Iodine monochloride [ICl or ClI] by Asch

Iodine monochloride [ICl or ClI]

Query Query 1. Query

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Date

113 reactions in Reaxys

2018-07-17 15h:27m:30s (UTC)

Search as: Product, As drawn, No mixtures ) AND (IDE.RN='7790-99-0') AND (IDE.INCHI='QZRGKCOWNLSUDKUHFFFAOYSA-N') NOT (RX.RXRN=3902972))

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Iodine monochloride [ICl or ClI]

Rx-ID: 26366871 View in Reaxys 1/113 Yield

Conditions & References in gas, reaction of gas stream of starting materials (Ar as carrier gas) at room temp. Lilenfeld, H. V.; Whitefield, P. D.; Bradburn, G. R.; Journal of Physical Chemistry; vol. 88; nb. 25; (1984); p. 6158 - 6162 ; (from Gmelin) View in Reaxys in water, passing Cl2 into suspension of I2 in water;; not isolated; anonymous; Dinglers Polytech. J.; vol. 256; (1885); p. 324 - 324 View in Reaxys Patent; anonymous; Chemische Fabrik auf Actien, vormals E. Schering; DE30358; (1884) View in Reaxys Patent; anonymous; Schering-Kahlbaum Akt.-Ges.; DE512563; (1930) ; (from Gmelin) View in Reaxys Wariishi, Koji; Morishima, Sin-Ichi; Inagaki, Yoshio; Organic Process Research and Development; vol. 7; nb. 1; (2003); p. 98 - 100 View in Reaxys in water vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys 3.2 : (2) preparation of iodine monochloride: In 500L the reaction kettle is added 100 kg of iodine, the reaction temperature is 70 °C, iodine sublimation, access chlorine, chlorine and iodine mole than 1.5: 1, end point of the reaction is a solid fully into liquid, the liquid will be of distillation, to obtain a iodine monochloride product. , T= 70 °C , Large scale, Temperature, Concentration Patent; Zhejiang Borui Electronic Technology Co., Ltd.; Chen Gang; Zhang Xiaodong; Li Jun; Zhou Jingsen; Wang Ning; Chen Lifeng; Qian Hongdong; Hua Yongjin; Xu Jianxian; (7 pag.); CN106336342; (2017); (A) Chinese View in Reaxys I

Rx-ID: 24296007 View in Reaxys 2/113 Yield 80%

Conditions & References 8.b : b b Iodination by ICl To the paste obtained in a) dissolved in 100 ml of a mixture MeOH/H2 O:50/50 are added dropwise 2.1 ml (0.027 mole) of a 70percent solution of ICl. When the addition is complete, the reaction mixture is heated at 60° C. for 4 h, then left to stand at room temperature for 12 h. The brown solution obtained is poured with stirring into 200 ml of water. The precipitate formed is filtered off, then washed with a 20percent solution of sodium bisulfite and H2 O. The product is taken up in ether, then dried. 3 g of white crystals are obtained. Yield=80percent Purity with respect to iodine=99percent TLC (CH2 Cl2) 85/MeOH 15): Rf =0.4 1

H NMR (DMSO) δ2.9 and 3.1 ppm (s, N--CH3 Z) (s, N--CH3 E) 6H; δ3.2 to 4 ppm (m, CH2 --CH--CH2, 10H); δ4.4 to 4.8 ppm

STR95 exchangeable with D2 O) δ5.5 ppm (s, NH3, 4H exchangeable with D2 O) Patent; Guerbet S.A.; US5616798; (1997); (A) English View in Reaxys 15 : Reaction of Excess Hexafluoropropylene Oxide (HFPO) with Iodine Monochloride in Hastelloy.(R). C Shaker Tube Example 15 Reaction of Excess Hexafluoropropylene Oxide (HFPO) with Iodine Monochloride in Hastelloy.(R). C Shaker Tube A 0.4-L Hastelloy.(R). C shaker tube was charged with 114 g of iodine monochloride and then evacuated at low temperature. After 120 g of HFPO was added, the resulting mixture was heated at 185° C. for 8 hours.

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Iodine monochloride [ICl or ClI]

Then, 112.3 g of crude liquid products were obtained, which were distilled to give 14.7 g of CF2 ICI, bp 31-34° C., 61.7 g of CF2 I2, bp 103-104° C. 19 F NMR for CF2 ICI: +8.2 (s). HRMS: calcd. for CF2 ICI: 311.8637. Found: 311.8678. Trace of CICF2 CF2 CF2 I was also observed by GC-MS. Patent; E. I. du Pont de Nemours and Company; US6002055; (1999); (A) English View in Reaxys XI : (R)—((S)-5-(tert-butyldimethylsilyloxy)-4-cyclopentenyl-2-isopropyl-7,7-dimethyl-5,6,7,8-tetrahydroquinolin-3-yl)(4(trifluoromethyl)phenyl)methanol General procedure: Under argon 490 mg (R)—((S)-5-(tert-butyldimethylsilyloxy)-4-iodo-2-isopropyl-7,7-dimethyl-5,6,7,8-tetrahydroquinolin-3-yl)(4-(trifluoromethyl)phenyl)methanol and 900 mg 2-cyclopent-1-enyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane are dissolved in 20 ml tetrahydrofurane. 900 mg caesium fluoride are added and the mixture is purged for 5 minutes with argon. After the addition of 50 mg of 1,1δ-bis-(diphenylphosphino)-ferrocene-dichloro-palladium-(II) the mixture is heated to 50° C. for 36 hours. Then the mixture is diluted with diethylether, washed with saturated aqueous ammonium chloride and brine and dried with magnesium sulphate. The solvents are evaporated in vacuo and the residue is chromatographed on silica gel (cyclohexane/ethylacetate 95:5 to 60:40).[1084]Yield: 330 mg (74percent of theory)[1085]Mass spectrometry (ESI+): m/z=574 [M+H] +[1086]R -value: 0.37 (silica gel, petrole ether/ethylacetate 8:1) f With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride, cesium fluoride in tetrahydrofuran, Time= 36h, T= 50 °C , Inert atmosphere Patent; BOEHRINGER INGELHEIM INTERNATIONAL GMBH; Wagner, Holger; Berta, Daniela; Fuchs, Klaus; Giovannini, Riccardo; Hamprecht, Dieter Wolfgang; Konetzki, Ingo; Streicher, Ruediger; Trieselmann, Thomas; US2013/53404; (2013); (A1) English View in Reaxys O

O Cl

Na +

O–

Rx-ID: 30049458 View in Reaxys 3/113 Yield

Conditions & References

99.6 %

1 :Iodine (7.61 kg, 30 mole), hydrochloric acid (37 percent, 6.91 kg, 70 mole), water (0.62 kg, 35 mole) and sodium chloride (1.46 kg, 25 mole) was mixed in a reactor at 25°C. A solution of sodium chlorate (1.07 kg, 10 mole) in water (1.20 kg, 67 mole) was prepared under heating and added with caution to the reactor over 2 hours at rigorous stirring. The reaction continued with moderate stirring at 27-30°C for 17 hours. Free iodine was demonstrated by extraction of a sample with chloroform in presence of hydrochloric acid (pink colour obtained). A pH of 1.06 was measured. An aqueous iodine chloride solution (18.80 kg) with a concentration of 51.6 w/w percent (relative to reaction solution) was obtained, corresponding to a yield of 99.6 percent. With hydrogenchloride, sodium chloride in water, Time= 19h, T= 25 - 27 °C Patent; GE Healthcare AS; EP2277845; (2011); (A1) English View in Reaxys 1 :Iodine (2700 kg, 10.6 kmole), hydrochloric acid (35 percent, 2285 kg, 21.9 kmole), water (250 kg, 13.3 kmole) and sodium chloride (475 kg, 8.1 kmole) are mixed in a reactor at 20 °C. An aqueous solution of sodium chlorate (43 w/w percent, 864 kg, 2.6 mole) is added carefully to the reactor over 3-4 hours at rigorous stirring. The reaction continues with moderate stirring at about 50 °C for at least 10 hours. Extraction of a reaction sample with dichloromethane in presence of hydrochloric acid gives a negative result (no colour in the organic phase), which means that there is no free iodine in the iodine chloride solution prepared. Small portions of potassium iodide (about 2-4 kg in each portion) are added. The free iodine test (dichloromethane extraction) gives a positive result after the addition of less than 15 kg potassium iodide. With hydrogenchloride, sodium chloride in water, T= 20 - 50 °C Patent; GE Healthcare AS; EP2277846; (2011); (A1) English View in Reaxys

