GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
ENERGETICOS VERSIÓN 1.0 2018-2019
PERFIL DE LA EMPRESA
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
CONFIDENCIAL
Company Profile
Fuel Enterprises, Inc. Fuel and Oil Distribution / Trader with National and International Reach
Company Profile
Basic Information Fuel Enterprises is a premier Fuel and Oil Supply Distribution / Trading company with National and International Reach.
History • Fuel Enterprises, Inc. Established in 2014 as Part of Bonima Corporations’ Expansion into the Commercial Fuel and Oil Supply Distribution. • Bonima Corporation Established in 1998 (Multi-Branded Retail Gas Station Chain). • Florida, USA Based Company • Corporate Office in Doral, Florida, USA.
Company Profile
Our Merits • Unique and Creative Solutions that Meet Clients’ Expectations • Consulting Approaches to Clients’ Special Needs in Order to Find Tailored Fuel and Oil Supply and Management Tool solutions. • Team Work Based on the Implementation of Progressive Fuel and Oil Supply Chain Management. • Professional Quality of Services Provided by Highly Motivated Staff.
Our Strengths Financial Stability – Financially Stalwart with an Outstanding Credit History and Significant Purchasing Capacities. Business Relationships – Outstanding Business Relations with Major, Midmajor, and Independent Fuel Terminals and Refiners to Provide unmatched fuel access at highly competitive prices all under one intergrated supply roof. National Reach – Hundreds of Trucks and Third Party Partners Serving Nationwide. International Reach – Strategic Partnerships Serving Worldwide.
Company Profile
What We Do Fuel Distribution • • • • • • •
Wholesale Delivery to Gas Stations Commercial Transport Deliveries Mobile/ Fleet Refueling Bulk Tank Refueling Oil Field Services Green Fuels- Ethanol & Bio- Diesel JP-54
Markets Served • Commercial Business • Export
Fuel Supply Chain Management • • • • •
Supply optionality – Spot, Indexed Contracts, and Fixed Price Solutions Single Source for Purchasing, logistics & Invoicing Inventory & Transaction Management Risk Management Mitigate Supply & Price Volatility
Markets Served • Regional Wholesalers • National Accounts • International Accounts
Company Profile
How We Define Our Relationships “Fuel Enterprises Core Values” Passion – we love what we do and always give 100% Pride & Image – we deliver “best in class” services, facilities, equipment, and processes. Customer Focus – we exist to serve our customers and exceed their expectations. Solution Driven – we will never compromise integrity or neglect promises.
Major and Mid-Major Strategic Partnerships Atlas Oil BP Citgo Colonial Oil Exxon Mobil Fleet Card O’Rourke Petroleum Port Consolidated
Company Profile
Key Client Relationship Portfolio Banking and Finance Continental National Bank
Healthcare Baptist Hospital
Construction C&C Concrete South Florida Concrete
Transportation / Logistics Fed-Ex American Ambulance Down Town Towing
Landscaping Dixie Landscape Sunshine State Biomass of Florida
Retail Gas Stations S&B Unbranded Gas Station Florida Turnpike Service Gas Station Plazas FX Gas Station
Corporate Aviation 100+ Independent Fixed Based Operators Nationwide and Worldwide
Engineers Gonzalez & Sons
Company Profile
Leadership Team Ricardo Echeverria Co-Founder / President
Ricardo has an Engineering degree in Process Control/Informatik from Fachhochschule Konstanz Germany and postgraduate Management Studies Arthur D. Little in Boston USA. He was hired by Reynolds Aluminum and started as Process Control Engineer for Venalum, an Aluminum Smelter (420,000 MT/year - 4,500 employees) in Puerto Ordaz Venezuela. During 21 years in the Aluminum Industry he was: Division Head for Process Control, Manager of System Information, General Plant Manager, General Construction Manager for the Aluminum Expansion Project ($750 million dollars -Quinta Linea), Vice-President and the first Executive Member of the Board. President of Interalumina a Alumina Refinery with a capacity of 2.5 million MT/year and 3,000 employees. At the same time he was a member of the board in Alcasa a Aluminum Smelter with a capacity of 300,000 MT/year and a member of the board for CVG International (Corporation responsible for buying most of the spare parts and services required by CVG (Corporacion Venezolana de Guayana) and member of the board in Alunasa Rolling Mill in Costa Rica. Then he became President of CVG International. Ricardo is member of AIME (American Institute of Mining, Metallurgical and Petroleum Engineers) and assists every year to the worldwide conferences. In 1997 Ricardo moved to the US and built four gas stations under Bonima Oil Corp. He is also a business Associate of JHC Contractors and Architect, a General Contractor firm in Miami. In 2014 he co-founded Fuel Enterprises and is its President with more than 18 years of experience in the retail oil industry.
Company Profile
Leadership Team Omar Ochoa Co-Founder / Managing Sales Director
Omar Ochoa is Fuel Enterprises’ Sales Director for the National and International markets. He started working in the Fuel & Oil supply industry in the capacity of Regional Sales Manager for the Exxon Mobil / WEX, Inc. Retail and Commercial distribution in the Florida and South America regions in 2003. In early 2014 through parent company Bonima Corporations’ Commercial distribution expansion, Fuel Enterprises was created. During his career in Sales and Marketing, Omar Ochoa established himself as a respected and well trusted adviser in the Fuel and Oil supply industry. In the Past, Omar Ochoa has held a wide range of Managerial positions spanning from New Business Development, International and Domestic trade in Banking and Advertising. Omar Ochoa enjoys excellent relations with foreign and local business leaders. Thanks to his leadership and language skills in Spanish and English he has built long lasting business relationships with local and foreign companies.
Company Profile
Leadership Team Oscar Vilaro Co-Founder / Operations Vice-President
Oscar Vilaro is Fuel Enterprises’ Operations Director for the national and the International markets. Currently oversees the company’s logistics on a day to day basis. He coordinates the delivery of various fuel products and a considerable amounts of branded lubricants to cover the region conducting business fluently in English and Spanish. Started his career 35 years ago in the restaurant business in many capacities opening opportunities to the commodities trade where he currently specializes in managing logistics, personnel training and customer satisfaction.
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
ENERGETICOS VERSIÓN 1.0 2018-2019
ANALISIS DE PRODUCTO
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
CONFIDENCIAL
NOMBRE CIUDAD CONTACTO MUESTRA
Septiembre 04 de 2018. Multiservicios Asociación de Horticultores del Valle del Carrizo, SA de CV. Sinaloa. Sr. José Juan Ramírez. Combustible Diésel EVALUACIÓN
CARACTERÍSTICAS
Peso específico a 20/4 °C Viscosidad Cin. a 40°C. Temperatura de inflamación °C Azufre ppm Poder calorífico Kcal/kg Índice de Cetano Temperatura escurrimiento Agua y Sedimentos % Temperatura inicial de ebullición El 5% destila a El 10% destila a El 20% destila a El 30% destila a El 40% destila a El 50% destila a El 60% destila a El 70% destila a El 80% destila a El 90% destila a El 95% destila a Temperatura final de ebullición Recuperado % Residuos % Pérdida % Color
MÉTODOS
ASTM-D1298 ASTM-D445-94 ASTM-D93 ASTM-D5453 ASTM-D4868 ASTM-D613 ASTM-D97 ASTM-D1796 ASTM-D86 ASTM-D86-95 ASTM-D86-95 ASTM-D86-95 ASTM-D86-95 ASTM-D86-95 ASTM-D86-95 ASTM-D86-95 ASTM-D86-95 ASTM-D86-95 ASTM-D86-95 ASTM-D86-95 ASTM-D86
VISUAL
NORMAL
RESULTADO DE ANÁLISIS
ESPECIFICACIÓN
0.8257 4.0 70.1 4.00 10,345 57.5 +2 0.0 180 205.5 218.2 237.4 251.2 263.9 276.5 288.9 301.5 316.7 336.9 354.1 357.9 97.2 1.9 0.9 Claro
Normal Normal 45°C Min. A reportar Normal Mín. 48 Normal 0.05 Max. Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal A reportar
OBSERVACIONES/COMENTARIOS De acuerdo a resultado de análisis, el combustible se encontró en buenas condiciones para su operación. RESPONSABLE Q.I. JAVIER SÁNCHEZ PARDINI.
