VRLA-Sealed&NonSpillablebattery
AccordingtoRegulation(EU)No2020/878 AccordingtoRegulation(EC)No1272/2008
Version4.0
Section1Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1Productidentifier:
ProductForm: Article
Productname: VRLA-Sealed&NonSpillablebattery
Productcode: GEL/SLAbattery
UFIcode: N/A
1.2Relevantidentifiedusesofthesubstanceandusesadvisedagainst:
1.2.1Identifieduses: MotorcycleandPowersportstarterbattery.
1.2.2Usesadvisedagainst: Notavailable.
1.3Detailsofthesupplierofthesafetydatasheet:
Supplier: FULBATSAS
Address: 30RuePasteur 92150Suresnes
France
Telephone: (France)+33183624555
1.4EmergencytelephoneNumber:
CHEMTREC(US,Canada&Mexico)0086-1-800-424-9300
CHEMTREC(International)0086-1-703-527-3887
Availableoutsideofficehours?YES
Section2HazardsIdentification
2.1Classificationofthesubstance/mixture:
2.1.1Classification: ThemixtureisclassifiedasfollowingaccordingtoREGULATION(EC)No1272/2008: : Harmfulifswallowed. H302 Harmfulifinhaled. H332 Skincorrosion/irritationCategory1A H314 Causesseriouseyedamage. H318 Reproductivetoxicity,Category1A H360Fd Maycauseharmtobreast-fedchildren H362 Specifictargetorgantoxicity(repeatedexposure)Category1AH372 Hazardoustotheaquaticenvironment-AcuteHazard,Category1H400 Hazardoustotheaquaticenvironment-ChronicHazard,Category1H410 Fulltextofhazardclasses,H-andEUH-statements:seesection16
Productname:VRLA–Sealed&NonSpillablebattery
Issuedate:02/12/2019
Revisiondate:18/04/2023
1/18 Version#:4.0 Revisiondate:18/04/2023.
Nohazardsincaseofanintactbatteryandusingaccordingtheinstructions.Thebatteryshouldnotbeopenedorburned.Exposuretothe ingredientscontainedwithinortheircombustionproductscouldbeharmful.
2.2labelelements:
HazardPictograms:
SignalWord(S): Danger
HazardStatement:
Precautionarystatement:
2.3Otherhazards:
H302+H332-Harmfulifswallowedorifinhaled.
H314-Causessevereskinburnsandeyedamage H360Fd-Maydamagefertility.Suspectedofdamagingtheunbornchild H362-Maycauseharmtobreast-fedchildren
H372-Causesdamagetoorgansthroughprolongedorrepeatedexposure H410-Verytoxictoaquaticlifewithlonglastingeffects
P201-Obtainspecialinstructionsbeforeuse
P202-Donothandleuntilallsafetyprecautionshavebeenreadandunderstood P273-Avoidreleasetotheenvironment
P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection/hearing protection.
P301+P330+P331:IFSWALLOWED:Rinsemouth.DoNOTinducevomiting.
P303+P361+P353:IFONSKIN(orhair):Takeoffimmediatelyallcontaminated clothing.Rinseskinwithwater/shower.
P304+P340:IFINHALED:Removepersontofreshairandkeepcomfortablefor breathing.
P305+P351+P338:IFINEYES:Rinsecautiouslywithwaterforseveralminutes. Removecontactlenses,ifpresentandeasytodo.Continuerinsing
Otherhazardswhichdonotresultinclassification:Leadmaybetoxictoblood,kidneys,centralnervoussystem. Thissubstance/mixturedoesnotmeetthePBTcriteriaofREACHregulation,annexXIII Thissubstance/mixturedoesnotmeetthevPvBcriteriaofREACHregulation,annexXIII ContainsnoendocrinedisruptorandPBT/vPvBsubstances≥0.1%assessedinaccordancewithREACHAnnexXIII
Productname:VRLA–Sealed&NonSpillablebattery
2/18 Version#:4.0
Revisiondate:18/04/2023.
Section3Composition/informationoningredients
Substance/Mixture: Mixture
Ingredient(s):
Name Productidentifier
Lead (CASNo)7439-92-1 (ECno)231-100-4
Leaddioxide
SulfuricAcid
Tin
Calcium
Aluminium
CAS-No.:1309-60-0 ECNo.:215-174-5
CAS-No.:7664-93-9 ECNo.:231-639-5
CAS-No.:7440-31-5 ECNo.:231-141-8
CAS-No.:7440-70-2 ECNo.:231-179-5
CAS-No.:7429-90-5 ECNo.:231-072-3
Name Productidentifier
Lead (CASNo):7439-92-1 (ECno):231-100-4 (REACHno):01-2119458838-20
SulfuricAcid
CAS-No.:7664-93-9 ECNo.:231-639-5
Productname:VRLA–Sealed&NonSpillablebattery
Version#:4.0
Concentration%Classificationaccordingto Regulation(EC)No. 1272/2008[CLP]
56-63%Repr.1A,H360 STOTRE1,H372
AquaticAcute1H400(M=10) AquaticChronic1,H410(M=10)
27-37%AcuteTox.4(Oral),H302 (ATE=500mg/kgbodyweight) AcuteTox.4(Inhalation:vapour), H332Repr.1A,H360STOTRE 2,H373AquaticAcute1,H400
20-27%SkinCorr.1A,H314
0.10-0.25%Notclassified
0.04-0.11%H261
≤0.04%H261 H228
Specificconcentrationlimits
(0.03≤C≤100)Repr.1A,H360D
(5≤C<15)EyeIrrit.2,H319 (5≤C<15)SkinIrrit.2,H315 (15≤C≤100)SkinCorr.1A,H314
Revisiondate:18/04/2023.
