution;

Lorenzin, Michele; Guerriero, Antonio; Pietra, Francesco

Journal of Organic Chemistry, 1980 , vol. 45, # 9 p. 1704 1705 Title/Abstract Full Text View citing articles Show Details

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1158 Synthesize Find similar

A: 35% B: 10%

Rx-ID: 2539159 Find similar reactions

With potassium tert-butylate; tert-butyl alcohol

336 h; Ambient temperature;

Goldmann, Siegfried

Synthesis, 1980 , # 8 p. 640 - 642 Title/Abstract Full Text Show Details

1159 Synthesize Find similar

Synthesize Find similar

Rx-ID: 2541818 Find similar reactions

With hydrogenchloride in tetrahydrofuran

2 h; Ambient temperature;

Broekhof, N. L. J. M.; Jonkers, F. L.; Gen, A. van der

Tetrahedron Letters, 1980 , vol. 21, p. 2671 - 2674 Title/Abstract Full Text View citing articles Show Details

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1160 Synthesize Find similar

A: 66% B: 10%

Rx-ID: 2542093 Find similar reactions

With potassium tert-butylate; tert-butyl alcohol

336 h; Ambient temperature;

Goldmann, Siegfried

Synthesis, 1980 , # 8 p. 640 - 642 Title/Abstract Full Text Show Details

Synthesize Find similar

1161 Synthesize Find similar

A: 40% B: 10%

With potassium tert-butylate; tert-butyl alcohol

336 h; Ambient temperature;

Rx-ID: 2551382 Find similar reactions

Goldmann, Siegfried

Synthesis, 1980 , # 8 p. 640 - 642 Title/Abstract Full Text Show Details

1162 Synthesize Find similar

A: 62% B: 10%

Synthesize Find similar

Rx-ID: 2563570 Find similar reactions

With potassium tert-butylate; tert-butyl alcohol

336 h; Ambient temperature;

Goldmann, Siegfried

Synthesis, 1980 , # 8 p. 640 - 642 Title/Abstract Full Text Show Details

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1163 Synthesize Find similar

A: 50%

Rx-ID: 2990751 Find similar reactions

Arnould, J.C.; Cossy, J.; Pete, J.P.

Tetrahedron, 1980 , vol. 36, p. 1585 - 1592 Title/Abstract Full Text View citing articles Show Details

in diethyl ether

4 h; Irradiation; Product distribution;

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1164 Synthesize Find similar

B: 1.3 g

Rx-ID: 3052330 Find similar reactions

With lead(IV) acetate

T=20°C; 0.5 h;

Cole, Edward R.; Crank, George; Minh, H. T. Hai

Australian Journal of Chemistry, 1980 , vol. 33, # 3 p. 527 543 Title/Abstract Full Text Show Details

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1165 Synthesize Find similar Rx-ID: 3077693 Find similar reactions

A: 5% B: 44% C: 3% D: 17%

Feld, W. A.; Serve, M. P.

Journal of Heterocyclic Chemistry, 1980 , vol. 17, p. 825 827 Title/Abstract Full Text Show Details

in methanol

12 h; Irradiationphotolysis in presence of sensitizer, photolysis in methanol-d4 for 6 h; Product distributionMechanism;

1166 Synthesize Find similar Rx-ID: 3077694 Find similar reactions

A: 5% B: 5% C: 8% D: 40% E: 4% F: 12%

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Feld, W. A.; Serve, M. P.

Journal of Heterocyclic Chemistry, 1980 , vol. 17, p. 825 827 Title/Abstract Full Text Show Details

in cyclohexane

12 h; Irradiation; Product distributionMechanism;

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1167 Synthesize Find similar

A: 43% B: 4% C: 20%

Rx-ID: 3077695 Find similar reactions

Feld, W. A.; Serve, M. P.

Journal of Heterocyclic Chemistry, 1980 , vol. 17, p. 825 827 Title/Abstract Full Text Show Details

in acetonitrile

12 h; Irradiationphotolysis in presence of sensitizer; Product distributionMechanism;

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1168 Synthesize Find similar

A: 38%

Synthesize Find similar

Rx-ID: 3127442 Find similar reactions

With potassium carbonate

T=90°C; 5 h; Product distribution;

Yoneda, Fumio; Tsukuda, Kinshiro; Shinozuka, Kazuo; Hirayama, Fumitoshi; Uekama, Kaneto; Koshiro, Akira

Chemical and Pharmaceutical Bulletin, 1980 , vol. 28, # 10 p. 3049 - 3056 Title/Abstract Full Text Show Details

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1169 Synthesize Find similar

A: 65%

Synthesize Find similar

T=90°C; 5 h; Rate constant;

Rx-ID: 3150971 Find similar reactions

Yoneda, Fumio; Tsukuda, Kinshiro; Shinozuka, Kazuo; Hirayama, Fumitoshi; Uekama, Kaneto; Koshiro, Akira

Chemical and Pharmaceutical Bulletin, 1980 , vol. 28, # 10 p. 3049 - 3056 Title/Abstract Full Text Show Details

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1170 Synthesize Find similar

A: 10% B: 75%

Rx-ID: 3275188 Find similar reactions

With hydrogenchloride in ethanol

0.05 h; Heating; Product distribution;

Gubnitskaya, E. S.; Parkhomenko, V. S.

