MATERIAL SAFETY DATA SHEET
1.
IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name:
Epotec High Build Epoxy Part A
Recommended Use:
Two pack epoxy surface coating.
Supplier: Address:
Coating Technologies Ltd 16 Aetna Place Henderson, Auckland, NEW ZEALAND +64 9 837 0897 +64 9 837 3736
Telephone Number: Facsimile: Emergency Telephone:
2.
New Zealand 09 837 0897 Mon-Fri 8.00am – 5.00pm New Zealand Poisons Centre: 0800 764 766
HAZARDS IDENTIFICATION
Hazard Classification:
ERMA GROUP STANDARD – Surface Coatings and Colourants (Subsidiary Hazard).
Substance Classification:
6.3A, 6.4A, 6.5A, 6.5B, 9.1D.
Hazard Statements:
Skin irritant, eye irritant, respiratory sensitizer, contact sensitizer, aquatic ecotoxic.
3.
COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients Epoxy resin Diluent Titanium Dioxide* Inorganic/Organic Pigments*
CAS Number 25068-38-6 2426-08-6 13463-67-7 Mixture
Proportion 20-50% 0-20% 5-60% 5-60%
TLV: 25ppm 10 mg/m³ -
*Proportions/Type vary with colour
4.
FIRST AID MEASURES
If medical advice is needed, have product container or label at hand. Swallowed:
Skin: Inhaled: Eyes:
Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Seek medical attention. Remove immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Remove to fresh air and keep at rest in a comfortable position. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical attention promptly.
Coating Technologies Ltd – Epotec High Build Epoxy Part A and B MSDS – Page 1 of 8
5.
FIRE FIGHTING MEASURES
Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of combustion. Explosion: Fire Extinguishing Media: Special Information:
6.
ACCIDENTAL RELEASE MEASURES
Emergency procedures: Methods and materials for Containment and clean up:
7.
Not considered to be an explosion hazard. If material is involved in a fire use: Fine water spray, foam, carbon dioxide or dry chemical powder. o Material can splatter above 100 C. Polymer film can burn.
If contamination of sewers or waterways has occurred advise local emergency services. Slippery when spilt. Avoid breathing vapours. Avoid accidents, clean up immediately. Contain – prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material). Collect and seal in properly labeled containers or drums for disposal.
HANDLING AND STORAGE
Store under cover away from direct sunlight and frost. Avoid extreme temperatures. Store in clearly labeled containers. Keep containers closed when not in use. Avoid storage with metals.
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Airborne Exposure Limits:
No exposure standards has been established for this product.
Personal Protection: Hands/Feet:
Neoprene gloves or elbow length PVC gloves. PVC boots or PVC safety gumboots. Wear glasses/goggles with side shields or face shield to protect face and eyes. Provide sufficient ventilation. Use approved respiratory protection when spraying. Normal work clothes covering arms and legs. Overalls and boots.
Eyes: Breathing: Other:
9.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Odour: Solubility: Specific Gravity: pH: Boiling Point: Vapour Pressure: Vapour Density: % Volatile by Weight:
White/coloured viscous liquid. Insoluble in water 1.5 n/a 100C Not Available Not Available Not Available
Coating Technologies Ltd – Epotec High Build Epoxy Part A and B MSDS – Page 2 of 8
10.
STABILITY AND ACTIVITY
Chemical Stability: Conditions to avoid: Incompatible materials: Hazardous decomposition Products:
11.
Eye Contact: Skin Contact: Inhalation:
No adverse effects expected, however, large amounts may cause nausea, vomiting, diarrhea, abdominal pain. May be an eye irritant. Contact with skin may result in irritation. In badly ventilated areas, vapour may cause irritation to mucous membranes of the respiratory tract, headache and nausea.
ECOLOGICAL INFORMATION
Ecotoxicity:
13.
Oxides of carbon.
TOXICOLOGICAL INFORMATION
Ingestion:
12.
Stable under normal conditions of use. Avoid exposure to heat and contact with foodstuffs. Incompatible with oxidizing agents.
Do not allow the product to contaminate waterways.
DISPOSAL CONSIDERATIONS
Empty paint containers should be left open in a well ventilated area to dry out. Refer to Waste Management Authority. Dispose of material through a licensed waste contractor.
