The effect of mycorrhizal inoculation (Glomus mosseae) and brassinosteroid on the amount of antioxid

Page 1

Journal of Research in Ecology

Journal of Research in Ecology

ISSN No: Print: 2319 –1546; Online: 2319– 1554

An International Scientific Research Journal

Original Research

The effect of mycorrhizal inoculation (Glomus mosseae) and brassinosteroid on the amount of antioxidants in Pimpinella anisum l. under cadmium stress Authors: Sepideh Hajbagheri1, Hosein Abbaspour2, Shekoofeh Enteshari3, Saeed Habibollahi4 and Alireza Iranbakhsh5

ABSTRACT: Heavy metals are important environmental pollutants and their toxicity is considered as a major problem, because of ecological, evolutionary, environmental and nutritional effects. Many studies have shown that plants inoculated with mycorrhizal fungi or the use of brassinosteroids increased plants resistance to heavy metals. In this study, the effect of mycorrhiza inoculation with Glomus mosseae and 24-epibrassinolid (10-6 µM) on Pimpinella anisum antioxidants against cadmium Institution: chloride stress (0, 100, 200 and 800 ppm) were investigated and compared in green 1. PhD Student, Azad house and hydroponic condition. The results showed that cadmium stress reduced University, Iran shoot protein content, but amount of H2O2, flavonoid, flavonol and phenolic 2. Biology Department, compound increased. The activity of catalase, superoxide dismutase, peroxidase, Azad University, Iran polyphenol oxidase increased significantly in cadmium treatments. When plants were pretreated with brassinosteroid and inoculated with mycorrhizal fungi and then 3. Biology Department, Payam Noor University, Iran treated with cadmium H2O2 have reduced some antioxidative parameters such as flavonoid and anthocyanin content, and activity of ascorbate peroxidase, peroxidase 4. Chemistry Department, and polyphenol oxidase increased significantly. Therefore, it can be concluded that in Payam Noor University, this plant brassinosteroid application or mycorrhizal inoculation have positive effects Iran. on strengthening the antioxidant system in this plant against cadmium stress. 5. Professor of Biology Keywords: Department, Azad Glomus mosseae, brassinosteroid, cadmium chloride, Pimpinella anisum. University, Iran Corresponding author: Shekoofeh Enteshari

Email ID: Article Citation: Sepideh Hajbagheri, Hosein Abbaspour, Shekoofeh Enteshari, Saeed Habibollahi and Alireza Iranbakhsh The effect of mycorrhizal inoculation (Glomus mosseae) and brassinosteroid on the amount of antioxidants in Pimpinella anisum l. under Cadmium stress Journal of Research in Ecology (2017) 5(2): 1033-1051 Dates: Received: 23 July 2017 Web Address: http://ecologyresearch.info/ documents/EC0483.pdf

Journal of Research in Ecology An International Scientific Research Journal

Accepted: 26 Aug 2017

Published: 01 Sep 2017

This article is governed by the Creative Commons Attribution License (http://creativecommons.org/ licenses/by/4.0), which gives permission for unrestricted use, non-commercial, distribution and reproduction in all medium, provided the original work is properly cited.

1033-1051| JRE | 2017 | Vol 5 | No 2

www.ecologyresearch.info


Hajbagheri et al., 2017 INTRODUCTION

ed metals through secreted compounds such as catego-

Plants in nature are constantly exposed to the per-

rizing the metals inside the fungal cells. The beneficial

sistent presence of heavy metal toxic ions and experi-

effects of mycorrhizal on growth in terms of heavy met-

ence the damage of their cumulative toxicity. Toxic

al toxicity have been reported in many plant species

effects of heavy metals are mainly related to these four

(Leung et al., 2013; Sharma and Sharma, 2013; Upadh-

factors: disabling the active groups of enzymes, replac-

yaya et al., 2010). Mycorrhizal fungi regulated the bal-

ing instead of essential metals, inducing structural

ance of nutrients absorption that has been disturbed by

changes to polymers and affecting the strength and

heavy metals and improves the toxicity of metals in

structure of the membrane and the membrane transport

soils contaminated with heavy metals (Singh et al.,

processes (Tangahu et al., 2011). Cadmium with the

2012). It has been reported that G. mosseae is resistant

symbol Cd and atomic number 48 is one of the most

to cadmium and plays a role in absorption, transport and

toxic heavy metals. Weathering of rocks, forest fires and

inactivity of cadmium (Upadhyaya et al., 2010).

volcanoes, human activities such as industrial waste

Brassinosteroids are from steroid hormones and

leachates, the production of artificial phosphate fertiliz-

a new group of plant growth regulators that are widely

ers are the important sources of cadmium in the environ-

distributed throughout the plant kingdom. Due to the

ment. Cadmium accumulation in plant tissues reduced

multiple effects of the hormone, these compounds are

the cell division, root growth, root hydraulic conductivi-

known as plant hormones. This hormone stimulate the

ty and causes growth inhibition, chlorosis and cell death

growth and protein synthesis, increase the content of

(Liu et al., 2011).

