Boron tribromide (Tribromoborane) [BBr3] by Asch

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73 reactions in Reaxys

2018-07-08 00h:39m:20s (UTC)

Br B

1. Query

Search as: Product, As drawn, No mixtures ) AND (IDE.RN='10294-33-4') AND (IDE.INCHI='ILAHWRKJUDSMFHUHFFFAOYSA-N') NOT (RX.RXRN=3903058))

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Br B

Rx-ID: 26086819 View in Reaxys 1/73 Yield >=70%

Conditions & References boron is mixed with ca. 9 w percent Mg, in H2 atmosphere Bartal, von; Liebigs Annalen der Chemie; vol. 345; (1906); p. 338 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys

57.6 %

in not given, kept over liq. Hg for 48 h; distd. (vac., room temp.) Timoshkin, Alexey Y.; Kazakov, Igor V.; Lisovenko, Anna S.; Bodensteiner, Michael; Scheer, Manfred; Inorganic Chemistry; vol. 50; nb. 18; (2011); p. 9039 - 9044 ; (from Gmelin) View in Reaxys

40%

at red heat; in H2 atmosphere Michaelis; Richter, E.; Liebigs Annalen der Chemie; vol. 315; (1901); p. 26 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys at 700 °C; treated with Hg or distn. over Hg Moissan; Ann. Chim. Phys.; vol. 6; nb. 7; (1895); p. 312 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys

With iodine, addn. of B to boiling Br2 Gamble, E. L.; Gilmont, P.; Stiff, J. F.; Journal of the American Chemical Society; vol. 62; (1940); p. 1257 - 1258 ; (from Gmelin) View in Reaxys

With aluminium trichloride, addn. of B to boiling Br2 Gamble, E. L.; Gilmont, P.; Stiff, J. F.; Journal of the American Chemical Society; vol. 62; (1940); p. 1257 - 1258 ; (from Gmelin) View in Reaxys

With iron(III) chloride, addn. of B to boiling Br2 Gamble, E. L.; Gilmont, P.; Stiff, J. F.; Journal of the American Chemical Society; vol. 62; (1940); p. 1257 - 1258 ; (from Gmelin) View in Reaxys 700°C Cueilleron, J.; Annales de Chimie (Cachan, France); vol. 19; (1944); p. 459 - 486 View in Reaxys KIESSLING; Acta chemica Scandinavica; vol. 2; nb. 8; (1948); p. 707 - 712 ; (from Gmelin) View in Reaxys B (prepared by the method of Moissan) is heated in Br2 vapour at red heat previously; shaken with Hg, fractional distn. Stock; Kuss; Ber.; vol. 47; (1914); p. 3113 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys dried (prepared by the method of Moissan) B is heated at 600-700 °C in Br2 vapour in H2 or N2 atmosphere; condensation, addn. of Cu-bronze, distn. over B

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Meyer, F.; Zappner; Ber.; vol. 54; (1921); p. 551 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys reacton of B (prepared by the method of Moissan) with Br vapour ( diluted with He); shaken with Hg, fractional distn. in vacuo Baxter; Scott; Proc. Am. Acad. Arts Sci.; vol. 59; (1923); p. 21 View in Reaxys Baxter; Scott; Science (Washington, DC, United States); vol. 54; (1921); p. 524 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys at 700 °C; treated with Hg or distn. over Hg Moissan; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 114; (1892); p. 617 ; (from Gmelin) View in Reaxys 0%

With iron(III) chloride, addn. of B to boiling Br2 vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys

With iodine, addn. of B to boiling Br2 vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys

With aluminium trichloride, addn. of B to boiling Br2 vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys 700°C vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys Br B

Rx-ID: 23935763 View in Reaxys 2/73 Yield 50%

Conditions & References 5.c : EXAMPLE 5 Ethyl 2-(3-chloro-4-hydroxyphenylamino)benzoate [I; R and R'=H, R"=3-Cl, Alk=C2 H5, OH at 4-position] was prepared by reaction of ethyl 2-(3-chloro-4-methoxyphenylamino)benzoate with boron tribromide according to the procedure of Example 1, part (d), and was obtained in about 50percent yield as a pale yellow solid, m.p. 87°-88° C. when recrystallized from cyclohexane. Patent; Sterling Drug Inc.; US4515980; (1985); (A) English View in Reaxys

38%

2.b : EXAMPLE 2 Ethyl 2-(4-hydroxyphenylamino)benzoate [I; R, R' and R"=H, Alk=C2 H5, OH at 4-position] was prepared by reaction of ethyl 2-(4-methoxyphenylamino)benzoate with boron tribromide according to the procedure of Example 1, part (d), and was obtained in 38percent yield as a yellow solid, m.p. 103°-104° C. when recrystallized from aqueous ethanol. Patent; Sterling Drug Inc.; US4515980; (1985); (A) English View in Reaxys Synthetic Procedures Demethylation of 6a with BBr3 produced compound 8. Conversion of amines 7a-b to benzamide derivatives followed by demethylation produced compounds 10a-b.

