ROCOL EASYLINE ULTIMATE ALL COLOURS Chemwatch Material Safety Data Sheet Issue Date: 13-Nov-2007 C9317EC
CHEMWATCH 61611 Version No:4 CD 2007/3 Page 1 of 7
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME ROCOL EASYLINE ULTIMATE ALL COLOURS SYNONYMS "line-marking spray paint" PROPER SHIPPING NAME AEROSOLS PRODUCT USE Application is by spray atomisation from a hand held aerosol pack. Line marking paint. SUPPLIER Company: ITW POLYMERS & FLUID (NZ) Address: UNIT 2/ 38 TRUEGOOD DRIVE EAST TAMAKI AUCKLAND, 2013 NZL Telephone: +64 9 272 1945 Emergency Tel: +64 9 273 6489 Fax: +64 9 272 1945
Company: ITW POLYMERS & FLUIDS Address: 100 Hassall Street Wetherill Park NSW, 2164 AUS Telephone: +61 2 9757 8800 Emergency Tel: +61 2 9757 8800 Fax: +61 2 9757 3855
Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE DANGEROUS GOODS. NON-HAZARDOUS SUBSTANCE. According to the Criteria of the ADG Code and NOHSC. POISONS SCHEDULE S5 RISK Extremely flammable. Vapours may cause drowsiness and dizziness.
SAFETY Keep away from sources of ignition. No smoking. Do not breathe gas/fumes/vapour/spray. Use only in well ventilated areas. Take off immediately all contaminated clothing. In case of contact with eyes rinse with plenty of water and contact Doctor or Poisons Information Centre. This material and its container must be disposed of in a safe way.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS NAME acetone xylene propylene glycol monomethyl ether dimethyl ether
CAS RN 67-64-1 1330-20-7 107-98-2 115-10-6
% 10-30 10-30 1-10 10-30
Section 4 - FIRST AID MEASURES SWALLOWED Not considered a normal route of entry. For advice, contact a Poisons Information Centre or a doctor. - If swallowed do NOT induce vomiting.
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ROCOL EASYLINE ULTIMATE ALL COLOURS Chemwatch Material Safety Data Sheet Issue Date: 13-Nov-2007 C9317EC
CHEMWATCH 61611 Version No:4 CD 2007/3 Page 2 of 7 Section 4 - FIRST AID MEASURES
- If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. EYE If this product comes in contact with the eyes: - Wash out immediately with fresh running water. - Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. SKIN If skin contact occurs: - Immediately remove all contaminated clothing, including footwear. - Flush skin and hair with running water (and soap if available). INHALED - If fumes or combustion products are inhaled remove from contaminated area. - Lay patient down. Keep warm and rested. NOTES TO PHYSICIAN Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA - Water spray or fog. - Foam. FIRE FIGHTING - Alert Fire Brigade and tell them location and nature of hazard. - May be violently or explosively reactive. When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 100 metres in all directions. FIRE/EXPLOSION HAZARD - Liquid and vapour are highly flammable. - Severe fire hazard when exposed to heat or flame. Other combustion products include: carbon dioxide (CO2). FIRE INCOMPATIBILITY Avoid contamination with strong oxidising agents as ignition may result. HAZCHEM: Personal Protective Equipment Gas tight chemical resistant suit.
Section 6 - ACCIDENTAL RELEASE MEASURES EMERGENCY PROCEDURES MINOR SPILLS - Clean up all spills immediately. - Avoid breathing vapours and contact with skin and eyes. MAJOR SPILLS - Clear area of personnel and move upwind. - Alert Fire Brigade and tell them location and nature of hazard. Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING - Avoid all personal contact, including inhalation. - Wear protective clothing when risk of exposure occurs. SUITABLE CONTAINER - Aerosol dispenser.