Section4Firstaidmeasures
4.1Descriptionoffirstaidmeasures: Inallcasesofdoubt,orwhensymptomspersist,seekmedicalattention.
4.1.1Incaseofinhalation:
SulfuricAcid:Removetofreshairimmediately.Ifbreathingisdifficult,giveoxygen.LeadCompounds:Removefromexposure, gargle,washnoseandlips,consultphysician.
4.1.2Incaseofskincontact:
SulfuricAcid:Flushwithlargeamountsofwaterforatleast15minutes,removeanycontaminatedclothing.Ifirritation developsseekmedicalattention.LeadCompounds:Washwithsoapandwater.
4.1.3Incaseofeyescontact:
SulfuricAcid:Flushimmediatelywithwaterfor15minutes,consultaphysician.LeadCompounds:Flushimmediatelywith waterfor15minutes,consultaphysician.
4.1.4Incaseofingestion:
SulfuricAcid:Donotinducevomiting,consultaphysicianimmediately.LeadCompounds:Consultaphysicianimmediately.
4.2Mostimportantsymptomsandeffects,bothacuteanddelayed:
Causessevereskinburnsandeyedamage.Maydamagefertility.Maydamagetheunbornchild.Maycauseharmtobreast-fedchildren.
AcuteHealthHazards:SulfuricAcid:Severeskinirritation,burns,damagetocorneamaycauseblindness,upperrespiratory irritation.LeadCompounds:Maycauseabdominalpain,nausea,headaches,vomiting,lossofappetite,severecramping,muscular achesandweakness,anddifficultysleeping.Thetoxiceffectsofleadarecumulativeandslowtoappear.Itaffectsthekidneys, reproductiveandcentralnervoussystems.Thesymptomsofleadoverexposurearelistedabove.Exposuretoleadfromabatterymost oftenoccursduringleadreclamationoperationsthroughthebreathingoringestionofleaddustorfumes.
ChronicHealthHazards:Sulfuricacid:Possiblescarringofthecornea,inflammationofthenose,throatandbronchialtubes, possibleerosionoftoothenamel.LeadCompounds:Maycauseanemia,damagetokidneysandnervoussystem,anddamageto reproductivesysteminbothmalesandfemales.
MedicalConditionsGenerallyAggravatedbyExposure:Inorganicleadanditscompoundscanaggravatechronicformsofkidney,liver, andneurologicaldiseases.Contactofbatteryelectrolyte(acid)withtheskinmayaggravateskindiseasessuchaseczemaandcontact dermatitis.Overexposuretosulfuricacidmistmaycauselungdamageandaggravatepulmonaryconditions.
4.3Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded: Nofurtherrelevantinformationavailable.
Section5Fire-Fightingmeasures
5.1Extinguishingmedia:
Suitableextinguishingmedia: Useextinguishingmediaappropriateforsurroundingfire-lfabatteryruptures,usedry chemical,sodaash,lime,sandorcarbondioxide.
Unsuitableextinguishingmedia:NoneKnown.
5.2SpecialhazardsarisingfromtheSealedbatteriescanemithydrogenonlyifovercharged(floatvoltage>2.41VPC). substanceormixture Thegasenterstheairthroughtheventcaps.ToABS:Temperaturesover300°C
5.3Adviceforfirefighters:
Section6Accidentalreleasemeasures
GeneralMeasures:
6.1.1Fornon-emergencypersonnel:
6.1.2Foremergencyresponders:
(572°F)mayreleasecombustiblegases.ToPP:Temperaturesover380°C(716°F) mayreleasecombustiblegases.
Leadcompoundsandsulfuricacidfumemaybereleasedduringafireinvolvingthe product.Batterymayruptureduetopressurebuildupwhenexposedtoexcessive heatandmayberesultinthereleaseofcorrosivematerials.
Mayreactwithcombustiblesubstancescreatingfireorexplosionhazard.Reacts violentlywithwater.Reactsviolentlywithoxidizingsubstances.Reactswithmost metalstoproducehydrogengas,lvhichcanformanexplosivemixturewithair.
Wearpositivepressureself-containedbreathingapparatus.Wearfullyprotective suit.
Avoidcontactwithspilledmaterial.Donottouchdamagedcontainersorspilled materialunlesswearingappropriateprotectiveequipment.
UseproperpersonalprotectiveequipmentasindicatedinSection8.Ensureadequate ventilation.Avoidcontactwitheyes.Wearprotectiveequipment.Keepunprotected personsaway.
Wearpositivepressureself-containedbreathingapparatusifdustisgenerated.
