Philip Harris Catalogue 2015/16 - Chemicals by Findel Ltd

CHEMICALS Allow up to 2 weeks for delivery

Direct Delivery

All chemicals are delivered directly from our supplier, and therefore next day delivery is not available. Please allow up to 2 weeks for delivery. As chemicals are packed and shipped separately from any other products ordered from Philip Harris, they will be subject to their own carriage charge. You will be informed of this charge at the point of order. See terms and conditions for details.

Special Transport

Freight Surcharge

Several chemicals in our range fall into the most hazardous category for transport and may only be carried by specially trained drivers. This has forced us to place a Carriage Surcharge (applied to the consignment, not the individual material) on these particular chemicals.

Non-UK Mainland Customers (Including Northern Ireland and UK ‘Island’ areas) All orders to these areas will be subject to additional charges, to cover the additional costs of shipping and packaging required to comply with prevailing legislation on the transport of dangerous goods.

Disposal of Unwanted or Waste Chemicals For any queries regarding returning or disposing of chemicals, please call our disposal service on 0845 6060 558. Chemicals should not be returned to Philip Harris, as this may breach current legislation and your school will be liable for any subsequent disposal and handling charges. Please read all of the following points carefully before placing your chemicals order.

Chemicals Chemicals are subject to growing and constantly changing legislation governing all areas including supply, use, storage and disposal. Failure to comply with this legislation can result in serious legal proceedings and penalties, and places additional obligations on you as the purchaser and Philip Harris (and our agents) as the supplier. Due to prevailing legislation and security considerations, chemicals cannot be supplied to private individuals.

Points on ordering chemicals a. Many chemicals have a limited shelf life b. Please do not order more chemicals than you require c. Disposal of unwanted or excess chemicals is covered by extensive legislation and has become a specialized business (see opposite)

Ethanol permits.

Security At Philip Harris we recognise that chemicals represent a major hazard for schools and act responsibly to reduce the risk they represent. We only use UN approved packaging, with the appropriate hazard warnings and delivery note clearly visible on the outside. So when chemicals arrive at a school it is clear what they are, helping staff to deal with them promptly and safely. For the latest SDS sheets, please see www.philipharris.co.uk or email techsupport@philipharris.co.uk.

Purity and molarity Some chemicals, irrespective of grade, contain additives such as an anti-caking agent. This has no appreciable effect on the chemical behaviour of the substance, but does affect the amount that must be weighed out to achieve solutions of accurate molarity. E.g. copper sulfate-5-water is 98% pure, so a 1M solution requires 249.68 ÷ 0.98 = 254.78g to be dissolved in 1 litre. Allow to settle or ﬁlter to remove any insoluble component.

As of 1st July 2013, academic customers (as deﬁned by our sale of chemicals policy) may purchase upto 5 litres of IDA per annum without requiring authorisation from HM Revenue & Customs. Those customers who wish to purchase more than this must obtain a permit to do so. HMRC Glasgow can be contacted on 0141 555 3586.

CLP Regulation No 1272/2008

Example of Hazard Statement

Example of Precautionary Statement

GHS02

Heating may cause a ﬁre

Keep only in original container

GHS03

May intensify ﬁre; oxidiser

Take any precaution to avoid mixing with combustables

GHS05

Corrosive to metals and skin; Causes serious eye damage

Wear eye protection

GHS06

Toxic if swallowed

Do not eat, drink or smoke when using this product

GHS07

May cause an allergic skin reaction

Contaminated work clothing should not be allowed out of the workplace

GHS08

May cause allergy or asthma symptoms or breathing difﬁculties if inhaled

In case of inadequate ventilation wear respiratory protection

GHS09

May cause allergy or asthma symptoms or breathing difﬁculties if inhaled

In case of inadequate ventilation wear respiratory protection

Call 0845

120 4520 8am-5:30pm Monday to Friday

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CHEMICALS • CHEMICAL CLASSIFICATION AND LABELLING CODES H Codes

H281

PHYSICAL HAZARDS H200 H201 H202 H203 H204 H205 H220 H221 H222 H223 H224 H225 H226 H228 H240 H241 H242 H250 H251 H252 H260 H261 H270 H271 H272 H280

Unstable Explosive Explosive; mass explosion hazard Explosive; severe projection hazard Explosive; fire, blast or projection hazard Fire or projection hazard May mass explode in fire Extremely flammable gas Flammable gas Extremely flammable aerosol Flammable aerosol Extremely flammable liquid and vapour Highly Flammable liquid and vapour Flammable liquid and vapour Flammable solid Heating may cause an explosion Heating may cause a fire or explosion Heating may cause a fire Catches fire spontaneously if exposed to air Self-heating; may catch fire Self-heating in large quantities; may catch fire In contact with water releases flammable gases which may ignite spontaneously In contact with water releases flammable gases May cause or intensify fire; oxidizer May cause fire or explosion; strong oxidiser May intensify fire; oxidizer Contains gas under pressure; may explode if

