Delivering chemicals for a world of applications Cosmetics
Medical
Epoxies
Solvents
Coatings
Personal Care
Organics
Adhesives
Local service, global reach
Need a bespoke solution? Trust, reliability, experience?
Delivers WHYTE CHEMICALS ESTABLISHED IN 1976 IS ONE OF THE LARGEST UK PRIVATELY OWNED COMPANIES IN THE CHEMICALS DISTRIBUTION MARKET. The company has a focus on several core product areas which cater for a comprehensive range of industries. With sustained organic growth since our conception we have continually offered our customers greater value and support by establishing networks & relationships with international manufacturers. With this growth, the company has never lost sight of the most important aspect of any business, people. At Whyte Chemicals we have never given up the ethos of people matter and the key to business sustainability is good stakeholder relationship management. This combined with our global sourcing has given us the dual advantage of international reach and local service. Whyte Chemicals' coatings and Epoxy
Continuous investment in this area over
product areas have grown substantially
2 decades has seen our Epoxy business
over the past 20 years. Today, the raw
go from strength to strength. Now, we can
materials which we supply for the coatings
proudly claim an impressive customer
industry represent a key strategic and
portfolio spread over a truly pan European
integral part of our overall business.
territory.
Traditionally with a strong presence as an
With a history of success based on delivering personal service to our customers, we continue to meet the challenges of tomorrow with our global network.
Intermediates supplier to the Resin industry, Whyte’s position in the market really established itself in 1991 when we commenced our partnership in Epoxy Resins with Nan Ya Plastics of Taiwan.
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CHEMICAL SOURCING HEADACHES?
LET WHYTE CHEMICALS PROVIDE THE CURE We would like to introduce to you our Global Chemical Sourcing Service. Through our extensive network of offices
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Competitive Prices and Significant Savings
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Confidentiality and Security
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Alternative Sources of Chemicals
situated in India, China, Japan, Brazil, United Arab Emirates and throughout Europe, we offer an exclusive customer focused
chemical
sourcing
capability.
Our
Business
■
Development Team can provide you with the high quality chemicals you require at the most competitive prices. WITH OVER 30 YEARS OF EXPERIENCE IN THE
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Warehousing Service
■
ISO9001 Quality Assured
■
Auditing Service
■
Custom/Toll Manufacture
CHEMICAL INDUSTRY WE HAVE GAINED A BROAD AND
DIVERSE
KNOWLEDGE
OF
THE
CHEMICAL MARKET.
Local service, global reach
An Independent, Swift, Flexible and Responsive Service
WORLD
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Products & Services for the Pharmaceutical Industry
FINE CHEMICALS
SOLVENTS
N,N-Diisopropylethylamine (Hunig’s Base);
Acetonitrile; Dimethyl Formamide; Tetrahydrofuran;
N,N’-Dibenzylethylenediamine Diacetate (DBEDA);
N Methyl Pyrrolidone; Pyridine; Monopropylene Glycol
N-Benzyl Ethanolamine; Piperidones; Alkyl Ethyl Amines;
USP; 1,4 Dioxane; Propylene Carbonate; High Purity
Amine Hydrochlorides; Amine Hydrobromides
Solvents (e-lab Direct Ltd)
PROCESS CHEMICALS & INTERMEDIATES
PEPTIDE SYNTHESIS REAGENTS
Aluminium Chloride; Dimethyl Sulphate; Diethyl Sulphate;
General Reagents; Coupling Reagents;
Benzylamine; Benzyl Chloride; Acid Chlorides;
Protected Amino Acids
Ethanolamines; Ethylamines; Salicyclic Acid; Methoxides TOLL MANUFACTURE/CUSTOM SYNTHESIS EXCIPIENTS
Grosvenor Chemicals Limited
Citric Acid; Benzoic Acid BP; Adipic Acid; Malic Acid; Potassium Sorbate; Sorbic Acid; Vitamins; Aspartame;
ENVIRONMENTAL INNOVATION
Gelatine; Sorbitol; Polyethylene Glycols; Glycerine;
Scionix Limited – Ionic Solvents and Eutectic Mixtures
Plant Extracts
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Local service, global reach
BASF Alcoholates
Reduce your costs and increase your yields with BASF Alcoholates - offering efficient, cost effective catalysis of Transesterification reactions. Increased Purity. Increased Yields. Increased Sales. Sodium Methylate 30% Solution in Methanol
Sodium Methylate Crystals
CAS Nr: 124-41-4 in 67-56-1
CAS Nr: 124-41-4
Key Advantages: Reduces liquid handling and the need for
Key Advantage: Reduces water content, reducing
mixing of flammable liquids. Reduces water content, reducing
saponification and subsequent purification costs. Increases
saponification and subsequent purification costs. Increases
yield of Biodiesel.
