Icbces abstractbook 2016

Conference Proceedings Book 2nd International Conference on Innovations in Chemical, Biological & Environmental Sciences (ICBCES), 12th February, 2016 Being jointly organized by Swami Sukdevanand PG College, Shahjahanpur GIAP Journals, Oman and Association of Chemistry Teachers, Mumbai

Editors Dr Priy Brat Dwivedi, Senior Faculty, Caledonian College of Engineering, Oman Dr Alok Kumar Singh Head, Department of Chemistry, SSPG College, Shahjahanpur, UP, India

Published by Gyandhara International Academic Publications (GIAP Journals), Oman www.giapjournals.org, www.giapjournals.com, Email: publications.giap@gmail.com

Swami Chinmayanand Saraswati Former Union Home Minister (State) Govt. of India

Message An Ideal education Institution aims not just at imparting the knowledge and information rather it equips the learner with our ancient values and ethics laid down and fostered through the scriptures over the centuries. It targets at enhancing the Intellectual as well as the daily living standards of a common human being. Over the decades, the science has progressed by leaps and bounds and yet the reflective process centered on the principles, values and ethics that can evolve a common human mind to a real human being, is still the cry of the age.

I am elated to proclaim that our alma mater Swami Sukdevanand PG College, Shahjahanpur is heading its way by bestowing knowledge coupled with Human Values to the sincere and genuine learners of this small town of Uttar-Pradesh and it is proving its worth like an oasis in a desert. In this eternal continuum, Swami Sukdevanand PG College, Shahjahanpur, UP, India is organizing 2nd International Conference on Innovations in Chemical, Biological & Environmental Sciences (ICBCES) on 12th February in our lush green alluring college campus.

I extend my warm greetings and blessings to this unstoppable journey of knowledge-seekers and hope sanguinely that the Inter-cultural interaction of the learned scholars will surely go a long way and set milestone on the ever sprawling path of knowledge.

(Swami Chinmayanand Saraswati)

Rajni Dwivedi CEO, GIAP Journals Oman

Message The management of GIAP Journals is congratulating SSPG College, Shahjahanpur for organizing 2nd International Conference on Innovations in Chemical, Biological and Environmental Sciences on 12th February 2016 in its campus.

At GIAP Journals, we strongly believe in creating values for best interest of society. ICBCES 2016 is a perfect platform where researchers, academicians, students will be delivering innovative solutions, discussing, networking and motivating each other by lively interactions. We know all committee members have worked very hard to make this conference successful.

To recognize special efforts of researchers and academicians, GIAP Journals is announcing GIAP’s Community Service award and GIAP’s Researcher award for year 2016.

GIAP Journals is also bringing innovative mobile research conferences in 2016 so that International and National research conferences can be organized online and huge amount of money, energy and time can be saved. More details will be coming at www.giapconferences.org We are thankful to Association of Chemistry Teachers, Mumbai for collaboration, Reliance Rosa power plant and all sponsors of the conference.

I wish great success for ICBCES 2016 (Rajni Dwivedi)

Prof. A. K. Mishra Principal S. S. PG College, Shahjahanpur

Message Founded in 1964 by HH Swami Shukdevanand Saraswati Ji Maharaj, Swami Shukdevanand (PG) College, Shahjahanpur is now an idiom of success, quality and world class education in the Rohilkhand region. Presently the Institution runs graduate and postgraduate courses in Faculties of Arts, Science, Commerce, Education and Computer Science in which the students and scholars are learning various academic, professional and life skills.

The Faculty of Science has been constantly striving to establish newer heights in the firmament of knowledge and research and is organizing 2nd International Conference on Innovations in Chemical, Biological & Environmental Sciences (ICBCES) on 12th February 2016. I can foretell without any frail hitch that the eminent and learned scholars hailing from different parts of the globe will surely enlighten the participants by acquainting them with the recent innovations and inventions in Chemical, Biological, and environmental sciences and prove to be beneficial for the scientists, research scholars, teachers and students.

I appreciate the conjoint toil of the faculty members of Science and organizing secretary in particular and wish them for the successful publication of the souvenir.

(Prof. A. K. Mishra)

Ram Chandra Singhal Secretary S. S. PG College, Shahjahanpur

Message Swami Shukdevanand (PG) College, Shahjahanpur is one of the pioneering educational Institutions of M. J. P. Rohilkhand University. For the all round development of the students and scholar community of the region, the Institution is regularly organizing many symposia, Seminars, workshops and other curricular and extracurricular activities and the present 2nd International Conference on Innovations in Chemical, Biological & Environmental Sciences (ICBCES) held on 12th February 2016 is one of such events organized by the Faculty of Science of the college.

I wish and congratulate for grand success of the Seminar.

(Ram Chandra Singhal)

Dr Alok Kumar Singh Organizing Secretary ICBCES 2016 HoD, Chemistry Department S. S. PG College, Shahjahanpur

Message Organizing committee of ICBCES 2016 welcomes all delegates in beautiful campus of Swami Shukdevanand (PG) College, Shahjahanpur. ICBCES 2016 is being organized in association with GIAP Journals, Oman and Association of Chemistry Teachers, Mumbai. This conference has created an ecosystem in which researchers, academicians and industry are working in collaboration for better interest of society.

ICBCES 2016 is attracting best research articles in the field of chemical, biological and environmental sciences. We are hopeful that the outcome of ICBCES will benefit the society and will generate innovative solutions to the chronic challenges of environment.

We are thankful to management, administration, staff and students of college for overall support and coordination.

I wish and congratulate for grand success of the ICBCES 2016.

(Dr Alok Kumar Singh)

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India SYNTHESIS AND FUNGICIDAL ACTIVITY OF BIOACTIVE 4,4’-BIS [4”-(N-BENZYLIDINYLAMINE) -3” MERCAPTO -1”,2”,4”-TRIAZOLE-5”YL METHOXY] BIBENZYL 1 2 Smriti Dwivedi *,I.R Siddiqui 1 *Dept. of Chemistry, Galgotia College of Engg. & Technology, Greater Noida, U.P, India 2 Laboratory of Green Technology, Dept. of Chemistry. University of Allahabad, Allahabad, U.P, India smriti96@rediffmail.com, Among heterocyclic compounds,Nitrogen heterocyclic compounds containing 1,2,4 triazole nucleus posses various biological activities and have been used for development of useful pharmacological agents.It has been found that natural as well as synthetic bibenzyls both show antifungal activity Bibenzyl are naturally occurring potential fungicides.With the hope of exploring new antifungal bibenzyls having 1,2,4 triazole heterocyclic moieties it was considered to synthesize new potentially bio-active, safe, environment friendly fungicides with aim to increase permeability into the fungal cell. Several bibenzyl incorporating 1,2,4 triazole heterocyclic moieties have been designed in such a way so that most of them incorporate toxophorically important grouping for fungi.

Keywords: bibenzyl,triazole fungicides, toxophoric AN ESIPT BASED FLUORESCENT PROBE FOR SELECTIVE DETECTION OF CYANIDE IN DIFFERENT MEDIUM Rashid Ali, Ramesh C. Gupta, Sushil K. Dwivedi and Arvind Misra Department of Chemistry, Institute of Science, Banaras Hindu University alirashid85@gmail.com A new polynuclear hetero atom containing molecular organic scaffold 3 has been synthesized, and characterized. The detailed optical properties of probe 3 have been investigated in THF/HEPES buffer (v/v = 20%, pH 7.04). The molecular probe 3 showed good photophysical behavior due to excited state intramolecular proton transfer (ESIPT) mechanism. The UV-vis spectrum of 3 (10 µM) showed a low energy transition band at 376 nm (ε = 1.64 x 104 M-1cm-1) with a shoulder at 480 nm (7.61 x 10-2 M-1cm-1) and upon excitation at 376 nm displayed a weak emission at 528 nm (Ф3 = 0.009; Stokes shift, 7656 cm-1). Upon interaction with different anions 3 showed high selectively with excellent sensitivity (15.34 ppb) for cyanide anion (CN-) through a reaction based chemodosimeter approach, in which relative fluorescence intensity of 3 enhanced significantly, „turn-on‟ (~8.0 fold) with blue shift of ~34 nm to appear at 494 nm (Ф3+CN- = 0.121).

Probe 3 enabled naked-eye sensitivity in which a fluorescent dark green colour changed to bright blue-green colour with considerable fluorescence „turn-on‟ due to the formation of cyclic oxazole derivative 4 in the medium. Job‟s plot analysis revealed a 1:1 binding stoichiometry between 3-CN-. The mechanism of interaction between 3 and CN- has been confirmed by the change in optical behaviours, 1H NMR, 13C NMR, HRMS, and X-ray crystallography data. The potential chemodosimeter 3 has also been utilized to detect cyanide on test paper strips and silica coated microslides. Moreover, probe 3 is also applicable to determine CN- concentration in real contaminated water samples with excellent recovery of CN- in the range of 98 to 94%.

APPLICATIONS OF ULTRASOUND IN FOOD PROCESSING Ahmet ÜNVER* *Necmettin Erbakan University, Faculty of Engineering and Architecture, Department of Food Engineering, Meram, Konya, TURKEY unveraet@konya.edu.tr Nowadays, researchers are interested in minimally food processing techniques because of the fresh or freshlike food preference of the consumers. Ultrasound is an acoustic energy but, its effect is a result of physical energy which is generated by the kinetic energy of the molecules in the applied medium. Its powerful effect, drawn the interest of the scientists to investigate on its applications in many areas. In food science, ultrasound has a wide range of applications. Microbial inactivation, drying, filtration, extraction, homogenization, cutting, emulsifying, cleaning, degassing and inactivation of enzymes are some of the examples of efficient applications of ultrasound. The two important well-known benefits of the usage of ultrasound are the reduction of the process duration and process cost. In this review, some ultrasound applications will be discussed in food science and technology.

Key words: Ultrasound, food processing, minimally food processing 1

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India HYPERSPECTRAL IMAGING TECHNIQUE AS A STATE OF ART TECHNOLOGY IN MEAT SCIENCE Hasan İbrahim KOZAN*, Cemalettin SARIÇOBAN**, Hasan Ali AKYÜREK***, Ahmet ÜNVER**** *Necmettin Erbakan University, Seydişehir Vocational School, 42090, Seydişehir, Konya/TURKEY e-mail: hkozan@konya.edu.tr **Selçuk University, Agricultural Faculty, Department of Food Engineering, Selçuklu, Konya, TURKEY ***Necmettin Erbakan University, School of Applied Sciences, Department of Managemet Information Systems, Selçuklu, Konya, TURKEY ****Necmettin Erbakan University, Faculty of Engineering and Architecture, Department of Food Engineering, Meram, Konya, TURKEY Nowadays, the concern of meat consumption, safety and quality has been popular due to some health risks such coronary heart disease, stroke and diabetes caused by the content as saturated fat, cholesterol content and carcinogenic compounds, for consumers. The importance of the need of new non-destructive and fast meat analyze methods are increasing day by day. For this, researchers have developed some methods to objectively measure the meat quality and meat safety as well as illness sources. Hyperspectral imaging technique is one of the most popular technology which combines imaging and spectroscopic technology. This technique is a non-destructive, real-time and easy-to-use detection tool for meat quality and safety assessment. It is possible to determine chemical structure and related physical properties of meat.

It is clear that hyperspectral imaging technology can be automated for manufacturing in meat industry and all of data‟s obtained from the hyperspectral images which represents the chemical quality parameters of meats in the process can be saved to database.

Keywords: non-destructive method, hyperspectral imaging, meat science.

COMPARISON OF THIOBARBITURIC ACID LEVEL PREDICTION POWER BETWEEN STATISTICAL AND ARTIFICIAL NEURAL-NETWORK MODELS IN GROUND MEAT 1 2 3 4 Hasan Ali AKYÜREK , Hasan İbrahim KOZAN , Barış KOÇER , Cemalettin SARIÇOBAN 1 Necmettin Erbakan University, School of Applied Sciences, Department of Management Information Systems, Selcuklu, Konya, TURKEY e-mail: hakyurek@konya.edu.tr 2 Necmettin Erbakan University, Seydisehir Vocational School, 42090, Seydisehir, Konya, TURKEY 3 Selcuk University, Faculty of Engineering and Architecture, Department of Computer Engineering, Selcuklu, Konya, TURKEY 4 Selcuk University, Agricultural Faculty, Department of Food Engineering, Selcuklu, Konya, TURKEY In this study, it‟s aimed to predict Thiobarbituric Acid (TBA) level by processing the data from color parameters of ground meat. A dataset of 600 TBA, L*, a*, b*, Chrome, Hue, Day of Storage and Light Source values obtained from the experimental analysis of ground meat was mined. Five hundred objects were used as the training set and one hundred as the test set in application of artificial neural-network model. The final developed model presented higher performance as R2 = 0.99 (R2 = 0.99 on the training set, R2 = 0.98 on the test set) for the artificial neural-network than statistical model as R2 = 0.91(R2 = 0.92 on the training set, R2 = 0.90 on the test set). Artificial neural network is shown to be a powerful and suitable tool for the prediction of TBA level of ground meat.

Keywords: Artificial Neural-Network, Ground Meat, Thiobarbituric Acid, Statistical Model INDIAN INITIATIVES FOR ENVIRONMENT CONSERVATION D V Prabhu Department of Chemistry, Wilson College (University of Mumbai) Mumbai 400007 Email: dvprabhu48@gmail.com Society, at large has to realize the gravity of environmental degradation and participate fully in the mitigation of environmental problems. The commitment of the Indian Government to the cause of public awareness of environment conservation is reflected in its outreach and educational programmes involving its ministries, environmental monitoring agencies, NGOs, academic and research institutions. The Ministry of Environment and Forests (MoEF) has played a leading role in the national priority programmes of environmental monitoring, assessment and pollution control. All the stake holders have succeeded to some extent in creating public interest in environmental issues but much more needs to be done. This presentation discusses the Indian initiatives and the important milestones in the path of environmental protection and pollution abatement.

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India A NEW TITRIMETRIC METHOD FOR DETERMINATION OF AMIDARONE HYDROCHLORIDE IN PURE FORM AND IN THEIR PHARMACEUTICAL PREPARATIONS a,b b a* Sanjai Kumar , Manoj Kumar Singh and I.C.Shukla a Department of Chemistry , University of Allahabad, Allahabad-211002, b Department of Chemistry , S.V.N.P.G. College, Kalan, Sultanpur Email: sanjai.chem.au@gmail.com, This article describes a simple and convenient titrimetric method for determination of Amidarone hydrochloride in pure form and in their pharmaceutical preparations like Cardasol and Cordarone. Amidarone hydrochloride is an anti-arrhythemic agent used for various types of cardiac dysrhythmias both ventricular and atrial. Aliquots containing 1, 3, 5 mg of samples were determined and percentage error, standard deviation, coefficient of variation was calculated for each sample size. To evaluate the authenticity of the method recovery experiments were also carried out by standard drug addition method.

Key words: Amidarone hydrochloride, Titrimetric method, Recovery experiments.

MECHANISTIC ASPECT OF RH(III) CATALYSED OXIDATION OF 2-METHYL CYCLOHEXANOL AND 2PHENYL ETHANOL BY CERIUM(IV) SULPHATE IN ACIDIC MEDIUM Alok K. Singh , Raj Kamal Rastogi, Sumit Saxena, Gulshan Rastogi Department of Chemistry, SSPG College Shahjahanpur-242001, India, E-mail: alokks32@gmail.com Un-catalyzed oxidation of aromatic compounds by cerium (IV) has been frequently reported from the kinetic and synthetic point of views, but proper attention has not been given to these oxidations in the presence of transition metal ions. Present study shows that oxidation of 2-methyl cyclohexanol and 2-phenyl ethanol by cerium (IV) sulphate in aqueous sulphuric acid medium is greatly enhanced by rhodium (III) chloride.

Reactions follow direct proportionality with respect to catalyst concentrations while the first order kinetics shown by the oxidant and organic substrate at their low concentrations become zero order at higher + concentrations of both oxidant and organic substrate. Rate decreased with increasing concentrations of H III ions. Externally added Ce and Cl ions have negative effects on the reaction rate. Catalyst combines with the complex formed between cerium (IV) and organic substrate and ultimately gives rise to corresponding aromatic dicarboxylic acids as the product of oxidation. Complex formation in 2-methyl cyclohexanol is easier compared to that in case of 2-phenyl ethanol.