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
ENERGETICOS VERSIÓN 1.0 2018-2019
CARTA USO
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
CONFIDENCIAL
Fuel Enterprises FLEET CARDS
PRODUCTS
FUELS
LUBRICANTS
10-6-2017
To whom it may concern, Fuel Enterprises, Inc. Is a premier Fuel and Petroleum Distillate distributor in the U.S. and in Mexico. This letter is to certify that our proprietary Petroleum Distillate products is an approved petroleum product for major commercial vehicle brands such as Freightliner, Mercedes Benz and amongst other major brands. Our Petroleum Distillate product is an ASTM and EPA standard approved. Sincerely, Ricardo Echeverria President
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
ENERGETICOS VERSIÓN 1.0 2018-2019
PEDIMENTO DE IMPORTACION
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
CONFIDENCIAL
HORA DE PAGO: REF: OT009059
-1 17 17 3624
NUM. PEDIMENTO:
9
DESTINO:
TIPO CAMBIO:
7000311 19.09600
T.OPER:
IMP
A1
CVE.PEDIMENTO:
SALIDA:
6
IMD
CERTIFICACIONES
***PAGO ELECTRONICO*** BANAMEX, S.A. 3624 7000311 NO. DE DOCUMENTO: OP. 00000G34UE 443835.00 30/10/2017 ACUSE: 0040534060 IMPORTE TOTAL : $ 71281.00 CONTRIB. OTRA F.P : $ 0.00 CONTRIB. EFECTIVO : $ 71224.00 TOTAL CONTRIBUCIONES: $ 71224.00 CONTRAPRESTACION : $ 57.00
170
442116.00443835.00
VALOR ADUANA: PRECIO PAGADO/VALOR COMERCIAL:
6
REGIMEN:
ADUANA E/S:
VALOR DOLARES:
ARRIBO:
6
Página 1 de 2
PESO BRUTO: 83122.200
MEDIOS DE TRANSPORTE ENTRADA/SALIDA:
19:20:00
PEDIMENTO
23242.30 443835 442116
DATOS DEL IMPORTADOR / EXPORTADOR RFC: NAO150305960 CURP:
NOMBRE, DENOMINACION O RAZON SOCIAL:
NAFTA ADITIVOS ORGANICOS, SA DE CV DOMICILIO: MANUEL ACUÑA No.Ext. 600 Colonia. CENTRO BARRANQUITAS C.P.44280, GUADALAJARA,, JALISCO, MEXICO (ESTADOS UNIDOS MEXICANOS)
BANCO: FECHA DE PAGO: VAL. SEGUROS
SEGUROS
FLETES
EMBALAJES
OTROS INCREMENTABLES
0
0
0
0
1719
CODIGO DE ACEPTACIÓN:
CLAVE DE LA SECCION ADUANERA DE DESPACHO:
4V43WU66
170 MATAMOROS
S/M S/N
MARCAS, NUMEROS Y TOTAL DE BULTOS: FECHAS ENTRADA 30/10/2017 PAGO 30/10/2017
1 LOTE TASAS A NIVEL PEDIMENTO CONTRIB
CVE T. TASA
TASA
PRV CNT
2 2
210.00 20.00
CUADRO DE LIQUIDACION CONCEPTO
F.P
IMPORTE
CONCEPTO
F.P
IMPORTE
CNT
0
57
PRV IVA
0 0
210 71014
TOTALES
71281 0 71281
EFECTIVO OTROS TOTAL
DATOS DEL PROVEEDOR O COMPRADOR NOMBRE, DENOMINACION O RAZON SOCIAL FUEL ENTERPRISES INC
ID FISCAL
47-162-8594
NUM. FACTURA
FECHA
EX8973
30/10/2017
DOMICILIO: NW 53RD ST SUITE 350 No.Ext.8300 C.P.33166 DORAL FL ESTADOS UNIDOS DE AMERICA
INCOTERM MONEDA
DAP
VINCULACION:
NO
VAL. MON. FACT
FACTOR MON. FACT
VAL. DOLARES
23152.30
1.00000000
23152.30
USD
COVE17273Z8W7 TRANSPORTE TRANSPORTISTA: CURP:
NTRX29036
IDENTIFICACION:
KANSAS CITY SOUTHERN DE MEXICO, S.A. DE C.V.
DOMICILIO/CIUDAD/ESTADO:
NUMERO(GUIA/ORDEN EMBARQUE)/ID:
000001820637
M
NUMERO/TIPO DE CONTENEDOR:
NTRX29036
63
CLAVE/COMPL. IDENTIFICADOR ED
COMPLEMENTO 1 0192170AZZN73
ED
0192170B005Q8
ED
0192170B00594
PAIS:
MEX
RFC: KCS970506DQ3
AVENIDA MANUEL L. BARRAGANNo.Ext. 4850 C.P. 64290 HIDALGO MONTERREY NUEVO LEON
COMPLEMENTO 2
COMPLEMENTO 3
OBSERVACIONES FACTURA NUMERO: EX8973 CON COVE NUMERO: COVE17273Z8W7 BILL OF LADING DIGITALIZADO BAJO EDOCUMENT: 0192170AZZN73 ACLARACION DE FACTURA BAJO LA REGLA 3.1.7 DIGITALIZADA CON EDOCUMENT NUMERO: 0192170B005Q8 2A Y ULTIMA SUBDIVISION DE LA FACTURA EX8973 DE FECHA 30/10/2017 DE CONFORMIDAD CON EL 2DO PARRAFO DEL ART 65 DEL REGLAMENTO DE LA LEY ADUANERA DIGITALIZADA CON EDOCUMENT NUMERO: 0192170B00594 PARTIDAS FRACCION SUBD. VINC. MET VAL UMC CANTIDAD UMC UMT CANTIDAD UMT P. V/C P. O/D SEC DESCRIPCION (RENGLONES VARIABLES SEGUN SE REQUIERA) CON. TASA T.T F.P IMPORTE VAL. ADU/USD IMP. PRECIO PAG. PRECIO UNIT. VAL AGREG. MODELO MARCA CODIGO PRODUCTO
AGENTE ADUANAL, APODERADO ADUANAL O DE ALMACEN NOMBRE O RAZ. SOC.: RFC:
OLIMPIA GUADALUPE TAPIA GARZA
GCA010924G63
TAGO530420NP6
DECLARO BAJO PROTESTA DE DECIR VERDAD, EN LOS TERMINOS DE LO DISPUESTO POR EL ARTICULO 81 DE LA LEY, PATENTE O AUTORIZACION:
CURP: TAGO530420MTSPRL01
3624
FIRMA AUTOGRAFA NUMERO DE SERIE DEL CERTIFICADO:
00001000000403617716
e.firma: NyQ0kVqhIdLYkrjWqjEHjYYEHlyGzSctENZRCMo/y8Iac5p0p4H0jgqap39C6eZRw3wOaIS8Clp96Cp/Pz11uE4fv4Ya6aG7KwuG60Xo4RwtWHQva370rddXeO/G5T7QtxPnrnk38qjSqlG8yjDcirYhS459CYAjBxQMtF5qQN9SscfL41+fRfMnI6hXcH+1rJD0msMP4Eho
El pago de las contribuciones puede realizarse mediante el servicio de PECA, conforme a lo establecido en la regla 1.6.2., con la posibilidad de que la cuenta bancaria de la persona que contrate los servicios sea afectada directamente por el Banco. El agente o apoderado aduanal que utilice el servicio de PECA, deberá imprimir la certificación bancaria en el campo correspondiente del pedimento o en el documento oficial, conforme al Apéndice 20 “Certificación de Pago Electrónico Centralizado” del Anexo 22. El Importador-Exportador podrá solicitar la certificación de la información transmitida al SAAI por el agente o apoderado aduanal en el momento de la elaboración del pedimento en la ACIA.
