Rapid prototyping and engineering of plant‐based natural products - Prof Anne Osbourn

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Rapid prototyping and engineering of plant-based products Anne Osbourn anne.osbourn@jic.ac.uk


Plants are a rich source of drugs and other high-value compounds


Triterpenes – examples of plant metabolic diversity Sapindus mukorossi Avena sativa

S. Mukorossi saponin

Avenacin A-1

Molluscicidal effects

Antifungal/ Allelopathy

Plant defence Medicago truncatula

Insecticidal properties

Anti-feedant

Soyasaponin βg 3-GlcA-28-Ara-Rha-Xyl-medicagenate

Glycine max


Triterpenes – examples of plant metabolic diversity Cucumis sativus

Glycyrrhiza uralensis

Cucurbitacins

Anti-tumoral

Glycyrrhizin

Anti-inflammatory

Pharmacological properties Many reported uses

Vaccine adjuvant

Panax ginseng

Ginsenosides

Quillajasaponin

Quillaja saponaria


Avenacin A-1 – An antimicrobial defence compound produced by oat (Avena spp.)

Avenacin A-1

Papadopoulou et al. (1999) PNAS 96:12923


The genes for avenacin biosynthesis are organized in a biosynthetic gene cluster


The biosynthetic pathways for many diverse plant specialized metabolites are encoded by co-localized genes

Nutzmann & Osbourn, Curr Opin. Biotechnol. 2014


The biosynthetic pathways for many diverse plant specialized metabolites are encoded by co-localized genes


HyperTrans - A simple system for rapid transient plant expression

Sainsbury F and Lomonossoff G. (2008) Plant Phys. 148:1212


Advantages of a plant-based expression system • Availability of precursors and co-enzymes • mRNA and protein processing • Localisation and compartmentalisation


Improved vacuum infiltration

Pressure reduced by 880 mbar


Gram quantities of purified triterpene

Michael Stephenson


Generation of structural analogs of oxygenated triterpenes in milligram quantities for bioassays

James Reed, Maria O’Connell m/s submitted

Reference compound: Bardoxolone-methyl A semi-synthetic triterpenoid derived from oleanolic acid.


Assembly of the 11-gene cluster for avenacin biosynthesis in N. benthamiana

Avena (oat)

Nicotiana benthamiana

Accumulation of acylated terpene in the vacuole


Mining for new pathways and chemistries

PREDICT

BUILD

TEST


A pilot and production business on the Norwich Research Park with a purpose-built facility employing the HyperTransÂŽ expression system:


Harnessing plant metabolic diversity Identification/validation of bioactives: • Bioactive discovery (e.g. new antimalarials) • Support local knowledge

PARTNERSHIPS WITH DEVELOPING COUNTRIES: KNOWLEDGE SHARING, TRAINING, Commercial production through CO-LEARNING, BUILDING INFRASTRUCTURE, bioengineering: SUSTAINABLE ECONOMIC DEVELOPMENT, PRESERVING BIODIVERSITY, SOCIETAL BENEFIT

Transient plant expression technology

Production in yeast

Production in the field



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