EFFICIENCY OF SOME CORROSION INHIBITORS ON REBAR IN SALINE MEDIA 1,* 2 3 Monalisa Kundu , Shailesh Kumar Prasad , Virendra Kumar 1,2 3 Department of Chemistry, Department of Civil Engineering National Institute of Technology Jamshedpur E-mail address: monaiitr08@gmail.com Many different methods have been proposed to address rebar corrosion in reinforced concrete structures.

Corrosion inhibitors may be a good way to control reinforcing steel corrosion because they are easy to apply and less costly than other prevention methods like barrier layers, and cathodic protection. The objective of this paper is to study the inhibitive effects of several inhibitors when they are used in reinforced cement mortars.

Electrochemical monitoring of half-cell potential (HCP), linear polarization resistance (LPR) and compressive strength taking different inhibitor concentrations were performed in 3.5% NaCl medium in order to obtain inhibitor information on the corrosion behavior of the reinforcing steel in cement mortar. Results demonstrated best inhibitory effect in presence of inorganic Sodium nitrite based inhibitor compare to chromate inhibitor and DMEA based inhibitor. Moreover, in case of DMEA based organic corrosion inhibitor the passivation of the steel was reached in much longer time. Compressive strength effect showed significant reduction with nitrite inhibitor whereas in the case of chromate inhibitor there was an improvement in the compressive strength of the rebar in saline medium. No significant change in compressive strength was determined with DMEA based inhibitors.

Keywords: Corrosion inhibitor, inorganic inhibitor, organic inhibitor, half-cell potential, linear polarization resistance, compressive strength.

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India PHYSICOCHEMICAL PARAMETERS STUDY OF CHITOSAN-STARCH-GLUTARIC ACID IN ACETIC ACIDWATER MIXTURES Virpal Singh Department of Applied Chemistry, M J P Rohilkhand University, Bareilly - 243006 (U.P.), India Email: singh_veer_pal@rediffmail.com Chitosan/starch solutions of different concentrations (90/10 to10/90) are prepared in dilute acetic acid solution (1% ). Glutaric acid solution concentration is 1% fixed. The solution properties such as viscosity and refractive index are measured. Viscosity of Chitosan-Starch-Glutaric acid solution is measured by Brookfield viscometer modal DV-E version 1.00 and refractive index is also measured by Abbes refractometer. The influence of concentration of solution and speed of rotation on shear stress are also determined for polymer solution.

Keywords: Chitosan, starch, Glutaric acid, refractive index, viscosity SYNTHESIS AND CHARACTERIZATION OF TI (III), V (III),VO (IV), MOO (V),FE (II) AND FE (III) COMPLEXES OF BENZIL- 2,4-DINITROPHENYL HYDRAZONE P-BROMO ANILINE. * # ** * Raj Kamal Rastogi , Sonu Sharma , Gulshan Rastogi Alok K. Singh * Department of Chemistry, S.S (P.G) College Shahjahanpur, # M.S.I.C Shahjahanpur, **Arya Mahila ( P.G) College, Shahjahanpur, (U.P), India.

Email: rajkamal902@gmail.com The complexes of Benzil-2, 4-dinitrophenyl hydrazone-p- bromo aniline with Ti(III),V(III), VO(IV),MoO (V), Fe(II), Fe(III) have synthesized and characterized by elemental analysis, magnetic measurement data, molar conductance, TGA,UV-visible and IR spectra data. The complexes of Ti (III), V (III), Fe (II) and Fe (III) have octahedral geometry while VO (IV) and MoO (V) have distorted octahedral geometry due to the presence of M=O moiety.

Key word: Schiff base, Synthesis, Molar Conductance, Spectroscopy.

DESTRUCTION OF RESINOUS COMPOUND FROM WASTE BY USE OF NATURAL ENZYMES. 1 2 Dr. Harsha Chatrath, Rohit Durge 1 2 Adjunct Professor, Research Associate, Department of Chemistry Dr. D.Y. Patil ACS College, Pimpri, Pune. (India) harshamohini@gmail.com In present scenario huge quantity of waste are produced every day. It contains plastics, waste papers, plastic containers, some of these are degradable, and some of these are non degradable waste. Non biodegradable things are present in waste treated with mechanical pulverizing mechanisms and with few of strong chemical.

Chemicals such as concentrated Hydrochloric, Sulphuric acids, sulphamic acids and many other hazardous chemicals are used for destroying wastes in simple form or in disperse form. Almost 70% of the waste is being dumped in the soil layer. After certain interval of time compounds present in soils such as salts of the metals and temperature of soil help in decomposing the waste periodically. Due to this process large quantity of soil gets contaminated. In this project we have tried to replace hazardous chemicals with other nonhazardous chemicals and some natural enzymes, which may give same reactions as with toxic chemicals.

Objectives may also helps in use of eco friendly chemicals for reducing soil pollution and water pollutions.

Hence it will minimize the other impacts on environment such as air pollution, noise pollutions, water pollutions and soil pollutions. All process will carry out under Green Chemistry cycles.

Key Words: Non biodegradable waste material, Hazardous chemicals, natural enzymes, Green Chemistry SYNTHESIS AND ANTIFUNGAL ACTIVITY OF SOME 3', 5'- BIS (3-ARYL RHOCLANIN-5-ALAZO) -4PHENYL-'1',2',4'-TRIAZOLES Bandana Dwivedi Department of Chemistry, T.D.P.G. College, Jaunpur Email: drrajnishdwivedijnp@gmail.com, 3', 5'- Bis (3-Aryl Rhoclanin-5-Alazo) -4- Phenyl-'1',2',4'-Triazoles were prepared by diazotization of 4-Phenyl 3,4 - diamino-1, 2, 4-triazoles followed by adding ice cold solution of 3-Phenyl rhodanin in acetone containing sodium acetate gradually by stirring and cooling. The synthesized triazoles were screened their antifungal activity against the test fungi viz. A.flavus and C.albicans at different concentrations.

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India DESIGN AND SYNTHESIS OF AN EFFICIENT MOLECULAR ORGANIC SCAFFOLD EXHIBITING HG INDUCED FLUORESCENCE QUENCHING AND CYANIDE SENSING (ON-OFF-ON) VIA MERCURY DISPLACEMENT APPROACH Ramesh C. Gupta, Syed S. Razi, Sushil K. Dwivedi, Rashid Ali and Arvind Misra* Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, INDIA Email: arvindmisra2003@yahoo.com; amisra@bhu.ac.in

2+

A simple triazole-appended antharacene-quinoline conjugates, probe 7 have been designed and synthesized.

The photophysical behaviour of probes and their interaction with metal ions and anions have been examined through the absorption and fluorescence spectroscopy in HEPES buffer medium. Probe 7 showed good optical behaviour in 60% aqueous THF and upon interaction with different metal ions and anions displayed strong 2+ 2+ fluorescence quenching (~ 94%; switch-Off) selectively with Hg . Moreover, 7-Hg ensemble when tested toward different anions only cyanide (CN ) enable mercury displacement (as Hg(CN)2) and led to fluorescence 2+ enhancement (switched-On). Probe 7 has shown high sensitivity to detect Hg selectively in real water sample, and on cellulose paper strips. Additionally, the naked eye sensitive “On-Off-On” sensing behaviour of probe 7 mimics the function of a sequential logic circuit at molecular level. The proposed mechanism of 1 13 interaction has been supported by FTIR, NMR ( H and C), ESI-MS spectroscopy and DFT. STUDY OF POLYVINYL BUTYRAL COMPOSITE MATERIALS WITH THEIR NOVEL CHARACTERISTICS AND VARIOUS POTENTIAL APPLICATIONS 1 2 3 Nida Khan, Deepak Kumar, Pramendra Kumar 3 1,2 Assistant Professor, Research Scholar, Department of Applied Chemistry, MJP Rohilkhand University Bareilly, 243006 (UP) Email: nidarehman09@gmail.com As composite materials are crucial part of life, a great deal of composites is available around us and is also synthesized in laboratory since these are being used for the preparation of significant articles. Their classification and applications in various fields are highly governed by the size of particles they acquire.

Polyvinyl butyral (PVB) is a material, when used as a constituent part in the formation of composite, induces a specific property in a resulting one which are utilized by various ways because of being stronger in binding, sharper in optical clarity, and being able for providing flexibility and toughness in the formed composite. This random copolymer is constituted by means of hydrophilic vinyl alcohol group and hydrophobic vinyl butyral group which behave as promoters of polymer adhesive and binders for organic moieties to provide a vast area of applications using this polymer in different forms like as material to produce antireflecting coating, to generate mesosphere, in the formation of polymeric electrode, in the formation of polymeric electrolyte, as nanofibre and in the synthesis of alumina fiber and in other ways as in manufacturing of photovoltaic thin film solar modules and as nanofibre in the construction of surface acoustic wave humidity sensor.

Key words- Composite, Nanoparticle, PVB, nanofibre, antireflecting material etc.

A MOLECULAR KEYPAD LOCK SYSTEM EXHIBITS TUNABLE FLUORESCENCE SWITCHING (ON-OFF) 2+ WITH ZN AND F IONS Arvind Misra, Mohammad Shahid, Priyanka Srivastava, Ramesh C. Gupta, Sushil K. Dwivedi Rashid Ali and Syed S. Razi Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, UP. India alirashid85@gmail.com, arvindmisra2003@yahoo.com, amisra@bhu.ac.in, A bischromophoric dyad 1 upon interaction with various cation and anion exhibits fluorescence enhancement 2+ and quenching with Zn and F ions in H2O-ACN (10%), respectively. The output emission signals providing + 2+ chemical inputs of H , OH , Zn and F have been implemented to construct OR, INHIBIT and TRANSFER logic gates. The fluorescence „On-Off‟ switching behavior of a molecular keypad lock authorizing password entries has been realized in which computing the output emissions of chemical inputs, sequentially (F (A) then 2+ Zn (I) ions) unlock the keypad lock (M; On state) whereas on reversing the sequence of inputs it remained locked (T; Off state) keeping in memory a correct and incorrect password entries, AIM and IAT respectively. A 2+ correct combination of chemical inputs (F , Zn and EDTA) easily reset-set logic operations and make the device reusable.

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India QSPRS STUDY ON HUMAN CARBONIC ANHYDRASE IV INHIBITORS a a Shalini Singh and M.B. Kalhans a QSAR & Cheminformatics Laboratory, Department of Chemistry, Bareilly College, Bareilly, (U.P.) India shalinisingh_15@yahoo.com, The membrane-associated CA IV increased production of aqueous humor and excitatory function Neurons causes glaucoma and epilepsy disease . A series of 2-substituted-1,3,4-thiadiazole-5-sulfamides was prepared and assayed as inhibitors of carbonic anhydrase (CA, EC 4.2.1.1), the membrane-associated CA IV

by C.T. Supran. This paper presents result of quantitative structure–Property relationships (QSPR) study realized with the PRECLAV, omega, brood and MOPAC software. The dependent property is the inhibitory activity against human carbonic membrane-associated hCAIV. The calibration set includes 11 heterocyclic sulphonamides incorporating with two clinically used CA inhibitors namely AZA and ZNS molecules. The prediction set contains 11 others not yet synthesized substituted sulphonamides having unknown observed values of activity. In the presence of prediction set, the predictive quality of QSPR of hCA VI (r2 = 0.9869, F =338.1053, r2CV =0.9795) is large. The obtained models suggest a slightly different inhibition mechanism for the two isoforms. Large percentage, in weight, of C2HN3, Br atom molecular fragments seems to be favorable to inhibitory activity and NH2 and SO2.

Keywords: QSAR, omega, brood, PRECLAV, carbonic anhydrase IV SYNTHESIS AND C.N.S. DEPRESSENT ACTIVITY OF NOVAL SERIES OF THIAZOLIDENE DERIVATIVES Dhananjay Singh *Department of Chemistry, P.P.N. (P.G.) College, C.S.J.M. University, Kanpur (U.P.) India Email- dhananjay360@gmail.com /

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Several new 5 -(p-substituted /unsubstituted) phenyl-1,3,4- Thiadiazolyl-2 -(5-pheyl-2- oxo-thiazolidine) & 4 / (p-substituted /unsubstituted) phenyl-1,3- oxazolyl -2 -(5-pheyl-2- oxo-thiazolidine) have been prepared by reaction of 2-substituted arylidine- 5-phenyl thiadiazole & 2-substituted arylidine- 5-phenyl oxazole with thioglycolic acid respectively. Few of these compounds are characterized by IR and NMR spectra. These compounds have been tasted for their C.N.S. activity. Spontaneous motor activity (SMA) of mice in group was recorded by using automatic activity cage. Some of the compounds were possess a moderate degree of central sedative action as in evident from the reduction in SMA. Keywords: Oxazole, Thiadiazole, Spontaneou motor activity, C.N.S. IRIDIUM CHEMISTRY AND ITS CATALYTIC APPLICATIONS: A BRIEF REVIEW Santosh Bahadur Singh Department of Chemistry, National Institute of Technology Raipur, Raipur-492010, Chhattisgarh (India) E-mail: singhsbnitrr15@gmail.com; Iridium is very important element among the all transition metals with highest reported oxidation state i.e. +9 in + gas phase existing species IrO4 . Instead of its less reactivity, it forms number of compounds having oxidation states between -3 to +9. It is second known densest element after osmium. Till now its toxicity and environmental impact is not much more reported and thus it may be use as green element in various fields of its application. Reason behinds itâ€&#x;s less toxicity and environmental impact may be due to its less reactivity and solubility. Corrosion and heat resistant properties of Iridium makes it much more useful element for alloying purpose. Iridium is the member of platinum family and used as catalyst due to its variable oxidation states.

Iridium(III) complexes shows great catalytic activity in both the acidic and basic medium for various organic as well as inorganic chemical conversions. Catalyst may be defined as the substance which can increases the rate of reaction of a specific chemical reaction without changing its own composition. Iridium is only one reported catalyst which is able to capture the sunlight and convert it into the chemical energy. Thus, it may be used in artificial photosynthesis process to solve our future food problem. Instead of these advantage, Iridium chemistry and its catalytic activity is not much reviewed till date, therefore, present review includes a brief introduction about chemistry and catalytic application of Iridium, which proof itself a boon for beginners to start their research career in the field of Iridium chemistry.

Keywords: Iridium, Oxidation State, Catalysis, Photosynthesis, Alloys, Environmental Impact.

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India IMMUNOMODULATORY POTENTIAL OF MADHUCA LONGIFOLIA Dr. Santosh Kumar Singh Assistant Professor, Department of Chemistry Sri J.N.P.G. College, Lucknow E-mail: santoshsinghjnpg@gmail.com A large number of plants and their isolated constituents have been shown to have potential immunity. Some medicinal plants have been shown to exert immunomodulatory and anti-cancer activity. The present study was undertaken to evaluate the effect of Madhuca latifolia on immunomodulatory activity that comprises of screening to identify the activity of ethanolic extract of Madhuca latifolia on humoral and cell mediated immunity (specific immune response). Experiments were conducted in vivo in Swiss albino mice. Madhuca latifolia ethanolic extract was found to enhance humoral immune response on 10th day by 15% as compared to the standard control cyclophosphamide that exhibited 64% humoral immune response, where as cell mediated immune response was observed with an enhancement in the values (25.57%) in comparison with control cyclosporine (47.80%).

SHIFTING PRACTICES IN PHARMACEUTICAL INDUSTRY: ROLE OF GREEN CHEMISTRY *Dr Abha Dubey, Dr Rakhi Dwivedi, Dr Subhashini Sharma, Dr Renu Sharma Dept. of Chemistry MMH College Ghaziabad CCS University Meerut UP E-mail: abhaadubey@gmail.com, Madison, Wisconsin – “Production of a single kilogram of pharmaceuticals often yields hundreds of kilograms of chemical waste”.