Donotallowproducttoreachsewagesystemoranywatercourse.Inform respectiveauthoritiesincaseofseepageintowatercourseorsewagesystem.Do notallowtoentersewers/surfaceorgroundwater.
Incasethereleaseoccurs,stopflowofmaterial:contain/absorbsmallspillswithdry sand,earth,andvermiculite.Ifpossible,carefullyneutralizespilledelectrolytewithsoda ash,sodiumbicarbonate,lime,etc.Wearacid-resistantclothing,boots,gloves,and faceshield.Donotallowdischargeofunneutralizedacidtosewer.SpentBatteriessendtosecondaryleadsmelterforrecycling.Followapplicablefederal,stateandlocal regulationsNeutralizeasinprecedingstep.Collectneutralizedmaterialinsealed containerandhandleashazardouswasteasapplicable. 6.4Referencetoothersections:
SeeSection7forinformationonsafehandling.
SeeSection8forinformationonpersonalprotectionequipment.
SeeSection13forinformationondisposal.
Productname:VRLA–Sealed&NonSpillablebattery
5/18 Version#:4.0 Revisiondate:18/04/2023.
Section7Handlingandstorage
7.1Precautionsforsafehandling:
7.1.1Protectivemeasures:
7.1.2Adviceongeneraloccupational
Ensuregoodventilation/exhaustionattheworkplace.Avoidcontactwitheyes.Keep ignitionsourcesaway-Donotsmoke.Duetothebattery’slowinternalresistanceand highpowerdensity,highlevelsofshortcircuitcurrentcanbedevelopedacrossthe batteryterminals.Donotresttoolsorcablesonthebattery.Useinsulatedtoolsonly. Followallinstallationinstructionsanddiagramswheninstallingormaintainingbattery systems.
Donoteat,drinkandsmokeinworkareas.Washhandsafteruse.Remove hygiene: contaminatedclothingandprotectiveequipmentbeforeenteringeatingareas.
7.2Conditionsforsafestorage,including anyincompatibilities:
Storebatteriesinacool,dry,wellventilatedareathatareseparatedfromincompatible materialsandanyactivitieswhichmaygenerateflames,sparks,orheat.Keepaway fromallmetallicarticlesthatcouldcontactthenegativeandpositiveterminalsona batteryandcreateashortcircuitcondition.Batteryshouldbestoredunderrooffor protectionagainstadverseweatherconditions.Storeandhandleonlyinareaswith adequatewatersupplyandspillcontrol.Avoiddamagetobatterycase.
7.3Specificenduse(s): Notapplicable.
Section8ExposureControls/PersonalProtection
8.1Controlparameters:
Lead(7439-92-1)
EUEuropeanBEI
AustriaMAK(mg/m3)
(Medium:blood-Time:norestriction-Parameter:
Lead(bindingbiologicallimitvalue)
0.075mg/m3(Medium:air-Time:40hoursperweek Parameter:Lead(TWAmedicalsurveillancethresholdinair measuredasatimeweightedaverageover40hoursperweek)
(Medium:blood-Time:norestriction–Parameter:Lead (medicalsurveillancethresholdmeasuredinindividualworkers)
0.1mg/m3(inhalablefraction)
AustriaMAKShorttimevalue(mg/m3)0.4mg/m3(inhalablefraction)
BulgariaOELTWA(mg/m3)
BulgariaBulgaria-BEI
Lead(7439-92-1)
0.05mg/m3
300µg/l(Medium:blood-Time:notlixed-Parameter:Lead (forwomenunder45yearsold)
400µg/l(Medium:blood-Time:notfixed-Parameter:Lead)
CroatiaGVI(graniënavrijednostizloZenosti)(mg/m3)0.15mg/m3
Productname:VRLA–Sealed&NonSpillablebattery
6/18 Version#:4.0 Revisiondate:18/04/2023.
Lead(7439-92-1)
CroatiaCroatia-BEI
CyprusOELTWA(mg/m3)
(Medium:blood-Time:notcritical-Parameter:Lead(Medical surveillanceshouldbecarriedoutlvhenthelimitvalueofLead inbloodofworkers>40µg/100mLblood)
(Medium:urine-Time:singlesampleorurinecollectedover 24hours-Parameter:Lead(Forallresultsthatareexpressed onCreatinine,Creatinineconcentration<0.5g/Land>3.0g/L shouldnotbeconsidered)
(Medium:blood-Time:notcritical-Parameter: delta.Aminolevulinicaciddehydratase)
(Medium:blood-Time:afterexposureduring2-3months(light protectedsample)-Parameter:
Protoporphyrininerythrocytes(lnterferenceoflrondeficiency (anemiasideropenic))
0.15mg/m3
CzechRepublicExpoziënilimity(PEL)(mg/m3)0.05mg/m3
(Medium:urine-Time:discretionary-Parameter:5 Aminolevulinicacid(Forshorttermcontinualexposures<=30 calendardays)
(Medium:urine-Time:discretionary-Parameter: Coproporphyrin(Forshorttermcontinualexposures<=30 calendardays)
CzechRepublicCzechRepublic-BEI
(Medium:urine-Time:discretionary-Parameter:5 Aminolevulinicacid(Forshorttermcontinualexposures<=30 calendardays)
(Medium:urine-Time:discretionary-Parameter: Coproporphyrin(Forshorttermcontinualexposures<=30 calendardays)
0.4mg/l(Medium:blood-Time:discretionary-Parameter: Lead)
DenmarkGrænseværdie(langvarig)(mg/m3)0.05mg/m3(dust,fumeandpowder)
DenmarkDenmark-BEI
EstoniaOELTWA(mg/m3)
FinlandHTP-arvo(8h)(mg/m3)
FinlandFinland-BEI
FranceVME(mg/m3)
FranceFrance-BEI
(Medium:blood-Parameter:Lead)
0.1mg/m3(totaldust)
0.05mg/m3(respirabledust)
0.1mg/m3(allworks)
(Medium:blood-Time:notcritical-Parameter:Lead)
0.1mg/m3(restrictivelimit)
400µg/l(Medium:blood-Parameter:Lead(biologicallimit value,men)
300µg/l(Medium:blood-Parameter:Lead(biologicallimit value,women)
200µg/l(Medium:blood-Parameter:Lead(medical surveillancevalue,men)
100µg/l(Medium:blood-Parameter:Lead(medical surveillancevalue,women)
Productname:VRLA–Sealed&NonSpillablebattery
7/18 Version#:4.0 Revisiondate:18/04/2023.