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Patent; Dutta, Aloke K.; US2003/195219; (2003); (A1) English View in Reaxys 11 : BBr3 hydrolysis Example 11 BBr3 hydrolysis To a solution of 1.0 mmol of substituted 2-[(5-diethylphosphonate)furanyl]benzimidazole in 3 mL of anhydrous CH2 Cl2 was added 10 mmol of 1.0 M BBr3 solution in CH2 Cl2 at -78° C. and the mixture was allowed to warm to room temperature. After 16 h, solvent and excess BBr3 were removed under reduced pressure and the residue was taken into 3 mL of water. The precipitate was filtered, washed with water, and MeOH and was dried under vaccum at 50° C. The following compound was prepared in this manner: 11.1: 4-Amino-5-hydroxy-1-isobutyl-2-(2-phosphono-5-furanyl) benzimidazole. mp=206-209° C.; Anal. Cald. for C15 H18 N3 O5 P+2.7H2 O: C: 45.05; H: 5.90; N: 10.51. Found: C: 44.96; H: 5.78; N: 10.14. Patent; Sankyo Company Ltd.; US6110903; (2000); (A) English View in Reaxys 4 : Reaction of IV A with 0.5 Mol-Equiv of Boron Tribromide EXAMPLE 4 Reaction of IV A with 0.5 Mol-Equiv of Boron Tribromide To an ice-cold solution of the diformate (304 mg, 0.675 mmol), in methylene chloride (5 mL), was added dropwise, with stirring, a solution of boron tribromide (86 mg, 0.34 mmol) in methylene chloride (0.8 mL). Stirring was continued for 1.5 h at 0° C., and the solution was then poured onto ice-cold 5percent sodium bicarbonate. The layers were separated and the aqueous layer was extracted with methylene chloride (3*60 mL). The combined organic layers were washed with brine (3*10 mL), dried (Na2 SO4) and evaporated to a colourless foam (322 mg). This was purified by plc (silica gel, acetone:hexane, 1:4) to give three products. The leading band was IV B (25 mg). The middle band was a 79/21 mixture of IV H and IV I (245 mg, 75percent). Separation and characterization of these two compounds is described in the following example. Patent; Queen's University at Kingston; US4391975; (1983); (A) English View in Reaxys 8.r : (Comparative) (Comparative) Example 9 The polymerization procedures of Example 7 were repeated at a temperature of -40°C. Component concentrations calculated on total polymerization volume were: DTBP: 3x10-3M; BCl3: 0.5M; BBr3: 6.25x10-3M; isobutylene: 1M. Patent; DOW CORNING CORPORATION; UNIVERSITY OF MASSACHUSETTS LOWELL; EP1044226; (2001); (B1) English View in Reaxys 42.1 : 2-Sec-butyl-4-(2,3-dimethyl-naphtho[2,3-b]thiophen-4-yl)-phenol In a manner similar to the procedure of Example 49, Step 1, there was obtained from (2-benzyl-4,5-dimethyl-thiophen-3-yl)-(3sec-butyl-4-methoxy-phenyl)-methanone (6.2 g, 15.8 mmol), boron tribromide (7.1 mL, 74.8 mmol), and methylene chloride (54 mL) the title compound as a solid (2.34 g, 41percent): MS(EI): [M+] 360. Patent; American Home Products Corporation; US6251936; (2001); (B1) English View in Reaxys

Br HBr

B H N

Br S

N O

Rx-ID: 25471078 View in Reaxys 3/73 Yield

Conditions & References 21 : 5-Chloro-8-hydroxy-N-(3-phenylpropyl)-7-quinolinesulfonamide monohydrobromide

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EXAMPLE 21 5-Chloro-8-hydroxy-N-(3-phenylpropyl)-7-quinolinesulfonamide monohydrobromide (Formula J-5 wherein R1=H, X1=Cl, and R2=(CH2)3C6H5) Refer to Chart J. The title compound is prepared from 5-chloro-8-methoxy-N-(3-phenylpropyl)-7-quinolinesulfonamide, which is the title compound of Preparation 11, and 6 equivalents of BBr3 according to the procedure described in Example 18. Crystallization from CHCl3/acetone/EtOH affords 0.063 g of the title compound as a red-brown solid. Physical characteristics are as follows: MP 210-212° C. (decompose). 1H NMR (300 MHz, CDCl ) δ 9.35, 9.18, 8.06, 7.95, 7.27-7.12, 7.11-7.05, 3.16-3.02, 2.63, 1.83 ppm. 3 IR (mull) 3273, 2757, 1626, 1550, 1444, 1353, 1326, 1297, 1281, 1152 cm-1. MS (EI) m/z 376 (M+) 376, 258, 181, 180, 179, 178, 150, 118, 115, 91. HRMS (EI) found 376.0631. Anal found: C, 46.96; H, 4.09; N, 6.08. Patent; Pharmacia and Upjohn Company; US6211376; (2001); (B1) English View in Reaxys Br

(R)-6-(4-Hydroxy-phenyl)-4-r(1-phenyl-ethyl)-amino]-7H-pyrrolo-[2,3-d]pyrimidine

Rx-ID: 24366095 View in Reaxys 4/73 Yield

Conditions & References 39 : (R)-6-(4-Hydroxy-phenyl)-4-r(1-phenyl-ethyl)-amino]-7H-pyrrolo-[2,3-d]pyrimidine EXAMPLE 39 (R)-6-(4-Hydroxy-phenyl)-4-r(1-phenyl-ethyl)-amino]-7H-pyrrolo-[2,3-d]pyrimidine The title compound, in the form of a colorless powder, is obtained analogously to Example 10 by removing the methyl group from (R)-6-(4-methoxy-phenyl)-4-[(1-phenyl-ethyl)-amino]-7H-pyrrolo[2,3-d]pyrimidine with boron tribromide; m.p. 216-218° C.; FAB-MS: (M+H)+ =331. The starting material is prepared as follows: Patent; Novartis AG; US6140332; (2000); (A) English View in Reaxys O O

H N

Br N H

Rx-ID: 24448945 View in Reaxys 5/73 Yield

Conditions & References 54 : Synthesis of 2-Acetamido-N-benzyl-2-(N,N-dimethylamino)acetamide EXAMPLE 54 Synthesis of 2-Acetamido-N-benzyl-2-(N,N-dimethylamino)acetamide By making use of 2-acetamido-N-benzyl-2-ethoxyacetamide (3.00 g, 12.0 mmol), BBr3 (1M in CH2 Cl2, 13.2 mL, 13.2 mmol), and Me2 NH (5-6 equiv) was obtained a brown residue which was purified by flash column chromatography on SiO2 gel (2.5percent MeOH/CHCl3) to give the desired product. Patent; Research Corporation Technologies, Inc.; US5378729; (1995); (A) English View in Reaxys 54 : Synthesis of 2-Acetamido-N-benzyl-2-(N,N-dimethylamino)acetamido. EXAMPLE 54 Synthesis of 2-Acetamido-N-benzyl-2-(N,N-dimethylamino)acetamido. By making use of 2-acetamido-N-benzyl-2-ethoxyacetamide (3.00 g, 12.0 mmol), BBr3 (1M in CH2 Cl2, 13.2 mL, 13.2 mmol), and Me2 NH (5-6 equiv) was obtained a brown residue which was purified by flash column chromatography on SiO2 gel (2.5percent MeOH/CHCl3) to give the desired product. The product was recrystallized from ethyl acetate/hexane to give light yellow cubic crystals. Yield: 1.20 g (40percent).