DESTINO/ORIGEN. INTERIOR DEL PAIS Usuario: Victor Torres
30/10/2017 07:27:14 PM
REF:
-1
OT009059
Pagina 2 de 2
ANEXO DEL PEDIMENTO
17 17 3624 7000311
NUM. PEDIMENTO:
IMP
TIPO OPER:
CVE.PEDIM:
RFC:
A1
NAO150305960
CURP:
PARTIDAS FRACCION SUBD. VINC. MET VAL UMC CANTIDAD UMC UMT CANTIDAD UMT P. V/C P. O/D SEC DESCRIPCION (RENGLONES VARIABLES SEGUN SE REQUIERA) VAL. ADU/USD IMP. PRECIO PAG. PRECIO UNIT. VAL AGREG. MODELO MARCA CODIGO PRODUCTO 1 38119099 0 1 8 103107.025 1 83122.20000 USA USA DESTILADO DESTILADODE DEPETROLEO PETROLEOADITIVO ADITIVOPARA PARACOMBUSTIBLE COMBUSTIBLEDIESEL DIESEL27238 27238GAL GAL 443835.00000 IDENTIF
442116
COMPLEMENTO 1
COMPLEMENTO 2
USA
PG
3
1993
EN
XIV
NOM-050-SCFI-2004
********** FIN DE PEDIMENTO ****** NUM. TOTAL PARTIDAS:
OLIMPIA GUADALUPE TAPIA GARZA
GCA010924G63
T.T
F.P
IMPORTE
IGI/IGE IVA
Ex. 16.00000
1 1
0 0
0 71014
COMPLEMENTO 3 8004249300
1
****** CLAVE PREVALIDADOR: 010 **********
AGENTE ADUANAL, APODERADO ADUANAL O DE ALMACEN
RFC:
TASA
4.29000
TL
NOMBRE O RAZ. SOC.:
CON.
TAGO530420NP6
DECLARO BAJO PROTESTA DE DECIR VERDAD, EN LOS TERMINOS DE LO DISPUESTO POR EL ARTICULO 81 DE LA LEY, PATENTE O AUTORIZACION:
CURP: TAGO530420MTSPRL01
3624
FIRMA AUTOGRAFA NUMERO DE SERIE DEL CERTIFICADO:
00001000000403617716
e.firma: NyQ0kVqhIdLYkrjWqjEHjYYEHlyGzSctENZRCMo/y8Iac5p0p4H0jgqap39C6eZRw3wOaIS8Clp96Cp/Pz11uE4fv4Ya6aG7KwuG60Xo4RwtWHQva370rddXeO/G5T7QtxPnrnk38qjSqlG8yjDcirYhS459CYAjBxQMtF5qQN9SscfL41+fRfMnI6hXcH+1rJD0msMP4Eho
DESTINO/ORIGEN. INTERIOR DEL PAIS Usuario: Victor Torres
30/10/2017 07:27:14 PM
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
ENERGETICOS VERSIÓN 1.0 2018-2019
HOJA DE SEGURIDAD
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
CONFIDENCIAL
Safety Data Sheet
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
DIESEL FUEL No. 2 Product Use: Fuel [See Section 16 for Additional Product Numbers] Synonyms: 15 S Diesel Fuel 2, Alternative Low Aromatic Diesel (ALAD), Calco LS Diesel 2, CALCO ULS C-B0-B5 DF2, CALCO ULS C-B0-B5 DF2 DYED, CALCO ULS C-B2 DF2, CALCO ULS C-B2 DF2 DYED, CALCO ULS C-B5 DF2, CALCO ULS C-B5 DF2 DYED, Calco ULS DF2, Calco ULS Diesel 2, CALCO ULS S-B0-B5 DF2 DYED, Calco ULS S-B5 DF2, Calco ULS S-B5 DF2 DYED, CALCO ULS TC-B1 DF2, CALCO ULS TC-B1 DF2 DYED, CALCO ULS TC-B2 DF2, CALCO ULS TC-B2 DF2 DYED, CALCO ULS TC-B3 DF2, CALCO ULS TC-B3 DF2 DYED, CALCO ULS TC-B4 DF2, CALCO ULS TC-B4 DF2 DYED, CALCO ULS TC-B5 DF2, CALCO ULS TC-B5 DF2 DYED, CALCO ULS TX-B1 DF2, CALCO ULS TX-B1 DF2 DYED, CALCO ULS TX-B2 DF2, CALCO ULS TX-B2 DF2 DYED, CALCO ULS TX-B3 DF2, CALCO ULS TX-B3 DF2 DYED, CALCO ULS TX-B4 DF2, CALCO ULS TX-B4 DF2 DYED, CALCO ULS TX-B5 DF2, CALCO ULS TX-B5 DF2 DYED, Chevron LS Diesel 2, Chevron ULS Diesel 2, CT ULS C-B0-B5 DF2, CT ULS C-B0-B5 DF2 DYED, CT ULS C-B2 DF2, CT ULS C-B5 DF2, CT ULS S-B0-B5 DF2 DYED, CT ULS S-B5 DF2, CT ULS S-B5 DF2 DYED, CT ULS S-BO-B5 DF2, CT ULS SPECIAL DF2 DYED, CT ULS TC-B1 DF2, CT ULS TC-B2 DF2, CT ULS TC-B3 DF2, CT ULS TC-B4 DF2, CT ULS TC-B5 DF2, CT ULS TX-B1 DF2, CT ULS TX-B2 DF2, CT ULS TX-B3 DF2, CT ULS TX-B4 DF2, CT ULS TX-B5 DF2, Diesel Fuel Oil, Diesel Grade No. 2, Diesel No. 2-D S15, Diesel No. 2-D S500, Diesel No. 2-D S5000, Distillates, straight run, Gas Oil, HS Diesel 2, HS Heating Fuel 2, Light Diesel Oil Grade No. 2-D, LS Diesel 2, LS Heating Fuel 2, Marine Diesel, RR Diesel Fuel, Texaco Diesel, Texaco Diesel No. 2, ULS C-B0-B5 DF2, ULS C-B0-B5 DF2 DYED, ULS C-B2 DF2, ULS C-B2 DF2 DYED, ULS C-B5 DF2, ULS C-B5 DF2 DYED, ULS S-B0-B5 DF2 DYED, ULS S-B5 DF2, ULS S-BO-B5 DF2, ULS TC-B1 DF2, ULS TC-B1 DF2 DYED, ULS TC-B2 DF2, ULS TC-B2 DF2 DYED, ULS TC-B3 DF2, ULS TC-B3 DF2 DYED, ULS TC-B4 DF2, ULS TC-B4 DF2 DYED, ULS TC-B5 DF2, ULS TC-B5 DF2 DYED, ULS TX-B1 DF2, ULS TX-B1 DF2 DYED, ULS TX-B3 DF2, ULS TX-B3 DF2 DYED, ULS TX-B4 DF2, ULS TX-B4 DF2 DYED, ULS TX-B5 DF2, ULS TX-B5 DF2 DYED, Ultra Low Sulfur Diesel 2 Company Identification Chevron Products Company Marketing, MSDS Coordinator 6001 Bollinger Canyon Road San Ramon, CA 94583 United States of America Transportation Emergency Response CHEMTREC: (800) 424-9300 or (703) 527-3887 Health Emergency Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800) 231-0623 or (510) 231-0623 Product Information MSDS Requests: http://www.chevron.com/contact/ Technical Information: (510) 242-5357
_____________________________________________________________________ Revision Number: 24 Revision Date: MAY 07, 2015
1 of 11
DIESEL FUEL No. 2 SDS : 6894
SPECIAL NOTES: This MSDS covers all Chevron, Texaco and Calco CARB & non-CARB Diesel No. 2 Fuels. The sulfur content is less than 0.5% (mass). Red dye is added to non-taxable fuel. (MSDS 6894) SPECIAL NOTES: This MSDS covers all Chevron and Calco CARB Low Sulfur Diesel No. 2 Fuels. Red dye is added to non-taxable fuel. (MSDS 7098)
SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION: Flammable liquid: Category 3. Aspiration toxicant: Category 1. Carcinogen: Category 1B. Skin irritation: Category 2. Target organ toxicant (repeated exposure): Category 2. Target organ toxicant (central nervous system): Category 3. Acute inhalation toxicant: Category 4. Acute aquatic toxicant: Category 2. Chronic aquatic toxicant: Category 2.
