Natsciapec

Arceo, Carmela C.

NatSci

ABMCB-2B

Measurement Measurement is the assignment of a number to a characteristic of an object or event, which can be compared with other objects or events. The scope and application of a measurement is dependent on the context and discipline.

In the natural sciences and engineering, measurements do not apply to nominal properties of objects or events, which is consistent with the guidelines of the International vocabulary of metrology published by the International Bureau of Weights and Measures. However, in other fields such asstatistics as well as the social and behavioral sciences, measurements can have multiple levels, which would include nominal, ordinal, interval, and ratio scales.

Measurement is a cornerstone of trade, science, technology, and quantitative research in many disciplines.

Historically, many measurement systems existed for the varied fields of human existence to facilitate comparisons in these fields. Often these were achieved by local agreements between trading partners or collaborators. Since the 18th century, developments progressed towards unifying, widely accepted standards that resulted in the modern International System of Units (SI). This system reduces all physical measurements to a mathematical combination of seven base units. The science of measurement is pursued in the field of metrology.

Methodology The measurement of a property may be categorized by the following criteria: type, magnitude, unit, and uncertainty. They enable unambiguous comparisons between measurements.

The type or level of measurement is a taxonomy for the methodological character of a comparison. For example, two states of a property may be compared by ratio, difference, or ordinal preference. The type is commonly not explicitly expressed, but implicit in the definition of a measurement procedure. The magnitude is the numerical value of the characterization, usually obtained with a suitably chosen measuring instrument. A unit assigns a mathematical weighting factor to the magnitude that is derived as a ratio to the property of an artifact used as standard or a natural physical quantity. An uncertainty represents the random and systemic errors of the measurement procedure; it indicates a confidence level in the measurement. Errors are evaluated by methodically repeating measurements and considering the accuracy and precision of the measuring instrument.

Standardization of measurement units Measurements most commonly use the International System of Units (SI) as a comparison framework. The system defines seven fundamental units: kilogram, metre, candela,second, ampere, kelvin, and mole. Six of these units are defined without reference to a particular physical object which serves as a standard (artifact-free), with the exception of the kilogram which is still embodied in an artifact which rests at the BIPM outside Paris.

Artifact-free definitions fix measurements at an exact value related to a physical constant or other invariable phenomena in nature, in contrast to standard artifacts which are subject to deterioration or destruction. Instead, the measurement unit can only ever change through increased accuracy in determining the value of the constant it is tied to.

The first proposal to tie an SI base unit to an experimental standard independent of fiat was by Charles Sanders Peirce (1839–1914), who proposed to define the metre in terms of the wavelength of a spectral line This directly influenced the Michelson–Morley experiment; Michelson and Morley cite Peirce, and improve on his method.

Standards With the exception of a few fundamental quantum constants, units of measurement are derived from historical agreements. Nothing inherent in nature dictates that an inch has to be a certain length, nor that a mile is a better measure of distance than a kilometre. Over the course of human history, however, first for convenience and then for necessity, standards of measurement evolved so that communities would have certain common benchmarks. Laws regulating measurement were originally developed to prevent fraud in commerce.

Today, units of measurement are generally defined on a scientific basis, overseen by governmental or independent agencies, and established in international treaties, pre-eminent of which is the General Conference on Weights and Measures (CGPM), established in 1875 by the Treaty of the metre and which oversees the International System of Units (SI) and which has custody of theInternational Prototype Kilogram. The metre, for example, was redefined in 1983 by the CGPM as the distance traveled by light in free space in 1â „299,792,458 of a second while in 1960 the international yard was defined by the governments of the United States, United Kingdom, Australia and South Africa as being exactly 0.9144 metres.

In the United States, the National Institute of Standards and Technology (NIST), a division of the United States Department of Commerce, regulates commercial measurements. In the United Kingdom, the role is performed by the National Physical Laboratory (NPL), in Australia by the Commonwealth Scientific and Industrial Research Organisation, in South Africa by the Council for Scientific and Industrial Research and in India the National Physical Laboratory of India.

Metric system Main articles: Metric system, History of the metric system and Introduction to the metric system The metric system is a decimal systems of measurement based on its units for length, the mertre and for mass, the kilogrram. It exists in several variations, with different choices of base units, though these do not affect its dayto-day use. Since the 1960s, the International System of Units(SI) is the internationally recognised metric system.

Metric units of mass, length, and electricity are widely used around the world for both everyday and scientific purposes.

The metric system features a single base unit for many physical quantities. Other quantities are derived from the standard SI units. Multiples and fractions of the units are expressed as Powers of 10 of each unit. Unit conversions are always simple because they are in the ratio of ten, one hundred, one thousand, etc., so that convenient magnitudes for measurements are achieved by simply moving the decimal place: 1.234 metres is 1234 millimetres or 0.001234 kilometres. The use of fractions, such as 2/5 of a metre, is not prohibited, but uncommon. All lengths and distances, for example, are measured in metres, or thousandths of a metre (millimetres), or thousands of metres (kilometres). There is no profusion of different units with different conversion factors as in the Imperial system which uses, for example, inches, feet, yards, fathoms, rords.

Converting prefixes The SI allows easy multiplication when switching among units having the same base but different prefixes. To convert from metres to centimetres it is only necessary to multiply the number of metres by 100, since there are 100 centimetres in a metre. Inversely, to switch from centimetres to metres one multiplies the number of centimetres by 0.01 or divide centimetres by 100.

Length A 2-metre carpenter's ruler A ruler or rule is a tool used in, for example, geometry, technical drawing, engineering, and carpentry, to measure lengths or distances or to draw straight lines. Strictly speaking, the ruler is the instrument used to rule straight lines and the calibrated instrument used for determining length is called a measure, however common usage calls both instruments rulers and the special name straightedge is used for an unmarked rule. The use of the word measure, in the sense of a measuring instrument, only survives in the phrase tape measure, an instrument that can be used to measure but cannot be used to draw straight lines. As can be seen in the photographs on this page, a two-metre carpenter's rule can be folded down to a length of only 20 centimetres, to easily fit in a pocket, and a five-metrelong tape measure easily retracts to fit within a small housing.

Some special names. Some non-systematic names are applied for some multiples of some units. • 100 kilograms = 1 quintal; 1000 kilogram = 1 metric tonne; • 10 years = 1 decade; 100 years = 1 century; 1000 years = 1 millennium Building trades The Australian building trades adopted the metric system in 1966 and the units used for measurement of length are metres (m) and millimetres (mm). Centimetres (cm) are avoided as they cause confusion when reading plans.

For example, the length two and a half metres is usually recorded as 2500 mm or 2.5 m; it would be considered non-standard to record this length as 250 cm.[9] Surveyor's Trade American surveyors use a decimal-based system of measurement devised by Edmund Gunter in 1620. The base unit is Gunter's chain of 66 feet (20 m) which is subdivided into 4 rods, each of 16.5 ft or 100 links of 0.66 feet. A link is abbreviated "lk," and links "lks" in old deeds and Land Surveys done for the government.

Time Main article: Time Time is an abstract measurement of elemental changes over a non spatial continuum. It is denoted by numbers and/or named periods such as hours, days, weeks, months andyears. It is an apparently irreversible series of occurrences within this non spatial continuum. It is also used to denote an interval between two relative points on this continuum.

Mass Main article: Weighing scale Mass refers to the intrinsic property of all material objects to resist changes in their momentum. Weight, on the other hand, refers to the downward force produced when a mass is in a gravitational field. In free fall, (no net gravitational forces) objects lack weight but retain their mass. The Imperial units of mass include the ounce, pound, and rton. The metric units gram and kilogram are units of mass.

One device for measuring weight or mass is called a weighing scale or, often, simply a scale. A spring scale measures force but not mass, a balance compares weight, both require a gravitational field to operate. Some of the most accurate instruments for measuring weight or mass are based on load cells with a digital read-out, but require a gravitational field to function and would not work in free fall.