J. Gen. Chem. USSR (Engl. Transl.), 1980 , vol. 50, # 7 p. 1502 - 1506,1213 - 1217 Title/Abstract Full Text Show Details

1171 Synthesize Find similar

Synthesize Find similar

Rx-ID: 3611008 Find similar reactions

With sodium hydrogencarbonate in diethyl ether

4 h; Yield given;

Tanaka, Kazuhiko; Matsui, Syuichi; Kaji, Aritsune

Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 12 p. 3619 - 3622 Title/Abstract Full Text Show Details

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1172 Synthesize Find similar Rx-ID: 3788766 Find similar reactions

A: 44 % Chromat. B: 17 % Chromat. C: 20 % Chromat. D: 20 % Chromat.

With oxygen

T=60°C; P=759.8 Torr;

Blau, K.; Mueller, U.; Pritzkow, W.; Schmidt-Renner, W.; Sedshaw, Z.

Journal fuer Praktische Chemie (Leipzig), 1980 , vol. 322, # 6 p. 915 - 932 Title/Abstract Full Text Show Details

A: 44 % Chromat. B: 17 % Chromat. C: 20 % Chromat. D: 20 % Chromat.

With oxygen

T=60°C; P=759.8 Torr;

Blau, K.; Mueller, U.; Pritzkow, W.; Schmidt-Renner, W.; Sedshaw, Z.

Journal fuer Praktische Chemie (Leipzig), 1980 , vol. 322, # 6 p. 915 - 932 Title/Abstract Full Text Show Details

With oxygen

T=60°C; P=759.8 Torr; Mechanism;

Blau, K.; Mueller, U.; Pritzkow, W.; Schmidt-Renner, W.; Sedshaw, Z.

Journal fuer Praktische Chemie (Leipzig), 1980 , vol. 322, # 6 p. 915 - 932 Title/Abstract Full Text Show Details

Hide Details

A: 44 % Chromat. B: 17 % Chromat. C: 20 % Chromat. D: 20 % Chromat.

With oxygen

T=60°C; P=759.8 Torr; Title compound not separated from byproducts;

Blau, K.; Mueller, U.; Pritzkow, W.; Schmidt-Renner, W.; Sedshaw, Z.

Journal fuer Praktische Chemie (Leipzig), 1980 , vol. 322, # 6 p. 915 - 932 Title/Abstract Full Text Show Details

A: 44 % Chromat. B: 17 % Chromat. C: 20 % Chromat. D: 20 % Chromat.

With oxygen

T=60°C; P=759.8 Torr; Title compound not separated from byproducts;

Blau, K.; Mueller, U.; Pritzkow, W.; Schmidt-Renner, W.; Sedshaw, Z.

Journal fuer Praktische Chemie (Leipzig), 1980 , vol. 322, # 6 p. 915 - 932 Title/Abstract Full Text Show Details

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1173 Synthesize Find similar Rx-ID: 3796245 Find similar reactions

With hydrogen; palladium in tert-butyl alcohol

T=30°C; further catalyst; Product distribution;

Teratani, Shousuke; Chihara, Teiji

Chemistry Letters, 1980 , p. 807 - 808 Title/Abstract Full Text Show Details

With hydrogen; palladium in tert-butyl alcohol

T=30°C; Yield given. Yields of byproduct given;

Teratani, Shousuke; Chihara, Teiji

Chemistry Letters, 1980 , p. 807 - 808 Title/Abstract Full Text Show Details

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1174 Synthesize Find similar

Zajc, Barbara; Zupan, Marko

Journal of the Chemical Society, Chemical Communications, 1980 , # 16 p. 759 - 760 Title/Abstract Full Text View citing articles Show Details

With XeF2; hydrogen fluoride

Ambient temperature; Yield given. Yields of byproduct given;

1175

Rx-ID: 3843404 Find similar reactions

Synthesize Find similar

B: 90%

Synthesize Find similar

Rx-ID: 3855971 Find similar reactions

Doleschall, Gabor; Toth, Gabor

Tetrahedron, 1980 , vol. 36, p. 1649 - 1666 Title/Abstract Full Text View citing articles Show Details

in chloroform

24 h; Ambient temperature;