The mute point is to deal with this mountain of chemical waste. This chemical waste seems impossible to be disposed off without leaving damages to the environment. Link between pharmaceutical industry and environment is the serious concern for the researchers. Certain pharmaceutical contains chemicals which can adversely affect living beings. To address the problem of this chemical waste would be a patch work if we just think of dealing with this waste. Instead Green Chemistry has a momentous task of creating newer practices of producing relevant molecules with least generation of hazardous by products. Modern pharmaceutical research has taken up this challenge of investing massively on new facilities of R&D to reach out to the desired products with possibility of recycling the by-products.

Taking up the responsible, the pharmaceutical industry has started adopting “greener” processes and technological operations. Big drug manufacturers in the developed countries are advancing new methodologies, better bio-catalytic reactions, less solvents and generation of lesser waste. Pharmaceutical industry introduces practices to save a negative impact of its products on environment. Still bigger is the challenge that this is to be done without adding to the cost by resorting to financially viable methods. Safety, Efficiency, Reliability and Economy are the four pillars of establishing a sound foundation for Green Practices and their promotion is considered as bringing competitive advantage, better environmental credentials and economic benefits. The hope is that new technology will contribute to the „greening‟ of the pharmaceutical industry.

COMPETITIVE ADSORPTION BEHAVIOR OF CR(VI) AND MO(VI) THROUGH SIX TYPES OF SOIL BEDS a* b Abdul Moheman and Ali Mohammad a Department of Chemistry, Gandhi Faiz-e-Aam (Post Graduate) College, Shahjahanpur, 242 001, India b Department of Applied Chemistry, Aligarh Muslim University, Aligarh, 202 002, India *E-mail: amohemanappchem@gmail.com Generally chromium(VI) and molybdenum(VI) are found in soil at low concentration level as a result of contamination by agricultural activities, sewage sludge, industrial wastes and waste water. Both metals have many physical and chemical similarities and belong to the same group (group VI) of the periodic table. These metals when apply to soil, may transport through soil and can react with organic and inorganic compounds to form soluble or insoluble compounds or get adsorbed on soil colloids. Our goal was to investigate the adsorption behavior of chromium (VI) and molybdenum (VI) using six types of soil beds by thin layer chromatography. On the basis of differential migration, optimum conditions for the separation of Cr(VI) from Mo(VI) on soil thin layer plates were identified. The adsorption of Cr(VI) and Mo(VI) through all soils follows the order: Mo(VI) > Cr(VI). A statistical analysis of the results (p ≤ 0.05 and 0.01 level) revealed, a significant positive correlation between RF values of Cr(VI) and Mg content of soil (r = 0.930) or the base saturation (r = 0.831) as well as between RF value of Mo(VI) and Mg content of soil (r = 0.872), sum of bases (r = 0.847) or 7

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India the base saturation (r = 0.925). Conversely, a significant negative correlation between R F values of Cr(VI) and soil organic matter (r = -0.916) or cation exchange capacity of soil (r = -0.851) was observed. Similarly, significant negative correlation between RF values of Mo(VI) and clay content (r = -0.928) or cation exchange capacity (r = -0.852) of soil also exists. The adsorption of Cr(VI) and Mo(VI) were found to depend upon the soil parameters such as soil organic matter, clay content of soil, cation exchange capacity of soil, cation saturation, size of soil particles, soil pH, sewage sludge content as well as the sample pH and the nature of surfactant in the mobile phase.

Key words: Adsorption, metal ions, soil parameters, surfactants, soil thin layer chromatography.

SYNTHESIS AND CHARACTERIZATION OF ZINC COMPLEXES WITH NUCLEOBASES Dr. Shalu Tyagi

M.M.H.College, Ghaziabad, U.P. shalutyagi.30@gmail.com, The metal coordination of nucleobases, their precursors, derivatives and of nucleosides, nucleotides is very active area of research. Zinc is also present in various enzymes along the biosynthetic pathways of the t nucleobases or for phosphate transfer during nucleotide interconversions. The synthesis of HB(3-Bu -5i t i Pr pz)3)ZnX (where X is thymine 2/ adenine 3) using HB(3-Bu -5-Pr pz)3)Zn-OH 1 has been described. The complexes were characterized by elemental analysis, I. R. and X-ray powder diffraction. I. R. data also suggested that the thymine is bound to zinc via N1 as in the case of uracil while N9 seems to be preferred donor atom in case of zinc complex of adenine. The indexing pattern of X-ray powder diffraction yield the lattice constants, a = b = 14.31, c = 19.24 Å for 2; a = b = 13.38, c = 15.07 Å for 3 indicating tetragonal symmetry for these complexes. During these studies it became obvious that the deprotonation of mildly acidic NH functions is facilitated in the presence of zinc ions and the encapsulation of zinc by sterically demanding tripodal ligands facilitates complexation of the corresponding anionic species. The substituted pyrazolylborate t i ligand KHB(3-Bu -5-Pr pz)3) was found to stabilize monoanionic species X by protecting them in the hydrophobic pocket of the neutal complexes 2 and 3.

SYNTHESIS, SPECTROSCOPIC AND BIOLOGICAL STUDIES OF LANTHANUM(III) AND PRASEODYMIUM (III) DERIVATIVES WITH LIGANDS DERIVED FROM BENZIL-α-MONOOXIME Anita Rai, Department of Chemistry, P.P.N. P.G. College, Kanpur, U.P., India Email: raianita19@gmail.com, Eighteen new lanthanum(III) and praseodymium(III) complexes of the general formula [LnCl(L)H 2O]2 (Ln=La or Pr); L=benzil-α-monoxime semicarbazones/ thiosemicarbazones / dithiocarbazates, have been synthesized in methanol in presence of potassium hydroxide. The complexes have been characterized by elemental analysis, 1 13 molar conductance, electronic absorption, fluorescence, infrared, far infrared, H and C NMR spectral o studies. Thermal studies of these complexes have been carried out in the temperature range 25-800 C using TG, DTG and DTA techniques. All these complexes decompose gradually with the formation of Ln 2O3. These complexes are used as polymer catalyst, fungicides and bactericides.

SYNTHESIS, CHARACTERIZATION AND APPLICATIONS OF SILVER NANOPARTICLES PREPARED BY BIOMIMETIC METHODS: A REVIEW Mahesh Kumar Gupta, Girdhari Lal Chaurasia, Neelam Shukla, P.K.Tandon * Department of Chemistry, University of Allahabad, Allahabad, U.P E-mail: pktandon1@gmail.com, mahesh27620@gmail.com, Nanotechnology is science, engineering and technology conducted at the nanoscale, which is about 1 to 100 nanomters. In the nano size range the physical, chemical and biological properties of matter may change drastically in relation to the bulk of atoms or molecules. The applications of nanoparticles and nanomaterials are increasing rapidly due to their enhanced properties based on size, their distribution and morphology. It is an important discipline which has multiple applications such as in the fields of health care, cosmetics, biomedical, food and feed, drug-gene delivery, environment, health, mechanics, optics, chemical industries, electronics, space industries, energy science, catalysis, light emitters, single electron transistors, nonlinear optical devices, photo-electrochemical industries etc.. Metallic nanoparticles are long being used by different disciplines in the science and engineering and are still charming the scientists to explore the valuable 8

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India characteristics, properties and application tiny size of nonmaterial. Conventionally silver nanoparticles are synthesized by chemical methods using chemicals as reducing agents which may be harmful to living organisms and pose environmental contamination. To reduce the hazards of contamination to the environment and other organisms, the ecofriendly biomimetic synthetic methods have been used by different researchers in which bio-molecules extracted from the parts of plants are used for the synthesis of nanoparticles. The present review explores the use of various bio molecules obtained from different plant parts for the rapid and one step green synthetic methods and also describes the applications of these materials for environmental applications and also for the remediation of water contaminated with chemical and microbial pollutants.

Keywords: Ecofriendly, Nanoparticles, biomolecules, Pollution, remediation SYNTHESIS AND CHARACTERIZATION OF POLY(ESTER-AMIDE ) RESIN OF MALEIC ACID DERIVED FROM MELIA AZEDARACH SEED OIL A. Hasnat* and Sageer Ahamad Department of Chemistry, G.F. College (MJP Rohilkhand University) Shahjahanpur, UP Email: amohemanappchem@gmail.com, Synthesis of polymeric materials using renewable resources as precursor now- a-days attracted the attention of academia and scientists due to depletion of traditional resources petrochemical and environmental problems both. It is desire to innovate the materials which are not only eco-friendly but it must also be friendly to environment. Numerous polymers have been synthesised using the renewable resources such as starch, lignin, protein, cashew nut, wool fibre, vegetable oil and many others. They find innumerable application in diverse field of life. Among the different renewable resources vegetable oils especially those obtained from seeds of different plants play vital role in the syntheses of various polymers.

Melia azedarach belongs to the family of Meliaceae, largely cultivated in rural areas with especial reference to its wood and ornamental look. The seeds of plant contain triglyceride oil comprise with saturated and unsaturated fatty acids. The iodine value of oil is found sufficiently high, encourage us to utilized this seed oil in making poly(ester-amide) - a polymer of film forming ability. Poly(ester-amide)s are amide modified alkyds reported for improve performances due to presence of both groups. Keeping these facts in mind in present work we have made effort to utilized the Melia azedarach seed oil in the synthesis of poly(ester-amide) using the poly(condensation) polymerizing techniques where, maleic acid is used as dibasic acid. The synthesized polymer and intermediates were characterized as per standard reported method and by spectral analyses.

Synthesis of poly(ester-amide) of maleic acid provides a suitable and profitable utilization of the Melia azedarach seed oil a precursor of natural renewable resource.

POLYMER OF NATURE Gihar Sachin, Itwari lal Sr. Lecturer, V.R.A.L. Govt. Degree College, Bareilly Email: gungunpapa15@gmail.com, Green polymers are those produced using green ( sustainable ) chemistry. Polymers are the sustances having very large number of repeatig units and hence having very high molecular mass.The polymers are formed by polymerisation process.They may be natural or synthetic.The green polymers are dedicated to the latest developments in producing conventinal polymers from sustainable sources including plants and biofertilisers , algae , waste and carbon di oxide.

In modern society the life is fully crowded by innumerable applications of polymers or roughly called plastics.

The synthetic polmers are used in industrial production of elastomers , fibers, resins, adhesives, plastics etc.

Besides above excessive uses of polymers due to their low cost, they have many environmental hazards issues, like occupational hazards, pollutions ( land, air, water, marine,mountain ) , health hazards etc.The plastic products are nongradable to environmental forces like solar radiations , hydrolysis, atomospheric oxidation.These synthetics are also nonbiodegradable because of high molecular weight ,poor water solubility and high branched structure.

Nowadays synthetic polymers having some structural similarities with natural biodegradable polymers have been prepared under the concept of green chemistry i.e. green polymers. Some examples are polyhydroxybutyrate ( PHB ), polyhydroxyvalerate ( PHV ), polylactides ( PLA ),carboxy methoxy cellulose ( CMC ), BIOPOL, COHPOL, bioplast etc.The PLA can be obtained from the renewable sources like sugarcane and corn.

Key words- Sustainable chemistry, polymers , pollution , biodegradable , PHB , PHV , BIOPAL. 9

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India

SUSTAINABLE BIODEGRADATION OF POLYMERS: A COMPARATIVE ANALYSIS Alka Chaudhary Govt. Raza (P.G.) College, Rampur (U.P.) Email: alkach4@gmail.com, Development of ecofriendly pathways to create sustainable livelihood is the focus of modern chemical research. It is necessary to set benchmark in the area of environmental and social responsibility. Many pathways are being developed to achieve status of carbon positive, solid waste positive and cycling positive globally. The study is about ecofriendly, non-toxic pathways in synthetic chemistry and safe pollution free decomposition of wastes in the field of polymer chemistry. The polymers produced by renewable resources such as poly lactic acid created by fermenting starch has shown the potential of replacing some regular plastics. The co-polymers of poly lactic acid (PLA) and polyethylene glycol (PEG) produce biodegradable polymers. Oil eating microbes have also been discovered. The study conducted with samples of some biodegradable polymers at various temperatures gave interesting results. In many cases addition of metal salts catalyzed the degradation process and produced water, carbon di oxide and bio mass. The degradation time of different samples with different metal salts depends upon the type of linkage in polymers and temperature.

Key words: Biodegradation, Metal Catalysts CATALYTIC ACTIVITY OF SILVER NANOPARTICLES: APPLICATION IN FIELD OF MICROWAVE ASSISTED OXIDATION OF SOME AROMATIC ALCOHOLS BY IN SITU GENERATED ZINC DICHROMATE TRIHYDRATE Manish Srivastava,* Aakankasha Mishra, and Anamika Srivastava * Department of Chemistry, Banasthali Vidyapith, Banasthali, Rajasthan, 304022, India.

Email: sagermanish1@gmail.com, The oxidation of some aromatic alcohols by zinc dichromate trihydrate has been presented. As the activator of ZDT the catalytic amount of AgNPs was chosen as catalyst was examined in homogeneous condition. The reaction in conventional conditions was compared with the microwave assisted reactions. It was found that without catalyst, no reaction takes place in 7.0 min under microwave irradiation, although in presence of nanocatalyst, reaction completed within 2.0 min with excellent yield. The size of silver nanoparticles was found that the average particle size of individual silver nanoparticles is approximately 27.84 nm on the basis of XRD, SEM and TEM analysis.

ROLE OF GREEN ECO-FRIENDLY TECHNOLOGY IN SYNTHESIS OF VARIOUS INDOLE DERIVATIVES OF MEDICINALLY POTENT PROPERTIES 1 2 a1 Rajendra , Tiwari S. P. and Dwivedi Jay 1 Department of Chemistry, Banasthali University, Banasthali, Rajasthaan-304022 2 Department of Chemistry, The IIS University, Jaipur, Rajasthaan-302 020 Email: sagermanish1@gmail.com, This paper explores importance of synthesis of various indole derivatives using microwave assisted techniques. Additionally, this paper enlightens the biological applications of indole and its derivatives.

Preparation of differently substituted indoles through microwave-assisted technique found to be efficient and resulted in intermediate to high yields. These reactions did not involve any added catalyst like acid, or base, and conventional heating. This approach has been used for catalytic hydrogenation reactions and furnishes the indole derivatives in good yields. Eventually, in this paper microwave-assisted engineered indole derivatives are discussed to develop new drugs for instance thieno[3,2-b]indoles for M. tuberculosis H37Rv (MTB) and multi-drug resistant M. tuberculosis (MDR-TB).

INTRINSIC VISCOSITY OF HYDROXYL TERMINATED POLYBUTADIENE (HTPB)-AN ENVIRONMENTAL APPROACH V.S.Gangwar and Sandeep Singh Department of Chemistry, VSSD College,Kanpur (India) Email: vs_gangwar@rediffmail.com In this work, theoretical determination of intrinsic viscosity, [Ρ], of HTPB polymers was carried out which have environmental utility as they use relatively less solvent than the classical methods. Various theoretical 10

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India methods were utilized to study the intrinsic viscosity, [η] of HTPB. The polymer-solvent interaction parameter in three different solvents, i.e. toluene, tetra hydro furan, and chloroform, was evaluated to select the suitable solvent for this study. Two approaches, i.e. Hoftyzer-Van Krevelen and Hoy, were used for estimation of solubility parameter (δHTPB) of the polymers. The δHTPB obtained by Hoftyzer-Van Krevelen method was found to deviate slightly from Hoy‟s method. The ∆ value (difference between solubility parameters of polymer and solvent) was in the order: toluene < chloroform < tetrahydrofuran. The value in toluene was the lowest (i.e.

0.38) indicating good solvation of the polymer. The results of [η] in toluene at 30 ± 0.1 °C obtained were compared with the value obtained by graphical extrapolation methods based on Huggins, Kraemer, Martin, and Schulz-Blaschke equations. The Huggins constant was < 0.4 for both the polymers. The single point method based on Kuwahara was found to be the best alternative to the graphical extrapolation methods with a deviation of ± 0.1 % from the value obtained by Huggins method. The proposed method would save approximately 80 % solvent used as well as labour and time. Thus, it is the most economical and environmental method for the determination of intrinsic viscosity of HTPB polymer.