yield of Biodiesel.
Application: Preferred for Biodiesel production from rapeseed &
Application: Preferred for Biodiesel production from rapeseed &
sunflower oils.
sunflower oils.
Availability: 100kg drums.
Availability: 200kg drums, 900kg IBCs.
Local service, global reach
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BASF Alcoholates
Potassium Methylate 32% Solution in Methanol
Sodium Ethylate 21% Solution in Ethanol
CAS Nr: 7632-0-0 in 67-56-1
Application: Organic Synthesis (condensation reactions). Also Available: Sodium Ethylate Crystals (141-52-6). Availability: 180kg drums.
Key Advantage: Reduces liquid handling and the need for mixing of flammable liquids. Reduces water content, reducing saponification and subsequent purification costs. Increases yield of Biodiesel. Produces liquid glycerol for easier separation. Application: Preferred for Biodiesel production from spent vegetable oil and used cooking oil. Availability: 200kg drums, 900kg IBCs.
CAS Nr: 141-52-6 in 64-17-5
Potassium Methylate Crystals CAS Nr: 865-33-8 Key Advantages: Reduces water content, reducing saponification and subsequent purification costs. Increases yield of Biodiesel. Produces liquid glycerol for easier separation. Application: Preferred for Biodiesel production from spent vegetable oil and used cooking oil. Availability: 100kg drums.
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If you require more information please contact: David Hobden, Assistant Business Manager david.hobden@whytechemicals.co.uk Tel: 020 8371 3932 Fax: 020 8349 4589 www.whytechemicals.co.uk
Local service, global reach
ACETONITRILE WHYTE CHEMICALS IS ONE OF THE LARGEST IMPORTERS INTO THE EU
Whyte Chemicals have exclusive distribution agreements with major Asian and transatlantic manufacturers ensuring our supply is always secure. We offer you a focused customer lead service based on your specific requirements:
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Long term relationship with supply from key manufacturers ranked 3, 4 and 5 in the global market for Acetonitrile supply, allowing pricing to commercially reflect your requirement. Our volumes are contracted and multi-sourced.
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REACH registration under the Whyte Chemicals banner.
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Stocked in the UK and mainland Europe with extensive bulk iso tank and drum capacity to reduce lead-times.
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Dedicated tanks to allow traceability and continuity for the Pharma sector.
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Our High Purity grade is supported by the manufacturer with analytical and statistical data that demonstrates the quality and consistency of this grade. The manufacturer works to satisfy every customer’s specific needs and can certify the material to your exact requirement. Our key position in this market allows us to purchase the product competitively and pass this flexibility and saving on to you.
Local service, global reach
Commercial Grade Acetonitrile Assay, (as CH3CN), by GC Appearance
Color (APHA) Water (H2O) % Acrylonitrile (ppm) Propionitrile (ppm) Acetone (ppm) HCN (ppm) Acidity (as CH3 COOH) (ppm) Total Residues
Specification 99.90% min Clear, calories’ liquid with no visible impurities 10 max 0.1 max 5 max 500 max 5 max 10 max 50 max 0.01% max
Ultra Low Water/Gradient HPLC Acetonitrile Assay, (as CH3CN), by GC UV Cut-Off (nm) Fluorescence Trace Impurities (as Quinine Base, ppb) @450 nm Emission Emission Maximum for Impurities Titrable Acid (meq/g) Titrable Base (meq/g Water (H2O) by Coulometry (ppm) Gradient Elution Test (a.u.) @210 nm @254 nm
Specification 99.90% min 190
0.3 max 1.0 max 0.008 max 0.0006 max 5 max 0.001 max 0.001 max
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DIBASIC ESTER MDBE
Whyte Chemicals distribute MDBE for Weifang Yuanli Chemical Co. Ltd throughout Europe, offering a strong alternative sourcing option to the traditional European manufacturers. MDBE is a blend of dimethyl succinate, dimethyl glutarate and dimethyl adipate. This unique blend offers a number of industrial applications, combined with some excellent working properties and environmental benefits.