14.
TRANSPORT INFORMATION
This product is Non Hazardous for transport. Proper Shipping Name: U.N No: Packing Group: Hazchem: Class:
15.
Not Not Not Not Not
Applicable Applicable Applicable Applicable Applicable
REGULATORY INFORMATION
Classified as hazardous, the following sub classifications apply: 6.3A 6.4A 6.5A 6.5B 9.1D
Substances which are skin irritants Substances which are eye irritants Substances which are respiratory sensitizers Substances which are contact sensitizers Substances which are aquatic ecotoxins
Coating Technologies Ltd – Epotec High Build Epoxy Part A and B MSDS – Page 3 of 8
16.
OTHER INFORMATION
Date of Preparation:
7 May 2010
Product Code:
70-XXXX
Version:
2
The information contained herein is based on data considered accurate and reliable to the best of our knowledge and belief as of the date compiled. However no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use hereof. Coating Technologies Ltd assumes no responsibility for personal injury or property damage to vendors, users or third parties caused by the material. Such users or vendors assume all risks associated with the use of the material. It is the user’s responsibility to satisfy themselves as to the suitability and completeness of the information for their own particular use. The users must determine whether the use of the information and data is in accordance with local laws and regulations.
Coating Technologies Ltd – Epotec High Build Epoxy Part A and B MSDS – Page 4 of 8
MATERIAL SAFETY DATA SHEET
1.
IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name:
Epotec High Build Epoxy Part B Hardener
Recommended Use:
Hardener for epoxy surface coating.
Supplier: Address:
Coating Technologies Ltd 16 Aetna Place Henderson, Auckland, NEW ZEALAND +64 9 837 0897 +64 9 837 3736
Telephone Number: Facsimile: Emergency Telephone:
2.
HAZARDS IDENTIFICATION
Hazard Classification: Substance Classification: Hazard Statements:
3.
ERMA GROUP STANDARD – Surface Coatings and Colourants (Flammable) 3.1C, 6.1D, 6.3A, 6.4A, 6.5A, 6.5B Flammable liquid, acute toxicity, skin irritant, eye irritant, contact sensitizer.
COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients Propan-2-ol 1-[bis[2-[(1,3Dimethylbutylidene)amino] ethyl]amino]-3-phenoxy Diethylenetriamine Methyl iso-butyl ketone
4.
New Zealand 09 837 0897 Mon-Fri 8.00am – 5.00pm New Zealand Poisons Centre: 0800 764 766
CAS Number
Proportion
TLV:
68541-07-1 111-40-0 108-10-1
>94% <4% <2%
-
FIRST AID MEASURES
If medical advice is needed, have product container or label at hand. Swallowed: Nil by mouth. Do NOT induce vomiting. Seek medical attention IMMEDIATELY. Skin: Remove immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. If persistent irritation occurs, seek medical attention. Inhaled: Remove to fresh air and keep at rest in a comfortable position. If rapid recovery does not occur, seek medical attention. Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical attention promptly. Prolonged contact may result in chemical burns and permanent damage. May cause allergic respiratory reaction. May cause allergic skin reaction.
Coating Technologies Ltd – Epotec High Build Epoxy Part A and B MSDS – Page 5 of 8
5.
FIRE FIGHTING MEASURES
Explosion:
Fire Extinguishing Media: Special Information:
6.
ACCIDENTAL RELEASE MEASURES
Emergency procedures: Methods and materials for Containment and clean up:
7.
Flammable liquid. Can cause explosive mixtures with air. Closed container may explode when exposed to extreme heat. Isolate from heat, electrical equipment, sparks and open flame. Carbon monoxide may be evolved if incomplete combustion occurs. May generate ammonia gas. May generate toxic nitrogen oxide gases. Foam, carbon dioxide or dry chemical powder. In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode.
If contamination of land, sewers or waterways has occurred advise local emergency services. Slippery when spilt. Extinguish all naked flames and remove ignition sources. Ventilate the area and evacuate all nonessential personnel. Avoid breathing vapours, and contact with skin, eyes or clothing. Avoid accidents, clean up immediately. Contain – prevent run off onto soil and into drains and waterways. Use absorbent (soil, sand or other inert material). Collect and seal in properly labelled containers or drums for disposal.