CATALYTIC EFFECT OF TRANSITION METAL IONS AU (III) AND PD (II) ON THE OXIDATION OF AROMATIC AND CYCLIC HYDROCARBONS BY IN SITU GENERATED SODIUM FERRATE UNDER MICROWAVE IRRADIATION Anamika Srivastava* and Manish Srivastava * Department of Chemistry, Banasthali Vidyapith, Banasthali, Rajasthan, 304022, India.

Email: sagermanish1@gmail.com, Oxidations of various aromatic and cyclic hydrocarbons by in-situ sodium ferrate in the presence of metal ion catalysts like Au (III) and Pd (II). Ethyl benzene, propyl benzene cyclohexane, naphthalene, anthracene and phenanthrene, dissolved in minimum amount of acetic acid oxidized by in-situ sodium ferrate in the presence of traces of Au (III) catalyst and Pd (II) catalyst under microwave irradiation. In case of oxidation of ethyl benzene, propyl benzene, cyclohexane, naphthalene, anthracene, and phenanthrene, dissolved in acetic acid to give 93.33 %, 86.66%, 57.55%, 82.08%, 91.34 and 83.33% yields in case of gold catalyst and 48.33%, 45.0%, 32.37%, 47.68%, 48.07% and 47.02% yields in case of palladium as a catalyst. That in case of gold(III) catalyst give the higher yield as compare to copper(II) catalyst because the electrode potential of the Au(III) is +1.5 and Pd(II) is 3+ +0.987.The electrode potential of Au(III) is higher than compared to Pd(II) electrode potential so Au oxidation 2+ state is more stable and more reactive than Pd . The reported novel one-pot system is highly efficient, and also can be used to oxidize a variety of other functional group comparisons, for which studies are being done.

SYNTHESIS AND EVALUATION OF HERBICIDAL ACTIVITY OF SOME 1,3-DIARYL-10-SUBSTITUTED-2THIOIMIDAZOLO[4,5-B] PYRIMIDINO[3,2-A] PYRIDINES Kahkashan Begum Department of Chemistry, Gandhi Faiz-e-Aam College, Shahjahanpur, U.P. E-mail: apkahkashanbegum@gmail.com A series of compounds involving five and six membered nitrogenous heterocyclics have been synthesized and screened for their herbicidal activity. 1,3-Diaryl-10-substituted-2-thioimidazolo[4,5-b] pyrimidino[3,2-a] pyridines have been synthesized by refluxing a mixture of 1,3-diaryl-5-alkyledin-2-thiohydantoin (0.01 M) and fused sodium acetate (0.01 M) in dioxane (10 mL) for 5 hours. The required reactant was obtained when a mixture of 1.3-diaryl-2-thiohydantoin (0.01 M), an aldehyde (0.01 M) and anhydrous sodium acetate (0.11M) in acetic acid (30 mL) was refluxed for 3-4 hours. Newly synthesized compounds have been characterized by IR recorded in KBr as Perkin Elmer 881 spectrophotometer, PMR spectra was recorded in CDCl 3. All other analysis was carried out at RSIC, CDRI Lucknow and at BHU Varansi. These compounds have been found to have mild to high herbicidal activity against D. Ciliaris, C.album and N. Tabacum.

Key words: Herbicidal activity, nitrogenous compounds, Heterocyclic compounds Au (III) AND Cu (II) CATALYST FOR OXIDATION OF AROMATIC AND CYCLIC HYDROCARBON BY CERIUM (IV) IN ACIDIC MEDIUM UNDER MICROWAVE IRRADIATION Manish Srivastava, * Ashu Goyal, Anamika Srivastava, Aakanksha Mishra and Preeti Tomar * Department of Chemistry, Banasthali Vidyapith, Banasthali, Rajasthan, 304022, India. sagermanish1@gmail.com The addition of traces of Au(III) chloride with Ce(IV) sulphate (catalyst: substrate ratio (1: 80 to 1: 300)) and in case of Cu(II) sulphate with Ce(IV) sulphate(catalyst: substrate ratio (1: 60 to 1: 250)) in solution phase under 11

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India microwave irradiation resulted in good to excellent yields of corresponding to phenol, quinone and carbonyl compounds. In case of oxidation of anthracene, phenanthrene, naphthalene, cyclohexane and toluene dissolved in acetic acid to give 95.02 %, 85.25%, 34.68%, 40.94%, and 56.54% yields in case of gold catalyst and 93.5%, 83.4%, 24.68%, 38.25% and 47.11% yields in case of copper as a catalyst. Phenanthrene was oxidized in 9-Fluorenone instead of phenanthraquinone to get the benzylic rearrangement.

Keywords– Aromatic hydrocarbons, Oxidation, Cerium(IV) sulphate, Ce(IV)-Au(III), Ce(IV)-Cu(II) system, Characterization, Microwave Synthesizer.

SYNTHESIS AND CHARACTERIZATION OF ALUMINA-INCORPORATED POLY (ESTER-AMIDE) FROM JATROPHA CURCAS SEED OIL Mohsin Hasan Khan Department of Chemistry, G.F. College (M J P Rohilkhand University) Shahjahanpur, U.P. India drmhkhan6485@gmail.com, Polymers are one the applied part of Chemistry and technology as it receives versayile application in our day to day life. However, most of the polymeric materials are derived from the petrochemicals which are going deplete with fats rate, consequently cost of final product in increasing order. Over the last few years research workers are trying to search economical and friendly to environment specialty chemicals from the spectrum of natural renewable resource. The utilization of vegetable oils (VO) for the synthesis of polymers provides an opportunity to utilize a renewable raw material, which benefits industries and environmental stakeholders. The common seed oils such as linseed, sunflower, castor, soybean and many others have already been utilized in the synthesis of useful polymers. Among these traditional oils some of them have medicinal values and are also edible. Therefore, it is required to explore the spectrum of nature‟s gifts and utilized the vegetable oil of non-edible characteristics in the development of polymers to arrest the demand of feed stock.

Jatropha curas is a medium sized tree wildly grown in different part of the country and also largely cultivated in rural areas with special reference to its wood. Its seed contain about 46- wt% triglyceride oil of saturated and unsaturated fatty acids. Meager utilization of Jatropha curcas seed oil (JCSO) especially in the syntheses of polymeric materials encourages us to prepare alumina-incorporated poly (ester-amide) of adipic acid (JCAPEAU). Jatropha curcas Poly (ester-amide) of adipic acid (JCAPEA) is synthesized by the aminolysis of JCSO followed by the step-growth polymerization with adipic acid. To improve the physic-mechanical and chemical resistance properties Alumina was incorporated in the JCPEA. The synthesized resin and intermediates were characterized by measuring the physic-chemical properties as per standard laboratory methods; where as structural elucidation of the resins were carried out by the spectral analyses. The studies reveals that JCAPEA resin of adipic acid holds promise for one of the useful utilization of Jatropha curcas seed oil which is also eco-friendly.

APPLICATION OF MICROWAVE IN API SYNTHESIS Poonam Gupta Department of Chemistry, M.M.H. College, Ghaziabad.U.P. E mail: pg4542@yahoo.co.in Microwave chemical synthesis has become a method of choice for chemists through out many industries. The technology allows the synthesis to be done faster and cleaner with reduced solvent consumption as a “greener” process. Due to mass heating effect much faster temperature increase can be obtained depending upon microwave power. A variety of organic reactions can be done faster and with higher yield with microwave assistance. It allows less byproducts, high purity, selective heating, low energy input, green solvent, less solvent usage and software supported experiment documentation. Many active pharmaceutical agents (API) have synthesized using microwave assistance. For example, Trimethoprim, Albuterol and oxaprozin etc. In the synthesis of Albuterol, the different steps require prolonged heating. With microwave heating the rate of reaction and yields are significantly increased.

FACILE ECO-FRIENDLY SYNTHESIS, CHARACTERISATION AND EVALUATION OF ANTI-MICROBIAL ACTIVITY OF Cu(II) COMPLEXES OF TRIDENTATE LIGANDS Krishna P. Srivastava*, Om Prakash Putul & Nagendra Kumar Department of Chemistry, Jai Prakash University, Chapra-841301, Saran, Bihar, INDIA *Presently Principal, N.L.S.College, Jaitpur-Daudpur, Saran (Bihar) E-Mail: gscdrkpsritprin@gmail.com, jpukpsrichem@rediffmail.com 12

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India A facile, fast, simple, highly efficient, environmentally safe and economical method has been used for the synthesis of the two new biologically active 1,2-dihydroquinazolin-4(3H)-ones (L1 & L2) in single step by treating o-aminobenzoylhydrazone (o-ABH) with aromatic aldehydes with superior yields using microwave irradiation in polyethylene glycol (PEG) as an alternative solvent and other two new hydrazones (L 3 & L4) by condensing o-ABH with same aromatic aldehydes under normal conditions. The copper (II) complexes of synthesed ligands have been prepared in an environmentally benign microwave protocol and characterized by elemental analysis, conductivity measurements, magnetic moment, spectral and thermogravimetric analysis.

The antimicrobial activity of the free ligands and their copper (II) complexes clearly indicates that the ligands have both an antibacterial and antifungal potency against the organisms tested. In most cases, the complexes were found to be more active than the free ligands, but in some cases, an equal activity was displayed.

Keywords: Coordination Complexes; Quinazolinone; antimicrobial activity; PEG-300; Copper (II) IMPROVE THE NATIVE CHARACTERISTICS OF POLYSACCHARIDES BY GRAFTING THROUGH THE GAMMA RADIATION: A REVIEW 1 1 *1 *2 Deepak kumar , Nida khan , Pramendra Kumar , Jyoti Pandey 1 Department of Applied Chemistry, M J P Rohilkhand University, Bareilly (U.P.), India 2 Department of Applied Chemistry, Babasaheb Bhimrao Ambedkar Central Government University, Lucknow (U.P.), India Email: dpk.4470@yahoo.in, deepak200789@gmail.com Polysaccharides are bio-degradable, inexpensive and easily available from consistent agricultural resources.

Polysaccharides and their derivatives represent a group of polymer widely used in pharmaceutical and biomedical fields. The biodegradability of natural polymers reduces their shelf life. Grafting copolymerization technique is a most effective fascinating way for chemical modification of native characteristics of polysaccharides with maximum possibilities for improving the properties of polysaccharides and enhanced the range of exploitation. While the major difficulty facing us during synthesizing a graft copolymers reaction, is the lack of commercial methods of synthesis and lower percent graft yield. It is well known that, the most important methods of synthesis engage the employ of chemical free radical initiator i.e. conventional based methods.

Graft copolymerization through Îł-radiation method is a better method of grafting in comparison to chemical method and exhibits a great potential to synthesize the graft copolymers by virtue of its higher efficiency, low cost, higher thermal stability as well as enhanced the yield of graft copolymer. Future prospective of irradiation technique would be significant impacts to develop of polymerization.

Key words - Grafting, Polysaccharides, Gamma Radiation, Copolymer, Polymerization.

SYNTHESIS, CHARACTERIZATION AND ANTIFUNGAL ACTIVITY OF SOME NOVEL 4-ARYL HYDRAZONO-2,5-DISUBSTITUTED-2,4-DIHYDRO-3H-PYRAZOL-3-ONES *Vipin Kumar Singh, Dr. D.P. Singh Synthetical Organic Research Lab., Department of Chemistry T. D. P. G. College, Jaunpur (U.P.), INDIA E-Mail: vipinksingh24@gmail.com 4-Aryl hydrazono-2,5-disubstituted-2,4-dihydro-3H-pyrazol-3-ones were prepared by the reaction of ethyl-2arylhydrazono-3-oxobutyrates with substituted hydrazine in the presence of glacial acetic acid. The synthesized compounds have been characterized by elemental and spectroscopic methods viz; UV, IR & PMR spectroscopic methods. The title compounds have been screened antifungal activity against P.Graminis tritici and P.recondita at different concentrations.

Keywords: pyrazol-3-one, antifungal, substituted hydrazine, oxybutyrates SYNTHESIS, CHARACTERISATION AND PERFORMANCE EVALUATION OF IRON CONTAINING POLYESTERAMIDE FROM MELIA AZEDARACH SEED OIL-A RENEWABLE RESOURCE Mohd.Naseem*, A.Hasnat and S.Aziz Ahmad Applied Chemistry Lab, University Polytechnic, Integral University Campus, Shahjahanpur, U.P. Email: naseemm53@yahoo.com The depletion of petroleum oil reserves and the environmental issues draw the attention of modern day chemists to search low cost renewable starting raw material for the chemical industries. In this regard the seed oil of different plants pay considerable attraction by the academia and scientists for the utilization as a starting raw material especially for the polymer industries. Melia azedarach is a medium sized tree widely grown 13

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India throughout the country as a shadow tree and its wood largely used as a timber. The seeds of the plant have approximately 40-wt% non edible oil with sufficiently high unsaturation. In the present work, oil of the M. azedarach seeds utilized in making low molecular weight polyesteramide which was further modified by the incorporation of iron. The physico-chemical characterization of the polyesteramide and iron-filled polyesteramide were carried out as per standard reported methods. The newly developed polyesteramide and iron- incorporated polyesteramide resins were applied on mild steel strips of required size to investigate the chemical resistance performances. The results show that the incorporation of iron had enhanced the performance of polyesteramide and is more suitableas a coating material.

Key words- M.azedarach seed oil, Iron-filled polyesteramide, coating material.

SYNTHETIC AND SPECTRAL STUDIES OF COMPLEXING BEHAVIOR OF NITRITO COMPLEX OF 4[(NBENZALIDENE) AMINO] ANTIPYRINE Sakshi Chaudhary D.N. (P.G.) College, Meerut shivashish08@gmail.com, Pyrazolones have been reported to be potential extractants as well as powerful drugs. Trivalent Lanthanides behave as hard acid and thus are expected to form stronger stable complexes with ligands having N-donor atoms. Coordination number less than six are uncommon for the lanthanides. Substituted Pyrazolones have been reported to possess strong pharmaceutical properties. Lanthanide (III) Nitrate and double amount of ligand 4[(N-benzalidene)amino]antipyrine(C18H17N3O) are used for the preparation of complexes. Molar conductance, molecular weight, magnetic susceptibility, infrared and electronic spectroscopy were used to characterization of newly synthesized complexes.

Key Words: Lanthanide Nitrate, Pyrazolones, Magnetic susceptibility, Infra red and electronic spectroscopy, Molar conductance and Thermal studies of the complexes.

CONVERSION OF PRIMARY AMIDES INTO NITRILES ADAPTING NEW PROCEDURE Rakesh Mani Misra, Assistant Prof. Department of Chemistry, Harish Chandra P. G. College, Varanasi Email: rakeshmanimisra@hotmail.com, The conversion of amide group into cyano group is an important conversion with wide utility in organic synthesis. Although there are various pathway by which this change in functionality may be brought about but, in this piece of work we wish to report more convenient way for this conversion. Basically this conversion can be brought about by dehydration. The new process of dehydration can be facilitated by coupling amide with methyl di chloro phosphate (MeOPOCl2) or phenyl dichlorophosphate (C6H5OPOCl2) followed by rapid elimination with 1,8 - [diazabicyclo 5.4.0]undec-7-ene (DBU) to form the corresponding nitriles. the mild reagent, either MeOPOCl2 or C6H5OPOCl2, applied in this newly developed methodology, to our knowledge, are unprecedented. We carried out the experiment with benzamide in presence of different bases to get Benzonitrile accompanied with different dehydrating agent including N,N-dimethylphosphoramidic dichloride [(CH3)2NPOCl2],{ and N,N-dimethylphosphoramidous dichloride [(CH 3)2NPCl2] . considered the reagent of choice to facilitate the dehydration reaction in terms of conversion rate and reaction time (Entry 3). As well, DBU was found to be more effective than other commonly used bases such as triethylamine and pyridine among the dehydration systems investigated. Under similar conditions, dehydration of several functionally diverse primary amides can further be performed.