Signal Word: Danger Physical Hazards: Flammable liquid and vapor. Health Hazards: May be fatal if swallowed and enters airways. May cause cancer. Causes skin irritation. Harmful if inhaled. May cause drowsiness or dizziness. Target Organs: May cause damage to organs (Blood/Blood Forming Organs, Liver, Thymus) through prolonged or repeated exposure. Environmental Hazards: Toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS: General: Keep out of reach of children. Read label before use. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. -- No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting/equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Wash thoroughly after handling. Avoid release to the environment. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. IF ON SKIN (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. IF SWALLOWED: Immediately call a poison center or doctor/physician. Do NOT induce vomiting. Call a poison center or doctor/physician if you feel unwell. In case of fire: Use media specified in the SDS to extinguish. Specific treatment (see Notes to Physician on this label). Collect spillage. Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
_____________________________________________________________________ Revision Number: 24 Revision Date: MAY 07, 2015
2 of 11
DIESEL FUEL No. 2 SDS : 6894
HAZARDS NOT OTHERWISE CLASSIFIED: Not Applicable SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENTS
CAS NUMBER
AMOUNT
Diesel Fuel No. 2
68476-34-6
95 - 100 %vol/vol
Fatty Acid Methyl Esters (FAME)
Mixture
0 - 5 %vol/vol
Alkanes,C10-C20-Branched And Linear
928771-01-1
0 - 5 %vol/vol
Naphthalene
91-20-3
0.02 - 0.2 %vol/vol
Total sulfur
Mixture
0 - 5000 ppm (weight)
SECTION 4 FIRST AID MEASURES Description of first aid measures Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water. Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical attention if any symptoms develop. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by mouth to an unconscious person. Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if breathing difficulties continue or if any other symptoms develop. Most important symptoms and effects, both acute and delayed IMMEDIATE HEALTH EFFECTS Eye: Not expected to cause prolonged or significant eye irritation. Skin: Contact with the skin causes irritation. Symptoms may include pain, itching, discoloration, swelling, and blistering. Contact with the skin is not expected to cause an allergic skin response. Ingestion: Highly toxic; may be fatal if swallowed. Because of its low viscosity, this material can directly enter the lungs, if swallowed, or if subsequently vomited. Once in the lungs it is very difficult to remove and can cause severe injury or death. May be irritating to mouth, throat, and stomach. Symptoms may include pain, nausea, vomiting, and diarrhea. Inhalation: The vapor or fumes from this material may cause respiratory irritation. Mists of this material may cause respiratory irritation. Symptoms of respiratory irritation may include coughing and difficulty breathing. Excessive or prolonged breathing of this material may cause central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion, or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors or convulsions, loss of consciousness, coma or death. DELAYED OR OTHER HEALTH EFFECTS: Cancer: Whole diesel engine exhaust has been classified as a Group 2A carcinogen (probably carcinogenic to humans) by the International Agency for Research on Cancer (IARC). Prolonged or repeated exposure to this material may cause cancer. Contains naphthalene, which has been classified as
_____________________________________________________________________ Revision Number: 24 Revision Date: MAY 07, 2015
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DIESEL FUEL No. 2 SDS : 6894
a Group 2B carcinogen (possibly carcinogenic to humans) by the International Agency for Research on Cancer (IARC). Target Organs: Contains material that may cause damage to the following organ(s) following repeated inhalation at concentrations above the recommended exposure limit based on animal data:Liver Blood/Blood Forming Organs Thymus Risk depends on duration and level of exposure. See Section 11 for additional information. Indication of any immediate medical attention and special treatment needed Note to Physicians: Ingestion of this product or subsequent vomiting may result in aspiration of light hydrocarbon liquid, which may cause pneumonitis. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unusual Fire Hazards: See Section 7 for proper handling and storage. PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this material is released into the work area, evacuate the area immediately. Monitor area with combustible gas indicator. Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent materials or pumping. All equipment used when handling the product must be grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to collect absorbed material. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802 as appropriate or required. SECTION 7 HANDLING AND STORAGE General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Precautionary Measures: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with explosive force. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding equipment, and electrical motors and switches. Fire hazard is greater as liquid temperature rises above 29C (85F). Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Do not breathe vapor or fumes. Do not breathe mist. Wash thoroughly after handling. Keep out of the reach of children. Unusual Handling Hazards: WARNING! Do not use as portable heater or appliance fuel. Toxic fumes may accumulate and cause death. Slow heat generation may occur with oil-soaked rags, spent filter aids
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DIESEL FUEL No. 2 SDS : 6894
and spent absorbent material and may cause spontaneous combustion if stored near combustibles and not handled properly. Store biodiesel soaked rags, filter aids, and spill absorbent material in approved safety disposal containers and dispose of properly. Biodiesel soaked rags may be washed with soap and water and allowed to dry in well ventilated area. Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces . USE AND STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL CONSIDERATIONS: Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits. PERSONAL PROTECTIVE EQUIPMENT Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may include gloves, apron, boots, and complete facial protection depending on operations conducted. Suggested materials for protective gloves include: Chlorinated Polyethylene (or Chlorosulfonated Polyethylene), Nitrile Rubber, Polyurethane, Viton. Respiratory Protection: Determine if airborne concentrations are below the recommended occupational exposure limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an approved respirator that provides adequate protection from this material, such as: Air-Purifying Respirator for Organic Vapors. When used as a fuel, this material can produce carbon monoxide in the exhaust. Determine if airborne concentrations are below the occupational exposure limit for carbon monoxide. If not, wear an approved positive-pressure air-supplying respirator. Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide adequate protection. Occupational Exposure Limits:
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DIESEL FUEL No. 2 SDS : 6894
Component
Agency
TWA
STEL
Ceiling
Notation
Diesel Fuel No. 2
ACGIH
100 mg/m3
--
--
Skin A3 total hydrocarbon
Diesel Fuel No. 2
--
1000 mg/m3
--
--
--
--
--
--
Alkanes,C10-C20-Branched And Linear
CVX Not Applicable Not Applicable
--
--
--
--
Naphthalene
ACGIH
10 ppm (weight)
15 ppm (weight)
--
Skin
Naphthalene
OSHA Z-1 Not Applicable
50 mg/m3
--
--
--
--
--
--
--
Fatty Acid Methyl Esters (FAME)
Total sulfur
Consult local authorities for appropriate values. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Attention: the data below are typical values and do not constitute a specification. Color: Varies depending on specification Physical State: Liquid Odor: Petroleum odor Odor Threshold: No data available pH: Not Applicable Vapor Pressure: 0.04 kPa (Approximate) @ 40 °C (104 °F) Vapor Density (Air = 1): >1 Initial Boiling Point: 175.6°C (348°F) - 370°C (698°F) Solubility: Soluble in hydrocarbons; insoluble in water Freezing Point: Not Applicable Melting Point: Not Applicable Specific Gravity: 0.8 - 0.88 @ 15.6°C (60.1°F) (Typical) Viscosity: 1.9 cSt - 4.1 cSt @ 40°C (104°F) Decomposition temperature: No data available Octanol/Water Partition Coefficient: No data available FLAMMABLE PROPERTIES: Flammability (solid, gas): No Data Available Flashpoint: (Pensky-Martens Closed Cup) 52 °C (125 °F) Minimum Autoignition: 257 °C (494 °F) Flammability (Explosive) Limits (% by volume in air): Lower: 0.6 Upper: 4.7 SECTION 10 STABILITY AND REACTIVITY Reactivity: etc.