H290

heated Contains refrigerated gas; may cause cryogenic burns or injury May be corrosive to metals

HEALTH HAZARDS H300 H301 H302 H304 H310 H311 H312 H314 H315 H317 H318 H319 H330 H331 H332 H334 H335 H336 H340 H341 H350 H351 H360 H361 H362

Fatal if swallowed Toxic if swallowed Harmful if swallowed May be fatal if swallowed and enters airways Fatal in contact with skin Toxic in contact with skin Harmful in contact with skin Causes severe skin burns and eye damage Causes skin irritation May cause an allergic skin reaction Causes serious eye damage Causes serious eye irritation Fatal if inhaled Toxic if inhaled Harmful if inhaled May cause allergy or asthma symptoms or breathing difﬁculties if inhaled May cause respiratory irritation May cause drowsiness or dizziness May cause genetic defects Suspected of causing genetic defects May cause cancer Suspected of causing cancer May damage fertility or the unborn child Suspected of damaging fertility or the unborn child May cause harm to breast-fed children

Safety Check List HANDLING AND USE • Read the label before opening the container • Check that the chemical is the one required • Consider the hazards including violent reactions between chemicals and use appropriate protective clothing and equipment • Open container carefully in well ventilated area • Take care while extracting and using hazardous chemicals and use methods which reduce the risk of inhalation, ingestion and contact with skin, eyes and clothing • Avoid using contaminated apparatus and instruments • Seal container tightly after use • Do not eat, drink or smoke while handling and using chemicals

GENERAL P101 P102 P103

If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use

P210 P211 P220 P221 P222 P223 P230 P231 P232 P233 P234 P235 P240 P241 P242 P243 P244 P250 P251 P260 P261 P262 P263 P264 P270 P271 P272 P273 P280 P281 P282 P283 P284

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RESPONSE P310

PREVENTION P201 P202

In case of inadequate ventilation wear respiratory protection. P231 + P232 Handle under inert gas. Protect from moisture. P235 + P410 Keep cool. Protect from sunlight. P285

P Codes

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Keep/Store away from clothing/.. ./combustible materials. Take any precaution to avoid mixing with combustibles/... Do not allow contact with air. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep wetted with ... Handle under inert gas. Protect from moisture. Keep container tightly closed. Keep only in original container. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/ lighting/.../equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep reduction valves free from grease and oil. Do not subject to grinding/shock/.. ./friction. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapours/ spray. Avoid breathing dust/fume/gas/mist/vapours/ spray. Do not get in eyes, on skin, or on clothing. Avoid contact during pregnancy/while nursing. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Wear cold insulating gloves/face shield/eye protection. Wear fire/flame resistant/retardant clothing. Wear respiratory protection.

P311 P312 P313 P314 P315 P320 P321 P322 P330 P331 P334 P335 P336 P338 P340 P341 P342 P350 P351 P352 P353 P360 P361 P362 P363 P371 P372 P373 P374 P376 P377 P378 P380 P381 P390 P391

Immediately call The NPIS (see below) or doctor/ physician. Call The NPIS (see below) or doctor/physician. Call The NPIS (see below) or doctor/physician if you feel unwell. Get medical advice/attention. Get medical advice/attention if you feel unwell. Get immediate medical advice/attention. Specific treatment is urgent (see ... on this label). Specific treatment (see ... on this label). Specific measures (see ...on this label). Rinse mouth. Do NOT induce vomiting. Immerse in cool water/wrap in wet bandages. Brush off loose particles from skin. Thaw frosted parts with lukewarm water. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Gently wash with plenty of soap and water. Rinse cautiously with water for several minutes. Wash with plenty of soap and water. Rinse skin with water/shower. Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Remove/Take off immediately all contaminated clothing. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. In case of major fire and large quantities: Explosion risk in case of fire. DO NOT fight fire when fire reaches explosives. Fight fire with normal precautions from a reasonable distance. Stop leak if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Use ... for extinction. Evacuate area. Eliminate all ignition sources if safe to do so. Absorb spillage to prevent material damage. Collect spillage. Hazardous to the aquatic environment