Economics Main article: Measurement in economics The measures used in economics are physical measures, nominal price value measures and real price measures.

These measures differ from one another by the variables they measure and by the variables excluded from measurements.

Energy In physics, energy is a property of objects which can be transferred to other objects or converted into different forms, but cannot be created or destroyed.[1] The "ability of a system to perform work" is a common description, but it is difficult to give one single comprehensive definition of energy because of its many forms. [2] For instance, in SI units, energy is measured in joules, and one joule is defined "mechanically", being the energy transferred to an object by the mechanical work of moving it a distance of 1 metre against a force of 1 newton.[note 1] However, there are many other definitions of energy, depending on the context, such as thermal energy, radiant energy, electromagnetic, nuclear, etc., where definitions are derived that are the most convenient.

Common energy forms include the kinetic energy of a moving object, the radiant energy carried by light, the potential energy stored by an object's position in a force field(gravitational, electric or magnetic), elastic energy stored by stretching solid objects, chemical energy released when a fuel burns, and the thermal energy due to an object'stemperature. All of the many forms of energy are convertible to other kinds of energy, and obey the law of conservation of energy which says that energy can be neither created nor be destroyed; however, it can change from one form to another.

For "closed systems" with no external source or sink of energy, the first law of thermodynamics states that a system's energy is constant unless energy is transferred in or out bymechanical work or heat, and that no energy is lost in transfer. This means that it is impossible to create or destroy energy. The second law of thermodynamics states that all systems doing work always lose some energy as waste heat. This creates a limit to the amount of energy that can do work by a heating process, a limit called the available energy. Mechanical and other forms of energy can be transformed in the other direction into thermal energy without such limitations.

[3] The total energy of a system can be calculated by adding up all forms of energy in the system.

Examples of energy transformation include generating electric energy from heat energy via a steam turbine, or lifting an object against gravity using electrical energy driving a crane motor. Lifting against gravity performs mechanical work on the object and stores gravitational potential energy In the object. If the object falls to ground, gravity does mechanical work on the object which transforms the potential energy in the gravitational field to the kinetic energy released as heat on impact with the ground. Our Sun transforms nuclear potential energy to other forms of energy; its total mass does not decrease due to that in itself (since it still contains the same total energy even if in different forms), but its mass does decrease when the energy escapes out to its surroundings, largely as radiant energy.

Mass and energy are closely related. According to the theory of mass–energy equivalence, any object that has mass when stationary in a frame of reference (called rest mass) also has an equivalent amount of energy whose form is called rest energy in that frame, and any additional energy acquired by the object above that rest energy will increase an object's mass. For example, if you had a sensitive enough scale, you could measure an increase in mass after heating an object.

Living organisms require available energy to stay alive, such as the energy humans get from food. Civilisation gets the energy it needs from energy resources such as fossil fuels. The processes of Earth's climate and ecosystem are driven by the radiant energy Earth receives from the sun and the geothermal energy contained within the earth.

FORMS The total energy of a system can be subdivided and classified in various ways. For example, classical mechanics distinguishes betweenkinetic energy, which is determined by an object's movement through space, and potential energy, which is a function of the position of an object within a field. It may also be convenient to distinguish gravitational energy, thermal energy, several types of nuclear energy (which utilize potentials from the nuclear force and the weak force), electric energy (from the electric field), and magnetic energy (from themagnetic field), among others. Many of these classifications overlap; for instance, thermal energy usually consists partly of kinetic and partly of potential energy.

Some types of energy are a varying mix of both potential and kinetic energy. An example is mechanical energy which is the sum of (usually macroscopic) kinetic and potential energy in a system. Elastic energy in materials is also dependent upon electrical potential energy (among atoms and molecules), as is chemical energy,

which is stored and released from a reservoir of electrical potential energy between electrons, and the molecules or atomic nuclei that attract them. [need quotation to verify].The list is also not necessarily complete. Whenever physical scientists discover that a certain phenomenon appears to violate the law of energy conservation, new forms are typically added that account for the discrepancy.

Heat and work are special cases in that they are not properties of systems, but are instead properties of processes that transfer energy. In general we cannot measure how much heat or work are present in an object, but rather only how much energy is transferred among objects in certain ways during the occurrence of a given process. Heat and work are measured as positive or negative depending on which side of the transfer we view them from.

Potential energies are often measured as positive or negative depending on whether they are greater or less than the energy of a specified base state or configuration such as two interacting bodies being infinitely far apart. Wave energies (such as radiant or sound energy), kinetic energy, and rest energy are each greater than or equal to zero because they are measured in comparison to a base state of zero energy: "no wave", "no motion", and "no inertia", respectively.

HISTORY The word energy derives from the Ancient Greek: ἐνέργεια energeia "activity, operation",[4] which possibly appears for the first time in the work of Aristotle in the 4th century BC. In contrast to the modern definition, energeia was a qualitative philosophical concept, broad enough to include ideas such as happiness and pleasure.

In the late 17th century, Gottfried Leibniz proposed the idea of the Latin: vis viva, or living force, which defined as the product of the mass of an object and its velocity squared; he believed that total vis viva was conserved. To account for slowing due to friction, Leibniz theorized that thermal energy consisted of the random motion of the constituent parts of matter, a view shared by Isaac Newton, although it would be more than a century until this was generally accepted. The modern analog of this property, kinetic energy, differs from vis viva only by a factor of two.

In 1807, Thomas Young was possibly the first to use the term "energy" instead of vis viva, in its modern sense.

[5] Gustave-Gaspard Coriolis described "kinetic energy" in 1829 in its modern sense, and in 1853, William Rankine coined the term "potential energy". The law of conservation of energy, was also first postulated in the early 19th century, and applies to any isolated system. It was argued for some years whether heat was a physical substance, dubbed the caloric, or merely a physical quantity, such as momentum. In 1845 James Prescott Joule discovered the link between mechanical work and the generation of heat.

These developments led to the theory of conservation of energy, formalized largely by William Thomson (Lord Kelvin) as the field ofthermodynamics. Thermodynamics aided the rapid development of explanations of chemical processes by Rudolf Clausius, Josiah Willard Gibbs, and Walther Nernst. It also led to a mathematical formulation of the concept of entropy by Clausius and to the introduction of laws of radiant energy by Jožef Stefan. According to Noether's theorem, the conservation of energy is a consequence of the fact that the laws of physics do not change over time.[6]Thus, since 1918, theorists have understood that the law of conservation of energy is the direct mathematical consequence of the translational symmetry of the quantityconjugate to energy, namely time.

UNITS OF MEASURE In 1843 James Prescott Joule independently discovered the mechanical equivalent in a series of experiments. The most famous of them used the "Joule apparatus": a descending weight, attached to a string, caused rotation of a paddle immersed in water, practically insulated from heat transfer. It showed that the gravitational potential energy lost by the weight in descending was equal to the internal energygained by the water through friction with the paddle.

In the International System of Units (SI), the unit of energy is the joule, named after James Prescott Joule. It is a derived unit. It is equal to the energy expended (or work done) in applying a force of one newton through a distance of one metre. However energy is also expressed in many other units not part of the SI, such as ergs, calories, British Thermal Units, kilowatt-hours and kilocalories, which require a conversion factor when expressed in SI units.

The SI unit of energy rate (energy per unit time) is the watt, which is a joule per second. Thus, one joule is one watt-second, and 3600 joules equal one watt-hour. The CGS energy unit is the erg and the imperial and US customary unit is the foot pound. Other energy units such as the electronvolt, food calorie or thermodynamic kcal (based on the temperature change of water in a heating process), and BTUare used in specific areas of science and commerce.

SCIENTIFI USE CLASSICAL MECHANICS Main articles: Mechanics, Mechanical work and Thermodynamics In classical mechanics, energy is a conceptually and mathematically useful property, as it is a conserved quantity.