May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides,
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Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Conditions to Avoid: Avoid contact with heat, sparks, fire and oxidizing agents Incompatibility With Other Materials: Not applicable Hazardous Decomposition Products: None known (None expected) Hazardous Polymerization: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for similar materials. Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for similar materials. Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials. Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar materials. Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials. Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials. Acute Toxicity Estimate: Not Determined Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material. Carcinogenicity: The hazard evaluation is based on data for components or a similar material. Whole diesel engine exhaust has been classified as a Group 2A carcinogen (probably carcinogenic to humans) by the International Agency for Research on Cancer (IARC). Contains naphthalene, which has been classified as a Group 2B carcinogen (possibly carcinogenic to humans) by the International Agency for Research on Cancer (IARC). Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for components or a similar material. ADDITIONAL TOXICOLOGY INFORMATION: The National Institute of Occupational Safety and Health (NIOSH) has recommended that whole diesel exhaust be regarded as potentially causing cancer. This recommendation was based on test results showing increased lung cancer in laboratory animals exposed to whole diesel exhaust. This product contains naphthalene. GENERAL TOXICITY: Exposure to naphthalene has been reported to cause methemoglobinemia and/or hemolytic anemia, especially in humans deficient in the enzyme glucose-6-phosphate dehydrogenase. Laboratory animals given repeated oral doses of naphthalene have developed cataracts. REPRODUCTIVE TOXICITY AND BIRTH DEFECTS: Naphthalene did not cause birth defects when administered orally to rabbits, rats, and mice during pregnancy, but slightly reduced litter size in mice at dose levels that were lethal to the pregnant females. Naphthalene has been reported to cross the human placenta. GENETIC
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TOXICITY: Naphthalene caused chromosome aberrations and sister chromatid exchanges in Chinese hamster ovary cells, but was not a mutagen in several other in-vitro tests.CARCINOGENICITY: In a study conducted by the National Toxicology Program (NTP), mice exposed to 10 or 30 ppm of naphthalene by inhalation daily for two years had chronic inflammation of the nose and lungs and increased incidences of metaplasia in those tissues. The incidence of benign lung tumors (alveolar/bronchiolar adenomas) was significantly increased in the high-dose female group but not in the male groups. In another two-year inhalation study conducted by NTP, exposure of rats to 10, 30, and 60 ppm naphthalene caused increases in the incidences of a variety of nonneoplastic lesions in the nose. Increases in nasal tumors were seen in both sexes, including olfactory neuroblastomas in females at 60 ppm and adenomas of the respiratory epithelium in males at all exposure levels. The relevance of these effects to humans has not been established. No carcinogenic effect was reported in a 2-year feeding study in rats receiving naphthalene at 41 mg/kg/day. This product contains gas oils. CONCAWE (product dossier 95/107) has summarized current health, safety and environmental data available for a number of gas oils, typically hydrodesulfurized middle distillates, CAS 64742-80-9, straight-run middle distillates, CAS 64741-44-2, and/or light cat-cracked distillate CAS 64741-59-9. CARCINOGENICITY: All materials tested have caused the development of skin tumors in mice, but all featured severe skin irritation and sometimes a long latency period before tumors developed. Straight-run and cracked gas oil samples were studied to determine the influence of dermal irritation on the carcinogenic activity of middle distillates. At non-irritant doses the straight-run gas oil was not carcinogenic, but at irritant doses, weak activity was demonstrated. Cracked gas oils, when diluted with mineral oil, demonstrated carcinogenic activity irrespective of the occurrence of skin irritation. Gas oils were tested on male mice to study tumor initiating/promoting activity. The results demonstrated that while a straight-run gas oil sample was neither an initiator or promotor, a blend of straight-run and FCC stock was both a tumor initiator and a promoter. GENOTOXICITY: Hydrotreated & hydrodesulfurized gas oils range in activity from inactive to weakly positive in in-vitro bacterial mutagenicity assays. Mouse lymphoma assays on straight-run gas oils without subsequent hydrodesulphurization gave positive results in the presence of S9 metabolic activation. In-vivo bone marrow cytogenetics and sister chromatic exchange assay exhibited no activity for straight-run components with or without hydrodesulphurization. Thermally or catalytically cracked gas oils tested with in-vitro bacterial mutagenicity assays in the presence of S9 metabolic activation were shown to be mutagenic. In-vitro sister chromatic exchange assays on cracked gas oil gave equivocal results both with and without S9 metabolic activation. In-vivo bone marrow cytogenetics assay was inactive for two cracked gas oil samples. Three hydrocracked gas oils were tested with in-vitro bacterial mutagenicity assays with S9, and one of the three gave positive results. Twelve distillate fuel samples were tested with in-vitro bacterial mutagenicity assays & with S9 metabolic activation and showed negative to weakly positive results. In one series, activity was shown to be related to the PCA content of samples tested. Two in-vivo studies were also conducted. A mouse dominant lethal assay was negative for a sample of diesel fuel. In the other study, 9 samples of No 2 heating oil containing 50% cracked stocks caused a slight increase in the number of chromosomal aberrations in bone marrow cytogenetics assays. DEVELOPMENTAL TOXICITY: Diesel fuel vapor did not cause fetotoxic or teratogenic effects when pregnant rats were exposed on days 6-15 of pregnancy. Gas oils were applied to the skin of pregnant rats daily on days 0-19 of gestation. All but one (coker light gas oil) caused fetotoxicity (increased resorptions, reduced litter weight, reduced litter size) at dose levels that were also maternally toxic.
SECTION 12 ECOLOGICAL INFORMATION ECOTOXICITY This material is expected to be toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment. A series of studies on the acute toxicity of 4 diesel fuel samples were conducted by
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one laboratory using water accommodated fractions. The range of effective (EC50) or lethal concentrations (LC50) expressed as loading rates were: 72 hour(s) EC50: 2.6-25 mg/l (Selenastrum capricornutum) 96 hour(s) LC50: 21-210 mg/l (Salmo gairdneri) 48 hour(s) EC50: 20-210 mg/l (Daphnia magna) MOBILITY No data available. PERSISTENCE AND DEGRADABILITY This material is not expected to be readily biodegradable. On release to the environment the lighter components of diesel fuel will generally evaporate but depending on local environmental conditions (temperature, wind, mixing or wave action, soil type, etc.) the remainder may become dispersed in the water column or absorbed to soil or sediment. Diesel fuel would not be expected to be readily biodegradable. In a modified Strum test (OECD method 301B) approximately 40% biodegradation was recorded over 28 days. However, it has been shown that most hydrocarbon components of diesel fuel are degraded in soil in the presence of oxygen. Under anaerobic conditions, such as in anoxic sediments, rates of biodegradation are negligible. The product has not been tested. The statement has been derived from products of a similar structure and composition. POTENTIAL TO BIOACCUMULATE Bioconcentration Factor: No data available. Octanol/Water Partition Coefficient: No data available SECTION 13 DISPOSAL CONSIDERATIONS Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by international, country, or local laws and regulations. SECTION 14 TRANSPORT INFORMATION The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific shipping requirements. DOT Shipping Description: For packages with an Initial Boiling Point > 35 deg C and a Flash Point (PM Closed Cup) >/= 23 deg C but </= 60 deg C: UN1202, GAS OIL, 3, III; OPTIONAL DISCLOSURE: UN1202, GAS OIL, 3, III, MARINE POLLUTANT (DIESEL FUEL) Optional disclosure per 49 CFR when Flash Point (PM Closed Cup) >/= 38 deg C < 93 deg C per 49 173.150 (f): UN1202, GAS OIL, COMBUSTIBLE LIQUID, III; NON-BULK PACKAGES ARE EXEMPTED FROM THE PROVISIONS OF 49 CFR IN USA JURISDICTIONS Optional disclosure as a GHS Environmental Hazard/Marine Pollutant when Flash Point (PM Closed Cup) > 60 deg C: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(DIESEL FUEL), 9, III, MARINE POLLUTANT (DIESEL FUEL) IMO/IMDG Shipping Description: For packages with an Initial Boiling Point > 35 deg C and a Flash Point (PM Closed Cup) >/= 23 deg C, </= 60 deg C: UN1202, GAS OIL, 3, III, FLASH POINT SEE SECTION 5 OR 9, MARINE POLLUTANT (DIESEL FUEL); OPTIONAL DISCLOSURE: UN1268, PETROLEUM DISTILLATES, N.O.S. (DIESEL FUEL), 3, III, FLASH POINT SEE SECTION 5 OR 9, MARINE POLLUTANT (DIESEL FUEL) For packages with a Flash Point (PM Closed Cup) > 60 deg C: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DIESEL FUEL), 9, III, MARINE
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POLLUTANT (DIESEL FUEL) ICAO/IATA Shipping Description: For packages with an Initial Boiling Point > 35 deg C and a Flash Point (PM Closed Cup) >/= 23 deg C, </= 60 deg C: UN1202, GAS OIL, 3, III For packages with a Flash Point (PM Closed Cup) > 60 deg C: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DIESEL FUEL), 9, III, MARINE POLLUTANT (DIESEL FUEL) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable
SECTION 15 REGULATORY INFORMATION EPCRA 311/312 CATEGORIES:
1. 2. 3. 4. 5.