H370 H371 H372 H373 H400 H410 H411 H412 H413

Causes damage to organs May cause damage to organs Causes damage to organs through prolonged or repeated exposure May cause damage to organs through prolonged or repeated exposure Very toxic to aquatic life Very toxic to aquatic life with long lasting effects Toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects May cause long lasting harmful effects to aquatic life

COMBINATION OF H-CODES H300 + H310 Fatal if swallowed or in contact with skin H300 + H330 Fatal if swallowed or if inhaled H310 + H330 Fatal in contact with skin or if inhaled H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled H301 + H311 Toxic if swallowed or in contact with skin H301 + H331 Toxic if swallowed or if inhaled H311 + H331 Toxic in contact with skin or if inhaled

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled H302 + H312 Harmful if swallowed or in contact with skin H302 + H332 Harmful if swallowed or if inhaled H312 + H332 Harmful in contact with skin or if inhaled H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled H315 + H320 Causes skin and eye irritation

ADDITIONAL HAZARD STATEMENTS (EU) EUH001 Explosive when dry EUH006 Explosive with or without contact with air EUH014 Reacts violently with water EUH018 In use may form ﬂammable/explosive vapourair mixture EUH019 May form explosive peroxides EUH029 Contact with water liberates toxic gas EUH031 Contact with acids liberates toxic gas EUH032 Contact with acids liberates very toxic gas EUH044 Risk of explosion if heated under conﬁnement EUH059 Hazardous to the ozone layer EUH066 Repeated exposure may cause skin dryness or cracking EUH070 Toxic by eye contact EUH071 Corrosive to the respiratory tract

• Wash hands and exposed areas regularly, and change contaminated clothing • Deal with spillages using precautions and methods appropriate to the hazards • Seek medical attention immediately if affected by chemicals and use appropriate ﬁrst aid until medical attention is available

STORAGE • • • • • •

Store in a dry well ventilated area, protected from extremes of temperature and sources of ignition Secure chemicals from unauthorized use Segregate stock to reduce hazards Inspect stock from time to time and dispose of deteriorated materials Do not smoke where ﬂammable chemicals are stored Take care in handling containers with hazardous residues

P301 + P310 If swallowed: Immediately call The NPIS (see below) or doctor/physician. P301 + P312 If swallowed: call The NPIS (see below) or doctor/physician IF you feel unwell. P301 + P330 + P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P302 + P334 If on skin: Immerse in cool water/wrap in wet bandages. P302 + P350 If on skin: Gently wash with plenty of soap and water. P302 + P352 If on skin: wash with plenty of soap and water. P303 + P361 + P353 If on skin (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P304 + P312 If inhaled: Call The NPIS (see below) or doctor/ physician if you feel unwell. P304 + P340 If inhaled: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P304 + P341 If inhaled: If breathing is difﬁcult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P306 + P360 If on clothing: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. P307 + P311 If exposed: call The NPIS (see below) or doctor/ physician. P308 + P313 If exposed or concerned: Get medical advice/ attention. P309 + P311 If exposed or if you feel unwell: call The NPIS (see below) or doctor/physician. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P335 + P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

P337 + P313 If eye irritation persists: Get medical advice/ attention. P342 + P311 If experiencing respiratory symptoms: call The NPIS (see below) or doctor/physician. P370 + P376 In case of fire: Stop leak if safe to do so. P370 + P378 In case of fire: Use ... for extinction. P370 + P380 In case of fire: evacuate area. P370 + P380 + P375 In case of fire: evacuate area. Fight fire remotely due to the risk of explosion. P371 + P380 + P375 In case of major fire and large quantities: evacuate area. Fight fire remotely due to the risk of explosion.

STORAGE Store... Store in a dry place. Store in a well-ventilated place. Store in a closed container. Store locked up. Store in corrosive resistant/... container with a resistant inner liner. P407 Maintain air gap between stacks/pallets. P410 Protect from sunlight. P412 Do not expose to temperatures exceeding 50°C/122°F. P413 Store bulk masses greater than ... kg/...lbs at temperatures not exceeding ... °C/...°F. P420 Store away from other materials. P422 Store contents under... P402 + P404 Store in a dry place. Store in a closed container. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P410 + P403 Protect from sunlight. Store in a well-ventilated place. P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. P411 + P235 Store at temperatures not exceeding ... °C/.. .°F. Keep cool. P501 Dispose of contents/container to P502 Refer to manufacturer/supplier for information on recovery/recycling P401 P402 P403 P404 P405 P406

The National Poisons Information Service is contacted through www.npis.org

Need advice? Email techsupport@philipharris.co.uk

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THE GLOBAL HARMONISED SYSTEM (GHS) WITHIN THE EU •

Hazard class

Explosives