Lead(7439-92-1)
GermanyTRGS903(BGW)
GibraltarOELTWA(mg/m3)
GibraltarGibraltar-BEI
GreeceOELTWA(mg/m3)
HungaryAK-érték
lrelandOEL(8hoursref)(mg/m3)
lrelandOEL(15minref)(mg/m3)
ItalyOELTWA(mg/m3)
ItalyItaly-BEI
LatviaOELTWA(mg/m3)
LatviaLatvia-BEI
LithuaniaIPRV(mg/m3)
LuxembourgOELTWA(mg/m3)
LuxembourgLuxembourg-BEI
PolandNDS(mg/m3)
Productname:VRLA–Sealed&NonSpillablebattery
Revisiondate:18/04/2023.
300µg/l(Medium:wholeblood-Time:norestriction Parameter:Lead(womenagebelow45years)
400µg/l(Medium:wholeblood-Time:norestriction Parameter:Lead(women45yearsandolder)
0.15mg/m3
(Medium:blood-Time:norestriction-Parameter:Lead(binding biologicallimitvalue)
0.075mg/m3(Medium:air-Time:40hoursperweek Parameter:Lead(medicalsurveillancethresholdmeasuredin individualemployees)
(Medium:blood-Time:norestriction-Parameter:Lead(medical surveillancethresholdmeasuredinindividualemployees)
0.15mg/m3
0.15mg/m3
0.15mg/m3
0.45mg/m3(calculated)
0.075mg/m3
(Medium:blood-Time:endofworkweek(Leadremediationmust beperformedwhenuorkersoffertileagehaveLeadinblood levels>40µg/100mL)
0.005mg/m3
(Medium:blood-Parameter:Lead(referencevalueinbloodfor occupationallyunexposedpopulation<=10µg/100mL)
(Medium:urine-Parameter:Coproporphyrin(referencevalue 22-57µg/gCreatinine)
(Medium:urine-Parameter:Aminolevulinicacid(reference value0.5-2.5mg/gCreatinine)
0.15mg/m3(inhalablefraction)
0.07mg/m3(respirablefraction)
0.15mg/m3
(Medium:blood-Parameter:Lead)0.075mg/m3
(Medium:blood-Parameter:Lead(medicalsurveillance thresholdinairmeasuredasatimeweightedaverageover40 hoursperweek)
(Medium:blood-Parameter:Lead(medicalsurveillance thresholdmeasuredinindividualworkers)
0.05mg/m3
Lead(7439-92-1)
PortugalOELTWA(mg/m3)
RomaniaOELTWA(mg/m3)
RomaniaOELSTEL(mg/m3)
RomaniaRomania-BEI
0.15mg/m3(mandatoryindicativelimitvalue)
0.05mg/m3
0.10mg/m3
150µg/l(Medium:urine-Time:endofshift-Parameter:Lead) (Medium:blood-Time:endofshift-Parameter:Lead)
(Medium:hair-Time:endofshift-Parameter:Lead)10mg/l (Medium:urine-Time:endofshift-Parameter:.delta.Aminolevulinicacid)
300µg/l(Medium:urine-Time:endofshift-Parameter: Coproporphyrin)
(Medium:blood-Time:endofshift-Parameter::Erythrocytes protoporphyrin)
SlovakiaNPHV(priemerna)(mg/m3)0.15mg/m3
400µg/l(Medium:blood-Time:notcritical-Parameter:Lead)
100µg/l(Medium:blood-Time:notcritical-Parameter:Lead (womenyoungerthan45yearsofage)
SlovakiaSlovakia-BEI
SloveniaOELTWA(mg/m3)
SloveniaOELSTEL(mg/m3)
SpainVLA-ED(mg/m3)
15mg/l(Medium:urine-Time:notcritical-Parameter:.delta.Aminolevulinicacid)
6mg/l(Medium:urine-Time:notcritical-Parameter:.delta.Aminolevulinicacid(womenyoungerthan45yearsofage)
0.30mg/l(Medium:urine-Time:nctcriticalParameter: Coproporphyrins)
0.1mg/m3(inhalablefraction)
0.4mg/m3(inhalablefraction)
0.15mg/m3
Spain (Medium:blood-Time:notcritical-Parameter:Lead(3,K)
Swedennivagränsvärde(NVG)(mg/m3)0.1mg/m3(totalinhalabledust)
UnitedKingdomWELTWA(mg/m3)
UnitedKingdomWELSTEL(mg/m3)
0.05mg/m3(totalrespirabledust)
0.15mg/m3
0.45mg/m3(calculated)
NorwayGrenseverdier(AN)(mg/m3)0.05mg/m3(dustandfume)
NorwayGrenseverdier(Korttidsverdi)(mg/m3)0.05mg/m3(dustandfume)
SwitzerlandVME(mg/m3)
SwitzerlandVLE(mg/m3)
SwitzerlandSwitzerland-BEI
Productname:VRLA–Sealed&NonSpillablebattery
0.1mg/m3(inhalabledust)
0.8mg/m3(inhalabledust)
400µg/l(Medium:wholeblood-Time:norestrictionsParameter:Lead (menandwomenover45yearsold)
100µg/l(Medium:wholeblood-Time:norestrictions Parameter:Lead(womenlessthan45yearsold,)
9/18 Version#:4.0
Revisiondate:18/04/2023.