O O

S N

Na +

INa

–

Rx-ID: 29974636 View in Reaxys 4/113

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Iodine monochloride [ICl or ClI]

Yield

Conditions & References in tetrahydrofuran, water, mixing NaI and S compd. in aq. THF; not isolated Rawls, Katherine A.; Grundner, Christoph; Ellman, Jonathan A.; Organic and Biomolecular Chemistry; vol. 8; nb. 18; (2010); p. 4066 - 4070 ; (from Gmelin) View in Reaxys O

OH F

Rx-ID: 25614323 View in Reaxys 5/113 Yield

Conditions & References 8 : Synthesis of [Me3NH][1-H-CB11Cl11] (UCC) Trimethylammonium chloride (98percent), octadecanoic acid chloride, 4-aminoazobenzene, triethylamine (99.5percent), and lithium aluminum hydride were acquired from Aldrich. All solvents were ACS grade from Aldrich and used as received. Synthesis: A thick-walled Pyrex tube was charged with Cs[CB11H12] (0.08 g, 0.29 mmol), trifluoromethanesulfonic acid (1.0 mL, 11.3 mmol), and iodine monochloride (1.0 mL, 19.6 mmol). Patent; Auburn University; US7201876; (2007); (B2) English View in Reaxys

HNaO

Rx-ID: 26367725 View in Reaxys 6/113 Yield

Conditions & References With sea-salt in neat (no solvent), heterogeneous reaction in a conventional flow system at 278 and 298 K; not isolated, detected by mass spectrometry Moessinger, Juliane C.; Cox, R. Anthony; Journal of Physical Chemistry A; vol. 105; nb. 21; (2001); p. 5165 - 5177 ; (from Gmelin) View in Reaxys

ClNa

HNaO

Rx-ID: 26367732 View in Reaxys 7/113 Yield

Conditions & References in neat (no solvent), heterogeneous reaction in a conventional flow system at 278 and 298 K; not isolated, detected by mass spectrometry Moessinger, Juliane C.; Cox, R. Anthony; Journal of Physical Chemistry A; vol. 105; nb. 21; (2001); p. 5165 - 5177 ; (from Gmelin) View in Reaxys

O N

ice doped with HI

Rx-ID: 26413224 View in Reaxys 8/113 Yield

Conditions & References Kinetics, byproducts: HNO3; continous flow experiments for heterogeneous reaction on ice doped withHI at 200 K, at various concentrations of ClONO2; products thermally desorbed and monitored by MS Allanic; Oppliger; Van Den Bergh; Rossi; Zeitschrift fur Physikalische Chemie; vol. 214; nb. 11; (2000); p. 1479 - 1500 ; (from Gmelin) View in Reaxys

Rx-ID: 26552088 View in Reaxys 9/113

Copyright ÂŠ 2018 Elsevier Life Sciences IP Limited except certain content provided by third parties. Reaxys is a trademark of Elsevier Life Sciences IP Limited.

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Iodine monochloride [ICl or ClI]

Yield

Conditions & References in neat (no solvent), addn. of solid I2 to 2fold amount of liquid Cl2; warming to room temp. for a longer period of time, evapn. of excessive Cl2; addn. of I2 (according to stoichometric amount); storage for 24 hours;; recrystallization for 1 or 2 times under exclusion of moisture; pure; Cornog, J.; Karges, R. A.; Journal of the American Chemical Society; vol. 54; (1932); p. 1882 - 1882 ; (from Gmelin) View in Reaxys in neat (no solvent), condensation of Cl2 at -196°C in high vacuum to I2, warming to 25°C, kept for 24 h; purifn. by condensation in a high vacuum glass line Minkwitz, Rolf; Berkei, Michael; Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences; vol. 54; nb. 12; (1999); p. 1615 - 1617 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys

(v3)

S S N N (v3) S N S (v2)

(v2) N (v2)

(v2)

(v3)

Rx-ID: 26821184 View in Reaxys 10/113 Yield

Conditions & References in neat (no solvent), fractional condensation (-50, -196°C); identified by IR spectroscopy Haas, Alois; Fleischer, Ulrich; Maetschke, Matthias; Staemmler, Volker; Zeitschrift fur Anorganische und Allgemeine Chemie; vol. 625; nb. 4; (1999); p. 681 - 692 ; (from Gmelin) View in Reaxys

Rx-ID: 26083206 View in Reaxys 11/113 Yield

F C

Cl F

Rx-ID: 26133877 View in Reaxys 12/113 Yield

Conditions & References in gaseous matrix, Kinetics, flow tube, large flow of N2 or He/N2 (5/16 torr), 298 K Turnipseed, Andrew A.; Gilles, Mary K.; Burkholder, James B.; Ravishankara; Journal of Physical Chemistry A; vol. 101; nb. 30; (1997); p. 5517 - 5525 ; (from Gmelin) View in Reaxys in gas, Kinetics, discussion of mechanism and kinetics; pulse photolysis followed by temp. jump; Dymov; Skorobogatov; Khripun; Kinetics and Catalysis; vol. 32; nb. 4 pt 1; (1992); p. 714 - 719 ; (from Gmelin) View in Reaxys

(v2)

(v1)

Rx-ID: 26367428 View in Reaxys 13/113

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Iodine monochloride [ICl or ClI]

Yield

Conditions & References in gaseous matrix, Kinetics, flow tube, large flow of Ne or He/N2 (5/16 torr), 298 K Turnipseed, Andrew A.; Gilles, Mary K.; Burkholder, James B.; Ravishankara; Journal of Physical Chemistry A; vol. 101; nb. 30; (1997); p. 5517 - 5525 ; (from Gmelin) View in Reaxys

Cl I

Rx-ID: 26483531 View in Reaxys 14/113 Yield

Conditions & References With water in water, extraction with ether; Serullas, G. S.; Ann. Chim. Phys.; vol. 45; (1845); p. 199 - 199 ; (from Gmelin) View in Reaxys in neat (no solvent), decompn. Woolf, Alfred A.; Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999); nb. 12; (1991); p. 3325 - 3330 ; (from Gmelin) View in Reaxys in water vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys

Cl Cl

I(1-)

Cl N H

HO( 1-)

Rx-ID: 26414700 View in Reaxys 15/113 Yield

Conditions & References With water in water, Kinetics, acid assisted reaction with phosphate buffer at various pH; rates measured by pulsed-acceleratedflow method Nagy, Julius C.; Kumar, Krishan; Margerum, Dale W.; Inorganic Chemistry; vol. 27; (1988); p. 2773 - 2780 ; (from Gmelin) View in Reaxys Ne

Rx-ID: 26510041 View in Reaxys 16/113 Yield

Conditions & References in neat (no solvent, gas phase), examination of the ICl product distribution following vibrational predissociation of the van-derWaals complexes via an optical-optical double resonance technique Drobits, Janet C.; Lester, Marsha I.; Journal of Chemical Physics; vol. 88; nb. 1; (1988); p. 120 - 128 ; (from Gmelin) View in Reaxys

Rx-ID: 26088579 View in Reaxys 17/113 Yield

Conditions & References in gaseous matrix, byproducts: CH3; reaction of in situ generated Cl atoms (by microwave discharge from Cl2/He or Cl2/Ne mixt., Cl atom beam velocity 1150-1950 m/s) with alkyl iodide according to: S. M. A. Hoffmann, D. J. Smith, R. Grice, Mol. Phys. 49 (1983) 621; mass spectroscopy Hoffmann, S. M. A.; Smith, D. J.; Gonzales Urenna, A.; Grice, R.; Chemical Physics Letters; vol. 107; (1984); p. 99 - 102 ; (from Gmelin) View in Reaxys

Copyright ÂŠ 2018 Elsevier Life Sciences IP Limited except certain content provided by third parties. Reaxys is a trademark of Elsevier Life Sciences IP Limited.