Key words: nitriles, DBU, dehydration CLEAN AND SELECTIVE BAEYER–VILLIGER OXIDATION OF KETONES WITH HYDROGEN PEROXIDE CATALYZED BY Sn-PALYGORSKITE Dr. Ashok Kumar Singh, Asst. Prof. Department of Chemistry Harish Chandra P. G. College, Varanasi Email: rakeshmanimisra@hotmail.com, An environmentally benign and selective Baeyer–Villiger oxidation system is introduced. Palygorskitesupported Sn complexes were prepared by a simple procedure. Cyclic ketones and acyclic ketones were oxidized by hydrogen peroxide in a reaction catalyzed by palygorskite-supported Sn complexes, affording corresponding lactones or esters with selectivity for the product of 90–99%. The influence of the solvents, reaction temperature, the amount of catalyst used and the reaction time on the catalytic activity and product 14

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India selectivity were investigated in detail. The catalyst is cheap, easy to be prepared in large scale and can be recycled. An environmentally benign and selective Baeyer–Villiger oxidation system is introduced.

Palygorskite-supported Sn complexes were prepared by a simple procedure. Cyclic ketones and acyclic ketones were oxidized by hydrogen peroxide in a reaction catalyzed by palygorskite-supported Sn complexes, affording corresponding lactones or esters with selectivity for the product of 90–99%. The influence of the solvents, reaction temperature, the amount of catalyst used and the reaction time on the catalytic activity and product selectivity were investigated in detail. The catalyst is cheap, easy to be prepared in large scale and can be recycled.

NEW CHELATING QUATERNARY AMMONIUM CRYSTAL VIOLET POLYELECTROLYTE: SOLVATION PROPERTIES AND ANALYTICAL APPLICATION. Dr. Anil Kumar Department of Chemistry, Harish Chandra P G College (MGKVP University), Varanasi-221001 anilk642@gmail.com Three new classes of quaternary ammonium crystal violet polyelectrolyte have been synthesized and their characterization through elemental analysis, infrared spectroscopy and conductometric titration. Their stability as ascertained by thermo gravimetric technique such as TGA and DTA. The purity (monodispersity) of the prepared compound was verified by thin layer chromatography. The solvation properties of these three linear polyelectrolytes containing crystal violet in the main chain like Poly [ N-ethylene monohydroxy crystal violet dibromide ], Poly [ N-p-xylylene crystal violet trimethoxide] and Poly [ N-2,5-diacylthiophenylene crystal violet trichloride]. The solvation characteristics of these systems are explored in dipolar aprotic solvents through viscosity measurements in Propylene Carbonate (PC) and Sulfolane over small temperature range 25±5˚C in PC and 35±5˚C in sulfolane. Intrinsic viscosities of these systems are also studied. These polymers were found to be useful for the modification of Chromatographic column packing materials to provide robust chelating resins. A comprehensive work for the applications of these resins for metal speciation of Ganges river water and sediments has been undertaken in our laboratory.

Keywords: Quaternary ammonium polyelectrolytes, reduced viscosity, crystal violet.

ICB Tracks GENETICALLY MODIFIED FOOD ADARSH PANDEY Department of Botany, SS (P.G.) college, Shahjahanpur, UP, INDIA Adarshspn73@gmail.com With the increasing pressure of population of india, the prime need of our nation is to improve the vegetables.

As most of the population of INDIA is vegetarian, the consumption of vegetables is enormous here. Of all the vegetables consumed in this country , Brinjal or Eggplant or Aubergine constitute the bulk of it due to its cheaper rate and easy availability. Brinjal is the king of vegetables which comes with its own crown. The eggplant, aubergine, or Brinjal (Solanum melongena), is a plant of the family Solanaceae . It bears a fruit of the same name, commonly used as a vegetable in cooking. It is closely related to the tomato and potato and is native to Bangladesh, Sri Lanka and India. Bt brinjal is a transgenic Brinjal created by inserting a gene cry1Ac from soil bacterium Bacillus thuringiensis into brinjal. Bt brinjal is marketed in India by MaHyCo (Maharashtra Hybrid Seed Company), and Monsanto, a US-based agricultural company. Six varieties of Brinjal were evaluated in at Kolhapur and Gadhinglaj in Maharashtra and at Kallolli Karnataka and at Brahmavar in coastal Karnataka. To be active against LEPIDOPTERANS insects (brinjal fruit and shoot borer) the protein must be ingested. In the insect gut, the protein binds to specific receptors on the insect midgut, inserts into the membrane and forms ion-specific-pores.These events disrupt the digestive processes and cause death of the insect. The Cry1AC protein produced in Bt brinjal is non-toxic to non-lepidopteran insects. In 2003, nearly 2,500 sheep died after grazing in Bt cotton fields. In a study, rats fed with GM tomatoes developed bleeding stomachs. Of the 20 rats, 7 developed stomach lesions; another 7 of 40 died within two weeks. Again, rats fed with Monsanto's GM maize exhibited 'significant changes in their blood cells, livers and kidneys. Matti is a village in the Udupi district of Karnataka state in India, famous for a particular variety of Brinjal ,"Mattu Gulla", which is known for its non-septic nature and special flavour. But the insertion of gene from Bt would remove the flavor of matti gulla and its medicinal properties.

Key words: Bt Brinjal, Eggplant, Aubergine, Bioterrorism, Bacillus thuringiensis.

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India EFFECT OF WATER STRESS ON INSECT INFESTATION IN SUGARCANE Keshav Shukla Department of Zoology SS (PG) College Shahajahanpur, UP India keshavupcsr@rediffmail.com Studies on relationship of shoot borer infestation in sugarcane varieties growing under soil moisture stress (20.80-25.00% ASM) and in respective normal soil moisture (52.00-58.00% ASM) was carried out. The results revealed that the shoot borer infestation in sugarcane varieties under soil moisture stress was severely higher while the sugarcane varieties grown in respective normal soil moisture pots did not show shoot borer infestation. The rate of shoot borer infestation varied from 8-20% in open condition and 14.28-45.45% in mosquito net covered pots respectively. In covered pots the pupae of shoot borer was released, thereby the covered pots showed more infestation than the respective normal pots where no pupae was released. It has been observed on the basis of overall mean, free amino acid and protein contents decreased from 0.13 in open pots and 0.27 in covered pots after insect infestation. The protein content decreased 25.22 in open condition and 53.25 in covered conditions after insect infestation. Concomitantly there was no decrease of these molecules in sugarcane varieties which were growing in normal soil moisture condition having no infestation of shoot borers. The rate of decrease of these constituents showed relationship with the rate of infestation, being more decrease where more infestation of shoot borer was observed. On the basis of observations, it has been reviewed that the shoot borer infestation might have relationship with the soil moisture stress and specific type of protein and amino acids in sugarcane varieties.

Key Words: Sugarcane varieties, total soluble protein, free amino acids, shoot borer, soil nutrients.

ROLE OF AZOSPIRILLIUM IN OKRA LEAVES 1 2 Mumtaz Husain and Adarsh Pandey 1,2 Department of Botany, SS (P.G.) College Shahjahanpur, U.P. (India) Email: husainmumtaz786786@gmail.com A simple randomized pot experiment was conducted at G. F. College, Shahjahanpur during January to March2011. Efficacy of various doses of nitrogen in combination with Azospirillium was studied on the nitrogen content of okra leaves. Two controls were set, one without nitrogen and Azospirillium and another without nitrogen with Azospirillium to compare the effect of Azospirillium alone and in combination with various nitrogen doses. The nitrogen was estimated in dry leaves at 15, 30 and 45 days after germination. All the treatments of nitrogen and Azospirillium seed inoculation gave significantly higher nitrogen contents in the leaves of okra. The maximum nitrogen content was reported in okra leaves receiving N22.5 + Azospirillium.

The minimum nitrogen content was reported in control (N0+B0) where no nitrogen and Azospirillium was applied. Therefore, it can be recommended that use of lower doses of nitrogen and Azospirillium seed inoculation improved the nitrogen content of leaves in okra plants which will enhanced the final yield of the crop. On the other hand, a large amount of nitrogen fertilizer is also saved thereby, decreasing the cost of production of crop.

Key words : Azospirillium, Nitrogen, Okra.

STUDY ON THE POLLUTION STATUS OF RIVER RAMGANGA IN BAREILLY UP INDIA Ramesh Chandra Department of Zoology, S.S.(P.G.) College, Shahjahanpur, (U.P.)India rameshraj379@gmail.com River Ramganga is a major source of water to the rural population of western Uttar Pradesh, India. The main goal of the present study was to assess the impact of urban and industrial activities on the water quality of river Ramganga at the Bareilly. For this, river water samples were collected from five different sites all along the route of Ramganga main streamline and were analyzed for chemical oxygen (COD) demand and biochemical oxygen demand (BOD) levels. There were variations for BOD (2.75–6.84 mg l − 1) and COD (23.90-43.60 mg l − 1) levels at different sites. The BOD values noticed were almost within the permissible limits of USPH and WHO (5mg/L and 6mg/L) at most of the sampling sites. The COD values in the present study remained higher than the COD values published for most of other Indian rivers by CPCB (1991). The values generally exceeded the tolerance limit of -5mg/L, prescribed by USPH and WHO. This is the study on itself and the interrelationship of human activities and river water quality makes the study significant and

16

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India interesting to assess the pollution load discharges in catchments of Ramganga at Bareilly. Overall, the water quality of Ramganga was relatively poor with respect to its use for domestic purposes.

PHYTOEXTRACTION OF LEAD FROM TWO VARIETIES OF MARIGOLD 1 2 Shikha Saxena and Adarsh Pandey 1,2 Department of Botany, SS (PG) College Shahjahanpur 242001 UP India Corresponding Author: drjauhari26@gmail.com Phytoextraction involves specific plant species which can absorb and hyperaccumulate metal contaminants and/or excess nutrients in harvestable root and shoot tissue,from the growth substrate(soil).The objective of present investigation is to examine the accumulation potential of lead in marigold.The experiment was carried out with two varieties of marigold i.e. Pusa narangi and Ritu raj.The seeds of marigold of two varieties were presoaked in distilled water and were sown in the field without any treatment as control.After 20 days,the plantlets of marigold of both varieties were transplanted into the pots,supplied with different doses of Pb (50,100 and 200 mg/kg of soil) at 10,15,25 and 30 days.The growth parameters were recorded at 25 and 45 days. The result of the present investigation clearly indicate that different concentration of Pb(50,100 and 200 mg/kg of soil) did not adversely affect the growth parameters of marigold in both varieties in terms of plant height, fresh and dry weight, chlorophyll,Carotenoid, carbohydrate, nitrogen and protein contents but some insignificant reduction were noticed in these parameters as compared to control, proline content insignificantly increased under the influence of different concentration of Pb at 25 days.At 45 days too,a insignificant reduction was noticed in these parameters and also the proline content was insignificantly increased as compared to 25 days old plants.The accumulation of Pb was found to be more in shoot than in the root.We have noticed that among both the varieties,Pusa narangi was found to be more resistant to metal toxicity and the accumulation potential of Pb was found to be more than in variety Ritu raj.So the marigold can be considered as a potential economic crop for phytoremediation of Pb contaminated sites.

Keywords: Marigold; Phytoextraction; Lead; Accumulation.

THE DUSKY SIDE OF SYNTHETIC FOOD DYES Dr. Madhumita Bhattacharjee, Assistant Professor, Post Graduate Govt. College For Girls,Sector -11, Chandigarh madhumita3680@gmail.com, Now -a -days increasing use of synthetic food dye is the consequence of industrialization and the development of food processing technology. All synthetic food dyes are chemicals.The indiscriminate use of synthetic food dyes pose a serious health hazards in human beings. Children are more prone to chemicals found in food dyes than the adults as they are attracted more towards the coloured food items. Numerous studies have demonstrated the dangers of artificial dyes in food, which include the possibility of onset of attention deficit disorder (ADD),inhibition of the immune system, hyperactivity and allergic reactions. Many studies also showed the carcinogenic, neurotoxic and genotoxic nature of synthetic food dyes .Long term use of synthetic food dyes also induce many chromosomal aberrations. In addition, the use of non-permitted colours or overindulgence of permitted colours may also cause thyroid tumours, dermatitis, asthma, nasal congestion, abdominal pain, nausea, eczema, liver and kidney damage and cancer. So the continuous monitoring of use of permitted colours in food products especially by the food processors, manufacturers, street vendors, must be carried out by the regulatory authorities. The developing countries like India need to frame proper legislation for the use of food dyes to protect our health especially our children.

CONSEQUENCES OF PLANT GROWTH PROMOTING FUNGI AND PLANT HEALTH PROMOTING BACTERIA ON THE GROWTH, ENZYME ACTIVITIES AND ROOT-ROT OF CHICKPEA Mohd. Sayeed Akhtar, Akil Ahmad Khan Department of Botany, Gandhi Faiz-E-Aam College, Shahjahanpur, U.P., India Email(s): sayeedbot@gmail.com , akil_nbri@yahoo.com The effect of plant growth promoting fungi (Aspergillus awamori, Aspergillus niger, and Pochonia chlamydosporia) and plant health promoting bacteria (Panibacillus polymyxa and B. pumilus) were studied alone and in combination under pot conditions on the growth, and enzyme activities (catalase and peroxidase) and on the root-rot of chickpea caused by Macrophomina phaseolina. Application of plant growth promoting fungi and plant health promoting bacteria caused a significant increase in growth and enzyme activities of both 17

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India root-rot fungus inoculated and uninoculated chickpea plants. Use of P. polymyxa was more efficient in reducing disease severity and improving the growth of root-rot fungus inoculated plants than A. niger and P. chlamydosporia. The greatest increase in growth, and enzyme activities (catalase and peroxidase) of root-rot fungus inoculated plants and reduction in disease severity was achieved when A. awamori or B. pumilus was used with P. polymyxa compared to other investigated combinations.

Keywords: Aspergillus, Bacillus, catalase; Macrophomina paseolina; peroxidase EFFICIENCY OF VITAMIN-B1 (THIAMINE HYDROCHLORIDE) IN IMPROVING GROWTH AND YIELD OF MUSTARD (BRASSICA JUNCEA L.) Azahar Sajjad Department of Botany, Gandhi Faiz-E-Aam College, Shahjahanpur, U.P., India Email: azharsajjad@rediffmail.com An experiment was conducted to evaluate the effects of foliar spray (0.01, 0.02 and 0.03 wt-%) of thiamine hydrochloride (vitamin-B1) on growth and yield characteristics of mustard (Brassica juncea L.) cultivar Varuna under field condition. The spraying was done only at 40 days after sowing (DAS) which coincide to the flower initiation stage. The growth parameters studied include plant fresh weight, plant dry weight, leaf area (LA), leaf area index (LAI), crop growth rate (CGR), relative growth rate (RGR), net assimilation rate (NAR) at different growth stages. Yield as well as its components such as number of pods per plant, 1000 seed weight, yield, biological yield, harvest index, oil content and oil yield were measured at harvest. In general, 0.03 wt-% of thiamine hydrochloride solution was more effective compared to other tested concentration for most of the parameters studied. Growth parameters like plant fresh weight, plant dry weight, CGR, RGR and NAR showed significant results at the early stages of sampling (i.e. 60-80 DAS). There was no significant difference between the different treatments of thiamine hydrochloride in case of LA and LAI. Different yield parameters like the pod number per plant, biological yield and seed yield as well as oil yield registered significant results.

The results suggest that the performance of B. juncea can be improved by spraying the plants with aqueous thiamine hydrochloride solution. Thus, it was concluded that the spray of thiamine hydrochloride solution ensured better growth and yield.

Keywords: Brassica juncea, Vitamin B1, Foliar Spray, Growth and Yield EFFECTS OF METAL ABSORPTION IN HUMAN BODY Dr. Shabana Sajid (DEPTT. OF CHEMISTRY), G F P.G COLLEGE SHAHJEHANPUR, U.P E-mail:drshabanaathar@rediffmail.com Are you tired? Are you suffering from depression or Anaemia? These are just a few signs that you may be suffering from metal poisoning-a toxic accumulation of metals in the tissues of the body. Zinc, Copper and iron etc. these transition metals generally present in our environment. When these metals enter in human body they seriously attack on kidney, lungs and brain. Zinc is an essential nutrient particularly for growing children and those who experience frequent infections. Many children in developing countries have insufficient Zinc nutrition that impairs their immune system and causes Diarrhoea and Pneumonia. Copper found in many kinds of food, drinking water and air. It is the trace element which is necessary for human health. Too much Copper can cause eminent health problems. People that live in houses still have Copper plumbing, due to this plumbing copper released into their drinking water through corrosion of pipes. In working environment Copper contagion can cause flu called â&#x20AC;&#x153;METAL FEVERâ&#x20AC;?, long term copper exposure can raise irritation, body aches, liver and kidney damage and even death. Anaemia is the primary consequence of Iron deficiency. Excess Iron level can enlarges the liver, may provoke diabetes and cardiac failure. This paper reviews certain transition metals and their absorption effects in human body.