Several formulations of mechanics have been developed using energy as a core concept.

Work, a form of energy, is force times distance.

This says that the work ( ) is equal to the line integral of the force F along a path C; for details see the mechanical work article. Work and thus energy is frame dependent. For example, consider a ball being hit by a bat. In the center-of-mass reference frame, the bat does no work on the ball. But, in the reference frame of the person swinging the bat, considerable work is done on the ball.

The total energy of a system is sometimes called the Hamiltonian, after William Rowan Hamilton. The classical equations of motion can be written in terms of the Hamiltonian, even for highly complex or abstract systems.

These classical equations have remarkably direct analogs in nonrelativistic quantum mechanics. [7] Another energy-related concept is called the Lagrangian, after Joseph-Louis Lagrange. This formalism is as fundamental as the Hamiltonian, and both can be used to derive the equations of motion or be derived from them.

It was invented in the context of classical mechanics, but is generally useful in modern physics. The Lagrangian is defined as the kinetic energy minus the potential energy. Usually, the Lagrange formalism is mathematically more convenient than the Hamiltonian for non-conservative systems (such as systems with friction).

Noether's theorem (1918) states that any differentiable symmetry of the action of a physical system has a corresponding conservation law. Noether's theorem has become a fundamental tool of modern theoretical physics and the calculus of variations. A generalisation of the seminal formulations on constants of motion in Lagrangian and Hamiltonian mechanics (1788 and 1833, respectively), it does not apply to systems that cannot be modeled with a Lagrangian; for example, dissipative systems with continuous symmetries need not have a corresponding conservation law.

Chemistry In the context of chemistry, energy is an attribute of a substance as a consequence of its atomic, molecular or aggregate structure. Since a chemical transformation is accompanied by a change in one or more of these kinds of structure, it is invariably accompanied by an increase or decrease of energy of the substances involved. Some energy is transferred between the surroundings and the reactants of the reaction in the form of heat or light; thus the products of a reaction may have more or less energy than the reactants. A reaction is said to be exergonic if the final state is lower on the energy scale than the initial state; in the case of endergonic reactions the situation is the reverse.Chemical reactions are invariably not possible unless the reactants surmount an energy barrier known as the activation energy. The speed of a chemical reaction (at given temperature T) is related to the activation energy E, by the Boltzmann's population factor e−E/kT – that is the probability of molecule to have energy greater than or equal to E at the given temperature T. This exponential dependence of a reaction rate on temperature is known as the Arrhenius equation.The activation energy necessary for a chemical reaction can be in the form of thermal energy.

BIOLOGY

In biology, energy is an attribute of all biological systems from the biosphere to the smallest living organism.

Within an organism it is responsible for growth and development of a biological cell or an organelle of a biological organism. Energy is thus often said to be stored by cells in the structures of molecules of substances such as carbohydrates (including sugars), lipids, and proteins, which release energy when reacted with oxygen in respiration. In human terms, the human equivalent (H-e) (Human energy conversion) indicates, for a given amount of energy expenditure, the relative quantity of energy needed for human metabolism, assuming an average human energy expenditure of 12,500kJ per day and a basal metabolic rate of 80 watts. For example, if our bodies run (on average) at 80 watts, then a light bulb running at 100 watts is running at 1.25 human equivalents (100 ÷ 80) i.e. 1.25 H-e. For a difficult task of only a few seconds' duration, a person can put out thousands of watts, many times the 746 watts in one official horsepower. For tasks lasting a few minutes, a fit human can generate perhaps 1,000 watts. For an activity that must be sustained for an hour, output drops to around 300; for an activity kept up all day, 150 watts is about the maximum. [8] The human equivalent assists understanding of energy flows in physical and biological systems by expressing energy units in human terms: it provides a "feel" for the use of a given amount of energy[9] Sunlight is also captured by plants as chemical potential energy in photosynthesis, when carbon dioxide and water (two low-energy compounds) are converted into the high-energy compounds carbohydrates, lipids, and proteins.

Plants also release oxygen during photosynthesis, which is utilized by living organisms as an electron acceptor, to release the energy of carbohydrates, lipids, and proteins. Release of the energy stored during photosynthesis as heat or light may be triggered suddenly by a spark, in a forest fire, or it may be made available more slowly for animal or human metabolism, when these molecules are ingested, and catabolism is triggered by enzyme action.

Any living organism relies on an external source of energy—radiation from the Sun in the case of green plants; chemical energy in some form in the case of animals—to be able to grow and reproduce. The daily 1500– 2000 Calories (6–8 MJ) recommended for a human adult are taken as a combination of oxygen and food molecules, the latter mostly carbohydrates and fats, of which glucose (C6H12O6) and stearin (C57H110O6) are convenient examples. The food molecules are oxidised to carbon dioxide and water in themitochondria C6H12O6 + 6O2 → 6CO2 + 6H2O C57H110O6 + 81.5O2 → 57CO2 + 55H2O and some of the energy is used to convert ADP into ATP ADP + HPO42− → ATP + H2O The rest of the chemical energy in the carbohydrate or fat is converted into heat: the ATP is used as a sort of "energy currency", and some of the chemical energy it contains when split and reacted with water, is used for other metabolism (at each stage of a metabolic pathway, some chemical energy is converted into heat). Only a tiny fraction of the original chemical energy is used for work: [note 2] gain in kinetic energy of a sprinter during a 100 m race: 4 kJ gain in gravitational potential energy of a 150 kg weight lifted through 2 metres: 3kJ Daily food intake of a normal adult: 6–8 MJ It would appear that living organisms are remarkably inefficient (in the physical sense) in their use of the energy they receive (chemical energy or radiation), and it is true that most real machines manage higher efficiencies. In growing organisms the energy that is converted to heat serves a vital purpose, as it allows the organism tissue to be highly ordered with regard to the molecules it is built from. The second law of thermodynamics states that energy (and matter) tends to become more evenly spread out across the universe: to concentrate energy (or matter) in one specific place, it is necessary to spread out a greater amount of energy (as heat) across the remainder of the universe ("the surroundings").[note 3] Simpler organisms can achieve higher energy efficiencies than more complex ones, but the complex organisms can occupy ecological niches that are not available to their simpler brethren. The conversion of a portion of the chemical energy to heat at each step in a metabolic pathway is the physical reason behind the pyramid of

biomass observed in ecology: to take just the first step in the food chain, of the estimated 124.7 Pg/a of carbon that is fixed by photosynthesis, 64.3 Pg/a (52%) are used for the metabolism of green plants,[10] i.e. reconverted into carbon dioxide and heat.

EARTH SCIENCE In geology, continental drift, mountain ranges, volcanoes, and earthquakes are phenomena that can be explained in terms of energy transformations in the Earth's interior., [11]while meteorological phenomena like wind, rain, hail, snow, lightning, tornadoes and hurricanes, are all a result of energy transformations brought about by solar energy on theatmosphere of the planet Earth.

Sunlight may be stored as gravitational potential energy after it strikes the Earth, as (for example) water evaporates from oceans and is deposited upon mountains (where, after being released at a hydroelectric dam, it can be used to drive turbines or generators to produce electricity). Sunlight also drives many weather phenomena, save those generated by volcanic events. An example of a solar-mediated weather event is a hurricane, which occurs when large unstable areas of warm ocean, heated over months, give up some of their thermal energy suddenly to power a few days of violent air movement.

In a slower process, radioactive decay of atoms in the core of the Earth releases heat. This thermal energy drives plate tectonics and may lift mountains, via orogenesis. This slow lifting represents a kind of gravitational potential energy storage of the thermal energy, which may be later released to active kinetic energy in landslides, after a triggering event. Earthquakes also release stored elastic potential energy in rocks, a store that has been produced ultimately from the same radioactive heat sources. Thus, according to present understanding, familiar events such as landslides and earthquakes release energy that has been stored as potential energy in the Earth's gravitational field or elastic strain (mechanical potential energy) in rocks. Prior to this, they represent release of energy that has been stored in heavy atoms since the collapse of long-destroyed supernova stars created these atoms.