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Rf 0.39 (5percent MeOH/CHCl3). mp 104°-106° C. H NMR (DMSO-d6) δ 1.91 (s, 3H), 2.11 (s, 6H), 4.22 (dd, J=5.2, 14.7 Hz, 1H), 4.34 (dd, J=6.1, 14.7 Hz, 1H), 5.11 (d, J=8.3 Hz,

1H), 7.23-7.31 (m, 5H), 8.18 (d, J=8.3 Hz, 1H), 8.55 (br s, 1H). C NMR (DMSO-d6) 22.43, 40.33 (2 C), 42.28, 69.42, 126.73, 127.27 (2 C), 128.21(2 C), 139.49, 168.49, 170.31 ppm.

IR (KBr) 3280, 1670 (br), 1500 (br), 1460, 760, 700 cm-1. Mass spectrum 250 (M+ +1). Elemental analysis Calculated for C13 H19 N3 O2 62.63percent C; 7.68percent H; 16.85percent N. Found 62.82percent C; 7.66percent H; 16.69percent N. Patent; Research Corporation Technologies, Inc.; US5654301; (1997); (A) English View in Reaxys

Br B

Rx-ID: 26406281 View in Reaxys 6/73 Yield

Conditions & References

8.6 %

Vac.-distn. of B2Br4 to CBr4, heating in an oil-bath (96°C, 5.75 h).; Monitored by (11)B-NMR. Ahmed, L.; Castillo, J.; Saulys, D. A.; Morrison, J. A.; Inorganic Chemistry; vol. 31; (1992); p. 706 - 710 ; (from Gmelin) View in Reaxys

Br (v4)

PBr BrB

(v4)

BBr BrP

(v4)

Rx-ID: 26948809 View in Reaxys 7/73 Yield

Conditions & References in dodecane, high vac. or inert atmosphere; thermolysis (160°C, 16 h); not isolated, detected by (11)B-NMR spectroscopy Keller, Willi; Sneddon, Larry G.; Einholz, Wolfgang; Gemmler, Armin; Chemische Berichte; vol. 125; nb. 11; (1992); p. 2343 - 2346 ; (from Gmelin) View in Reaxys

(v2)

H H H B H (v4) B (v4) H (v4) (v5) B B (v4) H H H

(v2)

Br B Br (v5) B (v4)H H(v4) B(v4) HB B H (v4)B H H (v2) H H

Br B

(v2)

Br B

Br H

Rx-ID: 26565218 View in Reaxys 8/73 Yield

Conditions & References

80 %

in neat (no solvent), Teflon-valve-equipped standard vacuum line or a nitrogen-filled glovebox;excess B5H9;pentaborane, B2Br4 separately condensed in the reactor, after 20 min at room temp., vessel cooled to -10 ° C,; over course of the following 10 h,all volatile material removed,reactor warmed to room temp.,all volatile material at room temp. were removed,BBr2B5H8 extd. with CH2Cl2, yield:80percent on basis of amt. of B2Br4 employed, 86percent on basis of unrecovered B5H9 Saulys, D. A.; Morrison, J. A.; Inorganic Chemistry; vol. 29; (1990); p. 4174 - 4179 ; (from Gmelin) View in Reaxys

Br B Br (v5) B (v4)H H(v4) B(v4) HB B H (v4)B H H (v2) H H

(v2)

H H H B H (v4) B (v4) H (v4) (v5) B B (v4) H H H

(v2)

Rx-ID: 26649922 View in Reaxys 9/73 Yield

Conditions & References in neat (no solvent), decompn.; also yellow solids formed Saulys, D. A.; Morrison, J. A.; Inorganic Chemistry; vol. 29; (1990); p. 4174 - 4179 ; (from Gmelin)

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View in Reaxys O

Br C H2

Br Br B

B H2 C

Rx-ID: 26750454 View in Reaxys 10/73 Yield

Conditions & References in neat (no solvent), byproducts: B2O3, ClCH2COBr; decompn. reaction immediately Lysenko, Yu. A.; Nevechera, I. V.; Pridat'ko, S. P.; Troshina, E. A.; Journal of General Chemistry USSR (English Translation); vol. 60; (1990); p. 505 - 510; Zhurnal Obshchei Khimii; vol. 60; (1990); p. 578 - 584 ; (from Gmelin) View in Reaxys O Br

N 2

Br Br

Rx-ID: 26750709 View in Reaxys 11/73 Yield

Conditions & References

50 %

in neat (no solvent), byproducts: o-CH3C6H4NO2; decompn. reaction immediately Lysenko, Yu. A.; Nevechera, I. V.; Pridat'ko, S. P.; Troshina, E. A.; Journal of General Chemistry USSR (English Translation); vol. 60; (1990); p. 505 - 510; Zhurnal Obshchei Khimii; vol. 60; (1990); p. 578 - 584 ; (from Gmelin) View in Reaxys Cl

Br Br

O Cl

C H2

Rx-ID: 26751062 View in Reaxys 12/73 Yield

Conditions & References

25 %

in neat (no solvent), byproducts: Cl3CCOOC2H5; decompn. reaction immediately Lysenko, Yu. A.; Nevechera, I. V.; Pridat'ko, S. P.; Troshina, E. A.; Journal of General Chemistry USSR (English Translation); vol. 60; (1990); p. 505 - 510; Zhurnal Obshchei Khimii; vol. 60; (1990); p. 578 - 584 ; (from Gmelin) View in Reaxys O Br

