Pathways to Decarbonizing the High Energy Intensive Mineral Sector

High-temperature processes (greater than 800 o C) are widely used in the mineral sector to produce materials vital to the global economy. These processes are driven more by heat than electricity and operate with high volumes and low-profit margins from capital-intensive plant in trade-exposed markets. These features create unique challenges and unique opportunities for the sector as it seeks pathways to decarbonization.

In order to explore the emergence of new technologies, and foster new opportunities, the inaugural High-Temperature Minerals Processing (HiTeMP) Forum convened in September 2018 bringing together 100+ industry, research and government stakeholders from around the world to discuss how to transform energy-intensive high temperature processes particularly in iron/ steel, alumina and cement/lime production.

OPPORTUNITIES BY SECTOR

The pathways toward CO2-free products vary significantly from one industry to another, although some technologies can be transferred between industries. The Hi- TeMP Forum identified key pathways for iron/steel making and cement/lime & alumina, which are responsible for some 8% and 7%, respectively, of global CO2 emissions.

- Iron and Steel

The most plausible first steps to further decarbonization are the replacement of the coking coal needed to reduce iron ore. Prime candidates for this are hydrogen and biomass-sourced coke from wood, and carbon capture and storage/utilization (CCS/U).

Fuels are likely to play a very important part in the industrial energy mix for many years to come. The challenge is to make them carbon neutral, or even carbon negative

The use of hydrogen in commercial blast furnaces has already been successfully demonstrated, so the key barrier is the cost of CO2-free hydrogen production. Researchers at the University of Adelaide are developing technologies based on solar energy with the aim of producing “$1 hydrogen”, meaning hydrogen with a production cost of $1/kg.

The good news is that the tide is beginning to turn in Europe, with Swedish company Hybrit planning hydrogen-based steel production from renewable energy, with a pre-feasibility study recently released. The major barrier is the need to develop and demonstrate technologies that reduce the cost of production. Other challenges include the need to develop iron ore pellets to meet ironmaking requirements, and for the steelmaking process to meet required steel grades in the new processing route.

- Alumina

There are no real technical barriers to the implementation of commercially available Concentrating Solar Thermal (CST) technologies to the digestion stage of the Bayer alumina process because their temperatures are compatible. The economic viability of this path is presently being evaluated and, if implemented, will achieve a significant reduction in emissions.

The development and demonstration of direct solar thermal heat for the higher temperature calcination stage is proceeding in parallel. Solar fuels, such as hydrogen and syngas, generated from solar and natural gas or biomass can contribute in the medium term, with 100% renewable fuels in the longer term. Syngas has already been used as a commercial fuel for calcination, while hydrogen has not. Further work is needed to de-risk the use of hydrogen, although no significant technical barriers are anticipated.

- Cement and Lime

In addition to its current use of municipal waste to produce heat, the Cement and Lime sector could also benefit from the development of high-temperature CST heat to reduce carbon emissions for the energy-intensive calcination step of cement production. In cement manufacturing there is an additional source of emissions: CO2 released from the calcination process itself. Around 70% of the CO2 emissions derives from the conversion of calcium carbonate (limestone) to calcium oxide, releasing CO2 from the limestone irrespective of the source of energy.

Thus, it is likely that carbon capture, storage and/or utilization (CCS/U) will also be needed to decarbonize this process. One enabler for this is oxy-fuel combustion, which is commercially available. Other emerging technologies include chemical looping combustion and photocatalytic CO2 to fuel conversion. Nevertheless, the temperature of calcination is also well suited to CST, and several technologies are under development for this process.

A number of workshopped discussions were held at HiTeMP, with the greatest input from “industry pull” and “innovation push”. The key technologies with the greatest potential to achieve low-cost renewable energy driven heat in the iron/steel, alumina and cement/lime industries are as follows:

Direct use of concentrated solar thermal (CST) heat: Technologies are under development with a realistic expectation to supply heat at 800 – 1000oC for AUD$10/GJ, which will be competitive with natural gas.

Solar/green energy fuels, such as hydrogen and syngas: New technologies are needed to produce solar hydrogen or syngas at costs competitive with fossil fuels. A series of new technologies are under development seeking to meet this need.

Refuse-derived fuels: These fuels are well established in industries such as cement and lime, whose long residence time and potential to adsorb gas phase species enables potentially harmful products to be managed safely. They are also a potential feedstock for more valuable products, such as plastics and liquid fuels, via solar gasification and other processes.

THE NEXT STEPS

Strong incentives exist to drive the transition toward net-zero CO2 high-temperature minerals processing. New markets are already emerging in certified low-carbon products, the cost of renewable energy is falling, and of course, company shareholders are demanding a reduction in carbon liability.

However, while industry is already investing to lower emissions intensity through increased efficiency, no technologies are yet commercially available for high-temperature processing with net-zero emissions at a competitive price.

Further government-industry-research co-investment is needed to continue technology development and to demonstrate cost-effective and reliable operations at sufficient scale for the new technologies to be taken up commercially without subsidy.