Cosmology In cosmology and astronomy the phenomena of stars, nova, supernova, quasars and gamma-ray bursts are the universe's highest-output energy transformations of matter. Allstellar phenomena (including solar activity) are driven by various kinds of energy transformations. Energy in such transformations is either from gravitational collapse of matter (usually molecular hydrogen) into various classes of astronomical objects (stars, black holes, etc.), or from nuclear fusion (of lighter elements, primarily hydrogen). The nuclear fusion of hydrogen in the Sun also releases another store of potential energy which was created at the time of the Big Bang. At that time, according to theory, space expanded and the universe cooled too rapidly for hydrogen to completely fuse into heavier elements. This meant that hydrogen represents a store of potential energy that can be released by fusion.

Such a fusion process is triggered by heat and pressure generated from gravitational collapse of hydrogen clouds when they produce stars, and some of the fusion energy is then transformed into sunlight.

Quantum mechanics Main article: Energy operator In quantum mechanics, energy is defined in terms of the energy operator as a time derivative of the wave function.

The Schrรถdinger equation equates the energy operator to the full energy of a particle or a system. Its results can be considered as a definition of measurement of energy in quantum mechanics. The Schrรถdinger equation describes the space- and time-dependence of a slowly changing (non-relativistic) wave function of quantum systems. The solution of this equation for a bound system is discrete (a set of permitted states, each characterized by an energy level) which results in the concept of quanta. In the solution of the Schrรถdinger equation for any oscillator (vibrator) and for electromagnetic waves in a vacuum, the resulting energy states are related to the frequency by Planck's relation: (where is Planck's constant and the frequency). In the case of an electromagnetic wave these energy states are called quanta of light or photons.

Relativity When calculating kinetic energy (work to accelerate a mass from zero speed to some finite speed) relativistically – using Lorentz transformations instead of Newtonian mechanics– Einstein discovered an unexpected by-product of these calculations to be an energy term which does not vanish at zero speed. He called it rest mass energy: energy which every mass must possess even when being at rest. The amount of energy is directly proportional to the mass of body: , where m is the mass, c is the speed of light in vacuum, E is the rest mass energy.

For example, consider electron–positron annihilation, in which the rest mass of individual particles is destroyed, but the inertia equivalent of the system of the two particles (itsinvariant mass) remains (since all energy is associated with mass), and this inertia and invariant mass is carried off by photons which individually are massless, but as a system retain their mass. This is a reversible process – the inverse process is called pair creation – in which the rest mass of particles is created from energy of two (or more) annihilating photons. In this system the matter (electrons and positrons) is destroyed and changed to non-matter energy (the photons). However, the total system mass and energy do not change during this interaction.

In general relativity, the stress–energy tensor serves as the source term for the gravitational field, in rough analogy to the way mass serves as the source term in the non-relativistic Newtonian approximation.[12] It is not uncommon to hear that energy is "equivalent" to mass. It would be more accurate to state that every energy has an inertia and gravity equivalent, and because mass is a form of energy, then mass too has inertia and gravity associated with it.

In classical physics, energy is a scalar quantity, the canonical conjugate to time. In special relativity energy is also a scalar (although not a Lorentz scalar but a time component of the energy–momentum 4-vector).[12] In other words, energy is invariant with respect to rotations of space, but not invariant with respect to rotations of space-time (= boosts).

TRANSFORMATION Energy may be transformed between different forms at various efficiencies. Items that transform between these forms are called transducers. Examples of transducers include a battery, from chemical energy to electric energy; a dam: gravitational potential energy to kinetic energy of moving water (and the blades of a turbine) and ultimately to electric energy through anelectric generator.

There are strict limits to how efficiently energy can be converted into other forms of energy via work, and heat as described by Carnot's theorem and the second law of thermodynamics. These limits are especially evident when an engine is used to perform work. However, some energy transformations can be quite efficient. The direction of transformations in energy (what kind of energy is transformed to what other kind) is often determined by entropy (equal energy spread among all availabledegrees of freedom) considerations. In practice all energy transformations are permitted on a small scale, but certain larger transformations are not permitted because it is statistically unlikely that energy or matter will randomly move into more concentrated forms or smaller spaces.

Energy transformations in the universe over time are characterized by various kinds of potential energy that has been available since the Big Bang, later being "released" (transformed to more active types of energy such as kinetic or radiant energy), when a triggering mechanism is available. Familiar examples of such processes include nuclear decay, in which energy is released that was originally "stored" in heavy isotopes (such as uranium and thorium), by nucleosynthesis, a process ultimately using the gravitational potential energy released from the gravitational collapse of supernovae, to store energy in the creation of these heavy elements before they were incorporated into the solar system and the Earth. This energy is triggered and released in nuclear fission bombs or in civil nuclear power generation. Similarly, in the case of a chemical explosion, chemical potential energy is transformed to kinetic energy and thermal energy in a very short time. Yet another example is

that of a pendulum. At its highest points the kinetic energy is zero and the gravitational potential energy is at maximum. At its lowest point thekinetic energy is at maximum and is equal to the decrease of potential energy. If one (unrealistically) assumes that there is no friction or other losses, the conversion of energy between these processes would be perfect, and the pendulum would continue swinging forever.

Energy is also transferred from potential energy ( ) to kinetic energy ( ) and then back to potential energy constantly. This is referred to as conservation of energy. In this closed system, energy cannot be created or destroyed; therefore, the initial energy and the final energy will be equal to each other. This can be demonstrated by the following: (4)

The equation can then be simplified further since

times the height) and can be found by adding

(mass times acceleration due to gravity

(half mass times velocity squared). Then the total amount of energy .

Conservation of energy and mass in transformation Energy gives rise to weight when it is trapped in a system with zero momentum, where it can be weighed. It is also equivalent to mass, and this mass is always associated with it. Mass is also equivalent to a certain amount of energy, and likewise always appears associated with it, as described in mass-energy equivalence. The formula E = mc², derived byAlbert Einstein (1905) quantifies the relationship between rest-mass and restenergy within the concept of special relativity. In different theoretical frameworks, similar formulas were derived by J. J. Thomson (1881), Henri PoincarÊ (1900), Friedrich HasenÜhrl (1904) and others (see Massenergy equivalence#History for further information).

Matter may be converted to energy (and vice versa), but mass cannot ever be destroyed; rather, mass/energy equivalence remains a constant for both the matter and the energy, during any process when they are converted into each other. However, since is extremely large relative to ordinary human scales, the conversion of ordinary amount of matter (for example, 1 kg) to other forms of energy (such as heat, light, and other radiation) can liberate tremendous amounts of energy (~ joules = 21 megatons of TNT), as can be seen in nuclear reactors and nuclear weapons. Conversely, the mass equivalent of a unit of energy is minuscule, which is why a loss of energy (loss of mass) from most systems is difficult to measure by weight, unless the energy loss is very large. Examples of energy transformation into matter (i.e., kinetic energy into particles with rest mass) are found in high-energy nuclear physics.

Reversible and non-reversible transformations Thermodynamics divides energy transformation into two kinds: reversible processes and irreversible processes. An irreversible process is one in which energy is dissipated (spread) into empty energy states available in a volume, from which it cannot be recovered into more concentrated forms (fewer quantum states), without degradation of even more energy. A reversible process is one in which this sort of dissipation does not happen. For example, conversion of energy from one type of potential field to another, is reversible, as in the pendulum system described above. In processes where heat is generated, quantum states of lower energy, present as possible excitations in fields between atoms, act as a reservoir for part of the energy, from which it cannot be recovered, in order to be converted with 100% efficiency into other forms of energy. In this case, the energy must partly stay as heat, and cannot be completely recovered as usable energy, except at the price of an increase in some other kind of heat-like increase in disorder in quantum states, in the universe (such as an expansion of matter, or a randomisation in a crystal).