Br Br Br

Rx-ID: 26751372 View in Reaxys 13/73 Yield

Conditions & References

50 %

in neat (no solvent), byproducts: C6H5NO2; decompn. reaction immediately Lysenko, Yu. A.; Nevechera, I. V.; Pridat'ko, S. P.; Troshina, E. A.; Journal of General Chemistry USSR (English Translation); vol. 60; (1990); p. 505 - 510; Zhurnal Obshchei Khimii; vol. 60; (1990); p. 578 - 584 ; (from Gmelin) View in Reaxys Cl

Br Br Br

Br B

Cl O

Rx-ID: 26752379 View in Reaxys 14/73

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Yield

Conditions & References in neat (no solvent), byproducts: B2O3, Cl2CHCOBr; decompn. reaction immediately Lysenko, Yu. A.; Nevechera, I. V.; Pridat'ko, S. P.; Troshina, E. A.; Journal of General Chemistry USSR (English Translation); vol. 60; (1990); p. 505 - 510; Zhurnal Obshchei Khimii; vol. 60; (1990); p. 578 - 584 ; (from Gmelin) View in Reaxys

Br B

Br B(v5) Br B BBr (v6) Br (v6) BrB B B (v6) Br (v5) (v5) (v6) BB B BrBr (v6) Br (v6)

Br Br

F B

B F

Rx-ID: 26406282 View in Reaxys 15/73 Yield

Conditions & References

2 %, 7 %, 2 %, 39 %

B2Br4 and CFBr3 were reacted in a NMR-tube at ambient temp. for 3,75 h; products detected by (19)F- and (11)B-NMR, CBr4 by (13)C-NMR Saulys, D. A; Castillo, J.; Morrison, J. A.; Inorganic Chemistry; vol. 28; (1989); p. 1619 - 1624 ; (from Gmelin) View in Reaxys

Br Br B

H (v5) B

(v5)

H (v6)B (v6)H H B B H BH B (v6)H H (v2)(v6)H(v2)

(v6)

H BHB BH B H H(v6) H HH

(v6)(v6)

(v2) (v2) (v2)(v2)

(v2)(v2)

Rx-ID: 26591448 View in Reaxys 16/73 Yield

Conditions & References in neat (no solvent), decompn. of 1-(bromoboryl)pentaborane on heating at 65°C for 4 h; detected by (11)B- and (19)F-NMR Saulys, D. A; Castillo, J.; Morrison, J. A.; Inorganic Chemistry; vol. 28; (1989); p. 1619 - 1624 ; (from Gmelin) View in Reaxys O

H N

Br B

Br HO Cl

Rx-ID: 25136362 View in Reaxys 17/73 Yield

Conditions & References 6.b : EXAMPLE 6 (b) 4-Chloro-2-(4-hydroxyphenylamino)benzoic acid [IX; R"=H, R'"=4-Cl, OH at 4-position] was prepared by treating 4chloro-2-(4-methoxyphenylamino)benzoic acid with boron tribromide according to the procedure of Example 1, part (d), and was obtained as a tan solid, m.p. 217° C. (decompn.) when recrystallized from aqueous ethanol. Patent; Sterling Drug Inc.; US4515980; (1985); (A) English View in Reaxys HO

O H N

Br Cl

Br OH

Rx-ID: 25136363 View in Reaxys 18/73 Yield

Conditions & References 9.a : EXAMPLE 9 (a)

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2-(3-Chloro-4-hydroxyphenylamino)benzoic acid [XI; R=H, R"=3-Cl, OH at 4-position] was prepared by reaction of 2-(3chloro-4-methoxyphenylamino)benzoic acid (prepared from 3-chloroanisidine and 2-chlorobenzoic acid) with boron tribromide according to the procedure of Example 3, part (b), and was obtained as a pale yellow powder, m.p. 180°-183° C. (decompn.). Patent; Sterling Drug Inc.; US4496590; (1985); (A) English View in Reaxys Br B

N (v4)

(v4)

B BrBr

Rx-ID: 26842495 View in Reaxys 19/73 Yield

Conditions & References in neat (no solvent), the educt was refluxed at 240-250°C for 48 h;; BBr3 was trapped at -80°C; the residue was an ill-defined mixt.; Sheikh, S. U.; Thermochimica Acta; vol. 95; (1985); p. 1 - 6 ; (from Gmelin) View in Reaxys

Br Br

B– BrBr

Br B N

N+

Br B

Rx-ID: 26930610 View in Reaxys 20/73 Yield

Conditions & References in neat (no solvent), byproducts: n-butyl bromide, s-butyl bromide; (n-Bu)4NBBr4 was heated at 240-270°C for 12 h;; volatiles were collected in trap at -80°C, the residue sublimed at 220-240°C/0.05 Torr; second sublimation at 200 °C/0.15 Torr; elem. anal.; Sheikh, S. U.; Thermochimica Acta; vol. 95; (1985); p. 1 - 6 ; (from Gmelin) View in Reaxys

Br B

B2S3

Rx-ID: 26536241 View in Reaxys 21/73 Yield

Conditions & References vol. S: SVol.4a/b; 1.3.10.1.5, page 262 - 264 ; (from Gmelin) View in Reaxys Bouix, J.; Hillel, R.; Canadian Journal of Chemistry; vol. 51; (1973); p. 292 - 301 ; (from Gmelin) View in Reaxys Br

Se I

B Se

Rx-ID: 26610413 View in Reaxys 22/73 Yield

Conditions & References With bromine, byproducts: I2 Siebert, W.; Riegel, F.; Chemische Berichte; vol. 106; (1973); p. 1012 View in Reaxys vol. B: B-Verb.3; 4.7, page 82 - 86 ; (from Gmelin) View in Reaxys

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Br H (v2) B (v4) H H (v4) H BH B (v4) H H (v4) (v2) (v2) H B H

(v2)

B Br

Rx-ID: 26552789 View in Reaxys 23/73 Yield

Conditions & References room temp. Dazord, J.; Mongeot, H.; Bull.Soc. Chim. France; (1972); p. 950 - 951 View in Reaxys vol. B: B-Verb.9; 1.2.3.1, page 26 - 28 ; (from Gmelin) View in Reaxys

Br H (v2) B (v4) H H (v4) H BH B (v4) H H (v4) (v2) (v2) H B H

(v2)

(v4)