AustraliaTWA(mg/m3)
Canada(Quebec)VEMP(mg/m3)
USA-ACGIHACGIHTWA(mg/m3)
Lead(7439-92-1)
0.15mg/m3(dustandfume)
0.05mg/m3
0.05mg/m3
USA-IDLHUSIDLH(mg/m3 100mg/m3
USA-NIOSHNIOSHREL(TWA)(mg/m3)0.050mg/m3
USA-OSHAOSHAPEL(TWA)(mg/m3)50µg/m3
Sulfuricacid(7664-93-9)
BulgariaOELTWA(mg/m3)
0.05mg/m3(whenchoosingasuitablemethodformonitoring exposureshouldtakeintoaccountpotentialconstraintsand interactionsthatmayoccurinthepresenceofothersulfur compounds-respirableaerosol)
CroatiaGVI(graniČnavrijednostizlozenosti)(mg/m3)0.05mg/m3
CyprusOELTWA(mg/m3)
0.05mg/m3(vapor)
CzechRepublicExpoziČnilimity(PEL)(mg/m3)1mg/m3
0.05mg/m3(concentrated-mist)
DenmarkGrænseværdie(langvarig)(mg/m3)0.05mg/m3(thoracicfraction-mist)
EstoniaOELTWA(mg/m3) 1mg/m3(fume)
FinlandHTP-arvo(8h)(mg/m3)
FinlandHTP-arvo(15min)
FranceVME(mg/m3)
0.05mg/m3
0.1mg/m3
0.05mg/m3(thoracicfraction)
FranceVLE(mg/m3) 3mg/m3
GermanyTRGS900Occupationalexposurelimitvalue(mg/m3)
GibraltarOELTWA(mg/m3)
GreeceOELTWA(mg/m3)
0.1mg/m3(Theriskofdamagetotheembryoorfetuscanbe excludedwienAGWandBGWvaluesareobserved-inhalable fraction)
0.05mg/m3(whenselectinganappropriateexposuremonitoring method,accountshouldbetakenofpotentiallimitationsand interferencesthatmayariseinthepresenceofothersulphur compounds-thoracicfraction)
0.05mg/m3(mist)
HungaryAK-érték 0.05mg/m3
lrelandOEL(8hoursref)(ppm) 0.05ppm
lrelandOEL(15minref)(ppm) 0.15ppm(calculated)
Productname:VRLA–Sealed&NonSpillablebattery SDSEU 10/18 Version#:4.0
Revisiondate:18/04/2023.