MORINGA OLEIFERA: A RICH SOURCE OF NATURAL ANTIOXIDANTS Nidhi Srivastava Department of Chemistry, P.P.N. College, Kanpur nidhi.srivastava2006@gmail.com, Antioxidant play an important role in inhibiting and scavenging free radicals, thus providing protection to human against certain disastrous diseases and strengthen the immune system of our body. Current research is now directed towards natural antioxidant originated from plant rather than investing in synthetic ones. Two 18

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India flavonoid 3,5,7,2ˊ,4ˊpentahydroxyflavone 1 and 3,5,7,3ˊ,4ˊ,5ˊ hexahydroxyflavone 2 have been isolated from the seeds of Moringa oleifera have potent antioxidant activity. The structures have been established on the basis of chemical evidences and spectroscopic methods.

Key word: Antioxidant, scavenging free radicals, flavones, spectroscopic methods.

BIOSENSORS: RECENT ADVANCES Dr. Renu Goel Assistant Professor, Department of Zoology, P.P.N. College, Kanpur E-mail:goelrenu63@gmail.com Biosensors represent biophysical devices which will detect the presence and measure the quantities of specific substances in a variety of environments. These specific substances may include sugars, proteins, or hormones in human body, pollutants in abiotic components of the environment including air, soil and water and a variety of toxins in the industrial effluents. In designing a biosensor an enzyme or an antibody or even microbial cells are associated with microchip devices which are used for quantitative estimation of a substance. The first reported application of biosensor dates back to 1860 when start content was estimated with the help of malt extract. Biosensor today is an analytical tool which consists of biological material in intimate contact with a transducer. This review discusses recent advances in biosensors technology which draw on the disciplines of physics, chemistry, biochemistry and electronics.

A NEW RECORD OF NAUCORIDAE SPECIES (HEMPTERA: HETEROPTERA) FROM UTTAR PRADESH Mohammad Shoeb, Jameel Ahmad Department of Zoology, Gandhi Faiz-E-Aam College, Shahjahanpur 242001, U.P., India Email: soabkhan92@gmail.com Naucoridae is the most studied fauna of water bugs throughout the world. The aim of the present study was to find out the diversity among the Naucoridae fauna. To achieve the objectives, a survey of various rivers, ponds, ditches and water reservoirs form different parts of Uttar Pradesh were conducted during season 20122013. The collected materials were examined under the compound and stereoscope microscope. The various taxonomic parameters were assessed for the sample collected and the sketches were made with the help of Camera lucida. On comparing the result using the taxonomic key, the present study showed a new record of Naucoridae species. This study is of great concern because of its ability in destroying the eggs and juveniles of mosquitoes. Thus, it could be a probable a potent candidate species for the control mosquito larvae in the future.

Keywords: Waterbug, Chirochel, mosquito larvae BOTANICALS: THE GREEN PESTICIDES Rajendra Singh, Amrita Singh and Mamta Singh Plant Nematology Research Lab., Department of Zoology, Bareilly College Campus MJP Rohilkhand University, Bareilly-243001, UP Email. singh.rajendra007@gmail.com Discovery of insecticidal properties of DDT in 1939 led the foundation of green revolution to enhance the agricultural production but the indiscriminate use of pesticides has generated problems, like pest resistance, resurgence of pests, eco toxicity and elimination of natural enemies. These glitches attract the attention of scientific world to develop an ecofriendly and human safe alternative method of pest control. In this regard use of phytochemicals (botanicals), biopesticides and biocontrol agents (natural enemies) offer a good alternative to manage the different pests and diseases in an ecofriendly manner. Over the last four decades there many useful phytochemicals have been identified and isolated with specific and general application to pest control.

Of the known about 4,00,000 plant species only about 3,000 plant species have been screened to possess pesticidal potential. Till now more than 500 pesticidal compounds have been identified from various plant species and few have achieved the commercial status worldwide. Present day biopesticide market in the world includes pyrethrins, rotenone, nicotine, ryanodine, sabadilla and azadirachtins. During last few years‟ plant essential oils comprising mono and sesquiterpenoids are being developed as green pesticides. Some of these oils are well known insect toxins, repellents and deterrents. Currently, ecofriendly pest management strategies are being popular worldwide to enhance crop production while maintaining and contributing to agriculture

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India sustainability. In context the relevance of ongoing researches on botanicals and their applications, here we have compiled the national and international bibliography for scholars of bioactive compounds.

Keywords: Botanicals, Biocontrol, Biopesticides, IPM, Phytochemicals EVALUATION OF ARTIFICIAL DIET FOR MULTIPLICATION OF LADYBIRD BEETLE COCCINELLA SEPTEMPUNCTATA (COLEOPTERA: COCCINELLIDAE) IN THE LABORATORY ARSHAD ALI and A.A. Rehman Department of Zoology, G.F. College, Shahjahanpur Email: drarshadali@yahoo.com About thirty artificial diets have been evaluated for feeding of ladybird beetle Coccinella septempunctata but no successful result was obtained for their development. The diets were prepared by using chemicals i.e. agar agar, ascorbic acid, casein, chloramphenicol, dried yeast powder, formaldehyde, fructose, glucose, nutipet, proteinex, riboflavin, sorbitol, sugar, vitamin b complex, vitamin E mixed in different combinations in the distilled water. In addition, aphid-mixed-diet (AMD) was prepared by adding paste of aphids (Lipaphis erysimi, Myzus persicae, Aphis craccivora) in the aforesaid artificial diets. The observations revealed that C. septempunctata showed successful development and highest fecundity was recorded on AMD-2 and AMD-3.

However, highest survival and better reproduction was obtained on control (L. erysimi). Moreover, the cost effectiveness of the successful diets was recorded cheaper with rupees 4.17/gm and 5.36/gm, respectively.

Key words: cost effective, development, ladybird beetle, reproduction, survival EFFECT OF GAMMA RADIATION ON TESTICULAR PROTEIN OF SWISS ALBINO MICE Arib Anjum Rehman Department of Zoology, G.F. College, Shahjahanpur Email: rehmanarib@gmail.com Testis is considered as one of the most radiosensitive organ of the mammals. The amount of total protein in the testes of irradiated mice displayed decremental trend vis-a-vis control. Total protein of control was obtained 162.33 mg/ml. While in case of irradiated groups the corresponding values for 0.05Gy was 134.83 mg/ml, it is 16.77 % less than the control; for 0.1Gy it was 150.93 mg/ml; and for 0.15Gy, 0.2Gy and 0.25Gy the corresponding values were 142.13 mg/ml, 149.93 mg/ml and 149.23 mg/ml, which shows 6.83%; 12.27%; 7.45% and 7.88% lower than the control, respectively. Fluctuating but decremental trend was observed in the total testicular protein. This may be due to random collision of gamma radiation on polypeptide chain of protein molecule causing fragmentation of definitive point i.e., “Fragile sites”. This process of collision and fragmentation is based on the theory of probability. The fragments thus produced may be small or large and consequently may escape detection by standard biochemical techniques as used in the present studies. The study of gamma radiation thus absorbed may also causes denaturation or coagulation of protein.

Key words: Ionized radiation, mammalian testis, protein EFFECT OF TEMPERATURE ON THE DEVELOPMENT OF SILK WORM, BOMBYX MORI L. (LEPIDOPTERA: BOMBYCIDAE) ON MORUS SPECIES Jamil Ahmad and Nidhi Tripathi Department of Zoology, G.F. (P.G.) College, Shahjahanpur, Uttar Pradesh, India E-mail: jamilahmadgfc@gmail.com Four different temperatures viz., 20±1°C, 24±1°C, 28±1°C and 32±1°C maintained in BOD incubators to observed development of B. mori. The different life stages including egg incubation, larval (Ist, IInd, IIIrd, IVth and Vth) instars, prepupal and cocoon period was recorded significantly (F3, 19 = 0.16, 0.22, 0.13, 0.16, 0.20, 0.20, 0.19 and 0.20; p < 0.01) shortest at 32±1°C. However, the observations recorded on male and female showed a variable pattern of development and recorded significantly (F3, 19 = 0.18 and 0.14; p < 0.01) longest period at 24±1°C. On the other hand, the findings on weight of last larval instar and cocoon was recorded significantly (F3, 19 = 0.034 & 0.020; p < 0.01) maximum at 24±1°C. Whereas, weight of cocoon shell was observed significantly (F3, 19 = 0.020 & 0.10; p < 0.01) minimum at 24±1°C compared to 20±1°C, 28±1°C and 32±1°C. In conclusion, silk worm, Bombyx mori attained shortest development at 32±1°C but better performance of adult and maximum yield of was obtained on 24±1°C, therefore, among all the temperature, 24±1°C considered to be most suitable for its development.

Key words: Biology, mulberry, sericulture, weight 20

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India

ISOLATION AND CHARACTERIZATION OF FUNGAL DISEASES OF MULBERRY (MORUS ALBA) IN UTTAR PRADESH Rajesh Kumar and Jamil Ahmad Department of Zoology,Gandhi Faiz-e-Aam (P.G.) College Shahjahanpur (Uttar Pradesh) India Email:rajeshseri@yahoo.in, dr.rajesh10@yahoo.com Mulberry (Morus alba) plant leaf is only natural food of silkworm (Bomyx mori L.), which is affected by number of vectors i.e., fungi, bacteria, viruses and nematodes. The fungal infection severely damage the plant leaves causes leaf rust, leaf spot, powdery mildew and leaf blight. The aim of present study to investigate the fungal infection in mulberry leaves at different districts of Uttar Pradesh. The findings revealed that maximum leaf affected by powdery mildew (Phyllactinia corylea) and leaf spot (Cercospora moricola) i.e., 20.00 and 16.50 %, respectively. The infection of fungal disease in mulberry was observed maximum during rainy as well as winter season in different places of Uttar Pradesh. Such abnormalities severely affected the life cycle of silkworm, consequently, the production and quality of silk.

Key Words: Leaf spot, leaf rust, powdery mildew, silk CADMIUM TOXICITY CAUSES DEPLETION OF LIVER GLYCOGEN RESERVE IN ALBINO RATS KSHAMA DWIVEDI AND D. K. GUPTA DEPARTMENT OF ZOLOOGY, BAREILLY COLLEGE, BAREILLY-243005 Email: kshamadwivedi74@gmail.com Cadmium is an important environmental pollutant, present as a non-essential element in food, water as well as in polluted air. Because of its non-corrosive properties, its main use is in electroplating or galvanizing. It is also used as colour pigments for paints and plastics and as cathode material for nickel -cadmium batteries. About 50 â&#x20AC;&#x201C; 75 percent of the body burden of cadmium is in the liver and kidneys. Exposure to high concentration of cadmium causes a debilitating and often fatal illness that affects most organ system. Chronic exposure appears to cause cancer, renal and liver toxicity. It also affects calcium metabolism and individual with severe neuropathy. In present study albino rats were divided into three groups A, B and C and were exposed to different doses of cadmium chloride. Group A control, Group B with low dose of 2.6 mg/ kg.b.wt. and Group C with high dose of 5.2 mg/ kg.b.wt. These albino rats were exposed to two test concentration for varying exposure periods of 15, 30 and 60 days. At the end of three treatment periods animals were sacrificed and liver tissue was collected for glycogen estimation.

After exposure of 15 days, animals of group B and group C shows sharp decline of liver glycogen (9.11%)and (12.67%) respectively. On 30 days exposure fall of liver glycogen reserve become more significant i.e.

(20.56%) and (26.52%) in group B and C respectively. On exposure to 60 days maximum fall of liver glycogen was observed i.e. (34.68%) in group B and (39.48%) in group C respectively. Animals of both the Groups B and C showed marked depletion of glycogen content in liver. The high dose of cadmium concentration has showed more adverse effect. The effect of cadmium in albino rats was found to be dependent on the period of exposure and concentration of metal.

Key Words: Cadmium, Glycogen, Liver.

EFFECT OF LEAD CONTAMINATION ON DEVELOPMENT OF TEETH IN CHILDREN # *Dr. Ashish Kumar Singh and Dr. Abhishek Singh *Assistant Professor, Department of Chemistry, V.S.S.D. College, Kanpur, U.P. #Anand Multi Speciality Dental Clinic, Swaroop Nagar Kanpur, www.ananddentalclinc.in Email- ashish4808@yahoo.com, singhabhi_49@yahoo.co.in The sources and intensity of lead exposure in utero and in early childhood were determined using stable lead isotopic ratios and lead concentrations of incisal and cervical sections of deciduous teeth from 30 exposed and non exposed children. Incisal sections, consisting mostly of enamel, generally have low amounts of lead and isotopic compositions consistent with those expected in the mother during pregnancy. Cervical sections, consisting mostly of dentine with secondary dentine removed by resorption and reaming, generally have higher amounts of lead than the enamel and isotopic compositions consistent with the source of postnatal exposure. There are significant differences in lead concentrations between incisal and cervical sections, representing within-tooth variation, for children with low and high lead exposure. The dentine results reflect an increased exposure to lead from the lead-zinc-silver mineral deposit (ore-body lead) during early childhood, 21

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India probably associated with hand-to-mouth activity. Leaded paint was identified as the source of elevated tooth lead in at least two cases. Increased exposure to lead from ore-body and paint sources in utero was implicated in two cases, but there was no indication of previous exposure from the mothers' current blood reports, suggesting an acute rather than a chronic exposure for the mothers. Permanent teeth from one subject had lower amounts of lead in the roots compared with the crowns, and the isotopic compositions of the crowns were consistent with the data for the deciduous teeth from the same subject. Based on changes in the isotopic composition of enamel and dentine, it is provisionally estimated that lead is added to dentine at a rate of approximately 2-3% per year.

A REVIEW STUDY OF BENEFITS OF OCIMUM TENUIFLORUM (TULASI) Dr.Vikas Kurana, Asst.Professsor, S.S.College Shahjahanpur drvikaskhurana2015@gmail.com Ocimum tenuiflorum, also known as Ocimum sanctum, holy basil, or tulasi (also spelled thulasi), is an aromatic plant in the family Lamiaceae which is native to the Indian Subcontinent and widespread as a cultivated plant throughout the Southeast Southeast Asian tropics. It is an erect, many branched subshrub, 30–60 cm (12–24 in) tall with hairy stems and simple phyllotaxic green or purple leaves that are strongly scented.

Leaves have petioles and are ovate, up to 5 cm (2.0 in) long, usually slightly toothed. The flowers are purplish in elongate racems in close whorls. The two main morphotypes cultivated in India and Nepal are green-leaved (Sri or Lakshmi tulasi) and purple-leaved (Krishna tulasi).

Tulasi is cultivated for religious and medicinal purposes, and for its essential oil. It is widely known across the Indian subcontinent as a medicinal plant and an herbal tea commonly used in Ayurveda, and has an important role within the Vaishnava tradition of Hinduism, in which devotees perform worship involving holy basil plants or leaves. This plant is revered as an elixir of life. Tulsi is an aromatic shrub in the basil family Lamiaceae (tribe ocimeae) that is thought to have originated in north central India and now grows native throughout the eastern world tropi.In Ayurveda, tulsi is known as “The Incomparable One,” “Mother Medicine of Nature” and “The Queen of Herbs,” and is revered as an “elixir of life” that is without equal for both its medicinal and spiritual properties.