(v2)

H B

(v4)

(v2)

Rx-ID: 26836803 View in Reaxys 24/73 Yield

Conditions & References in gas, decompn.; Dazord, J.; Mongeot, H.; Bulletin de la Societe Chimique de France; (1972); p. 950 - 951 View in Reaxys vol. B: B-Verb.14; 6.2, page 235 - 236 ; (from Gmelin) View in Reaxys

Br H (v2) B (v4) H H (v4) H BH B (v4) H H (v4) (v2) (v2) H BH

(v2)

B Br

Rx-ID: 26836804 View in Reaxys 25/73 Yield

Conditions & References With bromine, at room temp.; Dazord, J.; Mongeot, H.; Bulletin de la Societe Chimique de France; (1972); p. 950 - 951 View in Reaxys vol. B: B-Verb.14; 6.2, page 235 - 236 ; (from Gmelin) View in Reaxys

F F

F Br

F (v4) Br(v4) N Br B N Br

B Br

(v4)Br (v4) F

Br N

F F F N

Rx-ID: 26646043 View in Reaxys 26/73 Yield

Conditions & References heating in high vac. Meller, A.; Maringgele, W.; Monatsch. Chem.; vol. 101; (1970); p. 753 - 761 ; (from Gmelin) View in Reaxys heating in high vac. vol. B: B-Verb.4; 5, page 223 - 244 ; (from Gmelin) View in Reaxys

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F F

Br B

N B

N F

Rx-ID: 26648966 View in Reaxys 27/73 Yield

(v2)

(v4)

H B (v4)

(v2)

Rx-ID: 26342037 View in Reaxys 28/73 Yield

Conditions & References room temp.; 70 Torr; equil. state reached in 120 h; IR study of obtained gas mixt. Bouix, J.; Cueilleron, J.; Bulletin de la Societe Chimique de France; (1968); p. 3157 - 3161 View in Reaxys vol. B: B-Verb.9; 2.1.3.3, page 52 - 53 ; (from Gmelin) View in Reaxys Br

B2Se3

Rx-ID: 26609987 View in Reaxys 29/73 Yield

Conditions & References above 170°C; (fast decompn. above 350°C) Cueilleron, J.; Hillel, R.; Bulletin de la Societe Chimique de France; (1968); p. 3635 - 3640 View in Reaxys vol. B: B-Verb.3; 4.5, page 81 - 82 ; (from Gmelin) View in Reaxys

(v2)

(v4)

(v2)

Rx-ID: 26640297 View in Reaxys 30/73 Yield

Conditions & References equil. react. Bouix, J.; Cueilleron, J.; Bulletin de la Societe Chimique de France; (1968); p. 3157 - 3161 View in Reaxys vol. B: B-Verb.9; 1.2.3.3, page 31 - 31 View in Reaxys vol. B: B-Verb.9; 2.1.3.3, page 52 - 53 ; (from Gmelin) View in Reaxys equil react. Bouix, J.; Cueilleron, J.; Bulletin de la Societe Chimique de France; (1968); p. 3157 - 3161 View in Reaxys

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vol. B: B-Verb.9; 1.2.3.1, page 26 - 28 ; (from Gmelin) View in Reaxys equil. react. vol. B: B-Verb.9; 2.1.3.1, page 49 - 50 ; (from Gmelin) View in Reaxys Br B H

(v2)

(v4)

H B (v4)

(v2)

Rx-ID: 26640298 View in Reaxys 31/73 Yield

Conditions & References decompn. of HBBr2 in equil. react. Bouix, J.; Cueilleron, J.; Bulletin de la Societe Chimique de France; (1968); p. 3157 - 3161 View in Reaxys vol. B: B-Verb.9; 1.2.3.3, page 31 - 31 ; (from Gmelin) View in Reaxys Br

Te BrBr

Br B

Rx-ID: 26756183 View in Reaxys 32/73 Yield

Conditions & References room temp. Chen,M.T.; George,J.W.; Journal of the American Chemical Society; vol. 90; (1968); p. 4580 - 4583 ; (from Gmelin) View in Reaxys room temp. vol. B: B Comp.SVol.1/3; 12, page 102 - 104 ; (from Gmelin) View in Reaxys Br

Te BrBr

Br B

Te Br

Rx-ID: 26756184 View in Reaxys 33/73 Yield

Conditions & References in benzene, dissociation; according to cryoscopic and osmometric measurements Chen,M.T.; George,J.W.; Journal of the American Chemical Society; vol. 90; (1968); p. 4580 - 4583 ; (from Gmelin) View in Reaxys in nitrobenzene, dissociation; according to cryoscopic and osmometric measurements Chen,M.T.; George,J.W.; Journal of the American Chemical Society; vol. 90; (1968); p. 4580 - 4583 ; (from Gmelin) View in Reaxys in nitrobenzene, dissociation; according to cryoscopic and osmometric measurements vol. B: B Comp.SVol.1/3; 12, page 102 - 104 ; (from Gmelin) View in Reaxys in benzene, dissociation; according to cryoscopic and osmometric measurements vol. B: B Comp.SVol.1/3; 12, page 102 - 104 ; (from Gmelin) View in Reaxys

Copyright ÂŠ 2018 Elsevier Life Sciences IP Limited except certain content provided by third parties. Reaxys is a trademark of Elsevier Life Sciences IP Limited.