compatible solutes, changes in transcription and expres-

Today, a lot of research focused on the use of

sion of genes involved in stress, and the concentration

growth regulators or mycorrhizal fungi in reducing the

and activity of antioxidant enzymes and compounds that

effects of environmental stresses. In endo-mycorrhizal

all reduce the harmful effects of stress in plants in order

coexistences, the mycorrhizal fungi play an important

to maintain, and enhance the performance of the plant

role in host plants protection against the toxicity of

(Ahammed et al., 2012; Zhang et al., 2008). The studies

heavy metals. Mycorrhizal fungi change the heavy met-

have shown that the both endogenous and exogenous

al concentration through metal inactivity and the chelat-

brassinosteroids have an antioxidant role, and reduce the Glomus mosseae G.m* Br

Figure 1. The effect of cadmium chloride and brassinosteroid on Pimpinella anisum root mycorrhizal colonization percentage by Glomus mosseae (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) 1034

Journal of Research in Ecology (2017) 5(2): 1033–1051


Hajbagheri et al., 2017 Control Brassinosteroid Glomus mosseae G.m.* Br

Figure 2. The effect of G. mosseae, brassinosteroid and cadmium on the protein content of Pimpinella anisum shoot (a) and root (b) (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) stress damage (Chandler et al., 2009; Zhang et al.,

mutase, catalase, ascorbate peroxidase, peroxidase, pol-

2008). Some researchers showed that brassinosteroids

yphenol oxidase and the non-enzymatic antioxidants

have a significant effect on plant resistance against the

such as anthocyanins and phenolics. Superoxide dis-

accumulation of heavy metals in beans (Ali et al., 2008)

mutase dismutation catalyzes two superoxide molecules

and pea (Hasan et al., 2008).

to H2O2 and H2O2 should detoxificate the antioxidant

Oxidative stress caused by the accumulation of

defense in the next steps. Catalase enzyme breaks down

heavy metals in plants leads to the production of reac-

H2O2 to water and oxygen and is considered as the main

tive oxygen species and oxidative damage in the cells.

enzymes that sweep the Hydrogen Peroxide in peroxi-

One of the most important plant defense systems to con-

somes. (Shi and Zhu, 2008). Ascorbate peroxidase en-

trol and neutralize the free radicals is to induce the syn-

zymes revive hydrogen peroxide in different cell parts

thesis of antioxidant enzymes such as superoxide dis-

in water with the help of ascorbate as an electron donor. Control Brassinosteroid Glomus mosseae G.m.* Br

Figure 3. The effect of G. mosseae, brassinosteroid and cadmium on the hydrogen peroxide content of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) Journal of Research in Ecology (2017) 5(2): 1033–1051

1035


Hajbagheri et al., 2017 Control Brassinosteroid Glomus mosseae G.m.* Br

Figure 4. The effect of G. mosseae, brassinosteroid and cadmium on the catalase activity of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) Peroxidases cause the decomposition of hydrogen per-

pounds with free radicals and convert them into their

oxide by the oxidation of a substance. Polyphenol oxi-

stable form electrons to these reactive radicals (Bartwal

dase is mono-oxygenase enzyme with copper that leads

et al., 2013).

to hydroxylation of phenols to di-phenyls and the oxida-

In general, the adaptation or resistance to stress

tion of di-phenyls (Abdul-Jaleel et al., 2009). Phenolic

depends on the reduction of the amount of reactive oxy-

compounds such as flavonoids, flavonols and phenols

gen species by antioxidant system. Treatment of plants

are a large group of secondary plant products with only

with epi-brassinolide and inoculation with mycorrhizal

one phenolic group. Anthocyanins are a group of water-

fungi increases the activity of antioxidant enzymes and

soluble flavonoids that are made in the biosynthesis of

phenolic compounds compared to untreated plants

flavonoids in the cytoplasm. Anthocyanin's do not only

which increases the resistance of plants against various

destroy the free radicals but also prevent their produc-

stresses such as the heavy metals (Abdul-Jaleel et al.,

tion in the plant. Antioxidant properties are the phenolic

2009; Ahammed et al., 2012).

compounds resulting from the reaction of these com-

Anisum with the scientific name of Pimpinella aniControl Brassinosteroid Glomus mosseae G.m.* Br

Figure 5. The effect of G. mosseae, brassinosteroid and cadmium on the ascorbate peroxidase activity of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) 1036

Journal of Research in Ecology (2017) 5(2): 1033–1051


Hajbagheri et al., 2017 Control Brassinosteroid Glomus mosseae G.m.* Br

Figure 6. The effect of G. mosseae, brassinosteroid and cadmium on the superoxide dismutase activity of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) sum L. belongs to the Apiaceae family, Apiales order

cations in completely randomized factorial design. The

and known as medicinal plant that contains the ingredi-

applied treatments included: cadmium chloride at 0,

ents such as essential oils, resins, sugar compounds and

100, 200 and 800 ppm concentration, mycorrhizal fungi

oil. Anisum has the antibacterial property and an ex-

(G. mosseae) and brassinosteroids (10-6mM).