DISTRIBUTION AND MOLECULAR IDENTIFICATION OF PHYTOPLASMA DISEASES IN ORNAMENTALS Akil Ahmad Khan, Shoeb Ahmad, Mohd Sayeed Akhtar Department of Botany, Gandhi Faiz-E-Aam College, Shahjahanpur 242001, Uttar Pradesh, India E-mail: akil_nbri@yahoo.com Phytoplasma is the serious constraints for the most of the economically ornamental plants, worldwide. It may reduce the quality and yield of ornamental plants because of its unspecific symptoms viz., flower malformation, growth abnormalities, yellowing or decline of leaves, elongation and etiolation of internodes, witches broom, stunting, little leaf, and virescence. The aim of the present study is to identify and characterize the various types of phytoplasmas using phytoplasma universal primers pair P1/P7 in a polymerase chain reaction followed by primers pair R16F2n/R16R2 in the nested-PCR to amplify the 16S RNA gene fragments. The DNA samples were used to extend the RP and Tuf gene fragments by PCR using aster yellows group specific primer pairs RP(l)F1A/RP(l)R1A and fTufAy/rTufAy, respectively. Moreover, Restriction fragment length polymorphism (RFLP) analysis of RP gene fragments using digestion with Alul, Msel, and Tsp5091 restriction enzymes were also tested for aster yellows group.

Keywords: Candidatus, PCR, RFLP, Transmission, Yellows disease EFFECT OF FERTILIZER FACTORY EFFLUENT ON SEED GERMINATION AND EARLY SEEDLING GROWTH OF BROAD BEAN (Vicia faba,.L) CV T-41.

Manoj Kumar Srivastava and Aquil Ahmad PG Department of Botany, G.F College, Shahjahanpur rajeev.arora999@gmail.com A factorial randomized experiment was performed in petri plates to study the effect of fertilizer factory effluent on seed germination and early seedling growth of broad bean (vicia faba) CV T-41, which was procured from IARI New Delhi and local. The percent seed germination and seadling growth in term of shoot and root length and their fresh and dry weights were studied under the influence of various concentrations(1% , 2%, 5%, 22

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India 10%,25%, 50% and pure i.e 100% ) Fertilizer Factory Effluents(FFE) .Tthe percent seed germination did not show any adverse effect under low FFE concentrations i.e 1% , 2%, 5%, 10%, and 25%,. However in higher effluent concentrations of 50% and pure (100%) reduced the seedling germination by 60% and 45% respectively as compared to 92% in control(distilled water) Dilution of effluents @ 1% , 2%, 5% and 10%, did not show any significant effect on seedling growth. On the other hand , 25% dilution of effluent improved the seedling growth by 72%, 6% , 8% , 7%, 10% and 14% in term of shoot length , root length , shoot fresh weight, root fresh weight, shoot dry weight and root dry weights of seedling respectively . Highier effluent concentration of 50% and pure reduced the seedling growth in term of all the parameters noted. As far varietal difference is concerned, seed germination percentage percentage was found maximum in T-41 followed by local variety.

ICE Tracks STUDY OF RADON, THORON, ATTACHED/UNATTACHED PROGENY, UNATTACHED FRACTIONS, EQUILIBRIUM FACTORS AND THE RADIATION DOSES IN THE INDOOR ENVIRONMENT OF GARHWAL HIMALAYA 1 1 1 1 2 Mukesh Prasad , Anik Rudra , Tushar Kandari , Preeti Pant , Peter Bossew , Rosaline 3 1 Mishra and R.C. Ramola 1 Department of Physics, H.N.B. Garhwal University, Badshahi Thaul Campus, Tehri Garhwal,India 3 Radiological Physics and Advisory Division, Bhabha Atomic Research Centre Mumbai - 400 085, India 2 German Federal Office for Radiation Protection, Berlin, Germany Presenting author: bijalwanmukesh111@gmail.com The annual exposure to indoor radon, thoron and their progeny imparts a major contribution to inhalation dose received by the public. In this study, we report the time integrated passive measurements of indoor radon, thoron and their attached and unattached progeny concentrations that were carried out in Garhwal Himalaya with the aim of investigating whether the exposure to these nuclei involves significant health risk to the dwellers of the investigated region. The experimentally determined values of radon, thoron and their progeny concentrations were used to estimate the total annual inhalation dose, annual effective doses and equilibrium factors. The attached and unattached progeny fractions are found positively correlated, although only weakly, with Pearson correlations R² = 0.28 and 0.31, for radon and thoron, respectively (significant with p < 0.01 in both cases). The estimated values of equilibrium factors for radon and its progeny and for thoron and its progeny were found to be 0.42 and 0.07, respectively. The estimated value of total annual inhalation dose due to the exposure of radon, thoron and progeny was found to vary from 0.8 mSv/y to 4.6 mSv/y with an average of 1.8 ± 0.7 mSv/y. The estimated values of annual effective doses from the exposure to radon and its progeny and from the exposure to thoron and its progeny were found to vary from 0.5 mSv/h to 3.1 mSv/h with an average of 1.2 ± 0.5 mSv/y and from 0.2 mSv/h to 1.3 mSv/h with an average of 0.5 ± 0.3 mSv/y, respectively.

The estimated values of radiation doses have shown no significant health.

MEASUREMENTS AND ANALYSIS OF SEASONAL VARIATION OF RADIOACTIVE GASES IN THE ENVIRONMENT OF RAMPUR AND NEARBY TOWN (U.P.) BY USING SOLID STATE NUCLEAR TRACK DETECTOR (SSNTD) TECHNIQUE M. S. A. Khan Department of Physics, Gandhi Faiz-a-Aam College, Shahjahanpur, (U.P.), India E-mail: Salim_labphysics@rediffmail.com In the present study twin cup radon-thoron dosimeter based on LR-115 type-II plastic track detectors have been used for the measurement of radioactive gases i.e. radon and thoron in some selected dwellings of Rampur and nearby town of Uttar Pradesh. The measurement was repeated on a time integrated four quarterly cycles to cover all the four seasons (summer, rainy, autumn &winter) of the calendar year. During winter season the radon and progeny concentration was found to vary from 25 Bq/m3 to 85 Bq/m3 with an average of 44.92 Bq/m3 where as thoron and progeny concentration was found to vary from 17.66 Bq/m3 to 30 Bq/m3 with an average value of 21.35 Bq/m3 .During autumn season indoor radon and progeny concentration was found to vary from 15 Bq/m3 to 46 Bq/m3 with an average of 29.95 Bq/m3 where as thoron and progeny concentration was found to vary from 11.66 Bq/m3 to 24.5 Bq/m3 with an average value of 17.44 Bq/m3 .During summer season indoor radon and progeny concentration was found to vary from 9 Bq/m3 to 55 Bq/m3 with an average of 18.72 Bq/m3 where as thoron and progeny concentration was found to vary from 23

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India 7.33 Bq/m3 to 22.5Bq/m3 with an average value of 11.86Bq/m3 .During rainy season indoor radon and progeny concentration was found to vary from 11Bq/m3 to 40 Bq/m3 with an average of 24.41 Bq/m3 where as thoron and progeny concentration was found to vary from 10.50 Bq/m3 to 23Bq/m3 with an average value of 16.06 Bq/m3. The detail results will be presented in the paper.

A CRITICAL AND COMPARATIVE STUDY OF INDOOR AIR POLLUTION FROM HOUSEHOLD COOKING FUELS 1, 2 Basant Shubhankar* Balram Ambade 1,2 Department of Chemistry, National Institute of Technology, Jamshedpur, Jharkhand, India.

2013rsch001@nitjsr.ac.in This paper throws light on household cooking related exposures and level of indoor air pollutants (particulate matter and gaseous pollutants CO, CO2, SO2, NO, NO2) in different exposure area from the different types of cooking fuels used. Still the prevalence of biomass fuels exists in Indian households, combustion of which releases higher levels of solid and gaseous pollutants during the cooking hours. The indoor air pollutants (SPM, CO, CO2, SO2, NO, NO2) were measured with handy samplers with different types of cooking fuels (biomass,and LPG). For this purpose 50 randomly selected sampled of the indoor air quality were monitored.

The results suggests that average concentration of PM10 (394.07 μg/m3) and gaseous pollutants (CO-3.15 ppm, CO2- 492.63 ppm, SO2-0.56 ppm, NO-0.58 ppm, NO2-0.52 ppm) were highest during cooking hours with biofuels cooking places. Thus, not only the women who are involved in cooking suffer from the various ill effects, but also other family members who are inside the house during cooking hours also face exposures.

The recorded SPM (114.73 μg/m3 for PM10) and gaseous pollutants (CO-1.34 ppm, CO2-379.83 ppm, SO20.52 ppm, NO-0.54 ppm, NO2-0.52 ppm) in LPG using households were lower as compared to biomass fuel using households. Due to the LPG efficiency the time involved in cooking is also low leading to less exposure to the pollutants released.

Key words: PM10. SPM. Biomass. LPG. Gaseous pollutant. Household cooking fuel. Health.

“EVALUATION AND MODELLING OF GROUND WATER QUALITY DATA OF ALLAHABAD CITY BY ENVIRONMETRIC METHODS Girdhari Lal Chaurasia, Mahesh Kumar Gupta, Praveen Kumar Tandon# #Department of Chemistry, University of Allahabad, Allahabad, UP, India-211002 E-mail: girdhari.env@gmail.com In the present study water samples were analyzed for various physicochemical analyses by different methods following the standards of APHA, BIS and WHO and were subjected to further statistical analysis viz. the cluster analysis to understand the similarity and differences among the various sampling stations. Three clusters were found. Cluster 1 was marked with 3 sampling locations 1, 3 & 5; Cluster-2 was marked with sampling location-2 and cluster-3 was marked with sampling location-4. Principal component analysis/factor analysis is a pattern reorganization technique which is used to assess the correlation between the observations in terms of different factors which are not observable. Observations correlated either positively or negatively, are likely to be affected by the same factors while the observations which are not correlated are influenced by different factors. In our study three factors explained 99.827% of variances. F1 marked 51.619% of total variances, high positive strong loading with TSS, TS, Temp,TDS, phosphate and moderate with electrical conductivity with loading values of 0.986, 0.970, 0.792, 0.744, 0.695, 0.701, respectively. Factor 2 marked 27.236% of the total variance with moderate positive loading with total alkalinity & temp. With loading values 0.723 & 0.606 respectively. It also explained the moderate negative loading with conductivity, TDS, and chloride with loading values -0.698, -0.690, -0.582. Factor F 3 marked 20.972 % of the variances with positive loading with PH, chloride, and phosphate with strong loading of pH 0.872 and moderate positive loading with chloride and phosphate with loading values 0.721, and 0.569 respectively.

Keywords: Water, Physico-chemical, Environ-metric methods, Cluster Analysis, FA/PCA.

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India ESTIMATION OF INDOOR RADON AND THORON DECAY PRODUCTS CONCENTRATION IN DWELLINGS OF SHAHJAHANPUR AND NEARBY TOWNS,UTTAR PRADESH, INDIA, USING DEPOSITION BASED DIRECT PROGENY SENSOR (DPS) TECHNIQUE. a b a Anil Kumar, R B S Rawat & Brij Nandan Singh a Department of Physics, S S (P.G.) College, Shahjahanpur, Uttar Pradesh, India. b Department of Physics, M S (P.G.) College, Saharanpur, Uttar Pradesh, India. singhakphy586@gmail.com, Radon and thoron present in indoor environment is a potential source of radioactive dose, which is mostly contributed by inhalation of their decay products. Decay products of radon and thoron present in indoor environment are the most important sources of radiation from natural sources which affect human beings, since general public spend at least 80% of their time in indoor. Radon decays with a half-life of 3.825 days by alpha emission to a series of particulate progeny. The measurement of indoor radon and thoron decay products concentration in dwellings of Shahjahanpur and nearby towns have been carried out using deposition based direct progeny sensor (DPS) technique. In Present study the concentration of radon and thoron decay products were made to estimate the seasonal variations during different seasons of the year. In summer, the radon and thoron decay products concentrations have been found to vary from 7.35 Bq/m3 24.50 with an average of 12.65 Bq/m3 and 0.53 to 2.32 Bq/m3 with an average of 1.02 Bq/m3 respectively.

In rainy, the radon and thoron decay products concentrations have been found to vary 8.22 from to 20.35 Bq/m3 with an average of 13.69 Bq/m3 and 0.34 to 2.12 Bq/m3 with an average of 0.96 Bq/m3 respectively. In autumn, the radon and thoron decay products have been found to vary from 8.12 to 26.04 Bq/m3 with an average of 13.53 Bq/m3 and 0.61 to 1.7 Bq/m3 with an average of 1.07 Bq/m3 respectively. In winter, the radon and thoron decay products have been found to vary from 8.11 to 24.79 Bq/m3 with an average of 15.37 Bq/m3 and 0.13 to 2.02 Bq/m3 with an average of 0.89 Bq/m3 respectively. It has been observed that the average value of radon decay products concentration is maximum in winter and minimum in summer season, while thoron decay products concentration is maximum in autumn and minimum in summer. The results and their significance will be discussed in detail.

STUDY OF RADON AND THORON CONCENTRATION IN ENVIRONMENT OF MORADABAD DISTRICT OF UTTAR PRADESH, INDIA a b Indu Singh and Anil Kumar a Department of Physics, IFTM , University, Moradabad b Department of Physics, S S (P.G.) College, Shahjahanpur, Uttar Pradesh, India. singhakphy586@gmail.com, Measurement of indoor radon and thoron has been carried out in dwelling of Moradabad, Uttar Pradesh, India using LR-115 type II plastic track detectors. Radon is an invisible radioactive gas that occurs naturally in the indoor atmosphere. It comes from the naturally breakdown of uranium in soils and rocks.

Lung cancer risk depends upon the concentration of radon, thoron and their decay product in air above recommendation level. In the present study the value of radon concentration from10.5 Bq/m3to 30Bq/m3 with an average19.9 Bq/m3and thoron concentration from 5.6 Bq/m3 to 24 Bq/m3 with an average of 14.9 Bq/m3. It is observed that the concentration of radon is maximum in winter and minimum during summer. The maximum concentration in winter is essentially influenced by the intense temperature inversion, which generally occurs in winter season, when the wind velocity is low. The maximum concentration in winter is also the result of decreased ventilation because in this season the houses are closed for long time and radon accumulated inside the room. The variation in indoor radon and thoron concentration for different seasons will be discussed in the paper.

THE EFFECT OF GLOBAL WARMING ON ENVIRONMENT Dr. Hitendra Kumar Singh Assistant Professor, Department of Botany Govt. Raza Post Graduate College, Rampur, UP, India. drhksingh1@gmail.com, The planet is warming from North Pole to South Pole and everywhere in between. Signs are appearing all over and some of them are surprising. Global warming is far-reaching, long lasting and in many cases devastating consequences or planet earth. Global warming is caused due to human activity like burning of 25

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India fossil fuels that release carbon dioxide, methane and other green house gases into environment. Ice is melting worldwide especially at the Earthâ&#x20AC;&#x;s poles. This includes mountain glaciers, ice sheets covering West Antarctica and Greenland and Arctic sea ice. Sea level rise became faster over the last century. Alpine plants have moved faster to north or higher cooler areas. Storms are likely to become stronger. Floods and droughts have become more common. Many species of plants are moving their range to higher altitudes as a result of warming temperatures. Global warming affects the range of plans and animals, changing their behavior and causing disruptions up and down the food chain. Some warm weather species will expand, while cool weather species will face shrinking habitats. Spring arrives much earlier than it used to ten days earlier on average in the northern hemisphere. International Seminar on 12 Feb. 2016 organized by S.S. PG College Shahjahanpur.

Snow melts earlier. Vegetation and soils dry out earlier, setting the stage for longer and more damaging wildfire seasons. Global warming change affects people and environment in many ways. We can reduce global warming emissions and ensure communities have the resources they need to withstand the effects of climate change but not without us. We should try our best to reduce global warming effects than we can save earth, plant, humans etc.

Key Words: Environment, Global warming, Greenhouse effect.

ESTIMATION OF THE PARTICULATE MATTERS EMITTED FROM COAL POWER PLANTS IN ALLAHABAD DISTRICTS AND ITS EFFECT ON HUMAN HEALTH IN THIS AREA Anil Kumar Singh & Jay Prakash Patel Department of Physics, Ewing Christian College, Allahabad anilsingh012@rediffmail.com In this project, we will estimate the effect of particulate matter, sulfur dioxide (SO2), and nitrogen oxides (NOx) on human health and environment from individual coal-fired power plants in Allahabad. We will estimate health damages by combining data on power plant emissions of particulate matter, SO2 and NOx. In addition to the environmental and human health harm caused by greenhouse gas emissions, coal-fired power plants emit massive amounts of toxic air pollutants that result in significant numbers of deaths and disease.