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Br B

Rx-ID: 26617976 View in Reaxys 34/73 Yield

Conditions & References equilibrium reaction Palko, A. A.; Drury, J. S.; Journal of Chemical Physics; vol. 46; (1967); p. 2297 - 2300 View in Reaxys vol. B: B-Verb.3; 5, page 92 - 92 ; (from Gmelin) View in Reaxys F Br

B (v4)

(v4)

B F

FF N

Br F

Rx-ID: 26646999 View in Reaxys 35/73 Yield

Conditions & References on air, under N2 or at treatment with organic solvents Greenwood,N.N.; Hooton,K.A.; Journal of the Chemical Society [Section] A: Inorganic, Physical, Theoretical; (1966); p. 751 754 ; (from Gmelin) View in Reaxys on air, under N2 or at treatment with organic solvents vol. B: B-Verb.4; 4.4.3, page 130 - 132 ; (from Gmelin) View in Reaxys Br

Br Br

Se+

B– BrBr

Rx-ID: 26312941 View in Reaxys 36/73 Yield

Conditions & References byproducts: CH3Br; decompn. above 66°C Wynne, K. J.; George, J. W.; Journal of the American Chemical Society; vol. 87; (1965); p. 4750 - 4754 View in Reaxys vol. B: B-Verb.3; 4.12, page 91 - 91 ; (from Gmelin) View in Reaxys

Br B

(v4)

H B

(v4)

(v2)

Rx-ID: 26556230 View in Reaxys 37/73 Yield

Conditions & References Brieux De Mandirola, O.; Westerkamp, J. F.; Spectrochimica Acta; vol. 21; (1965); p. 1101 - 1103 View in Reaxys vol. B: B-Verb.9; 1.2.3.1, page 26 - 28 ; (from Gmelin) View in Reaxys O

Br Br

B O

O B H

Br H

Rx-ID: 26602979 View in Reaxys 38/73

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Yield

Conditions & References MS of gas phase react. product Wason, S. K.; Porter, R. F.; Journal of Physical Chemistry; nb. 69; (1965); p. 2461 - 2462 View in Reaxys vol. B: B-Verb.9; 1.2.3.3, page 31 - 31 ; (from Gmelin) View in Reaxys

(v2)

H (v4)

(v4)

(v2)

B H (v2)

(v4)

Rx-ID: 26640296 View in Reaxys 39/73 Yield

Conditions & References vol. B: B-Verb.9; 1.2.3.1, page 26 - 28 View in Reaxys vol. B: B-Verb.9; 1.2.3.3, page 31 - 31 ; (from Gmelin) View in Reaxys Lynds, L.; Bass, C. D.; Journal of Chemical Physics; vol. 41; (1964); p. 3165 - 3169 View in Reaxys Lynds, L.; Wolfram, T.; Bass, C. D.; Journal of Chemical Physics; vol. 43; (1965); p. 3775 - 3779 ; (from Gmelin) View in Reaxys vol. B: B-Verb.9; 1.2.3.2, page 28 - 31 ; (from Gmelin) View in Reaxys Br

Br O

B2O3

Br Br

Rx-ID: 26836788 View in Reaxys 40/73 Yield

Conditions & References in neat (no solvent), unstable at room temp., decompn.; Goubeau, J.; Keller, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 267; (1951); p. 1 - 25 View in Reaxys Greenbaum, M. A.; Proc. 1st Meeting Interagency Chem. Rocket Propulsion GroupThermochem., New York 1963 (1964), Bd. 1, S. 183/5; C. A.; vol. 62; (1965); p. 74 ; (from Gmelin) View in Reaxys in neat (no solvent), thermodynamically unstable; decompn. at room temp.; Goubeau, J.; Keller, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 267; (1951); p. 1 - 25 View in Reaxys Porter, R. F.; Sholette, W. P.; Journal of Chemical Physics; vol. 37; (1962); p. 198 - 199 View in Reaxys Greenbaum, M. A.; Proc. 1st Meeting Interagency Chem. Rocket Propulsion GroupThermochem., New York 1963 (1964), Bd. 1, S. 183/5; C. A.; vol. 62; (1965); p. 74 ; (from Gmelin) View in Reaxys in neat (no solvent), unstable at room temp., decompn.; Baumgarten, P.; Bruns, W.; Ber. Dtsch. Chem. Ges.; vol. 72; (1939); p. 1753 - 1763 View in Reaxys Baumgarten, P.; Bruns, W.; Ber. Dtsch. Chem. Ges.; vol. 74; (1941); p. 1232 - 1236 View in Reaxys Goubeau, J.; Keller, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 272; (1953); p. 303 - 312 View in Reaxys vol. B: B-Verb.13; 4.4, page 145 - 150 ; (from Gmelin) View in Reaxys

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in neat (no solvent), thermodynamically unstable; decompn. at room temp.; Goubeau, J.; Keller, H.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 272; (1953); p. 303 - 312 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. B: B-Verb.13; 4.1.2.1, page 120 - 122 ; (from Gmelin) View in Reaxys N

Br Br

Rx-ID: 26344245 View in Reaxys 41/73 Yield

Conditions & References Lappert,M.F.; Prokai,B.; Journal of Organometallic Chemistry; vol. 1; (1964); p. 384 - 400 ; (from Gmelin) View in Reaxys vol. B: B-Verb.9; 5.3.2, page 233 - 238 ; (from Gmelin) View in Reaxys

N N

B Br

Rx-ID: 26519463 View in Reaxys 42/73 Yield

Conditions & References in pentane Banister, A. J.; Greenwood, N. N.; Straughan, B. P.; Walker, J.; Journal of the Chemical Society; (1964); p. 995 - 1000 View in Reaxys vol. B: B-Verb.4; 2.4, page 32 - 40 ; (from Gmelin) View in Reaxys

H (v5) B (v6)

Br B H H (v6) BH BH H B(v6) B HH

(v5)

(v6)(v6)

H BHB BH B H H(v6) H HH

(v2)

(v6)

(v2) (v2) (v2)(v2)

(v2) (v6) (v2) (v2)

Rx-ID: 26622825 View in Reaxys 43/73 Yield

Conditions & References With bromine, excess of Br2; vol. B: B-Verb.14; 6.3.1.2, page 237 - 240 ; (from Gmelin) View in Reaxys With Br2, excess of Br2; Hall, L. H.; Subbanna, V. V.; Koski, W. S.; Journal of the American Chemical Society; vol. 86; (1964); p. 3969 - 3973 ; (from Gmelin) View in Reaxys Br

B Br

Rx-ID: 26368599 View in Reaxys 44/73

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Yield

Conditions & References 200°C Abel, E. W.; Gerrard, W.; Lappert, M. F.; Journal of the Chemical Society; (1957); p. 5051 - 5054 View in Reaxys vol. B: B-Verb.9; 6.3.2, page 303 - 314 ; (from Gmelin) View in Reaxys Br