Immediate (Acute) Health Effects: Delayed (Chronic) Health Effects: Fire Hazard: Sudden Release of Pressure Hazard: Reactivity Hazard:
YES YES YES NO NO
REGULATORY LISTS SEARCHED: 01-1=IARC Group 1
03=EPCRA 313
01-2A=IARC Group 2A
04=CA Proposition 65
01-2B=IARC Group 2B
05=MA RTK
02=NTP Carcinogen
06=NJ RTK 07=PA RTK
The following components of this material are found on the regulatory lists indicated. Naphthalene 01-2B, 02, 03, 04, 05, 06, 07 Diesel Fuel No. 2 07 CERCLA REPORTABLE QUANTITIES(RQ)/EPCRA 302 THRESHOLD PLANNING QUANTITIES(TPQ): Component Component RQ Component TPQ Product RQ Naphthalene 100 lbs None 40000 lbs CHEMICAL INVENTORIES: All components comply with the following chemical inventory requirements: AICS (Australia), DSL (Canada), EINECS (European Union), IECSC (China), KECI (Korea), PICCS (Philippines), TSCA (United States). NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be identified as follows: DIESEL FUEL SECTION 16 OTHER INFORMATION NFPA RATINGS:
Health: 1
HMIS RATINGS:
Health: 2*
Flammability: 2 Flammability: 2
Reactivity: 0 Reactivity: 0
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(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). Additional Product Number(s): 203408, 203410, 203413, 203417, 203431, 203436, 203437, 203441, 203443, 203447, 203449, 203450, 220122, 225114, 225115, 225150, 266176, 270000, 270005, 270030, 270031, 270032, 270033, 270034, 270040, 270041, 270042, 270043, 270044, 270045, 270046, 270047, 270048, 270049, 270050, 270051, 270052, 270053, 270054, 270058, 270059, 270060, 270062, 270063, 270064, 270065, 270068, 270069, 270070, 270081, 270082, 270083, 270084, 270085, 270086, 270087, 270088, 270089, 270090, 270091, 270094, 270095, 270096, 270100, 270101, 270102, 270103, 270104, 270105, 270106, 270107, 270108, 270109, 270110, 270111, 270112, 270113, 270114, 270115, 270116, 270117, 270118, 270119, 270120, 270121, 270122, 270123, 270124, 271006, 272006, 272007, 272008, 272009, 272010, 272011, 272012, 272013, 272093, 272102, 272126, 272129, 272130, 272131, 272152, 272185, 272190, 272195, 272593, 272601, 272602, 272693, 272793, 273003, 273030, 273053, 275000 REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 2,3,4,12,16 Revision Date: MAY 07, 2015 ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV
-
STEL -
Threshold Limit Value
TWA
-
Time Weighted Average
Short-term Exposure Limit
PEL
-
Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number ACGIH - American Conference of Governmental IMO/IMDG International Maritime Dangerous Goods Industrial Hygienists Code API - American Petroleum Institute
SDS
-
Safety Data Sheet
HMIS - Hazardous Materials Information System
NFPA
DOT - Department of Transportation (USA) IARC International Agency for Research on Cancer
NTP
NCEL - New Chemical Exposure Limit
EPA - Environmental Protection Agency
-
OSHA
National Fire Protection Association (USA) National Toxicology Program (USA)
-
Occupational Safety and Health Administration
SCBA - Self-Contained Breathing Apparatus
Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001 Bollinger Canyon Road San Ramon, CA 94583.
The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose.
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GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
ENERGETICOS VERSIÃ&#x201C;N 1.0 2018-2019
PROVEEDOR TRASVASE
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
CONFIDENCIAL
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
ENERGETICOS VERSIÃ&#x201C;N 1.0 2018-2019
CARTAS DE INTENCION
GLT INGENIERIA Y SERVICIOS INDUSTRIALES DE MEXICO SA DE CV
CONFIDENCIAL
1 de 7
PETROLAND S.A. DE C.V. Monterrey, México December 15, 2017 Mr. Omar Huracha REPRESENTATIVE FUEL ENTERPRISE, INC SUBJECT: Letter Intent to buy DIESEL, GASOLINE, GLP and Natural Gas P R E S ENT: We are able to generate this document with the intention presenting ourselves to you and clarifying the key points of the formal operation of a possible contract of purchase of hydrocarbons specifically with the products of DIESEL, GASOLINE , GLP and NATURAL GAS In case you have these products in your line of marketing. Our main interest is the acquisition, importation and commercialization of these products to México and that FUEL ENTERPRISE, INC sells in the United States of America. We inform you that with the energy reform carried out in Mexico since year 2015, this activity is no longer exclusive to PEMEX and that our company PETROLAND S.A. DE C.V. has the federal permits of the REGULATORY ENERGY COMMISSION (CRE-http: //www.gob.mx/cre) and the ENERGY SECRETARY (SENER-https: //www.gob.mx/ sener) to be able to carry out Its importation and marketing within the country. The oil companies in which we are interested must comply with the official Mexican rules in order to be introduced to the Mexican market, where we attach document "DOCUMENT ANNEX”. PRODUCT
MONTHLY VOLUME REQUIRED
UNITS
GASOLINE 87 OCTANOS
50,000,000
LITERS
GASOLINE 92 OCTANOS
5,000,000
LITERS
DIESEL
25,000,000
LITERS
LPG
1,500,000
GAL
5,000
mmBTU/daily
NATURAL GAS
*Different locations
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ANNEX GLP SPECIFICATIONS ACCORDING TO THE MEXICAN OFFICIAL STANDARD (ALL READY OPEN MARKET) COMPOSITION AND INGREDIENTS INFORMATION PROPERTY
GRADO DE RIESGO
COMPONENTES
%
2. No. CAS
3. No. ONU
4. LMPE; PPT.CT
5. IPVS
S
I
R
Propano
60
74-98-6
1075
ASFIXIANTE SIMPLE
2100 ppm
1
4
0
Butano
40
106-97-8
1011
PPT-800 ppm
—-
1
4
0
Etil-Mercaptano (Odorizante)
0.0017-0.0028 ppm
75-08-1
2363
PPT: 0.95 ppm CT: 2 ppm
500 pum
2
4
0
Especial
PROPIEDADES FISICAS/QUIMICAS
PROPIEDADES FISICAS / QUIMICAS PESO MOLECULAR
49.7
TEMPERATURA DE EBULLICION @ 1 atm
-35.2 ºC
TEMPERATURA DE FUSION
-167.9 ºC
DENSIDAD DE LOS VAPORES (aire=1) @15.5ºC
2.01 (Dos veces mas pesado que el aire)
DENSIDAD DEL LIQUIDO (agua=1) @ 15.5ºC
0.540
PREISON DE VAPOR @ 21.1 ºC
4500 mmHg
Relación de Expansión (Liquido a gas @ 1atm)
1 a 242 (Un litro de gas licuado, se convierte en 242 litros de gas fase vapor, formando con el aire una mezcla explosiva de aproximadamente 11,000 litros)
SOLUBILIDAD EN AGUA @ 20ºC
Aproximadamente 0.0079% en peso (Insignificante; menos del .1%)
APARIENCIA Y COLOR
Gas Insípido e Incoloro a temperatura y presión ambiente. Tiene un olorizaste que le proporciona un olor característico, fuerte y desagradable
INFORMACION SOBRE TRANSPORTACION
INFORMACION SOBRE TRANSPORTACION NOMBRE COMERCIAL
GAS LICUADO DEL PETROLEO
IDENTIFICACION *DOT:
UN-1075 (UN-NACIONES UNIDAS)
CLASIFICAICON DE RIESGO: *DOT ETIQUETA DE EMBARQUE IDENTIFICACION DURANTE SU TRANSPORTE
CLASE 2, DIVISION 2.1 GAS INFLAMABE CARTEL CUADRANGULAR EN FORMA DE ROMBO DE 273 mm X 273 mm (10 3/4 X 10 3/4), CON EL NUMERO DE NACIONES UNIDAS EN EL CENTRO Y LA CLASE DE RIESGO DOT EN LA ESQUINA INFERIOR