CHEMICAL PROPERTIES High solvency power
■
High flashpoint, 100°C
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Slow evaporation rate
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Low miscibility with water
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High miscibility with organic solvents
yua
■
ichem nl
®
INDUSTRIAL APPLICATIONS ■
Coatings Industry - Coil, Can, Industrial and Inks
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Paint stripping, an excellent alternative to Methylene Chloride
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Cleaning – degreasing, graffiti removal, adhesive removal, hand cleaning, resin & paint
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Foundry resins
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Recyclable
HSE ADVANTAGES ■
Low toxicity, classified as ‘non-hazardous’
SOURCING OPTIONS
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Mild odour
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Classified as Non – VOC in EU
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Bio-degradable
Whyte’s stock this item in drums (220kg) and IBC’s (1100kg) across our European distribution network with lead-times of 3-5 working days.
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Recyclable
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Alternatively bulk iso-tanks are available upon request.
Local service, global reach
2-METHYL TETRAHYDROFURAN
Methyl Tetrahydrofuran (MeTHF) is a versatile solvent and can be used to replace solvents such as Tetrahydrofuran (THF) and Diethyl Ether (DEE) in a number of applications including: ■
Grignard Reactions
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Biphasic Reactions
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Organometallic Reactions
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Lithiation
Local service, global reach
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HUNIG’S BASE N,N-Diisopropylethylamine CAS. No. 7087-68-5
The preferred auxiliary reagent in organic synthesis
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Local service, global reach
Hunig’s Base N,N-Diisopropylethylamine
The preferred auxiliary reagent in organic synthesis ■ Manufactured in a dedicated facility
at Huddersfield, UK ■ Site operates to ISO9001:2000
and ISO14001 ■ World’s leading producer ■ Recognised high purity product ■ Standard pack sizes include 18kg,
37.5kg and 150kg drums and isotanks. Other pack sizes available on request ■ Strategic stocks held globally to service
customer needs SPECIFICATION
Local service, global reach
TYPICAL ANALYSIS
GC Assay
99.70%
99.80%
Diisopropylamine
0.20%
0.10%
Total organic by products
0.30%
0.20%
Residue on evaporation
0.20%
0.10%
Water content
0.10%
0.05%
Appearance
Colourless to pale yellow liquid
Pale yellow liquid
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MAIN APPLICATIONS Alkylation Reactions
R–X+R’–Y–H
Elimination reactions
R–CH2 –CH–R’ X
Acylation Reactions
RCOX+R’–Y–H
➡ R’–Y–R+HX ➡ R–CH=CH–R’+HX ➡ RCO–Y–R’+HX
Peptide Synthesis Reagent Esterification Trans Esterification
KEY PROPERTIES
ENVIRONMENTALLY FRIENDLY
■ Non nucleophilic ■ Low water content
Hunig’s base is non – miscible with water and can easily be recovered from waste streams and recycled.
■ Recyclable
Full recycling process details are available under licence.
■ Excellent acid scavenger ■ Reduced side reactions
Whyte Chemicals can offer technical assistance and a full Recovery/Recycle service.
■ Improved yields ■ Replaces Triethylamine
and Dimethyl Aniline
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Local service, global reach
Hunig’s Base N,N-Diisopropylethylamine Whyte Chemicals are pleased to offer the reagent of choice when an acid scavenger is required.