traordinary importance in the pharmaceutical industry (Omidbeygi, 2006). The purpose of this study is to compare the role of brassinosteroids and G. mosseae inoculation in increas-

The seeds of the Pimpinella anisum L. were prepared from Pakan Bazr Company in Isfahan (IRAN), were rinsed three times by 10% sodium hypochlorite and washed with distilled water some times.

ing the resistance of P. anisum through the increase of

For the inoculation of seeds with G. mosseae on

enzymatic and non-enzymatic antioxidants against the

Petri dishes, seeds were excluded on 5 g of biological

cadmium chloride stress.

soil containing mycorrhizal spores of G. mosseae prepared from Hamedan Organic Plant Clinic (IRAN). The

MATERIALS AND METHODS This experiment was performed with three repli-

biological soil contained 15 spores per gram and 930 propagules per cubic centimeter. For non-inoculated Control Brassinosteroid Glomus mosseae G.m.* Br

Figure 7. The interaction of G. mosseae, brassinosteroid and cadmium on the polyphenol oxidase activity of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) Journal of Research in Ecology (2017) 5(2): 1033-1051

1037


Hajbagheri et al., 2017 Control Brassinosteroid Glomus mosseae G.m.* Br

Figure 8. The effect of G. mosseae, brassinosteroid and cadmium on the peroxidase activity of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) case seeds were excluded on filter paper impregnated

was placed on this and covered with perlite and co-

with distilled water. Petri dishes was put in germinator

copeat mixture. For each treatment, three pots were used

with optical/dark conditions for 16:8 hours, at day/night

and so considered considered as three replicates. In each

in the 23±2°C and 16±2°C temperatures respectively for

pot, five seedlings were planted. Pots were put in green-

4 weeks and after wards transferred to pots (Hewitt,

house with the optical condition of 14:10 light/night

1966).

hours, and 17 ± 2°C and 24 ± 2°C night/day temperature Seedlings were transferred in plastic pots with

respectively. Light intensity was 11,000 lux and humidi-

16 cm diameter and 15 cm height. In each pots, the

ty was 60%. For watering pots, distilled water and Long

mixture of autoclaved perlite and coco peat was poured

Ashton nutrient solution were used (Hewitt, 1966).

with 1:3 ratio. For mycorrhizal treatments in each pot,

Brassinosteroids treatments were applied after

50 g of mycorrhizal spores soils were poured on the

150 days of germination when the fourth leaf of the

surface of perlite and cocopeat mixture and seedling

plants were grown and plants were sprayed with a soluControl Brassinosteroid Glomus mosseae G.m.* Br

Figure 9. The effect of G. mosseae, brassinosteroid and cadmium on the anthocyanin content of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) 1038

Journal of Research in Ecology (2017) 5(2): 1033–1051


Hajbagheri et al., 2017 Control Brassinosteroid Glomus mosseae G.m.* Br

Figure 10. The effect of G. mosseae, brassinosteroid and cadmium on the flavonoid content of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) tion of 10-6 µM 24-epibrassinolide (Sigma (USA),

lin-acetic acid-ethanol (FAA) in the 14: 1: 1 ratio. Then

MW=480.7), 3 times every 72 hours at the beginning of

the roots were painted with fuchsine acid color and the

the optical phase. Control plants were sprayed with dis-

percentage of inoculated root was measured by using

tilled water. Three days after the last brassinosteroid

anatomical microscope Olympus model.

treatment, the cadmium chloride (100, 200 and 800 ppm

Determination of protein

CdCl2½H2O, MW=228.34) treatment was applied three

Total soluble protein content was measured ac-

times within 72 hour and the control plants were irrigat-

cording to Bradford (1976) using Bovine Serum Albu-

ed with distilled water. Plants were harvested 48 hours

min (BSA) as a protein standard. In each test tube to

after the last Cadmium treatment and some parameters

extract leaf protein, 250 microliter phosphate buffer,

were studied (Hewitt, 1966).

250 microliter of 1 M NaOH solution and 5 ml of Brad-

Root mycorrhizal colonization percentage

ford reagent were added. Then final volume of each

For this measurement, Rajapakes and Miler

tube was made up to 6 ml. The contents of each tube

(1992) method was used. For root fixation using forma-

were mixed in vortex and after 2 minutes the absorption Control Brassinosteroid Glomus mosseae G.m.* Br

Figure 11. The effect of G. mosseae, brassinosteroid and cadmium on flavonol content of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) Journal of Research in Ecology (2017) 5(2): 1033-1051

1039


Hajbagheri et al., 2017 Control Brassinosteroid Glomus mosseae G.m.* Br

Figure 12. The effect of G. mosseae, brassinosteroid and cadmium on the Phenol content of P. anisum (Dis similar letters indicate significant statistical comparison of treatments based on Duncan test (p≤0.05)) was read at a wavelength of 595 nm with UV visible

Determination of Antioxidant enzyme activity

spectrophotometer 1601 model (Bradford, 1976).