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Iodine monochloride [ICl or ClI]

Rx-ID: 26114723 View in Reaxys 18/113 Yield

Conditions & References in gaseous matrix, byproducts: C2H5; reaction of in situ generated Cl atoms (by microwave discharge from Cl2/He or Cl2/Ne mixt., Cl atom beam velocity 1150-1950 m/s) with alkyl iodide according to: S. M. A. Hoffmann, D. J. Smith, R. Grice, Mol. Phys. 49 (1983) 621; mass spectroscopy Hoffmann, S. M. A.; Smith, D. J.; Gonzales Urenna, A.; Grice, R.; Chemical Physics Letters; vol. 107; (1984); p. 99 - 102 ; (from Gmelin) View in Reaxys

Rx-ID: 26133874 View in Reaxys 19/113 Yield

Conditions & References in gaseous matrix, byproducts: C3H7; reaction of in situ generated Cl atoms (by microwave discharge from Cl2/He or Cl2/Ne mixt., Cl atom beam velocity 1150-1950 m/s) with alkyl iodide according to: S. M. A. Hoffmann, D. J. Smith, R. Grice, Mol. Phys. 49 (1983) 621; mass spectroscopy Hoffmann, S. M. A.; Smith, D. J.; Gonzales Urenna, A.; Grice, R.; Chemical Physics Letters; vol. 107; (1984); p. 99 - 102 ; (from Gmelin) View in Reaxys

Rx-ID: 26433536 View in Reaxys 20/113 Yield

Conditions & References in gas, Kinetics, byproducts: Cl; reaction of gas stream of starting materials (Ar as carrier gas) at room temp.; monitored by UVspectroscopy Lilenfeld, H. V.; Whitefield, P. D.; Bradburn, G. R.; Journal of Physical Chemistry; vol. 88; nb. 25; (1984); p. 6158 - 6162 ; (from Gmelin) View in Reaxys

Rx-ID: 26182435 View in Reaxys 21/113 Yield

Conditions & References Kinetics, byproducts: HCl; other Radiation Dolson, David A.; Leone, Stephen R.; Journal of Chemical Physics; vol. 77; nb. 8; (1982); p. 4009 - 4021 ; (from Gmelin) View in Reaxys Cl

Rx-ID: 26366872 View in Reaxys 22/113 Yield 85 %

Conditions & References in neat (no solvent), passing dry chlorine over dry iodine;; distillation in stream of chlorine at 100-101.5°C; Cornog, J.; Karges, R. A.; Journal of the American Chemical Society; vol. 54; (1932); p. 1882 - 1882 ; (from Gmelin) View in Reaxys

35 %

in neat (no solvent), passing dry chlorine over dry iodine;; distillation at 100-101.5°C; Cornog, J.; Karges, R. A.; Journal of the American Chemical Society; vol. 54; (1932); p. 1882 - 1882 ; (from Gmelin) View in Reaxys in neat (no solvent), excess of iodine

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Iodine monochloride [ICl or ClI]

Willis, Robert E.; Clark, William W.; Journal of Chemical Physics; vol. 72; nb. 9; (1980); p. 4946 - 4950 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys I

AgCl

AgI

Rx-ID: 26083015 View in Reaxys 23/113 Yield

Conditions & References in neat (no solvent), Kinetics, shock compression of AgCl/I2 mixt. (explosion in cylindrical ampoule using hexogen charge), ICl liberation after protective ampoule opening; X-ray diffraction Batsanov, S. S.; Lazareva, E. V.; Kopaneva, L. I.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 24; (1979); p. 1253 - 1254; Zhurnal Neorganicheskoi Khimii; vol. 24; (1979); p. 2258 - 2261 ; (from Gmelin) View in Reaxys

Cl I

Rx-ID: 26083351 View in Reaxys 24/113 Yield

Conditions & References in tetrachloromethane, other Radiation; δ-radiation of I2 soln. in CCl4; yield depends on concn. of I2 and on dose of radiation; Bibler; Journal of Physical Chemistry; vol. 75; (1971); p. 24 View in Reaxys vol. C: MVol.D2; 4.1.2.7.4.2, page 222 - 225 ; (from Gmelin) View in Reaxys O O

I Cl

Cl N

I N

I O

N H

O I

Rx-ID: 26667403 View in Reaxys 25/113 Yield

Conditions & References

75.6 %

absence of moist, 24h, 180-230°C, every 30 min ICl removed,; removing of (HNCO)3: sublimation (220-230°C, 0.1 Torr), purity >99 Gottardi; Monatshefte fuer Chemie; vol. 101; (1970); p. 655,656,658,660 View in Reaxys vol. C: MVol.D3; 5.6.3, page 147 - 148 ; (from Gmelin) View in Reaxys

Cl I

Rx-ID: 26083352 View in Reaxys 26/113 Yield

Conditions & References in tetrachloromethane, other Radiation; δ-radiation of I2 soln. in CCl4 saturated with air; Bibler, N. E.; Journal of Chemical Education; vol. 45; (1968); p. 722 - 724 View in Reaxys vol. C: MVol.D2; 4.1.2.7.4.2, page 222 - 225 ; (from Gmelin) View in Reaxys

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Iodine monochloride [ICl or ClI]

I Cl

Rx-ID: 26342337 View in Reaxys 27/113 Yield

Conditions & References in neat (no solvent), Kinetics, gas phase equilibrium at 620-740°C; mechanism discussed; enthalpy of reaction; Lord et al.; Journal of Physical Chemistry; vol. 71; (1967); p. 2705 ; (from Gmelin) View in Reaxys in neat (no solvent), enthalpy of formation given; Lord et al.; Journal of Physical Chemistry; vol. 71; (1967); p. 2705 ; (from Gmelin) View in Reaxys in neat (no solvent), enthalpy of formation given; vol. C: MVol.D2; 4.2.2.1, page 292 - 293 ; (from Gmelin) View in Reaxys vol. C: MVol.D2; 4.2.2.5.6, page 304 - 305 ; (from Gmelin) View in Reaxys

ClHgI

Cl 2Hg

Rx-ID: 26552099 View in Reaxys 28/113 Yield

Conditions & References in ethanol Lassaigne, M.; Ann. Chim. Phys.; vol. 63; (1836); p. 106 - 111 View in Reaxys Schulek, E.; Burger, K.; Talanta; vol. 7; (1960); p. 41 - 45 ; (from Gmelin) View in Reaxys in water Schulek, E.; Burger, K.; Talanta; vol. 7; (1960); p. 41 - 45 ; (from Gmelin) View in Reaxys in acetic acid Schulek, E.; Burger, K.; Talanta; vol. 7; (1960); p. 41 - 45 ; (from Gmelin) View in Reaxys in water vol. Hg: MVol.B2; 257, page 943 - 945 ; (from Gmelin) View in Reaxys in ethanol vol. Hg: MVol.B2; 257, page 943 - 945 ; (from Gmelin) View in Reaxys in acetic acid vol. Hg: MVol.B2; 257, page 943 - 945 ; (from Gmelin) View in Reaxys

Rx-ID: 26436539 View in Reaxys 29/113 Yield

Conditions & References With water, hydrogenchloride in water, Kinetics, byproducts: I2, NH4Cl; at 30-45°C, further intermediate Bodnar, L. E.; Cleave, A. B. Van; Canadian Journal of Chemistry; vol. 31; (1953); p. 923 - 936

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Iodine monochloride [ICl or ClI]

View in Reaxys vol. C: MVol.D3; 6.2.6.6.7.1, page 257 - 258 ; (from Gmelin) View in Reaxys With water, hydrogenchloride in 1,4-dioxane, Kinetics, byproducts: I2, NH4Cl; at 30-45°C, further intermediate Bodnar, L. E.; Cleave, A. B. Van; Canadian Journal of Chemistry; vol. 31; (1953); p. 923 - 936 View in Reaxys vol. C: MVol.D3; 6.2.6.6.7.1, page 257 - 258 ; (from Gmelin) View in Reaxys

Cl Cl

I– (v2)

Cl Cl

ClK

P+ ClCl

Cl Cl – Cl P Cl Cl

K+

Rx-ID: 26561152 View in Reaxys 30/113 Yield

Conditions & References in further solvent(s), react. of a soln. of PCl6I in ICl (0.0535 mol PCl6I/mol ICl) with KCl; formation of KICl2, eqilibrium react. of PCl6I with KICl2 forming ICl and KPCl6;; detected by conductometric titration; KPCl6 not isolated; Gutmann, V.; Research (London); vol. 3; (1950); p. 337 - 338 View in Reaxys Gutmann, V.; Monatshefte fuer Chemie; vol. 83; (1952); p. 583 - 590 View in Reaxys vol. P: MVol.C; 232, page 531 - 533 ; (from Gmelin) View in Reaxys Cl

Cl Cl

I– (v2)

Cl Cl

P+ ClCl

PCl Cl

Rx-ID: 26588683 View in Reaxys 31/113 Yield

Conditions & References in tetrachloromethane, dissociation in CCl4;; detected by spectroscopy; Popov; Schmorr; Journal of the American Chemical Society; vol. 74; (1952); p. 4672 ; (from Gmelin) View in Reaxys in tetrachloromethane, dissociation in CCl4;; detected by spectroscopy; vol. P: MVol.C; 232, page 531 - 533 ; (from Gmelin) View in Reaxys