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ANNEX DIESEL SPECIFICATIONS ACCORDING TO THE MEXICAN OFFICIAL STANDARD MEXICAN OFFICIAL STANDARD NOM-016-CRE-2016, PETROLEUM QUALITY SPECIFICATIONS Fourth. That, according to article 40, sections I and XIII of the LFMN, Mexican official standards will have, among other things, to establish the characteristics and / or specifications that must be met by industrial, commercial, , Services and domestic for sanitary, aquacultural, agricultural, livestock, ecological, communications, security or quality purposes and particularly when they are dangerous. Fifth. That all petroleum products marketed in Mexico must comply with quality specifications in such a way that they do not represent a risk to the health of persons, their property and the environment and are compatible with those established by those countries with which they Mexico has a commercial relationship. 4. Petroleum quality specifications. 4.1. The specifications set out in Tables 1 to 13 of the Standard are mandatory, and must be complied with by the producer, importer, warehouseman, transporter, distributor and retailer, in the conduct and, in general, by the person who Commercialize or alienate the oil companies. ADDITIONAL OBLIGATIONS: (1) The maximum temperature must be less than or equal to the minimum expected ambient temperature. (2) If the cetane number is measured, this parameter shall be measured without additive. In case the diesel additives are required, it should be in accordance with number 4.3 of the Standard. (3) On entry into force of the Standard, the maximum sulfur content in automotive diesel will be 15 mg / kg for ZMVM, ZMG, ZMM and ZFN, as well as for duct, buoy, tank or other Means of land transport and that distributed in the 11 corridors referred to in Annex 1; For the rest of the country the sulfur content will be 500 mg / kg maximum. Not later than 31 December 2018, the maximum sulfur content in this oil company shall be 15 mg / kg throughout the national territory. (4) In order to comply with the lubricity specification, diesel may be added to storage or distribution facilities prior to sale to the public; The test corresponding to the diesel whose composition is final, must be carried out by the Permitary who carries out the additivation. (5) The electrical conductivity must be measured at the diesel temperature prior to dispensing to the public. The minimum conductivity requirement of 25 pS / m applies in all cases of high speed transfer, ie 7 m / s. When the speed differs from 7 m / s, the conditions set out in Table 2 of the ASTM D975 standard shall apply.
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PROPERTY
Specific gravity at 20/4 °C
UNIT
dimensionless
TESTING METHOD
Density, relative density (specific gravity or severity of crude oil and liquid petroleum products by the hydrometric method, ASTM D1298, D4052)
LIMIT VALUE AUTOMOTIVE DIESEL
AGRICULTURAL/ MARINE DIESEL
report
report
Distillation temperatures: Initial Boiling Temperature
ºC
report
At 10% recovered
ºC
275.0 max.
At 50% recovered
ºC
At 90% recovered
ºC
345.0 max.
Final Boiling Temperature
ºC
report
Flash point
ºC
Flammability Flash Point: Pensky-Martens Closed Cup Test (ASTM D93, D7094, D3828)
Runoff temperature
ºC
Product Flow Point (ASTM D97)
Clouding temperature
ºC
Point at which petroleum fuels become turbid (ASTM D2500)
report
report
(1) Cetane Index
dimensionless
Calculation of cetane number of distillate fuels (ASTM D4737, D976)
45 minimum
45 minimum
(2) Cetane number (2)
dimensionless
Diesel Cetane Number (ASTM D613)
45 minimum
45 minimum
Determination of sulfur in petroleum products by energy dispersive fluorescence X-ray spectroscopy (ASTM D4294) Determination of total sulfur in light hydrocarbons (ASTM D5453, D2622, D7039, D7220)
15 maximum (3) 500 maximum Rest of the country
500 maximun
Detection of Copper Corrosion in Petroleum Products by the Copper Strip Stain Test (ASTM D130)
Standard # 1 maximum
Standard # 1 maximum
Coal wastes by Ramsbottom petroleum product test (ASTM D524)
0.35 maximum
0.35 maximum
Water and sediment in centrifuge medium distillation fuels (ASTM D2709)
0.05 maximum
0.05 maximum
1.9 to 4.1
1.9 to 4.1
Distillation of petroleum products (ASTM D86, D 7344, D7345)
report
report
45 minimum
345.0 max.
60 minimum
March to October: 0 ° C maximum; November to February: -5 ° C maximum
One of the following requirements must be met:
Sulfur
Cu corrosion, 3 hours at 50 ° C
Coal wastes (10% of waste)
Water and sediment Kinematic viscosity At 40 ° C
mg/kg (ppm)
dimensionless
% mass
% volume mm2/s
Kinematic Viscosity of Transparent and Opaque Liquids (Dynamic Viscosity Calculation, ASTM D445)
ashes
% mass
Ashes in Petroleum Products (ASTM D482)
0.01 maximum
0.01 maximum
Color
dimensionless
Color of Oil / Visual Products (ASTM D1500)
2.5 maximum
purple
% volume
Types of hydrocarbons in liquid petroleum products by fluorescent indicator absorption (ASTM D1319, ASTM D5186)
35 maximum
35 maximum
HFRR Test (ASTM D6079, ASTM D7688)
520 maximum
520 maximum
25 minimum
25 minimum
Aromatic content
Lubrication (4) Electrical conductivity (5)
microns pS/m
Electrical conductivity (ASTM D2624, ASTM D4308)
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GENERAL GASOLINE SPECIFICATIONS LIMIT VALUE PROPERTY
UNIT
SPECIFIC GRAVITY 20/4ºC
DIMENSIONLESS
SULPHUR MERCAPTANICO
mg/Kg
ONE OF THE FOLLOWING REQUIRMENTS MUST BE FULFILLED: DIMENSIONLESS
(1) Cu, CORROSION, 3 HRS AT 50ºC (2)
CORROSION TO THE Ag
TEST METHOD GASOLINE PREMIUM
GASOLINE REGULAR
INFORM
INFORM
DETERMINATION OF SULPHUR MERCAPTANICO IN PETROL, KEROSENE, FUELS DISTILLED FOR AIRCRAFT OF TURBINE (METHOD POTENTIOMETRIC, ASTM D3227)
20 MAXIMUM
20 MAXIMUM
(1) DETECTION OF CORROSION BY COPPER PRODUCTS OF OIL BY THE STAIN OF COPPER STRIP TEST (ASTM D130)
STANDAR #1 MAXIMUM
STANDAR #1 MAXIMUM
(2) DETERMINATION OF CORROSIVITY TO THE SILVER BY GASOLINE BY THE METHOD OF SILVER PLATE (ASTM D7667, ASTM D7671)
STANDAR #1 MAXIMUM
STANDAR #1 MAXIMUM
EXISTING FUEL EVAPORATIVE GUMS BY SPRAY (ASTM D381)
0.050 MAXIMUM (5 MAX)
0.050 MAXIMUM (5 MAX)
0.7 MAXIMUM (70 MAX)
0.7 MAXIMUM (70 MAX)
STABILITY OF OXIDATION OF GASOLINE (METHOD OF PERIOD INDUCTION ASTM D525)
240 MINIMUM
240 MINIMUM
94.0 MINIMUM
INFORM
PROCEDURE FOR DENSITY, RELATIVE DENSITY (SPECIFIC GRAVITY) OF GAVITY OF CRUDE OIL OR BY HYDROMETER LIQUID PETROLEUM PRODUCTS (ASTM D1298, D4052)
RUBBER WASHED
Kg/m3 (mg/100 mL)
GUMS NOT WAHS
Kg/m3 (mg/100 mL)
PERIOD OF INDUCTION
MINUTES
OCTANE NUMBER (RON) (2)
DIMENSIONLESS
FUEL RESEARCH OCTANE NUMBER SPARK (ASTM D2699) SPARK IGNITION ENGINES
OCTANE NUMBER (MON) (2)
DIMENSIONLESS
FUELS FOR ENGINES MOTOR OCTANE NUMBER SPARK (ASTM 2700)
INFORM
82.0 MINIMUM
OCTANE NUMBER (RON + MON) / 2 (2)
DIMENSIONLESS
FUEL RESEARCH OCTANE NUMBER SPARK (ASTM D2699) SPARK IGNITION ENGINES FUELS FOR ENGINES MOTOR OCTANE NUMBER SPARK (ASTM 2700)
91.0 MINIMUM
87.0 MINIMUM
ADDITIVE DETERGENT DIPERSANT (1)
mg/Kg
RUBBER BANDS EXISTING IN FUELS BY EVAPORATION BY SPRAY (ASTM D381)
EVALUATION OF LEAD FREE ENGINE GASOLINE OF INTERNAL COMBUSTION (ASTM D5598, ASTM D5500)
IN CONCENTRATION THAT MEETS WHIT THE SPECIFICATION OF THE EPA IN THE 80. 165 SECTION OF THE CFR.