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ROCOL EASYLINE ULTIMATE ALL COLOURS Chemwatch Material Safety Data Sheet Issue Date: 13-Nov-2007 C9317EC
CHEMWATCH 61611 Version No:4 CD 2007/3 Page 3 of 7 Section 7 - HANDLING AND STORAGE
- Check that containers are clearly labelled. STORAGE INCOMPATIBILITY Avoid storage with oxidisers. STORAGE REQUIREMENTS - Store in original containers in approved flame-proof area. - DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS Source __________________ AustraliaExposureStandar ds AustraliaExposureStandar ds AustraliaExposureStandar ds AustraliaExposureStandar ds
Material __________________ acetone(Acetone)
TWAppm _______ 500
TWAmg/m³ _______ 1185
STELppm _______ 1000
STELmg/m³ _______ 2375
xylene(Xylene(o- , m- , p- isomers)) propylene glycol monomethy lether (Propylene glycolmo nomethylether) dimethyl ether(Dimethylet her)
80
350
150
655
100
369
150
553
400
760
500
950
PERSONAL PROTECTION RESPIRATOR Type AX Filter of sufficient capacity EYE No special equipment for minor exposure i.e. when handling small quantities. HANDS/FEET No special equipment needed when handling small quantities. OTHERWISE: Wear general protective gloves, eg. OTHER No special equipment needed when handling small quantities. OTHERWISE: - Overalls. - Skin cleansing cream. ENGINEERING CONTROLS General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Supplied as an aerosol pack. Contents under PRESSURE. Highly flammable coloured liquid with characteristic odour; mixes with water. PHYSICAL PROPERTIES Liquid. Gas. Mixes with water. Molecular Weight: Not applicable. Melting Range (°C): <0 Solubility in water (g/L): Miscible pH (1% solution): Not applicable. Volatile Component (%vol): Not available Relative Vapour Density (air=1): >1 Lower Explosive Limit (%): Not available. Autoignition Temp (°C): Not Available State: Liquid
Boiling Range (°C): >40 solvent Specific Gravity (water=1): 1.0 approx pH (as supplied): Not applicable Vapour Pressure (kPa): Not Available Evaporation Rate: Fast Flash Point (°C): - 30 Upper Explosive Limit (%): Not available. Decomposition Temp (°C): Not Available Viscosity: Not Available
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ROCOL EASYLINE ULTIMATE ALL COLOURS Chemwatch Material Safety Data Sheet Issue Date: 13-Nov-2007 C9317EC
CHEMWATCH 61611 Version No:4 CD 2007/3 Page 4 of 7
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION CONDITIONS CONTRIBUTING TO INSTABILITY - Elevated temperatures. - Presence of open flame.
Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS Vapours may cause dizziness or suffocation. Vapours may cause drowsiness and dizziness.
CHRONIC HEALTH EFFECTS Not applicable.
TOXICITY AND IRRITATION Not available. Refer to individual constituents. ACETONE: unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. TOXICITY IRRITATION Oral (man) TDLo: 2857 mg/kg Eye (human): 500 ppm - Irritant Oral (rat) LD50: 5800 mg/kg Eye (rabbit): 3.95 mg - SEVERE Inhalation (human) TCLo: 500 ppm Eye (rabbit): 20mg/24hr - Moderate Inhalation (man) TCLo: 12000 ppm/4 hr Skin (rabbit):395mg (open) - Mild Inhalation (man) TCLo: 10 mg/m続/6 hr Skin (rabbit): 500 mg/24hr - Mild Inhalation (rat) LC50: 50100 mg/m続/8 hr Dermal (rabbit) LD50: 20000 mg/kg XYLENE: unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. TOXICITY IRRITATION Oral (human) LDLo: 50 mg/kg Skin (rabbit):500 mg/24h Moderate Oral (rat) LD50: 4300 mg/kg Eye (human): 200 ppm Irritant Inhalation (human) TCLo: 200 ppm Eye (rabbit): 87 mg Mild Inhalation (man) LCLo: 10000 ppm/6h Eye (rabbit): 5 mg/24h SEVERE Inhalation (rat) LC50: 5000 ppm/4h Oral (Human) LD: 50 mg/kg Inhalation (Human) TCLo: 200 ppm/4h Intraperitoneal (Rat) LD50: 2459 mg/kg Subcutaneous (Rat) LD50: 1700 mg/kg Oral (Mouse) LD50: 2119 mg/kg Intraperitoneal (Mouse) LD50: 1548 mg/kg Intravenous (Rabbit) LD: 129 mg/kg Inhalation (Guinea) pig: LC 450 ppm/4h The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis. The substance is classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in animal testing. Reproductive effector in rats PROPYLENE GLYCOL MONOMETHYL ETHER: unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. TOXICITY IRRITATION Oral (rat) LD50: 3739 mg/kg Skin (rabbit) 500 mg Open - Mild Inhalation (human) TCLo: 3000 ppm Eye (rabbit) 230 mg Mild Inhalation (rat) LC50: 10000 ppm/5 h. Eye (rabbit) 500 mg/24 h. - Mild Dermal (rabbit) LD50: 13000 mg/kg The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis. NOTE: Exposure of pregnant rats and rabbits to the substance did not give rise to teratogenic effects at concentrations up to 3000 ppm. Fetotoxic effects were seen in rats but not in rabbits at this concentration; maternal toxicity was noted in both species. DIMETHYL ETHER: unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. TOXICITY IRRITATION Inhalation (rat) LC50: 308000 mg/m続 Nil Reported MATERIAL
CARCINOGEN
REPROTOXIN
SENSITISER
SKIN
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ROCOL EASYLINE ULTIMATE ALL COLOURS Chemwatch Material Safety Data Sheet Issue Date: 13-Nov-2007 C9317EC
_______________ xylene
____________
CHEMWATCH 61611 Version No:4 CD 2007/3 Page 5 of 7 Section 11 - TOXICOLOGICAL INFORMATION __________ ILOEl
__________
__________
REPROTOXIN ILOEl: ILO Chemicals in the electronics industry that have toxic effects on reproduction: xylene