HANDLING AND STORAGE
Store at ambient temperatures. Keep containers tightly closed and in a well ventilated area. Keep away from direct sunlight, and other sources of heat or ignition. Keep away from water, acids and oxidizers. (See section 10 below.)
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Airborne Exposure Limits: Personal Protection: Hands/Feet: Eyes:
Breathing: Other:
Nitrile gloves or elbow length PVC gloves. PVC boots or PVC safety gumboots. Wear glasses/goggles with side shields or face shield to protect face and eyes. Contact lenses pose a special hazard: soft lenses may absorb irritants and all lenses concentrate them. Full face respirator with organic vapour canister NPF 400. Normal work clothes covering arms and legs. Overalls, solvent resistant apron and boots. Provide sufficient ventilation to maintain exposure at safe level.
Coating Technologies Ltd – Epotec High Build Epoxy Part A and B MSDS – Page 6 of 8
9.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Odour: Solubility: Specific Gravity: pH: Boiling Point: Flash Point: Flammability Limits, % vol: Vapour Pressure: Vapour Density: Autoignition Temp: % Volatile by Weight:
10.
Incompatible materials: Hazardous decomposition Products:
Stable under normal conditions of use. Avoid exposure to heat or ignition sources. Container can be pressurized by carbon dioxide due to reaction with humid air or water. Sodium hypochlorite, organic acids, mineral acids, peroxides, nitrous acid, reactive metals, oxidizing agents, alcohols, water. Nitric acid, ammonia, nitrogen oxides, carbon monoxide, carbon dioxide, aldehydes, flammable hydrocarbon fragments, nitrosamine. Product slowly corrodes copper, aluminium, zinc and galvanized surfaces. Reaction with peroxides may result in explosion. Reacts energetically with water. Carcinogenic n-nitrosamines may be formed on reaction with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations.
TOXICOLOGICAL INFORMATION
Ingestion: Eye Contact: Skin Contact:
Inhalation:
12.
0.97 alkaline o >100 C o 57 C no data (mm Hg at 21°C) <1.00 no data no data no data
STABILITY AND REACTIVITY
Chemical Stability: Conditions to avoid:
11.
Light yellow liquid. Amine
Acute oral LD50 (rat) > 670 mg/kg. Aspiration into lungs may cause chemical pneumonitis which can be fatal. Severe Irritant. Acute dermal LD50 (rabbit) > 1250 mg/kg. Contact with skin will result in irritation. Known to be a skin sensitizer. Prolonged or repeated exposure may cause defatting of skin, leading to dermatitis. Respiratory sensitizer. Acute inhalation LC50 (rat) > 10mg/l. Harmful by inhalation. Narcotic at high vapour concentrations.
ECOLOGICAL INFORMATION
Ecotoxicity:
N/A
Coating Technologies Ltd – Epotec High Build Epoxy Part A and B MSDS – Page 7 of 8
13.
DISPOSAL CONSIDERATIONS
Refer to Waste Management Authority. Dispose of material through a licensed waste contractor.
14.
TRANSPORT INFORMATION
Proper Shipping Name: U.N No: Packing Group: Hazchem: Class:
15.
Flammable Liquid, N.O.S. 1993 III 3(Y)E 3b
REGULATORY INFORMATION
Classified as hazardous, the following sub classifications apply: 3.1C 6.1D 6.3A 6.4A 6.5B
Flammable liquid Acute toxicity Skin irritant Eye irritant Contact sensitizer
16.
OTHER INFORMATION
Date of Preparation:
10 May 2012
Product Code:
70-0000
Version:
4
The information contained herein is based on data considered accurate and reliable to the best of our knowledge and belief as of the date compiled. However no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use hereof. Coating Technologies Ltd assumes no responsibility for personal injury or property damage to vendors, users or third parties caused by the material. Such users or vendors assume all risks associated with the use of the material. It is the user’s responsibility to satisfy themselves as to the suitability and completeness of the information for their own particular use. The users must determine whether the use of the information and data is in accordance with local laws and regulations.
Coating Technologies Ltd – Epotec High Build Epoxy Part A and B MSDS – Page 8 of 8