Cl Cl SbCl Cl

I– (v2)

Cl Cl

P+ ClCl

– Cl SbCl Cl Cl Cl

Rx-ID: 26588687 View in Reaxys 32/113 Yield

Conditions & References in further solvent(s), react. of a soln. of PCl6I in ICl with SbCl5; react. of PCl6I with formed ISbCl6 forming ICl and PCl4SbCl6; Gutmann, V.; Z. Anorg. Chem.; vol. 264; (1951); p. 151 - 168 View in Reaxys vol. P: MVol.C; 232, page 531 - 533 ; (from Gmelin) View in Reaxys

I I

Rx-ID: 26478080 View in Reaxys 33/113 Yield

Conditions & References With chlorine in neat (no solvent), Irradiation (UV/VIS); velocity of reaction depending on UV-radiation;

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Iodine monochloride [ICl or ClI]

Banus, J.; Emeleus, H. J.; Haszeldine, R. N.; Journal of the Chemical Society; (1950); p. 3041 - 3045 View in Reaxys vol. C: MVol.D2; 4.2.4.4.5, page 319 - 320 ; (from Gmelin) View in Reaxys Cl( 1-)

H( 1+)

Cl 2Pb

Rx-ID: 26083115 View in Reaxys 34/113 Yield

Conditions & References in diethyl ether, water, Electrochem. Process SATOR; Comptes rendus hebdomadaires des séances de l'Académie des sciences; vol. 229; nb. 22; (1949); p. 1142 - 1142 View in Reaxys vol. Cl: SVol.A; 131, page 298 - 301 ; (from Gmelin) View in Reaxys Cl( 1-)

I(1+)

Cl 2Pb

Rx-ID: 26109381 View in Reaxys 35/113 Yield

(v1)

2+Hg

(v1)

O–

Cl 2Hg

Rx-ID: 26621724 View in Reaxys 36/113 Yield

Conditions & References With hydrogenchloride in neat (no solvent), on heating; Lefort, J.; Journal de Pharmacie et de Chimie; vol. 8; (1845); p. 5 - 18 View in Reaxys Castagnou, R.; Devasle, M.; Bull. Trav. Soc. Pharm. Bordeaux; vol. 84; (1946); p. 67 - 70 ; (from Gmelin) View in Reaxys With HCl vol. Hg: MVol.B2; 247, page 923 - 925 ; (from Gmelin) View in Reaxys O

O– O

Cl OO

N+ O

I O

Rx-ID: 26551928 View in Reaxys 37/113 Yield

Conditions & References in neat (no solvent), heating; Gordon, W. E.; Spinks, J. W. T.; Canadian Journal of Research, Section B: Chemical Sciences; vol. 18; (1940); p. 358 - 362 ; (from Gmelin) View in Reaxys in neat (no solvent), heating; vol. Cl: SVol.B2; 102, page 536 - 538 ; (from Gmelin) View in Reaxys

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Iodine monochloride [ICl or ClI]

Cl I

Rx-ID: 26483535 View in Reaxys 38/113 Yield

Conditions & References at 77 °C and common pressure Caglioti, V.; Centola, G.; Gazzetta Chimica Italiana; vol. 63; (1933); p. 909 - 914 ; (from Gmelin) View in Reaxys in acetic acid, not isolated; Stortenbeker, W.; Z. phys. Ch.; vol. 10; (1892); p. 188 - 188 View in Reaxys Stortenbeker, W.; Z. phys. Ch.; vol. 10; (1892); p. 190 - 190 View in Reaxys vol. I: MVol.2; 170, page 623 - 625 ; (from Gmelin) View in Reaxys in tetrachloromethane, at ambient temp.; Gillam, A. E.; Morton, R. A.; Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences; vol. 124; (1929); p. 606 - 606 View in Reaxys vol. I: MVol.2; 170, page 623 - 625 ; (from Gmelin) View in Reaxys

>99, >99

in neat (no solvent), at 77°C and atmospheric pressure; also at excess of chlorine; Melikoff, P.; Ber.; vol. 8; (1875); p. 490 - 490 ; (from Gmelin) View in Reaxys in neat (no solvent), easily decomn.; Gosselin, A.; Gosselin, M.; Journal de Chimie Physique et de Physico-Chimie Biologique; vol. 26; (1929); p. 350 - 350 ; (from Gmelin) View in Reaxys in neat (no solvent), equilibrium; Koenigsberger, J.; Kuepferer, K.; Annalen der Physik (Weinheim, Germany); vol. 37; (1912); p. 639 - 639 View in Reaxys Gosselin, A.; Gosselin, M.; Journal de Chimie Physique et de Physico-Chimie Biologique; vol. 26; (1929); p. 350 - 350 ; (from Gmelin) View in Reaxys in neat (no solvent), heating in air or indifferent gas to 25°C; Brenken, O.; Ber.; vol. 8; (1877); p. 488 - 488 ; (from Gmelin) View in Reaxys in neat (no solvent), in Cl2 atmosphere; at 67°C;; cooling down to 60°C recombination to ICl3; Brenken, O.; Ber.; vol. 8; (1877); p. 488 - 488 ; (from Gmelin) View in Reaxys in nitrobenzene, not isolated; Bruner, L.; Galecki, A.; Z. phys. Ch.; vol. 84; (1913); p. 549 - 549 View in Reaxys vol. I: MVol.2; 170, page 623 - 625 ; (from Gmelin) View in Reaxys at 77 °C and common pressure vol. K: MVol.3; 2.5, page 652 - 660 ; (from Gmelin)

12/31

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Iodine monochloride [ICl or ClI]

View in Reaxys in water, dissociation; Forbes, G. S.; Glass, S. W.; Fuoss, R. M.; Journal of the American Chemical Society; vol. 47; (1925); p. 2892 - 2903 View in Reaxys vol. Cl: SVol.A; 113, page 259 - 261 ; (from Gmelin) View in Reaxys in neat (no solvent), in Cl2 atmosphere; at 67°C;; cooling down to 60°C recombination to ICl3; vol. I: MVol.2; 169, page 621 - 623 ; (from Gmelin) View in Reaxys >99, >99

in neat (no solvent), at 77°C and atmospheric pressure; also at excess of chlorine; vol. I: MVol.2; 168, page 619 - 621 ; (from Gmelin) View in Reaxys in neat (no solvent), easily decomn.; vol. I: MVol.2; 168, page 619 - 621 ; (from Gmelin) View in Reaxys in neat (no solvent), equilibrium; vol. I: MVol.2; 168, page 619 - 621 ; (from Gmelin) View in Reaxys in neat (no solvent), heating in air or indifferent gas to 25°C; vol. I: MVol.2; 169, page 621 - 623 ; (from Gmelin) View in Reaxys K+

Cl Cl

ClK

(v4) I–

ClCl

Rx-ID: 26606309 View in Reaxys 39/113 Yield

Conditions & References at higher temp. Caglioti, V.; Centola, G.; Gazzetta Chimica Italiana; vol. 63; (1933); p. 909 - 914 ; (from Gmelin) View in Reaxys between 67.5-85 °C Caglioti, V.; Centola, G.; Gazzetta Chimica Italiana; vol. 63; (1933); p. 909 - 914 ; (from Gmelin) View in Reaxys at higher temp. vol. K: MVol.3; 2.5, page 652 - 660 ; (from Gmelin) View in Reaxys between 67.5-85 °C vol. K: MVol.3; 2.5, page 652 - 660 ; (from Gmelin) View in Reaxys

I– (v2)

Cs +

I– (v2)

Cs +

Rx-ID: 26618746 View in Reaxys 40/113 Yield

Conditions & References in neat (no solvent), mechanism discussed; Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 182 ; (from Gmelin)

13/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

View in Reaxys in neat (no solvent), mechanism discussed; Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1933); p. 183 - 183 View in Reaxys vol. I: MVol.2; 76, page 415 - 417 ; (from Gmelin) View in Reaxys I

Cl( 1-)

Rx-ID: 26367736 View in Reaxys 41/113 Yield

Conditions & References in water Flatt, R.; Boname, A.; Bulletin de la Societe Chimique de France; vol. 51; (1932); p. 764 - 764 View in Reaxys vol. I: MVol.2; 46, page 350 - 352 ; (from Gmelin) View in Reaxys

