Lab Management and Science Issue 6 2018

Page 8

ME TRO LO G Y

Alas, poor kilogram!

Your 50-parts-in-a-billion fluctuations will not be missed

Photo credit: NIST

Advanced measuring instruments like the NIST-4 Kibble balance have enabled a redefinition of SI units like the kilogram. The quadrennial General Conference on

the copies and original. The physical

of the triple point of water, but it s not

Weights and Measures (GCWM) doesn’t usually

substance of the IPK was also subject to

possible to prepare two exactly identical

make the evening news, but it got a mention

natural degrading processes, resulting in

formulations of the isotopic mixture

on Friday 16 November when it redefined the

extremely small fluctuations in weight, as

of water required for this test. New

definition of four commonly used units of

small as 50 parts in a billion. While these are

advances in acoustic thermometry

measurement, including the kilogram. Also

not significant fluctuations if you’re weighing

have resulted in extremely accurate

affected were the ampere, kelvin and mole, so

meat at the butcher’s, they become extremely

measurements of the Boltzmann

that altogether four of the seven measurement

important if you are, for example, conducting

units that comprise the International System

experiments at a subatomic level.

of Units (SI) were changed. Instead of linking the SI units to physical

constant. jjThe ampere will now be measured

Fundamental forces of nature remain

according to the elementary electrical

consistent and can be measured far more

charge. Where the past definition relied

artefacts, the revision ties their values

precisely, hence the GCWM’s decision

on the charge in newtons between

to fundamental physical constants that

to adopt the following as the constants

two wires containing 1 ampere each

allow for far more precise measurements.

underlying SI measurements:

and separated by a distance of 1 metre,

Since 1889, the kilogram, for example, was

jjThe kilogram will be linked to Planck’s

the new definition is refreshingly

linked to the weight of a platinum/iridium

constant. The Planck constant relates a

straightforward: 1 ampere equals

compound cylinder referred to as the

light particle s energy, and hence mass, to

International Prototype of the Kilogram (IPK),

its frequency. New measuring technology

colloquially known as Le Grande K. While the

like NIST-4 Kibble balance can measure

constant. In the present metric system,

original was carefully housed in a sealed

the constant with incredible accuracy.

a mole is the amount of substance that

glass container in a suburb of Paris, copies

1 coulomb per second. jjThe mole will be linked to the Avogadro

jjThe kelvin will be linked to the

contains as many elementary entities

of the IPK were distributed to measurement

Boltzmann constant. This constant

as there are atoms in 0.012 kilograms

associations around the world.

relates temperature to energy by means

of carbon-12. The Avogadro constant is

of statistical mechanics. Previously,

expressed as the number of molecules in

the kelvin was measured as a fraction

one gram-molecule of oxygen. M

Eventually it was discovered that there were miniscule variations in weight between

The new defining constants of the International System of Units Defining constant Hyperfine transition frequency of Cs

8

LMS  Issue 6 | 2018

Symbol

Numerical value

Unit

∆vCs

9 192 631 770

Hz

Speed of light in a vacuum

c

299 792 458

m s-1

Planck constant

h

6.626 070 15 x 10-34

Elementary charge

e

1.602 176 634 x 10

Boltzmann constant

k

1.380 649 x 10-23

J K-1

Avogadro constant

NA

6.022 140 76 x 1023

mol-1

Luminous efficacy

Kcd

683

lm W-1

-19

J Hz-1 C

w w w.lm s m a g a z i n e .c o. z a


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