Catalase

Determination of hydrogen peroxide

Catalase (CAT) activity assay was based on

0.5 g of leaf tissue in phosphate buffer 3 ml

reduceing the amount of hydrogen peroxide at 240 nm

pH=6.8 was homogenized. The resulting extract was

wavelength for one minute. The reaction mixture con-

centrifuged for 25 min at 6000 g. To determine the

taining 100 mM potassium phosphate buffer, 15 mM

amount of hydrogen peroxide 3 ml the resulting extract

hydrogen peroxide and 100 ml enzyme extract

was removed and the 1 ml chloride titanium 0/1% in

(Extraction enzyme extract: 0.25 grams of leaf tissue

sulfuric acid at 20% (v/v) was added and the solution

were worned by liquid nitrogen and poured into eppen-

was centrifuged for 15 min at 6000 g. The absorption of

dorf 1.5 ml. Then 50 mM potassium phosphate buffer

resulting solution was read by the UV-visible spectro-

(pH = 7.5) containing 11% Triton was added to every

photometer 1601 model at 410 nm and hydrogen perox-

eppendorf 1 ml. All Extraction steps were performed on

ide content was measured according to Jana and

ice and samples were placed in the refrigerator for one

Choudhuri (1982) method.

hour. The extracts were centrifuged for 15 min at 4 °C at 15000 g. The supernatant was used to measure enzyme activity) in a final volume of 3 ml. Enzyme activi-

Figure 13. Microscopic image from the control of Pimpinella anisum root (non-mycorrhizal) (10X)

1040

Journal of Research in Ecology (2017) 5(2): 1033–1051


Hajbagheri et al., 2017

Figure 14. Microscopic image from the mycorrhizal colonization of P. anisum root (10X) ty was determined using the extinction coefficient of

maximum color without enzyme extract were decreased

3/94 mM-1cm-1 calculated on the basis of a unit (mol

in absorbance decreased with enzyme addition. The

hydrogen peroxide consumed per minute) per mg pro-

absorbance was recorded by the UV-visible spectropho-

tein (Aebi, 1984).

tometer 1601 model at 560 nm (Gianopolitis and Ries,

Super oxide dismutase

1977).

Super oxide dismutase (SOD) was assayed by

Ascorbate peroxidase

measuring its ability to inhibit the photochemical reduc-

Ascorbate peroxidase (APX) activity was deter-

tion of Nitro Blue Tetrazolium (NBT). The reaction

mined by the decrease in absorbance of ascorbate at 290

mixture contained 50mM potassium phosphate buffer

nm. The reaction mixture contained 50 mM potassium

(pH=7.5), 13 mM L-methionine, 75 μM NBT, 3 μM

phosphate buffer (pH=7), 0.5 mM ascorbate, 1 mM

riboflavin, 0.1 mM EDTA and 100 μM of enzyme ex-

H2O2, 0.1 mM EDTA and enzyme extract. APX activi-

tract. Riboflavin was added at the mixture. The tubes

ty was calculated by using extinction coefficient 2.8

were properly shaken and placed 30 cm below light

mM-1 cm-1 (Nakano and Asada, 1981).

source from two 100 W fluorescent lamps. The reaction

Peroxidase

was started by switching on the light and terminated

For this assay, 50 μl of enzyme extract, 100 mM

after 20 min of incubation by switching off the light.

phosphate buffer (pH=7.0), 200 µl of 10 mM pyrogallol

After terminating the reaction, the tubes were covered

and 300 μl of 5 mM H2O2 were added. After incubation,

with black cloth to protect them from light. A non-

the reaction was stopped by adding 1.0 ml of 2.5 N

illuminated reaction mixture that did not develop color

H2SO4. The amount of pur-purogallin formed was esti-

served as the blank. The reaction mixture that developed

mated by measuring the absorbance at 420 nm (Kar and

Figure 15. Microscopic image from the mycorrhizal colonization of Pimpinella anisum root in Glomus mosseae + brassinosteroid treatment (10X) Journal of Research in Ecology (2017) 5(2): 1033-1051

1041


Hajbagheri et al., 2017 Mishra, 1976).

curve (Akkol et al., 2008).

Polyphenoloxidase

Flavonoid

2.8 mL of phosphate buffer at monosedic 25

For total flavonoid assay1 mL of methanolic

mM with pH=6.8 was added to pyrogallol 10 mM and

extract, 250 μL of aluminum chloride solution and 250

100 ml of the enzyme extract. Enzyme activity was

μL of potassium acetate were mixed and the samples

measured at 420 nm using UV-visible spectrophotome-

remained at room temperature for 30 min. The absorb-

ter 1601 based on the Orange color intensity of poor-

ance of their action mixture was measured at 415 nm

porogalin in times of 40 and 100 seconds after the addi-

with the UV-visible spectrophotometer 1601 model

tion of pyrogallol measured (Kar and Mishra, 1976).