F I F F F

Rx-ID: 26475525 View in Reaxys 42/113 Yield

Conditions & References in tetrachloromethane, byproducts: Cl2, CCl3F; at ambient temp.; Ruff, O.; Keim, R.; Z. Anorg. Chem.; vol. 201; (1931); p. 249 - 249 ; (from Gmelin) View in Reaxys in tetrachloromethane, byproducts: Cl2, CCl3F; at ambient temp.; vol. I: MVol.2; 159, page 600 - 602 ; (from Gmelin) View in Reaxys K+ Cl

(v2)

ClK

–I

Rx-ID: 26585627 View in Reaxys 43/113 Yield

Conditions & References decompn. at 180 °C Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1931); p. 2252 ; (from Gmelin) View in Reaxys decompn. at 180 °C vol. K: MVol.3; 2.5, page 652 - 660 ; (from Gmelin) View in Reaxys

I– (v2)

Cs +

Rx-ID: 26618744 View in Reaxys 44/113 Yield

Conditions & References in not given, removal of ICl from CsICl2 with organic solvents; Cremer, H. W.; Duncan, D. R.; Journal of the Chemical Society; (1931); p. 2248 ; (from Gmelin) View in Reaxys in not given, removal of ICl from CsICl2 with organic solvents; vol. Cs: MVol.2; 54, page 209 - 210 ; (from Gmelin)

14/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

View in Reaxys 5 Hg 2+

HO –

2 –O– I O – O O O–

H O

As HO OH O

Cl 2Hg

Rx-ID: 26623780 View in Reaxys 45/113 Yield

Conditions & References With hydrogenchloride in water, concd. HCl; Willard, H. H.; Thompson, J. J.; Industrial and Engineering Chemistry, Analytical Edition; vol. 3; (1931); p. 398 - 399 View in Reaxys vol. Hg: MVol.B2; 249, page 927 - 929 ; (from Gmelin) View in Reaxys

I(1-)

Rx-ID: 26109467 View in Reaxys 46/113 Yield

Conditions & References With hydrogenchloride, cerium (IV) sulfate in hydrogenchloride, strongly acidic solution; Berry, A. J.; Analyst (Cambridge, United Kingdom); vol. 54; (1929); p. 463 - 463 View in Reaxys Swift, E. H.; Journal of the American Chemical Society; vol. 52; (1930); p. 894 - 894 ; (from Gmelin) View in Reaxys in hydrogenchloride vol. I: MVol.2; 48, page 354 - 356 ; (from Gmelin) View in Reaxys O

I(1-)

O–

Rx-ID: 26109568 View in Reaxys 47/113 Yield

Conditions & References in not given, acidic soln.; ClO3(1-) : I(1-) = 1 : 3; Magidson, O. I.; Baitschikow, A. G.; Zh. Russ. Fiz. - Khim. O - va., Chast Khim.; vol. 62; (1930); p. 956 - 956 View in Reaxys vol. I: MVol.2; 149, page 576 - 578 ; (from Gmelin) View in Reaxys

Rx-ID: 26399768 View in Reaxys 48/113 Yield

Conditions & References in hydrogenchloride, passing Cl2 into soln. of KI in concd. HCl;; not isolated; Patent; anonymous; Schering-Kahlbaum Akt.-Ges.; DE512563; (1930) ; (from Gmelin) View in Reaxys in hydrogenchloride vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys Cl

F F

F F I F F F

Rx-ID: 26493816 View in Reaxys 49/113

15/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

Yield

Conditions & References With Cl2 in neat (no solvent), on heating; Ruff, O.; Keim, R.; Z. Anorg. Chem.; vol. 193; (1930); p. 176 - 176 View in Reaxys vol. I: MVol.2; 160, page 602 - 604 ; (from Gmelin) View in Reaxys -1 Cl N

(v4)

I ClCl

H+

Rx-ID: 8240546 View in Reaxys 50/113 Yield

Conditions & References ueber den Schmelzpunkt Chattaway; Garton; Journal of the Chemical Society; vol. 125; (1924); p. 187 View in Reaxys

I–

thallium(III)-chloride

Sn2+

diethyl tin dichloride

metallic thallium Rx-ID: 8280104 View in Reaxys 51/113

Yield

Conditions & References Goddard,A.E.; Journal of the Chemical Society; vol. 121; (1922); p. 259 View in Reaxys Cl

I(1-)

O–

Rx-ID: 26414786 View in Reaxys 52/113 Yield

Conditions & References in water, strongly acidic soln.;; very small amounts of IO3(1-), ICl and ICl3; Kolthoff, I. M.; Rec. Trav. chim.; vol. 41; (1922); p. 623 - 623 View in Reaxys vol. I: MVol.2; 138, page 554 - 556 ; (from Gmelin) View in Reaxys

Cl N

Rx-ID: 26366517 View in Reaxys 53/113 Yield

Conditions & References in tetrachloromethane, addn. of NCl3 to soln. of I2 in CCl4; Dowell, C. T.; Bray, W. C.; Journal of the American Chemical Society; vol. 39; (1917); p. 902 - 902 ; (from Gmelin) View in Reaxys in tetrachloromethane vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys OH

CdS HO

S OO

CdCl 2

Rx-ID: 26098488 View in Reaxys 54/113 Yield

Conditions & References With potassium iodate in not given, byproducts: S, KCl, H2O; oxidation with KIO3 in presence of HCl;

16/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

Dean, R. S.; Journal of the American Chemical Society; vol. 37; (1915); p. 1134 - 1137 ; (from Gmelin) View in Reaxys With KIO3 in not given, byproducts: S, KCl, H2O; oxidation with KIO3 in presence of HCl; vol. Cd: MVol.; 47, page 119 - 120 ; (from Gmelin) View in Reaxys OH

SZn HO

ClK

S OO

Cl 2Zn

Rx-ID: 26104972 View in Reaxys 55/113 Yield

Conditions & References With hydrogenchloride, potassium iodate in not given, byproducts: S, H2O; oxidation with KIO3; HCl-concentration: 65 vol.percent HCl; Dean, Reginald S.; Journal of the American Chemical Society; vol. 37; (1915); p. 1136 - 1136 View in Reaxys vol. Zn: MVol.; 75, page 205 - 207 ; (from Gmelin) View in Reaxys

SZn

ClK

Cl 2Zn

Rx-ID: 26104973 View in Reaxys 56/113 Yield

Conditions & References With hydrogenchloride, potassium iodate in not given, byproducts: S, H2O; oxidation with KIO3; HCl-concentration: < 15 vol.percent HCl; Dean, Reginald S.; Journal of the American Chemical Society; vol. 37; (1915); p. 1136 - 1136 View in Reaxys vol. Zn: MVol.; 75, page 205 - 207 ; (from Gmelin) View in Reaxys

Cl Cl SbCl Cl

Rx-ID: 26167027 View in Reaxys 57/113 Yield

Conditions & References With potassium iodide, composition of double salt with excess KI Moles, E.; Z. phys. Ch.; vol. 90; (1915); p. 83 ; (from Gmelin) View in Reaxys vol. Sb: MVol.B2; 9.6, page 443 - 447 ; (from Gmelin) View in Reaxys

Cl Cl SbCl Cl Cl

(v0) Cl SbCl Cl

Sb Cl

Sb I

Rx-ID: 26167028 View in Reaxys 58/113 Yield 0%

Conditions & References byproducts: antimony(V) chloroiodide; room temp. Moles, E.; Z. phys. Ch.; vol. 90; (1915); p. 77 - 84 View in Reaxys Ruff, O.; Zender, J.; Hecht, L.; Ber.; vol. 48; (1915); p. 2070 ; (from Gmelin) View in Reaxys vol. Sb: MVol.B2; 9.6, page 443 - 447 ; (from Gmelin) View in Reaxys

17/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

Cl SbCl Cl

Sb Cl

SbCl5#ICl

Rx-ID: 26167029 View in Reaxys 59/113 Yield

Conditions & References With iodine, room temp., finely powdered I2; stirring Moles, E.; Z. phys. Ch.; vol. 90; (1915); p. 77 - 84 View in Reaxys Ruff, O.; Zender, J.; Hecht, L.; Ber.; vol. 48; (1915); p. 2070 ; (from Gmelin) View in Reaxys vol. Sb: MVol.B2; 9.6, page 443 - 447 ; (from Gmelin) View in Reaxys

Cl SbCl Cl

Rx-ID: 26366637 View in Reaxys 60/113 Yield

Conditions & References in not given, from soln. of I2 in SbCl5;; precipitation; further product: ICl*(x)SbCl5; Ruff, O.; Zedner, J.; Hecht, L.; Ber.; vol. 48; (1915); p. 2070 - 2070 ; (from Gmelin) View in Reaxys in not given vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys

Cl SbCl Cl

Sb Cl Cl

Rx-ID: 26366638 View in Reaxys 61/113 Yield

Conditions & References in further solvent(s), I2 is dissolved in SbCl5 (reactn. proceeds with evolution of heat, the compounds SbCl3, ICl, ICl3 are formed in soln.; Moles, E.; Z. phys. Ch.; vol. 90; (1915); p. 77 - 77 View in Reaxys Ruff, O.; Zedner, J.; Hecht, L.; Ber.; vol. 48; (1915); p. 2068 - 2068 View in Reaxys vol. I: MVol.1; 55, page 182 - 183 ; (from Gmelin) View in Reaxys

(v2) I–

H H

N+ HH

Rx-ID: 26447835 View in Reaxys 62/113 Yield

Conditions & References slow reaction at room temp., fast by heating or in vacuum Chattaway, F. D.; Journal of the Chemical Society; vol. 107; (1915); p. 106 - 108 ; (from Gmelin) View in Reaxys slow reaction at room temp., fast by heating or in vacuum vol. NH4: MVol.1; 2.10.3, page 236 - 242 ; (from Gmelin) View in Reaxys

18/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

Cl SbCl Cl

SbCl5*2ICl#SbCl5*3ICl

Rx-ID: 26635311 View in Reaxys 63/113 Yield

Conditions & References heating of vapor Ruff, O.; Zender, J.; Hecht, L.; Ber.; vol. 48; (1915); p. 2071 - 2074 View in Reaxys vol. Sb: MVol.B2; 9.7, page 447 - 452 ; (from Gmelin) View in Reaxys

I 3 Cl

Cl SbCl Cl

Rx-ID: 26731000 View in Reaxys 64/113 Yield

Conditions & References in neat (no solvent), on heating; Ruff, O.; Zedner, J.; Hecht, L.; Ber.; vol. 48; (1915); p. 2073 - 2073 View in Reaxys vol. I: MVol.2; 167, page 616 - 618 ; (from Gmelin) View in Reaxys

I 2 Cl

Cl SbCl Cl

Rx-ID: 26731701 View in Reaxys 65/113 Yield

Rx-ID: 26367724 View in Reaxys 66/113 Yield

Conditions & References With hydrogenchloride in water, byproducts: H2O; equilibrium; Kurtenacker, A.; Monatshefte fuer Chemie; vol. 35; (1914); p. 451 - 451 View in Reaxys Kurtenacker, A.; Monatshefte fuer Chemie; vol. 35; (1914); p. 459 - 459 View in Reaxys Kurtenacker, A.; Monatshefte fuer Chemie; vol. 35; (1914); p. 461 - 461 ; (from Gmelin) View in Reaxys With HCl in water, byproducts: H2O; equilibrium; vol. I: MVol.2; 115, page 494 - 496 ; (from Gmelin) View in Reaxys

–O

O I O

K+ HO

S OO

ClK

H O

Rx-ID: 26532350 View in Reaxys 67/113 Yield

Conditions & References With hydrogenchloride, sulfur dioxide, water

19/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

Jamieson, G. S.; Am. J. Sci.; vol. 38; (1914); p. 166 - 168 View in Reaxys vol. S: MVol.B2; 1.6.2.5, page 520 - 522 ; (from Gmelin) View in Reaxys O

Cl I

Rx-ID: 26483533 View in Reaxys 68/113 Yield

Conditions & References With water in water, mechanism discussed; Skrabal, A.; Buchta, F.; Chemiker-Zeitung; vol. 33; (1909); p. 1194 - 1194 ; (from Gmelin) View in Reaxys With H2O in water, mechanism discussed; vol. I: MVol.2; 172, page 626 - 628 ; (from Gmelin) View in Reaxys O

O +I

O–

Rx-ID: 26588611 View in Reaxys 69/113 Yield

Conditions & References With hydrogenchloride in hydrogenchloride, byproducts: Cl2; heating with concd. cold HCl; on longer heating with excess of concd. HCl decompn. of HIO3; Millon, E.; Ann. Chim. Phys.; vol. 12; (1844); p. 353 - 353 View in Reaxys Millon, E.; Journal fuer Praktische Chemie (Leipzig); vol. 34; (1845); p. 337 - 337 ; (from Gmelin) View in Reaxys With HCl in hydrogenchloride, byproducts: Cl2; heating with concd. cold HCl; on longer heating with excess of concd. HCl decompn. of HIO3; Muir, M. M. P.; Journal of the Chemical Society; vol. 95; (1909); p. 658 - 658 View in Reaxys vol. I: MVol.2; 85, page 434 - 436 ; (from Gmelin) View in Reaxys

Rx-ID: 26374388 View in Reaxys 70/113 Yield

Conditions & References in neat (no solvent), passing CH3I vapor (excess) in gaseous Cl2; Ilosvay, L. v.; Chemiker-Zeitung; vol. 31; (1907); p. 609 - 609 ; (from Gmelin) View in Reaxys in neat (no solvent), passing CH3I vapor (excess) in gaseous Cl2; vol. I: MVol.2; 168, page 619 - 621 ; (from Gmelin) View in Reaxys

I(1-)

Rx-ID: 26109541 View in Reaxys 71/113 Yield

Conditions & References in neat (no solvent), byproducts: metal chloride; formation from metal iodides and liquid Cl2; Thomas, V.; Dupuis, P.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 143; (1906); p. 282

20/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

View in Reaxys vol. I: MVol.2; 68, page 396 - 399 ; (from Gmelin) View in Reaxys Cl

Rx-ID: 7055004 View in Reaxys 72/113 Yield

Conditions & References beim Erwaermen ueber den Zersetzungspunkt Thiele; Peter; Chemische Berichte; vol. 38; (1905); p. 2844; Justus Liebigs Annalen der Chemie; vol. 369; (1909); p. 127 View in Reaxys

I H

Rx-ID: 7055005 View in Reaxys 73/113 Yield

Conditions & References Thiele; Peter; Chemische Berichte; vol. 38; (1905); p. 2844; Justus Liebigs Annalen der Chemie; vol. 369; (1909); p. 127 View in Reaxys

O Cl

–

K+

O I

K+

O–

Rx-ID: 26366961 View in Reaxys 74/113 Yield

Conditions & References With nitric acid in water, at higher concn.; KClO3/I2 ratio is 2:1 mol; Schloetter; Z. Anorg. Chem.; vol. 45; (1905); p. 270 - 270 View in Reaxys vol. Cl: MVol.; 118, page 316 - 318 ; (from Gmelin) View in Reaxys -3

(v1)

O–

As (v1)

O O (v1)

Rx-ID: 26440114 View in Reaxys 75/113 Yield

Conditions & References

>99

in hydrogenchloride, weakly acidic soln.; Andrews, L. W.; Z. Anorg. Chem.; vol. 36; (1903); p. 80 - 80 View in Reaxys Andrews, L. W.; Journal of the American Chemical Society; vol. 25; (1903); p. 759 - 759 View in Reaxys vol. I: MVol.2; 118, page 499 - 501 ; (from Gmelin) View in Reaxys O

O–

Cl Sb Cl

O–

Sb O

O–

Rx-ID: 26440124 View in Reaxys 76/113 Yield >99

Conditions & References in hydrogenchloride, weakly acidic soln.; Andrews, L. W.; Z. Anorg. Chem.; vol. 36; (1903); p. 80 - 80 View in Reaxys

21/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

Andrews, L. W.; Journal of the American Chemical Society; vol. 25; (1903); p. 759 - 759 View in Reaxys vol. I: MVol.2; 118, page 499 - 501 ; (from Gmelin) View in Reaxys

Rx-ID: 7055006 View in Reaxys 77/113 Yield

Conditions & References T= 20 - 30 °C Chattaway; Wadmore; Journal of the Chemical Society; vol. 81; (1902); p. 200 View in Reaxys O

Cl H

Rx-ID: 26377705 View in Reaxys 78/113 Yield

Conditions & References in water, formation of HIO3 at reaction of ICl3 with H2O; Weinland, R. F.; Schlegelmilch, F.; Z. Anorg. Chem.; vol. 30; (1902); p. 134 - 143 View in Reaxys Schlegelmilch, F.; Diss. Muenchen 1901, S. 6-14 ; (from Gmelin) View in Reaxys in water, formation of HIO3 at reaction of ICl3 with H2O; vol. Ca: MVol.B2; 140, page 628 - 630 ; (from Gmelin) View in Reaxys