ItalyOELTWA(mg/m3)
LatviaOELTWA(mg/m3)
LithuaniaIPRV(mg/m3)
LithuanraTPRV(mg/m3)
LuxembourgOELTWA(mg/m3)
MaltaOELTWA(mg/m3)
0.05mg/m3(Whenchoosingasuitablemethodformonitoring exposureshouldtakeintoaccountpotentialconstraintsand interactionsthatmayoccurinthepresenceofothersulfur compounds,respirablefraction-thoracicfraction,mist)
0.05mg/m3(possiblelimitationsandtheimpactthatmayresult fromthepresenceofotherSulfurcomponentsshouldbetakeninto accountwhenchoosinganappropriateexposuremonitoring method-fog,whichisdefinedasthethoracicfraction)
0.05mg/m3(vapor)
3mg/m3(fog-vapor)
0.05mg/m3
0.05mg/m3(mist)
NetherlandsGrenswaardeTGG8H(mg/m3)0.05mg/m3(definedasthoracicfraction-mist)
PolandNDS(mg/m3)
PortugalOELTWA(mg/m3)
RomaniaOELTWA(mg/m3)
SlovakiaNPHV(priemerná)(mg/m3)
SloveniaOELTWA(mg/m3)
SpainVLA-ED(mg/m3)
0.05mg/m3(thoracicfraction)
0.05mg/m3(thoracicfraction-mist)
0.05mg/m3
0.1mg/m3
0.05mg/m3(inhalablefraction,fog)
0.05mg/m3(indicativelimitvalue-mist)
Swedennivågränsvärde(NVG)(mg/m3)0.1mg/m3
Swedenkortidsvärde(KTV)(mg/m3)0.2mg/m3
UnitedKingdomWELTWA(mg/m3)
0.05mg/m3(mist)
NorwayGrenseverdier(AN)(mg/m3)0.1mg/m3(inhalablefraction)
NorwayGrenseverdier(Korttidsverdi)(mg/m3)0.1mg/m5(inhalablefraction)
SwitzerlandVME(mg/m3)
SwitzerlandVLE(mg/m3)
0.1mg/m3(inhalabledust)
0.1mg/m3(inhalabledust)
AustraliaTWA(mg/m3) 1mg/m3
AustraliaSTEL(mg/m3) 3mg/m3
Canada(Quebec;VECD(mg/m3) 3mg/m3
Canada(Quebec)VEMP(mg/m3) 1mg/m3
USA.ACGIHACGIHTWA(mg/m3) 0.2mg/m3(thoracicfraction)
USA–IDLHUSIDLH(mg/m3) 15mg/m3
USA–NIOSHNIOSHREL(TWA)(mg/m3)1mg/m3
USA.OSHAOSHAPEL(TWA)(mg/m3)1mg/m3
Productname:VRLA–Sealed&NonSpillablebattery
11/18 Version#:4.0
Revisiondate:18/04/2023.
8.2Exposurecontrols:
8.2.1Appropriateengineeringcontrols:Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Washhands beforebreaksandattheendofworkday.
8.2.2Individualprotectionmeasures,suchaspersonalprotectiveequipment:
Eye/faceprotection: Noneneededundernormalconditions.Ifbatterycaseisdamaged,usechemical gogglesorfaceshield.
Handprotection: Noneneededundernormalconditions.Ifbatterycaseisdamaged,userubberor plasticacid-resistantgloveswithelbow-lengthgauntlet.
Bodyprotection: Noneneededundernormalconditions.Ifbatterycaseisdamagedwearacid-resistant apron.Undersevereexposureoremergencyconditions,wearacid –resistantclothingandboots.
Respiratoryprotection: Nonerequiredundernormalconditions.Whenconcentrationsofsulfuricacidmist areknowntoexceedPEL,useNIOSHorMSHA-approvedrespiratoryprotection.
Thermalhazards: Wearsuitableprotectiveclothingtopreventheat.
8.2.3Environmentalexposurecontrols:Donotallowproducttoreachsewagesystemoranywatercourse.Informrespective authoritiesincaseofseepageintowatercourseorsewagesystem.Donotallowto entersewers/surfaceorgroundwater.
Section9Physicalandchemicalproperties
9.1Informationonbasicphysicalandchemicalproperties:
Physicalstate: Solid
Colour: Black
Odour: Notavailable
Odourthreshold: Notavailable
pH: Notavailable
Meltingpoint/range(°C): -33.67°C(CAS#7664-93-9)
Boilingpoint/range(°C): Notavailable
Flashpoint(°C): Notavailable
Evaporationrate: Notavailable
Flammabilitylimit-lower(%): Notavailable
Flammability(solid,gas): Notavailable
Ignitiontemperature(°C): Notavailable
Productname:VRLA–Sealed&NonSpillablebattery
12/18 Version#:4.0 Revisiondate:18/04/2023.
Upper/lowerexplosivelimits: Notavailable
Vapourpressure(20°C): 0.485hPa(CAS#7664-93-9)
Vapourdensity: Notavailable
RelativeDensity: 1.81(20°C)(CAS#7664-93-9)
Bulkdensity(kg/m3): Notavailable
Watersolubility(g/l): Notavailable
n-Octanol/Water(logPo/w): Notavailable
Auto-ignitiontemperature: Notavailable
Decompositiontemperature: Notavailable
Viscosity,dynamic(mPa.s): Notavailable
Explosiveproperties: Notavailable
Oxidisingproperties: Notavailable
9.2.Otherinformation:
Fatsolubility(solvent-oiltobespecified) etc: Notavailable
Surfacetension: Notavailable
Dissociationconstantinwater(pKa):Notavailable
Oxidation-reductionPotential: Notavailable
Section10Stabilityandreactivity
10.1Reactivity: Thesubstanceisstableundernormalstorageandhandlingconditions.
10.2Chemicalstability: Stableatroomtemperatureinclosedcontainersundernormalstorageandhandling conditions.
10.3Possibilityofhazardousreactions:Nodangerousreactionsknown.
10.4Conditionstoavoid: Incompatiblematerials.Hightemperature,Sparksandothersourcesofignition. Avoidmixingacidwithotherchemicals.
10.5Incompatiblematerials: Potassium,carbides,sulfides,peroxides,phosphorus,sulfurs,ketone,ester, petrolatum.Reactivemetals,strongbases,mostorganiccompounds.