As the universe evolves in time, more and more of its energy becomes trapped in irreversible states (i.e., as heat or other kinds of increases in disorder). This has been referred to as the inevitable thermodynamic heat death of the universe. In this heat death the energy of the universe does not change, but the fraction of energy which is available to do work through a heat engine, or be transformed to other usable forms of energy (through the use of generators attached to heat engines), grows less and less.

Conservation of energy Main article: Conservation of energy According to conservation of energy, energy can neither be created (produced) nor destroyed by itself. It can only be transformed. The total inflow of energy into a system must equal the total outflow of energy from the system, plus the change in the energy contained within the system. Energy is subject to a strict global conservation law; that is, whenever one measures (or calculates) the total energy of a system of particles whose interactions do not depend explicitly on time, it is found that the total energy of the system always remains constant. [13] Richard Feynman said during a 1961 lecture:[14] There is a fact, or if you wish, a law, governing all natural phenomena that are known to date. There is no known exception to this law—it is exact so far as we know. The law is called the conservation of energy. It states that there is a certain quantity, which we call energy, that does not change in manifold changes which nature undergoes. That is a most abstract idea, because it is a mathematical principle; it says that there is a numerical quantity which does not change when something happens. It is not a description of a mechanism, or anything concrete; it is just a strange fact that we can calculate some number and when we finish watching nature go through her tricks and calculate the number again, it is the same. — The Feynman Lectures on Physics Most kinds of energy (with gravitational energy being a notable exception) [15] are subject to strict local conservation laws as well. In this case, energy can only be exchanged between adjacent regions of space, and all observers agree as to the volumetric density of energy in any given space. There is also a global law of conservation of energy, stating that the total energy of the universe cannot change; this is a corollary of the local law, but not vice versa.[3][14] This law is a fundamental principle of physics. As shown rigorously by Noether's theorem, the conservation of energy is a mathematical consequence of translational symmetry of time,[16] a property of most phenomena below the cosmic scale that makes them independent of their locations on the time coordinate. Put differently, yesterday, today, and tomorrow are physically indistinguishable. This is because energy is the quantity which is canonical conjugate to time. This mathematical entanglement of energy and time also results in the uncertainty principle - it is impossible to define the exact amount of energy during any definite time interval. The uncertainty principle should not be confused with energy conservation - rather it provides mathematical limits to which energy can in principle be defined and measured.

Each of the basic forces of nature is associated with a different type of potential energy, and all types of potential energy (like all other types of energy) appears as system mass, whenever present. For example, a compressed spring will be slightly more massive than before it was compressed. Likewise, whenever energy is transferred between systems by any mechanism, an associated mass is transferred with it.

In quantum mechanics energy is expressed using the Hamiltonian operator. On any time scales, the uncertainty in the energy is by

which is similar in form to the Heisenberg Uncertainty Principle (but not really mathematically equivalent thereto, since H and t are not dynamically conjugate variables, neither in classical nor in quantum mechanics).

In particle physics, this inequality permits a qualitative understanding of virtual particles which carry momentum, exchange by which and with real particles, is responsible for the creation of all known fundamental forces (more accurately known as fundamental interactions). Virtual photons (which are simply lowest quantum mechanical energy state ofphotons) are also responsible for electrostatic interaction between electric charges (which results in Coulomb law), for spontaneous radiative decay of exited atomic

and nuclear states, for the Casimir force, for van der Waals bond forces and some other observable phenomena.

Transfer between systems Main article: Energy transfer Closed systems Energy transfer usually refers to movements of energy between systems which are closed to transfers of matter. The portion of the energy which is transferred by conservative forces over a distance is measured as the work the source system does on the receiving system. The portion of the energy which does not do work doing during the transfer is called heat.[note 4] Energy can be transferred between systems in a variety of ways.

Examples include the transmission of electromagnetic energy via photons, physical collisions which transfer kinetic energy,[note 5] and the conductive transfer of thermal energy.

Energy is strictly conserved and is also locally conserved wherever it can be defined. Mathematically, the process of energy transfer is described by the first law of thermodynamics:[note 6]

where

is the amount of energy transferred,

represents the work done on the system, and

represents the heat flow into the system. As a simplification, the heat term, especially when the thermal efficiency of the transfer is high.

, is sometimes ignored,

This simplified equation is the one used to define the joule, for example.

Open systems There are other ways in which an open system can gain or lose energy. In chemical systems, energy can be added to a system by means of adding substances with different chemical potentials, which potentials are then extracted (both of these process are illustrated by fueling an auto, a system which gains in energy thereby, without addition of either work or heat). These terms may be added to the above equation, or they can generally be subsumed into a quantity called "energy addition term " which refers to any type of energy carried over the surface of a control volume or system volume. Examples may be seen above, and many others can be imagined (for example, the kinetic energy of a stream of particles entering a system, or energy from a laser beam adds to system energy, without either being either work-done or heat-added, in the classic senses).

Where in this general equation represents other additional advected energy terms not covered by work done on a system, or heat added to it.

Thermodynamics Internal energy Internal energy is the sum of all microscopic forms of energy of a system. It is the energy needed to create the system. It is related to the potential energy, e.g., molecular structure, crystal structure, and other geometric aspects, as well as the motion of the particles, in form of kinetic energy. Thermodynamics is chiefly concerned with

changes in internal energy and not its absolute value, which is impossible to determine with thermodynamics alone.[17] First law of thermodynamics The first law of thermodynamics asserts that energy (but not necessarily thermodynamic free energy) is always conserved[18] and that heat flow is a form of energy transfer. For homogeneous systems, with a well-defined temperature and pressure, a commonly used corollary of the first law is that, for a system subject only to pressure forces and heat transfer (e.g., a cylinder-full of gas), the differential change in the internal energy of the system (with a gain in energy signified by a positive quantity) is given as , where the first term on the right is the heat transferred into the system, expressed in terms of temperature T and entropy S (in which entropy increases and the change dS is positive when the system is heated), and the last term on the right hand side is identified as work done on the system, where pressure is P and volume V (the negative sign results since compression of the system requires work to be done on it and so the volume change, dV, is negative when work is done on the system).

This equation is highly specific, ignoring all chemical, electrical, nuclear, and gravitational forces, effects such as advection of any form of energy other than heat and pV-work. The general formulation of the first law (i.e., conservation of energy) is valid even in situations in which the system is not homogeneous. For these cases the change in internal energy of a closed system is expressed in a general form by

where

is the heat supplied to the system and

is the work applied to the system.

Equipartition of energy The energy of a mechanical harmonic oscillator (a mass on a spring) is alternatively kinetic and potential.

At two points in the oscillation cycle it is entirely kinetic, and alternatively at two other points it is entirely potential. Over the whole cycle, or over many cycles, net energy is thus equally split between kinetic and potential. This is called equipartition principle; total energy of a system with many degrees of freedom is equally split among all available degrees of freedom.

This principle is vitally important to understanding the behaviour of a quantity closely related to energy, called entropy. Entropy is a measure of evenness of a distribution of energy between parts of a system.

When an isolated system is given more degrees of freedom (i.e., given new available energy states that are the same as existing states), then total energy spreads over all available degrees equally without distinction between "new" and "old" degrees. This mathematical result is called the second law of thermodynamics.

Source Of Energy sources of energy, origins of the power used for transportation, for heat and light in dwelling and working areas, and for the manufacture of goods of all kinds, among other applications. The development of science and civilization is closely linked to the availability of energy in useful forms. Modern society consumes vast amounts of energy in all forms: light, heat, electrical, mechanical, chemical, and nuclear. The rate at which energy is produced or consumed is calledpower, although this term is sometimes used in common speech synonymously with energy.