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1176 Synthesize Find similar

A: 76%

Synthesize Find similar

Rx-ID: 3855979 Find similar reactions

Yoneda, Fumio; Tsukuda, Kinshiro; Shinozuka, Kazuo; Hirayama, Fumitoshi; Uekama, Kaneto; Koshiro, Akira

Chemical and Pharmaceutical Bulletin, 1980 , vol. 28, # 10 p. 3049 - 3056 Title/Abstract Full Text Show Details

T=90°C; 5 h; Product distribution;

Synthesize Find similar

1177 Synthesize Find similar

A: 16%

Synthesize Find similar

Rx-ID: 3856015 Find similar reactions

Yoneda, Fumio; Tsukuda, Kinshiro; Shinozuka, Kazuo; Hirayama, Fumitoshi; Uekama, Kaneto; Koshiro, Akira

Chemical and Pharmaceutical Bulletin, 1980 , vol. 28, # 10 p. 3049 - 3056 Title/Abstract Full Text Show Details

T=90°C; 5 h; Product distribution;

1178 Synthesize Find similar

Synthesize Find similar

Rx-ID: 18846577 Find similar reactions

Multi-step reaction with 2 steps 1: aq. HCl / 1 h 2: aq. NaHCO3 / diethyl ether / 4 h View Scheme

Tanaka, Kazuhiko; Matsui, Syuichi; Kaji, Aritsune

Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 12 p. 3619 - 3622 Title/Abstract Full Text Show Details

1179 Synthesize Find similar

Synthesize Find similar

Rx-ID: 20442643 Find similar reactions

Multi-step reaction with 3 steps 1: 73 percent / LiAlH4 / diethyl ether / 2 h / Heating 2: 92 percent / p-toluenesulfonic acid / toluene / 6 h / Heating 3: lead tetraacetate / 0.5 h / 20 °C View Scheme

Cole, Edward R.; Crank, George; Minh, H. T. Hai

Australian Journal of Chemistry, 1980 , vol. 33, # 3 p. 527 543 Title/Abstract Full Text Show Details

1180 Synthesize Find similar

Synthesize Find similar

Rx-ID: 20442853 Find similar reactions

Multi-step reaction with 2 steps 1: 92 percent / p-toluenesulfonic acid / toluene / 6 h / Heating 2: lead tetraacetate / 0.5 h / 20 °C View Scheme

Cole, Edward R.; Crank, George; Minh, H. T. Hai

Australian Journal of Chemistry, 1980 , vol. 33, # 3 p. 527 543 Title/Abstract Full Text Show Details

1181 Synthesize Find similar

Synthesize Find similar

Rx-ID: 20443815 Find similar reactions

Multi-step reaction with 4 steps 1: 20 mg / lead tetraacetate / 1 h / 20 °C 2: 73 percent / LiAlH4 / diethyl ether / 2 h / Heating 3: 92 percent / p-toluenesulfonic acid / toluene / 6 h / Heating 4: lead tetraacetate / 0.5 h / 20 °C View Scheme

Cole, Edward R.; Crank, George; Minh, H. T. Hai

Australian Journal of Chemistry, 1980 , vol. 33, # 3 p. 527 543 Title/Abstract Full Text Show Details

1182 Synthesize Find similar

Synthesize Find similar

Rx-ID: 20462848 Find similar reactions

Multi-step reaction with 4 steps 1: 0.7 g / lead tetraacetate / acetic acid / 10 h / 80 °C 2: 73 percent / LiAlH4 / diethyl ether / 2 h / Heating 3: 92 percent / p-toluenesulfonic acid / toluene / 6 h / Heating 4: lead tetraacetate / 0.5 h / 20 °C View Scheme

1183 Synthesize Find similar

Synthesize Find similar

Rx-ID: 20628485 Find similar reactions

Cole, Edward R.; Crank, George; Minh, H. T. Hai

Australian Journal of Chemistry, 1980 , vol. 33, # 3 p. 527 543 Title/Abstract Full Text Show Details

Multi-step reaction with 2 steps 1: 40 percent / cumenhydroperoxide / Fe(TTP)Cl / benzene / 0.25 h / 20 °C / t1/2, further metalloporphyrin-cat. and TPPH2, (also tBuOOH, C6H5IO) 2: 15 percent / cumenhydroperoxide / Fe(TTP)Cl / benzene / 20 °C View Scheme