(Akkol et al., 2008).

Determination of non-enzymatic antioxidants

Statistical analysis

Anthocyanin

This experiment was performed with three repli-

Total anthocyanin was determined according to

cations in factorial design. Data analysis were per-

modified Wagner (1979) method using acidified ethanol

formed using SAS, version 15 and MSTAT-C statistical

(ethanol: HCl 99: 1 v/v) as 0.05 g of frozen leaf was

software. Compared using the Duncan test at the 5%

homogenized in 2.5 ml acidified ethanol and then kept

level, and the graphs were drawn by Excel software

at 25°C for 24 h in the dark. The extract was centrifuged

(Bazargan, 2017).

at 4000 g for 10 min at room temperature. The absorbance of each supernatant was read at 550 nm. The ex-

RESULTS

tinction coefficient 33,000 (mol-1cm-1) was used to

Mycorrhizal colonization in root

calculate the amount of total anthocyanin and it was

The results of this study showed that the roots

expressed as μmolg-1FW (Wagner, 1979).

mycorrhizal colonization percentage decreased in 200

Phenol

and 800 ppm cadmium chloride concentrations but 0.05 g of lyophilized cells were in 3 ml of ho-

brassinosteroid treatment significantly increased this

mogenized 80% methanol and 3 hours in Ben Murray at

parameter in all levels of cadmium chloride. The highest

70° C was placed. Then it was centrifuged at 9000 x g

percentage of root mycorrhizal colonization was in

for 15 minutes and methanol extract was separated from

brassinosteroid treatment and the lowest was in 800

the sediment. Methanol extracts to measure total phe-

ppm of cadmium chloride treatment (Figure 1 and 2,

nols, flavonoids and flavonoids were used.

Image 1-3).

To 50 µl of methanol extract, 500 µl Folin -

Hydrogen peroxide

Ciocalteau solution was added. After five minutes 500

The results of this study showed that cadmium

ml of 7% sodium carbonate solution was added to the

chloride caused a significant increase in the amount of

mixture and absorption at 765 nm was read after 10

hydrogen peroxide. Interactions of brassinosteroid,

minutes. Finally, total phenol content in mg/g dry

G. mosseae and G. mosseae + brassinosteroid with all

weight was measured (Singleton and Rossi, 1965).

levels of cadmium chloride significantly reduced this

Flavonol

parameter (Figure 3).

For total flavonol assay 1 mL of methanolic

Catalase

extract, 1 mL of aluminum chloride solution and 3 mL

Results of this study showed that catalase activi-

of sodium acetate were mixed and absorbance was read

ty increased significantly in 200 and 800 cadmium chlo-

at 445 nm. Rutin was used as a standard for calibration

ride treatments. Treatment with brassinosteroid and

1042

Journal of Research in Ecology (2017) 5(2): 1033–1051


Hajbagheri et al., 2017 G. mosseae + brassinosteroid increased significantly

Anthocyanin

this parameter. In the interactions of brassinosteroid,

Anthocyanin content increased significantly in

G. mosseae and Glomusmosseae + brassinosteroid with

interactions

200 and 800 ppm of cadmium chloride the activity of

G. mosseae and brassinosteroid with 0, 100 and 200

this enzyme significantly decreased (Figure 4).

ppm of cadmium chloride (Figure 9).

Ascorbate peroxidase

Flavonoid

The results of this study showed that ascorbate

of

G.

mosseae

+

brassinosteroid,

Flavonoid content increased significantly in

peroxidase activity increased significantly in 200 ppm

interactions

cadmium chloride and G. mosseae treatments groups. In

G. mosseae and brassinosteroid with 0, 100 and 200

interactions

and

ppm of cadmium chloride. In the other hand this param-

G. mosseae + brassinosteroid with 100 and 800 ppm of

eter reduced significantly in all treatment group with

cadmium chloride the activity of this enzyme increased

800 ppm cadmium chloride (Figure 10).

significantly (Figure 5).

Flavonol and Phenol

of

brassinosteroid,

G.

mosseae

G.

mosseae

+

brassinosteroid,

The results of this study showed that flavonol

Superoxide dismutase Results of this study showed that the activity of

of

and

phenol

content

increased

significantly

in

superoxide dismutase increased significantly in the 200

G. mosseae and G. mosseae + brassinosteroid. But re-

and 800 ppm cadmium chloride, brassinosteroid, plants

duced significantly in brassinosteroid, G. mosseae and

G. mosseae and G. mosseae + brassinosteroid treat-

G. mosseae + brassinosteroid with all concentration of

ments. In interactions of brassinosteroid, Glomus

cadmium chloride (Figures 11 and 12).

mosseae, G. mosseae + brassinosteroid with all levels of cadmium chloride activity of this enzyme significantly

DISCUSSION

decreased (Figure 6).