Rx-ID: 26436535 View in Reaxys 79/113 Yield

Conditions & References

With hydrogenchloride in water Chattaway, F. D.; Wadmore, J. D.; Journal of the Chemical Society; vol. 81; (1902); p. 191 - 203 View in Reaxys vol. C: MVol.D3; 6.2.6.6.7.3, page 259 - 260 ; (from Gmelin) View in Reaxys

Rx-ID: 26436538 View in Reaxys 80/113 Yield

Conditions & References With hydrogenchloride Chattaway, F. D.; Wadmore, J. M.; Journal of the Chemical Society; vol. 81; (1902); p. 197 - 197 View in Reaxys vol. I: MVol.2; 96, page 456 - 457 ; (from Gmelin) View in Reaxys

S Cl

O S

Rx-ID: 26083340 View in Reaxys 81/113 Yield

Conditions & References in neat (no solvent), presence of AlI3; vigorous reaction; Ruff, O.; Ber.; vol. 34; (1901); p. 1749 - 1758

22/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

View in Reaxys vol. S: MVol.B3; 135, page 1815 - 1817 ; (from Gmelin) View in Reaxys in neat (no solvent), presence of AlCl3; Ruff, O.; Ber.; vol. 34; (1901); p. 1749 - 1758 View in Reaxys vol. S: MVol.B3; 135, page 1815 - 1817 ; (from Gmelin) View in Reaxys Cl

Cl I

Rx-ID: 26083341 View in Reaxys 82/113 Yield

Conditions & References in not given, in presence of AlCl3; vol. I: MVol.1; 55, page 182 - 183 View in Reaxys Ruff, O.; Ber.; vol. 34; (1901); p. 1752 - 1752 ; (from Gmelin) View in Reaxys Cl

Cl Al

Cl I

Rx-ID: 26366528 View in Reaxys 83/113 Yield

Conditions & References in sulfuryl dichloride Ruff, O.; Ber.; vol. 34; (1901); p. 1752 - 1752 ; (from Gmelin) View in Reaxys in sulfuryl dichloride vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys

S Cl

Rx-ID: 26366583 View in Reaxys 84/113 Yield

I2Mo

Rx-ID: 26501452 View in Reaxys 85/113 Yield

Conditions & References With Cl2 in neat (no solvent), react. of MoI2 with Cl2 below 240°C; Guichard, M.; Ann. Chim. Phys.; vol. 23; (1901); p. 566 - 566

23/31

2018-07-17 15:29:30

Iodine monochloride [ICl or ClI]

View in Reaxys Guichard, M.; Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences; vol. 123; (1896); p. 821 - 821 View in Reaxys vol. Mo: MVol.; 64, page 179 - 181 ; (from Gmelin) View in Reaxys I

(v4)

Pt I I

Rx-ID: 26344338 View in Reaxys 86/113 Yield

Conditions & References With chlorine, in cold Pigeon, L.; Ann. Chim. Phys.; vol. 2 {7}; (1894); p. 491 - 496 ; (from Gmelin) View in Reaxys With Cl2, in cold vol. Pt: MVol.C1; 7.2, page 99 - 103 ; (from Gmelin) View in Reaxys

(v4)

Pt I I

(v4)

Pt ClCl

Rx-ID: 26344339 View in Reaxys 87/113 Yield

Conditions & References With chlorine, in cold Cl2 flow Pigeon, L.; Ann. Chim. Phys.; vol. 2 {7}; (1894); p. 448 ; (from Gmelin) View in Reaxys With Cl2, in cold Cl2 flow vol. Pt: MVol.C1; 6.2, page 64 - 68 ; (from Gmelin) View in Reaxys

Rx-ID: 26399692 View in Reaxys 88/113 Yield

Conditions & References With sodium nitrite in hydrogenchloride, addn. of sodium nitrite to strongly HCl acidic KI soln.;; not isolated from solution; anonymous; Dinglers Polytech. J.; vol. 256; (1885); p. 324 - 324 View in Reaxys Patent; anonymous; Chemische Fabrik auf Actien, vormals E. Schering; DE30358; (1884) ; (from Gmelin) View in Reaxys in hydrogenchloride vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys

HgCl2#HgI2

Cl 2Hg

Rx-ID: 26622425 View in Reaxys 89/113 Yield

Conditions & References With chlorine, dry chlorine; formation of heat; Koehler, H.; Hellebreckers; Ber. Dtsch. Chem. Ges.; vol. 12; (1879); p. 1187 - 1191 ; (from Gmelin) View in Reaxys With Cl2, dry chlorine; formation of heat; vol. Hg: MVol.B2; 256, page 942 - 943 ; (from Gmelin)

Copyright ÂŠ 2018 Elsevier Life Sciences IP Limited except certain content provided by third parties. Reaxys is a trademark of Elsevier Life Sciences IP Limited.

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Iodine monochloride [ICl or ClI]

View in Reaxys Cl

Cl I

Cl Cl

Rx-ID: 26483532 View in Reaxys 90/113 Yield

Conditions & References With carbon monoxide in neat (no solvent), in CO atmosphere; Christomanos, A. C.; Ber.; vol. 10; (1877); p. 438 - 438 ; (from Gmelin) View in Reaxys With CO in neat (no solvent), in CO atmosphere; vol. I: MVol.2; 169, page 621 - 623 ; (from Gmelin) View in Reaxys

Cl I

Rx-ID: 26483534 View in Reaxys 91/113 Yield

Conditions & References With hydrogen in neat (no solvent), passing H2 over moderately heated ICl3; Christomanos, A. C.; Ber.; vol. 10; (1877); p. 440 - 440 ; (from Gmelin) View in Reaxys With H2 in neat (no solvent), passing H2 over moderately heated ICl3; vol. I: MVol.2; 169, page 621 - 623 ; (from Gmelin) View in Reaxys Cl

Cl I

Cl Cl

Rx-ID: 26483551 View in Reaxys 92/113 Yield

Conditions & References in neat (no solvent), in CO2 atmosphere; Christomanos, A. C.; Ber.; vol. 10; (1877); p. 438 - 438 ; (from Gmelin) View in Reaxys in neat (no solvent), in CO2 atmosphere; vol. I: MVol.2; 169, page 621 - 623 ; (from Gmelin) View in Reaxys Cl

I Sb

Rx-ID: 26475426 View in Reaxys 93/113 Yield

Conditions & References With chlorine, with Cl2 gas MacIvor, R. W. E.; Journal of the Chemical Society; vol. 29; (1876); p. 329 View in Reaxys vol. Sb: MVol.B2; 13.3, page 492 - 494 ; (from Gmelin) View in Reaxys

Cl 2Hg

HgI 2

Rx-ID: 26083508 View in Reaxys 94/113

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Iodine monochloride [ICl or ClI]

Yield

Conditions & References in water, 6h heating to 250°C in sealed tube; vol. Hg: MVol.B2; 71, page 546 - 548 ; (from Gmelin) View in Reaxys in water, 6h heating to 250°C in sealed tube; Gramp, F.; Ber. Dtsch. Chem. Ges.; vol. 7; (1874); p. 1721 - 1723 ; (from Gmelin) View in Reaxys in not given, at heating to 250°C in sealed tube; molar rate = 1:1; Gramp, F.; Ber. Dtsch. Chem. Ges.; vol. 7; (1874); p. 1721 - 1723 ; (from Gmelin) View in Reaxys in water Millon, E.; Ann. Chim. Phys.; vol. 18; (1846); p. 333 - 443 View in Reaxys vol. Hg: MVol.B2; 257, page 943 - 945 ; (from Gmelin) View in Reaxys in ethanol Millon, E.; Ann. Chim. Phys.; vol. 18; (1846); p. 333 - 443 View in Reaxys vol. Hg: MVol.B2; 257, page 943 - 945 ; (from Gmelin) View in Reaxys vol. Hg: MVol.B2; 51, page 503 - 505 ; (from Gmelin) View in Reaxys I

Cl 2Pt

Rx-ID: 26184700 View in Reaxys 95/113 Yield

Conditions & References With iodine in not given, at room temp. Gramp, F.; Ber.; vol. 7; (1874); p. 1723 ; (from Gmelin) View in Reaxys With I2 in not given, at room temp. vol. Pt: MVol.C1; 6.1, page 59 - 64 ; (from Gmelin) View in Reaxys

Cl Au

AuI

(v3)

Rx-ID: 26485674 View in Reaxys 96/113 Yield

Conditions & References With iodine in not given, ambient temp., slowly Gramp, F.; Ber.; vol. 7; (1874); p. 1721 - 1723 View in Reaxys vol. Au: MVol.3; 7.1, page 657 - 659 ; (from Gmelin) View in Reaxys With iodine in not given, ambient temp. Gramp, F.; Ber.; vol. 7; (1874); p. 1721 - 1723 ; (from Gmelin) View in Reaxys With I2 in not given, ambient temp.