Mansuy, Daniel; Bartoli, Jean-Francois; Chottard, JeanClaude; Lange, Marc

Angewandte Chemie, 1980 , vol. 92, # 11 p. 938 - 939 Title/Abstract Full Text Show Details

1184 Synthesize Find similar

Synthesize Find similar

Rx-ID: 21196586 Find similar reactions

Multi-step reaction with 2 steps 1: 1. Diisopropylamin, 15percent Butyllithium/Hexan / - 78 deg C, 10 min., THF 2: 10 percent / 1M tert-BuOK/tert-BuOH / 336 h / Ambient temperature View Scheme

Goldmann, Siegfried

Synthesis, 1980 , # 8 p. 640 - 642 Title/Abstract Full Text Show Details

1185 Synthesize Find similar

Synthesize Find similar

Rx-ID: 21199570 Find similar reactions

Multi-step reaction with 2 steps 1: 1. Diisopropylamin, 15percent Butyllithium/Hexan / - 78 deg C, 10 min., THF 2: 10 percent / 1M tert-BuOK/tert-BuOH / 336 h / Ambient temperature View Scheme

Goldmann, Siegfried

Synthesis, 1980 , # 8 p. 640 - 642 Title/Abstract Full Text Show Details

Multi-step reaction with 2 steps 1: 1. Diisopropylamin, 15percent Butyllithium/Hexan / - 78 deg C, 10 min., THF 2: 10 percent / 1M tert-BuOK/tert-BuOH / 336 h / Ambient temperature View Scheme

Goldmann, Siegfried

Synthesis, 1980 , # 8 p. 640 - 642 Title/Abstract Full Text Show Details

Multi-step reaction with 2 steps 1: 1. Diisopropylamin, 15percent Butyllithium/Hexan / - 78 deg C, 10 min., THF 2: 10 percent / 1M tert-BuOK/tert-BuOH / 336 h / Ambient temperature View Scheme

Goldmann, Siegfried

Synthesis, 1980 , # 8 p. 640 - 642 Title/Abstract Full Text Show Details

1186 Synthesize Find similar

Synthesize Find similar

Hide Experimental Procedure

11:EXAMPLE 11

EXAMPLE 11 The process is carried out as in Example 1, but using 32 g of methyl acrylate instead of the acrylonitrile. The reaction mixture is extracted with ethyl acetate. The following are obtained from the extract: methyl semiester of 1,9-nonadionic acid 13.8 g

Rx-ID: 25402670 Find similar reactions

Brichima S.p.A.

Patent: US4217290 A1, 1980 ; Title/Abstract Full Text Show Details

methyl diester of 1,11-undecandioic acid 6.6 g Yield with respect to H2 O2 58.1percent. Yield with respect to cyclohexanone 44.6percent.

1187 Synthesize Find similar Rx-ID: 25404156 Find similar reactions

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Brichima S.p.A.

Patent: US4217290 A1, 1980 ;

Hide Experimental Procedure

Title/Abstract Full Text Show Details

1:EXAMPLE 1

The residue is extracted with ether, and the acid part is separated from the neutral part by a 10percent soda solution. The acid part consists of two products: 7 g of hexanoic acid which are separated by distillation, and 14.5 g of 8-cyano-octanoic acid. The neutral product consists of 7 g of 1,9-dicyanononane. Yield of useful products with respect to H2 O2 80percent. Yield with respect to cyclohexanone 72percent.

1188 Synthesize Find similar 55%

Synthesize Find similar

Rx-ID: 25336069 Find similar reactions

With hydrogenchloride; triethylamine in chloroform

Hide Experimental Procedure

Science Union et Cie, Societe Francaise de Recherche Medicale

Patent: US4154851 A1, 1979 ; Title/Abstract Full Text Show Details

1.B:Step B To solution of 16.7g 1-morpholino cyclohex -1 ene in 45 ml chloroform, 10.1g of triethylamine are added. Over a period of one hour a solution of 13.4g of isocaproyl chloride in 15 ml chloroform is added, with stirring. The mixture is stirred for two hours at room temperature and is thereafter heated at 60° for 3 hours. It is kept aside for a night, then 150 ml hydrochloric acid are added. The mixture is shaken and is then allowed to settle. The chloroformic phase is discarded. The aqueous phase is partially neutralized with sodium carbonate until the ph value reaches 6 and is then extracted with chloroform three times. The organic phases are united, washed with water, dried over sodium sulphate, filtered and evaporated to dryness. The crude residue weighing 20.1g, is purified by distillation under reduced pressure, 10.3g of the pure cyclohexanone are recovered (Yield 55percent). 2-(4'-methyl valeryl) cyclohexanone is a liquid boiling under 0.3mm at 96 to 100°. ND25 = 1.4895