Types of Energy Chemical and Mechanical Energy An early source of energy, or prime mover, used by humans was animal power, i.e., the energy obtained from domesticated animals. Later, as civilization developed, wind power was harnessed to drive ships and turn windmills, and streams and rivers were diverted to turn water wheels (see water power). The rotating shaft of a windmill or water wheel could then be used to crush grain, to raise water from a well, or to serve any number of other uses. The motion of the wind and water, as well as the motion of the wheel or shaft, represents a form of mechanical energy. The source of animal power is ultimately the chemical energy contained in foods and released when digested by humans and animals. The chemical energy contained in wood and other combustible fuels has served since the beginning of history as a source of heat for cooking and warmth. At the start of the Industrial Revolution, water power was used to provide energy for factories through systems of belts and pulleys that transmitted the energy to many different machines.

Heat Energy The invention of the steam engine, which converts the chemical energy of fuels into heat energy and the heat into mechanical energy, provided another source of energy. The steam engine is called an externalcombustion engine, since fuel is burned outside the engine to create the steam used inside it. During the 19th cent. the internal-combustion engine was developed; a variety of fuels, depending on the type of internal-combustion engine, are burned directly in the engine's chambers to provide a source of mechanical energy. Both steam engines and internal-combustion engines found application as stationary sources of power for different purposes and as mobile sources for transportation, as in the steamship, the railroad locomotive (both steam and diesel), and the automobile. All these sources of energy ultimately depend on the combustion of fuels for their operation.

Electrical Energy Early in the 19th cent. another source of energy was developed that did not necessarily need the combustion of fuels—the electric generator, or dynamo. The generator converts the mechanical energy of a conductor moving in a magnetic field into electrical energy, using the principle of electromagnetic induction. The great advantage of electrical energy, or electric power, as it is commonly called, is that it can be transmitted easily over great distances (see power, electric). As a result, it is the most widely used form of energy in modern civilization; it is readily converted to light, to heat, or, through the electric motor, to mechanical energy again. The large-scale production of electrical energy was made possible by the invention of the turbine, which efficiently converts the straight-line motion of falling water or expanding steam into the rotary motion needed to turn the rotor of a large generator.

Nuclear Energy The development of nuclear energy made available another source of energy. The heat of anuclear reactor can be used to produce steam, which then can be directed through a turbine to drive an electric generator, the propellers of a large ship, or some other machine. In 1999, 23% of the electricity generated in the United States derived from nuclear reactors; however, since the 1980s, the construction and application of nuclear reactors in the United States has slowed because of concern about the dangers of the resulting radioactive waste and the possibility of a disastrous nuclear meltdown

Environmental Considerations The demand for energy has increased steadily, not only because of the growing population but also because of the greater number of technological goods available and the increased affluence that has brought these goods within the reach of a larger proportion of the population. For example, despite the introduction of more fuel-efficient motor vehicles (average miles per gallon increased by 34% between 1975 and 1990), the consumption of fuel by vehicles in America increased by 20% between 1975 and 1990. The rise in gasoline consumption is attributable to an increase in the number of miles the average vehicle traveled and to a 40% increase in the same period in the number of vehicles on the road. Since 1990 average fuel efficiency has changed relatively little, while the number of vehicles, the number of miles they travel, and the total amount of fuel consumed has continued to increase.

As a result of the increase in the consumption of energy, concern has risen about the depletion of natural resources, both those used directly to produce energy and those damaged during the exploitation of the fuels or as a result of contamination by energy waste products (see underconservation of natural resources). Most of the energy consumed is ultimately generated by the combustion of fossil fuels, such as coal, petroleum, and natural gas, and the world has only a finite supply of these fuels, which are in danger of being used up. Also, the combustion of these fuels releases various pollutants (see pollution), such as carbon monoxide and sulfur dioxide, which pose health risks and may contribute to acid rain and global warming. In addition, environmentalists have become increasingly alarmed at the widespread destruction imposed on sensitive wildlands (e.g., the tropical rain forests, the arctic tundra, and coastal marshes) during the exploitation of their resources.

The Search for New Sources of Energy The environmental consequences of energy production have led many nations in the world to impose stricter guidelines on the production and consumption of energy. Further, the search for new sources of energy and more efficient means of employing energy has accelerated. The development of a viable nuclear fusion reactor is often cited as a possible solution to our energy problems. Presently, nuclear-energy plants use nuclear fission, which requires scarce and expensive fuels and produces potentially dangerous wastes.

The fuel problem has been partly helped by the development of breeder reactors, which produce more nuclear fuel than they consume, but the long-term hopes for nuclear energy rest on the development of controlled sources using nuclear fusion rather than fission. The basic fuels for fusion are extremely plentiful (e.g., hydrogen, from water) and the end products are relatively safe. The basic problem, which is expected to take decades to solve, is in containing the fuels at the extremely high temperatures necessary to initiate and sustain nuclear fusion.

Another source of energy is solar energy. The earth receives huge amounts of energy every day from the sun, but the problem has been harnessing this energy so that it is available at the appropriate time and in the appropriate form. For example, solar energy is received only during the daylight hours, but more heat and electricity for lighting are needed at night. Despite technological advances in photovoltaic cells, solar energy has not become a more significantly more financially competitive source of energy. Although several solar thermal power plants are now in operation in California, they are not yet able to compete with conventional power plants on an economic basis.

Some scientists have suggested using the earth's internal heat as a source of energy. Geothermal energy is released naturally in geysers and volcanoes. In California, some of the state's electricity is generated by the geothermal plant complex known as the Geysers, which has been in production since 1960, and in Iceland, which is geologically very active, roughly 90% of the homes are heated by geothermal energy. Still another possible energy source is tidal energy. A few systems have been set up to harness the energy released in the twice-daily ebb and flow of the ocean's tides, but they have not been widely used, because they cannot operate turbines continuously and because they must be built specifically for each site.

CLASSIFICATION OF MATTER Matter can be identified by its characteristic inertial and gravitational mass and the space that it occupies. Matter is typically commonly found in three different states: solid, liquid, and gas.

Introduction A substance is a sample of matter whose physical and chemical properties are the same throughout the sample because the matter has a constant composition. It is common to see substances changing from one state of matter to another. To differentiate the states of matter at least at a particle level, we look at the behavior of the particles within the substance.When substances change state, it is because the spacing between the particles of the substances is changing due to a gain or loss of energy. For example, we all have probably observed that water can exist in three forms with different characteristic ways of behaving: the solid state (ice), liquid state (water), and gaseous state (water vapor and steam). Due to water's prevalence, we use it to exemplify and describe the three different states of matter. As ice is heated and the particles of matter that make up water gain energy, eventually the ice melts in to water that eventually boils and turns into steam.

Before we examine the states of matter, we will consider some ways samples of matter have been classified by those who have studied how matter behaves.

Classifying Matter Evidence suggests that substances are made up of smaller particles that are ordinarily moving around. Some of those particles of matter can be split into smaller units using fairly strong heat or electricity into smaller rather uniform bits of matter called atoms. Atoms are the building blocks of elements. Elements are all those substances that have not ever been decomposed or separated into any other substances through chemical reactions, by the application of heat, or by attempting to force an direct electric current through the sample. Atoms in turn have been found to be made up of yet smaller units of matter called electrons, protons, and neutrons.

Elements can be arranged into what is called the periodic table of elements based on observed similarities in chemical and physical properties among the different elements. When atoms of two or more elements come together and bond, a compound is formed. The compound formed can later be broken down into the pure substances that originally reacted to form it.

Compounds such as water are composed of smaller units of bonded atoms called molecules. Molecules of a compound are composed of the same proportion of elements as the compound as a whole since they are the smallest units of that compound. For example, every portion of a sample of water is composed of water molecules.

Each water molecule contains two hydrogen atoms and one oxygen atom, and so water as a whole has, in a combined state, twice as many hydrogen atoms as oxygen atoms..