Section 12 - ECOLOGICAL INFORMATION Marine Pollutant:Not Determined No data for Rocol Easyline Ultimate all colours. Refer to data for ingredients, which follows: ACETONE: log Kow: -0.24 Half-life (hr) air: 312-1896 Half-life (hr) H2O surface water: 20 Henry's atm m続 /mol: 3.67E-05 BOD 5 if unstated: 0.31-1.76,46-55% COD: 1.12-2.07 ThOD: 2.2 BCF: 0.69 Toxicity Fish: LC50(96) 5540-13000mg/L Toxicity invertebrate: cell mult. inhib. 28-7500mg/L Bioaccumulation: not sig Nitrif. inhib.: 75% decr. at 840mg/L Anaerobic effects: sig degrad Degradation Biological: sig processes Abiotic: Rxn OH*,photodissoc In air, acetone is lost by photolysis and reaction with photochemically produced hydroxyl radicals; the estimated half-life of these combined processes is about 22 days. The relatively long half-life allows acetone to be transported long distances from its emission source. Acetone is highly soluble and slightly persistent in water, with a half-life of about 20 hours; it is minimally toxic to aquatic life. Acetone released to soil volatilises although some may leach into the ground where it rapidly biodegrades. Acetone does not concentrate in the food chain. Drinking Water Standard: none available. Soil Guidelines: none available. Air Quality Standards: none available. DIMETHYL ETHER: log Kow: 0.1-0.12 Koc: 14 Half-life (hr) air: 528 Half-life (hr) H2O surface water: 2.6-30 Henry's atm m続 /mol: 9.78E-04 BCF: 1.7 Bioaccumulation: not sig processes Abiotic: RxnOH*
Section 13 - DISPOSAL CONSIDERATIONS - Consult State Land Waste Management Authority for disposal. - Discharge contents of damaged aerosol cans at an approved site.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE GAS
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ROCOL EASYLINE ULTIMATE ALL COLOURS Chemwatch Material Safety Data Sheet Issue Date: 13-Nov-2007 C9317EC
HAZCHEM: UNDG: Dangerous Goods 2.1 Class: UN Number: 1950 Shipping Name:AEROSOLS Air Transport IATA: ICAO/IATA Class: 2.1 UN/ID Number: 1950 Special provisions: None Shipping Name: AEROSOLS, FLAMMABLE Maritime Transport IMDG: IMDG Class: 2.1 UN Number: 1950 EMS Number: F- D, S- U Marine Pollutant: Not Determined Shipping Name: AEROSOLS
CHEMWATCH 61611 Version No:4 CD 2007/3 Page 6 of 7 Section 14 - TRANSPORTATION INFORMATION
Subrisk:
None
Packing Group:
None
ICAO/IATA Subrisk: Packing Group:
None None
IMDG Subrisk: Packing Group: Special provisions:
SP63 None 63 190 277 327 959
Section 15 - REGULATORY INFORMATION POISONS SCHEDULE: S5 REGULATIONS Rocol Easyline Ultimate all colours (CAS: None): No regulations applicable acetone (CAS: 67-64-1) is found on the following regulatory lists; Australia Exposure Standards Australia High Volume Industrial Chemical List (HVICL) Australia Illicit Drug Reagents/Essential Chemicals - Category III Australia Inventory of Chemical Substances (AICS) Australia National Pollutant Inventory Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5 IMO IBC Code Chapter 18: List of products to which the Code does not apply IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances OECD Representative List of High Production Volume (HPV) Chemicals United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International Control xylene (CAS: 1330-20-7) is found on the following regulatory lists; Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - organic compounds) Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Domestic water quality Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported Australia Dangerous Goods Code Draft 7th Edition - Goods too Dangerous to be Transported Australia Exposure Standards Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6 IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water propylene glycol monomethyl ether (CAS: 107-98-2) is found on the following regulatory lists; Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported Australia Exposure Standards Australia Inventory of Chemical Substances (AICS) IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk International Council of Chemical Associations (ICCA) - High Production Volume List OECD Representative List of High Production Volume (HPV) Chemicals propylene glycol monomethyl ether (CAS: 1320-67-8) is found on the following regulatory lists; Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported propylene glycol monomethyl ether (CAS: 28677-93-2) is found on the following regulatory lists; Australia Inventory of Chemical Substances (AICS) dimethyl ether (CAS: 115-10-6) is found on the following regulatory lists; Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported Australia Exposure Standards Australia Inventory of Chemical Substances (AICS) International Council of Chemical Associations (ICCA) - High Production Volume List OECD Representative List of High Production Volume (HPV) Chemicals
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ROCOL EASYLINE ULTIMATE ALL COLOURS Chemwatch Material Safety Data Sheet Issue Date: 13-Nov-2007 C9317EC
CHEMWATCH 61611 Version No:4 CD 2007/3 Page 7 of 7
Section 16 - OTHER INFORMATION INGREDIENTS WITH MULTIPLE CAS NUMBERS Ingredient Name propylene glycol monomethyl ether
CAS 107- 98- 2, 1320- 67- 8, 28677- 93- 2
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700. Issue Date: 13-Nov-2007 Print Date: 13-Nov-2007