One of the most important indicators of mycor-

Polyphenol oxidase

rhizal fungi activity is the colonization percentage that

The results of this study showed that activity of

is affected by several factors such as appearance and

the polyphenol oxidase enzyme increased significantly

structural properties of the root system, the quantity and

in the 200 and 800 ppm cadmium chloride, G. mosseae

quality of root exudates, the use of fertilizers and of

and G. mosseae + brassinosteroid. In interactions of

high concentrations of heavy metals (Al –Karaki, 2000).

brassinosteroid, Glomus mosseae, G. mosseae + brassi-

In general, the negative effects of high concentrations of

nosteroid with all levels of cadmium chloride the activi-

heavy metals on root colonization with mycorrhizal

ty of this enzyme significantly increased (Figure 7).

fungi have been observed in the root system of plants.

Peroxidase

For example, it has been reported that the spores of Glo-

Results of this study showed that of peroxidase

mus intraradices fungus do not germinate in 1 mM or

activity significantly increased in all levels of cadmium

10 mM cadmium concentration (Pawlowska and Char-

chloride. In interaction of brassinosteroid and all levels

vat, 2004).

of cadmium chloride the activity of this enzyme signifi-

In this study, cadmium toxicity reduced the my-

cantly increased. In interaction of G. mosseae + brassi-

corrhizal contamination of anisum root with G. mosseae

nosteroid and G. mosseae with 100 and 200 ppm of cad-

fungus. In mycorrhizal communities, the fungus is en-

mium chloride the activity of this enzyme significantly

tirely dependent on the plant growth and nutrition’s pro-

increased (Figure 8).

duction in the host plant. Thus, any factor which affects

Journal of Research in Ecology (2017) 5(2): 1033–1051

1043


Hajbagheri et al., 2017 the production of carbohydrates and its transfer to the

cadmium, and magnesium reduced

roots can effect on the amount of contamination. Since

maize, this may be due to the very close relationship

heavy metal stress reduced the plant growth, it can also

between heavy metals types and the side-chain of pro-

reduce the mycorrhizal inoculation (Asghari, 2008). In

teins (Ghani and Wahid, 2007). Doganlar et al. (2012)

the same reports, the mycorrhizal contamination was

reported that the protein content reduced in high con-

reduced under cadmium toxicity in wheat plants that

centrations of manganese and nickel in Lemna and this

inoculated with Glomus intraradices (Jamalabad and

effect may be due to the protein degradation caused by

Khara, 2008) and Cajanus cajan plant inoculated with

oxidative stress (Doganlar et al., 2012). In the sunflower

G. mosseae (Garg and Bhandari, 2012).

that treated with cadmium, oxidized proteins were gath-

Plant hormones play an important role in mycorrhizal symbiosis. Plant hormones or phytohor-

protein content in

ered in cotyledons and leaves and the protease activity increased significantly (Pena et al., 2007).

mones are involved in signaling pathways and regula-

In this study the pre-treatment of plants with

tion of this symbiosis at different stages of plant growth

brassinosteroids, the inoculated plants with G. mosseae

(Jutta, 2000). In this study, brassinosteroids has a stimu-

and the interaction of G. mosseae and brassinosteroids,

lating role in mycorrhizal inoculation under control and

the shoot protein increased at 200 and 800 ppm concen-

cadmium toxicity conditions. Some experiments have

tration of cadmium chloride but the root protein content

shown that brassinosteroids, gibberellin and cytokinine

increased at 100 and 200 ppm concentrations of cadmi-

are needed for the early stages of root mycorrhizal con-

um chloride. Studies showed that brassinosteroids have

tamination and are not involved in the next stages of

a positive effect on the processes of DNA and RNA

coexistence (Hanlon and Coenen, 2011).

modeling and protein synthesis to enhance the plant

The results of this study showed that the protein

growth. Fariduddin et al. (2009) reported that the use of

content significantly decreased in 800 ppm of cadmium

brassinosteroids increased the amount of protein in cab-

chloride. Some researchers believed that protein reduc-

bage under copper stress (Fariduddin et al., 2009). In

tion could be due to the induction of oxidative stress,

Lycopersicon esculentum plants under salinity stress,

proteases activity, changes in the proteins structure and

the interaction of 24-Epibrassinolide and putrescine

function through denaturation and fragmentation and the

increased the protein content and antioxidant enzymes

replacement of metals in the thiol groups of protein

and reduce the harmful effects of salinity stress (Sharma

(Rastgoo and Alemzadeh, 2011). Cadmium stress

et al., 2012).

changed protein structure or replacing a vital element

Based on some studies insoluble glycoprotein

for the activities of essential enzymes and protein con-

synthesis is one of the resistant mechanisms in mycor-

tent of the plants. The heavy metal inhibits sulfydryl

rhizal plants against heavy metals such as cadmium.