Keywords: Particulate Matter (PM), health damages, coal-fired power plant, pollution control.

BIOMONITORING WITH MOSSES: AN EXTENSIVE STUDY OF METALS POLLUTION OF ATMOSPHERE a b Kajal Srivastava and Shivom Singh a Department of Biological Sciences, CBSH, GB Pant University of Agriculture and Technology, Pantnagar b Department of Environmental Science, ITM University, Gwalior Shivom101@rediffmail.com The environmental quality can be monitored by measuring pollutants, metals precipitation, using bio-indicators.

Biomonitoring of atmophile element by mosses is one of the most popular and cost effective method to control, detect and evaluate changes in the air quality. They represent a suitable approach for screening air quality at higher spatial resolution. The most important environmental features of mosses as a good tool of air pollution deposition reflection are: mosses do not have any roots, their surface is large, they grow in wide-spread population in groups, they have long life cycle, they survive in the high-polluted environment, they are able to obtain nutrients from wet and dry deposition and clearly reflect the atmospheric deposition.

The moss biomonitoring technique is usually used for the monitoring of airborne metals and polycyclic aromatic hydrocarbons (PAHs), but it can also be very helpful for biomagnetic analysis. So far, leaf magnetic properties, such as susceptibility and remanence, have been reported as valuable proxies for PM pollution. In addition, the abundance and large geographical distribution of mosses is advantageous and provides for an inexpensive and simple alternative to conventional bulk deposition analysis. Thus, a high density network of sampling sites is easily achieved. This allows for pollution distribution maps to be produced. This technique as a complementary method to standardized measurements by filling gaps in the regulatory monitoring network.

Moss biomonitoring surveys could be of great use as they provide a cost-effective and efficient means for a time-integrated assessment of the environmental situation and evaluation of anthropogenic changes.

Keywords: Bioindicator, biomonitoring, metals, mosses, pollution.

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India ENVIRONMENTAL IMPACT OF NUCLEAR POWER: LAW AND POLICY MEASURES IN INDIA Dr. Ajay Kumar Singh*, Nalnish Chandr Singh# ajay24bhu@gmail.com, Healthy and clean environment is a fundamental right in India, simultaneously in modern time energy requirements are increasing. It is required that dependency on traditional source of energy should be decreased because of environmental and other reasons. Nuclear energy undoubtedly a present day hope for the energy requirement due to rich and eco-friendly source of energy. But this source also contains some danger for human health and wellbeing. It is a basic question before every nation that what safety and regulatory measures should be adopted to secure the safe use of nuclear energy. This article is an attempt to analyse the impact radiations caused by nuclear accidents on human health and environment. It also analyse the international regulatory measures and national legal and policy measures, adopted to combat the nuclear disaster. The article enumerates the liability issue arise due to the enactment of new law in 2010, it analyse the controversy and provide concluding remarks on the issue.

Keywords: nuclear, environment, pollution, protection, judiciary.

EVALUATION OF WATER QUALITY OF GANGA RIVER AT ALLAHABAD: PHYSICO-CHEMICAL PROPERTIES AND CORRELATION CO-EFFICIENT a b b a b Neelam Shukla , Vandana Srivastava , B.K. Dwivedi , Mahesh Kumar Gupta , D. N. Shukla , P. K. a Tandon a b Department of Chemistry, Department of Botany, University of Allahabad, Allahabad-211002 email; neelamshukla82@yahoo.com Physico-chemical parameters of water samples of river Ganga at Allahabad district were analyzed to see the water quality of river. Water samples were collected from five sampling stations from Phaphamau Ghat to Chatnaag Ghat in the year 2014. Sixteen water quality parameters for all the sites were estimated by adopting the standard methods and procedures. The samples were analyzed for Physico-chemical attributes and Pearson‟s correlation (r values) was calculated to quantify relationships between various physico-chemical attributes of river Ganga at Allahabad. It is found that turbidity, COD and electrical conductivity were found to be positively correlated with temperature while pH and transparency was negatively correlated with temperature. DO was negatively correlated with temperature, turbidity, electrical conductivity, TS, TDS and TSS during the study of period and positively correlated with pH. BOD was positively correlated with temperature, electrical conductivity, turbidity, TS, TDS and TSS whereas negatively correlated with DO. Free CO2 was positively correlated with temperature. Calcium and Magnesium hardness were negatively correlated with pH and DO whereas positively correlated with electrical conductivity, BOD, COD, TS, TDS, and TSS. Nitrate and Phosphate showed almost no significant correlation with each other and with other parameters during the course of study.

Keywords: Physico-chemical parameters, correlation, water quality, hardness, turbidity.

EVALUATION OF PHARMACEUTICALS INDUSTRIAL EFFLUENT TOXICITY AND GENOTOXICITY EFFLUENT USING- ALLIUM CEPA MODEL Vineeta kumari*, A. K. Tripathi Forest Ecology & Environment Division, Forest Research Institute Dehradun Email: Vineeta.env@gmail.com Water is the fundamental resource for the living beings. Water is basic need for all types of the small and large scale industrial sectors. Pharmaceutical industries are among the major contributors to industrial waste. Their effluents when wrongly handled and disposed of endanger both human and environmental health. In this study, we investigated the potential cytotoxicity and genotoxicity effect of effluents released by two different pharmaceutical industries in Lucknow, India, by using the Allium cepa. A.cepa model was used to determine the mean root length,mitotic index and chromosomal aberrations effects of these plants on Onion bulbs using 6.25, 12.5 and 25% concentration of the pharmaceutical effluent at 6 or 24 h treatment. The A.cepa test showed significant results of cytotoxicity, mutagenic index and chromosome aberration in the area under the same influence. The concentration of some toxic metals and anions in the effluent were above standard permissible limits. There was a statistically different (p < 0.05), concentration-dependent inhibition of onion root growth and mitotic index, and induction of chromosomal aberrations in the onion. The pharmaceutical industrial effluents induced chromosomal aberrations in root tip cells of A. cepa with vagrant chromosome,

27

Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & 2016 Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India bridges, fragments, tripolar anaphase, and micronucleated cell observed. At lower concentrations sticky chromosome, bridges and fragments were the most common aberration.

KEYWORDS: Pharmaceutical, Industrial effluent, Alliums cepa, Mitotic index, chromosomal aberrations EFFECT OF CONCENTRATION OF WATER POLLUTANTS ON ADSORPTION Jyotsna Chaturvedi and N K Pandey DEPARTMENT OF CHEMISTRY, HARISHCHANDRA PG COLLEGE VARANASI-221001, U.P., INDIA jyotsna.1june@gmail.com A study on removal of water pollutants by adsorption method was carried out using water sample from ghats of river Ganga at Mirzapur district. The water samples having effluents of carpet industries were rich in heavy metals and dyes. For removal of heavy metals, wallastonite and china clay were used as adsorbents during the adsorption process. The results showed that under similar reaction conditions, the time required to attain equilibrium for adsorption of Cr(VI) and Ni(II) on wallastonite was more than the time required by china clay whereas the dyes (OCR and OCB) required more time for saturation state on china clay than on wallastonite.

Also, the saturation state was independent of adsorbate concentrations.

EFFICACY OF A NEWLY FORMULATED AREA SPECIFIC MINERAL MIXTURE ON PRODUCTION AND HAEMATOBIOCHEMICAL PARAMETERS OF CATTLE Chinmay Joshi Assistant Professor in Zoology H.N.B. Govt. P.G. College Khatima, Udham Singh Nagar, Uttarakhand Email: joshic28@yahoo.co.in A study was conducted in Uttarakhand state to observe the mineral status in soil, fodder and serum samples of the bovines. Significant deficiency of copper, zinc, iodine and phosphorus was observed in this hilly area.

Deficient cattle showed anemia, debility, and dullness. Symptoms of parakeratosis and pica were also observed in deficient animals. The biochemical profile viz. enzymes, hormones and vitamins also showed severe deficiency. Therapeutic trial was conducted on some cattle in local dairy farm for sixty day. It was observed that after the experimental study all the parameters returned towards normalcy. Significant improvement was observed in Thyroid hormone, Vitamin A and E level. The treated animals also showed a significant gain in milk yield and body weight gain. Approximately 37% increase in milk yield and 30% increase in body weight of calves and heifers was observed after supplementation of this newly formulated mineral mixture. From the overall analysis, it was envisaged that mineral supplements should be provided to the deficient animals for their better health and production.

Key Words: - Cattle, Mineral Deficiency, hormones, vitamin A&E, Haematobiochemical profile, Therapy, Production SYNTHESIS OF SOME NEW INDOLE DERIVATIVES WITH POSSIBLE LOCAL ANESTHETIC ACTIVITY Roopali Tandon, S C Mehra Chemistry Dept, Bareily College yashishucomm@gmail.com, Indole and their derivatives possess various pharmacological activities. Thus new indole derivatives have been synthesized as potential local anesthetic by treating indole with chloroacotyle chloride to get Nâ&#x20AC;&#x;-[1-chloro acetyl]-Indole which on further treatment with amines to afford Nâ&#x20AC;&#x;(1-morphollino-1-acetyl/piperidino-1-acetyl / dimethyl-1-aminoacetyl/ diethyl-1-aminoacetyl, N,N-dimethyl amino-p-aminoacetyl / N,N-diethylamino-paminoacetyl/pyridine-1-amino acetyl, pyrimidine-1-aminoacetyl / diphenyl-1-aminoacetyl/ piperizino-1-acetyl]Indole.

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological & Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India

2016

खाद्य पदार्थों में जहर घोऱते रं गीन रसायन १

डॉ. ममता ससंह एवं २डॉ. राजेंद्र ससंह

१

पोस्ट डोक फ़ेऱो (य.ू जी.सी.)ऱसऱतकऱा ववभाग, बरे ऱी कॉऱेज, बरे ऱी २

सह आचायय, जंतुववज्ञान ववभाग बरे ऱी कॉऱेज, बरे ऱी Email. manumamtamanan@gmail.com

जीवन के ऱगभग हर ऺेत्र में मानव के कायय कऱाऩों से ऩयायवरण में जो ऩररवर्यन आये हैं उन्होंने हमारे स्वास्​्य को प्रभभर् ककया है . यह मान्यर्ा सही नहीॊ है कक आर्थयक समर्ृ ध मानव की प्रगतर् का अकेऱा सच ू क है . हररर् क्ाॊतर् के दौरान खाद्य-उत्ऩादन बढ़ाने वाऱे कीटनाशकों ने खेतर्हर मजदरू ों को और ऩैदावार का उऩयोग कर रहे हम सभी को प्रभाववर् ककया है . ऱाखों ऱोग काययस्थऱों ऩर या घरों में घटक रसायनों के सॊऩकय में आर्े हैं जजस से स्वास्​्य ऩर प्रतर्कूऱ असर ऩड़र्ा है क्योंकक उद्योगों में तनयॊत्रण उऩायों का ठीक से ऩाऱन नहीॊ ककया जार्ा. रसायनों से प्रदवू षर् भोजन जन स्वास्​्य की एक प्रमुख समस्या है . यह प्रदष ू ण हवा ऩानी और भमटटी के घटकों को असॊर्ुभऱर् करर्ा है . ववषैऱी धार्ुएॊ ऩी. सी. बी. और दाइअक्सन का या रोगनाशकों, ऩशुओॊ कक दवाओॊ और दस ू रे खेतर्हर रसायनों जैसे ववभभन्न रसायनों का समवेर् उऩयोग मनुष्य के स्वास्​्य ऩर गम्भीर प्रभाव डाऱर्ा है . खाद्य ऩदाथों के ववतनमायण और प्रसॊस्करण के दौरान उनमें भमऱाए जाने वाऱे ऩदाथय और प्रदष ू क भी मानव के स्वास्​्य ऩर प्रतर्कूऱ असर छोड़र्े हैं. मानवीय कक्या-कऱाऩों व प्राकृतर्क सॊसाधनों के अवववेक ऩूणय व अनैतर्क दोहन के ऩररणाम स्वरुऩ ऩाररजस्थकी घटकों में ववघटन एवॊ ऺरण के साथ साथ ऩयायवरण में ववषैऱी धार्ुओॊ की मात्र में अप्रत्याभशर् ववृ ि हुई है जजनका घनत्व ५ ग्राम/घन सेमी. से अर्धक होर्ा है जैसे आसेतनक, कैडभमयम, क्ोभमउम, कोऩर, ऱेड, मैग्नीज, मकयरी

सेभऱतनयम, ऱोहा आदद. इन भरी र्त्वों के प्रमुख स्रोर् कीटनाशक, उवयरक, प्रदवू षर् जऱ, धार्ु गऱाने वाऱे उऩक्म, र्था औद्योर्गक बदहस्राब मुख्य हैं. ये र्त्व भोजन श्रॊखऱा द्वारा मनुष्य में ऩहुॉच कर कैंसर, हाइऩरककराटोभसस, मधुमेह, ह्रदय रोग, नऩुॊसकर्ा, भमनीमार्ा रोग र्था अनेक स्नायु रोगों को जन्म दे रहे हैं. ववश्व स्वास्​्य सॊगठन (डब्ऱ.ू एच.ओ.) की ददसम्बर

२०१५ की ररऩोटय के अनस ु ार सॊदवू षर् भोजन से मनष्ु य में २०० से भी अर्धक प्रकार के

रोग होर्े हैं. प्रतर्वषय ऱगभग ६ करोड ऱोग दवू षर् भोजन से बीमार होर्े हैं और इनमें से ४ ऱाख २० हज़ार ऱोग उर्चर् इऱाज न भमऱने के कारण मत्ृ यू को प्राप्र् हो जार्े हैं. इस मत्ृ यू दर में १ ऱाख २५ हज़ार ५ वषय की आयु से कम के बच्चे होर्े हैं. डब्ऱू.एच.ओ. ने भोजन को सॊदवू षर् करने वाऱे ३१ कारकों का ऩर्ा ऱगाया जजसमें भारी र्त्व ऱेड (शीशा), केडभमयम र्था मकयरी मख् ु य रूऩ से स्नायु र्ॊत्र और गद ु ों को प्रभभर् करर्े हैं. कंु जी शब्द: खाद्य ऩदाथय, भारी र्त्व, रसायन, प्रदष ू ण, मानव स्वास्​्य

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Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh

2nd International Conference on Innovations in Chemical, Biological &Environmental Sciences (ICBCES) at SSPG College, Shahjahanpur, UP, India

2016

SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF Cr (III) COMPLEXES OF 2 & 3 PYRIDINEFORMAMIDE SEMICARBAZONES AND THIOSEMICARBAZONES Smriti Raizada* and Sangeeta Sadwal Department of Chemistry; MMH College, Ghaziabad ;(U.P.),India *Email: smriti_raizada@live.com

New Cr (III) metal complexes containing ligands2-pyridineformamide semicarbazone (L1), 2pyridineformamidethiosemicarbazone (L2), 3-pyridineformamide semicarbazone (L3), 3pyridineformamidethiosemicarbazone (L4), have been synthesized. These ligands were characterized on basis of elemental analyses, molar conductance, IR, electronic and EPR spectral studies. The complexes may be formulated as [Cr(L)2X2]X where L = L1, L2, L3, L4,; X =Cl- , NO3-). The significant IR spectral bands of the metal complexes show the shifting of the bands corresponding to (-C=N) and (-C=S) towards lower side (around ca.~~20 â&#x20AC;&#x201C; 50 cm-1) on complexation for L1, L3 and (C=O) for L2, L4. In all the Cr(III) complexes observed magnetic moment is 3.74 â&#x20AC;&#x201C; 3.89 B.M suggesting an octahedral environment An intense EPR line centered at about 340 mT(g eff ~ 1.972) is also observed for all the analyzed samples. On the basis of IR, electronic, and EPR spectra of complexes octahedral geometry is assigned for all the complexes.

30 Editors: Dr Priy Brat Dwivedi, Dr Alok Kumar Singh