Rx-ID: 26438278 View in Reaxys 45/73 Yield

Conditions & References With bromine Abel, E. W.; Gerrard, W.; Lappert, M. F.; Journal of the Chemical Society; (1957); p. 5051 - 5054 ; (from Gmelin) View in Reaxys With hydrogen bromide Abel, E. W.; Gerrard, W.; Lappert, M. F.; Journal of the Chemical Society; (1957); p. 5051 - 5054 ; (from Gmelin) View in Reaxys vol. B: B-Verb.9; 4.3.1.7, page 140 - 141 ; (from Gmelin) View in Reaxys Br

Rx-ID: 26438292 View in Reaxys 46/73 Yield

Conditions & References 100°C Abel, E. W.; Gerrard, W.; Lappert, M. F.; Journal of the Chemical Society; (1957); p. 5051 - 5054 View in Reaxys vol. B: B-Verb.9; 6.3.2, page 303 - 314 ; (from Gmelin) View in Reaxys Br

B2O3

BrNa

Rx-ID: 26075898 View in Reaxys 47/73 Yield

Conditions & References 800-1000°C vol. Na: SVol.6; 6.3.3, page 401 - 402 View in Reaxys Wood, J. H.; Zabielski, C.; MCC-1023-TR-80 (1954) 28 S.; N.S.A.; vol. 9; (1955); p. 598 ; (from Gmelin) View in Reaxys

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SH S HS

S S

Br SH

Rx-ID: 26536006 View in Reaxys 48/73 Yield

Conditions & References With hydrogen bromide, reversible reaction Wiberg, E.; Sturm, W.; Angewandte Chemie; vol. 67; (1955); p. 483 - 493 View in Reaxys Wiberg, E.; Sturm, W.; Z. Naturforsch. b; vol. 8; (1953); p. 529 - 531 ; (from Gmelin) View in Reaxys With HBr, reversible reaction vol. B: B-Verb.3; 2.5.1.1, page 16 - 17 ; (from Gmelin) View in Reaxys

(v2)

H (v4)

(v2)

H B H

(v2)

(v4)

(v2)

(v4)

Rx-ID: 26342036 View in Reaxys 49/73 Yield

Conditions & References decompn. at room temp. Cornwell; Journal of Chemical Physics; vol. 18; (1950); p. 1118 View in Reaxys vol. B: B-Verb.9; 2.1.3.3, page 52 - 53 ; (from Gmelin) View in Reaxys Br

Cl Br

B Cl

Rx-ID: 26086820 View in Reaxys 50/73 Yield

Conditions & References Forbes; Anderson; Journal of the American Chemical Society; vol. 62; (1940); p. 761 ; (from Gmelin) View in Reaxys vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys Br

Br F B

Rx-ID: 26111006 View in Reaxys 51/73 Yield 70 %

Conditions & References with excess of BF3; addn. of Al to depress formation of Br2; addn. of Hg to get rid of Br2 Gamble, E. L.; Gilmont, P.; Stiff, J. F.; Journal of the American Chemical Society; vol. 62; (1940); p. 1257 - 1258 ; (from Gmelin) View in Reaxys

70 %

with excess of BF3; addn. of Al to depress formation of Br2; addn. of Hg to get rid of Br2 vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys

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B–

Br F

K+

Rx-ID: 26159642 View in Reaxys 52/73 Yield

Conditions & References

30 %

Gamble, E. L.; Gilmont, P.; Stiff, J. F.; Journal of the American Chemical Society; vol. 62; (1940); p. 1257 - 1258 ; (from Gmelin) View in Reaxys

30 %

vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys Br

B2O3

Rx-ID: 26075820 View in Reaxys 53/73 Yield

Conditions & References With coal, 250°C; fractionated distn. Anderson, T. F.; Lassettre, E. N.; Yost, D. M.; Journal of Chemical Physics; vol. 4; (1936); p. 703 - 707 View in Reaxys vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys

Br B

Rx-ID: 26308522 View in Reaxys 54/73 Yield

Conditions & References decompn. by moisture of air Pohland, E.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 201; (1931); p. 282 - 288 ; (from Gmelin) View in Reaxys decompn. by moisture of air vol. C: MVol.D1; 16.5, page 244 - 245 ; (from Gmelin) View in Reaxys Br

Ag+

Br N–

(v3)

Br (v3)

Rx-ID: 26445813 View in Reaxys 55/73 Yield

Conditions & References above 150°C Pohland, E.; Z. Anorg. Chem.; vol. 201; (1931); p. 282 - 288 View in Reaxys vol. B: SVol.1; 4.6, page 204 - 209 ; (from Gmelin) View in Reaxys Br

Br B

Br(v1)

Rx-ID: 26734904 View in Reaxys 56/73

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Yield

Conditions & References in neat (no solvent), heating at 150°C; Pohland, E.; Zeitschrift fuer Anorganische und Allgemeine Chemie; vol. 201; (1931); p. 282 - 288 View in Reaxys vol. Ag: MVol.B3; 16.4.10, page 319 - 319 ; (from Gmelin) View in Reaxys

(v2)

(v4)

(v2)

Rx-ID: 26091315 View in Reaxys 57/73 Yield

Conditions & References

>99

With bromine, at 100°C in light Stock; Kuss; Priess; Ber.; vol. 47; (1914); p. 3117 ; (from Gmelin) View in Reaxys With bromine, at room temperature in light Stock; Kuss; Priess; Ber.; vol. 47; (1914); p. 3117 ; (from Gmelin) View in Reaxys With hydrogen bromide, aluminium bromide, at 80-90 °C Stock; Kuss; Ber.; vol. 56; (1923); p. 799 View in Reaxys vol. B: MVol.; 10.2, page 126 - 127 ; (from Gmelin) View in Reaxys With Br2, at room temperature in light vol. B: MVol.; 5.3.1, page 59 - 61 ; (from Gmelin) View in Reaxys