Water can still consist of the same molecules, but its physical properties may change. For instance, water at a temperature below 0째 Celsius (32째 Fahrenheit) is ice, whereas water above the temperature of 100째 C (212째 F) is a gas, water vapor. When matter changes from one state to another, temperature and pressure may be involved in the process and the density and other physical properties change. The temperature and pressure exerted on a sample of matter determines the resulting form of that the matter takes, whether solid, liquid, or gas.

Since the properties of compounds and elements are uniform, they are classified as substances. When two or more substances are mixed together, the result is called a mixture. Mixtures can be classified into two main categories: homogeneous and heterogeneous. Ahomogeneous mixture is one in which the composition of its constituents are uniformly mixed throughout. A homogeneous mixture in which on substance, the solute, dissolves completely in another substance, the solvent, may also be called a solution. Usually the solvent is a liquid, however the solute can be either a liquid, solid, or a gas. In a homogeneous solution, the particles of solute are spread evenly among the solvent particles and the extremely small particles of solute cannot be separated from the solvent by filtration through filter paper because the spaces between paper fibers are much greater than the size of the solute and solvent particles. Other examples of homogeneous mixtures include sugar water, which is the mixture of sucrose and water, and gasoline, which is a mixture of dozens of compounds.

A heterogeneous mixture is a nonuniform mixture in which the components separate and the composition varies.

Unlike the homogeneous mixture, heterogeneous mixtures can be separated through physical processes. An example of a physical process used is filtration, which can easily separate the sand from the water in a sand-water mixture by using a filter paper. Some more examples of heterogeneous mixtures include salad dressing, rocks, and oil and water mixtures. Heterogeneous mixtures involving at least one fluid are also called suspensionmixtures and separate if they are left standing long enough. Consider the idea of mixing oil and water together. Regardless of the amount of time spent shaking the two together, eventually oil and water mixtures will separate with the oil rising to the top of the mixture due to its lower density. Mixtures that fall between a solution and a heterogeneous mixture are called colloidal suspensions (or just colloids). A mixture is considered colloidal if it typically does not spontaneously separate or settle out as time passes and cannot be completely separated by filtering through a typical filter paper. It turns out that a mixture is colloidal in its behavior if one or more of its dimensions of length, width, or thickness is in the range of 1-1000 nm. A colloidal mixture can also be recognized by shining a beam of light through the mixture. If the mixture is colloidal, the beam of light will be partially scattered by the suspended nanometer sized particles and can be observed by the viewer. This is known as theTyndall effect. In the case of the Tyndall effect, some of the light is scattered since the wavelengths of light in the visible range, about 400 nm to 700 nm, are encountering suspended colloidal sized particles of about the same size. In contrast, if the beam of light were passed through a solution, the observer standing at right angles to the direction of the beam would see no light being reflected from either the solute or solvent formula units that make up the solution because the particles of solute and solvent are so much smaller than the wavelength of the visible light being directed through the solution. • Solutions: molecules ~0.1-2 nm in size • Colloids: molecules ~ 2-1000 nm in size • Suspensions: molecules greater than ~ 1000 nm in size Separation of Mixtures Most substances are naturally found as mixtures, therefore it is up to the chemist to separate them into their natural components. One way to remove a substance is through the physical property of magnetism. For example, separating a mixture of iron and sulfur could be achieved because pieces of iron would be attracted to a magnet placed into the mixture, removing the iron from the remaining sulfur. Filtration is another way to separate mixtures. Through this process, a solid is separated from a liquid by passing through a fine pored barrier such as filter paper. Sand and water can be separated through this process, in which the sand would be trapped behind the filter paper and the water would strain through. Another example of filtration would be separating coffee grounds from the liquid coffee through filter paper. Distillationis another technique to separate mixtures. By boiling a solution of a non-volatile solid disolved in a liquid in a flask, vapor from the lower boiling point solvent can be driven off from the solution by heat, be condensed back into the liquid phase as it comes in contact with cooler surfaces, and be collected in another container. Thus a solution such as this may be separated into its original components, with the solvent collected in a separate flask and the solute left behind in the original distillation flask. An example of a solution being separated through distillation would be the distillation of a solution of copper(II) sulfate in water, in which the water would be boiled away and collected and the copper(II) sulfate would remain behind in the disllation flask.

States of Matter Everything that is familiar to us in our daily lives - from the land we walk on, to the water we drink and the air we breathe - is based upon the states of matter called gases, liquids, and solids.

Solids When the temperature of a liquid is lowered to the freezing point of the substance (for water the freezing point is 0oC), the movement of the particles slows with the spacing between the particles changing until the attractions between the particles lock the particles into a solid form. At the freezing point, the particles are closely packed together and tend to block the motions of each other. The attractions between the particles hold the

particles tightly together so that the entire ensemble of particles takes on a fixed shape. The volume of the solid is constant and the shape of a solid is const

Newton’s Law of Motion Newton's laws of motion are three physical laws that, together, laid the foundation for classical mechanics. They describe the relationship between a body and the forces acting upon it, and its motion in response to those forces.

They have been expressed in several different ways, over nearly three centuries, [1] and can be summarised as follows.

First law:

When viewed in an inertial reference frame, an object either remains at rest or continues to move at a constant velocity, unless acted upon by an external force.[2][3] Second The vector sum of the external forces F on an object is equal to the mass m of that object multiplied by law: the acceleration vectora of the object: F = ma.

Third law: When one body exerts a force on a second body, the second body simultaneously exerts a force equal in magnitude and opposite in direction on the first body.

The three laws of motion were first compiled by Isaac Newton in his Philosophiæ Naturalis Principia Mathematica (Mathematical Principles of Natural Philosophy), first published in 1687.[4] Newton used them to explain and investigate the motion of many physical objects and systems. [5] For example, in the third volume of the text, Newton showed that these laws of motion, combined with his law of universal gravitation, explained Kepler's laws of planetary motion.

Newton’s First Law The first law states that if the net force (the vector sum of all forces acting on an object) is zero, then the velocity of the object is constant. Velocity is a vector quantity which expresses both the object's speed and the direction of its motion; therefore, the statement that the object's velocity is constant is a statement that both its speed and the direction of its motion are constant.

The first law can be stated mathematically as

Consequently, • •

An object that is at rest will stay at rest unless an external force acts upon it.

An object that is in motion will not change its velocity unless an external force acts upon it.

This is known as uniform motion. An object continues to do whatever it happens to be doing unless a force is exerted upon it. If it is at rest, it continues in a state of rest (demonstrated when a tablecloth is skilfully whipped from under dishes on a tabletop and the dishes remain in their initial state of rest). If an object is moving, it continues to move without turning or changing its speed. This is evident in space probes that continually move in outer space. Changes in motion must be imposed against the tendency of an object to retain its state of motion. In the absence of net forces, a moving object tends to move along a straight line path indefinitely.

Newton placed the first law of motion to establish frames of reference for which the other laws are applicable. The first law of motion postulates the existence of at least oneframe of reference called a Newtonian or inertial reference frame, relative to which the motion of a particle not subject to forces is a straight line at a constant speed.[8][12]Newton's first law is often referred to as the law of inertia. Thus, a condition necessary for the uniform motion of a particle relative to an inertial reference frame is that the total net force acting on it is zero. In this sense, the first law can be restated as: In every material universe, the motion of a particle in a preferential reference frame Φ is determined by the action of forces whose total vanished for all times when and only when the velocity of the particle is constant in Φ. That is, a particle initially at rest or in uniform motion in the preferential frame Φ continues in that state unless compelled by forces to change it.[13]

Newton's laws are valid only in an inertial reference frame. Any reference frame that is in uniform motion with respect to an inertial frame is also an inertial frame, i.e. Galilean invariance or the principle of Newtonian relativity Newton’s Seocnd Law The second law states that the net force on an object is equal to the rate of change (that is, the derivative) of its linear momentum p in an inertial reference frame:

The second law can also be stated in terms of an object's acceleration. Since Newton's second law is only valid for constant-mass systems,[16][17][18] mass can be taken outside the differentiation operator by the constant factor rule in differentiation. Thus,

where F is the net force applied, m is the mass of the body, and a is the body's acceleration. Thus, the net force applied to a body produces a proportional acceleration. In other words, if a body is accelerating, then there is a force on it.