10.6Hazardousdecompositionproducts:Sealedbatteriescanemithydrogenonlyifovercharged(floatvoltage>2.41VPC). Thegasenterstheairthroughtheventcaps.ToABS:Temperaturesover300°C(572°F) mayreleasecombustiblegases.ToPP:Temperaturesover380°C(716°F)mayrelease combustiblegases.
Section11Toxicologicalinformation
11.1InformationonhazardclassesasdefinedinRegulation(EC)No1272/2008: Acutetoxicity: ATEmix(oral): Harmfulifswallowed
Productname:VRLA–Sealed&NonSpillablebattery
13/18 Version#:4.0 Revisiondate:18/04/2023.
ATEmix(inhalation): Harmfulifinhaled.
ATEmix(Dermal): Notavailable
Sulphuricacid(CAS#7664-93-9)
LD50(Oral,Rat): 2140mg/kg
LC50(Inhalation,Rat): Notavailable
LD50(Dermal,Rabbit): Notavailable
Skincorrosion/Irritation: Causessevereskinburnsandeyedamage.
Seriouseyedamage/irritation: Causesseriouseyedamage.
Respiratoryorskinsensitization: Notclassified
Germcellmutagenicity: Notclassified
Carcinogenicity: Notclassified
Reproductivetoxicity: Notclassified
STOT-singleexposure: Notclassified
STOT-repeatedexposure: Notclassified
Aspirationhazard: Notclassified
11.2Informationonotherhazards
Endocrinedisruptingproperties
Themixturedoesnotcontainendocrinedisruptor.
Otherinformation Notapplicable
Section12Ecologicalinformation
12.1Toxicity:
Lead(CAS:7439-92-1):
AcutetoxicityTimeSpeciesEvaluationRemarks
LC50440µg/L96hFishN/A
Species:Cyprinuscarpio[semi-static])
LC501170µg/L96hFishN/ASpecies:Oncorhynchusmykiss[flow{hroughl)
EC50600µg/L48hDaphniaN/A Species:waterflea
SulfuricAcid(CAS:7664-93-9):
AcutetoxicityTimeSpeciesEvaluationRemarks
LC5082mg/L24hFishN/A Exposuretime:24h-Species:Brachydaniorerio[static]
12.2Persistenceanddegradability:Notavailable.
12.3Bioaccumulativepotential:BCFfish;nobioaccumalion
12.4Mobilityinsoil: Notavailable.
12.5ResultsofPBT&vPvBassessment:Notapplicable
12.6Otheradverseeffects: Notavailable.
Productname:VRLA–Sealed&NonSpillablebattery SDSEU 14/18 Version#:4.0 Revisiondate:18/04/2023.
Section13Disposalconsiderations
13.1Wastetreatmentmethods:
Mustnotbedisposedtogetherwithhouseholdgarbage.Donotallowproductto reachsewagesystem.
Disposeofcontents/containertocomplywithapplicablelocal,nationaland internationalregulations.
Recyclingtheproductisrecommended.Wastemustbedisposedofinaccordance withfederal,stale,andlocalenvironmentalcontrolregulations.
Consulttheappropriatelocalwastedisposalexpertaboutwastedisposal.Since emptiedcontainersretainproductresidue,followlabelwarningsevenaftercontainer isemptied.
Europeenwastecode:160601--leadbatteries
Section14Transportinformation
14.1UNnumberorID number
14.2UNPropershipping name BATTERIES, WET,NONSPILLABLE ELECTRIC STORAGE BATTERIES, WET,NONSPILLABLE ELECTRICSTORAGE
BATTERIES, WET,NONSPILLABLE ELECTRICSTORAGE
BATTERIES, WET,NONSPILLABLE ELECTRICSTORAGE
14.3Transporthazard Class(es) NotregulatedNotregulatedNotregulatedNotregulated 14.4PackinggroupNotregulatedNotregulatedNotregulatedNotregulated
14.5Environmental hazards YesYesYesYes
14.6Specialprecautions foruser SeebelowSeebelowSeebelowSeebelow
14.7Maritimetransportin bulkaccordingtoIMO instruments NotregulatedNotregulatedNotregulatedNotregulated
14.6Specialprecautionsforuser
Landtransport(ADR)
Classificationcode(ADR) :C11
Specialprovisions(ADR) :238,295,598
Limitedquantities(ADR) :1L
Exceptedquantities(ADR) :E0
Packinginstructions(ADR) :P003,P801
Specialpackingprovisions(ADR):PP16
Transportcategory(ADR) :3
Specialprovisionsforcarriage-Bulk(ADR):VV14
Hazardidentificationnumber(KemlerNo.):80 Orangeplates :
Productname:VRLA–Sealed&NonSpillablebattery
15/18 Version#:4.0 Revisiondate:18/04/2023.