ADDITIONAL OBLIGATIONS: (1) Additive should be added to gasoline in México during the load of the tankers or other means of transport, on the premises of wholesalers and distributors in the point more close to the sale to the public, and demonstrate in a half-yearly report (as part of the information which will annually evaluate the verification unit), the required amount of additive used through the balance of gasoline produced or imported and the corresponding additive consumption. (2) Parameter unwashed gum must be determined prior to the addition of detergent additive dispersant.
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(3) Only be used additives tested in accordance whit de ASTM D5598 and ASTM D5500 method in laboratories accredited and approved in terms of the LFMN (Ley Federal sobre Metrologia y Normalizaciรณn). The technologists of additive must used for them evidence of certification, gasoline produced or imported that meet them following features.
GASOLINE
SULPHUR mg/Kg MINIMUM
TEMPERATURE OF DISTILLATION TO THE 90% (ยบC), MINIMUM
OLEFINS, % VOL. MINIMUM
AROMATICS, % MINIMUM VOL.
OXYGENATION, % MINIMUM VOL
MINIMUM DEPOSITS REQUIRED IN THE TEST ASTM D5500 (AVARAGE) (mg/valve)
ADJUSTED WHITOUT OXYGENATING
80
170
11.4
31.1
0
290
REGULAR OXYGENATING
80
170
11.4
31.1
5.8 ETHANOL OR 11 MTBE
290
(4) The application of the methods of test ASTM D2699 and ASTM D2700 through instruments , cited in these standards are required to determine the quality of production and import. The use of them analysis of reference based in them methodologies Mid-IR (Mid-Infrarred) and Near-IR (Near-Infrarred) for the determination of the index of octane, MON and RON to is refers the standard in its numeral 6.3, are applicable exclusively for effects of them tests of control referred in the present section, for which is accepts a tolerance maximum of 0.3 numbers of octane with regard to the retrieved previously through them methods ASTM D2699 and ASTM D2700. SPECIFICATIONS ADDITIONAL OF GASOLINE PROYECTO ZONA 1 LIMIT VALUE PROPERTY
UNIT
TEST METHOD GASOLINE PREMIUM
GASOLINE REGULAR
AROMATIC
% VOL
TYPES OF HIDROCARBONS IN PRODUCTS LIQUIDS OF PETROLEUM BY ABSORPTION OF FLUORESCENT INDICATOR (ASTMD1319)
32.0 MAXIMUM
INFORM
OLEFINS
% VOL
TYPES OF HIDROCARBONS IN PRODUCTS LIQUIDS OF PETROLEUM BY ABSORPTION OF FLUORESCENT INDICATOR (ASTMD1319)
12.5 MAXIMUM
INFORM
BENZENE
% VOL
DETERMINATION OF BENZENE AND TOLUENE IN PETROL COMPLETED FOR USE IN ENGINES AND AVIATION BY GAS CHROMATOGRAPHY (ASTM D3606, D5580, D6277)
2.0 MAXIMUM
2.0 MAXIMUM
TOTAL SULPHUR
mg/Kg
DETERMINATION OF TOTAL SULPHUR IN LIGTH HYDROCARBONS (ASTM D5453, D2622, D7039, D7220)
30 AVARAGE (1), 80 MAXIMUM (2)
% MASS
DETERMINATION OF MTBE, ETBE, TAME, DIPE AND ALCOHOLS TO C4IN GASOLINE BY CHROMATOGRAPHY GAS (ASTM D4815) DETERMINATION OF MTBE, ETBE, TAME, DIPE, ATHANOL AND TERBUTANOL IN GASOLINE BY INFRARED SPECTROSCOPY (ASTM D5845)
2.7 MAXIMUM
OXYGEN
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SPECIFICATIONS ADDITIONAL OF GASOLINE PROYECTO ZONA 2 LIMIT VALUE PROPERTY
UNIT
TEST METHOD PREMIUM AND REGULAR GASOLINE
AROMATIC
% VOL
TYPES OF HIDROCARBONS IN PRODUCTS LIQUIDS OF PETROLEUM BY ABSORPTION OF FLUORESCENT INDICATOR (ASTMD1319)
32.0 MAXIMUM 25.0 MAX TO STARTING FROM THE 1ST OF JANUARY 2020
OLEFINS
% VOL
TYPES OF HIDROCARBONS IN PRODUCTS LIQUIDS OF PETROLEUM BY ABSORPTION OF FLUORESCENT INDICATOR (ASTMD1319)
11.9 MAXIMUM 10.0 MAX TO STARTING FROM THE 1ST OF JANUARY 2020
BENZENE
% VOL
DETERMINATION OF BENZENE AND TOLUENE IN PETROL COMPLETED FOR USE IN ENGINES AND AVIATION BY GAS CHROMATOGRAPHY (ASTM D3606, D5580, D6277)
1.0 MAXIMUM
TOTAL SULPHUR
mg/Kg
DETERMINATION OF TOTAL SULPHUR IN LIGTH HYDROCARBONS (ASTM D5453, D2622, D7039, D7220)
30 AVARAGE (1) 80 MAXIMUM (2)
% MASS
DETERMINATION OF MTBE, ETBE, TAME, DIPE AND ALCOHOLS TO C4IN GASOLINE BY CHROMATOGRAPHY GAS (ASTM D4815) DETERMINATION OF MTBE, ETBE, TAME, DIPE, ATHANOL AND TERBUTANOL IN GASOLINE BY INFRARED SPECTROSCOPY (ASTM D5845)
1.02.7 MAXIMUM
OXYGEN
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Gerardo Rodriguez PETROLAND S.A. DE C.V. www.petroland.com.mx Member PETROLEUM EQUIPMENT INSTITUTE http://www.pei.org/about