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Iodine monochloride [ICl or ClI]

vol. Au: MVol.3; 9.2, page 711 - 716 ; (from Gmelin) View in Reaxys Cl I

Rx-ID: 26366616 View in Reaxys 97/113 Yield

Conditions & References in melt, melting equimolar amounts;; pure; Linnemann, E.; Liebigs Annalen der Chemie; vol. 161; (1872); p. 38 - 38 ; (from Gmelin) View in Reaxys in melt vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys

(v1)

2+Hg 5 Hg

(v1) O– –

2 –O– I OO– O O

Rx-ID: 26621660 View in Reaxys 98/113 Yield

Conditions & References With hydrogenchloride in hydrogenchloride, at warming; Lautsch, C. G.; Journal fuer Praktische Chemie (Leipzig); vol. 100; (1867); p. 65 - 100 View in Reaxys vol. Hg: MVol.B2; 249, page 927 - 929 View in Reaxys Dick, J.; Diss. Freiburg i. Br. 1890, S. 30 ; (from Gmelin) View in Reaxys

–O

Ca 2+

2 Cl

Rx-ID: 26366161 View in Reaxys 99/113 Yield

Conditions & References in ethanol, addn. of Ca(OCl)2 to soln. of I2 in alc.; Flight, W.; Z. Gesamte Naturwiss.; vol. 23; (1864); p. 250 - 250 ; (from Gmelin) View in Reaxys in ethanol vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys Ca 2+

Ca 2+ Cl

O–

–O

O I

Cl –

Rx-ID: 26366690 View in Reaxys 100/113 Yield

Conditions & References in ethanol, at elevated temp.; Dingler, E. M.; Dinglers Polytech. J.; vol. 26; (1827); p. 229 - 229 View in Reaxys Flight, W.; Z. Gesamte Naturwiss.; vol. 23; (1864); p. 250 - 250 View in Reaxys vol. I: MVol.1; 57, page 185 - 187 ; (from Gmelin) View in Reaxys

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Iodine monochloride [ICl or ClI]

O I

O–

I O

K+

ClK

Rx-ID: 26600943 View in Reaxys 101/113 Yield

Conditions & References byproducts: I2, O2, KCl; at higher temp. Rammelsberg, C. F.; Annalen der Physik (Weinheim, Germany); vol. 97; (1856); p. 93 ; (from Gmelin) View in Reaxys byproducts: I2, O2, KCl; at higher temp. vol. K: MVol.3; 3.5, page 678 - 680 ; (from Gmelin) View in Reaxys

Rx-ID: 26082942 View in Reaxys 102/113 Yield

Conditions & References With aqua regia in not given, oxidation; Trapp, J.; Bull. Acad. Imp. Sci. St. - Petersbourg; vol. 13; (1855); p. 13 - 13 View in Reaxys Trapp, J.; Journal fuer Praktische Chemie (Leipzig); vol. 63; (1854); p. 108 - 108 View in Reaxys vol. I: MVol.1; 51, page 175 - 177 ; (from Gmelin) View in Reaxys

Cl 2Hg

Rx-ID: 26083507 View in Reaxys 103/113 Yield

Conditions & References in water Selmi, F.; L'Institut I; vol. 12; (1844); p. 412 - 412 View in Reaxys vol. Hg: MVol.B2; 71, page 546 - 548 ; (from Gmelin) View in Reaxys

Cl Pt I I (v4)

Rx-ID: 26436682 View in Reaxys 104/113 Yield

Conditions & References heating at 205-315 °C; spongy Pt remins Mather, W. W.; Am. J. Sci.; vol. 27; (1835); p. 258 ; (from Gmelin) View in Reaxys heating at 205-315 °C; spongy Pt remins vol. Pt: MVol.C1; 7.2, page 99 - 103 ; (from Gmelin) View in Reaxys

Cl O

Rx-ID: 26366243 View in Reaxys 105/113 Yield

Conditions & References in neat (no solvent), from gaseous Cl2O and I2;

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Iodine monochloride [ICl or ClI]

Balard, A. J.; Ann. Chim. Phys.; vol. 57; (1834); p. 275 - 275 ; (from Gmelin) View in Reaxys byproducts: iodic acid Balard; Ann. Chim. Phys.; vol. 57; (1834); p. 275 - 275 View in Reaxys vol. Cl: MVol.; 84, page 232 - 234 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys O OH

I HO

OH OH

Rx-ID: 26518800 View in Reaxys 106/113 Yield

Conditions & References With hydrogenchloride, byproducts: Cl2 Ammermueller, F.; Magnus, G.; Liebigs Annalen der Chemie; vol. 11; (1834); p. 20 - 20 ; (from Gmelin) View in Reaxys With HCl, byproducts: Cl2 vol. I: MVol.2; 129, page 526 - 528 ; (from Gmelin) View in Reaxys 2 H+ -2

I (v4)

Cl Cl

Pt I I

(v6)

(v4)

Pt ClCl

Rx-ID: 26344337 View in Reaxys 107/113 Yield

Conditions & References With chlorine in water, composition of product depends on amount of Cl2 Lassaigne,; Ann. Chim. Phys.; vol. 51 {2}; (1832); p. 123 ; (from Gmelin) View in Reaxys With Cl2 in water, composition of product depends on amount of Cl2 vol. Pt: MVol.C1; 7.2, page 99 - 103 ; (from Gmelin) View in Reaxys

O Cl

K+

O–

Rx-ID: 26366960 View in Reaxys 108/113 Yield

Conditions & References distillation; Woehler, F.; Annalen der Physik (Weinheim, Germany); vol. 8; (1826); p. 95 - 95 View in Reaxys Woehler, F.; Jber. Berz.; vol. 7; (1828); p. 119 - 119 View in Reaxys vol. I: MVol.2; 84, page 432 - 433 View in Reaxys vol. I: MVol.2; 89, page 441 - 443 ; (from Gmelin) View in Reaxys

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Iodine monochloride [ICl or ClI]

in neat (no solvent), distillation; Woehler, F.; Annalen der Physik (Weinheim, Germany); vol. 8; (1826); p. 95 - 95 ; (from Gmelin) View in Reaxys in neat (no solvent) vol. I: MVol.2; 162, page 606 - 608 ; (from Gmelin) View in Reaxys O–

O O–

O–

I(1-)

Rx-ID: 26410986 View in Reaxys 109/113 Yield

Conditions & References With hydrogen cation in water, possible products: I, I2 or ICl, depending on reaction conditions vol. S: MVol.B2; 1.6.2.5, page 520 - 522 View in Reaxys Kurtenacker, A.; Analytische Chemie der Sauerstoffsaeuren des Schwefels, Stuttgart 1938 p. 81 ; (from Gmelin) View in Reaxys

O–

I(1-)

AgI

Rx-ID: 26411955 View in Reaxys 110/113 Yield

Rx-ID: 26436456 View in Reaxys 111/113 Yield

Conditions & References With hydrogenchloride in hydrogenchloride, fast decompn. with HCl to form N2 and I2, the latter redissolves forming ICl; Raschig, F.; Schwefel- und Stickstoffstudien, Leipzig-Berlin 1924, S. 45 ; (from Gmelin) View in Reaxys With HCl in hydrogenchloride, fast decompn. with HCl to form N2 and I2, the latter redissolves forming ICl; vol. I: MVol.2; 157, page 595 - 597 ; (from Gmelin) View in Reaxys

5 Hg 2+

O –

2 –O– I O – O O O–

Cl 2Hg

Rx-ID: 26623773 View in Reaxys 112/113 Yield

Conditions & References With hydrogenchloride in hydrogenchloride, on warming; excess of HCl; vol. Hg: MVol.B2; 249, page 927 - 929 View in Reaxys Dick, J.; Diss. Freiburg i. Br. 1890, S. 39 ; (from Gmelin) View in Reaxys

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Iodine monochloride [ICl or ClI]

(v1)

2+Hg

(v1)

2 O

O–

I OO

Cl 2Hg

Rx-ID: 26626037 View in Reaxys 113/113 Yield

Conditions & References With hydrogenchloride in hydrogenchloride, excess of HCl; vol. Hg: MVol.B2; 249, page 927 - 929 View in Reaxys Dick, J.; Diss. Freiburg i. Br. 1890, S. 36 ; (from Gmelin) View in Reaxys

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