BENEFITS INCLUDE: ■ High purity ■ Low water content ■ Low environmental impact ■ UK manufactured ■ Readily recyclable ■ Non nucleophilic
TYPICAL ANALYSIS: GC ASSAY
99.8%
WATER
0.05%
Whyte Chemicals can offer contract synthesis, involving Hunigs base if required, on our fine chemicals unit. A further range of Alkyl Amines are available including: ■ N,N,N',N',-Tetramethylethylenediamine ■ N,N'-Dibenzylethylenediamine diacetate ■ N,N-Dimethylethylene Diamine ■ N,N'-Diisopropylethylene Diamine
Local service, global reach
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Ingredients for human nutrition & health
CAROTENOIDS
NUTRACEUTICALS
B-Carotene, Apocarotenal, (Genistein)*, (Lutein),
LY C O P E N E
(Trans-resveratrol)*,
TM
L I S T E N T O Y O U R H E A R T
(Lycopene), (Coenzyme Q10), (Zeaxanthin)* (Emulsion of palm and oat oil),
FAT-SOLUBLE VITAMINS Vitamin A, Vitamin D3, Vitamin E, Vitamin K1
(Specialized Rosehip powder)*,
WATER-SOLUBLE VITAMINS Thiamin, Riboflavin, Niacin, Pantothenic Acid,
(Dairy based peptides),
Vitamin B6, Vitamin B12, Folate, Biotin, Vitamin C (Tomato based extract)
TM used with permission. *Not to be used within the EU.
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Local service, global reach
Ingredients for human nutrition & health CEPs have been granted for the following products: dl-alpha- Tocopheryl acetate
(Vitamin E)
Phytomenadione
(Vitamin K1)
d-alpha- Tocopheryl acetate
(Natural Source Vitamin E)
Pyridoxine hydrochloride
(Vitamin B6)
Ascorbic acid
(Vitamin C)
Riboflavin Fermentation process (Vitamin B2)
Ascorbyl palmitate
(Vitamin C palmitate)
Riboflavin sodium phosphate
(Vitamin B2)
B-Carotene
(Pro Vitamin A)
Sodium ascorbate
(Vitamin C)
Biotin
(Vitamin H, Vitamin B7)
Thiamine hydrochloride
(Vitamin B1)
Calcium ascorbate
(Vitamin C)
Thiamine mononitrate
(Vitamin B1)
Calcium D-Pantothenate
(Vitamin B5)
Vitamin A palmitate
(Vitamin A)
Cholecalciferol
(Vitamin D3)
Vitamin A acetate
(Vitamin A)
Dexpanthenol
(Panthenol, Vitamin B5)
Nicotinamide
(Niacinamide - Vitamin B3)
Dextromethorphan hydrobromide
Cyanocobalamin non GMO
(Vitamin B12)
Folic acid
Cyanocobalamin
(Vitamin B12)
(Vitamin B9)
Local service, global reach
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ACRYLIC ACID WHYTE CHEMICALS IS ONE OF THE LARGEST IMPORTERS INTO THE EU
Whyte Chemicals Distribute AA for
Shanghai
Huayi
(Group)
Company throughout Europe, offering
a
strong
alternative
sourcing option to the traditional European manufacturers.
Acrylic acid (IUPAC: prop-2-enoic acid) is an organic compound with the formula CH2=CHCO2H. It is the simplest unsaturated carboxylic acid,
MARKETS AND APPLICATIONS ■
Coatings
Specifications
■
Consumer goods
Assay:
99.5% min.
This colorless liquid has a
■
Adhesives
Colour:
10 APHA max.
characteristic acrid or tart smell.
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Paints
Water:
0.1% / 1000 ppm max.
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Chemical processing
Inhibitor content: 180 - 220 ppm (MEHQ)
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Super-absorbent polymers
Dimer:
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Detergents
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Chemical processing
Bulk ISO Tank.
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Water treatment
Drums.
consisting of a vinyl group connected directly to a carboxylic acid terminus.
It is miscible with water, alcohols, ethers, and chloroform. More than one billion kilograms are produced annually. ACRYLIC ESTERS. BA. EA. 2Eha also available.