groups of structural proteins and guides the enzymes to

These proteins have link places with heavy metals and

incorrect folding and activity inhibitory. This compo-

have a positive role for plant protection by linking to

nent reduced the production of proteins and stops the

heavy metals. (Trotta et al., 2006). In a similar report on

growth with a disorder in nitrogen metabolism through

wheat plant that was inoculated with Glomus intra-

inhibiting the activity of enzymes such as glutamine

radices under cadmium stress, the sugars and total pro-

synthase, glutamate synthase, nitrate reductase and ni-

teins content increased in comparison with non-

trate regeneration process. Ghani and Wahid (2007)

inoculated plants (Jamalabad and Khara, 2008). Also the

showed that some heavy metals such as lead, cobalt,

use of arbuscular mycorrhizal fungi in Anadenanthera

1044

Journal of Research in Ecology (2017) 5(2): 1033–1051


Hajbagheri et al., 2017 colubrine increased the proteins production (Pedone-

antioxidant enzyme activities and proline content

Bonfim et al., 2012). Enteshari et al. (2012) reported

(Hasan et al., 2011). Brassinosteroids application on

shoot and root protein content increased in mycorrhizal

tomato plants that against cadmium photosynthesis,

sweet basil plants compared to non-mycorrhizal plants

antioxidant enzymes activity, transcription levels, anti-

under salinity stress conditions (Enteshari et al., 2012).

oxidant system and secondary compounds metabolism

Heavy metals can be catalyzed and accelerated

significantly increased these results showed that brassi-

reactive oxygen species. Hydrogen peroxide is the most

nosteroids had positive role in the detoxification of cad-

stable molecule of the active oxygen species. Heavy

mium stress (Ahammed et al., 2012).

metal ions can stimulated the metabolism of free radi-

In this research the activity of ascorbate peroxi-

cals and alter the concentration of H2O2 (Shaw et al.,

dase, peroxidase and polyphenol oxidase increased in

2004). In this study, the toxicity of cadmium increased

inoculation of plants with G. mosseae or interaction

H2O2 levels this result was according with Belkadhi et

between mycorrhizal plants and brassinisteroid. This

al., 2014 on Linum usitatissimum (Belkadhi et al.,

study showed that inoculated plants against cadmium

2014).In the other hand inoculation with mycorrhiza

toxicity were mainly related to the effect of this fungi on

(G. mosseae) or brassinosteroid treatment

decreased

the ascorbate peroxidase and polyphenol oxidase.

H2O2 content by increasing enzymatic

and non-

Glomus mosseae mycorrhiza significantly in-

enzymatic antioxidant parameters. In the same reports,

creases the activity of superoxide dismutase, catalase

24-epibrassinolide in Brassica juncea under cold stress

and peroxidase in the Cajanus cajan (Garg and

(Kumar et al., 2010) and in mycorrhizal cucumber plant

Bhandari,

under low temperature stress (Liu et al., 2014) H2O2

G. mosseae under salinity stress (Abdel latef and

content were reduced.

Chaoxing, 2011) and pomegranates inoculated plants

2012).

In

inoculated

tomatoes

with

The antioxidants compounds are considered as

with Glomus intraradices under oxidative stress under

important defensive systems in plants against oxidative

dehydration (Bompadre et al., 2014), the activity of

stress that induced by heavy metals (Hasan et al., 2011).

superoxide

dismutase,

catalase,

peroxidase

and

In this study, the activity of catalase, superoxide dis-

ascorbate

peroxidase

was

increased.

In

mutase, polyphenol oxidase, ascorbate peroxidase and

Lycopersicon esculentum plants under salinity stress,

peroxidase, especially at high concentrations of cadmi-

the interaction of 24-Epibrassinolide and putrescine

um chloride increased. In the root and leaves of radish,

increase the activity of catalase, superoxide dismutase

catalase and glutathione reductase activity increased

and guaiacol peroxidase enzymes (Sharma et al., 2012).

after 13 hours of exposure to cadmium (Vitoria et al.,

The evidences showed that there is a relation-

2001). Cadmium increased the superoxide dismutase

ship between phenol content and polyphenol oxidase

activity in sunflower (Laspina et al., 2005). In Ara-

activity in plants, when the total concentration of phenol

bidopsis plant under cadmium toxicity FeSOD and

increased in the plants and, the polyphenol oxidase ac-

MnSOD activity were increased (Drazkiewicz et al.,

tivity also increased subsequently (Tegelberg et al.,

2007).