>99

With Br2, at 100°C in light vol. B: MVol.; 5.3.1, page 59 - 61 ; (from Gmelin) View in Reaxys With HBr, AlBr3, at 80-90°C in sealed tube vol. B: MVol.; 5.3.1, page 59 - 61 ; (from Gmelin) View in Reaxys With AlBr3, HBr, at 80-90°C in sealed tube Stock; Kuss; Ber.; vol. 56; (1923); p. 797 ; (from Gmelin) View in Reaxys Br B

Rx-ID: 26131102 View in Reaxys 58/73 Yield

Conditions & References With C2H4Br2, at 250°C in sealed tube Chabrie; Bulletin de la Societe Chimique de France; vol. 7; nb. 3; (1892); p. 29 ; (from Gmelin) View in Reaxys With bromine, at 700°C, or at red heat Meyer, F.; Zappner; Ber.; vol. 54; (1921); p. 551

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View in Reaxys Stock; Kuss; Ber.; vol. 47; (1914); p. 3113 View in Reaxys vol. B: MVol.; 4.2, page 30 - 30 ; (from Gmelin) View in Reaxys With C2H4Br2, at 250°C in sealed tube vol. B: MVol.; 4.4, page 31 - 35 ; (from Gmelin) View in Reaxys

(v2)

(v4)

(v2)

Rx-ID: 26342040 View in Reaxys 59/73 Yield

Conditions & References Stock; Kuss; Priess; Ber.; vol. 47; (1914); p. 3128 - 3145 View in Reaxys vol. B: MVol.; 10.2, page 126 - 127 ; (from Gmelin) View in Reaxys Br B

B2Br2H 4

Rx-ID: 26362114 View in Reaxys 60/73 Yield

Conditions & References Stock; Kuss; Priess; Ber.; vol. 47; (1914); p. 3128 - 3145 View in Reaxys vol. B: MVol.; 10.2, page 126 - 127 ; (from Gmelin) View in Reaxys Br B

B2Br3H 3

Rx-ID: 26362121 View in Reaxys 61/73 Yield

Conditions & References Stock; Kuss; Priess; Ber.; vol. 47; (1914); p. 3128 - 3145 View in Reaxys vol. B: MVol.; 10.2, page 126 - 127 ; (from Gmelin) View in Reaxys

(v2)

(v4)

B2Br2H 4

(v4)

(v2)

(v4)

B2Br3H 3

(v2)

Rx-ID: 26368398 View in Reaxys 62/73 Yield

Conditions & References Stock; Kuss; Priess; Ber.; vol. 47; (1914); p. 3128 - 3145 View in Reaxys vol. B: MVol.; 10.2, page 126 - 127 ; (from Gmelin) View in Reaxys Br

Rx-ID: 26119410 View in Reaxys 63/73 Yield

Conditions & References With bromine, at moderate temp.

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Bartal, von; Liebigs Annalen der Chemie; vol. 345; (1906); p. 338 View in Reaxys vol. B: MVol.; 4.2, page 30 - 30 ; (from Gmelin) View in Reaxys Br

Br B

S Br

B S

Rx-ID: 26350015 View in Reaxys 64/73 Yield

Conditions & References by intensive heating, over 100 °C Stock; Blix; Ber.; vol. 34; (1901); p. 3039 View in Reaxys vol. B: MVol.; 12.7, page 135 - 135 ; (from Gmelin) View in Reaxys in carbon disulfide, heating of the CS2 soln. Stock; Blix; Ber.; vol. 34; (1901); p. 3039 View in Reaxys vol. B: MVol.; 12.7, page 135 - 135 ; (from Gmelin) View in Reaxys Br

C 2B6Be2

BeBr2

Rx-ID: 26368607 View in Reaxys 65/73 Yield

Conditions & References Lebeau; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 126; (1898); p. 1347 View in Reaxys Lebeau, P.; Ann. Chim. Phys.; vol. 16; (1899); p. 481 View in Reaxys vol. Be: MVol.; 3.10, page 146 - 161 ; (from Gmelin) View in Reaxys Br

BNi

Rx-ID: 26368930 View in Reaxys 66/73 Yield

Conditions & References in neat (no solvent), at dark red heat; Moissan, H.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 122; (1896); p. 424 - 426 ; (from Gmelin) View in Reaxys in neat (no solvent), at dark red heat; vol. Ni: MVol.B3; 3, page 769 - 771 ; (from Gmelin) View in Reaxys Br

B S

Rx-ID: 26061964 View in Reaxys 67/73 Yield

Conditions & References heating of B2S3 in Br2 vapour

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Moissan; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 115; (1892); p. 203 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys Br B

Rx-ID: 26062242 View in Reaxys 68/73 Yield

Conditions & References 250 °C in reaction tube Chabrie; Bulletin de la Societe Chimique de France; vol. 7; nb. 3; (1892); p. 29 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys at 250°C in sealed tube Chabrie; Bulletin de la Societe Chimique de France; vol. 7; nb. 3; (1892); p. 29 ; (from Gmelin) View in Reaxys at 250°C in sealed tube vol. B: MVol.; 4.4, page 31 - 35 ; (from Gmelin) View in Reaxys Br

Rx-ID: 26131471 View in Reaxys 69/73 Yield

B2O3

P Cl

Rx-ID: 26062736 View in Reaxys 70/73 Yield

Conditions & References Gustavson; Z. Ch.; vol. 13; (1870); p. 521 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys

B2O3

PBr Br Br

Br B

Rx-ID: 26076265 View in Reaxys 71/73 Yield

Conditions & References 140 °C, reaction tube Gustavson; Ber.; vol. 3; (1870); p. 426 View in Reaxys

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vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys Br

B2O3

Rx-ID: 26075821 View in Reaxys 72/73 Yield

Conditions & References byproducts: CO; glowed B2O3-C mixt. is treated with Br2 Poggiale; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 22; (1846); p. 124 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys Br

BFe

Rx-ID: 26087050 View in Reaxys 73/73 Yield 0%

Conditions & References Poggiale; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 22; (1846); p. 124 View in Reaxys vol. B: MVol.; 10.1.1, page 124 - 124 ; (from Gmelin) View in Reaxys

23/23

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