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0.2% / 2000 ppm max.
Sourcing options
Local service, global reach
Performance Chemicals Speciality Solvents
Whyte Chemicals distribute performance chemicals on behalf of Future Fuel Chemical Company across Europe - offering competitive supply options for Specialty Solvents, whilst ensuring continuity of supply from a non-Asian source.
Specialty Solvents FUTURESOL速 DEM DIETHOXYMETHANE CAS Number: 462-95-3 Applications: Carrier for organometallics, Formaldehyde equivalent, Ethoxy transfer agent. Key Advantages: High solvent power, Water miscibility, Low drying times, compatibility with organic solvents and surfactants, Low polarity. Green alternative to THF, diethyl ether or DCM. 速
FUTURESOL DBM DIBUTOXYMETHANE CAS Number: 2568-90-3 Applications: Monomer, cleaners/degreasers, Adhesives, Chain transfer reagent, anti-foam agent Key Advantages: Low toxicity, non-carcinogenic, high solvent power, non flammable.
Local service, global reach
FUTURESOL速 FAME Fatty acid methyl esters, Distilled CAS Number: 515152-40-6 Applications: Paints and coatings, cleaners, cosmetics, polymers, intermediate.
FUTURESOL速 GLYSOL GLYCEROL FORMAL CAS Number: 4740-78-7 and 5464-28-8 Applications: Veterinary medicine, cosmetics, pesticide carrier, coatings, inks, paint strippers, cleaners Key Advantages: Low odour, low toxicity, low volatility. If you require more information or require a price please contact: Emma Walker, Business Manager emma.walker@whytechemicals.co.uk
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Performance Chemicals Sulfonated Monomers and Hydrotropes
Whyte Chemicals distribute performance chemicals on behalf of Future Fuel Chemical Company across Europe - offering competitive supply options for Sulfonated Monomers and Hydrotropes, whilst ensuring continuity of supply from a non-Asian source.
Sulfonated Monomers and Hydrotropes FUTURECHEM™ LiSIPA 5-LITHIOSULFOISOPHTHALIC ACID CAS Number: 46728-75-0 Applications: Monomer for waterborne polyesters, Monomer for nylon fibres, Amine free polyurethane dispersions, adhesion aid for magnetic tapes.
FUTURECHEM™ SSIPA 5-SODIOSULFOISOPHTHALIC ACID CAS Number: 6362-79-4 Applications: Monomer for waterborne polyesters, Monomer for nylon fibres, amine free polyurethane dispersions, Adhesion aid for magnetic tapes.
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FUTURECHEM™ KHQS POTASSIUM HYDROQUINONESULFONATE CAS Number: 21799-87-1 Application: Photographic developing solutions, copolymer films, corrosion control in aqueous systems.
If you require more information or require a price please contact: Emma Walker, Business Manager emma.walker@whytechemicals.co.uk
Local service, global reach
SYNTHESIS CAPABILITIES
The Grosvenor Site has Top Tier COMAH status and can handle a number of hazardous reagents and products in a multi-purpose plant.
SYNTHESIS CAPABILITIES INCLUDE:-
WE HAVE:-
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Alkylation of amines
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Stainless Steel reactors from 1m3 to 10m3
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Michael reactions
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Centrifuges
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Reactions of isocyanates
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Pressure Filters
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Reaction between inorganic sulphides and alcohols
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Pressure Filters
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Condensation reactions
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Acid/Base reactions
Talk to us about your custom synthesis needs.