2004). Also in this research showed that the polyphenol In this study brassinosteroid increased catalase,

oxidase activity increased by the increase in the phenol-

superoxide dismutase and polyphenol oxidase activity.

ic compounds content in anisum. Likely, ascorbate pe-

The treatment of tomato with 24-epibrassinolide and 28-

roxidase activity reduction in high concentrations of

Homo epibrassinolide increased the photosynthesis,

cadmium chloride is related to the inactivation of this

Journal of Research in Ecology (2017) 5(2): 1033–1051

1045


Hajbagheri et al., 2017 enzyme by the excessive production of active oxygen

um stress, anthocyanin content increased. It was report-

species, non-specific degradation, destruction, or bind-

ed

ing of unnecessary heavy metals to the enzyme (Sharma

Glomus etunicatum fungus significantly increased an-

et al., 2012). Reactive oxygen species production in

thocyanin content in sweet basil compared to non-

cadmium stress conditions increase the lipid peroxida-

mycorrhizal plants (Sharifi et al., 2011). Phenylalanine

tion, caused oxidative stress and damage the antioxida-

ammonia lyase and chalcone isomerase enzymes are

tive enzymes (Filek et al., 2008).

involved in the anthocyanin and 3-doxyanthocyanidin (a

that

the

mycorrhizal

inoculation

with

Another important plant defense system to con-

kind of phytoestrogen auxin), biosynthesis so that the

trol and neutralize free radicals is inducing the synthesis

fungal infection or brassinosteroids severely induced

of some non-enzymatic antioxidants such as anthocya-

these enzyme’s gene expression (Tripathi et al., 2006). It

nin and phenolic compounds. Generally, the consistency

was reported that the inoculation of plant with mycor-

with stress depends on the reduction of reactive oxygen

rhizal fungi increased the concentration of anthocyanin

species by the antioxidant system (Abdul-Jaleel et al.,

in strawberry (Lingua et al., 2013) and lettuce (Baslam

2009). In this study, anthocyanin content in cadmium

et al., 2013) and is considered as a reliable method to

chloride treatments showed no significant difference,

enhance the nutritional value of edible and medicinal

This result cannot be attributed to the less resistance of

plants consistent with the results in the present study.

anisum against the of cadmium toxicity, because the

The results of this study showed that the flavo-

plant may use other resistant mechanisms such as oth-

noids, flavonols and phenolic compound in cadmium

er phenolic compounds likely flavonoid production. On

stress increased significantly. It seems that this plant

the other hand, in plants treated with 24-epibrassinolide

under cadmium stress increased phenolic compounds in

anthocyanin content increased. Brassinosteroids activat-

order to have good defense reactions against the stress.

ed some enzymes such as phenylalanine ammonia lyase

Many flavonoids are an active component of secondary

and Chalcone Synthase (CHS) and other key enzymes in

metabolites from medicinal plants and their medicinal

the anthocyanin synthesis pathway (Campos et al.,

properties. They have an important role in plants re-

2003).

sistance as physiologically active compounds, protective In the same report, the use of 24-epibrassinolide

factors against stress and also light absorbers (Tattini et

in grape can increase the activity of phenylalanine am-

al., 2004). Phenolic compounds production in anisum

monia lyase enzyme or increased phenols, flavonoids,

under cadmium stress may be due to the induction of

tannins, and anthocyanin content (Xi et al., 2013). In

genes expression or the

grapes treated with brassinosteroids, a considerable in-

of these compounds in the phenylpropanoids pathway.

crease of anthocyanin concentration was observed in

The increase of the soluble phenolic compound content,

comparison with the control plant. Because of this in-

especially lignin precursors alongside the increase of the

crease, the impact of brassinosteroids on structural and

cell wall thickness creates a biological barrier to pre-

regulatory genes is related to anthocyanin biosynthesis

vent entry of heavy metals into living cells and increases

(Luan et al., 2013). In this study, the 24-epibrassinolide

their tolerance to these metals. These compounds direct-

probably increased the amount of anthocyanins through

ly prevent the oxidative stress by entering into the re-

this mechanism.

ducing reactions or indirectly by chelating the cadmium.

enzyme synthesis stimulation

In pretreated plants with mycorrhizal or

High levels of phenolic compounds in beans have also

brassinosteroids and mycorrhizal fungi under the cadmi-

been reported as the answer to cadmium toxicity

1046

Journal of Research in Ecology (2017) 5(2): 1033–1051


Hajbagheri et al., 2017 (Michalak, 2006)

tion of the activity of catalase, superoxide dismutase,

The treatment of anisum with brassinosteroid

peroxidase and polyphenol oxidase, and the amount of

increased flavonoids and phenols content in low concen-

flavonoids, flavonols and phenol in anisum due to cad-

trations of cadmium chloride. One of the causes of re-

mium toxicity improved the antioxidative defense sys-

ducing the effects of oxidative stress in plants treated

tem. The treatment of anisum with brassinosteroids and

with brassinosteroids is the effects of this substance on

inoculation with G. mosseae improves the host plant

the synthesis of substances such as flavonoids. Brassi-

growth by providing more plant resistance to cadmium

nosteroids at these concentrations reduced the toxic ef-

toxicity stress.

fects of cadmium chloride by affecting the antioxidant system. In a similar report, in Cichorium endivia L.

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