Tunnelrestrictioncode(ADR)E EACcode 2R
Seatransport(IMDG)
Specialprovisions(IMDG) :238,295
Limitedquantities(IMDG) :1L
Exceptedquantities(IMDG) :E0
Packinginstructions(IMDG) :P003
Specialpackingprovisions(IMDG):PP16
EmS-No.(Fire :F-A
EmS-No.(Spillage) :S-B
Stowagecategory(IMDG) :A
Propertiesandobservations(IMDG):Metalplatesimmersedingelledalkalineoracidelectrolyteinaglass,hardrubber orplasticsreceptacleofanon-spillabletype.Whenelectricallycharged,maycause firethroughshort-circuitingofterminals.Causeburnstoskin,eyesandmucous membranes.
MFAG-No :154
Airtransport
PCAExceptedquantities(IATA):E0
PCALimitedquantities(IATA):Forbidden PCAlimitedquantitymaxnetquantity(IATA):Forbidden PCApackinginstructions(IATA):872
PCAmaxnetquantity(IATA):Nolimit
CAOpackinginstructions(IATA):872
CAOmaxnetquantity(IATA):Nolimit
Specialprovisions(IATA) :A48,A67,A164,A183
ERGcode(IATA) :8L
Section15Regulationinformation
15.1Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture:
REACHAnnexXVII(RestrictionList):Notapplicable.
REACHAnnexXIV(AuthorisationList):Notapplicable.
REACHCandidateList(SVHC):Containsonesubstance(s)fromthelistofcandidatesubstancesofREACH:Lead(EC231-100-4,CAS 7439-92-1)
OtherNationalregulations:
Noadditionalinformationavailable
15.2ChemicalSafetyAssessment
Noadditionalinformationavailable
Productname:VRLA–Sealed&NonSpillablebattery
16/18 Version#:4.0 Revisiondate:18/04/2023.
Section16Otherinformation
16.1Indicationofchanges: Version4.0Amendedby(EU)2020/878
16.2Abbreviationsandacronyms:
ADR:EuropeanAgreementconcerningtheInternationalCarriageofDangerousGoodsbyRoad
RID:RegulationforrailInternationaltransportationofDangerousgoods
ADN:EuropeanAgreementconcerningtheInternationalCarriageofDangerousGoodsbyInlandWaterways
IMDG:Codeinternationalmaritimedangerousgoodscode
ICAO:InternationalCivilAviationOrganization
IATA:InternationalAirTransportAssociation
UFI:UniqueFormulaIdentifier
LC50:medianlethalconcentration
EC50:Theeffectiveconcentrationofsubstancethatcauses50%ofthemaximumresponse.
NOEC:NoObservedEffectConcentration
DNEL:derivedno-effectlevel
PNEC:predictedno-effectconcentration
16.3Keyliteraturereferencesandsourcesfordata ECHARegisteredsubstancesdata
16.4Traininginstructions: Notapplicable.
16.5Furtherinformation: Thisinformationisbaseduponthepresentstateofourknowledge.ThisSDShasbeencompiledandissolelyintendedforthis product.
16.6Noticetoreader:
Employersshouldusethisinformationonlyasasupplementtootherinformationgatheredbythem,andshouldmakeindependent judgmentofsuitabilityofthisinformationtoensureproperuseandprotectthehealthandsafetyofemployees.
FulltextofH-andEUH-statements:
AcuteTox.4(Inhalation)
AcuteTox.4(Inhalation:dust,mist)
AcuteTox.4(Inhalation:vapour)
AcuteTox.4(Oral)
AquaticAcute1
AquaticChronic1
AquaticChronic3
Acutetoxicity(inhal.),Category4
Acutetoxicity(inhalation:dust,mist)Category4
Acutetoxicity(inhalation:vapour)Category4
Acutetoxicity(oral),Category4
Hazardoustotheaquaticenvironment–AcuteHazard,Category1
Hazardoustotheaquaticenvironment–ChronicHazard,Category1
Hazardoustotheaquaticenvironment–ChronicHazard,Category3
Carc.2 Carcinogenicity,Category2
EyeDam.1
Seriouseyedamage/eyeirritation,Category1
H302 Harmfulifswallowed.
H314
Causessevereskinburnsandeyedamage.
H315 Causesskinirritation
H318
Causesseriouseyedamage.
H319 Causesseriouseyeirritation
H332 Harmfulifinhaled.
H351 Suspectedofcausingcancer.
H360 Maydamagefertilityortheunbornchild.
H360DMaydamagetheunbornchild.
H360FD Maydamagefertility.Maydamagetheunbornchild.
H362 Maycauseharmtobreast-fedchildren.
H372 Causesdamagetoorgansthroughprolongedorrepeatedexposure.
H373 Maycausedamagetoorgansthroughprolongedorrepeated exposure.
H400 Verytoxictoaquaticlife.
H410Verytoxictoaquaticlifewithlonglastingeffects.
H412
Productname:VRLA–Sealed&NonSpillablebattery
Harmfultoaquaticlifewithlonglastingeffects.
17/18 Version#:4.0 Revisiondate:18/04/2023.
Thisinformationisfurnishedwithoutwarranty,andanyuseoftheproductnotinconformancewiththisSafetyDataSheet,orin combinationwithanyotherproductorprocess,istheresponsibilityoftheuser.
Productname:VRLA–Sealed&NonSpillablebattery
Version#:4.0
Revisiondate:18/04/2023.