Name
Area
MOC
Volume litre
Des Press
Reactor 1
Reactor Room
S/S
4900
45 psig
Reactor 2
Reactor Room
S/S
Reactor 3
Ashlade
S/S
4000
Reactor 4
Reactor Room
Glass lined
5500
Reactor 5
Yellow Dye
Glass lined
1300
Reactor 6
Reactor Room
Glass lined
7000
Des Temp °C
Normal Press
Normal Temp °C
Type
0-130 0-130
0-130 6 barg
200
Reactor 7
Tank Farm
S/S
12000
Recovery Still
Recovery Still
S/S
6000
Reactor 9
Yellow Dye
S/S
3000
Reactor 10
GMP
S/S
2750
vac to 3.5 barg
Reactor 11
GMP
S/S
2929
vac to 3.5 barg
Reactor 12
GMP
S/S
10414
vac to 2 barg
200
Reactor 13
GMP
S/S
2032
vac to 2 barg
200
Reactor 14
GMP
S/S
Hazardous solid handling facility
atmos
130
200
atmos
100
200
atmos
100
atmos
ambient
200
Distillation only
All reactors steam heated and water cooled. Max temp 130°C. R6 has potential s/s rosenmund 4000 litre filter (no mixing paddle) for solid filtration. R1-R6 has a s/s centrifuge, 1000 litre for solid handling. Cone dryer available (vacuum type), -0.5bar vacuum, 90°C maximum drying temp, 2000 litre max volume, 670 litre working volume. Cannot handle oxidizers or acidic solids.
Grosvenor Chemicals Ltd, Grosvenor Works, Linthwaite, Huddersfield, West Yorkshire, HD7 5QE, UK Tel: +44 (0) 1484 842451 Fax: +44 (0) 1484 847066 Email: enquiries@grosvenorchemicals.co.uk www.grosvenorchemicals.co.uk Part of the Whyte Group
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Want the widest range of products? Responsible, ethical?
Delivers Epoxy Resins Liquid Epoxies, Solid Epoxies, Solutions, BPF Liquids, Novalacs, Reactive Diluents, Modified Epoxies, Cycloaliphatic Epoxies, benzyl Alcohol Resin Intermediates Adipic Acid, Benzoic Acid, Maleic Anhydride, Melamine, Bisphenol-A, Phthalic Anhydride, Pentaerythritol Curing Agents Polyaminoamides, Aliphatic Amines, Cycloaliphatic Amines, Mannich Bases Additional Paint Products Pigments, Polyols, Isocyanates Micrex Whyte Chemicals – non hazardous anti-corrosive pigment Specialist resins for pigment dispersions
MEKO Anti-skinning agent
Peptides General Reagents, Coupling Reagents, Protected Amino Acids
Intumescent coatings components – Micronised Melamine and Pentaerythritol Organic Pigments Yellow, red and violet
Fine Chem Hungi’s Base, DBEDA, Piperidones, Alkyl Ethylene Amines Colour & Pigment Intermediates Bon Acid, Naphthols, Arylamides
Development Products Organoclays, Anhydrides, Flame Retardant Additives, Hydrocarbon Resins Solvents Glycols, Esters, Ketones, Chlorinated hydrocarbons Speciality Solvents NMP, THF, DMF, DMSO, Methyl THF Process Chemicals & Speciality Intermediates Acetonitrile, Benzyl Chloride, Acetate Esters, Amines, Ethanolamine, Alcoholates, Diols, Dimethyl / Dimethyl Sulphate.
Personal Care & Cosmetics Fatty Alcohols, Fatty Amines, Glycerine, Plant Extracts, Cold Pressed Oils, PEG’s Inorganics Sodium Hydroxide, Aluminium Chloride, Hydroxylamine Sulphate Food, Flavours & Fragrances Vitamins, Acidulants, Preservatives, Aroma Chemicals
Long haul? Short haul? Or just around the corner?
Delivers 20
Local service, global reach
Want a true first class service?
Delivers Melvyn Whyte Chairman
Regulatory Affairs REACH MSDS
Epoxy Resins
Epoxies European Sales
Surface Coatings Business Development
European Business
Organics
Resins, Coatings & Additives
Fine Chemicals
Food / Cosmetics
Process Chemicals
Acrylic Monomers
Glycols & Solvents
Sales Organisation
Whyte Chemicals, Marlborough House, 298 Regents Park Road, Finchley, London N3 2UA, UK Tel: +44 (0) 20 8346 5946 Fax: +44 (0) 20 8349 4589 Email: sales@whytechemicals.co.uk
www.whytechemicals.co.uk