Consistent with the first law, the time derivative of the momentum is non-zero when the momentum changes direction, even if there is no change in its magnitude; such is the case with uniform circular motion. The relationship also implies theconservation of momentum: when the net force on the body is zero, the momentum of the body is constant. Any net force is equal to the rate of change of the momentum.

Any mass that is gained or lost by the system will cause a change in momentum that is not the result of an external force. A different equation is necessary for variable-mass systems (see below).

Newton's second law requires modification if the effects of special relativity are to be taken into account, because at high speeds the approximation that momentum is the product of rest mass and velocity is not accurate.

Impulse An impulse J occurs when a force F acts over an interval of time Δt, and it is given by[19][20]

Since force is the time derivative of momentum, it follows that This relation between impulse and momentum is closer to Newton's wording of the second law.

[21]

Impulse is a concept frequently used in the analysis of collisions and impacts. [22] Variable-mass systems Main article: Variable-mass system Variable-mass systems, like a rocket burning fuel and ejecting spent gases, are not closed and cannot be directly treated by making mass a function of time in the second law; [17]that is, the following formula is wrong:[18]

The falsehood of this formula can be seen by noting that it does not respect Galilean invariance: a variable-mass object with F = 0 in one frame will be seen to have F ≠0 in another frame.[16] The correct equation of motion for a body whose mass m varies with time by either ejecting or accreting mass is obtained by applying the second law to the entire, constant-mass system consisting of the body and its ejected/accreted mass; the result is[16]

where u is the velocity of the escaping or incoming mass relative to the body. From this equation one can derive the equation of motion for a varying mass system, for example, the Tsiolkovsky rocket equation. Under some conventions, the quantity u dm/dt on the left-hand side, which represents the advection of momentum, is defined as a force (the force exerted on the body by the changing mass, such as rocket exhaust) and is included in the quantity F. Then, by substituting the definition of acceleration, the equation becomes F = ma.

Newton’s Third Law The third law states that all forces between two objects exist in equal magnitude and opposite direction: if one object A exerts a force FA on a second object B, then Bsimultaneously exerts a force FB on A, and the two forces are equal and opposite: FA = −FB.[24] The third law means that all forces are interactions between different bodies,[25] [26] and thus that there is no such thing as a unidirectional force or a force that acts on only one body. This law is sometimes referred to as the action-reaction law, withFA called the "action" and FB the "reaction". The action and the reaction are simultaneous, and it does not matter which is called the action and which is calledreaction; both forces are part of a single interaction, and neither force exists without the other. [24] The two forces in Newton's third law are of the same type (e.g., if the road exerts a forward frictional force on an accelerating car's tires, then it is also a frictional force that Newton's third law predicts for the tires pushing backward on the road).

From a conceptual standpoint, Newton's third law is seen when a person walks: they push against the floor, and the floor pushes against the person. Similarly, the tires of a car push against the road while the road pushes back on the tires—the tires and road simultaneously push against each other. In swimming, a person interacts with the water, pushing the water backward, while the water simultaneously pushes the person forward—both the person and the water push against each other. The reaction forces account for the motion in these examples. These forces depend on friction; a person or car on ice, for example, may be unable to exert the action force to produce the needed reaction force.

Importance and range of validity Newton's laws were verified by experiment and observation for over 200 years, and they are excellent approximations at the scales and speeds of everyday life. Newton's laws of motion, together with his law of universal gravitation and the mathematical techniques of calculus, provided for the first time a unified quantitative explanation for a wide range of physical phenomena.

These three laws hold to a good approximation for macroscopic objects under everyday conditions. However, Newton's laws (combined with universal gravitation and classical electrodynamics) are inappropriate for use in certain circumstances, most notably at very small scales, very high speeds (in special relativity, the Lorentz factor must be included in the expression for momentum along with rest mass and velocity) or very strong gravitational fields. Therefore, the laws cannot be used to explain phenomena such as conduction of electricity in a semiconductor, optical properties of substances, errors in non-relativistically corrected GPS systems and superconductivity. Explanation of these phenomena requires more sophisticated physical theories, including general relativity and quantum field theory.

In quantum mechanics concepts such as force, momentum, and position are defined by linear operators that operate on the quantum state; at speeds that are much lower than the speed of light, Newton's laws are just as exact for these operators as they are for classical objects. At speeds comparable to the speed of light, the second law holds in the original form F = dp/dt, where F and p are four-vectors.

ant unless deformed by a sufficiently strong external force. (Solids are thus unlike liquids whose particles are slightly less attracted to one another because the particles of a liquid are a bit further apart than those in the corresponding solid form of the same substance.) In a solid the particles remain in a relatively fixed positions but continue to vibrate. The vibrating particles in a solid do not completely stop moving and can slowly move into any voids that exist within the solid.

Liquids When the temperature of a sample increases above the melting point of a solid, that sample can be found in the liquid state of matter. The particles in the liquid state are much closer together than those in the gaseous state, and still have a quite an attraction for each other as is apparent when droplets of liquid form. In this state, the weak attractive forces within the liquid are unable to hold the particles into a mass with a definite shape. Thus a liquid's shape takes on the shape of any particular container that holds it. A liquid has a definite volume but not a definite shape. Compared to to the gaseous state there is less freedom of particle movement in the liquid state since the moving particles frequently are colliding with one another, and slip and slide over one another as a result of the attractive forces that still exist between the particles, and hold the particles of the liquid loosely together.

At a given temperature the volume of the liquid is constant and its volume typically only varies slightly with changes in temperature.

Gases In the gas phase, matter does not have a fixed volume or shape. This occurs because the molecules are widely separated with the spaces between the particles typically around ten times further apart in all three spatial directions, making the gas around 1000 times less dense than the corresponding liquid phase at the same temperature. (A phase is a uniform portion of mater.) As the temperature of a gas is increased, the particles to separate further from each other and move at faster speeds. The particles in a gas move in a rather random and independent fashion, bouncing off each other and the walls of the container. Being so far apart from one another, the particles of a real gas only weakly attract each other such that the gas has no ability to have a shape of its own.

The extremely weak forces acting between the particles in a gas and the greater amount of space for the particles to move in results in almost independent motion of the moving, colliding particles. The particles freely range within any container in which they are put, filling its entire volume with the net result that the sides of the container determine the shape and volume of gas. If the container has an opening, the particles heading in the direction of the opening will escape with the result that the gas as a whole slowly flows out of the container.

Other States of Matter Besides of the three classical states of matter, there are many other states of matter that share characteristics of one more of the classical states of matter. Most of these states of matter can be put into three categories according to the degrees in varying temperature. At room temperature, the states of matters include liquid crystal, amorphous solid, and magnetically ordered states. At low temperatures the states of matter include superconductors, superfluids, and Bose-Einstein condensate state of matter. At high temperatures the states of matter include, plasma and Quark-gluon plasma.

Another direction of research and experimentation is in the search for alternatives to gasoline. Possibilities include methanol, which can be produced from wood, coal, or natural gas; ethanol, an alcohol produced from grain, sugarcane, and other agriculture plants and currently used in some types of U.S. motor fuel (e.g., gasohol and E85, a mixture of 85% ethanol and 15% gasoline); compressed natural gas, which is much less polluting than gasoline and is currently used by a 1.5 million vehicles around the world; and electricity, which if ever practicable would be cheaper and less polluting, especially if derived from solar energy, rather than gasoline.